Document G4DMqYGqX4xOENmV1V5DrnON
Monsanto
11537 C0PY1
MOMMIO MHMCN (OWOWTM / OAVTONLABOHATOMY / OAVTON. OMO 4MOT
tC - OATTOW___________________ (Oi^i /tici*i
ANALYTICAL
m V Mnyii
1
M0t
MtOftTNO.: MCA-421 J04.AOJ4CT NO 411.5450
DAT! November 7, 1903 7|*0 COVtACO
'
TITU: ANALYSIS Or WATER AND SEDIMENTS fO PCB'S
1
P)
AUTMOAS: B. K. Hughes
ABSTRACT: Voter and sediment samples from Monsanto PIT were
analvsed for their possible PCB eontamintions.
The results of these analyses are shown in this
report.
^
ANALYSIS OP WATHF AMO SlIOtMKSTS POP PCO'S
AUTHOM: . M. lluehC S
tITU :
r.O :N 0-421
'
f
iI
Approved bv:
"7
robert T. Ivory
^
Environstental Sciences Center
Service Project "onager
Approval date* _
//-//- /j
BESTBICTED DISTBIBLTION (see over)
COMPANY CONFIDENTIAL
HONS 022665
COfVNUMKN
1 D. H. Batchelor, Jr.
ISIS
2 r. r. ivory
1250
1 B. M. Hughes
12S0
4 Central Files
1250
5 Technical Reports liby. R2C
ABSTRACT ONLY
*. n. seott
0
H. A. ^olttrMnn last
NOTE:
Distribution of this report is restricted. Requests for dditionel copies should be made through the principal
contact at the Monsanto location involved or the Manager, Environmental Sciences Center, Dayton Laboratory, Dayton, Ohio.
ACKNOWLEDGEMENT
Contributions of the following Dayton Laboratory personnel to this project are gratefully acknowledged:
Analyses:
B. M. Hughes
D. McKenzie C. Trang
rC' (.1 V (' A \ V C O \ F : D \ T ' .
When no longer needed, or iipon request, return this report to Control Fites, Dayton.
MOMS
OZibbb
AMttttlt WORT
LOO NUntCRi 1-03-10-28-01
DATE* I1/2/13 PROJECT NOi 403.54518
PTP/Huaho*
FROM*
Envircn*ontal Scianco* Cantor
Monsanto Rasoarch Corporation
1515 Nicholas Road
Davton. Ohio
45413
Phono Not <513) 2*3-3411
Tit)** Analysis of FC8t ir. Two Wator Saiknlo* and Four Sod.nont Sam*I** Standard Saanlins Mothod NotsM N/A Standard Extraction Mothod NoffM PCEX02. NSEX01 Standard Analysis Mothod No<>* ECAN02 Final Rorort Fit* NoCsl: A54510 Tail* Ft 1* No< f)* E54S18. C54518. D54518
So* TaMos 1-3 for rasults wsin* tho at-c-vo refr*nc*d Standard Extraction and Analysis Mothod*.
ANALYST<5)1
hONS 02it>b1
JMMH* T oauwii
ifliv
H)m
no PrtlKt J6L 483*94918
Dmtol N*v*m6r 1.1*83
ANALYTE
ESC
analytical
METHOD
LOD
Aroelor 1243 Art; lor 1254 Aroelor 1260
ECAN02 ECAN02 ECAII02
1.0
1.0 t.o
Totil Aroelor ECANCC
1.0
Mbthb* BUnk
ND ND ND ND
SAMPLE IDENTIFICATION
102583-IR
102983-IR Dwrlic.t.
CONCENTRATION <u/9>
ND 1.03 ND
1.03
NO 1.9 NO
l.T
&URR0&ATC JFIK1NO COMPOUND
AMOUNT ADDED
CL3-b*nzono
EC AN02
1.0
93
RECOVERY U> 66
66
DOCUMENTATION
ESC Extraction Motbo*i &.mnl. Amt .xtr.et.d (*) E>.trct Finot Volgin* dot)
Extract Dilution ESC Extract No. ProcoM Pilo N*tO
FCEX02 0 to
111 PCB199 BP 179
PCEX02 1.0634
10
111 FCB29J BP191
PCEX02 0.9965
10
HI PCP202
BP 192
EXPLANATION OF ABEREV1 AT 10N51 LOP limit oF d.t.etion in u/t
NO non* d.t.ct.d with d.t.ction limit *iv*n tv- th LOD v.lu#
NA not .n.lvz.d
TABLE FILE MOl B94513
HONS 022668
MU
IMUXV . CUESVftry OpfC
Rir *4i.*r
fcCrrJ.<t N*i 4U.M9I*
ANALYTE
ESC ANALYTICAL
METHOD
LOO
Ar ? 1 * r Ar#fi1*r *r<1r
|; J l.M IK-.'1
CC*NO> ECANO2 c< AtKC
1.0 1*0 1.0
T*t 1 A <: i ii cc AN:*i
1.0
I02903-2ft
NO NO NO NO
Sl'40CV*T *M Imc.
