Document DDQ8NXxmZOJ1gQOoB34JpGR6n

ISECTION I. [manufacturer I BURTON RUBSER ] 14330 KINSMAN MATERIAL SAFETY PROCESSING/ INC. ROAD BURTON/ OHIO DATA SHEET 44021 (chvV;al name and synonyms ! P* ' DATE 216-834-4644 CHEMICAL FAMILY POLYMERIC [TRADE NAME_ 1 [546-86017-71"? FORMULA PROPRIETARY-GgNERATED BY DOW CHEMICAL 1-......................................................... -................................................................................................................................ [SECTION II. HAZARDOUS INGREDIENTS ; {MATERIALS LISTED IN THIS SECTION ARE IN CONCENTRATIONS OF 0.1X | MORE IF CARCINOGENIC AND IX OR MORE IF TOXIC/ IRRITANT/ ETC. PER 29CFR 1910.1200. OR ACGIH OSHA TLV PEL OTH ' tA jDIOCTYL PHTHALATE (DOP);BIS-2-ETHYL ANIMAL CARCINOGEN ] HEXYL PHTHALATE(DEHP),CAS 117-81-7 )** SOURCE FOR OTHER- ACGIH STEL FOR CIL MIST HEAVY PARAFFINIC DISTILLATE SOLVENT ANIMAL CARCINOGEN EXTRACT/ CAS H742-C4-7 I** SOURCE FOR OTHER- SUN RECOMMENDED 5.00 5.00 10. MG/M3 MG/M3 MG/ NE NE , MG/ 1* NE- NOT ESTABLISHED jsECTlON III. PHYSICAL DATA j ING POINT (0 F.) NA * 1 V VAPOR | J VAPOR 1 PRESSURE (KM. H G. ) NA DENSITY <AIft=1) NA i SOLUBILITY IN WATER NIL I APPEARANCE ,AND ODOR J*NA- NOT APPLICABLE BLACK SPECIFIC GRAVITY <H20=1) PERCENT VOLATILE BY VOLUME (X) 1.44 NA EVAPORATION RATE NA POLYMERIC SOLID; CHARACTERISTIC ODOR [section IV. FIRE AND EXPLOSION HAZARD DATA | FLASH POINT (METHOD USED) NA* FLAMMABLE LIMITS NA ,j EXTINGUISHING MEDIA - WATER SPRAY/ PROTEIN TYPE AIR FOAM/ ABC DRY CHEMICAL 1 SPECIAL FIRE FIGHTING PROCEDURES- WEAR SELF-CONTAINED BREATHING APPARATUS. j UNUSUAL FIRE AND EXPLOSION HAZARDS- NONE * N A - NOT APPLICABLE J "I I i {1 c . i 00 085954 CONFIDFNTTAI. 4 MSp$_: 546^66017-71 SECTION V. REACTIVITY DATA DATE 08/17/88 PAGE ; j STABILITY1 RDOUS polymerization- maVirials to avoid- STABLE; AVOID DECOMPOSITION TEMPERATURES WILL NOT OCCUR/* NO CONDITIONS TO AVOID STRONG OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS CO, C02 , HCL SECTION VI. HEALTH HAZARD DATA j THRESHOLD LIMIT VALUE- SEE SECTION II. ENTRY ROUTE: INHALATION, SKIN, EYE | EFFECTS OF OVEREXPOSURE CONTAINMENT IN POLYMERIC BINDER GREATLY REDUCES RISK OF CONTACT WITH j HAZARDOUS MATERIALS. iDCP/DEHP MAY CAUSE EYE, SKIN, MUCOUS MEMBRANE, UPPER RESPIRATORY TRACT IRRITA' tion; VERY HIGH LEVELS FED TO RATS/MICE PRODUCED LIVER TUMORS (IARC/NTP); | ANIMAL TESTS ALSO INDICATE THAT TARGET ORGANS ARE THE LIVER,TESTES,AND FETUS. (THE HEAVY PARAFFINIC DISTILLATE CONTAINS AROMATIC PETROLEUM OIL, AN ANIMAL I CARCINOGEN PER IARC WHICH CAUSED SKIN TUMORS DURING ANIMAL TESTING,* EXCESSIVE ] EXPOSURE MAY CAUSE EYE/NOSE/THROAT IRRITATION. ! EMERGENCY AND FIRST AID PROCEDURES | FLUSH EYES/SKIN WITH PLENTY OF WATER - CONSULT PHYSICIAN IF IRRITATION PERSISTS | IE^INHALED REMOVE TO FRESH AIR - IF INGESTED, CONSULT PHYSICIAN | M&w'CAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: 1 INDIVIDUALS WITH CHRONIC RESPIRATORY DISORDERS (I.E., ASTHMA, CHRONIC BRONCHITIS, | EMPHYSEMA, ETC.) MAY BE ADVERSELY AFFECTED BY ANY FUME OR AIRBORNE PARTICULATE EXPOSURE. SENSITIVE INDIVIDUALS MAY BE SUSCEPTABLE TO ALLERGIC REACTION UPON l CONTACT WITH SKIN, EYES, OR RESPIRATORY TRACT. ;S EC TI ON VII. i SPILL OR LEAK PROCEDURES | STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: j COLLECT: RETURN TO CONTAINER WASTE DISPOSAL METHOD: J DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. L............................................