Document G6OB25q9np9Y6k7XZxV74X91m

-*\i' ; V4 V'' : ,J*w >. ?! * fi.' '. ^ v ' *< .'`.-**J./... '-.-'7v~r'J*'. **" * ` t % * - . . , , *V 1'* it * *m c ; :->0'/i- 1 'r nc% *4; ,v- MONSANTO CHEMICAL COMPACT ORGANIC CHEWCAIS DIVISION XXXRO, VEST TOOINIA . if'i MTM sS& a >&>. r-V'i *"*"i _r,, '. lK.- ^ _-" ( .. .*7, V '" : 1 * -,1L . ; ` ! , ' i'* t'f^i t / .*'J* '.**' iv-.s-vi/. ` - M H t n m i m t w w m w w i > S tandard M anufacturing Proceaa fo r Sodium 2,A ,5-T richlorophenete In . Department 095.06 X evleeat S tandard M anufacturing Froees* Vhnual preperedvfcf L*-P. H arleb July 6, I960. R eviled: June 6 1962 R eviled By* J . T. Pebeorth Approved By: R e itirc h Group Leader S afety D irector ' Production Superintendent . W 'VPS T his la copy 1 _ o f 15. A -r< 'it ^irrp*> *. ^ ~ i*-./* r'VV*? 'Ti vr/\V>Jii >> ~ .. : "'- i 1 -,,t 6T,` wf- V _ *' "* ` / ; * ' '" * :f,l 7 . V o ' .> -^..V - - - * f - . f t - " v . v -i:'. V rr ; -r-. * ^ v V - T V . - \ **'? . ' yj- ', VV x "\ * ' n ' > * *3TABLE OP CONTENTS SECTION I SYNOPSIS OP PROCESS SECTION I I PLOW SHEET SECTION n x PROCESS IK DETAIL SECTION IV co k x q tts ok t h e p r o c e ss AFFBtOlX A Eq0IPKEHT LIST AFMKDH B MATERIAL SPECIFICATIONS AFHWD3X c PHYSICAL CONSTANTS DATA APPENDIX D UTILITIES APPSKDIX E PERSONNEL APPENDS F PACKAGING AHD SHIPPING APPENDS 0 MATERIAL BALANCE > APPENDS E STANDARD COST SHEET > AFFHtDS I PROCESS CONTROL PROCnJORE ' *" APPENDS J SAFETY AND TOXICITY DATA APPENDS X KATERIAIS OF CONSTRUCTION APPENDS Ir BACKGROUND INFORMATION APPgHDS H TIME CYCLES m w a x r KCSCZUANEOUS PAOE NO. 4 5- 6 T - 10 11 - 12 13 - 15 16 - 20 21 - 25 26 7 26 29 - 30 31 - 32. 33 ' 3* - 41 42 43 - 44 ' 45 46 - 56 001780 appekddc j samar m v tgrain pm g e n e ra l The Sod lux TCP a o lu c lo n produced c o n ta in s chem ioal compound* known a* " eh lo racn e gens . These m a te r ia ls , a s y e t not iso la te d or id e n tifie d produce a fo r of d e n a a tltis Imown a s e h lo rs c n e , very s im ila r in appearance to cocaon a c n e . Care s u e t be taken to avoid c o n ta c tin g the s o lu tio n of Sodium TCP o r th e h o t vapors from the s o l u t io n . P erso n a l c le a n lin e s s frequent washing, b a rrie r creams, are a l l necessary to f o r e s ta ll ehloracne exposure. la a ism ' 1 . T e tra c h lp ro b e n te n e - The mete r i a l la m ild ly t o x i c , c a u sin g n au sea. R e sp ira to rs and mono-goggles are req u ired f o r handling, 2 . Sodium TCP - A c o rro a iv e m a te ir a l. Rubber g lo v es and g o g g les are required. 3. Methanol - Highly to x ic . R eapiretors re q u ire d . 4. Tars - A h ig h ly a c tiv e chlorecnegen. Complex p ro te c tio n of tbs akin-and eyea required. 5 . g u s t l c ^ S |d a - _A__h_ig_h ly c__o_r_r_o_s_i_v_e_ t e r i a l . and re s p ira to r a rt required. Rubber g lo v es. Ba D im ethyl E th e r - n i l s b y -product has a b o ilin g p o in t o f -27*C i t 760 mas and i s v en ted th ro u g h the condenser when the b a to h la tranafm rred to the s t i l l . I t ia a highly lnflam nable g a s . T h e 'o p e r a tin g a re a must be k ep t fr e e from a l l s p a rk so u rc e s w hile th e a u to o la r e la under p r e s s u r e . Any le a k s > -.-r- In th e sy stem v l U a llo w th e r e le a s e o f d im e th y l e t h e r . .' -vv -cl.ir.t--;rW "_ ;:-id .* \ . v ' 'T -~Sr' ' .The -Y- flash poin " t r--^ *A. ^ t (c lo s e d v cup) Is -40*p. Methanol - Methanol is a highly inflammable m ateria l w ith a b o i l in g p o in t o f 64*C. Zta f l a s h p o in t la 12*C and i t s a n t o - l g n l t l o n tem p eratu re la i70*C. The e x p lo siv e l i c i t * w ith a i r (% o f volum e) a re 6 .0 to 36.5%. *' * ^ The as ami p re c a u tio n s a s f o r dim eth y l e t h e r a p p ly . .t. ' v -v\ . -'-1 001813 i w.