Document G6L6KqNgReaEQmdQkYLkdEowY

Monsanto11496 copyi MONSANTO ft(MARCH CORPORATION / DAYTON LAftORATOftY / DAYTON. OMO 40407 ESC - DAYTON /HCT> ANALYTICAL IWI 0* 111FONT RIROAT IMPORT NO.: HDA 436 JORIPROJCCT NO: 443.2510 DAT! 22 Deceeber 1913 PtftiOD COVIREO nni: analysis or samples tor pcs's RECEIVED JflNC ^^JO-DAYTON CENTRAL PILES 2 2 3 `A i ii ii authors B. N. Hughes ASSTRACT: Saeples Iron the MOTCO, Texas City Kaste-site were analysed (or possible PCS concentrations. Tho results of these analyses are shown in this report. Technical Approval JJJ. Brd Research Croup Leader Approved By t X. R. F. ivory CJ Environmental Sciences Center Service project Manager Approval Data: r ? i DO COMPANY CONFIDENTIAL RONS 022252 COPY NUMBER 1 V. M. Schotts TIED 2 1. r. Ivory 1250 3 B. H. Hughes 1250 4 Central riles 1250 3 Technical Beports Library K2C T :O\ abstract only R. M. Scott 02B H. A. Molteraan 1250 NOTEi Distribution of this rsport is restricted Requests for additional copiss should bs uds through ths principal contact at ths Monsanto location involved or ths Hangar. Environmental Sciences Center, Dayton Laboratory, Dayton, Ohio. ACKNOWLEDGEMENT Contributions of the following Dayton Laboratory personnel to this project ars gratefully acknowledged: Analyses: B. M. Hughes David McRentie Chi Trang O COMFinFMlAI HONS 022753 ANALYSIS REPORT LOO MUnSCRi 1-93-11-29-Ol 1-93-12-04-01 I 3-12-00-01 DATEi Deceaber IS. IN3 PROJECT NOi 493.29919 PRCHI Hr. Vlrtll Schttli *r Or. Rebert Fere HNOnrl-Cll Ceneultante 7330 Ueetvlea Dr. Htufttfl. Texae 77059 CnvIrtMMlil Science* Center Heneante Reeearch Cerreratien ISIS Nlchela* Rea* Devten. Okie 4S4I9 Phene Net ISI3I 249-3411 Title! Anal me ef MOTCO HazarOeue Malt* Snarl** far PCtl Stan4ar4 Snarl in* Hethe4 Helen M/A Staneare Cxtractien Hethee Meleli PCCXOI Stealer* Anal re I Methe* Meleli MSAN03 Pinal Aerert File NeleM A290I9 Table File Neleli nene Extractieni Tetal PCD ceacentratien* In MOTCO Hazar*eu* Uaete Sanelee were leteralae* vein* the abeve reference* nethe**. Arrrexlnntelv 1.0 e ef the eaarl* Me Mlehe* In a 40 nl Pierce wlal alth teflen-llne II* an* the eaarl* Ml erlke* alth 2 n 2.4.4-trlchl*r*bl*h**l ahlch eerve* ae a eerreeate erlklaa cenreen*. Thle cenreen* le net rreeent In the MOTCO eearlet. Ten ate 9ar*tck an* Jeckeen Cletille* In elaee benzene wee a**e* an* each Marl*' ace eltracenicallr aeeitate* far 30 alnntee. On* al ef the benzene *iitract rae el etc* tilth hexane threeeh a clean-ur celaan ahlch ceneiete* af retaeeloa reraaneanate-larreanate* elite* eel. eulfwric acil-larrennate* efllca, eel,>m4 ee*iea hr*rexl*e--tnrreenate* elllca eel. The reewltln* eleate an* cencentrate* t* 1.0 ale'an* analvze* vein* carillarv OC/MS-SIN technlatie*. HONS 022^54 AmIyiU an* RaaultH Concentration*"!!