Document Ed2yEdGLbzYYrnOmDGmQYK7yj

PPG Industries, Inc. Chemicals P.O. Box 1000 Lake Charles, Louisiana 70602 December 10, 1991 Mr. Gus Von Boduncjen Department of Environmental Quality Air Quality Division P 0 Box 82135 Baton Rouge, LA 70884-2135 Dear Mr. Von Bodungen: Re: LESHAP VCM Quarterly Report In accordance with LESHAP requirements contained in LAC 33:111. 2561, PPG Industries' Lake Charles Complex submits the attached Quarterly Report for the period September 1, 1991 through November 30, 1991. Emissions in excess of 10 ppm (averaged on an hourly basis) in the stacks exiting the incinerators are listed in Exhibit I. There were no (0) such incidents this quarter. Exhibit II is a record of emissions in excess of 10 ppm which resulted from a temporary by-pass of incineration. There was one (1) incident this quarter resulting in an estimated total release of 0.2 pounds of vinyl chloride. Exhibit III is a record of sudden discharges of vinyl chloride during the quarter. There was one (l) such incident this quarter resulting in an estimated total release of 0.16 pounds of vinyl chloride. Also, in accordance with the provisions of Section 61.243-1 of the NESHAP regulations, PPG is hereby submitting the results of performance leak tests of 204 randomly selected valves in vinyl chloride service performed at our VCM-II Unit on October 30 and 31, 1991, and 203 randomly selected valves at our TE II Unit which were leak tested on October 21, 1991. A listing of the valves checked is attached as Exhibits IV and V, respectively. For these tests, a leak was considered to be any reading greater than 1500 ppm right at the valve (more stringent than the regulatory definition of a leak as any reading of 10,000 ppm or greater). There were no valves found leaking out of the 407 valves tested. Thus, the percentage of leaking valves in each unit is demonstrated to be less than 2.0%. Based on these results, PPG intends to continue its LESHAP approved leak detection and elimination program in its VCM II and TE II Units. 1 Environmental Engineer SL 026587 EXHIBIT I CONTINUOUS STACK EMISSION RESULTS > 10 PPM VCM DATE STACK NCL. HOUR HOURLY 3-HOUR* ENDING AVG PPM AVG PPM NONE FOR THIS QUARTER COMMENTS SL 026588 EXHIBIT II NON-INCINERATION OF VCM VENTS PATS TIME SOURCES NOT INCINEPATEP EST. QUANTITY VCM VENTED. LBS. COMMENTS 9/10/91 10:38 am VCM II 0.23 See Below During a supplier's planned outage of instrument air, PPG was required to operate totally on its internal instrument air system. During the process of isolating the supplier's input and adjusting PPG's air compressor system, the plant air pressure was interrupted. This interruption caused the VCM II vent scrubber valve to open, creating a bypass of incineration. The duration of the bypass was 5 minutes. Several actions are being taken to prevent a reoccurrence of this bypass. A standard Operating Procedure for switching the air supply in and out of the plant air system will be written. A plot plan of the main instrument air header system has been developed. Extra operator coverage will be supplied when switching air systems in the future. An Engineering Work Order has been written to install an automatic reset on the Derivatives air compressor surge control system. SL 026589 EXHIBIT III SUDDEN DISCHARGES OF VCM D&EE TIME/DURATION ESTIMATED QUANTITY VCM RELEASED. LBS. COMMENTS 9/10/91 07:35/30 minutes 0.16 SEE BELOW During a supplier's planned outage of instrument air, PPG was required to operate totally on its internal instrument air system. During the process of isolating the supplier's input and adjusting PPG's air compressor system, the plant air pressure was interrupted. In