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Material Safety Data Sheet Hoechst Celanese Hoechst Celanese Corporation Route 202-206 North Somerville, NJ 08876 Telex 833 449 Fax 201 231 3225 THE EMERGENCY PHONE NUMBER IS. (201) 231-2244 FOR OTHER PRODUCT SAFETY INFORMATION CALL. (201) 231-2132 PAGE 1 ----------------------------------------------------------------PRODUCT IDENTIFICATION------------------------------------------------------ VERSION DATE. 11/28/89 DATE PRINTED. 11/28/89 PRODUCT NAME. M5DS NUMBER. 1103706080 11-1101 PERMANENT YELLOW G SYNONYMS < C.I. PIGMENT YELLOW 14, Cl #21095 ----------------------------------------------------------------HAZARDOUS INGREDIENTS-------------------------------------------------------- INGREDIENT. THIS PRODUCT IS NOT REGULATED UNDER THE OSHA HAZARD COMMUNICATION STANDARD, 29CFR1910.1200. OR S.A.R.A. TITLE III. PERCENT. HAZARD DATA. PHYSICAL DATA PHYSICAL DATA MELTING POINT SOLUBILITY IN WATER PH LOW >250 6.1 HIGH UNITS C COMMENT NEGLIGIBLE APPEARANCE AND ODOR. YELLOW SOLID, NO ODOR FIRE AND EXPLOSION HAZARDS EXTINGUISHING MEDIA. CARBON DIOXIDE, WATER SPRAY, FOAM OR DRY CHEMICAL. SPECIAL PROCEDURES. USE SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING. UNUSUAL HAZARDS. ELECTRICAL GROUNDING OF EQUIPMENT IS REQUIRED WHEN HANDLING POWDER TO PREVENT POSSIBLE DUST EXPLOSION. EMITS TOXIC FUMES UNDER FIRE CONDITIONS. ------------------------------------------------------------------ HEALTH INFORMATION----------------------------------------------------------------- PRIMARY ROUTE OF EXPOSURE. INHALATION. YES SKIN ABSORPTION. NO INGESTION. NO EFFECTS OF OVEREXPOSURE. FOUND TO BE A NON-IRRITANT WHEN TESTED ON SKIN AND EYES OF RABBITS. TOXICITY. ROUTE TEST ORL-RAT LD 50 DOSE UNITS >10,000 MG/KG COMMENTS (1) TOXICITY TEXT. (1) DATA ON BASE PIGMENT. CARCINOGEN. IARC. NO NTP. NO OSHA. NO --------------------------------------------------------- OCCUPATIONAL EXPOSURE LIMITS TEXT; NOT ESTABLISHED. 00 8665? CO/s/p* rDF'VTTA( VlUv ;hstEB Material Safety Data Sheet HoechstCelanes Hoechst Celanese Corporation Roule 202 206 North Somerville, NJ 08876 Telex 833 449 Fax 201 231 3225 THE EMERGENCY PHONE NUMBER IS. (201) 231-2244 FOR OTHER PRODUCT SAFETY INFORMATION CALL* (201) 231-2132 PAGE 2 PRODUCT NAME. 11-1101 PERMANENT YELLOW 0 MSDS NUMBER. 1103706080 ------------------------------------------------------- EMERGENCY AND FIRST AID PROCEDURE--------------------------------------- INHALATION. CONSULT PHYSICIAN IF IRRITATION OF RESPIRATORY PASSAGES OCCURS. EYE CONTACT. FLUSH THOROUGHLY WITH WATER FOR 15 MINUTES. CONSULT PHYSICIAN IF IRRITATION CONTINUES. SKIN CONTACT. WASH WITH SOAP AND WATER. CONSULT PHYSICIAN IF IRRITATION CONTINUES. INGESTION: IF PERSON IS CONSCIOUS, GIVE WATER OR MILK TO DILUTE STOMACH CONTENTS. CONSULT PHYSICIAN. ADDITIONAL MEASURES. NONE FOUND ------------------------------------------------------------------REACTIVITY DATA----------------------------------------------------------------- CHEMICAL