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Material Safety Data Sheet UNIROYAL Uniroyal Chemical Company, Inc. UNIROYAL Emergency Phone: (203) 723*3670 t. World Headquarters Middlebury, CT 06749 CHEMTREC Transportation Emergency Phone: 1-800*424-9300 SAFETY DATA Information (203) 573-3303 MSDS Nn C205001 IDENTIFICATION Trade Name: AMINOX i/ Chemical Name: Diphenylamine-acetone reaction product Date Issued: 7/26/85 CAS Number: 9003-79-6 Chemical Family: Aromatic Amine SPECIAL REGULATORY HAZARDS Ingredient CAS No. Exposure Limit Product 9003-79-6 ND OSHA (1910.1200) Not hazardous EEC* Not hazardous Hazard assessment based on available data. Transportation: NA PHYSICAL DATA Appearance and Odor: Greenish-brown powder; characteristic odor Solubility: Insoluble in water Soluble in benzene & acetone Melting Point: 185F (85C) Boiling Point: NA Other Data: NA Specific Gravity (H2O = 1): 1-16 Vapor Pressure @ 20C. ND Vapor Density (Air =1): ND Volatility @ 70 F: Low FIRE AND EXPLOSION HAZARD DATA FlashPoint: 355 F (179.4 C) TCC Autoignition Temp: ND Extinguishing Media: Water spray, dry chemical Flammable Limits: ND Special Fire Fighting Procedures: Protect against inhalation of combustion products. Unusual Hazards: May form explosive dust-air mixtures. REACTIVITY DATA Stability: Stable at ambient temperatures and pressures. Incompatibility: Strong oxidizing agents. Decomposition Products: Oxides of carbon and nitrogen under burning conditions D 085SA9 cDNrr DFNTrA( NA - Not Applicable ND = Not Determined 'European Economic Community Uniroyal makes no representation or warranty with respect to the information in this Material Safety Data Sheet. The information i$ however, as of this date provided, true and accurate to the best or Uniroyal's knowledge. This list of Information is not intended to be all inclusive. Actual conditions of use and handling may require considerations of information other than, or in addition to, that which is provided herein. SPECIAL PROTECTION INFORMATION ---------------------- Engineering Controls: Sufficient ventilation to minimize vapor exposure. Avoid accumulation of dust on surfaces of Building and equipment. Personal Protection Equipment: Avoid all personal contact. Observe good personal hygiene. Impervious gloves and goggles should be worn when handling. In the absence of adequate ventilation, use NIOSHapproved dust cartridge respirator. STORAGE, SPILLS AND DISPOSAL INFORMATION ------- Storage: Store away from sources of direct heat in a dry area. Keep containers closed when not in use. Spills: Sweep or vacuum up. Shovel into secure containers for proper disposal. Avoid creating dust. Use personal protective equipment as outlined above. Disposal: In accordance with any applicable local, state, federal regulation regarding organic waste. Environmental Information: Environmental effects have not been determined. HEALTH RELATED DATA ------- Specific Hazard(s): No health hazards have been identified. Primary Route(s) of Entry. Inhalation and skin absorption. First Aid Procedures. Eye contact: Flush with water for 15 minutes. Skin contact: Wash thoroughly with soap and water Inhalation: Remove to fresh air. Toxicology Information: toxicity: LD50 (rats) - > 5 g/kg Irritation: eye (rabbits) - negative skin (rabbits) - negative No history of any significant adverse effects noted with long-term production and and use of this material. DO s5870 DOMp lOFNTTAl OxyChem______ t MATERIAL SAFETY DATA SHEET V MSDS NUMBER t M8363 MSDS DATE : 10-02-91 PRODUCT NAME : AMMONIA, ANHYDROUS 24 HOUR EMERGENCY PHONE: (716) 278-7021 I. PRODUCT IDENTIFICATION HMIS HAZARD RATINGS HEALTH HAZARD 3* FIRE HAZARD 1 REACTIVITY 1 Based on the National Paint & Coatings Association HMIS rating system. SARA/TITLE III HAZARD CATEGORIES (See Section X) Immediate (ACUTE) Health: YES Delayed (Chronic) Health: YES Fire Hazard: NO Reactive Hazard: NO Sudden Release of Pressure: YES MANUFACTURER'S: NAME AND ADDRESS Occidental Chemical Corporation, Agricultural Products, 4830 West Kennedy Blvd, Suite 950 Tampa, Florida 33609 (Telephone 813-286-3800) CHEMICAL NAME: Ammonia CAS NUMBER: SYNONYMS/COMMON NAMES: Ammonia Gas, Anhydrous Ammonia CHEMICAL FORMULA: NH3 DOT PROPER SHIPPING NAME: Ammonia. Anhydrous DOT HAZARD CLASS: 2.2 DOT I.D. NUMBER: UN 1005 DOT HAZARDOUS SUBSTANCE: RQ 100# ADDITIONAL/DESCRIPTION REQUIREMENT: Inhalation hazard 7664-41-7 II. HEALTH HAZARD INFORMATION EMERGENCY AND FIRST AID PROCEDURES EYES: OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY AND THEN SEEK MEDICAL ATTENTION. IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes while forcibly holding eyelids apart to ensure complete irrigation of all eye and lid tissue. Washing eyes within one (1) minute Is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY. oo 085871 CAS Chemical Abstract Service Number ecu OSMA Permissible Exposure Limit ND C0*F No reievent information