Document DDoge32L7poNk2nJ9GD21dpYo

OxyChem MATERIAL SAFETY DATA SHEET Responsible Care* lift Public Commitmwit 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION MSDS NUMBER: PRODUCT NAME : M9192 VINYL CHLORIDE (MONOMER) ISSUE DATE: 06-12-97 Manufacturer's Name and Address : Occidental Chemical Corporation, Occidental Tower 5005 LBJ Freeway, P.O. Box 809050 Dallas, TX 75380 (972)404-3800 24 HOUR EMERGENCY TELEPHONE : TO REQUEST AN MSDS : CUSTOMER SERVICE : PRODUCT USE : PVC manufacturing 1-800-733-3665 OR 972 404 -3228 1-800-699-4970 I-800 752 5151 S' CHEMICAL NAME : Ethylene, Chloro- CHEMICAL FORMULA : Mixture d t_ H , SYNONYMS/COMMON NAMES : MONOCHLOROETHYLENE CHLQROETHENE HTIIpNE, CHLORO vm 2. COMPOSITION/INFDRMATION ON INGREDIENTS CAS NUMBER / NA$?E 75-01-4 ifekene, chioro- EXPOSURE LIMITS PEL:See 1910.1017 TLV: 5 pptn; 13 mg/m3 ; TWA, A1 COMMON NAMES: MONOCHLOROETHYLENE VINYL CHLORIDE# VINYL CHLORIDE MONOMER Listed On(List Legend Below): 00 02 OS 08 11 15 18 21 22 45 50 51 PERCENTAGE VOL WT ND 99-100 OCC 11761 oxv Occidental Chemical Corporation OCCIDENTAL CHEMICAL CORPORATION MSDS NUMBER : M9X92 PRODUCT NAME : VINYL CHLORIDE (MONOMER) PAGE 2 OF 11 06-12-97 2. COMPOSITION/INFORMATION ON INGREDIENTS (Continued) # Chemical name used in the SARA Section 313 List of Toxic Chemicals (40 CFR - Section 372.65) if different from CAS name. LIST LEGEND 00 TSCA INVENTORY 06 NTP "KNOWN HUMAN CARCINOGEN" 11 CA PROP 65 - CARCINOGEN 18 NY HAZARDOUS SUBSTANCES 22 CANADIAN DOMESTIC SUB LIST 50 PHILIPPINES INVENTORY (PICCS) 02 SARA TOXIC CHEM, SECTION 313 08 IARC HUMAN CARCINOGEN, GROUP 1 15 PA SPECIAL & ENV HAZ SUBSTANCE 21 NJ SPECIAL HEALTH HAZ SUB 45 EPA/OSHA ACCIDENTAL RELEASE 51 EINECS 3. HAZARDS IDENTIFICATION *********************** * * * Colorless gas, "sweet EMERGENCY odor" OVERVIEW *************!)************* * * * POTENTIAL HEALTH EFFECTS _ ROUTES OF ENTRY: 9 9999-COOS There are no standard TARGET ORGANS: PP0B9- J4, |S, IZ A There are no standard statements statements ent^rad for ..1 -4 4" M ::s> entered for this this section. section. IRRITANCY: 1/2.1 There are no standard sta|emdnts entered for this section. SENSITIZING CAPABILITY: 99909- /O ^ There are no stHhdard statements entered for this section. REPRODUCTIVE EFFECTS. /07 4V There are no standard statements entered for this section. CANCER INFORMATION: vm*-/BSl There are no standard statements entered for this section. SHORT-TERM EXPOSURE (ACUTE) INHALATION: [4 35. 2I>7 There are no standard statements entered for this section. OCC 11762 EYES: There are no standard statements entered for this section. SKIN: L&9-9-9_ (j) j There are no standard statements entered for this section. OCCIDENTAL CHEMICAL CORPORATION MSDS NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) PAGE 3 OF 11 06-12-97 3. HAZARDS IDENTIFICATION (Continued) INGESTION: 99999 ST- There are no standard statements entered for this section. REPEATED EXPOSURE (CHRONIC) 9-9 9 93 There are no standard statements entered for this section. SYNERGISTIC MATERIALS: z&aw /oT- There are no standard statements entered for this section. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: -2^3^ /52. There are no standard statements entered for this - yt, ,v,v,v.`.v.vc sect:ioi. Revised 4. FIRST AID MEASURES EYES: /Sf ,, There are no standard statements entered for this section. SKINr jf|j. 164 #% For contact with liquid or cold gas gu|iok 1 y remove victim from source of contamination and flush l<j$c%#sfcrm (100-105) not hot, flowing water until the chemical is removed. DO %OT attempt to re-warm the affected area on site. DO NOT rub area or apply dry heat. Loosely cover with a dry sterile pressing. GET MEDICAL ATTENTION QUICKLY. INHALATION: 1899 Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops, have a trained person administer artificial respiration. GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: t '% 179 IJ NEVER GIVE ANYTH I IJQyB Y MOUTH TO AN UNCONSCIOUS PERSON. Have patient drink several glasses of water then induce vomiting by having patient tickle back of throat with finger. Keep airway clear. GET MEDICAL ATTENTION IMMEDIATELY. NOTES TO PHYSICIAN: 2.2.7.A There are no standard statements entered for this section. 