Document G6jOEqJ14zMvbqERJMpd4KDgr
Occupational Sniolv and Health Administration
MATERIAL SAFETY DATA SHEET
Required under USDL Sflfntv and Health Requisitions for Stun Repairing.
V Shipbuilding, and Shipbrenking (29 CFR 1915, 1916, 1917)
CELANESE CHEMICAL COMPANY
c MANUFACTURER S NAME
SECTION
CELAIME5G CHEMICAL COMPANY
EMERGENCY TELEPHONE NO
512-584-3511
ADDRESS (Number. SlretJl. City. SMto .ina ZIP CT.ntr I 1211 AVE. OF AMERICAS, MEW YORK, N.Y. 10036
cmfmicai name ano jv-'nonyms
,,
,.
1-Propanol; n-Propyl Alcohol; Ethylcarbmol
^-^Propanol fN a^ropyl Alcohol
CHE MlCALFAMILY
Alcohols
____
FORMULA C3H7OH
SECTION II - HAZARDOUS INGREDIENTS--NOT APPLICABLE
PAINTS, PRESERVATIVES. S SOLVENTS
pigments
uo`t Applicable
%
TLV (Units)
ALLOYS AND ^ETAlUC COATINGS BASE METAL
CATAI YST
ALLOYS
VEHICLE
METALLIC COATINGS
SOLVENTS ADDITIVES
FILLER METAL PLUS COATING OH CORE FLUX
OTHERS
OTHERS
HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS. OR GASES
~~ )
i' |
I L7 `UwtM
-------------------
--
6 __ TLV
------------ - -
SECTION III - PHYSICAL DATA
760 mm Hg
207
-St ltth;. unrwiryttt-o^~---- ,, -----------
@ 20/20 C
VAPOR PRESSURE tmm Hg )
<3 20C
PERCENT VOLATILE
15 BY VOLUME t%)
VAPOR DENSITY (AIR-1)
~
2.07
EVAt'i IRAT ION RATE
(BuAc = i)
SOLUBILITY IN WATER
Complete
Vl-p'l /'MAM' '"ANDOOi'Vi
Water-White liquid; mild and nonresidual odor
0.8046 1002 1.3
c SECTION IV - FIRE AND EXPLOSION HAZARD DATA
) 1 HoIftV |fv>thoi ujveoi
84F., TeOeC*; 71F*, C.C*
V AMMARI y * IV: 1 ^
1
X by volume in air^__[2* 1^
13.51"1
< \ MNMnSHINC. Mr l)tA
Carbon dioxide or dry chemical for small fires. Alcohol foam for large fires.
'spicim i tf fighting pnort'Di-pi ;"
Addition of water vill reduce intensity of flames.
RECEIVF.n
j
UNUSt IAL FIRE AND EXPLOSION HAZARDS
_N ne
-AUG-2--1976
PAGE (1)
(Continued on reverse side)
SL 049650
Form OSHA-20
SECTION V- HEALTH HAZARD DATA
J
; I' t SMi >1 O LIMIT VALUE:
200 ppm;______________________________________________________________________________________________ ____ fw;E:CT? or nvrRF.xposun& Contact with eyes is extremely irritating and may cause burns. Breathing vapors
'will be irritating to the nose and throat. In high concentrations, may cause nausea, --dizziness, -headache. ..and--stupor .______________
FMERC.ENCY and FIRST AID PROCEDUHFS
Flush skin and eye_contact at once with plenty of water.___Get-JRfidi&al caie.for_.eyes..
--Remove,-inhalation_exposure_case_to fresh air. Call a physician.
SECTION VI - REACTIVITY DATA
"
STABILITY
UNSTABLE STABLE
CONDITIONS TO AVOID
Heat and flames
iMCOMRATAOIUTY (M.ilertnls to avoid)
X
__None__________________________
HAZARDOUS DECOMPOSITION products
Thermal decompos Ltion mav
HAZARDOUS
MAY OCCUR
POLYMERIZATION
Droduce
WILL NOT OCCUR
carbon
monoxide and/or
CONDITIONS TO AVOID
None
-X
carbon
dioxide
' ~)
f SECTION VII - SPILL OR LEAK PROCEDURES
STFPS TO HE TAKFN IN CASE MATEHIAL IS RELEASE D OR SPILLED
__Eliminate aIXsources of. ignitirtn. Flush heavily with water. Dike large spills
and dump to salvage tank.