AfWNT AODEL*
\U9/9 )
ECANCO
1.0
4J
0*l*t Nv**r l.|*W
Mint IDENTIFICATION
I02S83-3A
I0I383>4A
CONCENTRATION 1 ./>
NO HO NO
NO
NO Kit NO
NO
RECOVER* iX >
:?
K>:vnElTA* ION
EV: E .tr*cti#r, r.tth-,4
$*!+ A*.?
<>
C Fi*.l Volum* IaD
t U:t P:*vt:ori
E^ trt N*. ?**;* Ftl* tom*
PC Eli 02 l.ITS!
10
i: 1 F -rfiCC--: *P 1*3
PCEX02 1.1243
10 1> 1 RCP204 1*1*4
EXPLANATION OF AOOREVlATIONSt
L*.0 lm. t
n i9/
HO
4ct*ct4 with 4*t*ctic>n limit rivtri bf tht LOO
h* r.<*t n*1v:*4
TAKE FILE *i CS45I8
ace*-:; X.Cl:1
10 ID PC0200 EFI20
HONS 022669
*f CspIIUtv OCfltC
nMUIr^lWrH
CC PrtJ.tt N*l W.H$H
DtUI Nw4<r I.1W]
Aar4 Uttar
AMAL V TE
ESC ANALYTICAL
METHOD
LOO
Ar{l<.r 1 24 3
Ar *< 1 <>r 1 *54 Ar o\ 1 vf 1 l-i'O
CCAN02
EC AMCC ECAWOi
.001
.001 .001
Total A: v:1'>r ECANCC
.'1
NO ND ND
ND
WU IKNTiriCATION Diatillad Matar
CONCENTRATION (*/*> ND NO NO ND
:*.*FP.:-vATC IFII ]1 NO C0Hf cu:::<
AMOUNT AOt-E D
(!/*)
RECOVERY U)
CL5-t>r*?#r.#
ecanco
. :> 1
47
4
MiiiimittmiititimiitiifftiKtaiiittaaianitMatattitmtstitiMititniit
do:vwentation
E i l Z tr *:t ior. M*tho-l Earn*)# Amt #.<tract*4 <f> E t'4Ct F i r.% 1 Volume (ml) C t r a : t Oil*jti->r. EiC 6 t r c t No. fr#c# Fil* Nam#
USEXOt 1CK'>0
1
1*1 AC8205 BP14S
WSEXOl 1000
1 1*1 PCB204.
8P14*
EXPLANATION or AtBAEV I AT 1 ON *: LOO limit (*' 4*t<ticn ir> ui/v
ND fion* d*t*ct*4 *itt a OttactiOfi limit ?iv*r tv th# LOO vtlu*
M r#t
TAELE FILE N0 054513
HONS 022670
T>* follows** m> tfotcribo M hotbod* utti for tMt rrojoct.
Extract!** rtotbotfo r4 $t%r>4%r4
HONS 022671
K$C ttendord Extraction Method ttfKI TITLE* N#a>IC Activ* Nttrlltl
MATItim.CCCSH
$41* end ether non-EC elid* end *olvent
CSC (Untoril Extract Im IklM Ni K(>2
TYPICAL MPIE
SIZE <)
TYPICAL EXTRACT VOLUME <mf >
0.5 - 5.0
to
Tp;.:AL ANALTEi* aroclon 1232.
1241* Ut4, lit-:*. 12*2. tnchlorotpt.en,l ikiikp throueh octechlorotiehen.l tvr.*r*
ESC Stonderd Antlvtit Method Noel ECAN01. ECAN02
INTERFCRENCE&I Ar.. electron CAeturine teeciei ir, the retention time re*ion
.f' r i:hl or otieher.. 1 iiomere throueh e ctocr 1 ot*i*hen. 1 i cmer ,
TYPICAL RWROGATEi
TYPICAL PECOVERIEJ IS
eentech)orobensene 24.6-trlchl<ro-
biehenr I
50 - |20 SO - 120
AepAAATUi AMD MATERIALS*
Durdicfc end JocHfor. tensene for mele extrection or dilution, Dt t p>*M e 91 s*w4r .
