Document Eqe8zxgEpK31K53aovaMZx2pj

AR 22 _066 70 ATTACHMENT TO LETTER TO C. AUER DATED AUGUST 31, 2000 Jf e o] ENVIRONMENTAL 5 = ` 000944 ENVIRONMENTAL MONITORING: SURFACE WATER MULTL-CITY STUDY August 2000 Adessfiuglnleyddteoscorbitbaeidn ipnrethleimMianayry4,d2a0t0a0absuobumtitdtiaspletrosiEoPnAo,ftfhleuomruolcthi-ecmiitcyalsstuidnytwheas peontveinrtoinamlesnotu,rcuepstaokfehuinmtao nfoaodnsd, eannvdirpornemseenntcealinexdproisnukriensg twhaattemritgohutnrdeesruslttafnrdomthtehis type of dispersion. The multi-city commercial useoffluorochemical study paired a city products based on having manufacturing or customer sales with a city that does not. Initially six cities, (three pairs) are being examined. The study may be expanded depending on further results. cBaosmemderocniaflurutsheerofrefvluioerwoachnedmiacnaallyss,iist ohfasinbfeoernmalteiaornnepdertthaaitnfiinvge toofmtahneusfiaxcctituyring or slohcoautlidonbsefaclolnisnitdoertehadtacsaatebgroorayodfbassuepdpleynvliocraotnimonesn.taTlhumso,nitthoersiinxg-iptryosgtruadmy ponrloyg,ram without the ability to differentiate supply chain from non-supply chain cities. `Tphoetenmtuilatli-scoiutrycesstuodfyhwuilmlaynieelxdpeonsuvrier.onTmehnetaciltideisswtreirbeutsieolnecdtaetdataosrweeplrlesaesndtautraboann `lomcuantiicoinpsalwiwtahtevrarsiuopupslileesv.elTshoef fslaumoprloecshetmoibcealobrtealienaeseds, awnhdervearpioosussibtley,peisncolfude: durribnakninaigrw, astuerfraicnetwakaet,etrrceaotleudmdnrainnkdisnugrwfaatceerm,itcarpolwaayteerr,, stehdeimienfnltu,enrtivteorafnisdh, lefefalcuheantte.frAodmdiptuiobnlailcllyy,-oaw"nmeadrwkaesttebatsrkeeatt"meonftsewvoerrkasl,fsolouddgper,oaduncdtsmuwniillcibpealsalmapnldfeidl.l aTphpelseesifnrcolumdeg:robceeerfy,sptoorrke,s cahnidc,keifn,pohsositbdloeg,sp,rcoadtuficseh,fergogms,lomciallk,fabrrmeaedr,sgmraereknetbesa.ns, `rTehpereMsaenyts4,th2e00f0irsdtatraespulrtosvifdreodm dtehteaimlulotnit-hietydesstiugdny.anIdncslturduecdtuirneotfhatthesubsmtiutdtyaalnd `were reports the results of on the quality assurance plan and the drinking water samples taken field from sampling procedures used the six cities. The results and Tinedninceastseeteh;aMtodbriilnek,iAnglawbaatmear;inafnodurPocrittieSst.(LDuecciaet,urF,loArliadba)amdai;d Cleveland, not contain detectable Flelvoerlisdao)f fclounotraoicnheedmidceatlesc.tabOlnelylevtewlos ociftiseuslf(oCnoaltuemdbfulsu,orGoecohregmiiac,alasndinPtehnesadcroilnak,ing wwaatteerr. reSsueletst.heIMncalyud4e,d2a0g0a0insuibnmitthitsalsufbomrimttoarleadreetatihle rfeiegladrdriepnogrtthsefsoerdursienkiinng reviewing the surface water data. `aSdudibtsieoqnuaelntantaolytthiecoarlidgaitnaalhsausbmbietetnaloobftaiinnfeodrmfaortivoanrifoourstwhaetMeurltcio-lcuitmynsstaumdyp,les from the six cities. Samples were collected from surface water sources, both flowing 000945 satnrdePamFsOaSnAd. iMnaaprseasofotfhqeusieatmpwlaetelro.caAtniaolnyssaensdwethree dpaetrafoarremepdrefsoerntPeFdOSin, tPhFe OA, attached data