Document Dd0yxp96M9K4JR4NBzJO2483N
AXYS METHOD MLA-031 Rev 01
pfos_s i_D2
Forni 1AI2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT 1D:
Sample Collection:
24-Nov-2004 14:30
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
NIA
Contract No.:
4191
Lab Sample ID:
L7415-1
Matrix:
SOLID
Sample Size:
17.0
g (dry)
Sample Receipt Date:
25-NOV-2004
Initial Calibration Date:
17-Jan-20Q5
Extraction Date:
14-Jan-2005
instrument ID:
LC-MS/MS
Analyele Date:
17-Jan-2005
Time: 19:37:42
LC Column ID:
Discovery C16
Extract Volume (mL):
2
Sample Datafile:
PFS5G 004S29
Injection Volume (pL): 15.0
Blank Data Filename:
PFS5G_004S19
Dilution Factor:
N/A
Cal. Vsr. Date Filename: PFS5G 004S26
Concentration U nite:
r>g/g (dry weight basis)
% Moisture:
18.2
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION UNIT
RETENTION TIME
PFOA PFOS
1.61 5.60
0.0061 0.0253
7.32 9.22
LABELED COMPOUND C13-PFOA
LAB F L A G 12
SPIKE CONC.
(ng)
25.0
CONC. FOUND
("9>
26.7
R(%)J
RETENTION TIME
107 7.32
(1) U = not delected (2) R (%) = Percent recovery
M7B7PFD1_2.*t*. 55
Approved by:_
_QA/QC Chemist
11-06-2006 dd-mm-yyyy
CJ[[0 -AJKYS ANALYTICAL SERVICES LTD PLJOif.OlillfilSti WK7,SHWfT.*MU3SK!Hi55-iKrt*SII)i-in
AXYS METHOD MLA431 Rov 01
PFOS_st_D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
24-Nov-2004 15:00
Lab Name: A X YS ANALYTICAL SERVICES
Project Neme:
N/A
Contract No.:
4191
Lab Sample ID:
L7415-2
Matrix:
SOLID
Sample 5tee:
16.2
g
Sample Receipt Date:
25-Nov-2004
Initial Calibration Date:
20-Jan-2Q05
Extraction Date:
19-Jan-2005
Instrument ID:
LC-MS/MS
Analysis Date:
20-Jan-2005
Tima: 20:37:02
L C Column ID:
C18, Zorbax XDB
Extract Volum e fmL):
2
Sample Datafile:
PFS5G_0Q7S5O
Injection Volum e (pL); 15.0
Blank Data Filename:
PFSSG_Q07S38
Dilution Factor:
N/A
Cal. Ver. Data Fllenama: PFS5G_007S46
Concentration U n its:
ng/g (dry weight basis)
%Moisture:
19.5
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
2.45 4.49
0.0082 0.0100
4.93 6.12
LABELED COMPOUND C13-PFOA
LAB FLAG'
SPIKE CONC.
(al
25.0
CONC. FOUND
(og)
20.0
R * ) 12 RETENTION TIME
00.1 4.93
(1) U = not detected (2) R {%) = Percent recovery
14832PFDi_2.XH. S 5
Approved by:
QA/QC Chemist
11-05-2005 tJd-mirvyyyy
A X Y S / \ . l 'v l / \ L _ Y T I O \ | _ S E R V I C E S L T D M. I0X 221?. 70 MILLS ID. WEST. SIDNEY, 11, UNUIV81 359 TEI (2S0) 455-5900 FU (250) 455-5*11
/4 3
AXY5 METHOD MLA-031 Rev 01
PFOS_Si,,D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID`
Lab Name; A X Y S ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Sample Receipt Date:
25-NOV-2004
Extraction Date:
14-Jan-2005
Analysis Date:
17-Jan-2005
Time: 10:56:36
Extract Volume (mL):
2
Injection Volume (pL): 15.0
Dilution Factor:
N/A
Concentration U n its:
ng/g (dry weight basis)
Sample Collection: Project Name: Lab Sample ID: Sarnple Size: Initial Calibration Date: Instrument ID: LC Column ID: Sample Datafile: Blank Date Filename: Cal. Ver. Data Filename: % Moisture:
24-Nov-2004 15:35
N/A
L7415-3
17.D
g
17-Jan-2005
LC-MS/MS
Discovery C18
PFS5G004S30
PFS5G004S19
PFS5G004S26
15.4
COMPOUND
LAB FLAG *
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
2.27 6.22
0.0092 0.0290
7.32 9.22
LABELED COMPOUND C13-PFOA
(1) U = not delected (2) R (%) = Percent recovery
LAB FLAG'
SPIKE CONC.
(no)
25.0
CONC. FOUND
(ng)
23.8
R O D 12 RETENTION TIME
95.1
7.32
i4rerpfDi_i.nl. se
Approved by:
QA/QC Chemist
t1' D5>200S dd-mm-yyyy
AXYS ANALYTICAL SERVICES LTD f.Oin1.?D4SMILLSll.WfSI,SIBNIT,6.C..CJUUMVtl3S8TfLI2S0)655-58001Bid)ISS-SI11
AXYS METHOD MLA-031 R*v 01
pfos_si D2
Form 1A/2
" PERFLUORINATED SURFACTANT ANALYSIS REPORT
CU EN T ID:
Sample Collection:
22-NOV-2004 12:30
Lab Name: A X YS ANALYTICAL SERVICES
Project Name:
N/A
Contract No.:
4191
Lab Sample ID:
L7415-4
Matrix:
SOLID
Sample Size:
15.5
g
Sample Receipt Date:
25-NOV-2004
Initial Calibration Date:
21-Jan-2005
Extraction Date:
21-Jan-2005
Instrument ID:
LC-MS/MS
Analysis Date:
21-Jan-2005
Time: 22:27:19
L C Column ID:
C l 8. ZorbaxXDB
Extract Volume (mL>:
2
Sample Datafile:
PFS5G,008S47
Injection Volum e (pL): 15.0
Blank Data Filename:
PFS5GJJ08S34
Dilution Factor:
N/A
Cal. Var. Data Fllanama: PFS5G_008S43
Concentration Unite :
ng/g (dry weight basis)
KMoiatura
22.5
COMPOUND
LAB FLAG *
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
2.70 5.02
0.0019 0.0147
4.84 6.08
LABELED COMPOUND
C13-PFOA
(1) U = noi detected (2) R (%) = Percent recovery
LAB F L A G 12
SPIKE CONC.
