Document EbjoNw3dodwxNpwmGB28n350
OSHA HAZARD COMMUNICATION COMPLIANCE CHECKLIST
FOR MANUFACTURING OPERATIONS
Designate individual who will coordinate facility compliance with this standard;
advise Corporate Medical Services. V"
L rr-9^
Compile a list of aU chemical materials (including crude oil, coal and natural gas products) used and produced at the facility, indicating those materials meeting the OSHA definition of a "hazardous chemical" (see attached Classification Guide). Submit this list to Corporate Medical Services for review and any necessary assistance in identification of hazardous chemicals.
Request Material Safety Data Sheets (MSDS's) through Purchasing Department using attached form, for those hazardous chemicals for which a current MSDS is not on hand.
Purchasing Department will request MSDS's from suppliers and confirm this in writing to the facility.
Develop method for communicating hazards of known hazardous process inter mediates either by means of MSDS or written operating procedures.
Request Kerr-McGee MSDS's for all finished products through appropriate divisional or subsidiary contact (if necessary).
Establish master MSDS file and develop system whereby copies of applicable
MSDS's are available to potentially exposed employees during each work shift in
their work areas.
SWRflAsbestos 6709
1 B 030452
8. Develop list(s) of hazardous chemicals on the site, either on a facility-wide basis or by department or work area. List(s) must be consistent with MSDS terminology.
9. Develop system for monitoring of incoming containers of hazardous materials for proper labels, tags or markings which specify chemical identity and hazard warnings.
10. Develop a system whereby the identity and hazardous properties of the contents of any container* in the workplace are communicated to potentially exposed employees. (Note: This may be accomplished by means of labels, tags, markings, signs, placards, batch tickets or written operating procedures.)
11. Develop a system for communicating to potentially exposed employees the hazards and identity of hazardous chemicals contained in unlabelled pipelines. (Note: Pipe markers, if used for this purpose, must describe hazards as well as contents.)
12. Develop written procedures for non-routine tasks (e.g., confined space entry, pipeline breaking, emergencies) which will convey to the employees performing these tasks the required information on hazardous chemicals that may be encountered.
"Container" means any bag, barrel, bottle, box, can, cylinder, drum, reaction vessel, storage tank or the like that contains a hazardous chemical. Pipelines and containers intended for immediate transfer of contents are excluded.
030453
13. Develop system to inform contractors of the identity and hazards of hazardous chemicals to which their employees may be exposed while working on the site (if applicable). (Note: This should include a procedure governing the facility relationship with contractors and their employees.)
14. Develop written descriptions of any existing industrial hygiene survey, monitor ing program, or respiratory protection program, where any of these are applic able.
15. Develop a comprehensive employee training program which covers all of the above items and item (16), below. Establish training schedules whereby affected employees will be trained at the time of their initial assignment and whenever a new hazardous chemical is introduced into their work area.
16. Develop a written hazard communication program either on a facility-wide, or departmental basis. Program should include all applicable documents mentioned above, and methods for documenting all required activities. (Note: A model program will be provided in the near future.)
17. Develop a system whereby required information on hazardous chemicals, includ ing trade secrets if necessary, will be made "immediately" available to health professionals treating a patient in a medical emergency. (Note: Further guidance on this subject will be forthcoming, following a review by the Corporate Law Department.)