sheets. Istnrseuammsm,atrhye,ltehveeldoaftPaFinOdSicwataessctihtahterinbmeolsotw sthaempdleetsecotfitohneliwmaitteorf2c5olpupmtnoirnaftlloewvienlsg rtharnegeincigtifers,omMo2b5iplpet, tAol,8D3pepcta.tuArn,alAly,seasndofPsoarmtpSlte.sLcuoclileecFtle,dsfhroowmedqutiheetpwraetseernsceinof PquFiOetSwiantvearrsyaimnpglceosncienntthreatPioornts.St.TLhuecrieealroecattwioons.etTshoef dfiartsat saentodfredpaotrat,sMfaoryt2h0e00, sanhaolwyezdeda,naonmdalsouumsmarersiuzltesd. iTnhuthse,raepsoerctonddatseedt oAfusgaumsptl2e0s0w0.ere collected and Tshhoewaendallyesveelssooffsaapmpprloexsimoafttehleyqu3i0eptptw,at1e1r0pfpotr,Maonbdil2e9,0D0eppcta,turre,spaenctdivPeolryt. StI.nLucie gEfefneecrtalL,etvheellfeovrelPsFfOouSnidnibnoatlhl sfaatmhpelaeds mairennwoelwls,bealnodwdtahpehcnhiraonmiacgnNao,Obbostehrovfabwlheich h10a,v0e00b.eeItnidseutnecrlmeiarnetdhetorebaes0o.n30foprptmh.e TfhiindsiwngouilndthyeiePlodrat sSta.feLtuycfiaectqourisetofwa1t0e0rto samples, other than to note that the sample location indicated the presence of considerable manmade debris. `mTohsetcroenscuelnttsraattioornsbeolfotwhethoethleevrelasnaolfyqtueasn,tPifFiOcaAtiaonnodfP2F5OpSptA.,Aatrethvreereycliotyw,lowciatthions, PFOA was found in levels less than 100ppt. There are no environmental effects expected at these levels. Towhneeodvetrraellatmmuelntti-wciotryksst(udPyOiTs Wc)ontpilnaunitnign.flSuaemnptlaensdoefftfhleuelnetaacrheatbeeainngd apnuabllyizceldy. Vstaulfifds,ataenddatnhaelymtaicrakleptrboacsekdeutressamhpalviengbepernodgervaemlowipleldcroecmemnetlnycfeosrhvoarrtliyo.us food 000946 Centre Analytical Laboratories, Inc. 3048 Research Drive State College, PA 16801 Phone: (814) 231-8032 Fax: (814) 231-1253 or (814) 231-1580 Analytical Report Fluorochemical Characterization of Surface Water Samples Columbus, GA (W2336) Centre Analytical Laboratory Report No. 023-014E Testing Laboratory Centre Analytical Laboratory, Inc. 3048 Research Drive State College, PA 16801 3M Environmental Laboratory Contact Kent R. Lindstrom Bldg. 2-3E-09 P.O. Box 33331 St. Paul, MN 55133-3331 Phone: (651) 778-5352 Requester Kris J. Hansen, Ph.D. 3M Environmental Technolog&y Safety Services Bldg. 2-3E-09 P.O. Box 33331 St. Paul, MN 55133-3331 paceroes 000947 1 Introduction ARneasluyltsiacaeLarbeoproartotreidesf,orItnh.e (aCneanltyrsei)sfoofmatsherei3esMoEnfvsiurrofnomceenwtaatleLrabsoarmaptloersy.reTcheeisvaemdbplyesCwenetrree olected from Cokimbs, GA. The Centr study number assigned toth projec fs 023.014. S(LpCeIcMiSMuSo)rowcahsemriecqaulesciheadrafcotrearlizsaatmiponlebsy. qAuiodtaclhofro8msaalmopglreaspwh/eyrtearnedecmeimvafsosrasnapleycsitsomety The samples were prepared and analyzed byLCIMSIMS fr the folowing lisoffucrochemicas: + Table 1: Target Analysis PPeerrffuuoorrooooccttaanneeSSuuffoonnaylasride TE PPFFOOSSA | TYS-- TfhleewainhalCyeinctarle.meDtahtoadpruesseedntweadshvearleidstahtedbhyigCheensttqruea.liTtyhdeatvaaliadvaatiiobnlpero1toicosl atinmde.resus are on 2 Sample Receipt Tihndeivsiadumapllseasmwpleerecosnutbaimnietreswderienirnedciediuvaedl.pSlaasmtpilcceosntwaeirneerrseacenidvWedeornen0o50tp3r0e0s.erTvheed.samEpiglhet collectiondateswerenotsupplied. Chain-of-custodyinformation is resienAnlistchmeentdA. 