Document DY7Zvog4vrwoqqVygYed4JN5
RSV 0014923
60-600.00
TABLE OF CONTENTS
600.00 MATERIAL SPECIFICATIONS. STORAGE, HANDLING & TESTING
601.00 MATERIAL SPECIFICATIONS
601.10 Raw Materials
601.101 601.102
601.103 601.104 601,105 601.106 601.107 601.108 601.109 601.110 601.Ill 601. 112 601.113 601.114
Acrylamide Ammonia 'Ammonium persulfate Butylated hydroxy toluene Ethylene Ferric Amnonium Sulfate Methanol Mono methyl ether hydroquinone Sodium formaldehyde sulfoxylate Sodium hydroxide Sodium lauryl sulfate Tetrasodium ethylene diamine tetraacetate Tetrahydrofuran Vinyl chloride
601.20 Finished Goods
601.201 601.202 601.203
Latex B Latex BH Latex E
602.00 ANALYTICAL METHODS
602.10 Sample Schedule 602.20 Methods
Rev. 3/15/72
-1RSV 0014924
MONSANTO COMPANY D(0tMC CXIMCtLI DIVIWON
RAW MATERIAL
1 MAT CHI. L COOK
: 10440
IrtlMO OtPTO. 840.60
SPECIFICATION
MAT(t(AL ACRYLAMIDE CH|MC>L *6*MUL*
American Cvanamide
0
II ch2 -chcnh2
mol r. 71. 1 upcnatoit Mia op NEW
I4MPLI POR 4M4LTIII 1x8 ounce WM Bottle
TEST
LIMITS
On each lot
Appearance Assay Melting range
Solubility (207. aqueous solution)
Color Turbidity
White pelletized solid 96X min
83-86*C
APHA 30 max. Essentially clear
Uoon Reouest
Iron Moisture Sulfate (as S04")
40 ppm max. 0.87. max. 1.5Z max.
60-601.101 Approvals:
??rz
Mfg. Representative M. E. Gibbs
Research Gt. Leader L. P. Bosanquet
METHOD
602.431 602.433 602.244 602.245
602.449 602.246 602.247
8/9/71
CONFIDENTIAL
RSV 0014925
. .*
MONSANTO COMPANY ON*M< ei*MC ALf DIVWIOM
RAW MATERIAL SPECIFICATION
AMMONIA CMiaeu roffHuki
nh3
MW VT.I7 0 lUAIMMI VICI
NEW
TEST
nk3, * Moisture, X Cil, ppm Iron, ppm Sulfur Chlorides, ppm Na20, ppm
! 12150
| mim ocpti. I 840.60 i suwi(a
Monsanto,
Texas
City
1 liter pressure bomb
LIMITS
MIN MAX
99.5 0
0.5
5 0.5 NIL
1 1
60-601.102 Approvals:
Mfg. Representative M. E. Gibbs
Research/Cr. Leader L. P. Bosanquet
METHOD
n/9/71
CONFIDENTIAL
RSV 0014926
MONSANTO COMPANY MANIC CNtHKAb* MVM40N
SAW MATERIAL SPECIFICATION
AMMONIUM PERSULFATE Cx(M(H re*HUL
UtfltUl COOK 12540
ll UHM DKPTK. < 840.60
FMC
(NH4)2S20b
Not -T. 228.2 luAIMINI MCI or NEW
TEST
SAMPkt PM AMkTIII 1 x 16 ounce WM Bottle LIMITS
Assay Active oxygen content
98.07. min. 6. 87. min.
60-601.103 Approvals:
^r/
_____
Mfg. Representative
M. E. Gibbs
lesearch /Jr. Leader L. P. Bosanquet
METHOD 602.435 602.248
8/9/71
CONFIDENTIAL
RSV 001*927
MONSANTO COMPANY
*MC CMMCIU MVMtON
RAW MATERIAL SPECIFICATION
TMUL COOK
16050
I UKIMK DKHTft.
840.60
Shell (IONOL CP-40)
M*TC*I*W
BUTYLATED HYDROXY TOLUENE
CNKMCAW
HOW HT. 220.4 lUKttMMI OICI or NEW
1x8 ounce WM Bottle
TEST
LIMITS
Appearance
407. emulsion
Specifications for purified crystals
Purity Solidification point,
c
Color, Pt-Co, 301 v solution in acetone
99. OX 69.4 min. 15. max.
Ash, X w. max.
