Document DMy49YyVv5xj4J8J8zoOwZezn
Government
-pvc -Ft/*
Conflicting views on vinyl chloride coalesce
Industry decrtst OSHA'*
no'detectdblo leva! rula
as unnecessarily harsh;
both labor and ACS
support proposed standard
Mere mentioning of the word* vinyl chloride to Occupational Safety and Health Administration official* who presided over public hearings on the agency's proposed permanent work place standard for the chemical may well lead to muttering* that enough is enough. In nine days, the officials lis tened to 35 hours of direct testimony by 44 panels of witnesses--and many additional hours in question and an swer sessions--and received 89 written submissions for the hearing record. Much of the data presented OSHA is conflicting. All this is of little comfort to the officials as OSHA has until Oct. 5 to come up with its final version of a permanent standard.
It's likely that OSHA may well pick some middle ground standard--tougher than that proposed by industry, softer than that initially proposed by the Government--which, if either labor or industry is unhappy about it. may well be challenged in the courts anyway.
Data presented at the hearings tend ed to coalesce, in effect, into two posi tions: that of industry and that of Gov ernment-labor-ACS. For instance, a spokesman for the Society of the Plas tics Industry maintained that OSHA's proposed work-plate standard--which, among other things, calls for a no-de tecta ble level of vinyl chloride^"is not technologically feasible and. if adopt ed, would shut down the industry." In contrast. Peter Bommarito. president of the United Rubber Workers, said that the "OSHA proposal comes closer to the ideal standard than any yet pro posed or promulgated for any work place hazard."
However. Dr. Daniel P. Boyd, direc tor of the office of standards develop ment for OSHA although emphasizing that the proposed standard is just that--a proposal--said that "it repre sents our best judgment based on the information available on May 10 . .. our present judgment is chat vinyl chloride is a carcinogenic agent." Dr. Boyd pointed out that in protecting employees from a carcinogenic material. "We are operatingin the area of many unknowns.
For example, we do not know the mecha nism by which a chemical carcinogen operates or whether a safe level of ex posure can be set." Much of the testi mony presented at the hearing dealt with industry's, labor's, and research workers' effort to resolve the latter question.
The initial impetus for the vinyl chloride industry came during World War II when it was used as a substitute for natural rubber. According to Dr.
Irving J. Selikoff, professor of medicine at CiV University of New York's
Mount Sinai School of Medicine, "This immediately points to a problem of current vinyl chloride-polyvinyl chlo ride investigation*; the industry is a
relatively young one. and the late ef fects of toxic exposure have only begun to appear; most of our experience is still ahead of us.'* He told the hearings that clinical field studies are being
conducted that include examinations
of more than 1200 vinyl chloride-PVC polymerization, workers. Although all
the results are not yet in. he reportird that studies of 354 current and former workers at Goodyear's plant in Niagara Falla. N.Y., "demonstrated a signifi cant prevalence of liver abnormalities, peripheral vascular changes, and lung abnormalities."
Information on deaths from two plants, one which produces monomer and the other polymer, was presented by Df. John M. Peters of the Harvard
School of Public Health. He said that studies on 161 deceased white males showed "a 50% excess of deaths due to cancer." There was a "60% excess of lung cancer (13 cases with 7.9 expect ed) and a 320% excess of brain cancer (five cases with 1.2 expected) with the
number of liver cancer cases being 10 times those expected in a similar unex posed population. He stressed that these studies, though preliminary, show that multiple cancer sites are in volved and cancer it increasing over time in the population. Dr. Peters agreed with Dr. Selikoff in that he said, "I do not believe we will know the
full cancer-causing potential of vinyl chloride for several years. At this point the only way to assure an end to this
serious hazard is to eliminate the expo sure."
The vinyl chloride-PVC industry, in general, took the opposite view. Harry E, Conners, vice president of Diamond
Shamrock Chemical, told the hearings. "In our judgment the cases of worker illness recently discovered in industry
are the delayed result of conditions that were common many years ago but
are no Longer present in today's plants." Dr. Richard W. McBuraey, corporate medical director of Diamond
Shamrock Chemical, pointed out that "during the early years of PVC produc tion attention was given to vinyl chlo ride vapors only because of the anes thetic qualities and the explosion haz ard- Since the explosion hazard occurs at upward of 30,000 p-p-m. and the an esthetic effect at 1000 to 5000 p.p.m.
the vinyl chloride levels in work areas were undoubtedly quite high."
Dr. Carl U. Dernehl, associate medi cal director of Union Carbide, told the
hearing of a health survey conducted
by SPI covering 16 plants employing 2372 persons whose current work per mits exposure to vinyl chloride, plus
471 who had worked with it in the past. He said that the study identified
1402 men who were exposed to vinyl
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chloride et leest 10 year* ago, of which
416 had a latent period of more than 20
years. Also identified were 737 men ex-
poaed continuously to vinyl chloride for
more than 10 years, with 104 being ex
posed for more than 20 year*- Dr. Der-
nehl said. "Examination* of these men
have failed to show the existence of ab
normal liver function tests in greater
proportion than would be found in
control population. There is no case of
angiosarcoma of the liver among these
men even though their exposure time is
sufficient for the disease to have oc
curred and exposures are believed to
have been in excess of 50 p.p.m." He
concluded that "these data fail to sup
port the need for an exposure level as
drastic as that proposed in the stan
dard."
The SPI survey's findings were sup
ported by Diamond Shamrock. Dow
Chemical. B. F. Goodrich. Tenneco
Chemicals, and Firestone. All reported
that despite extensive surveys of their
current and former vinyl chloride-PVC
workers, no further cases of or deaths
due to liver cancer have been found,
other than the 13 previously reported to
OSHA.
