Document DvYvm6DyY4ydq0vNGvN3waY8N

ENVIRONMENTAL HEALTH SURVEY FOR 1980 CHLORINATED METHANES PLANT LOUISIANA DIVISION Submitted by: R* J* Bordelon DO 101.939 CONFIDENTIAL CHLORINATED METHANES PLANT INDUSTRIAL HYGIENE JOB ANALYSIS A- Introduction The Plaquemine, Louisiana Chlorinated Methanes Plant was MONITORED DURING 1980 IN A ROUTINE' AND CONTINUAL SURVEY OF THE CHEMICALS AND NOISE PRESENT IN THIS BLOCK* LISTED BELOW ARE THE CHEMICALS PLUS NOISE, WITH THEIR RESPECTIVE STANDARDS: Chemical Standard (TLV) Methyl Chloride Vinyl Chloride Methylene Chloride Chloroform Carbon Tetrachloride Methanol Ethylene Dichloride B-trichloroethane Dimethyl Ether 1,1,1 Trichloroethane (degreaser) Chlorine Hydrochloric Acid Sulfuric Acid Noise 50 ppm 1 PPM 200 ppm 10 PPM 5 PPM 200 ppm 10 PPM 10 PPM H00 ppm 350 ppm 3 mg/m~3 7 mg/m-3 1 mg/m-3 85 DBA -1- DO 101940 confidential. B. Conclusion from 1980 Survey All employees in the CMP block were monitored using personnel monitors- Most were monitored two or three times during the YEAR AND ALL JOBS WERE COVERED- As IN THE PREVIOUS YEAR THE DATA REFLECTS THAT EMPLOYEES ARE WITHIN THE THRESHOLD LIMITS WHEN PERFORMING THEIR ROUTINE JOBS- PEOPLE ARE PROVIDED WITH AND REQUIRED TO WEAR PROPER PROTECTIVE EQUIPMENT WHEN A JOB HAS THE POTENTIAL OF EXPOSING THEM TO LEVELS WHICH MAY EXCEED THE STANDARDS- To KEEP A CLOSER WATCH ON SUCH JOBS THERE WILL BE MORE EXCURSION SAMPLES IN THE 1981 MONITORING PROGRAM- This WILL HELP TO PINPOINT THE JOBS WHICH REQUIRE CLOSE ATTENTION- There is a decline in the use of chlorothene to clean pump parts* It was discovered that much of the cleaning can be ACCOMPLISHED BY USING LOW-PRESSURE STEAM AND WATER- THE MATERIAL CONTROLLER REPORTS THAT HE IS HAVING TO ORDER FEWER DRUMS OF CHLOROTHENE THAN IN THE PAST, DESPITE THE INCREASE IN PUMP REPAIR WORK OVER PREVIOUS YEARS- Changes in the standards for 1980 effecting this plant are: Chlorine - ceiling lowered to 1 ppm (3mg/M-3)- Carbon tetrachloride - TLV lowered from 10 ppm to 5 PPM- Ethylene dichloride - TLV lowered from 50 ppm to 10 PPM- Noise - The average noise level for the 0T job was greater than in past years- This resulted from a single exposure reading OF 170% WHICH occurred when the operator was venting down M-l filters for approximately one hour prior to RECHARGING THESE FILTERS* HEARING PROTECTION WAS USED, BUT THIS HIGH READING POINTS TO A DEFINITE PROBLEM- 1 O J <54 j cNF-TOFNTrA!.. -2- C* Additional Comments The waste heat boiler has done a lot to reduce the need for VENTING THE V"800's TO ATMOSPHERE IN ORDER TO READY THEM FOR RECHARGING* HOWEVER, THERE ARE PERIODS WHEN THE WASTE HEAT BOILER IS DOWN OR NOT OPERATING PROPERLY AND THE V"800#S HAVE TO BE VENTED TO ATMOSPHERE* THE AIR MONITORS SUPPORT EVIDENCE OF SUCH ACTIVITY* People have developed a greater awareness toward protection WHICH CAN BE PROVIDED BY EQUIPMENT AVAILABLE TO THEM TO REDUCE THEIR EXPOSURES TO VARIOUS CHEMIMCALS THEY ARE TAKING ADVANTAGE OF THE PROTECTION AFFORDED BY NITRILE GLOVES OVER THE NEOPRENE TYPE, USE OF DUST MASKS, TYVEK COVERALLS, ETC* We HAVE ALSO PURCHASED AN EMERGENCY WORK SUIT WHICH CAN FIT OVER A SCOTT AIR PAK TO PROVIDE COMPLETE v PROTECTION TO THE INDIVIDUAL EVEN IN HEAVY SPILLS* The new change