0.002
60-601.104 Approvals:
j&M*'_____ Mfg. Representacive M. E. Gibbs m.^Sa. iM.JResearch Gr. Leader L. P. Bosanquet
METHOD
8/9/71
CONFIDENTIAL
RSV 0014928
ORSARTO COMPANY ** twuftu owwioii
AW MATERIAL SPECIFICATION
ETHYLENE CNMKAL
1 32550 i UOtMO OO^T*.
840.60
Monsanto. Texas Citv
c2h4
MOL OT. 28.0 IUPIIHMI MIC! OP
NEW
TEST
IllMlI POP ANALYSIS 1 liter pressure bomb
LIMITS
Upon Request
Ethylene
99.85% min.
Impurities:
Acetylene
Cerbon dioxide Carbon monoxide DMF Hydrogen Methane Ethane Methanol Water Nitrogen Oxygen Propylene + Heavier Sulfur
. %0 0002 max.
0.0005% max. . %0 0002 max. . %0 0001 max. . %0 0100 max. 0.15 % max. 0.15 % max. 0.0005% max. 0.002 % max. 0.050 % max. . %0 0002 max. 0.002 % max. . %0 0001 max.
60-601.105 Approvals:
)?L
Mfg. Representati' M. E. Gibbs
Research Gr. Lead* L. P. Bosanquet
METHOD
602.016 <GC)
602.016 (GC) 602.040 (GC) 602.041 (GC) 602.332 602.042 602.016 (GC) 602.016 (GC) 602.331 (GC) No Method 602.041 (GC) 602.041 (GC) 602.043 (GC) No Method
CONFIDENTIAL
RSV 0014929
MONSANTO COMPANY M44MC CMlMCAbl OiVMIOM
RAW MATERIAL SPECIFICATION
` 33600 it uiim oc m. ' 840.60
1 Mallinckrodt
FERRIC AMMONIUM SULFATE CNIMCtL *OMUk*
Fe(NHa)(SO*)s * I2H20
Mot *t480.9
IU*IIINI VICI or NEW
MIPII rom AMALV4I* 1x8 ounce WM Bottle
TEST
LIMITS
Appearance
Colorless to pale violet with some brown discoloration
Chloride (as Cl")
. %0 01 max.
Odor
Odorless
Assay
99% min.
60-601.106 Approvals:
m / aj4 Mfg. Representative M. E. Gibbs
Research G/. Leader L. P. Bosanquet
METHOD 602.431
602.440 602.249 602.436
a/*/"7i
CONFIDENTIAL
RSV 0014930
MONSANTO COMPANY MlAMC (HUM ALS DtVtftlOW
RAW MATERIAL SPECIFICATION
NtTtHUL
METHANOL____
CHtMCtL retMUL*
-________
CH30H
MOL *T. 32. 0 urcntCOBt *Ri OR
NEW
1 uaiMO o<RTk I 840.60 I BURRLICR
Celanese
lilPLI roo AMALVM
60-601.107 Approvals:
'?K
Mfg. Representative M. E. Gibbs
i P(j%rA*A*rjiiJuf*~
Research G^. Leader L. P. Bosanquet
TEST
LIMITS
METHOD
X Methanol
99.857. min.
Color - Pt Co
5 APHA max.
Acidity (Acetic Acid) 0.003 wt. 7. max.
Permanganate time
50 minutes min.
Acetone
0.003 wt. X max.
Odor
Characteristic - free of foreign odors
Water Appearance
0.10 wt. Z max. Clear & free of suspended matter
8/9/71
CONFIDENTIAL
RSV 0014931
MONSANTO COMPANY miimc cHietu eivniM
RAW MATERIAL SPECIFICATION
> COOC
1 mum dc art. 840.60 IVMLIII Eastman
MONO METHYL ETHER HYDROQUINONE (MIMICAL rMMULA
CH3OC0H4 OH
124.13 urcaacoc* v(ci or
NEW
TEST
Appearance
AMPLl roc AMALTIII 1x4 ounce WM Bottle
LIMITS
White crystals
Melting point, *C
54-56
Boiling point, *C Flash point, *C
246 132
Fire point, *C
135
60-601.108 Approvals:
Mfg. Representative M. E. Gibbs
P(j)cAl*<-LLuf'
P.esearch Gi. Leader L. P. Bosanquet
METHOD
8/9/71
RSV 0014932
CONFIDENTIAL
MONSANTO COMPANY 0A6AMC cnimciu eivnioN
RAW MATERIAL SPECIFICATION
52652 .1 IMtMS OCATt.