found or not Corporate Exposure Limit confidential TLV > ACGJH Threshold Limit Vlui, Current * > See Chronic Effects Information NA Not epplit v"*v` IMPORTANT The information presented herein whil not guaranteed, was prepared by competent technical personnel end true and accurate to the best of our Knowledge, NO WARRANTY. OR GUARANTY, EXPRESS OR IMPLIED I* MADE RECAR0INC PERFORMANCE, stability, DR OTHERWISE. This information is net intended to be e 11-inclusiva as to the manner end conditions of use, handling end storege other factors mey involve other or eddttionet safety or performenco considerotions wniio our technical personnel will be nappy to respond to questions regarding safe handling end use procedures, safe handling end use remains the responsibility of the customer No suggestions for use are intended as, and nothing herein shell be construed as a rocommendat<on to infringe any existing patents or violate any Pederai, State or local laws OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA, ANHYDROUS Page 2 of 7 10-02-91 II. HEALTH HAZARD INFORMATION (Continued) SKIN: IMMEDIATELY flush contaminated skin with water and wash with soap and water. If clothing Is penetrated, IMMEDIATELY use safety shower - remove clothing and flush skin with copious amounts of water for at least 15 minutes. GET PROMPT MEDICAL ATTENTION. Wash clothino before reuse. INHALATION: Move exposed person to fresh air at once. Keep affected person warm and at rest. If breathing is difficult, have trained person administer oxygen. If breathino has stopped, perform mouth-to-mouth resuscitation. GET IMMEDIATE MEDICAL ATTENTION. INGESTION: Unlikely to occur. If victim quantities of water IMMEDIATELY. IMMEDIATE MEDICAL ATTENTION. Is conscious, administer large Do not Induce vomiting. GET ROUTES OF EXPOSURE INHALATION: Irritation of upper respiratory tract occurs above 140 ppm. Ammonia fumes may cause difficulties which may be delayed In onset. at concentrations severe breathing SKIN: Severe irritant. Contact severe burns of the skin. with liquid ammonia may produce EYE CONTACT: Aqueous Ammonia rapidly penetrates permanent damage. Exposure to high temporary blindness. Contact with severe eye burns. ocular tissue and may concentrations may liquid ammonia may cause cause cause INGESTION: Not a likely route of exposure. EFFECTS OF OVEREXPOSURE ACUTE: Severely irritating to tracts. Contact with irreversible damage. skin, eyes, liquid may respiratory and digestive cause severe burns and CHRONIC: Prolonged inhalation of ammonia at concentrations above the PEL may cause bronchitis and/or pneumonia, with residual reduction In pulmonary function. TOXICOLOGY DATA: Acute Inhalation LC50 Acute inhalation LC50 (mouse) (rat) 4230 ppm(2945 mg/m3)lhr 2000 ppm(1400 mg/m3)4hr Inhalation of concentrations of 1750-4600 mg/m3 (2430-6390 ppm) causes shortness of breath, bronchospasm, chest pain and pulmonary edema which may be fatal. Maximum tolerable concentration in one hour Is between 210-350 mg/m3 (290-485 ppm). Prolonged and repeated exposure to very high concentrations (eg: 165ppm) may also result in kidney damage. Subchronic (42-day) Inhalation toxicity studies were performed In rats, guinea pigs, rabbits, dogs and monkeys. Animals were exposed for 8hr/day, 5 days/week over a dose range of 165-611 ppm. At the low dose, nonspecific changes were observed in lungs and kidneys. At the high dose (611ppm) all animals developed pneumonitis and many had kidney damage. In a second subchronic inhalation study with rats and mice, 500 ppm ammonia induced increases in the weights of the lungs and kidneys plus signs of upper respiratory tract Irritation. DO 085872 ^onftdfnttai OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA. ANHYDROUS Pago 3 of T 10-02-91 III. IMPORTANT COMPONENTS CAS HUMBER / NAME 7664417 Ammonia EXPOSURE LIMITS STEL=35 ppm; 27 mg/m3 TLV-25 ppm; 17 mg/m3 STEL"35 ppm; 24 mg/m3 COMMON NAMES: ANHYDROUS AMMONIA Listed On(List Legend Below): 01 02 13 18 21 PERCENTAGE VOL WT 99.70 99.70 See Section II All components of this product that are required to be on the TSCA Inventory are listed on the inventory. Not listed as carcinogen - I ARC, NTP. OSHA LIST LEGEND 1 SARA EXTR HAZ SUB, SECTION 302 13 PA ENVIROMENTAL HAZ SUBSTANCE 21 NJ SPECIAL HEALTH HAZ SUB 2 SARA TOXIC CHEM, SECTION 313 18 NY HAZARDOUS SUBSTANCES IV. FIRE AND EXPLOSION DATA FLASH POINT: NA AUTOIGNITION TEMPERATURE: 651C (1204F) FLAMMABLE LIMITS IN AIR, % BY VOLUME- UPPER: LOWER: 27 16 EXTINGUISHING MEDIA: Use water spray, fog, foam, dry chemicals. C02, or other agents as appropriate for materials in the fire. SPECIAL FIRE FIGHTING PROCEDURES: Use NIOSH/MSHA approved positive pressure breathing apparatus and full protective equipment. if tanks are leaking or heavily exposed to heat. self-contained Evacuate area UNUSUAL FIRE AND EXPLOSION HAZARD: Excessive heat will form nitrogen oxides. V. SPECIAL PROTECTION VENTILATION REQUIREMENTS: Provide good general room ventilation to minimize exposure. Use local exhaust ventilation at points of emission. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY: Use NIOSH/MSHA approved ammonia vapor where airborne exposure is excessive. respirator for areas EYE: Wear safety glasses with side shields or chemical goggles. GLOVES: Wear protective gloves made of vinyl, neoprene or rubber to minimize skin contact. Wash thoroughly after handling. OTHER CLOTHING AND EQUIPMENT: Eye wash facility and emergency shower should be proximity. Use of chemical resistant c1oth1ng,face rubber shoes are recommended. in close shield and 0q C-0l\lpr 3 0FrHTl4, OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA, ANHYDROUS Page 4 of 7 10-02-91 VI. PHYSICAL DATA BOILING POINT 9 760 mm Hg : -33.3C <-28"F) MELTING POINT: -77.7C VAPOR PRESSURE: 5 ATM IV 4.4C (40*F) SPECIFIC GRAVITY (H2O-1): 0,7 9 -33.3C SOLUBILITY IN H2O % BY WT: 51 (V 20C VAPOR DENSITY <Alr=l): 0.597 80C and 1 ATM APPEARANCE AND ODOR: Colorless gas, pungent odor pH : NA % VOLATILE: 100 VII. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY: Avoid heat and ignition sources. Avoid storage with oxidizing gases, chlorine, bromine, iodine, and acids. May form explosive compounds on contact with silver, mercury or halogens. Reacts with copper, copper alloys, aluminum alloys and galvanized surfaces. INCOMPATIBILITY: Silver, mercury, halogens, copper, alloys and galvanized surfaces. copper alloys, aluminum , HAZARDOUS DECOMPOSITION PRODUCTS: Products of decomposition include oxides of nitrogen. VIII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: Store in a cool, dry, well ventilated, f1 re-res 1stant area separate from acids and oxidizing gases, bleach and chlorates. Provide automatic monitoring system. Avoid copper, copper alloy, aluminum alloy or galvanized fittings. Wear protective equipment to prevent contact. IX. ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Keep unprotected people away. Stay upwind of source. Personnel involved in clean-up must wear full protective equipment and self-contained breathing apparatus. Use copious amounts of water spray to reduce concentration and vapor pressure. Contaminated area and equipment should be thoroughly washed down with water. Do not allow substance to enter sewers or streams. WASTE DISPOSAL METHOD: Dilute with water and drain to waste treatment facilities. Dispose of in accordance with federal, state and local regulations. Report spills of 100 pounds or more to the National Response Center, 1-800-424-8802. DO OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA. ANHYDROUS Page 5 of 7 10-02-91 X. ADDITIONAL INFORMATION Shipment regulated by US DOT. Classified as non-flammable material, requires a non-flammable DOT label. and is assigned UN # 1005. Designated hazardous substance by 29 CFR Sec 1910 Subpart Z by OSHA. Designated hazardous substance by ACGIH. Sec 311 of Clean Water Act lists as hazardous which, If discharged to or upon water may require Immediate response to mitigate danger to public. Spills of 100 pounds or more must be reported to the National Response Center 1-800-424-8802, Listed under provisions of Sec 304 of The Clean Water Act which requires the EPA administrator to establish water quality criteria reflecting the latest scientific knowledge concerning specific pollutants. Listed on a composite list as required under Sec 101(14) of the Comprehensive Environmental Response. Compensation and Liability Act (CERCLA), usually referred to as Superfund. OSHA Standard 29CFR 1910. 1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, material safety data sheets, training and access to written records. We request that you, and it Is your legal duty to, make all Information in this Material Safety Data Sheet available to your emp1oyees. To aid our customers In complying with regulatory requirements, SARA Title III hazard categories for this product are indicated in Section I. If the word "YES" appears next to any category, this product may be reportable by you under the requirements of 40 CFR Part 370. Please consult those regulations for details. This product contains a toxic chemical or chemicals subject to the reporting requirements of SECTION 313 of TITLE III of the SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT OF 1986 and 40 CFR PART 372. (See Section I I I.List Legend 02) XI. PREPARATION INFORMATION For additional Non-Emergency health, safety, or environmental information telephone (716) 286-3606, or write to: Occidental Chemical Corporation Product Stewardship Department Suite 400 360 Rainbow Boulevard South Niagara Falls, NY 14302 For Emergencies: 24 HOUR EMERGENCY PHONE: (716) 278-7021 This MSDS replaces OCC MSDS dated 10/02/90. no 088B78 CONnnFNtTAt OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA, ANHYDROUS Page 6 of 7 10-02-91 WARNING LABEL INFORMATION Occidental