WASTE DISPOSAL METHOD
__TnrineratP in A-fnrnafA
Notify authorities in the event of major spills.
)
c SECTION VIII - SPECIAL PROTECTION INFORMATION RESI'IRA IORY PROIL-CtlON (Spoctlv lydCl
-^iT^PPiied- respirat,<gr^-in-cnf ined -areas.
SPECIAL
PreferableMECHANICAL (General)
OTHER
----------------------- Acceptable-
pnof^CTTvr. gloves
EYE PROTECTION
.-Plastic gloves--
111Hi R I'ROTFh ilVE EQUIPMENT
CoveralXgogglea.
-.Impermeable_apron_and.boots; eye. bath.and_saety_shower.__
c SECTION IX - SPECIAL PRECAUTIONS F'HEC.A'jriONS TO ([ TAKtN IN HANDLING AND -jtOHINU
--Avoid breathing vapor.- Avoid contact_with_eyes---Keep away_fronuiieat,-sparks^
_and_fjtne.__ Do. jiot_leave..container-ppea.
( iTHER PRECAUTIONS
--None--------------------------------------------- ------ ---------------
J
D
PAGE (2)
o 44 : yK)
Fi*n OSHA-20
SL 49651
MATERIAL SAFETY DATA SHEET
"ESSENTIALLY SIMILAR" TO OSHA FORM 20
FORM 4040 (Rev. *40)
Pennwalt Product Niim
PtonwlK COO* NO.
Pen tap hen 67
0067
Channel) Name end Molacular Formula
Phenol, 4-(l 1-dimethylpropyl)C11H16
Synonym*
4-tert-Amylphenol, p-t-Pentylphenol,
MATERIALS OR COMPONENTS
% w/w
AOORCSSi Rudwiii Corporation
Three Parkway Philad lphia, PA 19102
Emergency Phona Humbert!)
Butina*) 215-587-7707 oihar: 313-285-9200
CAS No.It)
80-46-6
Chemical Family
Alkyl Phenol
HAZARD DATA (TLV. LD90. LCSO, ale.I
para-tertiary-amyl phenol
J8-99I See Toxicity S ction
D scription on Shipping Papers: Amyl Phenol
Shipping Containers: Plastic Bags, 50 lbs. net Fiber Drums, 175 lbs. net
Bolling Polnt/Ranoa
Malting Point
Freezing point
Molecular vr.ight (calculated)
265 C 509 F
c o p
Specific Gravity (H2OM) of DIETt--------- Vapor Netware |mm Hg )
91.5 C 196.7 6F
164.3
Vapor Oantlty (Alr*l)
.93 @>
100 C
@
C
F 5.7
Solubility In h20
% Voiatnat by Volume
Evaporation Rata
Moderate
0
........ .. T........
Appaaranca ano Odor
Otnar
White flakes - phenolic odor
Flath Point
Teat Method FlammaPW Llmlti
Autolgnmon Temoerature/Fira Point
mm
H
I*nC 250A OFr P-M CC Lower
EXTINGUISHING MEOIA
1 I water* LJ ipray
r~1 meter* LJ *od
1 1 Water LJ ttraam
SPECIAL FIRE FIGHTING PROCEDURES
1 1 Do not antar 1 I Allow tiro
LJ building
LJ to bum
1LJI
Water may cauac frothing
M8
% upper I 1 Dry 1 J cnamlcal
| | Do not um LJ wotor
%
I | Alcohol L . J foam
c
| ~| Foam
| 1 Earth or 1___1
in Quit esptotlon
hazard
Senttthre tdthock
Contamination
Tamporature
Other (tpecify)t
STABILITY
CONDITIONS CONTRIBUTING TO INSTABILITY
51 Stab*
1 lunatabM
1 1 Thermal
1 ] Photo
1 1 Polymarliation
I--1 oocompoaitlon
L_l degradation
| | Contamination
INCOMPATIBILITY Avoid contact with
Strong
I I Strong
|y~l Strong
I | Other
aciot
LJ aikaile
|XJ oaidUcr* |___J (tpedfy)i
HAZARDOUS DECOMPOSITION PROOUCTS THERMAL ANO OTHER PM)
CONDITIONS TO AVOIO
--
&
Spark*
Ignition
Other (tpeclfy)i
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
Pluait wNh water
dmoae el
Immediately
I | Abaorb with tend or inert matwni
I IOther 1 1 j(appclfy)i
I-TM!