<ng>
25.0
CONC. FOUND
(ng)
20.9
R(% )J
RETENTION TIME
83.5
4.84
133PFD1_2.x1*. Sfi
Approved by:
QA/QC Chemist
11-05-2005 dd-mm-yyyy
^[(9 AXYS A P v J y X L Y T I O S L SERVICES L T D PO tot221. !M5 MIUS to.WEST, SiWIT. O.C., UHU V8L 3S9 TET tSO) 65SSMW FAX (5D) 655-5811
/& s
A X YS M ETHOD MLA-031 Rev 01
PFOS_S1_D2
Fonti 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID'
La Name: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Sample Receipt Date:
25-Nov-2004
Extraction Date:
14-Jan-2005
Analysis Date:
17-Jan-2005
Time: 20:15:18
Extract Volum e (mL):
2
Injection Volume (pL): 15.0
Dilution Factor:
N/A
Concentration Units :
ng/g {dry weight basis)
Semple Collection: Project Name: Lata Sample ID: Sample Size: Initial Calibration Date: Inetrument ID: LC Column ID: Sample Datatile: Blank Data Filename: Cal. Ver. Data Filename: %Moisture:
22-NOV-2004 13:40
N/A
L7415-5
16.6
g
17-Jan-2005
LC-MS/MS
Discovery C18
PFS5Q_004S31
PFS5G_004S19
PFS5G_004S26
16.8
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
1.52 20.0
0.0111 0.0440
7.32 9.22
LABELED COMPOUND C13-PFOA
(1) U = not detected (2) R (%) = Percent recovery
LAB FLAG1
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
21.3
R{%)1
RETENTION TIME
85.2
7.32
14767PFD1_2kI, S7
, ..
,
Approved by:_________________----------------------- --------- QA/QC Chemist
11-05-2005 dd-mm-yyyy
A X Y S A N A L Y T I C A L S E R V I C E S L T D P.. BOX 2219, ?MS MIU5 ED. WEST, SIDM, It., (MUM V813St 111 (250) 1551800 f*t f?50J 455-5811
/(%
AXYS METHOD MLA-031 Rev 01
PF0S_S1_D2
Forni 1A/2
PERFLUORJNATED SURFACTANT ANALYSIS REPORT
C U E NT ID:
Lab Name: AXYS ANALYTICAL SERVICES
Sample Collection: Project Name:
22-NOV-2004 14:35 N/A
Contract No.:
4191
Lab Sample ID:
L7415-6 (A)
Matrix: Sample Receipt Data:
SOLID 25-NOV-2004
Sample Size: Initial Calibration Date:
1B.0 21-Jan-2005
g
Extraction Date:
21-Jan-2005
Instrument ID:
LC-MS/MS
Analysis Date:
21-Jen-2005
Time: 22:40:23
LC Column ID:
CIS, Zorbax XDB
Extract Volume (mL):
2
S empie Datafile:
PFSSG_008S48
Injection Volume (pL): 15.0
Blank Data Filename:
PFS5G_008S34
Dilution Factor:
N/A
Cal. Var. Data Filename: PFS5G_008S43
Concentration Units : ng/g (dry weight basis)
%Molsture
12.4
COMPOUND
LAB FLAG'
CONO FOUND
DETECTION UMIT
RETENTION TIME
PFOA PFOS
0.518 3.40
0.0057 0.0084
4.90 6.12
LABELED COMPOUND C13-PFOA
LAB FLAG1
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
24.6
R(%>*
RETENTION TIME
98.2
4.90
(1) U = noi delected (2) R (%) = Percent recovery
14B33PF01_2.xl*, SS
Approved by:
QAfQC Chemist
1145-2005 (M-mm-yyyy
A X Y S A N A L Y T I C A L S E R N / I C Z E S L T D P.D. SOI 22I9, 2M5 MIUStt.WESl. SIMEY, ( C., UUDIVBL 3SITFE(250) *55-5000FA*(250) *55-5811
AXYS METHOD MLA-031 Rev 01
pfos_si_D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
Contraci No.:
4191
Lab Sample ID:
Matrix:
SOLID
Sample Size:
Sample Receipt Date:
25-NOV-2004
Initial Calibration Date:
Extraction Date:
21-Jan-2005
Instrument ID:
Analysis Date:
21-Jan-2005
Time: 20:19:03
LC Column ID:
Extract Volume (mL);
2
Sample Datafile:
Injection Volume (pL): 15.0
Blank Data Filename:
Dilution Factor:
N/A
Cal. Ver. Data Filename:
Concentration Units :
ng/g (dry weight basis)
%Moisture
CLIENT ID:
22-NOV-2004 14:35
N/A
W G 14833-104
17.5
g
21-Jan-2005
LC-MS/MS
C18, ZcrbaxXDB
PFS5G 008S37
PFS5G_OOBS34
PFS5G_00BS28
13.1
COMPOUND
LAB FLAG1
CONO FOUND
DETECTION UMIT
RETENTION TIME
PFOA PFOS
0.630 3.69
0.0022 0.0117
4.84 6.08
LABELED COMPOUND C13-PFOA
LAB FLAG'
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
25.0
R(% )2
RETENTION TIME
100 4.84
(1) U = not detected (2) R (%) = Percent recovery
14833PFD1_2.nl*, S 3
Approved by:
QA/QC Chemist
11-05-2005 dd-mm-yyyy
A X Y S A N A L Y T I C A L SE R V IC ES L T D P.o BOX719, 20 IUIISRD. WEST, SIDNEY.C., MM Vfl 351TEI (250) 455-5100F*X(2501 455-5B11
AXYS METHOD MLA431 Rev 01
PFOS_S1 D2
Foni 1A/2
" PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
Contract No.:
4191
Lab Sampta ID:
Matrix:
SOLID
Sample Size:
Sample Receipt Date:
25-Nov-2004
Initial Calibration Date:
Extraction Date:
14-Jan-2005
Instrument ID:
Analysis Date:
17-Jan-2005
Time: 20:34:01
LC Column ID:
Extract Volume (mL):
2
Sample Datafile:
