Document EmYno1aJ5Lvxbaq8bp2ampEgL

Alfa Products f 3UCT NAME: tron Division MATERIAL SAFETY DATA SHEET ____________________________typ. S'k______________ _ Lithium Phosphate' CHEMICAL NATURE: Metal Salt % ACTIVITY: BOILING POINT. 760 mm. Hg Mo Data Melting Point specific GRAVITY 2.54 VAPOR PRESSURE AT20*C. VAPOR DENSITY PERCENT VOLATILES BY WEIGHT appearance and ODOR m jt- Mot Applicable SOLUBILITY IN H,0 Not Applicable IONIC NATURE White solid SfNG MATERIAL Lithlus phosphate i * it - - m k....... % J: 99+Z 1205 C No Data Soluble tea TLV (Units) % None established PATAji mmsm FLASH POINT (test method) j Not flanmable FLAMMABLE LIMITS IN AIR. % by volum* No Data AUTOIGNITION TEMPERATURE LOWER No Data UPPER | EXTINGUISHING MEDIA Not flammable - Use water, carbon dioxide, dry chemical extingui shing agents., dry sand, or dry ground dolomite. --------- SPECIAL FIRE FIGHTING PROCEDURES JSUAL FIRE ANO uaPLOSION HAZARDS No special firefighting procedures needed, use normal procedures which include wearing NIOSH/MSHA approved self-contained breathing apparatus, flaae and chemical resistant clothing; hats, boots std gloves. If without risk, remove material from fire area. Cool containers with water from maximum aistadd'E. May emit toxic fumes of FO^ when heated to decomposition. 1 --------------------------------------------------------.---I. QQ 7%*0&>6/ventron DMthn coNFTo fnttal Alfa Products, 152 Andover Street, Danvers, Massachusetts 01923 (617) 777-1970, (415) 836-1777 Telex: 94-0378 ALFA DARS iblJl The burden of safe use of our MATERIALS must rest entirely WITH the user, we cannot ASSUME RESPONSIBILITY FOR TmE COMPLETENESS O ACCURACY OF ANY INFORMATION SUPPLIED BY US CONCERNING The HAZARDS OR RECCMMEnOcO USE OF The CHEMICALS. RESHOLD limit value FECTS OF OVEREXPOSURE URGENCY AND FIRST 3 PROCEDURES Kcne established 1 / lithium has a high CN'S toxicity. Large doses can cause dizziness and prostration, kidney damage, anorexia, nausea, apathy, coma and death.______________________________________________________________________ Remove from exposure. Eyes: Flush vlth copious amounts of water fea st least IS minutes. Skin: Remove any contaminated clothing. Flood skin with large volumes of water for 15 mlnutee. Ingestlon/Inhalation; Seek prempt, empetent medical attention. ABILITY UNSTABLE COMPATIBILITY aterials to avoid) stable X .ZARDOUS COMPOSITION PRODUCTS .ZARDOUS POLYMERIZATION May Occur | Will not Occur 1x EPS TO BE TAKEN ~ MATERTATTSflEtEASED \ SPILLED XSTE OISPOSAL METHOD CONDITIONS TO AVOID DATA Excessive heating No data POX CONDITIONS TO AVOID , >1 , PIUM>R^.EAKPROCEDURES fSrA;jl r-' 1) Wearing full proteetlve-clothingand-resplratory .protection (See Sect. ^IiyT^llminaCe^all^fidiiTces of-Ignition;" Cover spill with dry sand ~dt dry vermlcullte, mix well and carefully transfer to a well-marked container. Close container tightly. Submit or retain for disposal. Consult state, local, and federal regulaltons for proper disposal of Lithlun phosphate. :SPIRATORY PROTECTION (specify type) ENTILATION LOCAL EXHAUST MECHANICAL N10SH/MSHA approved dust mask for ordinary use, self-contained breathinz apparatus for gnereencies. Acequate SPECIAL OTHER 10TECTIVE GLOVES Rubber EYE PROTECTION OSHA approved safety goggles THER PROTECTIVE 3UIPMENT Lab coat and apron, flame & chemical resistant coveralls, eyewash capable of sustained flushing, safety drench shower and hygienic J^PECI/USPRECAUTIONS ^CAUTIONARY LABELING Warning 1 CNS toxicity can occur. 00 0856?5 CONFIDENT TAl THER HANDLING AND TORAGE CONDITIONS Keep container tightly closed. Store In a cool, dry, we11-ventilatt area. Wash thoroughly after use. r v _.y/J Associated Lead Inc. " MATERIAL SAFETY DATA SHEET - (MA_HUf actumrs .! nami i int i .i ASSOCIATED LEAD, INC. `-,7aW^ A MJN tevV3H ----------------------------------------- ----------- ----------------- &$.. . . REGULATORY AFFAIRS DEPARTMENT 2/27/84 SIMM A00ftS4 2545 ARAMINGO AVENUE CITT. t*t. w PHILADELPHIA, PA. 19125 PRODUCT CLASS Stabilizer MAMUfACTUM*** COO* I D. 34535 TIUD* HAM* iMtlGENCV TIllFHONI HO. ________ v Lectro 65- ^ _ 215-427-'3 000 --vr/V?V "'Tv'* INGREDIENT PERCENT BY WEIGHT *&mm nv FFM n fl/m* wsmrnmm V-"~-W - - . LEL% VAPOR PRESSURE mm Hg @ A*F Lead-Phthalate Complex (1) OSHA Standard, 29 CFR 1910.1025 100.0 -05{2) 0.2 lZ) A 2H year implementation including cable coating, manufacturing. schedule pottery, i. e> effect a plosives. ; of Oan. 1 glass, amm I, 1982 jnition fo anil certai industries plastft s and rubber (2) OSHA Standard, 29 CFR 1910.1000 Table Z-2 in effect during the 2k vt ar implementation--pe 4od;- \ *-1 . THRf&HOlD UMlT VAUJI ' | _ T *m -- Si iSi!' -jkfe/ftltr? ;jf ijfepjjk; 'mOng/m based on lead using engineering and work practice controls infective 2b yrs. from 1/1 TS Of OVEREXPOSUtt "' nding on individual suscc-ptabil ity and degree of overexposure, effects are generally seen ;:,ly after long-term exposure, although short-term high-level exposure may also be poisonous. r -ptoms may include tiredness, decreased appetite, metallic taste and stomach cramps resem bling colic (intermittent rather than continuous pain). More severe symptoms could include .'-'e muscle weakness, intense headaches and on rare occasions convulsions and even more rare! rath. Kidney damage may occur without symptoms. Lead crosses the placenta. Fetal exposure hould be kept within guidelines of the Communicable Disease Center of the U.S. Department :K-30ug/100g of blood. tvEfcCE^CY *sD PiRJT AID PkOCEOUKES ^normal Ingestion - Induce vomiting. Use syrup of ipecac-one ounce followed by eight ounces T rater. Call a physician at once. ur : - 'arnal - The product may be removed by washing with soap and water. fiT r r *c>ivl STEfi TO 6E TAKEN IN CASE MAUR'Al, i$ ifiEtitD OR SPIUED -'H - l f 'f'VVoo.r f;yci ear gloves, goggles and respirator. Clean area returning all material possible to container * -.et use compressed air for cleaning floors and other surfaces. These surfaces should be r.ed by vacuuming, taking care that the material is not returned to the work area. Wi5Tf DiSFOSAl METHOD :-ep waste rags in a labeled safety container-do not incinerate. Disposal must be. in O ccordcnce-wit-h- state, local er federal regulation. [ 7.... RfciF.tAlOliY PYOtlCTlON ]OSH approved respiratory protection must be used in accordance with existing standards. ::-:dical Removal Protection (MRP) and biological surveillance are necessary. Respirator must La worn if PEL of 0.05mg/m3 is' exceeded^ See 29CFR 1910.1025(k); 1910.134. vInTilaTION ;I work areas where lead compounds are used must be ventilated to keep TLV below acceptable >t?TfaSi.GiovSee 29CFR 1910.94. EYE PROTECTION Y 6S o:hepROTECTivicouipment . Yes - goggles .. ... , ------ ---------------------------------- Use respi rotor*--Use--cl osir v/oy'kclothes.--Ch9nQfii.Mwor.kclAfa5--Q31 ly*-- PRICAUiiQnS TO IE TAKEN IN HANDLING AND STOKING DO 085677 CONFTDENTIAl 5 every precaution to avoid contamination of the atmosphere. *Special care should be givei -emoving lead from hair and under fingernails. ^Working or contaminated clothes and shoes ,, not be worn home. ^Before entering eating areas, work clothing should be removed or loo st vacuumed off clothing surface. *Take every precaution to avoid ingestion and inhalation Jse gloves and avoid spilling on hands, face or body. *Do not smoke, eat or apply cosmetics i work area. *i,'ash hands and face thoroughly before entering into eating areas. While the lformation and recommendations set forth are believed to be accurate as of the date hereof, isociated Lead Inc. MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM T 'rr no crTlO'i p:cFn thfdfqn. __Ennp_jjlp nf -fhp nature of the product, user assumes all_,_r N/A--NOT APPLICABLE MATERIAL SAFETY DATA SHEET (Approved by U.8. Department of Labor "Essentially Similar" to F rm LSD-008-*) "535)1 onhSTURER'S KAMI Section I N L Industries, Inc. Pigments end Chemicals Division street address Post Office Box 420 Jersey 08520 Minmitti'-WM0 EXT. 473 - Manager, Quality Control CHEMICAL NAME AND IVNONYMS Normal Lead Stearate TRADE NAME Leadstar CHEMICAL family Lead Stearate FORMULA Pb(C8H17C0)2 Section II - HAZARDOUS INGREDIENTS PIGMENTS PAINTS, PRESERVATIVES. & SOLVENTS % tlv (Unite) solvents NPVLA 6-70 % TVV (Uflitft) CATALVfT V1 additives OTHERS HAZARDOUS MIXTURES OF OTHER LIQUIDS. SOLIDS. OR GASES PbO % nv (Unito) 29 Q. 2mg/M~ OILING POINT I'F ) VAPOR PRESSURE (mm Hj.| VAPOR 0ENSITY (AIRsI) SOLUBILITY in water appearance ANO ODOR Section III - PHYSICAL DATA N/A N/A N/A Insol. SPECIFIC GRAVITY (H,0=1) PERCENT VOLATILE BY VOLUME (%) (EVAPORATION RATE =1) Fine White Powder l.A N/A N/A FLA" TlNT*fMfTHOD USED) Section IV ~ FIRE AND EXPLOSION HAZARD DATA N/A Flammable limits EXTINGUISHING MEDIA Chemical, Foam, CO2, Water (fog) on fires involving Leadstar SPECIAL FIRE FIGHTING PROCEDURES Decomp ses above 300C. with out melting JlL DO 085628 CONFIDENT! Al Hal pipe and explosion hazard* Because`Of the high fatty aCid content DfLeadSCar abnormal concentre of dust coupled with abnormally high temperatures and/or spark sources may cause^a du*t explosion Ltua'tidfTFT c .Reference Section II Section V - HEALTH HAZARD DATA tmresholo limit value Prolonged excessive absorption of Inorganic lead by Ingestion or inhalation of' o dustimects overexposure and fume is characterized by adornInal pain (lead colic), metallic taste "''j Bbuth, iosS dl weight, pains in muscleiTand muscular weakness. The similarity of these symptoms with those of other Illnesses require that excessive ahaorpMnn of. lead be.verified by medical----examination ana analysis of biological specimens. consultemergency and hast aid procedures a physician if you have symptoms of illness. Abnormal Ingestlc * Call'a physiccliaan'at Obrnicce,. As- first aid, induce vomiting, give milk and magnesium sulfate . External; Normal work A*y can ba. effectively cleansed with flnap- and water. Eyes: Use first aid procedure for dust.