`Arecior 1249 fwnldlm In the 1.0 nl extract vara cal culate* tv vain* the tatal CLt-blehenvl leaner* ta nuantlfv the anaeat at the formulation rraaant. The cancantratian at tatal CLO-birhanvl an* tatal CL4-kiPhanvl laonert In the 1.0 nl extract ware calculate* (after cerrectlen far thaae iaaewr* from the Aroelar 1240 farnulatian) from Relative Raaranae Fatter* *ataratna* far thaia toe leaner claetaa fran the analvate af CL5klrhenvl an* CL4-klrh*nv1 leaner etan*ar*e. The total amount! of Aroclor 12*4. CLS-birhanvl an* CL4-biPhanv1 in the ortelnal eamrloe were calculate* kv aaaunino that the total extract volutM ae 11.0 nla (aaaumtne a *aa*itv ' af 1.0 a/ml far tke hatarfou* naata eaarlal an* aaaumlna that racavarv af FC2 liomart in the eamrlee ora raflectatf kv the recover!!! af the 2.4.4trichloroklphtnv! turrooata anlkin* comaoun*. Tablet 1-3 euanariie the raaultt af theae onolveaa. The value! aivan in parentheaea ora calculate* concantrationa. ualna the aurroaeta coapoun* recover, to correct PCk valuaa. OA/OC Reeultai Raaulta of Ouplicate temple an* math** blank analvtat ere ihoon in Tablet 1-3. Table 4 tamper not rotullt of *upllcate analvaot of tue Ere Aroclor 1240 Ovelitv Control Somplat. No CLS-biPhanvl or CL4-biehenvl Owalitv Centre! temrlot ere oveilekl*. ANALVtmw k. n. HuaMa. D. NcKAnti* C. Trane ANALYST AFFAOVM.I HONS 022755 Table 1. Retulti of PCI Anolytoo In HOTCO Soapier *3.ai8 Doctabor I. Ill) --It 10 X of 2,4,4-Cli-4f* tone. (>t/) AI2Uk Cl,-If* CU-lf* NOT-77-NW-0\ NOT-77-W-OI (Daayllc.la) H0T-II-M-O2 HOX-IO-IM-02 HDT-07-MW-07 NOf-XO-NW-OI MT-O4-NW-0I MTT-IT-HW-OI N0V*61-W-QI MT-77-IW-02 MOT-14-MW-OI Hatha4 llaak *1.4 (2.2 66.0 17.6 7).2 101.6 M.l 1.6 90.6 0.4 6.9 106.5 66.6 (40,0* 61.1 (52.4) 10.6 (77.2) 14.1 (14.*) 61.0 (74.7) 10.6 (2*.)) 61.2 (4I.() 29.5 (41.7) 57.2 (4).)) 66.0 (72.0) 41.2 (41.)) <2 4.) (4.*) 6.9 (10.0 22.2 (25.1) 9a9 (11.7) 10.0 (11.7) 17.6 (14.0 t.l (*.) 6.1 (i.)> 11.6 (17.7) .) (11.2) 16.2 (i*.i> <2 7.0 0.7) 2.t 0.4) 17.2 (16.1) 7.0 (4.7) 7.7 (4.0 7.7 (7.2) 1.7 (7.7) 2.6 0.4) 5.2 (4.7) 7.7 (4.4) 1.5 (4.1) <2 TU.I TBa 72.1 (77.0) 74.0 (44.7) 44.0 (7.l) 70.1 (74.0) 74.7 (77.2) 77.7 (77.0) M.l (77.4) 20.0 (77.2) 26.2 (04.0) 77.0 (40.7) 60.9 (11.7) 2 * nit *.