Document DDY06EyzNgeGvG7j472xm0Gp5

RECYCLED CO AR226-2625 mm AR226-2625 DuPont Engineering Barley Mill Plaza - Bldg. 27 4417 Lancaster Pike Wilmington, DE 19805 October 19,2004 Mr. Todd Kelleher Environmental Supervisor Chemical Monitoring Compliance Unit Ohio Environmental Protection Agency Columbus, Ohio 43216-1049 Earnhart HCiirllcslePvuilbleli,cOWhiaoter System Dear Mr. Kelleher: On August 30,2004, groundwater from the Eamhart Hills Public Water System was sampled and perfluorooctanoic acid (PFOA) concentrations determined. Groundwater sampled included an after treatment sample, a duplicate after treatment sample, a before treatment sample, and four production well samples (W3 through W6). A ll PFOA results were non-detectable (ND; <0.01 ug/L). Please contact me at (302) 992-6820, if you have any questions. Sincerely, Andrew S. Hartten Project Director cc: James Riley Steve Williams Mary Dominiak Andrea V. Malinowski David W. Boothe Dennis W illiams Attachments E.I. du Pont de Nemours and Company Earnhart Hills Public Water System Circleville, Ohio Sam olo Name CVL-EHWC-AT CVL-EHWC-AT (DUP) CVL-EHWC-BT CVL-EHWC-W3 CVL-EHWC-W4 CVL-EHWC-W5 CVL-EHWC-W6 W ater Source After Treatment After Treatment Before Treatment Production Weil Production Well Production Well Production Well Date 8/30/2004 8/30/2004 8/30/2004 8/30/2004 8/30/2004 8/30/2004 8/30/2004 PFOA (ug/L) ND (<0.01 ) ND (<0.01 ) ND (<0.01 ) ND (<0.01 ) ND (<0.01 ) ND (<0.01 ) ND (<0.01 ) 10/19/2004 Page 1 of 1 Circleville.xls E)gen RESEARCH ^ P Pr ereccisisee Research. Proven Results. Flprochemicl Characterization of Water Samples Analytical Results DuPont , Sample Identification CVL-EHWC-AT \ Exygen Research Sample identification L0003262-1 Collection Date 30-Aug-04 APFO * (pg/L**) ND * APFO - ammonium pbrfluorooctanoate (also referred to as FC-143 and C8) ** pg/L - micrograms/liter' (parts per billion) DEFINITIONS: Limit of Detection (LOD) for the procedure is approximately 0.010 pg/L Limit of Quantitation (LOQ) for the procedure is 0.050 pg/L ND - Compound not detected , NQ - Compound detected at a level betyveen the LOD and LOQ. Result is not quantifiable. \ Relative values: ND < LOD < NQ < LOQ \ RESULTS ARE CALCULATED ACCORDING TO THE FOLLOWING CRITERIA: All samples were analyzed in duplicate. If the sarhple and laboratory duplicate are greater than 0.250 pg/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater than ,20, the higher value is reported. If the sample and laboratory duplicate are less than 0.2.50 pg/L, and the absolute difference is less than 50, the average value is reported:-. If the absolute difference is greater than 50, the higher value is reported. \ SUBMITTED BY: ><iohn M. Flaherty, Operations Manager 18-Qct-04 Date \ J&3030558 Research Drive m s` tSatatte College, PA 16801, USA VT: 800.281.3219 F: 8 1 4.272.1019 exygen.com en RESEARCH Precise Research. \ Proven Results. Flprochemical Characterization of Water Samples Analytical Results DuPont \ Sample Identification CVL-EITWC-BT \ Exygen Research Sample Identification L0003262-2 Collection Date 30-Aug-04 APFO* (pg/L**) ND * APFO - ammonium pferfluorooctanoate (also referred to as FC-143 and C8) ** pg/L - micrograms/liter (parts per billion) DEFINITIONS: Limit of Detection (LOD) for the procedure is approximately 0.010 pg/L Limit of Quantitation (LOQ) for the procedure is 0.050 pg/L ND - Compound not detected , NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. \ Relative values: ND < LOD < NQ < LOQ . RESULTS ARE CALCULATED ACCORDING TO THE FOLLOWING CRITERIA: All samples were analyzed in duplicate. If the sample and laboratory duplicate are greater than 0.250 pg/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater thark20, the higher value is reported. If the sample and laboratory duplicate are less than 0.250 pg/L, and the absolute difference is less than 50, the average value is reported,, If the absolute difference is greater than 50, the higher value is reported. , RES EARC H Precise Research. \ Proven Results. Flprochemical Characterization of Water Samples Analytical Results DuPont , Sample Identification C V L-EH W C -A T-D U P Exygen Research Sample Identification L0003262-3 Collection Date 30-Aug-04 APFO* (pg/L**) ND * APFO - ammonium perfluorooctanoate (also referred to as FC-143 and C8) ** pg/L - micrograms/liter'(parts per billion) ' DEFINITIONS: Limit of Detection (LOD) for the procedure is approximately 0.010 pg/L Limit of Quantitation (LOQ) for the procedure is 0.050 pg/L ND - Compound not detected \ NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. \ Relative values: ND < LOD < NQ < LOQ \ RESULTS ARE CALCULATED ACCORDING TO THE FOLLOWING CRITERIA: All samples were analyzed in duplicate. If the sample and laboratory duplicate are greater than 0.250 pg/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater thaii-,20, the higher value is reported. If the sample and laboratory duplicate are less than 0.2.50 pg/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. \ SUBMITTED BY: 18-Qct-04 Date \ J k 3 03505E8 Research Drive mSStataite College, PA 16801, USA VT: 800.281.3219 F: 8 1 4 .2 7 2 .1 0 1 9 exygen.com Flprochemical Characterization of Water Samples Analytical Results DuPont , Sample Identification CVL-EHWC-W3 \ Exygen Research Sample Identification L0003262-4 Collection Date 30-Aug-04 APFO* (pg/L**) ND * APFO - ammonium perfluorooctanoate (also referred to as FC-143 and C8) ** pg/L - micrograms/iiter'(parts per billion) DEFINITIONS: Limit of Detection (LOD) for the procedure is approximately 0.010 pg/L Limit of Quantitation (LOQ) for the'procedure is 0.050 pg/L ND - Compound not detected \ NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. \ Relative values: ND < LOD < NQ < LOQ , RESULTS ARE CALCULATED ACCORDING TO THE FOLLOWING CRITERIA: All samples were analyzed in duplicate. If the sarhple and laboratory duplicate are greater than 0.250 pg/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater thari-,20, the higher value is reported. If the sample and laboratory duplicate are less than 0.250 pg/L, and the absolute difference is less than 50, the average value is reported:. If the absolute difference is greater than 50, the higher value is reported. \ SUBMITTED BY: 18-Qct-04 Date \ > rm staiJ^303055f8 Research Drive State College, PA 1 6 8 01 , USA VT: 800.281.3219 F: 8 1 4 .2 7 2 .1 0 1 9 exygen.com en RESEARCH .Precise Research. \ Proven Results. Fltiprochemlcal Characterization of Water Samples Analytical Results DuPont \ Sample Identification CVL-EHWC-W4 \ Exygen Research Sample Identification L0003262-5 Collection Date 30-Aug-04 APFO* (pg/L**) ND * APFO - ammonium p'erfluorooctanoate (also referred to as FC-143 and C8) ** pg/L - micrograms/liter (parts per billion) DEFINITIONS: Limit of Detection (LOD) for the procedure is approximately 0.010 pg/L Limit of Quantitation (LOQ) for the procedure is 0.050 pg/L ND - Compound not detected , NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. \ Relative values: ND < LOD < NQ < LOQ . RESULTS ARE CALCULATED ACCORDING JO THE FOLLOWING CRITERIA: All samples were analyzed in duplicate. If the sample and laboratory duplicate are greater than 0.250 pg/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater thari,20, the higher value is reported. If the sample and laboratory duplicate are less than 0.250 pg/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. \ SUBMITTED BY: / J o h n M. Flaherty, Operations Manager 18-Oct-04 Date \ 3 058 Research Drive State College, PA 1 6801, USA T : 8 0 0 .2 8 1 .3 2 1 9 F: 814.2 7 2 .1 0 1 9 exygen.com EWgenI R E S E A R C H 'i ^ .P re c is e Research. J \ Proven Results. Flprochemical Characterization of Water Samples Analytical Results DuPont \ Sample Identification CVL-EHWC-W5 \ Exygen Research Sample Identification L0003262-6 Collection Date 30-Aug-04 APFO* (pg/L**) ND * APFO - ammonium p'erfluorooctanoate (also referred to as FC-143 and C8) ** pg/L - micrograms/liter (parts per billion) DEFINITIONS: Limit of Detection (LOD) for the procedure is approximately 0.010 pg/L Limit of Quantitation (LOQ) for the'procedure is 0.050 pg/L ND - Compound not detected \ NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. \ Relative values: ND < LOD < NQ < LOQ . RESULTS ARE CALCULATED ACCORDING TO THE FOLLOWING CRITERIA: All samples were analyzed in duplicate. If the sarhple and laboratory duplicate are greater than 0.250 pg/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater thart-,20, the higher value is reported. If the. sample and laboratory duplicate are less than 0.250 pg/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. \ SUBMITTED BY: Florochemical Characterization of Water Samples Analytical Results DuPont \ Sample Identification CVL-EHWC-W6 \ Exygen Research Sample Identification L0003262-7 Collection Date 30-Aug-04 APFO* (pg/L**) ND * APFO - ammonium p'erfluorooctanoate (also referred to as FC-143 and C8) ** pg/L - micrograms/liter (parts per billion) DEFINITIONS: \ Limit of Detection (LOD) for the procedure is approximately 0.010 pg/L Limit of Quantitation (LOQ) for the'procedure is 0.050 pg/L ND - Compound not detected \ NQ - Compound detected at a level between the LOD and LOQ. Result is not quantifiable. \ Relative values: ND < LOD < NQ < LOQ \ RESULTS ARE CALCULATED ACCORDING TO THE FOLLOWING CRITERIA: All samples were analyzed in duplicate. If the sample and laboratory duplicate are greater than 0.250 pg/L, and the relative percent difference (RPD) is less than 20, the average value is reported. If the RPD is greater thart-,20, the higher value is reported. If the sample and laboratory duplicate are less than 0.250 pg/L, and the absolute difference is less than 50, the average value is reported. If the absolute difference is greater than 50, the higher value is reported. \ SUBMITTED BY: ^<Tohn M. Flaherty, Operations Manager 18-Oct-04 Date \ J ^3 03055f8 Research Drive > r m s tSataite College, PA 1 6801, USA VT : 800.281.3219 F: 8 1 4 .2 7 2 .1 0 1 9 exygen.com