Document ExNndbNenbDdJmvLZe1576DNL

} AR226 - 067Y Centre Analytical Laboratories, Inc. 3048 Research Drive State College, PA 16801 Phone: (814) 231-8032 Fax: (814) 231-1253 or (814) 231-1580 Analytical Report Fluorochemical Characterization of Surface Water Samples Pensacola, FI (W2176) Centre Analytical Laboratory Report No. 023-014C Testing Laboratory Centre Analytical Laboratory, Inc. 3048 Research Drive State College, PA 16801 3M Environmental Laboratory Contact Kent R. Lindstrom Bldg. 2-36-09 P.O. Box 33331 St. Paul, MN 55133-3331 Phone: (651) 778-5352 Requester Kris J. Hansen, Ph.D. 3M Environmental Technology & Safety Services Bldg. 2-3E-09 P.O. Box 33331 St. Paul, MN 55133-3331 pacerors 000978 1 Introduction ARneasluylicsalarLeabroerpaotrotreidesfo, Intch.e(Caennatlrye)ssfoofmathseer3ieMs EofnvsiurfoanmceenwtaalteLrabsoarmalpolreys. rTehceeisvaemdpblyesCwenetrree collected from Pensacola, Fl. The Genre study number assigned t the project is 023-014. (`SLpCeIciMiScIfMlSu)oowcahsemriecqaulesctheadrfacotraelrlizsaatmipolnebs.y qAutiotdaclhorfo8mastaomgprlaepshwye/rtearnedceemivmedasfosr asnpaelcystirso.mety Thesamples were prepared and analyzed by LCIMSIMS for the following ist of fuorochemicas: Table 1: Target Analysis [Com__p __o _ undN TAa conm m e| [PeruorooctaneSuonate-- [pros | [Peruorooctane Sufonviamide |prosa____| [Pefuorooctan[rcoaante| fiThlweiatnalCyetnitcarle.mDeatlhaopdruesseednwieadshveareiciaslheedbhyigChoensttqeu.aitTyhdeatvaalaivdaaitiaobnleproatttohciosltiamned.results are on 2 Sample Receipt Tinhdeivisdauamlplseasmpwleerecosnutabimnietresdweinreinrdeciediuvaeld.plaSsatimcplcoenstawienreersreacnedivweedroenn0ot50p3r/e0se0r.vedT.h"e Ssiaxmepelne collection dates were not supplied. Chiain-of custody Information is presented in Attachment A 3 Holding Times Tshtaebianaloyfttihcealamnealtyhtoedsoufsiendtwreasstvfoarlliodnagteerdpaegraiiondssthaasmnaotxbieemnhdoeltdeirnmginteidm.eof 14days. The PASERORS 000979 4 Methods - Analytical and Preparatory 4414.1 SLaCmIpMleSIPrMoSparation for LCIMSIMS Analysis r`eSsaimdpulaels cwhelorreinie.naSloltdreaptheadsweithex2tr0a0ctuilo.nof(2S5P0E)gwLassoudsieudm 1t0hiopsruelfpaatreesothleiosnatmoplreesmofvoer TLhCeMScaIrMiSdgaenawlyassisf.irsAt efoerydmivlitlhtr5pmoLroonf 4of0s%ammpeltheawnaosl tnrawnastfeerresdou(t0aon.CyyTShePEelcuaartteidwgaes.. dmiestchaarndoeldawnadstchoeleSctPeEdcfoorluanmanlywsiassbtyheLnCMelSuItMeSd.wihThi1s0e0a%miemtehnatnorles.uleAdSinmalnpoeirghitfooolnfd concentration of the samples prior to analysis. 412 Sample Analysis by LOMSIMS cIonlHuPmnL,C,Baanseadolnithoqefeauxtforattct iosfjheectaenadlyatnedfopatshsesdtatthiroonuagrhypahiaqsuiedi-nphtihaesceochurmomatoolagirvaephi0c HhPeLCsuiedpamroabtiloen,phEaSsIeM,Stperoavnidaelsyairsarpeitdaianneddafcorcuarcahtaemraecatnesrifso aamnaoluynztiongf mawei.de Froalnogweinogf omrigdantiecmpceormaptouruensd;s,moilncelcuudilneg farueorioocnhizeemdi,cfarsa.gmEelnetcerdo,sparnady fdsetgeecnteerda.l oIpoensractheadracatteorliasitiivceloyf Known fluorochemicals are observed and quaniated against sandarcs. Haneawllyeztet-tPheacskaamrpdlHeP1ex1tr0a0ctsH.PLACnalsyyssitsemwacosuppleerdfotra0meMdicursionmgassselUelcttiemdaMrSea/cMtiSonwamsoniutsoerdintgo (nSdRM)M.SISMaSmpmleetshowdesreuseextdrfaocrteadnaolynsi5s/1a7n/d00nsanidumaennatlypzaerdambeytMerSsIcMaSnbone fSo/1u6n/d00in. tTahcehHmPeLnCt 0. 5 Analysis 51 ACaTl-ipbairnactailobnratoncurvewasanalyzedatthebeginning andendofheanalytical sequence 5fo0r0,thnedco1m0p0o0unndglsLo(fopitn)teTrehst.rTehsepocnasleobrfattihoen qpouianntsiawieorne fpornepvaerrseudsatth0e,c2o5n,ce5n0,iza10t0o,n2w5e0s, pcloomtsiiedatfoonr ecoaecfhficpioeinnt.