*,(*trItUinMHM|il *44*4 tt mrlt ktfort ntractloa u4 lulrala. tmln 1240 Tatal ftmcUmklHMltl lmin (catiwtU In Cl.-lf la Arsclor I XU). Taul hHaarialaraUyiawyl laeaara (car>acta4 lor Cl|-I? la Aroclor I2U). Him la fitulaiM ara caacwtratlaaa With haw haw carracta4 far r.cowry al l.I.MIHI, HONS 022756 Table 2. Rfiulti of PCI Analyaaa In WTCO Suplti, laaalr ID 4H).21*14 X >rc. af 2.*.*-0.12* MOT-lt-U-02 (Duyllratr) NBT-2I-IN-02 Mf-ll-W-fl dafllcata) Wt-02-M-Ol IOT-I2-W-01 MT-I7-M-0I HOT-M-M-Ol MT-ll-M-OI nm-m-w-o WT-XO-M-OI ibt-2hw-oi MM klaak *i.i in.* 110.0 *4.1 44.9 79.* *. .> 49.4 79.5 *7.0 in.t *u*jk Dtrrtkvr I), 1901 Com . (/) Cl.-If* 11.4 n*.*i' 1.1 (2.*) 4.4 (*.0) 4).* (**.> 12.0 (17.0 M.7 (*.!> .* (22.2) 47.9 (*0.2) 44.2 (*). 29.1 o*.*) 11.4 (M.l) <2 a* (9.)) 1.4 (2.0 4.4 (.0) 10.4 (11.2) 12.1 (11.2) 11.4 (12.0) 11.7 (12.2) 10 a 0 (12.0 l). (11.2) 21.7 (22.2) 9.2 (io.o <2 2.2 (2.2) 2.0 (1.2) 2.2 (2.2) 2.4 0.0 4.1 (*.2) 2.2 (*.t) 2.* (*.2) 2.2 (2.4) 2.9 (*.2) 1.9 (*. 2.2 (2.) <2 xaial 20.2 (2.-0 1.2 (7.2) II.1 (10.2) M.7 112.2) 10.0 (**. >2.2 (M.2) 24.2 (02.2) M.i (20.2) M.l (M.) M.l (D.l) 2.1 (*.) 2 J t |/| a^M tm tiapU fcafara ntraetlM tm4 auljrtU. ; (mlM IIM * VMal rWKUmtlrlmil limri (carracta* for cl,-2 la Araclar 12*0. * SUl iHBMklanklaiwajrl iaaaara (nmtid far Clftt ta Araclar 12*0. * ValaM la paiaatkaiM ara coacaatralloaa aklck kava kaaa cerractaA far racavary af 2,*.*-Clj-*r. HONS 022757 mu i. ktwlt. ( 1C n<ly... In HOtCO (npltt. Swplt IB 44).2)414 I 4c. I>( 2.4.4-Cli-41* NOT-M-RU-OJ MOT-M-NU-Q) (tk.yUc.1.) WI-4I-4M-02 NBT-lt-BW-0) WT-28-W-0) M0T-0B-8U-U NhM Uuk IS.I 4.7 42.0 IM 11.* $4.2 ).* 102. * w 20.0 m.* if.7 (22.1) 27.1 (.0) II.1 (12.t) M (12.0) *4.9 (52.1) 10.4 (19.*) <2 Dnciaknr I). IM) CMC. (./) CU-fc CI.-BB* 10.0 in. n 4.0 (1.0) 7.9 (9.*) 11.4 in.)> 1.2 o.i 14.) (U.> 7.1 (l.BI 2 2.1 (2.41 2.0 (2.4) l.l (2.1) 4.) (1.2) 1.1 (l.t) 7.2 O.l) 1.4 o.l) <2 12.2 01.4) 28.8 OI.I) J4.4 (44.*) 2*.8 Ol.l) 14.S 01.2) 41.* (11.8) 24.* (28.2) 2 { 2 it%i% tf4f4UleMacaOloWajrl 44H to ia^l< feCot* tatcactlaa Md mlnlt. ' tlKlN lit* : TMil pMncl>Umiphn|fl Ihwii (e.rrct4 (or Cl fir la Aroclor 1241). : Tnul tewUmUyimirl MMn (earractW far C1*IP ta AraeUr 1240). " Vnlann la parwiInHi nrn toKMlratlem wfcftch Mv kM earractk I#r rtctvtr; af 1.4.4-cii-ir. HONS 022758 Table 4. Result* of-ERA Areder 1241 fatality Control Standard# IttlaJfi HT** CMCMintlM 0 WHI CmcMlntlM I Will CwKMtrc. Im 10 Will OMCMInllM 10 >/! NHMfli ArocUr 12*0 CoKtfitrH low 1.0? ?.05 