-............. .. ................................................................................................................................................. jS EC TI ON VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION | RECOMMEND NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF VENTILATION IS INADEQUATE VENTILATION: LOCAL EXHAUST - YES 1 MECHANICAL (GENERAL) - YES j PROTECTIVE GLOVES: RECOMMEND IMPERVIOUS EYE PROTECTION - RECOMMENDED i DO 085955 CONFIDENTIAL ! ; MSDS: 546-8601 7-71 DATE 0S/17/S8 PAGE : SECTION IX SPECIAL PRECAUTIONS ! PRECAUTIONS TO 3E TAKEN IN HANDLING AND STORING | BELOW 120 f AWAY FROM DIRECT SOURCES OF HEAT AND SUNLIGHT, OTHER PRECAUTIONS: WASH THOROUGHLY AFTER HANDLING | A CLASS OF MATERIALS CALLED NITROSAMINES ARE ANIMAL CARCINOGENS AND SHOULD BE | TREATED AS POSSIBLE HUMAN CARCINOGENS. BECAUSE-MANY RUBBER MATERIALS CONTAIN AMINE; BASED INGREDIENTS/ TRACE RESIDUAL AMOUNTS (WELL BELOW 0.1%) OF NITROSAMI.NE ARE ! LIKELY TO EXIST IN MOST RUBBER COMPOUNDS AS A RESULT OF BEING FORMED IN EARLIER ! PROCESSING STEPS/' CERTAIN PROCESSING STEPS CAN FORM HIGHER AMOUNTS OF NITROS AMINE S. ; AVOID MIXING OR EXPOSING THIS PRODUCT WITH: NITRATES/ NITRITES/ NITROGEN OXIDES ; OR OTHER NITROSAMINES AS POTENTIALLY HAZARDOUS LEVELS OF NITROSAMINES MAY BE FORME! ! SALT BATH CURING WITH NITRATE/NITRITE SALTS CAN BE .EXPECTED TO PRODUCE HAZARDOUS ! AMOUNTS OF VOLATILE NITROSAMINES. 'MISSIONS FROM SUCH PROCESSES MUST BE EXHAUSTED. 1 EMPLOYEES MUST AVOID INHALING FUMES FROM HOT RUBBER PROCESSING. ! SIGNATURE Li. TITLE CHEMIST AS CONDITIONS OR METHODS OF USE ARE BEYOND OUR CONTROL/ WE DO NOT ASSUME ANY RESPONSIBILITY AND EXPRESSLY DISCLAIM ANY LIABILITY FOR ANY USE OF THIS MATERIAL. INFORMATION CONTAINED HEREIN IS BELIEVED TO BE TRUE AND ACCURATE BUT ALL STATEMENT; OR SUGGESTIONS ARE MADE WITHOUT WARRANTY EXPRESSED OR IMPLIED/ REGARDING ACCURACY OF THE INFORMATION/ THE HAZARDS CONNECTED WITH THE USE OF THE MATERIAL OR THE RESULTS TO BE OETAINED FROM THE USC THEREOF. COMPLIANCE WITH FEDERAL/ STATE/ AND LOL^L LAWS AND REGULATIONS REMAINS THE RESPONSIBILITY OF THE USER. I) LAST REVISED (06/30/87! I D0 0859Bfo OONFTDFNt1AL [ Section i. MATERIAL SAFETY [manufacturer t BURTON RUBBER PROCESSING/ INC. [ 14330 KINSMAN ROAD BURTON/ OHIO IctCvICAL NAME AND SYNONYMS DATA SHEET 44021 I DATE <WWW 216-834-4644 CHEMICAL FAMILY POLYMERIC TRADE NAME . \ 1700^4^4 FORMULA PROPRIETARY-GENERATED BY DOW CHEMICAL [SECTION II. HAZARDOUS INGREDIENTS [materials LISTED IN THIS SECTION ARE IN CONCENTRATIONS OF 0.1X OR ! MORE IF CARCINOGENIC AND IX OR MORE IF TOXIC/ IRRITANT/ ETC. | PER 29CFR 1910.1200. t [BASIC SILICATE WHITE LEAD : CAS 11120-22-2 lN-3UTYL-4,4-BI$-(T-8UTYLPERQXY) ! VALERATE/ CAS 995-33-5 jEPOXlDIZED SOYBEAN OIL 'DIALLYL PHTHALATE (DAP) MONOMER/ 1 CAS 131-17-9 BLOOD TOXIN IRRITANT-EYE/SKIN/RESPIRATORY IRRITANT-EYE/SKIN HEPATCTOXIN (LIVER) ACGZH OSHA OTHl TLV PEL ** .15 .05 MG/M3 MG/K3 NE NE NE NE NE ft NE NE NE NE * NE- NOT ESTABLISHED iSEf'ICN III. iL PHYSICAL DATA | BOILING POINT CO F.) NA* SPECIFIC GRAVITY (H20*1) 1.34 [ VAPOR PRESSURE (MM HG.) NA I ! VAPOR DENSITY CAIR=1) NA PERCENT VOLATILE CY VOLUME (X) NA SOLUBILITY IN WATER NIL EVAPORATION RATE NA | APPEARANCE AND CDCR j*NA- NOT APPLICABLE BLACK POLYMERIC SOLID; CHARACTERISTIC ODOR [SECTION IV. FIRE AND EXPLOSION hAZARD DATA | FLASH POINT (METHOD USED) NA* ' FLAMMABLE LIMITS NA | EXTINGUISHING MEDIA - WATER SPRAY/ PROTEIN TYPE AIR FOAM/ ABC DRY CHEMICAL ) SPECIAL i UNUSUAL NA- NOT FIRE FIGHTING PROCEDURES" WEAR SELF-CONTAINED FIRE AND EXPLOSION HAZARDS- NONE APPLICABLE BREATHING APPARATUS. 