response to the loss of instrument air, an attempt was made in the Tri-Ethane II Unit to switch to the instrument nitrogen supply. Improper switching resulted in the loss of all instrumentation In the OHC area at TriEthane II. Due to the loss of instrumentation, the OHC Reactor in this area shutdown resulting in a blown rupture disk on the vent header. In order to prevent a reoccurrence, all OHC operators at Tri-Ethane II will be instructed concerning the proper procedure for switching from instrument air to instrument nitrogen. The operator involved in the incident was counseled. A work order has also been written to modify the nitrogen to instrument air manifold to make it less complex, safer, and quicker to swap. 02*>590 SL CHEMICALS PPG EXHIBIT IV INTEROFFICE / LAKE CHARLES TO: Esther Liggio FROM: MIKE GUIDRY DATE: NOVEMBER 1. 199l SUBJECT: VCM-II Annual Leak Patrol Compliance Test Attached please find a list of approximately 204 valves that were selected at random from the list of valves in VCM service at VCM-II. These valves were checked for leaks with the definition of a leak, for the purpose of the survey, being any reading greater than 1500 ppm right on the valve. This definition was used because our meters only indicate amounts up to 2000 ppm. The true definition of a leak, as dictated in the regulations, is a reading of 10.000 ppm or greater right on the valve. Please note that the meter used for the testing was calibrated daily at 1500 ppm VCM. Of the valves surveyed none showed any leakage, therefore it can be said that "no leaks were found SL 026591 ' 10 3'-BATE: __ lIS L PSNE: mz 'n0iL LEAK PATROL COMPLIANCE TEST pN fj***-^ ^ap^NETER t: 9 (3 _ - 1991 CALIBRATION DATE: _______ ~/o-3o-q f No. LEAKAGE PtIDt DESCRIPTION NOTE: A LBAI IS DEFINED AS A HEADING >1500 PPN RIGHT ON THE HUE. t __\^f 2. /' BlocR Uht lor PT 545S 41 Furstce 41 Ptss Out 1 __ ^4. /' BlocR Vi Ire on 41 Fumce 42 Puss goits to Pest Beider 5 19. 5" Dump Pi Ire froo Q.T. to 12 Dopp Settle 4 5" Strsoes Ptire fro Q.T. to 42 Dopp Kettle 5 ^25. Botton Block Ptire os Q.T. Sightgltss 6 y^52. 1/2' BlocR Ptire os Flush Lise to LT 5240 I __ l^5B. 1/2' Block Ptire os Pressure Gisge os Eist SRP os Q.T. Pspor Lise S __(' Block Ptire usder Nest SRP os Q.T. Ptpor List 9 is~ 19. 5' Block Ptire Cosdessitt Drtis os Quesch Torer Ptpor List 10 l^14. Product Still Rttork CCP it Q.L.T. II \s^l2. 1/2' Block Ptire os PT 5440 Quesch Ptpor to Absorber r ' 1^65. Jpstreis Block Ptire for PCN Retort FCP 5199 12 i/^61. Dorsetrest Block Ptire for PCN Rework FCP 5199 I* .J^I- Sttplt Poist Block Ptire os Dischtrgt of Q. Lid.Fusp 15 t^25. 6' Dischtrte Ptire os 41 Q. Lid Fusp IS J^IS. S' Dischtrge Ptire os 42 Q. Lid. Fusp 11__,, 17. Upstreis Block Ptire to EDC Rework frot Q. Lid Fusps ^'ss. IS / 1/2' Block Ptire for Pressure Gtute os Top 41 Dopp Kettle 19 S' Block Ptire os Ptpor Use out of 41 Dopp Kettle 20 _.\^S1. l i/2' Block Ptire os Top 41 Dopp Kettle ftot Estrtissest Septrttor 21 94, I 1/2* Block Ptire os Top 42 Dopp Kettle (rot Estrtissest Septrttor 22 99. Top Block Ptire os Q.Dopp Kettle Estmsseit Septrttor Sightgltss 25 US. 5' Block Ptire os Suctios tl Dopp Orerhetd Fusp 24 1^ 151. Dorsstreis Block Ptire os FCP 504S Dopp Orerhetd to Q.T. 125. 4' Opstreis Block Ptire os FCP 5102 Presit Receirer Flos 26 146. S' Block Ptire os Suctios of tl HCt Preset Fusp 21 U9. S' Block Ptire os Dischtrge of 42 HCt Preset Fusp SL 026592 MTE: Ft)" ?0" 9/ kKKDAL MU PATSOL COKPLIAKCf TEST - 1991 HAKE: Kj0^ UJltv^fNv METES /: ^ / ?__ CALIBEATIOH DATE: ID' 30'9/ HO to. LEAKAGE PilDt DBSCSIPTIOK 21 J^lTo. S' Bloct Vilre on Suction of 42 HCl Preset Pm W .tzct^lll. 6' 9ilre oo Suction of Upper Intercooler Puap MOTE: A LEAt IS DEFIKED AS A tEADIKG >1500 PPK SIGHT OK THE VALVE. 