Document EvKZEgqoJ66X5GG09GvyqYgjb

%7 o o o o 0 Monsanto offers you the largest assortment of plasticizers--both in number and variety--in the world. This broad line has unique advantages: you can select from o one source the plasticizing system that offers you the optimum in processing and performance; you can obtain impartial technical guidance; you can take advantage of the savings in combined shipments; you can simplify your purchasing procedure. The need for a selection of plasticizers is readily apparent. In the 1930'$--when a Monsanto pioneered the technology of plasticization--performance demands were relatively mild. Plasticizing was simple because applications were few and resins fewer. In the intervening years, many new resins were commercialized, countless applications have developed, and today there are rigorous specifications and a variety of needs for ease of processing, speed of cure, and particular perform ance qualities. Confronted with the multiplicity of end-use requirements on one hand and a multitude of plasticizer and resin choice on the other--even the most experienced # formulator is bewildered by the maze of possibilities of from which to select the one best system for his particular application. This catalog has been designed to serve as one tool to help you solve the often perplexing problems of what plasticizer to use. It contains complete descriptions of the performance and processing characteristics of each of Monsanto's more than eighty plasticizers, it also includes tabulations of performance data of various o plasticizers in several end-use applications and guides to superior plasticizers to develop compounds with special performance. This catalog is not the final guide to plasticizer selection. It is primarily a guide to performance of types. However, if these data are used as a guide to plasticizer selection, Monsanto technical bulletins on individual plasticizers and on certain end- m use applications will provide more complete information. # Specific consultation services are offered by Monsanto's Plasticizer Council. We hope these three sources of information will be helpful to you in your manufacture of plastics products, surface coatings, and adhesives. m e 0*1bO*1 m TOWOLDMONOQ33017 Lai |L A S T I C- I Z S3 S *r the Widest Choice in the World '. ' The following am trademarks of Monsanto Company, registered In the U.$. latent Office; Arocfor, Geiva, Msdaftow, HB40, Mod*pox, Montar, Gpaion, f*hosgard, Santiciser* Santo!ite, . m ^mr 0*160*8 ( o TOWOLDMONOQ33018 II/pag* 2 ten bulk station distribution points To give rapid delivery and multi-produet shipment*, Monsanto maintains built station inventories at strategic industrial centers along the east coast, the south and southwest, the midwest and the west coast. These bulk stations are another customer service that enables plasticiser users to save money to the following ways; lowest cost/lb. With -\1onsanV>':distnbution, corrtfour.d'-r', tan reduce their rnotensh costs by pur<hs ini; in tank <'i,rs dnect from the producing I Ur.tor by ordering tank truck shipments from the nearest balk storage station Bulk prices are about (/?. lower than car- and track-lot drum prices. Conservation of plant storage space Since the Monsanto bulk stations are strategically located i lev: to major manufacturing centers, minimum j ifw.ticizcr storage space is needed. Supplies are ;u silablo in most areas for fast, short-haul delivery. Corn pa rtmented shipments With such a brood line -f piastHzevs. compounders con take the savings of unlit purchasing by ordering as many as three -l.flerent plasticirer s m a single order. The different nlssticircrs are shipped in compartmented tank trucks. Multi-product combined shipments from 'bulk stations can also reduce in-plant inventory costs. Mixed Car- and Truck-lot Shipments By offering such a full line of plasticisers, Monsanto can load out mixed drum orders In a single car or truck. This gives the buyer the cost economy of full carriers. Ordering, invoicing simplified With this efficient distribution system, compounders can make ad ditional savings by fewer shipments, fewer orders, and reduced paper work in clerical handling of invoices. Monsanto is always ready to work with customers to establish and maintain convenient bulk station distribution centers wherever volume justifies a mutually convenient storage station. TOWOLDMONOQ33019 s:zm specifications and physical characteristics jj of Monsanto plasticizers Monsanto plasticizers comprise both liquids and. solids representing a variety of distinct chemical types, including phthalate esters adipate esters permanent plasticizers glycollates sulfonamides phosphate esters aroclor* plasticizers .,. plus a variety of "specialty" compounds and extenders, Each of these, in themselves, but primarily in combination offer special processing or end product quality advantages in particular applications. Specific plasticizers and specialty researched combinations have been developed for formulation of plastisols for slush molding, fabric and paper coating; for adhesives and surface coat ings; for extrusions both profile and cross section; for floor tile; and for cast or cal endered free film. ) O m o m m The Mtetog pages Assert* physical properties of the vartoBS plasticizers of cMet available from Monsanto. > 04,?f050 'V- TOWOLDMON0033020 w J |: ',,w.y,s^M"A m processing specialty color improver feraikyd resins : ^ tlt/page 84 m 0 o Q Q O O Q m % m m a General Description . yjfr] "iV 5. $'>* ; .* */ - ; LTMu. Triph*-ny\ |jhosphile is widely used os a sb*bi lly i in |k>lycmyi nfduride comp/x-it ions. It serves a < .p1 function' M) When cadmium compounds are po r *f the com|yy,itio, triphenyl phosphite v>1u~ and jem*>ves the here developed hv the eadrruu x> chkuide formation; <bi When chlorine urns ;u'*- -.phi from polyvinyl chlonde. double-bonds 5us~ < c-{ 4 'hie to oxygen-darkening at e left behind on the $* vn.et; ittphenyi phosphite acts as an mdioxida r ~md con tributes to bettor light stability [This fue'/hon, also valuable in other resins, is covered by i: Patents 2,572 571 (Monsanto) and 2.564,646 (A i 4ns Chemical Company) ] ffc alkyd restws triphonyl phosphite improves th*' color of the rosins which tend to oxidize at the 464 540''F. processing tempo* aturos due to presence of f 'oe peroxides. m iron soluble salts If calcium hy iroxtde is used as an alcoholysis catalyst, the yv* o?nce of ti iphenyl phosphite will improve the mn.hed resin's clarity by sniuhihzmg the calcium ph thzdste precipitate which f^ms In polyester re?v'' u-raud.'K't'uc. --m'dl amount..- of triphenyl phosph.V/ reduce the reaction t.me and improve the re5''oi->r The otmo col**r improvement is ol>far 44o 40 ihe natn Mac*. ue of b*dted <oh made by tie- iM*otr*.enl of sova linseed, and tall oils with mi l '.< ur.hydv,-U' or fum^nn arad in phrnolv reoiii rfs mufaeture, biphenyl phosphite promotes the lot nation of permanently light colored liquid pho no formaldehyde compositions (U. S. Patent 2,H 6,674, Monsanto Co*). B Properties fcH;Chemical formula' Molecular weight 310.28 Appearance Oily liquid or fight yellow solid Neutralization number 0,08 mg. KOH/gm. max. Color APHA 50 max. Hydrolyzable chlorine 0.010% max. Free phenol 0,5% max. Refractive index <8> 25*C, 1.5875--1.59G0 Specific gravity 30*715.5eC, 1.176 to IM2 Weight per gallon {> 25aC. 9.33 fb. Soiling point, 760 mm Hg ii Crystallizing point 360*C, 25*C. Flash point CC.O.C.) 3?5aF> Fire point (C.O.C.) 525s F, Vapor pressure (g> 2205C. li mm Hg Viscosity C# 25'C. 17.5 cks Solubility in water <3> 2$*C, Hygroscopic Genera! solubility Soluble in common solvents ` Specifications Tr;phenyl phosphite is considered only slightly tome from the standpoint of oral ingestion and is no5, readily absorbed in lethal doses through the unbroken skin Repeated or prolonged skin contact fJhmibt be avoided, however,-to prevent skin irrita tion The material may cause irritation if there is ae* ukntal contact with eye tissues but no perma nent damage should result. Prompt flushing of the ey'"> with waiet will reduce the degree of irritation. In laboratory studies, no deaths occurred among ram exposed for six hours to a saturated atmos phere of atomized triphenyl phosphite. 0476051 TOWOLDMONOQ33021 TOWOLDMONOQ33022 ' j AROCLOR PLASTICIZERS AND RESIN EXTENDERS VJ | ' Q- o o m m o o o o m m m m Tt >' Aroclor polychlorinated polypheny lx range m in ;<> uni appetence him mobile oily liquids to fn - v/iu?c crystals and hard yeHow transparent re Jor Tbe Aroclor products arc t/Wui as iow-e<r-,t, efl.. e nt plasters* t > rod resin encoders fir vinyls, r<"/; m'v, and rnbh* % mateiials, The Aroclor compo mv'v an- compatible with most if the common plrir, resins ami m<u."Ktns specie! io;-?ns. 'ITc- permanently thermoplant *e materials are nou e ddrdng; non-coiroslvc to metals, and not h>*hoJyrabh by wa^r, alkalies, or acids. They po-jf*:/ 'xcellrnt elci iricai pi*.pe>'t>es. The viscous hur'i'Xu and resms will not support cembus*am when heated alone The flexibility they impart to re- -mf increases with the mobility of the particular Aro'-iot compound, while the decree of hardness htqeu ted Increases v/ith the viscosity o the Aroclor In and sto/'me ^oatinpc:, the Aroclois imfm "t ojUtandmg adhesive qualities, gtxid resistance to wot*''!' and chemical act ion. and resistance to ba/'wiu and fungi attack. fn firyl resins, the Aroclors are used mainly as co piasdci/.ers with tricresyl phosphate, dioctyl ph * halaU and ofhers Th'-y impart pbed icizingaction, ch -m-oal and corrosion lecistanee, flame resistar^a trJ r rl'W'i * . > i<> udr-rr.-lbAo'-r U?"'l /soh A: fvl phU,.iiut<> and Santiciz* r 14!, the Ai ^h>r< are ' *'nt co-p^^-.tfci/^rs f'*r wnyl o**- ga , ,'.vj|?c p,`" : m p**Y*.* f*n fret fin,/., and te ; t * I *' &od|..o/i y, b. th'Cw applications, the A'-^lorr, iii'.pii* ''-do? Je h?e ic'.rdcmce and servo us *<ce!lent grinding and dn^/rsing media for pigments. fn fsolyvinyl acetate, the liquid Aioclor compounds make excellent low-co^t, quick-tack adhesives, The mo;e viscous and solid Aroclor compound*? are wiiM/ used m hot-melt adhesives, T> e Arorlors are highly compatible with ethyl celhi nm. The liquids impart gieat flexibility, and the re hr.-, impart great baldness. Aroclor 5480 conir.holes high gloss and exceptional weathering qualities to coatings for rigid surfaces. fn s.elbtlase ari'tatt'butyrate, the Aroclor com* peauvif, are useful in making flame-resistant, lowcod formulation?? for applications inch as paper co *4Jt*g&. iacquers.and sirippablo coatings. fn narooclfuinse, the Aroe tors function both as plastieirors and resins. They may bo used alone or with other plasticisers and resins to impart weather itsjdu/i e, luster, adhesion, and dor? eared burning rale. B' cause of their excellent clccnicai charoctr ? isiics Oiigh dielectric strength and ro.