5. FIRE FIGHTING MEASURES Flash Point: -78C (-108f') Method: Mat--wa^-L-abl-e '~T~^ Autoignition Temperature: 882F OCC 11763 OCCIDENTAL CHEMICAL CORPORATION MSDS NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) PAGE 4 OF II 06-12-97 5. FIREFIGHTING MEASURES (Continued) FLAMMABLE LIMITS IN AIR, BY % VOLUME Upper: 33.0 Lower: 3.6 EXTINGUISHING MEDIA: 206 Dry chemical, carbon dioxide, foam, water fog or spray. Water may be ineffective, but should be used to keep fire-exposed containers cool. 207 If a leak or spill has not ignited, use water spray to disperse the vapors and to protect persons attempting to stop leak. FIRE FIGHTING PROCEDURES: i3c>e> FIRE AND EXPLOSION HAZARD: 303 For large cargo fires, evacuate all personnel to at least 1/2 mile in all directions due to danger of exploding vessels. Down wind areas may require additional evacuation due to toxic products of combustion. Do not attempt to extinguish largli^,.,hires. Evacuate the area and notify the fire department. If possible t.o do without danger to personnel, containers exposed to intense bifeat from fires should be cooled with water to prevent vapor pressure buildup which could result in container rupture. Container areas exposed to direct flame contact should be cooled with large c0f^.ntities of water as needed to prevent weakening of container st ructuro. SENSITIVITY TO MECHANICAL IMPACT: 05^9- (o'! There are no standard statements entered for this section. SENSITIVITY TO STATIC DISCHARGE '% There are no standard statemerits entered for this section. 6. ACCIDENTAL RELEASE MEASURES w.. PERSONAL PRECAUTIONS: siaas-a- $\2_ There are no standard statements entered for this section. ENVIRONMENTAL PRECAUTIONS: 314 According to 40 CFR 302 Table 302.4 (CERCLA), environmental releases that_exceed the RQ must be reported to the National Response Center by calling 800-424-8802 (202-426-2675) and the State Emergency Response Commission and the Local Emergency Planning Committee (40 CFR 355.40) as appropriate. METHODS FOR CLEANING UP: There are no standard statements entered for this section. OCC 11764 OCCIDENTAL CHEMICAL CORPORATION MSD.S NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) PAGE 5 OF 11 06-12-97 7. HANDLING AND STORAGE HANDLING: 359 Keep away from sources of ignition. The vapors can travel to an ignition source and flash back causing a flash fire. SPECIAL MIXING AND HANDLING INSTRUCTIONS: -9-9-9-99 3^ There are no standard statements entered for this section. STORAGE: ass** 3G>9,3SS There are no standard statements entered for this section. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION ENGINEERING CONTROLS: PERSONAL PROTECTION RESPIRATORY: 468 Avoid breathing vapor. If exposure may or does exceed occupational exposure limits (Sec III) use a NIOSlfpsapproved respirator as required to prevent overexposure. In accord wjft'ti 29 CFR 1910.134, use an atmosphere supplying respirator (ai#1Ine or self-contained breathing apparatus) . No air purifying respi^lffrb^ilias been approved for vinyl chloride. EYE/FACE: 41 I | There are no standard sta^fagiits entered for this section. f' % SKIN: H 12.GZ. Wear chemical resistant gloves such as rubber, neoprene or vinyl. OTHER: n 4 94 Emergency showef "ifid eyewash facility should be in close proximity (ANSI Z358.1). 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance and Odor: Colorless gas, "sweet odor" Odor Threshold: Not available Specific Gravity (Water=l): 0.91 @ 25C/25C Vapor Pressure: 1,210 mm Hg @ 20C Vapor Density (Air=l): 2.IE Density: Not available occ 11765 OCCIDENTAL CHEMICAL CORPORATION MSDS NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) 9. PHYSICAL AND CHEMICAL PROPERTIES (Continued) Evaporation Rate: >15 % Volatiles by Wt: 100 Boiling Point: 7F Freezing Point: Not available Melting Point: -245F Solubility in Water (% by wt.): Slight pH: Not determined Octanol/Water Partition Coefficient: Not available Thermal Decomposition