10 l^T56. 1/2' Bloct Vilre On Hist Pressure Side FT JUS Upper Intercooler Flor 11 i^Tso. FCV JUS Upper Intercooler Floe . J2 Is'Tsi. 2' Bjpiss Vilre on FCV JUS Upper Intercooler Floe 11 2' Bloct Vilre on Bottoa LT JJOS Preset Surge Trip Lerel 14 ^^~ltl. 2' Bloct Vilre on Bottoa L.I.C. D.P. Tnnsaitter 1525 11 l^Til. 10' Bloct Vilre Kent to Absorber Froa Quench Toner 15 2' Bloct Vilre on Bottoa Of LT 1140 Absorber Pot Lerel 17 1^199. }' Dornstrein Bloct Vilre on VCK Seeort Holder l^^i^f^OO. S' Bloct Vilre Just Out the Bottoa of Absorber 19 j ^201. Staple Point Bloct Vilre on Suction of Absorber Bottoas Puaps 40 L^201, S' Suction Vilre to St Absorber Bottoa Puap 41 L^204. S' Dischirge Vilre to U Absorber Bottoa Puap 91 J^fo. FCV1140 Absorber Pot Lerel 41 .J^^Tll- Dornstreta Bloct Vnlre on LCV 1140 Absorber Pot Lerel 94 JfF^217. 4' Dischirge Vilre to Spire U.I.C. Puap 41 ,J??r^227. 4' Bloct Vilre Hest to Stripper froa Quench Liquor Drua 45 L^PO. High Pressure nitrogen to Stripper Kelt to Stripper 47 .C^219. 1' Upstreia Bloct Vilre on VCK leaort Heider to ProductStill Feed Drua 4S _U:_" 240. 4' Bloct Vilre on EDC Seeort Heider on Top Product Still Feed Drua 49 241. }' Doenstreta Bloct Vilre on VCK Seeort Heider 10 J:^Tl4. 5' Dischirge Vilre on S2 Product Still Feed Puap 11 C_t 250. 5' Doenstreta Bloct Vilre FCV 1150 Product Still Feed I 11 __271. Top Bloct Vilre on Product Still Sightgliss 11 Top Bloct Vilre os LT 1175 Product Still Lerel 14 -ir/lSl. 1/2' Bloct Vilre on High Pressure Side FT 1170 Product Still Seflui ct 026593 D WL annual leu PiTiOL comma test - t99t ; p'SC'-Cf/ ms:..L~Ld DATE. HETER t: ?/3 CALIBRATION DATE: /0~?O~9/ mam H Ho. IMAGE PUDt DESCimtOt }55} ^L^W"l8).. /' Block Vi I re on PT 2580 Product Still Orethtld HOTS: A LEAS IS DEFINED AS A READING >1500 PPH RIGST OH THE VALVE. 56 184. 1' Block Vilre on Pressure Giute Product Still Overbad into Condenser 57 _.._}z^^2~28866. S' Dpstretg Block Vslre PCV 55S0 Product Still Overbad S58B .Jt^^~22992l.. Top Block Vilre on Product Still Refluz Dm Sightplus 59 ,J^19). Bottoi Block Vtlre on Product Still Refluz Drug Sightgltss B6O0 J.1^292. fop Block Vilre on Product Still Refluz Drug LT BJSO 61 .U^T011122- 4" Dischtrge Vilre on tl Product Still Refluz Punp 62 4' Dischtrge Vilre on t2 Product Still Refluz Pump B623 -1t^11U8S.- 2/4' Bleed Vtlre on R2 Product Still Refluz Punp 664 .,U1T^2)1188.. J* Block Vtlre on Top Hutidifier Product Still Refluz ___j12^0.))0. /' Block Vilre on Pressure Giugt Product Still Refluz out of Htiidifier 66 -4-^- m 2' Block Vilre on Rework into (i Heutrilizer 67 i^lll. 2' Bleed Vtlre on Top tl Heutnlizer 68 ns. 4' Drun Vilre frow tl Heutrilizer to Heutrilizer Drm Oho 69 ty'w. 4' Drun Vtlre frow tl Heutrilizer to Heutrilizer Drm Drug 270 -LCz'-c'"'H24*4.. 2' Block Vilre on Top tl Heutrilizer frog Heutrilizer fish Pugp 71 ___jJy/^')M4S8. V Block Vilre on Top tl Heutrilizer 72 HHII-- 2` Block Vilre on Product out of tl Heutrilizer 71 l/'156. 4` Product Outlet Vilre on tl VCH Product Filter I7S4 jS'm. US- I' Block Vilre to Pressure Giuge on Outlet of VCH Product Filter 2752 __^k^~J12766.. )' Block Vilre Hezt to Heutrilizer Dnin Drug frog Sihine fiter 2S 12S. 4* Block Vtlre Hezt to Heutrilizer Dnin Drug frog Heutrilizers #2^ 111. 1/2' Block Vtlre on High Pressure Side FT 2187 Heutrilizer fish to Heutrilizer .J/^J84. FCV JIS7 Heutrilizer fish to Heutrilizer SL 26594 22 189. V Upstrag Block Vilre for LCV 2190 Heutrilizer Drm Drug 80 192. Bottog Block Vilre os LT 1188 HiOB Stonge Tink ~ vcp. ammgal leak patiol compliamce test - m ME:___ L--jZjJ-J-' BABE: h- ' ' r j C met /. CALIBRATIOM OATS:___J " / / ^7 ) Qcbeci m 10 Mo. LEABAGE PtlBt DESCimOl NOTE: A LEA! IS BEFIMEB AS A HEADIMG >1300 PPM tIGST OM TSE VALVE. El ^ 399. /' Slock Vi I re under tost Rupture Oise on Vent Beider it Eist Bitterr Units 62 ^ 402. 