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AR 226.0693 ACUTE TOXICITY TO FISH (FATHEAD MINNOW) TEST SUBSTANCE Identity: A mixture containing perfluorooctanesulfonate, which may also be referred to as PFOS, FC-95 or as a component of FC-201AF. (1- Octanesulfonic acid) (CAS # 2795-39-3). Remarks: _ The 3M production lot number was not noted. The test sample i1s8F.C5-92%01dAiFet.hylCeunreregnltycionlfoburtmyaltieotnheirn,di3c7a.t8es1%it wisataerm,ix1t4ur%e eotfh3yl%enPeFgOlSyc,ol, 8.25% Acrylic foamer, 9% sodium octyl sulfate, 0.3% sodium lauryl sulfate, 3% triethanolamine, 6% sulfonated alkyl ether salts, and 0.05% tolyltriazole. The following summary applies to a mixture with incompletely rcehfalreacctttehreizteoxdiccoitnyceonfttrhaetfilounosorofcihmepmuirciatliecso.mDpaotnaemntaoyfntohteatcecsutrsaatmepllye. METHOD: Method: OECD Guideline 203 TGyLpPe:: NAocute static-renewal Year completed: 1995 Species: Pimephales promelas ASnuaplpyltiiecra:lAmqounaittiocriBnigo:sysTteemmpse,raItncu.r,eF,orptH,Colalnidns,diCsOso.lved oxygen. Exposure period: 96-hours SStpaetaisrtmiacanl Kmaertbheordmse:tLhCosd uvsailnugetsheweErPeAcaPlrcobuiltatAendalbyysitshePTrrogirmamme,dVersion 1.5. TLeesntgtfhisahnadgew:eiJguhvte:niles (A~8v9e-r9a0gedalyesn)gth = 25 mm Average weight = 0.109 g (wet) Loading: 0.607 g/L. TPeresttrceoantdmietnito:nsN:one. DDiilluuttiioonn wwaatteerr:chCearmbiosnt-rfyi:lteNroetd gweilvlenwater (3M #2, St. Paul, MN) Lighting: Not given. Stock and test solution preparation: The test material was added directly Ctoontcheendtilruattioinownastderosoinnga rwaetieg:htD/aviollyusmoelubtaisoins.renewal during the study. `Stabilityofthe test chemical solutions: Not noted. NExupmobseurreofverespsleilcsa:tes2:L 2glass beakers containing 1.8 Ltest solution. Number of fish per replicate: 10 000184 Numbeorf concentrations: five plus a blank control Water chemistry during the study: pH ran8g.e0(80-.946 h(coounrtsr)ol: exposure) Temper7a.t9u--re8.r3a(n3g2e0 (m0g-/9L6 hexopuorssu)r:e)1"7.6 -19.8 C Dissolved oxygen range (0-96 hours): 6.1-8.5 mg/L (control exposure) 2.18.5 mg/L (320 mg/L exposure)" * 320 mg/L (intermediate concentration) exposure values used because the highest two concentrations resulted in total mortality by 24 hours. RESULTS Nominal concentrations: Blank control, 100, 180, 320, 560, and 1000 mg/L. Element values: 96-hour LCso = 310 (270 - 370) mg/L. Element values based on nominal concentrations SRuebmsatraknsc:eTReesmtianrgkswafsielcdo. nTduhcetveadlouensarempioxrttuerde aapspdleystcorithbaetd miinxtthuereTeasntd not the fluorochermical proportion alone. ThOeNCtest sSaImOplNeS86-hour LCs for fatheadminnowwas determined to be 310 mg/L with a 95% confidence interval of 270 to 370 mg/L. Submitter: 3M Company, Environmental Laboratory, P.O. Box 33331, St. Paul, Minnesota, 55133 DATA QUALITY Reliability: Kiimisch ranking 2. Testing meets the criteria for quality testing. However, sample purity was not properly characterized and the study lacks analytical confirmation of the amountoffluorochemical proportion in the solution. REFERENCES This study was conducted by the 3M Company, Environmental St. Paul, MN, Lab Request number N2964, 1995. Laboratory, OTHER Last changed: 6/2600 000185 BEST COPY AVAILAB : Losmacenso L204. foarmote Description Environmental Lab --WorkSheet poe Lot 5 | outa 10/13/55 p Analyst: _GOD 4 Uo Howe Acute Topeciky di Fathead flint Boneplols oconclas Tost Tope: Sakic Feoremal ' VE wins wo Too BET il Bbc ce BTestTSabeshebsce:PcFCt-ICIAeFde 100A Aldud dhe Clovis