STABILITY. STABLE HAZARDOUS POLYMERIZATION. WILL NOT OCCUR HAZARDOUS DECOMPOSITION PRODUCTS: THERMAL DECOMPOSITION MAY GENERATE CARBON MONOXIDE, CARBON DIOXIDE AND OXIDES OF NITROGEN ------------------------------------------ SPILL OR LEAK PROCEDURES/WASTE DISPOSAL--------------------------------------- SPILL OR LEAK PROCEDURES. WEARING APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT, CONTAIN SPILL, VENTILATE AREA OF SPILL OR LEAK COLLECT INTO SUITABLE CONTAINER. WASTE DISPOSAL: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS. ----------------------------------------------------------------EMPLOYEE PROTECTION ----------------------------------------------------------- RESPIRATORY PROTECTION: IF AIRBORNE CONCENTRATIONS POSE A HEALTH HAZARD, BECOME IRRITATING, OR EXCEED RECOMMENDED LIMITS, USE A NIOSH APPROVED RESPIRATOR IN ACCORDANCE WITH OSHA RESPIRATORY PROTECTION REQUIREMENTS UNDER 29 CFR 1910.134. PROTECTIVE CLOTHING: CLOTHING SUITABLE TO PREVENT SKIN CONTACT. SAFETY GOGGLES. CHEMICAL RESISTANT GLOVES. ADDITIONAL PROTECTIVE MEASURES: USE ENGINEERING CONTROLS SUCH AS LOCAL OR GENERAL EXHAUST TO MAINTAIN AIRBORNE CONCENTRATIONS BELOW EXPOSURE LIMITS. EYE WASH STATION SHOULD BE AVAILABLE IN AREAS OF USE. WASH HANDS AND FACE BEFORE EATING, DRINKING OR SMOKING. D 0866 Hoechst D3 Material Safety Data Sheet MoechstCelan se Hoechst Celanese Corporation Route 202 206 North Somerville, NJ 08876 Telex 833 449 Fax 201 231 3225 THE EMERGENCY PHONE NUMBER IS. (201) 231-2244 FOR OTHER PRODUCT SAFETY INFORMATION CALL > (201) 231-2132 PAGE 3 PRODUCT NAME* - 11-1101 PERMANENT YELLOW G MSDS NUMBERt 1103706080 SPECIAL PRECAUTIONS NONE ------------------------------------------ TRANSPORTATION REGULATORY REQUIREMENTS DOT PROPER SHIPPING NAME. NOT REGULATED BY D.O.T. OTHER REGULATORY CONTROLS OTHER REGULATORY CONTROLS * THIS PRODUCT IS LISTED ON THE TSCA INVENTORY. REFERENCE. PA STATE CODE 34 REGULATIONS; N.J.S.A. 34. 5A-1 ET SEQ.,. C.I. PIGMENT YELLOW 14, C.I. *21095, CAS *005468-75-7 CALIFORNIA PROPOSITION 65 WARNING STATEMENT: UNDER THE NOTIFICATION REQUIREMENTS OF THE STATE OF CALIFORNIA, THIS PRODUCT MAY BE FOUND TO CONTAIN ONE OR MORE OF THE LISTED CHEMICALS COVERED BY PROPOSITION 65. THESE ARE NOT INTENTIONALLY INCLUDED, BUT CAN BE NATURALLY OCCURRING CONTAMINANTS AND/OR RAW MATERIALS USED TO PRODUCE THE PRODUCT. WHILE WE DO HOT ANALYZE EXPRESSLY FOR PROPOSITION 65 SUBSTANCES, THE POSSIBILITY OF THEIR PRESENCE IN TRACE QUANTITIES EXISTS. IN ORDER TO COMPLY WITH THE . CALIFORNIA LAW WE ARE THEREFORE PROVIDING THE FOLLOWING STATEMENT. \ "WARNING: THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF \ CALIFORNIA TO CAUSE CANCER AND/OR BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM." / THIS PRODUCT IS NOT SUBJECT TO SARA TITLE III SECTION 313 REPORTING REQUIREMENTS UNDER 40 CFR 372. HAZARD COMMUNICATION LABEL. 000.0 SARA HAZARD CLASS. ACUTE. NO CHRONIC. HO FIRE HAZARD. NO PRESSURE. NO REACTIVITY. NO 0 086659 CONFTDFNTTAI,, Hoechst IB