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REPLACEMENT SUGGESTIONS FOR
AROCLOR PLASTICIZERS
The information contained in this bulletin is, to our best knowledge, true and accurate, but all recommend ations or suggestions are made without guarantee, since the conditions of use are beyond our control. Monsanto Company disclaims any liability incurred in connection with the use of these data or suggestions. Furthermore, nothing contained herein shall be construed as a recommendation to use any product in conflict with existing patents covering any material or its use.
OAIOOIA
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In conjunction with our removal of Aroclor plasticizers from the market, Monsanto has attempted to put together a list of replacement suggestions for this line of pro ducts. Anyone who has had experience with Aroclors will
recognize that this is a difficult task. The combination of thermal and chemical stability, good compatibility, low cost, and fire retardance make Aroclors difficult products to replace.
On the following pages, you will find listed products pro duced by Monsanto and by other competitive suppliers which could be used as a starting point in reformulation work. This list has been compiled based upon our understanding of the requirements of the various application areas and not necessarily upon extensive application research.
Therefore, the list should not be construed to be a blanket recommendation.
Monsanto would be happy to discuss replacement reformulation questions as they arise. Listed below are several people who have had contact with the various application areas in volved. Please feel free to contact them.
Dr. A. William Coaker (314) 694-2486
Polysulfides
Acrylics Adhesives
Dr. Charles P. Farley (314) 694-2438
Mr. John H. Orem (314) 694-2489
Polyurethane Foam Rubber
Melamines Phenolics Coatings Carpet-backing
Mr. L. David Press (314) 694-2487
Polyurethane Film Pigments Film and Sheeting
Coated Fabrics
Product Supervisor Bi/Terphenyl Derivatives (314) 694-2518
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AROCLOR REPLACEMENT SUGGESTIONS Application Area___________ Polymer/Binder
Replacement Suggestions Aroclor UsedSupplierProduct
Adhesives Delayed Tack
SBR, PVAc, PS
6090, 5^60
Monsanto
DCHP, DPP Santlcizer 1-H Santolite MHP
Emulsion Pressure Sensitive Hot Melt
PVAc, SBR Acrylic-VAc Acrylic-Ethylene
1221-B, 6040, 6050
Natural Rubber, SBR, Cl Rubber
1221-B, 6062, 5460
EVAc, PVC, Phenoxles, Polyamides
5460, 5060 Montar 5
Monsanto
FRP Monsanto PRP Monsanto
Pic CO Velslcol Goodyear FRP
Santlcizer 218-A Santlcizer 885 Santlclzers 8, B-l6, M-17
Isoester A, B, C
Santlclzers 140, 148, 160 Triphenyl Phosphate
Isoester B
Santlclzers 9, 1-H
Santowax OM '
2.
DCHP/Santiclzer 160 `
Triphenyl Phosphate
DPP
Piccotex 75
Klyrvels
Wingtac
Isoester D
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AROCLOR REPLACEMENT SUGGESTIONS
Replacement Suggestions Application AreaPolymer/BinderAroclor UsedSupplierProduct
Adhesives (Continued) Hot Melt (Continued)
Hercules
Staybelite
4.
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1. Potentially available in mid-February. Not available now. 2. Alkali dispersible hot melt systems.
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AROCLOR REPLACEMENT SUGGESTIONS
Replacement Suggestions
Application AreaPolymer/BinderAroclor UsedSupplier
Product
5
Sealants
Polysulfide, Nitrile, Epoxy, Polyurethane
1254, 5432 Santicizer 261/ 5460
Monsanto
Thiokol ICI
HB-40 2'
Santicizer 26l Santicizer 278 Santicizer 358 Santicizer 898
p
" p -> '
ZP-680
Cereclor 4985
Caulking Compounds
Acrylic, Butyl
5060, 6070
Monsanto
Santicizers 412, 429
Santicizer 8 Santicizer 26l Santicizer 278
DCHP/DPP Santicizer 148
Surface Coatings Paints
PVAc, FVC, Nitriles Styrene Acrylics Cl Rubber
5460, 6062, 6070, 6090
1. Developmental Item - Refer to P. R. Graham.
Monsanto
FRP ICI
2. Recommended primarily for resin system.
3. Recommended primarily for catalyst dispersion system.
4. Several products available under this code name.
Santicizers 160, 261, 278 Santicizer 898 Santicizers 140, 148 DCHP, Santolite MHP
HMP, Filtrez
Cereclor 42 Cereclor 70
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AR0CL0R REPLACEMENT SUGGESTIONS
Replacement Suggestions
Application AreaPolymer/BinderAroclor UsedSupplier
Product
Surface Coatings (Continued)