2' Top Block Vilre to Floit ChuPer iron B-l 53 401. 4' Block Vilre for Product into B-l 54 414. 3' Prim Vilre on Bottoi B-l S3 y 421. 2' Top Block Vilre on LT 1202 B-2 / Si 42J. 2' Block Vilre to Sigh Bigk Pressure stitch on B-2 SI .A. <39- 3' Bottoi Block Vilre on LT 1203 B-3 S9 /445. 2' Block Vilre for High Pressure Stitch A Pressure Gmge on 3-3 90 J50. 2' Driin Vilre on Bottoi B-3 91 ..AA51. 4" Block Vilre on Product Line into B-4 4$. 4' Block Vilre os iecircohtioi Line os B-4 s**0, 3` Block Vilre os Retotk Lise on B-4 94 .A.461. 2' Block Vilre os Sigh Pressure Stitch 1 Pressure Gtuge os B-4 / 95 y 463. 3` On in Vilre on Bottoi B-4 96 A__J65. S' Retork Suction Vilre os B-4 91 }u..^66. 2'Driin Vilre os Bottoi B-4 9S A.. 461. 1' Plotting Lise os 6' Use to/froi VCM Storige Spheres 99 .:_ 46S. S' Block Vilre hetteei Product Tnnsfer heider t Lot Teip. Tnssfer Beider ISO ..1/ 459. I' Floitisg Lise 01 6' Lise to/froi Lot Teip. Storige 101 .A. . 412. 6' Block Vilre hetteen Altersite Trissfer Beider to Lot Teip. Tnssfer Beider 102 __/_ 414, Block Vilre on Product Puip Bischirge Lise into Product Trissfer Beider 103 .a/iis. 3/4' Block Vilre on Plotting Lise froi Product Trissfer Beider iMorthl to Suet. Line of Prod. Trissfer Puip 104 ----- 411. 3/4' Block Vilre os Plotting Line froi Altersite Trissfer Beider (South) to Suction of Prod. Tnssfer Puip j^h'rL- 419. 2' Top Block Vilre to Floit Chuher on B-S W> 106 .A.. '463. 2' Block Vilre to Sigh Bigh Pressure Stitch on B-3 101 ___.J94. 6' Bischirge Vilre os U Product Tnssfer Puip $L 026595 fOS A... 495. 10' Suction Vilre on tl Product Trissfer Puip ' UTl:J)fe.............. VCH'" it*OiL LEU PATROL COKPLIAHCE TEST - 1991 ___________ KETER 7/3 CAL IBUTIOH BATE: /P-tf-l/ CHECK rot HO Ho. LEAKAGE ,PUDt DESCRlPTIOi HOTE: A LEAK IS DEFIHEO AS A READIHG >1500 PPH RIGHT OH THE VALVE. 109 04. Staple Point Block Vtlre op Sod ion Product Rework Poop l!0 v 5fl. V Block Vtlre to Bpptss Vents Around Shift Stonge Vent Coapressor V lit ___ 515. 4' Slock Vtlre Best VCH Coapressor Suction Brua Proa Vent Line 112 l/ -51!. 4" Auto Vtlre on Suction of Shift Stonge Vent Coapressor 11) .C. 520. 1-1/2' Block Vtlre on Shift Stonge Vent Coapressor Recirculttion Line 114 (L__/521. 1/2' Block Vtlre to Pressure Gtuge os Bischtrge VCH Shift Stonge Vent Coapressor US 524. 2" Block Vtlre on Line Proa VCH HP Vent Condenser to Incinerttor Hetder 72' Top Block Vtlre on Sightgltss of VCH HP Vent Condenser Receirer __\/ 5JI, 1-1/2' Ortin Vtlre on Bottoa VCH HP Vent Condenser Receirer 120 </ 29. 1/2' Block Vlire on PT 7426 Shift Stonge Vent to Incinerttor 121 __j/ 540. 2' Upstreta Block Vtlre on PCV 7426 ShiftStonge Vent to Incinerttor 122 ,J/^S55. Block Vtlre to Pressure Stitch ted Pressure Gtuge on B-l 125 556. 5-Vty Vtlre (or SRVs on 0-1 121 ,.!</^560. 6' Product Suction Vtlre on 61Bty Ttnk 125 571. 5' Block Vtlre oi Product Lite into 0-2 126 ,,\/^S77. 5-ftp Vtlre to SRVs ot 0-2 , 127 5!6. 5' Bottoa Block Vtlre to LT 7001 0-5 12! V,/pi. 5-ftp Vtlre to SRVs on 0-5 129 ,V_ 595. 6' Product Suctioi Vtlre on 0-5 110 609, 2' Top Block Vtlre to Vtrec on 0-4 0^ UU4 111 idi 612. 4' Retork Suction Vtlre on 0-4 15. 4' Bottoa Block Vtlre to Vtrec on 0-4 155 515- I' Block Vtlre os Rework Recirculttion Line Between 0-1 h 0-! / 154 _\/_ 619. 4' Block Vtlre Oownstreta CertunTeed Plot Heter SL 026596 CATS: MAKE: KM- AMMOAL LEAS PATIOL COMPUAMCE TBST - 1991 ____________ METES ___ CALIBEAT!OK DATE:__V CHECS EOS MO Mo. LEAKAGE PHD/ DESCIWWM MOTE: A LEAS IS DEFIMED AS A tEADIKG >1500 PPM EIGHT OH THE PALPS. 