Chemical Corporation Agricultural Products Inc. 4830 West Kennedy Blvd., Suite 950, Tampa, Florida 33609 (Telephone 813-286-3800) In case of CHEMICAL EMERGENCIES - Call (716) 278-7021 (24 hours) CAS Number: 7664-41-7 SIGNAL WORD: DANGER STATEMENT OF HAZARDS: COMPRESSED LIQUIFIED GAS UNDER PRESSURE. LIQUID CAUSES SEVERE BURNS TO EYES AND SKIN. VAPOR EXTREMELY IRRITATING TO EYES, SKIN AND RESPIRATORY MAY BE FATAL IF INHALED OR INGESTED. PROLONGED EXPOSURE MAY REDUCE PULMONARY FUNCTION. TRACT. PRECAUTIONARY STATEMENTS: Do not breathe vapor. Insure adequate ventilation or use NIOSH/MSHA approved respirator with ammonia cartridge. Do not get In eyes, on skin or on clothing. Use goggles, face shield and rubber boots. Wear gloves and protective clothing made of vinyl, neoprene or rubber, Keep away from heat, sparks and open flame. FIRST AID: IN CASE OF CONTACT: FOR EYES: OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY AND THEN SEEK MEDICAL ATTENTION. IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes while forcibly holding eyelids apart to ensure complete Irrigation of all eye and lid tissue. Washing eyes within one (1) minute Is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY. FOR SKIN: IMMEDIATELY flush contaminated skin with water and wash with soap and water. If clothing is penetrated, IMMEDIATELY use safety shower - remove clothing and flush skin with copious amounts of water for at least 15 minutes. GET PROMPT MEDICAL ATTENTION. Wash clothing before reuse. IF INHALED: Move exposed person to fresh air at once. Keep affected person warm and at rest. If breathing is difficult, have trained person administer oxygen. If breathing has stopped, perform mouth-to-mouth resuscitation. GET IMMEDIATE MEDICAL ATTENTION. IF SWALLOWED: Unlikely to occur. If victim quantities of water IMMEDIATELY. IMMEDIATE MEDICAL ATTENTION. is conscious, administer large Do not induce vomiting. GET IN CASE OF: SPILL OR LEAK: Wear full protective equipment and clothing Use copious amounts of water spray to reduce concentrat 1on vapor pressure. Evacuate unprotected personnel in downwind areas Keep contaminated water out of sewers and streams and Do 085876 CONFTDFNTTAI. OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA. ANHYDROUS Page 7 of 7 10-02-91 WARNING LABEL INFORMATION (Continued) FIRE*. Wear self-contained breathing apparatus and full protective c1oth1no. Use water spray, foam, dry chemicals, C02 or other extinguishing medium as appropriate for surrounding fire. Evacuate area if tanks are leaking or heavily exposed to heat. HANDLING AND STORAGE: Store in cool, monitoring system. dry, well Store separate from acids, and metals. ventilated area with oxidizing gases, bleach, automatic chlorates DISPOSAL: Dilute with water and drain to waste treatment facilities. Dispose of regu1 at 1ons. in accordance with federal, state and local Report spills of 100 pounds or more to the National Response Center, 1-800-424-8802. INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS: This product contains: CAS# 7664417 NAME Ammonia HMIS RATING SYSTEM: HEALTH 3* FLAMMABILITY 1 REACTIVITY 1 FOR INDUSTRIAL USE ONLY LABEL For further information, Request OCC MSDS M8363 101M8363 DO 085877 CONFIDENTIAL OxyChem, MATERIAL SAFETY DATA SHEET \ ----------------------------------------------------------------------------------------------------------------------------------------- MSDS NUMBER M8363 MSDS DATE 10-02-91 PRODUCT NAME AMMONIA, ANHYDROUS 24 HOUR EMERGENCY PHONE: (716) 278-7021 I. PRODUCT IDENTIFICATION HMIS HAZARD RATINGS HEALTH HAZARD 3* FIRE HAZARD 1 REACTIVITY 1 Based on the National Paint & Coatings Association HMIS rating system. SARA/TITLE III HAZARD CATEGORIES (See Section X) Immediate (ACUTE) Health: YES Delayed (Chronic) Health: YES Fire Hazard: NO Reactive Hazard: NO Sudden Release of Pressure: YES MANUFACTURER'S: NAME AND ADDRESS Occidental Chemical Corporation, Agricultural Products, 4830 West Kennedy Blvd, Suite 950 Tampa. Florida 33609 (Telephone 813-286-3800) CHEMICAL NAME: Ammonia CAS NUMBER: SYNONYMS/COMMON NAMES: Ammonia Gas. Anhydrous Ammonia CHEMICAL FORMULA: NH3 DOT PROPER SHIPPING NAME: Ammonia, Anhydrous DOT HAZARD CLASS: 2.2 DOT I.D. NUMBER: UN 1005 DOT HAZARDOUS SUBSTANCE: RQ 100# ADDITIONAL/DESCRIPTION REQUIREMENT: Inhalation hazard 7664-41-7 II. HEALTH HAZARD INFORMATION -------------------------------------------------------------------------------------------------------------------------------------------------------- oo 085fi7 C0^dpnt?a, EMERGENCY AND FIRST AID PROCEDURES EYES: OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY AND THEN SEEK MEDICAL ATTENTION. IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes while forcibly holding eyelids apart to ensure complete irrigation of all eye and lid tissue. Washing yes within one (1) minute is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY. CAS Chemical Abstract