________ \__________________________ t ability UNSTABLE STABLE INCOMPATABIUTY (UaUrialt is avoid) hazardous decomposition products Section VI - REACTIVITY DATA CONDITIONS TO AVOID X Can react vigorously with mineral acids Pb, PbO At high temperatures toxic fumes are emitted HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X Section VII -- SPILL OR LEAK PROCEDURES steps TO Be taken in case material is released or spilled Sweep carefully, wear gloves, goggles and respirato > WASTE DISPOSAL METHOD Landfill or smelter. Disposal must be done in accordance with local. state, and federal regulations. Section VIII - SPECIAL PROTECTION INFORMATION res iratory protection (Sptoiy trp.) DUSt and/or fume respirator (Bureau of Mines Approved) VENTILATION local exhaust Ventilation provided as required by lob condition to keep TLV liste in Section II below acceDtable limits? MECHANICAL (CtatroU other PROTECTIVE GLOVES OTHER PROTECTIVE EQUIPMENT yes EYE PROTECTION Change i.n wor,k c.loth. es goggles _____________ Section IX-SPECIAL PRECAUTIONS --________________ confidential J_ ^8-5629 Other precautions Avoid dusting. P rsonnel must wear prescribed protective equipment. Ground storage hoppers ______________ ___________________________________________________ June 11, 1973 Pr duct Ho.: LZ 0038 MATERIAL SAFETY DATA SHEET SECTION I mfacturer's Name enrich Petrochemicals. Inc. Address 140 E. 22nd Street, Bayonne, KJ 07002-0032 Chemical Name Zirconium IV neoelkanolato, tris(dioctyl) pyrophosphsto-0 Chemical Family Emergency Telephone No. (201) 823-9000 Date of Preparation January 22, 1986 Trade Name Ren-React* LZ 38 Formula Organo-Zirconate Ingredient ROZr [0P(0) (0H)0P(0) (OCgHiy^^ SECTION II - HAZARDOUS INGREDIENTS CAS Nominal Registry No. Percent Threshold Limit Value (TLV-TWA) Permissible Exposure Limit (PEL) A) Ken-React LZ 38 B) Isooctyl Alcohol C) N-propylalcohol Developmental 95 26952-21-6 LT 5 71-23-8 LT 5 NE 270 mg/M3 500 mg/M3 NE NE NE Hazard Classification - 0SHA Health Hazard: Irritant OSHA Physical Hazard: Combustible liquid SECTION III - PHYSICALDATA AB Boiling Point (F): 345 361 Vapor Pressure (mm Hg.): NE 5 68F ,)or Density (air =1): GT 1 4.5 Solubility in Water: Negligible Negligible Specific Gravity (H2O =1): 1.1 0.83 Percent Volatile by Weight @ 77F: 5 50 Evaporation Rate (H2O =1): LT 1 LT 1 Appearance and Odor: Reddish liquid, fatty odor C 207 10 @ 57F 2.07 Miscible 0.80 100 GT 1 SECTION IV ~ FIRE AND EXPLOSION HAZARD DATA Flammable Limits Flash Point (Method Used): LELUEL (TCC) 170F NE NE Extinguishing Media: Foam (X), Dry Chem. ( ), CO2 (X), Water Spray ( ) Special Fire Fighting Procedures: Wear self contained breathing apparatus with a full facepiece operated in a pressure demand mode. Also, wear full protective clothing. Pnusual Fire and Explosion Hazards: None known SECTION V ~ HEALTH HAZARD DATA Threshold Limit Value: NE Effects of Overexposure: Irritant to skin, eyes and respiratory tract. swallowed. Avoid all direct contact with this material. Harmful if NA = Not Applicable/NE - Not Established/UNK = Unknown/LT = Less Than/GT APX = Approximate (Essentially similar to OSHA-20 Form) Greater Than DO cONp rFNrTAi Product Mo.: LZ 0038 SECTION V - HEALTH HAZARD DATA (continu d) ~"---------------- Emergency and First Aid Procedures; External Contact: Wash thoroughly with soap and water. Consult a physician. Eye Contact; Flush with water for 15 minutes - consult a physician. Ingestion; Immediately consult a physician, before taking any action. Inhalation: Remove to uncontaminated area - consult a physician. A. SECTION VI - REACTIVITY DATA Stability; Unstable ( ) Stable (X) Conditions to Avoid; Contact with alkaline materials, amines. Incompatibility (materials to avoid); Alkaline materials, amines Hazardous Decomposition Products: Oxides of carbon, phosphorous, possibly phosphoric acid if decomposed in the presence of water. Hazardous Polymerization; Conditions to Avoid: NA May Occur ( ) Will Not Occur (X) SECTION VII - SPILL OR LEAK PROCEDURES Steps to be taken in Case Material is Released or Spilled; Collect and place in an appropriate disposal container. Use proper safety equipment when handling this material. Prevent entry to surface and ground waters. Promptly remove any contaminated soils. Waste Disposal Method: Dispose of in accordance with applicable Federal, State and local regulations. SECTION VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection; NIOSH/MSHA approved vapor respirator. Ventilation; Local Exhaust (required) Mechanical (required) Protective Gloves; Polyolefin Eye Protection; Safety Goggles Hygenic Practices; Wash thoroughly before eating, smoking, applying cosmetics, etc. Thoroughly launder work clothing before reuse. Other Protective Equipment; Eye bath, safety shower SECTION IX - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing; Store containers closed in a cool dry place. Other Precautions; pH of 5% solution of Ken-React LZ 38 in HjO APX 3. DO 085631 CONFTOFNTTAl. WHILE THE INFORMATION ACCUMULATED AND SET FORTH HEREIN IS BELIEVED TO BE ACCURATE AS OF THE DATE HEREOF. KENRICH PETROCHEMICALS. INC. MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. THE INFORMATION CONTAINED HEREIN WAS COMPILED IN ACCORDANCE WITH APPLICABLE FEDERAL REGULATIONS AND MAY BE BASED UPON INFORMATION PROVIDED BY OUR SUPPLIERS. January 29, 1986 KENRICH PETROCHEMICALS, KEN-RKACT ZIRCONATE COUPLING AGENT LZ 38 PRODUCT DATA SHEET INC. Chemical Description: Chemical Strncture: Zirconate Type: Zirconium IV neoalkanolato, trisfdiocty1) pyrophoaphato-0 00 II H ^0-c8b17 RO-Zr- OP-O-P I Vc8h17 OH 3 Neoalkoxy modified monoalkoxy Typical Properties: Physical Form Liquid Solids, % 95 Color, descriptive Gardner Transparent, Reddish 4 Viscosity, cps @ 77F (25C) 360 Specific Gravity @ 77F (16"C) 1.10 Flash Point, F (TCC) 170 Initial Boiling Pt., "F, ASTM 345 Ph (saturated solution) 6 Solubility Isopropanol - Soluble Xylene - Soluble Toluene DQP - Soluble - Soluble Mineral Oil - Insoluble (<1%) Water - Insoluble -T Nft^Ntt^i. Emulsification Technioue(s): (E^) Add 2% nonyl phenol ethoxylate (Qj) Solubilized by reaction with excess DMAMP-80 140 EAST 22rd STREET . P.O. BOX 32 BAYONNE. N,J. 07002*0032 Telephone: (201) 623-9000 TELEX 12-5023 NEOALKOXY ZIRCONATES Tetrafunctional organometallic compounds based on titanium (Ti), silicone (Si) and Zirconium (Zr) make useful coupling agents because the central metal's tetravalency is conducive to electron sharing. Titanium ester derived coupling agents have an advantage in their relative ease of manufacture and molecule building as compared to organosilanes, thus providing specific function for a vide scope of composite applications. However, titanium acts as a reducing agent in the presence of peroxide. Peroxide free radicals are thereby eliminated and cure efficiency is diminished as Ti+^ is reduced to Ti+3. On the other hand, Zn+^ i8 an activator for peroxide resulting in a frequently desirable acceleration of peroxide and air-based cures - the basis for many thermoset and coatings systems. Since zirconates are not as active Lewis acids as titanates, they have less of a catalytic effect in urethane systems and, therefore, may prove useful as cure rate independent rheology modifiers. Another area of concern in using titanates is the possibility of undesirable color formation experienced when they come in contact with additives containing phenolic functionality. Phenolic functionality is encountered in the form of: heat and light stabilizers (antioxidants) used in thermoplastic vinyl and polyolefin systems, alkyds and urethanes. Phenolics are also used as chain stops in polyester systems, urethanes, alkyds and acrylics. Zirconates in general are not color body producers in contact with phenols other than nitrophenols. Both organotitanate and organozirconate coupling agents as produced by Kenrich do not interact with hindered amines (light stabilizers and/or antioxidants - HALS) under common operating conditions. Zirconium chemistry provides a functional equivalent alternative to silanes and titanates in these instances. Heretofore, organozirconates have been restricted in availability because of their high cost. Kenrich has now overcome the cost hurdle through proprietary (patents applied for) manufacturing techniques and is able to supply these materials at commercially realistic prices. The neoalkoxy zirconates LZ 01, LZ 09, LZ 12, LZ 38 and LZ 44 are parallel organofunctional materials to neoalkoxy titanates LICA 01, LICA 09, L1CA 12, LICA 38 and LICA 44. Also, since the aliphatic amine functional KR 44 and LICA 44 titanates have been so successful in adhesive applications, LZ 97, an aromatic amine functional zirconate as well as LZ 44 was developed. Reactive Substrates: Minerals, silicas, silicates, metals-oxides, peroxides. hydrates, acetates, borates, sulfates, carbonates, nitrates, carbon black, graphite, aramid, pigments, cellulosics, sulfur, azodicarbonamide, polymers, etc. Amounts to.Use: Zirconate use level can vary from ppm when used as a catalyst to 10% of formulation when used as a comonomer, A general rule of thumb is to use 0.2% by weight of polymer or 0.2% to 0.5% by weight of filler, whichever is the greater. Typically, a 2.7 Sp. Gr., 2.5 micron mineral filler such as CaCOg will require 0.2% to 0.4% zirconate by weight of CaC03* 0.1% to 0.5% is a good range for ladder studies. Suggested Applications: See Neoalkoxy Zirconate (LZ) Selection Tables for Coatings, Thermoset Polymers and Elastomers as listed in the Ken-React Reference Manual, Bulletin KR-1084L. DO 085633 CONFTDf-NTTAt .Product No.: LZ 0044 * MATERIAL SAFETY DATA SHEET SECTION I 'nufacturer's Name Aenrich Petrochemicals, Inc. Address 140 E. 22nd Street, Bayonne, NJ 07002-0032 Chemical Name Zirconium IV neoalkanolato, tris(2-ethylenediamino-ethanolato) Chemical Family Organo-Zirconate Emergency Telephone No. (201) 823-9000 Date of Preparation January 24, 1986 Trade Name Ken-React LZ 44 Formula ROZr(OC2H4OTC2H4NH2)3 Ingredient SECTION II - HAZARDOUS INGREDIENTS CAS Nominal Registry No. Percent Threshold Limit Value (TLV-TWA) Permissible Exposure Limit (PEL) A) Ken-React LZ 44 P86-358 B) N-propylalcohol 71-23-8 C) 2-ethylenediaminoethenol 111-41-1 95 LT 5 LT 5 NE 500 