1.00 ).4 Cnmi Arotlor 12*0 CwwihiIm 1.10 0.10 1.51 1.51 IHtmuilCmictl I-- 00.A oo.i 05.0 00.0 HONS 022759 The (dlMlM MMI deacrlba Standard EdrullHi Method* end Standard Mnalv*t* hathad* *d far thla project. HONS 022760 CSC ItwMrl IxtractlM Hathad (SEMI TITLEI Kil in Variaua Mlrlui HATRKXI.ICESii (till tftlMli bill. btaF f*t< ill! rim. xhala ilk. baaF Faca CSC SlMitri EalrtdiM MM Hal PCEXOI TYPICAL SAMPLE SITE <*> TYPICAL EXTRACT VOUOK Call 0.5 - 5.0 1 - 10 TYPICAL ANALYTES! kKliri 1332. I24S. 1234. 1360. 1262. tricblaraIIMkvI itMrt lirtNti actachlarabirMvl iiMtn ESC StanAarA AnalvaU MathaA Naal ECAN01. ECAN02. HSAN03 INTERFERENCESI Rnr alactran carturia. <! m tba rt*ntln tiaa raaian a* tricblarabirhaarl iaa*ar> thrauah actachlarabirhanvl iaaaara Far ECAN01 an4 ECMN02. Any >racla> in tha . rrrarnta ratantian IIm raaian hich aiva tba *aaa ralativa charaettnatic hh raaranaa* FC6 taaaar* Far HSAN03. TYPICAL SURROGATES ------------------ TYPICAL RECOVERIES XI --------- --------- ------ rantachlarabanzana 2.4.6-trichlara- birhanyl SO - 120 30 - 120 APPARATUS AND MATERIALS! OurAick ana Jacktan haxana. banzana ana nathvlana cMartaa Far ala a>tractian. CancantrataA awlFwric acta Far iiarla Ai.aattan ar iurW claan-xr. Silica aal calimn* iarra.nataA with rataiilm aaraanaanata. ulFaric acta. ana aataaaiim hrAraxIAa. ActivataA bailc alimina. Dttraiaalt ala*ara. LIMITATIONS! HatbaA aaalia* anlv ta natricas which Aa nat cantain naa-hvAralizabla alactran carturlna traciaa in tba trlcblarabirhanyl tbrauah actacblarabirbanvl liMar ratantian tiaa raaian Far EC Aatactlan aathaAa. SAFETY PRECAUTIONS! Saa PCS KanAtlna aratacala In labaratary aaFatv munI. DATES OF METHOD CREATION AND UPDATES! 10/23/03 MOMS 02276* UC ItwMN Mnlvin HltliM (Wl) TITlEi OrnanI< Cmmw<i in Salvanta ESC ttw<r4 Mtlrill MtM Nat ISM03 ANALYTICAL INSTRUMENT AM) NODE OF OFEIMTIONI HP-39898 Cari Mar~OC/NS^7#cUd * Ian HinItwiM ltk Ravlalan-0 Multi-driv* Mflutrt. T*l*l Run Tin*' Tvrleal MultiplierV*IU**I Tvrical Dwall Tin**' Maxinun f HaiMU Elactran Enaravl 3-40 nin. ISOO - 2800 #V 200 - 900 nc/Mii 20 70 *V TYPICAL ANALYTE TYPICAL INSTRIPCNT LEVEL OF DETECTION (LOO) (ua/nl) Oraanic Canraunda alutina katuaan taluana ana n-C34-an* 0.01 -0.1 TYPICAL PRECISION t 101 LOO (X) 30 TYPICAL ACCURACY 10* LOO (XI 30 INTERFERENCES AND LIMITATIONS* Analvt* ckaractamtic Mil nuat ka chranatatrarkicallv raaalvad Fran atkar alutina cannaunda .kick rraduc* tR* tana naaa. OMHATOONAPNIC COLUMN* 30-n#t*r Fuaad aitica JtM 08-9 (0.29 uM> witk Id* kara (0.32 anI COLUTM TEMPERATURE PROORAHi 90(41/8/300 CALI8RATI0N AM) STAMMNDIZATION* INJECTION TYPE* Srlitlaa* Ouantitativa* Uaa intarnal atandard awantitatian tackmau* and catikrat* inatrunant raaranaa factara (ran atandard aalutiana a# ar.al.tai Oualltativa* Mian nultlrl* charactartalic naaaaa are nanitarad Far a aivan analvt*. tR* rati* *F ckaractamtic naaa raaranaa* nuat ka itRin 20X *F tRaaa Far tR* autRantic atandard. Far PCS anal.aaa. tR* cRaractariatid naaaaa uRleR are nanitarad ar* tR* nalacular ian cantaimn* all 39-CL iaatanaa and tk* nalacular ian takicR cantain* ana 37-CL iaalar* Far cRlarakirRanvl tRrauak RartacRIarakinRanvl iaanara. Octacklarakirkan.1 tkrauak dacacRIaraklrRanvl iaanara ar* analvxad Fran Fraananta rraducad F-an CL tkrauak CL3 laaa. TR* Fallawina naaaaa and ratantian tin* raaiana ar* nanitarad Far PCS analvaan* Analvt* Mat*** Ratantian Tina* (ninut**) CL-kinRanvl iaanara CLS*klPR*nvl iaanara aatkracana-diOl 1ST CLS-kiPkanvl iaanara CL4-kirRanrl iaanara CLS-klrkanvl iaanara OA-fcipRanvl iaanara CL7-klnRanvl iaanara 188.190 222.234 188.2.189.2 296.298 2S9.9.291.9 323.9.329.9 397.81399.8 39I.8S993.9 11.01 - 21.00 il.Ol - 21.00 21.01 - 23.80 21.01 - 23.80 23.81 - 29.90 39.01 - 29.90 27.91 - 40.00 30.51 - 40.00 HONS 022762 CALCULATIONS! Analvta cancantratlan iMlYtt'VHin'IMITM MAIIwn af 10) Mrtl Analvta im la tha cfcaraetarlatle mM aran a# tM analvta. RAF la tka ralatlva raamnaa fa<tf far tha analvta. It la tka internal ataatart ul ia mm) tv ulkrttaatHIt. mm m (analvta araa In atantart)/lcanc. af analvtaMaraa if It) Kt cencentretieaa ara calculated In ana af tva vavai 1) If an Araclar fernwtatlan can ka Identified fran tka aattarna af act laaaara. aeleted act laanara ar claaaaa af laaaara (I. a. all CL4*klakenvl laaaara) ara aaat ta nvantlfv tka Araclar cancantratlan. Ralatlva Raaaanaa Factara ara calculated valna tka cancantratlan af tka tatal Araclar fernulatlan In tka akava RAF enuatlen. 2> If na unluue Araclar faravlatien la rreaent. tkan tka tatal FCt cancantratlan la calculated fc uainv atandard aalvtlana cantalnlnv knaan anavnti af ckleraklrkenvl tkrauak tfecacklereklehenvl laanara ta calculate Ralatlva Raiaanaa Factara In tka akava RRF anvatlan. Tka RRFa far tka cerraanendinv FCt laanar claaaaa ara aial ta calcvlata tatal FCt laanar cancantratlana In unfcnewn aanrlaa. tAFCTV PRECAUTIONS! Saa FCt kandlina aratacala in lakeraterr aafati nanual. OATES OF METHOD CREATION ANO RETHOO UPDATES> 11/9/43 RONS 022 763