Document DMpX4kZMej5xz9dzBzo0ZJ1Eo

* - XYsi8 rheynRE.SEARCH Attachmen2t AR226~ 1774 Air Sampling Fluorochemical Report [ DuPont Washington Works -- Air Sampling Program Round 9 r Exygen Research Report No. L0001508 ; Testing Laboratory [ Exygen Research 3058 Research Drive | State College, PA 16801 - Michiel D Aucoin Requester | URS Corporation ~ " Barley Mill Plaza g Building 27 Room 1260 = | Lancaster Pike and Rt 141 NT Wilmington, DE 19805 3 38 ~ S | <S ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXXGEN RESEARCH Frieter? CLES! Bion, us Tian, GNO3B?TT eypencom Summary . Seven solid media samples were received by Centre Analytical Laboratories, Inc. (dba Exygen Research) (Exygen) from DuPont Corporation. The media represent samples of air collected on [OVS tubes. Please sce Table1 for a completed listing of samples received and field air volumes collected. `The samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography [ / mass spectrometry (LCMS). The OVS tubes were separated into three fractions for specific fluorochemical analysis. |" Fraction A consisted of the filter, backing material and plastic ring. Fraction B contained the first bed of XAD resin and the PUE backing. Fraction C contained the second bed of XAD ~ resin and PUF backing. Fractions A and B were extracted with 1 mL of methanol. Fraction C |" Was not analyzed but saved for possible future analysis. Perfluorodecanoic Acid (C10 Acid) was added as a surrogate spike to each fraction prior to extraction. Instrument operating conditions can be found at the beginning of cach analytical run. Raw ~ instrument data is given in Appendix A. Chain-of-custody information can be found in [" Appendix B. | ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page20f7 6n0388 f Results Summary [ Air Volume 8 Acid Sampled (1 (mgm3) | VCVAWCAKAASAAMISSTEES9CAE98 11443399 1439 r ------ ---- e CCAAAAUSSZEES AE98 | PsWpARS EOC 11444422 1442 1 Z<o0..0000000077 G0NA0 <00.0000001017 G0NA0 [ VWWHKCAAAAMMSS3SEE995A ICAEUSESC r WAEs022 Tc | WICAARANSSSE058A WHCARMSESC na 13139922 1392 1 11441177 1417 1 <00..0000001017 00N0Ai Z<o00..0000000077 NA Coot |= WHAARIAMSSESE908 [ WCHAAASSSEo(S9TuCa) 14145533 1453 1 <00..0000000077 00N0A074 CWHACAMASSEEESSSA | WKAAMSD5 C [7 SareWeAsSO.i0 Tnotoa)m 11442299 1420 <<00..0000000077 NA n-- p -- eeeeet eensGoo eor I 1. <i defined as not detected at or above the reported level. 2. Sample results have not been corrected for blank results or control spike recoveries | "3. Please note the following descriptions of the OVS sample tbe fractions: | EAC Frit Extract c8 [12sntdssaettbboeaadsseexxttrraacctt (not analyzed) ALLDATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH | Page 3017 cneas9 }, | 2 3 | i 5 cl 292s | iL | i! CHIR [ i 32: i 8s - |||gg ihi SEE fg dfif | 1 | .g <+i3] zi g | || || | Gn0N390 r r Surrogates I Ta [ SAursruorgraotgaetsepsipkiekreec(oCv1e0riAecsiadr)ewgaisveandidnedthteofaollllOowViSngttuabbelse.toTghievreeaarfeinnalocsoentccernittreraitaiofnorosfu5r0ro0gpatpebsipniktehe extract. recoveries. Advisory ranges are 75-125%. f WWKAAMSE8 A 500 504 101 Een 2 | BO| OE f WHA ANS4E9B 500 352 70 | WK AAMSS ESB 500 a7 60 * Surrogate recovery outside of advisory range. ST ! Gn0391 -| | | | ta I [ i Ss99358555ss5s8s . o33% [22cegegeeegocong | BE VYVVRIRIIUSIIVEY | 2 [F | Eisssn gaaisisiig Dog |Ran |3 | ' g| ; 2g :: E zz 0392 I" Banat comune | For sample WWK-A-AMS2-E9 A C8 Acid. = [158 ng/ml of C8 Acid x (1 mlx()1 ug/ 1000 ng)x (1 mg/1000ug)] / [(1442L) x (1 m3 / I- 1000 L)] = 000011mg /m3 Signatures F E=>a \ CN 32leslok |- een l S3hs | or CAAA [ somes tr { I ALLDATA CONTAINED IN THIS REPORT WASGENERATED BY EXYGEN RESEARCH | rs Gn0393 r 1 3 FIIIIICASIEIIIINGY | 7 BE E %F gE 3 8E pf st pigEfpi8%isigfisi8i8si2i8si2i8si2i8si2y9 |- Bl 5223532525535352355E3335855335338355385235583)3 S| FRSEFSErSEEREESEEEEEEERT | H3 oH os ESBH EEEEE EEEEEAEAEE | 3HIE E EERE LEER ELLEREERE BE r Eo R|cE8oglR22E3E3EH 3B3E2R3E2EE 3E3g5aE5s3g5aH E5s5s5s5aT2sE 8aH5a3tTa8s3 - 3 g <BBaEo <E0<pO<N0<RO<IDODO | g :020288299993932333599 S2| |gS 2g2h2g0g0g0s0g8a8g8i2i8a5c5o2c5e8d8e8e8d4n5i2d3 3z 8 3SI2 3I32 SiEi3 EiS3 iEiS3 iSi3 EiS3 EiSi3 SiE3 iSi3 SiEi3 NiE23 iS5iS33 gY9 | 2 322232233333333335%8%% 2 ==3 I" U0Us 60394 r "| i | | | |- FCI 5B BS2.i23s3t8 8t% s0BE85t058i833mg2330330E83Rss, 2$3) 82 22 22 22 22 90 ve 9g | . B Be...EEE H EHexR ExREzERxES sREE I 8 - 2(8 gEzzzzzsszssssssssssssg | 8 I 8 599959939953 555533858877 - | | f2tcmoxgocnocmocaosno i | bees 70395 ! [: ANALYTICAL DATA REVIEW SHEET r ` - }- -- LC/MS I Tones R. Miller Lt ive Soy I Analyst ignature/Date Toho 11 lect, I Reviewed by 2m] ignature/Date - - - - - - , 0010 f n0N396 Sequence: C:\HECHEH\I\SEQUENCEN010504.5 Sequence Table: [ome wil, I | Method and Injection Info Part: - LPovviianl - {$Vvviiaaaill:s } Ss5 oVViwalE:ko - 0HBOOVVVD:E _ DVT i . i11Is5o4 VVVViiiiasaalill1?ss5 f 13l50o VVViiidteils2s0 . 