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ACUTE TOXICITY TO AQUATIC INVERTABRATES (DAPHNIA MAGNA) TEST SUBSTANCE Identity:A mixturecontainingperfluorooctanesulfonatweh,ich may also be referredtoas PFOS, FC-95, oras a component ofFC-600. (1-Octanesulfoniaccid,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8heptadecafluoro-p,otassium salt,CAS # 2795-39-3) Remarks: The 3M productionlotnumber was not noted. The test sample isFC-600 (SCAS Treated Effluent*)C.urrentinformationindicates FC-600 isa mixtureof 1.0% PFOS, 81.20% water,12.00% diethylene glycolbutylether,1.00% sodium octylsulfate2,.00% propane Sultone foamer, 1.00% sodium decylsulfate0,.85% xanthan gum, 0.1% N-(3chloroallyhle)xaminium chloride0,.80% starch,and 0.05 % benzotriazole. The followingsummary applies to a mixture with incompletely characterizedconcentration of impuritiesthatwas treatedin a SCAS reactor.Date may not accuratelyreflectthe toxicityof the fluorochemical component of the testsample. Thisstudy isthethirdof 3 daphnia studiesconducted to determinethe toxicitoyf FC-600 afterbeingtreatedthrougha SCAS reactor.This study isthe controlforthe FC-600 SCAS Treated Effluensttudy. Itused the supernatantofa mixed microbialculturethatinitialcloyntainedno FC-600. The effluenwtas collectedafter4 hours oftreatmentina SCAS reactor. The inoculumused came from the Metro Wastewater Treatment Plant,St. Paul,MN. METHOD: Method: Not noted. Type: Staticacute GLP: No Year completed: 1977 Species: Daphnia magna Supplier:Not noted. Analyticalmonitoring:Dissolvedoxygen Exposure period:48-hours Test organism age: Not noted. Statisticamlethod: EC5o calculatebdy graphingdataand by probit analysis. Test conditions: Dilutionwater: Carbon-filterewdellwater,aerated. Dilutionwater chemistry: Dissolved oxygen: 9.4 rrig/L Lighting:Not noted. Stockand testsolutiopnreparatioVno:lumetvolumdeirecatdditiotno testvessels. Exposure vessels: Not noted. Number of replicates:two Number of daphnids per replicate:10 Number of concentrations: six Water chemistry during the study: Dissolved oxygen (final): 7.5mg/L (5.6% exposure) 6.5mg/L (100% exposure) RESULTS Nominal concentrations:5.6%, 10%, 18%, 32%, 56%, and 100% Element values: 48-hourEC50 = 15 (13 - 18) % Element values based on nominal concentrations Remarks: Testingwas conducted on thesupernatantcreatedfrom a SCAS studyas describedintheTest Substance Remarks field.The values reportedapplytothatsolutionand notthetestsubstance. CONCLUSIONS The SCAS treatedeffluent48-hour EC50 was determined to be 15% witha 95% confidenceintervaolf 13 to 18%. Submitter: 3M Company, EnvironmentalLaboratory,P.O. Box 33331, St.Paul,Minnesota,55133 DATA QUALITY ReliabilityK:limischranking= 3.This studylacksdescripbonofthe methodology used, reportingoftestconditionsa,nd informationon characteristiocfsthe effluenatfterSCAS treatment. REFERENCES This studywas conducted by 3M Company, EnvironmentalLaboratory,St. Paul,MN, 1977. OTHER Last changed: 6/28/00 -,7.40101 ENVIRONMENTAL ENGINEERING LABORATORY AQUATIC TOXICITY WORK SHEET Type Test 99 Hours - To,-ERA4kC STW Wi4luiA K"DA, Test Organism P-C-b-.,4L4;rauw Date Starte(@- 5@IR177 Material Tested Avg. Weight Date Completed Fe- (000 Se_A 5 CotaTIZOL Avg. Size Time Started Plotted LCSO Dilution Water Carb)On Filtered - Well Water (AAL'- ACRO CTC 1> -m 14 LSUPCPIPA-T@ 2W hrs 4,9hrs Conc. % D.0 % D.0 Survival PH ppm /Survival PH p pa C-6 7- /190 tod7, it hrs % D.0 Survival pH ppm /00. 7.2 96hrs % D.0 Survival pH ppm 72 7.2 Average Temperature Comments *.4r lr44;4_0.0, 1. 0 im 100 ri 4-1,@It 4 bl LC so Calculation ce 41 0 de E3 f 10 a to T -4 T@ -4- 20 30 40 so 60. 70 80 90 100 Survival uufi 'e @FRPrG@T,,10r+RE-SP[,INDINC@ FITTE@ FRRCTI llri 0. 15 2 7 I@-i567433 'ItiTERC@ -T 11 39 'Ent(t-,IC IINF.'.--L-1 M I T'@ @-.UUNF-- T--- SLOPE (]B>;. 142 96 a 7: L I NEFIR I TY,@, I SQ Fo PROBRBILITY ' 'l 12 8 6 0.5,687392,, c@ '-142551