->istiviiy and low power factor) and thei? propci ty of retarding the p-js-^gc- of moiatuie and gar^e*- through mtroce}h?loe, chlorinatofl rubber, and other similar plastics films, they arc es|>eciaily useful in coatings for electrical insulating materials. fn chlorinated rubber (Parian} and copolymers 0/ xtyrene-hiitadiene (Phohle S-5), Aroclm 1254 is on excellent plasticizer; and Aroclor 5100 acts as a him fortifier in protective and decorative coatings for concrete and masonry structuies, steel struc tures, railway tank and gondola ears, wood, and metal maritime equipment. Aroclor in these types of coatings imparts excellent lesistancc to flame, corrosion, acids, alkalies, and water; as well as good electrical insulating properties. The Aroelors are most useful in natural and syn thetic rubbers. The liquid Arocloia l?2h 1232, 1242 and 1240 provide a strong plasticizing action Small amounts of Aroclor 12*10 plasticize haid rubber and reduce brittleness. Milled into rubber AroH^r 1254 and 1260 import pormiu^nt tackine-- ',nd db.' i/n. As a ps.'j `.icizi-r for ci< pe-rnbber rest? fformulated mto p>d?>i^). Aroclor 1262 increase::, "ho glo^s and alkali ron Uu.ic- H tlic fhm and i4*- :.uh?.-siVi-r!e<r toward st<-c) Aroclor 1263 has exc^-imit woikmg qualme.i ,it 225-J25vF. as a plastic?;'' r m miectlon molding.-. Ground into powder and nuiled into rub ber at a temperature below its melting point, Aroclor 1268 can be dispersed through the rubber and acts as an efficient flame retardant. In epoxy re.nn coatings, the Aroclor compounds with their excellent chemical resistance, oxidation resistance, and adhesion enable the formulator to reduce costs without detracting from the saleable features of the epoxy resins. In plastic applications, a combination of an Aroclor compound phis anti mony oxide make low-cost non-bummg formula tions. The Aroclor compounds are also useful with phenolic resins, polyester resins, poly?sobutylene, waxes, and rosin. m 0<,?t>053 TOWOLDMONOQ33023 u i jt,rwj*vix.*.BO As .n timnrv teuttutiHiw?,, the Amdnr nhhrnnalnd Aroclor 1221 j*6tv|#h:nv};j have nut pm-unltd UA-.t trial U*xi~ - 5 Properties . f'A^knl When Arcekm v>n poumlr* are ,<tA hi 'k:v;de<i i.tfnp'jt'^ivn:?, Kuf'.k- c-nvy 'A Appearance , . ' Clear, mobile oil fq!* n, >"t be npfdind, dfhnr by tbq u-r; c.f cke.^d *! * Acidity or by dfocllvt* k*\'d-*x.hau;d v^diksfinn to* * ^ 045I4 mg. KOH/gm. max. y'dher wdh nartii workroom exh/u;4 y * Color f f Refractive index @ 20'C, 7 he threnbr-M hrml* <jmxirmmi nil''?5..dJe eoiKxm- fmdion for Kit g~hour v.qrtdm: day) -td by the * Specific gravity Ss^HSJ-C, Anmmqn conference of {kr.em-.mm-f JfygknMs ' ' Chlorine, % 1 0 ftubiyram <>f tin- b*'ynr~'*hk>n*`.-dM AroHor ; j Weight per gallon @ 25SC APHA 100 max. 1,617 to 1.618 1.182 to 1.192 21.0 0.5 9.85 lbs. ; >nf?our?d:; j>< ? c>iMc of air undo n>?Digram | J Boiling point. 760 mm Hg 275>320,SC, of |ho nionohiybly-chloj'imii/al romiymmb, such as ^ Pour point (ASTM D-97) Crystals at kC. Amdor J2v4, |rr cubic mnter of nir. in kln pahh tonts, nnifh^r Arodor 125* alone or n\ a polyvinyl cloxldo Him f 11,> p*jr C'-nt Aroclor) / or Arodor f>4bA in an aikyd rc*in mutiny (17 per ceot Arodu?) on canvas irritated or .-mm iiised the || S| ft i :\ Flash point (C.O.C.) fire point (C.O.C.) Viscosity @37.S*C* 54.4'C. 98,9-C. 286-302af349"F, 38 to 41 SUS 35 to 37 SUS 30 to 31 SUS nkm. f*Specltlcat1onsl t'mtfinwsK- or repeated rkin contact with the Arodot compounds most b** avoided VetoF'-e of the possible occurrence of ddornene. Q 0 m m m m m m o -D Aroclor 1248 * Appearance Clear, mobile oil * Acidity 0.018 mg, KOH/gm. max. - Color APHA 100 max. * Moisture 50 ppm max, Refractive index f> 20*C, 1.630 to 1.631 * Specific gravity 65*/15,5*0, 1.405 to 1,415 Weight per gallon 28s, idling point, 760 mm Mg 12.04 lb, 340 to 375*0. ' f%w pomt, CASTM D-97) ~?*C. flash point (C.O.C.) 379 to 384"f, fke Point CC.O.C.) None to boiling point Viscosity # 37>8'C. ' 54.4'C.* 98<9*C, '^ 185 to 240 SUS 73 to 80 SUS 36 to 3? SUS r*i^sificati^s| Properties Aroclor 1254 Appearance Acidity Color * Moisture Refractive index @ 20*C. * Specific gravity 654/!5>5sC. Weight per gallon @ 25'C. Soiling point, 760 mm Hg Pour point, (ASTM D-9?) flash point tC.O.C) fire point {C.O.C.} Viscosity 3?.8*0. 54.4*C. 98.9C. tight-yellow viscous liquid Q.Q10 mg. KOH/gm, max. APHA 100 max. 50 ppm max. 1.639 to 1.641 1.495 to 1-505 12.82 lb. 365 to 390*C, 10*0. None to boiling point None to boiling point 1800 to 2500 SUS 260 to 340 SUS 44 to 48 SUS j ^Specifications [ # 0 Q O o o o m m 0476054 TOWOLDMONOQ33024 O o oi frt'm Aroclor 1232 0 0 0 hp ,V, iHv tern nve mdex % 20`C. Sprite gmrby 25*115.5*0- {> % per gallon# 25aC Co no/ pomF 763 mm Hg f< ,r pnint, {AS1M D-9?) ICO.CJ Fir** no.t (COC.) Vi?;r**fy 17.H*CS SC4*C. s&rc. Clear, mobde oil 0,014 mg. KOH gm. max. APHA 180 max. 1620-1-622 14/8 to \m 320 x 0.0 10.55 lb. 2S& to 325`C, -35.5*0. 305-3io*f. w?. 44 to SI SUS 39 to 41SUS 31 to 32 SUS |*Spgiftga%rjsl o.a HI 7page 91 Properties Arocfor. 1242 1 * Appearance i * Acidity 1 Color -J Moisture | Refractive index { 20*C. j * Specific gravity 25a/15.5*C. J Weight per gallon @ 25*C. \ Soiling point, 760 mm Hg Pour point (A$TM D-9?} 1 Flash point (C.Q.C.) 1 Fire point {C.O.C.) I Viscosity 37.8*C. I 54.4*0. 1 98.9*C. Clear, mobile oil ,0.15 mg. KOH/gm. max. APHA lOO max. 50 opm max. 1.6274.429 1.381 to 1.392 11.50 lb. 325 to 3S6"C. 13SC, 348 to 356*F, None to boiling point 82 to 92 SUS 49 to 56 SOS 34 to 35 SUS 0 o 0 0 0 m m. Properties Aroclor 1260 r Appearance nd#ty > Color . ! Molftore Refractive index {) 20'C. Specific gravity 90*/15.S8C. Weight per gallon t> 25*C. Holing point, 766 mm Hg f%y? point, <ASTM 097) Fl#t point (C.O.C.) Fire point (C.Q.C.) sily # 54,4*C, 983"C.* tight-yellow, soft, sticky resin 0.S14 mg. KOH/gm. max. APHA 158 max. 58 ppm max. 1.647 to 1X49 1.555 to 1,366 13.50 lb. m to 42o*c. 31aC. None to boiling point None to boiling point 3200 to 4m SUS 72 to 78 SUS o |*Specificatjo'ns"| Properties Aroclor 1262 Appearance Ught-yallow, sticky viscous resin Acidity 0.014 mg. KOH/gm. max. Color APHA 150 max. Chlorine, % 61.5 to 62.5 Refractive index <> 20*0. 1.6501 to 1.6517 Specific gravity 90U15.5'C. 1.572 to 1.583 Weight per gallon <> 258C. 13.72 lb. Boiling point, 760 mm Hg 390 to 425'C. Pour point 35 to 38*C. Flash point (C.O.C.) None to boiling point Fire point (C.O.C.) None to boiling point Viscosity @ 71.0aC, 98.9*0.* 600 to 850 SUS 86 to 100 SUS f*'s'peclficatk>'ns'| m1 m 0476^ m TOWOLDMONOQ33025 Aroclor 1268 * Appearance * P&M'Vf Crh-r Arnmrrn) *>%,*, gravity ?rS !?*>C. V/ *,jhf per gallon ^ 25'C, 8' '*!< * (X' of, ?&) mm Hg Srhcnmg pmnr *>VM t-7Z) U 't pomf (EO.C) f* < P'm-t iC O.C} White te ofNrfnte powder MS mg, K0H/gm. max. 1 5 MPA vmi IS.09 te m to ??0'C. Non* to feotbng pom! NonetoPoilmg pcmt f Propertys Aroclor 4465 Appearance Acuity * Color (molten) Refractive index @ 20*0, Specific gravity 25*f25*. Weight per gallon # 2$*C. Soiling point, 4 mm Hg * Softening point CASTM E2S-51T) Hash point (C.Q.C.) . Firs point (C.O.C.) Viscosity (S) 130"C- Clear, lighbyellow resin 0.05 mg. KOH/gm. max. 2 MPA max. 1.664 to 1.667 1.670 13,91 t>. 230 to 320*C, 60 to 66'C- None to boiling point Mona to boiling point SO to 150 SUS Specifications j 7ro*rti* Aroclor 5442 * Appearance Acidity r Color (molten) Specific gravity 25s/2S!,C, Weight per gallon <S> 25*> Softening point CASTM E28-51T) gplting point, 4 mm Hg Poor point, CASTM 0-971 Plash point (C.G.C.) fife point (C.O.C.) Viscosity ( 9S,9*C, Clear, yellow, sticky resin 0.05 mg. K0H/gm> max. 2 NFA max. I.47S 12.24 lb. 46 to 52*C, 215 to 300'C. 46*C. 477*F. >662*F, m to m sus Specifications 1 Aroclor 5460 Properties I Appearance Clear, yellow fp amber. brittle resin or flakes Acidity 1 * Color (molten) 0.05 mg. KOH/gm. max. 2 MPA max. Refractive index @ 20"C. I.66D to 1.665 Specific gravity 25*/2"C. 1.670 f Chlorine, % 59.5 Weight per galion @ 25*C. 13.91 Boiling point, 5 mm Hg 2m to SB^C. * Softening point (ASTM E28-51T) 98 to 105'C. Plash point (C.O.C.) None to boiling point Fire point (C.O.C.) None to boiling point Specifications j 0 G) O m e 04 76056 e TOWOLDMONOQ33026 , ;#.;r r I J t " ' ' o ' r**" I# ':!.' T >&P,:* i Q "'T'" O . \ o o o Summary of Specifications and Typical Properties For your convenience the following chart lists Monsanto's Permanent, Sulfonamide, and Miscellaneous plasticizers. If a specific property is D ideally suited for a specific application simply find the optimum value of that property in the vertical column, the name of the plasticizer o offering this value may be read from the left hand listing. o m ow VL-I ... 1 <H?60Sy TOWOLDMONOQ33027 MOMS POV t M m m t tS OTH EH: SanttctMf ! Stffciitr4K $ant>c>;?r409 3antw m itrtutltr 462 $rticar4S8 ' Sanbe*zer48t - Sant*e*;ter 482 Zsiniicher 4$1 -- | * 14) -- 1 * 14) - | * us -- | * to -- I * 0.24 -- j * 0.60 -- ! * 0,85 -- j*U - * 024 * Cigar, viscous liquid * Claw, city liquid * Clear Mauid * tight yellow* viscous liquid some solids on standing * Clear, oily liquid * CI*r, oily Mould * Clear, oily liquid Clear oily liquid * Clear, oily liquid * 250 (50ml.; 50ml.) 95% Ethanol 200 (SSmf.s 50mi.) %% Ethanol * 158 mmU 50ml) 95% Ethanol * 17$ (50mL; 50ml.) 95% Ethanol *m *m *m * 325 * 125 * 0,1$ * &15 : * 8.15 * 0.15 * S.15 * 0.15 * 0,15 * 8.15 * S.15 1 Santlcizer 1-H ; Santietawl Santscizer 8 Santidzer 9 ; Santcsfite MNP SantoliM MS-5% 1' ! Arocior 1221 ; Afocter !232 Arocior 1242 ' Arcelor 1248 o Arocior 1254 ' Arocior 1260 Arocior 1262 , Arocior 1268 Arocior 4465 , Arcelor 5442 5 Arocior 5460 ' ^ 2S336 199J3 19942 1714 - - * 1,00 * 0JO pH 4.0 (mm.) X,0 (mg KON/g) - * Yellow-lx-oum fused mass . * 300 (molten) . * 845 * Practically white solid * 60 (molten) . * 0.25 ; * light-yellow, viscous liquid * 200 (molten) ; -* * Pine, white to light-cream granular particle * 85 (33-1/3 wt. % in acetone) ' Hard, practically colorless resin * 50 (25g;?5g butyl acetate) * Light-colored, viscous liquid. Free flowing above 20*C * 80 (25g:35g butyl acetate) . * L0 : *' _ - . ~ -- * .0X4 (mg KOH/s?) * <814 (mg KOH/g) * .81$ (mg KQM/g) * .0X0 (mg KOH/g) * 0.10 (mg KOH/g) * 8.14 (mg KOH/g) * .014 (mg KOH/g) * .05 (mg KOH/g) 0.5 (mg KOH/g) * .05 (mg KOH/g) .05 (mg KOH/g) Clear, mobile oil Clear, mobile oil * Clear, mobile oil * Clear, mobile oil tight-yellow viscous liquid * Light-yellow, soft, sticky resin * tight-yellow, sticky, viscous resin * White to off-white powder * Clear, light-yellow resin * Clear, yellow, sticky resin * Clear, yeiiow-io-amber - brittle resin or flakes * 100 * 100 * XO0 . * X00 * XQ0 * 150 4 150 * 1.5 NPA (molten) 2 NPA max. (molten) * 2 NPA max. (molten) * 2 NPA max. (molten) -- * 58 (ppm * 50 (ppm * 50 (ppm * 50 (ppm - ,, ,, - H8-40 ! Mod-Epo* ` Phosgard C'22-ft s Triphenyl Phosphite _ ~ 8I 3X0,28 * 0.08 (mg KOH/s) * 5.0 * 0.8 (mq. KOH*> Clear, oily liquid * 100 * Oily liquid or light-yellow solid * 50 * Clear, viscous liquid * 50 * Oily liquid or light-yellow solid * 50 ' * 125 p '_ ~~ 047605* TOWOLDMONOQ33028 m s^onsamto plasticizers^ Bv' 4Bw- is * rat>, iiwih fispAJ * 25C {70* * *r#s\y 95% Ohanol * 0.15 %& * ClraqnPy liquid ' 200 immumir^ 95% Cthanot * 0.15 5.S * fleer Uqora ' * 150 mnU 50mU 05% ethanol * 0.J5 m * t *ght yeifow, v<-'C0o2 liquid rame sohdc on standing * 175 mm!.