LJ
s Sweep or tcoop up end remove
Keep upwind. Evacuate ancloiad tpacaa.
IWASTE OISPOSAL METHOD Contutt I tl, ftate, or local atrthpr/rrai for prop* dmpom! proewdurm.
Prevent apraed or tolll
SL 0^9652^
C NTINUED ON PFUFOCCCinF ^
Before using product, read and follow directions and precautions on product label and bulletins.
Oral <aeui*l
LD3nl830mg/kgrat.
Donti iMMlil
LDS0 2000 mg/kg rabbit. Irritant to rabbit akin.
Ey* Unwashed: Irreversible cornea damag i'n! ticietlon (acuta) Washed: Reversible conjunctival inflanmation.
Cnronic, Subcnronic, ate.
N.A.
-flfl 6J,
3
PERMISSIBLE EXPOSURE LIMIT (Spaclly It TLV/TWA or Celllny (cl)
Otner i
ACGIH 19__
I OSHA 19
Not established
IRRITATION CORROSIVITY
StSkin
ey (washed)
Sever* Severe
Skin
t hra. (DOT)
5A1--M--o-d-e--ra-
Moderate
I 1 Mild (trannant)
Q as w*. (cfsci See Toxicity Sectio
Eya pn mMiay cauae nilndneaa
____ (above) .______________
SENSITIZATION Qshln
l~~l Ratolratory
LUNG EFFECTS (Spectfy)i
AIMryen
INHALATION EFFECTS
Narcotic
attaet
|
| Cyenoua
Q Aiphynlant
Fumes from molten product and dust mav cause discomfort.
OTHER (Specify):
Repeated contact
min dafattar
INGESTION
induce
vomltm*
DERMAL
m Fiutn wltn toad and water
I I Otner LJ (Specify|i
o NOT induca vomit my
B Gat medical attention
Give plenty of water Bother
Gat medical attention
Otner (toaciry)i
EYE CONTACT
| vI Fiutn with plenty of water for
|V I Gat medical
Other
|AJ at Matt IS mlnutet
INHALATION Remove to
train air
if not breatninc, ive artificial retolratlon
(J attention fl Give I--I oeyyen
(tpeclfy)i Get medical attention
ventilation requirements -- AJwmyi mamam exposure below permissible expoeure limns
Comult an Induttrial nyplenltt or environmental naaitn tpecielM
Local .e.e..h.a..u.t.t
r[AyJi Ute with aoeouata
|~"j Other (tpecify)i Check tor air contaminant and oxypen deficMncy
0 Other (tpaclfy):
Avoid breathing dust
from solid product or fuses
from molten produc
5
Si
S
EYE
Face
HAND (GLOVE TYPE)
Butyl
Safety
Qssssr eiattet
mieid
0
RESPIRATOR TYPE Use only NIOSH /MSA approved equipment
ruooer
Natural '
Saif*
contained
iir
Can or cartridge 9t or vioor
b Filter dutt.
OTHER PROTECTIVE EQUIPMENT
I I Soot*"
Q Apron
Otner
Polyvinyl
aicono!
(--1 FolyI I ethytene
Other (wcclfy)t
fI vXl||
Other f(tpeelty)i
Any of thes
(tpeclty)i
PRECAUTIONARY LA6ELINQ
Watn thorouphly
after nandilhf
E Do not yet in eye*, on tkln or ciotniny
BOo not More near
computtipiet
Keep from contact wltn ctothiny and otner comouMioie material*
a Oo not breatne dutt, vapor. Empty container may contain heurdowi retidwei
Other Itandllny and ttoraye condNIon*
Keep container doted
Ute axplotlon proof equipment
Keep away from
heat, warkt, and 1 ooppeenn nflaammee** Other (ipeclfy)i
rn store In tientiy | | cloved container* "
SL 049653^
Prepares by
Oat*
Addteta
. ne
Lee W. Dieste low
3/3/82 Three Parkway, Phil dclphia, PA 1910k (215)587-77
i c ...
*TM wmwmenwn n kwuii is inv pvh of our enowteoye. However, tlnce data, Mfety standard*, and yovernment reyulatlontar* tublect to
^ cnanye and the condition* of handllny and ute. or mitute are beyond our control. Pennwait MAKES NO WARRANTY, EITHER EXPRESS OR
~ LMfV,ED- WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN AND