840.60
| Rohm & Haas
SODIUM FORMALDEHYDE SULFOXYLATE (NlwCtl PQAMULA
NaHSOs CH20 - 2H*0
154.1 IUMMIOII rCCS or
NEW
ilAtril POM AMALlit ! 1 x 8 ounce WM Bottle
TEST Appearance
LIMITS White solid
Ash Assay
Report (16.57. Typical)
97.0 to 101. 17.
Odor
Odorless to faint garlic-like odor
60-60L.L09 Approvals:
Mfg. RepresenCacive M- E. Gibbs IX P&fildrtTpLLt/'___ Research Or. Leader L. P. Bosanquet
METHOD 602.431 602.434
602.437 602.249
8/9/71
RSV 0014933
CONFIDENTIAL
MONSANTO COMPANY
MIWC CHtMCAkl OtWttlOn
RAW MATERIAL SPECIFICATION
CAUSTIC CMIMICAk re*MUL
i 18610 (507.) J IMIM OC^Tt.
J 840.60 SU#lblC [ Monsanto, Texas
City
60-601.110 Approvals:
Mfg. Representative M. E. Gibbs
NaOH
^0HOI. WT.
WIG*IUPIMIBII
or
HEW
TEST
Appearance
Assay, wt.% as NaOH
Iron, ppm Chlorides, wt. % Sulfates, wt. 7. Carbonates, wt. % Color, APHA
Research Or. Leader L. P. Bosanquet
Ull>l PM IMbTIII
1x8 ounce NM glass bottle with polyseal cap
LIMITS
METHOD
Clear to milky liquid free of suspended matter
602.212 (WC)
24 min.
602.063 (WC)
3 max. 0.6 max. 0.02 max. 0. 15 max. 100 max.
602.657 (WC) 602.659 (WC) 602.660 (WC) 602.658 (WC) 602.009 (WC)
e/9/7i
M M IMV. /*
CONFIDENTIAL
RSV 0014934
MONSANTO COMPANY MUM( (MMCAU OtVtMM
RAW MATERIAL SPECIFICATION
liMTnub ease
k 52902 j kMtM OBVTk '840.60 1 lUMvian
I Proctor & Gamble
SODIUM LA.URYL SULFATE chimcUi (oawLt
NaC12H2sS04
wbt. 288 #4 luMMIMI (MCI OW
NEW
UWII row AMkHII 1x8 ounce WM Bottle
TEST
LIMITS
On each lot
Appearance
Clear liquid, free of sediment
Assay (Alkyl Sulfate)
29.0% min.
pH (10% solution)
8.0 (Typical)
Upon request
Free fatty alcohol* 1.0% max.
Inorganic salt
1.0% max.
Iron
1.0 ppm max.
Cloud point
12C max.
60-601.Ill Approvals:
Mfg. Representative M. E. Gibbs
'f
Research r. Leader L. P. Bosanquet
METHOD
602.432
602.438
602.250
602.251 602.440, 602.247 602.449 602.441
8/9/71
im m imv. aw
CONFIDENTIAL
RSV 0014935
J
MONSANTO COMPANY OIWC tn--fill MVWOM
RAW MATERIAL
32710 1 UIIM Mm.
i 840.60
SPECIFICATION
Dow Chemical Company
WTt*lkL
TETRASODIUM ETHYLENEDIAMINE TETRAACETATE CMCkMCAk POMMWC*
380.2
lufiMioii --tea or NEW
PON AMAUTSIt 1x8 ounce WM Bottle
60-601.112 Approvals:
Mfg. Representative M. E. Gibbs
f Research G. Leader L. P. Bosanauet
TEST
LIMITS
METHOD
On each lot
Appearance
White powder, free of foreign 602.431 particles
Chelation value @ pH 11
215 mg CaC04/gram min.