room is complete with a new set of lockers to COMPLY WITH GOVERNMENT REGULATIONS REQUIRING SEPARATE LOCKERS FOR WORK AND STREET CLOTHES AND THEREFORE MINIMIZE THE POSSIBILITY OF CONTAMINATING CLOTHES WORN HOME* ^ ^ A NEW AND MORE RIGID RESPIRATOR POLICY IS GOING INTO EFFECT* IT WILL SPELL OUT THE CARE AND CLEANING OF THE RESPIRATORS AS WELL AS THEIR USES* ALL PERSONNEL UNDERWENT FIT "TESTING OF THE SCOTT"0"VISTA AND SCOTT AIR MASKS DURING DECEMBER 1980, THUS COMPLYING WITH GOVERNMENT REGULATIONS COVERING RESP I RATORS* -3- DO 101.94? CONFIDENTIAL D* Monitoring Results Personnel monitoring using charcoal adsorption tubes was EMPLOYED TO COVER ALL THE JOBS FOR THE FOLLOWING CHEMICALS: METHYL CHLORIDE, VINYL CHLORIDE, DIMETHYL ETHER, METHYLENE CHLORIDE, CHLOROFORM, CARBON TETRACHLORIDE, ETHYLENE DICHLORIDE, AND B~TRICHLOROETHANE THE SAMPLES REVEALED THE FOLLOWING RESULTS, BASED ON TWA* Chemical Stan- dard High/Job Average High/Indiv- Sample Methyl Chloride 50 0T 2*3 EDO 7-A Vinyl Chloride 1 All Samples <0-1 All Samples <0-1 Dimethyl Ether aoo All Samples <0*1 All Samples <0-1 Methylene Chloride 200 EDO Loader 1.8 EDO 1-8 13.8 Chloroform 10 EDO 0-8 EDO a.5 Carbon Tetrachloride 5 SS 0-5 EDO SS 2-5 Ethylene Dichloride 10 All Samples <0.1 Loading Coord* 0*3 B"Trichloro- ethane 10 All Samples <0-1 All Samples <0-1 DO 1.01943 CONFIDENTIAL. -U- D. Monitoring Results (cont'd) Some excursion monitoring was done on certain jobs of short duration with THE POTENTIAL OF HIGH EXPOSURE LEVELS* (Numbers shown ARE HIGH READINGS IN PPM) Job: OT CATCHING SAMPLES IN DISTILLATION AREA (10-12 MIN / M-l M-2 M-3 M EDC B-tri 12*1 0*4 1*0 36*6 2*1 0*0 Job: Millwright replacing leaking T-800 PUMP (22 MIN*) M-l M-2 M-3 M-4 EDC B-tri 62*2 6*4 3*1 0*0 0*0 0*0 Job: Loader - loader not wearing pump; pump mounted at breathing zone level above open dome of M-2 T/C while loading* Temperature 72F* (35 min*) M-l M-2 M-3 M-4 EDC B-tri 2*9 161*8 2*8 0*0 0*0 0*0 -5- DO 101944 CONFTDENTIAL D* Monitoring Results (cont'd) Area monitoring was employed to check for methanol and 1,1,1 TRICHLOROETHANE (a DEGREASER USED IN THE CLEANING OF PUMP parts)* For methanol, samples were collected in saran bags AT VARIOUS POINTS THROUGHOUT THE PLANT, SAMPLE RESULTS AVERAGED, AND TWA FIGURES WERE OBTAINED BY USING THE AVERAGE TIME SPENT IN THESE AREAS FOR EACH JOB* ALL OF THE MONITOR ING for CHLOROTHENE was done in the warehouse where it is USED TO CLEAN PUMP PARTS* THE HIGHEST READING WAS 7*2 PPM, WHICH WAS TAKEN CLOSE TO AN OPEN CONTAINER IN A MILLWRIGHT'S WORK AREA* Monitoring for chlorine, hydrochloric acid, and sulfuric acid WAS CONDUCTED BY SCRUBBING AIR WITH DISTILLED WATER FOR HCl AND SULFURIC ACID, AND WITH 1*0 N NaOH FOR CHLORINE FOR 7"8 HOURS PER SAMPLE* A TOTAL OF 16 SAMPLES WERE TAKEN* Highs in ppm Chemical Stan- dard High/Job Average High/Area Reading Methanol 200 SOT 2*2 Decks above Lewis U* 15*9 1,1,1 Tri- 350 Mtl* CONTRL* 2*0 Warehouse only chloroethane 7*2 Chlorine 1 All <0*01 All <0-01 Hydrochloric Acid 5 OT 0*06 Distillation, grnd* 0*94 Sulfuric Acid *25 All <0*1 K - 350 0-09 -6- DO 101945 CONFTDENTTAL INDUSTRIAL HYGIENE JOB ANALYSIS VERSUS % OF HYGIENE STANDARD Standard 100% 50-100% 25-50% 10-25% <10% Methyl Chloride Vinyl Chloride