Service NumOtr NO < No relevant information found or not available EL i OSHA PBrniissibls Exposure Limit CORA * Corporato Exposure Limit T l V ACC t H Threshold Limit Valut, Currant * too Chronic Effects Information na i Net applicable IMPORTANT. Th# information presented hrin while not guaranteed, was prepared by competent technical personnel and 15 trui And accurate to the bast Of our knowledge. NO WARRANTY. OR GUARANTY, EXPRESS OR IMPLIES IS MAOE RECAROINC PERFORMANCE, STABILITY. OR OTHERWISE. This information is not intended to be a 11 -ino 1u$lve a to the manner and conditions of use, handling and storage other factors may involve other or additional safety or par f or manea considiritions wh1 1a our technical personnel will be nappy to respond to questions regarding safe handling and use procedures, safe handling end use remains the responsibility of the customer. No suggestions for u$e are intended as, and nothing herein shall be construed as e recommendation to infringe any existing patents or violate any Federal, State or local laws OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA, ANHYDROUS Page 2 of 7 10-02-91 II. HEALTH HAZARD INFORMATION (Continued) SKIN; IMMEDIATELY flush contamlnated skin with water and wash with soap and water. If clothing Is penetrated, IMMEDIATELY use safety shower - remove clothing and flush skin with copious amounts of water for at least 15 minutes. GET PROMPT MEDICAL ATTENTION. Wash clothing before reuse. INHALATION: Move exposed person to fresh air at once. Keep affected person warm and at rest. If breathing Is difficult, have trained person administer oxygen. If breathing has stopped, perform mouth-to-mouth resuscitation. GET IMMEDIATE MEDICAL ATTENTION. INGESTION; Unlikely to occur. If victim quantities of water IMMEDIATELY. IMMEDIATE MEDICAL ATTENTION. is conscious, administer large Do not induce vomiting. GET ROUTES OF EXPOSURE INHALATION; Irritation of upper respiratory tract occurs above 140 ppm. Ammonia fumes may cause difficulties which may be delayed in onset. at concentrat 1ons severe breathing SKIN: Severe irritant. Contact severe burns of the skin. with liquid ammonia may produce EVE CONTACT: Aqueous Ammonia rapidly penetrates permanent damage. Exposure to high temporary blindness. severe eye burns. Contact with ocular tissue and may concentrat 1ons may liquid ammonia may cause cause cause INGESTION: Not a 1Ikely route of exposure. EFFECTS OF OVEREXPOSURE ACUTE: Severely irritating to tracts. Contact with irreversible damage. skin, liquid eyes, respiratory and digestive may cause severe burns and CHRONIC: Prolonged inhalation of ammonia at concentrat1ons above the PEL may cause bronchitis and/or pneumonia, with residual reduction in pulmonary function. TOXICOLOGY DATA: Acute Inhalation LC50 Acute inhalation LC50 (mouse) (rat) 4230 ppm(2945 mg/m3)lhr 2000 ppm(1400 mg/m3)4hr Inhalation of concentrations of 1750-4600 mg/m3 (2430-6390 ppm) causes shortness of breath, bronchospasm, chest pain and pulmonary edema which may be fatal. Maximum tolerable concentration in one hour is between 210-350 mg/m3 (290-485 ppm). Prolonged and repeated exposure to very high concentrat 1ons (eg: I65ppm) may also result In kidney damage. Subchronic (42--day) Inhalation toxicity studies were performed in rats, guinea pigs, rabbits, dogs and monkeys. Animals were exposed for 8hr/day, 5 days/week over a dose range of 165-611 ppm. At the low dose, nonspecific changes were observed in lungs and kidneys. At the high dose (611ppm) all animals developed pneumonitis and many had kidney damage. In a second subchronic inhalation study with rats and mice, 500 ppm ammonia Induced increases in the weights of the lungs and kidneys plus signs of upper respiratory tract Irritation. 00 085879 00NFTDENTTAI OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA, ANHYDROUS Pago 3 of 7 10-02-91 III. IMPORTANT COMPONENTS CAS NUMBER / NAME 7664417 Ammon 1a EXPOSURE LIMITS STEL=35 ppm; 27 mg/m3 TLV=25 ppm; 17 mg/m3 STEL=35 ppm; 24 mg/m3 COMMON NAMES: ANHYDROUS AMMONIA Listed On(List Legend Below) 01 02 13 18 21 PERCENTAGE VOL WT 99.70 9970 See Section II All components of this product that are required to be on the TSCA Inventory are listed on the inventory. Not listed as carcinogen - IARC, NTP, OSHA LIST LEGEND 1 SARA EXTR HAZ SUB, SECTION 302 13 PA ENVIROMENTAL HAZ SUBSTANCE 21 NJ SPECIAL HEALTH HAZ SUB 2 SARA TOXIC CHEM, SECTION 313 18 NY HAZARDOUS SUBSTANCES IV. FIRE AND EXPLOSION DATA FLASH POINT: NA AUTOIGNITION TEMPERATURE: 651C (1204F) FLAMMABLE LIMITS IN AIR. % BY VOLUME- UPPER: LOWER: 27 16 EXTINGUISHING MEDIA: Use water spray, fog, foam, dry chemicals, C02, or other agents as appropriate for materials in the fire. SPECIAL FIRE FIGHTING PROCEDURES: Use NIOSH/MSHA approved positive pressure breathing apparatus and full protective equipment. if tanks are leaking or heavily exposed to heat. self-contained Evacuate area