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GLP10-01-02 Interim Report 12: Analysis for PFOS, PFHS and PFBS in Decatur, AL Off-Site Soils Collected September/October 2010
Study Title
3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program
Data Requirement
EPA TSCA Good Laboratory Practice Standards 40 CFR Part 792
Study Director
Jaisimha Kesari P.E., DEE Weston Solutions, Inc. 1400 Weston Way
West Chester, PA 19380
Phone: 610-701-3761
Principle Analytical Investigator
Cleston C. Lange, Ph.D. 3M Environmental Laboratory
Interim Report Completion Date
Date of signing
Performing Laboratory
3M Environmental Health and Safety Operations Environmental Laboratory
3M Center, Bldg 260-05-N-17 St. Paul, MN 55144
Project Identification
GLP-10-01-02-12
Total Number of Pages 419
Study: GLP10-01-02, Interim Report 12 Analysis for PFOS, PFHS and PFBS in Off-Site Soils Collected October 2010
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GLP C o m p l ia n c e S t a t e m e n t
Report Title: GLP10-01-02 Interim Report 12. Analysis for PFOS, PFHS and PFBS in Decatur, AL Off-Site Soils Collected September/October 2010. 3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Periluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program.
This analytical phase was conducted in compliance with Toxic Substances Control Act (TSCA) Good Laboratory Practice (GLP) Standards, 40 CFR 792, with the exceptions listed below:
Exceptions to GLP compliance:
Test, control and reference substances were not all characterized under GLPs. As these are real-life environmental samples, there was no dosing and no specific test
substance for this study.
Date
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Study: GLP10-01-02, Interim Report 12 Analysis for PFOS, PFHS and PFBS in Off-Site Soils Collected October 2010
Q u a l it y A s s u r a n c e S t a t e m e n t
Report Title: GLP10-01-02 Interim Report 12. Analysis for PFOS, PFHS and PFBS in Decatur, AL Off-Site Soils Collected September/October 2010. 3M Environmental Laboratory Analytical Protocol GLP-10-01-02: Analysis of Perfluorooctane Sulfonate (PFOS), Perfluorohexane Sulfonate (PFHS) and Perfluorobutane Sulfonate (PFBS) in Groundwater, Soil and Sediment for the 3M Decatur Phase 3 Site-Related Monitoring Program.
This report and the accompanying data were audited by the 3M Environmental Laboratory Quality Assurance Unit (QAU), as indicated below. The findings were reported to the principal investigator (P.I.), laboratory management and study director.
Inspection D ates 03-M arch-2010 06/07-Jan-2010
Phase Protocol Data & Report
P .l. 03-M arch-2010
10-Jan-2010
D ate Reported to Study D irector M anagem ent 03-M arch-2010
19-Jan-2010
Study D irector 03-M arch-2010
19-Jan-2010
QAU Representative
2 -a -//
Date
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Study: GLP10-01-02, Interim Report 12 Analysis for PFOS, PFHS and PFBS in Off-Site Soils Collected October 2010
T Ca b l e o f o n t e n t s
GLP Compliance Statement............................................................................................................................3 Quality Assurance Statement..........................................................................................................................4 Table of Contents.............................................................................................................................................5 List of Tables.................................................................................................................................................... 6 1 Study Information......................................................................................................................................7 2 Summary................................................................................................................................................... 8 3 Introduction..............................................................................................................................................10 4 Test, Control and Reference Substances.............................................................................................. 10 5 Test System.............................................................................................................................................12 6 Method Summary....................................................................................................................................12
6.1 Methods...................................................................................................................................... 12 6.2 Sample Collection........................................................................................................................12 6.3 Sample Preparation.....................................................................................................................12 6.4 Percent Soil Moisture Determination...........................................................................................13 6.5 LC/MS/MS Analysis....................................................................................................................14 7 Analytical Results ....................................................................................................................................15 7.1 Calibration ................................................................................................................................... 15 7.2 Limits of Quantitation (LOQs)..................................................................................................... 16 7.3 Continuing Calibration................................................................................................................. 17 7.4 Blanks.......................................................................................................................................... 17 7.5 Laboratory Control Spikes (LCSs)...............................................................................................17 7.6 Laboratory Matrix Spikes (LMSs)................................................................................................18 7.7 Percent Soil Moisture Determinations.........................................................................................19 7.8 Individual Sample Results........................................................................................................... 20
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8 Conclusion.............................................................................................................................................. 23 9 Data/SampleRetention............................................................................................................................ 23 10 List of Attachments................................................................................................................................. 23 11 Signatures............................................................................................................................................... 23
L Tis t o f a b l e s
Table 1. Results for Decatur, AL Off-Site Soils Collected September/October 2010................................... 8 Table 2. LMS Recovery Results for Decatur, AL Off-Site Soils Collected September/October 2010.......... 9 Table 4. Instrument Information....................................................................................................................14 Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053)........................................................... 14 Table 6. Mass Transitions............................................................................................................................ 15 Table 7. PFOS Calibration Summary.......................................................................................................... 16 Table 8. PFHS Calibration Summary........................................................................................................... 16 Table 9. PFBS Calibration Summary........................................................................................................... 16 Table 10. LCSResults (PFOS).....................................................................................................................17 Table 11. LCSResults (PFHS).....................................................................................................................18 Table 12. LCS Results (PFBS)..................................................................................................................... 18 Table 13. Percent Moistures for Decatur, AL Off-Site Soils Collected September/October 2010...............19 Table 14. Individual PFOS Results for Decatur, AL Off-Site Soils Collected September/October 2010.....20 Table 15. Individual PFHS Results for Decatur, AL Off-Site Soils Collected September/October 2010.....21 Table 16. Individual PFBS Results for Decatur, AL Off-Site Soils Collected September/October 2010.....22
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1 Study Information
Sponsor 3M Company
Sponsor Representative Gary A. Hohenstein Environmental Manager Special Projects, EHS Operations Bldg 224-5W-03 St. Paul, MN 55144 Phone: (651) 737-3570 gahohenstein@mmm.com
Study Director Jaisimha Kesari, P.E., DEE Weston Solutions, Inc. 1400 Weston Way West Chester, PA 19380
Study Analytical Testing Facility 3M EHS Operations Environmental Laboratory Building 260-5N-17 St. Paul, MN 55144
Study Personnel (3M Environmental Laboratory) William K. Reagen, Ph.D., Laboratory Manager Cleston C. Lange, Ph.D., Principal Analytical Investigator Gabriel P. McMurtry, Laboratory Technician (Pace Analytical, Professional Services) Kevin J. Eich, Laboratory Technician (Quality Associates, Professional Services)
Study Dates Study Initiation: March 24, 2010 Interim Analytical Initiation: July 14, 2010 Interim Analytical Completion: August 27, 2010 Interim Report Completion: February 1,2011
Location of Archives All original raw data and analytical reports have been archived at the 3M Environmental Laboratory according to 40 CFR Part 792. The test substance and analytical reference standard reserve samples are archived at the 3M Environmental Laboratory according to 40 CFR Part 79
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2 Summary
This interim report 12 of study GLP10-01-02 provides the determined concentration results for perfluorooctane sulfonate (PFOS), perfluorohexane sulfonate (PFHS) and perfluorobutane sulfonate (PFBS) measured in soils collected in September/October 2010 from off-site locations near the 3M Decatur, AL facility. Samples were received into the laboratory under related project GLP10-01-02-12. Triplicate aliquots of soil from each sample bottle were accurately weighed. The third replicate of each was fortified with a known quantity of PFOS, PFHS and PFBS as a laboratory matrix spike (LMS) sample, and then each was extracted for analysis. Quantitative analysis of extracts was performed by a sensitive LC/MS/MS method. The percent moisture of each soil was also determined. The PFOS, PFHS and PFBS concentrations determined are summarized in Table 1. The LMS recoveries for each analyte are summarized in Table 2.
Table 1. Results for Decatur, AL Off-Site Soils Collected September/October 2010
3M LIMS ID [a]
Sample ID
Average Concentration (ng/g; dry weight)
PFOS
PFHS
PFBS
G L P 10-01-01-12-001
D AL SS T R IP 0 0 0 0 0
BLQ
BLQ
BLQ
G L P 10-01-01-12-002
D AL SS 6 1 1 R 0 0 0 0 0
2 1 .8
BLQ
0 .4 1 7 [c]
G L P 10-01-01-12-003
D AL SS 6 1 1 R 0 0 0 1 0
1 4 .6
0 .6 5 8 [b]
0 .5 4 8
G L P 10-01-01-12-004
D AL SS 6 1 1 R 0 0 0 4 0
4 .6 7
BLQ
BLQ
G L P 10-01-01-12-005
D AL SS 6 1 1 R 0 0 0 5 0
2 .7 3
BLQ
BLQ
G L P 10-01-01-12-006
D AL SS 6 0 7 R 0 0 0 0 0
1 4 .7
BLQ
0 .4 8 0
G L P 10-01-01-12-007
D AL SS 6 0 7 R 0 0 0 1 0
2 0.0
BLQ
BLQ
G L P 10-01-01-12-008
D AL SS 6 0 7 R DB 0 0 1 0
2 3.0
BLQ
BLQ
G L P 10-01-01-12-010
D AL SS 6 0 7 R 0 0 0 4 0
4 .6 1
BLQ
BLQ
G L P 10-01-01-12-011
D AL SS 6 0 7 R 0 0 2 7 0
BLQ
BLQ
BLQ
G L P 10-01-01-12-012
D AL SS 6 0 9 R 0 0 0 0 0
2 4.0
0 .1 9 5
0 .5 1 7
G L P 10-01-01-12-013
D AL SS 6 0 9 R 0 0 0 1 0
9 .0 8
BLQ
BLQ
G L P 10-01-01-12-014
D AL SS 6 0 9 R 0 0 0 4 0
1 .0 7
BLQ
BLQ
G L P 10-01-01-12-015
D AL SS 6 0 9 R 0 0 1 1 0
BLQ
BLQ
BLQ
BLQ; LC/MS/MS analyte response was below the nominal 0.200 ng/g lower lim it o f quantitation. All associated LMS results were w ithin acceptance criteria o f 100 + 30% Values in table are shown at 3 significant figures, but more precise data was used fo r data calculations. [a] Samples were logged into 3M LIMS under study GLP10-01-01-12, and analyzed fo r this parallel study GLP10-01-02-12 [b] RPD o f duplicate results was greater than 50% [c] Value reported was from one result when the duplicate result was BLQ
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Table 2. LMS Recovery Results for Decatur, AL Off-Site Soils Collected September/October 2010
3M LIMS ID [a]
Sample ID
PFOS
LMS Recovery (%)[b] PFHS
PFBS
G L P 10-01-01-12-001
D AL SS T R IP 0 0 0 0 0
98 .2 %
98 .9 %
105%
G L P 10-01-01-12-002
D AL SS 6 1 1 R 0 0 0 0 0
97 .9 %
106%
97.4%
G L P 10-01-01-12-003
D AL SS 6 1 1 R 0 0 0 1 0
106%
108%
108%
G L P 10-01-01-12-004
D AL SS 6 1 1 R 0 0 0 4 0
108%
116%
123%
G L P 10-01-01-12-005
D AL SS 6 1 1 R 0 0 0 5 0
112%
112%
107%
G L P 10-01-01-12-006
D AL SS 6 0 7 R 0 0 0 0 0
104%
108%
90.3%
G L P 10-01-01-12-007
D AL SS 6 0 7 R 0 0 0 1 0
103%
108%
127%
G L P 10-01-01-12-008
D AL SS 6 0 7 R DB 0 0 1 0
111%
111%
124%
G L P 10-01-01-12-010
D AL SS 6 0 7 R 0 0 0 4 0
93 .8 %
104%
98.7%
G L P 10-01-01-12-011
D AL SS 6 0 7 R 0 0 2 7 0
100%
92 .9 %
107%
G L P 10-01-01-12-012
D AL SS 6 0 9 R 0 0 0 0 0
88 .3 %
101%
122%
G L P 10-01-01-12-013
D AL SS 6 0 9 R 0 0 0 1 0
111%
109%
125%
G L P 10-01-01-12-014
D AL SS 6 0 9 R 0 0 0 4 0
99 .1 %
87 .9 %
113%
G L P 10-01-01-12-015
D AL SS 6 0 9 R 0 0 1 1 0
124%
105%
116%
[a] Samples were logged into 3M LIMS under study GLP10-01-01-12, but same samples analyzed fo r this study GLP10-01-02-12 [b] LMS recovery results were calculated using a value o f zero fo r samples th a t had a BLQ result.
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3 Introduction
This analytical study was conducted to further characterize the PFOS, PFHS and PFBS concentrations in environmental media collected from locations in the vicinity of the 3M Decatur, AL facility. Reported herein are the measured PFOS, PFHS and PFBS results for the off-site soils collected in September/October 2010. The samples were collected by Weston Solutions, Inc. personnel in September/October 2010 and shipped to the 3M Environmental Laboratory for quantitative analysis. One soil travel blank (trip blank) which accompanied the sample bottle shipment was also analyzed and is reported herein. An aqueous equipment rinseate blank (sample GLP10-01-01-12-009) that was also received with the soil samples was analyzed separately with surface waters and groundwaters received from Decatur as part of the same program; the analysis and result for that sample are reported elsewhere in GLP-10-02-01 interim report 11.
This interim report #12 for study GLP10-01-02 describes the sample shipping, receipt, extraction and quantitative liquid chromatography with triple quadrapole mass spectrometric detection (LC/MS/MS) analysis procedures conducted for the determination of PFOS, PFHS and PFBS concentrations in the off-site soils collected September/October 2010. The project ID for this sampling event and analysis was GLP10-01-02-12. Additionally, included in this report are the assessment of the analytical precision and accuracy for the reported analyte concentration results, the recovery results for a stable isotope labeled surrogate (1 3 C4 -PFOS) that was added to each soil aliquot prior to extraction, and the determined percent moisture (w/w) of each soil.
4 Test, Control and Reference Substances
This study does not have a test or control substance in the classic sense of a GLP study because this study was purely analytical to measure specific target analytes in collected environmental samples. The analytical reference substances used are listed in Table 3.
Table 3. Reference Substances
R eference ID
Chemical Name
Chemical Formula
Use
CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description
Purity
PFOS (linear)
PFOS (linear + branched)
PFHS (linear)
n-Perfluorooctane-1Sulfonate Potassium Salt
n-C8 F1 7 SO3 K Reference Standard for Calibration and LMSs
2795-39-3 Wellington Laboratories
10/18/13 -20C
LPFOSKBM06 TCR08-0001-1/1
Crystalline
98%
Perfluorooctane Sulfonate Potassium Salt C8 F1 7 SO3 K
Reference Standard for LCSs
2795-39-3 3M
12/14/16 -20C 171
TCR-696 White Powder
86.4%
n-Perfluorohexane-1-sulfonate Sodium Salt
n-C6 F1 3 SO3 Na Reference Standard for Calibration and LMSs
3871-99-6 Wellington Laboratories
4/2/13 -20C LPFHxSAM08 TCR08-0018-1/1 Crystalline
>98%
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Table 3. Reference Substances
R eference ID
Chemical Name
Chemical Formula Use CAS # Source Expiration Date Storage Conditions Chemical Lot Number TCR Number Physical Description Purity
R eference ID Chemical Name Chemical Formula Use CAS #
Source
Expiration Date
Storage Conditions Chemical Lot Number TCR Number
Physical Description
Purity
PFHS (linear + branched)
n-Perfluorohexane-1sulfonate Potassium Salt
n-C6F13SO3 K Reference Standard for
LCSs 3871-99-6
3M 2/12/17
-20C
NB 120067-69
TCR-083
W hite Powder
98.6%
[1 ,2 ,3 ,4 ,5 ,6 ,7 ,8 - 13C 8] PFOS
[13C 8]- P e rflu o ro o c ta n e -1 Sulfonate Sodium Salt
13C8F17SO 3 Na
Internal Standard for PFOS
2795-39-3 Wellington Laboratories 6/17/12 -20C
M8PFOS0609 TCR09-0051-8/15 Methanol solution, sealed ampule
>98%
PFBS (predominantly linear)
Perfluorobutane-1-sulfonate Potassium Salt n-C4FgSO3 K
Reference Standard for All PFBS
29420-49-3 3M
1/10/17 -20C
101 TCR-121 White Powder
96.7%
[18O 2]-PFHS
[18O 2]-P erfluo roh exa ne-1 Sulfonate Sodium Salt C 6F13S 18O 216O Na
Internal Standard for PFHS
3871-99-6
W ellington Laboratories
7/24/11 -20C MPFHxS0706 T C R 0 9 -0 0 6 8 -2 /5 M ethanol solution, sealed a m p ule
>98%
[ 1 , 2 ,3 ,4 - 13C 4]-PFOS
[1 ,2 ,3 ,4 -13C 4]P e rflu o ro o c ta n e -1 -S u lfo n a te
Sodium Salt
13C 412C 4F17S O 3 Na
S u rro g a te
2795-39-3 W ellington Laboratories
9/9/2012 -20C
MPFOS0808 T C R 1 0 -0 0 4 4 -1 /9 Methanol solution, sealed
ampule >98%
[18O 2]-PFBS
[18O 2]-P e rflu o ro b u ta n e -1 Sulfonate Am m onium Salt
c 4f 9s 18o 216o n h 4
Internal Standard for PFBS
29420-49-3
RTI International
9/23/10 -20C 11546-107-2 T C R -1 0 2 7 M ethanol solution, sealed am pule
>99%
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5 Test System
There was not a test system for this study in the classic sense of a GLP study, nor was there a dosed test substance. This study was conducted for the determination of PFOS, PFHS and PFBS concentrations in "real world" environmental samples collected in September/October 2010 from off site locations in the vicinity of the 3M Decatur, AL site.
6 Method Summary
6.1 Methods
Soil extraction and quantitative LC/MS/MS analyses were performed using validated method ETS-8-053.0. Initially, a range finding (screening) preparation and analysis was conducted October 20 22, 1010 to approximate the concentrations of PFOS, PFHS and PFBS in the soils; analyzed in analytical run S101022c. The range finding results were used to establish the proper LMS fortification concentrations for the definitive analysis. The definitive LC/MS/MS preparation and analysis for the results reported herein was conducted November 17-19; analyzed as analytical run s101119a.
6.2 Sample Collection
On September 21,2010 seventeen (17) empty 250-mL HDPE NalgeneTM sample bottles, one liter of Milli-QTM water, and one travel blank (trip blank) containing approximately 26 grams of a control soil, were sent from the 3M Environmental Laboratory to Weston Solutions, Inc. field personnel for collection of soils and sediments during drilling of three off-site wells near the 3M Decatur, AL facility, and nearby locations to the Decatur site. Following the soil sample collections, fourteen (14) soil-filled sample bottles, one (1) equipment rinseate blank sample and one (1) trip blank were returned back to the laboratory for analysis. Samples were received at the laboratory with sample chains of custody numbers 16898 and 16899 on October 15, 2010 and were logged into project GLP10-01-01-12 in the 3M laboratory information management system (LIMS) on October 19, 2010. Samples were stored refrigerated until they could be extracted and analyzed.
Soil samples from Decatur, AL are regulated and were appropriately shipped in accordance with USDA/APHIS soil permit number P330-09-00125.
Sample nomenclature follows the form DAL-SS-6xxR-xx-xxxx where the first string defines the Decatur Alabama (DAL) project area, the second string defines the sample media (i.e., SS = soil sample), the third string defines the specific residuum well boring. The fourth string defines the sample type (0 = primary sample, DB = field duplicate, RB = equipment rinseate blank). The fifth string indicates the sampling depth range (0040 indicates 4.0 ft to 4.5 ft interval soil sample).
6.3 Sample Preparation
Once the soil samples were received at the laboratory, they were refrigerated until extraction could be performed. Each soil extraction involved removal of a 1 cubic centimeter (1 cc; 1 mL) soil aliquot (typically ~ 1 gram) from each sample bottle using a fixed volume 1 cc spoon, followed by accurate weight determination of the aliquot on a 5-place balance. Then, a known quantity of internal standard (IS; nominal 3.0 ng for each) and surrogate (nominal 3.0 ng) were added to each soil aliquot. For LMS
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preparations, an additional known quantity of PFOS (linear), PFHS (linear) and PFBS were also added. After fortifications were complete, the soil aliquots were each extracted by addition of 8 mL of a 4:1 acetonitrile:water solution followed by sonication for 1 to 2 hours and then centrifugation to remove solids. The supernatant from each extract was transferred to an autovial for analysis. An accurately measured volume of each supernatant was analyzed by LC/MS/MS.
For this study, a range finding analysis was initially performed to approximate the concentrations of PFOS, PFHS and PFBS in each soil and sediment sample. Preparation of the samples for the range finding analyses were performed on October 20, 2010, and prepared extracts analyzed on October 22, 2010 as analytical run s101022c. The range finding results were used to determine the appropriate laboratory matrix spike (LMS) levels for the definitive analysis. The range finding results are not reported herein, but the analytical run data are contained in Attachment A .
After the range finding analysis was completed, triplicate aliquots of each soil were taken from the bulk samples and extracted for definitive analysis. The third aliquot of each was prepared as a LMS and was fortified with a known quantity of PFOS (linear), PFHS (linear) and PFBS prior to extraction. Fortifications were performed at a level that was appropriate to the endogenous analyte level in the soils (0.5- to 10-times the endogenous analyte level), and based on results determined during the screening analysis. For those samples with PFOS levels above the range of the curve, a separate set of LMSs were fortified with PFOS only, in order to minimize interferences in quantifying PFBS and PFHS in those same samples. Sample preparations for the definitive analyses were performed as a single preparation batch on November 17, 2010 and analyzed on November 19, 2010 as analytical run s101119a.
Laboratory control spike (LCS) samples were prepared with each sample extraction batch, prepared at two levels (3.0 and 30 ng fortifications) and each level prepared in triplicate. The LCSs were prepared using control soil TCR-842 and were fortified with PFOS (linear + branched), PFHS (linear + branched) and PFBS.
A set of calibration standards were prepared by spiking known quantities of PFOS (linear), PFHS (linear) and PFBS, and surrogate (13C4-PFOS) into 1-cubic centimeter (1 cc; equivalent to 1 mL) aliquots of 3M Environmental Laboratory matrix soil TCR-842. The nominal mass of 1 cc of control soil TCR842 is 1.0 gram (dry). Therefore, the range of prepared calibration standards was nominal concentrations 0.200 ng/cc to 200 ng/cc (equivalent to 0.200 ng/mL to 200 ng/mL). When adjusted for the nominal mass of standard soil TCR-842, the nominal calibration standard range was 0.200 ng/g to 200 ng/g.
6.4 Percent Soil Moisture Determination
The percent moisture of each soil and sediment was determined by gravimetric analysis. Dry weights were determined for separate sample weighings than the weighings performed for the LC/MS/M extract preparations. To determine the percent moisture, duplicate aliquots of each soil sample were removed and the accurate "wet" weight determined for each. Then the aliquots were dried at > 100C until no further significant mass loss occurred from water evaporation, at which time the accurate dried weights were determined. The difference in mass, attributed to water evaporation, was used to calculate the percent moisture in the original soil. The averaged percent moisture result for each was then used to calculate the soil PFOS, PFHS and PFBS concentrations on a dry weight basis.
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6.5 LC/MS/MS Analysis
The analysis of soil extracts for PFOS, PFHS and PFBS was performed by liquid chromatography with triple quadrapole mass spectrometric detection (LC/MS/MS) as described in method ETS-8053.0. The relative percent difference (RPD) of duplicate sample results was used as a measure of analytical precision. The determined recovery of fortified PFOS (linear), PFHS (linear) and PFBS from LMS samples was used as a measure of analytical accuracy. Recovery of the surrogate (13C4-PFOS) is included within this report in Table 14, and is also part of an on-going method validation aspect in which surrogate recovery is being evaluated in real environmental samples.
Details of the specific instrument parameters, the liquid chromatography gradient program, and the specific mass transitions analyzed are detailed in the raw data, and are briefly described below in Table 4, Table 5 and Table 6.
Range finding (screening) analysis was performed as analytical run s101022c on October 22, 2010 and is not reported herein, but the data is included in Attachment A . The definitive results reported herein were acquired as analytical run s101119a.
Table 4. Instrument Information
Instrument Name Analytical Method ID Liquid Chromatograph Pre-sampler column Analytical guard column Analytical column Injection Volume Mass Spectrometer Ion Source Polarity Software
ETS-Stan ETS-8-053.0 Agilent 1100 with Binary Pump Prism RP (2.1 x 50 mm, 5 g)
Oasis HLB (3 x 20 mm, 25 g); 30C
Betasil-C18 (2.1 x 100 mm, 5 g); 30C 25 gL
API 4000 Turbolon Spray
Negative Analyst 1.4.2
Table 5. Gradient Liquid Chromatography Conditions (ETS-8-053)
Step Number
Total Time [min]
1 0 .0
2 3.0 3 3.5 4 17.0 5 17.5 6 19.5 7 2 0 .0 8 23.0
Flow Rate [mL/min]
0.400 0.400 0.400 0.400 0.400 0.400 0.400 0.400
Percent A [2 mm Aqueous Ammonium Acetate]
97.0 97.0 70.0 40.0
1 0 .0
1 0 .0
97.0 97.0
Percent B [ Methanol]
3.0 3.0 30.0 60.0 90.0 90.0 3.0 3.0
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Table 6. Mass Transitions
Analyte
Mass Transitions Monitored
PFBS
299>99, 299>80
1 8 O2-PFBS (IS)
303>84
PFHS
399>99, 399>80
1 8 O2-PFHS (IS)
403>84
PFOS
499>130, 499>99, 499>80
13C 8-P F O S (IS)
507>80
13C4-P F O S (S urrogate)
503>80
Note: Multiple mass transitions are summed to give the instrument response for that analyte.
7 Analytical Results
Concentration results are rounded to three significant figures according to EPA rounding rules. Because of rounding some calculated values may vary slightly from those found in the raw data. Laboratory matrix spikes (LMS) meeting the method acceptance criteria of 100 30%, demonstrate that the method was appropriate. The LMS spiked concentrations were adequate for the given matrix and their respective quantitative ranges of PFOS, PFHS and PFBS measured in the samples. All of the LMS recovery results were determined at within 100+ 30%.
7.1 Calibration
A set of calibration standards were prepared by spiking varying known quantities of PFOS (linear), PFHS (linear), PFBS and surrogate (13C4-PFOS), and a fixed quantity of stable isotope labeled internal standards, into one cubic centimeter (1 cc, 1 mL) aliquots of 3M Environmental Laboratory control soil TCR-842 (nominal soil mass of 1.0 g/mL). A total of eleven (11) calibration standards were prepared as a set. The prepared standards ranged from nominal concentration 0.200 ng/mL to 200 ng/mL (0.200 ng/g to 200 ng/g). Following analysis of calibration standards, the concentration of each standard was plotted against the measured analyte /IS peak area ratio. A quadratic equation with 1/x weighting was used to fit the data. Calibration curves were not forced through zero. Determining the standard concentration using the resultant calibration curve and comparing to the known concentration confirmed accuracy of each curve point at within 100 30% (+ 35% at the LLOQ). The correlation coefficient (r) was greater than 0.999 for all calibration curves, and the coefficient of determination (r2) was greater than 0.990. Calibration results for PFOS, PFHS and PFBS are summarized in Table 7, Table 8 and Table 9, respectively.
Because soil weights can vary significantly for a 1 cc (1 mL) field sample, depending on soil type and moisture content, the instrument response was calibrated for the known concentrations of target analytes based on the mass quantity of each pertinent reference substance added to a 1 cc soil (1 mL) calibration standard prior to extraction (e.g. calibrated in this study for a range of 0.200 ng/mL to 200 ng/mL PFOS, PFHS and PFBS). Because a 1cc aliquot of control soil TCR-842 weighs nominally 1.0 gram (dry weight) and has less than 5% moisture content, the nominal concentration range of the calibration was essentially 0.200 ng/g to 200 ng/g. However, because the sample soil aliquots typically weigh more than 1.0 gram and contain significant moisture, the determined concentrations during the analysis on a ng/mL basis from the calibration curve were adjusted for the accurate determined weight and percent moisture so they could be reported on a ng/g (dry weight) basis.
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Table 7. PFOS Calibration Summary
Analytical Run Actual S101119a Recovery (%) n
STD 1
0.200 0.207 104%
1
STD 2
0.500 0.472 94.4%
1
STD 3
0.750 0.72 96.0%
1
STD 4
1.00 0.984 98.4%
1
STD 5
2.50 2.65 106%
1
PFOS (ng/mL) STD 6 STD 7 STD 8
5.00 4.89 97.8%
1
10.0 10.6 106%
1
25.0 24.6 98.4%
1
STD 9
50.0 50.2 100%
1
STD 10
100 99.3 99.3%
1
STD 11
200 200 100%
1
r
N/A 0.9999
N/A 1
Table 8. PFHS Calibration Summary
Analytical Run Actual S101119a Recovery (%) n
STD 1
0.200 0.193 96.5%
1
STD 2
0.500 0.522 104%
1
STD 3
0.750 0.745 99.3%
1
STD 4
1.00 0.922 92.2%
1
STD 5
2.50 2.61 104%
1
PFHS (ng/mL) STD 6 STD 7
5.00 5.33 107%
1
10.0 9.82 98.0%
1
STD 8
25.0 24.5 98.0%
1
STD 9
50.0 50.6 101%
1
STD 10
100 99.6 99.6%
1
STD 11
200 200 100%
1
r
N/A 0.9999
N/A 1
Table 9. PFBS Calibration Summary
Analytical Run Actual S101119a Recovery (%) n
STD 1
0.200 0.174 87.0%
1
STD 2
0.500 0.452 90.4%
1
STD 3
0.749 0.815 109%
1
STD 4
0.999 0.882 88.3%
1
STD 5
2.50 2.62 105%
1
PFBS (ng/mL) STD 6 STD 7 STD 8
5.00 5.3 106% 1
9.99 10.6 106%
1
25.0 23.5 94.0%
1
STD 9
50.0 51.6 103%
1
STD 10
99.9 98.3 98.4%
1
STD 11
200 201 101%
1
r
N/A 0.9996
N/A 1
7.2 Limits of Quantitation (LOQs)
The lower limit of quantitation (LLOQ) is considered to be the lowest non-zero calibration standard in the curve that meets linearity and accuracy requirements (100 + 35%) and for which the area counts are at least 2-times that of the average response determined from the method blanks. The LLOQ for this study was determined as nominal 0.200 ng/g for PFHS and PFOS. The LLOQ for PFBS was nominal 0.500 ng/g. Each sample that gave an analyte response less than the response of the LLOQ calibration standard was reported as BLQ (below the lower limit of quantitation). The upper limit of quantitation (ULOQ) was nominal concentration 200 ng/g for all analytes, and samples with endogenous analyte levels at greater than the ULOQ were appropriately diluted with extracts from method blanks to achieve analyte results within the curve range. The PFOS concentrations in most of the LMS samples exceeded the ULOQ and required dilution. Samples with an analyte/IS peak area response ratio that was less than the LLOQ analyte/IS response ratio were reported as below the limits of quantitation (BLQ).
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7.3 Continuing Calibration
During the course of each analysis, continuing calibration verifications (CCVs) was performed by injection of a mid-level calibration standard to confirm that the instrument response and the initial calibration curve were still in control. All CCVs flanking reported data met the method criteria of 100% 30% (+ 35% at LLOQ).
7.4 Blanks
Four types of blanks were analyzed during this analysis, and included the following: three method blanks were prepared with blank matrix soil TCR-842 and were spiked with IS, three method blanks without IS were prepared, two travel blanks (trip blanks) were prepared from aliquots of the travel blanks that accompanied the sample shipment, and solvent blanks contained extraction solvent. The different blanks results are reviewed to evaluate potential contamination during shipment and sampling, to evaluate method performance parameters such as injector carry over and also to establish the LLOQ. In addition to the aforementioned blanks, one aqueous equipment rinseate sample `equipment rinseate blank' sample was received with the soils/sediments and was analyzed by a sensitive water analysis LC/MS/MS method. The results for the rinseate sample showed PFBS less than 0.0255 ng/mL, PFHS less than 0.103 ng/mL and PFOS less than 0.255ng/mL; reported in GLP10-01-02 interim report 06.
7.5 Laboratory Control Spikes (LCSs)
Laboratory control spikes were prepared by spiking know quantities of PFOS (linear + branched), PFHS (linear + branched) and PFBS into 1 cc aliquots of soil TCR-842, fortified with nominal 3.0 ng and 30 ng and each level prepared in triplicate. Only the 30 ng LCS was analyzed for PFOS in the analytical run s100826a. The results of the LCS analyses and calculation of analyte measurement accuracies (percent recovery) for PFOS, PFHS and PFBS are shown in Table 10, Table 11 and Table 12, respectively. The LCS recoveries were calculated using the following equation: TLCS R,, ecovery = -(-D--e-t-e-r-m---i-n-e:-d--C--o--n-c--e-n--t-r-a-t-i-o:-n--o--f--L--C--S-)- *. ,100%,,
Spike Concentration
Table 10. LCS Results (PFOS)
S am ple ID
Actual Conc. (ng/g) LCS 1 (run s 1 0 1 1 1 9 a ) LCS 2 (run s 1 0 1 1 1 9 a ) LCS 3 (run s 1 0 1 1 1 9 a ) Average Standard Deviation Relative Std. Dev. A v e ra g e LCS R ecovery
M easu red PFOS (ng)
3 .0 ng LCS 3 .0 0
3 0 ng LCS 3 0 .0
2 .8 8
33
3 .1 4
3 4 .6
3 .2 1
32
3 .0 8 0 .1 7 5.7% 103%
33.2 1.3 4.0% 111%
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Table 11. LCS Results (PFHS)
S am ple ID
Actual Conc. (ng/g) LCS 1 (run s 1 0 1 1 1 9 a ) LCS 2 (run s 1 0 1 1 1 9 a ) LCS 3 (run s 1 0 1 1 1 9 a ) Average Standard Deviation Relative Std. Dev. A v e ra g e LCS R e c o v e ry
M e a s u re d PFHS (ng)
3 .0 ng LCS 3 .0 0
3 0 ng LCS 3 0 .0
3 32
3 .1 7
3 4 .2
2 .93
3 4 .6
3.03 0 .1 2 4.1%
33.6 1.40 4.2%
101%
112%
Table 12. LCS Results (PFBS)
S am ple ID
Actual Conc. (ng/g) LCS 1 (run s 1 0 1 1 1 9 a ) LCS 2 (run s 1 0 1 1 1 9 a ) LCS 3 (run s 1 0 1 1 1 9 a ) Average Standard Deviation Relative Std. Dev. A v e ra g e LCS R ecovery
M e a s u re d PFBS (ng)
3 .0 ng LCS
3 0 ng LCS
3 .0 0
3 0 .0
2.85
3 0 .4
3 .1 1
3 0 .4
3.06
3 0 .8
3 .0 1
30.5
0 .1 4
0 .2 3
4.6%
0.76%
100%
102%
7.6 Laboratory Matrix Spikes (LMSs)
Laboratory matrix spikes (LMSs) were generated by adding a known quantity of PFOS (linear), PFHS (linear) and PFBS to an aliquot of soil collected from the field, and then preparing the sample the same as non-spiked samples. Spikes For this study, LMSs were spiked at levels that were appropriate for the endogenous analyte levels in the soils, determined from screening analysis and fortified with the target analytes from 0.5-times to 10-times the endogenous analyte levels determined in the soil/sediment samples during the range finding analysis. The LMS method acceptance criterion of within 100 30% were met for all reported results. The LMS recovery results are summarized in Table 2, and individual sample results for PFOS, PFHS and PFBS are shown in Table 14, Table 15 and Table 16, respectively. The PFOS, PFHS and PFBS recovery calculations for LMSs used the following equation:
TLM,, ,,S ,,Recovery = -(-D--e-t-e-r-m---i-n-e--d--C--o--n-c-e--n-t-r-a--t-io--n--o--f--L--M--S------D--e--te--r-m--i-n--e-d--C---o-n--c-e-n--t-r-a-t-i-o-n---o-f--F--i-e-l-d--S--a--m-*p1le0)0.%.., _... Spike Concentration
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7.7 Percent Soil Moisture Determinations
The percent moisture was determined for each soil sample. Duplicate aliquots of each soil were taken and accurately weighed to determine the "wet" weight. Then each aliquot was dried at > 100C until no further loss in mass occurred, presumed due to water evaporation, then the dry weight was accurately determined. The average percent moisture and RPD of the duplicate determinations for each soil is reported in Table 13. The percent moisture was calculated by the following equation:
,, ,,, .
(Original Soil Wet Mass - Dried Soil Mass) .
Percent Moisture = --- ---------------------------------------------- - * 100%
Original Soil Wet Mass
Table 13. Percent Moistures for Decatur, AL Off-Site Soils Collected September/October 2010.