602.439
pH (101 aqueous solution)
10.5 to 11.5
602.250
Upon request
Heavy metals (Pb)
Color (30X aqueous solution)
Odor (301 aqueous solution)
20 ppm maximum 500 AFHA maximum No NHa odor
602.448 602.442 602.249
8/9/71
CONFIDENTIAL
RSV 0014936
MONSANTO COMPANY
ommhmc tMMttu nie
RAW MATERIAL SPECIFICATION
TBTRAHYDROFURAN
CMSMFCAL FORMULA
C4HaO
>Lot. 72.1 lUFIDMMl aOECS OF
NEW
TEST
On each lot
Appearance
Color
Distilling range:
1st drop 95% over
Specific gravity <? 25/25*C
| MATERIAL CODE
! 58380
I UIW MPT*.
840.60 WAfkll* -P^Ponc
AMPLE FOO AMALTtlS 1x8 ounce Bottle LIMITS
Clear liquid APHA 20 max.
65.5C min. 66.7*C max 0.880 to 0.883
Udoq request
Acetone
Hydroxyl (as Isopropyl alcohol)
Moisture
Peroxide (as THF-peroxide)
. %0 10 max. 0.25% max.
0.03% max. 0.015% max.
60-601.113 Approvals: Xf. * Mfg- Representative M. E. Gibbs ^ft(7$cAa*nJuLf~ Research Gt.Leader L. P. Bosanquet
METHOD
602.432 602.442 602.443
602.444
602.447 602.447
602.445 602.446
8/9/71
CONFIDENTIAL
______________
RSV 0014937
MONSANTO COMPANY MAtWC CMBHKAU OlVWeN
RAW MATERIAL
SPECIFICATION
U>T(ltL Vinyl Chloride CMCHIOL
62300 | UIIM OC^Tft. j 840.60
1 Dow
60-601.114 Approvals:
%
Mg
Mfg. Representative M. E. Gibbs
mol *t.62.5 New
CH2 - CHC1
IMVLI re* AMAIY1IS
x1
8
oz.
glass
sample bomb
test
Appearance
LIMITS
Clear, colorless, free of suspended matter
cf PQo'Z&Ar-tiAJ-J'" Research Qf. Leader L. P. Bosanquet
METHOD Visual iobservation
Acidity <hs HC1), ppm by weight
Aldehyde, ppm by weight
Iron, ppm by weight
Non-Volatile matter. Z by weight
Phenol, ppm by weight
1 max 5 max. 0.5 max.
0.1 max. 0.1 max.
602.343 (WC) 602.344 (WC)
Dow 6 602.639 (WC)
Sulfur (as S), ppm by weight
Water, % by weight
5 max. 0.03 max.
Dow 10 Dow.11
Hydrocarbons
Acetylene, mol ppm Butadiene, mol ppm Total all others,
mol ppm
2 max. 2 max. 10 max.
602.628 (GC)
Chlorinate Hydrocarbons
Methyl Chloride, mol ppm
Ethyl Chloride, mol PENS
Total all others. mol ppm
25 max. 10 max. 10 max.
602.626 (GC) RSV 0014938
8/9/71 CONFIDENTIAL
MONSANTO COMPANY Industrial Chern. Co.
RAW MATERIAL SPECIFICATION
iAk coec
UWM SCAT*. 840.60
CHEMLIME CORP.
LIME SLURRY (CHEMLIME)
CMlMClIi PO<*MWk*
CALCIUM HYDROXIDE (95%)
MQk t.
uransaoet i*ie* or
BMS--977-3
PROPERTY
4/1/69
Calcium Hydroxide Calcium Oxide Equiv. Calcium Carbonate Magnesium oxide R2O3(PejO^ and AL2O3) Insolubles Minimum Solid
iuwa roo AKAkTSIB
SPECIFICATION (Typical)
93 - 95%
72%
1.5% .25% 1.6 1.1 35.0%
Sieve Analysis:
Retained by No. 10 - 0% By Wt. " " No. 30 - .25% By Wt. H " No. 200 - .5% By Wt.
Loss on Ignition - 23.4%
None
60-601.115
TESTS None Normally
Performed
5/12/72
RSV 0014939
MONSANTO COMPANY
rooouer coos
UtB
jocrT. on joo
840.61
finished PRODUCT SPECIFICATION
lALU COM
moouCT iTKM rumm
TTP
T-ATEX
fwoosiCT
B____nmmm)
Tt
ETHYLENE/VINYL CHLORIDE/ACRYLAMIDE LATEX
CMMCtL rORMULA
MOL WT.