UNUSUAL FIRE AND EXPLOSION HAZARD: Excessive heat will form nitrogen oxides. V. SPECIAL PROTECTION VENTILATION REQUIREMENTS: Provide good general room ventilation to minimize exposure. Use local exhaust ventilation at points of emission. SPECIFIC PERSONAL PROTECTIVE EQUIPMENT RESPIRATORY: Use NIOSH/MSHA approved ammonia vapor where airborne exposure is excessive. respirator for areas EYE: Wear safety glasses with side shields or chemical goggles. GLOVES: Wear protective gloves made of vinyl, neoprene or rubber to minimize skin contact. Wash thoroughly after handling. OTHER CLOTHING AND EQUIPMENT: Eye wash facility and emergency shower should be in close proximity. Use of chemical resistant cl othing,face shield and rubber shoes are recommended. DO 0 conf 1 OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA, ANHYDROUS Page 4 of 7 10-02-91 VI. PHYSICAL DATA BOILING POINT 760 mm Hg: -33.3C (-28F> MELTING POINT: -77.7C VAPOR PRESSURE: 5 ATM 4.4"C (40F) SPECIFIC GRAVITY (H20-1): 0.7 9 -33.3C SOLUBILITY IN H2O % BY WT: 51 20C VAPOR DENSITY <A1r=l): 0.597 80"C and 1 ATM APPEARANCE AND ODOR: Colorless gas, pungent odor pH : NA % VOLATILE: 100 VII. REACTIVITY DATA CONDITIONS CONTRIBUTING TO INSTABILITY: Avoid heat and Ignition sources. Avoid storage with oxidizing gases, chlorine, bromine, iodine, and acids. May form explosive compounds on contact with silver, mercury or halogens. Reacts with copper, copper alloys, aluminum alloys and galvanized surfaces. INCOMPATIBILITY: Silver, mercury, halogens, copper, alloys and galvanized surfaces. copper alloys, aluminum HA/ARDCJS DECOMPOSITION PRODUCTS: Products of decomposition include oxides of nitrogen. VIII. HANDLING AND STORAGE HANDLING AND STORAGE PRECAUTIONS: Store in a cool, dry, well ventilated, fire-resistant area separate from acids and oxidizing gases, bleach and chlorates. Provide automatic monitoring system. Avoid copper, copper alloy, aluminum alloy or galvanized fittings. Wear protective equipment to prevent contact. IX. ENVIRONMENTAL PROCEDURES STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED: Keep unprotected people away. Stay upwind of source. Personnel involved In clean-up must wear full protective equipment and self-contained breathing apparatus. Use copious amounts of water spray to reduce concentrat 1on and vapor pressure. Contaminated area and equipment should be thoroughly washed down with water. Do not allow substance to enter sewers or streams. WASTE DISPOSAL METHOD: Dilute with water and drain to waste treatment facilities. Dispose of in accordance with federal, state and local regulations. Report spills of 100 pounds or more to the National Response Center, 1-800-424-8802. 0 085881 CONFTOFNrrAI. OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA, ANHYDROUS Page 5 of 7 10-02-91 X. ADDITIONAL INFORMATION Shipment regulated by US DOT. Classified as non-flammable material, requires a non-flammable DOT label, and Is assigned UN # 1005. Designated hazardous substance by 29 CFR Sec 1910 Subpart Z by OSHA. Designated hazardous substance by ACGIH. Sec 311 of Clean Water Act lists as hazardous which, if discharged to or upon water may require immediate response to mitigate danger to public. Spills of 100 pounds or more must be reported to the National Response Center 1-800-424-8802. Listed under provisions of Sec 304 of The Clean Water Act which requires the EPA administrator to establish water quality criteria reflecting the latest scientific knowledge concerning specific pollutants. Listed on a composite list as required under Sec 10a(14) of the Comprehensive Environmental Response. Compensation and Liability Act (CERCLA), usually referred to as Superfund. OSHA Standard 29CFR 1910. 1200 requires that information be provided temployees regarding the hazards of chemicals by means of a hazard communication program Including labeling, material safety data sheets, training and access to written records. We request that you, and it is your legal duty to, make all information in this Material Safety Data Sheet available to your emp1oyees. To aid our customers in complying with regulatory requ1rements, SARA Titl= III hazard categories for this product are Indicated in Section I. If the word "YES" appears next to any category, this product may be reportable by you under the requirements of 40 CFR Pa'-t 370. Please consult those regulations for details. This produc-1 contains a toxic chemical or chemicals subject to the reporting requirements of SECTION 313 of TITLE III of the o.JPERFUND AMENDMENTS AND RE AUTHOR IZAT I ON ACT OF 1986 and 40 CFR PART 372. <See Section I I I,List Legend 02) XI. PREPARATION INFORMATION For additional Non-Emergency health, safety, or environmental information telephone (716) 286-3606, or write to: Occidental Chemical Corporation Product Stewardship Department Suite 400 360 Rainbow Boulevard South Niagara Falls, NY 14302 For Emergencies: 24 HOUR EMERGENCY