Document EdekKRb3BnK81aEJdzqzmoyzL

Refining, North America Conoco tnc. PO. Bo* 37 Westlake LA 70669 <318)491-5211 September 28, 1990 Louisiana Emergency Response Commission Office Of State Police Hazardous Substance Control Section Right-To-Know Unit P. 0. Box 66614 Baton Rouge, LA 70896 SUBMITTAL OF USDS UPDATES - THIRD QUARTER 1990 Dear Sir: Enclosed you will find Material Safety Data Sheet Updates for the third quarter of 1990, for the Conoco Refinery, Westlake, Louisiana. This information is being provided to you in accordance with the update requirements of Section 311 of Community Right-To-Know Act. If you have any questions concerning this submittal, please contact Dave Tinker at 318-491-5543. Sincerely, fbK D. R. Unruh Plant Manager Lake Charles Refinery am att cc w/o att: W. 0. Lukens (Conoco) P. B. Butler (Conoco) D. L. Tinker (Conoco) DLT: MSDS.DOC SAL 000009769 Refining, North America Conoco Inc. PO. Box 37 Westlake. LA 70669 (318) 491-5211 September 28, 1990 Fire Chief Westlake Fire Department 2401 Guillory Street Westlake, LA 70669 SUBMITTAL OF MSDS UPDATES - THIRD QUARTER 1990 Dear Sir: Enclosed you will find Material Safety Data Sheet Updates for the third quarter of 1990, for the Conoco Refinery, Westlake, Louisiana. This information is being provided to you in accordance with the update requirements of Section 311 of Community Right-To-Know Act. If you have any questions concerning this submittal, please contact Dave Tinker at 318-491-5543. Sincerely, PF th~0 D. R. Unruh Plant Manager Lake Charles Refinery am att cc w/o att: W. 0. Lukens (Conoco) P. B. Butler (Conoco) D. L. Tinker (Conoco)*^ DLT: MSDS.DOC SAL 000009770 Refining. North America (conoco) Conoco Inc. P O. Box 37 Westlake. LA 70669 (318) 491*5211 September 28, 1990 Mr. Samuel H. Russell Calcasieu Parish Local Emergency Planning Committee P. 0. Box 1391 Lake Charles, LA 70602-1391 SUBMITTAL OF MSDS UPDATES - THIRD QUARTER 1990 Dear Sir: Enclosed you will find Material Safety Data Sheet Updates for the third quarter of 1990, for the Conoco Refinery, Westlake, Louisiana. This information is being provided to you in accordance with the update requirements of Section 311 of Community Right-To-Know Act. If you have any questions concerning this submittal, please contact Dave Tinker at 318-491-5543. Sincerely, PF ______ D. R. Unruh fo* plant Manager Lake Charles Refinery am att cc w/o att: W. 0. P. B. D. L. Lukens (Conoco) Butler (Conoco) Tinker (Conoco)^ DLT: MSDS.DOC SAL 000009771 DU PONT Material Safety Data Sheet Page 1 MATERIAL IDENTIFICATION DUPONT CORROSION INHIBITOR NO. 6 6S l 42 MSDS NUMBER S DUO00226 Revision Date Date Printed s 04-Nov-90 s 09-Nov-90 MANUFACTURER/DISTRIBUTOR Du Pont 1007 Market Wilmington, Street DE 19898 PHONE NUMBERS PRODUCT INFORMATION TRANSPORT EMERGENCY MEDICAL EMERGENCY 1--(800)441-7515 1-(800)424-9300 1-(800)441-3637 CHEMICAL FAMILY ORGANIC ACIDS TRADE NAMES / SYNONYMS DCI-6 DU PONT REGISTRY NUMBER: TSCA INVENTORY STATUS : NPCA-HMIS RATINGS : DP19-81-2 Reported/Included Health: 2 Flammability: 3 Reactivity: 0 Personal Protection rating to be supplied by user depending on use conditions. COMPONENTS Material NJ TRADE SECRET NJ TRADE SECRET *XYLENE *ETHYLBENZENE BENZENE REGISTRY REGISTRY #00850201001-5001 #00850201001-5003 P P CAS Number 1330-20-7 100-41-4 71-43-2 60-70 10-20 20-30 0-5 <0.0212 * Regulated as a toxic chemical under section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR part 372. PHYSICAL DATA Boiling Point Vapor Pressure Water Solubility Odor Form color Specific Gravity IBP 138 deg C (280 deg F) at 760 mm Hg. 10 mm Hg at 24 deg C < 0.02% wt. Aromatic hydrocarbon Liquid Dark Amber 0.95 at 16 deg C (60 deg F) SAL 000009772 MSDS No. DU000226 GS 142 DU PONT Material Safety Data Sheet Page 2 HAZARDOUS REACTIVITY Instability Incompatibility Decomposition Polymerization Stable. None reasonably foreseeable. Decomposition will not occur. Polymerization will not occur. FIRE AND EXPLOSION DATA Flash Point Method : 31 deg C (88 deg F) : PMCC FIRE AND EXPLOSION HAZARDS Flammable liquid. EXTINGUISHING MEDIA Water Spray. Foam. Dry Chemical. 