00 085957 I CONFTOP-NTTA! 87009-24-2 DATE 10/17/88 PAGE 2 : TlON V. ^(ILITY W*RDOU$ POLYMERIZATION TERIALS TO AVOID- REACTIVITY DATA stable; avoid decomposition temperatures WILL NOT OCCUR; NO CONDITIONS TO AVOID STRONG OXIDIZING AGENTS ZAP.DOUS DECOMPOSITION PRODUCTS / C02 / HCL/ LEAD/ LEAD OXIDE/ MGO FUME TION VI. HEALTH HAZARD DATA RESHOLD LIMIT VALUE- SEE SECTION II. ENTRY ROUTE: INHALATION/ SKIN/ 'EYE 5. FECTS OF OVEREXPOSURE 0NTAINP1ENT IN POLYMERIC BINDER GREATLY REDUCES RISK OF CONTACT WITH AZARDOUS MATERIALS. * REXPOSURE TO LEAD MAY CAUSE LEAD INTOXIFICAT I ON/ ABDOMINAL PAIN/ FATIGUE/ ADACHE/ CONSTIPATION/ NAUSEA/ HIGH LEAD LEVEL IN BLOOD. T-EUTYLPEROXY VALERATE MAY CAUSE SKIN IRRITATION/RE ONE $S UPON PROLONGED NTACT/'MAY CAUSE EYE IRRITATION/DAMAGE/NOSE/THROAT/RESPIRATORY irritant; may USE UNKNOWN TOXIC EFFECTS. XIDIZED SOYBEAN OIL MAY CAUSE MILD EYE IRRITATION; PROLONG ED/REPEATED NTACT MAY CAUSE SKIN IRRITATION. MONOMER INHALATION MAY CAUSE COUGHING/DIZZINESS/INTOXIFIC ation/COllapse; DERATE EYE IRRITANT WITH BURNING SENSATION/TEARING/REDNESS /SWELLING/'MAY USE DELAYED ' SKIN IRRITAT ION;CHRON IC EXFOSURE MAY CAUSE LUN G/LIVER DAMAGE. JJGENCY AND FIRST AID PROCEDURES LUSH EYES/SKIN WITH PLENTY OF WATER - CONSULT PHYSICIAN IF IRRITATION PERSISTS F INHALED REMOVE TC FRESH AIR - IF INGESTED/ CONSULT PHYSICIAN 11 1. J |~ DICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: DIV1 DUAL S WITH CHRONIC RESPIRATORY DISORDERS (I.E./ ASTHMA / CHRONIC BRONCHITIS/ PHYSEKA/ ETC.) MAY BE ADVERSELY AFFECTED BY ANY FUME OR AI RBORNE PARTICULATE fOSURE. SENSITIVE INDIVIDUALS MAY BE SUSCEPTA3LE TO ALLERG IC REACTION UPON NTACT WITH SKIN/ EYES/ OR RESPIRATORY TRACT. TICN VII. SPILL OR LEAK PROCEDURES EPS TO 9E TAKEN IN CASE MATERIAL IS COLLECT: RETURN TO CONTAINER STE DISPOSAL METHOD: ISPOSE OF IN ACCORDANCE WITH LOCAL/ RELEASED OR SPILLED: STATE AND FEDERAL REGULATIONS. TION VIII. SPECIAL PROTECTION INFORMATION SPIRATORY PROTECTION ECCMMEND NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF VENTILATION IS INADEQUATE NTILATION: LOCAL EXHAUST - YES MECHANICAL (GENERAL) - YES 3XECTIVE GLOVES: RECOMMEND IMPERVIOUS EYE PROTECTION - RECOMMENDED ^0 08595Q C0NFr08NTTAt ' (SECTION I.' MANUFACTURER BURTON RUBBER 14330 KINSMAN MATERIAL SAFETY PROCESSING/ INC.' ROAO . BURTON/ OHIO DATA SHEET 44021 DATE 216-834-4644 AL NAME AND SYNONYMS CHEMICAL FAMILY POLYMERIC 'TRADE.. f87021-20-6 FORMULA PROPRIETARY-GENERATED BY DOW CHEMICAL SECTION II. HAZARDOUS INGREDIENTS MATERIALS LISTED IN THIS SECTION ARE IN CONCENTRATIONS OF 0.1% OR I MORE IF CARCINOGENIC AND IX OR MORE IF TOXIC/ IRRITANT/ ETC. | PER 29CFR 1910.1200. (tRIALLYL CYANURATE (TAC) IRRITANT-EYE/SKIN/RESPIRATORY j CAS 101-37-1 ]DIOCTYL PHTHALATE ( DOP) ; BIS-2-ETH YL ANIMAL CARCINOGEN J . HEXYL PHTHALATE(DEHP)/CAS 117-31-7 !** SOURCE FOR OTHER- ACGIH STEL FOR OIL MIST ACGIH OSHA OTH TLV PEL ** NE NE NE 5.00 5 . C 0 10,i MG/M3 KG/M3 MG/ NE- NOT ESTABLISHED Is EC T ION III. j B^t-LING POINT (C F.) NA* j V^F-CR PRESSURE (MM HG. ) NA 1 VAPOP DENSITY ( AI R = 1 ) 1 SOLUBILITY IN WATER NA NIL PHYSICAL D-ATA SPECIFIC GRAVITY (H20=1> 1.49 PERCENT VOLATILE BY VOLUME (X) NA EVAPORATION RATE NA J APPEARANCE AND ODOR * N A- NOT APPLICAELE BLACK POLYMERIC SOLID; CHARACTERISTIC ODOR (SECTION IV. FIRE AND EXPLOSION HAZARD DATA i FLASH POINT (METHOD USED) I j EXTINGUISHING MEDIA - NA* FLAMMABLE LIMITS NA WATER