Document G6YELJDpoZqVOG8ON3enqKQEr
:
\Y3RESEARCH Foe Re.
Attachment 2
E2271 - 776-
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Air Sampling Fluorochemical Report
DuPont Washington Works -- Air Sampling Program Round 10
Exygen Research Report No. L0001667
Testing Laboratory
Exygen Research 3058 Research Drive
State College, PA 16801
Requester
Michael D Aucoin
URS Corporation
LBauncialBsdatirenlrgeyP2i7MkieRlloanoPdlmaRz1ia261401
`Wilmington, DE. 19805
z.
2 8 ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
preter
SekEig Bon, usa
noaas sAEiLTEE
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f Summary
[TM Seven solid media samples were received by Centre Analytical Laboratories, Inc. (dba Exygen Research) (Exygen) from DuPont Corporation. The media represent samples of air collected on
{OVS tubes. Please see Table 1 for a completed listing of samples received and field air volumes |" collected. Results are not reported for sample WWK-A-AMS2-E10 because of sampler
malfunction. The samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography (~ / mass spectrometry (LCMS). The method employed is entitled "Method of Analysis for the [Determination of Ferfluoroocianote Acid (PFOA) in OVS Airtubes by LCMS" (James Miller, Exygen Research, February 17, 2003). r The OVS tubes were separated into three fractions for specific fluorochemical analysis. ~ Fraction A consisted of the filter, backing material and plastic ring. Fraction B contained the [first bed of XAD resin and the PUF backing. Fraction C contained the second bed of XAD resin and PUF backing. Fractions A and B were extracted with 1 mL of methanol. Fraction C [7 was not analyzed but saved for possible future analysis. Perfluorodecanoic Acid (C10 Acid) was added as a surrogate spike to each fraction prior to extraction. [instrument operating conditions can be found at the beginning of each analytical run. Raw instrument data is given in Appendix A. Chain-of-custody information can be found in
I Appendix B.
|
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
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Page2007
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650453
Results Summary
f
Ar Voumo
Coad
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WWAASS1100A8
r
AWAAKAS!1E01(0T0o)
|
TWAAKIaAASSnIIEE1s1008A
WKAUSIE10 Toa
Sampled (L)
(mg/m3)
11044477 1a47
Z<o0..0000000077 NA
0.0007
i11841138
<00.0r000y00407
Tew
[
WAAMIASASE1E08A
11441100
<Z0o.0000000077
I
WHWWAKANAIMSSHSE1-0E1T0oC)
T 1410 om NA
.
WKANISS--EI--OS
11a4s811
|
VK AANSS10C
1451
<00.000000807
NA
WAKA HSS 10 Ton
Tew
|
WAAKNSAIASNSSSSEEEIII00ODCA
111444885666
<<00..N0000A000077
I
WARHSO 10 To) T CC ow]
NA =Not Antyzed. fraction was below the quantitation limit estore the backup faction does not require anlyss.
[ 1. "<"is defined as not detected at or above the reported level.
| 2. Sample results have not been corrected for blank results or control spike recoveries.
a 3. Please note the following descriptions of the OVS sample tube fractions:
a8 F1istsEtrebcetads extact
Cc
|2nd set beads extract (not analyzed)
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
|!
Page 3007
000454
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PZELGE 338
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204a55
Surrogates
[aSursruorgraotgeatsepiskpeikreec(oCv1e0riAecsiadr)ewgaisveanddinedthteofaollllOoVwiSngttuabbeles.toTghievreeaarfienanlocsoentccernittrearitaiofnorofsu5r0ro0gpatpebsipnikthee extract. [7 recoveries. Advisory ranges are 75-125%.
[[moee me | og2re [regAres[Peze] -
ppb)
ppb)
(5)
: VIWKWAKAAAMMSSFLBLECIED1ADB 550000
555440
m10n8
|
WWOWNKKAAAAMMSSIS-EEN1008A
550000
55294
WKAAMSIEID 8
500
504
111059 119
e WWCAAMSAEIOA
500
517
103
VWKKAAAAMMSSSSEEIIOBA
550000
5a2901
1804
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WWNCKAAAAMMSSEEE11008A
550000
395217
ono SpaA
500
522
17085 104
[
Gonirl Spe 8
500
337
7
* Surrogate recovery outside of advisory range.
