Document GK1p4kzr39Yzg68MREBDJg6mV
PYRANOLTM COMPOSITIONS
GENERAL ELECTRIC COMPANY 1932 - 1976
* GE Specification - 1488, 1467, 1470, A13B3B. (1497 = A13B3B), A50P5.. # ASTM 0 2283 Type (_), Annual Book of Standards, Vol . 10.03. 1242, 1254, 1260 - AroclorTM PCB mixtures - Monsanto Chemical
T3 4CB - tri- & tetra-ch1orobenzenes - Hooker Chemical Sni4 - tin tetraphenyl - Hooker Chemica1(1944-1957),
Metal 4 Thermite Corp
EDDC - epoxide dicyclo-dlepoxy carboxylate - ERL 4221, Union Carbide 4 CY-179, Ciba-Geigy
PITTSFIELD. MA
1932-NOV 1944 1 488*
60S 1260 40% T3C8
NOV 1944-APR 1 952 1467
60% 1260 40% T3CB 0.125% Sn*4
APR 1 952-MAR 1963 1470
45% 1260 40% T3CB 15% T4CB 0.125% Sn*4
APR 1972-NOV 1973 A13B382 (F) 45% 1254 40% T3CB 15% T4CB 0.125% EDOC
NOV 1973-FE3 1974 A50P559
65% 1254 23% T3CB 12% T4C8 0 .125% EDDC
MAR 1963-APR 1972 A13B3B (B)S 45% 1260 40% T3CB 15% T4CB
0.125% EDDC
JAN 1974-END A13B3B3 (G) 60% 1254 40% T3C3
0.125% EDDC
1953 - 1963 1470
45% 1260 40% T3CB 15% T3CB 0.125% Sn*4
1970 - 1972 A50P559 65% 1254 23% T3CB 12% T3C8
0.125% EDDC
ROME. GA
1963 - 1965 A13B3B f B1 45% 1260 40% T3CB 15% T4CB 0.125% EDDC
1965 - 1970 A50P524 (Cl
80% 1242 13% T3C8
7% T4C8 ' 0.125% EDOC
1972 - 1974 A13B3B2 f F)
45% 1254 40% T3C8 15% T4C8 0.125% EDOC
NOV 1973 -- FEB 1974 A50P559 65% 1254 23% T3CB 12% T4CB
0.125% EDDC
SEP 1969 - OCT 1970 A13B3B {B 7
45% 1260 40% T3CB 15% T4CB ' 0.125% EDOC
MAR 1974-END A50P570
40% 1254 60% T3CB 0.125% EDDC
HICKORY, NC 4 SHREVEPORT. LA Pyranol - never used
/38Q0B
tor 12-29-87
(JLil* 000654
WATER PCB-SD0000029153
Designation: D 2233 - 86
Cil.il' UUUVK2J fill D 2233
1)1903 Test Method for Coefficient of Ther mal T.xpansion of Electrical Insulating Liq ride with lesser amounts of combustible gases.
uids of Petroleum Oiigin, and Askarcls' 1)19.36 I ts! Method for T hermal Stability of
Chlorinated Aromatic Hydrocarbons (Aslarels)'
4. DelaH Requirements
4.1Askarcls for use in capacitors shall con form lo (he requirements prescribed in Table I.
Standard Specification for
CHLORINATED AROMATIC HYDROCARBONS (ASKARELS) FOR CAPACITORS'
Jiid h Inord toxin ihr Oifd dtslgnalkxt D Jilt, the atmibet Imnirtlielely following the designation Indicates thf if id 11 fdiifHiofl ot. In Ihe [fK of rtf itttxi, the year of law rrvbroo. A number in parentheses indicates the year of hd
02129 T est Method Tor Color of Chlorinaled Aromatic Hydrocarbons (Askarcls)*
D40.59 Method for Analysis of Polychlorin ated Biphenyls in Insulating Liquids by Gas Chromatography'
3, Definition
3.1 nskarrt--a generic term for group of
Notr 4--Since October 1971 askarel produced in the United Slates for use in capacitors has conformed lo Type D aj shown in Table I. Materials previously available are still in use in the field.
Note 5--These materials sometimes contain addi tives whose presence may interfere with the chemical tests prescribed in Table I. Unless it b known that no additivei ate present, results of the chemical tests may be misleading.