5 Vif de ~ 2G3iovVWiiInGEE3 |! 25B6oVVVIiiaLtlizDSsS = 3535 Vvviiilslli:tho ~ GBovoG ivinsd: [R3 E visie sosonk ffaea 11 Saanme SSmmao0saeopbBsEe rffeeeddao 11 1 ccaaass ImSoDileclnteiocEihEi RfRoeendedaeo0 1 1 caseanmshe oDIooooionsicseoes:zsss rRRoeeeedddsoo 111 sssaaammmmisse domes reed 1 sams Di1i0ono0ooo0oo1iii5sm0so8ees-sss4 rFRRCoaeBa-dtd1oos0 1111 sSSSaaaammmmpildisee SDDooMoo0oosllissboopesellise RPReoeellooe 111 SSSawammmpbelldee Sohvems Blame Fesdo 1 Semie DLDoodooooiiseeseoiti:s merreedcsdtdoo 111 ssseaeemmmmliieee lDSoonomooiiissootsasless pRreeesldtooo 111 sSseaemmppmlleee SBtohtiiumcmhBeaw fRroeennndooo 1 1 sccaemmse SSSemohaRpElsY omRRoeRo 1 o 1 cc aab SORmEiRdE S RoeloE1 R canis Catibration parts [7 bine tocstion sompiotame vetnos_ calien update Se me i update 57 Interval - 2 vial1 STD 50 ppb FC8-10 1 Replace = D$SuuVdn:ss SSSmhlooee mERaoNndDdd 31 mmhemhlaa | 0SUvVIAiAISa1 SSSDeDleDamos RFReaadddoos 751 hhheevlleaa SRSSUVuNTS: BSSBhRlaoohhee ffeeadddoes 1i5 Mmmvveeenmmksseee Co hwnd mam mod Nan | R35 ovinalS6 OSTDS10S00 ppb Rf FC8-10 6 Amvaermagne | Luss 1/5/04 5:11:04 2M mister J Ye 0yn 011 Average -3 hhmeeenmnne 333 hmheeemmmss 3 3 hhMeeemmmees 333 hen 3 ARvaemraigne -33 6n0397 Page 1 of 2 gr -------------- -! |r f: r ; : - | I "nse wrss08 ssi0s vu misses 207 Ht 0012 as r LC/MS SYSTEM AND OPERATING CONDITIONS 3 Client: Dupont EXYGEN STUDY: __L0001508 - i Instrument: Hewlett-Packard 1100 LC/MSD (LC/MS 5) API-ES Interface - Negative SIM mode [ FNirtargomgeennt:or1:0 VLa/rmiianblaet; 3V0c0apC: 3500V I Computer: Hewlett-Packard Kayak workstation a Software: Microsoft Windows NT 4.0 Agilent Chemstation Version A.08.03 I HPLC Equipment: HP G1322A Solvent Degasser HP G1311A Quaternary Pump ~ HP G1313A Autosampler | HP G1316A Column Thermostat HP G1946A MSD | HPLC Column: Thermo Hypersil-Keystone Betasil C18, 30 x 2.0 mm x 3um Column Temp.: ~~ 35C I MMoobbiillee PPhhaassee ((8A)):: 2HPmLMCAgmrmadoeniMeutmhaancoeltate in OmniSolv Water . Ti0.m0e %7A0 %3B0 | 160..00 10 10 % 90 I= 10.0 STOP STOP Post Time = 4 min. Total run time = 14 min. I IFnljoewctReadteV:olume: 50.u3LmL/min ( Page 102f. uois ! 60399 r fons monitored: [ Analyte C8 Acid (PFOA) C10 Surrogate lon (m/z) 369 469 Extraction Date: January 5, 2004 r Analyst: [ ' JExaymgeesn RR.eMsielalrecrhYael Peg 3058 Research Drive, State College, PA 16801 Phone: (814) 272-1039, FAX: (814) 231-1580 | Page202 0014 i NN400 [ERIT NT EE ee iste: 3525 ogatiCvs omade\1RdeBTE\CRTONHES.E8tag0 10 3 [- 7T Ti T sa | aEE w h | eI ee R2 E TE aaPNwY e |[Ce h ER I |[)|J e[[a5m5r5 sEo IsoEgEinnRy EmTesoEEscoBl03a0nes 0.2 NE wo) [a lo | }| 0WTeHLsEt AHoNnEws oiCRsoNnsiTeoAo sS/s ae ame 550 mOWn 200 ENYa WMSFUirEiEgt nEE4mmEReE BEdE h EEaRmR RmSR Ean E 0 uunm I7 01s efiefoy nea01 [i mHtURrT L soTs 200s Gises: 4615S NegatCiveErodAe B4RSTUCNEAHRTONEGS.N708tage 2 08 3 tfTfotrhraomngalimbent SunRsFrweRivdeinRgeeaineOn 10]i31 . meron TSsooorfnyfst 350.80 | [ GWoavien Wm2s.R0 uHsQuaawdmideCn od30.00 - | SGstRanEn: o3narragEeyns 1.0 dt rn 99300 ren 15 [| Syms Fareneter Fave [a 250 } [| L . f _ | 100 -- NE | [| ro [ wo wom aes | awe oo HWases SetCtEinEg oMases WE Setting Mass setting | 001L6o THeJ!Yo conaoz { Instrument : LOMSS t Tue Dec 16 12:15:46 2003 o| width Offset t 20 -10 [{ -60 f" -80 | -100 [ 120 ! -160 | -160 61946: API_ES Negative mode Page 3 of 3 C: \HECHEM\1\194 STUNE\ATUNES . TUN Dynanic Parameter Ramp - fo5r00 Smn10e00 wes 1500Smiw 2000mes 25s0e0ine 3000 16131321/9959 -115599..0000 2263031..9518 --115599..0000 1033.99 159.00 a i f r he eo) uo7 N04a03 [Method C:\HPCHEIN\1\METHODS\010504.1. Calibration Table TT ~ calib. Data Modified 1/6/08 8:52:34 au Based on I beak Area [eArbs. Rneefteorreennccee wWiinnddooww ;: 05..0000008min = ARbesl.l NNoonn-rreeff.. WWiinnddooww i: 03..000000 m8in |" CPnacratirailbraCatleidbrraetaikosn |; Yneost, reipdoerntteidfied peaks are recalibrated _ Correct All met. Times; No, only for identified peaks [curGrvigeinsme a I Ignore weight Do aqal A-- verage Response i Average all calibrations [~~ ARveragS e Rete-- ntion T-- imel Floating Average New 75% - PrinCtoaultibrofatiroencaTlaibblreataifotnerwiRtehcianlibarasceiquoennce: [ If tRNheoersmusaleltqsuReeonfpcoerftiLsrsatfdtoencreycwlRieetcha(leibnbrdaricanktgeirpoirnnegv:ious bracket) | sSitdonnael 21;: wNSoDnL 346699,, mErIcCe-s4e6s8..n7::346699..77 ernmiinnewivsl" mToowubnlt Area Amt/Area -- Ref Grp Name _ T9230 112 105001.000000000 13..6137665213e4a 33.0114783697a6-33 1 Ca Acid 3i 255000110000000000 81..362451639045 33..000d267336aa--33 [~ 7 115000001/000000000 34..5125273510055 33..32106839088-33 ~ 8.056 2 125 1203500011.000000000000000 231.11080272837075337e00345 323..44356285041435ee0--333 1 C10 Surrogate | 746 110550000001.1000000000000000 235...058263778727239e0355 222...466609544893394e0e---333 [| wore comound-specisic settings: ComTpiomuendW:inCd6owAcid