(1)Uasnindgcnoeefafircireengtorefsdseitoenrmwiinlhat1i1oxnwe(i1g)hwtienrge, dtehteesrimoipnee,d.y-nAtcearclebprtataonnd curveisacceifpr2.0t.98a5(b20l97e0). Galbration standards are prepared using the same SPE procedure usedforsamples. tChalrioburgahtoiuont cthheeckasntaalnydsaisrdssweeqrueencaen.alyzCeodmppelraondciacaliys (eovbetrayitnreed ff10tfhiev.e ssatmanpdlaerdinjeacntailoyntse) concentrations are within +-20% ofthe actual value. For the resus reported here, calbraton ceria were met. pacesors 000950 52 BExltaranctkison blanks were prepared and analyzed wih every extracion batch of samples. The etxhterlaocwt-iloenvebllacnaklsbrsahtoiuonldstnaontdhaarvd.e Faonrytthaersgeetsaanmapllyetse,sphreeseexnttraacttoiornabbloavnketshweecroenccoemnptlriaatnito.n of lIenvsetlrucamlebnrtatbiloannksstainndtahred,foarnmdofafcteraknnomwenthhaingohl-lesvoellvesnatmpwleers.e" alAsgoaainna,ltyhzeedbalfatenrksevsehroyudhingohth`saavmeplaensyprteasregentteadnahleyrteestheprienssetnrtumeaintobrlaanbkosvaerethceomplloiwadnetv.el caibraton standard. For the 53 Surrogates `Surrogate spikes are not a componentofthe LGMSMS analytical method. 5.4 MMaattirxixspSkpesikweesre prepared for every fied sample (excluding blanks) at a concentration of A1l0l0abnogrlaLtoursyinmgatarlixcospmipkoeusnsdhsoowfeidntreerceostv.eriMeastorfiaxllspciokemproecuonvdesribesetawreeegniv7e0n-1in30A%t.tachment C. cFioemlpdosupnidksesofwienrteerepsrte.paFrieelddosnpkseamrpelceoveMrCi-es30arTeHalastoagicvoennceinntAratttiaonchomfe1nC0t.0 Anloflieludssinpgieasl showed recoveries of al compounds between 70-130%. 55 Duplicates tAhlefsiaemdpslaemrpelseusls(eixncAltutdiancghmbelnatnk8s.) were analyzed in duplicate. Results are given along with 56 Laboratory Control Samples Mciloi wmatepr wwoaesruebsnpeitkdwedewesinlh7ll0c-om1pio3nuen0adco%hfinLtCeSr.estRat25eancda2r5oe0gnvegLn.ewAilthrretchoevireraiweesdfaotrsaailn Attachment D. 57 Sample Related Comments thFireokudgbhlaanhk syampplescecaornrisidsgcteedwaaofsraemdpdbteyd(co0nttahieneermsp.tyFcoornttyamiinletrearnsdoafnatlyypzee|diwnattehresfiatemrsed manner as the other samples. 6 Data Summary PlseeeAattaschmeent 8foradetaed stingofthe analytical resuls. 7 Data/Sample Retention `elSeacmipolneiscardeatdaisipsoasrecdhoifveodneonmorenttrhievaafbelre hmeedrieapaonrdst ihasrsduedcoupnylersespoortthserawriesestsoperceidfiiend.daAtlal folders maintainedbyCentre. PAGE4OFS. 000981 8 Attachments 62 Ata: Ress. 81 AttachmenAt: Chain-of-Custody 83 Attachment C: Matrix Spike Recoveries (Field and Laboratory Spikes) 84 AttachmenDt: LC/RM awAS nal/ yticM alDaS ta 9 Signatures an." Fig, operons ~Marae Basthsy at Kevin J Lloyd, Vice President Date Orr Lab Members Contig 0 Data KEanraeknshSamiWtihcrsmesinhe Bava et -- 000982 LTR Go INC 30) 1g 53A 08 ReseaN rch Drive, Sats CoLlleagebPAoT6r001atS1o42r8i03e2 sFA.X STIAnTcI.S J-- Morr Sia wfwooen sB ft orrrSiuientieiSUd mosoe a+5s =a syso FBEo erHern e s opicte 132p90o317 a pSrEE =a Campos eat,tt io esti ssi paring 2510 nk 201.Th rl3 or ECS ad PEOSA i510 tnd 0 POA mrosaea az= ===2 =% Poses) ` 322 =z2= =z CO --Fiesso seeriR e evareawTaoaToorSosaandraeresSndocannatisons 0009s 83 BES: cOPY AVAILAB SMNTNGEEREER LTR mE ET J EX Se A Th pes mm a Fe Ala Erevan LEO a 10] AHsede eslenmeB SAdlT T SEo R ie CHRVETTANG Ca nad Salivienkene I= Pode elie 7 a ed 2S fA S(eFfpor moinweer PTOEd ela]drene Borage ae = A Foch AB e V R oE hE Las nee bn Yoo. Tl Sa 1960MapQuest.com, Ina.; 1998 GOT,Ir gate! SrA Environmental Sampling Sites and Supply Chain Facilities for Pensacola, FL _ 000984 BEST Lu tv aermmnitt PINT FS Om `i = A perdidoLanar&mn N DEK N"ay Jdn TENEE on EINES .rWeN ba TJNi A0 ) YEE BE ; NLLE ONGNLRREEThT eadibLloT)TRU ct Oy EAL SET, 3 A SET Rt rT &, NTE ec } mani oath LeLA 2 TE, Air SACs shonosouwthmnap Environmental Sampling Sites and Supply Chain Facilities North of Pensacola, FL. 000955