(uRinion vici or
a/9/7i
MMTLI POM AUkTIII
1 .x 16 oz. WM Bottle
60-601.201
APPROVALS:
ssz&L
-______________
R. T. Haaasann Mfg. Supervisor
'j. L. Rasmus s en
,^ ^ ^Mfg. Superintendent
22
----
R. W. Flint Guest Superintendent
Suu
M. E. Gibbs Research Group Leader
S '} :-::U .
L. D. Shand
Product Manager
TEST
UNRESTRICTED SALES LIMITS
% Total Solids
48.0%, Min.
Viscosity (cp)
25-200
PH 7.0 - 8.5
% Grit
0.05%, Max.
Uoon Recroest Surface Tension (dyne/cm)
Tg (C)
Intrinsic Viscosity
Particle Size, A
Instron Tensile Stress(lb/in2) Elongation (%) 100% Modulus (lb/in2)
% Acrylamide
% VCM
Film Clarity
INTERNAL CONTROL LIMITS 48.0 - 50.0 25-300 7.0 - 8.6 0.05%, Max.
40-45 8-16 0.6, Min. 650-900
800, Min. 400, Min. 200, Min. 2.7 - 3.2 74 - 77 Clear
METHOD 602.255 602.256 602.257 602.258
602.259 602.260 602.261 602.262 602.263
602.264 602.265 602.266
3/13/72
RSV 00149*0
CONFIDENTIAL
- v>l 7
MONSANTO COMPANY Texas City
PHOOUCT COO
use
lOOPT. OO JO#
1 840.62
FINISHED PRODUCT SPECIFICATION
AkU eooc
pmogucT (TiaPi
LATEX BH
POOOUCT fftllMl MMMj
ETHYLENE/VINYL
TTM
tTM
CHLORIDE/ACRYLAMIDE LATEX
CNBMCAL PONMUIA
UOl WT.
WMMtSII IPICI OP
8/9/71
IAMPLI POO AHAkTIII
1 x 16 oz. WM bottle
60-601.202
*47APPROVALS: . s. R. T. Hammann Mfg. Supervisor
. d! ' L. Rasmussen
Mfg. Superintendent
R. W."Flint Guest Superintendent
7 M. E. Gibbs Research Group Leader
L. D. Shand Product Manager
UNRESTRICTED
INTERNAL
TEST________________________
SALES LIMITSCONTROL LIMITS
METHOD
% Total Solids
46.0% Min.
46.0 - 49.0
602.255
Viscosity (cp)
40 - 1500
40 - 1500
602.256
PH % Grit
9.5 - 11.0 0.05% Max.
9.5 - 11.3 0.05% Max.
602.257 602.258
Upon Request IGT
602.267
3/13/72
RSV 0014941
confidential
MONSANTO COMPANY Texas City
MOOUCT eooc WM
loaPT. e* jom 840.63
FINISHED PRODUCT SPECIFICATION
ULU CODS
moouct
LATEX E
OOUCT fOwllll
fT*I
ETHYLENE/VINYL CHLORIDE/ACRYLAMIDE LATEX
CmMCL FMMUk*
k VT.
whwmi tnu op 8/9/71
1 x 16 oz. wm Bottle
60-601.203
APPROVALS: '4.*' R. T. Hanunann Mfg. Supervisor
J. L. Rasmussen
Mfg. Superintendent
R. W. Flint
77? _ _Guest Superintendent
If. E. Gibbs
Research ;Group Leader
-If j \
I:
rSr* r*
Shand
TEST % Total Solids Viscosity (cp) PH % Grit
UNRESTRICTED SALES LIMITS 49.0%, Min. . 25 - 150 7.5 - 9.0 0.05%, Max.
INTERNAL CONTROL LIMITS 49.0 - 51.0 25 - 250 7.5 - 9.0 0.05%, Max.