LIMS ID GLP10-01-01-12-001
Sample ID DAL SS TRIP 0 0000
Average Percent Moisture (w/w) [a]
3.21%
Relative Percent Difference [a]
0.77%
GLP10-01-01-12-002 DAL SS 611R 0 0000
13.0%
15%
GLP10-01-01-12-003 DAL SS 611R 0 0010
10.6%
0.69%
GLP10-01-01-12-004 DAL SS 611R 0 0040
12.7%
20%
GLP10-01-01-12-005 DAL SS 611R 0 0050
12.5%
2.6%
GLP10-01-01-12-006 DAL SS 607R 0 0000
9.88%
8.7%
GLP10-01-01-12-007 DAL SS 607R 0 0010
12.4%
2.7%
GLP10-01-01-12-008 DAL SS 607R DB 0010
12.4%
4.5%
GLP10-01-01-12-010 DAL SS 607R 0 0040
15.8%
4.2%
GLP10-01-01-12-011 DAL SS 607R 0 0270
22.6%
18%
GLP10-01-01-12-012 DAL SS 609R 0 0000
7.99%
5.2%
GLP10-01-01-12-013 DAL SS 609R 0 0010
10.2%
0.34%
GLP10-01-01-12-014 DAL SS 609R 0 0040
9.58%
7.3%
GLP10-01-01-12-015 DAL SS 609R 0 0110
29.5%
5.0%
[a] Result determined for duplicate soil aliquots removed from each sample bottle.
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7.8 Individual Sample Results
Table 14. Individual PFOS Results for Decatur, AL Off-Site Soils Collected September/October 2010.
LIMS Sample ID
Sample Description
Surrogate (13C4- PFOS) Recovery
[a]
Actual LMS Spike Conc. (ng/g; dry
weight)
Measured PFOS Concentration
(ng/g; dry weight)
RPD/ LMS Recovery
(%)
Average PFOS Concentration (ng/g; dry wt.)
GLP10- 01- 01- 12- 001 GLP10- 01- 01- 12- 001 Dup
DAL SSTRIP 0 0000 DAL SSTRIP 0 0000 Lab Duplicate
102% 97.7%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 001 LMS DAL SSTRIP 0 0000 Lab Matrix Spike
96.3%
0.824
0.81
98.2%
N/A
GLP10- 01- 01- 12- 002 GLP10- 01- 01- 12- 002 Dup
DAL SS 611R 0 0000 DAL SS 611R 0 0000 Lab Duplicate
106% 99.0%
N/A
21.7 21.8
0.49%
21.8
GLP10- 01- 01- 12- 002 LMS DAL SS 611R 0 0000 Lab Matrix Spike
91.0%
30.5
51.6
97.9%
N/A
GLP10- 01- 01- 12- 003 GLP10- 01- 01- 12- 003 Dup
DAL SS 611R 0 0010 DAL SS 611R 0 0010 Lab Duplicate
111% 94.0%
N/A
17.5 11.7
40%
14.6
GLP10- 01- 01- 12- 003 LMS DAL SS 611R 0 0010 Lab Matrix Spike
107%
33.3
50.1
106%
N/A
GLP10- 01- 01- 12- 004 GLP10- 01- 01- 12- 004 Dup
DAL SS 611R 0 0040 DAL SS 611R 0 0040 Lab Duplicate
99.3% 93.0%
N/A
4.33 14% 4.67
5.00
GLP10- 01- 01- 12- 004 LMS DAL SS 611R 0 0040 Lab Matrix Spike
108%
32.9
40.1
108%
N/A
GLP10- 01- 01- 12- 005 GLP10- 01- 01- 12- 005 Dup
DAL SS 611R 0 0050 DAL SS 611R 0 0050 Lab Duplicate
120% 106%
N/A
3.22 2.23
36%
2.73
GLP10- 01- 01- 12- 005 LMS DAL SS 611R 0 0050 Lab Matrix Spike
129%
5.62
9.01
112%
N/A
GLP10- 01- 01- 12- 006 GLP10- 01- 01- 12- 006 Dup
DAL SS 607R 0 0000 DAL SS 607R 0 0000 Lab Duplicate
108% 109%
N/A
15.4 14.1
8.9%
14.7
GLP10- 01- 01- 12- 006 LMS DAL SS 607R 0 0000 Lab Matrix Spike
106%
33.8
49.9
104%
N/A
GLP10- 01- 01- 12- 007 GLP10- 01- 01- 12- 007 Dup
DAL SS 607R 0 0010 DAL SS 607R 0 0010 Lab Duplicate
123% 108%
N/A
21.8 18% 20.0
18.1
GLP10- 01- 01- 12- 007 LMS DAL SS 607R 0 0010 Lab Matrix Spike
98.3%
31.4
52.3
103%
N/A
GLP10- 01- 01- 12- 008 GLP10- 01- 01- 12- 008 Dup
DAL SS 607R DB 0010 DAL SS 607R DB 0010 Lab Duplicate
93.7% 102%
N/A
22.9 23.0
0.38%
23.0
GLP10- 01- 01- 12- 008 LMS DAL SS 607R DB 0010 Lab Matrix Spike
102%
36.2
63.1
111%
N/A
GLP10- 01- 01- 12- 010 GLP10- 01- 01- 12- 010 Dup
DAL SS 607R 0 0040 DAL SS 607R 0 0040 Lab Duplicate
104% 109%
N/A
4.26 15% 4.61
4.96
GLP10- 01- 01- 12- 010 LMS DAL SS 607R 0 0040 Lab Matrix Spike
101%
4.36
8.70
93.8%
N/A
GLP10- 01- 01- 12- 011 GLP10- 01- 01- 12- 011 Dup
DAL SS 607R 0 0270 DAL SS 607R 0 0270 Lab Duplicate
107% 98.7%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 011 LMS DAL SS 607R 0 0270 Lab Matrix Spike
106%
1.03
1.03 100% N/A
GLP10- 01- 01- 12- 012 GLP10- 01- 01- 12- 012 Dup
DAL SS 609R 0 0000 DAL SS 609R 0 0000 Lab Duplicate
102% 100%
N/A
23.9 24.1
0.87%
24.0
GLP10- 01- 01- 12- 012 LMS DAL SS 609R 0 0000 Lab Matrix Spike
105%
34.3
54.3
88.3%
N/A
GLP10- 01- 01- 12- 013 GLP10- 01- 01- 12- 013 Dup
DAL SS 609R 0 0010 DAL SS 609R 0 0010 Lab Duplicate
101% 100%
N/A
8.17 10.0
20%
9.08
GLP10- 01- 01- 12- 013 LMS DAL SS 609R 0 0010 Lab Matrix Spike
103%
36.5
49.5
111%
N/A
GLP10- 01- 01- 12- 014 GLP10- 01- 01- 12- 014 Dup
DAL SS 609R 0 0040 DAL SS 609R 0 0040 Lab Duplicate
109% 109%
N/A
1.21 0.928
27%
1.07
GLP10- 01- 01- 12- 014 LMS DAL SS 609R 0 0040 Lab Matrix Spike
102%
4.01
5.05
99.1%
N/A
GLP10- 01- 01- 12- 015 GLP10- 01- 01- 12- 015 Dup
DAL SS 609R 0 0110 DAL SS 609R 0 0110 Lab Duplicate
90.3% 99.0%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 015 LMS DAL SS 609R 0 0110 Lab Matrix Spike
103%
1.03
1.28
124%
N/A
BLQ; Analyte/IS peak area response ratio was less than that of the lowest acceptable standard in the curve and was nominal 0.200 ng/g
Values are shown at 3 significant figures, but more precise data was used for data calculations.
All results were reported from the least diluted sample that that fell within the range of the calibration curve.
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Table 15. Individual PFHS Results for Decatur, AL Off-Site Soils Collected September/October 2010.
LIMS Sample ID
Sample Description
Surrogate (13C4- PFOS) Recovery
[a]
Actual LMS Spike Conc. (ng/g; dry
weight)
Measured PFHS Concentration
(ng/g; dry weight)
RPD/ LMS Recovery
(%)
Average PFHS Concentration (ng/g; dry wt.)
GLP10- 01- 01- 12- 001 GLP10- 01- 01- 12- 001 Dup
DAL SSTRIP 0 0000 DAL SSTRIP 0 0000 Lab Duplicate
102% 97.7%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 001 LMS DAL SSTRIP 0 0000 Lab Matrix Spike
96.3%
0.824
0.815
98.9%
N/A
GLP10- 01- 01- 12- 002 GLP10- 01- 01- 12- 002 Dup
DAL SS 611R 0 0000 DAL SS 611R 0 0000 Lab Duplicate
106% 99.0%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 002 LMS DAL SS 611R 0 0000 Lab Matrix Spike
91.0%
0.762
0.808
106%
N/A
GLP10- 01- 01- 12- 003 GLP10- 01- 01- 12- 003 Dup
DAL SS 611R 0 0010 DAL SS 611R 0 0010 Lab Duplicate
111% 94.0%
N/A
0.914 0.402
78%
0.658 [a]
GLP10- 01- 01- 12- 003 LMS DAL SS 611R 0 0010 Lab Matrix Spike
107%
0.833
1.56
108%
N/A
GLP10- 01- 01- 12- 004 GLP10- 01- 01- 12- 004 Dup
DAL SS 611R 0 0040 DAL SS 611R 0 0040 Lab Duplicate
99.3% 93.0%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 004 LMS DAL SS 611R 0 0040 Lab Matrix Spike
108%
0.822
0.954
116%
N/A
GLP10- 01- 01- 12- 005 GLP10- 01- 01- 12- 005 Dup
DAL SS 611R 0 0050 DAL SS 611R 0 0050 Lab Duplicate
120% 106%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 005 LMS DAL SS 611R 0 0050 Lab Matrix Spike
129%
1.12
1.26
112%
N/A
GLP10- 01- 01- 12- 006 GLP10- 01- 01- 12- 006 Dup
DAL SS 607R 0 0000 DAL SS 607R 0 0000 Lab Duplicate
108% 109%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 006 LMS DAL SS 607R 0 0000 Lab Matrix Spike
106%
0.845
0.914
108%
N/A
GLP10- 01- 01- 12- 007 GLP10- 01- 01- 12- 007 Dup
DAL SS 607R 0 0010 DAL SS 607R 0 0010 Lab Duplicate
123% 108%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 007 LMS DAL SS 607R 0 0010 Lab Matrix Spike
98.3%
0.784
0.848
108%
N/A
GLP10- 01- 01- 12- 008 GLP10- 01- 01- 12- 008 Dup
DAL SS 607R DB 0010 DAL SS 607R DB 0010 Lab Duplicate
93.7% 102%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 008 LMS DAL SS 607R DB 0010 Lab Matrix Spike
102%
0.904
1.00
111%
N/A
GLP10- 01- 01- 12- 010 GLP10- 01- 01- 12- 010 Dup
DAL SS 607R 0 0040 DAL SS 607R 0 0040 Lab Duplicate
104% 109%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 010 LMS DAL SS 607R 0 0040 Lab Matrix Spike
101%
0.871
0.906
104%
N/A
GLP10- 01- 01- 12- 011 GLP10- 01- 01- 12- 011 Dup
DAL SS 607R 0 0270 DAL SS 607R 0 0270 Lab Duplicate
107% 98.7%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 011 LMS DAL SS 607R 0 0270 Lab Matrix Spike
106%
1.03
0.956
92.9%
N/A
GLP10- 01- 01- 12- 012 GLP10- 01- 01- 12- 012 Dup
DAL SS 609R 0 0000 DAL SS 609R 0 0000 Lab Duplicate
102% 100%
N/A
0.186 0.203
8.6%
0.195
GLP10- 01- 01- 12- 012 LMS DAL SS 609R 0 0000 Lab Matrix Spike
105%
0.857
1.06
101%
N/A
GLP10- 01- 01- 12- 013 GLP10- 01- 01- 12- 013 Dup
DAL SS 609R 0 0010 DAL SS 609R 0 0010 Lab Duplicate
101% 100%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 013 LMS DAL SS 609R 0 0010 Lab Matrix Spike
103%
0.912
0.995
109%
N/A
GLP10- 01- 01- 12- 014 GLP10- 01- 01- 12- 014 Dup
DAL SS 609R 0 0040 DAL SS 609R 0 0040 Lab Duplicate
109% 109%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 014 LMS DAL SS 609R 0 0040 Lab Matrix Spike
102%
0.802
0.705
87.9%
N/A
GLP10- 01- 01- 12- 015 GLP10- 01- 01- 12- 015 Dup
DAL SS 609R 0 0110 DAL SS 609R 0 0110 Lab Duplicate
90.3% 99.0%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 015 LMS DAL SS 609R 0 0110 Lab Matrix Spike
103%
1.03
1.08
105%
N/A
BLQ; Analyte/IS peak area response ratio was less than that of the lowest acceptable standard in the curve and was nominal 0.200 ng/g
Values are shown at 3 significant figures, but more precise data was used for data calculations.
All results were reported from the least diluted sample that that fell within the range of the calibration curve.
[a] RPD was greater than 50%
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Table 16. Individual PFBS Results for Decatur, AL Off-Site Soils Collected September/October 2010.
LIMS Sample ID
Sample Description
Surrogate (13C4- PFOS) Recovery
[a]
Actual LMS Spike Conc. (ng/g; dry
weight)
Measured PFBS Concentration
(ng/g; dry weight)
RPD/ LMS Recovery
(%)
Average PFBS Concentration (ng/g; dry wt.)
GLP10- 01- 01- 12- 001 GLP10- 01- 01- 12- 001 Dup
DAL SSTRIP 0 0000 DAL SSTRIP 0 0000 Lab Duplicate
102% 97.7%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 001 LMS DAL SSTRIP 0 0000 Lab Matrix Spike
96.3%
0.824
0.865
105%
N/A
GLP10- 01- 01- 12- 002 GLP10- 01- 01- 12- 002 Dup
DAL SS 611R 0 0000 DAL SS 611R 0 0000 Lab Duplicate
106% 99.0%
N/A
BLQ 0.417
N/A 0.417 [a]
GLP10- 01- 01- 12- 002 LMS DAL SS 611R 0 0000 Lab Matrix Spike
91.0%
0.763
1.16
97.4%
N/A
GLP10- 01- 01- 12- 003 GLP10- 01- 01- 12- 003 Dup
DAL SS 611R 0 0010 DAL SS 611R 0 0010 Lab Duplicate
111% 94.0%
N/A
0.679 0.417
48%
0.548
GLP10- 01- 01- 12- 003 LMS DAL SS 611R 0 0010 Lab Matrix Spike
107%
0.834
1.45 108% N/A
GLP10- 01- 01- 12- 004 GLP10- 01- 01- 12- 004 Dup
DAL SS 611R 0 0040 DAL SS 611R 0 0040 Lab Duplicate
99.3% 93.0%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 004 LMS DAL SS 611R 0 0040 Lab Matrix Spike
108%
0.822
1.01 123% N/A
GLP10- 01- 01- 12- 005 GLP10- 01- 01- 12- 005 Dup
DAL SS 611R 0 0050 DAL SS 611R 0 0050 Lab Duplicate
120% 106%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 005 LMS DAL SS 611R 0 0050 Lab Matrix Spike
129%
1.123
1.20
107%
N/A
GLP10- 01- 01- 12- 006 GLP10- 01- 01- 12- 006 Dup
DAL SS 607R 0 0000 DAL SS 607R 0 0000 Lab Duplicate
108% 109%
N/A
0.523 18% 0.480
0.437
GLP10- 01- 01- 12- 006 LMS DAL SS 607R 0 0000 Lab Matrix Spike
106%
0.846
1.24
90%
N/A
GLP10- 01- 01- 12- 007 GLP10- 01- 01- 12- 007 Dup
DAL SS 607R 0 0010 DAL SS 607R 0 0010 Lab Duplicate
123% 108%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 007 LMS DAL SS 607R 0 0010 Lab Matrix Spike
98.3%
0.785
1.00
127.0%
N/A
GLP10- 01- 01- 12- 008 GLP10- 01- 01- 12- 008 Dup
DAL SS 607R DB 0010 DAL SS 607R DB 0010 Lab Duplicate
93.7% 102%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 008 LMS DAL SS 607R DB 0010 Lab Matrix Spike
102%
0.905
1.12 124% N/A
GLP10- 01- 01- 12- 010 GLP10- 01- 01- 12- 010 Dup
DAL SS 607R 0 0040 DAL SS 607R 0 0040 Lab Duplicate
104% 109%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 010 LMS DAL SS 607R 0 0040 Lab Matrix Spike
101%
0.872
0.86
98.7%
N/A
GLP10- 01- 01- 12- 011 GLP10- 01- 01- 12- 011 Dup
DAL SS 607R 0 0270 DAL SS 607R 0 0270 Lab Duplicate
107% 98.7%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 011 LMS DAL SS 607R 0 0270 Lab Matrix Spike
106%
1.03
1.10
107%
N/A
GLP10- 01- 01- 12- 012 GLP10- 01- 01- 12- 012 Dup
DAL SS 609R 0 0000 DAL SS 609R 0 0000 Lab Duplicate
102% 100%
N/A
0.534 0.501
6.3%
0.517
GLP10- 01- 01- 12- 012 LMS DAL SS 609R 0 0000 Lab Matrix Spike
105%
0.858
1.56
122%
N/A
GLP10- 01- 01- 12- 013 GLP10- 01- 01- 12- 013 Dup
DAL SS 609R 0 0010 DAL SS 609R 0 0010 Lab Duplicate
101% 100%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 013 LMS DAL SS 609R 0 0010 Lab Matrix Spike
103%
0.913
1.14
125%
N/A
GLP10- 01- 01- 12- 014 GLP10- 01- 01- 12- 014 Dup
DAL SS 609R 0 0040 DAL SS 609R 0 0040 Lab Duplicate
109% 109%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 014 LMS DAL SS 609R 0 0040 Lab Matrix Spike
102%
0.803
0.91
113%
N/A
GLP10- 01- 01- 12- 015 GLP10- 01- 01- 12- 015 Dup
DAL SS 609R 0 0110 DAL SS 609R 0 0110 Lab Duplicate
90.3% 99.0%
N/A
BLQ N/A BLQ
BLQ
GLP10- 01- 01- 12- 015 LMS DAL SS 609R 0 0110 Lab Matrix Spike
103%
1.03
1.19
116%
N/A
BLQ; Analyte/IS peak area response ratio was less than that of the lowest acceptable standard in the curve and was nominal 0.500 ng/g
Values are shown at 3 significant figures, but more precise data was used for data calculations.
All results were reported from the least diluted sample that that fell within the range of the calibration curve.
[a] Value attained from a single result, duplicate result was BLQ.
3M Study: GLP10-01-02 Interim Report 12
Page 22 of 419
Study: GLP10-01-02, Interim Report 12 Analysis for PFOS, PFHS and PFBS in Off-Site Soils Collected October 2010
8 Conclusion
Quantitative analysis for PFOS, PFHS and FPBS in the Decatur, AL off-site soils collected in September/October 2010 was successfully completed following 3M Environmental Laboratory method ETS-8-053.0. The average PFOS, PFHS and PFBS concentration results are summarized in Table 1 and the LMS recoveries are summarized in Table 2. The PFOS, PFHS and PFBS results for the individual sample replicates that were analyzed are shown in Table 14, Table 15 and Table 16, respectively.
The overall results showed that PFOS was the dominant analyte measured in each of the environmental samples. The LMS samples gave recoveries within 100+ 30% for all analytes. Analytical precision was acceptable as indicated by the RPDs of less than 50%. One RPD result for PFHS was 78% and was footnoted in the results tables.
9 Data/Sample Retention
All samples and associated project data (hardcopy and electronic) will be archived according to 3M Environmental Laboratory standard operating procedures.
10 List of Attachments
Attachment A: Raw Data, Chromatograms, Preparation Forms and Correspondence.
11 Signatures
Report Approval:
Cleston C. Lange, Ph.D., Principal Analytical Investigator
Date
g / y # o //
William K. Reagen, Ph.D., 3M Environmental Laboratory Management
Date
3M Study: GLP10-01-02 Interim Report 12
Page 23 of 419
Study: GLP10-01-02, Interim Report 12 Analysis for PFOS, PFHS and PFBS in Off-Site Soils Collected October 2010
Attachment A
Raw Data, Chromatograms (Partial Set), Preparation Forms and Correspondence
3M Study: GLP10-01-02 Interim Report 12
Page 24 of 419
ENVIRONMENTAL LABORATORY
Sample set ID # Lims #
N/A GLP10-01-01-12
Sample Description: Decatur Soils
INTERNAL CHAIN OF CUSTODY
INTERNAL CHAIN-OF-CUSTODY
Sample Internal Transfer
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
J. . j -, '______ :__________ j ________ Page 25 of 419
GLP10-01-02-12
ETS-8-053
Samples Weighed 17-Nov-2010
Sample ID
Sample Description
1 EC-101117-01 EC-101117-02 EC-101117-03 EC-101117-04 EC-101117-05 EC-101117-06 EC-101117-07 EC-101117-08 EC-101117-09 EC-101117-10 EC-101117-11 MB--101117-01 MB--101117-02 M B -1 0 1 117-03 M B -1 0 1 117-04 M B -1 0 1 117-05 M B -1 0 1 117-06 LCS-101117-01 LCS-101117-02 LCS-101117-03 LCS-101117-04 LCS-101117-05 LCS-101117-06 GLP10-01-01-12-001 GLP10-01-01-12-001 Dup GLP10-01-01-12-Q01 LMS GLP10-01-01-12-002 GLP10-01-01-12-002 Dup GLP10-01-01-12-002 LMS GLP10-01-01-12-003 GLP10-01-01-12-003 Dup GLP10-01-01-12-003 LMS GLP10-01-01-12-004 GLP10-01-01-12-004 Dup GLP10-01-01-12-004 LMS GLP10-01-01-12-005 GLP10-01-01-12-005 Dup GLP10-01-01-12-005 LMS GLP10-01-01-12-006 GLP10-01-01-12-006 Dup GLP10-01-01-12-006 LMS GLP10-01 -01-12-007 GLP10-01-01-12-007 Dup GLP10-01-01-12-007 LMS GLP10-01 -01-12-008 GLP10-01-01-12-008 Dup GLP10-01-01-12-008 LMS GLP10-01-01-12-010 GLP10-01-01-12-010 Dup GLP10-01-01-12-010 LMS GLP10-01-01-12-011 GLP10-01-01-12-011 Dup GLP10-01-01-12-011 LMS GLP10-01-01-12-012 GLP10-01-01-12-012 Dup GLP10-01-01-12-012 LMS GLP10-01-01-12-013 GLP10-01-01-12-013 Dup GLP10-01-01-12-013 LMS GLP10-01-01-12-014 GLP10-01 -01-12-014 Dup GLP10-01-01-12-014 LMS GLP10-01-01-12-015 GLP10-01-01-12-015 Dup GLP10-01-01-12-015 LMS
2 0.2 ng Extracted Curve Point 0.5 ng Extracted Curve Point 0.75 ng Extracted Curve Point 1 no Extracted Curve Point 2.5 ng Extracted Curve Point 5 nq Extracted Curve Point 10 ng Extracted Curve Point 25 nq Extracted Curve Point 50 ng Extracted Curve Point 100 nq Extracted Curve Point 200 nq Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w/ IS Method Blank 6 w/ IS 3 ng LCS in TCR-842 3 ng LCS in TCR-842 3 ng LCS in TCR-842 30 ng LCS in TCR-842 30 ng LCS in TCR-842 30 nq LCS in TCR-842 DAL SS TRIP 0 0000 DAL SS TRIP 0 0000 Lab Duplicate DAL SS TRIP 0 0000 Lab Matrix Spike DAL SS 611R 0 0000 DAL SS 611R 0 0000 Lab Duplicate DAL SS 611R 0 0000 Lab Matrix Spike DAL SS 611R 0 0010 DAL SS 611R 0 0010 Lab Duplicate DAL SS 611R 0 0010 Lab Matrix Spike DAL SS 611R 0 0040 DAL SS 611R 0 0040 Lab Duplicate DAL SS 611R 0 0040 Lab Matrix Spike DAL SS 611R 0 0050 DAL SS 611R 0 0050 Lab Duplicate DAL SS 611R 0 0050 Lab Matrix Spike DAL SS 607R 0 0000 DAL SS 607R 0 0000 Lab Duplicate DAL SS 607R 0 0000 Lab Matrix Spike DAL SS 607R 0 0010 DAL SS 607R 0 0010 Lab Duplicate DAL SS 607R 0 0010 Lab Matrix Spike DAL SS 607R DB0010 DAL SS 607R DB 0010 Lab Duplicate DAL SS 607R DB 0010 Lab Matrix Spike DAL SS 607R 0 0040 DAL SS 607R 0 0040 Lab Duplicate DAL SS 607R 0 0040 Lab Matrix Spike DAL SS 607R 0 0270 DAL SS 607R 0 0270 Lab Duplicate DAL SS 607R 0 0270 Lab Matrix Spike DAL SS 609R 0 0000 DAL SS 609R 0 0000 Lab Duplicate DAL SS 609R 0 0000 Lab Matrix Spike DAL SS609R 0 0010 DAL SS 609R 0 0010 Lab Duplicate DAL SS 609R 0 0010 Lab Matrix Spike DAL SS 609R 0 0040 DAL SS 609R 0 0040 Lab Duplicate DAL SS 609R 0 0040 Lab Matrix Spike DAL SS 609R 0 0110 DAL SS 609R 0 0110 Lab Duplicate DAL SS 609R 0 0110 Lab Matrix Spike
(> Tl?*-
k
ne^riX
i> o o S ' l M H .
< )G ?
.
Soil Maxtrix Soil Weight ID U s e d (g)
(9 3 10 005-224 , 10 005-224 : 10 005-224/ 10 005-224/ 10 005-224/ 10 005-224 10 005-22 10 005-23U 10 005-22V 10 005-20$ 10 005- m
10Q(ty2'24 10WP-224 10 005-224 10 QD5-224
p i o 005-224 P i o ] 005-224
10 005-224 TO005-224 /IO 005-224 /1 0 005-224 / 10 005-224
O O
,%
-
''V"* ' v
mM s
o m u m
M --
mm
mHIw IK M B III!
to n s * *
Si:
_ ___fly_1_.
71i i
t ;.
1. . -,.. .
...............
'-
4
1.1210 1.1468 1.1176 1.1681 1.1248 1.1354 1.1107 1.1121 1.1727 1.1380 1.2003 1.2468 1.1956 1.1435 1.1651 1.1557 1.1508 1.1617 1.1381 1.1313 1.1811 1.1625 1.0354 1.1660 1.1776 1.2542 1.3819 1.6227 1.5079 1.4076 1.5086 1.3420 1.5569 1.5467 1.3929 1.0459 1.1365 1.0176 1.2272 1.3341 1.3117 1.3442 1.3590 1.4539 1.0611 0.9132 1.2615 1.4067 1.5143 1.3629 1.0003 1.0837 1.2554 1.1365 1.1492 1.2662 1.3181 1.1918 1.2201 1.3124 1.4532 1.3781 1.6196 1.3569 1.4852
Col 3 & 4: T K Balance ID: 900
&
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
Page 26 of 419
GLP10-01-02-12
ETS-8-053
Samples Extracted 16-Nov-2010
Sample ID
Sample Deacriptlon
EC-101117-01
EC-101117-02
EC-101117-03
EC-101117-04
EC-101117-05
EC-101117-06
EC-101117-07
EC-101117-00
EC-101117-09
EC-101117-10
EC-101117-11
MB-101117-01
M B -10 11 17 -0 2
M B -10 11 17 -0 3
MB--101117-04
M B -1 0 1 1 1 7 -0 5
M B -10 11 17 -0 6
LCS-101117-01
LCS-101117-02
LCS-101117-C3
LCS-101117-04
LCS-101117-05
LCS-101117-06
GLP1001-01-12-001
GLP1001-01-12-001 Dud
GLP10O1-01-12-001 IM S
GL P1 00 1-0 1 -1 2 -0 0 2
GLP1001-01-12-002 Dud
G LP1001-01-12-002 LMS
GL P1 00 1-0 1 -1 2 -0 0 3
GLP10-01-01-12-003 Dud
GLP10-01-01-12-003 LMS
GLP10-01-01-12-004
GLP10O101-12-004 Dup
GLP10 0 1 0 1 -1 2 0 0 4 LMS
GLP100101-12005
GLP10 0 1 0 1 -1 2 0 0 5 Dud
G LP100101-12005 LMS
GLP10O10 1 -1 2 0 0 6
GLP10O10 1 -12 00 6 Dup
GLP10 0 1 0 1 -1 2 0 0 6 LMS
G LP 100101-12007
GLP10O10 1 -12 00 7 Dud
GLP10O10 1 -12 00 7 LMS
GLP100101-12006
G LP10010 1 -12 00 8 Dud
GLP10O10 1 -12 00 6 LMS
GLP10O10 1 -1 2 0 1 0
GLP10O10 1 -12 01 0 Dup
G LP10010 1 -12 01 0 LMS
GLP10 0 10 1 -1 2 0 1 1
GLP100101-12011 Dud
GLP1D0101 -12011 LMS
GLP10O10 1 -1 2 0 1 2
GLP10O10 1 -1 2 0 1 2 Dud
GLP10O10 1 -1 2 0 1 2 LMS
G LP 100101-12013
GLP10O1 O l -12013 Dup
G LP100101-12 0 13 LMS
GLP100101-12014
GLP10O101 -1 2 0 1 4 Dup
GLP10O101 -1 2 0 1 4 LMS
GLP100101-12015
GLP10O101 -1 2 0 1 5 Dud G LP100101-12015 LMS
0.2 no Extracted Curve Point 0.5 na Extracted Curve Point 0.75 na Extracted Curve Point 1 na Extracted Curve Point 2.5 na Extracted Curve Point 5 na Extracted Curve Point 10 na Extracted Curve Point 25 na Extracted Curve Point 50 na Extracted Curve Point i n na Extracted Curve Point 200 na Extracted Curve Point Method Blank 1 w/o IS Method Blank 2 w/o IS Method Blank 3 w/o IS Method Blank 4 w/ IS Method Blank 5 w / IS Method Blank 6 w / IS 3 na LCS in TCR-642 3 na LCS In TCR-842 3 na LCS In TCR-642 30 no LCS in TCR-842 30 no LCS in TCR-642 30 na LCS in TCR-842 DAL SS TRIP 0 0000 DAL SS TRIP 0 0000 Lab Duplicate DAL SS TRIP 0 0000 Lab Matrix Spike DAL SS 611ROOOn DAL SS 611R 0 0000 Lab Duplicate DAL SS 611R OOCW Lab Matrix Spike DAL SS 611R 0 0010 DAL SS 611R O n tO Lab Duplicate DAL SS 611R O n tO Lab Matrix Spike DAL SS 611R 0 0040 OAL SS 611R 0 0040 Lab Duplicate DAL SS 611R 0 0040 Lab Matrix Soike DAL SS 611R 0 0050 DAL SS 611R 0 0 05 0 Lab Duoficate DAL SS 611R 0 0050 Lab Matrix Soike OAL SS 607R 0 0000 DAL SS 607R 0 0 00 0 la b Duoficate DAL SS 607R 0 0000 Lab Matrix Soike DAL SS 6 0 7 R 0 n i0 DAL SS 607R 0 0010 Lab Duplicate DAL SS 607R 0 0 01 0 Lab Matrix Spike DAL SS 607R DB 0010 DAL SS 607R DB 0010 Lab Duplicate DAL SS 607R DB n i O Lab Matrix Soike DAL SS 607R 0 0040 DAL SS 607R 0 0040 Lab Duoticate DAL SS 607R 0 0040 Lab Matrix Soike DAL SS 607R 0 0270 DAL SS 607R 0 0270 Lab Duoficate DAL SS 607R 0 0270 Lab Matrix Soike DAL SS 609R 0 0000 DAL SS 609R 0 0000 Lab Dupficate DAL SS 609R 0 0000 Lab Matrix Soike DAL SS 609R 0 0010 DAL SS 609R 0 0010 Lab Dupficate DAL SS 609R 0 0010 Lab Matrix Soike DAL SS 609R 0 0040 DAL SS 609R 0 0040 Lab Duplicate DAL SS 609R 0 0040 Lab Matrix Soike DAL SS609R 00110 DAL SS 609R 0 0110 Lab Duoficate DAL SS 609R 0 0110 Lab Matrix Spike
() The. Soi I
Soli Maxtrlx ' G >
Soil Weight Used (g)
8plke ID
Spike Volume
(uL)
Internal Standard
ID
Internal Standard Volume (uL)
Surrogate Spike ID
Surrogate
Spike Volum e (uL)
PFB8 Spike ID
PFB8 Spike Volume (uL)
L-PFHxS 8 pike ID
L-PFHX8 Spike
Volume (uL)
L-PF08 8 pike ID
L-PFOS 8pike
Volume (uL)
Extraction 8otvent
Volume (mL)
Sonicate 1 hr
C e n trif u g e
C o m m e n ts
& 0006-224-
i.ia o
10 005-167
20 10 006-16
& 0005-2249 .... - 1 .1 0 8
10 005-167
50 10 006-16
& 0 006-2247. * 1 1 76 ^
10 005-167
75 10006-16
^ 1 0 0 0 5 3 2 4 ^ _ 1 1-rC
%10 005-224*
1
-`0 - 1 1 3
. 1
10 005-167 10005-166 10 005-166
i n 10006-16 25 10 006-16 5* 10006-16
&1005-224 : 1 1107 0 X 7 -/J 4 = 1 .1 1 2 1 . .
10005-166 10 005-165
x 10006-16 10006-16
.-1 0 006-224
1.1727
10 005-165
10006-16
10 005-224 .
1 'V S?
10 005-165
i n 10006-16
.il60O 5-224"
* 20* ;
10 005-165
10006-16
1 2468 -
10005-224
1 1956
"10005-224
1.1435
10005-2^4
1 1651 M m & m m m m .
10 006-16
A 10005-224 - ' L-f ' . I&10 006-224 < ss 1 1508 f t
10006-16 10006-16
10005-164
X. 10006-16
L i.. .:
.
%1 ) 006-2249 m .1313&
10005-164 10005-164
30 10006-16 30 10006-16
S 10Q 05-Z 43 * T e T i- s 3&1 >QQ6-224i3 w s * s m s m
1005-Z 4S
10005-163 T*
10005-163
30 10006-16 v 10006-16 > . 10006-16
m ms&. m f j . *-i-'
liHillil MlflMI.*1 *B H k --
UK
v /l 3819
mmmmmmmmm M LB C P
>t -
10 005-167
in
-----
10006-16 10006-16 *: 1 10006-16
1.6227
10006-16
. - 1.5079 1 407
10006-16 *- i . /
1 506 7 , 1 342
" s * - ; **.
,, 7-- (V '
'-.ssss, m
1.{56
mmmmmmmmm
t I.
15-6 N
-
m m s m m m I 3l 2
w nm m m m m -
--v~7funifi--fiTy'iiiiiiifff . . 3H1,0< S j. >.1.136 >
017 &
* * s m im tt-
w a a w m s e , ?<" . { M M M I S M H 4 * 444.
1 ^ 3C*-
eM W M ,
9^81^11
e
10006-16 10 006-16 10 006-16 *,, O It 10 006-16 10 006-16 10 006-16 10006-16 10006-16
m m m m s m 9 S 1 344 '-S "T iT iiin rf essassmssssm "5?s1.359< *54
a * 4. -- .
10006-16 :'o r ic
- 1.4539 10611
m m m m sm . ? -\* \
10 006-16 ` . o x 1b
* L V *?
10006-16
" -
10 006-16
15145
10 006-16 10 006-16
' 10 006-16
s m ' 10006-16
V ***
!
. 1.
. -m 1 492-r
10 005-167
* ; 10006-16 m 10006-16 10006-16
ages 10006-16 10 006-16
* " t5 T mmmm
* * 1 3181 m rrm r^ m ii- p m ,, -
1 1-7' W 1 4532
* __ a ................. -
*
*'
10006-16 10006-16 10006-16 10006-16 10006-16
13761 ,
10006-16
I --
isT ss-- 1 1.3569
10006-16 1006-16
1.4652 ! 10 005-167
i n 10006-16
30 30 30 30 30 30 30 30 30 30 30
30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30 30
30 30 30 30 30 30 30 30 30
10005-133 10005-133 10 005-133 10005-133 10005-132 10005-132 10005-132
10 006-2 10 006-2 10 006-2 10 006-2 v 'n r - * -* *
10 X ro " in
50 in
`X
10005-132 10005-132 10005-132 10005-132 10005-132 10005-132 10005-132 10 005-132 10005-132 10005-132 10 005-132 10 005-132 10005-132 10 005-132 10 005-132 10 005-132 10 005-132 10 005-132 10 005-132 10 005-132 10 005-132 10 005-132 10005-132 10005-132 10005-132 10005-132 10 005-132 10 005-132 10 005-132 10 005-132 10 005-132 10 005-132 10 005-132 10005-132 10005-132 10 005-132 10005-132 10 005-132 10 005-132 10005-132 10005-132 10 005-132 10 005-132 10005-132 10005-132 10005-132 10 005-132 10005-132 10005-132 10005-132 10005-132
| :
30 30 30
f. TO
30 V 30 30 30 30 Vi - 30 30 30 30 V 30 V 30 30 30 30 30 X V. M y 30
X
< % 30
30 -* 30 30 30 30 30 30 30
Col 3 & 4: N/A Balance ID: 900
II' I t ' l O
Pipette ID: 3402277
Col 7 & 8: Pipette ID: 3402277
CoM1 & 12: Pipette ID: 3402277
Col & 10: 6 'n lt - /s '- ic >
Pipette 10:3402277
11 M '
IS
V
i, .*
M KM
r
ifeG&mmtMrwa m **- ' '
. ._ ,
m- , *
t* '
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f H .1
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V.
ass
SSSKS8SSSS .
i SM E .. :V i1
ty
mmmmm < m m m sm .