- TOmf.) 95% Elhaiiol * 0,15 * Characteristic 1475 1 * Very slight, characteristic 1.478 Very taint, ester 1.4654 : j * Slight, characteristic 1-4772 m rm * Clear, wfy hquid >w ' fhra'.cdy h$n>4 *m *m *045 * 0-15 Charattariitis Slight, characteristic IS* to 1.510 14043 @ '2& * Cfoaq osly hquid 1 t iloa* yily bquid *m * $ * 045 * 045' Slight, characteristic . Slight, characteristic 1,4795 1,4751 ^; Vi m * <l*q,0dy liquid * IB * 045 Slight, characteristic * 15015 to 1.5050 - im m .40 ?fo.) i.0 * effow-bmwn fused mass . * m (molten) * Practically wm?e solid * 6D (molten) * tlght-yelbm vtscws liquid * 200 (molten) * for*, whne to ughterm-m granular pAtV'Jes * 15 (334/3 wt % In acetone) * Ha?d, practically colorless resin * 50 {2$gs?5g butyl acetate) ' t ght-colerad, w&eous liquid, foea flowing ehoxe 20*C * IS C2g45g butyl acetate) * 045 m *u - ' -- * Slight, characteristic . Essentially none Faint formaldehyde - ~ 1312 to 1532 (65*0 AM 1340 _ Wf 1.4275 to 1.4325 C2^s?5g butyl acetate) rs. -- W) /ioH.'g) ! AM mobile oil Hw, mobile od * Cfoa', mobile od * C'ear, mobile od t gnbyellow ws/,os liquid a< * mt/fj * L get yeifow, soft, sttcfey resin m * iughi-yellow, sticky, ****''& ,, vssoous recm 4)5 sKOH/d ' White to off-wMe powder >5 * Clear, lght-yeow resin $5 *#0HW J5 * Csear, yellow, sticky resin * Clear, yeliow-ta-amber ivihfo recm or flakes * 100 _ * 100 * 100 * 100 * 100 * 150 * ISO - * 50 {ppm max.) * 50 (ppm max.) * 50 (ppm max.) * 50 * {ppm max.) -- * IS NFA {molten} 2 NPA max* {molten) -- _ * 2 NPA max. {molten} - * 2 NPA max, (molten) - --, -- _ _ _ - 1.617 to 1.618 (20*C) t,0 to 1S 20-0 1427 to!mm*Q AJ ^ im to 1531 (20*0 |||| 1.639 to 1.641 {20*C} 1.647 to 1.649 (20*0 15501 to 15517 {20*0 .- ' .. @ 1564 to 1.667 (20*0 - t @i 1560 to 1,665 m*C} _ Clear, oily liquid * 100 * IS ppm ? * City liquid or tight-yellow solid * m iSIH.'sL. -- 9 * Clear, viscous liquid * so - - a 0. KOHg} * Gdy liquid or light yellow solid * 50 - Faint characteristic _ Essentially none - 15600 to 15750 * 1587 to 1590 * 1492 to 1.494 * 1.5875 to 15900 ^1 9 ^1 0476059 TOWOLDMONOQ33029 TOWOLDMON0033030 0476061 TOWOLDMONOQ33031 !r_at.'-r, .;; 7~. , * *"** s ' ::.;, t*ji **< . , ' ~;*'r I' .J.r . ?(/ - f r. ...I tt. .. * >?** ----r* "Si I i ' .3^!^ ' i ' 7 i.lttfeel! f;^5 0*76062 TOWOLDMONOQ33032 TOWOLDMONOQ33033 0 O . 0 o m m :::;7T f. f * r ,,' /:"f with DOP ' ItffppiMSi % with DOA V with SANTICIZER 141 r? 7 Q o FLAME-RETARDANT MODIFIERS 0 0 Fire retardant plastics materials are growing in favor in many end uses. m Recent Underwriters Laboratories' rulings on air conditioners, the California fire laws on plastics film, and the specifications of end-product m users mark a trend toward greater safety consciousness. This awareness for possible dangers will increasingly put a limit upon the flammability of materials of manufacture, construction, and decoration. Monsanto supplies a variety of plasticizers which provide molecular structures with tightly linked chlorine and phosphorus, to impart fire resistance to compositions containing them. These plasticizers represent a range of properties, in addition to the imparting of fire resistance, that make them efficient plasticizers for a variety of resins for uses in a large number of diverse applications. These plasticizers offer a choice of price and compatibilities; many offer outstanding chemical resistance, extraction resistance, and good permanence. By selecting a one, two, or three component plasticizer system based on these products, the formu lator can develop fire-resistant compositions using a number of resins, offer a variety of end product characteristics, in a range of costs. O-riKtOb* TOWOLDMONOQ33034 FtAME-RETARDANT MO0IFK8S to*rtj4K The following r liquid and solid Arc-rot aidant modifiers: TRICRESYL PHOSPHATE Tric.re.iy! phosphate is a standard flame retarding liquid pkuticizer for polyvinyl chloride, cellulose (excepting acetate), and synthetic rubber. It has low volatility and offers (rood permanence; it is especially recommended for electrical insulation applications. It is also compatible with phonetics, imparts a degree of flexibility to phenolic electrical laminates. f --------- ---r~ I-------'i 11., *i aaa.. . SANTICIZER 140 Santicizer 140 is a phosphate type liquid plasticizer. It makes an excellent general purpose plasticizer as well as a means of making flame resistant products. On a pound for pound basis it is more eflident than tricresyl phosphate in vinyl resins and imparts a superior flexibility. TRIPHENYL PHOSPHATE Triphenyl phosphate U a solid plasticizer, particularly suited for producing flame retardant cellulosic compositions and coatings. It may also !>e used with synthetic rubber and with a variety of vinyl resins in conjunction with a solvating type plasticizer. SANTICIZER 141 S&nticfzer 141 is a liquid, phosphate-type general purpose plasticizer which is non-toxic. It imparts good low temperature flexibility, has low odor and improves the processing characteristics of most formulations because of its excellent resin solvating power. . 4 m o ' Q m 0 Q AROCLOR PLASTICIZERS MONTAR PLASTICIZERS The Arocior polychlorinated biphenyls' and terphenyls are particularly effective in reducing ftameout time and the glow termed "punking." The Arocior compounds are compatible in varying degree* with vinyls, celiufosic*, rubbers, poiyethylene, and epoxies. m These polychlorinated polyphenvls are similar to Arocior* except for their dark color and lower cost. Although slightly compatible with vinyls (for use as low-cost, extender plasticizers where color can be tolerated), they are especially effective in asphalt, to which they impart instant flameout when present in concentrations of 25 to 30 per cent. ,mBMi8M \ PHOSGARD C-22-R Phosgard C-22-R is a flame-retardant organophosphorus polymer for urethane foams, polymethylmethacrylate, phenolic*, polyester resins and epoxies with optimum performance properties: high efficiency through high phosphorus and chlorine content, essentially non-volatile for lasting flame-retardant service life, excellent color stability on XJV and heat exposure, easy formulating and non-oomplSeated handling, long storage stability ("per se" or in formulation), and good hydro lytic stability, 0476065 s e o m o TOWOLDMONOQ33035 .. . . ...- i SOLID PLASTICIZERS 1 Solid plasticizers perform unusual functions in adhesive*, coatings and lacquers, foams, rigid compositions and films. Many times solid plasticizers are overlooked in solving processing problems or in obtaining unique product properties. A solid plasticizer often transforms a deficient product info a completely different, high performance product HOT PROCESSING Solid plasticisers offer processing advantages in hot processing applications. For example, in Banbury mixing, a solid plasticiser will melt at or below the processing temperature and function as a solvating or fluxing liquid; the lowered viscosity of the Banbury charge improves the flow resulting in faster and easier processing. Upon cooling, the plasticizer returns to a solid form producing a rigid or semi-rigid film or molded product. The solid plasticizer thus reduces processing costs as well as imparting unique, properties to the finished product. SOLVENT PROCESSING Certain solid plasticizers enable successful formulation of higher solids content in lacquers. This means fewer coats to build a surface and, there fore, reduced application costs. As the lacquer dries, the presence of the solid plasticizer helps reduce blushing, sweating and separation. \ ! 0476066 i TOWOLDMONOQ33036 SOUD PLASTICIZERS (continue Description of Monsanto Solid Plasticizers n Plasticizer Description m f! > iI Melting Point or Softening Range (C) m m m in m Q Q m a o Q Q o m m m m m TOWOLDMONOQ33037 Mt/pag 1 o0 0 m m 0 o m o 0 m m m FOR ADHESIVES ,.. unusual properties Delayed-lack and hent-seaJ adhesives owe their existence to solid plasticizers, because it is the solid plasticizer that makes delayed-tack and heat sealing possible. Delayed-tack adhesives are activated hy beat, and once activated, remain tacky tong enough to permit handling before the adhesive eoojs and s-is. The sharp melting point of solid plasticizers provides a sharp activa tion point for the adhesive. This activation temperature varies with different solid plasticizers, and special adhesives am he easily formulated to fit handling methods hy selecting the proper solid plasticizer. Delayed-tack adhesives are covered by several U.S. Patents. FOR FILMS ... no blocking Solid plasticisers can be used with other primary plasticizers to produce tough, clear films that feel dry and separate easily. Liquid plasticizers used alone often cause blocking due to a slight surface tackiness. Solid plasticizers also add resilience to films and impart exceptional resist ance to extraction by kerosene, oils and grease. FOR RIGID PRODUCTS .., easier processing , Processing of rigid vinyl products can be made easier by using solid plasticizers . . . without changing present equipment or methods. With heating, the solid melts and acts as a solvating liquid plasticizer for the resin. Upon cooling, the article becomes rigid because the plasticiz ing effect of the solid plasticizer is slight at room temperature. Used strictly as a processing aid, the solid plasticizer pays its own way by lowering processing costs. FOR HEAT-SEAL COATINGS ,.. sharp activation temperature Like adhesives, heat-seal coatings require the sharp melting points of solid plasticizers to give them the beai-.-eai property. By themselves, liquid plasticizers cannot endow coatings with a sharp activation temperature. Instead, the coatings tend to block and be tacky at tempera tures beneath (he activation temperature. In this type of coating, solid plasticizers can be chosen to provide an exact temperature at which t}ie heat-seal property is activated. And be neath that critical temperature, the coating docs not block or have tackiness. FOR RIGID FOAMS ., . toughness In the chemically-blown foams, solid plasticizers can be used to add' toughness to the finished foam. In the plastigol foam process, solid plasticizers thicken the starting formulation to make pos sible more uniform ceil formation as the gas is released. A uniform cellular structure makes the foam tough and provides uniform dimensional stability. In chemically-blown vinyl foams made by milling or Banburying, the solid plasticizer acts as a liquid solvating plasticiser at the process temperature to make possible easy processing. At room temperature, the solid plasticizer's inefficiency results in a higher compression-resistant foam. FOR IMPREGNANTS .,. better flow To get even dispersement of impregnating powders, solid .plasticizers can be used as a flow aid for producing brake band linings. The flow aid property is.also useful in certain types of adhesives, phenolic moldings, thermosetting ureas, and melamine coatings. 