bobbins fe di dual beakers Cilled dodo LSE mack" oid) bce ccndificned carkon Silboced well nedec Hived inlel with olan ed PD) Cone wall Concimg [LZ ALL Al zone eee 100 TEHgo AR 150 zo : 520 i580 : a 560 : dElo00: 5 000 CFO Ov ai SLasnit [rails 1otluib7sjaans)eDnvoic)daSrtaHl DIOARRREIECTE ia2 07, ol 07| iki dale Fo HEORIRNERIRLOES) of unl) BRT oC CEL poneCn fy RR TORRY |BESTS RC 9) RYRE: LC Ld . TT REY Lon i,rR WAR, T SIRe ELORIo Eh SNCe A Til hiis [fernsCSR [E ieRAN sr Aa SRE LA RE I ; lek i} I 00018 B OPY AVAILABLE Lab Request No. AI2964 > Eionmental La --Worksheet Pt --2-- ot =I-- ample Description J oa: 10/12/75 che des Toricily debe. rae S603. {dT ey 10/L 13/95) Rugeated <a sa) arncili ae { Ee demeon esday [iTS Dilufon a0: Temp 1.4C, andlWednesdaysofisfos. pHES DO 35ugll. eee To m k e dll a se s |GHEE = 0 mmm a |r A A ar Aen 00018 7 3ef Ss ENVIRONMENTALLABORATORY. tn nase S64 ACUTETORICIY TO FATHEAD MINNOW, PUEPHALES PRONELAS j TweTesT. same ox stAneRenewaL _X TesTsuBsTANGE: Fear 2 : DLURTRONWATER CARBONAnLWETT LELWAAETEDRGMWELLfe,TST.PA ---- Q- R ff RToEnSATcRES:HSOURCE2:9-904F0AOQRUTACTOILCUBNISO,SaYCSw0T.EnMS:,NC."TT5Fr_oo_i_rDA?TERECENEaD:vGsz_EG//2/75 5 sole n o2 37 No.oF PSWTEST CHAMBER: 10 FL lonomarare: 6. CIo/L z> testsoumonvouuwe: 11 smmortesTvessals: coleeaen 2 E ONEINT(I4/4A(0T(12E.cCD.11:/) DATETERMINATED: tesco tip) gc : vi esr I Croce) 6 Si3ogiTm_y_CAagPg =TT gART cord==EO2rFoV gSE er BD ER R ERE] Sear [aoe] . 1 mg | " Feeney CC] DeToTe7 os Hee] a w{e iu|ow|e E[aEDF ulap ne{aLl oula eclon aes] olen = alse Tela Ta Taseere frSel ianid feoof|fam ITeEe PTATFERPSp FRPEER = P|etane sReo Sew [aTr9 TRE sa Fieha leaf I[v=e[roapfL@P ioTlsaaTle-roT= -1 SvFiael]EffeEoes|]foeetshBEe aufIee ITPeOeahVeaST= 2 = --Topsatre=s4E ==TrSaoTII==T==| ] 2 Go EEE RE CT Fa [a eee mE m |aL ea lo] | oon rd 73 tn meer een p11 I PE Ev ce } Enric TT 553 me 7] = bE o 10 ETLTOTo)aL|[0OleTniAmSeRs L|SpTin0 3lopeiln]LSeOS GD2T10m | FSEoes| m: se Be OAEERG enoi TalR ER ATR MDR e+ R ERE S G pirrimea AcCiATeIAd]lGe51 Solel ve rom ae o oTo5o EE oi pn J FRE SRE AC TEIN WoALE Y1.35or RR AEN ER RRRRRRRRBDDRDRDDEEEEEEEGEC------ 000188 ; py debs ENVIRONMENTALLABORATORY w N29Y sar I oe -------------- TESTSUBSTANCE: NaCl, granular, CHEMPURE BRAND ACS, LOYM272KPKE Rr a Tomp.. C.pH_35.2,00. 5 mot sn ute "TESTFISHSOURCE: Aquatic BioSystems,Inc. DATERECEIVED: 12/55 mowAG: SG-90dume WGWE: Gutisigig AVGSZE 25sehen ol on 8a . 2 BN > 5 mrr-- iT r-- NO.OFFISHTEST CHAMBER: 10 LOADINGRATE: 0.6 ote wemnTES itJIS (enced) oare enmaree: 10/26/95 8Cc FE TF roEmEE|Vobr raeE2-- f0Ca PEs_ Te E e_e-- IlO_ Nm aL wrolmaeR E meanntnvCs_e LE _oa&_eT--eaohcAo_ anfE_)aS_na_dle=r_eA_lc_eh_r]]] w |u| darebledsven] lw me eae aa| 7s| ms PATIOS 28 or ue EY Zc aleee FEEqealse TeClsIavT wi 2 a l E wo Ewd Ear leE lee Lor rdSSeSTwoperE weelre a ppear BTlea 7s EHnEt 4s | fe 7 BAolen EE v ETt a CwE alo E Te i e es R areee 2E TeRnIECE F i| 4CEMSRE| a EReCeR al Le | imEeee ee ss fice Bl 5c IR gsii as wll SE SEA Ea EL Ee fi RE J ? Ly 000189 j oy Seb S BEST COPY AVAILABLE Environmental Laboratory ; LADaNw2s9l6oYl/sNsall Beh Ten. +. ceHour Acute Toxicity To Fathead Minnow, Plmephales Promelas Loading Rate DataSheat R restsusstance: FC=20VAE/ Ne Cl Ro LconeeSlibince 44 [CCsz_TToonig z22i7ce| [Toc T2a c | d [eldersT20 | (5 vitae oa] Co Tos2s 6 Fin: PO aah HR EHdERie abLiE Meelanep AS vg. Wi .(Q)Ce 1093x10=Lead g. YiREY TrGpilag t LE a LEA Tee E "rbd og Sl s SL aeatingaRaie=10e:sC7Et oa nd E RR EAERea et Geo sula tanRB HEa on Fata S a Bh amnaE oe ir A S25 Re i 000150