3 Holding Times The analytical method used was validated against a maximum holding time of 14 days. The stabilityoftheanalytesofinterestforlonger periodshasnotbeendetermined. pasezons 000948 4 Methods -Analytical and Preparatory 4411.1 SLaCmIpMleSIPrMepSaration for LCIMSIMS Analysis r`eSsaimdpulaels cwheorrenei.lSyoirdesptheadsweithex2tr0a0ctULionof(2S5P0E)mgwa.ssoudsieudm 1t0hiopsruelfpaatreesotlhuetiosnamtoplreesmofvoer TLhCeIcMaSrtIrMiSdgaenwaleyssifsi.rsAtfaourttye-dmwiliitther5pomrtLioonfo4f0s%ammpeltheanwoals itnrwaanstfeerrsroedlu0tiaonC.yTshSePEelcuaarttreiwdagse.. mdiestchaarndoeldwaensd ctohleleSctPedEfcoorlaunmalnyswiassbythLeCnIuMStIeMdS.witThh1i0t0r%eatmmeetnhtanroels.uleAd 5inmain peoirgihotnfolodf concentration of the samples por to analysis. 412 Sample Analysis by LOMSIMS IcnolHuPmLnC,,Baanseadlioqunotothfeeaxftfrnaicyotsfntjheocatneadtaenfdopratshseedsttahtiroonuagryhpahlaisqeuiid-pthhaesceoclhurmonmarteolgatriavpehifoc HthPeLiqCuisdepmaroabtlioen,phEaSsIe,MSthperaonvaildyetseaisraeptisdnaendd faocrcuarcahtaeramcetearnisstifcoraamonuantloyfaztiimwein.dgeFroalnlgoweionfg omrigdantiecmpceormaptouurensd;s,moilneccluudliensg uaroeroiconhiezmedi,caflra.gmEelnetcetdo,sparnady idsefgeecnteedr.alloopenractheardacatterreilsattiicveolfy Known fluorochemicals are observed and quantiated against standards. AanHaelwyizeetttPheacskaamrpdlHePe1x1a0c0tsH.PLACnalsyyssitsemwacso.uppleerdftoo:ra meMdicursoinmgassselUetcitmead MreSacMiSonwamosnuitsoerdinfgo (57S2R1M/)0.0. STahmeplHePsLCwearnedeMxtSrIacMtSedmeotnho5/d1s8/u0s0edafnodraannaallyysziesdbanyd iMnSsItrMuSmenbteptawreaemnet5/e2r0s/c0a0nanbde found in attachment D. 5 Analysis 51 CAaTl-piobirntatcailobnrationcurvewasanalyzedat thebeginingandendoftheanalyticalsequence 5f0o0r,thaendco1m0p0o0unnodlsL(opfptin)tTrehset.reTshpeoncsaelborfattihoen pquoainnttisawtieorne oprnevpearrseudsatth0e,co25n,ce5n0i,r1a0t0o,nw2a50s, Gpomllatfoioorntecaoicehfiepociednntt.(rU)sainndgcnoeefaircernetgroefssdieotnewmniihnat1ixonwe(i7g)htwienrge, dtehteesrimoipnee,dy.intAerccaelpbtatainodn curve is scceplabe ifr 20.985(+20.970). Calbrtion standardsarepreparedusingthesame SPEprocedureusedforsamples. tGharloburagthioount cthheeckasntalaynsdias.rdssewqeureenacnea.lyzCeodmppleirainocdeicails (eovbetrayinterdeeftotfhieve ssatamnpdlaerd.injeacntiaotnse) concentrations are within +-20% of the actual value. Fortheresulsreportedhere, calbrationcriteriaweremet. PAGEIOFS 000949 52 BExltaranckison blanks were prepared and analyzed wilh every extraction balch of samples. The. hexetlraocwtdieonvebllacnaklsbrsahtoounldsntoantdahradv.e Faonryhtearsgsetsaanmapllyetse,stphreeesxernatcatiotonabblaavneksthweerceonccoemnptlriaatnito.n of Inlesvterlucmaeinbtrbaltaonnksstaindtahredf,oanndofafctleeraknnmoewtnhahingohl-seovlevlesntawmpelreesa.lsAogaanina,lytzheedbalfatnkrsevsheoruylhdignho-t hSaamvpeleasnyprteasregentteadnheareetshepirnessternutmealntobrlaanbkosvaerethceomplloiwa-lnetv.el cafbraton standard. For the 5.3 Surrogates Surrogatespikesare not a component of the LC/MS/MS analytical method. 