04 76068 TOWOLDMONOQ33038 Heat-seeling eastings Oicyclohexyi phthalate <0CHP|2 Diphenyl phthalate, Saniofite* MHP, Smtitiz^r* 1-H, Santicizer 9 Rigid extrusions Diphenyl phthalate, Arcelor* 5460, Triphenyl phosphate Santicizer i-H, DCHP Moldings and rigid foams Triphenyl phosphate, Diphenyl phthalate, Aroclor 5460 and 1268, DCHP Break-awey *gb$sH Santoiite MNP Phenolic brake lininp Santicizer 9, Aroclor 1268 Surface coatlnp and composition wallboard Cellulose acetate Triphenyl phosphate Nitrocellulose DCHP, Diphenyl phthalate, Santolite MHP, Aroclor 5460 Melamine Santicizer 9 Thermosetting resins Santicizer % Santicizer 1-H, Triphenyl phosphate, Aroclor 5460 and 1268 Urea molding compounds Santicizer 9 Melamine molding compounds Santicizer 9 Fire-resistant cellulose acetate Triphenyl phosphate Crystallizing lacquers Santicizer 1-H Polyamides Santicizer 9. Santicizer 1-H Vinyl and other hot melts Triphenyl phosphate, DCHP, Diphenyl phthalate, Aroclor 5460 and 1268, Montar* < 5, and 9 Belayed-taek adhesives Diphenyl phthalate, Santicizer J-H DCHP Hook-hindleg adhesives Triphenyl phosphate, DCHP, Oiphenyi phthalate, Aroclor 5460 and 1268, Santolite MHP, Santicizer 1-H U # 4 Registered U,$. Pet. Off., Monsanto Company TOWOLDMONOQ33039 m o o i 0 0 m m o o Q O O' Q O plasticizer- mmsm compatibility; guide The following table shows a close approximation of the upper limit of compatibility of each of Monsanto's plasticizers with a particular type of resin, ' o%ft70 TOWOLDMON0033040 TOWOLDMONOQ33041 ca xu io sic ! v im type Plasticizer^Resin Compatibility Guide O i >,/ ; m 300 ' 300 m 90 ISO 75 n 100 100 68 ISO 20 1 i 1 15 15 25 ; re o"S 1 : i 3 ; * 1 i 1 3 1 1 i 40 50 40 40 00 50 a 100 50 50 50 100 ' 10 r, ; 25 25 ; 5a 1 25 i 100 100 $8 100 50 so 50 100 50 56 56 100 : 10 QJJ\ Z} ` 25 25 10 ) 25 20 10 io 15 15 75 75 SO 75 a 20 25 50 20 a 25 75 \ 1 j m > m 100 n ^ 100 60 n 25 100 a 15 50 100 15 a IS 10 a 10 10 10 30 : :* O i I 1 10SI 50 60 40 | 108 ?0 40 35 35 a 100 100 100 100 75 75 80 80 SO 100 100 loo ; ic ! ^ | 100 10S 75 ! xm 80 75 100 100 50 76 100 50 70 30 m 00 6S 75 75 n 75 ; 1 1 *; i If f 1 1 1 1 i B 20 10 15 35 26 45 a 30 a 25 108 j l o 40 25 30 28 | 58 55 a 50 25 25 30 a a 30 50 40 40 58 25 50 50 iso ; j a 1" 44 1"-----5 10 j 5 ) 20 5 5 1 1 40 100 40 50 .50 0 100 50 50 50 180 ; ' 1 j 1M M ; 100 100 ' 25 100 25 100 100 100 100 100 100 100 50 25 25 50 50 50 68 ; ; a w 50 - 40 40 ' 40 50 B 40 20 a 20 50 50 50 50 a a 25 25 25 a 25 50 : - a-; 1 ' i i i ! 1 t 1 1 1 i 0 a IS 30 10 30 30 50 40 25 a 25 ' J . I f1 1 1 ,1 1 1 1 1 i 1 1 1 a a 40 60 a a 10 : - --i* ( a ' 10 JO | i { 25 i 1 1 1 1 a 100 a 25 25 a a 25 a 25 i a i 1 1 I l ! 26 25 25 25. 25 a a 15 a 10 50 50 50 a 58 50 ' * ! ; ...''1 i 0 15 5 i 5 j 5 - 10 1 5 5 1 1 1 a a 20 m 10 5 5 10 5 a 20 5 j10 ? 1 j i 1 1 1 1 1 25 a a 25 IS a 20 50 58 a a a r ^SSr j 1--------1 | m 25 s 25 25 , 25 f 25 25 2S 25 a 25 ,50 50 50 50 50 50 50 50 50 so 58 50 .i O 25 j 25 25 25 ; a 25 25 a 50 a 70 70 50 70 50 40 30 a a a a 70 O e "7] % 1 j 1 J I 1 i i i i 1 1 1 ij i a a 50 go a a 11------- ' 20 20 ' 20 25 20 28 15 15 15 a 25 a 25 10 10 10 20 10 a a 25 - ...... * 50 ' 50 50 ! 56 50 5^ 50 33 20 33 33 40 50 55 50 50 50 50 50 50 50 50 TOWOLDMONOQ33042 TOWOLDMONOQ33043 exudation so that tack and dirt pick-up are frequently observed m a month or two, Comptetaiy saturated polymeric plasticizers. such as Santicieer 409, remain tack fra# mpm exposure to fforth indirect daylight for mom than oris year. oi hs enportaot in many vinyl applications. Plasticizers with g#<r%4 humidity compatibility do not exude from film specimens in IS weeks' exposure at 60'C end KM5*per cent revive humidity. Potential plasticizers are quickly screened for compatibility with polyvinyl chloride by com* pressing loops of plasticized vinyl specimens for one week at 23*C and 50 per cent relative humidity. The amount of plasticizer squeezed out, if any, is determined by wiping the inside of the fold with cigarette paper. * 0476074 TOWOLDMONOQ33044 TOWOLDMONOQ33045  nmm '':S: . J \ Cellule** Nitrate , 'irtpg&iyji Phosphate- Sadidzer I-H -: Santdze? 1B ' S&ntidzer Ml ' .- Saddtte MHP Diphenyl Pdhadte . Sadtdterg ` : Sadidzer 160 i Sadidzer 2S2:" 1 Tncresyl Phosphate* Sadidzer 165 AfOClOf Santdite MHP SanticUer 8 ;< if" Dihotyi Phthalate ? Dactyl Phthalate i Saobazer 160 : SantiCizer 165 ; Sadidzer 262. . |:j I ... . Ummm&H SadidzerS . SaaticizerS . Odthyl Phthalate j '- 1 Cdluteea Acetate 11 ' $sn#dzerS . SadldzerM4? . Saddlte MHP ' Diethyl Phthalate . Sadidzer -15 Smticmrm? Santotite 84HP Saotolita MS-^% $m(tck&r $ . | : Santicker M-l? 1 ^ i. i: 4 ............................................ : Sadidzer 1-H Sadidzer 8 Sadldzer 8 Sadidzer 141 \] | Cetfoie** Acetate- Sadidzer $ Diethyl Phthalate Santidzer M-l? Dioctyl Phthalate | f &upmi8 $&nticmr M~\7 Sadidzer -15 $snioltU MHP Dibutyi Phthalate | Dleydohej^i Phthalate Arsdof _________ JJ ! Ethyl Cellulose ; AClfilC 1 ` Polystyrene i\ 1I reiyvinmytiiwuwtwv Btztyzal Mirlnjrl Acaiata Pdyyieyl Alcohol Santldzer l-H Sadidzer S Santicizer M47 Sadidzer 8 Diethyl Phthalate Santidzer -15 $mmm t-H Sadolite MHP Diphenyl Phthalate Oieyetebexyl Phthalate &DniotfitcWwxf y1!-HPhthalate Dfphanjrt PMhalatt Sadidzer 9 Diphenyl Phthalate Sadidzer 8 Santicizer M4? Sadidzer IS3 Smticiz&r 141 Sadicizer 8-16 Sadidzer 262 Chphenyl Phthalate Sadidzer 0 Saddite MHP doctor Diphenyl Phthalate ?ricre*yl Phosphate Santicizer 148 Samicizer 27B Senhcaer 160 $anbc<zer262 Diphenyl Phihelete Dicydohexyl Phthalate Trrcresyl Phosphate Sadiazer 140 . Amdor Tricresyi Phosphate , Santlciz^- 8-16 Swttteiar B-16 Sattlictorl Sadidzer 168 Sadidzer 141 Dioetyi Adpate Di{n-ctyl, rKiecyi) Adipate Sadidzer 160 Sadidzer 141 Santkizarl Tricresyi Phosphate Sadidzer 8-16 Sadidzer 8 Sadidzer 9 Sadicjzer M4? Arodor $*ocir 8 Santieinr M-17 Santicizer 846 Santicizar 160 SaotioizerS Saotidzer M-17 Samdite MHP Saotdite MS-60% Sadidzer g . Sadidzas1 f Santollta MHP hfocim Santidzer 8 S&niom MHP Sartticizer 166 Sant>c>zr^2 Dicydohexyl Phthaiate Saotidzar S Sadidzer 8 Saddita MHP Aroclor Sadicker 160 - Aroclor Sadoitte MHP Santidzer 278 Sanhcizer 262 , Sadidzer 160 Sadidzar 8-16 Sadickar $ Arociof Diethyl Phthalata Dimethyl Phthaiata Sadidzer 9 Santidzer 8 ?| Santlctiw M-17 j 1 , Dioctyl AOipate ; 1 Oiisodecyl Di(n-octyl, Adipate rvdecyll ^.* i| M'mm ;| Sadicizer 160 Sadidzer 141 Santidzer 8-16 Santidzer 262 \\ '| ?f ?| Dibutyi Phthalate > \ Santidzer 141 j| Diootyt Adidite -1 Ditn-octyh Adipate o-decylj * \ ; Diisodecyl AOipate ; ? j; Santtciz Ml Santicizer MS 'i ^ 'i mbutyi Phthaiate Santidzer 141 - Ir Sadidzer M47 Sadidzer -15 ' Arodor S*ntlcta*r Ml DibuM Phthaiate Santidzw B-16 SaMidterl `* ,, << _^___-- E** V | vn)<Ui3tS( nOK99< f (p*rtel j ! Styrene-Butablene | {Plietlte * 1 Martel j | Ctaatit. Zaiit :I Ar*el0f Mob-Spo* Sadidzer * Triphenyl Phosphate $itfekr 140 AfOClOf Tricresyi Phosphate Arodor Olbotyl Phthalate SMlctZf # Santlcinr B-1S Dibutyl Phthalete Santlciz^ 141 Samidzar 160 Santidzer M-l? Santidzsf 160 Smkizer 141 Santiciz^ $. Rfe0-pox Arodot Arodor Sanlicijef JW Triphenyl pftoss^ate THcresyi Phosphate Arodor Tricresyl Phosphate Tripherryl Phosphate Saotidzer g Sadidzer 0 Sadidzer B-16 i' '! Santidzer 141 : * Dibutyi Phthalate - / Santidzer 1^1 . * -a Sadidzer 160 d Santidzer 141 - Sznticmr 8-16 i Sadidzer S ; 04760?* TOWOLDMONOQ33046 PhtmteH 0>bntyt Phthalate xtyi Pfc&wfeM t Sanhcizer j$5 ohcizer UM l ^tntfc>zar ' -nbcnrer W> I Tfipheo/I phosphate! ntklzertR f ' G&gckgmtf Fhihitlafe Oiptmfigt PhmM Trlezesyf Santicizer 4fi9 %olmeMHP. .. Sanfklier 146 ' Sanfkizer 8 Otphenyl Pbthatate Santolite MHP. Zityl Phth&i&t ' Triphenyl Phosphates hstkbzet $ \ Santicizer $ ! Sentidzer 1>H mticcfe*ir I Sanhazet 45 Tnphmfl Phosphate SantoHte MNP HI f Tnnhenyl Phnsphaiel Santicizer 1-B >octyi PbtH4a'g I Santicizer 140 Tdphenyi Phosphate -IMyl phin;4/dr f Sanhcizer 8 Diphenyl Phthalate Amdor Santicizer Sontidzer -1? Sanlicizer 3 Santicizer E-15 Santohte MHP Sanbcizer I Santicizer 47 Ssniklzm 45 Santoiile MHP Tfipbenyl Phesplrate Santicizer 141 Santicizer 140 Santicizer HI Trtcresyl Phespiiate Triphenyl Phosphate .Arpclor .wttcker t anhclz&r i? ' TnpMnyf Phosphate f ; Samir szer 140 SanUcszer 8 hpctyl Ad'pdc ; i-mtidzer M4? nisodecyl bd<i &,t i lnphef*y Phthalate d octyf, n d?yh I Sannci/er 8 *6*3***.....T- . 1 _ ________ ____ .,, -anhoxez 1/4 >*tuze/ HI ,muauf 8 & Sanhuzer 160 Santtttze* 8-10 Santicizer 262 >anttczer 262 $amlcizar i-H Otpheyi Phtftalate Dicyephaasyl Pbfhaiat DipbanyIi PFnbthalate OitnAyl PhihaMe Sanbozer HI 'sm&Kittt Ut -- l Samio/er 160 j $&mmm 84$ Oiphsr^l mh&tm Tripheny} Fm&phaU Santicizer 0 Santicizer 47 Santtcizer 45 Santohte MHP Santieize? 8 Diphenyl Phthalale Sanitcizer 8 Santieizer 846 Saotidzer 160 Santieizer 262 Dicyclohexyi Phthalate Santidzer 8 Santicizez 9 Santicizar 840 Triphenyl Phosphate .Santicizer 140 Tficresyl Phosphate Santicizer 141 Aroclor Tripberryi Phosphate Tricresyl Phi^phate Santicizer 141 Santicizer 140 Phosgard C-22-P Aroclor Tricresyi Phosphate Santicizer 141 Dwtyl Ad>o8?* tnoctyl Adipate g%-0fyl,n-^cy^ Di^-octyj. n decyl) Afloat* f Adipate Olisedecyi Ad.pat* f On&odecyf Adipate l Dipbenyi Phthaiate Santicim 213 AfOClOf $anticrref409 Sartticlzef 8*10 Santicizer 141 Santicizer iai Tricresyi Phosphate Santicizer 140 Santicizer HI Aroclor Sanfrdze' HI Sanbazer 840 Santicizer 141 i Santicizer 160 Santicizer 846 Diphenyl Phthalate Dicyctohexyi Phtbaiate Tricresyi Pbosphata Santicizer 8-16 Santicizer 160 Tricresyi Phosphate Santicizer HI Santicizer 140 DifctAyi pmhaizte : Santicizer 8 Seofcazer HI , Tr*pbenyi Phosphate f Sentrcrzer 846 ....| Cotrotyl Phthalate ^nticwM-!? Santkrza?-B ! Sanhdzer 4? ' Senildzer 45 Diphenyl Phtbalate Smiitizzr 1-H Tripbeny} Phosphat# Oicyciohexyi Phibaiate Santickor S Triphenyl Phosphate SaMldzer Hi fDibotyt Phthalate Drfcotyi phmmde Santiccrer 100 Senfceuer Wy l Amclor Santicizer 8 0fbutyl*Phthalate Santicizer l^i Santicizer 8 Santicizer Santicizer 160 Diethyl Phthalate Aroclor Tricresyi Phosphate Triphenyl Phosphate Santicizer 141 Triphenyl Phosphate Tricresyi Phosphate Aroclor Santicizer 141 Tricresyi Phosphate Santicizer M4? Santicizer 45 Diethyl Phthalate Dimethyl Phthalate Sanikizer M4? Sentidzer 409 Santicizer 846 Dioctyi Phthalate Santicizer M47 Santicizer E-15 Diethyl Phthalate Dioctyi Adipate Ditn-oetyh n-dec^l) Adipate Dioctyi PhthalateSanticizer 160 Santicizer 8-16 Santicizer 262 Dibutyi Phthalate Santicizer 160 Dioctyi Phthalate Diisodecyl Phthalate Santicizer 409 Santicizer 160 Santicizer 846 Dicydohexyi Phthalate 1 Oibutyi Phthalate Santicizer 160 Diethyl Phthalate Santicizer 8-16 Santicizer M47 Santicizer 45 Santicizer 846 Santicizer 8-16 Santicizer 45 Diethyl Phthalate : Bmtldm & ?o { Santicizer 846 fSantczf HI ' Santfeizer 846 | O&utyl Phtba ate ? O'butvi Phthalate j Sanilchw |i$ | SaeHdzer 141 1 ^ ^___ _ f Tncresyl Phosphate TSanticizer W? "1 Santicizer 160 "' i 5atfclza< Hi | Sawtidizaf 8 1$ ' Sa^ticizer 141 ; Santkizer 846 l Samkizar g ] Santicuer 8 Mod-Epo* Santlcizer 8 Arodor Arodo? Tdphenyl f4tpsphat Tricresyl Phosphate Santicizer 140 Tricresyi Phosphate.. SanMeize* 140 Tripbenyi Phosphate ^pctor_____ Santfcizerf Santicizer 8-16 Santicizer 100 Mod-Cpo* Oibutyl Phthatete S&ntwmr 8-16 Santicizer M47 Santlciz^ 160 Santicizer 846 Santicizer 141 Santicizer 8 SanK-c/zer 9 Aroclor Mod-Epox Tricresyi Phosphate Santicizer 140 Aroclor Tricresyi Phosphate Santicizer HI Aroclor Tricresyi Phosphate Santicizer 141 Santicizer 8-16 Santicizer 846 Santicizer 160 Di&otyl Phthalate Santicizer 160 Santicizer 8-16 Dibutyi Phthalate 04T*0?7 TOWOLDMONOQ33047 ^*P! 8'l$ | Snf 141 _t Santidzer 160 ..