.(X
f his specification rovers synthetic itonultlc electrical insulating liquids of the nated aromatic hydrocarbon type known ksicls, which are used as an electrical iiing and ctxtling medium in capacitors, specification includes liquids lha! were ottsly availahte and are still in use in
i slus ' Insulation systems incorporating these ieIs and cellulosic or other organic matemay, when arced, produce gaseous mixi that are moderately flammable, t AskartLs covered by this specification are nit types as follows: t I 7\fe A Biphenyl lha! has been chloled to a content of 42 weight %. I 2 Type B Biphenyl that has been chlo'ted to a chlorine content of 54 weight %. I 1 Type C--A mixture of approximately T fype f) 2213 B and 25 % trichloroben-
r.
I 14 Type f)--I he same as Type A, exteyd I tire higher boiling homologs have Ireen re ived lo a maximum level of 0.4 %.
fftrrt I--These statements are merely descriptions
the matcriah currently in common use and are not
rotted as pari of this specilienI ion, which b taml on
physxral and chemical properties present**! in Tn
I
Note 2-Current governmental tegtilalionj pco-
Ut the manufactuic and sale of polychlorinated H-
'tenyb ( cstareh) I hii methtxl b being maintained for
(ritnoe ol those uni'
-e slitl in service,
ft trf 1 / or infoi
in IX. It's in mineral oils.
D88 Test Methtxl Tor Sayboll Viscosity1
1)92 Test Method Tor Mash and f ire Point!
by Cleveland Open Cup* D9T Test Method for Pour Point of Petroletin
Oils'
1)664 Test Method for Neutralization Nunr
l>er hy Potentiometric Titration'
0 877 lest Method Tor Dielectric Breakdowi
Voltage of Insulating Liquids Using Drsl
Llectfrxlea'
1)923 Methods of Sampling Electrical Instil*
ing Liquids'
D924 Tesl Methtxl for A-C loss Character*
lies and Relative Permittivity (Dielectric
Constant) of FTectriral Insulating I k|iiHr'
1)974 I est Method for Neutralization Numba
hy Color Indicator Titration'
1)1169 Test Method for Specific Resistant*
(Resistivity) of Electrical Insulating (squab*
1)1218 Test Method for Refractive Index itJ
Refractive Dispersion ol llydrocartxm I*
uids*
D 15.33 Test Methods for Water in Insulatiq
I iquids (Karl Lischcr Reaction Method)1
1)1810 Test Mtlhrxl for Specific Gravity of
Askarcls'
1)1820 Test Method for Hydrolyzable CW
rine Compounds in Chlorinated Aromstic
11ydrooarlxms (Askarcls)*
!
1)1821 Test Mtlhrxl fiyr Inorganic Chlosidd
in Askarcls'
tynlhetic, fire-resistant, chlorinaled aromatic hy drocarbons used as electrical insulating liquids. They have a properly under arcing conditions such that any gases produced will consist pre dominantly of noncombustible hydrogen chlo-
5. Sampling ami Teal Methods
5.1 The material shall be sampled In accord ance with Methods D 923 and tests shall be conducted in accordance with the methods of tesl listed In Table i.
TV Amerirm Jwtrly for 7'rlttof onj Motrrlob tobn no portrlm rrywrh| rV rWlikTy of my pvnv rtgArr arKrtr) X
tomrrrtoo wfrh my Hern tmrrstornjkt ibh rlmJord. l/tera of (Ail rtanjmf oro i x/rrrrrty ojrbrd Ihol Jrtrrmhurtlon of rV rotUHy f my ml potent fljMi. onj the rli) of hfrtngrmml of nrch Ojto art enitrrly ibrir oim rrtyortrlblllty.
IVi MmJorJ b mbfrtl lo rrvbim ol my IX* It tV mponrtbU lerbrJcol commklrt onj non! be rerlttrj terry ftrr ytmt
xlfr reritrfi. titbit rroyororrj or wtlKmoem Tom etwranen/s me kirltnl rbbtrfor rirtetm oftbh itomiord of for odjtttoemt
Omomjr mj ihoetlj bo odjIfltrW to ASTbT Hmjynmlrrx Tom oommntit wft rrcrir* cmnfbi conrtJtnrtUm 0t m m+rtbig *f tk*
ififuIbU tr<h*ic*f rofnrrttne*, wkkk y*m
atlrnri IfjBfmfkri th* your c+mmer*9 k+r nrt rrc+frtJ 9 fair kraefng y** rKo+UJ
wAi^w viorg A.*0am i# tkr ASTki ComnmU* m Stan4*nfct l9t6 Roc* St., fkUadriphi*. Ra 1910).