1U2S5 _Vj7' 6H2O0. 1/2' Block Pilre to SEP on Dischtrge Line on CertsinTeed Transfer Puap _V^62S. 126 S2S. J/4" SianIt Point Block Pi l re on Discdirge CertimTeed Trinsfer Poap 1U2?7 \/^ 627. 4' Discharge Pilre on tl PC Prodoct Trinsfer Poap 627. US 642. 4' S-2 Trinsfer Block Pslrt on PC Prodoct Trinsfer Lint -,,\^64S. 1U29 \/ 64S. 4' Block Pi I re Upstreia SEP on S-2 Trinsfer Lint froa PC - 140 v/ 666611.. 1/2' Block PiIre to Prtssort Sritcd tnd Pressore Giogt on D-S 141 662. S-Mty Ptlre to SEPs on D-S -v^?64142 664. 6' Product Suction Ptlre on D-S _!^/666. 142 666. 4' Bottoa Block Ptlre to Pirec on D-S 144 ,,V7 677., 6' Product Suction Ptlre on 0-7 ~6 s/ m. /' Block Ptlre on Eeaork Eecircuhtion into D-6 656. 1/2' Block Ptlre to Pressure Saitci tnd Pressure Gtuge on D-6 147 657. 2-Ptj Ptlre to SEPs on D-6 US 692. 4' Bottoa Block Ptlre to Perec on D-6 149 692. 1/2` Top Block Ptlre to LT 71291 D-S 159 797. l/2'Top Block Ptlre to LT 9699 S-l S19S. 2' Block Ptlre on S-l Pent Opstreta of Eqoiliting tnd Stick Pi I res 151 ,,.\//7iJ. 4' Auto Ptlre on S-l Fill Line Meit to Ttnk 152 152 722. 4' Eecircuhtion Ptlre on S-2 154 727. 2* Dischtrge Ptlre oa tl PC Ttnk Ctr Lotding Puap 7 155 ___ 729. 4' Suction Ptlre on S2 PC Ttnk Ctr Lotding Puap ' TG9. 2' Discdirge Ptlre on t2 PC Ttnk Ctr Lotding Puap 156 IS7 \y 727. 4' Blinded Block Ptlre nett the north PC Tk Ctr Ldg line tderail SEP .5^^7.49< 6' Auto Ptlre on S-2 Suction Line Mert to Ttnk 159- _v/y 747. 1-1/2* Equtliting Pent Ptlre on S-2 169 ___ 752. 4' Block Ptlre on Pent Line on Top S-2 161 V 755. 2--Ptj Ptlre to t2 SEPs on S-2 SL 026597 m ANNUAL LEAS PATROL CONPLIANCE TEST - 1991 DATE:jQ'J&-__________ NANS: o NEVER t: 7/3___CALIBRATION DATE:_____t CBBCSm & No. LEAIAGI PAIDt DESCUPTION NOTE: A LEAl IS DEFINED AS A REAPING >1500 PEN RIGBT ON TBE VALVE. m ISS. 5' Bottou BIocR Vtlre to LT SOIS S-I IS5 i / ISS. S' Cotton Discktrge Vtlre for Both S-I Putps 164 .^Zns. Downstreti 8lost Vtlre on OP Trmtitter Across ON/OFP Vtlre on Lot Tetperttnre Vents _l/Zl9. 1-1/2' Suction Vtlre on C-4 IS5 ISS ^^785. hi/V Drtin rtlre on bottot T-4 vr>.IS1 S' Inlet Vtlre to E-l ISS 191, S' Bloci Vtlre Opstreu Bypsss Vtlre for E-l 169 ^ 191. S' Suction Block Vtlre frot T-2 to P-5 HO \Sl9S. S' Block Vtlre Between P-5 A P-4 Suction. ill 1/^SQS. S' Dischttge Block Vtlre on P-4 X/^SIQ. 10' Oiscktrgt Vtlre on P-l 115 _Z815, 10' Cktin Vtlre to VCN Dock 1?4 \Zs20. 14' Block Vtlre on Suction Between P-l A P-2 m _}y^85l. 5' Suction Vtlre ot P-S frot T-5 ns _y/^S54. 1-1/2' Top Block Vtlre to Sigktgltss on T-5 III 1-1/2' Block Vtlre to Pressure Gtuge os T-5 ns / 859. 2' Inlet Periling Vtlre to S-4 \Z> 119 842. 2' Drtin Vtlre frot B-5 to T-5 / 150 y 84,4. 2' Drtin Vtlre frot t-5 to T-2 151 _ 14 847. S' Block Vtlre on B-5 to Incineritor IBS .^Z/52. S' Inlet to t-5 frot Dock ns ___/ 659. PCV 6427 C-S Recirculttion / 184 SSI. 4' Suction Vtlre on C-S &xZ 864. 2' Inlet Vtlre to D-l ISS y 872. Bottot Block Vtlre on D-l Sigktgltss IS? 815. 2' Top Block Vtlre os D-l Sigktgltss SL 026598 t BATE:Jj/lbO__________ HAKE: Ef '< AHHUAL LEAK PATiOL COHPLIUC! TEST - 199 ____________ KBm /, -1(3 .. CAUBIATIOH BATE: /~ ^7'?/ CHECK rot HO Ho. LEAKAGE Pi104 OESCtlPTIOK m ^ in. 1-1/2* Bleed mte on Top 0-1 Hi \Sin, 1/2* Bloct inlet on Dornstrent of Filter Out of D-I 191 ,,\{/iiO. 1-1/2* Top Bloct Hire to LT 6213 T-7 192 \S'iB2. 3* Onin Vilre on T-7 to P-S i PS 193 _}*/ US. 2* Bloct Vtlft on Oeriiing Line into T-7 194 H4. 2" Bloct inlee on T-7 Vent Line 193 _jw/^Hi, 1-1/2* Bloct inlet into T-7 Ftot Tnnsfer Line MOTE: A LEAK IS BEFIHEB AS A XiABIHG >1500 PPH tlGET OH TEE iALiE. >96 _BS7. 