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02/07/96 15:30 610 341 7157 Saint-Gobaln HSE rttftth SAINT-GOBAIN CORPORATION FAXTRANSMinAL To %e location A/ G>?3 7 Oate/Time Jjl l<iQ, Number of pages (including cover page) From Location V-F Telephone ~)> 7 Fax Message P%JOS A/C /0Q> 001/005 The Information contained In This facsimile Is directed In confidence solely to the Individual named aoove, and may not otherwise be distributed, copied or disclosed. It you are not the Intended recipient and have received this facsimile In error, please notify us Immedtarely by telephone (collect. If necessary) and return the original transmission to us by mad. without making a copy, thank you for your assistance Salnt-GoboifT Corporation 750 6. Swedesford Road PO Box 860 Valiev Forgo. PA 19482-0)01 CertalnTeed Corporation Norton Compony CTD007280 02/07/96 15:30 610 311 7157 Saint-Gobaln HSE @002/005 Material Safety Data Sheet CertairifeedB CertainTeed Corporation P.O.Box 860 Valley Fonje, PA 19*82 (21SI 3*1-7000 (24 Hour Telephonel DATE PREPARED: September 14,1990 PRODUCT IDENTIFICATION: FLUID-TITE* Asbestos Cement Pipe and Fittings Chemical Name: CAS No.: Common Name (s): Asbestos Cement Pipe None A/C Pipe and Fittings NFPA Rating: HMIS Rating: Health Fire Reactivity 00 0 lm 0 0 (See Section 8 for aeronyms/definitions.) Degree of Hazard 0 - Minimal (Insignificant) 1-Slight 2-Moderate 3 - Serious (High) 4 - Severe (Extreme) Chronic Health Effects)--See section S. 1. INGREDIENT INFORMATION: Chemical Name: Asbestos (Chrysotfle and Croddolite) CAS No.: 1332-21-4 (12001-29-S and 12001-28-4) Common Name: Exposure Limits: OSHA ACGIH TLV Other 8 hr PEL - 0.2 fibers Chrysotile - 2 fibers None > S um/cc > S um/cc 30 min. EL -1 fiber Croddolite - 0.2 fibers > S um/cc > 5 um/cc This chemical is listed on EPA, SARA, Tide'III, Section 313 but not Section 302, and is listed on California's Proposition 65. Chemical Name: CAS No.: Common Name: Exposure Limits: Quarts 14808-60-7 Crystalline Silica OSHA PEL Respirable Duse 0.1 mg/m* ACGIH TLV Respirable Dust: 0.1 mg/m3 Otfagr None This chemical is not listed on EPA, SARA, Title III, Section 302 or 313. but Crystalline Silica is listed on California's Proposition 65. with a qualifier for airborne particles of respirable size. 2. PHYSICAL DATA Boding Point (F): None Melting Point (F): None Odor None Color Cement Gray Vapor Density (Air-1): N/A Specific Gravity (HjO-l): 235 Evaporative Rate (ethyl ether=l): N/A Vapor Pressure (mmHg @ 20C): N/A % Volatile by Volume: N/A % Solubility: Negligible Appearance: Cement gray-colored pipe and fittings Page 1 of 4 01 <08-0020 S/00 CTD007281 02/07/96 15:30 610 341 7157 Saint-Gobaln HSE 81003/005 3. FIRE AND EXPLOSION HAZARD DATA Flash Point (F) and Method: Does not support combustion.Flammable Limits: LEL: N/A UEL: N/A Autotgidtioc Temperature: Does not support combustion. Extinguishing Media: Use that which is applicable to surrounding Ere. This material is non-combustible. Special Fire Fighting Procedures None Unusual Fire and Explosioo Hazard: None 4. PHYSICAL HAZARDS Corrosivity: None Reactivity: None Reactivity with water None 5. HEALTH HAZARD DATA Health effects from storing and handling asbestos cement pipe and fittings should not be a problem if industry recommended work practices are used. (See section 7 for information on industry work practices.) Failure to follow these practices may result in the airborne release of the entrapped asbestos fibers and silica dust ingredients. Exposure to the ingredient dust and fiber may cause the following health effects: Primary Routes of Entry: Inhalation, skin and eye contact. Acute Effects: Inhalation: Dust from cutting/grinding may cause irritation and coughing. Skin contact: Dusts may cause irritation and itching. Eye contact: Dust may cause redness and irritation. Chronic Effects: Inhalation: Excessive exposure to silica and asbestos dust causes a disabling scarring of the lungs, or pneumonoconiosts. called "silicosis" and "asbestosis," which gradually reduce lung capacity and efficiency. Symptoms, which appear 15-20 yean after the first exposure indude coughing, decreased vital capacity, basal rales, cyanosis, cor pulmonale, dubbing of the fingers, anorexia, weakness and .weight loss. Radiologic studies may show diffuse increase in lung opacities and pleural calcifications. Asbestos is classified is a human carcinogen by the IARC and NTP and is regulated by OSHA as a human carcinogen. Asbestos-exposed workers show an increased incidence of pleural or peritoneal mesothelioma and high rates of respiratory cancer. The incidence of pulmonary fibrosis and lung cancer in asbestos-exposed workers is greatly increased by smoking. Reports associating cancer to other body organs exist, although the evidence is not dear. Skin Contact Prolonged exposure to asbestos may cause asbestos warts and dermatitis, usually confined to the hands and forearm. Eye Contact Prolonged exposure to asbestos may cause conjunctivitis. Page 2 of 4 CTD007282 02/07/90 15:31 610 311 7157 Salnt-Gobain HSE 001/005 Medial Conditions WUcfa May be Aggravated: In groups of workers exposed to asbestos, 97.5% of asbestos-related lung cascen occur with those who also smoke cigarettes. 