Hi m m *
..... --
- f!W
.. .3 a m t
m ssm if M
<
* M sm & m m sfssssisasfsssss . . . . . . . . . 'w m .'A
_
' .tW S if*
' .8* * * V f
'.
. 1 100 1 ' 4 - n
. " r
40
10 007-3-5
100
I1 0 n 7 - 3 - 5
in
io n
- --
*
io n *e 'IM S * * * 10n7-3-5
in
10n7-4-5 <#*
T 4 5
10 007-4-5
mmmm* 10n7-4-5
11 0 n 7 -4 -5
> 10 X 7 -5 -3
' 9 -v i n 10 X 7
4 40
t i. i n T T ~ -- 17
m sm m m ss
-
in
1 0 X 7 5 "
40
.
wmmmm. -
i n 10X7-5-3
. 40
mmmm
10 0 0 7-3 ^
IX
10n7-4-5
in
.-a .
4'
..............
10n7-3-5
100 1 0 X 7 -4 -5
in
'L x a m - aS M B a .. .
" .
m m ta m m
4 , 4. H4 10n7-3-5 I m
...
1 0 X 7 -4 -5
.
r tV ''".
io n :
__ 10X7-4-5
100
2 ;
*
10X7-5-4 ______ .
50
s a m im s n
****-- 10X7-5-3
10X7 a
50
6 6 6 6 6 6 6 6 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 8 6 8 8 e 8 8 6 6 6 6 6 8 6 8 6 6 6 6 8 6 8 6 8 8 8 8
8 8 8 8 8 8 8 8 8
18 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM -GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM
GPM GPM GPM GPM GPM GPM GPM GPM GPM
Col 1 3 & 14: Pipette ID: 3402277
^ C o l1 7 :6 < *t i / ' / l " / Extraction Solvent ID: 10 006-25
C o in a iB : A ' Pipette ID: 3402277
Col 18: Sonicator ID: QEJ100595003
19 GPV
23
GPV GPM
>
-V
GPM
GPM GPM GPM GPM GPM
"" " _________
"
W m w m m im m m m
GPM GPM
..
_--_--_--_-_- _--_--_--_-_--_--_-_----
GPM
GPM GPM
!...............................
GPM GPM GPM GPM
--S'. , * * * '- ,c
GPM GPM GPM
I
GPM GPM
GPM GPM
GPM GPM
GPM
GPM
GP" GPV
GPM GPM GPV GPV
GPV GPM
GPM GPM
1
GPM GPM GPM GPV GPM GPV GPM
1w M w S jw s M M . Im im m s m m m s m
1m m M m m rn m m m m
GPM GPV GPV
.-
-- -
GPM
GPV GPM
GPV GPV
-- M GPM' GPM GPM
* "s "
-
1
GPM GPM GPM
"" "
GPV
GPV
GPM
Col 19: Centrifuge ID: 021163-55
769613 (for 50mL tubes) 10 min f t 3000 RPM
Sh* l<i
I o o o 2 - `i H
Cm JL-T-Z'I
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
Page 27 of 419
IProject or Study I Description:
1L IM S N um ber: 1A ffected D ata:
Note To File
Decatur Soil Sam pling
Q L ? l o - 0 ) - 0 \- 12. (4cf) C None
/O- Sto\S - Z.OI
On 9/21/10 a bottle order for soil sampling was prepared as follows:
One soil trip blank in a 250 mL Nalgene bottle, closed and sealed with tape, and labeled as Soil Trip Blank. The Soil Trip Blank contains 26.1322g o f 10 003-238 (10 003-238 is an aliquot o f TCR-842). The trip blank was weighed on balance 900 on 9/21/10.
Two 500 mL bottles containing Milli-Q Element water (TN I0-0340) for rinseate samples.
17 empty 250 mL Nalgene bottles (for collecting soil and rinseate samples).
Recorded By: Gabriel P. M cM urtry
< ^ 7^ ^ 1^ "
3M Study: GLP10-01-02 Interim Report 12
Date: 9/21/10 ? i !-/
Page 28 of 419
ENVIRONMENTAL LABORATORY
Sample set ID # Lims #
N/A GLP10-01-01-12
INTERNAL CHAIN-OF-CUSTODY
Sample Internal Transfer
B a c i Copy o f Original
In itia l
D ate
Sample Description: Decatur Soils
INTERNAL CHAIN OF CUSTODY
# 3M Sample IDs Out: storage ID Init./date In: storage ID Init./date Ouf: storage ID
1 GLP10-01-01-12-001 U ( L o l______ 6 0 Y /A z -y g La Z O I
2 GLP10-01-01-12-002
-
3 GLP10-01-01-12-003
4 GLP10-01-01-12-004
C lrj f l- t - t
5 GLP10-01-01-12-005
6 GLP10-01 -01-12-006 7 GLP10-01 -01-12-007
8 GLP10-01-01-12-008
9 GLP10-01-01-12-010
10 GLP10-01-01-12-011 11 GLP10-01-01-12-012 12 GLP10-01 -01-12-013 13 GLP10-01-01-12-014 14 GLP10-01 -01-12-015
Nz _____
I ' ____
-SfcHMa
"Ni
\/ BB
Init./date In: storage ID
/ G rAy / <^i0
M I
mm n a s e j^ v .v.-v. *>}->**
^SSSiBSSB ri& oe m m
wawwMw. BlSVnWH^fttE SPaBSS.S'. `W
mm
ZQW t
. - ,x iiasfiiatjgrcK
..v x tv m
. Ma r a t`U * 4 li
(M W ffil/
SW8SiKSS^.Vl
iQDKS^t'SYrW
M B N T C ,- / r a * f t * w a
21:& r 22
M*"SwwKgsaaRmMSSBBaMrPWtMIefireaRwt1'.*^** r-
fAtSfli -' W 9*
B*. i W 9!
r ; s MB-- i fla s s a s e s s r^ s a g a B M g g
23-rjS B B E U 4ii>w H ia 2m m
^Arfl
aM S W ? fq i
25m
mm1
mm
mm
m m vm m m m sG B M m
m m *
:v->*W M*5Pf M M S g ia M W
Init./date
Comments/lnit/date
a i.:-
ai 4 Ir?" *ir- ',,... * H
St t J W M M S 'i-'" . B a B R iiH M M F * % B B B m M m m s s & r-'f r
Bi
B
B n oe
w
=T
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
Page 29 of 419
GLP10-01-01-12
% Moisture Determination
Sam ple ID
Sample Description
1 GLP10-01 -01 -12-001 GLP10-01-01 -12-001 Dup GLP10-01-01-12-002 GLP10-01-01-12-002 Dup GLP10-01-01-12-003 GLP10-01-01-12-003 Dup GLP10-01-01-12-004 GLP10-01-01-12-004 Dup GLP10-01-01 -12-005 GLP10-01-01-12-005 Dup GLP10-01-01-12-006 GLP10-01-01-12-006 Dup GLP10-01 -01-12-007 GLP10-01-01 -12-007 Dup GLP10-01-01-12-008 GLP10-01-01-12-008 Dup GLP10-01-01-12-010 GLP10-01-01-12-010 Dup GLP10-01-01-12-011 GLP10-01-01-12-011 Dup GLP10-01-01 -12-012 GLP10-01-01-12-012 Dup GLP10-01-01-12-013 GLP10-01-01-12-013 Dup GLP10-01-01-12-014 GLP10-01-01-12-014 Dup GLP10-01-01-12-015 GLP10-01-01-12-015 Dup
2 DAL SS TRIP 0 0000 DAL SS TRIP 0 0000 Lab Duplicate DAL S S 611R 0 0000 DAL SS 611R 0 0000 Lab Duplicate DAL SS 611R 00010 DAL SS 611R 0 0010 Lab Duplicate DAL S S 611R 0 0040 DAL SS 611R 0 0040 Lab Duplicate DAL S S 611R 0 0050 DAL SS 611R 0 0050 Lab Duplicate DAL SS 607R 0 0000 DAL SS 607R 0 0000 Lab Duplicate DAL SS 607R 0 0010 DAL SS 607R 0 0010 Lab Duplicate DAL SS 607R DB 0010 DAL SS 607R DB 0010 Lab Duplicate DAL SS 607R 0 0040 DAL SS 607R 0 0040 Lab Duplicate DAL SS 607R 0 0270 DAL SS 607R 0 0270 Lab Duplicate DAL SS 609R 0 0000 DAL SS 609R 0 0000 Lab Duplicate DAL SS 609R 0 0010 DAL SS 609R 0 0010 Lab Duplicate DAL SS 609R 0 0040 DAL SS 609R 0 0040 Lab Duplicate DAL SS 609R 0 0110 DAL SS 609R 0 0110 Lab Duplicate
Column 3: Balance ID: 908 Initial/Date: ( ft* , l l ' Z ~ / 3
Column 4: Balance ID: 908 Temp o f Oven fC ): 106.3 Oven Time/Date In: 11/2/2010 14:00
Initial/Date: C. r**i II c 1
W eight of W eighing Dish (g)
Initial W eight (soil + Dish) (g)
1st D ete rm in a tio n W eight (soil +
Dish) (g)
Difference (9)
2nd D e te rm in a tio n W eight (soil +
Dish) (g)
Difference
Average %
(g) % M oisture * M oisture
RPD (% M o is tu re )
3 1.3263 1.3217 1.3320 1.3300
4 5 6 7 8 9 10 11
1.9353
f YSCSM
v * v* v V . ' '
1.9949 n i
* . - z iV tf& S M tr *
- - ..
5.6523
-- W it.
m m o u 'i-
4.9165 B S
m s a m . . o t w m e as w s m m
`4 T
,, ' Z tts v & r t 7-
1.3314 1.3287
10.1057 m 10.2558
m
sm
GMBHEHHHBbmShBsSSsI* v m m m
1.3309 1.3334
11.5925 -- 11.7681
m m r n m m i* * ,- -
1.3172
7.8381 B B H H B S l 9 B H H B
m m m m its a u i
1.3284
8.7303
W m # s t# m s r - * u i-
1.3330
6.0085
m am m
1.3259 1.3320 1.3326 1.3302 1.3269
6.9862 5 5 5 6.7811 8.1448 7.0945 4.5300
H R
W aH E BW ff^
s z a & G a n oe HBSsBroS M M N M iSSM M U
n rc *
*
W IB B B y w R & S m . -M HiM sfinlfa'
1.3323 1.3249
4.4704 4.5902
--
a V V * H U R H M K w tm & * * iJ F iW E
t `? -
1.3294
5.6636
~
1.3250
5.8707 I H
H
h h h h S vS S S fflB B B W t
1.3147
5.9027 M M H H H
IH H H H H H i
1.3262 1.3282 1.3270
4.8116 5.9105 6.7619
W BSSBt ttm
HHH
bh
RfiSSBRHBRH &ggmsS&SS& EoeSFsR&l*gY&i^8gpsvi5mRm$r&w
TTHlliirii'TiiT""''
1.3296 1.3247 1.3212
5.6460 4.6847 5.6423
m b M BH 5 M M H M K W t K
HsSphEn SNm * o e m i m r * * 1w m m s fi
V -A B H O n 0 E P T V ,;-.-
1.3243
5.0285 H H H S H M H N5S5)SEi^fii
Column 5: N/A
Column 7: N/A
Oven ID: OV-1 Probe ID: RTD Probe 14
E xact C opy o f Original _______/ f - / 2 - / o
in itia i
D ate
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
Page 30 of 419
GLP10-01-01-12
Sample ID
Sample Description
12
GLP10-01-01-12-001
DAL SS TRIP 0 0000
GLP10-01-01-12-001 Dup DAL SS TRIP 0 0000 Lab Duplicate
GLP10-01-01-12-002
DAL SS 611R 0 0000
GLP10-01-01-12-002 Dup DAL SS 611R 0 0000 Lab Duplicate
GLP10-01-01-12-003
DAL SS 611R 0 0010
GLP10-01-01-12-003 Dup DAL SS 611R 0 0010 Lab Duplicate
GLP10-01-01-12-004
DAL SS 611R 0 0040
GLP10-01-01-12-004 Dup DAL SS 611R 0 0040 Lab Duplicate
GLP10-01-01-12-005
DAL SS 611R 0 0050
GLP10-01-01-12-005 Dup DAL SS 611R 0 0050 Lab Duplicate
GLP10-01-01-12-006
DAL SS 607R 0 0000
GLP10-01-01-12-006 Dup DAL SS 607R 0 0000 Lab Duplicate
GLP10-01 -01-12-007
DAL SS 607R 0 0010
GLP10-01-01-12-007 Dud DAL SS 607R 0 0010 Lab Duplicate
GLP10-01-01-12-008
DL SS 607R DB 0010
GLP10-01-01-12-008 Dup DAL SS 607R DB 0010 Lab Duplicate
GLP10-01-01-12-010
DAL SS 607R 0 0040
GLP10-01-01-12-010 Dud DAL SS 607R 0 0040 Lab Duplicate
GLP10-01-01-12-011
DAL SS 607R 0 0270
GLP10-01-01-12-011 Dud DAL SS 607R 0 0270 Lab Duplicate
GLP10-01-01-12-012
DAL SS 609R 0 0000
GLP10-01-01-12-012 Dud DAL SS 609R 0 0000 Lab Duplicate
GLP10-01-01-12-013
DAL SS 609R 0 0010
GLP10-01-01-12-013 Dud DAL SS 609R 0 0010 Lab Duplicate
GLP10-01-01-12-014
DAL SS 609R 0 0040
GLP10-01-01-12-014 Dud DAL SS 609R 0 0040 Lab Duplicate
GLP10-01-01-12-015
DAL SS 609R 0 0110
GLP10-01-01-12-015 Dud DAL SS 609R 0 0110 Lab Duplicate
Column 3: Balance ID: 908 Initial/Date: N / a
Balance ID: 908 Temp of Oven fC): 106.3 Oven Time/Date In: 11/2/2010 14:00 Initial/Date:
Oven ID: OV-1 Probe ID: RTD Probe 14
3M Study: GLP10-01-02 Interim Report 12
% Moisture Determination
Weight of Weighing Dish (g)
Initial Weight (soil + Dish) (g)
1st Determination Weight (soil +
Dish) (g)
Difference (9)
2nd Determination Weight (soil +
Dish) (g)
Difference % Moisture * (9)
Average % Moisture
3 1.3263 1.3217 1.3320 1.3300 1.3314 1.3287 1.3309 1.3334 1.3172 1.3284 1.3330 1.3259 1.3320 1.3326 1.3302 1.3269 1.3323 1.3249 1.3294 1.3250 1.3147 1.3262 1.3282 1.3270 1.3296 1.3247 1.3212 1.3243
4 1.9353 1.9949 5.6523 4.9165 10.1057 10.2558 11.5925 11.7681 7.8381 8.7303 6.0085 6.9862 6.7811 8.1448 7.0945 4.5300 4.4704 4.5902 5.6636 5.8707 5.9027 4.8116 5.9105 6.7619 5.6460 4.6847 5.6423 5.0285
5 1.9140 1.9728 5.0464 4.4826 9.1710 9.3116 10.4151 10.3114 7.0315 7.7902 5.5654 6.4012 6.0931 7.3089 6.3642 4.1413 3.9632 4.0854 4.7719 4.7468 5.5258 4.5392 5.4428 6.2064 5.2167 4.3728 4.4003 3.9061
6 0.0213 0.0221 0.6059 0.4339 0.9347 0.9442 1.1774 1.4567 0.8066 0.9401 0.4431 0.5850 0.6880 0.8359 0.7303 0.3887 0.5072 0.5048 0.8917 1.1239 0.3769 0.2724 0.4677 0.5555 0.4293 0.3119 1.2420 1.1224
7 1.9157 1.9734 5.0469 4.4833 9.1723 9.3127 10.4165 10.3134 7.0317 7.7908 5.5667 6.4029 6.0963 7.3113 6.3651 4.1425 3.9640 4.0847 4.7726 4.7488 5.5265 4.5404 5.4435 6.2061 5.2175 4.3746 4.4008 3.9098
8 -0.0017 -0.0006 -0.0005 -0.0007 -0.0013 -0.0011 -0.0014 -0.0020 -0.0002 -0.0006 -0.0013 -0.0017 -0.0032 -0.0024 -0.0009 -0.0012 -0.0008 0.0007 -0.0007 -0.0020 -0.0007 -0.0012 -0.0007 0.0003 -0.0008 -0.0018 -0.0005 -0.0037
9 3.22 3.19 14.01 12.08 10.64 10.56 11.46 13.94 12.37 12.69 9.45 10.31 12.57 12.24 12.65 12.10 16.14 15.48 20.56 24.68 8.20 7.78 10.19 10.23 9.93 9.23 28.73 30.20
10 3.21 13.05 10.60 12.70 12.53 9.88 12.40 12.38 15.81 22.62 7.99 10.21 9.58 29.47
RPD (% Moisture)
11 0.77 14.83 0.69 19.53 2.60 8.66 2.68 4.49 4.15 18.23 5.24 0.34 7.29 4.99
Column 5: Temp of Oven fC ): 112.9
Oven Time/Date Out: 11/3/2010 13:20 Oven Time/Date In: 11/3/2010 13:40 Balance ID: 908
Initial/Date:
h3r~ t a
Column 7:
-
Temp of Oven fC ): 112.4
Oven Time/Date Out: 11/3/2010 16:30
Oven Time/Date In: N/A
Balance ID: 908
Initial/Date:
* The last recorded weight is used for the calculation of % moisture. Page 1 of 1
Exact C opy o f O riginal
--O f**In itia l
f aasgeesd,l of 419
Date: n -
Analyst: _
Description:
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 133
- ( 3 sStock Number:
/o ooS
3
W eight or Volume Used:
Concentration or Purity:
Corrected Weight:
Balance ID:
c-
Other Correction Factors:
Solvent and TN -A Number:
,
r^
-, . . i
/
Final Volume: Storage Location:
Final Concentration: Expiration Date:
3M Study: GLP10-01-02 Interim Report 12
Page 32 of 419
Date:
A nalyst:__ _
Description:
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 132_
X
Stock Number:
y o 3 0 (j?
W eight or Volume Used:
Concentration or Purity:
/ /4 s6 \ /
Corrected Weight:
B alance ID:
Other Correction Factors:
Solvent and TN-A
Number: s ^ > o k '
Final Volume:
c S S n o C ___
Storage Location:
Final C o n cen tratio n ^
/,
Expiration Date:
(t
3M Study: GLP10-01-02 Interim Report 12
Page 33 of 419
Description: S /A A 'T lX tx X j f l i t *
Date Prepared:
Prepared By: Storage Location:
/9 -
Expiration Date:
l
M ULTI-CO M PO NENT PREPARATION LOG Book No. 10 006 P age No. ____ 2
AotOSolvent:
3M Trace #: Expiration Date:
/O
Otj '
Description
Standard ID #
10 006-2
Component Standard
ID #
Cone, or Purity
Expiration Date
W eight or V o lu m e
Balance ID
Corrected W eight
Final Concentration
/ Q d C & 'iZ p
3H i
-- if f
o ^ '13 ! y y ?
/v> n V ty L -
--
----------
/ O
?
(o
-
^0
y u)
/
S -------------
Final Volume
Approximate
j v f i L ^ - Concentration of the mix
1/ ] ( --
3M Study: GLP10-01-02 Interim Report 12
Page 34 of 419
D a te Analyst: _
Description:
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 131
m
Stock Number:
-/ O --
O ^ A /!A
W eight or Volume Used: . / / f a J l V t s
y jr y lJ ix d L /
B alance ID:
4 /9 -
Concentration or Purity:
Corrected Weight:
V 'J
Other Correction Factors:
0 , S~Z&
Solvent and TN-A Number:
Final Volume:
J'
Storage Location:
Final Concentration:
A ?A '
Expiration Date:
Exact Copy of Original Initial ' Date
3M Study: GLP10-01-02 Interim Report 12
Page 35 of 419
Date: Analyst:
9" #
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 130
Description:________ / ^ A i A
Stock Number:
0 7 Q ~hS
W eight or Volume Used:
n
O r n - p i4 / - C _
Balance ID:
$ i3 l
Concentration or Purity:
A y /--
Corrected W e ig h t:__________ ^
^ ^ 4/
A
Other Correction Factors:
- W J '
Solvent and TN-A Number-
Final Volume:
Storage Location:
/) 5
Final Concentration: Expiration Date:
i / t y / s u L A .1
Exact Copy of Original Initial : bate
3M Study: GLP10-01-02 Interim Report 12
Page 36 of 419
Date: Analyst:
SINGLE COMPONENT PREPARATION LOG
_____
Description:
L
W
Book No. Page No.
10 005 51
Stock Number: _
I c f i - Q i - O t f - '/i
W eight or Volume Used:
Concentration or Purity:
Corrected Weight:
o. k m j,
B alance ID:
`i n
Other Correction Factors:
0 - lU
solvenlt r AcaJ
Final Volume: Storage Location:
4
Final Concentration:
Expiration Date:
1 -II
Exact Copy of Original - 6<r" _______ / 2 - 3 - / p
Initial " Date
3M Study: GLP10-01-02 Interim Report 12
R e v ie w e d
A
ignature,
) }/o / /o
Date
Page 37 of 419
Date: Analyst:
(
Jfe
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 50
Description: L - P F f l S
Stock Number: _ T c r - M - m o i - Y ,
W eight or Volume Used:
O .\0 T ? j,
Concentration or Purity:
fti l
Corrected Weight:
0 . 0 T7^
Balance ID:
in
Other Correction Factors:
0 . 1 2 9
Solvent and TN -A Number:
A L aL J M
l M M J j-
Final Volume:
Storage Location:
A < r^ 0
Final Concentration:
7 7 /o
Expiration Date:
l- n - u
Exact Copy of Originai
G * '* '___________ /? Z 3 - / C
Initial
Date
3M Study: GLP10-01-02 Interim Report 12
Reviewed
)/l/Q
Date
Page 38 of 419
Date:
- y i- w
SINGLE COMPONENT PREPARATION LOG
Analyst:
P f ( )Description:
f /5 e c f
Book No. Page No.
10 005 48
Stock Number:
Ta i-
W eight or Volume Used:
O .U fK
Balance ID:
9/7
Concentration or Purity:
7v .l 2 ,
Other Correction Factors:
0.9//
O .IO C ^ L
S0,ven' " dX i A ( j S TjJM-CMa-V,,
Final Volume:
Storage Location:
4 s ">
Final C oncentration^ 9 - K Expiration Date:
Exact Copy of Original
_ iv .z rs 'to . D ate
3M Study: GLP10-01-02 Interim Report 12
Reviewed
^j/p j'/O
Date
Page 39 of 419
Date: Analyst:
J fk
SINGLE COMPONENT PREPARATION LOG
Description: P F f l S ( S C F ) S for,(-
Book No. Page No.
10 005 46
Stock Number:
TC -ML
W eight or Volume
f) {H Oj U-
U sed:________ L / v | l
^
Concentration or Purity: _
Corrected Weight:
o. \
m
Balance ID:
117
Other Correction Factors:
o.vi
Solvent and TN-A
Final Volume:
Storage Location:
A c no
Final Concentration:
wo
Tl
Expiration Date:
Y Y i'it
Copy Of Original " 5 5 5 ---------- ----
3M Study: GLP10-01-02 Interim Report 12
Review ed by: Signature,
9 h o / /
Date
Page 40 of 419
S-T 7 0Date:
Analyst:
J/7
SINGLE COMPONENT PREPARATION LOG
Book No. 10 005 Page No. 45
Description:
gC/
Stock Number: f C P - i n
W eight or Volume Used:
Q -R m
Concentration or Purity:
% n l.
Corrected Weight:
o .c tfK j
B alance ID:
9 /7
Other Correction Factors:
Solvent and TN-A
Number: P \ L K / T y ( l ' ) - O % - `>L
Final Volume:
Storage Location:
4 s .7 / )
Final C oncentration^
Wo
Expiration Date:
77H I
j ? c p yo fO rfg /na,
-- J
3M StJaylP10-0f-02 D a t a
Interim Report 12
a l
Review ed by: ( Signature,
7 /0
Date
Page 41 o f 419
Date: Analyst:
K\ ^
Description:
SINGLE COMPONENT PREPARATION LOG
____J
-fazbi- JU//-Stock Number:
-mv7
Book No. Page No.
10 005 37
W eight or Volume Used:
.
Concentration or Purity:
3
r>. I o\Corrected Weight:
Balance ID:
Other Correction Factors:
Solvent and TN -A Number:
.^f J C T O `S'3jf tJ-33
cUSPitX.Final Volume:
Storage Location:
pspo
Final Concentration:
}<3
3 ' -//Expiration Date:
f ^ f c P y o f Origina,
3M Study: GLP10-01-02 Interim Report 12
Date: _ Analyst: _
Description:
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 36
P if ) A -
Concentration or Purity:_
Corrected Weight: _
0. W j A
Balance ID:
Other Correction Factors:
6 -9 3 8
Solvent and TN -A Number:
3 /j>
Final Volume: Storage Location:
Final Concentration:
"T 9
--
A i* / / y jis C _
c/ '
Expiration Date:
o f Origina/
Irm i--
Dai
3M Study: GLP10-01-02 Interim Report 12
Reviewed byr
Oh
Signature,
TJ
g /io !/o
Date
Page 43 of 419
SINGLE COMPONENT PREPARATION LOG
k Date: / 1 / V 7
Analyst:
.-T) /
Book No. Page No.
10 005 244
Description:
So
m: Stock Number: ~ r p jc - <SYK
M ,'
W eight or Volume Used:
/ S S '.
Concentration or Purity:
Corrected Weight: J S 1 . 7 7 ^ 7
Balance ID:
Other Correction Factors:
Solvent and TN-A Number:
Final Volume: Storage Location:
Final Concentration:
Expiration Date:
S '/ Q > ~ / /
Exaet Copy o f Original
-- G f ? - -------------- t e t a - y o
3M Study: GLP10-01-02
D ate
Interim Report 12
R eview ed by: Signature,
Date Page 44 of 419
I
fcCi i S jYhDescription:
Y
Date Prepared: / O
S f)
P*1
Prepared By: Storage Location:
_______
r
Expiration Date:
" //
M ULTI-CO M PO NENT PREPARATION LOG
Book No. 10 006
Page No.
16
Solvent: _ s O 3M Trace K / lW o Q " O O fr ! Expiration Date: ' Y " S " / " * /
tr
r Description
5P V S
rn p fH y S , 'p it ? f t
//)< ?
Standard ID #
10 006-16
Component Standard
ID #
Cone, or Purity
Expiration Date
W eight or V olu m e
Balance ID
Corrected W eig h t
Final Concentration
)b O p " / Y
Y - L ? -// 3 iy -
------------
-- 0-/0/
jo c o Y '/ f r ^
St 3
----
O . /o o
S o t o s '- i l o
<7 ^ jh u Y ,
V ?. f*
/ O S - )-Y (
1
c5 ^ *
-- O . W f
-- 0 .0 9 9 7
S
" 0
0
E ^ ^ (W o f o p i n a i
L i 2 *A > udy: GLP10-0 0 a 2 e
Interim Report 12
Final Volume
Approximate Concentration of the mix
0 - 1 / jA < l
.
Reviewed by:
Signature,
Date Page 45 of 419
M ULTI-CO M PO NENT PREPARATION LOG
Book No. 10 006
Page No.
25
Description:
O r * ).-
Date Prepared:
//
~ /0
Prepared B y:_______________________________
Storage Location:_______ / Q < T
" )_________
Expiration D a te :______ A > ~ / 0 ? ~ ~ / j ______
Solvent: 3M Trace # i Expiration Date:
71
Description /7 7 /V /iO -
Standard ID #
10 006-25
Component Standard Cone, or
ID # Purity
Expiration Date
W eight or Volume
Balance ID
Corrected W eig h t
Final Concentration
%
lN )o ' 6 ^
/( o d *j l
-- jt > %
' 'fr J iO ' > y y /
lo o
--
J? o %
.... ^
~ P
y|C)
A
.. I
t*
-X
Final Volume
A IL
Approximate
Concentration of the mix $ d : o
E xact Copy o f Original
C t r l ________^ - - ^ 3 ^ /
Pa*e3M^Study! GLP10-01-o
Interim Report 12
Review ed by:
Signature,
1 2 ,'Z rs .'! >
Date
Page 46 of 419
Date. | Q - \ 7 - - 1 0 Analyst: C J t3
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 168
Description:
I % 0 HL P F & S
Stock Number:
|0 7-~ )
W eight or Volume Used:
E n t i r e A m r v f i u V C ____________
B alance ID :_________^ O Q
Concentration or Purity: _
9>(o ja g t in n L
%I. 2Corrected Weight:
Other Correction Factors:
0 ,9
. i
Solvent and TN-A Number:
Final Volume:
I - *2- ip n L
Storage Location:
Final Concentration:
^ 1 -2 ja g lm L .
Expiration Date:
3 "*9 ^ /5
3M Study: G LP 10-W Interim Report 12
Page 47 of 419
Date: \ D - ) 2 - ~ ) 0
Ana|yst: C iTf
SINGLE COMPONENT PREPARATION LOG
Description:
FC M t O f A V "
I
Book No. 10 005 Page No. 167
Stock Number: l 0 0 0 S - I ig jg1
W eight or Volume Used:
. I T P t-
Concentration or Purity:
0.
Corrected Weight:
B alance ID:
Other Correction Factors:
Solvent and T N -A / t e c h m i + r i Number: T N t O - Q O ^ l - " ) T L
Final V o lu m e :_ I D m l
IV5 1 PStorage Location:
Final C o n c e n tra tio n ^ O . D \ U g t Y \ L
Expiration D a te :_ `U 1 M ' t >
Exact Copy of Original
iffleH m R eport '12 0 3 t 8
R e v ie w e d
Signatui
/a s z 5 ~ y a
Page 48 of 419
Date: i Q - I Z - I O
Analyst: C X 0
SINGLE COMPONENT PREPARATION LOG
Book No. 10 005 Page No. 166
Description:
U n e a f FC M ix
Stock Number: _ \ 0 D O S - I L f> 5
W eight or Volume Used:
I VY\ L-
Concentration or Purity:
Corrected Weight:
Balance ID:
Other Correction Factors:
Solvent and TN -A /Q - c t L f D n 1 " t r i \_ Number: T t J / - c o z i - i r / ) 2 _
Final Volum e:_ I P m L Storage Location:
Final Concentration:
A
Im L
Expiration Date:
Date: l Q - | ? - - ) D Analyst: C J ( 3_____
SINGLE COMPONENT PREPARATION LOG
Description: L \ Y i t ( \ Y FC M U
Book No. 10 005 Page No. 165
Stock Number: IOOQ(p-~~7
W eight or Volume Used:
\m b
Concentration or
t oPurity: _
Corrected Weight:
Balance ID:
Other Correction Factors:
Solvent and TN -A Ace't'O Y\ \ t Y \ )6 Number: T N 10-OOfSI - U ln .
Final Volume:
lOtrvoL
Storage Location: _ a s n o
Final Concentration:
j
Expiration Date:
'2 - ' 2 -*-/ " t1
??5 * o r o n g e
tm a l
3M Study: GLP10-01-02 Interim Report 12
Date: | D ~ \ " 2 -- I O
CJjfoAnalyst:
SINGLE COMPONENT PREPARATION LOG
Book No. 10 005 Page No. 164
Description:
E rC -^ r F C M I X
Stock Number:^ 1 0 0 0 5 - I [ p %
W eight or Volume Used:
\
L
Balance ID:
Concentration or Purity:
\ -O
v r\ L
Other Correction Factors:
Corrected W e ig h t:_______
~ ________ ______________________
Solvent and TN -A ^
^ ^
Number: T ~N I - Q ^ t - ^ 1 1 X
Final Volume: _
ID m i
Storage Location:
fre n o
Final Concentration:______ @ ^
1YY\ L
Expiration Date:
'Z ~ 7 ^ Li~ l I
3M Study: GLP10-01-02 Interim Report 12
Page 51 o f 419
f~CDescription: L l Kl \ ( A f
M IX
D ate Prepared: I Q - l ^ - j P __________
Prepared By: C T G ? _____________________
Storage Location: Expiration Date:
A 5 ~ 7 O ___________________
Z ~ Z H ~ I t________
MULTI-COMPONENT PREPARATION LOG
Book No. 10 006
Page No. ____ 7
Solvent: A-cetpQi t r i l&
3M T ra c e #: T N I 0 - & 8 1 ~ n / l Z Expiration Date: L i - ~ i ~ l H
Description pFBS
L - P FHyS
PF A L- PFO S
Standard ID #
10 006-7
Component Standard
ID # 1 0 0 0 5 -^ 5
Cone, or Purity
vw o, IA \ln a O
Expiration Date II
z - V 'A
W eight or V olu m e
Balance ID
Corrected W eig h t
Final Concentration
----
l O S 5 1 1 0 005-3"?
M IS O lA g lw rL
lu
k
M 13D | A 0 1 vi L
2-Z M -l l
p O .^ ia L
--
--
-- ; D O j u O j I m L -- ^ fA U n i
10005- S O
3 l IO
Z -Z l'll t f y L
-- ji itn L
'--
.
Copy Of O rignal
Initial
3M Study: GLP10-01-02 Interim Report 12
Final Volume
A pp ro xim ate y S m L Concentration of the mix / 0 / u j l k V t L
Reviewed by:,.
/< 5
Date
Page 52 of 419
Date: I O - ) "2 - I D
Analyst:
CSG>
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 163
Description:
E D F F~ C - M I %
Stock N umber: _ I 0 0 0 > - . g
W eight or Volume Used:
\ W tL .
Concentration or Purity:
IQ
Corrected Weight:
Balance ID:
Other Correction Factors:
Solvent and TN -A A C C -T d fV + T l C Number: T K I P ' ' 0 0 % I - * M 17_
Final Volum e: _ ____ i O m i Storage Location: _
Final Concentration:_______ I b A . 0 I IT I L
Expiration Date.
"2-~
~ II
Exact.Copy of Original
Initial
Date
3M Study: GLP10-01-02 Interim Report 12
MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. ____ 8
Description: C F F C . M I A _________
D ate Prepared: I 0 ~ 12 - ) O _____________
Prepared By:
C J S C b __________________
Storage Location: A 5 1 0__________
Expiration Date: _ 2 - 2 4 - I I ________________
Solvent:
T r1 1 .
3M Trace #: T N W - ( ) C %
I'Z -
Expiration Date: 4 ~ 1 ~ / M _________
Description
PFBS ,
P F H S CecfO PFo a ( ^ c f ) PFDS C ecf)
#Standard ID
10 006-8
Component Standard
ID #
Cone, or Purity
Expiration Date
W eight or V o lu m e
Balance ID
Corrected W eig h t
Final Concentration
1 0 0 05 -45 3 i 40 2-21-11 |nr<-
--
--
jv i0 w L
4250
J
1000*5 -3L0 3 ^ 1 0
2 - 2 7 'U Sg-SpiL 2 - 2*-) -11 3 0 | jL
--
-- 10-0 pLglmL -- 0.0 /vujJnoL
1ODO<5-H0> 5 1 5 0 2 - 2 1 'M H 3 .5 ^ L --
-- |O O |u 0 /m L
A jr
'2 ^ .
Exact Copy of original
in ita l
D a ti"
3M Study: GLP10-01-02 Interim Report 12
Final Volume
Approximate Concentration of the mix
/O^A^lyviL
Date Page 54 of 419
Date: | 0 - L Z " | O Analyst: C J 6
Description:
SINGLE COMPONENT PREPARATION LOG
Book No. Page No.
10 005 169
Stock Number:
S
W eight or Volume Used:
rrH re A m pu
____________
B alance ID:
Concentration or Purity:
5 0 /v A O lm l-
Corrected Weight:
3 fiA 0l>ViL
Other Correction Factors:
O .^ ^ L o
Solvent and TN -A Number:
Final Volume: [ . X r Y t L
Storage Location:
h S IO
Final C oncentration^ H 1 - Z
Expiration Date:
iC '2 ~ I~ ILI
Date: iO - 1 7 , - i n
Analyst: CXG?_____
SINGLE COMPONENT PREPARATION LOG
Book No. 10 005 Page No. 170
Description: _
PFO A
Stock Number: T G R O * ' ? - O O t C j - 3 / | q
W eight or Volume
.
Used: h n t i / V l T D p U * G __________
Balance ID:
^ 100
Concentration or Purity: _
/u g /m L
Corrected Weight: M ^ ; 0 ) p i l m L
Other Correction Factors:
O - cI ^ ^
Solvent and TN -A Number:
Final Volume:
\- 'L YY* L
Storage Location: f t
P
Final Concentration:
HZ ^
t
Expiration Date:
I " 2-~2-- I *2-
^< 2 2 C<?py of Original
1 ... -- JZ~2"y--*.