mg/M^ NE NE NE NE Hazard Classification - OSHA Health Hazard: Irritant OSHA Physical Hazard: NA SECTION III - PHYSICAL DATA AB Boiling Point (F): 300 207 Vapor Pressure (mm Hg.): Vapor Density (air = 1): NE GT 1 10 @ 57 F 2.07 ubility in Water: Negligible Miscible Specific Gravity (H20 = 1): 1.17 0.8 Percent Volatile by Weight I 77 F: 5 100 Evaporation Rate (H20 = 1): LT 1 GT 1 Appearance and Odor: Yellow liquid, amine odor. C 470 LT 0.01 3.6 100% 1.03 0 LT 1 SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flammable Limits Flash Point (Method Used): LELPEL (TCC) GT 200 F NE NE Extinguishing Media: Foam (X), Dry Chem. (X), C02 (X), Water Spray (X) Special Fire Fighting Procedures: Wear self contained breathing apparatus with a full facepiece operated in a pressure demand mode. Also, wear full protective clothing. Unusual Fire and Explosion Hazards: Direct water stream may cause frothing. SECTION V - HEALTH HAZARD DATA Threshold Limit Value: NE Effects of Overexposure: Irritating to skin, eyes and respiratory tract. swallowed. Avoid all contact with this material. Harmful if N* * Not Applicable/NE = Not Established/UNK = Unknown/LT = Less Than/GT = Greater Than . * Approximate (Essentially similar to OSHA-20 Form) DO 085634 CONFTDFNTTAl .Product No.: LZ 0044 SECTION V ~ HEALTH HAZARD DATA (continued) Emergency and First Aid Procedures: External Contact: Wash thoroughly with soap and water. Consult a physician. Eve Contact: Flush with water for 15 minutes - consult a physician. Ingestion: Immediately consult a physician, before talcing any action. Inhalation: Remove to uncontaminated area - consult a physician. ) SECTION VI - REACTIVITY DATA Stability; Unstable ( ) Stable (X) Conditions to Avoid: Contact with acids. Incompatibility (materials to avoid): Acids Hazardous Decomposition Products: Oxides o? carbon and nitrogen, ammonia, oxides of zirconium Hazardous Polymerization: Conditions to Avoid: NA May Occur ( ) Will Not Occur (X) SECTION VII - SPILL OR LEAK PROCEDURES Steps to be taken in Case Material is Released or Spilled: Collect and place in an appropriate disposal container. Use proper safety equipment when handling this material. Prevent entry to surface and ground waters. Promptly remove any contaminated soils. Waste Disposal Method: Dispose of in accordance with applicable Federal, State and local regulations. , SECTION VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection: NIOSH/MSHA approved organic vapor respirator. Ventilation: Local Exhaust (required) Mechanical (required) Protective Gloves: Polyolefin Eve Protection: Safety Goggles Hygenic Practices: Wash thoroughly before eating, smoking, applying cosmetics, etc. Thoroughly launder work clothing before reuse. Other Protective Equipment: Eye bath, safety shower SECTION IX - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing: Store containers closed in a cool dry place. Other Precautions: pll of 5% solution of LZ 44 in ^0 APX 11. Avoid all direct contact with this product. WHILE THE INFORMATION ACCUMULATED AND SET FORTH HEREIN IS BELIEVED TO BE ACCURATE AS OF THE DATE HEREOF, KENRICH PETROCHEMICALS, INC. MAKES NO WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM RELIANCE THEREON. THE INFORMATION CONTAINED HEREIN WAS COMPILED IN ACCORDANCE WITH APPLICABLE FEDERAL REGULATIONS AND HAY BE EASED UPON INFORMATION PROVIDED BY OUR SUPPLIERS. DO 085635 CONFTDFNTTA =333i333El lJ January 29, 196 KENRICH PETROCHEMICALS, KEIJ-REACT ZISCC1IATE COUPLING AGEHT LZ 44 PRODUCT DATA SHEET INC Chemical Description: Zirconium IV neoalkanolato, tris(2-ethylenediamino-O) ethanolato-0 Chemical Structure: Zircooate Type: Typical Properties; R0-Zr4OC2n4->!Il-C2H4-HH2b Neoalkoxy modified monoalkoxy Physical Form Solids, % Liquid '95 Color, descriptive Gardner Transparent (tentative) 13 Viscosity, cps @ 77F (25C) 1000 Specific Gravity @ 77F (16C) 1.17 Flash Point, F (TCC) ..200 Initial Boiling Pt., F, ASTM 300 Ph (saturated solution) Solubility 11 Isopropanol - Soluble Xylene - Limited (*5%) Toluene - Limited (*5%) DOP - Reacts Mineral Oil - Insoluble (<1%) Water - Insoluble (*1%) Emulaif ication Techniques); (Ej) Add 2% nonyl phenol ethoxylate U3 AST ::~j s"iu 3.o : ex ?: b-sv.s, -,.j, 07C02-. 03; v^cnon*- .rc-iaiisooo DO 085636 CONFIDENTIAL IQ *#AMfOyTMuct Tfc.ux 12VJ23 V.EV.SEF IRIOALEOX? ZIRCOHATES 'V- Tetrafunctional organometal 1 ic compounds based on titanium (Ti), silicone (Si) and Zirconium (Zr) make useful coupling agents because the central metal's tetravalency is conducive to electron sharing. Titanium ester derived coupling agents have an advantage in their relative ease of manufacture and molecule building as compared to organosilanes, thus providing specific function for a wide scope of composite applications. However, titanium acts as a reducing agent in the presence of peroxide. Peroxide free radicals are thereby eliminated and cure efficiency is diminished as Ti+^ is reduced to Ti+^, On the other hand, Zn+^ is an activator for peroxide resulting in a frequently desirable acceleration of peroxide and air-based cures - the basis for many thermoset and coatings systems. Since zirconates are not as active Lewis^acids as titanates, they have less of a catalytic effect in urethane systems and, therefore, may prove useful as cure rate independent rheology modifiers. Another area of concern in using titanates is the possibility of undesirable color formation experienced when they ccme in contact with additives containing phenolic functionality. Phenolic functionality is encountered in the form of: heat and light stabilizers (antioxidants) used in thermoplastic vinyl and polyolefin systems, alkyds and urethanes. Phenolics are also used as chain stops in polyester systems, urethanes, alkyds and acrylics. Zirconates in general are not color body producers in contact with phenols other than nitrophenols. Both organotitanate and organozirconate coupling agents as produced by Kenrich do not interact with hindered amines (1ight stabilizers and/or antioxidants - HALS) under common operating conditions. Zirconium chemistry provides a functional equivalent alternative to silanes and titanates in these instances. Heretofore, organozirconates have been restricted in availability because of their high cost. Kenrich has now overcome the cost hurdle through proprietary (patents applied for) manufacturing techniques and is able to supply these materials at commercially realistic prices. The neoalkoxy zirconates LZ 01, LZ 09, LZ 12, LZ 38 and LZ 44 are parallel organofunctior.a 1 materials to neoalkoxy titanates LICA 01, LICA 09, L1CA 12, LICA 38 and LICA 44, Also, since the aliphatic amine functional KU 44 and LICA 44 titanates have been so successful in adhesive applications, LZ 97, an aromatic amine functional zirconate as well as LZ 44 was developed. Reactive Substrates: Minerals, silicas, silicates, metals-oxides, peroxides, hydrates, acetates, borates, sulfates, carbonates, nitrates, carbon black, graphite, aramid, pigments, cellulosics, sulfur, azodicarbonamide, polymers, etc. Amounts to Use Zirconate use level can vary from ppm when used as a catalyst to 10% of formulation when used as a comonomer. A general rule of thumb is to use 0.22 by weight of polymer or 0.22 to 0.5% by weight of filler, whichever is the greater. Typically, a 2.7 Sp. Cr., 2.5 micron mineral filler such as CaCO-j will require 0.2% to 0.4% zirconate by weight of CaCOj. 0.1% to 0.5% is a good range for ladder studies. Suggested Applications: See Neoalkoxy Zirconate (LZ) Selection Tables for Coatings, Thermoset Polymers and Elastomers as listed in the Ken-React Reference Manual, Bulletin KR-10S4L. OO 085637 CONFIDENTIAL Product No. : LZ 0097 MATERIAL SAFETY DATA SHEET SECTION I Manufacturer's Name Xenrich Petrochemicals, Ina Address 140 E. 22nd Street, Bayonne, NJ 07002-0032 Chemical Name Zirconium IV neoalkanolato. tris(3-amino) phenolato-0 Chemical Family Emergency Telephone No. (201) 823-9000 Date of Preparation April 16. 1986 Trade Name Ken-React LZ 97 Formula Organo-Zirconate Ingredient RQZr(0C6H4NH2-m)3 SECTION II - HAZARDOUS INGREDIENTS CAS Registry No. Nominal Percent Threshold Limit Value (TLV-TOA) Permissible Exposure Limit (PEL) A) Ken-React LZ 97 B) N-propyl alcohol C) 3-amino phenol Developmental 67 71-23-8 LT 5 59127-5 LT 5 NE 500 mg/M3 NE NE NE NE Hazard Classification - OSHA Health Hazard: Not a skin irritant However, in the absence c eye irritation testing. this product must b considered a potential eye irritant. OSHA Physical Hazard:NA SECTION III! - PHYSICAL DATA AB C Boiling Point (F): 300 207 327 @ llmmHg Vapor Pressure (mm Hg. ): NE 10 @ 27 F UNK Vapor Density (air = 1): GT 1 2. 07 UNK Solubility in Water: 5% Miscible Sol uble Specific Gravity (H2O = 1): 1. 25 0. 