-f fzm tons. '/ >4thdate* ^11?..Jpsoc'V8 *<npat ! S^nn. f;</f W5 jgmA - WjjBf;; Santidzer 141 . Tricresyl Phosphate Sanneszer HO Santicizer HI Santicizer 252 Dioctyl Phthalate Aroctef *.. 5 . * i. . P '! *- Ksnticittr 8 Santidzer *447- Santidzer 46 : QtefhyJ Phthalate Santicizer 160 Tricresy? Phosphate Sentic^erS Santicizer 762 Santieizar M*l? 0`octyl Pnthalate SaotiCizer 160 Santidzer 141 San,ti.dzerv262. Arocior Saeticizer ht*17 .... Santidzer 8 ' ^htkizer E4 - Santidzer *447 SahtidzerS . - - %mtetm MHP . |3B%i lip! 1 1 jiy Santidzer 45 Santidzer 848 Smtiimw 141 Diociyi Phthalate* Paetyi Mmt% %mMwm 45 I Diethyl Phthalate _g_ | Dioctyl Mlpata S#*itici3^r 1# Tricresyl Phosphate fa!W$W Dioctyl Phlfiaiate Trmmyt Phosohato g&nimzw WSi Sanlklzer S Tripheoyi Phosphate Seotidzer 409 ^htldzer 140 Santidzer 8 Santidzer M4? Santidzer 149 Santidzer A Santicizer *447 m Otethyl PMhaiate SartHcket 8 Santidzer 1# Santicizer H-17 Santidzer 8 Triphenyl Ph^phate Santidzer M-17 Dibuty! Phthalate Santicizer 160 Dioctyl ^hthalate Santicizer 165 Santicizer 262 ' Santoiite MHP Santscizer 45 Santicizer M4? Santdite MHP ' nttcizr M47 Sarticser E45 ; ^ r i: ; ' |;., h |' 1 1 Santidzer M4? Santicizer -15 ( I f SanltdMr 84$ 1 S&ntfdzar 45 i^s-f Saniklzer 141 ffw Dioctyi Phthalate* Santidzer 846 Sawtidzer 141 Q ^ Santidzer 846 gB Sartfdze? Ml Dioctyt Adpate Tricresyi Phosphate Dioctyi Palate Santidzer m Santidzer HI Santidzer ISO Ssntkiaer 141 Santicizer 2$2 Oioctyf Phthafate Tricresyf Phosphate $antcf 160 Trktesyl Fl^osphatt $atki**f 762 $atictzer U47 Saoticizer -15 Tddienyl Phosphate Sthtidzer 8 Sadjcaet M-l? $aticzer 8 Santidzer 1M Santicizer ^2 Dioctyt Phthalate Santidzer 400 Dhsnoctyt Phthaiafce Santidzer 160 Santidzer 141 Santidzer 262 Trtphenyl Phosphate l Santicizer l-H |- Santiciz^S | Santidzer 8-16 Santidzer 160 Dibutyl Phthalate Santidzer 2^ !' f 1 | Sundciw Ml Oiphenyi Ptithaiat StntkaM 1M doctor SanUclJ^ 141 SfntlclMf Saieaef ltt wipneoyt roaiate Oicyciphexyl Phthalate Sanheizer 160 Santidzer 160 Santicizer 8-16 ` 1 1 f jm* lgp ^ flB ^ g^ SanfYzer 141 Sent t*r 846 SmX-r,zxtm 'Hoc*'/ PhtNslate* 0if*> ?ctyt Phthalate 0W4d Adpt8 &WS ir S-S8 $An*x>rcf 141 Cfe-Jy! Admans gn Br Drifv; Phtha?t Sant-c m 846 Senhc zer 6'15 Sard'- zar 160 Sanhc zer 45 0Klvi Adipate -- j4B| 9P Oi-tfv Pnmlt S*S.cz<rf.W Snt,r r 8-W Oieti^i P4ipte Sntv.ixr Ml S<lt>tZ*r 1 flfc Sanndzer 846 BF, Sami ^ zer 45 Santidzer m Santicizer 262 Urnodeeyi Phthalate Tricresyl Phosphate Santicizer 140 fntmyl Phosphate Santitizar 141 ' Santicizer 140 Santiazer 160 Tncreayl Phosphate Santicizer HI Diphenyl Phthalate Tnphenyl Phosphate Santidzer 8-16 Triphenyi Phosphate Tricresyl Phosphate Tricreeyi Phosphate $ant*c**r HI Santiciaaz 8-16 Mo#-Es* Aroclw Stieizf Arocfor Dsoctyi Phlhaiate Trscreayl Pbo^jhate Tricresyf Santicr W0 Arocior Tricreayt Phosphate Diethyl Phthalate Santicizer 6-1S ArocfOf Santidier 141 Atosiof Mod-Epon B SantY/er Hi Arociof w Sant^/er 846 : Tficresyl PfKJSphate D>ecM Adpate Santicsier 149 dn Saoikker 141 V 8sfltttuw6-16 Szotituer 141 Triaa^y! Pho^5hat $aet7i2^f 140 # %f Ad(p Sarstfcjzar 141 ! Aroelor -------------------------------- ! Santc2ef S | SatcMf9 Arodor THcresyl Phosphate Santtcixer 141 Afodor Tfic#esyl Phosphate Santicizer 8 Santicizer 169 Tncresyi Phosphata Saotidzer^ Saotidzer^S Tric(syl Phosphate Snticlzr 140 SaMcr B-M SanMc Ml Saotidzet 8 Saotidze? M47 Triphenyi Phosphate Diisodecyi Phthalate Santidzer 4M Diodyl Phthalate Santicizer ^2 Dioctyl Phthalate !; Santicizer HI *. Santidzer 8-16 r ...II fSantidzer 1^ . | Santidzer Hi Santicizer 169 Tricresyl Phosphate . Santidzer 160 Santiciter 141 Santidzer 8*1$ I 1 1. Santicizer 8 Santidzer 8-16 Triphenyl Phosphate Dibutyi Phthalate Santicizer 8-16 Santicizer 141 ? | Santkizer $ Santicte&mr Santicizer 8 Santidzer *4-17 Santicteer B-16 SsnMeiar M-17 * j Santicker M-l? Sehtidzer 45 Smtkzkm 160 Saeticizer 141 Arocfor Santicizer 141 Santictw l Santicizer -15 Santicizef 8-J6. f f f i izat*v'e| sM-ytil?t rftnA.o--s^pnillaIt iiheMl Santidzer -15 Med-Epox ModEpox Aroelor Arodor Santicizer M-17 Tficresyi Phosphate Santicuez 141 Ssnticaar M-IJ S*ntKef 14 Amctef Santidzer 8 Tricresyl Phosphate Santicizer 140 Arodor Santicizer 141 Tricresyl Phospt^te Santidzer 141 Santicizer 8-16 Arodor Santidzer 8 SantictzerO.......... Santicizer 8-16 Santicizer 160 Santicizer 141 OitHityi Phthalate Santidzer 8-16 Santicizer 169 Santidzer 149 Oihutvl Phthalate Santidzer 8 i * h* C j , ' -. 0476078 TOWOLDMONOQ33048 **-------- ""......................................... -'! ' ' '-VfvW '*., ,^, \,V: *A S5 ' , ,/ ?'v I f T F .W rSiflSIlitS Santicrtt# I imparts- flexibility without adversely affecting tensile strength, abrasion resistance, or oil resistance. Saotteifer #, Santicizer 1*H and Saototift MW* each impart property, improvements In particular applications. Poiywter* Awlor compounds impart flame resistance and improve adhesion, chemical and oxidation resistance. Itebmine'FomahtehyAs Santcs/tr 9 improves solution and color st rtehty, gloss, flow, adh&st&n, and impact 'esistance of meiaonne Urea-FsrmaWehjd# Santicizer $ improves ftow and acts as a- hardening agent &Mfa PfMB#l-F#nmWhyd Saftticlxer 8 and Santicizer 9 improve flow and adhesion, Tricresyl Phosphate, Santicizer 160, Dihuiyi Phthalate. Santicizer 140 and lipoid A/odor compounds improve ponchabihty of laminates. Tricresyl Phosphate, Santicizer 140, Santicizer 141 and Aroclor compounds impart flame resistance. C a Alleyds Aroclor plasticizers impart improved adhesion, chemical and oxidation resistance. **60 ? TOWOLDMONOQ33049 lo in the final molded part or extrusion. The plasticizers shown provide the optimum effect for each designated property when used with the resin shown. When the same plasticizer appears under two or more of the properties desired in the final product--that plasticizer definitely merits evaluation. Q%tfcod TOWOLDMON0033050 mt.m Pdrdnyl mnm # Chimtto ' SS-&:'*.J* Santicizer 163 ' Dioctyl Adipate Ssntfdztr 141 Ofhi octyl. n*decyf] . .. Imham IM .. Tricresyl Phvsph&te Adipate Dosedecy? A#pate $antldzer 27$ . Diethyl Phthatete Santldzer 641 .. Seoticizer 141 Dibutyl Phthalate . Sentidzer 8-16 Potrdnyi Santicizer 9 tant<czer 8 Santicizer tM7 Santicizer H47 Santicizer 45 PaiyMyrene %mhcm( 160 Dibutyl Phthalate , Dibutyl Phthalate Santieoer 141 . tupnertft "fftuaia?e " .: Sattttcfeer m .- Santtdzer 409 ' Tricresyl Phosphate ' Santk'mr 262 ' Santldzer ISO Santldzer 141 Dioctyl Adipate Santicizer 262 *1 illi ^1 Arodor .. . Santldzer 141 Santldzer 848 . 1 Santicizer 9 . Santldzer 8 Santldzer M4? .. ' SanbdierS Santicizer M47 . ||jfe| ImK Diphenyl Phthalate il !i Santldzer M4? Diethyl Phthalate . Santicizer E4S . Diethyl Phthalate Santicizer 8 Santldzer M4? Santiclzer 8 Santldzer 1-H . Triphenyl Phosphate . Diphenyl Phthalate Dimethyl Phthalate Diethyl Phthalate Santldzer *15 Santldzer 8 . I Aoefet# ' l^a*alsM Santicizer 160 Santidzer 141 Santldzer4 Santldzer U-17 Santldzer 2?8 Santldzer 262 Dibutyl Phthalate Santldzer 160 Santldzer 165 . Sentkizr 278 S*ntlcizar262 Santicizer 160 - Dibutyi Phthalate Santldzer 278 Santldzer 262 Santicizer HI Dioctyl Phthalate Dibutyl Phthalate ,. Trlphenyl Phosphate . Santldzer S Diphenyl Phthalate Arcelor Dibutyl Phthalate Tricresyl Phosphate Santldzer 140 | Dibutyl Phthalate Dioctyl Phthalate Santldzer 165 Dicydohexyi Phthalate Diphenyl Phthalate Tricresyl Phosphate Aradot . ......................................~t*% Dioctyl Phthalate ^1 Dibutyl Phthalate ; Santldzer 165 Dioctyl Adipate Dhsodecyl Adipate DiCn-octyl, n-decyl) Adipate Santldzer 1-H , Diphenyl Phthalate Dicydohexyi Phthalate Santldzer 8 Dioctyl Phthalate Santldzer 1S5 1 $w tetidisne _ mmmmrn Tricresyl Phosphate Dibutyl Phthalate Arcelor Saotldzer 160 Santicizer 278 Dioctyl Phthalate Olactyl Adipate Santicizer 141 . Tricresyl Phosphate Dibutyl Phthalate Santldzer 160 Santicizer 141 ^ W e Santldzer 262 tluteifehe Aetyteaftrtie mmmmwmm SnMeiw 160 Dioctyl Adipate Tftoesjrt Ptw!ht Di'isodecyf Adipate : Sonlidar Hi QHn-ociyi, n-decyD Adipate Trlphenyl Phosphate Tricresyl Phosphate Diphenyl Phthalate Santicizer 160 Santicizer 141 Santicizer 8-16 Sj | I .. v. Santldzer 180 mom . . . Santldzer 141 Santldzer 262 Santldzer 846 Santldzer 160 Santldzer 262 Dicyclohexyi Phthalate Santldzer 1-H Diphenyl Phthalate Santicizer 160 Santicizer 141 Santicizer 8*16 Santkte& 2S2 w| '1 0/f Caici* * Santicwl SanttcbS SanticBW t Santldzer 9 Stnticiwr* _1 PhanSt . Santiesw J SnUdrl60 TOWOLDMONOQ33051 om Qiph'/i Phtbateta Amcits o TPno&pfcat*. Uniterm Santicz/sr Z7$ o ______ ^ Arodo s . 0 S&ntk s~t? # f Triphe *>f Phosphate freresyf Phosphate Sanhcizer 140 ^dv*** *4* Arodor Sanhc>Zr 160 Sdflt(Cf'2gf 14J TncteSyt Phosphate Samicizer 262 Santidzer 2?8 Arador ' Santidzer 141 Trifyt Pbewtato Tftphenyt Ph<*ptte Tncresyf Phesphate Dlsetyt Dtedyt Phthafate* Diisodecyi PMhatetef Dif$ooetyt Phthalate* Santidzer 489 Santidzer 141 SantidzerMO Santidzer 846 Dioctyf Adipate Santicizer 846 Santicizer 45 Diethyl Phthalate Diethyl Phthalate Santidzer 45 Santtcizer B48 Santicizer 141 Dioctyf Adipate Santrcl^f M*l? Santidzer 45 ' Santidzer 846 Smiitimr 45 Santidzer 846 Dioctyl Adipate _________________ I Cipher ?f Pntitalats ` Tnpbeuft Pfmphate O .Arecior fricresyi Phosphate SwiticiMf MI 1 f^Bantidi ` W Santidzer DH j Triplrff pjitspfcatss ' Trlphenyl Phosphate Triphenyf Phosphate Santidzer 141 Diethyl Phthalate Santicizer 140 Santldler f Sarrtlsfe^ I"H Diphenyl Phthalate f Aroefo? Sanilcker 141 Trfcmyi Phosphate Triphef^fl Phosphate Arodor Triphenyf Phosphate Diphenyl phthafate Santidzer 160 Santidzer 278 Dibutyi Phthalate Santidzer 160 Santicizer M-17 Santidzer 45 Diethyl Phthalate Dimethyl Phthalate Santicizer M4? Santicizer 409 Santidzer 846 Dioctyf Phthalate Santidzer 141 Santidzer 8-16 Santidzer E-15 Diethyl Phthalate Dioctyf Adipate Sentldzer 45 Diethyl Phthalate Santidzer 141 Santidzer 8-16 Santidzer 141 Dioctyl Phthalate* Diisooctyl Phthalate* Dioctyl Adipate # fMyckmmfi Phthalate 4 Diphenyl Phthafate Trlcreeyi Phosphate Satidier4p9 Aroclo? Trleresyi Phosphate Santidzer 140 Santidzer Hi Diphenyl Phthalate ? Santidzer 160 Dicyclohej^l Phthalate s Dibutyl Phthalate Samidzer 160 * Santidzer 278 Dloctyl Phthalate Santicizer 165 Santidzer 160 Dibutyl Phthalate f SioWeiw 1-H Diphenyl Phthafate 4 Trleresyi Phosphate Triphenyf Phosphate 4 Diphenyl Phthalate Aroefor '. Trleresyi Phosphate Santidzer 140 Santicizer 141 Amdor Tricresyl Pbospbete Triphenyf Phosphate Sartttdztr 141 Areclor Dioctyl Adipate DiCrvoctyf, rKfecyl) ' Adipate Dioctyf Phthalate Dioctyf Phthalate Santicizer 168 Santidzer 141 Dloctyl Phthafate* Dlisoodyi Phthalate* Santidzer 8-16 Dioctyf Adipate Santidzer 141 Santicizer 846 Dioctyf Phthalate* Diisooctyt Phthalate* Santidzer 141 Dioctyf Phthalate* Santidzer 8-16 Dlisoodyi Phthalate* Dioctyi Adipate Diphenyl f%ihafate * Pi^doheeyl Phthalate d Trlphenfl Phosphate t^mrnrnm ' Dieyetehaayf Phthalate o Diphenyl Phthafate Trkresyl Phosphate Santicizer 1# Santicizer 141 Arcelor Tricresyl Phosphate Santicizer 141 Santidzer W - Dlcydohexyl Phthalate Santidzer# 5 0 Santidzer $ Areder " Aroefor Tricresyl Phosphate Santicizer 140 Santidzer 141 Dioctyi Phthalate Santicizer 8-16 Santidzer 409 Santicizer 160 Santicizer 262 Santicizer 141 Santicizer 8-16 Dioctyf Phthalate* Dlisooctyl Phthalate* Santidzer 141 Santidzer 8-16 Santidzer 141 Santidzer B46 o*n>09* TOWOLDMONOQ33052 foctyi Phtha&M* jooctyl Ph*h? Ate* antmzw Mi , anticlzaf M anttcfzer846 toetyf Adlptte . .. nethyt Pilthaiatc -antlclxer 4S -antidzar 845 Keizer Ml nodyl Adipate . anfldzer 45 >antidzer 848 Jloctyl Adipate aatidw Ml -antldzer 8*16 lefltk&er 45 Jitthyi Phthaiate ZlOCfyt Adipate %Mmt 4$ >6sAhyl f^thdete *ntidzer 141 iM&mM? &~l6 SahtidMf Mt 7loetyi mholeft* >ilsooetyl Phthifet#* lloetyi Adipate ?