J
11 hh iprrirKtllofl ft gmki (he }wfixfiefton of A.* FM Cc nttllfT l> 2/ on f IrOiHil lntulj|io| I iquitfs fend (ion tWfe |fw tfttex l trt^Mintihtlily of 5ul<t)tnntiflft I)) 7 0) Oft S)rtKr1iQ
.......over! I.ry FI, |9*6 PuMithcd MW
/
WATER_PCB-SD0000029154
4ft) D 2233
Datlgnation: O 2283 - 86
GCP 000656
Standard Specification for
CHLORINATED AROMATIC HYDROCARBONS (ASKARELS) FOR TRANSFORMERS*
Tlwi MiMUrd h hsunl uoda the fi*c<J dnifMlIon D 17%); the number immediately following the thrigratkm Indicates the year of
r%tns4 adoption or, in the case of revision, the year of Iasi rrridow. A namber in parentheses indicate* the year of Iasi reapproval. A mpcrscripl epsilon () JnJksfrr an editoWal ch*r>fe r>cc the Iasi revision or rrapproval.
rI
I. Scopt
her by Potentiometric Titration'
1.1 tills specification covers synthetic non ` D877 Test Method for Dielectric Breakdown
flammable electrical insulating liquids of (he
Voltage or Insulating Liquids Using Disk
chlorinated aromatic hydrocarbon-type known
Electrodes'
ts askarels, which are used as an insulating and
D92J Melhocls of Sampling Electrical Insulat
, cooling medium in liquid Tilled transfotmers.
ing liquids'
< This specification includes liquids that were 1)924 I ni Method for A-C 1 oss f haracteriv
previously available and are still in use in
lies and Relative Permittivity (Dielectric
apparatus. 1.2 Askarels covered by this specification are
of various types, having components in weight
Constant) of Fleelrical Insulating I squids' D974 lest Method for Neutralization Num
ber by Color-Indicator Titration*
' percent in accordance with Table I.
DII69 Test Method for Specific Resistance
' Not* I -- The components and the respective perrroUgrz given lie descriptive of the materials cutIttitly hi common use and ait not Intended as part of
(Resistivity) of F.kctrkal Insulating Liquids' DI2I8 l est Method for Refractive Index and
Refractive Dispersion of llydrxx-aibon liq
. tU> apecifKation. which is based on physical and
rhemfeal properties.
'
Not* i- types A through O are PC B type aa-
' larch previously available and still In use in the field.
| 1 htemlly Type II. a non Il'B aslarel. was introduced
uids' DI533 Test Method for Water in Insulating
liquids (Karl fischer Reaction Method)' D 1701 l est Method fos Scavenger Content of
. t as a retrofit and replacement. Noil 3 -- Cunenl govecnmental regulations pro
Whit the manufacture and sale of polychlorinated t Wphessyla (PC'Bs) ihii method serves as a reference
fc* ad askarels, PC B and non PC8.
Askarels' DI8I0 Test Method for Specific Gravity of
Askarels' DI82I Test Method for Inorganic Chlorides
in Askarels*
.
i 1 Applicable Documents
DI903 Test Method for Coefficient of Ihermaf Expansion of Electrical Insulating liq
2.1 ASTM StaruhwHs:
uids of Petroleum Origin, and Askirels*
D88 Test Method for Sayboll Viscosity'1
D2I29 Test Method for Color of Chlorinated
1 D92 Test Method for flash and Hie Points by
Aromatic Hydrocarbons (Askarels)*
(level* nd Open Cup'
D97 Test Method Tor Pour Point of Petroleum
**'
. ...