8 UNK Percent Volatile by Weight @ 77 F: 5 100 NA Evaporation Rate (HoO = 1): LT 1 GT 1 LT 1 Appearance and Odor: Brown liquid, phenolic odor SECTION IV - FIRE AND EXPLOSION HAZARD DATA Flammable Limits Flash Point (Method Used): (TCC) 210F LEL UEL NE NE * Extinguishing Media: Foam (X), Dry Chem. ( ). CO 2 (X), Water Spray ( ) Special Fire Fighting Procedures: Wear self contained breathing apparatus with a full facepiece operated in a pressure demand mode Also, wear full protective clothing Unusual Fire and Explosion Hazards; None known SECTION V - HEALTH HAZARD DATA Threshold Limit Value; NE Effects of Overexposure: Not a skin irritant according to OSHA Standard 29 CFR 1910.120 However, may irritate eyes and respiratory tract May be harmful if swallowed. NA = Not Applicable/NE = Not Established/UNK = Unknown/LT = Less Than/GT = Greater Than APX = Approximate (Essentially similar to OSHA-20 Form) DO 085638 OONriDENTTAl Product No.i SECTION V ~ HEALTH HAZARD DATA (continued) LZ 0097 Emergency and First Aid Procedures: External Contact; Hash thoroughly with soap and water. Consult a physician. Eye Contact; Flush with water for 15 minutes ~ consult a physician. Ingestion; Immediately consult a physician, before taking any action. Inhalation; Remove to uncontaminated area - consult a physician. SECTION VI - REACTIVITY DATA Stability; Unstable ( ) Stable (X) Conditions to Avoid; Strong acids. Incompatibility (materials to avoid); Strong acids. Hazardous Decomposition Products; Oxides of carbon, nitrogen, ammonia Hazardous Polymerization; Conditions to Avoid; NA May Occur ( ) Will Not Occur (X) SECTION VII - SPILL OR LEAK PROCEDURES Steps to be taken in Case Material is Released or Spilled: Collect and place in an appropriate disposal container. Use proper safety equipment when handling this material. Prevent entry to surface and ground waters. Promptly remove any contaminated soils. Waste Disposal Method; Dispose of in accordance with applicable Federal, State and local regulations. SECTION VIII - SAFE HANDLING AND USE INFORMATION Respiratory Protection; NIOSH/MSHA approved organic respirator. If large amounts of vapor are present, a full face piece with supplied air is necessary. Ventilation; Local Exhaust (required) Protective Gloves: Polyolefin Mechanical (required) Eye Protection; Safety Goggles for small quantities. If large quantities of vapor are generated, a full facepiece with supplied aire is necessary. Hygenic Practices; Wash thoroughly before eating, smoking, applying cosmetics, etc. Thoroughly launder work clothing before reuse. Other Protective Equipment; Eye bath, safety shower SECTION IX - SPECIAL PRECAUTIONS Precautions to be taken in Handling and Storing; Store containers closed in a cool dry place. Other Precautions: pH of 5% solution of L2 97 in H20 APX 8. DO 085639 CONFIDENTIAL WHILE THE INFORMATION ACCUMULATED AND SET FORTH HEREIN IS BELIEVED TO BE ACCURATE AS OF THc. DATE HEREOF, KENRICH PETROCHEMICALS, INC. MAKES N0 WARRANTY WITH RESPECT THERETO AND DISCLAIMS ALL LIABILITY FROM EL TANCE THEREON. THE INFORMATION CONTAINED HEREIN WAS COMPILED IN ACCORDANCE WITH APPLICABLE FEDERAL REGULATIONS AND MAY BE BASED UPON INFORMATION PROVIDED BY CUR SUPPLIERS. MATERIAL SAFETY DATA 68937 41 7 KRONITEX(R) 1O0 TRIISOPROPYLAtED PHENYL PHOSPHATE EMERGENCY TELEPHONE NUMBERS CHEMTREC <800) 424-9300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT NFPA Designation 704 OEGAEE OF HAZARD 4 * EXTREME 3 * HIGH 3 * moderate 1 * SLIGHT 0 * INS'GNFICANT HEALTH (BLUE} 4 HFMC FLAMMABILITY (BED) 2m o REACTIVITY , (YELLOW) special HAZARD REVISION: 08 EFFECTIVE: 03/13/90 PRINTED: 08/20/90 PREPARED FOR USE BY. C.P. HALL COMPANY 7300 S. CENTRAL CHICAGO IL 60638 IDENTIFICATION INFORMATION PROVIDED BY : FMC CORPORATION 2000 MARKET STREET PHILADELPHIA, PA 19103 PRODUCT INFORMATION ="==*==**======*=*=**"=*= SYNONYMS............................ r SHIPPING NAME - DOT. I AT A IMCO FORMULA............................... CHEMICAL FAMILY.......... PRODUCT USES.................. MIXED ISOPROPYLPHENYL PHENYL-PHOSPHATE KRONITEX(R) TRIARYL PHOSPHATE KRONITEX(R) TRIARYL PHOSPHATE KRONITEX(R) TRIARYL PHOSPHATE (RO)3P0 ORGANOPHOSPHATE FLAME RETARDANT PLASTICIZER? CATALYST CARRIER AND PIGMENT VEHICLE FOR POLYURETHANES? PROCESSING AID, PLASTICIZER AND FLAME RETARDANT IN RUBBIR BELTING. PRECAUTIONARY INFORMATION PRECAUTIONARY STATEMENT..: HEALTH: MIST GENERATED BY HEAT,VIOLENT AGITATION (PLEASE USE THIS STATEMENT OR SPRAYING WILL IRRITATE EYES,NOSE,& THROAT. TO SATISFY THE IN-PLANT CONTINUOUS CONTACT WITH LIQUID WILL IRRITATE LABELING REQUIREMENTS SKIN. LONG AND CONTINUOUS CONTACT WITH THE OF THE OSHA HAZARD LIQUID OR MIST MAY EFFECT THE NERVOUS SYSTEM. COMMUNICATIONS STANDARD PRODUCT PRESENTAS A NEGLIGIBLE HAZARD TO HEALTH 29CFR 1910.1200) DURING NORMAL HANDLING EXCEPT AT ELEVATED TEMP- ATURES & CONTINUOUS/PROLONGED CONTACT WITH SKIN. PHYSICAL: NO SIGNIFICANT HAZARD EXCEPT IN FIRE CONDITIONS WHERE PHOSPHORUS OXIDE GASES ARE EMITTED. J 11, DhMbutort nO 085640 CONFIDENT' _________i rtufc. 01 MATERIAL SAFETY OATA 68937 41 7 2 NFPA Designation 704 KRONITEX(R) 110 ( TfUISOPROPYLATED PHENYL PHOSPHATE DEGREE Of HAZARO EMERGENCY TELEPHONE NUMBERS 4 * EXTREME 3 HIGH 2 MODERATE I * SLIGHT 0 & INS1GNFICANT HEALTH (BLUE) 4 CHEMTREC (8001 424-9300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT -FMC FLAMMABILITY (RED) REACTIVITY > (YELLOW) SPECIAL HAZARD REVISION: 08 EFFECTIVE: 03/13/90 PRINTED: 08/20/90 CBBIKXBXVStl SEY =SSS1EBS&eXSS INGREDIENTS CAS# AND COMPONENT............... : CANADIAN PRODUCT IDENTIFICATION NUMBER____ : MATERIAL/COMPONENT: PHENOL, ISOPROPYLATED, PHOSPHATE (3-1) TRIPHENYL PHOSPHATE CAS NO. 68937-41-7 115-86-6 3018 FOR ORGANIC PHOSPHATES, LIQUID. BCBBBSBESBBCSSSBBBC=SBSBB8 PHYSICAL DATA BBBCSBeBBBBBBBSBBSBBBBBBEBBBBSSCS MELTING/FREEZING POINT...: < -40*C BOILING POINT............................ : @ 4MM HG 220-270*C (428-518*F) VAPOR PRESSURE......................... ! 0.26MM HG 150*C (320*F) VAPOR DENSITY (AIR = 1)..: ABOVE 1.0 ROOM TEMPERATURE APPEARANCE AND STATE: CLEAR LIQUID ODOR...................................................: ODORLESS SPECIFIC GRAVITY (H20 =1): 20*/20*1.150-1.165 SOLUBILITY IN H20 % BY WT: INSOLUBLE 7. VOLATILES BY VOLUME____ : NIL EVAPORATION RATE (BUTYL ACETATE = 1).: NOT APPLICABLE PH (AS IS)................................... : NOT APPLICABLE PH (iy. SOLUTION).................... : NOT APPLICABLE ODOR THRESHOLD......................... : NOT APPLICABLE DENSITY (GMS/ML).................... : 1.15-1.17 COEFF. WATER/OIL DIST : NOT AVAILABLE ^D 085641 CONFrDETNTrA!.. PCD -------- ------------------------------------------------------------------------ PAGE 02____ MATERIAL SAFETY DATA 68937 41 7 KR0N1TEX (R) 100 'RI1S0PR0PYLATED PHENYL PHOSPHATE EMERGENCY TELEPHONE NUMBERS CHEMTREC (800) 424-9300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT NFPA Designation 704 DEGREE OF HAZARD EXTREME 3 - HIGH 3 * MODERATE 1 * SLIGHT 0 INSIGNFICANT HEALTH IBLUE) 4 *FMC FLAMMABILITY REDI REACTIVITY > (YELLOW) SPECIAL HAZARD REVISION: 08 EFFECTIVE: 03/13/90 PRINTED: 08/20/90 FIREf EXPLOSION AND REACTIVITY DATA * FLASH POINT.............................. AUTOIGNITION TEMPERATURE FLAMMABLE LIMITS UPPER. (AIR) LOWER. EXTINGUISHING MEDIA.......... SPECIAL FIREFIGHTING____ PROCEDURES DEGREE OF FIRE AND .............. : EXPLOSION HAZARD STABILITY........................................: HAZARDOUS POLYMERIZATION.: CONDITIONS TO AVOID.............. : MAJOR CONTAMINANTS THAT..: CONTRIBUTE TO INSTABILITY INCOMPATIBILITY........................ : HAZARDOUS DECOMPOSITION..: PRODUCTS SENSITIVITY TO MECH.............. : IMPACT SENSITIVITY TO STATIC____ : DISCHARGE PMCC 19S*C(38S*F)SETAFLASH 242*C(468*F> 551*C (1024*F) NOT AVAILABLE NOT AVAILABLE WATER FOGf C02, DRY CHEMICAL, MULTIPURPOSE FOAM FOR FIRES INVOLVING THIS MATERIAL, WEAR FULL PROTECTIVE CLOTHING, INCLUDING NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. DO NOT ENTER ANY ENLCOSED OR CONFINED FIRE SPACE WITHOUT NIOSH APPROVED SELF-CONTAINED BREATHING APPARA TUS. SEE SECTION ON HAZARDOUS DECOMPOSTION PRODUCTS FOR DECOMPOSITON PRODUCTS. SLIGHTLY COMBUSTIBLE. NO EXPLOSION HAZARD. STABLE WILL NOT OCCUR. PROTECT AGAINST WELL VENTILATED NONE PHYSICAL AREA, DAMAGE. STORE IN COOL, NONE UNDER FIRE CONDITONS TOXIC ACIDIC VAPORS MAY BE FDRMED FROM PHOSPHORUS OXIDE. NONE NONE ROUTES OF EXPOSURE ===*======= &C83tSS= EYE CONTACT.................................: SKIN CONTACT... SKIN ABSORPTION NON IRRITATING (RABBIT) REF:ICD/T-086/024 NON-IRRITATING (RABBIT) REF:ICD/T-076/024 NO SIGNIFICANT HAZARD DERMAL LD50 ABOVE 10G/KG RABBIT REF:ICD/T-076/024 SOURCE FMC FMC FMC DATE 1976 1976 1976 PCD DAfiC m Oo COA/p 8S64? Mz, MATERIAL SAFETY DATA 68937 41 7 2 NFPA Designation 704 KRDNITEX(R) 100 c TRIIS0PR0PYLATED PHENYL PHOSPHATE EMERGENCY TELEPHONE NUMBERS DEGREE OF HA2ARO 4 EXTREME 3 - HIGH 2 . MODERATE i * slight 0 > INSIGNFICAHT HEALTH (BLUE) i CHEMTREC <800) 424-9300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT HFMC FLAMMABILITY (REO) REACTIVITY (YELLOW) special HAZARD REVISION! 08 EFFECTIVE! 03/13/90 PRINTED! 08/20/90 ROUTES OF EXPOSURE INHALATION....................................: INGESTION...................................... : INH(RAT)LC50 ABOVE 200MG/L NO SIGNIFICANT HAZARD REFiICD/T-076/024 NO SIGNIFICANT HAZARD ORAL LD50 ABOVE 20G/KG (RATS) REF! ICD/T-076/024 FMC 1976 FMC 1976 EXPOSURE LIMITS THE TWA AIR LIMIT FOR TRIPHENYL PHOSPHATE IS 3 MG/CU M.l KR0NITEX-100 CONTAINS ABOUT 15X TRIPHENYL PHOSPHATE BY GC ANALYSIS. EFFECTS OF OVEREXPOSURE ACUTE EXPOSURE BREATHING OR SWALLOWING LARGE QUANTITIES MAY CAUSE NEUROLOGICAL DISTURBANCES WHICH MAY PRO GRESS TO DELAYED NEUROTOXICITY CHARACTERIZED BY ATAXIA. MAY ALSO BE IRRITATING TO SKIN, RESPIR ATORY SYSTEM, MUCOUS MEMBRANES AND EYES. SEE EMERGENCY AND FIRST AID PROCEDURES AND NOTES TO PHYSICIAN. CHRONIC EXPOSURE.................... : MAY CAUSE IRRITATION TO SKIN, MUCOUS MEMBRANES, (EFFECTS CONSIDERED RESPIRATORY SYSTEM AND EYES. REPEATED EXPOSURE INCLUDE: SENSITIVITIES, OVER PROLONGED PERIOD OF TIME MAY CAUSE NEURO CARCINOGENICITY, LOGICAL DISTURBANCES WHICH MAY PROGRESS TO DE TERATOGENICITY, LAYED NEUROTOXICITY CHARACTERIZED BY ATAXIA. MUTAGENICITY, SEE EMERGENCY AND FIRST AID PROCEDURES AND NOTE SYNERGISTIC TO PHYSICIAN. FOLLOW GOOD INDUSTRIAL HYGIENE PRODUCTS, AND PRACTICES AND OBSERVE THE SPECIAL PROTECTION ANY MEDICAL CONDITIONS INFORMATION TO AVOID EXPOSURES. GENERALLY RECOGNIZED AS NOTE! EPIDEMEOLOGY STUDIES COMPLETED IN 1977 AND BEING AGGRAVATED BY 1985 OF CURRENT AND FORMER WORKERS AT THE FMC EXPOSURE.) PLANT WHERE KRONITEX, DURAD, NATURAL AND SYN THETIC TRIARYL PHOSPHATE ESTERS ARE MANUFACTURED HAVE NOT DEMONSTRATED ANY UNUSUAL PATTERN OF C MORTALITY OR DISEASE. 