Methylene Chloride Chloroform Carbon Tetrachloride Methanol Ethylene Dichloride B-TRICHLOROETHANE Dimethyl Ether 1,1,1 Trichloroethane Chlorine Hydrochloric Acid Sulfuric Acid Noise 50 ppm 1 PPM 200 ppm 10 ppm 5 PPM 200 ppm 10 PPM 10 PPM 400 ppm 350 ppm 3 mg/M-3 7 mg/M-3 1 mg/M-3 85 DBA ~ - - 1 - 14 - 14 - 14 - 14 1 13 - 14 - 14 - 14 - 14 - 14 - 14 - 14 - 14 A 18 TOTAL 01 4 2 189 % of TOTAL JOBS 0-00 0.51 2-04 1-02 96-43 Data Based on TWA \r l. -7- DO 101.946 CONFIDENTIAL ENVIRONMENTAL HEALTH SURVEY (NOISE BY JOB) Job Technical Shift Supervisor Operations Specialist Sr* Operations Technician Operations Technician EDO Supervisor EDO Millwright EDO misc* maintenance Loading Coordinator Loader Material Controller EnviRONMENTAL1ST Assistant Chemist Instrument Technician Fitter and Ironworker Electrician Laeorer Secretary Computer Technician Dosimeter Reading (A SCALEjI^i Avg* 1 09 03 03 47 62-c11 11 28 09 18 07 03 07 08 58 ^ 08 32 00 03 DO 101947 CONFIDENTIAL ENVIRONMENTAL HEALTH SURVEY NOISE BY AREA OCTOBER, 1980 Office Control Room Lab Instrument Shop Warehouse Distillation, ground Distillation, upper V-800's (filters) Acid area K-350 area Lewis Unit deck Levels above Lewis Unit Waste Heat Boiler 8 D-l area R-200 8 R-300 E-200 8 E-300 deck River Water pump area Check Tanks (T-804#s 8 T-806's) Check Tanks (T-104's 8 T~101) T/C Load Rack T/T Load Rack (front) T/T Load Rack (back) K-1002 (outside chain area) dBA 52 62 65 61 74-76 84-91 76-89 84-85 83-86 86*90 80-103 76-93 80-85 83-86 79-83 82-87 79-90 78-84 70-72 76 75 92-98 DO 101948 e * CONFIDENTIAL D* Monitoring Equipment Used in the Survey 1. For Chemicals a- Personnel Monitoring DuPont pump, model p-200 Sipin pump, model SP"1 DuPont constant flow sample calibrator for checking FLOW RATES b. Area Monitoring Science pump, model D-200 Bendix pump, model C-115 2* For Noise a* Personnel Monitoring DuPont dosimeter, model D~100 (modified for 85 dba) DuPont dosimeter, model D-285 b. Area Monitoring Edmont-Wilson dosimeter, model 60-510 Dosimeters calibrated on DuPont Audio Dosimeter Cali brator model C-114 -10- DO 101949 confidential Analytical Equipment and Methods used in Survey: 1. For organic vapors collected on charcoal and desorbed with CS-2* Instruments - Varian 3700 with auto-sampler and CDS-111 data system Conditions a* Temperatures 1- injector - 150C 2* detector - 240C 3* column - initial of 100C programmed to 130C b. Carrier gas flow - 25 cc/min c- Column - 20' x 1/8" 0D SP-1000 (10%) on 80/100 SUPELCOPORT d* Range setting - 10-12 e Sample size - 1-5 f* Calibrated weekly, blanks prepared daily 2* For Chlorothene in vapors collected in saran bags Instruments: Hewlett Packard 5730A gas chromatograph with 3390A reporting integrator Conditions a- Temperatures: 1. INJECTOR - 160 2* DETECTOR - 310 3- COLUMN - INITI b* Carrier gas flow - 22 cc/min , c- Column - 5' x 1/8" 0D Porapak R 80/100 D* "A" CONTROLS e- Range setting - 1 f- Sample size - 0*5cc g* Calibrated weekly DO 101.950 OONFTDfTNTrAL -11- 3. For Methanol Vapors in Air Instruments - Varian 3700 with CDS-lll Data System Conditions a* Temperatures 1- injector - 150C 2- detector - 240C 3* COLUMN - 150C operated isothermally b* Carrier gas flow - 42 cc/min c- Column - 3' x 1/8" 0D