METHOD 602.255 602.256 602.257 602.258
xypon Request Surface Tension Tg (*C) Intrinsic Viscosity
Particle Size (A0) Inatron
Tensile Stress(lb/in2) Elongation (%) 100% Modulus (lb/in2)
% Acrylamide % vex Film clarity
40 - 44 (-3) - (+2) 0.57 - 0.77 650 - 900
50 - 150 2100 - 2500 20 - 60 2.5 - 2.9 66 - 71 Clear
602.259 602.260 602.261 602.262 602.263
602.264 602.265 602.266
3/13/72
RSV 0014942
CONFIDENTIAL
SAMPLE SCHEDULE
Sample RAW MATERIALS
Acrylamide
Armenia
Frequency Each lot
. Upon Request Upon Request
No. of Samples
Size
Lab
Analysts
Expected Range
Test Method
I1
tI
16 oz.
Appearance
Assay Me 1 ting Range Solubl111 y
Colur Turbidity
Iron Moisture Sulfate (as SO4)
Nil 3 % Moisture Oil Iron Sul fur Chlorides Na20
!1i i te pe 1 1 et 1 zed solid
967. min.
B3-B6`C
APHA 30 max. Essentially clear | 40 ppm max
0.87. max. 1. 57. max. t1 99.57. min 0.5% max. 0-5 ppm
0-0. 5 ppm Nil 0' 1 ppm 0'1 ppm
602.4.11 602.433 602.244 602.24 5
602.449 602.246 602.24 7 1 )
Ammon lum Persulfate
Each Lot
8 oz.
Assay Active
98.07. min 6.8% min.
602.435 6 0 2 . 24 8
Butylated Hydroxy Accept Vendors Certificate of Analysts Toluene
O f 209*05
RSV 0 0 1 4 9 4 3
t
60-602.10
uuuuu
X 40-NN<0<0-*< /'O'-i f3v* INNcNoNoMM^NNN
^ ^^ ^ ^^ ^^
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Xo Xo Xo
S x(B xfl Qx x x3
a xa x
-
E E EE
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we
6
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M9SlA 0(M 3-CC l^^0A90Nj*O! --
-- ul ui m
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u a> --
0 83 9 --
--X X0
oc -- 5 a/ e "3 E
ca -- e e -->. u>.x00x
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4-
E
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an e o c BO C -- 4.
fcrio a c ft O 4/ >. 3
U
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>1 o --
Vv
O wg X
X X bJ 2 O CU U1
UK .
a ---- x
ma 3 -a sg 0oj c.
--u e
4> --
uo --i 3o eo K-- --u E
u DS
41 u c 4.
& O. < 5<
E -- a
H 4.
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3 3 *M
M1/1 ^<2C8e--e4/o < a 4i 4i
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u 8--O2"--3 E u 4.
0. 0.
M oncnethyl e th e r A ccept Vendors C e rtific a te o f A n a ly s is
H ydroqulnone
4/ N XT.
01 u 6 <5
O
>. u c 4) !3T 41 U
4/ C 4/ > Xu bj 7/30/71
N 0
co I
c o
J4I u
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a 4; 3
C4/
X
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-2-
RSV 0014944
KSV 0 0 1 4 9 4 5
Samp I <_
Frequency
ta Sodium Formaldehydes Each lot P Sulfoxylate
No. of Samples
Size
' 8 oz.
! Caustic
Upon Request
j
1
8 oz.
Sodium Lauryl Sul fate
Each lot
Upon Request
Tetrasodlum Ethy lene diamine Tetraacetate
Each lot
Upon Request
8 oz. 8 oz.
Lab
Ana lysis [Appearance
1 Ash
Assay Odor
Expected Range
White Solid Report
(16.57. typical) 97.0 - 101.1% Odorless to faint
garllc-tlke odor
Test Method
602.431 602.434
602.437 602.249
Appearance
,Assay I ron Chlorides Sul fates
Carbonates Color
Clear, free of pensions
247. min. 3 ppm max. 0.6 wt. X max. 0.027 max. 0.15% max. 100 APHA max.
sus-
602.212
602.063 602.257 602.659 602.660 602.658 602.009
Appearance
Assay (Alkly Sulfate)
pll (10% solution)
Clear liquid, free of sediment
29.0% min.
8.0
Free fatty alcohol inorganic salt Iron Cloud point
1.0% max. 1.0% max. 1.0 ppm max. 12 C
602.432
602.438
602.250
602.251 602.440 6 602.247 602.449 602.441
Appearance Chelation value
pH (107. Aq)
White Solid 215 mg CaCO-j/gram
minute 10.5-11.5
Heavy metals
20 ppm max.