18. Develop retrieval system whereby all written material developed in conjunction with this program, with the exception of trade secrets, is made available on request to employees, their designated representative, or an OSHA inspector.
030^5* SWRf/Asbestos 6711 -\B
19. Complete required initial training of all current employees.
.20 Post list(s) of hazardous chemicals and make MSDS's available, if not already
done.
SWRf/Asbestos 6712
1S030455
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Acetaldehyde Acetic acid Acetic anhydride Acetone Acetonitrile 2-Acetylaminofluorene Acetylene 2-Acetylaminofluorene Acetylene dichloride, see 1, 2-Dichloroethylene Acetylene tetrabromide Acetylsalicylic acid (Asprin) Acrolein Acrylamide Acrylic acid Acrylonitrile Adriamycin Aflatoxins Aldrin Allyl alcohol Allyl chloride Allyl glycidyl ether(AGE) Allyl propyl disulfide alpha-Alumina Aluminum
Metal & oxide Pyro powders Welding fumes Soluble salts
Alkyls (NOC) 2-Aminoanthraquinone
o-Aminoazotoluene 4-Aminobiphenyl, Bee 4-Aminodiphenyl 4-Aminodiphenyl 2-Aminoethanol, see Ethanolamine 1-Amino-2-methylanthraquinone 2-Aminopyridine 2-Amino-5(5-nitro-2-furyl)-l,3,4-thiadiazole 3-Amino 1, 2, 4-triazole, see Araitrole Amitrole Ammonia Ammonium chloride fume
Ammonium sulfamate (Ammate) n-Amyl acetate sec-Amyl acetate
X X X X X X
X X X X
X X X X X
X
X
X X X X
SOURCE*
ACGIH
X X X X X
X
NTP X
IARC
X X
X X X XXX
X XX
X X X X X X X X X X X X
X
X
X XX
X X
X
X XX X X X X X
SWRf/Asbestos 6713
1 00010
1B 030456
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Aniline & homologues Anisidine (o-,p-isomers) o-Anisidine o-Anisidine hydrochloride Antimony & compounds, as Sb
Antimony trioxide Handling and use, as Sb Production
ANTU (alpha naphthyl thiourea)
Aramite Argon Arsenic & soluble compounds, as As Arsenic trioxide production Arsine Asbestos, also see MINERAL DUSTS, page 22 Asphalt (petroleum) fumes Atrazine Auramine manufacture Azaserine Azinphosmethyl (Guthion) Barium, soluble compounds, as Ba BCNU (bischloroethyl nitrosourea) Benomyl Benz(a)anthracene Benzene Benzidine p-Benzoquinone, see Quinone Benzo(b)fluoranthene Benzo(a)pyrene
Benzoyl peroxide Benzotrichloride Benzyl chloride Benzyl violet 4B Beryllium and beryllium compounds Biphenyl, see Diphenyl
Bismuth telluride Se-doped
Borates, tetra, sodium salts, Anhydrous Decahydrate Pentahydrate
Boron oxide Boron tribromide Boron trifluoride
X X X
X X X X
X X
X X
X X X
X X
SOURCE*
ACGIH
X X
X X X X X
X X X X X X X
X X
X
X X
X X
X
X
NTP
X X
X X X X
X X X X X
X
IARC
X
X
X
X X X X X X X X X
X X X X X X X X X SWRf/Asbestos 6714
2 00010
1B 030457
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 191Q.1ZOO)
8UBSTANCE/PR0CESS
Bromacil Bromine Bromine pentafluoride Bromochloromethane, see Chlorobromomethane Bromoform 1,3-Butadiene Butane Butanethiol, see Butyl mercaptan 2-Butanone, see Methyl ethyl ketone (MEK) 2-Butoxyethanol (Butyl Cellosolve) n-Butyl acetate sec-Butyl acetate tert-Butyl acetate Butyl acrylate n-Butyl alcohol sec-Butyl alcohol tert-Butyl alcohol Butylamine tert-Butyl chromate, as Cr03 n-Butyl glycidyl ether (BGE) n-Butyl lactate Butyl mercaptan (Butanethiol) alpha-sec-Butylphenol p-tert-Butyltoluene beta-Butyrolactone Cadmium Dust & salts, as Cd Cadmium Chloride Cadmium oxide
Fume, as Cd Production Cadmium Bulfate Cadmium sulfide Calcium carbonate/marble Calcium chromate Calcium cyanamide
Calcium hydroxide Calcium oxide Calcium silicate Camphor, synthetic Caprolactam
Dust Vapor Captafol Captan
OSHA
X
X X
SOURCE*
ACGIH
NTP
X X X
X X X
IARC
XX XX
XX XX
X
XX XX
XX
XX
XX
XX X
XX X
XX X
XXX
X
X XX
X
X
X X
X
X X
X
XX X
XX X X
X
X X SWRf/Asbestos 6715
3 00010
-l B 030458
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SOURCE*
SUBSTANCE/PROCESS
OSHA
ACGIH
Carbaryl (Sevin) Carbofuran
XX X
Carbon black
XX
Carbon dioxide Carbon disulfide
XX XX
Carbon monoxide
XX
Carbon tetrabromide Carbon tetrachloride
X XX
Carbonyl chloride, see Phosgene
Carbonyl fluoride Catechol (Pyrocatechol)