Injection Volume (pL): 15.0
Blank Data Filename:
Dilution Factor:
N/A
Cal. Ver. Data Filename:
Concentration U n its;
ng/g (dry weight basis)
%Moisture:
CLIENT ID:
22-NOV-200415:15 N/A L7415-7 (A) 19.1 g (dry) 17-Jan*2006 LC-MS/MS Discovery C18 PFS5G_tKHS32 PFS5G_004S19 PFS5G 004S26 11.4
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.322 3.16
0.0084 0.0163
7.32 9.22
LABELED COMPOUND C13-PFQA
LAB FLAG'
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
26.2
R (%} *
RETENTION TIME
105 7.32
(1) U = not detected (2) R (%) = Percent recovery
147B7PFD1_2.m*. sa
Approved by:_
<? -
_QA/QC Chemist
11-05-2005 dd^trfh-yyyy
# A X Y S ^rvly^LVTICZAL SERVICES LTD P.O. IC)71U N 1 Mills IB. WEST. SHMEY. IX, UtUMYJL3SI m (2501 HS-SWOFAX (750) ASS-5811
/ 9
AXYS METHOD MLA-031 Rev 01
p f o s _s i _D2
F o rm 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Sam ple Receipt Date:
25-Nov-2004
Extraction Date:
14-Jan-2005
Analysis Date:
17-Jan-2005
Time: 17:44:40
Sample Collection: Project Name: Lab Sample ID: Sample Size: Initial Calibration Date: Instrument ID: LC Column ID:
22-Nov-2004 15:15
N/A
WG14767-105 19.0
9 (dry)
17-Jan-2005
LC-MS/MS
Discovery C18
Extract Volume (mL):
2
Sample Datafile:
PFS5G0O4S23
Injection Volume ftiL): Dilution Factor:
15.0 N/A
Blank Data Filename: Cat. Ver. Data Filename:
PFS5G_004S19 PFS5G_004S14
Concentration Units : ng/g (dry weight basis)
% Moisture:
11.5
COMPOUND
LAB FLAG*
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.315 2.65
0.0072 0.0067
7.32 9.22
LABELED COMPOUND
C13-PFOA
(1) U = not detected (2) R {%) = Percent recovery
LAB FLAG1
SPIKE CONC.
(n0l
25.0
CONC. FOUND
(HQ
25.6
R (S)'
RETENTION TIME
102 7.32
W 67PFD1_2.xl*. S4
Approved by:_
QA/QC Chemist
11-05-2005 dd-iTwi-yyyy
A X Y S A N A L Y T I C A L SE R V IC ES L T D M . 0* ??lf, 2M5 MUS K . IWS!, SIH i t I.C., UIUIM vet assIl (2M) liS-SIOO FJUt (MO) (SS-SS11
y/o
AXYS METHOD MLA-031 Rv01
PfOS_si_D2
Form 1A12
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Lab Nam: A X Y S ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Sample Receipt Date:
25-Nov-2004
Extraction Date:
21-Jan-2005
Analysis pate:
21-Jan-2005
Time: 22:53:10
Extract Volume (mL):
2
Injection Volume (pL): 15.0
Sample Collection: Project Name: Lab Sample ID: Sample Size: Initial Calibration Date: Instrument ID: L C Column ID: Sample Datafile; Blank Data Filename:
22-NW-200416:05 N/A
L7415-8
18.7
Qg idry)
21-Jan-2005
LC-MS/MS
C1B, Zorbax XDB
PFS5G_008S49
PFS5G_008S34
Dilution Factor:
N/A
Cal. Ver. Data Filename: PFS5G..008S43
Concentration U n its:
ng/g (dry weigh! basis)
%Moiature
15.1
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.270 1.63
0.0004 0.0053
4.62 6.08
LABELED COMPOUND C13-PFOA
{1} U = not detected (2) R (%) * Percent recovery
LAB FLAG1
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
21.5
R(%>*
RETENTION TIME
86.1
4.62
14833PFD1_2.*ls. S7
Approved by:_
QA/QC Chemist
11-05-2005 dd-mm-ywy
)J[C9 AXYS ANALYTICAL SERVICES LTD Ml.tot221.1015 MILLSto.WfST.SIMfi1C-,CAUDAW35TfL(250)A55-58D#FAXC250)(55 5811
///
AXYS METHOD MLA-031 Rev 01
pfo s_s i _dz
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
22-Nov-2004 11:25
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
N/A
Contract No.:
4191
Lab Sample ID:
L7415-9
Matrix:
SOLID
Sample Sire:
17.1
g
Sample Receipt Date:
25-NOV-2004
Initial Calibration Date:
17-Jan-2005
Extraction Data:
14-Jan-2005
Instrument ID:
LC-MS/MS
Analysis Date:
17-Jan-2005
Tims: 20:52:45
LC Column ID:
Discovery C18
Extract Volum e (mL(:
2
Sample Datafile:
PFS5G_004S33
Injection Volume (pL): 15.0
Blank Data Filename:
PFS5G_004S19
Dilution Factor:
N/A
Cal. Var. Data Filename: PFS5G_004S26
Concentration U n its:
ng/g (dry weight basis)
% Moisture:
20.1
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.965 8.19
0.0096 0.0349
7.32 9.22
LABELED COMPOUND C13-PFOA
{1} U = not detected (2) R (%) = Percent recovery
LAB FLAG'
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
21.5
R<%)'
RETENTION TIME
86.2
7.32
H767PVD1_2,*1. ss
Approved by.
QA/QC Chemist
11-05-7005 dd-mm-yyyy
A X Y S Ah>l>\.LVTIOavL S E R V IC E S L T D to.I0X 2711,2WS MIUS *0. Wist,SIDti,B.C., CANADAVBL 3S TEL (250) SS-StOOfM (250) 455-5111
//z .