*etidz#r Ml ilhetyf Phthaiate* Ji^octyl Phthaiate* SahHdaa? 846 31acfrt Adipate ..... Santidxer Ml Santidxer 846 Dlootyl Phthaiito* piigeodyf Phthaiate* Santicizer Ml DtocSyl PhthaMe* Santidxer 846 Disooctyi Phthaiate* Diec^i Adipate Santicizer Ml Santlelxer 846 Dilaeedyi Phthaiate* MS Santld*er-816- smrnmui Santicizer 8*16 i*<itKtr 3$2 S"ticir 409 3/ C*)f3 Ptowlwte FWwSir SjsitadS SwticiMf 262 SanMetjer m Irktm.>1 PiJte htmoz*rim i**t<uM2n Santidxer Ml ` Santicizer 8-16 Santicizer M47 Santicizer 45 Aroclor Santicizer 45 Santicizer 8*16 Phosphate Smticimtt Santicizer M47 Triphenyi Phosphate fncrssyf Phosphate Santicizer 846 ............ ... Tricresyi Phosphate Santicizer 141 SonticlMf I Santicizer M47 Santicizer -15 Aroclor Tncrevl Phosphate Tricresyi Phosphate Santicizer 141 Smticizer M-i? Santicizer 8-16 Santicizer 45 Santicizer 846 Oibwtyi Phthaiate Santicizer 141 Trtpfyf Phosphate Santicizer 45 SamlcizefS Semidzer48S Tmtmyi Phosphate Santicizer 1# Santfclxe? 141 Santicizer 409 Tricrfsyl Phosphate Dioctyi Phthaiate Santidxer 140 Santidzer $ Untk'mt M47 Santicizer 1-H Santicizer 27$ SanticiawrS Santicizer M4? Santicizer 160 Santidxer 1-H Santicizer 262 Santicizer 409 Santicizer 8 Santicizer M47 Diethyl Phthaiate Diethyl Phthaiate Santicizer 141 Aroclor Dioctyi Phthaiate Tricresyl Phosphate Aroclor Dioctyi I Tricresyi phosphate Santicizer 45 Santicizer M47 . Diethyl Phthaiate Santicizer 1*H Santicizer 262 Dioctyl Phthaiate Tricreayi Phosphate Santidzer Ml Santicizer 160 Santidxer 278 Dioctyi Phthaiate Tricresyi Phosphate Aroclor Santicizer M47 Santicizer 45 Diethyl Phthaiate Dioctyl Phthaiate Dibutyi PhthaiateSanticizer Ml Santicizer 8*16 l I Dioctyi Phthaiate Dibutyl Phthaiate Santicizer 141 Santicizer 165 :: \j \l Santicizer 409 Tricresyi Phosphate Diisodecyi Phthaiate Santicizer 8 Santicizer M47 Triphenyi Phosphate Aroclor Dioctyi Phthaiate Tricresyi Phosphate Santicizer 489 Tmmyt Phosphate Santicizer M47 Santicizer 141 Tricresyi Phosphate Aroclor Dioctyi Phthaiate, Tricresyi Phosphate Dioctyi Phthaiate . Diisodecyi Phthaiate Santicizer 165 Santicizer 160 Santicizer 278 Dioctyi Phthaiate Santicizer 141 Santicizer 166 Santidxer 160 Santicizer 27$ Dioctyi Phthaiate Dioctyi Adipate Di(n-octyl, n-decyl) Adipate Santicizer 846 Dioctyi Phthaiate Santicizer 141 Santicizer 409 Tricresyi Phosphate Dioctyi Phthaiate Santicizer Ml SantidxerM! Santicizer 160 Santicizer m Santicizer $ Santicizer 9 Santicizer M47 Tricresyi Phosphate Santicizer iW Satka**rM4? Santicizer $ Santicizer 168 Santicizer 262 SantidzerS Aroclor Tricresyi Phosphate Dioctyi Phthaiate Tricresyi Phosphate Santicizer 168 Santicizer 262 Santidzert Dioctyi Phthaiate Tricresyi Phosphate Santicizer 141 Santicizer Ml Santicizer 160 Santicizer 262 Santicizer 8 Santicizer 9 Diooctyi Phthaiate Santicizer 165 ' Santicizer 141 Santicizer 168 Santicizer 262 Aroclor , 'frfWkyl Phosphate Santicizer 141 Aroclor Tricresyi Phosphate Aroclor 0*I60&* TOWOLDMONOQ33053 PtASTICIZER PERFORMANCE IN MOLDING AND EXTRUDING (contimwd) O Tri'.rt >yf f^05p >/ef 109 I $wmmm.&m 0~-- 0 < Stk:S|W f 49l---- i %t*ea$ FftlfcaJate ittynw'wx Pin&ph& 0 Smtkmw 3 ' Suntkkm PH Triphawi PfK^phir? Santwiar I-H r ^rocfer f mcycMrnyl m?w DipPmwi ntm%tm Wmm0. Pbm&h&ti [ %wkmkm #5 Bmiklm PH ; Dletta^i Ptrtbaiate ///f flap for chart SnScfearlkllHMMMtMUHt J-H, Tfip^en/I Pnoai^ai 0<j5HMf* Pf>#safa?& Ar-sxk''*' 0leycf>n*y* PHfha Tfph**yl Sttitfri/ylQg Otcyel'^e*yl Phtfta D4ph***yl Phttefel# I st7t Samian S Ptfrxte/- ' H % ms4 ter teipt&viw fkm c&am&rist&s mi as a haffoaer. 0476084 TOWOLDMONOQ33054 TOWOLDMONOQ33055 Wp*g4i o o o o m fra i^s?*"15 & . f:%< - .;^r4 . fr,' \. \ "w--- "%*> *' ^ r'^ .. o **>. 'f-.vv ^ y ,/* s G O o o PLASTICIZER PERFORMANCE IN FILM AND SHEETINO The following table will assist resin compounders select plasticizers for formulation evaluation on the basts of those properties most 0 critical in the finished film or heavy sheeting. The plasticizers shown provide the optimum effect for each designated property when used 0 with the resin shown. When the same plasticizer appears under two or more of the properties desired in the finished film or sheeting-- that plasticizer definitely merits evaluation. .... . 0 O' 0 O ovzeoafe TOWOLDMONOQ33056 : 'VU' ~J; JC, Sadscsier 2?8 P'Octyl Adipate - . m ::=' ' DHo-ectyl, n-deeyi? Saohcfzer 262 Diphenyl Phthalate ' . P&tff. ' ' mutm - ' Santicizp' !40 ' Trlcmyi P&&sphte ' Diisodeeyi Adipate.,.. Santidzer W Santeslzer 485 Tricresyl Phosphate Santidze? 278 . WmM* sm^i mwa tolled g4S Santidzer 141 ' ' CHhotyl Phthalate SaMtdzer 8*16 Amctor SanUcfzer 160 Santidzer 141; Dioctyl Adipate Santidzer ^2 . . ill ^ .| :^ Santicizer 141 Smticizm 8-16 | | 1 Pdyyleyl MmMt nftntmm $otidzer9 SanticizerS SertOcim M4? %&n\mitr m Oihotyl Phthalate S&niidzer M4? Santicizer *15 Sifewty! Phthalate Santicizer 141 Santidzer 9 Santidzer 8 Santicizer 14-17 . Diphenyl Phthalete Santidzer 8 Santidr8W7 ,i wJ #! Dif|plp$e *eW* fSetttthlS 4 ' INtp'if# SanDdzef M-U Diethyl Phthalate Santid/er C-1S Sanhazer 160 Santidxer 141 Sam*etz*r 45 Samkf2rM47 . DMiyl Phttatete Ssrttkfeef 8 Santlcurar M-17 Santicil#* 1 Dioctvt Phttatat Dibutyi PMbatate ' Santicizer $ - Dimethyl Phthalate Santidzer 1-H ' Diethyl Phthalate Triphenyf Phosphate Santidzer -15 Diphenyl Phthalate Santicizef 8 '' ' , Triphenyi Phosphate Santidzer $ Diphenyl Phthalate Arociof . Diho^l Phthalate Tricresyf Phosphate Santidzer 140 mM w'| ; /f%f j p- - tmumn m mmrn wmt% G*t$uUm Difcotyl Phthalate , Santicizer 168 Santicizer 16S Dibutyl Phthalate Dioctyl Phthalate Santicizer 165 Santicizer IW 0it>Miy4 Phthalate Dioctyl Adipate Dllscdecyl Adipate DlCn-octyl, n-decyfl Adipate Dicyiehexyi Phthalate Diphenyl Phthalate Tricresyl Phosphate Aroclor Santicizer 1-H Diphenyl Phthalate Dicytohexyf Phthalate Dioctyl Phthalate Oibotyl Phthalate Santicizer 165 Satiticizm18 Dloctyl Phthalate Santicil 160 w 0 llty^eee-flolPdiehe RuttwCGITO TricnMjrl Phosphate Oiixrtyl Phttatete Araefo* , Sontkia* ISO Bwtedien** AssifteBitrMa BsMtstlSuraK! SaitOeim-m Trtowtl Phosphate Otoctyi mmim Dioctyl Adipate Saniielzer 141 Mac*) Adipate Diisedtcyt Adipate Giftwctyf, tb4ecyII Adipate TrfcfMyl Phosphate Dfbutei Phthalate Tripherwi Phosphate Tricresyt Phcsphate Dipheojd Phlh(t Santidzer 1% Santicizer 141 Santldw 166 Santidar 141 SanlickSf B-1S {SB m ) ami ' ":'trvatxfw PMrMi** SwitScixtr 8s ttw most sWen* ptastidm. Santieiw M, Santfeuw 9 and SaoWite MHP am aim useful 0 TOWOLDMONOQ33057 o O Qiph&ftgl f^hthatale Arcelor 1mw$yl Phosphate Santicizer 409 Trlere&yt Phosphate Santicizer M0 Santicizer Mi Arcelor $mkmr M2 Santicizer 160 Santicizer MI Tricresyl Phosphate SaMidzer 2?8 sts^smamm, ... -. 4. ,, - ' j J Santicizer SSI Santicizer 160 Sahtioizer Ml Santicizer 2W Dioctyl Phthalate Diisodecyf Phthalate Santicizer 409 Dioctyl Phthalate* 1 Diisooctyi Phthala^ Santlcizer Ml , { Santlcizer 8-16 t Smikher 160 :i O kfoclm o fewler Santicizer MI Tricresyl Phosphate Santicizer 840 Santicizer 45 Diethyl Phthalate Diethyl Phthalate Santlcizer 45 Santlcizer 8-16 Santicizer 141 :; o Sanhr tfy 9 Tfi&Uf vl Phosphate o 0*phe yf Pnthafate o o9 Sar&<,,?*( j-M TfiphK'hi Phosphate 'J if4k'9 1 Sannwer 1-M ^agj Oipn* .*? pnthalate Tripheny! Phosphate Jheresy! Phosphate Aroclof Tricresyl Phosphate Santicizer Ml Triphenyt Phosphate Santicizer Ml Santicizer 140 Triphenyi Phosphate Diethyl Phthalate Santicizer Ml Tricresyl Phosphate Triphenyt Phosphate Amdor Triphenyf Phosphate Diphenyl Phthalate Santicizer 160 Santlcizer M4? Santicizer 45 Santlcizer 846 Dihutyl Phthalate Santlcizer 160 Santicizer M47 Santlcizer -15 Diethyl Phthalate Dimethyl Phthalate Santlcizer M47 Santlcizer 409 Santlcizer 8-16 Oioctyl Phthalate Santlcizer 45 Santlcizer 84$ Santlcizer Ml Santlcizer 8-16 Santicizer -15 Diethyl Phthalate Santicizer E 15 Diethyl Phthalate Santlcizer 141 Santicizer 8-16 Santicizer Ml Dioctyl Phthalate* Diisooctyl Phthaletf O O Okw Phthalate Diw -4 pnt>alafe Tnffe -4 ? IVAOn>a?e SantK'^409 Arodor Tricresyl Phosphate Santidzer 140 Santicizer Ml Senfn-za* 1'H Dipt* >t\ Phthalate o o # frnr&.j Pfr'&ph&i# TttphfUfl Phosphate Dipt** syl Pnmalate Aredor m Dipheod Phthalate Dlcycl^e/yi Phthalate Tnphe'vl *hocph,ate SantP ^er 46*1 m Tricresyl Phosphate Santicmt 140 Santicizer 141 Arodor Tricresyl Phosphate Triphanyi Phosphate Santicizer Ml Amdor Tricresyl Phosphate Sanficizer 140 Stntidzez 141 Arodor Diphenyl Phthalate Dicydohe*yl Phthalate Santicizer 160 0 Santidzer 160 Dibutyl Phthalate Dioctyl Phthalate Santlcizer 165 Santlcizer 160 Dibtity! Phthalate Santicizer Ml Oioctyl Phthalate* Diisooctyl Phthalat? Santicizer 846 Oioctyl Adipate Di(n-octyl, n-decyl} Adipate Dioctyl Phthalate Dioctyl Phthalate Santlcizer 160 Dioctyl Phthalate Santicizer 84 Santicizer 409 Santicizer Ml Santicizer 8-16 - Dioctyl Phthalate* Diisooctyi Phthaiaty Santicizer 141 Dioctyl Phthalate* Santicizer 8-16 Diisooctyi Phmaiat* Santicizer Ml ; Santicizer 8-16 Dioctyl Phthalate* Diisooctyi Pbthzm -------- 4 04**0aa O TOWOLDMONOQ33058 :IJ ':-R M*A'WiC M n t. P*0ffyi 1 rpn^lare' vaotieizer 2?s ,t ihsK'/rt f ^tittvitvXc' 3anticiz*jr4tf9 #U'm Sanhcizer 282 Sootier 8 18 Tnc'esyl Phewtote SanbC'Z Dhsedecyl Pnthalate Santicizer 408 Santicizer 4J1 Santicizer 278 Santfdzer 499 tricresyi Phosphate Sanhclzer 140 Saoflcrrer 406 Santicizer 4|l Sanfcctzcr 262 Atw.ktf Doctyl PpthalateTftcresyi Phosphate Viffttiy/, i Sant*' </i' 15 'teuUt/z ? 8 i if i m Santicizer 141 Da^ticizer 8*14 Santicizer M-17 Santicizer -15 AroclQf Sant f C'%% Saotu /* f 8-le 5ant'c<z*r -16 Santic'Zer B-18 Tnphenyf Ptenphete Santicizer 8 Santicizer M-17 Tripbenyi Phosphate Tncresyi Phosphate Santicizgf 8-16 %&*>',*! ' Ul SantK'Z' * 8-16 Sanbozw 45 DietM i stf&ts Tricresyi Phosphate Santicizer Ml Santicizer 186 Santicizer M47 Santicizer -15 Aroclor Tricresyi Phosphate 3*r,c.z* f 14% Pncba'afe SantiKtp < Ml Santicizer 141 Triphenyf Phosphate Santicizer 45 Santicizer 8 Santicizer 8 Santicizer mj Santieiztt l-H Diethyl Phthalate Santidzer Ml Santki? -t 8 18 Santn ifs ( Ml D>octyi f rnbaiate' Omoo'A.t Phthalate* Santicizer 409 Trjcresyl Phosphate Santicizer HO Sa'Sioze' Ml Septiazw 8 Santlctzer M-17 Santlozer 1&1 Santiazer l-H Aroclor Dioctyf Phthalate Tricresyi Phosphate Hi fn-Xt/' r *fMV*e* Ouv/kX s P/tnaian'' Sab ,*/ - 8-M San* Jr tjer 409 PUy-4'1 >?