In,bal
D ate"
3M Study: GLP10-01-02 Interim Report 12
Page 56 of 419
Date: i D -1 X ~ ) O
Analyst: C5(b
SINGLE COMPONENT PREPARATION LOG
Book No. 10 005 Page No. 171
Description:
NA^> P P O ^
Stock Number: T C
0 0 *5 1" S /15
W eight or Volume Used:
E n f i f f * / N t Y l p l A U ^ __________
B alance ID :_______ O
Concentration or Purity: _
50
Corrected Weight:
Ml %
Other Correction Factors:
O .M 5 7
Solvent and TN -A Number:
1 '2- m iFinal V o lu m e :_ ____
Storage Location:
A S1
Final Concentration:
y i - f t fiA) m L
Expiration D ate:_ l - 3 - / M
Exact Copy of Original
ln,bal
- I Q - jo
"Date
3M Study: GLP10-01-02 Interim Report 12
Reviewed I
Page 57 of 419
Description: f r S Date Prepared:
Storage Location: /9_-gT
MULTI-LEVEL PREPARATION LOG
Book No. 10 007
Page No.
3
Solvent: - Y M Y --
Standard ID #
10 007-3-1
Description
Component Standards
Description
ID #
Cone
Expiration Date ^
fP rZ^
P?6S fh S
/o S /o o a -h - 3 ~ t
/ OC - c f " , 3
_ _ _ _ _ --------------------------------------------
/ *> , * 1 tA yJ
- eP ? *V f
/
Std 1
C@0
10 007-3-2 <=>?
Std 2
-------- -
10 007-3-3 10 007-3-4 10 007-3-S 10 007-3-6
S y jT "
Amount of Component Standard Added
10 007-3-7 10 007-3-8; /
/
Std 3
--
Std 4
Std 5
-------------
. ---------
Std 6
s t d ^ Std 8
D
yA~*J> n 4
T*,?
/ /> n
/ 7'
F'inai Volume Final Concentration
/ > / ~ C . f /> U - / rv d -- /O
/ 0 ^ y-
/, oo --. / >/'%j/ry U ... .......... r y
o . / > o 0 - O / o o
------- - 3/ -------:-_--_--_-_--_--_---- er----------------------------------------------------------------
Description
Standard ID #
Description Component Standards
ID # Cone
Expiration Date
10 007-3-9 10 007-3-10 10 007-3-11 10 007-3-12 10 007-3-13 10 007-3-14 10 0 0 7 - 3 ^ -T0M 7-3-16
Std 9
Std 10
Amount of ComponentStafiSard Added
Std 11^- - ^ t d 1 2
Std 13 Std 14
Std 15
Std 16
!"
3M Study: GLP10-01-02 Interim Report 12
_--
^ jW
,, -- ''navlum e
Fi nal Concentration
o r ig
* K
Reviewed by: Signature,
Page 58 of 419 Date
Description: / . Date Prepared:
Prepared By:
_______ --/ Q ____
________
Storage Location: Expiration Date:
MULTI-LEVEL PREPARATION LO(
Book No. 10 007
Page No. ___ 4
f ) 5G tG ______________ Solvent:
_______ ___
j? - p /______________3M Trace #: G loO Jr- /\ to I
Standard ID #
Description Component Standards
10 007-4-1
/
10 007-4-2
P
10 007-4-3 10 007-4-4 10 007-4-5 10 007-4-6
3 y 3~
Amount of Component Standard Added
10 007-4-7
10 007-4-9
//
Expiration
/ ---------
Description t r fih h S
ID# /o o o 'o 'S 'l
/ oco 1 - V',3
Cone
Date
Off < 7 ^^ - * / * * / , ! ,* w ,,
Std 1
Std 2 -------
Std 3 --------
---
Std 4 ---------
/AL1
Std 5
Std 6 Std 7 / Std 8
= / P1----------
(n /
-G
--
F"inai Volume
Final Concentration (
/ {\jy>U\ ^ 9
JO
9.9 y
/o .99 9
// o J O -
. 09?f O .c& tf*}
r
Description
Standard ID #
Description Component Standards
_ ID#
Cone
Expiration Date
10 007-4-9 10 007-4-10 10 007-4-11 10 007-4-12 10 007-4-13 10 007-4-14 10 007-4-15 _Jt0'tfO7-4-16
Std 9
Std 10
Amount of Component Standgcd-Adcied Std 11 S ic H - 2 ^ Std 13 Std 14
Std 15
Std 16
- - --g g *
y~ -p p '
B aw C opy of o rig in a ,
(fudy: GLP10-I Interim Report 12
Fimri'Voiume^ Final Concentration
Reviewed by: Signature,
/ l r /z-- U Date
Description: / \ Date Prepared: / o '-*?/?> --/7 D
Storage Location:
R ii W H K
MULTI-LEVEL PREPARATION LOG
Book No. 10 007
Page No.
5
Solvent:
____________
Description L 'f f o S
C-
L - P to 's
Standard ID #
10 007-5-1
Description Component Standards
ID # Cone
Expiration Date
/ Std 1
/ o o f 'S b 3 c/ / o / ^ - n n ! 0 D O l - / J O D ^ c j^ 3 ' i- I l
P
) b D O l ' ' 3 ) 0o/ ` iU . J
Final Volume C 1 ^ 3
/
Final Concentration
1nul-- /O D
10 007-5-2
cZ
10 007-5-3 10 007-5-4 10 007-5-5 10 007-5-6
3 3?~ Amount of Component Standard Added
10 007-5-7
10 007-5-8
/ /
Std 2 -------
/ /D . O
Std 3 -- /O O ^
/O /. oo
Std 4 ------- -
-
jo o O jtL
iS
. J*>o
Std 5
Std 6
Std 7 / ^ S t d 8
/U X
/o / ). OoO /
c,[f 7/ J/ 0
/3
Description
Standard ID #
Description Component Standards
ID # Cone
Expiration Date
10 007-5-9 10 007-5-10 10 007-5-11 10 007-5-12 10 007-5-13 10 007-5-14 10 007-5-1ji-H'0 00 7-5-1 6
Std 9
Std 10
Amount of Component Standard AddcT Std 11 Std 12 ^ s ta ^ fi Std 14
Std 15
Std 16
s ' I3
"I
7 I
/"
-
Exact Codv n fn -.-. .
iL S m o in a ^nrtjflttrim Report '
5 a ie
^ F inaV oum e Final Concentration
Reviewed by: Signature,
-- Page sn of a i q ) f ' 'L ' D Date
DATA REVIEW SUMMARY FORM
Date:
12/23/2010
Data Analyst: GPM
Study #:
GLP10-01-02-12
Description: Decatur Soils
Batch:
s 101119a
Results Table: sl01119a.rdb
Instrument: Stan V1660305
Method(s):
ETS-8-053.0
Analyte:
PFBS
Comments/Justifications:
Acceptable Linear Range:
Internal Standard:
LOO:
0.500 ng
1 0.500 ng to 200 ng MPFBS
Data Review Sign-Off
Analyst Review and Acceptance of M anual Integrations
Comments / Justifications: 1 Lowest curve point was dropped because it was not 2x the area counts o f the method blanks with IS and surrogate.___________________________________
A n aly te:
PFHxS
Comments/Justifications:
Acceptable Linear Range:
Internal Standard:
LOO:
0.200 ng
N/A 0.200 ng to 200 ng MPFHxS
A n aly te:
PFOS
Comments/Justifications:
Acceptable Linear Range:
Internal Standard:
LOQ:
0.200 ng
N /A _____________ 0.200 ng to 200 ng M8PFOS________
A n aly te:
M PFOS
Comments/Justifications:
Acceptable Linear Range:
Internal Standard:
LOQ:
0.200 ng
N/A_____________ 0,200 ng to 200 ng M8PFOS
Analyte:
N/A_____________
Comments/Justifications: N/A
Acceptable Linear Range: N/A
Internal Standard:
N/A
LOQ:
N/A_____________
3M Study: GLP10-01-02 Interim Report 12
Pa9e 1 of 1 Page 61 o f 419
Stan: API4000: V1660305
DATE 11/19/10
ANALYST: GPM
STUDY NUMBER: E l0-01-02-12 Matrix: Soils
Injection volume: 25 uL
Electrode: Turbo ion spray
Mobile Phase: (A)2 mM ammonium acetate (B) acetonitrile TN-A- or standard number (A) 10 010-16 (TT) tn10-0180-3/8
page 1/1
Guard (pre-autosampler) column Prism RP
Size: 2.1 mm X 50 mm__________ Type: C12 Sphere size: 5______
Part number: 32105-052130 Lot number: 9411 Serial number 0903542V
Analytical column 1 Oasis HLB
Size: 3 X 20 mm________ Type: NA
Sphere size: 25 um
Part number: 186002039 serial number: 006A300055105 03
Analytical column 2 Betasil C l8
Size: 2.1 mm X 100 mm_________ Type: C l8 Sphere size: 5______
Part number: 70105-102130 Lot number: 10559 Serial number 0701663T
Printed: Friday, November 19, 2010 12:17 PM
3M Study: GLP10-01-02 Interim Report 12
\Page 62 of 419
ETS Stan V1660305
Project: P:\Lab_lnstrument Data\Stan\Stan Data Files\Projects\fluorochemicals\soil Batch:s101119a Tab:Sample Set:SET01 AcqMethod:ets8-53 23 min Sulfonates Sample
S a m p le N am e
S a m p le ID
1 s101119a001 10 006-25 solvent blank 2 s101119a002 10 006-25 solvent blank 3 s101119a003 10 006-25 solvent blank 4 ,s101119a004 10 006-25 solvent blank 5 s101119a005 10 006-25 solvent blank 6 s101119a006 10 006-25 solvent blank 7 s101119a007 10 006-25 solvent blank 8 s101119a008 10 006-25 solvent blank 9 s101119a009 Warm Up EC-101117-07 10 ng 10 s101119a010 WarmUp EC-101117-07 10 ng 11 s 101119a011 WarmUp EC-101117-07 10 ng 12 s 101119a012 ' 10 006-25 solvent blank 13 s101119a013 10 006-25 solvent blank 14 (s101119a014 10 006-25 solvent blank 15 F siO l119a015 EC-101117-01 0.2 ng Extracted Curve Point 16 s101119a016 EC-101117-02 0.5 ng Extracted Curve Point 17 ,s101119a017 EC-101117-03 0.75 ng Extracted Curve Point 18 s 1 0 i119a018 EC-101117-04 1 ng Extracted Curve Fbint 19 s101119a019 EC-101117-05 2.5 ng Extracted Curve Point 20 s101119a020 ;EC-101117-06 5 ng Extracted Curve Point 21 s101119a021 ,EC-101117-07 10 ng Extracted Curve Point 22 1s101119a022 EC-101117-08 25 ng Extracted Curve Point 23 s101119a023 EC-101117-09 50 ng Extracted Curve Point 24 s101119a024 ,EC-101117-10 100 ng Extracted Curve Point 25 Is101119a025 *EC-101117-11 200 ng Extracted Curve Point 26 s101119a026 10 006-25 solvent blank 27 s101119a027 10 006-25 solvent blank 28 |s101119a028 ! 10 006-25 solvent blank 29 ;s101119a029 110 006-25 solvent blank 30 ^1011198030 ,MB--101117-01 Method Blank 1 w /o IS 31 is101119a031 jM B -1 0 1 117-02 Method Blank 2 w /o IS 32 s101119a032 ' MB--101117-03 Method B la n k 3 w /o IS 33 s101119a033 'M B -1 0 1 117-04 Method Blank 4 w / IS 34 s101119a034 M B -1 0 1 117-05 Method Blank 5 w / IS 35 s101119a035 MB--101117-06 Method B la n k 6 w /IS 36 s101119a036 LCS-101117-01 3 ng LCS in TCR-842 37 s101119a037 ]LCS-101117-02 3 ng LCS in TCR-842 38 s101119a038 i LCS-101117-03 3 ng LCS in TCR-842 39 s101119a039 ILCS-101117-04 30 ng LCS In TCR-842 40 s101119a040 ;LCS-101117-05 30 ng LCS in TCR-842 41 s101119a041 \ LCS-101117-06 30 ng LCS In TCR-842 42 s101119a042 110 006-25 solvent blank 43 s101119a043 EC-101117-05 2.5 ng Extracted Curve Point 44 s101119a044 10 006-25 solvent blank 45 s101119a045 :GLP10-01-01-12-001 DAL SS TRIP 0 0000 46 s101119a046 GLP10-01-01-12-001 Oup DAL SS TRIPO 0000 Lab Duplicate 47 s101119a047 GLP10-01-01-12-001 LMS DAL SS TRIP 0 0000 Lab Matrix Spike 48 s101119a048 GLP10-01-01-12-002 DAL SS 6 1 1R0 0000 49 s101119a049 GLP10-01-01-12-002 Dup DAL SS 611R 0 0000 Lab Duplicate 50 s101119a050 ;GLP10-01-01-12-002 LMS DAL SS 611R 0 0000 Lab Matrix Spike 51 :s101119a051 GLP10-01-01-12-003 DAL SS 611R0 0010 52 s101119a052 GLP10-01-01-12-003 Dup DAL SS 611R0 0010 Lab Duplicate 53 s101119a053 GLP10-01-01-12-003 LMS DAL SS 611R 0 0010 Lab Matrix Spike 54 s101119a054 10 006-25 solvent blank 55 js101119a055 | EC-101117-06 5 ng Extracted Curve Point 56 s101119a056 10 006-25 solvent blank 57 s101119a057 GLP10-01-01-12-004 DAL SS 611R0 0040 58 ' s 101119a058 'GLP10-01-01-12-004 Dup DAL SS 611R 0 0040 Lab Duplicate 59 s101119a059 ` GLP10-01-01-12-004 LMS DAL SS 611R 0 0040 Lab Matrix Spike 60 s101119a060 GLP10-01-01-12-005 DAL SS 611R 0 0050 61 i s 101119a061 GLP10-01-01-12-005 Dup DAL SS 611R 0 0050 Lab Duplicate
V ia l P o sitio n
In j.V o lu m e
D a ta File
C o m m en ts
(Ml)
91 s101119a 25.000
91 s101119a 25.000
91 s101119a 25.000
91 s101119a 25.000
91 s101119a 25.000
92 s101119a 25.000
92 s101119a 25.000
92 s101119a 25.000
7 s101119a 25.000
7 s101119a 25.000
7 s101119a 25.000
92 s 101119a 25.000
92
s101119a 25.000
|
93 s101119a 25.000
1 s101119a 25.000
2 s101119a 25.000
3 "s 101119a 25.000
4 s 101119a 25.000
5 s101119a 25.000
6 s101119a 25.000
7 s101119a 25.000
8 s101119a 25.000
9 s101119a 25.000
10 s101119a 25.000
11 s101119a 25.000
93 s101119a 25.000
93 s101119a 25.000
93 s101119a 25.000
94 s 101119a 25.000
12 s 101119a 25.000
13 s101119a 25.000
14 s 101119a 25.000
15 s101119a 25.000
16 s 101119a 25.000
17 s101119a 25.000
18 s101119a 25.000
19 s101119a 25.000
20 s 101119a 25.000
21 s 101119a 25.000
22 s101119a 25.000
23 s101119a 25.000
94 s101119a 25.000
5 s101119a 25.000
95 s101119a 25.000
24
s101119a 25.000
____________
25 s101119a 25.000
26 s101119a 25.000
27 s101119a 25.000
28 s101119a 25.000
29 s101119a 25.000
30 s101119a 25.000
31 s101119a 25.000
32 s101119a 25.000
95 s101119a 25.000
6 s101119a 25.000
96 s101119a 25.000
33 s101119a 25.000
34 s 101119a 25.000
35 s101119a 25.000
36 s101119a 25.000
37 s 101119a 25.000
Printing Date: Friday, November 19, 2010
Page 1 of 2
Printing Time: 12:18:02 PM
3M Study: GLP10-01-02 Interim Report 12
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ETS Stan V1660305
Acquisition Information:
Acquisition Method: Created: Last Modified: Content: Synchronization Mode: Auto-Bquilibration: Acquisition Duration: Nuirber Of Scans: Periods In File: Acquisition Module: Software version Agilent I Pump Method Properties Purp Model: Minimum Pressure (psi): Maximum Pressure (psi): Dead Volume (pi): Maxinun Flew Ranp (ml/min2): Maximum Pressure Rarrp (psi/sec):
ETS 8-53 23 min Sulfonates.dam Friday April OS 2010 12: 54: 09 EM Friday April OS 2010 15: 54: 27 EM Method for Sulfonates 23 minute gradient IC Sync Off 23min0sec 2281
1
Acquisition Method Analyst 1.4.2
Agilent 1100 LC Binary Purp
0.0
5801.0 40.0
100.0
290.0
Step Table: Step Total Time (min)
C 0.00
1 3.00
2 3.50 2 17.00 4 17.50 c 19.50
6 20.00 7 23.00
Flew Rate (pl/min) 400 400 400 400 400 400 400 400
A (%) 97.0 97.0 70.0 40.0 10.0 10.0 97.0 97.0
B (%) 3.0 3.0 30.0 60.0 90.0 90.0 3.0 3.0
Left Compressibility: 50.0
Right Carpressibility: 115.0
Left Dead Volume (pi): 40.0
Right Dead Volume (pi): 40.0
Left Stroke Volume (pi):
Right Stroke Volume (pi):
Left Solvent:
A1
Right Solvent:
B2
-1.0 -1.0
Agilent Autosarrpler Properties
Autosampler Model:
Agilent 1100 Thermo Autosarrpler
Syringe Size (|il):
100
Injection Volume (pi): 25.00
Draw Speed (pl/min): 200.0
Eject Speed (pl/min): 200.0
Needle Level (rm\):
0.00
Temperature Control Enabled
Setpoint (4 - 40 C): 10
Wash is not used
Use Custcm Injector Program
No
Agilent Column Oven Properties
Left Temperature (C):
30.00
Right Temperature (C): 30.00
Tarperature Tolerance +/- (C):
1.00
Start Acquisition Tolerance +/- (C):
0.50
Time Table
(Used) .
Column Switching Valve Installed
Position for first sample in the batch: Right
Use same position for all samples in the batch
Total Time (min)
Valve Position
O.OC Left
5.0C Right
Period 1:
Scans in Period:
2281
Relative Start Time: 0.00 msec
Experiments in Period: 1
Period 1 Experiment 1:
Scan Type: Polarity: Scan Mode: Ion Source: Resolution Ql: Resolution Q3: Intensity Thres.: Settling Time: MR Pause:
MPM (MRM) Negative N/A Turbo Spray Unit Unit 0.00 cps 0.0000 msec 5.0070 msec
Printing Date: Friday, November 19, 2010
Printing Time: 12:18:34 PM
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 3
6^
,Pag
Io
'419
ETS Stan V1660305
MCA: No .Step Size:
0.00 aim
Q1 Mass (amu) 399.0C
Q3 toss (amu) 99.00
Dwell (msec) 50.00
Parair DE CE CXF
Start Step -100.00-100.00 -54.00 -54.00 -5.00 -5.00
Q1 Mass (amu) 399.0C
Q3 toss (amu) 80.00
Dwell (msec) 50.00
Pararr DE CE CXF
Start Stop -100.00 -100.00 -82.00 -82.00 -5.00 -5.00
Q1 Mass (amu) 403.0C
Q3 toss (aim) 84.00
Dwell(msec) 50.00
Parair DE CE CXE
Start Stop -100.00 -100.00 -82.00 -82.00 -5.00 -5.00
Q1 Mass (amu) 299.0C
Q3 toss (aim) 99.00
Dwell (msec) 50.00
Pararr DE CE CXE
Start Step -65.00 -65.00 -44.00 -44.00 -15.00 -15.00
Q1 toss (amu) 299.0C
Q3 toss (aim) 80.00
Dwell (msec) 50.00
Pararr DE CE CXE
Start Step -65.00 -65.00 -64.00 -64.00 -5.00 -5.00
Q1 toss (amu) 303.0C
Q3 toss (amu) 84.00
Dwell (msec) 50.00
Pararr DE CE CXF
Start Stop -65.00 -65.00 -64.00 -64.00 -5.00 -5.00
Q1 toss (aim) 499.0C
Q3 toss (aim) 80.00
Dwell (msec) 50.00
Pararr DE CE CXE
Start Step -120.00 -120.00 -98.00 -98.00 -5.00 -5.00
Q1 toss (aim) 499.0C
Q3 toss (aim) 99.00
Dwell (msec) 50.00
Pararr DE CE CXF
Start Step -120.00-120.00 -82.00 -82.00 -5.00 -5.00
Q1 toss (amu) Q3 toss (amu)
499.0C
130.00
Dwell (msec) 50.00
Pararr DE CE CXE
Start Step -120.00 -120.00 -66.00 -66.00 -7.00 -7.00
Q1 Mass (amu) Q3 toss (amu)
503.0C
80.00
Dwell (msec) 50.00
Pararr DE CE CXF
Start Stop -120.00 -120.00 -98.00 -98.00 -5.00 -5.00
Q1 toss (aim) 507.0C
Q3 toss (amu) 80.00
Dwell (msec) 50.00
Parair DE a CXF
Start Stop -120.00-120.00 -98.00 -98.00 -5.00 -5.00
Parameter Table (Period 1
CAD:
6.00
CUR:
35.00
GS1:
45.00
GS2:
60.00
IS: -4500.00
TEM:
450.00
ihe:
CN
EF -10.00
Experiment
1):
Printing Date: Friday, November 19, 2010
Printing Time: 12:18:34 PM
3M Study: GLP10-01-02 Interim Report 12
. '
Page 2 of 3
Page 65 of 419
ETS Stan V1660305
Printing Date: Friday, November 19, 2010
Printing Time: 12:18:34 PM
3M Study: GLP10-01-02 Interim Report 12
Page 3 of 3
Page 66 of 419
ETS Stan V1660305
Project: P:\Lab_lnstrument Data\Stan\Stan Data Files\Projects\fluorochemicals\sol Batch:s101119a Tab:Samp1e Set:SET01 AcqMethod:ets8-53 23 min Sulfonates Sample
.
S a m p le N a m e
S a m p le ID
V ial Pos ition
D ata File
I n j. V o l u m e (pi! C o m m e n t s
1 s101119a001 10 006-25 solvent blank
91
2 s101119a002 10 006-25 solvent blank
91
3 s101119a003 10 006-25 solvent blank
91
4 s101119a004 10 006-25 solvent blank
91
5 s101119a005 10 006-25 solvent blank
91
6 s101119a006 10 006-25 solvent blank
92
7 s101119a007 10 006-25 solvent blank
92
8 s101119a008 10 006-25 solvent blank
92
9 s101119a009 'W arm Up EC-101117-07 10 ng
7
10 s101119a010 Warm Up EC-101117-07 10 ng
7
11 s101119a011 'W arm Up EC-101117-07 10 ng 12 s101119a012 10 006-25 solvent blank
7
92
13 s101119a013 10 006-25 solvent blank
92
14 s11119a014 10 006-25 solvent blank
93
15 s 101119a015 EC-101117-01 0.2 ng Extracted Curve Paint
1
16 s101119a016 EC-101117-02 0.5 ng Extracted Curve Paint
2
17 s101119a017 EC-101117-03 0.75 ng Extracted Curve Paint
3
18 s101119a018 EC-101117-04 1 ng Extracted Curve Paint
4
19 s101119a019 EC-101117-05 2.5 ng Extracted Curve Paint
5
20 s 101119a020 ,EC-101117-06 5 ng Extracted Curve Paint
6
21 ls 1 0 lil9 a 0 2 1 EC-101117-07 10 ng Extracted Curve Paint
7
22 s101119a022 EC-101117-08 25 ng Extracted Curve Paint
8
23 s101119a023 , EC-101117-09 50 ng Extracted Curve Paint 24 s 101119a024 .EC-101117-10 100 ng Extracted Curve Paint
9
10
25 s101119a025 EC-101117-11 200 ng Extracted Curve Point
11
26 s 101119a26 10 006-25 solvent blank
93
27 s101119a027 10 006-25 solvent blank
93
28 s 101119a28 10 006-25 solvent blank
93
29 s101119a029 , 10 006-25 solvent blank
94
30 s101119a030 .MB--101117-01 Method Blank 1 w /o IS
12
31 s101119a031 MB--101117-02 Method B la n k 2 w /o IS
13
32 !s 101119a032 MB-- 01117-03 Method Blank 3 w l o IS
14
33 's101119a033 M B -1 01 117-04 Method Blank4 w / IS
15
34 s101119a034 M B -1 0 1 117-05 Method Blank 5 w / IS
16
35 ;s101119a035 jMB--101117-06 Method B la n k 6 w / IS
17
36 |s101119a036 1LCS-101117-01 3 ng LCS In TCR-842
18
37 s 101119a037 ;LCS-101117-02 3 ng LCS In TCR-842
19
38 :s 101119a038 LCS-101117-03 3 ng LCS in TCR-842
20
39 s101119a039 LCS-101117-04 30 ng LCS In TCR-842
21
40 is101119a040 LCS-101117-05 30 ng LCS In TCR-842
22
41 :s101119a041 !LCS-101117-06 30 ng LCS in TCR-842
23
42 s 101119a042 110 006-25 solvent blank
94
43 s 101119a043 EC-101117-05 2.5 ng Extracted Curve Paint
5
44 s 101119a044 10 006-25 solvent blank
95
45 s101119a045 GLP10-01-01-12-001 DAL SS TRIP0 0000
. 24
46 s101119a046 GLP10-01-01-12-001 Dup DAL SS TRIP0 0000 Lab Duplicate
25
47
s101119a047 GLP10-01-01-12-001 LMS DAL SS TRIP0 0000 Lab Matrix Spike
26
48 s101119a048 GLP10-01-01-12-002 DAL SS 611R 0 0000
27
49 s101119a049 GLP10-01-01-12-002 Dup DAL SS 611R 0 0000 Lab Duplicate
28
50 s101119a050 GLP10-01-01-12-002 LMS DAL SS 611R 0 0000 Lab Matrix Spike 29
51 s101i19a051 GLP1-01-01-12-003 DAL SS 6 1 R 0010
^ 30
52 s101119a052 GLP10-01-01-12-003 Dup DAL SS 611R 0 0010 Lab Duplicate
31
53 s101119a053 GLP10-01-01-12-003 LMS DAL SS 611R 0 0010 Lab Matrix Spike 32
54 s101119a054 10 006-25 solvent blank
95
55 s101119a055 EC-101117-06 5 ng Extracted Curve Point
6
56 s 101119a056 10 006-25 solvent blank
96
57 s101119a057 GLP10-01-01-12-004 DAL SS 611R 0 0040
33
58 s101119a058 GLP10-01-01-12-004 Dup DAL SS 611R 0 0040 Lab Duplicate
34
59 s 10119a059 GLP10-01-01-12-004 LMS DAL SS 611R 0 0040 Lab Matrix Spike 35
60 s101119a060 GLP10-01-01-12-005 DAL SS 611R 0 0050
36
Printing Date: Thursday, December 23, 2010
s101119a s101119a s101119a s101119a s101119a s 1 0 1 119a s 101119a s101119a s101119a s101119a s 1 0 1 119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s 101119a s 101119a s101119a s101119a s 1 0 1 1 19a s101119a s 101119a s101119a s101119a s101119a s 101119a s 101119a s101119a s101119a s101119a s101119a s101119a s101119a s 1 0 1 119a s 101119a s 101119a s 101119a s101119a s101119a s101119a s101119a s101119a s 101119a s101119a s101119a 31011193 s101119a s 1 0 11 1 9a
25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000
I
Page 1 of 2
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3M Study: GLP10-01-02 Interim Report 12
Page
19
T Z '*'0
ETS Stan V1660305
Project: P:\Lab_lnstrument DatatStan\Stan Data Files\Projects\fluorochemicals\soil Batch:s1011t9 a Tab:Sampfe Set:SET01 AcqMethod:ets8-53 23 min Sulfonates
Sample
''
''
:
S a m p le N a m e
S a m p le ID
V ia l P os ition
D a ta File
i In j.V o lu m e (pi) C o m m e n ts .
61 :s 101119a061 GLP10-01-01-12-005 Dup DAL SS 611R 0 0050 Lab Duplicate
37
62 s101119a062 GLP10-01-01-12-005 LMS DAL S S 6 1 1R 0 0050 Lab Matrix Spike 38
63 s101119a063 GLP10-01-01-12-006 DAL SS 607R 0 0000
39
64 s101119a064 GLP10-01-01-12-006 Dup DAL SS 607R 0 0000 Lab Duplicate
40
65 s101119a065 GLP10-01-01-12-006 LMS DAL SS 607R 0 0000 Lab Matrix Spike 41
66 s101119a066 10 006-25 solvent blank
96
67 s101119a067 EC-101117-05 2.5 ng Extracted Curve Point
5
68 's101119a068 110 006-25 solvent blank
97
69 s101119a069 'GLP10-01-01-12-007 DAL SS 607R 0 0010
42
70 s101119a070 GLP10-01-01-12-007 Dup DAL SS 607R 0 0010 Lab Duplicate
43
71 s101119a071 GLP10-01-01-12-007 LMS DAL SS 607R 0 0010 Lab Matrix Spike 44
72 s101119a072 ;GLP10-01-01-12-008 DAL SS 607R DB 0010
45
73 s 101119a073 1GLP10-01-01-12-008 Dup DAL SS 607R DB 0010 Lab Duplicate
46
74 :s 101119a074 GLP10-01-01-12-008 LMS DAL SS 607RDB 0010 Lab Matrix Spike 47
75 !s101119a075 1GLP10-01-01-12-010 DAL SS 607R 0 0040
48
76 s101119a076 :GLP10-01-01-12-010 Dup DAL SS 607R 0 0040 Lab Duplicate
49
77 s101119a077 |GLP10-01-01-12-010 LMS DAL SS 607R 0 0040 Lab Matrix Spike 50
78 |s10H 19a078 110 006-25 solvent blank
97
79 s101119a079 EC-101117-06 5 ng Extracted Curve Fbint
6
80 's101119a080 10 006-25 solvent blank
98 .
81 s 101119a081 |GLP10-01-01-12-011 DAL SS 607R 0 0270
51
82 ;s101119a082 |GLP10-01-01-12-011 Dup DAL SS 607R 0 0270 Lab Duplicate
52
83 Ss101119a083 .GLP10-01-01-12-011 LMS DAL SS 607R 0 0270 Lab Matrix Spike 53
84 :s 101119a084 ;GLP10-01-01-12-012 DAL SS 609R 0 0000
54
85 s101119a085 GLP10-01-01-12-012 Dup DAL SS 609R 0 0000 Lab Duplicate
55
86 Is101119a086 .GLP10-01-01-12-012 LMS DAL SS 609R 0 0000 Lab Matrix Spike 56
87 !s 101119a087 |GLP10-01-01-12-013 DAL SS 609R 0 0010
57
88 js101119a088 GLP10-01-01-12-013 Dup DAL SS 609R 0 0010 Lab Duplicate
58
89 s101119a089 GLP10-01-01-12-013 LMS DAL SS 609R 0 0010 Lab Matrix Spike 59
90 ,s10l119a090 ; 10 006-25 solvent blank
98
91 ;s101119a091 EC-101117-05 2.5 ng Extracted Curve Fbint
5
92 s10H 19a092 j 10 006-25 solvent blank
99
93 ;s 101119a093 |GLP10-01-01-12-014 DAL SS 609R 0 0040
60
94 s101119a094 GLP10-01-01-12-014 Dup DAL SS 609R 0 0040 Lab Duplicate
61
95 T s i0 1 119a095 GLPiO-01-01-12-014 LMS DAL SS 609R 0 0040 Lab Matrix Spike 62
96 Sl01119a096 ,GLP10-01-01-12-015 DAL SS 609R 0 0110
63
97 ,s101119a097 ,GLP10-01-01-12-015 Dup DAL SS 609R 0 0110 Lab Duplicate
64
98 Is101119a098 ' GLP10-01-01-12-015 LMS DAL SS 609R 0 0110 Lab Matrix Spike 65
99 s101119a099 10 006-25 solvent blank
99
100 js101119a100 EC-101117-06 5 ng Extracted Curve Point
6
101 i s 101119a 101 : 10 006-25 solvent blank
99
s101119a s101119a s101119a s101119a s101119a s101119a s 101119a s 1 0 11 1 9a s101119a s101119a s101119a s101119a s101119a s 101119a s101119a s101119a s 101119a s101119a s 1 0 11 1 9a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s101119a s 1 0 11 1 9a s 1 0 11 1 9a s 101119a s 1 0 11 1 9a s101119a s101119a s101119a s101119a s101119a
25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000 25.000
'
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Printing Date: Thursday, December 23, 2010
Printing Time: 1:56:23 PM
3M Study: GLP10-01-02 Interim Report 12
Page 2 of 2
Page 68 of 419
Stan VT660305 3M Environmental Lab
Results Name: sl0lll9a.rdb
Sample Name
S am ple ID
1 s101119a001 10 006-25 solvent blank
? U $101119a002 Tl0 006-25 solvent blank
3
1
5f
eT
s101119a003 s"019a04 s101119a005 s101119a006
T l0 006-25 solvent blank
f i o 006-25 solvent blank
110 006-25 solvent blank
M 0 006-25 solvent blank
'
7 " s101119a007 M0 006-25 solvent blank
8 I s101H9a008 M 0 006-25 solvent blank
9 7 s101119a009 W arm Up EC-101117-07'10 ng
10 s101119a010 W arm Up EC-101117-07 10 ng
" s101119a011 W arm Up EC-101117-07 10 n g"
12 si il19 12 7To"o06-25 solvent blank
"
"
13 s 0 1 l9 a 0 3 "M 0 006-25 solvent b la n k .......................................
14 s101119a014 M 0 006-25 solvent blank
15" s101119a015 (EC-101117-01 0.2 ng Extracted Curve Point
16; s101119a016 (EC-101117-02 0.5 ng Extracted Curve Point
1 7 / s101119a017 EC-101117-03 0.75 ng Extracted Curve Point
1 8 ; s101119a018 EC-101117-04 1 ng Extracted Curve Point
19 ; s10lTl9a19" EC-101117-O5 2.5 ng Extracted Curve Point
20 j s101119a020 EC-101117-06 5 ng Extracted Curve Point
. 1 s101119a021 i EC-101117-07 10 ng Extracted Curve Point
22 s101119a022 EC-101117-08 25 ng Extracted Curve Point
73 Sl01119a023 "ECM01117-09 50 ng Extracted Curve Poinf
2 4 " s101119a024 EC-101117-10 100 ng Extracted Curve Point
s101119a025 lEC-101117-11 200 ng Extracted Curve Point
$101119a026 M0 006-25 solvent blank
s0119a027' i 10'006-25'^lvenTbla'nk
simM M0 006-25 solvent blank
""
S101119a029 M0 006-25 solvent blank
s101119a030 MB--101117-01 Method Blank 1 w/o IS
s1 01 19 a0 3 iM i P 10111f-C 2 Method Blank 2 w/o IS
s101119a032 iM B --101117-03 Method Blank 3 w/o IS
s101119a033 M B -1 0 1 117-04 Method Blank 4 w / IS
s101119a034 MB-101117-05 Method Blank 5 w /IS " "
sT01119a035 iM B --101117-06 Method Blank 6 w / IS
s101119a036 i LCS-101117-01 3 ng LCS in TCR-842
s101119a037 5LCS-101117-02 3 ng LCS in TCR-842
s101119a038 | LCS-101117-033 ng LC S ln ' fCR-842 "
'
s101119a039 LCS-101117434~30 ng LCS in TCR-842
"
s101119a040 >LCS-1011 i 7-5 3 ng LCS in TCR-842.........
s101119a041 L C S -1 0 ili7 ^ O 6 3 0 r i g i n TCR-842.........
s101119a042 MO 006-25 s e le n i blank
s11119a043 1 E C M 0 7 -0 5 2.5 ng Ejrtracfed CuTve Point
s101119a044 10 006-2.5...s..o..l.v..e..n...t..b..l.a..n..k.......................................
s101119a045 GLP10-01-01-12-001 DAL SS TRIP 0 0000
4C s101119a046 GLP10-01-01-12-001 Dup DAL SS TRIP 0 0000 Lab Duplicate
47 s101119a047 GLP10-01-01-12-001 LMS DAL SS TRIP 0 0000 Lab Matrix Spike
48 s101119a048 iG LP10-0 4 D -2-002 DAL SS 6 R
49 s101119a049 G LP10-01-01 -12-002 Dup D l SS 6 1 R 0 0 Lab Duplicate
50 s101119a050 GLP10-01-01-12-002 LMS DAL SS 611R 0 0000 Lab Matrix Spike
51 s101119a051 GLP10-01-01-12-003 DAL SS 611R 0 0010
52 s101119a052 GLP10-01-01-12-003 Dup DAL SS 611R 0 0010 Lab Duplicate
53 s101119a053 GLP10-01-01-12-003 LMS DAL SS 611R 0 0010 Lab Matrix Spike
54 s101 9 a 05 4 10 006-25 solvent blank
Analyte
Peak Name
Sam ple Type
MPFOS 'Double Blank
MPFOS [Double Blank :<
MPFOS 1Double Blank ;
MPFOS" [Double Blank i
MPFOS Double Blank ?