SPRAY/ PROTEIN TYPE AIR FOAM/ ABC DRY CHEMICAL j SPECIAL FIRE FIGHTING PROCEDURES- WEAR SELF-CONTAINED BREATHING APPARATUS. ! UNUSUAL FIRE AND EXPLOSION HAZARDS-'NONE j*NA- NOT APPLICAELE jc j I t L__ . W 085959 CONPTDFNTTA! I MSDS: 87021-20-6 jSECTICN V. J S I/*"*\I LIT Y I H\jb/D0U$ POLYMERIZATION I MATERIALS TO AVOID- DATE 08/17/88. REACTIVITY DATA STABLE/ AVOID DECOMPOSITION TEMPERATURES WILL NOT OCCUR; NO CONDITIONS TO AVOID STRONG OXIDIZING AGENTS PAGE HAZARDOUS DECOMPOSITION PRODUCTS CO/ 002 / HCL/ MG.O FUME/ HCN/ N OXIDES/ ALLYL CMPD jSECTICN VI. HEALTH HAZARD DATA | THRESHOLD LIMIT VALUE- SEE SECTION II. ENTRY ROUTE: INHALATION/ SKIN/ EYE ! EFFECTS OF OVEREXPOSURE I CONTAINMENT IN POLYMERIC BINDER GREATLY REDUCES RISK OF CONTACT WITH j HAZARDOUS MATERIALS. |tAC MAY CAUSE SKIN/ EYE/ RESPIRATORY TRACT IRRITATION. jDOP/DEHP MAY CAUSE EYE/ SKIN/ MUCOUS MEMBRANE/ UPPER RESP.IRATORY TRACT IRRITA TION/' VERY HIGH LEVELS FED TO RATS/MICE PRODUCED LIVER TUMORS (IARC/NTP); | ANIMAL TESTS ALSO INDICATE THAT TARGET ORGANS ARE THE LIVER/TESTES/AND FETUS. j. EMERGENCY AND FIRST AID PROCEDURES Jj FLUSH EYES/SKIN WITH PLENTY OF WATER - CONSULT PHYSICIAN IF IRRITATION PERSISTS IF INHALED REMOVE TO FRESH AIR - IF INGESTED/ CONSULT PHYSICIAN I MfLIUCAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: J If )v'I DUALS KITH CHRONIC RESPIRATORY DISORDERS (I.E./ ASTHMA/ CHRONIC BRONCHITIS/ j EfVriYSEMA/ ETC.) MAY BE ADVERSELY AFFECTED BY ANY FUME OR AIRSORNE PARTICULATE | EXPOSURE. SENSITIVE INDIVIDUALS MAY BE SUSCEPTABLE TO ALLERGIC REACTION UPON 1 CONTACT WITH SKIN/ EYES/ OR RESPIRATORY TRACT. jSECTICN VII. SPILL OR LEAK PROCEDURES | STEPS TO BE TAKEN IN CASE MATERIAL IS j COLLECT: RETURN TO CONTAINER WASTE DISPOSAL METHOD: j DISPOSE OF IN ACCORDANCE WITH LOCAL/ RELEASED OR SPILLED: STATE AND FEDERAL REGULATIONS. (SECTION VIII. SPECIAL PROTECTION INFORMATION j RESPIRATORY PROTECTION J RECOMMEND NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF VENTILATION IS INADEQUATE j VENTILATION: j I LOCAL EXHAUST - YES MECHANICAL (GENERAL) - YES | PROTECTIVE GLOVES: `RECOMMEND IMPERVIOUS ' EYE PROTECTION - RECOMMENDED \ 00 085960 CONFIDENT TA1 MSDS: 87021-20-6 DATE 08/17/88 PAGE jSECTION 'IX. SPECIAL PRECAUTIONS | PRECAUUTTIIOONNSS TTOO BBEE TAKEN IN HANDLING AND STORING j E BELOW 120 F AWAY FROM DIRECT SOURCES OF HEAT AND SUNLIGHT ! OTHER PRECAUTIONS WASH THOROUGHLY AFTER HANDLING A CLASS OF MATERIALS CALLED NITROSAMINES ARE ANIMAL CARCINOGENS AND SHOULD BE ! TREATED AS POSSIBLE HUMAN CARCINOGENS. BECAUSE MANY- RUBBER MATERIALS CONTAIN AMINE BASED INGREDIENTS/ TRACE RESIDUAL AMOUNTS (WELL BELOW,0.IX) OF MTROSAMINE ARE | LIKELY TO EXIST IN MOST RUBBER COMPOUNDS AS A RESULT OF BEING FORMED IN EARLIER , I PROCESSING STEPS/* CERTAIN PROCESSING STEPS CAN FORM HIGHER AMOUNTS OF NITROSAMINES | AVOID MIXING OR EXPOSING THIS PRODUCT WITH: NITRATES/ NITRITES/ NITROGEN OXIDES i OR OTHER NITROSAMINES AS POTENTIALLY HAZARDOUS LEVELS OF NITROSAMINES MAY BE FORME i SALT BATH CURING WITH NITRATE/NITRITE SALTS CAN BE EXPECTED TO PRODUCE HAZARDOUS j AMOUNTS OF VOLATILE NITROSAMINES. EMISSIONS FROM SUCH PROCESSES MUST BE EXHAUSTED. EMPLOYEES MUST AVOID INHALING FUMES FROM HOT RUBBER PROCESSING. SIGNATURE TITLE CHEMIST ; AS CONDITIONS OR METHODS OF USE ARE BEYOND OUR CONTROL/ WE DO NOT ASSUME ANY. ! RESPONSIBILITY AND EXPRESSLY DISCLAIM ANY LIABILITY FOR ANY USE OF THIS MATERIAL. I INFORMATION CONTAINED HEREIN IS BELIEVED TO BE TRUE AND ACCURATE BUT ALL STATEKEN OR SUGGESTIONS ARE MADE WITHOUT WARRANTY EXPRESSED OR IMPLIED/ REGARDING ACCURACY ! OF THE INFORMATION/ THE HAZARDS CONNECTED WITH THE USE OF THE MATERIAL OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. COMPLIANCE WITH FEDERAL/ STATE/ AND LOOM. LAWS AND REGULATIONS REMAINS THE RESPONSIBILITY OF THE USER. LAST REVISED (06/30/87 IDO 085961 confiofnitai [SECTION I.