PHONE: (716) 278-7021 This MSDS replaces OCC MSDS dated 10/02/90. r->0 08588? confidential OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA. ANHYDROUS Page 6 of 7 10-02-91 WARNING LABEL INFORMATION Occidental Chemical Corporation Agricultural Products Inc. 4830 West Kennedy Blvd., Suite 950, Tampa. Florida 33609 (Telephone 813-286-3800) In case of CHEMICAL EMERGENCIES - Call (716) 278-7021 <24 hours) CAS Number: SIGNAL WORD: 7664-41-7 DANGER STATEMENT OF HAZARDS: COMPRESSED LIQUIFIED uAS UNDER PRESSURE. LIQUID CAUSES SEVERE BURNS TO EYES AND SKIN. VAPOR EXTREMELY IRRITATING TO EYES. SKIN AND RESPIRATORY MAY BE FATAL IF INHALED OR INGESTED. PROLONGED EXPOSURE LAY REDUCE PULMONARY FUNCTION. TRACT. PRECAUTIONARY STATEMENTS: Do not breathe vapor. Insure adequate ventilation or use NIOSH/MSHA approved respirator with ammonia cartridge. Do not get in eyes, on skin or on clothing. Use goggles, face shield and rubber boots. Wear gloves and protective clothing made of vinyl, neoprene or rubber. Keep away from heat, sparks and open flame. FIRST AID: IN CASE OF CONTACT: FOR EYES: OBJECT IS TO FLUSH MATERIAL OUT IMMEDIATELY AND THEN SEEK MEDICAL ATTENTION. IMMEDIATELY flush eyes with a directed stream of water for at least 15 minutes while forcibly holding eyelids apart to ensure complete irrigation of all eye and lid tissue. Washing eyes within one (1) minute Is essential to achieve maximum effectiveness. SEEK MEDICAL ATTENTION IMMEDIATELY. FOR SKIN: IMMEDIATELY flush contaminated skin with water and wash with soap and water. If clothing is penetrated, IMMEDIATELY use safety shower - remove clothing and flush skin with copious amounts of water for at least 15 minutes. GET PROMPT MEDICAL ATTENTION. Wash clothing before reuse. IF INHALED: Move exposed person to fresh air at once. Keep affected person warm and at rest. If breathing is difficult, have trained person administer oxygen. If breathing has stopped, perform mouth-to-mouth resuscitation, GET IMMEDIATE MEDICAL ATTENTION. IF SWALLOWED: Unlikely to occur. If victim quantities of water IMMEDIATELY. IMMEDIATE MEDICAL ATTENTION. is conscious, administer large Do not induce vomiting. GET IN CASE OF: SPILL OR LEAK: Wear full protective equipment and clothing Use copious amounts of water spray to reduce concentration vapor pressure. Evacuate unprotected personnel In downwind areas Keep contaminated water out of sewers and streams and D0 065883 confidential OCCIDENTAL CHEMICAL MSDS NUMBER: M8363 PRODUCT NAME: AMMONIA, ANHYDROUS Pao 7 of 7 10-02-91 WARNING LABEL INFORMATION (Continued) FIRE: Wear self-contained breathing apparatus and full protective cloth 1ng. Use water spray, foam, dry chemicals, C02 or other extinguishing medium as appropriate for surrounding fire. Evacuate area If tanks are leaking or heavily exposed to heat. HANDLING AND STORAGE: Store in cool. monitoring system. dry, well Store separate from acids, and metals. ventilated area with oxidizing gases, bleach, automatic chlorates DISPOSAL: Dilute with water and drain to waste treatment facilities. Dispose of in accordance with federal, state and local regulations. Report spills of 100 pounds or more to the National Response Center, 1-800-424-8802. INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS: This product contains: CAS# 7664417 NAME Ammonia HMIS RATING SYSTEM: HEALTH 3* FLAMMABILITY 1 REACTIVITY 1 FOR INDUSTRIAL USE ONLY LABEL For further information, Request OCC MSDS M8363 101M8363 Do 085884 confidential -ANG'S STANDARD SOLUTIONS, INC 13445 S. Harrell's Ferry Road Baton Rouge, Louisiana 70816 MATERIAL SAFETY DATA SHEET SECTION 1 - NAME & PRODUCT CATALOG NO.: 1E43 CHEMICAL NP.MEs Ammonium Hydroxide 10YTRADE NAME 5 SYNONYMS: Ammonia Water CHEMICAL FAMILY r. Alkali Solution FORMULA: M/A / SECTION - PHYSICAL DATA / BOILING POINT 760 mm Hg <*C> : '103*C-108*C MELTING POINT ("c): N/A VAPOR PRESSURE & 0*C: 1 VAPOR DENSITY tair=l): l. PERCENT VOLATILES BY VOLUME: 100* SPECIFIC GRAVITY (KE0=1>: 1.00 SOLUBILITY IN HE0, */. BY WT. Oe'C: Miscible APPEARANCE AND ODOR; Greenish colored liquid EVAPORATION RATE (BUTYL ACETATES): N/A with pungent odor SECTION 3 - FIRE & EXPLOSION HAZARD DATA FLASH POIN''-TEET.' METHOD: N/A LEl: N/A UiSL s N/A EXTINGUISHING MEDIA: Appropriate fire. SPECIAL HAZARDS & PROCEDURES: N/A UNUSUAL FI HE & EXPLOSION HAZARDS: for N/A extinguishing surrounding SECTION 4 - REACTIVITY DATA STABLE/UNSTAULE: Stable MATERIALS TO AVOID: Acids Oxidizers HAZARDOUS DECOMPOSITION PRODUCTS: Ammonia Nitrogen compounds SECTION 5/- SPILLS OR LEAK PROCEDURES ft DISPOSAL STEPS TO L< TAKEN 'IN CASE MATERIAL IS RELEASED OR SPIlLED: PickUD with absorbent. Rinse area with water. WASTE DISPOSAL METHOD: In accordance with local 5tate and federal regulations. SECTION & - HEALTH HAZARD THRESHOLD LIMIT VALUE: Toxicity: LD50 (ORL-RAT) 350 mg/Kg EFFECTS OF OVEREXPOSURE: Irritant to skin eyes mucous membranes and resoj. i-afco.