MPFOS : Double Blank 1
MPFOS Double Blank s
MPFOS ?Double Blank >
MPFOS dJnknown
;
MPFOS {Unknown
1
MPFOS {Unknown
?
MPFOS -Double Blank :
MPFOS Double Blank ;
MPFOS Double Blank ;
iM PFO S i Standard
iM PFO S Standard
MPFOS Standard
iM PFO S Standard
IM P F O S " 'S tandard
MPFOS Standard
iM PFO S Standard
MPFO S Standard
iM PFO S Standard
iM PFO S Standard
iM PFO S Standard
iM PFO S Double Blank
IMPFOSTM ^Double Blank
IMPFOS Double Blank \
M PFO S {Double Blank i
MPFOS Double Blank ;
MPFOS (Double Blank j
MPFOS (Double Blank i
iM PFO S } Unknown
i
MPFOS Unknown
j
MPFOS Unknown
:
MPFOS Quality Control i
IMPFOS Quality Control
iM PFO S Quality Control ;
MPFOS Quality Control i
MPFOS Quality Control ;
IMPFOS Quality Control ;
IMPFOS Double Blank ;
MPFOS Quality Control ;
MPFOS Double Blank '
MPFOS Unknown
\
MPFOS (Unknown
|
MPFOS Unknown
s
iM PFO S (Unknown
;
M PFOS" Unknown
t
MPFOS Unknown
iM PFO S Unknown
MPFOS Unknown
MPFOS Unknown
{
iM PFO S [Double Blank j
Rl H El El E3 El El El El El El
3 g| ^ 0 *] g]
g|
Analyte J J ! 2 L Analyte Ie _
Concentration
Peak Are*. ' Peak
(ng/mL)
(min) <counts>
IS Peak Area
IS w c n trw M
(ng/mL)
Retention Time (min)
Calculated Concentration
(ng/mL)
Accuracy
.0.00 0 00 0.00 0.00 0.00 O.OO 0.00 0.00 N/A iN /A N/A 0.00 0.00 0.00 0.200 0.500 0.750 1.00 2.50 5.00 10.0 25.0 50.0 100. 200. 0.00 0.00 0.0Q 0.00 0.00 0.00 0.00 N/A N/A N/A 3 00 3.00 3.00 3.00 3.00 3.00 0.00 2.50 0.00 IN/A N/A N/A N/A N/A j N/A N/A N/A N/A 0.00
13 437 434 13.437 i 73 13.477 48 13.114 97 13.397 12 13.437 48 13 185 48 13.346 24 13.942 146138 13.447 M57037 13.467 144194 M3.346 24
0.000 To "
M3.235 48 i 13.276 13595 13.346 8365 13.407 i 10278 13.276 14563 13.326 35725 13.346 73466 13.346 151003 13.346 390847 13.346 767703 13.316 1458209 13.316 2620797 13.336 593 13.346 109 13.316 85 13 326 61 M 3 .2 7 6 " 61
M3.205" 112 ~
M3.518 36 13.306 43424 13l306~ 50273
713:256 48833"
13.276 47527 13.266 148180 13.276" 151957" 13.306 47952 13.256 48046 13.245 51545 13.225 36 13.306 39200 13.548 24 13.266 39719 13.256 40531 13.276 143218 13.245 47538 13.225 i45877 13.225 45188 13 235 (54231 13.245 46122 13.235 i 49366 13.155 1145
M8PFOS 1311 M8PFOS [36 M8PFOS 121 M8PFOS 48 M8PFOS v` 5 M8PFOS 73 M 8PFO S 185 i M8PFS 148 {M8PFS j45782 M8PFOS [45529 M8PFOS j44089 M 8 P F O S M 8P FO S " M8PFOS [12 IM8PFOS 40648 IM8PFOS 47549 M8PFOS 46085 M8PFOS 43658 M8PFOS 42890 M8PFOS 45468 M8PFOS 45313 M8PFOS 47113 M8PFOS 48640 IM8PFOS 45951 M8PFOS 41364 M8PFOS 24 M8PFOS 61 M8PFOS 48 M8PFOS 36 M8PFOS 36 M8PFOS 48 M8PFOS 73 M8PFOS 49524 IM8PFOS 51856 IM8PFOS 47599 M8PFOS 50504 M8PFOS 47987 M8PFOS 48326 M8PFOS 45479 M8PFOS 45541 M8PFOS 50818 M8PFS "33 IM8PFOS 45216 M8PFOS 24 M8PFOS 139489 M8PFOS 42310 " M8PFOS 45627 M8PFOS 45662 M8PFOS 47248 M8PFOS 150538" M8PFOS 50018 (M8PFOS 49885 M8PFOS 147256 iM'ePFOS i 4
N/A IN/A iN /A ;N/A iN /A N/A ;N/A N/A 2.98 12.98 2.98 N/A ] n/a "
Tn/'a"'
2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.96 2.98 N/A j N/A 1N/A I N/A |N/A
[N/
N/A 2.98 ]2.98 " 2.98 12.98 2 98 12.98 12.98 2.98 [2.98
Tn/a~
Z98~
;N/A [2.98
2798
12.90 2.98 2.96 ;2~98~ 2.98 52.98 72198" iN/A "
.13.4 133 13.2 13.2 113.5 13.2 13.3 T3.3 13.9 13.5 13.5 113.2 j 13.3 13 M "" 13.4 3l4 " 13.4 13.4 13.3 13.3 13.4 13.3 13.3 13.3 13.2 13.3 13.4 13.2 13.3 13.4 13.3 13.4 13.3 13.3 13.3 13 3 13 3 13.3 13.3 13.3 13.2 ~M3l3 13.3 13.5 13.3 13.3 13.3 13.3 13.2 13.3 13.2 13.3 113.3 13.4
N/A N/A N/A N/A
IN/A
N/A N/A
Tn/a '
19.87
tl0l7..
j 1M....
j N/A jN/A" "
'Wa_..
" f0.224"" ""i0.496 ` '"i'0"642""
"|o:'98i""
"E '54""" j 4.97"...
I1.3..
25.8 49.2 99.4 200. N/A "" N/A "N /A ~ ;N/A N / " N/A N/A 2.67 2.96 3 14 2.87
I33I.0279""
3.23 3 23 3.10 N /A" 2.64 N/A 3.07 2.93 2.89 3.18 2.97 2.73 3.32 2.82 3.20 "N/A
.N/A I N/A I N/A iN /A N/A iN/A iN /A iN/A iN/A iN/A N /A " 7 n/a ~ Tn/a IN/A
T12.
99M" 85.6 198.1
i 101.
99.4 103. 103. 198.4 994 100. iN/A" N/A N/A N/A N/A N/A N/A N/A N /A" N/A 95.8 102.
110
108. 108. 103. N /A ' 106?" N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 7n / a ~
s101119a.wiff s101119a.wiff
s 1 0 1 1 1 9 a .w if f
is 1 0 9 a .w iff s0119alwiff is101119a.wiff
s101119a.wiff
s01119a.w iff
s 1 0 1 1 1 9 a .w if f
is101119a.wiff
s 1 0 1 1 1 9 a .w if f
QL is101119a.wiff Is101119a.wiff
is 1 0 1 1 1 9 a .w if f
isoTl9a.w iff" s 1 0 11 19 a .w if f
s101119a.wiff s 1 0 1 1 1 9 a .w if f
is101119a.wifi :sl0 1 1 1 9 a .w iff
:s101119a.wiff s 1 0 11 19 a .w if f
is10T19.wiff s 1 0 1 1 1 9 a .w if f
s101119a.wiff s 1 0 11 19 a .w if f
is101119a.wiff" j "s101119a7wiff i :s101119a.wiff 's0119a.wi1T is101119a.wiff
s 1 0 11 19 a .w if f
;s101119a.wiff
is 0 9 a .w iff ;s101119a.wiff
s101119a.wiff
is101119a.wiff s 1 0 1 1 1 9 a .w if f
s101119a.wiff s101119a.wiff
JP
1
i i
s 1 0 1 1 1 9 a .w if f s101119a.wtff " si01119a.wfff ' s 1 0 1 1 1 9 a .w if f s101119a.wiff '
TsiTiTTwiF'
s101119a.wiff
_n
r r i
j
j
is 1 0 1 1 1 9 a .w if f is101lT9a.wiff " is101119a.wiff ` s101119a.wiff '
"s101119a.wiff "ls10~1119a.wiff `
s101119a.wiff
Printing Date: Thursday, December 23, 20 10 Printing Time: 1:23:17 PM
Page 1 of 8
3M Study: GLP10-01-02 Interim Report 12
,-Page 69 of 419
12 -2 -1 -7 0
Stan VI660305 3M Environmental Lab
Results Name: sl01119a.rdb
:Sam ple Nanu
Sample ID
Analyte Peak Name
Sam ple Type
Use Record
Analyte Concentration
(ng /m L )
Analyte
Retention Time
; (min)
rX . (counts)
>
Name
IS Peak Area
(counts)
IS Concentration
(ng/mL)
IS Retention
Time (min)
Calculated Concentration
(n g /m L )
Accuracy c*
Record M o d ifie d
File Name
55 is101119a055 56 is101119a056 57 is10V 9a057 58 is101119a058 59 is101119a059 160 is101119a060 61 is10111961 62 is101119a062 63 :s101119a063 64 ;s101119a064 [65 is101119a065 66 s101119a066 [67 s101119a067 168 $101119a068 69 is101119a069 17 is101119a070 171 s101119a071 172 is101119a072
is101119a073 P74 is101119a074 [75 is101119a075 [76 is101119a076 77 is101119a077 78 is101119a078 179 s101119a079 180 Is101119a080
is101119a081 I 81 <82 :s101119a082 ! 83 is101119a083 84 is101119a084 [85 is101119a085 [86 is101119a086 87 's101119a087 188 is101119a088 89 is101119a089 90 ' Is101119a090 91 Is101119a091 92 :s101119a92 93 Is101119a093
94 is101119a094
is101119a095 196 s101119a096 m =s101119a097 98 Is101119a098 |99 is101119a099 100 is101119a100 101 Is101119a101 102 !s101119a001 103 i$101119a002 104 is101119a003 105 is101119a004
106 :s101119a005 107 -!s101119a006 108 is101119a007
EC-101117-06 5 ng Extracted Curve Point 10 006-25 solvent blank G LP 10-01-01-12-004 DAL SS 611R 0 0040 G LP 10-01-01-12-004 Dup DAL SS 611R 0 0040 Lab Duplicate GLP 10-01-01-12-004 LMS DAL SS 611R 0 0040 Lab Matrix Spike G LP 1(H>141-12-05 DAL S S 611R 5 G LP 1-01-01-12-5 Dup DAL. SS 61 IR 0050 Lab Duplicate GLP 10-01-01-12-005 LMS DAL SS 611R 0 0050 Lab Matrix Spike GLP 10-01-01-12-006 DAL S S 607R 0 0000 GLP 10-01-01-12-006 Dup DAL SS 607R 0 0000 Lab Duplicate GLP 10-01-01-12-006 LMS DAL SS 607R 0 0000 Lab Matrix Spike 10 006-25 solvent blank EC-101117-05 2.5 ng Extracted Cune Point 10 006-25 solvent blank GLP 1001-01-12-007 DAL SS 607R 0 0010 GLP 10-01-01-12-007 Dup DAL SS 607R 0 0010 Lab Duplicate GLP 1001-01-12-007 LMS DAL SS 607R 0 0010 Lab Matrix Spike G L P C W ^ V 2 -0 0 8 DAL SS 67R DB 1 GLP 10-01-01-12-008 Dup DAL SS 607R DB 0010 Lab Duplicate GLP 10-4)1-01-12-008 LMS DAL SS 607R DB 001 la b Matrix Spike GLP1001"-01-12-010 DAL S S 607R 0 0040 GLP 10-01-01-12-010 Dup DAL SS 67R 0 0040 Lab Duplicate GLP 10-01-01-12-010 LMS DAL SS 607R 0 0040 Lab Matrix Spike 10 006-25 solvent blank EC-101117-06 5 ng Extracted Curve Point 10 006-25 solvent blank GLP 10-01-01-12-011 DAL S S 607R 0 0270 GLP10-01-01-12-011 Dup DAL SS 607R 0 0270 Lab Duplicate GLP 10-01-01-12-011 LMS DAL SS 607R 0 0270 Lab Matrix Spike GLP10-01-01-12-012 DAL S S 609R 0 0000 GLP10-01-01-12-012 Dup DAL SS 609R 0 0000 Lab Duplicate GLP10-01-01-12-012 LMS DL SS 609R 0 0000 Lab Matrix Spike G LP10-01-01-12-013 DAL S S 609R 0 0010 G LP10-01-01-12-013 Dup DAL SS 609R 0 0010 Lab Duplicate G LP10-01-01-12-013 LMS DAL SS 609R 0 0010 Lab Matrix Spike 10 006-25 solvent blank EC-101117-05 2.5 ng Extracted Cune Point 10 006-25 solvent blank GLP10-01-01-12-014 DAL S S 609R 0 0040 G LP10-01-01-12-014 Dup DAL SS 609R 0 0040 Lab Duplicate G LP10-01-01-12-014 LMS DAL SS 609R 0 0040 Lab Matrix Spike G LP10-01-01-12-015 DAL SS 609R 0 0110 G LP10-01-01-12-015 Dup DAL SS 609R 0 0110 Lab Duplicate GLP 1-01-01 -12-015 LMS DL SS 69R O li Lab Matrix Spike 10 006-25 solvent blank EC-101117-06 5 ng Extracted Curve Point 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank
MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS 'MPFOS" MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS PFBS PFBS PFBS PFBS PFBS PFBS PFBS
Q uality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank
E l 5.00 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00
1 2.50 . N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00
E l 5.00 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00
E l 2.50 .00 N/A N/A N/A N/A N/A N/A 0.00
E l 5.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00
13.215 13.377 13.256 13.235 13.225 13.225 13.145 13.235 13.205 13.205 13.215 0.000 13.195 13.084 13.235 13.205 13.225 13.235 13.215 13.235 13.215 13.205 13.215 13.488 13.215 13.558 13.205 13.235 13.245 13.215 13.215 13.215 13.215 13.225 13.215 13.407 13.225 13.266 13.225 13.195 13.235 13.215 13.215 13.225 13.165 13.215 13.215 7.949 7.969 7.909 7 929 7.980 7.808 7.919
84157 24 45697 47342 51799 54453 51231 54997 55264 51077 51693 0 33363 48 55322 53688 47694 48145 49863 50373 52129 50251 47830 36 80148 24 45410 51218 49223 47286 50880 51801 40808 50417 48157 12 40762 12 51641 53303 49836 48169 51702 50346 36 81407 157 180 268 278 22 1949 1474 1573
M 8 P F O S I 45977 M8PFOS 12 M8PFOS 46823 M8PFOS 51822 M8PFOS 48917 M8PFOS 46463 M8PFOS 49233 M8PFOS 43687 M8PFOS 52007 M8PFOS 47756 M8PFOS 49626 M8PFOS 85 M8PFOS 47766 M8PFS 24 M8PFOS 46133 M8PFOS 50663 M8PFOS 49390 M8PFOS 52224 M8PFOS 49573 M8PFOS 50192 M8PFOS 50881 M8PFOS 47225 M8PFOS 48180 M8PFOS 12 M8PFOS 46132 M8PFOS 61 M8PFOS 43437 M8PFOS 52840 M8PFOS 47128 M8PFOS 47268 M8PFOS 51849 M8PFOS 50262 M8PFOS 40990 M8PFOS 51446 M8PFOS 47760 M8PFOS 36 M8PFOS 50118 M8PFOS 24 M8PFOS 48154 M8PFOS 49804 M8PFOS 49765 M8PFOS 54137 M8PFOS 53248 M8PFOS 49908 M8PFOS 0 M8PFOS 50728 M8PFOS 109 MPFBS 36 MPFBS 97 MPFBS 0 MPFBS 36 MPFBS 0 MPFBS 48 MPFBS 0
2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98' 2.98 2.98 2.98 N/A 2.98 N/A 2.96 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2 98 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.96 2.98 2.98 N/A 2.98 N/A N/A N/A N/A N/A N/A N/A N/A
13.3 13.3 13.2 13.3 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.3 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.2 13.5 13.2 13.3 13.2 13.2 13.2 13.2 13.2 13.2 0.00 13.2 13.2 8.04 8.09 0.00 8.02 0.00 8.17 0.00
5.64 N/A 2.98 2.79 3.24 3.59 3.18 3.86 3.25 3.27 3.19 N/A 2.12 N/A 3.68 3.24 2.95 2.81 3.07 3.07 3.13 3.26 3.03 N/A 5.35 N/A 3.20 2.96 3.19 3.06 3.00 3.15 3.04 2 99 3.08 N/A 2.48 N/A 3.26 3.28 3.06 2.71 2.97 3.08 N/A 4.94 N/A N/A N/A N/A N/A N/A N/A N/A
113. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 84.8 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 107. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 99.1 N/A N/A N/A N/A N/A N/A N/A N/A 98.7 N/A N/A N/A N/A N/A N/A N/A N/A
s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wi1T s101119awiff s101119a.wiff s101119a.wiff s101119a.wi1T s101119a.wiff s101119a,wiff s101119a.wiff s101119a.wiff s101119a.wiff
s101119a.wiff s101119a.wiff s101119a.wifT
s101119a.wiff
s101119a.wiff s101119a.wiff s101119a.wiff
s019a.w iff
s101119a.wiff s101119a.wiff s101119a.wiff
s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff
n s101119a.wiff
s101119a.wifF s101119a.wi1T s101119a.wiff s101119a.wiff s101119a.wiff s101119a.witf
s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff
Printing Date: Thursday, December 23, 2010 Printing Time: 1:23:17 PM
Page 2 of 8
3M Study: GLP10-01-02 Interim Report 12
Page 70 of 419
Stan VI660305 3M Environmental Lab
Results Name: sl01119a.rdb
Sample Name .
S am ple 10
:109 is10119a008 10 006-25 solvent blank
110 s101119a009 Warm Up EC-101117-07 10 ng
; 111 is101119a010 Warm Up EC-101117-07 10 ng
f 112 s101119a011 Warm Up EC-101117-07 10 ng
1113 s101119a012 10 006-25 solvent blank
,114 s101119a013 10 006-25 solvent blank
115 s 1 0 9 a 4 10 006-25 solvent blank
i 116 Is101119a015 EC-101117-01 0.2 ng Extracted Curve Point
117 is101119a016 EC-101117-02 0.5 ng Extracted Curve Point
1118 ?s101119a017 EC-101117-03 0.75 ng Extracted Curve Point
` 119 s101119a018 EC-101117-04 1 ng Extracted Curve Point
i 120 s101119a019 EC-101117-05 2.5 ng Extracted Curve Point
<121 s101119a020 EC-101117-06 5 ng Extracted C un Point
'122 is101119a021 EC-101117-07 10 ng Extracted C u r Point
123 Is101119a022 EC-101117-08 25 ng Extracted Curve Point
124 s101119a023 EC-101117-09 50 ng Extracted Curve Point
125 Js101119a024 EC-101117-10 100 ng Extracted Curve Point
12$ s101119a025 EC-101117-1 i 200 ng Extracted Curve Point
127 s101119a026 10 006-25 solvent blank
128 : is101119a027 10 006-25 solvent blank
129 ' :s101119a028 10 006-25 solvent blank
1130 s101119a029 10 006-25 solvent blank
<131 is101119a030 MB--101117-01 Method Blank 1 w /o IS
!r12 is101119a031 MB--101117-02 Method Blank 2 w/o IS
133 Is101119a032 MB--101117-03 Method Blank 3 w /o IS
134 is101119a033 M B -1 0 1 117-04 Method Blank 4 w1 1S
135 is101119a034 M B -1 0 1 117-05 Method Blank 5 w / IS
136 1s101119a035 M B -1 0 1 117-06 Method Blank 6 w/ IS
1137 i$ 10 9 a 3 6 LCS-i o i 117-01 3 rig LCS in TCR4342
[138 is101119a037 LCS-101117-02 3 ng LCS in TCR-842
139 : :Sl01119a038 LCS-101117-03 3 ng LCS in TCR-842
>140 Is101119a039 LCS-101117-04 30 ng LCS in TCR-842
.141 !s 101119a040 ?LCS-101117-05 30 ng LCS in TCR-842
142 is101119a041 LCS-101117-06 30 ng LCS in TCR-842
143 's101119a042 10 006-25 solvent blank
.144 Is101119a043 EC-101117-05 2.5 ng Extracted Curve Point
145 Js101119a044 10 006-25 solvent blank
146 Is101119a045 GLP10-01-01-12-001 DAL SS TRIP 0 0000
147 is101119a046 GLP10-01-01-12-001 Dup DAL SS TRIP 0 0000 Lab Duplicate
1148 is101119a047 GLP10-01-01-12-001 LMS DAL SS TRIP 0 0000 Lab Matrix Spike
149 is101119a048 GLP10-01-01-12-002 DAL SS 6 1 1R 0 0000
150 s101119a049 GLP10-01-01-12-002 Dup DAL SS 611R 0 0000 Lab Duplicate
151 is101119a050 GLP10-01-01-12-002 LMS DAL SS 611R 0 0000 Lab Matrix Spike
[152 i$101119a051 G LP10-01-01-12-003 DAL SS 6 1 1R 0 0010
153 is101119a052 GLP10-01-01-12-003 Dup DAL SS 611R 0 0010 Lab Duplicate
154
i 155 *156
s101119a053 :s101119a054 s101119a055
GLP10-01-01-12-003 LMS DAL SS 611R 0 0010 Lab Matrix Spike 10 006-25 solvent blank EC-101117-06 5 ng Extracted Curve Point
157
(l5 8
,159
s101119a056 s101119a057 s101119a058
10 006-25 solvent blank
G LP10-01-01-12-004 DAL SS 611R 0 0040
GLP -01-0 1- 2-004 Dup DAL SS 61 R 4 Lati Duplicate
>160 is101119a059 GLP10-01-01-12-004 LMS DAL SS 611R 0 0040 Lab Matrix Spike
*161 is101119a060 GLP10-01-01-12-005 DAL SS 611R 0 0050
'162 s101119a061 GLP10-01-01-12-005 Dup DAL SS 611R 0 0050 Lab Duplicate
Printing Date: Thursday, December 23, 2010 Printing Time: 1:23:17 PM
------------ !
Analyte Peak Name
Sample Type
Use Record
Analyte Concentration
(ng/mL)
Analyte
Retention
Analyte Peak Area
Time (min)
(counts)
.s p -ak
` /t e a k Name
IS Peak
Area (c o u n ts )
IS
.Concentration (ng/mL)
IS Retention
Time (min)
C a lcu la te d Concentration
Accuracy
(ng/mL) (*
Record M o d ifie d
R ie Name
PFBS " Double Blank
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Double Blank
PFBS
Double Blank
PFBS
Double Blank
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Standard
PFBS
Double Blank
PFBS
Double Blank
PFBS
Double Blank
PFBS
Double Blank
PFBS
Double Blank
PFBS
Double Blank
PFBS
Double Blank
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Q uality Control
PFBS
Q uality Control
PFBS Quality Control
PFBS
Q uality Control
PFBS Quality Control
PFBS
Quality Control
PFBS
Double Blank ^
PFBS
Q uality Control
PFBS
Double Blank
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Double Blank
PFBS
Quality Control
PFBS
Double Blank
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
PFBS
Unknown
"
i
si 0 ID ID ID ID 0
0 0
0 0 0 0 R
0
0.0 '
N/A N/A N/A 0.00 0.00 0.00 0.200 0.500 0.749 0.999 2.50 5.00 9.99 25.0 50.0 99.9 200. .0 0.00 0.00 0.00 0.00 0.00 0.00 N/A N/A N/A 3. 3.00 3.00 30.0 30.0 30.0 0.00 2 50 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A 0.00 5.00 0.00 N/A N/A N/A N/A N/A
8.000 8.222 7.990 7.99 7.848 7.959 7.980 7.969 8.070 7.939 7.939 7.939 7.929 8.5 7.929 7.909 7 929 7 .9 9 8.030 8.050 7.919 7.879 7.909 8.040 7.879 7.889 7.909 7.899 7.899 8.010 7.899 7.899 7.889 7.899 7.990 8.000 7.859 7.909 7.889 7.889 7.899 7.899 7.899 7.899 7.879 7.879 7.919 7.889 7.919 8.010 7.909 7.899 7.889 7.899
9 0 " MPFBS " 12 " " "
1458810 MPFBS 312823
1416814 MPFBS
" 1369959 MPFBS
307035 313020
1084
MPFBS 133
727 MPFBS 36
31 MPFBS 36
33945
MPFBS 345518
69178
MPFBS 315725
110023 MPFBS 292232
134099 MPFBS 330622
359315 MPFBS 310166
720544 MPFBS 311310
1403216 MPFBS 306785
3251451 MPFBS 324499
7114850 MPFBS 331707
12669856 MPFBS 323925
23857378 MPFBS 330268
4422
MPFBS 36
958 MPFBS 0
415 MPFBS 48
863 MPFBS 12
2248
MPFBS 12
3606
MPFBS 12
1832
MPFBS 109
19231
MPFBS 340035
18648
MPFBS 363365
20136
MPFBS [350051
428112 MPFBS 339827
453636 MPFBS 331578
456292 MPFBS 338034
4290869 MPFBS 333154
4368634 MPFBS 339339
4433811 MPFBS 339842
2295
MPFBS 36
363152 MPFBS 323346
135 MPFBS 109
19652
~"117625
MPFBS MPFBS
294306 291112
142173 MPFBS 296727
71460
MPFBS 346108
98026
MPFBS 352498
254169 MPFBS 372861
136278 MPFBS 346167
89668
MPFBS 335434
257692 MPFBS 330719
137 MPFBS 48
7 9 5 7 MPFBS 322236
*52 MPFBS 73
44956
MPFBS 355526
45784
MPFBS 368189
203892 MPFBS 366824
32530
MPFBS 353983
31995
MPFBS 329712
N/A "
3.03 3.03 3.03 N/A N/A N/A 3.03 3.03 3.03 3.03 3.03 3.03 3.03 3.03 3.03 3.03 3.03 N/A N/A N/A N/A N/A N/A N/A 3.03 3.03 3.03 3.03 3.03 3.03 3 03 3.03 3.03 N/A 3.03 N/A 3.03 3.03 3.03 3.03 3.03 3.03 3.03 3.03 3.03 N/A 3.03 N/A 3.03 3.03 3.03 3.03 3.03
7.88 8.23 7.98 8.00 8.12 8.12 8.04 7.94 7.98 7.95 7.94 7.94 7.93 7.94 6.04 7.92 8.03 8.04 8.25 0.00 7.94 7.95' 8.12 7.99 8.07 7.90 6.01 7.90 7.90 7.90 7.91 7 93 7.90 8.02 8.11 7.93 7.97 8.00 7.90 7 91 7.98 7.89 7.88 7.88 7.89 7.88 8.01 7.88 8.00 7.89 7.99 7.87 7.68 7.87
N/A~ 10.8 10.7 10.1 N/A N/A N/A 0.174 0.452 0.815 0.882 2.62 5.30 1.6 23.5 51.6 98.3 201. N/A N/A N/A N/A N/A N/A N/A 0.0778 0.0657 0.0800 2.85 3.11 3.06 30.4 30.4 30.8 N/A 2 54 N/A 0.101 0.0869 1 05 0.423 0.588 1.52 0.854 0.563 1.74 N/A 5.11 N/A 0.239 0.234 1.23 0.159 0.171
N/A" "
N/A N/A N/A 1N/A N/A N/ 86.9 90.4 109. 88.3 105. 106. 106. 93.9 103. 98.3 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 95.2 104. 102. 101. 101. 103. N/A 102. N/A N/ N/A N/A N/A N/A N/A N/A N/A N/A N/A 102. N/A N/A N/A N/A N/A N/A
>
' s0119a.w iff ID s101119aw iff
s101119a.wiff
s101119a. wiff
s101119a.wiff s101119a wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff
s101119a.wiff
s101119a.wiff
s101119a.wiff s101119a.wiff
s101119a wiff
s101119a.wiff
s101119a.wiff
s101119a.wiff
s101119a.wiff s101119a.wiff s101119a.wiff 0 s101119a.wiff
0 $101119a.wiff
El s101119a.wiff
0 s101119a.wiff 0 s101119a.wiff
s101119a.wiff
n s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a. wiff s101119a.wiff s101119a. wiff s101119a.wiff s101119a.wiff s101119a.wiff
n s101119a.wiff
s101119a.wiff s101119a.wiff s101119a.wiff
s101119a.wiff
s101119a.wiff
D s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff $101119a. wiff s101119a. wiff s101119a.wiff s101119a.wiff s101119a.wiff
Page 3 of 8
3M Study: GLP10-01-02 Interim Report 12
Page 71 o f 419
Stan V1660305 3M Environmental Lab
Results Name: sl01119a.rdb
r ! :Sample Name
Sample ID
. .; : .
. .
Analyte , Peak
.>.... Name
Sam ple Type
Use Record
Analyte Concentration
(ng/mL)
Analyte.
Retention Time (mm)
PeakArca (counts) !
Name
IS Peak Area
(counts)
IS Concentration
(ng/mL)
IS Retention
Time (min)
(ng /m L )
163 s101119a062 5164 s101119a063 ,165 s101119a064 i1 66 ;s101119a065 f 167- :'is101119a066
168 S101119a067 >169 s1019a68 [170 is101119a069
171, ls101119a070 172 is101119a071 173 Is101119a072 ;174 s101119a073 175 Is101119a074 ;176 s101119a075 .177 s101119a076 1178 Is101119a077 [179 is101119a78 1180 s101119a079 1 181 s101119a080
1 82<v<:s10 1 1 19a081
<183 s101119a082 184' s101119a083 185 s101119a084 1186 Is101119a085 [ 1 8 7 is101119a086 ,188 s101119a087 [189 s101119a088 j'190 Is101119a089 191 Is101119a090 |192 is101119a091 193 Is101119a092 ^194: ':s101119a093
95 v ;s 101119a094 196 s101119a095 197 $101119a096 ; 198 s101119a097 1199 s101119a098 1200 is101119a099 201' Is101119a100 202 S 1 0 9 B 1203 is101119a001 204 ;s101119a002 f-a w 1s101119a003 [206 is101119a004 }207 Is101119a005 1208 Js101119a006 <209 is101119a007 ,210 $101119a008 ;211 sf 19009 212 s101119a010 <213 s101119a011 214 s101119a012 215 s101119a013 |216 is101119a014
G L P 0-01-01 -12-005 LMS DAL SS 6 1 1R 0 0050 Lab Matrix Spike GLP10-01-01-12-006 DAL SS 607R 0 0000 GLP10-01-01-12-006 Dup DAL SS 607R 0 0000 Lab Duplicate GLP10-01-01-12-006 LMS DAL S S 607R 0 0000 Lab Matrix Spike 10 006-25 solvent blank EC-101117-05 2.5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-01-12-007 DAL SS 607R 0 0010 GLP10-01-01-12-007 Dup DAL S S 607R 0 0010 Lab Duplicate GLP10-01-01-12-007 LMS DAL S S 607R 0 0010 Lab Matrix Spike GLP10-01-01-12-008 DAL S S 607R DB 0010 GLP10-01-01-12-008 Dup DAL S S 607R DB 0010 Lab Duplicate GLP10-01-01-12-008 LMS DAL S S 607R DB 0010 Lab Matrix Spike G LP 10-01-01 -12-01 DAL SS 67R 40 GLP10-01-01-12-010 Dup DAL S S 607R 0 0040 Lab Duplicate GLP10-01-01-12-010 LMS DAL S S 607R 0 0040 Lab Matrix Spike 10 006-25 solvent blank EC-701117-06 5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-01-12-011 DAL SS 607R 0 0270 GLP10-01-01-12-011 Dup DAL S S 607R 0 0270 Lab Duplicate GLP10-01-01-12-011 LMS DAL S S 607R 0 0270 Lab Matrix Spike GLP10-01-01-12-012 DAL SS 609R 0 0000 GLP10-01-01-12-012 Dup DAL SS 609R 0 0000 Lab Duplicate GLP10-01-01-12-012 LMS DAL S S 609R 0 0000 Lab Matrix Spike GLP1001-01-12-013 DAL SS 609R 0 0010 GLP10-01-01-12-013 Dup DAL SS 609R 0 0010 Lab Duplicate GLP10-01-01-12-013 LMS DAL SS 609R 0 0010 Lab Matrix Spike 10 006-25 solvent blank EC-101117-05 2.5 ng Extracted Curve Point 10 006-25 solvent blank GLP10-01-01-12-014 DAL SS 609R 0 0040 GLP10-01-01-12-014 Dup DAL SS 609R 0 0040 Lab Duplicate GLP10-01-01-12-014 LMS DAL S S 609R 0 0040 Lab Matrix Spike GLP10-01-01-12-015 DAL SS 609R 0 0110 GLP10-01-01-12-015 Dup DAL S S 609R 0 0110 Lab Duplicate GLP10-01-01-12-015 LMS DAL SS 609R 0 0110 Lab Matrix Spike 10 006-25 solvent blank EC-101117-06 5 ng Extracted Curve Point 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank W a m i lip E C M ill7Q )7 1 ng Warm Up EC-101117-07 10 ng Warm Up EC-101117-07 10 ng 10 006-25 solvent blank 10 006-25 solvent blank 10 006-25 solvent blank
PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS
Unknown Unknown Unknown [Unknown Double Blank Q uality Control [Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Q uality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Double Blank Double Blank Double Blank
N /A " " N/A IN/A N/A iO.OO a 2.50 ;0.00
IN/A jN/A [N/A IN/A [N/A [N/A jN/A IN/A jN /A 1. E l 5.00 iO.OO jN/A
!n /a
N/ jN/A jN/A jN/A IN/A N/A N/A 0.00 a 2.50 j0.00 IN/A IN/A IN/A IN/A N/A N/A 10.00 a 5.00
0.00 0.00 0.00 0.00 0.00
0.00 0.00 10.00 10.00 IN/A N/A N/A
0.00 0.00 0.00
*7.869 *7.869 7.869 .7.889 7.949 7.869 I6.020 7.889 ;7.889 I7.889 [7.990 [7.969 [7.879 7.869 [6.000 7.899 7.818 17.879 17.949 17.899 7.990 17.899 [7.879 ;7.889 17.889 17.879 [7.980 17.899 16.000 17.889 17.879 7 879 17.869 17.899 17.889 17.970 17.869 17.919 [7.879 [7.949 [10.502 [10.421 [10.592 110.391 [10.411 110.441 [10.431 110.431 i 10.925 110.552 110.522 110.401 110.431 110.370
176943 " MPFBS 36275" " *3.03
95548
MPFBS 349325 3.03
189015
MPFBS 354779
3.03
229776 MPFBS 346857 3.03
66
MPFBS 133
N/A
376191 MPFBS 330400 3.03
421 MPFBS 36
N/A
35810
MPFBS 344042
3.03
34980
MPFBS _ j 357262
3.03
"* 194139 MPFBS 338895 3.03
30119
MPFBS 347740
3.03
26183
MPFBS 337398
3.03
191867 MPFBS 341691
3.03
21531
MPFBS 350809
3.03
22802
MPFBS 335169
3.03
164604 MPFBS 364909
3.03
807 MPFBS 254
N/A
718606 MPFBS 316548
3.03
92
MPFBS 133
N/A
19721 IM PFBS 308690
3.03
18777
MPFBS 367296
3.03
164020 MPFBS 336883
3.03
94498
MPFBS 356451
3.03
91642
MPFBS 362115
3.03
267202 MPFBS 328731
3.03
29965
MPFBS 312645
3.03
34407
MPFBS 327540 3.03
185516 MPFBS 328945
3.03
6
MPFBS 12
N/A
374056 MPFBS 334446
3.03
68 jM PFBS 36
N/A
28372
MPFBS 315696
3.03
31614
MPFBS 345238
3.03
176788 MPFBS 345850 3.03
32165
MPFBS 368581
3.03
34112
MPFBS 353542 3.03
178961 MPFBS 341163 3.03
555 MPFBS 169
N/A
715869 MPFBS 320681
3.03
19 MPFBS 73
407 MPFHS 0 93 MPFHS 0
N/A N/A N/A
1114
MPFHS 48
N/A
172 MPFHS 12
N/A
42 MPFHS 0
N/A
111 MPFHS 12
N/A
54 MPFHS 0
N/A
40 MPFHS 0
N/A
921702 MPFHS 146954 3.00
h53330 MPFHS 145351
3.00
926469 MPFHS 139273 3.00
52 MPFHS 97
N/A
30 MPFHS 36
60 MPFHS 0
N/A N/A
" 7.87 7.88 7.88 7.87 8.02 7.89 7.94 7.90 7.87 7.87 7.90 7.87 7.98 7.90 7.89 7.88 7 88 7.88 7.97 7.89 7.88 7.89 7.87 7.89 7.98 7.88 7.89 7.88 7.93 7.87 7.97 7.99 7.86 7.89 7.89 7.89 7.88 8.05 7.89 7.97
0.00 0.00
10.3 10.5 0.00 10.6 0.00 0.00 10.9 10.5 10.5 10.6 10.5
0.00
' 1.07 ' " 0 578 0.525 1.47 N/A 2.57 N/A 0.187 0.173 1.27 0.147 0.140 1.24 0.0888 0.104" 0.987 N/A 5.20 N/A 0.0946 0.0652 1.07 0.558 0.530 1.82 0.168 0.189 1.25 N/A 2.53 N/A 0.154 0158 1.13 0.148 0.170 1.16 N/A 5.11 N/A N/A N/A N/A N/A N/A N/A N/A N/A 9.98 10.4 .6 N/A N/A N/A
Printing Date: Thursday, December 23, 2010 Printing Time: 1:23:18 PM
Page 4 of 8
Record
w
I Modified
File Name
N/A N/A N/A N/A N/A 103. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 104. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 101. N/A N/A N/A N/A N/A N/A N/A N/A 102. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
'j I j I i [ j j i : [ i i i f 7 1 I I 1 1 I j j { j 1 j j i I
* I I j j I ; j j j j j I [
j
J f j J
j
j
j
a
n
n
a a
s101119a. wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff 8101119a. wiff s101119a.wiff s 1 0 1 l1 9 a .w iff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s 101119a.wiff s 101119a.wiff s101119a.wifl s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff $101119a.wiff s 101119a.wiff s 101119a.wiff s 101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a. wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff
3M Study: GLP10-01-02 Interim Report 12
Page 72 of 419
Stan V1660305 3M Environmental Lab
Results Name: sl01119a.rdb
i v Sample Name
.