Prom 7.07 min To 8.058 min Com"pToRunendW:inCd1o0w Surrogate + From 7.659 min To 6.663 min [ peak sum maple [me meres in camer: I| conins 1/6/04 0:58:20 a smssreorcyK, t 0018 600a04Fse 1 of 2 [ Area [fron s r" I |200000- iB o- : = ed r=, -- 899030: roa : = C8 Acid at exp. RT: 7.230 i m: 301.15753 | onx: Amount (ppb) mR Re,ey a b: 7356.34233 - | . i [cave vos sizean susie 0 Zot oor SR. 20405 Sample Name:sT> 50 poh I Sample Info:Warm Up 1 Data file: \HPCHEN\1\DKTA\Chemstor\11798592\AG65384\FCO000D1.D [Injection pate: Lajos siisiad ow Sea tine nT | ATTciqoeotpeermator :|iJmMiololeir vIminaol vNNoee. sul1i [ [pNodE iyaviiaE aMsethod |+ CroeRnPnOiHnEN\1\ETHODS\00811502510445.am J1 Lc/ms analysis of perfluorooctanoic acid. [1]- a EDT E3873607 CHETORTRSERGs RFCTOrT co | aw [| | sed | owol RPE. SLFiVr | r =500 J N444 Co 53 | | HT E518 376 CHENSTOR SEAS AFOO0p1rinAteP Ndo SEH FSr 2500 | om [| od | [7] . wo | r= [ 7 7 p Compound raount (ng/o) RT. Area signat TE Saas went ses. micess qiaes.7 - r *** End of Report *** TTT | PC00414 Tue, 6. Jan. 2004 09:19:04 am Page 1 of 1 Gn04a06 [_ sSaammppllee NIanfmoe::STD 50 ppb 1 | Data file :C:\HECHEIN\1\DATA\Chemstor\11798693\A668416\7C000002.D [7 AmciqecOtpioenrapattoer:+ 137m2i/l0l0er pr Inlsteruiment :fricovata 5:28:22 2M SvieaqlLiNnoe. 1 21 mnji.l vNeo.l. sm3 | AAncaqlysMiesthoMdethod :: ECC:B\-H1Y0C.HMEM\1\METHODS\010504A. r Last Changed : 1/6/04 08:52:48 an 1C/4S analysis of perfluorooctancic acid. r WOT E0-38873697 (CHENSTORT 120 Z 0] APES, Nag, SW,Frag:Var 7205. co [| S| ee j|i [we20 Floawo [. =wo | e SDT 453EIG=46814607 (CHEWSTORY 17005e 50AESOHSFCO0000E0] APKV8eySEW.FSig:;Varmh 8057. cio --| aw i r[]| om-= [| e=w [1]| =w= [comms wore ws wre |810AcSiudrrogac 3345.3640 78..203557 2106535316 sina MMSSDDlI 346699,, EEIICC--346688..77::346699..77 r TEnaofmepore ce [ sesouse Tue, 6. Jan. 2004 09:19:42 an Page 1 of 1 600a07 _ sorpte tona:sto 100 oo | spatmtpleEEITn.fo:0 TATE 1 IB Tl Injection Date : 1/5/04 5:43:23 PM gE Seq Line : 3: [cTgSorneha e |+ SeacEsons mensionpin || [wd SR 1 7.2-0C8B [ 2000 wo MN - rl = | woaoer | "MSD 469,EIC=468.7:469.7(CHEMSTORV 1798812 on| O] APNoIg, SE IM,FS rag:, Var B ht2500. | [ oo1500 [ r 0. 1 : 3 coos mount wary nr mee wo aE THR Ee o :i T --- "++Endof Repoterrt| SE 0022 081 onna0s sample Nane:STD 250 ppb I Sample Info: 1 Data file sc: \KECHEN\1\DKTA\Chiemstor\11798897\AGT2960\FCO000004 [oHreE ropoenrae stor T1fJianrgtklher mae s[3ree foaNlei me 13} -- sitetion iT ve sub [|" sREerqd.ivRwaiosErMestehond. CroeAsPCtHoEM\1\KEMODS\S01e05e04.am L/S analysis of perflucrocctanoic acid. | OT ET TORHSTORTT wo aoeco ves voSWFar [| | [| owne p [owe on | ~| modi [1 - moro2ns sonr 4 _r s oe5 uv oo so6z- crosu [wo | [7] ao | rl pe. r oo r. T 1 7 - Compound Amount nase) RT. Aven signal S[ hLo"eGiitroguc a357e.39 TGiaoiioa alormeo haabti aseev EErroceaneessrii3a6e0s7s | I" seoonsa aor repent ot Me. 6. Jan. 2006 09:21:03 an A 002s ge iors GNRA09 [SeSmapmprlee NIantmee::5TD 500 ppb : ! Data file :C:\HPCHEM\1\DATA\Chemstor\11798978\A675328\FC000005.D " BieIMniaojuetiocptmoieenornamtoDrate :|i| f1mM/oi5ol/i0et4rs 6:13:22 BM wSyFeaq teELeiTne sui5ii [gAedeiyarts nvachod [PERE +| | CsSAeREPmCiHsEM1\KETHODS\ 00100850408s. an Le/MS analysis of perfluorsoctanois acid. - ee Ee a [|= r oo|] || pleJ [| P. I PS ; . |- HO2 Y 53,E488 4697 CHENSTOR 74 3657 AeT6 EzFCOo00050) APVW8o.ESWS,F,ra Var mn ano sos. C105 | wo17500 | - 12500 eo [fo | - | | 2500 i -. I 1 I 7 | compound twount (ngs) mT. hrea signal | ho"aSeesbrogar 51755 Svaiaer eMlaEs Waenmd be. Bmiecemsss3u13s80s7 - | . na of Report prsssssss sess sss menm n--en ers ens ees saas sens sass sEs sass tEEs RARs RRRs ES || COO:econus Ne, 66.. gan. 2004 09:21:32 an 0024 rage 1 of 1 -- Sample Name:STD 750 pob I sample Info: 1 Data file :C:\HECHE\1\DATA\Chemstox\11799076\A677568\EC0000.06D [= hTIonngjgeeocrtupimeoernnattoD|rate 1: Pm1i/0l50l/40e44r 6:28:23 PM VSTieagqlLNiNoon..e 1 i :s6 _ bilution i ny Vel. : sul . LAhoangsa.tiyecMihesatnhMgoeedtdhod +|: :17\/CH8a/E-0C14H0E.MM\I\METHODS\010085:0542A:4.8 am | toss analysis of perfluorocctancic acid. E-| fe]HST 360 E0365 7385 T (CHEWSTORT T3007667aRSFOor0a0u0Rc0)n APVES, Nog SW Fir Var | wed | | mo I a0 on I 10000. rl = o r isom] i- [| = TejecidCrromFmateid ogaa | | od cl taht 0 Roiod FloNo oan ORocxmet SooChoon,--___ Initials/Dete:_727_L, i CHET RTT AES SrF a TM | aos ae |lI| !i {| 10000 [, r z Compound Amount (ng/ml) [oRsooacSiidrogac 11335531.8037 z RT oJaeas | :; 5 --- Area signal asiim2a4e3s7 | vweeddii d2e6d9,, EEiicc--a3s6e8..77::436699..77 - | ecooare Erp rpr---- Tue, 6. Jan. 2004 09:22:12 am 4025 Page 1 of 1 ona [iSameple Nsaomee:STD 1000 ppb 1 Data file :C:\HECHEM\I\DATA\Chemstor\11799177\AG75744\FC0000.07D [sen meeroa + roacson [Injection Date : 1/5/04 ~ DATicnlqguitOripuoemnernattor i+| tj2cmoi0liliedr 6:43:23 PM Seq Line vIinaj.l vNNoeo.il. [AanaiysCihsanMgeetdhod 