002. SPECIAL FIRE FIGHTING INSTRUCTIONS Evacuate personnel to a safe area, apparatus. Wear self-contained breathing HEALTH HAZARD INFORMATION ANIMAL DATA: DU PONT CORROSION INHIBITOR NO. 6: Skin Absorption ALD: >7,500 mg/kg in rabbits Oral LD50: 8,314 mg/kg in rats DOT Skin Corrosivity Test: Not Corrosive XYLENE: Inhalation 4 hr. LC50: Skin Absorption LD50: Oral ALD: 6,700 ppm in rats 4,320 mg/kg in rabbits 4,500 mg/kg in rats The product is an eye irritant, and possibly a severe skin irritant in animals. Toxicity described in animals from exposure to xylene by inhalation include upper respiratory irritation? central nervous system and behavorial effects; decreased weight gain; hearing loss; and effects on the liver, kidneys, heart, spleen, lungs, bone marrow, and blood. Central nervous system effects; decreased body weights; and liver effects were seen in animals exposed to xylene by ingestion. Tests of xylene in animals demonstrate no carcinogenic activity. Xylene does not produce heritable genetic damage in animals or genetic damage in bacterial or mammalian cell cultures. Although abnormal sperm were SAL 000009773 MSDS No. DU000226 DU PONT Material Safety Data Sheet GS 1 42 Page 3 (HEALTH HAZARD INFORMATION - Continued) observed after an interperitoneal injection in rats, xylene did not produce reproductive effects. Developmental toxicity was observed in animals exposed to xylene but only at concentrations that were maternally toxicity. HUMAN HEALTH EFFECTS OF OVEREXPOSURE: Eye contact with the product may cause eye irritation with discomfort, tearing, or blurring of vision. Skin contact may cause skin irritation with discomfort or rash. Xylene can be absorbed through the skin in toxic amounts. Overexposure to xylene by inhalation may cause nonspecific discomfort, such as nausea, headache, or weakness; and temporary nervous system depression with dizziness, headache, confusion, incoordination, and loss of consciousness. Higher exposures may lead to cardiac stress; anemia and other blood changes; respiratory effects; possible liver and kidney damage; or fatality from gross overexposure. Ingestion may cause gastrointestinal irritation; nonspecific discomfort, such as nausea, headache, or weakness; liver effects and temporary nervous system depression. Individuals with preexisting diseases of the central nervous system, kidneys, liver, cardiovascular system, lungs, or bone marrow may have increased susceptibility to the toxicity of excessive exposures to xylene. CARCINOGENICITY The following components are listed by IARC, NTP, OSHA, or ACGIH as carcinogens. A 'P' indicates a Proposed Carcinogen. Material BENZENE IARC NTP OSHA ACGIH XXX X Du Pont controls the following materials as potential carcinogens : BENZENE. # APPLICABLE EXPOSURE LIMITS XYLENE AEL * (Du Pont) TLV (ACGIH) PEL (OSHA) 100 ppm - 8 Hr. TWA 150 ppm - 15 Min. TWA 100 ppm, 434 mg/m3 - 8 Hr TWA STEL 150 ppm, 651 mg/m3 100 ppm, 435 mg/m3 - 8 Hr TWA STEL 150 ppm, 655 mg/m3 00977^ SM- 000 KSD8 HO* DU000226 GS 142 DU PONT Material Safety Data Sheet Page (HEALTH HAZARD INFORMATION - Continued) ETHYLBENZENE AEL * TLV PEL (Du Pont): (ACGIH) : (OSHA) : None Established 100 ppm, 434 mg/m3 - 8 Hr TWA STEL 125 ppm, 543 mg/m3 100 ppm, 435 mg/m3 - 8 Hr TWA STEL 125 ppm, 545 mg/m3 BENZENE AEL * TLV PEL (Du Pont): (ACGIH) : (OSHA) : 1 ppm - 8 & 12 Hr. TWA 5 ppm - 15 Min. TWA 10 ppm, A2; 32 mg/m3, A2 - 8 Hr TWA See Notice of Intended Changes (1990-91) 0.1 ppm, 0.3 mg/m3 - 8 hr TWA, Al 1 ppm - 8 Hr. TWA 5 ppm - (Short term exposure limit) 0.5 ppm - Action level * AEL is Du Pont's Acceptable Exposure Limit. SAFETY PRECAUTIONS Avoid breathing vapors or mist. Avoid contact with eyes, skin, or clothing. Wash thoroughly after handling. 