- (MANUFACTURER bURTON RUBBER 14330 KINSMAN MATERIAL SAFETY PROCESSING/ INC. ROAD BURTON/ OHIO DATA SHEET 44021 DAT E^0^717/48 216-834-4644 NAME AND SYNONYMS CHEMICAL FAMILY POLYMERIC TADE FORMULA PROPRIETAR Y-GENERATED BY ' $J.' 7* 021*20-81^r DCW CHEMICAL L..................................................................................................................................... ................................................... [SECTION II. HAZARDOUS INGREDIENTS | MATERIALS LISTED IN THIS SECTION ARE IN CONCENTRATIONS OF O.U ] MORE IF CARCINOGENIC AND IX OR MORE IF TOXIC/ IRRITANT/ ETC. I PER 29CFR 1910.1200. OR ACGIH OSHA TLV PEL OTHt ** ;TIALLYL CYANURATE (TAC) | CAS 101-37-1 IRRITANT-EYE/SK IN-/RESPI R ATORY DIOCTYL PHTHALATE (D0P)/BIS_2"ETHYL ANIMAL CARCINOGEN I HEXYL PHTHALATE (DEHP)/CAS 117-81*7 SOURCE FOR OTHER- ACGIH STEL FOR OIL MIST NE NE NE 5.00 5.00 10. MG/M3 MG/M3 MG/ * NE- NOT ESTABLISHED '.SECTION III. PHYSICAL DATA SOWING POINT (0 F.) NA* VlWR PRESSURE (MM HG. ) NA VAPOR DENSITY (AIR=1) NA SPECIFIC GRAVITY (H20=1) 1.49 PERCENT VOLATILE BY VOLUME (X) NA SOLUBILITY IN WATER NIL EVAPORATION RATE na j APPEARANCE AND ODOR ** N A - NOT APPLICABLE j [SECTION IV. BLACK FIP E AND EXPLOSION POLYMERIC SOLID/* HAZARD DATA CHARACTERISTIC ODOR j FLASH POINT (METHOD USED) NA* FLAMMABLE LIMITS NA ) J EXTINGUISHING MEDIA - I WATER SPRAY/ PROTEIN TYPE AIR FOAM/ ABC DRY CHEMICAL j SPECIAL FIRE FIGHTING PROCEDURES- WEAR SELF-CONTAINED BREATHING APPARATUS. ! UNUSUAL FIRE AND EXPLOSION HAZARDS* NONE i*NA- NOT APPLICABLE I;________________________________________________________________________________ ! I c DO ONf 08596? MSDS; 87021-20-8 DATE 08/17/88 PAGE SECTION V REACTIVITY DATA S^ILITYifl^RDOUS POLYMERIZATION- MATERIALS TO AVOIO- STABLE; AVOID DECOMPOSITION TEMPERATURES WILL NOT OCCUR/* NO CONDITIONS TO AVOID STRONG OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS CO, C02 , HCL, MGO FUME, HCN, N OXIDES, ALLYL CMPD SECTION VI. HEALTH HAZARD DATA j THRESHOLD LIMIT VALUE- SEE SECTION II. ENTRY ROUTE:'INHALATION, SKIN, EYE I EFFECTS OF OVEREXPOSURE ' | CONTAINMENT IN POLYMERIC BINDER GREATLY REDUCES RISK OF CONTACT WITH j HAZARDOUS MATERIALS. )T AC MAY CAUSE SKIN, EYE, RESPIRATORY TRACT IRRITATION. DQP/DEHP MAY CAUSE EYE, SKIN, MUCOUS MEMBRANE, UPPER RESPIRATORY TRACT IRRITAI TION; VERY HIGH LEVELS FED TO RATS/MICE PRODUCED LIVER TUMORS (IARC/NTP); j ANIMAL TEsTS ALSO INDICATE THAT TARGET ORGANS ARE THE LIVER,TESTES,AND FETUS. !. EMERGENCY AND FIRST AID PROCEDURES j FLUSH EYES/SKIN WITH PLENTY OF WATER - CONSULT PHYSICIAN IF IRRITATION PERSISTS j IF INHALED REMOVE TO FRESH AIR - IF INGESTED, CONSULT PHYSICIAN MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: I If VIDUALS WITH CHRONIC RESPIRATORY DISORDERS (I.E., ASTHMA, CHRONIC BRONCHITIS, I EMVflYSEMA, ETC.) MAY BE ADVERSELY AFFECTED BY ANY FUME OR AIRBORNE PARTICULATE [ EXPrSURF SENSITIVE INDIVIDUALS MAY BE SUSCEPTABLE TO ALLERGIC REACTION UPON ) CONTACT WTTH SKIN, EYES, OR RESPIRATORY TRACT. SECTION VII. SPILL OR LEAK PROCEDURES j STEPS TO BE TAKEN IN CASE MATERIAL IS I COLLECT: RETURN TO