1| C1:/\6R/C0H4EM\I\METHODS\OL0O8S:O542A:4.6 am Lous analysis of perfluorooctancic acid. r S50. E635573887 (CHEN17S38TOAGRTAYVCOEST 0) APFES 7251.ca | | : 7 : : sul6I NSe W Fay rVar Fl| amo fr] on |e I. |-- "MSD1469,EIC=468.a 7:489.7(CHEMSTORN 1709177\ABT9744\FC000007) APES, Nog, Sil [[1] |le=w ) : 40000 80 -C106 Surr7 ogate Var in 200 | [| = 10000 [l= || I 2 i Compound Awownt (ng/ml) RT. | waTo"acSiidrogae 11000198.3003 G720571 8 area 8 mi Signal aloissaoen | uweebbii 43660,, EBIlCo-nd3e6s8.771:63699..77 | | C0014 +4 EndofReport ter Tue, 6. Jan. 2004 09:22:36 am u026 Page 1 of 1 cones saspte tase: 1500 poh I Sample Info: 1 Injection Date : 1/5/04 6:58BM:21 Seq Line 5 [7 sex, sorta +seston [rE RA I] eo A aon ------ | wo [7] ownr | 2w50r00 Fr a=.15000 | [7 raorTor case su | a [7] on [7] = I~ ,10000. I"somomt moms wo2 r ax i es 5 | i| -- ma | Piwsons ++ End of Report + mae coum sion opezssem TTT vies gonara im I Injection Date : 1/5/04 Ti13:21 mM . SeqLime + 9 Ee rc rrr rrr? | |.20 rn r= | [ 20 r|Lo| t.180 -- rm ---------- rl wl =] ro. I ow a 160 r coos am : m c:o | r "++ Ena of Report +++ TT =: 0028 [SSameple Name:%0001508-22 3 Data file :C:\PCHEN\1\DATA\Chemstor\11739347\AGSE784\C000010.D [| AfSeocpreorcanceerbTMia h| rJenraiHeter wDSeaateienre T i TTi1 | Sree Hh ov sal | fr RE Acnqd.iyeMien sthMoedthod ||: CGF:C8\E-H1P0C.HMEN\L\NETHODS0\051502500444.am L/S analysis of perfluorooctanoic acid. | - STO E036 T3%8T CHEHSTOR TRACTSFGRvoTeTn APES SF ar - | 017s00 || | es | [7] oor I|e- rl oe I e ST 55y EO 37097 HENSTORH TOSSA SRT F--CORTODT AP-- ESNo SW. FrVar p | Ee [7] == | [| | [| P Moa r 1 T 7 7 compound Aeownt (ng/en) RT. Area signal [S2h0elhaese 3a8s:i3n3 S8a hneimse wmenisges. mmice-aeis n13e6sn r i|| .sconnrs IioF Raper sem m------ 0029 Tue, 6. gan. 2004 08:56:39 am Page 1 of 1 n04as = sanple Nane:0001508-23 \ Data 5le 1C:\HECHEN\L\DATA\ChemsEor\11799425\A659024\FCO0DO11.D SmTeeisnpteepete s Limon | loots Tas swheaimteee HTi} Jig i i mv su r| BeEqo.iemesthHodathod|+ CzCc\eH-PtCoHmEN1\HETHODSA 010504. 1an 1e/MS analysis of perflucrooctansic seid. | CRE1 NTSI TROTRSTOESHaSESvRRenTtFa FTES a SH Fri [| mwii | [--- = fr 400. |= |} T5476z GRENSTORY1SSSREC7 T) AP5io,ESY.SFo Vr wo i 8.060 C10Sur ia [7] ao | ome | | l | I] | [l= |=i . |- 2 o 5 Compound smouns (n/n) RA. aves si8gna1 aia on Tan ew went be mies 7a] |~ I | scooase "++ End of Report *e+ Tue, 6. gan. 2006 08:57:32 an TUT rage 2 of 1 n0are Sample Nane:0001508-1 { Sample Info: i Data file :C:\HPCHEN\I\DATA\Chemstor\11739484\A691584\FC000012.D [ AITcnoqjgetocrtupimeoennrtaDtatoer:|: mp1/Ci50l/0l0ae4lr 7:58:25 BM VS5ei.qalLNien.oe l:: 1E2H1 I pDiqtutisoonrta i+ treaction 3 vei. : sul [EAnealysniseMsethod | Cio\ePrCHEM\I\METHODS\0081:05520:44A6.am Lc/u analysis of perfluorooctanoic acid. I WETTo ECT EAS ERECTED) APES, NeSW Frag ar [Nw- || =| r= | a| | I | hd HST 6,ECG 248 CHEN H | E | TORY4TOREARESTSBFEOM8MSTED) APESNog.SWF Var 80C710S5uro-oa | | | | NE 5000 | I I Compound Amount (ng/ml) RT. Area | "aSo"ciSuderogar 40.70.093 8o0o7m l0 ee21 3 signal wSeodli 436699,, Emiicc-e3d6s0s..77::346699..77 | | conara ++"End of Report ++ Tue, 6. Jan. 2006 08:58:04 am uusl Page 1 of 1 nar? = : [ InjectionDate : 1/5/04 8:13:25 on Seq Line : 13 Wo WER... [ eres sar tge of ese tiorcustr ane sci. e srs [1] = rl - | ow f = I. I : : rome-- I" WSD1 469, | ws cos [7] wo |[I NJ 7:460.7 (CHEMSTORI 1709550A6938241FC0000T3.0) APFES,Nog, SIM,Frag:Var [|[c|=p=ar. oe Te : 7s : r3n || TTT we End of Report ter | ecovara Tue, 6. Jan. 2008 08:58:34am 0032 Page 1 of 1 nats Sample Name:L0001508-4 | Sample Info: 1 Data file :C:\HPCHEH\I\DATA\Chemstor\11799617\R695936\FC000014.D | AmTcniqsetcortpuiemorenanttpoarte ii 1m2/0i50l/4l01e84r "8:28p:x39 VSneiiqaLivoNeno.el : : 1isH ~ dilution i In vei. : sul [AnE alysisaMethod | Ce:\rRPCHEM\I\METHODS\0051:05500:44A81.am Lous analysis of perfluorooctanoic acid. [ SOT,ECE T5507 (CHEVSTORY 908HGSSERFCONETED) APNVe SEWFSrag, Po 22u-ca lw | |0 rl = | | 0-000 bao i I :ass: cr05u sw | | "WISD1 469,EIC=468.7:460.7(CHEMSTOR 170961 7A6OS036FC000014.0) APNeI g,S- IM,E FraS g:V,ar. I| | [7] | I 10000 so00 I | compound | "60"hcSiuaErosac Amount 05.6030.63 z (ng/mL) I R.T. 8Jla0a6 Area 2i1s5ales : i signal wWSeDpL d3e6d9,, BE1ICC--3a6c8e..77::3a6e9s..77 LT | | ecooara wei EndofRetep r ort 033 Tue, 6. Jan. 2004 09:00:01 am Page 1 of 1 [DLESE:) [ Sampl Data e Info: ile 1 G : \HPCHEN1to\r\1D17N936T76\AA6\981C761h60e000m15s. 1 [imine Tan ween sbi "3% Acq Operator : jmiller vial No. : 16 imT s SetT hod | ES, VAbALHETHODS\010508 Lo/HS analysis of pertiuerosctanoic acid. I a - | 20 [= Fl = | - [Mw [[[[77]] |a || aoo=oeoonl- sore. Grose ||[ ||. | MSD 469, EIC=468.7:469.7(CHEMSTOR\I1799676 AB381761FCO0A0PI0E1S5, .Ne0g,)SIM, Frag: Var ICompound fmount ng/el) RT. a area 5 si8gnal i| scooaa u034 Ne, 6. dan. 2000 09:00:39an nest cnnazo "Ienjsecition oDaetes A : 1/5/04 8:58:42 BM wr Seq Line : iTis [" ses, wommon +reson [Ean BA [peas =ws r[FF| loooawml;] ye -- | 3 | 8071+Clos | | "WISD1469,EIC=468.7:469.7(CHEMSTOR\I1799748\AT00352FCO00016.0) AP NegI,S- IM,E FraS g:V,ar [7] = | |ol | i wr | ro | : I I 3 } | TT TTT T edof Report eer | ecooars Tue, 6. Jan. 2004 09:01:23 am Page 1 of 1 cnnars Ssaammpeliee Toenu0001508-3 . Data file :Co\HPCHENL\1D17A99T76A5\A\TOC2Sh92e\FCm00s00o17r. [7 Injection Date : 1/5/04 5:13:45 BM Seq Line 1 |UAnecivwesasthwodaned |-rE oa-1a 0 1m weToo nSO1n 05068 1 1 ss anatyats of ertivorooctansic acta. [r - TETCRO Jor. co R ES Wo SE r [] = | ro= fl = | i| Mow . 