X X
CCNU (l-(2-Chloroethyl)-3cylcohexyl-l-nitrosourea)
Cellulose (paper fiber)
X
Cesium hydroxide
X
Chlorambucil
Chlordane
XX
Chlordecone, see Kepone
Chlorinated camphene
XX
Chlorinated diphenyl oxide
XX
Chlorine
XX
Chlorine dioxide
XX
Chlorine trifluoride Chlornaphazine
XX
Chloroacetaldehyde
XX
alpha-Chloroacetophenone (Phenacyl chloride) Chloroacetyl chloride
XX X
Chlorobenzene (Monochlorobenzene)
XX
o-Chlorobenzylidene malononitrile (0CBM) Chlorobromomethane (Bromochloromethane)
XX XX
2-Chloro-l,3-butadine, see B-Chloroprene
Chlorodifluoromethane
X
1-Chloro, 2, 3-epoxy-propane, see Epichlorohydrin
2-Chloroethanol, see Ethylene chlorohydrin
N, N-bis (2-chloroethyl)-2-naphthylamine, see Chlornaphazine
Chloroethylene, see Vinyl chloride
Chloroform (trichloromethane)
XX
bis-Chloromethyl ether Chloromethyl methyl ether, technical grade
XX X
1-Chloro-l-nitropropane
XX
Chloropentafluoroethane
X
4-Chloro-o-phenylenediamine
Chloropicrin (nitrotrichloromethane)
XX
B-Chloroprene (2-chloro-l,3-butadiene)
XX
o-Chlorostyrene
X
NTP
IARC
XX X
XX XX
X
XX XX XX
X
SWRf/Asbestos 6716
4 00010
1B 030459
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESS
OSHA
o-Chlorotoluene Z-Chloro-6-(trichloromethyl) pyridine, see Nitrapyrin
Chlorpyrifos Chromic acid and chromates Chromite ore processing (Chromate), as Cr
X
Chromium Metal Chromium (II) compounds, as Cr Chromium (III) compounds, as Cr
X X X
Chromium (VI) compounds, as Cr
X
Water soluble Certain water insoluble
X X
Chromyl chloride Chrysene Citrus Red No. 2
Clopidol Coal dust, see MINERAL DUSTS, page 22 Coal tar pitch volatiles
(as benzene soluble fractions; anthracene, BaP, phenanthrene, acridine, chrysene, pyrene) Cobalt, as Co metal, dust & fume Cobalt carbonyl, as Co
X X
Cobalt hydrocarbonyl, as Co Coke oven emissions
X
Copper Fume Dusts & mists, as Cu
Cotton dust, raw
X X X
Crag herbicide
X
p-Cresidine
Cresol, all isomeres
Crotonaldehyde Crufomate
X X
Cumene
X
Cupferron Cyanamide
Cyanides, as CN Cyanogen Cyanogen chloride
X
Cycasin
Cyclohexane Cyclohexanol
X X
Cyclohexanone
X
Cyclohexene Cyclohexylamine
X
SOURCE*
ACGIH
NTP
X
X X X
XX XX XX
XX XX XX
X X
X
X
IARC X
X X X
X
X X X
XX X X X X
X X X X X
XX X X X X X SWRf/Asbestos 671
5 00010
IB 030460
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Cyclonite Cyclopentadiene Cyclopentane Cyclophosphamide Cyhexatin
2,4-D DDT (Dichlorodiphenyltrichloroethane) DDVP Dacarbazine Daunomycin Decaborane Demeton Diacetone alcohol (4-hydroxy-4methyl-2-pentanone) N,N'-Diacetylbenzidine
2.4-Diaminoanisole sulfate 4,4,-Diaminodiphenyl ether 1,2-Diarainoethane, see Ethylenediamine 2.4-Diaminotoluene Diazinon Diazomethane Dibenz (a,h) acridine Dibenz (a,j) acridine Dibenz (a,h) anthracene 7H-Dibenzo (c,g) carbazole Dibenzo (a,e) pyrene Dibenzo <a,h) pyrene Dibenzo <a,i) pyrene Diborane 1,2 Dibromo-3-Chloropropane
1.2-Dibromoethane, see Ethylene dibromide 2-N-Dibutylaminoethanol Dibutyl phosphate
Dibutyl phthalate
Dichloroacetylene o-Dichlorobenzene p-Dichlorobenzene
3,3'-Dichlorobenzidine (and its salts) 3,3'-Dichloro-4,4'-diaminodiphenyl ether Dichlorodifluoromethane 1.3-Dichloro-5,5-dimethyl hydantoin 1.1-Dichloroethane (Ethylidene chloride)
1.2-Dichloroethane, see Ethylene dichloride 1.1-Dichloroethylene, see Vinylidene chloride 1.2-Dichloroethylene (Acetylene dichloride)
X
X X X
X X X
X
X X
X X X X X X X X
X
SOURCE*
ACGIH
X X X
X X
NTP X
X X X
X X
X X X
X X X X
X X X X
X X X X X X XX
X X X
IARC
X
X X X X
X X X X X
X X X X X X X X
X X
X SWRf/Asbestos 6718
6 00010
IB 030461
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SOURCE*
SUBSTANCE/PROCESSOSHA
ACOIH
NTP
Dichloroethyl ether
XX
Dichlorofluoromethane
X
Dichlororaethane, aee Methylene chloride
Dichloromonofluoromethane 1.1- Dichloro-l-nitroethane
X XX
1.2- Dichloropropane, see Propylene dichloride
Dichloropropene 2.2- Dichloropropionic acid
X X
Dichlorotetrafluoroethane
XX
Dichlorvos
X
Dicrotophos
X
Dicyclopentadiene Dicyclopentadienyl iron Dieldrin
XX
X X
Diepoxybutane
X
Diethanololamine
X
