Document DMv4REbdXKov86VyYg0N6ZQvB
Materials
PVDF
PFAS Alternatives in the Proposed Restrictions
EPDM
Silicone
PEEK
Mica
Polyvinyl Polyethylene Ceramic
chloride
Based
PP-SFP-IPD-Ele 23/Aug/2023
Sumitomo Electric Fine Polymer
Flexibility
Semi rigid
Continuous use temperature()
175
Tensile breaking strength(MPa) Tensile breaking elongation(%) Flexural Modulus(MPa) Oil resistance
45 200 800 Excellent
Abrasion resistance Heat Shrinkable Tubing (Shrink ratio)
Excellent Possible (min.50%)
Flexible
90
520 100800
5~10 Poor
Poor Possible (50%)
Flexible
180
312 100500
5~10 Poor
Poor Possible (50%)
Rigid
260
90 50 4000 Excellent
Excellent Possible (1520)
Rigid
500(Mica) 180(Adhesi
ve)
0 10000
Poor (Adhesive) Excellent Impossible
Flexible Semi rigid
100
1550 500100 203000
Possible (min.50%)
Flexible Semi rigid
120
1030 5001000 202000
Possible (min.50%)
Rigid 500
0 10000
Impossible
Comparison of properties between [PVDF] and other PFAS alternatives. Gray shaded cells are issues when substituting PVDF heat-shrink sleeve. Materials with 175 or higher are Silicone, PEEK, Mica and Ceramic. Mica and Ceramic are inorganic, so cannot processed into tubing. Silicone and PEEK are potential candidate, but they have following issues:
PEEKVery stiffsee "Flexural Modulus")Shrink ratio is low SiliconeWeak in mechanical strength (see "Tensile breaking strength"),
oil resistance, abraision Therefore, they cannot be the substitute of PVDF heat-shrink tubing.
Shrink ratio: (D-d)/D *100 (%)
where as D: Inside diameter before shrink d: Inside diameter after shrink
Shrink ratio 50% = 2:1 shrink 67% = 3:1 shrink
before shrink
after shrink