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
|
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:=
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[~ Example Calculation
For sample WWK-A-AMSS-E10 A C8 Acid,
I
= [39 ng/mlof C8 Acix(d1 mL)x (1 ug/1n0g)0x0(1mg/ 1000ug)] / [(1451L)(x1m3 /
i
1000 L)]
I
= 0.0003mg /m3
I ote
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Law
oo --
3 Connaly, LEMS Team Leader
~
2
|
John M. Flaherty,Vie President
| Otherto Members Contin Data
|
James Willer
2 abn Date
Date
ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH
Page 7of7
|
Cn0ass
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ANALYTICAL DATA REVIEW SHEET
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LC/MS
r
Toes R. Milles
A pie Focfy
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Analyst
Sigrfature/Date
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Toko Flefewty
24m lf sab
Reviewed by
ighature/Date
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0008
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LC/MS SYSTEM AND OPERATING CONDITIONS
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Client: Dupont
EXYGEN STUDY: _ L0001667
-
|
Instrument: Hewlett-Packard 1100 LC/MSD (LC/MS 3)
APL-ES Interface - Negative SIM mode
[:
Nitrogen: 10 L/min at 300C
Fragmentor: Variable; Vcap: 3500V
I
Computer:
Hewlett-Packard Kayak workstation
r
Software:
Microsoft Windows NT 4.0
Agilent Chemstation Version A.08.03
I
HPLC Equipment: HHPP GG11337191AA SQoulavteenrtnaDreygaPsusemrp
|
HP
HP
G1313A
G1316A
CAuotlousmanmpTlheerrmostat
HP G1946A MSD
|
CHoPlLuCmCnoTleummpn.:: T3h5erCmo Hypersil-Keystone Betasil C18, 30 x 2.0 mm x 3pm
I
Mobile Phase (A): 2mM Ammonium acetate in OmniSolv Water
Mobile Phase (B): HPLC grade Methanol
-
Ti0m.0e
7A0 %3B0
|
6.0
10
%
I
1010..00
st10op st9o0p
Post Time = 4 min.
Total run time = 14 min.
r
Flow Rate: Injected Volume:
05.p3LmL/min
-
|
Paugel1 ouf2g
!
[LE]
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lons monitored:
I
Analyte
CB Acid (PFOA) C10 Surrogate
lon (m/z)
369
469
Extraction Date: January 21, 2004
|' Analyst:
[
James R.
ter
'
501 Yetey
Exygen Resear
3058 Research Drive, State College, PA 16801
|
Phone: (814) 272-1039, FAX: (814) 231-1580
|
Paugeo2i01o2
CnNast
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msm/z 2600618.794Bwg0.00.264
am/z 2110003836.97pu'g0.01.065 hy
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A`bsu0n35d2 21400
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2004 8.4106 x
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16 thReosSietuaenogferiisradtoEnvsclnei.(henbdrieocnyecpirnegc:ious bracket)
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& 1000-00000 1 5a0t008 7 dieses
7 1500100000 1.805796 8.306608-4
sore compound-specific settings:
|" ComEpoeundi: neC8sAcid
+ From 7.083 min To 5.088 nin
~ Compound: C10 surrogate
Tr
TT peak sum Table
Ere eeses eso
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439659
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FRoersmiidluaarl yoStd. mxDevs.b: 57325.18366
=
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mbii 761013975..2758534539
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|" 200814 2/26/08 3:07:13 a
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Sample Nane:ST> 50 ppb
:
I Sample Info:Warm Up Injection
Data file :C:\KECHEM\I\DATA\Chemstor\12075253\AS32864\2C00000>1
f| AITcnnqjseeocuptmeieronanttoprate |:: pj1em/oiol2alte1sr 70 ~ pidwion i
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Tha, 26. Feb. 2008 03:42:51 am
Page 1 of 1
ch1n04a6g:s
Sample Nase: 50 ppb
:
| Sample Info:
Data file :C:\HPCHEN\I\DKTA\Chemstor\12064016\ASZ3984\RCO00002.5
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Sample Nane:ST> 100 ppb
1
I Sample Info:
Data 4le SC:\HPCHEN\1\DNTA\Chemstor \12064886\A332032\FC000003.D
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TTT
| 2c00414
Thu, 26. Feb. 2004 09:32:30 am
0020
Page 1 of 1
cnnavL
Sample Nane:570 250 ppb
'
r Sample Info:
Data file .C:\HECHE\1\D1N20T64A36\4\CASh34e14m4\FsCDt00o00r4.\5
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+++ EndofReport +++
TTT
|| scooese
Tha, 26. Feb. 2008 09:30:20 am 021Page tori QNDATRY
Sample Nane:STD 500 ppb
.