Diethylamine
XX
Diethylaminoethanol
XX
Diethylene triamine Diethyl ether, see Ethyl ether
X
Di (2-ethylhexyl) phthalate
X
1,2-Diethylhydrazine Diethyl ketone
X
Diethyl phthalate
X
Diethylstilbestrol Diethyl sulfate
X
Difluorodibromomethane
XX
Diglycidyl ether (DGE)
XX
Dihydroxybenzene, see Hydroquinone
Dihydrosafrole
Dii6obutyl ketone (2,6-Dimethyl-4-heptanone) Diisopropylamine
XX XX
3, 3'-Dimethoxybenzidine (o-Dianisidine)
X
Dimethoxymethane, see Methylal Dimethyl acetamide
XX
Dimethylamine
XX
p-Dimethylaminoazobenzene Dimethylaminobenzene, see Xylidene
XX
trans-2 [(Dimethylamino)methylimino]-5-[2-(5-nitro-2-furyl)vinyl]-
1,3,4-oxadiazole Dimethylaniline (N, N-Dimethylaniline)
XX
Dimethylbenzene, see Xylene
3,3'-Dimethylbenzidine (o-Tolidine) Dimethyl carbamyl chloride
X XX
Dimethyl-1,2-dibromo-2-dichloroethyl phosphate,
See Naled (Dibrom)
SWRf/Asbestos 6719
7
IARC
X
X X X X X X X X X X
00010
1B 030462
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Dimethylformamide 2,6-Dimethyl-4-heptanone, see Diisobutyl ketone
1.1-Dimethylhydrazine 1.2-Dimethylhydrazine Dimethylphthalate
Dimethyl sulfate Dinitolmide (3,5-Dinitro-o-toluamide) Dinitrobenzene (all isomers)
Dinitro-o-cresol
3,5-Dinitro-o-toluamide, Dinitrotoluene 1,4-Dioxane, tech, grade Dioxathion
see Dinitolmide (Diethylene dioxide)
Diphenyl (Biphenyl)
Diphenylamine Diphenylmethane diisocyanate,
See Methylene bisphenyl isocyanate (MDI) Dipropylene glycol methyl ether
Dipropyl ketone Diquat Direct Black 38 Direct Blue 6 Di-sec, octyl phthalate
(Di-2-ethylhexylphthalate)
Disulfiram Disulfoton
2,6-Ditert. butyl-p-cresol
Diuron Divinyl benzene
Emery
Endosulfan Endrin
Epichlorohydrin <l-Chloro,2,3-epoxy-propane) EPN 1.2-Epoxypropane, see Propylene oxide
2.3-Epoxy-l-propanol, see Glycidol
Ethane Ethanethiol, see Ethyl mercaptan
Ethanolamine <2-Ami noethanol)
Ethinyloestradiol Ethion
2-Ethoxyethanol (Glycol monoethyl ether)
2-Ethoxyethyl acetate (cellosolve acetate)
X X X X X X X X X
X
X
X X X
X
X X
SOURCE*
ACGIH X
NTP
X
X X X X
X
X XX X X X
IARC X X
X
X X X
XX XX X
X X X X X X X X XX X
X
X X
X X X
SWRf/Asbestos 6720 8 00010
1B 030463
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESS____________________________________________SM
Ethyl acetate Ethyl acrylate Ethyl alcohol (Ethanol) Ethylamine Ethyl amyl ketone (5-methyl-3-heptanone)
Ethyl benzene Ethyl bromide Ethyl butyl ketone (3-heptanone)
Ethyl chloride Ethylene Ethylene chlorohydrin (2 Chloroethanol) Ethylenediamine (1,2 Diaminoethane) Ethylene dibromide (1,2 Dibromoethane) Ethylene dichloride (1,2 Dichloroethane) Ethylene glycol
Particulate Vapor Ethylene glycol dinitrate and/or Nitroglycerin Ethylene glycol methyl ether acetate, see 2-Methoxyethyl acetate Ethylene oxide Ethyleneimine Ethylene thiourea Ethyl ether (Diethyl ether) Ethyl formate Ethylidene chloride, see 1,1-Dichloroethane Ethylidene norbornene
Ethyl mercaptan (Ethanethiol) Ethyl methanesulfonate
N-Ethylmorpholine Ethyl silicate Fensulfothion Fenthion Ferbam Ferrovanadium dust Fibrous glass dust (Glass, fibrous or dust) Fluorides, as F Fluorine
Fluorotrichloromethane, see Trichlorofluoromethane
Fonofos
Formaldehyde
Formaldehyde gas Formamide
X X X X X X X X X
X X X X
X
X X
X X
X
X X
X X
X X
X
SOURCE*
ACGIH
X X X X X X X X X X X X X X
X X X
NTP
X X
X X
X X
X X
X X X X X X X X X
X XX
IARC
X X
9
SWRf/Asbestos 6721
00010
IB 030464
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Formic acid 2-(Z-Formylhydrazino)-4-(5-nitro-2-furyl)thiazole
Furfural Furfuryl alcohol Gasoline
Germanium tetrahydride Glass, fibrous or dust, see Fibrous glass dust Glutaraldehyde
Glycerin mist Glycidaldehyde Glycidol (2,3-Epoxy-l-propanol) Glycol monoethyl ether, see 2-Ethoxyethanol Graphite (Natural), see MINERAL DUSTS, page 22 Graphite (Synthetic) Guthion, see Azinphosmethyl Gypsum Hafnium Helium Hematite underground mining Heptachlor
Heptane (n-Heptane) 2-Heptanone, see Methyl n-amyl ketone 3-Heptanone, see Ethyl butyl ketone Hexachlorobenzene Hexachlorobutadiene Hexachlorocyclohexane isomers Hexachlorocyclopentadiene Hexachloroethane Hexachloronophthalene