Sample ID
Analyte Peak Name
Sample Type
Use Record
Analyte
Concentration (ng/mL)
(min) 1
i
217 s 1 0 1 1 1 9 a 0 H E c Tio T i 17^61" 0" 2 ng"Extracted Curve Point
'
1218 : is101119a016 EC-101117-02 0.5 ng Extracted Curve Point
219 : ;s101119a017 EC-101117-03 0.75 ng Extracted Curve Point
I220 is101119a018 EC-101117-04 1 ng Extracted Curve Point
221 is101119a019 EC-101117-05 2.5 ng Extracted Curve Point
222 s101119a020 EC-101117-06 5 ng Extracted Curve Point
223 s101119a021 E C -i 0 m 7 - 0 7 10 ng Extracted Curve Point
224 Is101119a022 EC-101117-08 25 ng Extracted Curve Point
225 is101119a023 EC-101117-09 50 ng Extracted Curve Point
(226 is101119a024 EC-101117-10 100 ng Extracted Curve Point
227 s101119a025 EC-101117-11 200 ng Extracted Curve Point
226 is101119a026 10 006-25 solvent blank
229 s101119a027 10 006-25 solvent blank
230 s101119a028 10 006-25 solvent blank
231 : s 101119a029 10 006-25 solvent blank
232 Is101119a030 MB-101117-01 Method Blank 1 w/o IS
*233 8101119*031 M B -1 0 1 117-02 Method Blank 2 w/o IS
234 s10i 9a 32 M B - ib i 117-03 Method Blank 3 w/o IS
235 is101119a033 MB-101117-O4 Method Blank 4 w/ 1S
1236 ; =s101119a034 MB-101117-05 Method Blank 5 w / IS
237 s101119a035 MB-101117-06 Method Blank 6 w / IS
'238 :s101119a036 LCS-101117-01 3 ng LCS in TCR-842
(239 Is101119a037 LCS-101117-02 3 ng LCS in TCR-842
(240 Is101119a038 LCS-101117-03 3 ng LCS in TCR-842
(241 :: is 1i 9a039 LCS-101117-04 30 ng LCS in TCR-842
242 is101119a040 LCS-101117-05 30 ng LCS in TCR-842
(243 :s101119a041 LCS-101117-06 30 ng LCS in TCR-842
(244 is101119a042 10 006-25 solvent blank
245 s1 0 iil9 4 3 EC-101117-05 2.5 ng Extracted Curve Point
246< ;s101119a044 10 006-25 solvent blank
|247:>is101119a045 GLP10-01-01-12-001 DAL SS TRIP 0 0000
|248: is101119a046 GLP10-01-01-12-001 Dup DAL SS TRIP 0 0000 Lab Duplicate
249 s101119a047 GLP10-01-01-12-001 LMS DAL SS TRIP 0 0000 Lab Matrix Spike
>250 s101119a048 GLP10-01-01-12-002 DAL SS 611R 0 0000
251 s101119a049 GLP10-01-01-12-002 Dup DAL SS 611R 0 0000 Lab Duplicate
i252 : Is 101119a050 GLP10-01-01-12-002 LMS DAL SS 611R 0 0000 Lab Matrix Spike
253 s101119a051 GLP10-01-01-12-003 DAL SS 611R 0 0010
254: is101119a052 GLP10-01-01-12-003 Dup DAL SS 611R 0 0010 Lab Duplicate
(255 s101119a053 GLP10-01-01-12-003 LMS DAL SS 611R 0 0010 Lab Matrix Spike
(256, \is101119a054 10 006-25 solvent blank
257 ;S l ii9 0 5 5 EC-101117-06 5 ng Extracted Curve Point
258 is101119a056 10 006-25 solvent blank
(259: Is101119a057 GLP10-01-01-12-004 DAL SS 611R 0 0040
260 is101119a058 GLP10-01-01-12-004 Dup DAL SS 611R 0 0040 Lab Duplicate
'261 s101119a059 GLP10-01-01-12-004 LMS DAL SS 611R 0 0040 Lab Matrix Spike
,262 s101119a060 G LP 10-01-01-12-005 DAL SS 611R 0 0050
263 s101119ai61 GLP10-01-01-12-005 Dup DAL SS 611R 0 0050 Lab Duplicate
.
264 s101119a062 G Lp'icW )1^i-12-0b5 LMS DAL S S 6 1 1R 6 0050 Lab Matrix Spike
265 s101119a063 GLP10-01-01-12-006 DAL SS 607R 0 0000
266 $101119a064 GLP10-01-01-12-006 Dup DAL SS 607R 0 0000 Lab Duplicate
(267 :is101119a065 GLP10-01-01-12-006 LMS DAL SS 607R 0 0000 Lab Matrix Spike
(268 s101 9 a 06 6 10 006-25 solvent blank
1269 !s101119a067 EC-101117-05 2.5 ng Extracted Curve Point
(270 is101119a068 10 006-25 solvent blank
p' f' h s " ` Standard
PFHS
Standard
PFHS
Standard
PFHS " 5Standard
PFHS
Standard
PFHS
Standard
PFHS
Standard
PFHS
Standard
PFHS
Standard
PFHS
Standard
PFHS
Standard
PFHS
Double Blank
PFHS
Double Blank
PFHS
Double Blank
PFHS
Double Blank
PFHS - Double Blank
PFHS
Double Blank
PFHS
Double Blank
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Quality Control
PFHS
Quality Control
PFHS
Quality Control
PFHS
Quality Control
PFHS
Quality Control
PFHS
Quality Control
PFHS
Double Blank
PFHS
Quality Control
PFHS
Double Blank
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Double Blank
PFHS
Q uality Control
PFHS
Double Blank
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Unknown
PFHS
Double Blank
PFHS
Quality Control
PFHS
Double Blank
oYdb S I 0.500 S I 0.750 0 1.00 0 2.50 0 5.00 S I 10. S I 25.0 S I 50.0 S I 100. S I 200.
0.00
0.00
.
0.00
0.00
0.00
0.00
N/A
N/A
N/A
S I 3.00 S I 3.00 S I 3.00 S I 30.0 S I 30.0 S I 30.0
0.00
SI 2.50
0.00
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
;N/A
10.00
s i 5.00
10.00 N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
N/A
0.00
El 2.50
0.00
10.491 ` 719284""
10.461 (47883
10.471 (68282
10.461 (88206
10.441 <234968
10.441 473429
10.461 956931
10.441 2399272
10.451 4796965
10.441 9020745
10.431 16995802
10.502 3534
10.340 (132
10.391 295
10.421 296
10.572 (583
10.562 (1181
10.401 (633
10.561 (1921
10.562 1691
10.431 174-4
10.421 (311732
"10.401 1307019
10.411 299856
10.411 3004709
10.421 3127409
10.391 3305308
10.552 [707
10.431 243658
10.471 l7 3
10.431 10.552 10.401 10.431
190O
f1596 I88260 17618
10.391 110912
10.401 10.411
111400
I 115275
10.421 50153
10.411 182007
10.431 23
10.411 488828
10.411 119
10.411 9150
10.523 11917
10.401 111231
10.512 9126
io '.481 17487
10.370 (111601
10.370 114309
10.390 f14377
10.370 M 12940
10.481 31
10.370 (253525
10.360 142
MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS
IS Peak Area
(counts)
IS Concentration
(ng/mL)
IS Retention
Time (min)
C a lcu la te d Concentration
(n g /m L )
. *** {? **
***
^Record Modified
File Name
165996 147416 146486 152483 142799 140919 155111 157829 156041 155742 160773 36 36 0 0 36 24 155379 169242 159492 164805 153525 162512 151942 148584 154953 48 150115 12 136496 129916 142161 151255 157096 167487 159808 148507 154513 24 154624 73 151371 171839 153017 165202 164418 158356 165660 158011 166488 24 157750 36
3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A N/A N/A N/A N/A N/A N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A 3.00 N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A 3.00 N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A 3.00 N/A
10?5 10.5 10.5 10.5 10.5 10.4 10.5 10.4 10.4 10.4 10.4 10.5 10.2 0.00 0.00 10.4 10.5 0.00 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.5 10.4 10.6 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 104 10.4 10.6 10.5 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.5 10.4 10.4
` 0.193" " 0.522 0.745 0.922 2.61 5.33 9.82 24.5 50.6 99.6 200. N/A N/A N/A N/A N/A N/A N/A 0.0289 0.0252 0.0266 3.00 3.17 2.93 32.0 34.2 34.6 N/A 2.57 N/A 0.0314 0.0288 0.989 0.0888 0.119 1 06 1.15 0.542 1.87 N/A 5.01 N/A 0.105 0.119 1.16 0.0965 0.0812 1.12 0.146 0.153 1 08 N/A 2.55 N/A
96.3 104. 99.3 i 92.2 104. 107. 98.2 97.9 101. 99.6 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. 106. 97.5 107. 114. 115. N/A 103. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 102. N/A
n
El
0
0
0
0 0 0 0 0 0 n 0
s10a.w iff s101119a.wiff s101119a.wiff s101119a.wi(T s101119a.wiff s101119a will s101119a.wiff s101119a.wifl s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff st01119a.wiff s101119a.wifF s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wilT s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wifl s101119a.wi(T s101119a.wiff s101119a.wiff s101119a.wilT s101119a.wifl s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s1Q1119a.wiff s101119a.wiff s101119a.wiff s101119a.wi1T s101119a.wilf s101119a.wiff
Printing Date: Thursday, December 23, 2010 Printing Time: 1:23:18 PM
Page 5 of 8
3M Study: GLP10-01-02 Interim Report 12
Page 73 of 419
Stan V1660305 3M Environmental Lab
Results Name: sl01119a.rdb
Sample Name
Sample ID
_____
!Sl01119a69 j G LP 10-01 -01 -12-07 DAL SS 607R 0 001
272 is101119a070 GLP10-01-01-12-007 Dup DAL SS 607R 0 0010 Lab Duplicate
273 is101119a071 GLP10-01-01-12-007 LMS DAL SS 607R 0 0010 Lab Matrix Spike
274 is101119a072 GLP10-01-01-12-008 DAL SS 607R DB 0010
275 ;s101119a073 GLP10-01-01-12-008 Dup DAL SS 607R DB 0010 Lab Duplicate
276 is101119a074 GLP10-01-01-12-008 LMS DAL SS 607R DB 0010 Lab Matrix Spike
277 ;s10111975 GLP10-01-01-12-010 DAL SS 607R 0 0040
278 Is101119a076 GLP10-01-01-12-010 Dup DAL SS 607R 0 0040 Lab Duplicate
279 is101119a077 GLP10-01-01-12-010 LMS DAL SS 607R 0 0040 Lab Matrix Spike
280 is101119a078 10 006-25 solvent blank
281 s101119a079 EC-101117-06 5 ng Extracted Curve Point
.
282 Is101119a080 10 006-25 solvent blank
283 s101119a081 GLP10-01-01-12-011 DAL SS 607R 0 0270
284 is1 01 9a 08 2 GLP10-01-01-12-011 Dup DAL SS 607R 0 0270 Lab Duplicate
285 is101119a083 G LP 10-01-01-12-011 LMS DAL SS 607R 0 0270 Lab Matrix Spike
286 s101119a084 GLP10-01-01-12-012 DAL SS 609R 0 0000
287 ;Sl01119a85 G LP i OOi 431-12-012 Dup DAL SS 609R 0 Lab Duplicate
288 is 1 0 'iil9 a 0 8 6 G L P M V 0 - 1 2 -0 2 LMS DAL SS 69R 0 Lab Matrix Spike
289 ]$101119a087 GLP1001-01-12-013 DAL SS 609R 0 0010
290 is101119a068 GLP1001-01-12-013 Dup DAL SS 609R 0 0010 Lab Duplicate
291 s11119a89 GLP1001 01 -1 2 -0 13 LMS DAL SS 609R 0 0010 Lab Matrix Spike
292 s01119a090 10 006-25 solvent blank
293 $101119a091 EC-10111705 2.5 ng Extracted Curve Point
294 is101119a092 10 006-25 solvent blank
295 is101119a093 GLP10 0 1 0 1 -1 2 0 1 4 DAL SS 609R 0 0040
296 !s101119a094 G LP 1 0 0 1 0 1 -1 2 0 1 4 Dup DAL SS 609R 0 0040 Lab Duplicate
297 is101119a095 GLP10 0101-12-014 LMS DAL SS 609R 0 0040 Lab Matrix Spike
298 s101119a096 G LP 1 0 0 1 0 1 -1 2 0 1 5 DAL SS 609R 0 0110
299 Is101119a097 GLP 0O1 O l -12 01 5 Dup DAL SS 69R l i' Lab Duplicate
300 :s101119a098 G LP 1 0 0 1 0 1 -1 2 0 1 5 LMS DAL SS 609R 0 0110 Lab Matrix Spike
301 is101119a099 10 006-25 solvent blank
302 is101119a100 EC-10111706 5 ng Extracted Curve Point
303 !s101119a101 10 006*25 solvent blank
304 is101119a001 10 0 06 25 solvent blank
305 :s101119a002 10 00&25 solvent blank
306 is101119a003 10 006-25 solvent blank
307 Is101119a004 10 006-25 solvent blank
308 i$101119a005 10 006-25 solvent blank
309 is101119a006 10 006-25 solvent blank
310 is101119a007 10 006-25 solvent blank
311 is101119a008 10 006-25 solvent blank
312 Is101119a009 Warm Up EC-101117-07 10 ng
313 is101119a010 Warm Up EC-101117-07 10 ng
314 is101119a011 Warm Up EC^1il17-7 10 ng
315 is101119a012 10 006-25 solvent blank
316 :s101119a013 10 006-25 solvent blank
317 i$101119a014 10 006-25 solvent blank
318, is101119a015 EC-101117-01 0.2 ng Extracted Curve Point
("319 s101119a016 EC-101117-02 0.5 ng Extracted Curve Point
320 is101119a017 EC-101117-03 0.75 ng Extracted Curve Point
321 4s101119a018 EC-101117-04 1 ng Extracted Curve Point
322 s101119a019 EC-101117-05 2.5 ng Extracted Curve Point
323 s101119a020 EC-101117-06 5 ng Extracted Curve Point
324 =s101119a021 EC-101117-07 10 ng Extracted Curve Point
Analyte Peak Name
PFHS" " PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS
Sample Type
Use Record
Analyte Concentration
(n g /m L )
Analyte I
t 1TM *
(m in )
i 1
(counts)
i j
' Nl aP mMek
IS Peak Area
(counts)
IS ;
IS ' Concentration
. (ng/mL)
Retention Time (min)
Calculated Concentration
(n g /m L )
Accuracy CXJ
Record Modified
File Name
Unknown
.... . N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
1
N/A
Unknown
N/A
Double Blank
.
Quality Control Double Blank
El 5.00
0.00
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Double Blank
0.00
Quality Control Double Blank
S 3 2.50 0.00
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Unknown
N/A
Double Blank
0.00
Quality Control Double Blank
a
5.00 0.00
Double Blank
0.00
Double Blank
0.00
Double Blank
0.00
Double Blank
0.00
Double Blank
0.00
Double Blank
0.00
Double Blank
0.00
Double Blank Unknown
_ 0.00
N/A
Unknown
N/A
Unknown
N/A
Double Blank
0.00
Double Blank
0.00
Double Blank
0.00
Standard Standard Standard Standard Standard Standard Standard
a 0.200
E l 0.500
E l 0.750
El 1 00 El 2.50 El 5.00 0 10.0
M O . 391 ' 7228 10.421 7104 10.360 113183 10.401 5430 10.370 4601 10.380 106538 10.380 2834 10.542 2259 10.391 105524 10.411 240 10.380 501473 10.421 214 10.391 2222 10.562 1960 10.401 93159 10.388 20018 10.403 21710 10.380 122070 10.391 4015 10.542 5029 10.381 105039 10.471 73 10.370 242696 10.431 143 10.552 3122 10.522 2982 10.380 91604 10.542 3637 10.391 3990 10.380 107638 10.431 88 10.380 473718 10.471 136 13.155 ^ 328 13^366" J 164 13.356 68 13.336 181 13.316 45 13.387 107 13.336 23 13.478 200 13.942 370451 13.477 371225 13.467 362155 13.316 471 13.316 395 13.306 ^409 13.367 9659 13.356 21368 13.407 29848 13.377 37642 13.356 93683 13.356 180720 13.356 383891
M P F H S "" *174597 MPFHS 160391 MPFHS 166261 MPFHS 161722 MPFHS 171236 MPFHS 152938 MPFHS 166107 MPFHS 164091 MPFHS 161599 MPFHS 61 MPFHS 150462 MPFHS 48 MPFHS 143928 MPFHS 156589 MPFHS 159738 MPFHS 170081 MPFHS 166702 MPFHS 156703 MPFHS 145460 MPFHS 165461 MPFHS 154053 MPFHS 24 MPFHS 150983 MPFHS 48 MPFHS 159562 MPFHS 159083 MPFHS 166394 MPFHS 181027 MPFHS 79389 MPFHS 162919 MPFHS 12 MPFHS 163072 MPFHS 73 M8PFOS 311 M8PFOS 36 M8PFOS 121 M8PFS 48 M8PFOS 315 M8PFOS 73 M8PFOS 85 M8PFOS 48 M8PFOS 45782 M8PFOS 45529 M8PFOS 44089 M8PFOS 24 M8PFOS 72 ' M8PFOS 12 M8PFOS 40648 M8PFOS 47549 M8PFOS 46085 M8PFOS 43858 M8PFOS 42690 M8PFOS 45468 M8PFOS 45313
" " 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A 3.00 N/A 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 3.00 N/A 3.00 N/A 3.00 3.00 3.00 3.00 3.00 3.00 N/A 3.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A 2.98 2.98 2.98 N/A N/A N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98
T.4 10.4 10.4 10.4 10.4 10.4 10.5 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10.4 10 4 10.4 10.4 10.5 10.4 10.4 10.4 10.5 10.4 10.4 10.4 10.4 10.4 10.4 10.5 10.4 10.5 13.4 13.3 13.2 13.2 13.5 13.2 133 13.3 13.9 13.5 13.5 13.2 13.3 13.1 13.4 13.4 13.4 13.4 13.3 13.3 13.4
070747'"" " 0.0792 1.08 0.0623 0.0516 1.11 0.0363 0.0311 1.04 N/A 5.29 N/A 0.0337 0.0291 0.929 0.195 0.215 1.24 0.0529 0.0573 1.09 N/A 2.55 N/A 0.0403 0.0390 0.878 0.0411 0.0886 1.05 N/A 4.61 N/A N/A N/A N/A N/A N/A N/A N/A N/A 10.1 10.2 10.2 N/A N/A N/A 0.207 0.472 0.720 0.984 2.65 4.89 10.6
'n /a "" "
N/A N/A N/A N/A N/A N/A N/A N/A N/A 106. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 102. N/A N/A N/A N/A N/A N/A N/A N/A 92.1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
r_N_/A_
103. 94.4 96.0 98.4 106. 97.9 106.
........
.....
El
El El
El
_____
n El
a
El El
si lV a .w if " s101119a wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wif s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s 1 0 1 l1 9 a .w iff s 101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.witT s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s 101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff * s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s 101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff s101119a.wiff
Printing Date: Thursday, December 23, 2010 Printing Time: 1:23:18 PM
Page 6 of 8
3M Study: GLP10-01-02 Interim Report 12
Page 74 of 419
Stan VI660305 3M Environmental Lab
Results Name: sl01119a.rdb
Sample Name
Sample ID
..
k . j -:
.
i1
. _ _... ...._ .. -- .......
325 s101119a022 EC-101117-08 25 ng Extracted Curve Point
|326 . s101119a023 EC-101117-09 50 ng Extracted Curve f
'3 27 Is101119a024 EC-101117-10 100 ng Extracted Curve Point
328 s101119a025 EC-101117-11 200 ng Extracted Curve Point
[3 2 9 ; is101119a026 10 006-25 solvent blank
3 3 0; s101119a027 10 006-25 solvent blank
f 331 s101119a028 10 006-25 solvent blank
*332 is101119a029 10 006-25 solvent blank
333;.: is101119a030 MB--101117-01 Method Blank 1 w/o IS
334; !S l0 V il9 a 0 3 1 MB--101117-02 Method Blank 2 w/o IS
>335 ;s101119a032 MB--101117-03 Method Blank 3 w/o IS
|;3 3 6 :: s101119a033 MB--101117-04 Method Blank 4 w/ IS
337;, ]s101119a034 MB-101117-05 Method Blank 5 w / IS
333: sl0 1119a035 M B -'1011174)6 Method Blank 6 w 1 \S
: 339 s101119a036 LCS-101117-01 3 ng LCS in TCR-842
340 is101119a037 LCS-101117-02 3 ng LCS in TCR-842
341 |s1 iil9 a 3 8 LCS-101117-03 3 ng LCS in TCR-842
'
342 i s 1o i i i 9a39 LCS-1011174)4 30 ng LCS in TCR-842
i343 is1 01 119a040 LCS-101117-05 30 ng LCS in TCR-842
s344 is101119a041 LCS-101117-06 30 ng LCS in TCR-842
!345 is101119a042 10 006-25 solvent blank
346 Is101119a043 EC-101117-05 2.5 ng Extracted Curve Point
;347 is101119a044 10 006-25 solvent blank
<348 :s101119a045 GLP10-01-01-12-001 DAL SS TRIP 0 0000
;349 s101119a046 G L P i0 ^ i# 1 - i2 4 X ) i Dup DAL SS TRiP 6 6666 Lab Duplicate
>350 s101119a047 GLP10-01-01-12-001 LMS DAL SS TRIP 0 0000 Lab Matrix Spike
351 s101119a048 GLP10-01-01-12-002 DAL SS 611R 0 0000
352 s101119a049 GLP10-01-01-12-002 Dup DAL SS 611R 0 0000 Lab Duplicate
353 s101119a050 GLPiCMO$31-124002 LMS DAL SS 611R 0 0000 Lab Matrix Spike
354 Is101119a051 GLP10-01-01-12-003 DAL SS 611R 0 0010
355 Is101119a052 GLP10-01-01-12-003 Dup DAL SS 611R 0 0010 Lab Duplicate
1356 is101119a053 GLP10-01-01-12-003 LMS DAL SS 611R 0 0010 Lab Matnx Spike
(357 - s101119a054 10 006-25 solvent blank
'
358 s101119a055 EC-101117-06 5 ng Extracted Curve Point
f3 5 9 ' :s101119a056 10 006-25 solvent blank
3 6 0 ' !s101119a057 GLP10-01-01-12-004 DAL SS 611R 0 0040
'361 ;s101119a058 GLP10-01-01-12-004 Dup DAL SS 611R 0 0040 Lab Duplicate
362 s101119a059 GLP10-01-01-12-004 LMS DAL SS 611R 0 0040 Lab M atrix Spike
363 s101119a060 GLP10-01-01-12-005 DAL SS 611R 0 0050
|364 is101119a061 GLP10-01-01-12-005 Dup DAL SS 611R 0 0050 Lab Duplicate
365 s101119a062 GLP10-01-01-12-005 LMS DAL SS 611R 0 0050 Lab Matrix Spike
366 s101119a063 GLP10-01-01-12-006 DAL SS 607R 0 0000
1367 s101119a064 GLP10-01-01-12-006 Dup DAL S S 607R 0 0000 Lab Duplicate
368 is101119a065 G LP16014)1 -12-006 LMS DAL SS 607R 0 0000 Lab Matrix Spike
369; s101119a066 10 0 06 25 solvent blank
370 is101119a067 EC-101117-05 2.5 ng Extracted Curve Point
371 s101119a068 10 0 06 25 solvent blank
372 s101119a069 GLP16-01-01 -12-007 DAL SS 607R 6 0010
373 s101119a070 GLP10-01-01-12-007 Dup DAL SS 607R 0 0010 Lab Duplicate
:374 s101119a071 GLP10-01-01-12-007 LMS DAL SS 607R 0 0010 Lab Matrix Spike
^375 s101119a072 GLP10-01-01-12-008 DAL SS 607R DB 0010
' 376 s101119a073 GLP10-01-01-12-008 Dup DAL SS 607R DB 0010 Lab Duplicate
S377 s101119a074 GLP10-01-01-12-008 LMS DAL SS 607R DB 0010 Lab Matrix Spike
[378 s101119a075 GLP10-01-01-12-010 DAL SS 607R 0 0040
Analyte Peak Name
i Sample Type
Use Record
Analyte Concentration
(ng/mL)
Analyte Retention
Time (m in)
SSJ (counts) j
- p" k Name
IS Peak Area
(counts)
IS Concentration
(ng/mL)
IS Retention
Time (min)
Calculated Concentration
(ng/mL)
Accuracy <%)
PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS
j Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank ; Double Blank i Double Blank Double Blank Unknown Unknown Unknown jQ uality Control Quality Control Quality Control Quality Control Quality Control Quality Control Double Blank Quality Control j Double Blank |Unknown IUnknown [Unknown Unknown [Unknown IUnknown IUnknown Unknown Unknown Double Blank I Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown IUnknown [Unknown Unknown I Unknown
s i 25.0 El 50.0 El 100. e 200:
j 0.00 iO.OO
0.00
0.00
0.00 0.00 10.00
N/A
N/A N/A
El 3.00 El 3.00 0 3.00 El 30.0 El 30.0 El 30.0
0.00
El 2.50 iO.OO N/A
N/A N/A
N/A N/A
N/A N/A
N/A
N/A 0.00 El 5.00 10.00 N/A N/A
N/A
N/A N/A
N/A
N/A
N/A N/A
0.00 El 2.50
0.00
N/A N/A
N/A N/A N/A N/A N/A
13.336 13.346 13.326 13.316 13.326 13.225 13.235 13.256 13.295 13.303 13.273 13.308 13.259 13.339 13.300 13.215 13.292 13.273 13.280 13.262 13.397 13.296 13.276 13.250 13.245 13.245 13.265 13.249 13.262 13.254 13.261 13.240 13.417 13.245 13.155 13.243 13.244 13.247 13.246 13.231 13.232 13.231 13.221 13.241 13.508 13.215 13.496 13.226 13.219 13.228 13.222 13.228 13.243 13.225
921576 1914597 3502669 6091015 2243 530 254 228 3675 3916 2606 3929 4503 3645 119791 123853 127252 1187030 1243925 1286447 35 103739 242 8907 4210 39098 946228 1152828 2662938 876685 630746 2216905 133 195923 424 223342 282253 1871016 ` 112676 90743 282188 706655 645208 2286947 240 106354 119 941143 871431 2560960 866296 726879 2724576 208727
M8PFOS 47113 M8PFOS 48640 M8PFOS 45951 M8PFOS 41364 M8PFOS 24 M8PFOS 61 M8PFS 48 M8PFOS 36 M8PFOS 36 M8PFOS 48 M8PFOS 73 M8PFOS 49524 M8PFOS 151856 M8PFOS 47599 M8PFOS 50504 M8PFOS 47987 M8PFOS 48326 M8PFOS 45479 M8PFOS 45541 M8PFOS 50818 M8PFOS 133 M8PFOS 45216 M8PFOS 24 M8PFOS 39489 M8PFOS 42310 M8PFOS 45627 M8PFOS 45662 M8PFOS 47248 M8PFOS 50538 M8PFOS 50018 M8PFOS 49885 M8PFOS 47256 M8PFOS 48 M8PFOS 45977 M8PFOS 12 M8PFOS 46823 M8PFOS 51822 M8PFOS 48917 M8PFOS 46463 M8PFOS 49233 M8PFOS 43687 M8PFOS 52007 M8PFOS 47756 M8PFOS 49626 M8PFOS 85 M8PFOS 47766 M8PFOS 24 M8PFOS 46133 M8PFOS 50663 M8PFOS 49390 M8PFOS 52224 M8PFS 49573 M8PFOS 50192 M8PFOS 50881
2.98 2.98 2.98 2.98 { N/A N/A N/A N/A N/A N/A N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2 98 2.98 N/A 2.98 N/A 2.98 2.96 2.98 2.98 2.98 2.98 2.98 2.98 2.98 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98 2.96 2.96 N/A 2.98 N/A 2.98 2.98 2.98 2.98 2.98 2.98 2.98
13.3 13.3 13.3 13.2 13.3 13.4 13.2 13.3 13.4 13.3 13.4 13.3 13.3 13.3 13.3 13.3 13.3 13 3 13.3 13.2 13.3 13.3 13.5 13.3 13.3 13.3 13.3 13.2 13.3 13.2 13.3 13.3 13.4 13.3 13.3 13.2 13.3 13.2 -13.2 13.2 ;13.2 13.2 13.2 13.2 =13.2 113.2 13.2 13.2 13.2 13.2 132 13.2 13.2 13.2
24.6 50.2 99.3 200. N/A N/A N/A N/A N/A N/A N/A 0.00870 0.0181 0.00524 2.88 3.14 3.21 33.0 34.6 32.0 N/A 2.78 N/A 6.192 0.0339 0.962 26.1 30.8 67.7 22.0 15.8 60.1 N/A 5.25 N/A 5.89 6.75 48.7 2.95 2.22 8.02 17.0 16.9 59.0 N/A 2.70 N/A 25.7 21.6 66.6 21.3 18.4 69.8 5.05
' 98.6 100. 99.3 100. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 96.1 105. 107. 110. 115. 107. N/A 111. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 105. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 108. N/A N/A N/A N/A N/A N/A N/A N/A
Record M o d ifie d
File Name
n 8101119a. wiff s101119a.wiff s101119a.wi1T s101119a.wiff n s101119a.wiff
s101119a.wiff si01119a.wiff
is101119a.wiff El is101119a.witr El is101119a.wiff El is101119a.wiff El |s101119a.wiff El ;s101119a.wiff El :si1119a.wiff El is101119a.wiff El is101119a.wiff El ;s101119a.wiff
El is101119a.wiff El !s101119a.wiff El is101119a.wiff
ls101119a.wiff El ;s101119a.wiff is101119a.wiff El is101119a.wiff El is101119a.wiff s101119a.wiff 0 is101119a.wiff El js101119a.wiff El isi1119a.wiff El is101119a.wiff El s101119a.wiff
El Is101119a.wiff is101119a.wiff n s101119a.wiff
|s101119a.wiff El is101119a.wiff El js101119a.wiff
El is101119a.wiff El l O i n ^ w i f f "1 El s i o i i i 9 i . w i f
El is101119a.wiff El is101119a.wiff El [s101119a.wiff
El |s101119a.wi1T s101119a.wiff El is101119a.wiff
is101119a.wiff El is101119a.wi(f El is101119a.witr E l !s101119a.wiff 0 is101119a.wiff El is101119a.wiff El ls101119a.wiff El l$101119a.wiff
Printing Date: Thursday, December 23, 2010 Printing Time: 1:23:19 PM
Page 7 of 8
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Results Name: sl01H9a.rdb
iSam pteNam e
1 Sam pleID
: ;..; >
|"379` [$10119a076 GLP10-01-01-12-010" Dup DAL S_S 607R 004 Lab Duplicate
360 !s101119a077 GLP10-01-01-12-010 LMS DAL SS 607R 0 0040 Lab Matrix Spike
361 1s101119a078 f i o 006-25 solvent biank
"'
"" ""
362 is101119a079 EC-101117-06 5 ng Extracted Curve Point
383 is101119a080 10 006-25 solvent biank
384 :Sl01119a081 GLP10-01-01-12-011 DAL S S 607R 0 0270
365 is 1 0 lil9 a 0 8 2 G LP10 O 4D-2 - 0 1 Dup DAL SS 67R 0270 Lab Duplicate
366 s101119a083 GLP10-01-01-12-011 LMS DAL SS 607R 0 0270 Lab Matrix Spike
387 s101119a084 GLP10-01-01-12-012 DAL SS 609R 0 0000
388 s101119a085 GLP10-01-01-12-012 Dup DAL SS 609R 0 0000 Lab Duplicate
1369 Is101119a086 GLP 10-01-01-12-012 LMS DAL SS 609R 0 0000 Lab Matrix Spike
390 ; i$101119a087 GLP 10-01-01-12-013 DAL SS 609R 0 0010
391 is101119a088 GLP1001-01-12-013 Dup DAL SS 609R 0 0010 Lab Duplicate
392 !s101119a089 GLP1001-01-12-013 LMS DAL SS 609R 0 0010 Lab Matrix Spike
393 !s101119a090 10 006-25 solvent biank
1394 [s101119a091 EC-1011 17 05 2.5 ng Extracted Curve Point
395 is101119a092 10 006-25 solvent biank
396 s101119a093 GLP1001 01 -1 2 -0 14 DAL SS 609R 0 0040
397 is101119a094 GLP10 0 1 0 1 -1 2 0 1 4 Dup DAL SS 609R 0 0040 Lab Duplicate
396 :s101119a095 GLP1001 01 -1 2 -0 14 LMS DAL SS 609R 0 0040 Lab Matrix Spike
399 is101119a096 GLP1001 01 -1 2 -0 15 DAL SS 609R 0 0110
400 Is101119a097 GLP1001 01 -1 2 -0 15 Dup DAL SS 609R 0 0110 Lab Duplicate
401 is101119a098 GLP1001 01 -1 2 -0 15 LMS DAL SS 609R 0 0110 Lab Matrix Spike
402 s101119a099 10 006-25 solvent biank
403 [s101119a100 EC-101117-06 5 ng Extracted C une Point
404 is101119a101 10 006-25 solvent biank
Analyte Peak Name
Use
Sam ple Type
Record
CoTM ""
(n g /m L )
T(mimlne)
Analy" IS Peak
5SLT
IS Peak Area
(counts)
IS Concentration
(ng/mL)
IS Retention
Time (min)
Calculated Concentration
(ng/mL)
Accuracy:
Record ; . Modified Fil Name
PFS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS
Unknown Unknown Double Biank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank
~[N/A
IN/A "
iO.O
"" T3.233
113.230
" IT3.165
"241295 M8PFOS " 47225
365918 M8PFOS 48180
313 " M8PFOS 12
798
~ 2 96 N/A '
0 [5.00
jO.OO
[13.225 [13.336
191935 IM8PFOS 46132 46 M8PFOS 61
2.98 N/A
jN/A
[13.239 1606
M8PFOS 43437
2.98
jN/A
i 13.209 3142
[M8PFOS 52840
2.98
[N/A
113.215 41137 iM BPFOS 47128
2.96
iN/A
i 13.205 937832 [M8PFOS 47268
2.98
[N/A
[13.228 1047960 M8PFOS 51849
2.98
IN/A
[13.221 2460644 M8PFOS 50262
2.98
IN/A
i 13.216 318491 M8PFOS 40990
2.98
iN/A
[13.213 439930 [M8PFOS 51446
2.98
iN/A
[13.218 2027148 [M8PFOS 47760
2.98
iO.OO
113.366 36
[M8PFS 36
N/A
R I2.50 iO.OO
|13.215 113.256
107805 [M8PFOS 50118 325 [M8PFOS 24
2.98 N/A
N/A
113.225 56976 [M8PFOS 48154
2.98
iN/A
113.215 51992 IM8PFOS 49804
2.98
iN/A
113.219 253225 M8PFOS 49765
2.98
iN /A
113.233 6775
IM8PFOS 54137
2.98
iN/A
i 13.246 7245
M 8PFO S 53248
2.98
iN/A
i 13.205 52911 [M8PFOS 49908
2.98
iO.OO
! 13.276 145
[M8PFOS 0
N/A
El 5.00 0.00
M3.225 =13.326
201500 M8PFOS 50728 120 M8PFOS 109
2.98 N/A
13.2 ' ~ 6.32 13.2 " 9 98 13.3" " N/A
13.2 5.13
13.2
N/A
13.2
<0
13.2
<0
13.2
1.00
13.2 25.0
13.2
25.5
13.2
63.3
13.2 9.67
13.2
10.7
13.2 54.2
13.5 N/A
13.2
2.60
13.3 N/A
13.2 1.44
13.2 1.22
13.2
6.29
13.2 0.0661
13.2 0.0797
13.2 1.24
0.00
N/A
13.2 4.89
13.2 N/A
" N/A
N/A N/A 103. N/A N/A N/A N/A W N/A N/A N/A N/A N/A N/A 104. N/A N/A N/A N/A N/A N/A N/A N/A 97.8 N/A
"
' 3 ~ "!s109a7w iff ~
[>3 [s101119a.wiff
"]s101119a.wiff
0 is101119a.wiff
n is101119a.wiff 0 is101119a.wiff 0 s101119a.wiff [s101119a.wiff El is101119a.wiff 0 ;s101119a.wiff 0 [s101119a.wiff El is101119a.wiff El is101119a.wiff El [s101119a.wiff is101119a.wiff El ;s101119a.wiff is101119a.wiff
El is101119a.wiff
El is101119a.wiff El is101119a.wiff El ts101119a.wiff
El ls101119a.wiff
is101119a.wiff :s101119a.wff [s101119a.wiff is101119a.wiff
Printing Date: Thursday, December 23, 2010 Printing Time: 1:23:19 PM
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3M Study: GLP10-01-02 Interim Report 12
30 35 Analyte Cone. / IS Cone.