-y tract. FIRST AID P lOCr-LDURES; Rinse eyes and skin with clean water. If inhaled - remove to fresh air. If irritation persists - see a physician. m SECTION 7 - PROTECTION INFORMATION VENTILATION, RESPIRATORY PROTECTION, PROTECTIVE CLOTHING, EYE PROTECTION; Use only with adequate ventilation. Do not breathe fumes. Use of safety glasses and gloves is recommended. SECTION 8 - SPECIAL HANDLING ft STORING PRECAUTIONS SPECIAL HANDLING AND STORING PRECAUTIONS: Store out of sunlight and away from heat. Keep container closed when not in use. SECTION 9 - HAZARDOUS INGREDIENTS (refer to Sections 3 through 8) Ammonium thc'roxide 10% as NHC4II0H DO 08588fe COMF1 DENT TAl SECTION 10 - OTHER INFORMATION NFPA: HEALTH *= 3 FLAMMABILITY = 1 REACTIVITY = O CORROSIVE MATERIAL. DUT - AUTHORIZED SIGNATURE EMERGENCY TELEPHONE NUMBER: DATE ISSUED: May 17, 138& (504)91-0011 DO 085887 CONFTDFNTTAl. ANOXSYIT442 ANTI XIDANT SYNERGIST Jflf,pEe?, EMERGENCY TELEPHONE NUMBERS: (215) 337-6615 (800) 424-9300 (CHEMTREC) PENNWALT CORPORATION PERFORMANCE CHEMICALS DEPT. 900 FIRST AVENUE KING OF PRUSSIA, PA 19406 MATERIAL SAFETY DATA SHEET PRODUCT IDENTIFICATION PRODUCT NAME ANOXSYN '"442 PENNWALT CODE NUMBER 9559-2 CHEMICAL NAME ALIPHATIC SULFIDE CAS NUMBER PROPRIETARY CHEMICAL FAMILY ALIPHATIC SULFIDE HAZARDOUS INGREDIENTS MATERIALS OR COMPONENTS ALIPHATIC SULFIDE HWW 100 SEE REVERSE SIDE FOR DATA ON TOXICITY SHIPPING INFORMATION DOT I.D. NO. NA DOT CLASS NA SHIPPING NAME NA PHYSICAL PROPERTIES PHYSICALSTATE BOILING POINT/RANGE NE MELTING POINT 56-66C FREEZING POINT HE MOLECULAR WEIGHT (CALCULATED) CA 700 SPECIFIC GRAVITY (HtO-1) 0,85 70C VAPOR PRESSURE (mm Hg) NE VAPOR DENSITY (AIR - 1) HE SOLUBILITY IN H,0 NONE H VOLATILES BY VOLUME NA EVAPORATION RATE HE APPEARANCE AND ODOR WHITE POWDER FIRE AND EXPLOSION DATA PLASH POINT (TEST METHOD) NE FLAMMABLE LIMITS HE AUTOIQNITION TEMPERATURE/ FIRE POINT NE EXTINGUISHING MEDIA ID DRY CHEMICAL S) WATER FOG H COi SPECIAL FIRE FIGHTING PROCEDURES HE UNUSUAL FIRE AND EXPLOSION HAZARDS HE REACTIVITY DATA, CONTINUED HAZARDOUS DECOMPOSITION PRODUCTS, THERMAL AND OTHER: NE CONDITIONS TO AVOID SI HEAT SI OPEN FLAMES SIIGNITION SOURCES SPILL OR LEAK STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED E SWEEP OR SCOOP UP AND REMOVE [2 FLUSH WITH WATER WASTE DISPOSAL METHOD: DISPOSE IN ACCORDANCE WITH ALL APPLICABLE LOCAL, STATE, AND FEDERAL REGULATIONS REACTIVITY DATA STABILITY S) STABLE CONDITIONS CONTRIBUTING TO INSTABILITY NE INCOMPA TIBILITY--A VOID CONTACT WITH ID STRONG ACIDS NA - NOT APPLICABLE NE - NOT ESTABLISHED oo 0858^8 C'NFjfrpNT TAL CONTINUED ON OTHER SIDE MATERIAL SAFETY DATA SHEET BEFORE USING PRODUCT, READ AND FOLLOW DIRECTIONS AND PRECAUTIONS ON PRODUCT LABEL AND BULLETINS, PENNMLT _ PRODUCT NAME: ANOXSYNm 442 ANTIOXIDANT SYNERGIST CODE NUMBER: roxtcmr ORAL (ACUTE! LDso (RAT) - >5.000 mg/kg DERMAL (SCUTE) LDo (RABBIT) -->2,000 mg/kg (NO TOXIC EFFECTS) INHALATION (ACUTE) NE CHRONIC, SUBCHRONIC, ETC. THIS MATERIAL IS NOT LISTED BY IARC, NTP OR OSHA AS A CAR CINOGEN NEGATIVE IN THE AMES ASSAY. OTHER EFFECTS Nfe HEALTH HAZARD INFORMATION PERMISSIBLE EXPOSURE LIMIT (TLV/TWA OR CEILING (CJ) ACGIH NE OSHA NE IRRITATION NON IRRITATING TO SKIN AND EYES SENSITIZATION NE HEALTH HAZARD INFORMATION, CONTINUED EMERGENCY FIRST AK) INGESTION IS GET MEDICAL ATTENTION SI INDUCE VOMITING DERMAL SI FLUSH WITH SOAP AND WATER IS CONTAMINATED CLOTHING- REMOVE AND LAUNDER EYE CONTACT IS GET MEDICAL ATTENTION IS FLUSH WITH PLENTY OF W/ FOR AT LEAST 15 MINUTES INHALATION SI GET MEDICAL ATTENTION IS REMOVE TO FRESH AIR SPECIAL PROTECTION INFORMATION VENTILATION REQUIREMENTS-- ALWAYS MAINTAIN EXPOSURE BELOW PERMISSIBLE EXPOSURE LIMITS IS USE WITH ADEQUATE VENTILATION EYE IS SAFETY GLASSES HANDJQLOVE TYPE) IS POLYVINYL CHLORIDE SI NEOPRENE SI BUTYL RUBBER IS NATURAL RUBBER IS POLYVINYL ALCOHOL IS POLYETHYLENE RESPIRATOR TYPEUSE ONLY NIOSH/MESA APPROVED EQUIPMENT SI FILTER. DUST, FUME. MIST OTHER PROTECTIVE EQUIPMENT NA SPECIAL PRECAUTIONS PRECAUTIONARY LABELING ISwASH THOROUGHLY AFTER HANDLING. SI DO NOT GET IN EYES, ON SKIN OR CLOTHING. SI DO NOT BREATHE DUST, VAPOR MIST. GAS SI KEEP AWAY FROM HEAT SPARKS AND OPEN FLAMES OTHER HANDLING AND STORAGE CONDITIONS j PREPARED BY: RICHARD G. ADAMS DATE: 3/10/8B ADDRESS: PENNWALT CORPORATION PERFORMANCE CHEMICALS DEPARTMENT 900 FIRST AVENUE KING OF PRUSSIA, PA 19406 PHONE: (215) 337-6615 PLEASE NOTE The strove mformuon is accurate to the best tX out knowledge. However, since data, salary standards, and government regulations arv subject Id change and the oondkkms ot handSng and use, or misuse, an beyond our control, PennwaC MAKES NO WARRANTY, EITHER EXPRESS OR IMPLIED. WITH RESPECT TO THE COMPLETENESS OR CONTINUING ACCURACY OF THE INFORMATION CONTAINED HEREIN AND DISCLAIMS ALL LIABILITY FOR RELIANCE THEREON. Uaar should safety hrmseH that he has a! currant data relevant lo las particular use. 085B89 DO Al- OONf7