Hexafluoroacetone Hexamethyl phosphoramide Hexane (n-Hexane)
Other isomers 2-Hexanone, see Methyl n-butyl ketone Hexone, see Methyl isobutyl ketone sec-Hexyl acetate Hexylene glycol Hydrazine
Hydrazine sulfate Hydrazobenzene Hydrogen Hydrogenated terphenyls Hydrogen bromide Hydrogen chloride
X X X
X
X X X
X X X
X X
X X
SOURCE*
ACGIH X
NTP
X X X X
X X
X
IARC X
X
X
X X X
X X
XX X
X X X X
X
XX X
X
X
X XXX
X X X X X X
SWRf/Asbestos 6722 10 00010
1B 030465
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Hydrogen cyanide Hydrogen fluoride, as F Hydrogen peroxide Hydrogen Belenide, as Se Hydrogen sulfide Hydroquinone (Dihydroxybenzene) 4-Hydroxy-4-methyl-2-pentanone,
see Diacetone alcohol 2-Hydroxypropyl acrylate Indene Indeno <l,2-cd) pyrene Indeno (1,2,3-cd) pyrene Indium & compounds, as In Inert (nuisance) dust, see MINERAL DUSTS, page 22 Iodine Iodoform Iron dextran complex Iron oxide fume (Fe203>, as Fe
Iron pentacarbonyl, as Fe Iron salts, soluble, as Fe Isoamyl acetate Isoamyl alcohol Isobutyl acetate Isobutyl alcohol Isooctyl alcohol Isophorone Isophorone diisocyanate Isopropoxyethanol
Isopropyl acetate Isopropyl alcohol Isopropylamine
Manufacture (strong-acid process) N-Isopropylaniline Isopropyl ether Isopropyl glycidyl ether (IGE) Isosafrole
Kaolin Kepone (Chlordecone) Ketene
Lasiocarpine Lead, inorg., dusts & fumes, as Pb Lead acetate
Lead arsenate, as Pb3(As04)2
Lead chromate, as Cr
X X X X X
X
X
X X X X X
X X X
X X
X X
SOURCE*
ACGIH
X X X X X X
NTP
IARC
X X
X X X
X X
XX X X X X X X X X X X X X X X
X X X X
X X
XX X
X X
XX X XX
11
SWRf/Asbestos 6723
00010
IB 030466
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SOURCE*
SUBSTANCE/PROCESS
OSHA
ACGIH
NTP
Lead phosphate Lead subacetate Limestone Lindane Lithium hydride L.P.G. (Liquified petroleum ga6) Magnesite Magnesium oxide fume Malathion Maleic anhydride Manganese, as Mn; Dust & compounds
Fume Manganese cyclopentadienyl tricarbonyl, as Mn Manganese tetroxide Marble/calcium carbonate Melphalan Mercury, as Hg; Alkyl compounds
All forms except alkyl; Vapor Aryl & inorganic compounds Merphalan Mesityl oxide Mestranol Methacrylic acid Methane Methanethiol, see Methyl mercaptan Methorny1 Methoxsalen with ultra-violet A therapy (PUVA) Methoxychlor 2-Methoxyethanol, see Methyl cellosolve 2-Methoxyethyl acetate (Ethylene glycol methyl ether acetate) 4-Methoxyphenol Methyl acetate Methyl acetylene (propyne) Methyl acetylene-propadiene mixture (MAPP) Methyl acrylate Methylacrylonitrile Methylal (Dimethoxymethane) Methyl alcohol (methanol) Methylamine Methyl amyl alcohol, see Methyl isobutyl carbinol Methyl n-amyl ketone (2-Heptanone) N-Methyl aniline 2-Methylaziridine Methylazoxymethanol and its acetate
12
X XX XX XX
X XX XX XX XX XX
X X X
XX XX XX
XX
X X
X
XX
X X XX XX XX XX X X XX XX
XX X
X X
X
SWRf/Asbestos 6724
IARC X X
X X X X
X X
OOOIO
W030467
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CPR 1910.1200)
SUBSTANCE/PROCESSOSHA
ACGIH
NTP
IARC
Methyl bromide Methyl n-butyl ketone (Z-Hexanone) Methyl cellosolve (2-Methoxyethanol)
Methyl cellosolve acetate Methyl chloride Methyl chloromethyl ether Methyl chloroform Methyl 2-cyanoacrylate Methylcyclohexane Methylcyclohexanol o-Methylcyclohexanone Methylcyclopentadienyl manganese tricarbonyl, as Mn Methyl demeton Methylene bisphenyl isocyanate (MDI)
(Diphenyl methane diisocyanate)
Methylene chloride (Dichloromethane) 4,4'-Methylene bis (2-chloroaniline) (MOCA) Methylene bis (4-cyclohexylisocyanate) 4,4'-Methylene bis (N,N-dimethyl) benzenamine 4,4*-Methylene bis (2-methylaniline) 4,4-Methylene dianiline Methyl ethyl ketone (MEfO (2-Butanone) Methyl ethyl ketone peroxide Methyl formate 5-Methyl-3-heptanone, see Ethyl amyl ketone Methyl hydrazine Methyl iodide
Methyl iBoamyl ketone Methyl isobutyl carbinol (Methyl amyl alcohol) Methyl isobutyl ketone (MIBK) (Hexone)
Methyl isocyanate Methyl isopropyl ketone