CONTAINER ! WASTE DISPOSAL METHOD: | DISPOSE OF IN ACCORDANCE WITH LOCAL, RELEASED OR SPILLED: STATE AND FEDERAL REGULATIONS. i--------------------------------------------------- ---------- ------------ ------------ --------------------------- ---------------------------------------------------------- jS EC TION VIII. SPECIAL .PROTECTION INFORMATION 1 RESPIRATORY PROTECTION I RECOMMEND NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF VENTILATION IS INADEQUATE VENTILATION: LOCAL EXHAUST - YES j MECHANICAL (GENERAL) - YES j PROTECTIVE GLOVES: RECOMMEND IMPERVIOUS EYE PROTECTION - RECOMMENDED ic Do CO/Vf- P8S963 ^frTyr MSDS: 87021-20-8 DATE 08/17/88 PAGE : iSECTION IX, SPECIAL PRECAUTIONS IONS TO,,BE TAKEN IN HANDLING AND STORING BELOW 120 F AWAY FROM DIRECT SOURCES OF HEAT AND SUNLIGHT. OTHER PRECAUTIONS: WASH THOROUGHLY AFTER HANDLING A CLASS OF MATERIALS CALLED NITROSAMINES ARE ANIMAL CARCINOGENS AND SHOULD BE TREATED AS POSSIBLE'HUMAN CARCINOGENS. BECAUSE MANY ROBBER MATERIALS CONTAIN AMINE* BASED INGREDIENTS/ TRACE RESIDUAL AMOUNTS (WELL BELOW O.U) OF NITROSAMINE ARE LIKELY TO EXIST IN MOST RUBBER COMPOUNDS AS A RESULT OF BEING FORMED IN EARLIER PROCESSING STEPS; CERTAIN PROCESSING STEPS CAN FORM HIGHER AMOUNTS OF NITROSAMINES. AVOID MIXING OR EXPOSING THIS PRODUCT WITH: NITRATES/ NITRITES/ NITROGEN OXIDES OR OTHER NITROSAMINES AS POTENTIALLY HAZARDOUS LEVELS OF NITROSAMINES MAY BE FORMEt SALT BATH CURING WITH NITRATE/NITRITE SALTS CAN BE EXPECTED TO PRODUCE HAZARDOUS AMOUNTS OF VOLATILE NITROSAMINES. EMISSIONS FROM SUCH PROCESSES MUST BE EXHAUSTED. EMPLOYEES MUST AVOID INHALING FUMES FROM HOT RUBBER PROCESSING. jvkau. SIGNATURE U2M.A ... TITLE CHEMIST AS CONDITIONS OR METHODS OF USE ARE BEYOND OUR CONTROL/ WE DO NGT ASSUME ANY RESPONSIBILITY AND EXPRESSLY DISCLAIM ANY LIABILITY FOR ANY USE OF THIS MATERIAL. INFORMATION CONTAINED HEREIN IS BELIEVED TO BE TRUE AND ACCURATE BUT ALL STATEMENT: OR SUGGESTIONS ARE MADE WITHOUT WARRANTY EXPRESSED OR IMPLIED/ REGARDING ACCURACY OF THE INFORMATION/ THE HAZARDS CONNECTED WITH THE USE OF THE MATERIAL OR' THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. COMPLIANCE WITH FEDERAL/ STATE/ AND \ LQAAL LAWS AND REGULATIONS REMAINS THE RESPONSIBILITY OF THE USER. LAST REVISED (06/30/87 J DO 085964 CONFIDENTIAL, f . EC TI ON I. MANUFACTURER BURTON RUBBER 14330 KINSMAN MATERIAL SAFETY PROCESSING/ INC. ROAD BURTON/ OHIO DATA SHEET 44021 oATE'-orrom 216*834*4644 CHl^JtAL NAME AND SYNONYMS WXl l CHEMICAL FAMILY POLYMERIC TRADE...NAME ^7021*20*9 ^ > FORMULA PROPRIETARY-GENERATED BY DOW CHEMICAL ISECTION II ! HAZARDOUS INGREDIENTS {MATERIALS LISTED IN THIS SECTION ARE IN CONCENTRATIONS OF 0.1% OR , MORE IF CARCINOGENIC AND 1% OR MORE IF TOXIC/ IRRITANT/ ETC. .1 PER 29CFR 1910.1200. ACGIH OSHA OTK TLV PEL ** iTRIALLYL CYANURATE (TAC) I CAS 101-37-1 IRRITANT-EYE/SKIN/RESPIRATORY |D10CT YL PHTHALATE (DOP);blS-2-ETHYL ANIMAL CARCIN06EN | HEXYL PKTHALATECDEHP;/CAS 117-31-7 I** SOURCE FOR' OTHER- ACGlH STFL FOR OIL IS T NE NE NE 5.00 5.00 10. MG/M3 MG/M3 MG/ I* NE- NOT ESTABLISHED I.............. -.................................................... jSECTION III. ! | eo^ling point (q f.) na* PHYSICAL DATA SPECIFIC GRAVITY (H20=1> 1.49 I V/n-tfR PRESSURE (MM HG.) NA VAPOR DENSITY ( AIR = 1) ]f S- OLUBILITY IN WATER ! APPEARANCE AND ODOR NA- NOT APPLICABLE NA NIL BLACK FERCENT VOLATILE BY VOLUME (%) NA EVAPORATION RATE NA POLYMERIC SOLID; CHARACTERISTIC CDCR SECTION IV. FIRE AND E XPLO SICN H A Z A