180, | HISD 465, E10=488.72:4697 (CHENSTOR 1a799788ATOZSOEF006001T0] AVNogE 8,SW.SFa:.Var | 16000 8062- C105. [| ao [ 14000 2000 I =wo | r .2000 re 1 1 rT TER 7 signa ae ee meas 96. r ~ { ecooats TTT aaof Report eer Tue, 6. Jan. 2004 09:01:51 am 0036 Page 1 of 1 onan sample Name:10001508-10 IN DSaamtpal e Info: file sC:\HRCHE H\L\DATA\Ch e m s t o r\ L1799822\NTOATE\RCO00018. 5 1 |E EoimeerY TM | iaite Po FllT3 |Undgi,yavgoemtmeenthod |+ moopyaeRtctie 1 METHODS 01050881 | Le/us anaiysts of perfiuoroostancic acid. |~ ES TR CRETSSFE CprEed PIES. SFr [l= | [] f 2000 | |] i [i| . porr es7mmr 7 ws eTdrIes ol 2s000 [7] an 80C7 10 S1 urro+ gate | [ 15000 Il 10000- a" ro. compomt rooms wo2rms wr. 4 rem 6 si8anat | ecooara Tue, 6. Jan. 2004 09:02:46 am J037 Page 1 of 1 cnn4aR3 Sample Name:L0001508-11 I sample Info: 1 Data file :C:\HECHEN\L\DATA\Chemstor\11799876\A706816\FC000019.D {7 Injection Date : 1/5/04 5:43:47 Bu SeqLine : 1 B {AcTnqee roupmeernattor ii: lpjmeiololsear vIinag.l NvNoe.ol.i:3 su201 | ~ AALcnaqas.ltysCmihesatnhgoMeedtdhod |:|rcG1s:/6-\/Kt0R04C.HmEM\I\HETHODS0\80:15025:01414Aam [OR -- r ST 8 EC-S887367 CHESTORFART BTS FCIaooTo5 APWo,ESiSFag,Ua - eo con I | = | I |: || | = Fl = - | wl | ww ue eW-- SO E6E8r EIG8 4r 68 (CFENSTORTT4 oTaATBTFCOO$SSTSS) PTESo Nogm :SW.FirVar ro a068104Sur.o [leo | | 10000. Ps [|e wo r | amd [- comooms_ome worms nr. I ween |a10"acsiudrrogar 303.20.05 87.200634 1i03s02509 TT : sigs MwSeDnId 436690,, EBIiCc-a4e6e8.775:436699.77 -- ! or CT ma of report nee or . | scons 0038 Tue, 6. Jan. 2004 03:04:45 am Page 1 of 1 cnoara sEampmle sane:510 500 . | Injection Date : 1/5/04 9:58:46 mM Seq Line : 20 [" sEe,SsomoTs n +|sEeoomn on sss [h ed s my [| [|1-=5000 f ol - | [| | =- [ee m----b-- [1] om |" 15000. |~| a10000|I cops tome a7r [Th SEs 5:20 xn : em EOE | : sn ms Emeriss] Tendof Report er L039 i wots mene essen mers oo ["_ sSaammppllee NIanfmoer:solvent blank : | Data file :C:\HPCHEM\I\DATA\Chemstor\117999S0\AT11296\FC000021.D = r oITnngdjeeorcputmeieronanttoDrate :|| 13I/cn5oa/0s0ii4tear 10:13:44 2 VSTaeigq.vLeNion:.e : 21 21 fr or i vel. su = AALcanqsa.tlysMCihesantMgheetdohodd:|+ CF1\/e6aR/-P01C40H.E1N\1\UETHODS\008L:05520:44A81.am | erms anatysis of poreruorsoctansic acsa. I EDT 85 EGRETCENSTaOssRo To APES. og SH Fr ar [] = r wo fr 20 ow (I ps ~ SDT 88 EAEz1697 CHENSTORY:{FSS =o | 20 r= =o lw TSEFEOMFTGEETD APNoTg,SEW.FSag .Va ny [| Nd - compose wz orm 1 weer : siina = | Sa10hasuirzogac o0l0e0n 0.a0o0n0 0 uMSSD1L 346699,, BEIiCc<e4a668a..77::436699..77 || covers CT Enaof Report ser u040 Tue, 6. Jan. 2008 09:05:38 am sage 1 of 1 n0aze . SSaorpeie Nane:10001506-13 : Date File. rT \ATA nes TOSSERATIISIENFO00008 0 " | pCIdenmajremceeptieeeonrsnDaaoterl:v:odme1/5s/e0)4 10:28:46 PM STHHeaqLeiEne Ld2221 pr EJAOyEesRvEamos | En 1wert mons 0i1e 0i5i081 I" cares snstyets of poreismmosessnnts sos. -i EE pevied roe | Mo. - f Fl ow | 20 | [7 - son [abanrksaeosrem I] a | | [7] woo | Fo ao || - 7 7 1 | Brcyompound Amount (ng/mL) TRR.T. Area Te Eee Signal Ta I [-- aE TR Te. 6. gan. 2008 03:08:36 am 0041 rage 1 of 1 enna? [7 Ssaimpele NmaEne::L0001508-14 : Data file iC:\HECHEM\I\DNFA\Chemstor\11600033\A715640\FCO000.23D TM sTIonfujeerocuptmeieronanttoDrat|e :| 1sm/oi5nt/a0et4ra 10:43:43 PM vSeqiL Neei:ne 2233 I~ sDeigl,utiwoaneros i+ reson vei. sul pr E Analysis t Method Cs \HECAEM\1\METHODSA001a07505422:.34am L/S analysis of perfluorocctanoic acid. ~I = SDT 6-308 7080CENSOR TOSCO5) APES oS Fa r= | we Flo= " lw i- E iEo soS e Eb mn [3 em a088- C10 [1] on | ee | 7] soo | woo {[7] exo om [7] = -I [compos Zaneia _wmowm waIrms a. I ole TT seen sigma win 36, Bicoace. 7269.7 | || xconane RE reer ul4z ue. 5. Jan. 2004 03:08:58 am Page 1 08 1 onars Same ve . "pata file :C: \HPCHEM\1\DATA\Chemstor\11800075\A718016\FC000024.D I Injection Date : 1/5/04 10:58:44 2 Seq Line :| 24 EI sEes, RtochEoa esto WR MT eg T SpSaid TRUST | -- 2500 i ~- | Ml Flow roe | "MSD 469,EIC=468.7:460.7 (CHEMSTORI1800075\A718016FC000024.0) API-ES, Nog, SIM, Frag: Var 1 8058 C10Surrogate [7] =e R| E . i. | | | r | 000. (NE I3 i = : Bi po | TTT +++"End of Repor++t+ TT I icootse ues 62 oom 20m ovioese am 0043 on 1ot 1 chnane fSaammplee Ntaenee::50001508-17 . Ep ---- 7EmIEnjenpcC tioomnoDnaE teeEE:v1/5e/04 11:13:48 BM SwCmeqoLrpinae : 2L5 dz{ . Srepimsnotownts 3s| SouSnieentwermoosaioosoren , |" sens satrats of pesttassoostancic acta. - SA ---------- Er [ol |2 | ow | | [~ oww=o|| Tp prods | "MSDT 469,EIC=468.7.469.7(CHEMSTORN1 1800112A720256FC000025.0) APNogI,S-IM,EFraSg:V,ar [ ao14000[| ao || IB ao6000 I ao1 r Compote war wT, : I ae ween s st8ant ese rene | [ seonesa Eh Some fo mn TO potest an fe 1or1 GONA30 [7 sSaempele NSamee:L0001508-19 : Data file :C:\HFCHEN\1\DATA\Chomstor\11800165\A722432\7C000026. 