* thh sprvirkalton h Vrwlcf the fudwhclkm of ASIM Cavamiller 1X2? on FtcdrfcW lnsbtln| I Iqvld* and (inn and I*
, D445 Test Method for Kinematic Viscosity of the direct rrtfiomibtlity of Snbcommlflr* D? ? 07 on 5fnthrtk%
1
Transparent -`id Ojsnjne Liquids (and the
Cntnl ttlilHwi ayipro>td Jn ll, 19*6 i*uMW*fd Mtr
Calculatin'
DM.4 icM m
nainic Viu osily)'
(" Met.i. .t;.-i;..- m.....
1916. OrlfinaRy ptiMitltd ti D 22B J - 64 I I *9f ptoitAi lion IX 22H) - 82(I981f\
I1
i.'lijI
WATER_PCB-SD0000029155
<tj||3 u 22B3
3. Definition
3 I orAmc/--a generic Icim for a group of synthetic. fire resistant, chlofinalctl aromatic hy drocarbons used as electrical insulating liquids. They have I property under arcing conditions such that any gases produced will consist pre dominantly of noncomliusliblc hydrogen chlo ride with lesser amounts of combustible gases.
4. l>rtH Rnjulrements
4 1 Askirels for use in transformers shall conform to the requirements prescribed in Ta ble 2.
Nmt 4 --If more convenient, a measurement of dissipation factor may he made by lest Method l) 924 in place of the resistivily measurement. Iheoreliaf consideralrons indicate and experiment confirms that I strong statistical correlation exists between the dissipa lion factor and resistivity, however, other factors mod ify in practice the precise relationship predicted by theory. A dissipation factor at 60 11/ and I0U*(' that ir not in excess of 15 % shall be considered satisfactory
3. Sampling and Vest Methods
5 1 The material shall Ire sampled in accord ance with Methods D923. and tests shall be conducted in accordance with the methods of lest listed in Table 2.
TABl.t t AiImHi ('Mnyowitr h Wd|St Pmnt
C omponcnli
lie tachlor obi phenyl4 fent achiorobrphcnyl" T ricMombiphenyf TiKhlotobenrenc" Tri Ulr a blend' The noay pi opene oxide'
DitpsuiJf 1 ype compound^
Type A 60
40 0 14(0
0 12
Type 45
55
0 115 (o 0 115
Typt C
10 70
0115 to 0 1)5
Type D
70 30 0 II to
022
Type E
100
0 10 lo 0 22
TypeF 45
55
0115 lo 0 1)3
J |4>|4x-n)l < Mofinjlni lo a rhkwirvc conlrnt of 60weifhl %
* nyt a UtMtn>(n) 1o a I hkninc (onttnl of 5 4
%)
1 prfrKcnyl < hlminalcd lo a chk*in< content of 42wtifhl \
* A mtaiuic of itomm of nkhlo<ottnrfn<
* A miaiuif of itORKii of Ifichlorolxnrtnf and lelf achtocobenrene. r(Hyc%dyl pbenyltthcr.
3.4 rpoxycydohexytmethyl 3,4 tpoxycyclobcaane ctit>oi)Ult.
"Non l"< 0 contains no chlorinated biphenyl*
TypeO Type It1
60 40
100
O il) to 0 1)3
0 to) 0 25
il' 000657
U 2203
Tiopeily
IABI F 2 |)r(all Kf^rlornfali f< A^ltiuh fw lfiii'lfHiaf< -
Type A Type B Type C Type 1) TypeE Type F Type <i
Type II'
AS 1 T*
Mtth
Acidity, mg KOll/g. mi* 0 014
>0|4
0014
OOM
0 014
0014
0 014
0014
Color APIlA max
IV)
Condition
dear
Chlorides, inorganic, ppm 0 1
150 dear 01
150 ilcar 01
150 clear 01
150 dear 01
150 dear 01
150 clear 01
150 dear 01
max Mifivc permittivity af
) 7 to 4 0 1 0 lo 4 3 4 4 lo 4 9 4 3 to 4 6 4 7 lo 4 9 4 5 lo 4 9 4 ) lo 4 6 t J to t./
I0OT and 1 h)l< Dielectric breakdown volt )5 15 )5 35 )5 35 j) )5
age min. h V Fire point4
foaf point, mu. *C Refractive index. 25*C
nonelo nonelo none lo none to none to nonelo nonelo none lo boiling boiling boiling boiling boiling boding boiling boiling
32 44 >0 J0 14 42 - 30 70
1 61)0 In 1 6061 Is 1 6146 In 1 616) lo 1 6740
1 6060 )i 1 6110 t<> 1 SlbO lo
1 6154
1 6080
1 *IM
1 619)
lo
1 6070
1 6120
1.3700
1 6260
P9 I) 61 D7 *i'U 1> 1
I) 9
17
D
1)9 Di
gniiti.ity ! IOOT. 5 V/ mil. d c* min. 0 cm 100 X 10' 100 x 10' 100 X 10* 100 X 10' 100 X 10' too X lo' 100 x 10' too X 10"
Seatengei content. 4: fhenoxypropene oxide
l>Wpotde type com pound
Specific gravity. 15 5/ 15 5*C
0 10 to 0 22
1 560 lo 1 360
il H5to 0 1)5
1 560 lo 1 571
0 115 to 0 1)5
1 TIJlo f 425
0 II lo 0 22
1 510 lo 1 528
0 10 to 0 22
1 381 to e 192
0 115 lo 0 M5
1 ) 15 lo IS?)
