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Analysis of PFOA and PFOS in Water Samples from Hastings Municipality
E05-0186
Exygen Report No. L0004709
s eee r Testing Lae boratory ereseeeee eesemen Exygen Research
3058 Research Drive
State College, PA 16801
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Manager, Environmental Operations
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1 Introduction
Re(sPuOlSs)ianrwearteeprosraiemdpfloerthreecaenisvieydssstoEfxpyegreuncarosorcetquaensctaetde(bPyFGOaAr)yHnodhepnesrliosrhooofc3iaMnCssaumfpoannsyte. aThneaEexsygqenuparojnecfitonrutmhbeasearimapeslseisdg.ned 1 tesamples aLOODATOS. Table|iststhe target
Tab|. TargetAnaesforGuartiston
Earmoter Pertuoroociancats
Parfucroocianssutonale
conn PFOAorCB ocd PROS orC8mifonste
Fomita CFC00" CFoSOy
2 SampleReceipt rFeoquuressatmopfl3eWs,woefrseamrpsloessiwveedraoiaEnxaylgyzeendi.nA5c0o0pymlo.fwlhitseapmlpalsetlicognanmofwor-mmaotuitohnbaistreess.enAttedhe AtochmenAt TshamepslaemspwleersdwsetorreerderceeirveeadtoendfrYoDm10m5e.oTfhreoscaompptulnetswaenrsehsailp.ped ambientviaUPS. Tha
3 Met-hAnoalydticsal andPreparatory TsuhoenEaxleg(ePnFOmSe)t,hPoedrsfnuoireodoc,ta"nMeesiuhloodnoyfaAmniadleys(iPsFfOoSrAt)h,eaDnedtePremrinuactrioooncioafnPceartteuo(rFoOoRcAi)nne sWuamlemra,r"myoodfiftiheedsfaompilseopmrerespeapraarteiicnoa,nwbeesfusoed{iu0nSperncetpidaornee3n.1daanndatlhyzeemothdesfaemdpaensa.esA ondiionsforsomesseparation canbefoundinSection 3.2.
34 Water Sample Preparation FoSrotypmhialsleeresxtorfactthieon l(eSrPEs)awmapsluewsaesdrtoapnrseipeamraedthoew8aGtyeSsPaEmpcalretsifdogre.LTChMeSIcaMrSiadlgyeswies.e w1a0s0h%emdwetihhan5 dmi.Aofpaa4rt0o%nomfehahenedx:t6e0ct%wwaaslterrawnassfehr.reTdhteocautaosarmpwlatesrevrikaesiadnwddiah5ngamlyLezosfd using seckospray LCMSIS.
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32 SampleAnalbyyLCsIMiSMsS
EIsnt0aHutioggnhhdPrryapeIhsuasiusdrepehLniabgsueeiCdcCoCMlhauvmtomnoargt8roaIgtrEhaNepGhicoyot(lHeuPmLqnCu.)i,dBamnaoasbeqdlueoepnhaotsfheee,xathrnaeictaiosnfajteeecstaarndeadinaydnpeTdaosotsree8d afncdrnaacacgurrmaataeeamcnnemdiaotdnueesrelfsoordcfreas,dnm.aeil.yTzFiohnlegoowoiwnnisgdcehHraParLnaCgcseieoepferorsratgtcaionofni,:tcmhoaemscpsoosmuppneodcust.noMdmosloetacyruperlocevbsiaadsreresvenadaaaspndid, Queangantsteixvoacisdtstanedardds.