085643 CONFTOENTTAl PAGE 04 MATERIAL SAFETY DATA 68937 417 2 NFPA Designation 704 KRONITEX(R) 100 i TRII5QPR0PYLATED PHENYL PHOSPHATE EMERGENCY TELEPHONE NUMBERS DEGREE OF HAZARD 4 EXTREME 3 HIGH 2 c MODERATE 1 SLIGHT 0 * INSIGNFlCANT HEALTH (BLUE) 4 CHEMTREC <800) 424-9300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT HFMC FLAMMABILITY (RED) REACTIVITY (YELLOW) srecial HAZARO REVISION: 08 EFFECTIVE: 03/13/90 PRINTED: 08/20/90 EMERGENCY AND FIRST AID PROCEDURES EYES............. IF EYE EXPOSURE OCCURS, IMMEDIATELY FLOOD WITH LARGE AMOUNTS OF TAP WATER, PREFERABLY TEPID, FOR AT LEAST 15 MINUTES. SEE A PHYSICIAN. SKIN............. REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN THOROUGHLY WITH SOAP AND WATER. AVOID FURTHER CONTACT. IF COMPLICATIONS DEVELOP, CALL A PHYSICIAN INHALATION REMOVE TO FRESH AIR.IF SUBJECT HAS DIFFICULTY BREATHING, ADMINISTER OXYGEN.IF COMPLICATIONS DEVELOP, TREAT SYMPTOMATICALLY AND CALL A c INGESTION. PHYSICIAN. IF SWALLOWED, IMMEDIATELY DILUTE CONTAMINANT BY DRINKING A PINT OF TEPID TAP WATER. THEN INDUCE VOMITING BY EITHER TICKLING THE BACK OF THE THROAT WITH THF FINGERS OR BY TAKING AN EMETIC,IE. SOAPY TEPID TAP WATER, POWDERED MUSTARD IN WATER, OR SYRUP OF IPECAC. NOTE: DO NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DECONTAMINATION PROCEDURE: REMOVE CONTAMINATED CLOTHING IMMEDIATELY. WASH SKIN THOROUGHLY WITH SOAP AND WATER. NOTES TO PHYSICIAN............... : MAY BE IRRITATING TO SKIN, MUCOUS MEMBRANES, RESPIRATORY SYSTEM AND EYES. CONTAMINATED EYES SHOULD BE IMMEDIATELY FLOODED WITH TAP WATER, PREFERABLY TEPID. SKIN SHOULD BE WASHED THOROUGHLY WITH SOAP AND WATER. EYE CONTACT SHOULD RECEIVE OPHTHALMOLOGIC EVALUATION IF COM PLICATIONS DEVELOP. TREATMENT OF ANY TOXICITY SHOULD BE SYMPTOMATIC AND SUPPORTIVE AFTER TER MINATING EXPOSURE THROUGH ABOVE MEANS, OR IN CASE OF INGESTION, GASTRIC EVACUATION VIA EMESIS INDUCTION OR GASTRIC LAVAGE. ( PCD CoNFTr0n^rn6t4t4Ai PAGE 05 MATERIAL SAFETY DATA 68937 41 7 2 NFPA Designation 704 KRONITEX(R> 100 ( TRIISOPROPYLATED PHENYL PHOSPHATE DEGREE OF HAZAftO EMERGENCY TELEPHONE NUMBERS 4 * EXTREME 3 * HIGH 2 * MODERATE 1 * SLIGHT 0 * INSlGNFtCANT HEALTH (BLUE) i CHEMTREC (SOO) 424*19300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT FMC flammability (RED) REACTIVITY (YELLOW) / SPECIAL HAZARD REVISION! 08 EFFECTIVE! 03/13/90 PRINTED: 08/20/90 EMERGENCY AND FIRST AID PROCEDURES HUMAN SYSTEMIC TOXICITY INFORMATION IS UNAVAIL ABLE. BUT EXPECTED TO BE LOW. IMPORTANTLY STRUCTURE-ACTIVITY RELATIONSHIPS SUGGEST THE ABSENCE OF APPRECIABLE ANTICHOLINESTERASE AC TIVITY SUCH AS POSSESSED BY STRUCTURALLY DIS SIMILAR ORGANIC PHOSPHATES. NEUROLOGICAL EVAL UATION OF WORKERS. WHERE NO SIGNIFICANT DIFFER ENCES WERE DEMONSTRATED BETWEEN TRIARYL PHOS PHATE ESTERS EXPOSED AND CONTROL POPULATIONS. SUPPORTS THIS CONCLUSION.(1) EXPOSURE TO HUMANS HAS BEEN SHOWN TO RESULT IN A SLIGHT INHIBITATION OF MONDCYTE NON-SPECIFIC ESTERASE. THE CLINICAL SIGNIFICANCE OF THIS FINDING HAS NOT BEEN DETERMINED.(2) SYNTHETIC TRIARYL PHOSPHATE ESTERS, AS TYPIFIED BY KRONITEX(R) 100, ARE MADE FROM CAREFULLY CON TROLLED MIXTURES OF ISOPROPYLPHENOLS AND PHENOLS.INTRODUCED IN EUROPE IN THE MID 60'S AND IN THE UNITED STATES IN 1969, KRONITEX(R) SYN THETIC TRIARYL PHDSPHATE ESTERS ARE WIDELY USED IN A VARIETY OF INDUSTRIAL APPLICATIONS. THEY HAVE A H1STDRY OF EVENT FREE MANUFACTURE. AND THERE ARE NO REPORTED INSTANCES OF TOXIC PROB LEMS. STANDARD TEST PROTOCOLS USING RODENTS FOR ACUTE ORAL, INHALATION, AND SKIN TOXICITY REVEAL KRONITEX(R) SYNTHETIC TRIARYL PHOSPHATE ESTERS TO BE OF NO SIGNIFICANT HAZARD (NIOSH RECOMMEND- c PCD rnMc-086645 ConftoehtTai PifiF OA MATERIAL SAFETY OATA 68937 41 7 KRONITEX(R) 100 TRIIS0PR0PYLATED PHENYL PHOSPHATE FMC FLAMMABILITY IREOI EMERGENCY TELEPHONE NUMBERS CHEMTREC <S00) 424-9300 MEDICAL <303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT REVISION: 08 EFFECTIVE: 03/13/90 SPECIAL HAZARD PRINTED: 08/20/90 EMERGENCY AND FIRST AID PROCEDURES ED RATING SYSTEM). THESE PRODUCTS ARE NOT CORROSIVE OR SUFFICIENT LY IRRITATING TO BE CLASSIFIED IRRITANT UNDER FHSLA. PROLONGED OR REPEATED EYE OR SKIN EXPOS URE CAN CAUSE MILD IRRITATION AND SHOULD BE AVOIDED. HUMAN PANEL TESTS HAVE SHOWN SUCH PRODUCTS TO BE NON-IRRITATING AND NON-SENSITIZING. BASED ON AMES TEST, SYNTHETIC TRIARYL PHDSPHATE ESTERS ARE NON-MUTAGENIC. NEUROTOXICITY OF A TYPE DIFFERENT THAN CHOLINES TERASE INHIBITION (SEE CHRONIC EXPOSURE DATA) HAS BEEN IDENTIFIED AND ASSOCIATED WITH CERTAIN TRIARYL PHOSPHATES FDR MANY YEARS. EXTENSIVE STUDIES CONDUCTED IN EUROPE AND IN THIS COUNTRY HAVE PINPOINTED THE EFFECTIVE NEUROTOXIC DOSE (ED50) OF THESE PRODUCTS. THE ED50 IS NOT A LETHAL DOSE, BUT RATHER A DOSE AT WHICH CLINICAL SIGNS OF ATAXIA ARE APPARENT IN 507. OF THE TEST ANIMALS (HENS) . THE MINIMAL NEUROTOXIC POTENTIAL OF KRONITEX(R) SYNTHETIC TRIARLY PHOSPHATE ESTERS IS SEEN IN THE HIGH ACUTE ED50 OF 4,000-8,000 MG/KG. (1)FMC-MJ REAPE THESIS MARCH 19822 (2)FMC-NITRO INTERNAL STUDY 1984 SPECIAL PROTECTION VENTILATION REQUIREMENTS.: RECOMMENDED PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY............... * USE IN VENTILATED AREAS. SEE BELOW IN HIGH TEMPERATURE APPLICATIONS OR EXPOSURE TO MISTING, USE NIOSH CERTIFIED ORGANIC VAPOR CAR TRIDGE. USE NIOSH RESPIRATOR AND SELF-CONTAINED BREATHING APPARATUS IN EMERGENCY SITUATIONS. C PCD MATERIAL SAFETY DATA 68937 41 7 2 KRONITEX(R) 100 TRIISDPROPYLATED PHENYL PHOSPHATE -FMC flammability IKED) EMERGENCY TELEPHONE NUMBERS CHEMTREC (800) 424-9300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT REVISION: 08 EFFECTIVE: 03/13/90 special hazard PRINTED: 08/20/90 SPECIAL PROTECTION ==========*== EYES...................................: GLOVES............................. : SPECIAL CLOTHING..: AND EQUIPMENT FOOTWEAR........................ : CHEMICAL SAFETY GOGGLES. RUBBER NON-PERMEABLE GLOVES. WHEN DIRECT CONTACT ON SKIN IS EXPECTED* RUBBER OR OTHER IMPERVIOUS COVERALLS OR SUITS AND BOOTS SHOULD BE WORN. NO SPECIAL REQUIREMENT STORAGE AND HANDLING =============*=======*== (PLEASE USE THIS STATEMENT KEEP CONTAINERS CLOSED WHEN NOT IN USE AND AWAY TO SATISTY THE IN-PLANT FROM HEAT AND OPEN FLAMES. PROTECT AGAINST PHYS LABELING REQUIREMENTS ICAL DAMAGE. STORE AND HANDLE AWAY FROM ANY PRO OF THE OSHA HAZARD DUCT INVOLVED IN FOOD PROCESSING. USE RESPIRA COMMUNICATIONS STANDARD TORY PROTECTION FOR MIST GENERATION (SEE HEALTH 29CFR 1910.1200) HAZARD WARNING). WEAR PROTECTIVE CLOTHING AND GLOVES WHEN HANDLING. IF SPLASHED ON CLOTHING, IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND WASH WITH SOAP AND WATER. ALWAYS USE CLEAN CLOTHING. DISCARD ANY CONTAMINATED LEATHER SHOES. PROPERLY LABEL STORAGE TANKS, BINS, VES SELS, CONTAINRES, PALLET LOADS OR STORAGE AREAS WITH NFPA DESIGNATION NO. 704 AS SHOWN ON PAGE ONE OF THIS MATERIAL SAFETY DATA SHEET. THIS DESIGNATION WILL ASSIST FIRE FIGHTING AND EMERGENCY PERSONNEL, AND ASSIST IN TRAINING/ COMMUNICATIONS OF MATERIAL HAZARDS. DISPOSAL, SPILL OR LEAK PROCEDURES ============ PROCEDURE FDR RELEASE, OR SPILL KEEP MATERIAL OUT OF STREAMS AND SEWERS. ABSORB SPILLED MATERIAL ON COMMERCIAL OIL ABSORBANT SAND OR DIRT (SOIL). PUT THE CONTAMINATED AB SORBANT INTO A DOT APPROVED CONTAINER AND DIS POSE OF ACCORDING TO THE METHODS OUTLINED BELOW FOR WASTE DISPOSAL. C PCD DO 085647 confidential PAGE 08 MATERIAL SAFETY DATA 62937 41 7 2 NFPA Designation 704 KRQNITEX(R) 100 / TRIIS0PR0PYLATED PHENYL PHOSPHATE DEGREE OF HAZARD EMERGENCY TELEPHONE NUMBERS 4 - EXTREME 3 - HIGH 2 MODERATE t SLIGHT 0 s INSIGNFiCANT HEALTH (BLUE) < CHEMTREC <800) 424-9300 MEDICAL (303) 595-904S CALL COLLECT OTHER (304) 755-6300 CALL COLLECT FMC FLAMMABILITY (RED) REACTIVITY (YELLOW) SPECIAL HAZARD REVISION: 08 EFFECTIVE: 03/13/90 PRINTED* 08/20/90 ***=*=**==****=" DISPOSAL* SPILL OR LEAK PROCEDURES WASTE DISPOSAL METHOD____ : AN ACCEPTABLE METHOD OF DISPOSAL IS TO BURN IN AN INCINERATOR IN ACCORDANCE WITH ALL LOCAL. STATE AND FEDERAL ENVIRONMENTAL LAWS. RULES. REGULATIONS. STANDARDS AND OTHER REQUIREMENTS. BECAUSE ACCEPTABLE METHODS OF DISPOSAL MAY VARY BY LOCATION, AND BECAUSE REGULATORY REQUIREMENTS MAY CHANGE. THE APPROPRIATE REGULATORY AGENCIES SHOULD BE CONTACTED PRIOR TO DISPOSAL. TRANSPORTATION DATA c DOT PROPER SHIPPING NAME.: KRONITEX(R) 100 TRIARLY PHOSPHATE DOT CLASSIFICATION.................: NOT REGULATED DOT LABELS..................................... : NONE DOT MARKING.................................. : NONE DOT PLACARD.................................. : NONE UN NUMBER.....................................: NONE HAZARDOUS SUBSTANCE/RQ...: NOT LISTEDD 49 STCC NUMBER........................... : NONE EMERGENCY ACCIDENT PRECAUTIONS AND PROCEDURE* KEEP UNNECESSARY PEOPLE AWAY. HANDLE AS A HIGH BOILING ORGANIC LIQUID. PRECAUTIONS TO BE TAKEN..: PROTECT AGAINST PHYSICAL DAMAGE. IN TRANSPORTATION TYPE PACKAGES............................. : DRUMS, TANK CARS, TANK TRUCKS. OTHER SHIPPING IDS................. * NONE ADDITIONAL REGULATORY INFORMATION ============= MATERIAL IS REPORTED IN EPA TSCA INVENTORY LIST? YES MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING NTP ANNUAL REPORT... ? NO I ARC GROUP I OR II. . .? NO ( OSHA 29CFR PART 1910 SUBPART Z ? NO ACGIH APPENDIX A.......... ? NO PCD PACE 09 DO 085648 conf T0^TTAi ________ :______ i______________________________________ MATERIAL SAFETY DATA 68937 41 7 2 KRONITEX(R) 100 TRIISOPROPYLATED PHENYL PHOSPHATE FMC FLAMMABILITY (RED) EMERGENCY TELEPHONE NUMBERS CHEMTREC (800) 424^-9300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-6300 CALL COLLECT REVISION: 08 EFFECTIVE: 03/13/90 SPECIAL HAZARD PRINTED: 08/20/90 ADDITIONAL REGULATORY INFORMATION DOES PRODUCT CONTAIN A TOXIC CHEMICAL(S) SUBJECT TO SARA TITLE III SECTION 313 REPORTING............................ CHEMICAL (S).......................I SARA TITLE III SECTION 311/312 CLASSIFICATION...: CONTAINS UP TO 1 PPM ARSENIC FROM CALIFORNIA'S "PROPOSITION 65" LISTS OF CARCINOGENS. NO MSDS REQUIRED; INVENTORY REPORTING REQUIRED. ( ADDITIONAL INFORMATION ============"*======*==** AQUATIC TOXICITY CLASSIFICATION SOURCE - NIOSH RTECS NO. 79-100 96 HR LC50-RAINB0W TROUT 2.4 (1.7- FMC 3.4)MG/L ICG/T-79-049 96 HR LC50-FATHEAD MINNOW 14.9 FMC (12.8-17.4)MG/L ICG/T-79-049 48 HR LC50-DAPHNIA MAGNA 0.83 (0.68 - FMC 1.00) MG/L ICG/T-79-049 DATE 1979 1979 1979 PCD Distributors TVtr C.R HAIZi IU * NT4N DO 085649 CONFIDENTIAL prc in MATERIAL SAFETY DATA KRONITE, .