Methyl mercaptan (Methanethiol) Methyl methacrylate Methyl methanesulfonate Z-Methyl-l-nitroanthraquinone (of uncertain purity) N-Methyl-N'-nitro-N-nitrosoguanidine Methyl parathion Methyl propyl ketone, see Z-Pentanone
Methyl silicate a-Methyl styrene Methylthiouracil Metronidazole Mevinphos
X X X X X X X X X
X X
X X
X X X X X X
X
SOURCE*
X X
X
X X X X X X X X
X XX X
X X X X
X X X X X X X X X
X
X X
X
X X
X
XX XXX
13
SWRf/Asbestos 6725
00010
IB 030468
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910,1200)
SOURCE*
SUBSTANCE/PROCESSOSHA
ACGIH
NTP
Hichler's ketone Mirex
Mitomycin C
Molybdenum, as Mo Soluble compounds Insoluble compounds
XX XX
Monocrotaline
Monocrotophos Monomethyl aniline
X
Monomethyl hydrazine
X
Morpholine
XX
5-(Morpholinomethyl)-3[(5-nitrofurfurylidene)amino]-2-oxazolidinone
Mustard gas, see Nitrogen mustard
Nafenopin
Naled (Dimethyl-1,Z-dibromo-Z-dichloroethyl phosphate)
X
Naphtha (coal tar)
X
Naphthalene alpha-Naphthylamine
XX X
B-Naphthylamine
XX
Neon
X
Nickel Metal
XX
Soluble compounds, as Ni Nickel carbonyl, as Ni
XX XX
Nickel subsulfide
Nickel sulfide roasting, fume & dust, as Ni Nicotine
X XX
Niridazole
Nitrapyrin (2-Chloro-6-(trichloromethyl)pyridine) Nitric acid
X
X X
Nitric oxide
XX
Nitrilotriacetic acid 5-Nitroacenaphthene
p-Nitroaniline
XX
5-Nitro-o-anisidine Nitrobenzene
XX
4-Nitrobiphenyl
X
p-Nitrochlorobenzene 4-Nitrodiphenyl
XX X
Nitroethane
XX
Nitrofen 1-t(5-Nitrofurfurylidene)amino]-2-imidazolidinone
N-[4-(5-Nitro-2-furyl)-2-thiazolyl]acetamide
Nitrogen dioxide
X
X X
X X
X
IARC X X X
X X
X X
X X
X
X X
14
SWRf/Asbestos 6726
00010
1B 030469
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SOURCE*
SUBSTANCE/PROCESSOSHA
ACGIH
NTP
IARC
Nitrogen trifluoride Nitrogen mustard and Nitrogen mustard N-oxide
Nitroglycerin (NG) Nitromethane 1-Nitropropane
Z-Nitropropane N-Nitrosodi-n-butylamine N-Nitrosodiethanolamine
N-Nitrosodiethylamine N-Nitrosodimethylamine (dimethylnitrosoamine) p-Nitrosodiphenylamine N-Nitrosodi-n-propylamine N-Nitroso-N-ethylurea N-Nitrosomethylethylamine N-Nitroso-N-methylurea
N-Nitroso-N-methylurethane N-Nitrosomethylvinylamine
N-Nitrosomorpholine N-Nitrosonornicotine N-Nitrosopiperidine N-Nitrosopyrrolidine N-Nitrososarcosine Nitrotoluene Nitrotrichloromethane, see Chloropicrin Nonane Norethisterone Octachloronaphthalene
Octane 0estradiol-17B Oestrone Oil mist, mineral Oil orange SS
Osmium tetroxide, asOs Oxalic acid Oxygen difluoride
Oxymetholone Ozone Panfuran S (Pihydroxymethylfuratrizine) Paraffin wax fume Paraquate, respirable sizes Parathion Particulate polycyclic aromatic hydrocarbons
(PPAH), see Coal tar pitch volatiles
XX XX XX XX XX
XX
XX X
XX XX
XX XX XX XX XX
X XX XX
X
X XX XX XX XX X XX XX
X XX
X XX XX XX XX XX XX
X
X X X
X
X
X
SWRf/Asb estos 6727
15 00010
1B 030470
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESS
Pentaborane Pentachloronaphthalene Pentachlorophenol Pentaerythritol Pentane 2-Pentanone (Methyl propyl ketone) Perchloroethylene Perchloromethyl mercaptan Perchloryl fluoride Petroleum distillates (naphtha) Phenacetin Phenazopyradine and its hydrochloride Phenol Phenothiazine Phenoxybenzamine and its hydrochloride N-Phenyl-beta-naphthylamine p-Phenylene diamine Phenyl ether, vapor Phenyl ether-biphenyl mixture, vapor Phenylethylene, see Styrene, monomer Phenyl glycidyl ether (PGE) Phenylhydrazine Phenyl mercaptan Phenylphosphine Phenytoin and its sodium salt Phorate Phosdrin, see Mevinphos Phosgene (carbonyl chloride) Phosphine
Phosphoric acid Phosphorus (yellow) Phosphorus oxychloride Phosphorus pentachloride Phosphorus pentasulfide Phosphorus trichloride Phthalic anhydride m-Phthalodinitrile Picloram Picric acid Pindone Piperazine dihydrochloride 2-Pivalyl-l, 3-indandione, see Pindone (Pival) Plaster of Paris Platinum
Metal Soluble salts, as Pt
16
OSHA X X X X X X X X
X
X X X X X
X X X X X X X X
X
X
SOURCE*
ACGIH
NTP
X X
X X X X X X X
X X X
X
X X X
IARC
X X X
X X X X
X X
X X X X X X X X X X X X X X
X X SWRf/Asbestos 6/28 X X
00010
IB 030471
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Polybrominated biphenyls (PBB's) Polychlorinated biphenyls (PCB's) Polytetrafluoroethylene decomposition products