r DSaatmpaleEilIenfo:1c:\HPCHEI\L\BHO Cheator\ 2075910\KSHL95ARCE00005.
" Injection Date : 1/21/04 6:16:32Bu SeqLine +s
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i I, La | Conpound Name [le ei IEEE EE c8 acid
Area 305549.25
Amount 570.33
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7.260
MSDL 369, EIC<368.71369.7
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[ SSaemmpilee NTaarmee: i570 750 ppb
.
I Data file _:C:\HPCHEN\1\DATA\Chesstor\ 12076078\AS44064\FCO00006.D
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[SSamEple MRamEe:sT 1000 ppb
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Data Eile: \HECHEI1\DNTA\Chemstor\12076271\AS46176\C000007.D
" | | [|IneSTjsaeetcreotipimeneoranncteDrate :|+| 13eJ/abta2ito1ss/08 6:47:4m2H
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IInaTjonaedcrotpmieeornnattDoar te|:| LbJ3eaLoio/li0et4rs 703118BH SVSeqiNetierne a i e 17
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Tha, 26. Feb. 2004 03:27:30 am
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Data file :C:\HECHEN\I\DATA\Chemstor\12076641\AS50528\7C0000009
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|
Sd1c/mo2io1ti/et0rs4
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Data file iC:\HICHEU\1\ONTA\Chomstor\12071376\A870144\FC000010.D
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[SSameple NEamEe:11667-23
Data file :C:\HPCHEM\I\DATA\Chemstor\12071465\A872512\FC000011.D
ST. {| InAIjcneqsctortpuimeoernnattDoarte |:: m1P/Ci2Ol1Gl/4e0Lr44
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Thu, 26. Feb. 2008
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foe | [ AIIncnsajterocutpmieeornnat.tDorat|e ||: sB1m/oi2ol1o/ir0es4r
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-- Thu, 26. rab. 2008 00:45:10 am 0031sage 1 of 1 cna~
SSaimple Name:11667-5 i Data file iC: \HPCHEN\1\DNTA\Chemstor'12072196\ABL216\FC000015. R | Bpreeiesmaetle:l1i0H r Thneee suilz: R I" rreqi,vanS oeshmoeathod A +| &peVnAtMo\nWETHODS\0LL210E81, an
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Thu, 26. Feb. 2008 08:49:54 an
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Sample Name:11667-7
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Data file :C:\ECHEM\I\DATA\Chemstor\12072360\AB83328\FCO00016..D
[7 AIZcnnasjterocuptmieeornnattoprate || h1Jc/mo2io1li/li0es4r 9:08:00 BM SeV5qanLeNien.se : 1671
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Thu, 26. Feb. 2004
08:50:58 am
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Page 1 of 1
Cnnasd
[7 Ssaammpilee Nmaarmee::L1667-8
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AIIcnnsqjterOcutnpieeonntr.aDattoer:::
j1/n2i1l/l0e4r 2cooara
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Thu, 26. Feb. 2004 08:53:52 am
Page 1 of 1
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[= SSameple NHamEe:L1667-10
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Data file :C:\HPCHEM\I\DATA\Chemstor\12072788\AS8T744\FC00001>8
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[AAcnE aa.lysMieR s tMehtohodd:| EsC:c\aA-EPiC0H.EuM\1\METHODS\00182:14014:06 am
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Thu, 26. Feb. 2004
08:56:36 am
ulss Page 1 of 1
NNA86
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Thu, 26. Feb. 2004
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Page 1 of 1
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[ req, eros sen Data file :C:\HECHEN\L\DATA\Chemstor\12073158\A891965\FC000020..D
Ir AITcnnqajtercOutpmieeornanttDoarte :|| 1p/mc2io1l0/ld0ei4rd Dilution i
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Thu, 26. Feb. 2004 09:02:39 am
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Page 1 of 1
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Sample Name:1667-13
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Data file .C:\HECHEN\I\DATA\Chemstor\12073506\AB96256\C000022.5
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aot ReperenT
or
| |" acoonra
u040
Tha, 26. Feb. 2000 09:05:29 am
mee iott
onpast
sample Name 1166716
.