Color (30% Aq. Sol.) 500 APHA max.
Odor (30% of sol.) No NH3 odor
602.431 602.439
602.250
602.448 602.442 602.249
o r 209-09
?/30/7i
Sample
Frequency
T
Tetrahydrofuran
Upon Request
No. of Samples
Size 8 oz.
Lab
Analysis
Expected Range
Appearance Color Distil 1lng Range
1st drop 95% over
Specific gravity <3 25"C/25*C
Clear Liquid APHA 20 max.
65. 5C min. '66.7*C max. 0.880 to 0.883
lest Methods
602.432 602.442 602.443 602.444
i
: 4- RSV 0 0 1 4 9 4 6
60-602.10
I
-5- RSV 0 0 1 4 9 4 7
7/30/71
Sample
Frequency
FINISHED PRODUCT IN PROCESS
Latex B
Upon Request (interlm)
No. of Samples l
Latex B Latex Bll
Each Batch (final prod) and
Each Packout Lot
Upon Request (in* terlm #1) *
2x 1
Size
Lab
Analysis
Expected Range
Test Methods
16 oz.
16 oz. 16 oz.
% Solids VlscosIty pH Surface Ten Tg Intrinsic Vis. Part. Size % Acrylamide % VCM Film Clarity Instron
Ten 811e elongation 100% modulus
47.5-50.5 (7.) 25-200 (Cp) ! 7.6-8.6 ' 40-45 dyne/cm 11-19 *C 0.6 min. 650-850 A* 2.7-3.2 7. , 74-77 7. Clear
800 lb/ln2 min.
400 7. min. 200 X min.
X Solids Viscosity PH Grit
48.0-50.0 25-200 ! 7.6-8.6 0.05% max.
602. 255 602 . 256 602. 257 602 . 259 602 . 260 602 . 261 602 . 262 602 . 264 602 . 26S 602 . 266 602 . 263
602 255 602 256 602 257 602 258
% Solids Viscosity pH Surface Ten
Tg Intrinsic Vis. Part. Size % Acrylamide % VCM Instron
Tens 1le ElongatIon 100% modulus
47.5-50.5 (%) 25-200 (Cp) 7.6-8.6 40-45 (dyne/cm) 11-19 (C) 0.6 min. 650-850 A* 2.7-3.2% 74-77%
800 lb/in2 min. 400 % min. 200 % min.
602 . 255 602 . 256 602 . 257 602 . 259 602 . 260 602. 261 602 . 262 602 . 264 602 . 264 602 . 263
o r *09-09
RSV 0 0 1 4 9 4 8
Sample Latex Bll i Latex Bll Latex E
Latex
Frequency
Upon Request (Interlm #2)
No. of Samples L
Each Batch (final prod) and
Each Packout Lot
Upon Request
Upon Request (interlm)
2x 1 l 1
Size 16 oz.
16 oz. 16 oz. 16 oz.
1 l
Each Batch (final prod) and
Each Packout Lot
(
;
2xi
16 oz.
Lab
Analysis
Viscosity pH Solids
Solids
PH
Viscosity Grit
1GT
Solids ' Viscosity | PH
| Surface Ten
? Tg , Intrinsic Vis. | Part. Size % Acrylamide
X VCM Film Clarity Instron
Tensile Elongation 100 % Modulus
Solids Viscosity
pll Grit
Expected Range
40-60 cp 10.2-11.2 46.0-49.0 7.
46.0-48.0 X 10.2-11.2
40-1000 cp 0.05Z max.
200-260
48.0-51.0 X 25-150 8.0-9.Q 40-44 (-2)-(+3)0C 0.55-0.77 650-850 A* 2.5-2.9 X 66-71 % Clear
50-150 lb/ln2 2100-2500 X 20-60 lb/ln2
TesL Methods
602.256 602.257 602.255
602.255 602.257
602.256 602.258
602.267
602.255 602.256 602.257 602.259 602.260 602.261 602.262 602.264 602.265 602.266 602.263
48. 5-5U. 57. 25-150 cp
8.0-9.0 0.057. max.