AXYS METHOD MLA-031 Rev 01
pfo s_s i_D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
Contract No.:
4181
Lab Sample ID:
Matrix:
SOLID
Semple Size:
Sample Receipt Date:
03-Dec-2004
Initial Calibration Date:
Extraction Date:
19-Jan-2005
Instrument ID:
Analysis Date:
20-Jan-2005
Time: 20:50:05
L C Column ID:
Extract Volume (mL):
2
Sample Datafile:
Injection Volume (pL): 15.0
Blank Data Filename:
Dilution Factor:
N/A
Cal. Ver. Data Filename:
Concentration Unite :
ng/g (dry weight basis)
% Moisture:
CLIENT ID:
30-Nov-2004 12:30
N/A
L7454-1
17.6
g
20-Jan-2005
LC-MS/MS
C18, ZortwxXDB
PFS5G_007S51
PPS5G07S38
PFS5G 007S46
11.2
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.173 1.87
0.0043 0.0139
4.93 6.12
LABELED COMPOUND
C13-PFOA
(1) U = not detected (2) R (%) = Percent recovery
LAB FLAG'
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
26.5
r m*
RETENTION TIME
106 4.93
UB32PFD1_2.ts. SB
Approved by:
------
QA/QC Chemist
11-05-200S iW-mm-yyyy
)][(JA X Y S /Vrvl/KLYTIOKU SE R V IC E S L T D RO.10*2211.ZW5 *IUSIt.ST.SIMIIT,BC.,UMUMVII35)!El(ISO!455*5100 FIX(Z50)455*5111
//3
AXYS METHOD MLA-031 Rev 01
p f o s s i _D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
Contract No.:
4191
Lab Sample ID:
Matrix:
SOLID
Sample Size:
Sample Receipt Date:
D3-Dec-2004
Initial Calibration Data:
Extraction Date:
19-Jan-2005
Instrument ID:
A nalytic Date:
20-Jan-2005
Time: 21:02:52
L C Column ID:
Extract Volume (mL):
2
Sample Datafile:
Injection Volume (pL): 15.0
Blank Data Filenama:
Dilution Factor:
N/A
Cal. Ver. Data Fllaname:
Concentration Unite :
ng/g (dry weight basis)
% Moisture:
CU EN T ID:
30-Nov-200413:10 N/A
L7454-2
18.5
g
20-Jan-2005
LC-MS/MS
C18, ZorbaxXOB
PFS5G_007S52
PFS5G_007S38
PFS5G_D07S46
11.4
COMPOUND
LAB FLAG1
CONC FOUND
DETECTION UMIT
RETENTION TIME
PFOA PFOS
0.758 7.42
0.0076 0.0184
4.90 6.09
LABELED COMPOUND C13-PFOA
LAB FLAG1
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(9)
22.9
R (%}*
RETENTION TIME
91.8
4.90
(1) U not detected (2) R (%) = Percent recovery
1W32PFD1_2.*I*, S7
Approved by:
QA/QC Chemist
11-0^2005 dd-mnvyyyy
A X Y S A N A L Y T I C A L SERVIC ES L T D ffcBOX221?,?M$K*IUS*DWSI.SlOltfY,B.t,(*HMiIL358 tEl(250*55-5800 Ftf(2S0)655 5811
//y '
AXYS METHOD MLA-031 Rev 01
PFOS_S1_D2
Fonn 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
30-Nov-2004 13:35
Lab Name: A X YS ANALYTICAL SERVICES
Project Name:
N/A
Contract No.:
4191
Lab Sample ID:
L7454-3 (A)
Matrix:
SOLID
' Sample Size:
17.5
g
Sample Receipt Date:
03-Dec-2004
Initial Calibration Date:
20-Jan-2005
Extraction Date:
19-Jan-2005
Instrument ID:
LC-MS/MS
Analyst Date:
20-Jarv2005
Time: 21:15:35
LC Column ID:
C18. Zorbax XDB
Extract Volume (mL):
2
Sample Datafile:
PFS5G_007S53
Injection Volume (pL): 15.0
Blank Data Filename:
PFS5GJ007S38
Dilution F actor Concentration Unite :
N/A ng/g (dry weight basis)
Cal. Ver. Data Filename: % Moisture:
PFS5G_007S46 14.6
COMPOUND
LAB F L A G 12
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
1.00 4.78
0.0053 0.0161
4.93 6.12
LABELED COMPOUND C13-PFOA
LAB FLAG'
SPIKE CONC.
(nfl)
25.0
CONC. FOUND
("8)
25.7
R (%)'
RETENTION TIME
103 4.93
(1) U = noi delected (2) R (%) = Percent recovery
14S32PFD1_2.jdi, 56
Approved by:
QA/QC Chemist
11-05-2005 dd-mnvyyyy
)][(A X Y S A N A L Y T I C A L S E R V IC E S L T D PO DDK ?T1Y, 2<H5 MUS Ml. WEST. SIDNEY, 6.C., CMUDUDE IS I TEI (5D) SS S6D0IH (250I 55-ST1
A X Y S METHOO M LA4B1 Rev 01
PFQSjStJ
Form 1A/2
PERFLUORMATED SURFACTANT ANALYSIS REPORT
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Sample Receipt Date:
03-Dec-2004
Extraction Date:
19-Jan-2005
A nalysis Date:
20-Jan-2005
Time: 18:41:17
Sample Collection: Project Name: Lab Sample ID: Sample Size: Initial Calibration Data: Instrument ID: LC Column ID:
Extract Volume (mL): Injection Volume (pLj: Dilution Factor: Concentration U n its:
2 15.0 N/A ng/g (dry weight basis)
Semple Datafile: Blank Data Filename: Cel. Ver. Dele Filename: % Moisture:
CLIENT ID:
30-NOV-2004 13:35
N/A
WG14832-104
17.7
g
20-Jan-2005
LC-MS/MS
C18, Zorbax XDB
PFS5G007S41
PFS5G_007S3B
PFS5G_007S31
14.7
COMPOUND
LAB FLAG *
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
1.21 5.39
0.0047 0.0099
4.93 6.12
LABELED COMPOUND C13-PFQA
(1) U = not detected (2) R (%) = Perceni recovery
LAB FLAG'
SPIKE CONC.
(ng)
25.0
CONC. FOUND
("tl)
24.4
R f l i ) 12
RETENTION TIME
97.8
4.93
14832PFD1_2.xls. S3
Approvedby:.