"sample Info:
Data file .C:\HECHEI\1\DATA\Chemstor \12073684\AS00416\C000024.D
. bHIleniajwecocrpiteoiarnoanstoDra"te J|: sm1o/i2la1t/en0r4 11:12:32 BM SanfeqntiLveeiel.n:e
oo AhLeanasd.tiyaMCiehstahnMogadetdhod |+ CrSoio\daRe-Rr1oC0nH.EuN1\HETHODS\01G2a140145.0164 am
L/S analysis of pertluorsoctanoie acid.
[TTRTO REE FE
sou {
7254
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[| w= | ast G10Sue,! || i
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2S1%8a20a5.5208
3E 95.72 S 7.254 MWSebDiI 316690,. EEiIcCw-i3g6e8.7v:i3e69n.s7
o
+++ End ofReport +e
CTT
[--
Thu, 26. Feb. 2004
09:06:15 am
u041
Page 1 of 1
chao
- fsaampmlee Neanee:11667-17
.
Data file GC: \HRCHEH\IA DATAChemscor\L2073773\A902466\FG000025.5
B bhceihmeonre: TfiE luer m m ri e e suxl{
I Aseyg eMsethvodamos |+a Eresm-1i0.un wemmoD 0T121E000
1/25 anaiyeta of perstusronctanois cid.
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Endof Retp ee ort
I
--
Thu, 26. Fab. 2004 09:06:55 am
rage 1 of 1
cn0493
Sample Name:11667-19
I Sample Info:
Data 416 :C:\HECHEH\1\D1N2T07A38\62C\AhSOeA4mOs\FtCOo00r02\6.D
[7 rTSobotmrmimeeantmsnaeti||TfMooaidinnotie ~ Bieion i
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move
su
[Miaiysviosrrmeedthod |+
[EE
Croe\RnPoCHnEN\L\HETHODS\012104 4
0541108
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I]
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CHROSRSRGEROS) APES = fy SN.Fiar
|| ow
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=
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||
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|
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- | joan rnI|I
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|
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u043
Sample ane:11667-20
[* Sample Info:
I Data file SC: \HRCHENL\orD!1N20T739A51\\AC007h52a00mC00s00t27.5
[ETseteiema Lfaan ebs = Hi
ile mThae tee 1e5: RL sul
i Aoseegt,fiveHaeethheoidthaod |+ &pegp-m1os0l.WETODS\01S210E81. an
IU a wems analysis of perfluorooctancic acid.
r= ~ -
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Thu, 26. Feb. 2004 09:20:44 am
ul044
Page 1 of 1
00495
* SSaammppllee NInafmoe.:STD 500 ppb
Data file :C:\HCHEM\I\DATA\Chemstor\12074040\A913664\FC000028 .D
[| InAIjcneascttoruipmoeennrtaDattoer::| 1j2C/m02i02l4/l10e44r 12:14:A56 SvIienajq.lnNNioo..ne:i 284i
i|
Dilution cq Method
Hh : rcg-10.x
mil vel. :
su
[LaAnsatiysCihsaMnegtheodd:: C2:/2\6R/P0C4HEM\1\METHODS\0031:24110:406. am
| 1e/us analysis of perfluorooctanoic acid.