R D -DATA FLASH POINT (METHOD USED) NA* FLAMMABLE LIMITS NA EXTINGUISHING MEDIA - WATER SPRAY/ PROTEIN TYPE AIR FOAM/ ABC DRY CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES- WEAR SELF-CONTAINED BREATHING APPARATUS. | UNUSUAL FIRE AND EXPLOSION HAZARDS- NONE J*NA- NOT APPLICAELE h................................................................... -.................................. !O D0 085965 confidential MSDS: JS7C21-20-9 DATE 08/17/88 PAGE ; SECTION V. REACTIVITY DATA SK*^LITYI H\_^DOUS POLYMERIZATION I MATERIALS TO AVQID- STABLE; AVOID DECOMPOSITION TEMPERATURES WILL NOT OCCUR; NO CONDITIONS TO AVOID STRONG OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS CO/ C02 / HCL/ MGO FUME/ HCN/ N OXIDES/ ALLYL CMPD [SECTION VI. HEALTH HAZARD DATA j THRESHOLD LIMIT VALUE- SEE SECTION II. ENTRY ROUTE: INHALATION/ SKIN/ EYE EFFECTS OF OVEREXPOSURE CONTAINMENT IN POLYMERIC BINDER GREATLY REDUCES RISK OF CONTACT WITH j HAZARDOUS MATERIALS. JtAC MAY CAUSE SKIN/ EYE/ RESPIRATORY TRACT IRRITATION. IDOP/DEHP MAY CAUSE EYE/ SKIN/ MUCOUS MEMBRANE/ UPPER RESPIRATORY TRACT IRRITA TION; VERY HIGH LEVELS FED TO RATS/MICE PRODUCED LIVER TUMORS (IARC/NTP); ANIMAL TESTS ALSO INDICATE THAT TARGET ORGANS ARE THE LI VER/TESTES/AND FETUS. j EMERGENCY AND FIRST AID PROCEDURES j FLUSH EYES/SKIN WITH PLENTY OF WATER - CONSULT PHYSICIAN IF IRRITATION PERSISTS j IF INHALED REMOVE TO FRESH AIR - IF INGESTED/ CONSULT PHYSICIAN ] MEAT CAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: j VlDUALS WITH CHRONIC RESPIRATORY DISORDERS (I.E./ ASTHMA/ CHRONIC BRONCHITIS/ EMVfiYSEMA/ ETC.) MAY BE ADVERSELY AFFECTED BY ANY FUME OR AIRBORNE PARTICULATE I EXPOSURE. SENSITIVE INDIVIDUALS MAY BE $USCEPTABLE TO ALLERGIC REACTION UPON ^CONTACT WITH SKIN/ EYES/ OR RESPIRATORY TRACT. (SECTION VII. SPILL OR LEAK PROCEDURES 1 STEPS TO BE TAKEN IN CASE MATERIAL lS | COLLECT: RETURN TO CONTAINER | WASTE DISPOSAL METHOD: j DISPOSE OF IN ACCORDANCE WITH LOCAL/ RELEASED OR SPILLED: STATE AND FEDERAL REGULATIONS. I......... ........................................................................... .. .............................................................................................................................. jSECTICN VIII. SPECIAL PROTECTION INFORMATION ) RESPIRATORY PROTECTION' RECOMMEND NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF VENTILATION IS INADEQUATE I VENTILATION: LOCAL EXH'AUST - YES ] MECHANICAL (GENERAL) - YES I PROTECTIVE GLOVES: RECOMMEND IMPERVIOUS EYE PROTECTION - RECOMMENDED o DO 085966 C0NFTDFNTTA1 jsECTION IX. SPECIAL PRECAUTIONS DATE 08/17/88 PACE pfr^UTI0NS TO BE TAKEN IN HANDLING AND STORING 1 BELOW 120 F AWAY FROM DIRECT SOURCES OF HEAT AND SUNLIGHT. | j OTHER PRECAUTIONS: WASH THOROUGHLY AFTER HANDLING A CLASS OF MATERIALS CALLED NITROSAMINES ARE ANIMAL CARCINOGENS AND SHOULD BE . TREATED AS P0SSI3LE HUMAN CARCINOGENS. BECAUSE MANY RUBBER MATERIALS CONTAIN AMINEI BASED INGREDIENTS/ TRACE RESIDUAL AMOUNTS (WELL BELOW 0.1%) OF NITROSAMINE ARE j LIKELY TO EXIST IN MOST RUBBER COMPOUNDS AS A RESULT OF BEING FORMED IN EARLIER PROCESSING STEPS/ CERTAIN PROCESSING STEPS CAN FORM HIGHER AMOUNTS OF NITROSAMINES, AVOID MIXING OR EXPOSING THIS PRODUCT WITH: NITRATES/ NITRITES/ NITROGEN OXIDES | OR OTHER NITROSAMINES AS POTENTIALLY HAZARDOUS LEVELS OF NITROSAMINES MAY BE FORME! I SALT BATH CURING WITH NITRATE/NITRITE SALTS CAN BE EXPECTED TO PRODUCE HAZARDOUS I AMOUNTS OF VOLATILE.NITROSAMINES. EMISSIONS FROM SUCH PROCESSES MUST