X
Ponceau MX Ponceau 3R Potassium hydroxide
Procarbazine and its hydrochloride Progesterone Propane
X
1,3-Propane sultone
Propargyl alcohol B-Propiolactone
X
Propionic acid Propoxur n-Propyl acetate Propyl alcohol n-Propyl nitrate Propylene Propylene dichloride<1,2 Dichloropropane)
X X X
X
Propylene glycol dinitrate Propylene glycol monomethyl ether Propyleneimine Propylene oxide (1,2Epoxypropane)
X X
Propylthiouracil
Propyne, see Methyl acetylene Pyrethrum
X
Pyridine
X
Quinone (p-Benzoquinone)
X
RDX, see Cyclonite
Reserpine
Resorcinol
Rhodium
Metal, fume and dusts, as Rh
X
Soluble salts, as Rh
X
Ronnel
X
Rosin core solder pyrolysis products, as formaldehyde
Rotenone (commercial) Rouge
X
Rubber solvent (Naphtha)
Saccharin, see Sodium saccharin Safrole
SOURCE*
ACGIH
X X
NTP
X X
X X
X X X XX X X X X X X X X X X X
X X X
X X
X X X X X X X
X
IARC X X X X X X X
X
X
SWRf/Asbestos 6729
17 00010
030472
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910,1200)
SOURCE*
SUBSTANCE/PROCESS
OSHA
ACGIH
NTP
IARC
Selenium compounds, as Se
XX
Selenium hexafluoride, as Se
XX
Selenium Sulfide
Sesone (Sodium 2,4-dichloro-phenoxyethyl 6ulfate)
X
Silane, see Silicon tetrahydride
Silica, Silicates - See MINERAL DUSTS, page 22
Silicon
X
Silicon carbide
X
Silicon tetrahydride (Silane)
X
Silver,
as Ag Metal Soluble compounds
XX XX
Sintered calcium chromate
Sintered chromium trioxide
Sodium azide
X
Sodium bisulfite
X
Sodium 2, 4-dichloro-phenoxyethyl sulfate, see Sesone
Sodium fluoroacetate (1080)
XX
Sodium hydroxide
XX
Sodium metabisulfite
X
Sodium saccharin
Soots, tars and mineral oils
Starch
X
Stibine
XX
Sterigmatocystin
Stoddard solvent
XX
Stroptozotocin
Strontium chromate Strychnine
XX
Styrene, monomer
XX
Subtilisins (Proteolytic enzymes as
X
100% pure crystalline enzyme)
Sucrose
X
Sulfallate
Sulfotep
X
Sulfur dioxide
XX
Sulfur hexafluoride
XX
Sulfuric acid
XX
Sulfur monochloride
XX
Sulfur pentafluoride
XX
Sulfur tetrafluoride Sulfuryl fluoride
X XX
Systox, see Demeton
X
X X
XX X X
XX X
X
SWRf/Asbestos 6730
18 00010
1B 030473
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Z, 4, 5-T Tantalum TEDP, see Sulfotep Tellurium & compounds, as Te Tellurium hexafluoride, as Te Temephos
TEPP Terphenyls Testosterone and itB esters
2,3,7,8-Tetrachlorodibenzo-p-dioxin (TCDD) 1.1.1.2-Tetrachloro-2, 2-difluoroethane
1.1.2.2-Tetrachloro-l, Z-difluoroethane 1.1.2.2-Tetrachloroethane Tetrachloroethylene, see Perchloroethylene Tetrachloromethane, Bee Carbon tetrachloride Tetrachloronaphthalene Tetraethyl lead, as Pb Tetrahydrofuran Tetramethyl lead, as Pb Tetramethyl succinonitrile Tetranitromethane Tetrasodium pyrophosphate Tetryl (2,4,6-trinitrophenyl-methylnitramine) Thallium Soluble compounds, as T1 Thioacetamide 4,4'-Thiobis (6-tert. butyl-m-cresol) 4,4'-Thiodianiline
Thioglycolic acid Thiourea Thiram Tin
Metal Oxide & inorganic compounds, except SnO^, as Sn Inorganic compounds, except oxides Organic compounds, as Sn Titanium dioxide, as Ti
o-Tolidine Toluene (toluol) Toluene-2, 4-diisocyanate (TDI)
o-Toluidine o-Toluidine hydrochloride Toxaphene, see Chlorinated camphene Tributyl phosphate Trichloroacetic acid
X X
X X
X X
X X X
X X X X X X
X X
X
X X X
X X X
X
SOURCE*
ACGIH
NTP
X X
X X X X X
X X
X X
IARC
X X
X X X X X X X X X
XX X
X X
XX X
X X
X X X X X X XX
X
X X
SWRf/Asbestos 6731
19 00010 -16 030*74
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESS
1,2,4-Trichlorobenzene 1,1,1-Trichloroethane, see Methyl chloroform 1,1,2-Trichloroethane Trichloroethylene Trichlorofluoromethane <fluorotrichloromethane) Trichloromethane, see Chloroform 2,4,6-Trichlorophenol Trichloronaphthalene Trichloronitromethane, see Chloropicrin 2,4,6-Trichlorophenol 1,2,3-Trichloropropane 1,l,2-Trichloro-l,2,2-trifluoroethane Tricyclohexyltin hydroxide, see Cyhexatin Triethylamine Trifluorobromomethane Trifluoromonobromomethane Trimellitic anyhdride Trimethylamine Trimethyl benzene Trimethyl phosphite 2,4,6-Trinitrophenol, see Picric acid 2,4,6-Trinitrophenyl-methylnitramine, see Tetryl 2,4,6-Trinitrotoluene (TNT) Triorthocresyl phosphate Triphenyl amine Triphenyl phosphate Tris (1-aziridinyl) phosphine sulfate (Thiotepa) Tris (1-aziridinyl) phosphine sulfide Tris (2,3-dibromopropyl) phosphate Trypan Blue (commercial grade) Tungsten, as W
