Document G5662zJK65znmDxwdp1owxGdq

AIRBORNE ASBESTOS COUNTS FOR Michael-Walters Industries Valier, Illinois Date Sampled: January 6, 1983 Date Reported: January 12, 1983 Samples Collected By: F. L. Smith Union Carbide Corporation Samples Analyzed By: F. L. Smith Union Carbide Corporation Reported By: F. L. Smith Union Carbide Corporation Union Carbide Corporation Metals Division Niagara Falls, New York PLAINTIFF'S EXHIBIT X 4 1 6638 OBJECTIVE To monitor airborne asbestos emissions at the subject company's production facility during the use of "Calidria" HPO asbestos in manufacturing a mine stopping wall sealant. OPERATION DESCRIPTION "Calidria" HPO asbestos is combined with sodium silicate in a ribbon type blender to form a compound known as "Stoppit". This sealant is used on mine stopping walls to insure a tight seal at the wall to prevent leakage of circulated air. Production involved charging the blender with 6000 lbs. of sodium silicate and 700 lbs. HPO. Mixing of the resultant slurry was M5 minutes and canning up of the material followed immediately. Five gallon cans were used that weighed ^60 lbs or ^12 lbs/gal. Personal samples were obtained from the mixer operator before, during and after the addition of HPO asbestos and reflected exposure for>7 hours in a normal workday. Environmental Samples were collected at the mixer hopper, in a storage-building adjacent to the production facility, and within an operating coal mine with a stopping wall coated with the sealant for 5 years. This environmental monitoring at the stopping involved placing monitors at the upwind and downwind ends of the wall. Also, a brushing and light scraping of the wall was done to simulate abrasion of the coating. Airflow past this location was calculated by the mine safety representative at the site to be ^50,000 cu ft. of air/min. Another environmental sample was taken at the 13th main east air return to determine asbestos concentrations in air that had been circulated through the mine and returning to surface. REMARKS Samples obtained in the storage area of the production facility and at the 13th Main east return of the mining operation were moderately loaded with other non-fiberous background particulate. Due to this interfering particulate some fine fiber may have been obscured in the analysis. X4I6639 SUMMARY OF FIBER COUNTS Personal Samples Sample No. Air Sample Time Minutes Operation Description J-15 On: 7:55 a Off:8:29 a J-17 On: 8:30 a Off:8:59 a 34 Personal sample-Randy Murry, mixer operator. Normal duties associated with preparing for batch 29 Personal sample - Randy Murry. Addition of 20 bags (700 lbs.) HPO asbestos to mixer, stacking of 20 bags HPO for next batch, and bag disposal. J-12 On: 9:00 a Off: 10:54 a 54 J-24 On: 10:55 a Off: 4:15 p 320 Personal Sample - Randy Murry. Post dump period. Mixing and drunming-up of material. Personal Sample - Randy Murry. Normal duties about plant and deliveries to various sites. Airborne Fiber Count (fibers/cc >5u) Possible Asbestos Asbestos 0.2 0.1 2.3 0.1 0.1 < 0.1 < 0.1 < 0.1 TWA Chrysotile 80.7W 437 = 0.2 fiber/cc TWA Amphibole 11.541 437 < 0.1 fJber/cc X4 1 6640 imple No. Air Sampl e Time Minutes J-26 On: 8:00 a Off: 8:29 a 29 J-27 On: 8:30 a Off: 8:59 a J-23 On: 9:00 a Off: 10:55 a 29 115 SUiVWKI Ul- MBLK LUyim Environmental Samples Location It 1 Operation Description Airborne Fiber Count ____(fibers/cc >5u) Possible Chrysotile Amphiboli Asbestos Asbestos Environmental Sample- Location #1. Located ^ 5' west of Hopper and even with chute opening. Sampler placed upon bags of HPO stacked in this location. Environmental Sample - Location #1. Addition of 20 bags (700 lbs) HPO Asbestos to mixer. Environmental Sample - Location #1. Post dump period. 0.1 * 0.1 2.2 0.1 0.1 < 0.1 J-18 On: 10:56 a Off: 3:15 p 259 Environmental Sample - Location #1. Post dump period. < 0.1 < 0.1 TWA Chrysotile 75.437 432 ' = 0.2 fiber/cc TWA Amphibole 8.651 432 =< Q] fiber/cc x 416641 Environmental Samples Location #2 ample No. Air Sample________ Time Minutes Operation Description J-10 On: 8:05 a Off: 10:56 a 171 Environmental Sample - Location #2. Located in storage bldg, on palletized bags of HPO Asbestos 6' above floor. Activity in this area consists of fork lift traffic through building and drumming-up of oils. Static monitoring. J-16 On: 10:57 a Off: 3:20 p 263 Environmental Sample - Location #2. Static monitoring. Airborne Fiber Count (fibers/cc >5y) Possible Chrysotile Amphibole Asbestos Asbestos < 0.1 < 0.1 <0.1 < 0.1 TWA Chrysotile 10.653 434 <0.1 fiber/cc TWA Amphibole 2 933 434 <0.1 fiber/cc X 416642 Sample No. SUWARY OF FIBER COUNTS OLD BEN #25 Location # 1 Air Sample Time Minutes Operation Description Airborne Fiber Count (fibers/cc >5u) Chrysotile Possible . Asbestos Amchibole Asb. A-l 7 On: 12:30 p Off: 2:25 p 115 Environmental Sample - Location 0.1 #1. located atl3thMain East return shafts 5 1/2' above floor. <0.1 X 416643 SampleAir Sample No. Time_______ Minutes A-26 On: 12:47 p Off: 1:24 p 37 SUMMARY OF FIBER COUNTS OLD BEN #25 Location #2 Operation Description Environmental Sample - location #2. Located at 8th South and 13th East Main return shaft upwind from stopping wall and *^6 1/2" above floor. Airborne Fiber Count (fibers/cc >5u) Possible Chrysotile Amphibole Asbestos Asbestos 0.1 <0.1 A-23 On: 1:25 p Off: 1:40 p 15 Environmental Sample - location #2. 0.2 Brush down of wall to simulate abrasion of coating. 0.1 A-6 On: 1:41 p Off: 2:15 p 34 Environmental Sample - location 42. Post sweep down period. < 0.1 <0.1 TWA Chrysotile 6.627 = 0.1 fiber/cc 86 TWA Amphibole = <0.1 fiber/cc X 416644 SUMMARY OF FIBER COUNTS Sample _______Air Sample No. Time Minutes OLD BEN #25 Location # 3 __________ Operation Description A-20 On: 12:45 P 39 Environmental Sample - location #3. Off: 1:24 P Located downwind from stopping wall. A-25 On: 1:25 P 15 Environmental Sample - location #3. Off: 1:40 P Brush down wall to simulate abrasion of coating. A-24 On: 1 :41 p Off: 2 : 15 p 34 Environmental Sample - location #3. Post sweep down period. Airborne Fiber Count (fibers/cc >5u) Possible Chrysotile Amphibole Asbestos Asbestos 0.1 0.1 0.2 0.1 0.1 < 0.1 TMA Chrysotile 6^993 = QJ f1ber/cc TWA Amphibole 4.292 ~W~ = < 0.1 fiber/cc X4I6645