'v Carcinogenicity: Ingredient Asbestos NIP: Human IARC: Classified as Group 1, Carcinogenic to Humans OSHA: Regulated in 29CFR1910.1001 Ingredient: Silica, Crystalline NTP: Not Lined IARG Classified as Group 2A, Probably Carcinogenic to Humans OSHA: Not Regulated as a Carcinogen 6. EMERGENCY AND FIRST AID PROCEDURES Inhalation; Upper respiratory - remove from exposure. Get medical help if irritation persists. Skin Contact Cleanse with soap and water. Get medial help if irritation persists. Eye Contact Flush well with running water for at least IS minutes. Get medical help if irritation persists. Ingestion: Unlikely. Consult physician if unusual reaction is noted. Spills: Pipe fragments and installation debris must be handled in a manner which avoids airborne dispersion of asbestos or silica dust Use wet or vacuum method with HEPA filter for cleanup. Avoid inhalaiinn of dusts. Fires: Does not support combustion. Explosion: N/A Accidental or Unplanned Releases: Avoid generation of dust from cutting or grinding. 7. SPECIAL PROTECTION INFORMATION Personal Protective Equipment Respiratory: OSHA requires the establishment of a respirator program using NIOSH and MSHA approved respirators in emergencies and in work situations where feasible engineering and work practice controls are not yet sufficient to reduce exposure to or below the PEL The airborne concentration of asbestos dictates the appropriate respirators to be used: Not in excess of 2 f/cc (10 x PEL) - Half-mask air-purifying respirator equipped with high-efficiency filters; Not in excess of 10 f/cc (50 x PEL) - Full facepiece air-purifying respirator equipped with high-efficiency filters; Not in excess of 20 f/cc (100 x PEL) - Any powered air-purifying respirator equipped with high-efliciency filters, or any supplied-air respirator operated in continuous flow mode; Not in excess of 200 f/cc (1000 x PEL) - Full facepiece supplied-air respirator operated in pressure demand mode; Greater than 200 f/cc ( > 1000 * PEL) or unknown concentration - Full facepiece supplied-air respirator operated in pressure demand mode equipped with an auxiliary positive pressure self-contained breathing apparatus. Page 3 of 4 CTD007283 Material Safety Data Sheet CertainTeedB CertamTeed Corporation P.0. Box 860 Valley Forge, PA 19482 (215) 341-7000 (24 Hour Telephone) DATE PREPARED: September 14, 1990 PRODUCT IDENTIFICATION: FLUID-TITL* Asbestos Cement Pipe and Fittings Chemical Name: CAS No.: Common Name (s): Asbestos Cement Pipe None A/C Pipe and Fittings NFPA Rating: HMIS Rating: Health Fire Reactivity 00 0 1* 0 0 (See Section 8 for acronyms/definitions.) Degree of Hazard 0 - Minimal (Insignificant) 1 - Slight 2 - Moderate 3 - Serious (High) 4 - Severe (Extreme) Chronic Health Effects)--See section 5. 1. INGREDIENT INFORMATION: Chemical Name: Asbestos (Chrysotile and Croddolite) CAS No.: 1332-21-4 (12001-29-5 and 12001-28^1) Common Name: Exposure Limits: OSHA ACGIH TLV Other 8 hr. PEL - 0.2 fibers Chrysotile - 2 fibers None > 5 um/cc > 5 um/cc 30 min. EL -1 fiber > 5 um/cc Croddolite - 0.2 fibers > 5 um/cc This chemical is listed on EPA, SARA, Title DL Section 313 but not Section 302, and is listed on California's Proposition 65. Chemical Name: CAS No.: Common Name: Exposure Limits: Quartz 14808-60-7 Crystalline Silica OSHA PEL Respirable Dust 0.1 mg/m3 ACGIH TLV Respirable Dust: 0.1 mg/m3 Other None This chemical is not listed on EPA, SARA, Title HI, Section 302 or 313, but Crystalline Silica is listed on California's :Proposition 65, with a qualifier for airborne particles of respirable size. 2. PHYSICAL DATA Boiling Point (F): None Melting Point (F): None Odor None Colon Cement Gray Vapor Density (Air=l): N/A Specific Gravity (H20=1): 2.35 Evaporative Rate (ethyl ether=l): N/A Vapor Pressure (mmHg @ 20C): N/A % Volatile by Volume: N/A % Solubility: Negligible Appearance: Cement gray-colored pipe and fittings Page 1 of 4 01-06-0020 9/90 CTD007285 3. FIRE AND EXPLOSION HAZARD DATA Flash Point (F) and Method: Does not support combustion.Flammable Limits: LEL: N/A UEL: N/A Autoignition Temperature: Does not support combustion. Extinguishing Media: Use that which is applicable to surrounding fire. This material is non-combustible. Special Fire Fighting Procedures: None Unusual Fire and Explosion Hazard: None 4. PHYSICAL HAZARDS Corrosivity: None Reactivity: None Reactivity with water None 5. HEALTH HAZARD DATA Health effects from storing and handling asbestos cement pipe and fittings should not be a problem if industry recommended work practices are used. (See section 7 for information on industry work practices.) Failure to follow these practices may result in the airborne release of the entrapped asbestos fibers and silica dust ingredients. Exposure to the ingredient dust and fiber may cause the following health effects: Primary Routes of Entry: Inhalation, skin and eye contact. Acute Effects: Inhalation: Dust from cutting/grinding may cause irritation and coughing. Skin contact: Dusts may cause irritation and itching. Eye contact Dust may cause redness and irritation. Chronic Effects: Inhalation: Excessive exposure to silica and asbestos dust causes a disabling scarring of the lungs, or pneumonoconiosis, called "silicosis" and "asbestosis," which gradually reduce lung capacity and efficiency. Symptoms, which appear 15-20 years after the first exposure include coughing, decreased vital capacity, basal rales, cyanosis, cor pulmonale, clubbing of the fingers, anorexia, weakness and weight loss. Radiologic studies may show diffuse increase in lung opacities and pleural calcifications. Asbestos is classified as a human carcinogen by the IARC and NTP and is regulated by OSHA as a human carcinogen. Asbestos-exposed workers show an increased incidence of pleural or peritoneal mesothelioma and high rates of respiratory cancer. The incidence of pulmonary fibrosis and lung cancer in asbestos-exposed workers is greatly increased by smoking. Reports associating cancer to other body organs exist, although the evidence is not clear. Skin Contact: Prolonged exposure to asbestos may cause asbestos warts and dermatitis, usually confined to the hands and forearm. Eye Contact: Prolonged exposure to asbestos may cause conjunctivitis. Page 2 of 4 CTD007286 Eye Protection: Wear eye protection (safety glasses or goggles) to prevent dust in eyes. Special Gothing: When airborne exposures exceed the PEL, coveralls or similar full-body clothing, head and foot coverings and gloves must be worn. Work Practices and Engineering Controls: Always use industry recommended work practices when handling or performing field operations with asbestos cement pipe. See Manufacturers' Installation Manual, American Waterworks Association Manual M-16, or Asbestos Cement Pipe Producers Association Publications for detailed information on industry recommended work practices. See also the Occupational Safety and Health Administration Regulation 29CFR1910.I001 which regulates workplace exposure to asbestos dust and any state or local workplace codes regulating asbestos exposure. Avoid generation of dusts, do not cut or bevel asbestos cement pipe or fittings with abrasive disc saws or abrasive disc sanders. Storage: None Waste Disposal Information: OSHA requires warning labels stating "DANGER, CONTAINS ASBESTOS FIBERS, AVOID CREATING DUST, CANCER AND LUNG DISEASE HAZARD" be affixed to all raw materials, mixtures, scrap, waste, debris and other products containing asbestos or their containers. Dispose of waste in accordance with federaL state and local regulations. 8. ADDITIONAL COMMENTS Acronyms used in this MSDS: A/C: Asbestos/Cement ACGIH: American Conference of Governmental Industrial Hygienists CAS No.: Chemical Abstracts Service Number EPA: Environmental Protection Agency (USA) f/cc: Fibers per cubic centimeter EL: Excursion limit Fibers > 5um/cc: Fibers greater than 5 microns in length per cubic centimeter of air HEPA: High Efficiency Particulate Air HMIS: Hazardous Materials Identification System IARC: International Agency for Research on Cancer LEL: Lower Explosive Limit mg/m3: Milligrams per cubic meter mppcf: Millions of particles per cubic foot MSHA: Mine Safety and Health Administration N/A: Not applicable NFPA: National Fire Protection Association NIOSH: National Institute for Occupational Safety and Health NTP: National Toxicology Program OSHA: Occupational Safety and Health Administration PEL: Permissible Exposure Limit SARA: Superfund Amendments and Reauthorization Act Title III: Emergency Planning and Community Right to Know Act Section 302: Extremely Hazardous Substances Section 313: Toxic Chemicals TLV: Threshold Limit Values UEL: Upper Explosive Limit Page 4 of 4 S < T IV