Insoluble compounds Soluble compounds Turpentine Uracil Mustard Uranium (natural). Soluble
& Insoluble compounds, as U Urethane Valeraldehyde Vanadium, as V2 05, respirable dust & fume Vegetable oil mists Vinyl acetate Vinyl benzene, see Styrene Vinyl bromide
OSHA
X X
X X X X X
X X X
X X X X
SOURCE*
ACGIH X
NTP
X
X X
X
X X X
X X
X X X X
IARC X
X X X X
X X X
X X X X X X X X XX X X X X
X SWRf/Asbestos 6732
20 00010
, IB 030475
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESSOSHA
Vinyl chloride(Chloroethylene) Vinyl cyanide, see Acrylonitrile Vinyl cyclohexene dioxide Vinylidene chloride (1,1 Dichloroethylene) Vinyl toluene VM & P Naphtha Warfarin Welding fumes Wood dust (certain hard woods as beech & oak)
Soft wood Xylene (o-, m-, p-isomers)(xylol)(Dimethyl benzene) m-Xylene a, a'-diamine Xylidine (Dimethylaminobenzene) Yttrium Zinc beryllium silicate Zinc chloride fume Zinc chromate, as Cr Zinc oxide
Fume
Dust Zinc stearate Zirconium compounds, as Zr
X
X X
X X X X X
X
SOURCE*
ACGIH X
NTP
X
X X X
IARC X
X X X X X X
X X XX
X X X X
SVVftfJAsbestos6733
21 00010
IB 030476
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE (FOR USE IN COMPLYING WITH OSHA HAZARD COMMUNICATION STANDARD. 29 CFR 1910.1200)
SUBSTANCE/PROCESS
MINERAL DUSTS Silica. Si02 Crystalline
Quartz Cristobalite Tridymite Silica, fused Tripoli Amorphous, including natural diatomaceous earth Silicates (1% quartz) Asbestos Graphite Mica
Mineral Wool Fiber Perlite Portland Cement Soapstone Talc (non-asbestos) Talc (fibrous) Tremolite (talc, fibrous) Coal Dust Inert (Nuisance) Dust
OSHA
SOURCE*
ACGIH
NTP
IARC
XX
XX XX XX
X X XX
XX X XXX XX XX
X X XX XX XX XX X XX XX
SWRf/Asbestos 6734
22 00010
IB 030477
HAZARDOUS CHEMICAL CLASSIFICATION GUIDE
^Sources used in compling this listing are as follows:
OSHA: 29 CFR Part 1910, Subpart Z, Toxic and Hazardous Substances, Occu pational Safety and Health Administration
ACGIH: Threshold Limit Values for Chemical Substances and Physical Agents in the Work Environment. 1983-1984 edition, American Conference of Governmental Industrial Hygienists
NTP:
Annual Report on Carcinogens, third edition, National Toxicology Program, Public Health Service, U. S. Department of Health and Human Services
IARC:
Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Humans, 1982, International Agency for Research on Cancer, World Health Organization.
The OSHA Hazard Communication Standard, 29 CFR 1910.1200 (d)(3), states: "The chemical manufacturer, importer or employer (emphasis added) shall treat the (above) sources as establishing that the chemicals listed in them are hazardous."
ThiB listing is considered a "baseline" for identification of chemicals designated as a "health hazard," and should not be considered allinclusive. In addition to "health hazards," the OSHA definition of a "hazardous chemical" includes those representing "physical hazards" as well. A "physical hazard" is defined as any substance which is combus tible liquid, a compressed gas, explosive, flammable, an organic per oxide, an oxidizer, pyrophoric, unstable or water-reactive. Any such substance must also be treated as a "hazardous chemical" for purposes of complying with the standard, regardless of whether it is included in this listing.
SWRf/Asbestos 6735 23 00010
IB 030478
REQUEST FOR MATERIAL SAFETY DATA SHEETS (MSDS)
TO: T. P. Robertson Purchasing Department MT-401, Oklahoma City
Location:
Date:
Subject: Request for Material Safety Data Sheets
Please obtain a Material Safety Data Sheet on the materials listed below:
Item No.
Name of Material (Include all names by which it is known)
Supplier (Name and Address)
SWRf/Asbestos 6736
(USE SEPARATE SHEET IF NECESSARY)
IB 030479