Lacquers
Alkyd Ethyl Cellulose Nitro Cellulose
5460, 6062, 6070, 6090
Monsanto
FRP Neville
Santiclzers 8, 9 B-16, M-17 DCHP Santolite MHP Santiclzers 26l, 278
Isorosin, Flltrez ^
Diamond Shamrock
Varnish Paper Coatings
Polysulfide Other
6070, 5^60
Ethyl Cellulose
6040, 6050
Monsanto FRP Monsanto
1. Approximately twenty Piltrez products are available.
Santiclzer 261 Santiclzer 278
Filtrez
Santiclzers 8, 9> B-16, M-17 DCHP Diphenyl Phthalate Santolite MHP
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AROCLOR REPLACEMENT SUGGESTIONS
Replacement Suggestions
Application AreaPolymer/BinderAroclor UsedSupplier
Product
Printing Inks
Nitrocellulose Acrylic Vinyl
5^60, 6062, 6070, 6090
Monsanto
Santicizers 160, 26l, 278 Santicizers 8, 9
FRP Flltrez ^
1, Approximately twenty Flltrez products are available.
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AROCLOR REPLACEMENT SUGGESTIONS
Replacement Suggestions Application AreaPolymer/BinderAroclor UsedSupplierProduct
Lost Wax Casting
Wax
5460
Monsanto
Santlclzer 9, 9? DCHP, DPP
Epoxy Systems
Epoxy
6062, 6070
Monsanto
Mod-Epox Santlclzer 8 Santlclzer 9 Phosgard C-22-R
Other
Laminating Resins
Phenolic
5460, 1221, 5432, 6070
Monsanto
Santolite MHP
Santlclzer 8 Santlclzer 9
Phosgard 2XC-20 Phosgard C-22-R Other
1. Monsanto has development products In this area. Contact L. 0. Raether
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LIST OF SUPPLIERS
Monsanto Diamond Shamrock FRP Goodyear Hercules ICI Neville Picco
Monsanto Industrial Chemicals Company 800 North Lindbergh Boulevard
St. Louis, Missouri 63166 W. S. Clark (314) 694-2518
Diamond Shamrock Chemical Company 300 Union Commerce Building Cleveland, Ohio 44115 (216) 621-6100
FRP Company
P. 0. Box 349 Baxley, Georgia (912) 367-3616
31513
Goodyear Tire and Rubber Company 1144 East Market Street Akron, Ohio 44316 (216) 794-4390
Hercules, Inc. 910 Market Street Wilmington, Delaware
(302) 656-98II
19899
ICI America, Inc. 151 South Street Stamford, Connecticut
(203) 327-3200
06904
Neville Chemical Company Neville Island Pittsburgh, Pennsylvania (412) 331-4200
15225
Pennsylvania Industrial Chemicals Corp. 120 State Street St. Clairton, Pennsylvania 15025 (412) 233-8600
0410022
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Thiokol Velsicol
LIST OF SUPPLIERS (Continued)
Thiokol Chemical Corporation 930 Lower Ferry Road Trenton, New Jersey 08607 (609) 396-4001
Velsicol Chemical Corporation 341 East Ohio Street Chicago, Illinois 606II (312) 467-5700
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MONSANTO DISTRICT SALES OFFICES
11.
AKRON, OHIO 44313 260 Springside Drive Montrose Development Park Tel. (216) 666-4111
ATLANTA, GEORGIA 30339 320 Interstate North Parkway Suite 500 Tel. (404) 432-7111
BOSTON, MASSACHUSETTS 02149 Everett Station Tel. (617) 387-5010
CHICAGO, ILLINOIS 3158 Des Plaines Avenue Des Plaines, Illinois 60018 Tel. (312) 296-6688
CINCINNATI, OHIO 45206 1501 Madison Road Tel. (513) 751-6707
DETROIT, MICHIGAN 500 Northland Towers West Southfield, Michigan 48075 Tel. (313) 357-0910
HOUSTON, TEXAS 77027 1301 Post Oak Tower 5051 Westheimer Road Tel. (713) 621-9550
LOS ANGELES, CALIFORNIA 90022 6670 East Flotilla Street Tel. (213) 723-2492
NEW YORK, NEW YORK 10036 1114 Avenue of the Americas Tel. (212) 764-5000
ST. LOUIS, MISSOURI 63166 800 North Lindbergh Boulevard Tel. (314) 694-1000
04X0024
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SAN FRANCISCO BAY AREA 2710 Lafayette Street Santa Clara, California Tel. (408) 243-0414
95052
SEATTLE, WASHINGTON 98121 2112 Third Avenue Tel. (206) 622-4203
WILMINGTON, DELAWARE I98IO Suite 204, Bancroft Building 3411 Sllverslde Road Tel. (302) 478-4600
Monsanto Industrial Chemicals Company A Unit of Monsanto Company 800 North Lindbergh Boulevard
St. Louis, Missouri 63166
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