40
Page 1 of 1
Page 77 of 419
Stan VI660305 3M Environmental Lab
105:
100:
95:
90:
85:
80:
75:
70:
65: (0 0)
< 60: CO
OS 5 5 :
<D
<
50:
CO 4 5 : <
40:
35:
30:
25:
20:
15:
10:
5:
0:
Printing Date: Thursday, December 23, 2010 Printing Time: 1:25:52 PM
3M Study: GLP10-01-02 Interim Report 12
Results Name: sl01119a.rdb
30 35 40 Analyte Cone. / IS Cone.
Page 1 of 1
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Results Name: sl01119a.rdb
Printing Date: Thursday, December 23, 2010 Printing Time: 1:27:04 PM
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
O'*
l { , * 2 3 ^ 1 Page 79 of 419
Stan V1660305 3M Environmental Lab
64 j 60:
55:
50:
45:
40:
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<
to 3 5 : <00) < 30-
<1>
>%
<0
c
< 25:
20:
15-
10:
5-
0-
Printing Date: Thursday, December 23, 2010 Printing Time: 1:27:30 PM
3M Study: GLP10-01-02 Interim Report 12
Results Name: sl01119a.rdb
30 35 40 Analyte Cone. / IS Cone.
Page 1 of 1
, V Page 80 of 419
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Results Name: slOH19a.rdb
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G lP lO -0 1 -0 2-12 Range Finding (Screening) Analysis Data
3M Study: GLP10-01-02 Interim Report 12
Page 283 of 419
ENVIRONMENTAL LABORATORY
Sample set ID # Urns #
N/A GLP10-01-01-12
INTERNAL CHAIN-OF-CUSTODY
Sample Internal Transfer
E xact Copy o f O riginal U-tz-
In itial
D ate
Sample Description: Decatur Soils
INTERNAL CHAIN OF CUSTODY
# 3M S a m p le ID s
1 GLP10-01 -01-12-001 2 GLP10-01 -01-12-002
O u t: s to ra g e ID
In itJd a te
In : s to ra g e ID
U )<ko\
0ncm. fo -e -tc > O < |
In itJ d a te O u t: s to ra g e ID G m M -ijo -K
In itJd a te
ln : s to ra g e ID
In itJd a te
C o m m e n ts/ln itJd a te
___ ' --
3 G LP10-01 -01-12-003
------'
4 GLP10-01-01-12-004
5 GLP10-01-01-12-005
6 GLP10-01-01-12-006
7 G LP10-01 -01-12-007
8 GLP10-01 -01-12-008
9 GLP10-01-01-12-010
10 G LP10-01-01-12-011 11 GLP10-01-01-12-012 12 GLP10-01-01-12-013
i /
13 G LP10-01-01-12-014 14 G LP10-01-01-12-015
1
V Vy
15 , w -,.
A 't - -AL' . * -- .
4 t * * s s ^ a s '- '.- v * W V ' ' . .
* .. *
16 f . 17 * (*
ta t win .v*' ipyn
M
!
'-.w -A T
.**, v ^ ^ s e w s s s ^ ^ a s s i t r i
' . ' -' '
> . . . . . . 15
8M M M P 8J5wBjn^^K^SK3n8gCSw@,^t^f^ v -
-- a racwr^S^ISaNoeWar a w ! &
18 "
nRM nHM M K3
HBM BI
.* :
M V * ; m.
-
v
19
20
2 T C < *
22 sfe
.s s A te fiM ri*' f j * 9*a*>s*iS**S*66iiaiQsa88iieateaF
nMnaHPb^'
^4S E K R B H I
^89H B H
a it o
m
a^fc'i^r.-^VliS: w^MunWVflu9tt*tnAxr*SS!%<
- -
*3 *
S-* V f-4- ^SflSPMSBS
<; * ,. ' S i fa& K Svsr* 5 * '
23^
24-:
p w 4^4>5lireKSiiSS " -iiFS-V1*.
ue^
HHBBTOI* *XKW*'w-V4raMretsW'v
hbh
*1is!SMt9KTK&*3-%.iMBgeTO&H
m s m a r n i iic s * * s s ^ 'S ' 1*-^ f " .
* m ir t't 'i : ^ -' ..
255*
an
ifV4s4*i.'WS?
sS4aoes^
HS
W V 4 . * A8^tjra**^>ri6fg4iaibe3||4Hnni*n^la~gll
f
m
mH M H i Tiipm/ liBUnrOll'T
2 8 ^ WCMW
r49|i Y ' ^iiW V 88BaaMWMWEt r -
W c-;
29
30 '
W8RSBB5SSW W-'Jfr'SW S* i i s s a s s i .j.,-
-v
aaHavsasb?- pprp?a `yVr-; WW ^s^WwW*- -
> i;- * * * * * * '
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
Page 284 of 419
GLP10-01-01-12
ETS-8-053
Samples Extracted 20-0ct-2010
S a m p le ID
1 E C -1 0 1 0 2 0 -0 1 E C -1 01020-02 E C -1 0 1 0 2 0 -0 3 E C -1 0 1 0 2 0 -0 4 E C -1 0 1 0 2 0 -0 5 E C -1 0 1 0 2 0 -0 6 E C -1 0 1 0 2 0 -0 7 E C -1 0 1 0 2 0 -0 8 E C -1 0 1 0 2 0 -0 9 E C -1 0 1 0 2 0 -1 0 E C -1 0 1 0 2 0 -1 1 M B -101020-01 M B -101020-02 M B -101020-03 M B -1 01020-04 M B -101020-05 M B -101020-06 L C S -1 0 1 0 2 0 -0 1 L C S -1010 2 0 -0 2 LC S-101020-03 LC S-101020-04 LC S-101020-05 LC S-101020-06 G LP10-01-01-12-001 G LP10-01-01-12-002 G LP10-01-01-12-003 G L P 1 0 -0 1 -0 1 -1 2 -0 0 4 G LP 10-01-01-12-005 G LP 10 -01-01-12-006 G L P 10-01-01-12-007 G LP10-01-01-12-008 G LP 10 -01-01-12-010 G LP 10-01-01-12-011 G L P 1 0 -0 1 -0 1 -1 2 -0 1 2 G L P 10-01-01-12-013 G L P 10-01-01-12-014 G L P 10-01-01-12-015
S am p le Description
Soil M axtrix Soil W eight ID U s e d (g )
S p ike ID
S p ik e Volum e
(uL)
In te rn a l Standard
ID
Internal StandardV olum e (uL)
S u rro g a te Spike ID
S u rro g a te S p ik e
Volum e (uL)
Add 8 mL E x tra c tio n
S o lv e n t
Sonicate 1 hr
C e n trifu g e
Com m ents
2 0.2 np Extracted Curve Point 0 .5 no Extracted Curve Point 0 .7 5 no Extracted Curve Point 1 ng E xtracted Curve Point 2 .5 nq Extracted Curve Point 5 nq Extracted C urve Point 10 nq Extracted Curve Point 25 nq Extracted Curve Point 50 nq Extracted Curve Point 100 nq Extracted Curve Point 200 nq Extracted Curve Point M ethod Blank 1 w /o IS Method Blank 2 w /o IS Method Blank 3 w /o IS Method Blank 4 w/ IS M ethod Blank 5 w / IS Method Blank 6 w / IS 3 nq LC S in T C R -8 4 2 3 nq LC S in T C R -8 4 2 3 nq LC S in T C R -8 4 2 30 nq L C S in T C R -8 4 2 30 nq LCS in T C R -842 3 0 nq LC S in T C R -8 4 2 DAL SS TR IP 0 0000 DAL SS 611R 0 0000 DAL SS 6 1 1R 0 0010 DAL S S 611R 0 0040 DAL SS 6 1 1R 0 0050 DAL SS 607R 0 0000 DAL SS 607R 0 0010 DAL SS 607R DB 0010 DAL SS 607R 0 0040 DAL SS 607R 0 0270 DAL SS 609R 0 0000 DAL S S 609R 0 0010 DAL SS 609R 0 0040 DAL SS 609R 0 0110
3 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122 10 005-122
. *1 ' - * i
wm m im m m
4 1.1242 1.0930 1.1198 1.1729 1.1069 1.1034 1.1869 1.1505 1.1568 1.1589 1.1123 1.1096 1.1765 1.1372 1.1251 1.1816 1.1357 1.1376 1.1130 1.1814 1.1648 1.1751 1.1608 1.1480 1.7229 1.5972 1.2088 2.0227 1.2511 1.2678 1.1072 1.7305 1.1436 1.0301 1.2545 1.3446 1.9548
5 10 005-167 10 005-167 10 005-167 10 005-167 10 005-166 10 005-166 10 005-166 10 005-165 10 005-165 10 005-165 10 005-165
._
6 20 50 75 100 25 50 100 25 50 100 200 *
10 005-164 10 005-164 10 005-164 10 005-163 10 005-163 10 005-163
--*
30 30 30 30 30 30
-
1 * - .* * ' .
_
*
7 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9
/
10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9 10 006-9
8 30 30 30 30 30 30 30 30 30 30 30 ii illi ' ' ~ **' "i
9 10 005-133 10 005-133 10 005-133 10 005-133 10 005-132 10 005-132 10 005-132
10 006-2 10 006-2 10 006-2 10 006-2
10 20 50 75 100 25 50 100 25 50 100 200
S lifllill!
30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 ' 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30 30 10 005-132 30
11 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM
12 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM
13 GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM GPM
14 . /
/ / /
i {
/
1
I *
/ 1'
ji
I i 1
I 1
j
/
I 1 I I
Col 3 & 4: i f *
Balance ID: 900
Col 5 & 6: C Pipette ID: 4215537
(O - L /C , " , S
C0 1 7 & 8: 6 0 ** I t f - Z 0 ' 10
Pipette ID: 4215537
Col 9 & 10: 0 ** / d - Z & ' t 0
Pipette ID: 4215537
C o m : 6 ***
Extraction Solvent ID: 10 006-13
Col 12: &
A > '& >
Sonicator ID: Q E J 100595003
COM3: A 4 "* / 0 - C W 0
Centrifuge ID: 021188-55 10 min @ 300 0 RPM C o l14 :
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
Exact Copy o f Original G f>rt ______ H - I L . - J O
Initial
D ate
Page 285 of 419
MULTI-COMPONENT PREPARATION LOG
Book No. 10 006
Page No. ____ 9
Description: F C. j S M IX
Date Prepared: 10 - I 2 -~ I D
Prepared By: C T O _________
* 5 7 0 ___Storage Location:
Expiration Date: M - I 2-~~ I O
Solvent: A c e + o n i t r t < e 3 M T ra c e #: 7 f s H 0 - - u i l 2 . Expiration Date: M - 1 - J H _______
Description
*0z PF8S
Standard ID #
10 006-9
Component Standard
ID#
Cone, or Purity
Expiration Date
Weight or Volume
Corrected Weight
Balance ID
Final Concentration (jU V ^W L}
lO D O S -ife S <B< 2
V 7-IS Si
--
-- >.101
MPFHxS
MS p ro A ia s p f o ^
|D 0O 5-IIp7 7 7 -3
io - Z M H `5 3 ^ 0
--
-- 0 4 0 0
1D o o s - n o MW-A lm L, [ 0 - T V ' \ %
/o o o s -n Hl-%
7 -3 -1 7 5 2 -M i-
--- --
--
--
0.0778 0-0^7H
J ri ^ 4 ? 's/ j t/xj
Final Volume
Exact Copy o f Original
3M Study: G L p llt0 ) io 2 Interim Report 12
'
O S td
'2.6'lrVll'
Approximate Concentration of the mix
0 -1
Date:
^
SINGLE COMPONENT PREPARATION LOG
A nalyst:________________________________
Book No. Page No.
10 005 122
Description: _ ______- r a ^ - P v s , ______ s o > / ________________
Stock Number:
'TC JC -PV ^
/to '/SOS ' .
I <K
Ba.ancs.D:
9Q
Concentration or
. /--
Purity:___________ ________________________________
Other Correction
'----------------- --- -
F a c to r s :____________________________
Y 5 D / Q,/( ? S .Corrected Weight:
Solvent and TN -A Number:
Final Volume:
Storage Location:
A tti
Final Concentration: Expiration Date:
ExactCopy of O tW "^ C4*_____ . 11 ' D ate
3M Study: GLP10-01-02 Interim Report 12
Review ed by: Signature,
n-t
Page 287 of 419
Description: Date Prepared:
Prepared By: Storage Location:
Expiration Date:
gp\lQ
] O ' Z .O - IO
G ? r \ ___________
a -c v
S-I-/I
MULTI-COMPONENT PREPARATION LOG Book No. 10 006 Page No. ___ 13^
Description
H -.o . K
Standard ID #
10 006-13
Component Standard Cone, or
ID # Purity
TNoS'-dZC
Expiration Date
Weight or Volume
Balance ID
Corrected Weight
Final Concentration
--
-
T N i "d > 3 l|
3 'i'll
/Oc`*L' --
--
~u>%
r\tyf
Final Volume
'V- 5
Approximate
go ; z>
L Concentration of the mix
Exact Copy o f Original
3M Stufly*GI_P10-01-02
Interim
1
Reviewed y:
//-
Date
Page 288 of 419
DATA REVIEW SUMMARY FORM
Date:
12/23/2010
Data Analyst: GPM
Study #:
G L P 10-01-02-12
Description: Decatur Soils
Batch:
sl01022c
Results Table: s!01022c.rdb Instrument: Stan V1660305 Method(s): ETS-8-053.0
A n aly te:
PFBS_____________ '__________
Comments/Justifications: _1________________
Acceptable Linear Range: 0.500 n g to200 ng
Internal Standard:
MPFBS__________
LOQ:
0.500 ng______________________
Data Review Sign-Off
Analyst Review and Acceptance of M anual Integrations N ame / Date:
Technical and M anual Integration Review Name / Date:
Comments / Justifications: 1 Lowest curve point was dropped because it was not 2x the area counts o f the method blanks with IS and surrogate.___________________________________
Analyte:
P F H x S _______________________
Comments/Justifications: N/A_____________
Acceptable Linear Range: 0.200 ng to 200 ng
Internal Standard:
MPFHxS_________
LOQ:
0.200 ng______________________
A n aly te:
PFOS
Comments/Justifications: Acceptable Linear Range:
Internal Standard:
LOQ:
0.200 ng
N /A _____________ 0.200 n gto200 ng M 8PFO S________
A n aly te:
M PFOS
Comments/Justifications:
Acceptable Linear Range:
Internal Standard:
LOQ:
0,200 ng
N/A_____________ 0.200 ng to 200 ng M8PFOS
A n aly te:
N/A
Comments/Justifications: N/A
Acceptable Linear Range: N/A
Internal Standard:
N/A
LOQ:
N/A_____________
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1 Page 289 of 419
Stan: API4000: V1660305
DATE 10/22/10
ANALYST: GPM
STUDY NUMBER: E l0-01-02-12 Matrix: Soils
Injection volume: 25 uL
Electrode: Turbo ion spray
Mobile Phase: (A12 mM ammonium acetate (B) acetonitrile TN-A- or standard number (A) 10 005-161 IB! tn10-0180-4/8
page 1/1
Guard (pre-autosampler) column Prism RP
Size: 2.1 mm X 50 mm__________ Type: C l2 Sphere size: 5______
Part number: 32105-052130 Lot number: 9411 Serial number 0903542
Analytical column 1 Oasis HLB
Size: 3 X 20 mm________ Type: NA
Sphere size: 25 um
Part number: 186002039 serial number: 006A300055105 03
Analytical column 2 Betasil C l8
Size: 2.1 mm X 100 mm_________ Type: C l8 Sphere size: 5______
Part number: 70105-102130 Lot number: 10559 Serial number 0701663T
Printed: Friday, October 22, 2010 11:27 AM
3M Study: GLP10-01-02 Interim Report 12
iT > w
Page 290 of 419
ETS Stai VI 660305
Project: P:\Lab_lnstrumentData\Stan\Stan Data Files\Projects\f!uorochemicals\soil Batch:s101022c Tab:Sample Set:SET01 AcqMethod:ets8-53 23 min Sulfonates Sample
Sample Name
Sample ID
Vial Pos ition
Data File
' (MO
C om m ents
1 s101022c001 ,10 006-13 solvent blank
86
2 s101022c002 ) 10 006-13 solvent blank
86
3 s101022c003 'Warm Up EC-101020-06 5 ng
46
4 ,s101022c004 WarmUp EC-101020-06 5 ng
46
5 s101022c005 Warm Up EC-101020-06 5 ng
46
6 s101022c006 ; 10 006-13 solvent blank
86
7 s101022c007 10 006-13 solvent blank
86
8 s101022c008 10 006-13 solvent blank
87
9 s101022c009 i EC-101020-01 0.2 ng Extracted Curve Point
41
10 s101022c010 <EC-101020-02 0.5 ng Extracted Curve Point
42
11 s101022c011 EC-101020-03 0.75 ng Extracted Curve Point
43
12 s101022c012 EC-101020-04 1 ng Extracted Curve Point
44
13 s101022c013 :EC-101020-05 2.5 ng Extracted Curve Point
45
14 s101022c014 ;EC-101020-06 5 ng Extracted Curve Point
46
15 s101022c015 EC-101020-07 10 ng Extracted Curve Point
47
16 s101022c016 EC-101020-08 25 ng Extracted Curve Point
48
17 s101022c017 EC-101020-09 50 ng Extracted Curve Point
49
18 s101022c018 ,EC-101020-10 100 ng Extracted Curve Point
50
19 s101022c019 EC-101020-11 200 ng Extracted Curve Point
51
20 s101022c020 10 006-13 solvent blank
87
21 s101022c021 ' 10 006-13 solvent blank
87
22 s 101022c022 ! 10 006-13 solvent blank
87
23 s101022c023 :10 006-13 solvent blank
88
24 s101022c024 MB--101020-01 Method Blank 1 w /o IS
52
25 s101022c025 ,MB--101020-02 Method'Blank 2 w /o IS
53
26 s101022c026 MB--101020-03 Method Blank 3 w /o IS
54
27 s101022c027 MB--101020-04 Method B la n k 4 w / IS
55
28 ;Sl01022c028 .MB--101020-05 Method B la n k w / IS
56
29 s101022c029 MB--101020-06 Method B la n k w / IS
57
30 s101022c030 LCS-101020-01 3 ng LCS in TCR-842
58
31 s101022c031 LCS-101020-02 3 ng LCS in TCR-842
59
32 s101022c032 LCS-101020-03 3 ng LCS In TCR-842
60
33 l s101022c033 LCS-101020-04 30 ng LCS In TCR-842
61
34 ;s101022c034 LCS-101020-05 30 ng LCS in TCR-842
62
35 |s101022c035 LCS-101020-06 30 ng LCS in TCR-842
63
36 Is 101022c036 ,10 006-13 solvent blank
88
37 js101022c037 IEC-101020-05 2.5 ng Extracted Curve Point
45
38 Is10i022c038 110 006-13 solvent blank
89
39 's101022c039 ;GLP10-01-01-12-01 DAL SS TRIP0 0000
64
40 's101022c040 ;GLP10-01-01-12-002 DAL SS 611R0 0000
65
41 ' s 101022c041 GLP10-01-01-12-003 DAL SS 611R0 0010
66
42 s101022c042 GLP10-01 -01-12-004 DAL SS 611R0 0040
67
43 s101022c043 'GLP10-01-01-12-005 DAL SS 611R0 0050
68
44 s101022c044 GLP10-01-01-12-006 DAL SS 607R 0 0000
69
45 s 101022C045 GLP10-01 -01 -12-007 DAL SS 607R 0 0010
70
46 s101022c046 GLP10-01-01-12-008 DAL SS 607RDB 0010 47 s101022c047 GLP10-01-01-12-010 DAL SS 607R 0 0040
71
72
48 s101022c048 GLP10-01-01-12-011 DAL SS 607R 0 0270
73
49 s101022c049 10 006-13 solvent blank
89
50 s101022c050 EC-101020-06 5 ng Extracted Curve Point
46
51 s101022c051 10 006-13 solvent blank
'
90
52 s101022c052 GLP10-01-01-12-012 DAL SS 609R 0 0000
74
53 s101022c053 GLP10-01-01-12-013 DAL S S 6 0 9R 0 0010
75
54 s101022c054 GLP10-01-01-12-014 DAL SS 609R 0 0040
76
55 s101022c055 GLP10-01-01-12-015 DAL SS 609R 0 0110 56 s101022c056 10 006-13 solvent blank
77
90
57 s101022c057 EC-101020-05 2.5 ng Extracted Curve Point
45
58 s101022c058 10 006-13 solvent blank
90
s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 S101022C 25.000 s101022c 25.000 |s101022c 25.000 s101022c 25.000 S101022C 25.000 S101022C 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s 101022c 25.000 S101022C 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 S101022C 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 S101022C 25.000 s 101022c 25.000 s 101022c 25.000 s101022c 25.000 s 101022c 25.000 S101022C 25.000 s 101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 S101022C 25.000 s101022c 25.000 s101022c 25.000 s101022c 25.000 s101022cn 25.000 s101022c 25.000 s101022c 25.000
| ]
[
|
'
.
<
'
Printing Date: Friday, October 22, 2010
Printing Time: 11:27:54 AM
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 1
- \t>
Page.291 of 4 l9
ETS Stan V166030S
Acquisition Information:
Acquisition Method: Created: Last Modified: Comment: Synchronization Mode: Auto-Equilibration: Acquisition Duration: Number Of Scans: Periods In File: Acquisition Module: Software version Agilent LC Purrp Method Properties Punp Model: Minimum Pressure (psi): Maximum Pressure (psi): Dead Volume (pi): Maximum Flow Ramp (ml/min2): Maximum Pressure Ramp (psi/sec):
ETS 8-53 23 min Sulfonates.dam Friday April 09 2010 13; 54: 09 PM Friday April 09 2010 16: 54: 27 EM Method for Sulfonates 23 minute gradient LC Sync Off 23min0sec 2281 1 Acquisition Method Analyst 1.4.2
Agilent 1100 LC Binary Purrp 0 .0 5801.0 40.0 100.0 290.0
Step Table:
Step
C 1 2 3
Total Time (min) 0.00 3.00 3.50
17.00
4 17.50 e 19.50
6 20.00
7 23.00
Flew Rate(pl/min) 400 400 400 400 400 400 400 400
A (%)
97.0 97.0
70.0 40.0 10.0 10.0 97.0 97.0
B (%) 3.0 3.0 30.0 60.0 90.0 90.0 3.0 3.0
Left Ccrrpressibility: 50.0
Right Compressibility: 115.0
Left Dead Volume (pi): 40.0
Right Dead Volume (pi): 40.0
Left Stroke Volume (pi):
Right Stroke Volume (pi):
Left Solvent:
A1
Right Solvent:
B2
-1.0 -1.0
Agilent Autosarrpler Properties
Autosarrpler ttodel: Syringe Size (pul):
Agilent 1100 Thermo Autosarrpler 100
Injection Volume (pi): 25.00
Draw Speed (pl/min): 200.0 Eject Speed (pl/min): 200.0
Needle level (mm):
0.00
Terperature Control Enabled Setpoint (4 - 40 C): 10
Wash is not used
Use Custom Injector Program
No
Agilent Column Oven Properties
Left Temperature (C):
30.00
Right Temperature (C): 30.00
Temperature Tolerance +/- (C):
1.00
Start Acquisition Tolerance +/- (C):
0.50
Time Table
(Used)
Column Switching Valve Installed
Position for first sanple in the batch: Right
Use same position for all samples in the batch
Total Time (min)
Valve P o s i t i o n
0.0C Left
5.0C Right
Period 1:
Scans in Period:
2281
Relative Start Time: 0.00 msec
Experiments in Period: 1
Period 1 Experiment 1:
Scan Type: Polarity: Scan Mode: Ion Source: Resolution Ql: Resolution Q3: Intensity Thres.: Settling Time: MR Pause:
MFM (MFM)
Negative
N/A
Turbo Spray (M t Unit 0.00 cps 0.0000 msec 5.0070 msec
Printing Date: Friday, October 22, 2010
Printing Time: 11:29:27 AM
3M Study: GLP10-01-02 Interim Report 12
Page 1 of 3
rge 2 9 2 o f 4 9 1
ETS Stan V1660305
MCA: No Step Size:
0 .0 0 arru
Q1 Mass (arru) 399.OC
Q3 toss (arru) 99.00
Ewell (msec) 50.00
Paran DP CE CXE
Start Step -100.00 -100.00 -54.00 -54.00 -5.00 -5.00
Q1 toss (arru) 399.OC
Q3 toss (arru) 80.00
D^ell (msec) 50.00
Paran DP CE CXE
Start Step -100.00-100.00 -82.00 -82.00 -5.00 -5.00
Q1 toss (anu) 403.OC
Q3 toss (arru) 84.00
Dwell (msec) 50.00
Paran DP CE CXF
Start Step -100.00-100.00 -82.00 -82.00 -5.00 -5.00
Q1 toss (anu) 299.OC
Q3 toss (arru) 99.00
Ewell (msec) 50.00
Paran DE CE CXP
Start Stop -65.00 -65.00 -44.00 -44.00 -15.00 -15.00
Q1 toss (arru) 299.OC
Q3 toss (arru) 80.00
Dwell (msec) 50.00
Paran DE CE CXE
Start Step -65.00 -65.00 -64.00 -64.00 -5.00 -5.00
Q1 toss (anu) 303.OC
Q3 toss (anu) 84.00
Dwell (msec) 50.00
Paran DE CE CXE
Start Step -65.00 -65.00 -64.00 -64.00 -5.00 -5.00
Q1 toss (anu) 499.OC
Q3 toss (anu) 80.00
Dwell(msec) 50.00
Paran DE CE CXE
Start Step -120.00 -120.00 -98.00 -98.00 -5.00 -5.00
'
Q1 toss (arru) Q3 toss (anu)
499.OC
99.00
Dwell(msec) 50.00
Paran DE CE CXP
Start Step -120.00 -120.00 -82.00 -82.00 -5.00 -5.00
Q1 toss (arru) Q3 toss (anu)
499.OC
130.0C
Dwell(msec) 50.00
Paran DE CE CXE
Start Step -120.00 -120.00 -66.00 -66.00 -7.00 -7.00
Q1 toss (arru) 503.OC
Q3 toss (anu) 80.00
Dell (msec) 50.00
Paran DE CE CXE
Start Step -120.00-120.00 -98.00 -98.00 -5.00 -5.00
Q1 toss (arru) 507.0C
Q3 toss (amu) 80.00
Dwell (msec) 50.00
Paran DE CE CXE
Start Step -120.00-120.00 -98.00 -98.00 -5.00 -5.00
Parameter Table(Period 1
CAD:
6.00
CUR:
35.00
GS1:
45.00
GS2:
60.00
IS: -4500.00
TEN:
450.00
ihe:
CN
EE -10.00
Experiment
1):
Printing Date: Friday, October 22, 2010
Printing Time: 11:29:27 AM
3M Study: GLP10-01-02 Interim Report 12
Page 2 of 3
Page 293 of 419
ETS Stan V1660305
Printing Date: Friday, October 22, 2010
Printing Time: 11:29:27 AM
3M Study: GLP10-01-02 Interim Report 12
Page 3 of 3
Page 294 of 419
Stan V1660305 3M Environmental Lab
Results Name: sl0l022c.rdb
Sample Name
Sam ple ID
h 8l lT2c001 " 10 006-13 solvent blank
2 s101022c002 10 006-13 solvent blank 3 ' S101022C003 W arm Up EC-101020-06 5 ng 4 s101022c004 Warm Up EC-101020-06 5 ng 5 s101022c005 Warm Up EC-101020-06 5 ng 6 s101022c006 10 006-13 solvent blank 7 s101022c007 10 006-13 solvent blank 8 S1D1022C008 10 006-13 solvent blank 9 s101022c009 EC-101020-01 0.2 ng E xtracte d Curve Point 10 s101022c010 EC-101020-02 0.5 ng E xtracted Curve Point 11 s101022c011 EC-101020-03 0.75 ng E xtracted Curve Point 12 s101022c012 EC-101020-04 1 ng E xtracted Curve Point 13 S101022C013 EC-101020-05 2.5 ng E xtracte d Curve Point 14 s101022c014 EC-101020-06 5 ng E xtracted Curve Point 15 S101022C015 EC-101020-07 10 ng E xtracted Curve Point 16 . S101022C016 EC-101020-08 25 ng E xtracted Curve Point 17 . s101022c017 EC-101020-09 50 ng E xtracted Curve Point 18 S1022C8 EC-101020-10 100 ng E xtracte d Curve Point 19 81010220019 EC-101020-11 200 ng E xtracte d Curve Point 120 s101022c020 10 006-13 solvent blank <21 s101022c021 10 006-13 solvent blank *22 S101022C022 10 006-13 solvent blank 23 s101022c023 10 006-13 solvent blank 24 s101022c024 MB--101020-01 Method Blank 1 w/o IS 25 S10022C025 MB-10Vd2CW)2 Method B lank 2 w/o IS 26 s101022c026 MB--101020-03 Method Blank 3 w /o IS 27 s101022c027 MB--101020-04 Method Blank 4 w / IS 28 s101022c028 MB--101020-05 Method Blank 5 w / IS 29 S101022C029 MB--101020-06 Method Blank 6 w / IS 30 s101022c030 LCS-101020-01 3 ng LCS in TCR-842 31 s10i22c31 LC S -10102002 3 ng LCS in TCR-842 32 S101022C032 LCS-101020-03 3 ng LCS in TCR-842 33 s101022c033 LCS-101020-04 30 ng LCS in TCR-842 34 s101022c034 LCS-101020-05 30 ng LCS in TCR-842 35 s101022c035 LCS-101020-06 30 ng LCS in TCR-842 36 s101022c036 10 006-13 solvent blank 37 s10i22c37 EC-101020-05 2 .5 ng E xtracte d Curve Point 38 ' S10Q22C038 10 006-13 solvent blank 39 s101022c039 GLP10-01-01-12-001 DAL SS TRIP 0 0000 140 , s101022c040 GLP10-01-01-12-002 D A L S S 6 1 1R 0 0000 41 s101022c041 G LP 10-0101-12-003 DAL S S 611R 0 0010 42 s101022c042 GLP10-01-01-12-004 DAL SS 611R 0 0040 43 S101022C43 G L P 10-010 1-12-005 DAL SS 611R 0 6050 44 s101022c044 GLP10-01-01-12-006 DAL SS 607R 0 0000 45 s101022c045 GLP 10-01 -01 -12-007 DAL S S 607R 0 0010 46 s101022c046 GLP 10-01 -01-12-008 DAL SS 607R DB 0010
47 s101022c047 GLP 10-01 -01-12-016 DAL SS 607R 6 00 40
48 s101022c048 GLP10-01-01-12-011 DAL SS 607R 0 0270 49 S101022C049 10 006-13 solvent blank 50 S101022C050 EC-101020-06 5 ng E xtracted Curve Point 51. s101022c051 10 006-13 solvent blank 52 s101022c052 GLP10-01-01-12-012 D A L S S 609R 0 0000 53 s101022c053 GLP10-01-01-12-013 D A L S S 609R 0 0010
'
Printing Date: Thursday, December 23, 2010 Printing Time: 12:59:10 PM
Analyte Peak Name
MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS MPFOS
Sam ple Type
Double Blank Double Blank Unknown Unknown Unknown Double Blank Double Blank Double Blank S ta n d a rd S ta n d a rd S ta n d a rd Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Quality Control Quality Control Quality Control Quality Control Quality Control Quality Control Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown
Use Record
Analyte -
Analyte Concentration
Retention Analyte Time Peak Area
(ng/m L) (m in) (counts)
IS Peak Name
.oo"
0.00
N/A
N/A
N/A
000
0.00
0.00
[3 0.200 0 0.500 m 0.750 s 1.00
e 2.50 13 5.00 e 10.0 13 25.0
0 50.0 0 100.
13 200. 0.00
0.00
.
0.0
0.00
0.00
0.00
]N /A
|N/A
!n/a
13 3.00 0 3.00 13 3.00 m 3 00 0 3.00 M 3.00
0.00
13 2.50
10.00
N/A
N/A
N/A
; N/A
N/A
N/A
N/A
N/A
N/A
N/A
0.00 0 5.00
0.00
N/A
N/A
13>10" " ' 36 " '
13.538 24
13.679 68235
13.659 68086
13.639 68809
13.669
157
13.619 12
13.720 24
13.710 3522
13.710 7578
13.629
10511
13.689
13949
13.639 33907
13.629 68598
13 669
126918
13.669 345037
13.649 691353
3.679
1312697
3.6 9
2394505
13.740 896
13.548
12
13.578
133
13.881
24
13.861
70
13.780 24
13.911
85
13.649 42246
13.588 44149
13.649 46487
13.619 48544
13.619 45972
13.689 47989
13.629 46637
13.629 43398
13.639 45771
13.649
12
13.649 35108
13.538
12
13.639 44513
13.619 45676
13.649 44480
13.649 48604
13.669 45709
13.629 43349
13.649 45467
13.639 45496
13.629 45030
13.649 44885
13.770
133
13.649 70821
13.790 36
13.750 43509
13.730 44923
M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS
IS Peak
IS
Area Concentration
(counts) : (ng/m L)
IS Retention
C a lcu la te d
Tim e Concentration
Accuracy
(m in )
(ng/mL) y .
85' 61 50617 46600 46253 36 24 73 42091 41449 45189 44002 45034 46888 47764 52357 46562 42575 3849 12 24 48 36 48 12 12 46699 47251 47707 48947 50109 51224 49966 49769 52189 36 51492 48 49778 46125 49719 53158 50505 49850 51291 50047 49123 48464 109 49085 61 50339 47131
/A ................" N/A 1.00 1.00 1.00 N/A N/A N/A 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 .00 . N/A N/A N/A N/A N/A N/A N/A 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 N/A 1.00 N/A 1.00 1.00 1.00 1.00 1.00 .00 1.00 1.00 i. 1.00 N/A 1.00 N/A 1.00 1.00
3 . 9 " ~ ~ / a' " " " " " " ' " " Ki/ a"~ "
13.6
/A
N/A
13.7
4.67
N/A
13.7
5.06
N/A
13.6
5.16
N/A
3 .8
/A
N/A
13.7
N/A
N/A
13.7
N/A
N/A
3.7 0.97
98.6
13.7
0.548
110.
13.7
0.725
96.6
13.7
1.02
102.
13.6
2.57
103.
13.6
5.07
101.
13.7
9.27
92.7
13.6
22.9
91.8
13.6
51.0
102.
13.6
103.
03.
13.6
199.
99.4
13.7
N/A
N/A
13.6
N/A
N/A
3.7
N/A
N/A
13.8
N/A
N/A
13.6
N/A
N/A
3 .5
N/A
N/A
13.6
N/A
N/A
13.7
3.10
N/A
3 .6
3.21
N/A
13.6
3.35
N/A
13.6
3.41
114.
13.7
3.15
105.
13.7
3.22
107.
13.6
3.20
107.
3 .6
2.99
99.5
13.6
3.00
100.
13.6
N/A
N/A
13.6
2.31
92.6
13.7
N/A
N/A
13.7
3.06
N/A
13.6
3.40
N/A
13.6
3.07
N/A
13.6
3.14
N/A
13.7
3.10
N/A
13.7
2.98
N/A
13.6
3.04
N/A
13.6
3.12
N/A
13.6
3.14
N/A
13.6
3.18
N/A
13.7
N/A
N/A
3 .7 5.00
100.