54 Matrix Spikes AM1la0lt0crniooxmlpsLopuiuskinendsgswseahrloecwpeordepmmaarpledioofsoufpriinnketeveedrrreeyscstof.vieeMlrdiaestsaibmxepstlpweeke(eenrx7cel0u-cd1io3ng0v%belainarrnaelklsi)GsieaavmtespnaliencsoA.ntcetnatrcahtmioennCot.f Fcioemdposupnidessofweinrteerperste.paFrieelddosnpkseamrpelcoeveMrCie-s5a0rTeHalasto agicvoennicneAnttiaztcohnmeofnt1C0.0 Tnhegfiuelsdinsgpikael rbeetswuesesnh7o0w-e1d30l%ow. recovefroyr PFOSA. Al other compounds showed malixspke recoveries 55 ADlul pslaimcplaetses(excuding blanks) were analyzed in duplicate. Results are ven along wit the Sample rein Astiacuhmes ntB. 5.6 MLaibgowraatetrowraysCspoinkterdowlithSaolml cpolmepsound of intresta 25and250ngL. Alrecoverfoirealsl compoundswere between 70-130% in each LCS. Results are given long wih the raw cata in AtiachmentD. 5.7 SFiaemdpbllaenkRsealmaptleesd cCoonsmismteednotfsemply containers. Forty miles of type | water fitered trough ahypercarbcartridgewasadded othe emplycontainerandanalyzedinthesame mannerasthe onersamples. 6 Data Summary PleaseseeAtiachmentBforadetaled ltingof the analyal resuls. 7 Data/Sample Retention e`lSeacmtpiloeniscadraetdaiisspoasrecdhoifveodnoenmroetnriiheavfatbleethmerdeipaoratndshiassrudecdoupnlyersespoortthserwariesesstpoecriefdiiendd.atAla folders maintained by Centre. dors 000950 8 Attachments 81 AtacA:hChamneCunstotdy 82 Atachment:Rests. 83 AtiachmentC:MatixSphkeRecoveries (FieldandLaboratorySpikes) 84 AttachmenDt: LC/RM awAS nal/ yticM alDaSta 9 Signatures " hn. - Operations Manager hile Dale KevinJ Loyd,VicsPresident Date OtherLabMembers Contbuting to Data KaErnaeknsShmaiWtihckremesinhe DavidBell Pacesors 000951 B PLR (TRI0S 0 aA Centre Analytical 5503 oseenah Ove, Stas CoLllaagebPAoTOrRTatE14o23r10i05e2 sFA.X SIEnEcS. I Sh sevns-- Fweerg moor oso sB hrismes ran Ya2 FBy22eeemn ea SS o B ans m. o 5a Pr 2 i SR testis eemp sn = rt.Tarn ci i wortotto emtSAFC FCAT FON mosao wpjwstts fEi=5r = : r=io"sa 22==2 22 000952 @m= BEST COPYAVAILABLE = TE a] 2) ei En Sp : J 13S eT BR AH ALE EeslT2i%n e|TOO 9N7 S LCwooomebmosb Mahiea iU A cA t38OS SCe EyL NSaSEEEwoSSneFHpLOKeeREU KS| LOH IST eh) pia bo mid:lt if{ Bi es FARVSAISN, | Te th 3 A en BL NE RS ke ov TR--7 VER G Ahade e Te e A He P(e ee A TRY Pe EAh R E Ee G a EnRT Y %. |i Shara Ee Environmental Sampling Sites N & E of Columbus, GA 000953 BEST COPY AVAILABLE (5) So es |p a press mbes LR OAR SBC SERA aT ofNoE% NkByEr E 2 i En)AN HL ROE a Fda Fels, 2 J fhe ETN bel Ere ds - SEMIels XCD ea eS a R (Qu ad DET BT NE meee UCT sr eatnlibee Al T i C BR SEl NSRN VKSi | ShY oi 7 PaE meR tSETNS NLeOs Ea LHLAAH N P.wh ER SA Cee | Ir TK A i 057 IN analnr TRI GN emer sams Environmental Sampling Sites for Columbus, GA 000354