r
HST560EC-38873607 GHENSTORY SSRRCOOIRER APEWoSS,WFag Var
|
7260. Canc
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781.12369 uNSSDDL 346699,, EBIICC=-346688..77::346695..77
CTT end of report wee
or
|| ecooata
Thu, 26. Feb. 2004 09:22:50 am 045Page 1 of 1
Erase
Sample Name:solvent. blank
| Sample Info:
Data file :C:\HECHE\I\DATA\Chemstor\12074178\AS17504\C000029.D
I" InjectionDate : 1/22/04
12:30:24 A Seq Line :
20
pr E ATcnqtre Oupmeernastor +i1 jbomoiolallesr
vial voNnoee..l
su9l23
pr AAE cnqa.lysMie es twehtohodd:| CEaoc\BH-aP1C0H.E4N\L\METHODS\00182:140141064 an
Les analysis of perfluorcoctancic acid.
r SOT E08 7089 REN TORTaI AGREaRo0as BAegSPWFgE
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|
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SNSDDIL 346695,, EExIcCe-d3e6s8.774:63659..77
or
"ii Endof Report trv
or
i |
| ecovata
Thu, 26. Feb. 2004
09:23:54 am
uu46
rage 1 of 1
[BLE
Sample Name:STD 50 pb
| " Sample Info:
Data file :C:\HPCHEM\I\DATA\Chemstor\12066508\AS83120\FC000030.D
|| " AtTcnnqajteorcutpmieeonnrtaptatoer:|: 1m3/0i20l24/e10r44 12:45:A50 VSIienaqglLiNNoon..e
[oe it
In vel.
[rAAcnEqa.iysMiienstheMoedtthod :| CrS:ca\aR-dP1C0eH.ExN\1\METHODS\00162:14014:06 am
Lo/us analysis of perfluorooctancic acid.
I
RE
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uu4/
Thu, 26. Feb. 2004 09:49:39 am
Page 1 of 1
cnoa9g
_ sample Name:5TD 100 pb
:
1" sample Info:
"pata file :C: \HPCHEM\1\DATA\Chenstor\12066543\A991168\FC000031.D
|[J" vISonjteecpetiotnppate
:1 ih
1ii/22oe/04
1:01:27
AM
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|
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:
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le Info:
file s
c
:
\WRCHChaEnstoNr'1\2066L595\\A9SD304N4\PCEOR0A032.
5
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TTT
CT EndofT Report eer
CTT
-
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Thu, 26. Feb. 2004
09:47:24 am
u049
Page 1 of 1
nn. 12500
| fl sample Name:sTM 500 ppb
'
| Sample Info:
Data file .C:\HPCHEN\I\DATA\Chemstor\12074750\AS26656\FC000033 0
|[7 fInrjeecotreiaorntoDrave: | CJmmariierosis me sHLeaareieme
y ii e
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sul
S | Aacnad.iyB sviesthVoeathod ||+ CSre:s\-HE1P0C.H0ENI\ETHODS\S0al1e2l1i0o14s6 om
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| - ST RTTCFESTORTES AASFOE) APWToorEeSWStFea Vo
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u050
Thu, 26. Feb. 2006 09:46:45 am
Page 1 of 1
&n0o501
Sample Name :STD 750 ppb
.
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Thu, 26. Feb. 2004
09:45:52 am
wus
Page 1 of 1
cNNsS02
[7 Ssaemmpplree Nzaemee::STD 1000 ppb
1
Data file :C:\HECHEN\I\DATA\Chemstor\12075056\A930880\FC000035..D
7 es. vores renin I hIIennqsjteOrcutpmieeonnrtDaattoer::| 12j0/m02i02l4/l10e44r
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i
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3 5 sul1
I ALansatlysCihsangMeedthod :| C2:/2\6H/E0C4HEM\1\METHODS0\80:14211:0.0644 am Le/kS analysis of perfluorooctancic acid.
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{| ecooars
Thu, 26. Feb. 2004 09:45:07 am
uub2
Page 1 of 1
"0503
Sample Name:$70 1500 ppb
I Sample Info:
Data file .C:\HPCHEN\1\DATA\Chemstor\ 12071280\ASE7969\FC000036 0
||" rITnnojgretocrrtiaimoecnnotrD"ate |:| ab1ei/bi2o2ia/er0rs4
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Thu, 26. Feb. 2004
08:42:42 am
u053
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