QA/QC Chemist
11-05-2005 dd-rrm-vy>y
AXYS ANALYTICAL SERVICES LTD ro.noxnii,7085 KillsHD.WEST. SIDNEY, I C,, UN(MV8L3SI IE!(250)655-SMFU{2S0I Wtll
AXYS METHOD MLA-031 Rv 01 p fo s _s i_D2
Fenn 1A/2
PERFLUORINATEO SURFACTANT ANALYSIS REPORT
CUEN T ID: '
Lab Name: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Sample Receipt Date:
03-Dec-2004
Extraction Date:
19-Jan-2005
Analysis Date:
2CKlan-2005
Time: 21:28:19
Ssmple Collection: Project Neme: Lab Sample ID: Sample Size: initial Calibration Data: instrument ID: L C Column ID:
30-Nov-2004 14:00
N/A
L7454-4
18.2
g
20-Jarv2005
LC-MS/MS
C l 8, Zorbax XDB
Extract Volume (ml): Injection Volume (pL): Dilution Factor
2 15.0 N/A
Sample Datafile: Blank Data Filename: Cal. Ver. Data Filename:
PFS5G_007S54 PFS5G_007S38 PFS5O_007S46
Concentration U n its:
ng/g (dry weight basis)
%Moisture:
12.2
COMPOUND
LAS F L A G 12
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0 8S9 4.75
0.0048 0.0181
4.90 6.09
LABELED COMPOUND
C13-PFOA
(1) U = not delected (2) R (%) = Percenl recovery
LAB FLAG'
SPIKE CONC.
ing)
25.0
CONC. FOUND
(ng)
22.0
R(%j*
RETENTION TIME
8B.0
4.90
Ua32PFD1_2.jda. S9
Approved by;
QA/QC Chemist
11-05-2005 dd-mm-yyyy
|[t A X Y S A N A L Y T I C A L S E R V IC E S L T D r.O. BOX 721 ?, 2045 MIIL& IO. WEST. S U M !, BE., CANADA VBL 359 TEL (250) 55 5000 FOX 1250) 055-5911
K7
AXYS METHOD MLA-031 Rev 01
pros st_D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Name: A X Y S ANALYTICAL SERVICES
Project Name:
Contract No.:
4191
Lab Sample ID:
Matrix:
SOLID
Sample Size:
Sample Receipt Date:
0 3 -0 e c -2 0 0 4
initiai Calibration Oate:
Extraction Date:
19-Jan-2005
Instrument ID:
Analyste Date:
20-Jan-2005
Time: 21:41:02
LC Column ID:
Extract Volume (mL):
2
Sample Datafile:
Injection Volume (pL): 15.0
Blank Data Filename:
Dilution Factor;
N/A
Cal. Ver. Data Filename:
Concentration Unita :
rtg/g (d ry w eight basis)
% U o istu ra :
CLIENT ID:
30-Nov-2004 14-25
N/A
L7454-5
16.6
g
20-Jan-2005
LC-MS/MS
C l 8 , Zorbax XDB
PFS5G_Q07S55
PFS5G_007S38
PFS5G_007S46
17.4
COMPOUND
LAB FLAG*
CONC FOUND
DETECTION LiMrr
RETENTION TIME
PFOA PFOS
1.72 8.42
0.0048 0.0209
4.90 6.09
LABELED COMPOUND C13-PFOA
LAB F L A G 12
SPIKE CONC.
<g)
25.0
CONC. FOUND
(no)
23.5
R{%)2
RETENTION TIME
93 9
4.90
(1) U = not detected (2) R (%) = Percent recovery
14832PF01_2.4s.S10
Approvedby:
QA/QC Chemist
11<4)5-2005 dd'flinn-yyyy
4$|[ijftAXYS ANALYTICAL SERVICES LTD r.o.BOt211,!MSMILLSBD.WfST.SIBtET,l.c,CAKMUWH3SBFL(250)155-5800 FU(250)655-5811
AXYS METHOD MLA-031 Rev 01
pfqs_S1_D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Nam: A X YS ANALYTICAL SERVICES
Project Name:
Contract No.:
4191
Lab Sample ID:
Matrix: Sample Receipt Date:
SOLID 03-D6C-2004
Semple Size: Initial Calibration Data:
Extraction Date: Analyala Date: Extract Volume (mL):
19-Jan-20QS 20-Jan-2005 2
Time: 23:49:27
Instrument ID: L C Column ID: Sample Datafile:
Injection Volume (pL): 15.0
Blank Data Filename:
Dilution Factor: Concentration U n its:
N/A ng/g (dry weight basis)
Cal. Ver. Data Filename: %Moisture:
C U EN TID :
30-NOV-2004 14:50
N/A
L7454-6
19.0
g
20-Jan-2005
LC-MS/MS C18, Zorbax XDB
PFS5G_007SB5
PFS5G_007S38 PFS5G_007S60
11.9
COMPOUND
LAB F L A G 12
CONO FOUND
DETECTION UMIT
RETENTION TIME
PFOA PFOS
0.411 4.76
0.0031 0.0076
4.66 6.09
LABELED COMPOUND C13-PFOA
LAB FLAG1
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
25.4
R(%)1
RETENTION TIME
102 4.66
(1) U = not detected (2) R (%} = Percent recovery
14832PFD1_2.nl. S11
Approved by:_
QA/QC Chemist
11-05-2005 dd-mm-yyyy
A X Y S A N A L Y T I C A L SE R V IC ES L T D f.O.BO*2II. MSIllsB.WST. SISU.(.. CAM*W35BTEII50) 15S-5!00 F riOl 4SS-5S1I
m
AXYS METHOD MLA-031 Rev 01
pFos_st_D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID;
Lab Name; AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Sample Receipt Date:
03-Dec-2Q04
Extraction Date:
19-Jan*2005
Analysts Date:
21-Jan-2005
Time: 0:02:30
Extract Volume (mL):
2
Sample Collection: Project Name: Lab Sample ID: Sample Size: Initial Calibration Date: Instrument ID: L C Column ID: Sample Datafile:
30-Nov-2004 15:15
N/A
L7454-7 (A)
17.4
g
20-Jan-2005
LC-MS/MS
C18, Zorbax XDB
PFS5G_007S66
Injection Volume (pL): Dilution Factor: Concentration U n its:
15.0 N/A ng/g (dry weight basis)
Blank Data Filename: Cal. Ver. Data Filename; %Moisture:
PFS5G_007S38 PFS5G_007S60 13.8
COMPOUND
LAB FLAQ '
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.957 5.80
0.0056 0.0096
4.93 6.12
LABELED COMPOUND
C13-PFOA
(1) U - not detected (2) R (%) = Percent recovery
LAB FLAG*
SPIKE CONC.