0 AIIcneajterOcitmpieeonrnta:tDoart|e :s| e1Io/mo5i/ta0lt4esr i ihcives of 11:28:84 2 Sewq5atLeNienroe : ven. 26 41 sul I" sAeSqa.iyniosnoVsetnoa + rCess\-H1R0CH0M1\WETHODS\010504. [rE 05:50:48 am L/S analysis of perfluorooctanoic acid r STSE 10-3675 HENS TORT TOAEEFSTOTT) APES No SW Fra Ps [| | =wd | | | 20 Fl 0o= = [om wo |~ Ed smn A aces. cos | | ao l |" 15000 rl on wo | . [--compos mre wo2gis me 4 EX) aon 1| en sbi__a min Nop 36, Bicease 1369.7 TT Endof Report +a I mwise mun 6 ou som onion on TTT 0045ios gopant [- dSamiple Nam:10001508-20 ) Data file SC: \HPCHEN1\ONTAChemator\LL800201\K724736\FC000027.0 _ lBpInijieecrttmiaonoeDatde :i1/5/04 11:43:44 aSH weqtLeieene 1 Tsu5a l? [7 LAsreaat.iveimteesemobraechdod;|+ sOCcFaS-eHoRuGnHN1\HETHODS\R O1050n 41A [7 terms snatyase of pestiuoroocrancie acia, [1~ we TT ERSTE RRR [oo | wo [ow Flo= Iw od RS1 ETO 7 [7] jeoen a0 [7] woo jp [7] weod [| = ~. I [sorooma soos wary aaa oon | 10 Surrogat 346.67 nm 7 TTI 8.063 | TATEISFA7T Eek1 or- aon ro | ween 135931 i || F--I| ons SeTd MSDL 469, EIC-468.7:469.7 | cooina Jp ------ - ue. 6. Gan. 2008 09:12:08 an ul46mersory ona Sample Nane:ST> 500 pob I" DSaatmaplefilIenfo::C:\NPCHEN\I\DATA\Chionstor\L1800237\AT2684IARCO0028.D 1 = mIfnojeeicpt"iemonneaDate :1 1j/5/i04 11:58:47 Bn nSpHemmq LEin+e 2su8 5: I" Erieg.vEneosLhaoath:od +| sECeSuRseso 1WEmHOOS\0a105a068n1 |" sens amtonss of portaomsccancte aca, [7] - amsBREST SESSFTTooIson Eo, or | [7] oo | I] | ooo12800 || | Fl owe | ~ .2500 | J | on a somo smart esan a i | | "| 1s000 | [= | wo ! ro > I I 7 1 A signal |aiae SJETaw mTiEen wmegve, BEeesme ITIeRY | | scooesa +++ Endof Report ++ u047 roa a om 20t o9eo) am foe iott GONAR3 [- fe bata lec: PCIE 1\ORT henson800251\W231SEARCIRRNES . I fInejcetcitioonnDhaetee mmm y: 1/e6/0e4 mh 12:1 AX3:Se4qL5 ime BE s+ 29 2 Lu frEE Les smatysts of perierecctanoic BR, aca. E 0 i [|== A wo | (I -- F| 2 Mw |" gi 2 4 "MSD1469, EiG=488 14607 (CHENSTOR 160020 AT TSFCONSE oY 8 ma APINe. g,SEIMS ,Fr,ag: Var | | ow MN || [7n] e= | |. [7] -wi |-- coos om arm wr wees sim [28eAciind 30.1080 R0.0E00 0 See MSDL 369, EIC-368.7:369.7 [ Fae CTT RAG of Report ser me tom ios onan v048 mmrors gpd Sample Nane:sTD 50 ppb e te Eile 1 HEy ChaterHOT ARe SEe . s = poe Ce mwoem : reo wetios TR rEenOcton EE Lens sT ms ofE portussaO netanie sci,T EE - a ol - ve | Mo.- - 1200- || [ow - [= [ -"MSD 00 469,EIC=468.7:489.7(CHEMSTORI1800026\A731392FC000030.0) API-ES, Neg, SIM, Frag: Var rom FlIz wn) r=oo r=hi [comma some wo:rms wr. wen |l -- | w:ot [So Sutrosar 35:92 r Tosi dome mem aes Benes | . | coours Tue, 6. Jan. 2004 08:55:19 an 0049 Page 1 of 1 cneaas * SSaammppllee NIanmoe::STD 100 pb 1 Data file .C:\HPCHEN\L\DATA\Chemstor\11800363\ATI3632\6C000031.D 7 AIIcnnqjsetocrptueimroeannttoDrate :i| 1Pm/Ci6Ol/0l0Ae4LrE 12:43:4A6X SevInqija. LmNioen..e + 3121 . pilution 1 my vel. sw ~~ LAAcanqsa.tlyCsMihesatnhgoNededthod |:+ Cr:e\sK-E1C0H.EmM\I\METHODS\010504A.} 1/6/04 08:52:45 am Mw | ses analysis of perfluorooctancic acid. ! WSDT09E1368758 CHEWSTORT TSO ISSrEocYa APTES, og, IWFgar |e r= 1500 [1] | ow | | ro r LHe ST 45, IG 468 wo [| = 200 [oe 2000- [1] =i 00 [l=o I [(i8oacSiudrcosar 5es5..972 CHEi NGTON 1003 ATSSS32FCO:003T0) sas: 1 : 28030588 333110577 wuesdp APES ogg , SHE Fagrm ar | osm ! | s5ion Py 34669s,, EBiIcCesadsces..77::346699..77 , | scooars ma ot Report wee Tue, 6. Jan. 2008 09:14:30 am or 0050 Page 1 of 1 n0a36 [sSaampele Nraatmee::STD 250 ppb 1 Data file :C:\HECHEN\1\DATA\Chemstor\11800400\A735808\FC000032.D [~ AIcnqjeOctpieonraDtatoer:: j1m/i6l/l0e4r 12:58:43 An Instrument : Pcooata SvieaqltNo. i:ne 332 Inj. No. 1 fr Othe 1 ml vol. : sul | cAnqa.lysMiesthMoedtho:d : CF:c\a-H1P0C.HuEM\1\METHODS\010504n. 1+ tast Changed : 1/6/04 08:52:48 an | terms anssyets of pertiuorcoctansic asia. - SDT 555, 10-35877363T (CHEMSTOR TO00H00RTIBORFCO0003Z0Y APHES: Vi SW,FgVr I ao 7.227 C8. 