0 1 i) lo 0 115
1 507 to 1 317
1) 10 to 0 23
1 101 lo i )j
Viscosity. Sayboll IJnivtr
sal. i at )2 0*C
52 lo 56 41 to 45
50 n> 55
56 lo 61
62 lo 92
19 to 4)
tt lo 46
11 to 4|
|I00*M
Cefficient of thermal ex pansion.* em'/rm'*( 00007
Water content max. ppm 30
7 0007 >0
0 0007 10
00007 30
00007 w
0 (XXI) VI
0 0007 10
(7 007 W
17 1 D1
ni !> 0
1) 1 f> 1
* When (citing for fire point. pseudo Hath may be observed: It differs noticeably from the flash obtained ft
tofabuttibU miioiili arid is not Indicative of Tire harard * See Note 4 r Hoc arc ippioaimile values included for Information only. *Hoc designationsrtfrv fo (he methods referenced in Section 2. * Non P( K contain* no chlorinated biphenyh
Hr American Sot ieiyfor 7rtfMg mf A/afrria/i takes ad yeiifioa rryrrf/n| the *alldtty of any potent rljAfi assettergwirrflda aid any hem mentioned A* /All standard. Users of /All Standard are expressly ajtised Ino/ determination of the rati ef any jv<A patent rights, and the riif of Infringement of nrrh rights, met entirely their ours responsibility.
lMi standardh tubfret lo rerlsion ol any lime hr the responsible lethnkaf committee and muxi Be reviewed erery fire .i. a*l f not re wised. either reappeared or iwithdrawn. Your comments are lurked either for rrelsiom of this standard or foe mddntt Standards and should be addressed lo A STM Headquarters fame comments will rretire tartful consideration at a meeting of rrponslblr tethnical committee, which you may attend. Ifyou fed that roue comments hare not rexcited a fair hearing you sh< nale your ticw% Hona to the A5 XM Committee on Standards, 1916 Race Si., thifadetphta. fa. f9IOf.
WATER PCB-SD0000029156
ASKARELTRADE NAMES
AROCIOR ASBES70L CLOPHEN CHLOREXTOL CHLORINOL CLORPHEN DIACLOR DK, INCLOR, FENCLOR DYKANOL ELEMEX EUCAREL HYVOL INERTEEN KANECHLOR N-3 . NO-FLAMOL PHENOCLOR PYDRAUL PYROCLOR PYRALENE PYRANOL --, SAF-T-KUHL SANTOTHERM THERMINOL
^Generic Name for PCB
SESO PROPRIETARY INFORMATION
MONSANTO CO. AMERICAN CORP, BAYER (GERMANY) ALLIS CHALMERS SPRAGUE JARD SANGAMO ELECT. CAFFARO (ITALY) CORNELL DUB I LIER MCGRAW EDISON
AEROVOX WESTINGHOUSE HOUSE MITSUBISHI (JAPAN) NIAGARA TRANSFORMER WAGNER ELECTRIC PRODELEC (FRANCE)
PRODELEC (FRMflCE) GENERAL ELECTRIC KUHUMAN ELECTRIC MITSUBISHI (JAPAN)
RDP/CE/040184 (3,
GCP 000658
WATER PCB-SD0000029157