1-1/2' Bloct inlee Kent to T-7 on H2 Line to T-7 >99 902. I* Bloct inlee on T-2 Section to inporiitr I9i _vT 904. lsolution inlet on T-l Suction m '/ >11. Sint rim ti ft 1111 T-l w.^ 914, 1-1/2* Bloct inlet Oomtrtnt HI OH/OFF inlet to T-l 201 920. H2 OK/OFF inlet on T-l 202 937. 3* ient inlet on T-2 Flout Chtnber / 203 y/. 9`4l. [solution inlet on Suction Line T-2 204 ___ 943. Bornftrent Bloct Hire on Product Still ICY nt Q.L.T. 026599 sh EXHIBIT V TEl .!. 1 VC/DLE. AREhS VAI..VC MON 1 TORINO TIP# 970 10-21-91 (CALI DRAT ION DATE) RANDOM SELECTiOn OF 203 VALLE DATE OF CHECK 10-21-91 CHECKED RV DaN VOtJNG #3273 SL 026600 TO: ESTHER LlGGIO FROM : Is06BY CH'ASSQN DATE: OCTOBER 22, 1991 SUBJECT: TE--II VCM ANNIJAL LEAF PATEOu C 0 MP LIAM 2 E T E S T ATTACHED IS A LIST Of7 203 VALVES THAT WERE SELECTED FROM A LIST OF VALVES IN VCM SERVICE AT TE-IT. THESE VALVES WERE CHECKED FOR LEAKS WITH A LEAK BEING DEFINED A3 BEING GREATER THAN .1.500 PPM RIGHT AT THE VALVE. REGULATIONS DICTATE THAT A LEAK L'S A READING OF 10,000 PPM OR MORE RIGHT AT THE VALVE. OUR METER WAS CALIBRATED AT 1.443 PPM. NONE OF THE VALVES SURVEYED WERE FOUND TO BE LEAKING. IT CAN BE SAID THAT "NO LEFTS WERE FOUND". PLEASE NOTE THAT THE METER USED FOR THE TESTING WAS CALIBRATED THE DAY OF THE TEST. SL 026601 L-.- :i3045 111056 "11057 tilu59 j 11 060 r j 1061 * J 1063 :1064 '11065 I J 067 H I L068 #riW7i ! 11072 |T 1073 .j 11075 |11076 TYPE VALVE" VALVE' VALVE VALVE" VALVE VALVE'' VALVE" VALVE VALVE VALVE VALVE VALVEVALVE" VALVE' VALVE VALVE' VALVE' VALVE VALVEVALVE VALVE VALVE VALVE" VALVE" VALVE" VALVE" VALVE" VALVE" VVIA" LVE" It"(ALVE" m_sr*'ALVE" 1/ALVE' */ALVE" VALVE" VALVE"" VALVE" VALVE" VALVE" VALVE" VALVE' VALVEVALVE VALVEVALVE ' VALVE" VALVE" VALVE" VALVE" VALVE^ VALVE" VALVE" VALVE" VALVE'' VALVE VALVE" VALVE/ VALVE' VALV^ SER LOCATION 5 SUPER VLV N SUPER VLV ND.i PASS VT VLV TO THE VT HDR EDC -'INLET TO THE QCH TWR BP-CELL BTM VLV BP CELL TOP VLV S3BHT. J3LASS TOP VLV S DOPP KET VAPOR RETURN VLV ... N DDPP KET VAPOR RETURN VLV N "STRAHMAN' VLV AT THE QCH TWR NO.l PASS OUTLET PRESS TRANS VLV NO.2 PASS OUTLET PRESS TRANS VLV NO.2 PASS VLV TO THE ATMOSPHERIC QCH LQR RFLX VJ_V AT THE FLOAT CHAMBER BTM VLV . NO.* DUMP UPSTR VLV NO**;-DUMP VLV - >ri - . ~ NQ.~8r'D0PP KET INLET VLV N/ N0.2 DUMP- VLV T- N0.2D0PPKET INLET VLV QCH COND DRAIN TO THE QCH LQR TNK QCH-TWR VAPOR LN EQUAL VLV QCH LQR TNK 3-WAY VLV TO SRV's JQCH LOR TNK VAPOR VLV TO VC/HCL STL '<&X FURNACE FEED VLV AT THE QCH LQR TNK `5-&DM LQR TNK SUCT VLV QCH LQR PMP SUCT -*''-TO*2-~acH LQR PMP SUCT NO.4. QCH LQR PMP DISCH QCH TWR RFLX FCV UPSTR VLV QCH TWR RFLX FCV BY-PASS VLV QCH TWR RFLX FCV (F-124) QCH TWR RFLX FCV DRAIN VLV QCH LQR DRM LCV UPSTR VLV QCH LQR BRM.LCV BY-PASS VLV QCH LQR DRM LCV DWNSTR VLV QCH LQR DRM LCV DRAIN VLV NO.I QCH LQR PMP DRAIN NO.4 QCH LQR PMP DISCH BLD NO.2 QCH LQR PMP DISCH BLD NS QCH LQR PMP DISCH PRESS IND VLV QCH LQR SAMPLE PNT VLV QCH LQR TNK LEV TRANS BTM VLV QCH LQR TNK lEV TRANS TOP VLV QCH LQR TNK LEV TRANS TOP BLD VLV QCH LQR TNK SITE GLASS BTM VLV QCH LQR TNK SITE GLASS TOP VLV rMr l QCH LQR TNK SITE GLASS TOP BLD VLV VC/HCL STL LQD FEED BTM VLV VC/HCL STL LQD FEED MIDDLE VLV N3 VC/HCL STL VAPOR FEED BTM VLV VC/HCL STL VAPOR FEED MIDDLE VLV VC/HCL STL VAPOR FEED TOP VLV M %C/HCL /VC/HCL STL STL 3-WAY 3-WAY VLV VLV SRV's SRV's S BLD VLV 'VC/HCL STL 3-WAY VLV SRV's N BLD VLV VC/HCL STL LEV TRANS TOP VLV /\JL VC/HCL STL LEV TRANS BLD VLV SL 026602 STL -'GLASS -BTM. VLV - AMT 0 0 o o 0 o o 0 0 o 0 0 0 0 o 0 o 0 o o 0 0 0 0 0 o o 0 0 0 0 0 0 0 o 0 o 0 0 0 0 0 o 0 0 0 0 y 0 0 o o 0 0 o o 0 