Porapak N, 80/100 d* Range setting - 10-12 e- Sample size - 0*5 cc drawn from saran bag sample F- CALIBRATED WEEKLY 4- For separation of Vinyl Chloride from Methyl Chloride Instruments - Hewlett Packard 5730A gas chromatograph with 3380A reporting integrator Conditions a* Temperatures 1* injector - 160C 2. detector ~ 310C 3* column - 180C operated isothermally b* Carrier gas flow - 22 cc/min c* Column - 5' x 1/8" 0D Porapak R, 80/100 mesh d* "A" controls e* Range setting - 1 f. Sample size - 1*4 ml -12- 00 101.951. OONFTDfrNTT^l, FILLED IN BY PLANT tm? EMPLOYEE EXPOSURE SUMMARY QUARTER ,i . _BLOCK ltjo ''it d I' I MINIMAL DETECTABLE STRESS CApnAUJj LIMIT AND UNIT YEAR }Cf 'c' 0. I PERSONNEL - J Vp'f AREA * EXCURSION ! JOB NO . i CLASS 01 ! OTT l 02 1 OT 03 ! SOT 3 04 ! OS 05 ! SS 1 AREA/ TASK I ! j | *PT. EQ. "*V tva NO. BASIS SAMPLES 8fw - AVG. y J7.l7.lJ> h)f. 1/^y ] i6 1.0 0.3 <0,1 d.z HIGH 7-- SAMPLE DURATION NO. SAMPLES JL'l. <0,J (9.3 \1 \\ '1 \________ !_________ \\ ! ,\ AVG. HIGH EXCUR. DURATION NO. SAMPLES AVG. HIGH 1; [ &i a ; <5.3 '6.7 i' 1t G6 -1 EDO , - It) 78 13, S \ ... 07 03 :-refc>' 1 09 i C L ij i\. 10 !INSTR 11 |LABORER i 1 i s IV>^ Ifj7J.6 1\ V A.2(; d-i S' fd,l q d,i 7 ^1 i,6 o. 7 \ V 7 Ay 7 ' 12 _ -- i 13 iCOLT MAINT | NON-OS uMJi___ i ' ' 14 i SPEC. _______ 7 i. *0,1 ^4 <6./ j 15 jSECUR. j |f 16 1 MATE CONT ! i| i LOADING 16 | T/C CLNC \ s-- l/l \I2MS | r "* -- __ 7 0.5: ......7. . / > (j 1i --j---------------- J------------ /, r 6 7, 1 \ ( ! MCRSVNONc m7oiV fot.-r. -"V - v 1 1 AREA SAMP 20 i(NO JC) i 7j - \ i iii - i 74 fI 1 * s*^vv* 3 1 2,1 ' 6,7 j ----------------- 11------------ 1----------------- J i _________1_______ 11 ' | ] ! ! i i " --"-- . i' i i; * ..(_ ............. . i _____J____________ ^ 0, 6 Aaa, a j izg j /& !1. 1 1---------------- i 1 1 i( i S1 !1 DO 10195? CONFIDENTIAL * PROTECTIVE EQUIPMENT: (1) Moudibit (2) Pull Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection F ILL.ED xvi o l PLANT C /X/ / BLOCK VC, _STRESS ^'xJJAjLu LIMIT AND UNIT 000/ - f&3/ 1/ 0 < PERSONNEL AREA 1 EXCURSION JOB NO. CLASS 01 OTT AREA/ TASK *PT. EQ. _ TWA NO. BASIS SAMPLES gc -- AVG. HIGH -- SAMPLE DURATION 02 0T 03 i SOT ! 04 i os 05 SS 06 EDO 07 LAB 08 TECH 09 CLER. i^ySf ) J* JFeYlrl*fj*m IAS IXS cd. / (?/ <s~ *0if *0) | *0,1 1 Li (o *o,h 0.1 K A ih *0,1 40.| 7 *0,1 0.1 X (d <0A OA . \......... 5 *()>} 40, | 10 INSTR 11 LABORER 12 SUMMER 13 CONT MAINT NON-OS 14 --S--P-E--C--.:---------15 SECUR. 16 MAIL CONT C 17 .LOADING fv 18 T/C CLNG (i 'Ijl TTV /riLpvr/r 1i----A <T .. </__ *6,1 *D,I <7).j N X -- cOA <0./ i7 *6,1' 40,J .. _ 1- -- -- X |7. Oi i <0// X 1 OA X --- MGRS/N0N- 29 Joi d//.f\ '| (AREA SAMP 20 ! (NO JC) A, V. v ' - . --* v 30 iXyh- /\ - \ - NO. SAMPLES ' AVG. ** EXCUR. NO. HIGH DURATION SAMPLES AVG. HIGH ... . / X C' 3,-Jwv 3 i.r cJl i 1 i i > 2 -t*J\M 3 4.0 A 4 d 11 \ 1 [ 1 l 1 ________i___________ \ I i i i1 61 A } ! *0 . , 1i DO 1 01953 CONFIDENTIAL ii * PROTECTIVE EQUIPMENT: (1) Mouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection FILLED IN BY PLANT tmf EMPLOYEE EXPOSURE SUMMARY QUARTER YEAR 1CI 6^ i/ _BLOCK Y & n ,1 . MINIMAL DETECTABLE STRESS [ fidjn/!LSl^vJ LIMIT AND UNIT GOOZ - k^Of TL-X (O ^ pw^vU^/ 0,, 1 JOB NO. CLASS 01 1 OTT 02 0T AREA/ TASK 03 SOT 04 OS 03 ss 06 EDO 07 03 TE&- 09 CLER. 10 INSTR 11 LABORER 1 12 SUMMER 13 CONT MAIN! NON-OS 14 SPEC. 15 SECUR. t 16 '3l> ,, 16 MATE CONT | [loading, Cj\o Tt/C CLNG \ ] j 1 I'MCRS/NON-. 