Temperature: Not available Other: This material is a gas at atmospheric pressure and room temperature. VOC (g/1. by wt.): Not applicable PAGE 6 OF 11 06-12-97 10. STABILITY AND REACTIVITY CHEMICAL STABILITY: STABLE REACTS WITH: X Alt" _____ water X HEAT HAZARDOUS POI.YMIiftlZATlON: 1 X OCCURS X UNSTABLE X OXIDIZERS ACIDS ALKALIS X METALS OTHER NONE _______ WILL NOT OCCUR COMMENTS: 9^9^ ------------------------------------------------------------------------------------------------------------------ There are no standard statements entered for this section. HAZARDOUS DECOMPOSITION PRODUCTS: /Z?0 There are no standard statements entered for this section. ISsiCK 11. TOXICOLOGICAL INFORMATION 743~ ' 75-01-4 Ethene, chloro- ------ ACUTE ORAL LD50 : (rat) ACUTE INHALATION LC50 : (rat) OCC 11766 500 mg/kg 150,000 mg/kg OCCIDENTAL CHEMICAL CORPORATION MSDS NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) PAGE 7 OF 11 06-12-97 11. TOXICOLOGICAL INFORMATION (Continued) Vinyl chloride has been demonstrated to be mutagenic in cultured cell tests, insects, and laboratory animals. It is also listed as a human carcinogen by OSHA, IARC (Group 1) and NTP. Long term exposure to vinyl chloride has caused liver and other cancers in animals and humans. At high concentrations vinyl chloride can cause central nervous depression, affect heart rhythms, and cause liver and kidney damage. Prolonged and repeated exposure may result in changes in the blood system and loss of bone from finger tips. 12. ECOLOGICAL INFORMATION o Ecological Data Available. 13. DISPOSAL CONSIDERATIONS There are no standard statements entered for this section. 14. TRANSPORT INFORMATION DOT PROPER SHIPPING NAME; Vinyl Chloride, Stabilized DOT HAZARD CLASS: 2.1 DOT IDENTIFICATION NUMBER!" U%08 6 DOT PACKING GROUP: Not Applicable DOT HAZARDOUS SUBSTANCE(S): RQ 1 Lb. (Vinyl Chloride) DOT MARINE POLL||TAftT (S) : Not Applicable ADDITIONAL DESC|lPTtON REQUIREMENT: Not Applicable OCC 11767 15. REGULATORY INFORMATION U.S. FEDERAL REGULATIONS: 880 This product contains a toxic chemical or chemicals subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR 372. See Section 2, List Legend 02. 877 OSHA Standard 29 CFR 1910.1200 requires that information be provided to employees regarding the hazards of chemicals by means of a hazard communication program including labeling, material safety data sheets, training and access to written records. We request that you, and it is your legal duty to, make all information in this Material Safety Data Sheet available to your employees. OCCIDENTAL CHEMICAL CORPORATION MSD3 NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) PAGE 8 OF 11 06-12-97 15. REGULATORY INFORMATION (Continued) 879 To aid our customers in complying with regulatory requirements, SARA Title III Hazard Categories for this product are indicated below. If the word "YES" appears next to any category, this product may be reportable by you under the requirements of 40.CFR.370. Please consult those regulations for details. TSCA: SARA/TITLE III HAZARD CATEGORIES: Immediate(Acute) Delayed(Chronic) Fire Hazard: Health: Health: YES YES YES -------------------------- Reactive Hazard Sudden Release of Pressurei % HMIS HAZARD RATINGS: HEALTH HAZARD: 3* FIRE HAZARD: 1 % 4 REACTIVITY: YES YES 2 STATE REGULATIONS: 8 88 ,,,, State of California Safe Drinking Water and l$spxic Enforcement Act of 1986 (Proposition 65) : || WARNING: This product contains a chemical known to the State of California to cause cancer. 1112 M, See Section 2. COM POSITION/INFORMAT10^ ON INGREDIENTS list legend for applicable state regulation. |n...% INTERNATIONAL REGULATIONS: ^ '* 894 Consult the regulations oj^afehe importing country. 