Document DM4DbrQaNMwa2BMoz6wX7N5do
Interoffice Communication
To Distribution
From
Tom Grumbles
Date March 28, 1984
Subject DRAFT MSDS FOR ALFONICS
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Enclosed are draft MSDSs for three new ALFONICS. As you will see, these products are very similar to existing products. The only significant changes are in Section 3, with a few additions elsewhere. Please review the appro priate sections as indicated below and return any comments to me by April 23.
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Thomas G. Grumbles
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Enclosure
Distribution:
Sid Pitts - Section 4,7,8,9 Bill Broddle - Section 5 Dr. Drumwright - Section 5 Dan Plummer - Sections 3,6 Joe Ledvina - Section 7 Susan Litzau - Legal Aspects
VVV 00o12382
conoco
MATERIAL SAFETY DATA SHEET
Conoco Chemicals Company Houston, TO 77224
1. PRODUCT IDENTIFICATION
MANUFACTURER'S NAME Conoco Chemicals Company
ADDRESS
P.O. Box 727, Westlake, LA 70669
TRADE NAME SYNONYMS
ALFON1C 610- 60
REGULAR TELEPHONE NO. (318) 491-5403
EMERGENCY TELEPHONE NO.(318) 491-5142
2. HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT
%
HAZARD DATA
-
3. PHYSICAL DATA
BOILING POINT (F) VAPOR PRESSURE (mm Hg.) VAPOR DENSITY (AIR = 1) SOLUBILITY IN WATER APPEARANCE AND ODOR
IBP 377
SPECIFIC GRAVITY (H20 =1) 0.98
<1 e 70F
PERCENT VOLATILE BY VOLUME (%)
EVAPORATION RATE { =1) '
Approx. 2%
MELTING POINT
Clear colorless liquid. Sweet pungent odor.
_i^5.28?
.. J
4. FIRE AND EXPLOSION DATA
FLASH POINT (TEST METHOD)
-2a48opF/p(PMMI)
ATEUMTPOEIRCANTIUTRIOEN
FLAMMABLE LIMITS IN AIR. % BY VOL. LOWER
UPPER 1
EXTINGUISHING
MEDIA
Water spray; carbon dioxide, dry chemical, alcohol approved foam.
SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE AND EXPLOSION HAZARD
Cool exposed equipment with water spray. Self-contained breathing appa ratus should be worn if fighting fires in confined spaces.
WV 000012383
5. HEALTH HAZARD INFORMATION
FIRST AID
EYES:
Flush eyes with large amounts of water for at least 15 minutes. If irritation persists, seek medical aid.
5K|N;
Flush with water, then wash affected area with mild soap and water.
INHALATION: Remove to fresh air. If breathing has stopped, administer artificial respira tion or oxygen. Seek medical aid.
iMrEcrirbU' Do Not Induce Vomiting, if large amounts are ingested, gastric lavage with large amounts INGESTION: Qf water or 5 percent sodium bicarbonate by qualified persons. Seek medical aid.
NATURE OF HAZARD
EY^S*
Irritation may occur with exposure to concentrated vapors. Liquid is contact irritant. May cause corneal inflammation.
5KjN:
Repeated or prolonged contact can cause reddening of the skin, scaling, ana dermatitis.
INHALATION: This material is a negligible hazard due to its low volatility. If vapor is pres ent in high concentrations, irritation to upper respiratory tract may occur.
INGESTION: Low order of toxicity. No hazard by this route in normal use.
EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: Irritation of contacted areas. CHRONIC OVEREXPOSURE: Unknown.
THRESHOLD LIMIT VALUE (TLV)
None established.
TfWIdTY DATA This specific product has not been tested. Data from lUAldlY UAIA a very similar material is below.
SKIN CONTACT: Acute Dermal LDcq, Rabbits: 1.5-1.7 g/kg Skin Irritation Index, Rabbits: 3.2 (Max. possible score is 8.0).
EYE CONTACT:
Eye Irritation Index: 58 (72 hrs. after exposure) (max. possible score is 110)
INHALATION:
All rats survived a 4-hour exposure to 8 mg/I.
INGESTION:
Acute Oral LD50, Rat: 5.1 g/kg.
SPECIAL PRECAUTIONS: Avoid Eye Contact
Vv 0ooj^33 4
6. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY High temperatures.
INCOMPATIBILITY Can react with strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Should not occur.
7. SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Eliminate open flames. Contain the spill.
NEUTRALIZING CHEMICALS
WASTE DISPOSAL METHOD May be picked up mechanically or with a solid sorbent and sent to an approved landfill or incin erated in accordance with federal, state, and local regulations.
SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS Mechanical ventilation may be necessary if working with this product in enclosed areas. Trace amounts of ethylene oxide may be present in the product ana could accumulate In vapor spaces of storage or transport vessels. The ACGIH TLV for ethylene oxide is 10 ppm.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT____________
RESPIRATORY (SPECIFY IN DETAIL): If needed, NIOSH approved organic vapor respirators should be worn.
EYE: Chemical goggles or full-face shield to protect from splash.
GLOVES: Rubber or other impervious material to avoid repeated or prolonged skin contact.
OTHER CLOTHING AND EQUIPMENT: Other impervious clothing as needed to avoid repeated or prolonged skin contact.
Wy OOOOlaags
9. SPECIAL PRECAUTIONS
HAZARD CLASSIHCATION INFORMATION
IMCO HAZARD CLASS AND NUMBER
US DOT CLASSIFICATION No hazard classification.
UN NUMBER
EEC DANGEROUS SUBSTANCE CLASSIFICATION
ADR CLASS NUMBER
EEC SPECIAL RISKS AND SAFETY ADVICE
CAS NUMBER 68439-45-2
TRANSPORTATION AND STORAGE
USUAL SHIPPING CONTAINERS
Tank cars Tank trucks Drums
STORAGE TRANSPORT TEMPERATURE
ELECTROSTATIC ACCUMULATION HAZARD Ambient
STORAGUTRANSPORT PRESSURE Ambient
LOADING/UNLOADSNG TEMPERATURE
Ambient
VISCOSITY AT LOADING/ UNLOADING TEMPERATURE
HANDLING AND STORAGE MATERIALS AND COATINGS
SUITABLE
UNSUITABLE
Carbon steel--if moisture control is suitable.
Recommend baked phenolic coating.
Stainless Steel
Aluminum
Zinc Galvanized
THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH CONOCO BELIEVES RELIABLE AND ARE SUPPLIED FOR INFORMATIONAL PURPOSES ONLY. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WAR RANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO.
NOVEMBER 1982
WV 000012386
CH-260
MATERIAL SAFETY DATA SHEET
conoco
Conoco Chemicals Company Houston, TX 77224
5. HEALTH HAZARD INFORMATION
FIRST AID
EYES:
Flush eyes with large amounts of water for at least 15 minutes. If irritation persists, seek medical aid.
SKIN:
Flush with water, then wash affected area with mild soap and water.
INHALATION: Remove to fresh air. If breathing has stopped, administer artificial respira tion or oxygen. Seek medical aid.
Do Not Induce Vomiting. If large amounts are ingested, gastric lavage with large amounts INGESTION: of water or 5 percent sodium bicarbonate by qualified persons. Seek medical aid.
NATURE OF HAZARD
EYES:
Irritation may occur with exposure to concentrated vapors. Liquid is con tact irritant. May cause corneal inflammation.
SKIN:
Repeated or prolonged contact can cause reddening of the skin, scaling, ana dermatitis.
INHALATION: This material is a negligible hazard due to its low volatility. If vapor is pres ent in high concentrations, irritation to upper respiratory tract may occur.
INGESTION: Low order of toxicity. No hazard by this route in normal use.
EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: Irritation of contacted areas. CHRONIC OVEREXPOSURE: Unknown.
THRESHOLD LIMIT VALUE (TLV)
None established.
TOXICITY DATA
SKIN CONTACT: Acute Dermal LD50, Rabbits: 1.5-5.0 g/kg
Skin Irritation index, Rabbits:]. 5 to 3.2
(Max. possible score is 8.0).
EYE CONTACT:
Eye Irritation Index: 32-58 (72 hrs. after exposure) (max. possible score is 110)
INHALATION:
INGESTION:
Acute Oral LDS0, Rat: 3-5 g/kg.
SPECIAL PRECAUTIONS: Avoid Eye Contact
WV
6. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY High temperatures.
INCOMPATIBILITY Can react with strong oxidizers.
HAZARDOUS DECOMPOSITION PRODUCTS
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Should not occur.
7. SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED Eliminate open flames. Contain the spill.
NEUTRALIZING CHEMICALS
WASTE DISPOSAL METHOD May be picked up mechanically or with a solid sorbent and sent to an approved landfill or incin erated in accordance with federal, state, and local regulations.
SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS Mechanical ventilation may be necessary if working with this product in enclosed areas. Trace amounts of ethylene oxide may be present in the product ana could accumulate in vapor spaces of storage or transport vessels. The ACGIH TLV for ethylene oxide is 10 ppm.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY (SPECIFY IN DETAIL): If needed, NIOSH approved organic vapor respirators should be worn.
EYE: Chemical goggles or full-face shield to protect from splash.
GLOVES: Rubber or other impervious material to avoid repeated or prolonged skin contact.
OTHER CLOTHING AND EQUIPMENT: Other impervious clothing as needed to avoid repeated or prolonged skin contact
VVV 000012389
9. SPECIAL PRECAUTIONS
1 HAZARD CLASSIFICATION INFORMATION
IMCO HAZARD CLASS AND NUMBER
US DOT CLASSIFICATION No hazard classification.
UN NUMBER
EEC DANGEROUS SUBSTANCE CLASSIFICATION
ADR CLASS NUMBER
EEC SPECIAL RISKS AND SAFETY ADVICE
CAS NUMBER 68439-45-2
TRANSPORTATION AND STORAGE
USUAL SHIPPING CONTAINERS Tank cars Tank trucks Drums
STORAGE TRANSPORT TEMPERATURE
Ambient
ELECTROSTATIC ACCUMULATION HAZARD
STORACS/TRANSPORT PRESSURE Ambient LOADING/UNLOADING TEMPERATURE Ambient VISCOSITY AT LOADING/ UNLOADING TEMPERATURE
HANDLING AND STORAGE MATERIALS AND COATINGS
SUITABLE
UNSUITABLE
Carbon steel--if moisture control is suitable.
Recommend baked phenolic coating.
Stainless Steel
Aluminum
Zinc Galvanized
|
THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH CONOCO BELIEVES RELIABLE AND ARE SUPPLIED FOR INFORMATIONAL PURPOSES ONLY. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR INJURY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WAR RANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO.
vvv 001239o
NOVEMBER 1962
CH-260
conoco
MATERIAL SAFETY DATA SHEET
Conoco Chemicals Company
P.O. Box 19029
Houston, TX 77224
1. PRODUCT IDENTIFICATION
MANUFACTURER'S NAME Conoco Chemicals Company
ADDRESS P.O. Box 727, Westlake, LA 70669
TRADE NAME "Alfonic" 1216-30 SYNONYMS
REGULAR TELEPHONE NO. (318) 491-5403
EMERGENCY TELEPHONE NO, (318) 491-5142 j
2. HAZARDOUS INGREDIENTS
MATERIAL OR COMPONENT
%
HAZARD DATA
-
3. PHYSICAL DATA
BOILING POINT (F)
432 0 IBP
VAPOR PRESSURE (mm Hg.) <1 @ 70F -
VAPOR DENSITY (AIR = 1)
SOLUBILITY IN WATER
Nil
SPECIFIC CRAVrrY(H20 =1)
PERCENT VOLATILE BY VOLUME (%) EVAPORATION RATE ( =D
MELTING POINT
j
APPEARANCE AND ODOR
Clear, colorless liquid. Sweet, pungent odor.
0.909 43-47F
4. FIRE AND EXPLOSION DATA
FLASH POINT (TEST METHOD)
?zyQy7F
ipka\ [rtv\)
TAEUMTPOEIRGANTIUTRIOEN
FLAMMABLE LIMITS IN AIR. % BY VOL. LOWER
UPPER
EXTINGUISHING MEDIA
Water spray; carbon dioxide, dry chemical, alcohol-approved foam.
SPECIAL FIRE FIGHTING PROCEDURES
UNUSUAL FIRE AND EXPLOSION HAZARD
Cool exposed equipment with water spray. Self-contained breathing appa ratus should be worn if fighting fires in confined spaces.
VVV GOOOL2391
5. HEALTH HAZARD INFORMATION
FIRST AID
EYES: SKIN:
Flush eyes with large amounts of water for at least 15 minutes. If irritation
perskte. <tgek medical aid.
_______________________________
Flush with water, then wash affected area with mild soap and water.
INHALATION:
Remove to fresh air. If breathing has stopped, administer artificial respira tion or oxygen. Seek medical aid.
IMf'FCTinN* Do Not Induce Vomiting. If large amounts are ingested, gastric lavage with large amounts of water or 5 percent sodium bicarbonate by qualified persons. Seek medical aid.
NATURE OF HAZARD
EYES: SKIN:
Irritation may occur with exposure to concentrated vapors. Liquid is con tact irritant. Mav cause corneal inflammation.
Repeated or prolonged contact can cause reddening of the skin, scaling, ana dermatitis.