602.255 602.256
j 602.257 602.258
0 IT 0 9 -O 9
Sampl e
Frequency
MAKEUP SAMPLES | Aqueous Solution
Upon Request
ACRYL-SLS Solutior Upon Request
Spent Solvent (THF)
Upon Request
207. Caustic
Upon Request
No. of Samples
Size
Lab
Analysis
Expected Range
Test Methods
8 oz. 8 oz. 8 oz.
8 oz.
SLS Cone.
7. ACRYL 7. SLS
Peroxides % water % solids
% Na( H
0. 095-0. 125 7.
20-351 B.5-13.57.
None 6-97. 0-2%
i 18-22%
602*268
602.251 602.254
602.446 602.445 602.255
602.252
Vinyl Chloride
Upon Request
8 oz.
Mon. l.ab.
Acidity, wt.
1 ppm max.
Aldehyde, wt.
5 ppm max.
Iron, wt.
0.5 ppm max.
Non-volatiles, wt7.' 0.1 max.
Phenol, wt.
0.1 max.
Sulfur, wt.
5 max.
Water, wt. %
0.03 max
Hydrocarbons
Acetylene, mol
2 ppm max.
Butadiene, mol
2 ppm max.
Total al 1 others. 10 ppm max
mo 1
Chlorinated Hydrocarbons Methyl Chloride, mol Ethyl Chloride, nio 1 Tot a 1 all others. mo I
25 ppm max. 10 ppm max. 10 ppm max.
i
602. 34 3 (WC) 602.344 (WC)
Dow 6 602.639 Dow 10 Uow t 1 602.628
(WC) (CC)
602.626 (CC)
l
60-6C 2.10
RSV 0014949
602.20 TEST METHODS Index of Test Methods
Raw Materials Color-caustic CH4., C2H2 C2H4 , CsHs C02 in ethylene CO in ethylene H2 in ethylene Propylene and heavier NaOH assay Appearance - caustic Melting Range Solution Appearance Moisture - Karl Fischer Sulfate Active oxygen Odor pH (raw materials) VCM Overhead Composition Caustic Composition by Gravity
7/19/71
1-
60-602.20
Method No. 602.009 (WC) 602.016 (GC) 602.040 (GC) 602.041 (GC) 602.042 (GC) 602.043 (GC) 602.063 (WC) 602.212 (WC) 602.244 602.245 602.246 602.247 602.248 602.249 602.250 602.251 602.252
RSV 0014950
602.20 (cont1d)
Raw Materials Percent Acrylamide - Bromination Percent Alkyl Sulfate SLS Concentration Iron in VCM Methanol in ethylene Appearance of Solids Appearance of Liquids Assay - Acrylamide Ash Assay - APS Assay - FAS Assay - SFS Assay - SLS Chelation Value Chlorides Cloud Point Color of Liquids, Melts, and Solutions
60-602.20
Method No. 602.253 602.254 602.268 602.289-A 602.331 (GC) 602.431 602.432 602.433 602.434 602.435 602.436 602.437 602.438 602.439 602.440 602.441 602.442
7/19/71
-2-
ftSV 0014951
602.20 (cont'd) Raw Material Distilling Range Specific Gravity Moisture - THF Peroxide - THF Carbonyl and Hydroxyl Compounds - THF Heavy Metals Iron Iron - caustic Carbonates - caustic Chlorides - caustic Sulfates - caustic V.CM Heavy End Impurities VCM Light End Impurities Phenol in VCM Acidity in VCM Aldehydes Product Percent total solids Latex Viscosity Latex pH
7/19/71
-3-
60-602.20
Method No. 602.443 602.444 602.445 602.446 602.447 602.448 602.449 602.657 (WC) 602.658 602.659 602.660 (WC) 602.626 (GC) 602.628 (GC) 602.639 (WC) 602.343 (WC) 602.344 (WC)
602.255 602.256 602.257
RSV 0014952
602.20 (cont1d) Raw Material Percent Grit Surface Tension Gears Transition Temperature Intrinsic Viscosity Particle Size Instron Tests Percent Acrylamide - Kjeldahl Percent VCM Film Clarity IGT Test
60-602.20
Method 602.258 602.259 602.260 602.261 602.262 602.263 602.264 602.265 602.266 602.267
7/20/71
-4-
RSV 0014953