AsanmpHlPe1e100xsysaftoormciqnutatenrafiasocne.d10anApplied Bicsystams API4000wasusedfoanslyzsthe
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Thefollowing parametaswereused foroperation ofthemassspectrometer;
oPrairzaamteotnetrioda TProatntsytons Morkorad OGraysigTGemapse(rNa2te
Shocmioyrpray 44N1e1g53a53t3h76e.00 ((P"FCO-AP)F,O4A9,6s-ur5r8o0ga(tPeOsSpi)k.e) 7305U0min
4 Analysis 41 Calibration
0APdFTOo1An00P!0cnFaolOb.rnaSd(i5opn")CcfuoPrrFvOLeACw.MaTSshI.MaSansahstsse. oColabnrrdatttonphsrciearnpcraaroimdehseaaurneaepygrioecopahalo rseeodquuseuint ncgettfho.r swaamselSPoEpfforretcohepcuodsened.dUosriusnagmrpnleeeas.reTghreesIsnisotnrwumiehnt1rxew#poohsievge,rshuesstohepceo,n-cmenivrectaopnt
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21 countofGeerinaton ()weredlemine. Acacburvea1sactcoto aie n72 iFnortthohrarwedsautssrinaApotraecdhhmere,nCcta.librationcerawero met. Thecalbcurrvesaarteinociunded 42 Surrogates ws"aaCsmpaPindFgdO.eRId(inCoFhfauhlef"eedCm,IpaFtAysCsIaeOmmOpHel)eacnsoudrtsqaeiundaearysscobanetfsrouortleobgtoathtieeestfwooratrethese wfwlaeetdeo(r0s.sa8anmvtpol1ekosa.mheerfCc oPlFfnOoA withtesample. CPFOArecoverscanbe oundinAtachment. 43 LaboratoryControl Spikes Loo`afrssPmeFsOasAm.netchCaondPaFcOcsAu.iraakncsdyP.iTEthGheaStaisooarabsotarnsykernytworaerlasSgrakane.reLeMubsakySabhdocwonornetarcokolsrvaaorkweenstsbceaobonewoencreianer7yt0o0.n 1i3t0%iothreatchcaedpettaablieerjacnigde.. Forheroesrari hrs, the abrsiryconv ateswars 44 Fold Matrix Spikes Colmkodpwfoouarnsnaddmsp8lwiinaggrh.emMaaadldtiessdspptokieehwseeeremopptrseyepsdaar0mepdalsweiecooentstheamsienetehrrosibdeeafacocnurdreastcayhmiplteheemspawitatsrete.esTnehen1m0faethh,ee S5PpiEkSeswsohroeuwdsihno1woreccoverciesabaasnsgeen70-130%.For 0 resusreported hers,te maine 45 Sample Related Comments ThAtoavcarlmorans8tampiswore cotectsd bn dupicate. Duplalo sampleresus re roared
5 Data Summary FipeaarssespoaeAblaocnh(erngi!mL8 oorraPFOtAalaendiPnRgOSof.the natalrouts.Theresus rereporied
Pacesors
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6 Statoefm Ace cun rat cy
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7 Data/Sample Retention
aH`haSeoramdG pcaloepsycwa iamlotabfaedrap sceaotirnunemdeedshdcootaroans3.Mr6pey0rrduameysrtafsteeer yiwnoalrrre.pToihrnteicdngh.eAtlolwe dlellosommeoacodanstta3sr i0saoo orycnhnEiviersdoncsn
8 Attachments
71 AtachmenAt: Antic Results 72 Anachmaas:SpaRecoveryDea 73 AtachmanC: CraofCustodyForma 74 Atacand: RawAcovalaa
9 Signatures
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~ SECTION A
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Summary of PFOA and PFOS in Water Samples E05-0186
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Field Matrix Spike Recovery SummfoarPrFOyA and PFOSin Water E05-0188
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282005 Project: E05-4186
:
3M ENVIRONMENTAL LABORATORY
CONTRACTLABORATORYWORK ORDERBY SAMPLE
`Contract Lab(e): EXYGEN.
Pagelort
Requester: Hobenstein, Gary A (0042-0227) DePrpoejtecmteNnutm:be3r0:7010122674449 DPraotjeecRtecDeeisvcreidp:ti2o2n5:7H2a0s0t5ings Municipal Well FC's11
`CompletionDate: PPrhoojneectNLuemabde:rK:e6n5tL1i-n7d7s8t-r3o5m2 Email Adres: krindstrom@eneom com
sou 2/257o%s 5"
Comments:
.
Pace flld saplng.
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`Nota: Reference ripbiaok on E0S-0184. DOJ224/05
505.0186 samples traveled wih B0S-0184 samples. AC, PLI, 22872005.
3 Sample Number __ Sampled Date _ Sample Description
E0S-018679868. 2202005 HW6207643
APmFwOiAsCode
APuFtrOiAtalMethod PCFoOmpAensms
PFOS.
`PROSby ESMS
PrOS
E0S-0186-79869 AuPaFiOnAi.sCote: #FOS
2202005 HW6207643 Duo.
APuFivOtAicalMeded PCRonOsAents
PFOS by BSMS
PrOS
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A301m372a00D8bueaDaite 3152008 Aa1l5n2i0a0D5unDate. 152005
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