1 19 !op Cl.}-J,'f. i - AREA SAMP ! 20 (NO JC) 1 *PT. EQ. -- TWA NO. BASIS SAMPLES s-tun AVG. PAX .pAX S' _.al 1 SAMPLE HIGH DURATION /.o \ a.r \ NO. SAMPLES f AVG. EXCUR. HIGH DURATION 1 0112. 'A/w* NO. SAMPLES AVG. HIGH ------- X. j------------ -1---------'-------- 3,7 / 0 ! J > IT ' ' i I, up Pi 10 a.S /) ixx _JL_ d-3 0 OX u? j x s ax (7, 0- 4 j Q.X aW </.s- 0-(, \ \ \ \ ou \ a.3 \ a,3 \ flW ! a]OiH ta kj 3 !i j 1 /.ST .p 3- . / ! , 1i i ii 7 j a. i o. 7 \ --i -- !>s~ i>) j-- i i JP - A 7 ' 'A - - - a,/ au" i_ OX *" i d.x i i 0,3 i i 1 \ \ ii i i : ! i ! i |i l1 [ i. |i *i i\ 'V ^ i i 0 i Co C^ 1 A \ ! cA. ` : j1 1 j jj 1 J\ i; J nn 101954 | CONFIDENTIAL i* * PROTECTIVE EQUIPMENT: (1) Mouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection FILLED IN BY PLANT imp _BLOCK 4(n /Jfo STRESS '/ tTLAOJtJlLfiM Q, MINIMAL DETECTABLE' LIMIT AND UNIT _____ 3 r I PERSONNEL AREA EXCURSION JOB NO. CLASS AREA/ TASK 01 OTT 02 OT 03 SOT 04 OS 05 SS 06 EDO 3 M TEG? * 09 CLER. 10 INSTR 11 LABORER 12 SUMMER 13 !C0NT MAINT NON-OS 14 SPEC. 15 SECUR. 16 MATE CONT .^0 LOADING ` *PT. EQ. TWA NO. BASIS SAMPLsES 8&C AVG. <0,1 t)x)z).S' i -r 0,/ 6' <0, 1 Lr*X) l'S-- Ui`l.7 u.r TV> L a.s* /a </),/ 4 L <0,/ *r <0,j i.igi; 7 <0,/ V <0,j HIGH / <0.1 0,</ SAMPLE DURATION 1 / > NO. SAMPLES <Af 2-Si > 4 0,7 '1 i0/6 ......... 7S . . <0,1 \ <07 7 -- r^Yrr1 mm 7 <0,/ <0,1 Tn - -- if f "T/v-c--urV.urs4 a <0, 1 < 6 J rs7 0,2. 1134? _ _- n //>'! 'MfMXKt1 AREA SAMP ! nf20 1(NO JC) 'MA A L3X-V4I lI { 1 AVG. 1 J HIGH EXCUR. DURATION NO. SAMPLES AVG. HIGH 1! v O.X L ,* i 1 / 7n 0,(ft 1-iTJU. 3 `0,1 <0,1 1 >/ I 1 L 1 \ -- 1 j i- - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - 3^ j< 0 , j 1 < O 1 , 1 1 11 DO 101955 1 CONFIDENTIAL. li 11 -- * PROTECTIVE EQUIPMENT: (1) Mouthbit (2) Full Face (3) Half or Duse Face (4) Air Supply (5) Hearing Protection FILLED IN BY PLANT C Mi f EMPLOYEE EXPOSURE SUMMARY QUARTER YEAR tty BLOCK y 6 ,. t ,L( MINIMAL DETECTABLE STRESS^-Xujl/U^fuX^qi^_LIMIT AND UNIT etooz-a&w M. PERSONNEL AREA EXCURSION JOB NO. CLASS 01 ]OTT '02 OT 03 SOT 04 OS 05 SS 06 EDO AREA/ |TASK ! ; T$y 09 CLER. 10 INSTR ii LABORER 12 SUMMER *PT. EQ. -- TWA NO. BASIS /SAMPLES / -> I i" ,/,xyr L_i 1 \\1 J A. 1 /7^Ci T 6 yo </ I)x)S' ")' 4 & AVG. -- <o, / i i l o, l <.0,1 *6i /' RQ, ] 4flt) <0.1 -- HIGH -- <0>( SAMPLE NO. DURATION 1 SAMPLES I1 k 4(1, i A. \ !\ / _______ 4 QJ i' 1 40. / \ 40>l <o,f <6*1 _ -- ], i. \ AVG. - HIGH '\ > EXCUR. DURATION /) NO. SAMPLES AVG. HIGH X 9. j. ; <6 t! - i a 0. (/1 ol I A/u . 3 1 [1 f1 70tl '<.0,1 !: i ( 13 CONT MAIN! NON-OS 14 SPEC. 15 SECUR. 16 MATL CONT IJ) * 1 ir i J) <0.( A > -- --- 1 *a.