'
Industry also felt that the proposed
standard was too far-reaching. Accord
ing to Anton Vittone, president of B.
F. Goodrich Chemical, "The produc
tion of vinyl chloride, its polymeriza
tion into PVC resin, and the processing
of PVC resin into semifinished or fin
ished products is treated in the pro
posed standard as one industrial health
problem." However, he contended,
"Each is an entirely different operation
posing its own problems, permitting
and requiring different solutions."
Of particular concern to many indus
try witnesses was the inclusion of PVC
processors and fabricators, such is phonograph record makers, under the
proposed standard. Monitoring data on
vinyl chloride exposure in processing
plants were presented by several wit
nesses, including Philip J. Weaver, di
rector of industrial affairs for B. F.
Goodrich. In a conclusion that agreed
with those of other witnesses, be said,
"Our data does not support this con
cept of inclusion of processor opera
tions" under the proposed standard
since "we find no detectable levels of
vinyl chloride in most of the processing
work places."
In addition to urging that fabricators
and processors not be included under
the permanent standard, the Society of
the Plastics Industry proposed that in
viny! chloride and PVC plants there be
a stepped reduction in worker expo
sure.
. -
This is in sharp contrast to the
American Chemical Society position
presented at the hearings by Dr. Ste
phen T. Quigley, head of the Society's
department of chemistry and public af
fairs, and Howard H. Fawcett, chair
man of the ACS Committee on Chemi
cal Safety. ACS, in essence, supports
the OSHA proposed standard, asking
PVC fabricators xhcuW not bo intiadad
under /ft* exposure standard, SPI orges
only that the standard be defined as a minimum practical level capable of de
tection by a recommended method rather than as a no-detectable level.
SPr# proposed standard drew sharp criticism from Anthony Mazxscchi, citizenship-legislative director of the Oil, Chemical and Atomic Workers In ternational Union. He said, "It will be a tragedy if OSHA adapts the so-called 'common denominator kind of stan dard that SPI sponsored. Under this approach a standard is adopted that everybody can meet. But those plants that can go further are under no incen tive, at that time, to do anything more."
Most companies at the hearing: said that although it would be difficult, they could live with SPt's proposed standard. Two companies, however, re ported that they are already operating at much lower levels. Dr. V. K. Rowe, Dow director of toxicological research in health and environmental affairs, said that the company, "is generally operating within an eight-hour timeweighted average (TWA) concentration of 10 p.p.m.; however, brief malfunc tions and other temporary situations
occasionally result in short-term excur sions in excess of 10 p.p.m," And Air Products and Chemicals' John T, Barr reported that his company has an eight-hour TWA in the 20- to 25-p.p.m. range for workers in its poIymeriration building and even lower levels for those in ocher job locations. Tenneco Chemi cals, however, estimated that it would have to spend in excess of $10 million to reach the exposure levels re-com mended by SPI.
Vinyl chloride-PVC industry wit
nesses contended throughout the hear ings that meeting the proposed stan dard was just not technologically
feasible, unless workers wore air-sup plied respiratory equipment all the time. However, Calgon Carp,, vrhieh was moved from 20th to last on the witness list, declared that technology was available to remove vinyl chloride from the air. William Lovett of the company's activated carbon division said that the monomer can readily be adsorbed on activated carbon in con
centrations ranging from t p.p.m. to more than 30% by volume in air. He said laboratory results show that 100% removal of vinyl chloride from air or nitrogen streams ix technically possible using dual bed*.
Earlier in the hearing Tenneco Chemicals testified that it hu carbon adsorption to recover the mono mer from two small process streams, neither of which contains air. in plans for iu new PVC plant in Pasadena. Tex. However, it pointed out that it considers this activated carbon method to be "wholly impractical" where large volumes of air and small concentra tions of vinyl chloride are involved.
Mr. Bom martto expressed the belief that the standard can be met. saying that where "engineering controls may not be applicable, personal protective equipment can be used." He added that especially in newer plants the problem is "characterized try the will, not the ability, to do the job." He con cluded that "the medical (acts are in and the problem ia now in the social and political arena."
International
U.S. reactor design loses out in U.K.
U.S. reactor design has lost out in its bid for the next generation of nuclear power stations in the U.K. The British government has opted instead for the steam-generating heavy-water reactor (SGHWR) system. The immediate plan is to build three twin-reactor sta tions with an overall capacity of about 4000 Mw. of electricity. The first of these stations should be operating by 1932.
The decision, taken by Eric Varley. U.K. Secretary of State for Energy, bucks the trend in other countries, where planned nuclear power programs center on U.S. designs for light-water reactor (LWR) systems, either General Electrics boiling-water reactor IBWR| or Westinghouse's pressurized-water reactor (PWRI, Indeed, at public hear ings before the Energy Resources Sub committee of the House of Commons Select Committee on Science and Technology last December, both Ar thur Hawkins, chairman of the Central Electricity Generating Board, which supplies power to England and Wales, and Sir Arnold Weinstock. managing director of British General Electric, which has a 50% stake in U.K. Nation al Nuclear Corp., came out strongly in favor of LWR's, primarily because the technology is already proven and can be fairly quickly brought into operation without major design and development effort (C&EN, Feb. 18, page 11).
Mr. Varley cites a number of reasons for deciding on the SGHWR route. "In the government's judgmentrdt will pro vide power reliably and we can proceed
to C4EN July 22. 1974
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