1 I 7000. | | eo [ | sm wn fl oo 200] I 1000 [od r m WT 89, EE 488719697 CHENSTEOGR S1 IGaATSSA5 IRDFYCRPOTES,GaNHog,RSEW, Fag Var 10000 80C5105Sur.oga M| o [1] a | Ir | "woo [rI | : | ["compore t wows maIres t w1we ` ] sina on [(17280Acsiudrrogac 225587..6717 78..202576 18305362070 NNSSDDLL 436699,, E1ICC-436688..77::436699..77 - TTT | r| ecovara +2 Enaof Report tev TT Tue, 6. Jan. 2004 wisi 09:15:07 am Page 1 of 1 6n0an? rsao mple i Hame:570 500 ppb : 1 Data file iC: \HPCHEN\I\DKEA\Chemstor\ L1800AS4\AT37964\FC000033.5 [ airmseeperleimocenoTMbas | Ljengtaiide Ansara swhaateee 53i - Bliarion iE mv sul | fnBeeqoa.rEoihtanhmUees R+ FScoi-at0S.wI--------e--e--n | seus anaysis of persiuorcoctancic acid. r TI BTR CREATORS ovogSeFr i= 7.238 C8, Uo | rr 14000- [| = | avo rr] w- i po | rf o= |o a | | "MSD pr 469,EIC=468.7:469.7 (CHEMSTORYI J 18004SAAT37984FC0000330) APNIog,-SIME,FrS ag:V,ar [| re on [| ws os [I mewodn]i | I 2500 | r I I I , ----r signal FE iacir a aan TveEe hdaew emnisees, mBiEcXaNsE7I0N.I7 ub voooats ue, 6. Jan. 2000 09:15:27 am rage 1 of 1 Crass [_ SSaammpwliee mNaemce::STD 750 ppb 1 Data file :C:\HECHEN\1\DATA\Chemstor\11800491\A740288\FC0000.34D [" Injection Date : 1/6/04 1:28:42 AM "Seq Line 3 | ~ pAIicnlqsturtouipmoeenrnattor f:: aemciolvlaetra vmmi3ja..l vNNooe..l. sul51 | AAcnqa,lysMeitshoMde:thod :FcCa:-\H1C0H.EuM\1\METHODS\010504A.4 Last Changed: 1/6/04 08:52:45 am | terms anasyats of pertiuorosctansic acid. M[ [oSDT E0-3887350 (CHENSTOR = R00 ATAOZSBFCO0GGSAD) APFES;Ne SW,FiVar Lf | om RenRnejeLct tpedChrot mslograe m | | ro. | | x0 10000 O Resist FileName | 0 RoaImnakltalyDSaetew:Co4o2nd =--| | [v SDT 165, E4i 4606 7(CHE8 WSTOR1 TI EGOo 49WTAOZBBFCOm 000004) ApPrTSe,e nNoeo,eSWmFie Var i 8057- G10Surogats - || econo. 1 [] | |e 0000| [1] a0 r | oon \ o r z Compound Amount (ng/ml) (| 8310Acsuirdrogat 1133751..8415 : RT 871.025378 area 452136207097 i 5 signal MNSeDLL 346699,, EE1ICC--36688..77::436699..77 | oC i | | ecooats "++ End ofReport +++ Tue, 6. Jan. 2004 u053 09:16:08 am Page 1 of 1 nang Sample Nane:STD 1000 ppb || " sDaatmaplefilIenf_o:C: \WECHEIN\1\D11A80T05A2\0\CATh42e52s8\sFCt00o00r35.D 1 [| TM ATTrnadsterGcoutemineoannccopr"ate|:| LmP/eieatjoeientrs 1iisia an wSneoahnLeiene 3:: Siete if we sul |[ | Aacrad.iE yaviesthMoead thod |: Crc:sA-P1C0H.EmM\1\NETHODS\G0a11055a0446.am 1/4 analysis of pertluorooctanoic acid. |- ST wot ETC CHES ORT TOES psdOT APESTSFar [1] mond || - Fo Fl | r= | | . || 4T8 716 C5 HESTOR :4 OG8ATIES25 8FOa7 a0G81A0PS7EurS.oNo,7 SWEFig Vr = | on I]| od =| eo Feo Fl oe [ |e 1 T 7 7 pr Comownd amount (ng/ml RT. Area signal Shea Tone Ta aes hab ses, Beene 1360.7 LT | | covais in ot Ra eport Tue, 6. Jan. 2004 09:16:48 am a LOb4 Page 1 of 1 10440 f+ Sanple sample NInafnoe::STD 1500 pob 2 Data File: \RRCHEI\ DATA Chemo\LLSOUSEE\RTAATONNFC0000%6.5 [* Injection Date : 1/6/04 1:58:44 Aut "seq Line: 36 b sEhalts etvte} mos pEhheiE emonsroBtosRtanAs "coms - smetyats of peivorssssanete TT -- acts. a Fl - wo Ten . I'l om | Fl ow I | rl 20000. | onj | ee | -- . ------ EA I "WSD1469, EIC=468.7:469.7(CHEMSTOR\1 1800582\A744T0AFCO00036.0) APNeE g,SS IM,F, rag: Var | ound 8053+ C10Sur !I woo | Fl =o || ao | -, : erm TL Tt | | | : :5 saat -i SE SEEEEEEssssssssssssEEssssssssssssssssssssssssssssssEEssssssssssssssmmmssss ,I" zcooars Tue, 6. Jan. 2004 09:17:08am ul55 rage 1 of 1 Gnoant {5 en8 3058 Research Drive Phone: 814-272-1039 State College, PA 16801 Fax: 814-231-1580 [ RESEARCH SR TE AT PCPrroaomjcepctatnSytoNraagmee:: P0000419 DuPont do Nemours& Co, Ic. CGCooonnnfflooorrrmmm RCSeaOqmCup:elset:: TTTuheee _ lSoegmniTtyeped.By. iMmimcehdaiealtbe.RAeucceopintof Samples | StDDaaurtsteDeaSdtt:asrt:: 0T112/20281/22000034 [[| RReeceetveesaboym:e: R1ozsa.0zsmas wn LSporbeead Semple: | CEProxopjoeacntNoTSeitDsl:IeP/TLype+: AMnIaLlLyEsRis, oJfAPMFEOSA in OVS Tubes / ROUTINE fre SSoRomRoe e ee-------------- [+cpoacekagre Garon etust 1on0st0io0n Packages reoS/ uCopnmteaiDners Paces ots Unromssd S2009188167020 TempCowoniolTemp. Di5ecEisonE/Haniedy [me o ie |" Container# ~~ GrossWeight pH ContainerType Preservative Mig. Lot M.D R 1 - CC"cuozooizoazr0s8H222000809 `Onnvtheeeerrrr TTNOooNeeE Noe GChmaz [Se 2200s0 0 nreerr omer NNNoooveee CCounuzzs Loon 222000088 ooOvnveeerr Nooonenee CCoonouzns ~ Cuzios 3200s9 209 fooevveetrr NNToooeee |" GoGnoiuazs 22200000s Orrneeerr NNToooeee |[GCuCoonmmimsxs 322000585 rnneeerrr NoNooneee | Ccomuiomso 320050 nneerr NNoonnee LU Ccoonpziaoeano 320089 ortheerr oNOeNE i MisMcoetaneous [7 v|= eLwoogoist ousrpion ecoece u056 ReportVersionP:ag'Deec10221.42003 0:44AM Instance: oonaaz Roorsiss |[IRHNERTE ~V =e Samples | LLo0oSioarinisgoecsloood0orn `mGGaAItSSs OOVVFSrTaTicuibboenoss SaWWmHpKKlAeAAANNSSFFOLLKKEEDDAD Data TeoiSoaasmDapt1e2l2Re0c2ee0i0vd3e DateDue. otose00s [7 LOolonMoiosEioiOsosoMooooEoss GGGAaaSss OOoVVveSeTTTiuwbeeesss wWWiWWaICAKAAuAANSNSLSFLEOEILDKASESC TToiivoao0ss 112222002200033 ootv0oss0a008s Tivas 2003 ovasaos loooiiosooos GAS OVETes VWIKAANSLEDC Toioaons 1200200 otosaos || " Llioocvoooorrmsicossso0o0oo0os7s GGGaAasSs. OOoVVvSeaTTruiibeeesss WWWwKWi-IaAK-AmAAsMMzSS2EA-EnENnA9C 1TT21ri19iv12oo00ss3 111222722200022200000333 0oo1vv/n0s5s/za2o000ss4 Luoiieooto GAS | LLOOO0O1IES006B0000T112 GGAASS OVTAM WIKAMSIEDA OOVVSSTTuubbeess WNWIWKKAARANMSSI3EEIDCS: T12o1t0o2a0o0s8 1122220022000033 o0tss20s08 Trios 12202000 aiszos - lLoooniiioescaotos