<0)
25.0
CONC. FOUND
(ng)
22.6
R(% )J
RETENTION TIME
90.5
4.93
i 3 2 p f d i_2.*h . s i2
Approved by:
QA/QC Chemist
11-05-2005 dd-mn-yjfyy
A X VS ANALYTICAL SERVICES LTD KI.OI!1.204iIUSItll.i[SI,SIOM,I.E.,CM*DIVlL3STEl(SOUS5-58(IOfUt?SO)i55 5tl
Z
AXYS METHOD MLA-031 Rev 01
pfo s_s i D2
Forni 1A/2
PERFLUOR1NATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Sample Collection:
30-Nov-2004 13:35
Lab Name: AXYS ANALYTICAL SERVICES
Project Name:
N/A
Contract No.:
4191
Lab Sample ID:
WG14832-105
Matrix;
SOLID
Sample Size:
17.5
g
Semple Receipt Date:
03-Dec-2004
Initial Calibration Date:
20*Jan-2005
Extraction Date:
19-Jan-2005
Inetrument ID:
LC-MS/MS
Analysis Date:
20-Jan-2005
Time: 18:54:04
LC Column ID:
C18, Zorbax XDB
Extract Volume (mL):
2
Sample Datafile:
PF35G007S42
Infection Volume (pL): 15.0
Blank Data Filename:
RFS5G_007S38
Dilution Factor
N/A
Cal. Ver. Data Filename: PFS5G_007S31
Concentration Unit* :
ng/g (dry weight basis)
% Moisture:
14.1
COMPOUND
LAB FLAG'
CONO FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.686 3.31
0.0071 0.0163
4.86 6.09
LABELED COMPOUND C13-PFOA
LAB FLAG'
SPIKE CCMC.
(ng)
25.0
CONC. FOUND
(ng)
14.6
R<%|'
RETENTION TIME
58.5
4.86
(1) U = not detected (2) R (%) = Percent recovery
i4832PFDi_2.xls. S*
Approved by:.
QA/QC Chemist
11-05-2006 dd-mm-yyyy
);[{A X Y S A N A L Y T I C A L S E R V IC E S L T D M.BOX22, 2D1i MUSRD.BRI,SIBK,IC-,[MUMV81S8 lit1250)*55-5800 FMt(250)5-SSH
nt
AXYS METHOD MLA-031 Rev 01
p fo s_s i _o2
Form 1A12
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Lab Name: A X Y S ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Sample Receipt Date:
03-Dec-2004
Extraction Date:
19-Jan-2005
Analyale Date:
21-Jan-2005
Time: 0:15:17
Extract Volume (mL):
2
Injection Volume (yL): 15.0
Dilution Factor:
N/A
Concentration U n its : ng/g (dry weight basis)
Sample Collection: Project Name: Lab Sample ID: Sample Size: Initial Calibration Data: Instrument ID: L C Column ID: Semple Datafile: Blank Data Filename: Cal. Var. Data Filename: % Moisture:
01-Dec-2004 14:20 NEA
L7454-6
1B.0
g
20-Jan-2005
LC-MS/MS
C18, Zorbax XDB
PFS5G_007S67
PFS5G_007S38
PFS5G_007S60
6.63
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.206 6.28
0.0036 0.0139
4.90 6.09
LABELED COMPOUND C13-PFOA
(1) U = not detected (2) R (%) = Percent recovery
LAB FLAG1
SPIKE CONC.
("0)
25.0
CONC. FOUND
In)
24.3
R (%)*
RETENTION TIME
97.4
4.90
U832PFDi_2.xfci. S13
Approved by:
QA/QC Chemist
11-OS-2DQS dd-mm-yyyy
K' A X Y S A h ' 4 / av L Y T I O `M _ S E R V I C E S L T D P.0. BOX221?. ?M5 Mitts N. WESI. SIDNEY, I.C, UMD4 HI 3Si III (ISO) SiS-SMDFH (ISO) 655-5SH
AXYS METHOD MLA431 Rev 01
p fo s _$i_d2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Name: A X YS ANALYTICAL SERVICES
Project Name:
Contract No.:
4191
Lab Sample ID:
Matrix:
SOLID
Sample Size:
Sample Receipt Date:
03-Dec-?004
Initial Calibration Date:
Extraction Data:
19-Jan-2005
Instrument ID:
Analysis Date:
21-Jan-2005
Time: 0:28:00
L C Column ID:
Extract Volume (mL):
2
Sample Datafile:
Injection Volume (pL): 15.0
Blank Data Filaname:
Dilution Factor:
N/A
Cal. Ver. Data Filename;
Concentration U n its:
ngJg (dry weight tresis)
% Moisture;
CLIENT ID:
Ol-Dec-2004 15:20
N/A
L7454-9
20.3
g
20-Jan-2005
LC-MS/MS
C18. Zorbax XDB
PFS5G 007S68
PFS5G_007S38
PFS5G_007S60
11.1
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.279 2.66
0.0051 0.0081
4.93 6.09
LABELED COMPOUND
C13-PFOA
(1)U=notdetected (2) R {%) = Percent recovery
LAB FLAG'
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
25.9
R(%)J
RETENTION TIME
103 4.93
t4S32PFD1_2.)(l*, S14
Approved by:
QAjTQC Chemist
11-05-2005 dd-mm-yyyy
#!l0 AXYS ANALYTICAL SERVICES LTD P.O. BOX??19. 7645 JWILSMJ. WS1, STDNET. IXCUULD4 VSI3$8 TEL{J0} SS-StOO rW(250)-6SS-581I
AXYS METHOD MLA-031 Rev 01
PFOS.S1 EM
Form 1A/2
PERFLUORINATED SUR FACTANT ANALYSIS REPORT12
CLIENT ID:
Sample Collection:
16-Dec-2G04 13:05
Lab Name: A X YS ANALYTICAL SERVICES
Project Name:
N/A
Contract No.:
4191
Lab Sample ID:
L7503-1
Matrix: Sample Receipt Date:
SOLID 21-Dec-2004
Sample Size: Initial Calibration Date:
16.3 21-Jan-2005
g
Extraction Date:
21-Jan-2005
Instrument ID:
LC-MS/MS
Analysis Date:
21-Jan-2005
Time: 23:05:52
L C Column ID:
C18, Zorbax XDB
Extract Volume (mL):
2
Sample Datafile:
PFS5GEKJ8S50
Injection Volume (pL): Dilution Factor:
15.0 N/A
Blank Data Filename: Cal. Ver. Data Filename:
PFS5G_008S34 PFS5G.008S43
Concentration U nit*:
ng/g (dry weight basis)
M oistu re
23.1
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA pros
3.63 5.24
0.0090 0.0208
4.B6 6.06
LABELED COMPOUND C13-PFOA
LAB FLAG'
SPIKE CONC.