99999 It"" There are no standard statements entered for this section. CANADA: 0 WHMIS Hazard Class: Not Rated/ 16. OTHER INFORMATION 895 7".............. ' "" " For additional non-emergency health, safety or environmental information telephone (972) 404-2405 or write to: Occidental Chemical Corporation Product Stewardship Department 5005 LBJ Freeway P.0. Box 809050 Dallas, Texas 75380 OCC 11768 OCCIDENTAL CHEMICAL CORPORATION MEDS NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) 16. OTHER INFORMATION (Continued) PAGE 9 OF 11 06-12-97 MSDS LEGEND: ACGIH = American Conference of Governmental Industrial Hygienists CAS = Chemical Abstracts Service Registry Number CEILING = Ceiling Limit (15 Minutes) CEL = Corporate Exposure Limit OSHA = Occupational Safety and Health Administration PEL Permissible Exposure Limit (OSHA) STEL = Short Term Exposure Limit (15 Minutes) ^ TDG = Transportation of Dangerous Goods (Canada) c: TLV = Threshold Limit Value (ACGIH) ........... TWA = Time Weighted Average (8 Hours) . WHMIS = Worker Hazardous Materials Information System (Canada) * = See Section 3 Hazards Identification - Repeated Exposure(Chronic) Information J:, #% IMPORTANT: The information present^a^&rein, while not guaranteed, was prepared by competent technicall^fli^lDnnei and is true and accurate to the best of our knowledge. NO WARRANTY OF MERCHANTABILITY OR FITNESS FOR PURPOSE, OR OF ANY OTHER KIND, EXPRESS OR IMPLIED, IS MADE REGARDING PERFORMANCE, STABIDJTY OR OTHERWISE. This information is not intended to be all-inclus|ve as to the manner and conditions of use, handling and storage. Other factors may involve other or additional safety or perfprmgnce considerations. While our technical personnel will be happy Lb respond to questions regarding safe handling and use procedures, safe handling and use remains the responsibility of the customer. No suggestions for use are intended as, and nothingiifibf^in shall be construed as a recommendation to infringe any existi hi) patents or violate any federal, state or local laws, rules, regulations or ordinances. Revised 17. WARNING LABEL INFORMATION SIGNAL WORD: 898 DANGER OCC 11769 HAZARD WARNINGS: 99999 THERE ARE NO STANDARD STATEMENTS ENTERED FOR THIS SECTION. PRECAUTIONS: 355 Keep away from flame. 1000 Keep container heat, sparks, pilot lights, tightly closed and properly welding operations labeled. and open OCCIDENTAL CHEMICAL CORPORATION ['CDS NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) PAGE 10 OF 11 06-12-97 17. WARNING LABEL INFORMATION (Continued) 1005 Never enter a pit or tank without following safety procedures - never alone, always with a lifeline, and always with a positive pressure supply of fresh air. Avoid use in confined spaces. 997 Ground and bond equipment to prevent electrostatic charge when pouring pellets. FIRST AID EYES: 99999 There are no standard statements entered for this sectaon. SKIN: 164 For contact with liquid or cold gas; quickly remove victim from source of contamination and flush lukewarm (100-105) not hot, flowing water until the chemical is removed. DO NOT attempt to re-warm the affected area on site. DO NOT rub area or apply'"'dry heat. Loosely cover with a dry sterile dressing. GET MEDICAL.^JTENTION QUICKLY. INHALATION: ft 189 9 Remove to fresh air. If breathing is difficult, have trained person administer oxygen. If respiration stops, have a trained person administer artificial respiration. MEDICAL ATTENTION IMMEDIATELY. INGESTION: 1 179 " l- NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. Have patient drink several glasses of waL-er then induce vomiting by having patient tickle back of throat with frtoger. Keep airway clear. GET MEDICAL ATTENTION IMMEDIATELY. IN CASE OF SPILL OR LEAK: ; 99999 There are no standard statements entered for this section. FIRE: I 99999 || ;;i There are no standard statements entered for this section. HANDLING AND STORAGE: 99999 There are no standard statements entered for this section. DISPOSAL: 99999 There are no standard statements entered for this section. INFORMATION REQUIRED BY FEDERAL, STATE OR LOCAL REGULATIONS: This Product Contains: CAS# NAME OCC,, .U.770 75-01-4 Ethene, chloro- HMIS RATING: HEALTH 3* FLAMMABILITY 4 REACTIVITY 2 OCCIDENTAL CHEMICAL CORPORATION KSDS NUMBER : M9192 PRODUCT NAME : VINYL CHLORIDE (MONOMER) 17. WARNING LABEL INFORMATION (Continued) LABEL NUMBER: 110M9192 1110 For Industrial Use Only PAGE 11 OP 11 06-12-97 OCC 11771