(R) TCP TRIARYL PHOSPHATE 68952 35 2 -FMC meetflammability EMERGENCY TELEPHONE NUMBERS MEDICAL (303) 595*9048 CALL CHEMTREC (800) 424-9300 OTHER (304) 755-3351 CALL REVISION: EFFECTIVE: 09/01/85 PRINTEO: 11/09/35 PREPAREO FOR USE BY. C P HALL CO OF ILL 2500 CHANNEL AVE PRESIDENTS ISLANO IDENTIFICATION ================================ INFORMATION PROVIOEO BY., FMC CORPORATION 2000 MARKET STREET PHILADELPHIA* PA 19103 PRODUCT INFORMATION =========================== SYNONYMS, SHIPPING NAME - DOT. , I AT A. IMCQ. FORMULA., CHEMICAL FAMILY. TRICRESYL PHOSPHATE* TRITOLYL PHOSPHATE KRONITEX(R) TCP TRIARYL PHOSPHATE KRONITEX(R) TCP TRIARYL PHOSPHATE KRONITEX(R) TCP TRIARTL PHOSPHATE C21H2104P ORGANOPHOSPHATE PRECAUTIONARY INFORMATION =================== PRECAUTIONARY STATEMENT..: (PLEASE USE THIS STATEMENT TO SATISFY THE IN-PLANT LABELING REQUIREMENTS OF THE OSHA HAZARD COMMUNICATIONS STANDARD 29CFR 1910.1200) HEALTH: MIST GENERA TEO BT HEAT* VIOLENT AGITATION OR SPRAYING WI LL IRRITATE EYES* NOSE* & THROAT.CONTINUOUS C ONTACT WITH LIQUID WILL IR" RITATE SKIN. LONG & CONTINUOUS CONTACT WITH THE LIQUID OR VAPOR MAY EFFECT THE NERVOUS SYSTEM. PRODUCT PRESENTS A NEGLIBLE HAZARD TO HEALTH DURING NORMAL HANDL ING EXCEPT AT ELEVATED TEMPERATURES & PROLONGE D 8 CONTINUCUS/PROLONGED CON TACT WITH SKIN. PHYSICAL: NO SIGNIF ICANT HAZARD EXCEPT IN FIRP CONDITIONS WHERE PH OSPHORUS OXIDE GASES ARE EMITTED. INGREDIENTS ================================== CAS# AND COMPONENT, MATERIAL/COMPQNENT: TAR ACIOS* CRESYLIC* PHENYL* PHOSPHATE PERCENT............................. : 100X CAS #................................. .. T58^-5f~55-2- 1330-78-5 HAZARD CLASS............... : NONE Distributors The C. P. HALL Company T 2500 CHANNEL AVENUE MEMPHIS, TENNESSEE 38113 901 -- 948-8663 PR-54 DO 085650 CONFIDENTIAL PAGE 01 MATERIAL SAFETY DATA 68952 35 2 KRONITEX(R) TCP NFPA Designation 704 ( TRIARYL PHOSPHATE EMERG_ ENCY TELEPHONE NUMBERS DEGREE Of HAZARD 4 a EXTREME 3 = HIGH 2 = MODERATE 1 * SLIGHT 0 * INSIGNFICANT HEALTH (BLUE) < HEOICAL (303) 595-9048 CALL COLLECT CHEMTREC (800) 424-9300 OTHER (304) 755-3351 CALL COLLECT HFMC flammability (RED) r ) REACTIVITY > (YELLOW) SPECIAL HAZARD REVISION: 0 EFFECTIVE: 09/01/85 PRINTED: 11/09/85 ==X;==3Z zxcatc^sxxtst PHYSICAL OATA ==**==**====*==*===**** HFl TING POINT___ -_______ .N A BOILING POINT...............................: 24l*-255*C (466*-491*F) VAPOR PRESSURE............ ............... : .033MM HG a 15Q*C VAPOR DENSITY (AIR - 1)..: NO OATA ROOM TEMPERATURE APPEARANCE AND STATE: CLEAR LIQUID 000 R....................................................... .. ODORLESS SPECIFIC GRAVITY (H20 =1): 2Q*C 1.160-1.75 SOLUBILITY IN H20 X BY WT: INSOLUBLE X VOLATILES BY VOLUME....: NIL AT ROOM TEMPERATURE EVAPORATION RATE (BUTYL ACETATE = 1).: NO OATA PH (AS IS)....................................... .. NA PH (IX SOLUTION).......................: NA / FIRE, EXPLOSION AND REACTIVITY OATA =========== FLASH POINT.................................... .. AUTOIGNITION TEMPERATURE.: FLAMABLE LIMITS UPPER...: (AIR) LOWER___ : EXTINGUISHING MEDIA...............: SPECIAL FIREFIGHTING............... PROCEDURES DEGREE OF FIRE ANO.............. .. EXPLOSION HAZARD STABILITY....................................... .. : HAZAROOUS POLYMERIZATION.: CONDITIONS TO AVOID...............: PMCC 1 99-4C (390*F), CC 210*C (410*F) 410*C (770*F) NO OATA NO DATA WATER FOG , C02, DRY CHEMICAL, MULTIPURPOSE FOAM FOR FIRES INVOLVING THIS MATRIAL,WEAR FULL PRO" TECTIVE CLOTHING, INCLUOING NIOSH APPROVED SELFCONTAINED BREATHING APPARATUS.00 NOT ENTER ANY ENCLOSED OR CONFINEO FIRE SPACE WITHOUT NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. SEJ SECTION ON HAZAROOUS DECOMPOSITION PRODUCTS FOR DECOMPOSITION PRODUCTS. SLIGHTLY COMBUSTIBLE - NO EXPLOSION HAZARD. STABLE WILL NOT OCCUR PROTECT 4GAINST WELL VENTILATED PHYSICAL AREA. DAMAGE. STORE IN COOL, DO 085651. CONFIDENTIAL PAGE 02 MATERIAL SAFETY OATA 6^52 55 1 L. KRDNITEX ( R ) TCP TRI4RYL PHOSPHATE EMERGENCY TELEPHONE NUMBERS MEDICAL (505) 595-9043 CALL CHEMTREC (SOO) 424-93GO OTHER (304) 755-3351 CALL NFPA Designation 704 DEGREE OF HAZARD 4 EXTREME 3 HIGH 2 MODERATE I SLIGHT 0 INSIGNFICANT COLLECT COLLECT REVISION; EFFECTIVE; Q9/01/35 HFEV1C (RED*FLAMMA0ILTV SPECIAL HAZARD PRINTED: 11/09/55 *=*===============-"=== FIRE* EXPLOSION AND REACTIVITY OATA MAJOR CONTAMINANTS THAT..: CONTRIBUTE TO INSTABILITY INCOMPATIBILITY......................... .. HAZARDOUS DECOMPOSITION..: PRODUCTS NONE KNOWN NONE UNDER FIRE CONDITIONS TOXIC ACIDIC FORMED FROM PHOSPHORUS OXIDES. VAP0R5 MAY 55 ROUTES OF EXPOSURE ============================ EYE CONTACT_____ SKIN CONTACT... SKIN ABSORPTION INHALATION...-.-. INGESTION............... SLIGHTLY IRRITATING (R435 IT) REF ICQ/T-76.030 SLIGHTLY IRRITATING (RA35IT) REF ICD/T-76.C30 NO SIGNIFICANT HAZARD L 0 5 0 ABOVE 10G/KG (RABBIT) REF ICD/T-76.030 SLIGHT IRRITANT (RAT) LC50 ABOVE ?G3 "G/L R" ICT/T-75.C30 NO SIGNIFICANT HAZARD ORAL LOSS ABOVE ?j G/KG (RAT) REF ICD/T-76.030 SOURCE DATE = MC 137 6 FMC 1976 -- MC FMC FMC 1975 1=76 I! 1976| ACUTE E<RGSURC === ..; EFFECTS OF OVEREXPOSURE =======================j i BREATHING OR SWALLOWING LARGE jU4NTI~IcS MAY j CAUSE NEUROLOGICAL DISTURBANCES WHIC^ *AY PPG- I GROSS T" DELAYED NEUROTOXICITY CHA=ACTrR I ZG BY ATAXIA. MAY ALSO BE IRRITATING TO SKIN, RES-j J IRATORY SYSIFM, MUCOUS MEMBRANES ANP EYES. | SI- <:3ERStNCY AND CI = $T AIO PROCEDURES AND NOTES T 0 PHYSICIAN. I DO 085652 CONFIDENTIAL. ^ F. O " MATERIAL SAFETY DATA 6 5952 55 2 KRONIT EX (R) TCP TRIARYL PHOSPHATE NFPA Designation 704 DEGREE OF HAZARD EMERGENCY TELEPHONE NUM3ERS 4 32 1 0 MEDICAL (3C3) 595-904S CALL COLLECT CHEMTREC (300 424-9300 OTHER (304) 755-3351 CALL COLLECT EXTREME HMIOGDHERATE SLIGHT insignficant REVISION: 0 EFFECTIVE: 09/01/35 "FMC FLAMMABILITY (RCOI special HAZARD PRINTED: 11/09/55 CHRONIC EXPOSURE EFFECTS OF OVEREXPOSURE MAY CAUSE IRRITATION TO SKIN, MUCOUS MEMBRANES, RESPIRATORY SYSTEM AND EYES. REPEATED EXPOSURE OVER PROLONGED PERIOD OF TIME MAY CAUSE NEURO LOGICAL DISTURBANCES WHICH MAY PROGRESS TO OE" LAY50 NEUROTOXICITY CHARACTERIZED Y ATAXIA. Set EMERGENCY AND FIRST AID PROCEDURES AND NOTES TQ PHYSICIAN. FOLLOW GOOD INDUSTRIAL HYGIENE PRAC TICES AND OBSERVE THE SPECIAL PROTECTION INFOR MATION SECTION TO AVOID EXPOSURES. A COMMERCIALLY AVAILABLE TRICRE5YL PHOSPHATE CONTAINING LESS THAN IX OF THE I R I QRTHGCRESYL ) PHOSPHATE ISOMER WAS ADMINISTERED TO MICE AND RATS BY STOMACH TUBE 5 DAYS PER WEEK FOR 13 WEEKS AT DOSE LEVELS OF 300, 400, 20C, 100, 5C, 0 MG (VEHICLE CONTROL) PER KG BODY WEIGHT. EXPOSED MICE EXHIBITED EVIDENCE OF NEUROTOX ICITY; DECREASED body, lung, thymus and testicl; WEIGHTS ; INCREASED LIVER WEIGHTS; INHIBITION OF SEP`JU cholinesterase; and decreased sperm COUNT AND MOTILITY. EXPOSED PATS EXHIBITED EVIDENCE Or neurotoxicity; decreased gody, LUNG, THYMUS INO i TESTICLE WEIGHTS; INCREASED LIVER WEIGHTS; IN- I HI3ITI0N OF SERUM CHOLINESTERASE, MICROSCOPIC ! LESIONS IN THE SPINAL CORO, ADRENAL CCSTEX, TESTES, AN0 OVARIES,' AND SIGNIFICANT EFFECTS ON SPERM MDRPHQLOGY (UNPUBLISHED RESULTS CF THE NATIONAL TOXICOLOGY PROGRAM). NOTE: FPIOEMEOLOGY STUDIES COMPLETED IN 1977 AND 1955 Oc CURRCNT AND FORMER WORKERS AT THE FMC | LANT KRC.NITEX, OUSAD, NATURAL AND SYN- i THETIC TRIARYL HOS PH ATE ESTERS ARE MANUFACTURE 3 HAVE NOT DEMONSTRATED ANY JNUSUAL PATTERN CF : mCRT^UTTY PR DISEASE. I ------ DO 095653 CONFIDENTIAL MATERIAL SAFETY DATA 6395 t 35 2 K RONIT EX(R ) TCP TRIARYL PHOSPHATE NFPA Designation 704 degree of hazard EMERGENCY TELEPHONE NUMBERS A EXTREME 3 HIGH i MODERATE 1 SLIGHT 0 INSIGNFICANT MEOICAL (303) 595-9043 CALL COLLECT CHEMTREC ( 3C`0> 424-9300 OTHER (304) 755-3351 CALL COLLECT H(OELAULETIH 4FIVIC flammabilitv IHEDl REACTIVITY (YELLOW) SHPAEZCAIRADL REVISION: EFFECTIVE: 09/D1/5 PRINTED; 11/09/35 :===*:=== =======:======= EMERGENCY AND FIRST AID PROCEDURES ============ : INHALATION, INGESTION. G = C0NTAMINAT I ON OROCEDURi NOTES TO PHYSiCIAN................ IF EYE EXPOSURE OCCURS* IMMEDIATELY FLOOD WITH LAPSE AMOUNTS OF TAP WATER* PREFERABLY TEPID, FOR AT LEAST 15 MINUTES. IF COMPLICATIONS DEVELOP* SEE AN OPTHALMOLCGI ST. REMOVE CONTAMINATED CLOTHING IMMEDIATELY AND WASH SKIN THOROUGHLY WITH SOAP AND WATER. AVDIO FURTHER CONTACT. IF COMPLICATIONS DEVELOP* CALL A PHYSICIAN. REMOVE TO FRESH AIR. IF SUBJECT HAS DIFFICULTY BREATHING* ADMINISTER OXYGEN. IF COMPLICATIONS DEVELOP* TREAT SYMPTOMATICALLY AND CALL A PHY$ IC I 4N. IF SWALLOWED* IMMEDIATELY DILUTE CDNTAMINANT BY D01 NX ING A PINT OF TEPID TAP WATER.THEN INDUCE VOMITING 6 Y EITHER TICKLING THE E AC X OF THE THREAT wITH THE FINGERS CR BY TAKING AN EMETIC* IE* SOAPY TEPID TAP w AT R *P OWOE A E 0 ``USTARO IN WATi;R* E k SYRUP C r IPECAC. NOTE: DC NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH T G AN UNCONSCIDUG 3 E k S 0 N. REMOVE CONTAMINATED CLOTHING IMMEDIATELY. WAGh SKIN THOROUGHLY WITH SCAP ANG WATER. MAT 5f IRRITATING TC SKIN* MUCOUS MEMBRANES* RESPIRATORY SYSTEM ANO EYES. CONTAMINATED EYES SHOULD SE IMMEDIATELY FLOODED FQP 15 MINUTES WITH TAP WATER PREFERABLY TEPID. SKIN SHOULD EE WASHED THOROUGHLY WITH SOAP AND WATER. EYE CON TACT SHOULD RECEIVE OPHTHALMOLOGIC EVALUATION If COMPLICATIONS OEVELCP. TREATMENT OF ANY TC<ICITV SHOULD 3= SYMPTOMATIC AND SUPPORTIVE A <= T r = TE-" *41 N A 7 I f.'G EXPOSURE THROUGH ABOVE MEANS* OR IN CASE Zr INGESMDN* GASTRIC EVACUATION VIA EMESIS INDUCTION OR GASTRIC LAVAGE. DO 085654 C0N^r^4 M/.. MATERIAL SAFETY DATA 63952 35 2 K*?NITFX<<o TC*> TRIARYL PHOSPHATE NFPA Designation 704 DEGREE OF HAZARD 4 EXTREME 3 HIGH 2 MODERATE HEALTH (BLUE) < EMERGENCY TELEPHONE NUMBERS 0 MEOICAL (303) 595-9048 CALL COLLECT CHcMTREC (300) 424-9300 OTHER (334) 755-3351 CALL COLLECT INSKjNFICANF HFMC flammability (BED) I 0 REACTIVITY . (YELLOW! SPECIAL HAZARD REVISION: 0 EFFECTIVE: 09/01/85 PRINTED: 11/09/35 EMERGENCY AND FIRST AID PROCEDURES ===-======== HUMAN SYSTEMIC TOXICITY INFORMATION IS UNAVAIL ABLE, BUT EXPECTED TO BE LOW. IMPORTANTLY, STRUCTURE-ACTIVITY RELATIONSHIPS SUGGEST THE ABSENCE OF APPRECIABLE ANTICHOLINE5TERASE ACTIV ITY SUCH AS POSSESSED BY STRUCTURALLY DISSIMILAf ORGANOPriOSPHATES. NEUROLOGICAL EVALUATION OF WORKERS, WHERE NO DIFFERENCES WERE DEMONSTRATED BETWEEN TRIARYL PHOSPHATE ESTERS EXPOSED AND CONTROL POPULATIONS,SUPPORTS THIS CONCLUSIDN.