4 FIRST AID INHALATION If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. SKIN CONTACT Flush skin with water after contact. reuse. Wash contaminated clothing before EYE CONTACT In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Call a physician. INGESTION If swallowed, water. Never physician. do not induce give anything vomiting. Immediately give two glasses of by mouth to an unconscious person. Call a NOTES TO PHYSICIAN Activated charcoal slurry may be administered. To prepare activated charcoal slurry, suspend 50 grams activated charcoal in 400mL water and mix thoroughly. Administer 5mL/kg, or 350mL for an average adult. SAL 000009775 MSDS MO. DU000226 DU PONT Material Safety Data Sheet PROTECTION INFORMATION Page 5 6S 1 42 GENERALLY APPLICABLE CONTROL MEASURES AND PROCEDURES Use only with adequate ventilation. Keep away from heat, sparks and flames. Keep container tightly closed. PERSONAL PROTECTIVE EQUIPMENT EYE/FACE PROTECTION Wear safety glasses or coverall chemical splash goggles. RESPIRATORS Where there is potential for airborne exposures in excess applicable limits, wear NIOSH/MSHA approved respiratory protection. of PROTECTIVE CLOTHING Where there is potential for skin contact have wear as appropriate, impervious gloves, apron, jackets. available and pants, and DISPOSAL INFORMATION AQUATIC TOXICITY Xylene 96 hour LC50, fathead minnows: 27-42 mg/L SPILL. LEAK. OR RELEASE NOTE: Review FIRE AND EXPLOSION HAZARDS and SAFETY PRECAUTIONS before proceeding with clean up. Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean up. Soak up with sawdust, sand, oil dry or other absorbent material. Superfund reportable discharge = 1000 lbs. This material is an ICR (ignitable, corrosive, reactive) substance under CERCLA. Unless released material is immediately cleaned up for reprocessing, recycling, or reuse, a release of 100 lbs. may trigger the reporting requirements of CERCLA Section 103. WASTE DISPOSAL Treatment, storage, transportation and disposal must be in accordance with applicable Federal, State/Provincial, and Local regulations. This material may be a RCRA regulated hazardous waste upon disposal due to the ignitability characteristic. SAL 000009776 M8DS MO. DU000226 GS 142 DU PONT Material Safety Data Sheet Page 6 SHIPPING INFORMATION POT Proper shipping Name ; XYLENE SOLUTION Hazard Class : FLAMMABLE LIQUID UN/NA NO. : 1307 DOT Labels(s) : FLAMMABLE LIQUID DOT/IMP proper Shipping Name : Hazard Class : UN no. : DOT/IMO Label : Special Information: XYLENE SOLUTION FLAMMABLE LIQUID, 1307 FLAMMABLE LIQUID PAGE 3158 3.3 Shipping Containers Steel Drums - DOT 17E STORAGE CONDITIONS Store in well ventilated area. Keep container tightly closed. in accordance with National Fire Protection Assn regulations. Store TITLE III HA2ARD CLASSIFICATIONS Acute Chronic Fire Reactivity Pressure : Yes : Yes : Yes : No : No r's w ADDITIONAL INFORMATION AND REFERENCES This product contains trace quantities (<210ppm) of benzene, a chemical known to the State of California to cause cancer. The data in this Material Safety Data Sheet relates only to the specific material designated herein and does not relate to use in combination with any other material or in any process. SAL 000009777 KSDS NO. DU000226 DU PONT Material Safety Data Sheet GS 1 42 (END OF MSDS - Continued) Responsibility for MSDS : R. V. DAUM Chemicals & Pigments Wilmington, DE 19898 800-441-9442 # Indicates updated section. End of MSDS Page 7 Ooooo<^* sM-