GGaAsS [7 liicosoots Gas OOVVSSTTweess WWWMIWKKAAAANNSSEHEEOOAD oveTwes wiAAMSeEC TTaotroooss 11222200220000 ootsso Tories 1220200 otszos |" LmLooootiiooms0c1ostsr GGAAsSS mOOUVSSrTTuibbeeess mWWeHIcKKAAhAAmNMsSSSSsEEsOOcAR TTaattooooss 1122000002000000 ootsas Tatoos 1220200 oso LLo0oriis0ooscc0o2t0s GGAASS Looiis00n GAS OOVVSSTTwobbeess WWMWIIKKAAAAMNSSHHEEODAD OVeTAms WIKAASEEIC TToriroo)s 11202002030 ootzso Toren onan otoseoos E[lLlooowoooirssso0sse0o0cs2z4 GGAAASSs OOOVvVSseTTTuuwbeeesss CCCOOONNNTTTRRROOOLLLACD T1T2o220r02o000s33 0oo1w0nn5s2az0o0ns8 i I~ t I | = 2004 on Report Version: Doc 22200030105:474AM re instance: Roo7ees Chia ui {~L0001508-0001 ! > CoCo0nt2aOim4neer6r N1ON8E | L0001508-0002 ~[7 caiCorntaninsernone L0001508-0003 Con2iGER Omar HONE | "L0001508-0004 r CanaCdontTaoimneerr NONE 100015080005 =7 connioCoznztraoimneerrnone [7 _.L0001c50o8n-0a0n06 Co024GE3 Ger NONE | "Looo1s08-0007 [coCnontdainoerne L0001508-0008 [ Co- nair NONE |Lovorsoa-socs CoC0ont2aOimineer6rN3ON8E | "Loootsos010 [= cmCsonitaoimnenrone 1L0001508-0011 = Container | coozOtheor /NzONsE | "Loootsoaaotz | coComntmaoinnerers | |.{7 Leo2gi0na0pt Bottles Method Method Method Method eto Method Method Method Method Method Method wuss Report VersiPona:gDoe3c02f2.42003 10:44AM cInnstoanace:ra ERoE 07845E 4 L0001508-0013 [.7 coCointaeimneerrone L0001508-0014 1I" cocaiCionntoaimneerr none In L0001508-0015 conCtonataoimneerr none |" Looo1s08-0016 [I7~ cw nCoenttaiinenrone [7 .L0C0ou0n1d5c0o8n-oa0nse0r17none F"Looo1508-0018 | cCoo ntaii ner n L0001508-0019 [ncom nniee mone [conn ..L0001508-0020 conde omar mone |" Looo1s08.0021 aContn ainerd L0001508-0022 1| conCiocnitoarionmearmone | -L0001508-0023 Container C0024040 7 Other/NONE | L0001508-0024 | coCnodnitfaiEnReirnone | || mLooginn MMeethnosd Ret A MMeetthhoodd Method Meetthhoosd MMeetthhoodd YMeattheosd Maettheosd VMeetthhoodd MMeetthhoodd Method TT HMeatnhogd Luby Report VersionP:agDeocd2o2ts2003 10:44AM enoInsstannces: HroN oradsN s [348 (IIe| #02 <1]3 } | . F-E] * fFo-|laS=]| = PTT HERR EE | LES = |S [ER>EZ Teme |5 flG2 gro LEP ele Em |=2 B5l [5 [PPEETEh EiLleE |>Z | 2[2 Q| S p2epEy REek e|S | T g [BTE ela| ishei spalkE8(B[|i EF LZEHE = [9 H : HC0 [2 =] =m A A mE maa [|1r hJiasg - # [BLPbpp| 5 28) 3) 3 M8E Z [ BLINIGNl:e [ OFeEmE] ] [2 |: Ex] BE 2) 2 WEE Eli 0 rr s [TLLLELDE LYE KE iG a| lli3egr il-ameAl i el i iE loEi R RES Hipsig .1[* [oooooog, ["gi gzeess) [fl eessed esr Gf 85 & | Ik gx 7B [REA ccd B s m 9 O zg [{T TII H IT, ITHB < sH @ [ O I OT T H"l* 32 g BO or WlHf = 2 4060 [GLEE Og -2 - "r | Fz3 | o[ | "| - oLfy | is 0B ocorooiddcey f EE HI EFECES RTEES `a 2[2 sg 3 = S: I3 f3 fZz e...BFRR BlEliEE g 3 ssl 3 IEEE a| 58 2 & i 23 3 3 eg 338ECBRe0EE 2 3 EB = g g@ casas fERRERES PE saevesnaeifiEaREEagkRs : || aofz + sssssEfEERREEEE izi staEsessepgEnEIg 1. E E lg! spa egrallseeReReAd : uo61 Bl copay Exygen.RTSEARCH r regiSeRensielre . : - - Sample "Condition Upon Regeipt" Form: | Ir Protecol #, oF : ' r Exygen Study # * POLL em Laff mes I Da&tTieme Received rafalym I Conditionof Samples _" ambit |~ `Temporary Storage Location= Deceaje} = I~ =. Initials Sate y SH belo ine o | Waybill r { $53 9129 gacy I" Comments: 5 pas fing foo plod riche patnh Joly wer X - l Opes Sapte adams os CL. Groars || CREJ RlbEyr orf7 m5edd - =F LETH ) - = = =.r REL|AIHeA FERTTS | HERE GE om |Bg EY S| Op 57 2h gs -- ui B =: 2 FE Bi J . I=" | = gids mE, => & i L Hee LEE ! ii SLfhEgL er EEE | I. BSyhloEdRsEE S5 EAREE [ I i i Ra fs dm | of px Jel0i eo Xs os RET FE r Lg pl KE aR | r [H i lis Tf EE il wg |i sli T ig i I df i Ed fF Eody . Elam lich | |B r i S PECICBYRPEE E EE HEISE Il | ff | HSiIECOTE Mfoo2 TEE Y | ri a HE 88 {os : IF IP = [iE ll BEC nl iii [ES r Eg] iH [ ) ) LJ i 0063 croang @UPIND `Washington Works [ ----------N--o --Cha--rg--e S--hi-- ppe--r ------L--1--55------ Ship To: |~ 3E0x5y8geRnesReeasrecahrcDrhive: AStttant:eSCohlalwegne,RoPbAbo16r8J0o1hn Flaherty |3 814-272-1039 | Phone Number: Date: 10/27/2003 NCS #: 38200304715 Rout4 i8n.g3:C0OFELDL,EECXT( SEE ABOVE ACCT) DBa/tLe:Shipped: [Quantity | ProductCode/Description | Weight | Units | r [1 TT Boxcontaining glasssampletubesforanalysis | 10] bs. | | rr rr A ES - rr | rr rr - er | EE ES EN EE - EE | rr EY ES - rr | --1 rr 1 rr - 1 1 | rr rr 1 rr I --ee 1 |- FOrriegiignhattColra:sCsr:aTnUe,BEASli,soGnLAASS, NOL. CostCode: 7035-507483-862200 I~ Purchase Order #: | Value for Customs: r| DSihmiepnFsrioomn:s:Stores ! sPthaotnues:: 4448 Hazardous Shipment@? No O Yes MSDS Sheets Required@? No O Yes SMahtieprpiianlgC#l:ass: (O]ToCodrircosive [CJl FOltahmemrable. ul64 crnaro ot `Special Instructions: This N-C-S will cover 6shipments beginning 10/30/03. | >>> Wil deliver package to Sores with completed FEDEX Bil. CRG Account Number 2230-5551-6. Weekend samples will be delivered directly to FEDEX. <<<< I Comments: I. i i" . i | uls Creare