(1) THE KRONITEX(R) NATURAL T R I A R Y L PHOSPHATE ESTERS ARE COMPLEX MIXUURES OF ALKYLPHENYL HGSpHATES ) DERIVED FPOM NATURAL CRESYLIC ACIDS. THE CRES- ' YLIC AGIOS ARE SELECTED TO YIELD VERY LOW CON CENTRATIONS OF THE ORTHO ESTER (LESS THAN 1 % ORTHO CRcSOD. USING NICSH RECOMMENDED RATING SYSTEM, THESE PRODUCTS WERE EVALUATED TO HAVE NO SIGNIFICANT HAZARD WITH ACUTE ORAL AN 3 DERMAL TOXICITY. KRCNITEXCR) TCP WAS EVALUATED cjR ACUTE INHALA TION AND, AGAIN, IT WAS FOUND T3 BE OF NO , SIGNIFICANT HAZARD. < THESE PRODUCTS ARE NOT CLASSIFIED AS IRRITANTS j UNDER FHSLA. PROLONGED OR REPEATED EXPOSURE CAN | CAUSE MILD SKIN OR EYE IRRITATION AND SHOULD BE AVOIDED. NEUROTOXICITY OF A TYPE DIFFERENT THAN CHOLINEESTERASE INHIBITION (SEE CHRONIC EXPOSURE DATA) HAS SEEN IDENTIFIED AND ASSOCIATED WITH CERTAIN TRIARLY PH0SoHATES FOR MANY YEARS. 00 085F.5S CONFIDENT! Al- P MATERIAL SAFETY DATA KRONITEX(R) TCP T RIA R YL PHOSPHATE 65952 35 Z HFMC fLAMMA0IUT V 1*ED) EMERGENCY TELEPHONE NUMBERS MEOICAL (303) 595-9043 CHEMTREC (803) 424-9300 OTHER (300 755- 3 351 REVISION: G EFFECTIVE: 09/01/S5 PRINTED: 11/09/55 EMERGENCY AND FIRST AID PROCEDURES EXTENSIVE STUDIES CCNDUCTEO IN EU0 E ANO IN THIS COUNTRY HAVE ESTABLISHED THAT ACUTE COSES 0*= 50-0 MG/ KG WILL PRODUCE CLINICAL SIGNS OF ATAXIA IN TEST ANIMALS (HENS). ALTHOUGH MORE NtURGTOXlC THAN KRONIT EX(R) SYN THETIC TRIARTL PHOSPHATE ESTERS/' THE KRQNITEX(R] NATURAL TRXA.RYL PHOSPHATE ESTERS CAN BE SAFELY USED WITHOUT UNDUE RISK 3Y OBSERVING PROPER IN DUSTRIAL HYGIENE AS CESCRI3E0 HEREIN.ORAL INGES TION, SKIN CONTACT, ANO INHALATION C= MISTS OR HIGH t^hpfrat'JRE VAPORS SHOULD 3E AVOICEO. KRDNITEX(R) TCP ANO TXP GIVE NEGATIVE AMES TEST FOP MUTAGENICITY. (1) FMC-MJ RE APE THESIS MARCH 1932. SPECIAL PROTECTION ============================ VENTILATION REQUIREMENTS.: RECOMMENDED PERSONAL...........: PROTECTIVE EQUIPMENT RESPIRATORY..................: EYES.....................................: GLOVES............................... : SPECIAL CLOTHING..: AND EQUIPMENT USE IN VENTILATED AREAS. IN high TEMPERATURE APPLICATIONS OR EXPOSURE TO MISTING, USE NIOSH CERTIFIEO ORGANIC VAPOR CARTRIDGE. USE NIOSH RESPIRATOR ANO S EL p" CONTAINED 3RFATHING APPARATUS IN EMERGENCY SITUATIONS. CHEMICAL SAFETY GOGGLES ARE RECOMMENDED. RUBBER N0N-PERMEA3LE GLOVES ARE RECOMMENDED. ,,iEN DIRECT CONTACT ON SKIN IS EXPECTED, RUE3EP OR OTHER IMPERVIOUS COVERALLS OR SUITS ANO SCOT: SHOULD E WORM. DO 085656 CONFTDFNTTAL J MATERIAL SAFETY DATA KRGNlT EX(Q ) TCP TRIARYL PHOSPHATE 6a95 2 35 2 fme FLAMMABILITY iff EOl EMERGENCY TELEPHONE NUMBERS MEDICAL (303) 595-9048 CHEMTREC (300) 424-930C OTHER (504) 755-3351 REVISION: 0 EFFECTIVE: 09/01/85 PRINTEO: 11/09/35 STORAGE AND HANDLING =========*=========*====== (PLEASE USE THIS STATEMENT TO SATISTY THE IN-PLANT LA3ELING REQUIREMENTS OF THE CSHA HAZARD COMMUNICATIONS STANDARD 29CFR 1910.1200) KEEP CONTAINERS CLOSED WHEN NOT IN USE AND AWAY FROM HEAT AND OPEN FLAMES. PROTECT AGAINST PHYSICAL DAMAGE. STORE AND HANDLE AWAY FROM ANY PRODUCT INVOLVEO IN F300 PROCESSING. USE RESPIR ATORY PROTECTION FOR MIST GENERATION (SEE HEALTH HAZARD WARNING). WEAR PROTECTIVE CLOTHING AND GLOVES WHEN HANDLING. IF SPLASHED ON CLOTHING IMMEDIATELY REMOVE CONTAMINATED CLOTHING AND WASH WITH SOAP AND WATER. ALWAYS USE CLEAN CLOTHING. DISCARD ANY CCNTAMINATEO LEATHER SHOES. PROPERLY LABEL STORAGE TANKS* BINS* VESSELS* CONTAINERS* PALLET LOADS uR STORAGE AREAS WITH NFPA OBSIGNATION N0.7C4 AS SHOWN DM PAGE ONE OF THIS MATERIAL SAFETY DATA SHEET.THI< DESIGNATION WILL ASSIST FIRE FIGHTING AND AND EMERGENCY PERSONNEL* AND ASSIST IN TRAINING) COMMUNICATIONS OF MATERIAL HAZARDS. DISPOSAL* SPILL OR LEAK PROCEDURES === ======"- PROCEDURE =QR RELEASE_____: OR S ILL WASTE DISPOSAL METHOD KEEP MATERIAL OUT OF STREAMS AND SEWERS. ABSORB SPILLED MATERIAL ON COMMERCIAL OIL A5S0REANT SAND OR DIRT (SOIL). PUT THE CONTAMINATED ADSORB ANT INTO 4 OOT APPPOVEO CONTAINER AND DISPOSE OF ACCORDING TO THE METHODS OUTLINED 3ELGW FOR WASTE DISPOSAL. AN ACCEPTABLE METHOD OF DISPOSAL IS TC a U R N IN AN INCINERATOR IN ACCORDANCE WITH ALL LOCAL* STATE AND FEOERAL ENVIRONMENTAL LAWS* PULES* REGULATIONS* STANDARDS AND CTHER REQUIREMENTS. BECAUSE ACCEPTABLE MfT HDDS OF DISPOSAL MAY VARY SY LOCATION* AND BECAUSE DEGULA TORY REQUIREMENT: way change* the appropriate regulatory agencies S-'SULO BE CONTACTED PRIOR TO DISPOSAL. DO 085657 OONFTDFNTTAI AGr I : i material safety data KRONIT EX <*f) TCP TRIARYL PHOSPHATE 6 95? HFIVSC FI AMifMttOABl lLltV EMERGENCY TELEPHONE NUMBERS MEDICAL (303) 595-904? CALL COLLECT CHEMTREC (300) 424-9300 OTHER (304) 755-5351 CALL COLLECT REVISION: 0 EFFECTIVE: 09/01/85 SOCIAL HAZARD PRINTED: 11/09/35 aessxsasssssxisssssssssssss: TRANSPORTATION OATA *=======*=="=**====*====* = DOT PROPER SHIPPING NAME-: KPQNITEX(R) TCP TRIAP.YL PHOSPHATE DOT CLASSIFICATION................. : NOT REGULATED DOT LA36LS....................................... .. NONE DOT MARKING-.................................... NONE DC I PLACARD................................: NONE UN NUM3 EP....................................... i NGNF HAZARDOUS SUDSTANCE/RC___ : NOT LISTED 49 STCC NUM5ER.............. .. EMERGENCY ACCIDENT NONE PRECAUTIONS AND PROCEDURE: KEEP UNNECESSARY PEOPLE AWAY. HANDLE AS A HIGH BOILING ORGANIC LIOUIO. PRECAUTIONS TC 3E TAKEN..: protect against physical DAMAGE. IN TRANSPORTATION CMA CHEMCARO NUMBER.............. : NONE typ= PACKAGES................................. DPUMS/ TANK T 0 U C K r TANK CARS. OTH'R SHIPPING IDS.................: RUiil 1 luliML H t w u u A 1 U K 1 1 PI 1 U K H A 1 X UN TM -- TM -- ** MATERIAL IS REPORTED in .'PA TSCA INVENTORY LIST? MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING NT ANNUAL REPORT... ? I A S C MONOGRAPHS............ * OSHA 29CFR PART 191C SUB PART l ? *=s NO NO NC I I DO 085658 CONFIDENTIAL Pt.;= ;; ----------- ~ 1~ MATERIAL SAFETY DATA 63952 35 2 KRONrTEX(R) TCP TRIARYL PHOSPHATE NFPA Designation 704 DEGREE Of HAZARD EMERGENCY TELEPHONE NUMBERS 4 EXTREME 3 HIGH 2 MODERATE 1 SLIGHT 0 - INSlGNflCANT MEDICAL (503) 595-9043 CALL COLLECT CHEMTREC (300) 424-9300 OTHER (304) 755-3351 CALL COLLECT HFSInc FlAMMABIUTY (RED) REVISION: EFFECTIVE: 09/01/85 PRINTED: 11/09/55 - ADDITIONAL INFORMATION == AOUATIC TOXICITY CLASSIFICATION SOURCE - NIOSH RTECS NO. 79-100 96 HR LC50"R6 IN3 OW TROUT 0.75 (0 54- FMC 1.04)MG/L ICG/T-79-069 96 HR LC50-FATHEAO MINNOW 100MG/L FMC ICG/T-79-069 43 HR LC50-DAPHNIA MAGNA 0.27 (0.21- FMC 0.3 3 ) M G / L ICG/T-79-069 96 HR LC50-3LU EGILL SUNFISH 7000MG/L EPA EF A CONTRACT NO. 69-01-4313 96 HR LC5Q-TIDEWATSR SILVERFISH ;ra ERA CONTRACT NO. 69-01-4313 DATE 1 975 19 7 5 1975 1 975 1 Do 08s659 CONFro/ENTTAI. RAG; 1 E U.S. DEPARTMENT OF LABOR Occupational Safety and Health Administration MATERIAL SAFETY DATA SHEET Form Approved OMfi NO. 44-RJ307 Required under USDL Safety and Health Regulations for Ship Repairing, Shipbuilding, and Shipbreaking <29 CFR 1915, 1916, 1917) SECTION 1 MANUFACTURER'S NAME ' FMC CORPORATION EMERGENCY TELEPHONE NO. 30*1-755-3351 ADDRESS (Number, Street, City, State, end ZIP Code) Nitro. West Vireinia 251**3 CHEMICAL NAME AND SYNONYMS TRADE NAME AND SYNONYMS Triarvl Phosphate' Kronitex 50 Triaryl phosphate CHEMICAL FAMILY Triaryl ohosohate formula (r0)3P0 SECTION II . HAZARDOUS INGREDIENTS PAINTS. PRESERVATIVES, & SOLVENTS % TLV (Unitil ALLOYS AND METALLIC COATINGS PIGMENTS .BASE METAL CATALYST ALLOYS VEHICLE SOLVENTS ADDITIVES METALLIC COATINGS FILLER METAL PLUS COATING OR CORE FLUX OTHERS OTHERS - ' HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS. OR GASES TLV % (Unit*) TLV % (Unit,) SECTION III - PHYSICAL DATA BOILING POINT (F.) g 3mmHg **75F. SPECIFIC GRAVITY (HjO*l) VAPOR PRESSURE (mm H9.) g 1|75F. VAPOR DENSITY (AIR-1) 3mm >10 PERCENT, VOLATILE BY VOLUME (%) E(BVAuPtOyRl AATcIOeNtaRAtTfjE SOLUBILITY IN WATER <0.01* appearance and odor Liquid light straw colored 1.1-1.2 Nil <1 SECTION IV - FIRE AND EXPLOSION HAZARD DATA FLASH POINT (Method u*d) UT5F. OC FLAMMABLE LIMITS Non-Flammable EXTINGUISHING MEDIA. Water, Waterfog, COp, dry chemical, foam SPECIAL FIRE FIGHTING PROCEDURES ________ Full protective clothing Self contained breathing apparatus UNUSUAL FIRE AND EXPLOSION HAZARDS Phosphorous compound fumes Fire and explosion hazard slight Lei Uel PAGE (1) (Continued on reverse side) CO 085660 Form OSHA-20 Re. Mj, 72 SECTION V - HEALTH HAZARD DATA THRESHOLD LIMIT VALUE LD50 = >20.000 mg/kg (rat); EFFECTS OF OVEREXPOSURE LC50 = >200,000 ng/m3 (rat) 1 EMERGENCY AND FIRST AID PROCEDURES Eyes - Flush with vater for 15 minutes. Skin - Flush with soap and water Inhalation - remove to fresh air, resuscitate If required. SECTION VI - REACTIVITY DATA STABILITY UNSTABLE CONDITIONS.T.O.AVOIO r ' STABLE incompatability (Materialsjo avoid) ' x. . HAZARDOUS DECOMPOSITION PRODUCTS HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID X 4; ... - * -- ** SECTION VII - SPILL OR LEAK PROCEDURES STEPS TO BE TAKEN IN CASE MATERIAL' IS RELEASED OR SPILLED Clean-up same as oil spill Absorb on inert material WASTE DISPOSAL METHOD _________ Biological abatement preferred. acceptable. Standard methods such as incineration SECTION VIII SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION (Specify type) ventilation LOCAL EXHAUST mechanical (General) SPECIAL other PROTECTIVE GLOVES Rubber. OTHER PROTECTIVE EQUIPMENT , EYE PROTECTION . .. Safety glasses SECTION IX - SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING Overheating - 200F. discoloration OTHER PRECAUTIONS ' ' ------------ -------------------------------------------------- ---------------------------------------------- 08S&61 " ^qnFIDENTI At - PAGE (21 tPO >33.3*0 ------------. ~ Distributors '1 -- -- -- The C. P. HALL Company 2500 CHANNEL AVENUE MEMPHIS, TENNESSEE 38113 901 - 9*8-8663 PR-S4 F rm OSHA-20 R*v. May 72 MATERIAL SAFETY DATA 78 1*P-140(R) V. TRIBUTOXYETHYL PHOSPHATE 51 3 HPrllwaInC flammability (RED) EMERGENCY TELEPHONE NUMBERS CHEMTREC (800) 424-9300 MEDICAL (303) 595-9048 CALL OTHER (304) 755-3551 CALL COLLECT COLLECT SPECIAL HAZARD REVISION: EFFECTIVE: 09/01/85 PRINTED: 11/09/85 PREPARED FOR USE BY. C P HALL CO OF ILL 2500 CHANNEL AVE PRESIDENTS ISLAND IDENTIFICATION =-**=-*==*========*=========--=== INFORMATION PROVIDED BY..: FMC CORPORATION 2000 MARKET STREET PHILADELPHIA, PA 19103 PRODUCT INFORMATION k=issmi*ssk=msi=s=s SYNONYMS............................... SHIPPING NAME - DOT. IATA IMCO FORMULA................. ............... CHEMICAL FAMILY............ TRIBUTOXYETHYL PHOSPHATE, BUTOXYLETHANOL PHOS PHATE, TRIBUTYL CELLOSOLVE PHOSPHATE, PHOSPHORIC ACID, TRIS (2-BUTOXYLETHYL) ESTER TRI-5UT0XYETHYL PHOSPHATE, PLASTICIZER TRI-BUTOXYETHYL PHOSPHATE, PLASTICIZER (CAH90C2H40)3P3 PHOSPHATE ESTER PRECAUTIONARY INFORMATION =================**== PRECAUTIONARY STATEMENT.. (PLEASE USE THIS STATEMENT TO SATISFY THE IN-PLANT LABELING REQUIREMENTS OF THE OSHA HAZARO COMMUNICATIONS STANDARD 29CFR 1910.1200) HEALTH: MIST (ROOM TEMPERATURE) AND VAPOR (EVAL UATED TEMPERATURE) MAY IRRITATE LUNGS, EYES, NOSE ANO THROAT. MAY CAUSE IRRITATION TO SKIN UPON OIRECT CONTACT. PROLONGED INHALATION OF MIST ANO/OR VAPOR MAY RESULT IN NERVOUS DISOR DERS. PHYSICAL: IN FIRES, PRODUCT HILL DECOMPOSE PRO DUCING TOXIC FUMES OF PHOSPHDRUS OXIDES. LIQUID WILL BURN AT ROOM TEMPERATURE. INGREDIENTS ======*"=======*====-======== CAS# AND COMPONENT, MATERIAL/COMPONENT: PERCENT............................... CAS #................. HAZARO CLASS Distributors TRI-BUTOXYETHYL PHOSPHATE 100X 78-51-3 NONE 00 085662 conftdfnttai The C. P. HALL Company 2500 CHANNEL AVENUE MEMPHIS, TENNESSEE 38113 901-948-8663 PR-54 PAGE 01 MATERIAL SAFETY DATA 78 KP-14C(R) TRIBUTOXYETHYL PHOSPHATE 51 3 -FMC flammability (RED) EMERGENCY TELEPHONE NUMBERS CHEMTR EC (800) 424-9300 MEOICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-3551 CALL COLLECT REVISION: 0 EFFECTIVE: 09/01/85 SHPAEZCAIRADL PRINTED: 11/09/85 SKSIIIZSSI3=SlItSIIXt?S==I PHYSICAL' DATA MELTING POINT..............................: BOILING POINT................................ VAPOR PRESSURE........................... .. VAPOR OENSITY (AIR - 1)..: ROOM TEMPERATURE APPEARANCE AND STATE: ODOR..................................................... .. SPECIFIC GRAVITY (H20 =1): SOLUBILITY IN H20 X BY WT: X VOLATILES BY VOLUME: EVAPORATION RATE (BUTYL ACETATE = 1).: PH (AS IS)........................................ PH (IX SOLUTION)......................: NA 222.2*C (432*F) 1.6 MM HG 13.8 WHITE TO STRAW BUTYL ODOR 1.020 0 25*C 0.1U NO DATA COLORED 1 NA NA LIQUID FIRE* EXPLOSION ANO REACTIVITY DATA =========== FLASH POINT................................... .. AUTCIGNITIQN TEMPERATURE.: FLAMA9LE LIMITS UPPER...: (AIR) LOWER...: EXTINGUISHING MEOIA.............. : SPECIAL FIREFIGHTING........... : PROCEDURES OFGREE OF FIRE ANO..............: EXPLOSION HAZARD STABILITY........................................ .. HAZARDOUS POLYMERIZATION.: CONDITIONS TO AVOID.............. : MAJOR CONTAMINANTS THAT..: CONTRIBUTE TO INSTABILITY INCOMPATIBILITY.........................: HAZARDOUS DECOMPOSITION..: PROOUCTS OC 224*C (435*F) 260*C (500*F) NO DATA NO DATA WATER* WATER FOG* C02* DRY CHEMICAL* FOAM NIOSH APPROVEO SELF-CONTAINED BREATHING APPARATUS ANO FULL PROTECTIVE CLOTHING. SLIGHT FIRE HAZARD; TOXIC FUMES MAY BE LIBERATED STA3LE WILL NOT OCCUR EXTREME HEAT OR NONE KNOWN. COLD. NONE KNOWN. HIGHLY TOXIC FUMES OF PHOSPHORUS OXIDES. DO 085663 CONFIDENT TAl 02 MATERIAL SAFETY DATA 78 KP-140 <R > TRIBUTOXYETHYL PHOSPHATE SI 3 HFMC FLAMMABILITV <EDI EMERGENCY TELEPHONE NUMBERS CHEMTREC (300) 424-9300 MEOICAL (303) S95-9048 CALL COLLECT OTHER (304) 755-3551 CALL COLLECT REVISION: EFFECTIVE: 09/01/85 SPECIAL HAZARD PRINTEO: 11/09/35 EYE CONTACT--.. SKIN CONTACT... SKIN ABSORPTION INHALATION........... INGESTION, ROUTES OF EXPOSURE sasss*****ss8e*xssseasssntrsa MILOLY IRRITATING (RABBIT) REF: ICO/T.76.019 NON-IRRITATING (RABBIT) REF: IC D/T.76.019 NO SIGNIFICANT HAZARD (RABBIT) LD50 ABOVE 10G/KG (RABBIT) REF: ICO/T.76.019 PROBABILITY OF EXPOSURE LOW DUE TO LOW VOLATILITY NO SIGNIFICANT HAZARO LC50 = 30 MG/LITER (RATS) NO TLV PUBLISHED REF: FORC LAB NO. 2734H NO SIGNIFICANT HAZARD L050 9.49/KG (RAT) REF: ICO/T.76.019 SOURCE FMC FMC FMC FMC FMC DATE 197( 1 97< 197<! 1 97< 1976 EXPOSURE LIMITS ========================= ACUTE EXPOSURE, CHRONIC EXPOSURE, EFFECTS OF OVEREXPOSURE ======================= MAY BE IRRITATING TO SKIN, RESPIRATORY SYSTEM, MUCOUS MEMBRANES ANO EVES. SEE EMERGENCY .AND FIRST AID PROCEDURES AND NOTES TO THE PHYSICIAN. MAY CAUSE IRRITATION TO SKIN, MUCOUS MEMBRANES, RESPIRATORY SYSTEM AND EYES. REPEATED (ORAL) EXPOSURE OF RATS CAUSED CLINICAL SIGNS (INCLUDING ATAXIA AND DYSPNEA) AND ELECTROPHYSIOLOGIC ANO MORPHOLOGIC CHANGES IN THE NERVOUS SYSTEM. SEE EMERGENCY AND FIRST AID PROCEDURES AND NOTES TO THE PHYSICIAN. rn? 0SS664 r'ONFT0 trNTTQi. PAGE 03 MATERIAL SAFETY DATA 78 KP-140(R) TRI3UTQX YE THY L PHOSPHATE 51 3 FMC FLAMMABILITY (REOI EMERGENCY TELEPHONE NUMBERS CHEMTREC (SOO) 424-9300 MEOICAL (303) 595-9043 CALL COLLECT OTHER (304) 755"3551 CALL COLLECT REVISION: EFFECTIVE: 09/01/85 SPECIAL HAZARD PRINTED: 11/09/35 EMERGENCY AND FIRST AID PROCEDURES **==*** EYES..................................................... SKIN..................................................... INHALATION..................................... INGESTION........................................ DECONTAMINATION PROCEDURE NOTES TO PHYSICIAN................ WASH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES WHILE HOLDING THE EYELIDS APART. SEE AN DPHTHAL-} MOLOGIST. WASH WITH SOAP AND WATER. IF IRRITATION OCCURS ANO PERSISTS/' OBTAIN MEDICAL ATTENTION. REMOVE TO FRESH AIR/ ADMINISTER OXYGEN AND/DR ARTIFICIAL RESPIRATION IF NEEDED. IF DISCOMFORT OCCURS AND PERSISTS/ OBTAIN MEOICAL ATTENTION. GIVE 1 OR 2 GLASSES OF WATER ANO INDUCE VOMITING BY TOUCHING SACK OF THROAT WITH FINGER/ OR IF AVAILABLE/ BY ADMINISTERING SYRUP OF IPECAC. 00 NOT INDUCE VOMITING OR GIVE ANYTHING BY MOUTH Tu AN UNCONSCIOUS PERSON. OBTAIN MEOICAL ATTENTION, SEE NOTES TO PHYSICIAN BELOW. WASH WITH SOAP AND WATER. HAY 8E IRRITATING TO SKIN/ MUCOUS MEMBRANES ANO EYES. CONTAMINATED AREA SHOULD BE FLOODED WITH WATER/ AND ANY EYE CONTACT CASES SHOULD RECEIVE OPHTHALMOLOGIC EVALUATION. HUMAN SYSTEMIC TOXIC-f ITY INFORMATION IS UNAVAILABLE/ BUT IS EXPECTED TO BE LOW GR NONEXISTENT. IMPORTANTLY/ STRUC TURE-ACTIVITY RELATIONSHIPS SUGGESTED THE AB SENCE OF APPRECIABLE ANTICHOLINESTERASE ACTIVITY SUCH AS POSSESSED BY STRUCTURALLY DISSIMILAR ORGANOPHOSPHATE-S. TREATMENT OF ANY TOXICITY SHOULD BE SYMPTOMATIC AND SUPPORTIVE AFTER TERMINATING EXPOSURE THROUGH ABOVE MEANS OR/ IN CASE OF IN GESTION/ GASTRIC EVACUATION VIA EMESIS INDUCTION OR GASTRIC LAVAGE. SPECIAL PROTECTION =s*=ss3==*=sas==ras====s=== VENTILATION REQUIREMENTS. RECOMMENOEO PERSONAL............. PROTECTIVE EQUIPMENT RESPIRATORY................ USE IN VENTILATED AREAS. IN HIGH TEMPERATURE APPLICATION OR EXPOSURE TO MISTING/ USE A NIOSH CERTIFIED SELF-CONTAINED BREATHING APPARATUS. PAGE 04 00 085665 conftdfnttai MATERIAL SAFETY DATA 78 KP-140(R> *Vj/i TRISUTOXYETHYL phosphate 51 3 <FMC FLAMMABILITY (RED) EMERGENCY TELEPHONE NUMBERS CHEMTREC (300) 424-9300 MEDICAL (303) 595-9048 CALL COLLECT OTHER (304) 755-3551 CALL COLLECT REVISION: 0 EFFECTIVE: 09/01/85 SPECIAL HA2ARD PRINTED: 11/09/85 SPECIAL PROTECTION lassissncsmxiisssESizsm EYES,................................ .. GLOVES................................ SPECIAL CLOTHING,.: AND EQUIPMENT SAFETY GOGGLES OR FACE SHIELD IN CASE OF SPLASHING. RUBBER OR PLASTIC LIQUID PROOF GLOVES. FULL PROTECTIVE CLOTHING. STORAGE AND HANDLING ==="================z==== (PLEASE USE THIS STATEMENT USE FULL FACEPIECE WITH ORGANIC CARTRIDGE OR TO SATISTY THE IN-PLANT CANISTER TO PROTECT AGAINST IRRITATION. USE FACE ( LABELING REQUIREMENTS OF THE OSHA HAZARD SHIELDS/ RUBBER GLOVES/ APRONS OR PROTECTIVE CLOTHING WHERE SPLASHING IS EXPECTED. PROTECT COMMUNICATIONS STANDARD FROM PHYSICAL DAMAGE. STORE IN COOL VENTILATED 2 9CF R 1 <?10.1 200) AREA. KEEP AWAY FROM FOOD PRODUCTS AND FOOD HANDLING AREAS. DISPOSAL- SPILL OR LEAK PROCEDURES ==-=======** PROCEDURE FOR RELEASE OR SPILL WASTE DISPOSAL METHOO KEEP MATERIAL OUT OF STREAMS AND SEWERS. ABSORB SPILLEO MATERIAL ON COMMERCIAL OIL ABSORBANT SAND OR DIRT (SOIL). PUT THE CONTAMINATED ABSQR9ANT INTO A OOT APPROVEO CONTAINER AND DISPOSE OF ACCORDING TO THE METHODS OUTLINED 8ELCW FOR WASTE DISPOSAL. AN ACCEPT A 3LE METHOD IS TO BURN IN AN INCIN ERATOR IN ACCORDANCE WITH ALL LOCAL* STATE AND FEDERAL ENVIRONMENTAL LAWS/ RULES/ REGULATIONS/ STANDARDS AND OTHER REQUIREMENTS. BECAUSE AC CEPTABLE METHODS OF DISPOSAL MAY VARY BY LOCA TION/ AND BECAUSE REGULATORY REQUIREMENTS MAY CHANGE/ THE APPROPRIATE REGULATORY AGENCIES SHOULD 3E CONTACTED PRIOR TO DISPOSAL. 00 0856 66 CONFrDPN ttai PAGE 05 MATERIAL SAFETY DATA 78 1C P--1 49 (R ) TRIBUTOXYETHYL PHOSPHATE 51 3 "FMC FLAMMABILITY IREDI EMERGENCY TELEPHONE NUMBERS CHEMTREC (300) 424-9300 MEDICAL (303) 595-904S CALL COLLECT OTHER (304) 755-3551 CALL COLLECT REVISION: 0 EFFECTIVE: 09/01/35 SPECIAL HAZARD PRINTED: 11/09/85 S3S8SS3SSSS38XS5SSSX3;8C8S TRANSPORTATION OATA ****=****=********* 00T PROPER SHIPPING NAME.: OOT CLASSIFICATION................. .. OOT LABELS............................ .. DOT MARKING...................................... OOT PLACARD..................................... UN NUMBER.......................................... HAZARDOUS SUBSTANCE/RO... : 49 STCC NUMBER............................ .. EMERGENCY ACCIDENT PRECAUTIONS AND PROCEDURE: PRECAUTIONS TO BE TAKEN..: IN TRANSPORTATION CMA CHEMCARO NUMBER................. TYPE PACKAGES................................. OTHER SHIPPING IDS................. : KP-140(R) TRI-BUTOXYETHTL NOT REGULATED NONE NONE NONE NONE NOT LISTED NONE PHOSPHATE OBSERVE PRECAUTIONS AS FOR ANY HIGH ORGANIC LIQUID. PROTECT AGAINST PHYSICAL DAMAGE. NONE TANK CARS, TANK TRUCKS, DRUMS BOILING =,,===s==s=======s==== ADDITIONAL REGULATORY INFORMATION =========== MATERIAL IS REPORTED IN EPA TSCA INVENTORY LIST? MATERIAL IS LISTED AS A CARCINOGEN/POTENTIAL CARCINOGEN IN FOLLOWING NTP ANNUAL REPORT... ? I ARC MONOGRAPHS............? OSHA 29CFR PART 1910 SUBPART Z ? TES NO NO NO KS8SSS8SS88SSS88SS8S8SS8S8 ADDITIONAL INFORMATION ======================== AQUATIC TOXICITY CLASSIFICATION - NIDSH RTECS NO. 79-100 NO DATA AVAILABLE DO 085667 CONFIDENTIAL PAGE 06