(ns)
25.0
CONC. FOUND
<ng)
19.8
R(%)*
RETENTION TIME
79.0
4.86
(1) U = not detected (2) R {%) = Percent recovery
14S33PFD1_Z.ld*. SB
Approved by:
ClA/QC Chemist
11-05-2005 dd-mm-yyyy
A X Y S A N A L Y T I C A L S E R N / I C T E S L T D tO. MX 2119, 20 Allis IB. WEST, SUBNET, I.C., DIMMML 3SI TEL(250! 555JM FK (2S0) 65S-5B11
AXYS METHOD MLA-031 Rev 01
p fo s _s i_D2
Forra 1A/2
PERFLUORINATEO SURFACTANT ANALYSIS REPORT
CU EN T ID:
Sample Collection:
16-Dec-2004 14:04
Lab Name: AXYS ANALYTICAL SERVICES
Project Name;
N/A
Contract No.:
4191
Lab Sample ID:
W G14833-105
Matrix:
SOLID
Sample Size:
18.3
g
Semple Receipt Data:
21-Dec-2004
Initial Calibration Data:
21-Jan-2005
Extraction Date:
21-Jan-2005
Instrument ID:
LC-MS/MS
Analysis Date:
21-Jan-2005
Time: 20:31:47
LC Column ID:
C18. ZorbaxXDB
Extract Volume (mL):
2
Sample Datafile:
PFS5G008S38
Infection Volume (pL): 15.0
Blank Data Fllenama:
PFS5G_008S34
Dilution F actor
N/A
Cal. Ver. Data Filename; PFS5G__008S28
Concentration Unite:
rg/g (dry weight basis)
%Molsture
12.1
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.167 2.88
0.0001 0.0038
4.88 6.12
LABELED COMPOUND C13-PFOA
LAB FLAG'
SPIKE CONC.
(ns)
25.0
CONC. FOUND
<nfl>
22.4
R(% )2
RETENTION TIME
89.7
4.86
{1) U = not detected (2) R (%) * Percent recovery
H833PFD1_2.S, 34
Approved by:.
-- ________ QA/QC Chemist
11-15-2005 dd-mrTV'yyyy
*)'>[($ AXYS a n a l y t i c a l SERVICES LTD rc.Bmrzm.ms #tsmi.west,simr, tc.ramm m 3Sm am us-unom am ismm
AXYS METHOD MLA-031 Rev 01
PFOS_S1 02
Form 1A/2
PERFLUORIMATED SURFACTANT ANALYSIS REPORT
Sample Collection:
Lab Name: AXYS ANALYTICAL SERVICES
Pn>|ect Name:
Contract No.:
4191
Lab Sample ID:
Matrix:
SOLID
Sample Size:
Sample Receipt Date:
21-Dec-2004
Initial Calibration Dete:
Extraction Date:
21-Jan-2005
Instrument ID:
Analysis Date:
21-Jan-2005
Time: 23:18:36
L C Column ID:
Extract Volum e <mL):
2
Sample Datafile:
Injection Volume (pL): 15.0
Blank Data Filename:
Dilution Factor:
N/A
Cal. Ver. Data Filename:
Concentration Units :
ng/g (dry weight basis)
'Moisture
CLIENT ID:
16-Dec-2004 13:11
N/A
L7503-2
19.0
g(dry)
21-Jan-2005
LC-MS/MS
C18, Zorbax XDB
PFS5GJM8S51
PFS5G_008S34
PFS5G 008S43
10.6
COMPOUND
LAB FLAG*
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.239 3.61
0.0005 0.0087
4.84 6.08
LABELED COMPOUND C13-PFOA
LAB FLAG*
SPIKE CONC.
()
25.0
CONC. FOUND
(f*9)
24.9
R (%) *
RETENTION TIME
99.6
4.84
(1) U = not detected (2) R (%) = Percent recovery
148WPFD1_2j<1*, SB
Approved by:_
QA/QC Chemist
11-05-2005 cW^tmvyyyy
AXYS Arvl/VLVTICAL SERX/ICES LTD PO BOI lti,W5AllisMLSI, SIDNIT Bt.CUttDAll SI TtlIKOI45SSHOO1(ISO) tss-stlI
A X Y S M ETHOD MLA-031 Rev 01
p fo s_s i _D2
Form 1A/2
PERFLUORINATED SU R FACTAN T ANALYSIS REPORT12
Lab Name: AXYS ANALYTICAL SERVICES
Sample Collection: Project Name:
Contract No.: Matrix:
4191 SOLID
Lab Semple ID: Sampla Size:
Sample Receipt Date: Extraction Date: A nalysis Date:
21-Dec-2004 21-Jan-2005 21-Jan-2005
Time: 23:31:19
Initit Calibration Date: Instrument ID: L C Column ID:
Extract Volume (mL): Injection Volum e (pL); Dilution Factor: Concentration Units :
2 15.0 N/A ng/g (dry weight basis)
Sample Datafile: Blank Data Filename: Cal. Ver. Data Filename: %Molstura
CLIENT 10: '
16-Dec-2004 13:40
N/A
L7503-3
16.5
g
21-Jan-2005
LC-MS/MS
C18, Zorbax XDB
PFS5G008S52
PFS5G_008S34
PFS5G_008S43
20.8
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
1.30 3.09
0.0001 0.D1G1
4.88 6.12
LABELED COMPOUND C13-PFOA
(1) U = not detected (2) R {%) = Percent recovery
LAB FLAG*
SPIKE CONC.