| A ' i. i i 1\ - ' 1 \, i1 i \ LOADING^ * 18 T/C CLNG ij^}.s> f 7 40. J *6.1 V - -- |/~ A/ 19 k A AREA SAMP 20 (NO JC) - A, A'I r> 'M-r' '40 ticta /! - i j i i ! ; kt O.oIaa oL -id)*! ; * Ci * , 1 1 \ i f k1 D0 101956 l CONFIDENTIAL ii j * PROTECTIVE EQUIPMENT: (1) Mouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection KILLED IN BY EMPLOYEE EXPOSURE SUMMARY QUARTER YEAR X c ,, PLANT BLOCK H- (? STRESS XOlWw1 MINIMAL DETECTABLE LIMIT AND UNIT 005-5*2/ s' -a^ <foo Q. I - CO O O 1 i JOB NO. ! CLASS 01 i OTT 02 OT 03 I SOT [ | AREA/ TASK PERSONNEL *PT. TWA NO. EQ. BASIS SAMPLES AVG. gu * UXX 3 i*0, 1 <T <0.1 [ AREA i EXCURSION HIGH y SAMPLE NO. DURATION SAMPLES 1 AVG. EXCUR. NO. HIGH] DURATION SAMPLES f AVG. HIGH i *0.1 <0,1 -\ --------------1------------- oLAA*- 2l *o.i ! <o. i ; i j1 05 SS 06 i EDO l G1\*wvutf 07 : HAS-' os i Tufy* 'A" SJ T i.UjlT r --" *0,1 *0,1 -N t <o./ <0J X lb <0>/ *6.1 .X il *6,1 *0,1 b <0.1 ,a.[ > -------------------13!---------------------------------- / A Oiifti. A*.ir.Aa*. 3 11 |<d i i . < & > \ ; i 09 iCLER. 10 |INSTR s" *0.1 -V-- <0,1 <o,i X <o, j j X i i; -------------------1----------- ;------------------i: 11 LABORER 12 SUMMER 13 CGNT MAIN! NON-OS 16 SPEC. 15___ SECUR. 16 IMATL CONT . -- /,S" </ - ,1 -- a <0,1 - *0.1 5-nX | !I - r ,_______________________ \*6>l -- -- i--i . *0,1 *0,1 XX'/ 1 . 1i i ` \ ! i i \ i i . ... '! ^ | 1 i_ ; ii 3P LOADING. IMS 1 <4,1 <0, i > i XT 0,6 JW- ! a 1<oj -*o., is * t/c clng KpilS/N^ 19 t .-aO AREA SAMP 20 |(NO JO) i i - --l V -- a: 1 - XtKii --=* **6T?b* !- iJ ill i 1 i y ! ! !; ii i , ' DO 101957 CONFIDENTIAL i * PROTECTIVE EQUIPMENT: (1) Moutlibit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection FILLED IK BY PLANT ! EMPLOYEE EXPOSURE SUMMARY QUARTER YEAR {L\ 6 t m P PERSONNEL ... _BLOCK v6 STRESS minimal detectable U, LIMIT AND UNIT t>//4-/fffr ,, , . ,. O.o f p'^OCrL AREA EXCURSION ! JOB NO. I CLASS 01 |OTT 02 I 0T AREA/ 1 TASK j *PT. TWA NO. EQ. BASIS SAMPLES - A 8^ * -- i : --i AVG. ^ *Q.0\ HIGH / SAMPLE NO. DURATION SAMPLES i ,X j 03 i SOT 04 I OS 05 1 SS ________ ifA\2T i >01 <0,01 jX p- 1 <d,oi <6,0j ,Y. L <0,61 <6,0 i !'r 06 i EDO x% i 09 iCLER. ! , La^AL I 10 U6 r <0,01 <6,0 \ J,i *0,01 <6,0i\ vX <6,Oi <6,01 X <6,01 10 INSTR 11 LABORER 12 SUMMER 13 CONT MAINT NON-OS 14 SPEC. 15 SECUR. li A 2) l,WS iyA>li l/jT - __ 7 7 {~ - <0,01 -401] 0( <0,01 <6,61! X -- <0,01 la,o\ A _ _ 7^ ! 16 | MATE CONT | /, s~ A 0,61 <6,0! j X 50 :ucLOcAoDINr*Gc-- _ _ _ _ J1UJ 'JJ .Js 7 18 T/C CI.NC ibtetAUj i i "AREA SAMP t '^e^ r^i 1 20 i (NO JC) i i i i ___ .... ! . Vi,| tfXih !__ * *___ ! EXCUR. AVG. HIGH DURATION rr i > 0.o2 SX*" NO. SAMPLES <5s AVG. HIGH --4)161 <-0j6; i! ,1 , | t , ------- i 1 ! 0,4 ei S'AflAT 3 \<6,or <l,o: I 1 !1 ; |1 i ...... Li . 1; 11 il ! ' 'A s [--------------- -------------- 11---------------- i 0*4) i X <6,01 '< 6,61 j !i _______ !______ ! 1 i Oo in,----- C0^tdPw7i"l * PROTECTIVE EQUIPMENT: (1) Moutitbit (2) Pull Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection Lx / i j i`T ,, aittaab / v u too_______ LIMIT AND UNIT 4*94-eec* l / ef 6 ^ d. >- <. V9X& PERSONNEL AREA EXCURSION 11 JOB NO. CLASS 01 0TT _0?-a 0T 03 ! SOT 04 OS AREA/ TASK 05 SS 06 EDO 07 LAB 08 TECH 09 CLER. 10 INSTR 11 LABORER 12 SUMMER 13 C0NT MAINT NON-OS 14 SPEC. 15 |SECUR. 16 MATE CONT M-.X LOADING- 18 T/C CLNG *PT. EQ. -- TWA BASIS NO. SAMPLES -- 5r 1S X (o 4 b S s 5 S --\ 5 _L 5 .-- 5 $ 1 4 4 i 5 3 -- is -- 5 L -- - <4 5 -- AVG. -- HIGH - SAMPLE DURATION NO. SAMPLES EXCUR. AVG. HIGH DURATION (o X (70 X 47 fOl N OX... 01 >. Oh 26 X Ah X X 05 H X X 14 X V . 