INHALATION: This material is a negligible hazard due to its low volatility. If vapor is pres ent in high concentrations, irritation to upper respiratory tract may occur.
INGESTION:
Low order of toxicity. No hazard by this route in normal use.
EFFECTS OF OVEREXPOSURE: ACUTE OVEREXPOSURE: CHRONIC OVEREXPOSURE:
Irritation of contacted areas. Unknown.
THRESHOLD LIMIT VALUE (TLV)
None established.
TOXICITY DATA
SKIN CONTACT:
This sPecifl'c product has not been tested. very similar product is below.
Acute Dermal LDen, Rabbits: ca 4 g/kg Skin Irritation Index, Rabbits: 4.3 (Maximum possible score is 8.0)
Data from a
EYE CONTACT:
Eye Irritation Index in Rabbits: 6.5 (Maximum possible score is 110)
INHALATION:
All rats survived one-hour exposure of 6.3 mg/I.
INGESTION:
Acute Oral LD50, Rat: >5 g/kg
SPECIAL PRECAUTIONS:
Avoid Eye Contact
VVV 000012392
6. REACTIVITY DATA
CONDITIONS CONTRIBUTING TO INSTABILITY High temperatures.
INCOMPATIBILITY ___________________ Can react with strong oxidizers. HAZARDOUS DECOMPOSITION PRODUCTS
CONDITIONS CONTRIBUTING TO HAZARDOUS POLYMERIZATION Should not occur.
7. SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED
NEUTRALIZING CHEMICALS
WASTE DISPOSAL METHOD
May be picked up mechanically or with a solid sorbent and sent to an approved landfill or incin erated in accordance with federal, state, and local regulations.
SPECIAL PROTECTION INFORMATION
VENTILATION REQUIREMENTS
Mechanical ventilation may be necessary if working with this product in enclosed areas. Trace amounts of ethylene oxide may be present in the product ana could accumulate in vapor spaces of storage or transport vessels. The ACGIH TLV for ethylene oxide is 10 ppm.
SPECIFIC PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY (SPECIFY IN DETAIL): If needed, NIOSH approved organic vapor respirators should be worn.
EYE: Chemical goggles or full-face shield to protect from splash.
GLOVES:
Rubber or other impervious material to avoid repeated or prolonged skin contact.
OTHER CLOTHING AND EQUIPMENT:
*VV 0Q0lz$9
Other impervious clothing as needed to avoid repeated or prolonged skin contact.
9. SPECIAL PRECAUTIONS
HAZARD CLASSIFICATION INFORMATION
IMCO HAZARD CLASS AND NUMBER
US DOT CLASSIFICATION No hazard classification.
UN NUMBER
EEC DANGEROUS SUBSTANCE CLASSIFICATION
ADR CLASS NUMBER
EEC SPECIAL RISKS AND SAFETY ADVICE
CAS NUMBER 68551-12-2
TRANSPORTATION AND STORAGE
USUAL SHIPPING CONTAINERS
Tank cars Tank trucks Drums
ELECTROSTATIC ACCUMULATION HAZARD
STORAG^TRANSPORT PRESSURE Ambient
STORAGE TRANSPORT TEMPERATURE Ambient
LOADING/UNLOADING TEMPERATURE Ambient
VISCOSITY AT LOADING/ UNLOADING TEMPERATURE
HANDLING AND STORAGE MATERIALS AND COATINGS
SUITABLE
UNSUITABLE
Carbon steel--if moisture control is suitable
Recommend baked phenolic coating
Zinc Galvanized
Stainless steel
Aluminum
______________________________________________ 1
THE ABOVE DATA IS BASED ON TESTS AND EXPERIENCE WHICH CONOCO BELIEVES RELIABLE AND ARE SUPPLIED FOR INFORMATIONAL PURPOSES ONLY. CONOCO DISCLAIMS ANY LIABILITY FOR DAMAGE OR IN|URY WHICH RESULTS FROM THE USE OF THE ABOVE DATA AND NOTHING CONTAINED THEREIN SHALL CONSTITUTE A GUARANTEE, WAR RANTY (INCLUDING WARRANTY OF MERCHANTABILITY) OR REPRESENTATION (INCLUDING FREEDOM FROM PATENT LIABILITY) BY CONOCO WITH RESPECT TO THE DATA, THE PRODUCT DESCRIBED, OR THEIR USE FOR ANY SPECIFIC PURPOSE, EVEN IF THAT PURPOSE IS KNOWN TO CONOCO.
JULY 1982
VVV 000012394
CH-256