(hfl)
25.0
CONC. FOUND
(ng)
19.9
R(%)*
RETENTION TIME
79.4
4.86
14B33PFD1_2.xll, S10
Approved by:
QA/OC Chemist
1'1-05-2005 dd-mm-yyyy
AXYS ANALYTICAL SERVICES LTD f.O,sot721?,2045MillsID.WES1,SIDNEY. UMMffltasfm[150155-5IMFIX(150)i55-5tn
/Z7
AXYS METHOD MLA-031 Rev 01
pfos_s i_D2
Forai 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
Sample Collection:
LebName: AXYS ANALYTICAL SERVICES
Contract No.:
4191
Matrix:
SOLID
Project Name: Lab Sample ID: Sample Size:
Sam ple Receipt Date: Extraction Date: Analysis Dats:
21-Dec-2004 21-Jan-2005 21-Jan-2005
Tim#: 23:44:03
Initial Calibration Date: Instrument ID: LC Column ID:
Extract Volum e (mL): Injection Volume (pL):
2 15.0
Sample Datafile: Blank Data Filename:
Dilution Factor:
N/A
Cal. Var. Data Ftlenama:
Concentration U n its:
ng/g (dry weight basis}
`/Moisture
CLIENT ID: '
16-Dec-2004 14:04
N/A
L7503-4 (A)
17.7
g
21-Jan-2005
LC-MS/MS
C18, Zorbax XDB
PFS5G 008853
PFS5G_008S34
PFS5G_008S43
12.2
COMPOUND
LAB FLAG*
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.189 3.53
0.0041 0.0098
4.88 6.12
LABELED COMPOUND C13-PFOA
(1) U = not detected (2) R (%) - Percent recovery
LAB FLAG'
SPIKE CONC.
(ng)
25.0
CONC. FOUND
(ng)
21.8
R(%)*
RETENTION TIME
87.2
4.86
1483P F D 1 ,2 .I,S1 1
Approved by:
QA/QC Chemist
11-05-2005 ctt-mm-yyyy
A X Y S /AIVI/\LVTKZ>\L SERVICES LTD PC 101 2719. 2045 MILLSID. WIST. SIDNEY. II.. MHUUV8L1SI FU 250) ISS 5100 FJt (7SD) SS-51I
AXYS METHOD MLA-031 Rev 01
pfo s_s i _D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Lab Name: A X Y S ANALYTICAL SERVICES
Contract No.:
4191
Matrlx:
SOLID
Sample Collection: Project Neme: Lab Sample ID: Sample Size:
16-Dec-2QD4 14:10
N/A
L7503-5
15.9
g
Sample Recelpt Date: Extractlon Date: Analysis Date: Extract Volume (mL): Injection Volum e (pL): Dllutlon F actor Concentraron U n it i:
21-Dec-2004
21-Jan-2005
21-Jan 2005
Time: 23:56:46
2
15.0
N/A
rig/g (dry weight basis)
Initial Calibration Data: Instrumanl ID: LC Column ID: Sampla Datafile: Blank Data Filename: Cal. Ver. Data Filename: %Motsture
21-Jan-2005 LC-MS/MS C1B, ZorbaxXDB PFS5G.008SS4 PFS5G_006S34 PFS5G_008S43 20.1
COMPOUND
LAB FLAG1
CONO FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
1.81 6.66
0.001 s 0.0189
4.66 6.12
LABELED COMPOUND C13-PFOA
(1 ) U * not detected
(2) R (%) = Percent recovery
LAB FLAG*
SPIKE CONC.
(nfl)
25.0
CONC. FOUND
(ng)
21.8
R(% )J
RETENTION TIME
87.0
4.86
WB33PFD1_2nH. $12
Approved by:
QA/QC Chemist
11-05*2005 (kf-mm-yyyy
fij p A X Y S A N A L V T I C A . L S E R V I C E S L T D F.S. MX H it, IM S IMILS n . Wist, SHHET. I.C., IMMtVSl VX Iti CIMI) t S H M FU 5 SS-S8U
AXYS METHOD MLA-031 Rev 01
PFOS_Si_D2
Form 1A/2
PERFLUORINATED SURFACTANT ANALYSIS REPORT
CLIENT ID:
Lab Name: A X Y S ANALYTICAL SERVICES
Contract No.:
4191
Sample Collection: Project Name: Lab Sample ID:
16-Dec-200414:38 N/A L7503-6
Matrix:
SOLID
Sample Sbe:
16.0
g
Sample Receipt Date:
21-Dec-2004
Initial Calibration Date:
21-Jan-2005
Extraction Date:
21-Jan-2005
Instrument ID:
LC-MS/MS
Analysis Date:
22-Jan-2005
Time: 0:09:29
LC Column ID:
C l 8, ZorbaxXDB
Extract Volume (mL):
2
Sample Datafile:
PFS5GJJ06S55
Injection Volume (pL): 15.0
Blank Data Filename;
PFS5G_008S34
Dilution Fector: Concentration Unit* :
N/A ng/g (dry weight basis)
Cal. Ver. Data Filename: %Moleture
PFS5G_008S43 19.6
COMPOUND
LAB FLAG'
CONC FOUND
DETECTION LIMIT
RETENTION TIME
PFOA PFOS
0.952 7.10
0.0029 0.0289
4.84 6.08
LABELED COMPOUND
C13-PFOA
(1 ) U = not detected
(2) R (%) = Percent recovery
LAB FLAG'
SPIKE CONC.
(i*9>
25.0
CONC. FOUND
l"9)
18.7
R(%)>
RETENTION TIME
74.9
4.84
1833PFD1_2 *fe, s o
Approved by:
QA/QC Chemist
11-05-2005 dd-mm-yyyy
AXYS ANALYTICAL SERVICES LTD ro.BDxni*, !0is u s nwa,siimi,c.UWMvL3S *k u s w h s -im f isohss-sbu