<? Zfi'n V ?'r>tlWK' "'>*<> 143 Lonticazt 411 5attc*zer 409 >er*hc</er 8 San?'caer 54-1? Diethyl Pi- delate SantiCfzef 411 Aroclor Dioctyf Phthalate Tricresyi Phosphate 1W*t * v- ` HI 'iarst.c zer 409 Sar-t-tun < B IS fr^'esyf Phocpf-ate Dipiffi P mhaiate* Dosodecyf Phthalate Ph^oxI'I Pnthaiate* | Santicizer 411 3anic*zer 8 $$ntiCi2(a M-i; Tndierwl Phosphate Aroclor Dioctyl Phthalate . Tricresyi Phosphate Santicizer m Biectyi Phthalate* Santictzar B-16 DimMfl Phthalate* Santicizer 499 Tricresyi Phosphate Santiclzer M l? Santkizer 141 ' Tncresyl Phosphate Aroclor Dioctyl Phthalate Tricresyi Phosphate Santicizer 141 Santicizer B46 . Dlectyl Phthalate* Dtisooetyf Phthalate* Santidiar409 Tricresyi Phosphate Dioctyf Phthalate Santicizer 141 Samlcizer M-17 Trtcfesyt Phosphate Santlcizez 140 Aroclor Tricresyi Phosphate Dioctyl Phthalate Santc*zer 282 DhsoPecyf Phthalate ^micfzer 409 Dioctyt Phthalate Aroclor Santicizer 406 Droctyl Phthalate / Dnsotfecyl Phthalate; Santicizer Ml Saotscszer Ml Aroclor - Saptcizer 8 Saoticiw M-3? Tricresyi Phosphate Santicizer 141 Santicizer B-16 SmUaz&f B-lb Santicizer M-17 Santicizer Ml Santicizer M*17 Santicizer 8-16 Santicizer -15 Santicizer B-16 . Dibutyl Phthalate * Santicizer *15 Santicizer mi Diethyl Phthalate Santicizer l-H Dioctyf Phthalate Tricresyi Phosphate Santicizer 141 Santicizer 160 Dioctyl Phthalate Tricresyi Phosphate Aroclor Santicizer M-17 Santicizer -15 Diethyl phthalate : j Oioctyl Phthalate Dibutyl Phthalate Santicizer 141 Santicizer &16 : 1 . Dioctyl Phthalate Dibutyl Phthalate Santicizer .141 Santicizer 165 Dioctyl Phthalate Diisodecyl Phthalate Santicizer 165 Santicizer 160 Dioctyf Phthalate Dioctyl Adipate Di(n-ectyl, n-decyl) Adipate | Dloctyl Phthalate Santicizer Ml Sat%ticiz6f 165 Santicizer 160 Dioctyl Phthalate Tricresyi Phosphate Santicizer 141 Santicizer 8-16 Dioctyl Phthalate Santidzer Ml *' : f 1 Dioctyl Phthalate Santicizer 165 Santicizer 141 : ^ p:i -'I 4 1 0*7600? TOWOLDMONOQ33059 Msedseyi PMNM* is willed us*4 in showsr curtsies, toby pants, aM simflsr artistes taeatss of its wpenor resistance to hot soapy waiter. 4| I # ;m tear-strength. .-- TOWOLDMON0033060 PLASTICIZER PERFORMANCE . IN ADHESIVES The following table will assist formulators of adhesives select plas ticizers for evaluation on the basis pf those properties most critical in the finished formulation. The plasticizers shown provide the optimum effect for each property when used with the particular resin shown. When the same plasticizer appears under two or more of the desired properties important to the finished adhesive--that plasticizer definitely merits evaluation. "v o*?wm TOWOLDMONOQ33061 0009 PtASTICIZER PERFORMANCE in nmv-rz-ir.n'ms : i::;';_** ' "^** c: v " ""' ` ' MffmR^A:N-.C:-B^/-- &:-., ,.;.V_. ,, ,, , Ci 4 .... , Nitrite j Trlphenyi Phosphate j Santicuer 1-M ; SMiciir ISO \ Diphenyl Phthalate Santteizer 6 Santicizer 160 Tiicrosyl Phosphate Santicizer 165 - Oibutyl Santitaef 165 Sant<C!zer 8 fnphenyi Phn&pbala Arodur Santohte MNP Santicizer 6 Santjclzer 8-16 I Ah tMfmMm Acetate Siw#eiirl- Swrlttze# SmtldiW *? Santollte SntierS DWfts Plrtbelete SnttclS45 t rspsreftys rnv5^ffic SaMldz^-8 . %mmz& 45 :,, % " SsPtlcizerM-l? Sateohte MNP Sa^tehte MS-60% i 1M 1 Santicizer 1-B . Santicizer 8 Trlpha^l Phospbate Sahtlctzer 6 JSMfci Dclltileee Acetate* Santicizer 8 Diethyl Phthalate Sanflcizer 140 Saotklzer M-17 tariffs Santicizer M-17 Santlcker 45 Santiciaaz 8 Sateohte MHP - ^^1 Dicyciobexyt Phthalate Aroclor J CMteteee Propionate latar Mi Srmttdzer $ Sarrttd* u-n Ssnticizsrt Diethyl FhtMete Sanfidzef E-15 Trlphenyl Phosphate Sarttlciza.r m Sabtlclzaf 8 Saptldzer 6 .. Smtmz& M-17 Santolfte MHP Santollte MS-80% | ^1 tf*yi getteiete Acrylic um&m 1~H Santolite MHP Diphenyl Phthalate Dleytlohexyl Phthalate . Dicydohe*yi Phthalate Santicizer 1-H Diphenyl Phthalate SanlldzerS Diphenyl Phthalate $aniicmr$ Santlclzer M4? Santicizer m 5antic!** 141 Santicizer846 Saollcizer M4? Olpt^nyl ^thalata Sanlidzer 8 $af$dzw 160 Sastkszaz 8-16 Saotlclzer 6 Saoticizer S Santelite MHP Afociw Santlclzer# Santohte MHP Saolkizor 166 ' ' 1 ^1 Md W| i . wuinHifv Diphenyl Phthalate SanficizerS Santolite MHP Arrxslor Diphenyl Phthatot* Oicyctohexyi Phthalate TrieMyi Ptxphete SenUcurer ISO Santlclzer 8-16 Santicizer 160 SantWzor 141 Santicker I Santidw MS Santicizer 18B Santicizer 141 Oisctyf Adipate Bitn-octyi, rwiecyl) Adipate Dtoctyl Adipate DI(-oetyt, n-decyll Adipate OHsodacy! Adipate Saptldz^S . SaterdzerO Santollte MHP Aroclor Samtdzer Ml Aroclor Santollte MHP j ^ I i gB| Wphenyi Phttiafat* Ok^dolwiyl PMIteiete Tncrcsyi Phospliats Sentidzer l# SanMctasr ISO Santicizer 141 Santldzar 141 Santimml Santlclzaz 8-16 Santlclzer 160 Santldzer 8-16 SM 6sv&S2$*e4i AA cetate Aroclor Trlcreayl Phosphate Santicizer 8*16 fsantfcizer 160 Santlclzer 8 Trtcrasyf Phosphate Santicizer 846 Santldzer 160 Santiciror 8 Santlclzer 8 trlphenyl Phosphate Aroclor Santicizar 8-Ii Diethyl Phthalate . Dibutyt Phthalata Dimethyl Phthalate -- Santidzar 160 Santlclzer l H fS'WkM.iSyM/t4iWSiU*l AAItC**Sfew**l Saticizr8 Santicizer 9 Santicizer M47 Santicizer 8 . Santicizer M47 . Santidzer M-17 ^fitlclzar -15 Santidzar S ftdIyBytSny#ltttenc Aroclor Santicizer m t*w vpfC?saste*fittsa#? tPartenJ Amcktr _ %ted~Epex Santicizer 8 Trlphonyl Phosphate Sentfcizer 140 Aroclor Sentlcizer B-16 Santicizer ISO Santidzer84$ Dihrtyi Phthalate Satrttcizer 141 Santicizer ISO CHIHLI Phthalate Sabtlclzar 160 Santicinr 8-16 Santktzer B-16 ,.. Dibutyl Phthalate Santklzef 141 Trlerasyt Phosphate Aroclor Mod-Eps* Aroclor .............. < d J Aroclor Santlclzer 168 Triphenyl Phosphate Trlcresyl Phosphate : ___ Bm St^te^e-Silta^eO; . *mi tfcrtent Trkmsyi Phosphate Aiodar Chbutel Phthalate Santicizer84-1? Santicizer 168 $atcr 141 Santlclzer 160 Santlclzer 141 Saetictzer 8-16 Aroclor Tricresyl Pte^phate Tripbervy! Phospliate f JMtt etP Ceeefn, Zeie Sootlcizar S Santteizar 1 Santxazart Santicizer 8 Santlclzer 3 OA7A092 JHH (Qpj J TOWOLDMONOQ33062 m'M -- mBBrnmis;. " i Sanhdzer 45 Sarddze? 846 Sadidzer Hi .. irtOCiy* rmnSiateKi;.; Aredor Santicizer 150 Diodyl Phthalate Tricresyl Phosphate Tncre&yl Phosphate Santicizcr 160 Santtozar 140 : mmmms: - . .- .-:: mmmm ui ..." / vt - ... " mmamm . . Sadidzerl^-i?_ '' = ..'Aroeiar'. ' "./V" -c'-. Dloctyl mhoiate = ;#v;::: : rnttilzlm? &>%$ ' :/: *. . samidzer mi . : y OWijti Phttglste SsmtlciwM-W : ' Sazitidzer 6 - ' ; . ' Saoticizer 8 ' 58BtWj8rE-: : "' Saotidzer M4?; \.- Santldzer mi ' San<s4*rS ' $aotlclzer E-15 $te* MW # Ssndie?g45''':.,:- ' '. Ated?':!' ;:::- "v< %amicizr846 :. ., . fcfHJdijft rmBaleiw SantldzerHi ''; Tricresyl i^phate- tHoctyi Phthalate*, Sarddzer U-Vt Smtmmri .. . . Tdphenyt Phosphate s&mcu&m ' Santietzer 1# - - ,;: ' :; ' Sateidzer 8 . " $&ntmzw mr Santlcfxer 140 Tripresyl Phosphate Sateidzer 409 O Santidzer 45 Diethyl Phthalate S*Hfc(W l# OMt) HrttwMa Untkizm 8 Santidzer M47 Triphenyl Phosphate Samldzer 1# . swfktot*#. Sanfidzer mtT Santiefew 140 Senticltef 8 Santidzar M-i7 o 1tir ..a # # Santlcizer 8!S Smiclir 45 Sentidzar Hi .. Dtodyl f%thaiate* Untizizw 8-16 SantldzerHi Santidzer 141 Untkizm 846 .. $tici*f Hi Santid*er846 Dtectyi Phthalate* Oiixooctyl Phthalate* AAfOCiOZ - - PIq^ Phthilgte Tricresyl Phosphate Trrer^eyt Phoaphate SantidzerHO tarnier Sanfctw 141 Arcelor urOCty* rntnetate Triemsyl l%osphate Santidzer M47 Santidzer 45 Tdphenyt Phosphate Saniidzer 8 Saohclzer M4? Samtdzer 8 Saniidzer 160 SarticImS Santicraer ' Santidzer 160< THcresyl Phosphate SantlciJtef 4C Dloctyl Phthalate Santidzer405 Dllsooctyl Phthalate Sartildzer i$0 Samldzer Hi Diphenyl Phthalate Oloyctehexyl Phthalate Santlclzer 160 MRSVWQ-v,.y.fp fm'-l,vifSLW..tiW,.C.I,S..' Samlclzer 409 Dlo#l Phthalate Tricresyl Phosphate Oksctyl Phthalate Santidzer 409 Santidzer HI Saotidzer HI Santidzer HO | Santidzer HI Diphenyl Phthalate Sarddzef 409 D-iyf,l.ilsos.--ored.s.a.yc.1iymrloP.o,hs.^tphkraitalatete Sentieiw 140 # # ^upp m M # @ Samidzer 8-16 Santldzar HI frtcresyi rhOSphate Safddzer lt& Diethyl Phthalate Smimzm 8-16 Sanhdzer -15 SanDdzer Hi ... Santidzer m $amid*f-i5 Aroctor tftS35gagrf friespngI k?fm*yf rmnasaie Sentldzer 166 SMHdMrE-15 Diethyl Phthalate Mdw E-IS Santidzef 8-16 Santidzar Hi SMt^MTEU ..... |Msr|H_ * , Arodor ' San^eizar HI Araster WaS*w*4Ottf* Tncresyl Phosphate Santidzer HI $micttetB~w Smttetkf HI Arodor Tricresyl Phosphate Sitiarl V~ / THctesyl f^K^phate Samiclzer 1^1 Saotldzar 8-16 Santfdzer Hi SarvUdzert SaMIdzer M-i? Tdphenyi Phosphate $antid$er HO Ssnticizef Ml Santictzf 168 Tfisy( Phosphate Samldzer $ Santldze? 8-16 Triphenyl Phosphate Samldzer 160 Trrcresyl Phosphate Sentldz^r 141 $antidzr 146 Santldzer lJ ireresyi rOnkoAs*ptfneAatt<eI SantldzerHi Diphenyl Phthalate Trlphete^ Phosphate !>.' SantlcIzerO Saohdzer H-l? Saitiidzer M-l? Santldzar 45 Saniiclzer HI Santicizer 8 Santidzer M-17 ftroelor $atidzer HI Saotldzer 8-H J Triphenyl Phosphate Tricresyl Phosphate ^ Tricresyl Phosphate SantldzerHi Santteir 846 1 I m Trlcresyl Phc^dtete^ S&ntidzer -15 Mod'Ep&x Aroctof Saotiolzet* H-l? ' Tdcrosyl Phosphate Sanilclzor HI S*nelclirM-i? SmUdmm Aroctar Sarttldzez 8 Mo&Emt Aroclor Tftemsyl Phosphate Santidzer 140 AroclOf Santidzer HI Triemsyl Phosphate Safiticizer Hi . Sarrfldzer 8-H Sahtfdzte 8 Sentidzof 9 '*,T' ' ?, 1 1 '( ' Mod~Epm> Arodor Sadici^r 8 Arocto Tricresyl Phosphate ' . Saotidzer 140 " . | Sateicizer HI- Tricresyl Phosphate Santtei*rl40 Santidzse HI Arodor : Santidzer 8 ? Samidzerf^ * TOWOLDMONOQ33063 PLASM-. fB PERFORMANCE iN ADHCSIVrS (continued) a o D 0 D TOWOLDMONOQ33064 o o In formulating plastisols for various kinds of coatings, slush molding, rotational casting--the selection of the plasticizer system is critical. b Storage life, speed of cure, the hardness and tensile strength of the cured compound can all be developed to the optimum values through o selection of the right plasticizer or plasticizer blend. The following chart shows, for quick comparison purposes, the o characteristics of a "standard" 65 PHR plastisoi formulated with the various Monsanto plasticizers, using Opaton* 410 resin without o stabilizer. These values can be used as a guide to the performance of a particular-type plasticizer. However, closer values to the particular property most important to you may be obtainable by a blended o plasticizer system...which can be recommended to you by Monsanto's Plasticizer Council. .' o o TOWOLDMONOQ33065 V*Vj3V*-/, %/%<&> SrcoHf*- 5-1 HAT #6 SpindMs mum :3*C / &*ys 2?' fty 48'C imlkl 1 tm$% % Uf% ' A'"W/""""' At..***,***, 7,700 10,706 13JOO 9300 1?O0 12300 11,700 10,900 3,600 5,400 $,000 14,000 17,000 26,500 2,400 4,400 5,100 3,500 7,700 8,900 6408 9,903 $,m 11000(4)! mwooK 16,080(4}* ?)