0 0 STR UNIT AA TE-II AA TE-II AA TE-II Q TE-II Q TE-II Q TE-II BB TE-II BB TE-II BB TE-II BB TE-II AA TE-II AA TE-II AA TE-II CC TE-II CC TE-II MM TE-II MM TE-II MH TE-II MM TE-II MM TE-II CC TE-II EE TE-II EE TE-II EE TE-II EE TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-IJ II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II II TE-II 11 TE-I I II TE-II II TE-II II TE-II EE TE-II EE TE-II EE TE-II KK TE-II KK TE-II KK TE-II 0 TE-II Q TE-II G TE--11 VALVE'' VALVE'' VALVE'' VALVE'' VALVE' VALVE' VALVE' VALVE' VAlVE' vAlvE ' VALVE' VALVE" VaLVE' /hiL. Vi 7VALVE' VALVE' VALVE' VALVE' VALVE' VAlvE ' VALVE/ VALVE ' VALVE' VALVE' VAlVE" VALVE' VALVE" VALVE' VALVE' VALVE' VALVE' VALVE' VALVE' VALVE' VALVE' VALVE' VALVE' VALVE' VALVE'/ oVALVE' 'VALVE" . VALVE' VALVE" VALVE" VALVE" VALVE'" VALVE VALVE""VALVE'' VALVE" VALVE" VALVE' VALVE" VALVE'' VALVE" VALVE' VALVE'* VALVE"" VALVES VALVE" VALVE" VALVE"" VALVE"' VALVE" 'SJE XL XiNil XL Njl VQ \G \G nn g G \G Nll ^*LL vcv VC/HCL STL REBOILERr UNDERFLOW VLV VC/HCL STL RFLX DRM LCV UPSTR VLV VC/HCL STL RFLX DRM LCV UPSTR BLD VLV VC/HCL STL RFLX DRM LCV (L-i50) VC/HCL STL RFLX DRM LCV DWNSTR BLD VLV VC/HCL STL RFLX DRM SPA LCV UPSTR VLV VC/HCL STL RFLX DRM SPA LCV BYPASS VLV VC/HCL STL COND INLET BLD VLV VC/HCL STL RFLXy DRM INLET VLV VC/HCL STL RFLX DRM EQUAL VLV VC/HCL STL RFLX DRM 3-WAY VLV FOR SRVs VC/HCL STL RFLX DRM 3-WAY VLV N BLD VC/HCL STL RFLX DRM 3-WAY VLV S BLD VC/HCL STL RFLX DRM LEV TRANS TOP VLV VC/HCL STL RFLX DRM LEV TRANS BTM VLV NO. 3 VC/HCL RFLX PMP DISCH BLD VLV VC/HCL STL RFLX DRM LEV TRANS TOP BLD VC/HCL STL RFLX DRM SITE GLASS BTM VLV VC/HCL STL RFLX DRM SITE GLASS TOP VLV VC/HCL STL RFLX DRM SITE GLASS TOP BLD VC/HCL STL RFLX DRM SUCT VLV VC/HCL STL RFLX DRM LEV TRANS BTM VLV NO.2 VC/HCL RFLX PMP SUCT VLV NO.1 VC/HCL -RFLX PMP SUCT DRAIN VLV NO.2 VC/HCL' RFLX PMP SUCT DRAIN VLV NO.1 VC/HCL RFLX PMP DISCH VLV NO.2 VC/HCL RFLX PMP DISCH VLV NO.l VC/HCL RFLX PMP DISCH BLD VLV NO.3 VC/HCL RFLX PMP DISCH VLV VC REWORK LN VLV AT THE PUMPS LQD VC.TC^VCI I FCV UPSTR VLV LQD VClTEOfeVCIX FCV UPSTR VLV BLD LQ$ VGYTtrVCtrTFCV IF-141) LOD^VCDTO/VCIIv FCV DWNSTR VLV BLD LQD'VCTO^VCri SRV BLK VLV VC/HCL. RFLJ! FCV UPSTR VLV VC/HCL. RFLX FCV BLD VLV VC/HCL: RFtX^FCV DWNSTR VLV VQ/HCL RFULSAFETY DRYER BY-PASS VC/HCL' rSAFETY DRYER INLET PI VLV VC/ -ETY DRYER INLET VLV VC/HCL- W*FRTY DRYER INLET BLD VLV ve/i BY-PASS SAFETY DRYER PI VLV SAFETY DRYER OUTLET VLV FLTR INLET VLV FLTR PI BLD VLV FLTR PI VLV {FLTR OUTLET VLV -FLTR TOR BLD VLV VC/HCL N8i2/FLTR PI BLD VLV VC/HCL ` W0ED2 FLTR PI VLV VC/HCL'TtLTERS- INLET BLD VLV VC/HCL FLTR OUTLET*BLD VLV VC/HCLNO.2 FLTR OUTLET BLD VLV VC/HCL-STL. FCV BLD VLV VC/HCL STL PCV (P-156) VC/HCL STL PCV . DWNSTR VLV VC/HCL STL PCV (HIC) BLD VLV 9&6o3 VC/HCL STL PCV (H-154) SL VC/HCL STL PCV (HIC> DWNSTR VLV DCE v FEED", SE SPARGER FEED VLV DCE . a FEED SW SPARGER FEED VLV 0 0 0 0 0 0 0 0 o 0 0 0 o 0 0 0 0 0 o 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 o 0 0 0 0 .0 0 0 0 0 0 0 o 0 0 C) o o Q TE-II KK TE -II kk TE- E I KK TE-II KK TE-II KK TE-II KK TE-II KK TE-II KK TE-II KK TE-II JJ TE-II JJ TE-II JJ TE-II JJ TE-I I JJ TE-II JJ TE-I I JJ TE-I I JJ TE-II JJ TE-I I JJ TE-II JJ TE-I I JJ TE-II JJ TE-I I JJ TE-II JJ TE-II JJ T%II JJ Ta-ii JJ TEf-U JJ T#II JJ TE-II JJ TE-II JJ TE-II JJ TE-II JJ TE-I I JJ TE-II JJ TE-I I JJ TE-I I JJ TE-II JJ TE-II JJ TE-II JJ.TE-II JJ TE-II JJ TE-II JJ TE-II JJ TE-II JJ TE-I I JJ TE-I I JJ TE-II JJ TE-II JJ TE-II JJ TE-II JJ TE-II JJ TE-II JJ TE-II JJ TE-II KK TE-II KK TE-II KK TE-'T I kk t L 1 KK TE - i I k K Til i r L. LI TE-11 r*i~ , r iiSf~ 79 ' 79 10 U <3 ,;4 13 ./? t^ 16 /7 99 00 01 03 04 05 07 08 ? 