1 X" XST* -- -- 1 ____________ i___________ Hr 75 X . I --- 01 14 01 x X ---- 1 i | I * 1------1 1 ] *1 MGRS/NON- j(oJ/n^aKj**y-Vyv AREA SAMP 20 (NO JC) ^_-K 1 l" - 111 NO. SAMPLES AVG. HIGH i -- 1 i i i i , : i i l i * i i \| ! i; * PROTECTIVE EQUIPMENT: CD Mouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (3) Hearing Protection DO 101959 CONFIDFNTTAL FILLED IN BY PLANT (L tY\ f PERSONNEL EMPLOYEE EXPOSURE SUMMARY QUARTER YEAR BLOCK 4A I)1!1), . i _ii MINIMAL DETECTABLE STRESS 'Jhi 1/Oilfr^uWntLIMIT AND UNIT ***9-02*4" Oj_l AREA EXCURSION JOB NO. CLASS 01 OTT 02 OT AREA/ TASK *PT. EQ. TWA BASIS NO. SAMPLES AVG. HIGH SAMPLE DURATION NO. SAMPLES AVG. _____ ' O.i HIGH _ EXCUR. NO. DURATION SAMPLES T X/ AVG. HIGH i 03 SOT 0,3 1.7 x T\ t 04 OS 05 SS 06 EDO 07 LAB 08 TECH 0> 1 1.X A / / 0.2- 1*7 */ / 1 ______ 1_____________ 1.1 <6. 1 0</ / YD :k i ! 6,1 1.x -X / 1 1 ---------------------------- j--------------------------------------- 1 1 1 "1 J l 09 CLER. 10 INSTR 11 LABORER 12 SUMMER 13 CONT MAINT NON-OS 14 SPEC. : t t ..... J_____ i i 0,1 <0,1 -- M 4.0,\ i<x y 1*7 A / / 1.7 o/ f -- i 1 1 1. 1 i [ 1i , ... 15 SECUR. 16 MAIL CONT 17 LOADING 18 T/C CLNG MGRS/NON 19 OP AREA SAMP 20 (NO JC) ! i i i ii 1 i i i| i i i i ii i ` 2',6 * 6. [ - * 4). 1 - \X / . 1.7- A / / -- V 4.0,\ > i -1 l \\ i i| Do"101960 r0MFTOENTIAL ----- I> * PROTECTIVE EQUIPMENT: CD Mouthbit (2) Pull Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection FILLED IN BY PLANT EMPLOYEE EXPOSURE SUMMARY QUARTER YEAR (H crr[ P _BLOCK , C/-fc> . , MINIMAL DETECTA STRESS HILIMIT AND UNIT >>02 -y393? a. t PERSONNEL AREA EXCURSION 1 JOB NO. ! CLASS 01 0TT AREA/ TASK. *PT. - TWA 02 0T 03 SOT .'Ay:. 04 OS 05 SS 1 xsf 06 EDO 07 LAB 08 TECH 09 CLER. IIS' i> 10 INSTR 11 LABORER 12 SUMMER t1 13 CONT MAINT NON-OS 14 SPEC. 15 SECUR. -- 16 MATL CONT 17 LOADING 18 T/C CLNG lA'if MGRS/NON 19 OP c.nr. AREA SAMP 20 (NO JC) " NO. SAMPLE DURATION / A /^ru^w. NO. SAMPLES F / 32 AVG. . J.,6 HIGH EXCUR. -- X NO./ " 1 i ! _ _ _ _ _ _ _ _ 1_ _ _ _ _ _ _ _ _ _ J-.l 0.1 /. 3 2.1 M 6.1 6.1 I.S ..hi ISA lie iX ixn / / \X ISA / */ /M & ts.<\ , i isA a / Y 3*> \X ISA / / ______ t*A 1 \ 1 j 1 1 1 l 11 \ ] 1 i : ......... 1 1 1 1 ! i 1i !_ _ _ _ _ _ _ _ _ _ _ 1_ _ _ _ _ _ _ _ _ _ i ril 1_ __ __ __ __ j__ __ __ i i 1 i -- -*1 tsA > -- ` d.r i \- / / i I.2> -- <L% _________ i--r i------------------ >6, 1 hi l - I- 1 i 1; | \ 1 |' i1 1! Li i 00 101961 CONFIDENTIAL. i , * PROTECTIVE EQUIPMENT: (I) Kouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection FILLED IN BY________________________ PLANT tr/j f PERSONNEL EMPLOYEE EXPOSURE SUMMARY QUARTER _ ___ YEAR IQ / J&LOCK T(q STRESS h tjA, DETECTABLE LIMIT AND UNIT 0004 - 3J4S AtAL^n^Lio^ u! AREA EXCURSION JOB NO. CLASS 01 0TT AREA/ TASK *PT. EQ. TWA BASIS ' NO. SAMPLES AVG. HIGH SAMPLE DURATION '7* 2> Aa* NO. SAMPLES /k AVG. -- HIGH - EXCUR. DURATION NO. SAMPLES AVG. HIGH | 02 0T 03 SOT G4 OS 03 SS 1 * _LI . O.Ofo o,oz. d,ol 6,63. /. 32. Ak/ /. 3.2. I,3X X (>3X X j 1 i i 06 EDO o.bS hZX $ / 07 LAB 08 TECH 09 CLER. 6,6 l I`ZX r^r o,ol /.3JL 1 *0,01 |i ]j 10 INSTR 11 LABORER 12 SUMMER 13 CONT MAIN! NON-OS 14 SPEC. 15 SECUR. 16 MATL CONT 6,0 3 6,bZ> -- q>d4 i-ZX hzx X 5 -- X - 1_ 11 ' i --. C6,0l (>Z2 * |i > ! j1 \ 11 \i i: ji > ! 