LIMITATION'S* Method ^plici onlv to Metric** which do not contein intor#errin
electron ctMurine eecie in the tr ichlor obiehenvl throueh octecMoro-
tirhin.l itoe.er retention time reeion.
'
SAFE7l PRECAUTIONS* See PCS hendlin* protocol* in l*bor*tor, fet. menu*).
DATE* OF METHOD CREATION AND UPDATES* 10/31/63
HONS 022672
MC IttMtrl Extraction HpthsS (SOI) TITLES OrfMlc Cm*nhO In Ihltr
HATRItXI.ICCSIl Matar
TYPICAL ANALYTES) Aroclors 1232. I24. 12S4. 1260. 1262. triehlorolifktxl isomars throuah octachlerotip).*!..1 iicmd. oraantc compounds alutina botwoan toluana ar.d n-C34-ana
IK ItMArl Extraction NIM Nal UCCMI
TYPICAL SAMPLE
SIZE (>
TYPICAL EXTRACT VOLUME (all
I - <000
| - |0
ESC Standard Analysis Mothod non ECAN01. ECAN02. HSAN01
INTERFERENCE:*! An. *)*ctr*rk et^tur tri?
M(WI ir< <.t tr l {hi <,r
r#t*r,tcr. tift . 1 itori throu*F>
1 tor
ECAN01 %u< EC AN02.
typical
SURROGATE $
typical
RECOVERIES I*)
*h#rol-d5 <L-*h*rio1-d4 CL2"b#fiztftfJ4 nhth1*n-d
*vr #r*-dlO chrYf#n#-dl2
p*rtcMorob*r.;n#
24.6-trichloroblphtrivl
2*i -
20 50 5* 50 50 -
50 -
120 i:o 120 120
120
50 - 120
APPARATUS AND MATERIALS! Curdick and Uacbson Mthvltnt chlorido for samala axtraction.
PisaosaHa alasswara for aaapla siras balow 20 a and saaaratorr funnala for laraar al:aa. Laraar samala si:as alao ranulra sodium sulfata columns for attract drvlna.
LIMITATIONS! Mathod aaatian on), to matricas which do not contain alactron caaturina saacias in tha trichlorobiahanvl throuah octachlorobiahanvl isomar
rataritivi. tima rasior. for ECAN01 and ECAN02.
SATETY PRECAUTIONS! Saa PCS handlina protocols in laboratory safaty manual.
CATES or METHOD CREATION AND UPDATES! 10/31/83
HONS 022673
jSff-gaaawsKgTO..... ne'w MM}
AmIV(I HMM Mi
AKALYTICAL INSTRUMENT ANO HOK 0T OPERATION.. HP-SOSO Crlllrv CC/EC Int.r(t ti t r> HT-333A-LAO L.b.r.torv Dt% Sv.t.a
T.'ICAL A'iMTTC
typical
INSTRUMENT LEVEL OF rCTECTION (LCD)
(u./.I)
Ar f. .`aviations
i::. \ 1254.
(2 ? and l ;*:
o.i
TYPICAL PRECISION C IOX LOO
(XI
30
TYPICAL ACCURACY IOX LOO
<x>
30
1VTC vxr.i.N'C;- ANT* LIMITATIONS* Any electron caPturino species in the reten tion tifv resior. of trichlorobiehenvl throuoh ctacMorotiehen> I umri
n*e *tjr.tsal interferences. Exact retention tines of most likely PC8 isomers cr< te vttained from the analysis of Aroclor 1*43. Aroclor 1254 or Aroclor 1210 fer.-w-,
Ott^iATGr.RAFHIC COLICS 30-aeter fused itic Ji.W 08-5 (0.25 ufl) with i i 1* ter* .0.32nn>.
CCUHN TCrrCRATUPE PROGRAMi 130( 11/4/300
INJECTION TYPE* Selitless
CM.irrsTK:: AND STANDARDIZATION* Use interne! standard agantitation technique i.-J iriitrueerit response factors from authentic Aroclor formulation
standard**. Ore a minimum of 10 PCD isomers for the determination of formvidontitr and auantitr.
CALCULATIONS* formulation concentration (isoaer area)/(isoaer RRF)
inre*
RRF is the relative response factor for the appropriate rCB isoaer in a eiven formulation. Poraulation concentra
tion is obtained froa the averaee of at least 10 such cal culations^
SAFETY PRECAUTIONS* $oo PCS handlino protocols in laboratory safety* manual.
CATES or METHOD CREATION AND METHOD UPDATES,* 10/25/S3
ONS 02267b