13.6
N/A
N/A
13.7
2.96
N/A
13.7
3.27
N/A
Page 1 of 5
Record M odified
File Name
s 101022c!wiff ~
s101022c.wiff
s101022c.wiff s101022c.wiff
s101022c.wiff s101022c.wiff s101022c.wrff s101022c.wiff s101022c.wiff s101022c.wiff s101022c. wiff
s101022c.wrff
s101022c. wiff s101022c.wiff
n s101022c.wiff
s 022c. wiff
s101022c.wiff s101022c.wiff
s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff sVI 022c. wiff s101022c.wiff s101022c.wiff
s0022c.w iff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff S101022c.wiff s101022c. wiff $101022c. wiff s101022c.wiff s101022c.wiff
S101022c.wiff s0022c.w iff
S101022c.wiff
m 8101022c, wiff
s lO I 022c. wiff
s 022c. wiff
s 101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff
3M Study: GLP10-01-02 Interim Report 12
j 2. 419
Stan V1660305 3M Environmental Lab
Results Name: sl01022c.rdb
T .......................... ISam ple Name
S am ple ID
54 js101022c054 55 is101022c055 56 js101022c056 57 |s101022c057 56 <s101022c058 59 is101022c001 60 |Sl01022c002 61 ;s101022c003 I62 jSl0i22c4 163 =s101022c005 I64 U l01022c006 65 S0022C007 66 ;s101022c008 67 ,is101022c009 68 is10022c 69 js101022c011 70 ;Sl01022c012 71 is 0 2 2 c 3 72 ]s 022c4 73 !s101022c015 74 <s101022c016 75 !s101022c017 76 :S101022c018 77 <s101022c019 78 is101022c020 79 1s101022c021 80- jsW 02 2c0 2 2 81 is101022c023 82 isi'122c024 83 IS101022C025 *84 isii22c26 [85 Is101022c027 186 S101022C028 87 |sii22c29 8 8 Is101022c030 89 ]s101022c031 90 ]s101022c032 91 is101022c033 92 !s101022c034 93 ` s101022c035 94 is101022c036 95 ]s101022c037 96 s 1010220038 97 S101022C039
;s101022c040 99 , s101022c041 100 1s101022c042 101 js101022c043 102 <js101022c044 103 js101022c045 104 is101022c046 |105 ]s101022c047 106 Is101022c048
GLP10-01-01-12-014 DAL SS 609R 0 0040 GLP10-01-01-12-015 DAL SS 609R 0 0110 10 006-13 solvent blank EC-101020-05 2.5 ng E xtracted Curve Point 10 006-13 solvent blank 10 006-13 solvent blank 10 006-13 solvent blank W arm Up EC-101020-06 5 ng W arm Up EC-101020-06 5 ng W arm Up EC-101020-06 5 ng 10 006-13 solvent blank 10 006-13 solvent blank 10 006-13 solvent blank EC-101020-01 0.2 ng E xtracted Curve Point EC-101020-02 0.5 ng Extracted Cun Point EC-101020-03 0.75 ng Extracted Curve Point EC-101020-04 1 ng E xtracted Curve Point EC-101020-05 2.5 ng E xtracted Curve Point EC-101020-06 5 ng E xtracted Curve Point EC-101020-07 10 ng Extracted Curve Point EC-101020-08 25 ng E xtracted Curve Point EC-101020-09 50 ng E xtracted Curve Point EC-101020-10 100 ng E xtracted Curve Point EC-101020-11 200 ng E xtracted Curve Point 10 006-13 solvent blank 10 006-13 solvent blank 10 006-13 solvent blank 10 006-13 solvent blank MB--101020-01 Method Blank 1 w/o IS MB--101020-02 Method Blank 2 w/o IS M B -1 0 1 020-03 Method Blank 3 w/o IS M B -1 0 1 020-04 Method Blank 4 w / IS M B -1 0 1 020-05 Method Blank 5 w / IS MB--101 02 0 66 Method Blank 6 w/ S LCS-101020-01 3 ng LCS in TCR-842 LCS-10 10 20 0 2 3 ng LCS in TCR-842 LCS-1010 2 0 0 3 3 ng LCS in TCR-842 LCS-10 10 2 0 0 4 30 ng LCS in TCR-842 LCS-10 10 2 0 0 5 30 ng LCS in TCR-842 LCS-10 10 2 0 0 6 30 ng LCS in TCR-842 10 006-13 solvent blank EC-101020-05 2 .5 ng E xtracted Curve Point 10 006-13 solvent blank G L P liw 101-12001 DAL SS TRiP 6 0000 G LP 1 00 1 01 -1 20 0 2 DAL SS 611R 0 0000 G LP1 0 0 1 0 1 -1 2 0 0 3 DAL SS 611R 0 0010 G LP1 0 0 1 0 1 -1 2 0 0 4 DAL SS 611R 0 0040 G LP 1 0 0 1 0 1 -1 2 0 0 5 DAL SS 6 1 1R 0 0050 G L P 1 00 1 01 -1 20 0 6 DAL SS 607R 0 0000 G LP1 0 0 1 0 1 -1 2 0 0 7 DAL SS 607R 0 0010 G LP1 0 0 1 0 1 -1 2 0 0 8 DAL SS 607R DB 0010 G L P 1 00101-12010 DAL SS 607R 0 0040 G L P 1 00 1 01 -1 20 1 1 DAL SS 607R 0 0270
Printing Date: Thursday, December 23, 2010 Printing Time: 12:59:11 PM
3M Study: GLP10-01-02 Interim Report 12
Analyte Peak Name
Sam ple Type
MPFOS MPFOS MPFOS MPFOS MPFOS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS
Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Unknown Unknown Unknown Double Blank Double Blank Double Blank Standard Standard S ta n d a rd Standard Standard S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd S ta n d a rd Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank DouDle Blank Unknown Unknown Unknown Quality Control Quality Control Quality Control Quality Control Quality Control Quality Control Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown Unknown
Use Record
Analyte Concentration
(ng/m L)
Analyte Retention Analyte
Tim e Peak Area (m in) (counts)
IS Peak Name
ei
H ei El s El El El El El El
~
El El El El El Rl El
N/A N/A 0.00 2.50 0.00 0.00 0.00 N/A N/A N/A 0.00 0.00 0.00 0.200 .5 0.749 0.999 2.50 5.00 9.99 25.0 50.0 99.9 200. 0.00 0.00 0.00 0.00 0.00 0.00 0.00 N/A N/A N/A 3.00 3.00 3.00 30.0 30.0 30.0 0.00 2.50 0.00 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
13.699 13.709 13.810 13.669 13.609 8.070 8.050 6.030 8.030 6.030 8.030 7.949 8.111 8.010 8.000 8.010 8.020 8.030 8.010 8.010 8.020 8.000 8.010 8.020 8.040 7.959 8.070 8.050 8.080 8.030 6.030 8.020 8.010 8.030 8.010 8.000 8.050 8.040 8.040 8.010 8.010 8.020 8.020 6.020 8.040 8.030 8.030 8.010 8.010 8.020 8.010 7.980 7.990
45203
M8PFOS
46550
M8PFOS
61 M8PFOS
35933
M8PFOS
182 M8PFOS
97 MPFBS
205 MPFBS
756265 MPFBS
759715 MPFBS
756725 MPFBS
48 MPFBS
308 MPFBS
20 MPFBS
70241
MPFBS
102427 MPFBS
137411 ' M PFBS
165062 MPFBS
368936 MPFBS
790733 MPFBS
1347510 MPFBS
3560681 MPFBS
6943639 MPFBS
13422359 MPFBS
23602173 MPFBS
3782
MPFBS
194 MPFBS
1790
MPFBS
64 MPFBS
2208
MPFBS
3118
MPFBS
1926
MPFBS
45106
MPFBS
49874
MPFBS
53072
MPFBS
460249 MPFBS
497821 MPFBS
469541 MPFBS
4159556 MPFBS
4441892 MPFBS
4343184 MPFBS
359 MPFBS
388503 MPFBS
116 M PFBS
48712
MPFBS
127222 MPFBS
112584 MPFBS
86543
MPFBS
75878
MPFBS
111555 MPFBS
61942
MPFBS
57748
MPFBS
52216
MPFBS
50513
MPFBS
IS Peak Area
(counts)
IS C o n c e n tra tio n
(ng/m L)
IS
Retention Calculated
Tim e Concentration
(m in )
(n g /m L )
Accuracy <%>
49139 50099 61 46462 24 24 61 342136 '338066 343247 133 24 36 334940 326669 3327 335958 33745 348645 333501 366079 348632 353484 336729 61 61 169 24 36 2 345473 345519 360575 361242 372214 352983 347933 359553 368831 45 346086 169 357926 359598 367604 375981 361310 358829 378011 356665 366242 369988
1.00 1.00 N/A 1.00 N/A N/A N/A 1.00 i.o o 1.00 N/A N/A N/A 1.00 100 1. 1.00 1 1.00 1.00 1.00 1.00 1.00 1.00 N/A N/A N/A N/A N/A N/A N/A 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 N/A 1.00 N/A 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00
13.7 13.7 13.8 13.7 13.6 8.03 8.13 8.02 8.03 8.03 8.06 8.01 8.06 8.01 8. 8.01 8.02 8.03 8.01 8.01 8.02 8.00 8.00 8.02 8.25 8.22 8.00 .0 8.07 8.00 8.10 8.02 8.01 8.02 8.01 8.00 6.05 8.04 8.03 8.01 8.10 8.01 8 . 8.01 8.04 8.03 8.03 8.01 8.00 8.02 8.01 7.98 7.99
3.16 3.19 N/A 2.64 N/A N/A N/A 5.22 5 .3 5.20 N/A N/A N/A 0.255 .52 0.759 0.952 2.44 5.36 9.78 24.2 50.7 100. 200. N/A N/A N/A N/A N/A N/A N/A 0.0598 0.0939 0.101 2.89 3.05 3.03 29.9 30.9 29.4 N/A 2.51 N/A 0.0735 0.612 0.494 0.306 0.256 0.505 0.142 0.137 0.0895 0.0746
N/A N/A N/A 106. N/A N/A N/A N/A N/A N/A N/A N/A N/A 128. 102. 101. 95.3 97.7 107. 97.9 96.6 101. 100. 99.8 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 96.3 102. 101. 99.6 103. 98.0 N/A 101. N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A
Page 2 of 5
Record M o d ifie d
File Name
s101022c.wiff s101022c.wiff s101022c.wrff s101022c.wiff s 101022c.wifi s 0 022c.wiff s101022c.wrff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff si i 22c.wiff
s101022c.wiff s 101022c.wiff s101022c.wHf s 101022c.wiff
s101022c.wiff s101022c.wiff s 101022c.wiff
s101022c.wiff s101022c.wiff s101022c.wiff
s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff
s101022c.wrff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s 101022c.wiff s101022c.wiff
s101022c.wiff s101022c.wrff s101022c.wiff S 0 022c.wiff s101022c.wiff s101022c.wiff n s1i22c.wiff s101022c.wiff El s101022c.wiff El s0022c.w iff s101022c.wrff s101022c.wiff si i 22c.wiff
Page 296 of 419
Stan V1660305 3M Environmental Lab
Results Name: sl01022c.rdb
iSam ple Name
S am ple ID
107 Is101022c049 108 Is101022c050 109 js101022c051 110 is101022c052 111 js101022c053 112 ;s101022c054 113 js101022c055 114 is101022c056 115 jsi122c57 116. !s101022c058 117 s101022c001 118 isi0 1 02 2 c00 2 119; is101022c003 120 js101022c004 121 ;s1122c5 122 isV122cO6 123 Is101022c007 124 is101022c8 125 is101022c9 126 Is101022c010 127 is101022c011 128 is101022c012 129 is101022c013 130 Is101022c014 131 :s10i22c15 132 s101022c016 133 s101022c017 134 s101022c018 135 S101022C019 136 s101022c020 *137 is101022c021 1138 is101022c022 139 is101022c023 140 ts101022c024 141 is101022c025 142 ;s101022c026 143 ;s101022c027 144 :s101022c028 145 is101022c029 146 Is101022c030 147 Is101022c031 148 is101022c032 149 :s101022c033 150 s101022c034 151 is101022c035 ^ 5 2 s101022c036 153 S101022C037 154 is101022c038 155 S101022C039 156 S101022C040 157 is101022c041 158 Is101022c042 159 is101022c043
10 006-13 solvent blank EC-101020-06 5 ng E xtracted Curve Point 10 006-13 solvent blank GLP10-01-01-12-012 DAL SS 609R 0 0000 GLP10-01-01-12-013 DAL SS 609R 0 0010 GLP10-01-01-12-014 DAL SS 609R 0 0040 GLP10-01-01-12-015 DAL SS 609R 0 0110 10 006-13 solvent blank EC-101020-05 2.5 ng E xtracted Curve Point 10 006-13 solvent blank 10 006-13 solvent blank 10 006-13 solvent blank W arm Up EC-101020-06 5 ng W arm Up EC-101020-06 5 ng W arm Up EC-101020-06 5 ng 10 006-13 solvent blank 10 006-13 solvent blank 10 006-13 solvent blank EC-101020-01 0.2 ng E xtracted Curve Point EC-101020-02 0.5 ng E xtracted Curve Point EC-101020-03 0.75 ng Extracted Curve Point EC-101020-04 1 ng E xtracted Curve Point EC-101020-05 2 .5 ng E xtracted Curve Point EC-101020-06 5 ng E xtracted Curve Point EC-101020-07 10 ng E xtracted Curve Point EC-101020-08 2 5 ng E xtracted Curve Point EC-101020-09 50 ng E xtracted Curve Point E C-10102010 100 ng E xtracted Curve Point EC-10102011 200 ng E xtracted Curve Point 10 006-13 solvent blank 10 006-13 solvent blank 10 006-13 solvent blank 10 006-13 solvent blank M B -1 0 1 020-01 Method Blank 1 w/o IS MB--101020-02 Method Blank 2 w/o IS MB--101020-03 Method Blank 3 w/o IS
M B -1 0 1 0 2 0 0 4 Method Blank 4 w/ IS
MB--101020-05 Method Blank 5 w / IS MB--101020-06 Method Blank 6 w / IS L C S -i0 1 0 2 0 6 i 3 ng LCS in fCR4342 LCS -10102002 3 ng LCS in fCR-842 LCS-101020-03 3 ng LCS in TCR-842 LCS-101020-04 30 ng LCS in TCR-842 LCS-101020-05 30 ng LCS in TCR-842 LCS-101020-06 30 ng LCS in TCR-842 10 006-13 solvent blank EC-101020-05 2 .5 ng Extracted Curve Point 10 006-13 solvent blank GLP10-01-01-12-001 DAL SS TRIP 0 MOO GLP10-01-01-12-002 DAL SS 6 1 1R 0 OOM GLP10-01-01-12-003 DAL SS 6 1 1R 0 0010 G LP 10 0 1 0 1 -1 2 -0 0 4 DAL SS 6 1 1R 0 0040 G LP1 0 0 1 0 1 -1 20 05 DAL SS 611R 0 0050
Printing Date: Thursday, December 23, 2010 Printing Time: 12:59:12 PM
Analyte Peak Name
Sam ple Type
PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFBS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS
Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Double Blank Q uality Control Double Blank Double Blank Double Blank Unknown Unknown Unknown Double Blank Double Blank Double Blank Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Quality Control Quality Control Quality Control Quality Control Q uality Control Q uality Control Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Unknown
Use Record
Analyte Concentration
(ng/m L)
Analyte Retention Analyte
Time Peak Area (m in ); : (counts)
IS Peak Name
O .M
e i 5.00 .0
N/A
N/A
N/A N/A
O.M
m 2.50 O .M
O.M
O.M
N/A
N/A
N/A
O.M
O.M
O.M
El .2
0El 0 .5 M 0.750
El 1.00 El l2.50 El 5.00 El 10.0 El 25.0 El 50.0 Ei 1. El 200.
O.M
O.M
O .M
O.M
O.M
O .M
O.M
rN /A
N/A
N/A
El 3.00 El 3.00 El 3.00 El 30.0 E 30.0 El 30.0
O.M
El 2.50
0.00
N/A
N/A
N/A
N/A
N/A
8.010 7.980 8.010 8.010 7.990 8.010 8.020 8.010 7.990 8.030 10.552 10.623 10.613 10.592 i 0.592 10.653 10.592 10.572 10.582 10.602 10.592 10.613 10.572 10.592 10.582 10.592 10.572 10.582 10.582 10.633 10.582 10.613 10.653 10.592 10.653 10.623 10.512 10.693 10.623 10.579 10.575 10.624 10.607 10.605 10.594 10.602 10.582 10.582 10.562 10.608 10.602 10.609 10.588
139 MPFBS
791288 MPFBS
40 MPFBS
123509 MPFBS
83037
MPFBS
62587 72269
MPFBS MPFBS
303 MPFBS
368479 MPFBS
95 MPFBS
516 MPFHS
179 MPFHS
439621 MPFHS
455182 MPFHS
445990 MPFHS
292 MPFHS
202 MPFHS
191 MPFHS'
20984
MPFHS
51271
MPFHS
70913
MPFHS
89788
MPFHS
229829 MPFHS
454819 MPFHS
892495 MPFHS
2395478 MPFHS
4702837 MPFHS
9289563 MPFHS
16938635 MPFHS
3948
MPFHS
1701
MPFHS
2325
1M P F H S
395 MPFHS
801 MPFHS
57 MPFHS
265 MPFHS
1M MPFHS
1438
MPFHS
1740
MPFHS
290115 MPFHS
316241 MPFHS
313847 MPFHS
3035686 MPFHS
3126828 MPFHS
3063163 MPFHS
475 MPFHS
239278 MPFHS
630 MPFHS
941 MPFHS
15163
MPFHS
30518
MPFHS
18548
MPFHS
11476
MPFHS
IS Peak Area
(counts)
IS
IS Concentration
Retention .Tim e
C a lcu la te d Concentration
(ng/m L)
(min) . (ng/m L)
TOA c c u ra c y
109 339410 48 353200 346831 381659 352970 121 331151 133 12 36 157166 162443 162343 36 61 24 159647 149554 156767 153602 157504 164141 153799 173103 166218 160048 157114 0 24 36 12 12 0 24 161797 161228 166223 171165 174772 170203 168771 175076 174389 73 165541 0 168153 177839 176740 177804 175801
N/A 1.00 N/A 1.00 1.00 1.00 1.00 N/A 1. N/A N/A N/A 1.00 1.00 1.00 N/A N/A N/A 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 N/A N/A N/A N/A N/A N/A N/A 1.00 1.00 1.00
-i.ob
1.00 1.00 1.00 1.00 1.00 N/A 1.00 N/A 1.00 1.00 1.00 1.00 1.00 /
8.08 7.98 7.99 8.01 7.98 8.00 8.02 8.23 7.99 8.08 10.8 10.7 10.6 10.6 10.6 10.5 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 0.00 10.7 10.7 10.7 10.6 0.00 10.5 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 10.6 0.00 10.6 10.6 10.6 10.6 10.6
N/A 5.52 N/A 0.601 0.325 0.142 0.243 N/A 2.49 N/A N/A N/A 4.79 4.80 4.70 N/A N/A N/A 0.198 0.561 0.750 0.977 2.48 4.74 9.98 24.0 49.4 103. 199. N/A N/A N/A N/A N/A N/A N/A
<0 <0 <0
2.89 3.09 3.15 31.2 31.0 30.5 N/A 2.46 N/A <0 0.118 0.269 0.151 0.0839
N/A 110. N/A N/A N/A N/A N/A N/A 99.6 N/A N/A N/A N/A N/A N/A N/A N/A N/A 98.8 112. 99.9 97.7 99.3 94.9 99.8 95.8 98.9 103. 99.3 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 96.3 103. 105. 104. 103. 102. N/A 98.4 N/A N/A N/A N/A N/A N/A
Page 3 of 5
Record M odified
File Name
S101022c.wiff S101022c.wiff s101022c. wiff
s101022c.wrff
s101022c. wiff s101022c.wiff
s101022c.wiff s101022c.wiff s i 01022c.wiff s101022c. wiff
s101022c.wi1T
sii22c.wHT s101022c.wiff
s101022c.wiff
s1i22c.wiff
sii22c.wtff s101022c.wiff s101022c.witf s101022c.wiff s 101022c.wiff
s101022c.wiff s101022c. wiff
S101022c.wiff
s101022c. wiff
s i I022c.wiff i
s101022c. wiff
S101022c.wiff
n S101022c.wiff s 101022c.wiff
S101022c.wiff s101022c. wiff
s 101022c.wiff
s101022c.wiff
s1i22c.wiff
s101022c.wiff s101022c.wiff s101022c.wiff
s101022c.wiff
s101022c.wrff
El s101022c.wrff El si01022c.w iff
1El s101022c.w$ff S i I 022c.wiff
0 sii22c.wiff
El s 101022c.w iff
s 101022c.wiff
s 101022c.w iff s 101022c.w iff
m s 101022c.w iff 101022c. w iff
EI s 101022c.w iff El s101022c. wiff El s ib i 22 c.w iff
3M Study: GLP10-01-02 Interim Report 12
Page 297 of 419
Stan V1660305 3M Environmental Lab
Results Name: sl01022c.rdb
;S am ple Nam e
S am ple ID
160 Is101022c044 G LP10-01-01-12-006 D A L S S 607R 0 0000 161 s101022c045 G LP 10-01-01-12-007 D A L S S 607R 0 0010 162 :s101022c046 G LP 10-01 -01-12-008 D A L S S 607R DB 0010 163 ?s101022c047 G LP10-01-01-12-010 D A L S S 607R 0 0040 164 S101022C046 GLP10-01-01-12-011 DAL S S 607R 0 0270 165 1s101022c049 10 006-13 solvent blank 166 *s101022c050 EC-101020-06 5 ng E xtracted Curve Point 167 S101022C051 10 006-13 solvent blank 168 :s101022c052 G L P i-01-01 -12-i 2 DAL SS 609R 0 169 :s101022c053 GLP10-01-01-12-013 DAL SS 609R 0 0010 *170 is101022c054 GLP10-01-01-12-014 DAL SS 609R 0 0040 I 171 :s101022c055 G LP 10-01-01 -12-0"i5 DAL SS 69R 0 0110 172 is101022c056 10 006-13 solvent blank 173 S101022C057 EC-101020-05 2 .5 ng E xtracted Curve Point 174" is101022c058 10 006-13 solvent blank 175 s101022c001 10 006-13 solvent blank 176 s101022c002 10 006-13 solvent blank 177 U101022C3... W arm Up EC-101020-06 5 ng p 7 8 *s10i22c4 W arm Up EC-101020-06 5 ng 179 s101022c005 W a n n Up EC-101020-06 5 ng 1180 S101022C006 10 006-13 solvent blank j181 S101022C007 10 006-13 solvent blank 1182 s101022c008 10 006-13 solvent blank h - is101022c009 EC-101020-01 0.2 ng E xtracted Curve Point jl8 4 s101022c010 EC-101020-02 0.5 ng E xtracted Curve Point fl85~ s101022c011 EC-101020-03 0.75 ng E xtracted Curve Point 186 is101022c012 EC-101020-04 1 ng E xtracted Curve Point l 187 s101022c013 EC-101020-05 2 .5 ng E xtracted Curve Point |1 88 s101022c014 EC-101020-06 5 ng E xtracted Curve Point 189: s 101022c015 EC-101020-07 10 ng E xtracted Curve Point 190 S10 0220016 1 ^ 1 0 1 0 2 0 0 8 25 ng E xtracted Curve Point 191 is101022c017 EC-101020-09 50 ng E xtracted Curve Point 192 s101022c018 EC-101020-10 100 ng E xtracted Curve Point 193 s101022c019 EC-101020-11 200 ng E xtracted Curve Point 1194 is101022c020 10 006-13 solvent blank 195 1S101022C021 10 006-13 solvent blank H 9 6 S101022C022 10 006-13 solvent blank 1197 s101022c023 10 006-13 solvent blank 1198 s101022c024 MB--101020-01 Method Blank 1 w/o IS | l9 9 :s101022c025 M B -101020-02 Method Blank 2 w/o IS |20G s101022c026 MB--101020-03 Method Blank 3 w/o IS
201 Is101022c027 MB--101020-04 Method Blank 4 w / IS
202 s101022c028 MB--101020-05 Method B lank 5 w/ IS |203 s101022c029 M B -1 0 1 020-06 Method Blank 6 w / IS 204 s101022c030 LCS-101020-01 3 ng LCS in TCR-842 *205 s101022c031 LCS-101020-02 3 ng LCS in TCR-842 206 s101022c032 LCS-101020-03 3 ng LCS in TCR-842 207 s101022c033 LCS-101020-04 30 ng LCS in TCR-842 208 ' is101022c034 LCS-101020-05 30 ng LCS in TCR-842 209 s101022c035 LCS-101020-06 30 ng LCS in TCR-842 210 is101022c036 10 006-13 solvent blank 211 s101022c037 EC-101020-05 2 .5 ng E xtracted Curve Point 212 s101022c038 10 006-13 solvent blank
Printing Date: Thursday, December 23, 2010 Printing Time: 12:59:12 PM
3M Study: GLP10-01-02 Interim Report 12
Analyte Peak Name
Sam ple Type
PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFHS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS PFOS
Unknown Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Unknown Unknown Unknown Unknown Double Blank Quality Control Double Blank Double Blank Double Blank Unknown Unknown Unknown Double Blank Double Blank Double Blank S ta n d a rd Standard Standard Standard Standard Standard Standard Standard Standard S ta n d a rd Standard Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Double Blank Unknown Unknown Unknown Quality Control Quality Control Quality Control Quality Control Quality Control Quality Control Double Blank Quality Control Double Blank
.
Use Record
' Analyte Concentration
(ng /m L )
Analyte
Retention Analyte
T im e (m in )
P e a k Ares (counts)
IS Peak Name
-:r;---rr------ 5
IS Peak
IS
*
Area (counts)
C o n c e n tra tio n (ng/m L)
IS
Retention Tim e
Calculated C o n c e n tra tio n
(m in )
(ng /m L )
Accuracy w
N/A
N/A N/A
N/A
N/A
0.00
E l 5.00
........ 0.00 N/A
.... N/A N/A
N/A
0.00
0 2.50 0.00
I0.00
N/A
N/A
N/A 0.00
.
0.00
E l 0.200 E l 0.500 E l 0 750 El 1.00 El 2.50 El 5.00 El 10.0 El 25.0 El 50.0 El 100. El 200.
0.00 0.00
.
.0
0.00
0.00
0.00
N/A
N/A
N/A
El 3.00 El 3.00 El 3. El 30.0 El 30.0 El 30.0
0.00
El 2.50 0.00
10.593 10.582 10.713 10.643 10.572 10.582 10.582 10.572 10.604 10.594 10.663 10.63 10.633 10.592 10.592 13.669 13.730 13.689 13.679 13.659 13.669 13.689 13.669 13.669 13.710 13.649 13.659 13.649 13.639 13.659 13.669 13.639 13.629 13.619 13.669 13.649 13.74 13.659 13.711 13.688 13.715 13.661 13.628 13.628 13.613 13.655 13.644 13.625 13.628 13.688 13.669 13.669 13.720
15422 5392 5670 2863 1929 263 461278 645 20389 8185 3625 11794 360 223672 183 436 196 175127 178097 178520 336 75 109 10398 20441 28240 34407 88762 178359 337260 939362 1801557 3452177 6009809 1608 541 857 315 3820 3098 2927 4375 4496 5742 117364 126463 123007 1179801 1213623 1180611 258 90176 266
MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS MPFHS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS M8PFOS
167424 174898 166647 162125 168599 109 170181 61 168351 168289 164011 165388 12 156374 85 85 61 50617 46600 46253 36 24 73 42091 41449 45189 44002 45034 46888 47764 52357 46562 42575 38149 12 24 48 36 48 12 12 46699 47251 47707 48947 50109 51224 49966 49769 52189 36 51492 48
1.00 1.00 1.00 1.00 1.00 N/A 1.00 N/A 1.00 1.00 1.00 1.00 N/A 1.00 N/A N/A N/A 1.00 1.00 1.00 N/A N/A N/A 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 N/A N/A N/A N/A N/A N/A N/A 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 N/A 1.00 N/A
10.6 10.6 10.6 10.6 10.6 10.7 10.6 10.6 10.6 10.6 10.6 10.6 10.8 10.6 10.5 13.9 13.6 13.7 13.7 13.6 13.8 13.7 13.7 13.7 13.7 13.7 13.7 13.6 13.6 13.7 13.6 13.6 13.6 13.6 13.7 13.6 13.7 13.8 13.6 13.5 13.6 13.7 13.6 13.6 13.6 13.7 13.7 13.6 13.6 13.6 13.6 13.6 13.7
. 130 0.0247 .32 0.00202 <0 N/A 4.64 N/A .18 0.0553 0 .0 0 9 6 6 " 1.943 N/A 2.43 N/A N/A N/A 4.45 4.93 4.97 N/A N/A N/A 0.227 0.551 0.724 0.931 2.49 4.90 9.17 23.4 50.2 104. 198. N/A N/A N/A N/A N/A N/A N/A 0.0251 0.0271 0.0603 3.05 3.22 3.06 30.8 31.8 29.5 N/A 2.21 N/A
N/A N/A N/A N/A N/A N/A 92.8 N/A N/A N/A N/A N/A N/A 97.3 N/A N/A N/A N/A N/A N/A N/A N/A N/A 113. 110. 96.5 93.1 99.8 98.0 91.7 93.5 100. 104. 99.1 N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 102. 107. 102. 103. 106. 98.2 N/A 88.2 N/A
Page 4 of 5
Record M o d ifie d
File Name .
E l s 101022c.wiff s101022c.wiff s101022c.wrff
s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff E l s101022c.wiff E l s101022c.wiff s101022c.wiff
s1 0 1 0 2 2 c.w iff
s101022c.wiff s101022c.wiff n s101022c. wiff s101022c.wrff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wiff s101022c.wrff s101022c.wiff s101022c.wiff s101022c.wrff s101022c.wiff fs101022c.wiff a s101022c.wiff s101022c.wiff s101022c.wiff s101022c. wiff
s 101022c.wiff s101022c.wiff s 101022c.wiff
s101022c.wiff s101022c.wiff s i 01022c.wiff s 101022c.wiff El s 101022c.wiff El s 101022c.wiff El s101022c.wiff El s101022c.wiff El s101022c.wiff s101022c.wrff
El s101022c.wiff El s101022c.wiff El s101022c.wiff
El s101022c.wiff El s101022c.wiff El s 101022c.wiff s 101022c.wiff s 101022c.wiff s101022c.wiff
Page 298 of 419
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Results Name: sl0l022c.rdb
Sam ple Name
S am ple ID.
^
213 ~ Is101022c039 214 is101022c040 215 Is101022c041 i216 s101022c042 :217 s101022c043 |21S :Sl0i22c44 j2 1 9 is101022c045 |2 20 S101022C046 221 s101022c047 1222 s101022c048 223 S101022C049 ?24 s101022c050 1225 s101022c051 |225 s101022c052 227 IS101022C053 228- is101022c054 |229: -s101022c055 1230.' s101022c056 231 =s101022c057 232 Is101022c058
GLP10-01-01-12-001 DAL S S TRIP 0 0000 G LP 10-01-01-12-002 DAL SS 6 1 1R 0 0000 GLP10-01-01-12-003 DAL SS 6 1 1R 0 0010 GLP 10-01-01-12-004 DAL SS 611R 0 0040 GLP 10-01-01-12-005 DAL SS 611R 0 0050 G L P l6 ^ ^ 1 - ^ 2 4 )6 6 DAL SS 607R 6 0000 GLP 10-01-01-12-007 DAL SS 607R 0 0010 GLP 10-01-01-12-008 DAL SS 607R DB 0010 GLP10-01-01-12-010 DAL SS 607R 0 0040 GLP10-01-01-12-011 DAL SS 607R 0 0270 10 006-13 solvent blank EC-101020-06 5 ng E xtracted Curve Point 10 006-13 solvent blank GLP10-01-01-12-012 DAL SS 609R 0 0000 GLP10-01-01-124313 DAL SS 609R 6 0010 GLP10-01-01-12-014 DAL SS 609R 0 0040 GLP10-01-01-12-015 DAL SS 609R 0 0110 10 006-13 solvent blank EC-101020-05 2.5 ng E xtracted Curve Point 10 006-13 solvent blank
Analyte Peak Name
Sam ple Type
p f o s T"~ " Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Double Blank
PFOS
Q uality Control
PFOS
Double Blank
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Unknown
PFOS
Double Blank
PFOS
Quality Control
PFOS
Double Blank
Use Record
--
. .. _ A nal.yte.. C o n c e n tra tio n
(ng/m L)
Analyte Retention Analyte
Peak Area (n lln ) (oounts)
IS Peak Name
N/A 113.658 4077 " M 8P F S "
N/A 113.627 1399095 M 8PFOS
N/A 113.638 950651" M 8PFOS
N/A
113.647
539986 M8PFOS
N/A
113.623
16l39 M8PFOS
N/A 113.705 642414 M 8PFOS
N/A
113.626
1193768 M8PFOS
N/A 113.635 893906 M 8PFOS
N/A
113.634
198805 M8PFOS
N/A
113.629
1754
M8PFOS
0.00
113.649
36
M8PFOS
5.00
13.659
174800 M8PFOS
0.00
113.619
182
M8PFOS
N/A 113.719 813798 M8PFOS
N/A 113.692 463100 M8PFOS
N/A
113.687 52433
M8PFOS
N/A jO.OO
113.748
18328
..... i 13.619 " 36
M8PFOS MBPFOS
IS) 2.50
0.00
113.720 113.679
88090 99
M8PFOS M8PFOS
IS Peak : Area i (oounts)
149778 146125 149719" " 153158 I50505 14985 151291 j 50047 149123 148464 1109 149085 161
]50339
147131 149139 150099 161 !46462 124
IS Concentration
(ng/m L)
1.00 1.00 too" 1.00 1.00 1.00 1.00 1.00 1.00 1.00 N/A 1.00 N/A 1.00
1.00 1.00
1.00 N/A 1.00 N/A
IS
Retention Calculated
Time Concentration
(m in )
(ng /m L )
Accuracy
Record M odified
File Name
13.7
0.00965
13.6
39.5
13.6 " " 24.9
13.6
13.2
13.7
4.11
13.7
16.8
13.6
30.3
13.6
23.3
13.6
5.22
13.6
<0
13.7
N/A
13.7
4.58
13.6
N/A
13.7
21.1
13.7
12.8
13.7
1.31
13.7
0.383
13.8
N/A
13.7
2.40
13.6
N/A
N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A N/A 91.7 N/A N/A N/A N/A N/A N/A 95.8 N/A
si
SI
El
SI
SI 1
SI SI SI
.
SI SI SI SI
....... ......
s 1 0 1 0 2 2 c.w iff s 1 0 1 0 2 2 c.w iff s101022c.wHT s 1 0 1 0 2 2 c.w iff s 1 0 1 0 2 2 c.w iff s lO I 022c.wifi s 1 0 1 0 2 2 c.w iff s 1 0 1 0 2 2 c.w iff s 1 0 1 0 2 2 c.w iff s 101022c.wiff s 101022c.wiff s1122c.wifF s 1 0 1 0 2 2 c.w iff s 101022c.wiff s 101022c.wiff s 101022c.wiff s1 0 1 0 2 2 c.w iff s 101022c.wiff s 101022c.wiff s 101022c.wiff
Printing Date: Thursday, December 23, 2010 Printing Time: 12:59:12 PM
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Page l of l
G ?^
t i ,P ag 5300sf 419
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Results Name: sl0l022c.rdb
w s101022c.rdb (PFHS): "Quadratic" Regression ("1 l x " weighting): y = -0.000195 xA2 + 0.582 x + 0.0165 (r = 0.9997)
109 105^
100:
95:
90-
85-
80:
75:
70:
(0 6 5 :
< w
60-
(<10> 55-
k_
< <D 5 0 :
(>c0* 4 5 :
<
4 0 -j
35:
30:
25:
20- ^ y
15- y y ' y*
10- ^ y
\\
5-
06 10 20 30 40
Printing Date: Thursday, December 23, 2010 Printing Time: 1:02:35 PM
3M Study: GLP10-01-02 Interim Report 12
y yS ' s'
y X
^y
s '' s'
"'
y M
s '''
y
.y
y '' y
y y ''
y
y
S' y'
'
,y
y'
s'
s' s'
y
y'
50 60 70 80 90 100 110 120 130 140 150 160 170 180 190 200 Analyte Cone. / IS Cone. Page 1 of 1
(S frt 12 - "
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80 90 100 110 120 130 140 150 160 170 180 190 200 ______ Analyte Cone. / IS Cone._______________________________________________________________________
Page 1 of 1
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20 30 40 50 60
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80 90 100 110 120 130 140 150 160 170 180 190 200 ______ Analyte Cone. / IS Cone.________
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6p" \l
2
1
^
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