17 LOADING 18 T/C CLNC MGRS/NON 19 OP AREA SAMP 20 (NO JC) l ______ <O.Ql <6.ai 1 i 1 __ J____________ 1i oo 107962 1_____________ ____ <6,61 < 6 li 1| r confidfnttal i t -l 1; * PROTECTIVE EQUIPMENT: CD Mouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection FILLED IN BY plant EMPLOYEE EXPOSURE SUMMARY QUARTER YEAR !Ci'c^ (L fyl P PERSONNEL BLOCK 4ta STRESS MINIMAL DETECTABLE LIMIT AND UNIT 0O0& - 7SS^ 0. JD I /yw,Ll^ Ut AREA EXCURSION JOB NO. 1 CLASS AREA/ TASK 01 OTT 02 OT 03 SOT 04 OS 05 SS 06 EDO 07 LAB 08 TECH 09 CLER. 10 INSTR 11 LABORER 12 SUMMER 13 C0NT MAINT NON-OS 14 SPEC. * 15 SECUR. 16 MATE CONT 17 LOADING 18 T/C CLNG MGRS/NON 19 OP AREA SAMP 20 (NO JC) *PT. EQ. TWA BASIS NO. SAMPLES AVG. SAMPLE HIGH DURATION 7" I 1 l 1 _l \ NO. SAMPLES l (=> /> 1 L 1 ! i [ j i i i ii V AVG. HIGH -- EXCUR. DURATION 0M\ 7------------ 1 QM \/A <6i0bl X <d,Sl\ 0 *53% X <0 *(0)1 DC *d.m om X <o,m ()MK .X cO.fl&l X / / / <0i6Dl x/ <o,mi 0.35V > / / * 5>J3! jV,\ i/ -- "\ 1 \ <4.ffD| X OM sx ---- <0 ,(T&/ <0i5J 1^ ---- NO. SAMPLES 1 AVG. HIGH / ------------1----------------- i j ' i ------------ 1------------------ i 1; i3 i i i i i ------------ 1----------------i | !, t1 D no 0 1019 nftoen 63 TTAl. 1\ * PROTECTIVE EQUIPMENT: (1) Mouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection CMP Uii-i-A iUW UlUi U * I /KtV CAOUKOlUW ) JOB NO. 1 CLASS 01 OTT 1 AREA/ *PT. TWA TASK EQ. BASIS -0.2. OT 03 SOT 04 OS 05 j SS 06 EDO 07 LAB . 08 TECH 09 CLER. 10 INSTR 11 | LABORER ________ _______ i 12 13 SUMMER CONT MAINT MON-OS 14 SPEC. 15 SECUR. 16 t MATE CONT 17 LOADING i1 18 T/C CLNG MGRS/N0N- 19 OP f AREA SAMP 20 (NO JC) NO. SAMPLES AVG. SAMPLE NO, HIGH DURATION SAMPLES EXCUR. NO. AVG. HIGH DURATION SAMPLES AVG. HIGH 7 ~ E . Am-i1 ',!_(o____ ______ _____ 1___ -- <o./ <0. / J < 6.1 j < d, / -- d.zl 1 d,in 0*17 \X 0.2 7 1^1 1 S' /. // // -- ji ... I 1 1 __ LJ___ , i i i i A____ I i <0,1 *a.l <6.1 d .37 X1/ , a >rf 'A 0,7.7 x / j <. o, l 4.6, \ X <&, 1 < 01 / -- o.sy A\ O.ll % _S / <6.f j---0--,-1---7-- 7i 1 1i ~ ^0, l ! 0,31 ^ > / / / ! il : ' 1 \ 4.0* 1 40./ i u__________ i___________ \ \t\ _ -- | j \ X4.0' l <o,i -i___________j________:___________ -- i" i; ii * PROTECTIVE EQUIPMENT: (1) Mouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection DO 101964 CONFIDENTIAL FILLED IN BY___________________________ PLANT P fFj P EMPLOYEE EXPOSURE SUMMARY QUARTER MINIMAL DETECTABLE BLOCK 4 (o STRESS CPdLni-tb j LIMIT AND UNIT ___ YEAR (Q[ SO 0 I PERSONNEL AREA EXCURSION JOB NO. CLASS 01 OTT AREA/ TASK *PT. EQ. -- TWA BASIS NO. SAMPLES -- AVG. ___ HIGH -- SAMPLE DURATION NO. SAMPLES EXCUR. NO. AVG. HIGH DURATION SAMPLES AVG. HIGH 02 OT 03 SOT 04 OS 05 SS 06 EDO 07 LAB 08 TECH 09 CLER. 10 INSTR 11 LABORER 12 SUMMER (AM, ST i) 2J s > i,as o ^.3 3.S" X S' o. 1 3.S V s' 0.x C).l / L> 0.0 /10 06 7'V '/ 0.0 0.0 X (o 6).X on vX 2 <0.1 on 0. S' \A X 4 0.1 M X -- 0-2 JL*, X IX.i vAs ankisJU. 3 XI' 3 ux.x 13 CONT MAINT USAi 1 o.x 0.1 X NON-OS 14 SPEC. 15 SECUR. 16 MATL CONT 17 LOADING 13 T/C CLNG _ /, s' - _ X o.x 6). 3 X 7 l' S. 6 X - * i/V 0.0 2.3 3 A MGRS/NON 19 OP C.fl.T. AREA SAMP 20 (NO JC) - - A o.l 0.0 DO 101965 CONFTDF-N 1 1 AL 11 * PROTECTIVE EQUIPMENT: (1) Mouthbit (2) Full Face (3) Half or Dust Face (4) Air Supply (5) Hearing Protection