12 13 15 16 .17 19 10 U >A ::5 27 28 29 31 12 "T T *-> 33 36 T "T ->/ 39 40 41 0 45 47 48 49 31 VALVE^ VALVE^ VALVE' VALVE'' VALVE' VALVE' VALVE" VALVE' vALVE VALVE' VALVE" VALVE^ VALVE VALVE'' VALVE' VALVE' VALVE' VALVE'' VALVE'' VALVE'' VALVE^ VALVE' valve' VALVE'' VALVE-' VALVE^ VALVE' VALVE' VALVE" VALVE' VALVE' VALyE^ valve' VALVE^ VALVE' valve' VALVE^ VALVE'* valve' VALVES valve' VALVE'J VALVE, VALVE'', VALVE VALVE', VALVEV VALVE VALVE' VALVE'' VALVE'' VALVE^ VALVE' VALVE-' VALVE' VALVE7/ VALVE VALVE VALVE, VALVE" VALVEf VALVE. VALVE" $ > N*l Xl v \L EL \4_ \lL ^4. \LL LL NbL v>iL NJl N=l itlt 'SjL nm1-tJCE%R^8eitfc- NC.l-OCE RX RECIR PMP SUCT BLD PKV NO. _ ;CE RX RECIR PMP DISCH (A/-^-j NO.i DOE RX RECIR PMP DISCH BLD(1" ) NQ.l DCE RX RECIR PMP. DISCH NO.2 DCE RX RECIR PMP SUCT VLV (A/Qp) NO.2 DCE RX RECIR PMP SUCT BLD VLV NO.2 DCE RX RECIR PMP DI3CH BLD VLV NO.2 DCE RX RECIR PMP DISCH NO.3 DCE RX RECIR PMP SUCT VLV NO.3 DCE RX RECIR PMP SUCT VLV (A/OP) NO.3 DCE RX RECIR PMP DISCH BLD VLV NO.3 DCE RX RECIR PMP DISCH (A/DP) NO.3 DCE RX RECIR PMP DISCH ND.2 DCE RX CODLER OUTLET BLD VLV NO. 2 DCE RX COOLER OUTLET VLV NO. 2 DCE RX COOLER OUTLET BLD VLV NO.l DCE RX COOLER OUTLET BLD VLV NO.1 DCE RX COOLER OUTLET VLV DCE CAT ADDITION POT INLET VLV (A/OP) VC/HCL STLSAMPLE PNT-TRAY #7 VC/HCL STLSAMPLE PNT-TRAY #8 VC/HCL STLSAMPLE PNT-TRAY #13 VC/HCL STLSAMPLE PNT-TRAY #27. VC/HCL STLSAMPLE PNT-TRAY #31 2 INCH P.I. NOZ QCH TWR BOTTOMS 1/2 INCH BLD FLOAT CHAMBER QCH TWR QCH TWR FLOAT CHAMBER BTM. FLUSH VLV BLD VLV BTM OF S SUPER VLV- N2 BLK VLV TO S VC KET DUMP LN N2 BLK VLV TO N VC KET DUMP/LN BLD VLV UNDER S VC DUMP LN AUTOMATIC Q.T, SITE GLASS DRAIN VLV Q.T. SITE BLASS'FLUSH LN Q.T. SZTE GLASS FLUSH LN S VC DQPRfP.I. BLK VLV N: VC DOPPjP*J. BLK VLV S VC DOPP RStD. FLUSH VLV N VC DOPP R.D. FLUSH VLV S. SUPER \4sV P.I. BLK VLV N SUP-EI*.V&V P.I. BLK VLV NDQP&STjRAHAM VLV DCEr TAR* BUSRVr INLET VLV . BLK VLV HEAD P.I. ftL LOOP BLK VLV OFF OH LN LaOfcPBLD 2<0RFICE BLK VALVES) 24(0RFICE BLK VALVES) i38(13RflC& BLK VAVLES) VALVES QCH LQR^PMP-SEAL POT BLK VLV QCH LOR PMP SEAL POT BLK VLV QCH LORSPMP/SEAL POT GAUGE VLV BLD VLVlQCHiLQR SUCT LN DRAUL V#- VC/HCL REBOILER BTM ELL Rll. K.leiVLV-'AfiOVE BTM ELL r F-141 ORFICE BLK VALVES VC/HCL RFLX PMP SUCT COOLER INLET VLV VC/HCL RFLX PMP SUCT COOLER BYPASS VLV #3 VC/HCL RFLX PMP SUCT VLV #3 VC/HCL RFLX PMP DISCH VLV #3 VC/HCL: RFLX' PMP SUCT'VLV ~ SL 026604 #3 VC/HCL RFLX PMP OIL POT BLK VLV * let 0 lL TE-ri 0 Ll TE-- I I 0 LL TE-n 0 LL TE-II 0 LL TE-II 0 LL TE-II 0 LL TE-II 0 LL TE-II 0 LL TE-11 0 LL TE-I I 0 LL TE-II 0 LL TE-II 0 LL TE-II 0 LL TE-II 0 LL TE-I I 0 LL TE-II 0 LL TE-II 0 LL TE-II 0 LL TE-II 0 JJ TE-II 0 . JJ TE-I I 0 JJ TE-II 0 I itTE-II Q TE-I I 0 B8 TE-I I a BB TE-I I 0 BB Tt-II 0 BB T-II 0 MM T-II 0 MM TE-II 0 MM TE-I I 0 BB TE-II 0 a TE-II 0 Q TE-II 0 Q TE-I I 0 Q TE-II 0 Q TE-II 0 Q TE-II 0 AA TE-II 0 AA TE-I I a MM TE-II 0 MM TE-II 0 MM TE-II 0 II TE-II 0 II TE-II 0 II TE-I I 0 II TE-I I 0 II TE-II 0 II TE-II 0 II TE-II 0 II TE-II 0 II TE-II 0 II TE-II 0 II TE-II 0 Q TE-II 0 Q TE-11 0 JJ TE-I I 0 JJ TE-I I 0 JJ re-- c 1 0 JJ TE-II 0 - JJ TE-II i.r - - JJ TE-I i O JJ T " - 1' T - v vv,i VE' vAl.VE'' V AL VE VALVC' ;.v,LVE VALVE'' VALVE . VALVE' VALVE / ! > 4- s-> Np . HDR BLK VLV TO #3 COND . \f3 HDR BYPASS VLV AROUND -#3 COND P.I. ON #3 COND BYPASS * \E P-156 BYPASS VLV P.T. BLK VLV P-15.6 Ne FE-154 ORFICE BLK VALVES >L LT 239 BTft~VLV~ \lL LT 212 BTIi VLV Ni LT 239 TOP VLV J) i a- 0 Kk TE" 1I 0 Kk TE-II 0 KK TE-II 0 KK TE-II 0 KK TE-II 0 KK TE--11 0 LL TE-II 0 LL TE-II 0 LL TE-II +<o ^l.o-~ ft /<**<& YS'K nhafv***** v SL 026605 'Mr*>z ' ;