} 11000(5!! 292300(7)* 5,000 11300 133(6 8408 9388 9,600 6,000 10,900 14,100 3,280 10,408 1,9 $400 m,m 7m 7,800 Get ism 3t4gg nm nm im 6,200 &m 7,400(4)! 17,500(4!! 20,600(5)! 36000(6): 624)00(6!! 84,000(6)! m jgik| di 4 fj trc t;t ' 'ttov/% . utmn J - 4,500 5300 6*200 zm 20,000 zm 9400 tm 7,700(4)1 22,000(6)1 U00 20.400 12408 m nm Gel im 74,000(6)! 69,008(6)1 iM 32,306 11,700 33400 15,400 ~~ Get ~~ 7300 251000(7)! 111000(7)* 'j Sew &, ce^tipolses 10 (Mi 64 p8 ' *`wi MOO im 5JOB 10300 8,000 (JOB 8300 8*000 6,000 3300 3,180 2,408 mm 31,400 29,000 4,800 4,900 4,0 5,500 6300 5.200 8^30 6300 5,100 22,080 22,700 18,600 WJ 249,000 145,000 i 1 7<eM V* mf djmtf/cro* Ftatfoo htfnl, *C ,m*Air-U*ttn* Tim* mifluto* inches rebound i%Unt$*ni stmi ball dropped 43* 4 onto 04* tolck spaceman # 23*0} WfRaiK)nclM.Sfris<af C4^v4iwdwMid*r to 0* to 0# 12 10 13 1.1 64 435 378 100 32 40 255 127 138 9 'H *3 54 127 10 44 - S3 m 105 148 - 30 20 14 7 18 5.1 4A 6,4 17 95 98 - _ U 18 _15 a 13 ..... nn V&M 9 3122 _ _ vr*mwwm rvr*? .www 0476096 TOWOLDMONOQ33066 i > tm v 12300 | il.400 6,m %m 19400 %m 10,6# 12,300 9,0# il! nm 3,440 4,480 4400 24,000 27,500 33*6# #,#0 38,000 42300 5300 11,2# 15,400 4,TO 5,TO 6,4# 53# 5,6# 5,6# 23# 3,#0 3,4# . J03# 163# 23,#0 97,TO 93,#0 92,6# mM 73,0# 63.4# ) 5,800 9460 10,900 I .. |...............* 4,?00 1)400 14,500 . 53# 53# } mm Yim wm mm > \\m tm p 7,000 im z,m 6*4# 11,4# 13308 400 II, 393# U.100 tm $m mm nm mm ,108 2,6# 44J00 9,700 8,180 630S 3/380 4m $,m 15*0# 4,4# 1034# 19,200 73,6# Gei 74# 250,900 Gel xrn mm mm auoo Gel -- 25,6# Gel -- 15,9# Ge *" 430 6*2# 43# 40*#3 72,700 73,100 53,300 119400 139,9# 5,TO 6*4# 5,8# 3,TO 6,8# 6400 43# 8,1# 12,0# 1,000 9# 7# 12 i& m 83 u 18 33 * 14 03 % ................. m m m 464 90 224 m 72 705 ) m m m 138 m 92 m 1# m ) w m 6 2 24 15 7 53$4 4S . 43 43 1,7 2J i$ 103 4,0# 4,0#' 4m 2,100 4300 4,600 9,6# 159300 Gel 42,4# 41,0# 403# mod 38,4# 39| 33# 5,2# 53# 2,7# 5,2# 6,2# 26.1# Gel *" 35,2# 32,0# 393# 313# 173# 27,609 2,5# 2,0# 1,5# 15,1# 14300 11*7# 163# 21,4# 183# 98.5# 85,0# 80,5# 1057X4 77,000 72,550 04 6,1 2,1 03 0,9 40 240 48 xm 320 156 148 100 - -? J7 7 . _ - 104 93 - -4 ) _j _ -- - 27 34 26 - i > (H760V7 TOWOLDMONOQ33067 9/OT n,m nm am OZMO mm 3ijm mm 73,000 mm mm mm mm mm %m nm nm mm mm mm mmmm i6y4m900 nm nm mm mm nm. 3m Am 4,100 7,500 104)00 aoo K.008 20OT 35500 * nm mm nm mm ' %m nm 44,000 mm nm Aim nm nm nm nm 54,000 mm aa m mm nm mm nm mm mm 40,000 nm M40O- om 4,900 $400 SOT 12OT 3S4W 8OT 1SOT 42OT mm mtm m nm -- mm 31 nm nm nm nm nm ,# Am nm 112,100 rtm KUOS nm nm nm 313609 37,200 3S,900 Mjm mm mm sot \im nm 2,900 10500 20OT 30500 >100400 >100500 >100400 m Get nm $nbmm wm 77m itm nm lUjm mm 38JSS8 mm % m,m jzm 27m 7 mm m a SM , sj IS i m mm m m m- - im -- -- - m _ - --- u - TM* % x - ... . _ - - _ f" I-- -- -- 120 0 - 1--- ~- --r ~~ ~~ -- 0 80 --_ ---- 6300 6,750 4.80O 23 ~~ ~~ . - " - 60 - --' 136 - - $ 4- 45 45 -- - - -- "7" vwfzwr?'''.: _ - y AW 0476098 TOWOLDMONOQ33068 TOWOLDMONOQ33069 m Plasticizer Performance in m Other Resins ----4-- ----r-- *!- .... -- -- - -- "7 ,' PLASTICIZER PERFORMANCE IN' ETHYL CELLULOSE FILM XJ ----------- * ' t4fe- 49.5% Ethoxy Content) o I8Pf i 44 f 0 fiz&wtT mm . nMrfl #4.0 Strength ^ Control (no plasticizer) w Diojtyl Phthalate O Diphenyl Phthalate 6755 3625 5405 8960 5120 7680 Trcresyl Phosphate 4550 7470 . Santicizer 140 0 Triphenyl Phosphate 5405 4550 8535 6685 . tlcizer E-15 4265 6685 Santicizer 8-16 Ok W Santicizer M47 3485 " 4125 4905 7965 Santicizer 1-H 5475 7750 ^ Santicizer 8 w Santicizer 9 Arodor 1242 . 4625 6900 4625 7325 4905 7395 Arodor 1248 5475 7540 ArDclorl254 ................................. W Arodor 1262 6185 7110 7825 , 8035 Arodor 4465 8535 9030 *YMd Point PtmtieimS Film YfeU Point UnpteMcizmJ Film xim <%> 30 38 38 48 38 30 40 '3638 32 34 40 36 30 28 22 22 I index* 100 HfcxiWHy to Retention on tigst loss Ixposure _i EE 55 G E' : 80 E G 1 70 E E- 4 ____ t 80 E E 70 E 65. G E ii E. 11 ! ' 50 G E 60 G E 80 E E 70 G E . 70 G E 75 P G * 80 P G 90 G G 105 E G 125 . G P l = Bwltot S = G0Ki f = Poor ; ! f 1 ____ 1 047O1OO TOWOLDMON0033070 Control (no plasticizer) Sarticizer 1-H Sarticizer 8 Santscizer 9 Sarticizer 160 Dibutyl Phthalate Trlphenyl Phosphate Trfcresyi Phosphate Camphor 26 22 27 n ' 25 29 20 10 3270 16 --2276 .... ... 14 -- 10 ----' 24 _. 3555 -- 2700 .-- 4410 _ _1210 ' _ -5405 7 45 41 11 31 63 ~~~ 60 -- 10 10 4 36 8 - 52 24 16 19 65 56 . 28 . 6 .. " m 1 jJ J m j0 4 PLASTICIZER PERFORMANCE IN CELLULOSE ACETATE (LOW ACETYL) ______ ____ __ MOLDING COMPOSITIONS (52.5-53.5%),^_____ . * 151,5 PHR unless otherwise specified! - f ..r Dimethyl phthalate Diethyl phthalate Sarticizer M17 Sarticizer E45 ' H*rdn**t?0'C. Rockwell "H" Scale Fleneral Strength (ss.sl) 120 32 5840 140 , is 5680 148 , 65 7110 148 - 50 6930 Per Cent Water AtorW 48 ta m 1.14 n .A1.20 - 30,77 0.97 i Sarticizer 8 Sarticizer 9 . Tripfieoyl phosphate (42,5 PHR) 133 153 180 75 90 , 81 ,. : 6860 9160 9020 0.94 . , 0.85 , 1.17 1 #Jk 4 OSZeiOJ. TOWOLDMONOQ33071  PLASTICIZER PERFORMANCE IN CELLULOSE ACETATEBUTYRATE FILM a (37% Butyrate, 13% Afatat#) " (50 PHRS ' :4 o o RasMitf 0 ,, Dimethyl Phthalate Dibotyl Phthalate \sJ Santicizer 160 Dioctyl Phthalate O " Dlcyclohexyl Phthalate Diphenyl Phthalate #L . Santicizer E-15 Santicizer B-16 %- Santicizer M-17 %fSk Santicizer 140 i, | 1 1 I| | l I. . i ; Sward Madness 48 38 42 . 44 30 42 34 40 52 ( 42 hP'Jt* V'fir.zih (p>m 4200 Etaplto . .(%) r-aW*&<% 14 1800 12 2700 2900. . 3900 ' 9 .......J- 19 1t 4 31 i,| 3800 2000 i ' 28 t1 14 1800 : 15 1800 18 . 2700 ' 13 a Santicizer 141 i ; 44 2300 : 15 | a Tricresyl Phosphate 54 3000 20 f m, _ Triphenyl Phosphate Dioctyl Adipate m. Santicizer 1-H Wf Santicizer 3 l 40 f \ . 28 i 46 1 34 '. 2500 2100 3900 1800 id ' 12 46 - 27 1 j .... j | TOWOLDMONOQ33072 n.mmm Conti c>! Olbut/I phthalate Di-2-f*thyl hexyl phthalate Diiso tecyl phthalate DiisodecyS adipate Santcizer E-15 SantCtzer M-17 Santloizer B-16 Tricresyl phosphate Santle-zer 140 * Santizizer 141 HB-40 Aroclur 1248 Aroetor 1221 Mod-Epox , commtibiuty Rosa !W C. Temperature for 2 ' tipa Cate Hour Care CC c CC c CI/P.S. c CI/P.S. c Cl cc cc cc cc c c* cc c SICI c .c cc cc c SIC! SICI w c C c c C C SICI c c c C = Compatible C* = Cloudy CI/P.S. = Cloudy, Phase Separation SO = Slightly Cloudy W = White 60 cpm (smless otter- wise specified) Before Adding Alter Siding Curing Agent Curing Agent 4 d 12,800 (30 rpnri) 1,550 2,650 3,250 7,900 1,300 2,700 2,450 0 ^ c| 1,200 3,050 1,100 2,100 ^4 3,150 2,300 3,750 2,450 O 2,000 j .. ' 3,000 IP 2,850 , 2,200 1,500 1,400 S 3,900 2,300 ft 7,700 1,650 4,300 ....... M fgP 1,200 1,650 1,250 wAm * J3 0476103 4 4 TOWOLDMONOQ33073  . mf IN EPOXY RESINS (EV,= 200) o o Piirsm Ssrstfles cared JOtf.'i <n V/s C Q icfN 8 phr fete-dVe* ultra:'* Q :d Imped feiftiaact C'y'.'f %m m*.ut Q ~ "I * 3.0 ) CT" wo . / ...a... .'.i. V "... SgPt # 9A -----0.54.9 0.5*0.8 0.5-0.8 ---- ---------- ---- -- ---0.50.6 0.6 9l_ 0.8-O.9 , 3.5 8.0 7,0 94.0 2.5 3.0 4.5 3.5 ' 3.8 4.0 4.0 3.0 3.0 4.0 , , ' 1 o Shore 0 Hardness GO See.) 78 31 48 56 10 6 7 15 22 5 27 40 8 84 Aged ?4 !kh;?s 8SV> C. m activated carbon Shore 0 Hardness (10 Sec.) 86 ' % Weight Change -0.012 78 , 82 83 ' 82 80 85 85 86 79 82 84 88 81 88 ' -0.734 -0.368 -0.168 -0.181 +0.119 -0.131 -0.013 -0.222 -0.284 -0.425 -0.648 -0.682 -2.118 . +0.134 r. l ______ J "<S J l l 1 i i I TOWOLDMONOQ33074 Performance in 0thcr Resins (continued) ; PLASTICIZER PERFORMANCE IN POLYVINYL ACETATE EMULSION ADHESIVES Vi (XxH plastic!mr m 100 parts Ociva 5-55 fpoly/m/l acetate) emyiofon. him t'eeknasa 0 040 <nch PSosJfcfes WatillN 24 h*r$ it %T C. Clttonl (per writ) Lc f. -V 'O'J.*' V-'./n it,.-. I ,'J) ( c, Oil Attraction--Weight loss After 24 Hours st Room TestpsrsSors (per rant) fesmit Oil Cotton-Seed Oil Arty (or 1221 5.2 frfA.hr 1232 4.8 An .dor 1242 4.4 1 nphertyl Phosphate 2.0 Tnctesyl Phosphate " r 0.75 Dimethyl Phthalate OHhyl Phthalate Dihutyl Phthalate 5.6 f rI 4.8 4.4 Diphenyl Phthalate 5.9 Sadictzer B-16 2.2 Saaficizer M-17 3.6 Sanitizer 1-H 1.5 Saiticizer 8 3.6 Saitlcizer 9 3.1 Samcizer 140 1.2 Saotictzer 141 1.8 Sanitizer 180 2.1 -5.0 4,0 5.3 5.7 3.6 -1.6 -5.0 --6.1 -- - "-3.9* 1.5 -- 6.4 -- 5.0 --3.3 1.9 0.63 0.54 0.57 0.02 0.16 0.92 0.85 0.59 1.31 0.08 0.19 0.96 0.43 1.13 0.15 0.17 ' 0.20 0.37 0.38 0.38 0.46 0.75 0.93 0.63 0.82 0.51 0.90 0.46 0.50 0.59 0.98 0.36 0.48 o m 0.36 0.53 0.60 0.64 0.57 0.63 m o0.34 0.36 * 0.42 0.31 0.39 0.34 m *76i05 4 TOWOLDMONOQ33075 Tift following technics! bulletins and brochure* drive complete technical infor mation about the properties d applications of the Monsanto plasticizers that are mentioned in Shit catalog* Monsanto technical literature is continuously revised to contain the most recent and reliable information possible. Your request for any lit erature will be promptly and cheerfully filled - - without obligation, of course. Title Technical Bulletin No. Phthaiate Plasticizers Dsbutyl Phthaiate Oicycfohexyi Phthaiate Diethyl Phthaiate and Dimethyl Phthaiate DHsodecyt Phthaiate DM2 ethylhexyi) Phthaiate (OOP) Diphenyl Pnthafate Ditri-decyl Phthaiate Di{rvoctyLn-decyO Phthaiate Santicizer 160 (butyl benzyl) Phthaiate Santicizer 165 Santicizer 213 and Santimer 214 Santicizer 215 Santicizer 218 Santicizer m Santicizer $02 anti Santicizer 636 Santicicwr 603 SsnMarer 630 and Ssnticaer 631 Santicizer 632 and Santicizer 683 Santicizer 681 Adipate Plasticizers Diisodecyi Adipate Di(n-octyl,n-deeyi> Adipate , Oioctyl Adipate PL-302 PL-312 Pi-303 Pt-300 PL-318 . PL-319 PL-3B PL-330 PL460 PL465 O/PL-213 PL-215 PL-218 PL-262 PL* PL* PL-630 PL-632 PL-481 PL* PL-316 PL-304 Phosphate Plasticizers Tricresyl Phosphate Triphenyi Phosphate Santicizer 140 Santicizer 141 . Pi* PL-301 1=1-140 O/PL-141 q<* TOWOLDMONOQ33076 V TECHNICAL immrum ieaifflamw Title Technical Bulletin No. Phthaiyf Giycoftate Ptasticizers " Smttcmt -15 (Ethyl phthalate ethyl glycollate) Santkize? 846 (Butyl Phthalyl fcutyl glycoliat*?} SantlUzer M47 (Methyl phthafate ethyl glycollate} ` Sulfonamide Plasticizers ' , Santicizer VH Santscizer 3 Santicizer 8 Santicizer 9 Santolite MNP and Santoiite MS-80% Permanent Plasticizers Santlclzer 405 Santicizer 4fe Santicizer 409 StnticiiW 411 Santicizer 452 Permanent Plasticizer Selector ' Other Plasticizers ' Arcelor Plasticizers H8- (pertwtty hytjregeratfflj terpfcemylS Modaflow Mod-Epox (epoxy-resin modifier) Montar Compounds Pfwgard C-&-R Triphenyl Phosphite Genera! Monsanto Solid Plasticizers \ Monsanto Plasticizers in Synthetic-Resin Adhesives " Monsanto Plasticizers in Protective Coatings Sulk Receiving of Plasticizers Monsanto Modifiers for Thiokoi* Poiysulflde Liquid Polymers Monsanto Plasticizers for Food Packaging Applications Monsanto Plasticizers for Hard-to-Plastieize Resins Chemical Resistance of Plasticizers in Plastisols Pl-15 ' PL-16 . PL-17 ' O/PL-I-H PL-3 ojpi-m O/PL-9 Q/PL-320 PL-40S PL-406 PL-409 Ft-411 PL-4620 Oift-344 ' 0/PL-308 PL-40 0/PL-330 PL-313 PL-328 0/PL-22 PL-317 , 0/PL-345 PL-307 PL-327 PL-314 PL-331 Pl-500 PL-332 PL-333 a%T> w* o ! d q o| o| oI .0 TOWOLDMONOQ33077