BE EXHAUSTED. | EMPLOYEES MUST AVOID INHALING FUMES FROM HOT RUBBER PROCESSING. SIGNATURE i AS CONDITIONS OR METHODS OF USE ARE EEYOND OUR CONTROL/ WE DO NOT ASSUME ANY RESPONSIBILITY AND EXPRESSLY DISCLAIM ANY LIABILITY FOR ANY USE OF THIS MATERIAL. INFORMATION CONTAINED HEREIN IS BELIEVED TO BE TRUE AND ACCURATE BUT ALL STATEMENT I OR SUGGESTIONS ARE MADE WITHOUT WARRANTY EXPRESSED OR IMPLIED/ REGARDING ACCURACY j OF THE INFORMATION/ THE HAZARDS CONNECTED WITH THE USE OF THE MATERIAL OR THE j RESULTS TO BE OBTAINED FROM THE USE THEREOF. COMPLIANCE WITH FEDERAL/ STATE/ AND LAW-S AND REGULATIONS REMAINS THE RESPONSIBILITY OF THE USER. LAST REVISED (08/30/87 iO SECTION I. MANUFACTURER BURTON RUBBER U33Q KINSMAN MATERIAL SAFETY PROCESSING/ INC. ROAD BURTON/ OHIO DATA SHEET 44021 tLJfCAL NAME AND SYNONYMS DATE 216-834-4644 CHEMICAL FAMILY POLYMERIC TRADE N AVE FORMULA PROPRIETARY-GENERATED 3Y DON CHEMICAL jSECTION II. HAZARDOUS INGREDIENTS [MATERIALS LISTED IN THIS SECTION ARE IN CONCENTRATIONS OF 0.1JC OR f MORE IF CARCINOGENIC AND U OR MORE IF TOXIC/ IRRITANT/ ETC. . I PER 29CFR 1910.1200. f (DIOCTYL PHTHALATE (DOP)/* BIS-2-ETHYL ANIMAL CARCINOGEN ' HEXYL PHTHALATE(DHP)/CA$ 117-SI-7 {** SOURCE FOR OTHER- ACGIH STEL FOR OIL MIST (DIALLYL PHTHALATE (DAP) MONOMER/ I CAS 131-17-9 HEPATOTOXIN ( LIV E f: > ACGIH OSHA OTHf TLV PEL ** 5.00 5.00 10. ( KG/M3 MG/M3 MG/! NE NE NE * NE- NOT ESTABLISHED SECTION III. PHYSICAL DATA | B^ING POINT (0 F . ) N A * SPECIFIC GRAVITY (H20=1) 1.49 | VAPOR PRESSURE (MM HG.) NA j VAPOR DENSITY (AIP=1) NA PERCENT VOLATILE 3Y VOLUME (X) NA | SOLUBILITY IN WATER | APPEARANCE AND ODOR j* N A - NOT APPLICABLE NIL BL*CK EVAPORATION RATE NA POLYMERIC SOLID/* CHARACTERISTIC ODOR 'SECTION IV. FIPE AND EXPLOSION HAZARD DATA ! j FLASH POINT (METHOD USED) NA* FLAMMABLE LIMITS NA | EXTINGUISHING MEDIA - WATER SPRAY/ PROTEIN TYPE AIR FOAM/ ABC DRY CHEMICAL SPECIAL FIRE FIGHTING PROCEDURES- WEAR SELF-CONTAINED BREATHING APPARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS- NONE NA- NOT APPLICABLE iO f ,3^ ! MSDS: 88003-10-2 DATE 10/17/88 `SECTION V. REACTIVITY DATA Git bilityARDOUS POLYMERIZATION i MATERIALS TO AVOID- STABLE; AVOID DECOMPOSITION TEMPERATURES WILL NOT OCCUR/* NO CONDITIONS TO AVOID STRONG OXIDIZING AGENTS > HAZARDOUS DECOMPOSITION PRODUCTS I CO/- C02 / HCL {SECTION VI. HEALTH HAZARD DATA PAGE l ; threshold limit value- see section ii. entry route: inhalation/ skin/ eye effects of overexposure , CONTAINMENT in POLYMERIC BINDER GREATLY REDUCES RISK OF CONTACT WITH I HAZARDOUS MATERIALS. 'DOP/DEHP MAY CAUSE EYE/ SKIN/ MUCOUS MEMBRANE/ UPPER RESPIRATORY TRACT IRRITAI TION/* VERY HIGH LEVELS FED ,T0 RATS/MICE PRODUCED LIVER TUMORS (IARC/NTP); j ANIMAL TESTS ALSO INDICATE THAT TARGET ORGANS ARE THE LIVER/TESTFS/AND FETUS. (DAP MONOMER INHALATION MAY CAUSE COUGHING/DIZZINESS/INTOXIFICATION.-COLLAPSEJ i MODERATE EYE IRRITANT WITH BURNING SENSAT I ON/TEARING/REDNESS/SWELLING;MAY j CAUSE DELAYED SKIN IPRITAT I ON;CHRONIC EXPOSURE MAY CAUSE LUNG/LIVER DAMAGE. { EMERGENCY AND FIRST AID PROCEDURES | FLUSH EYES/SKIN WITH PLENTY OF WATER - CONSULT PHYSICIAN IF IRRITATION PERSISTS \ INHALED REMOVE TO FRESH AIR - IF INGESTED/ CONSULT PHYSICIAN CJ ; MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: j INDIVIDUALS WITH CHRONIC RESPIRATORY DISORDERS (I.E./ ASTHMA/ CHRONIC BRONCHITIS/ j EMPHYSEMA/ ETC.) MAY BE ADVERSELY AFFECTED BY ANY FUME OR AIRBORNE PARTICULATE | EXPOSURE. SENSITIVE INDIVIDUALS MAY EE SUSCEPTA9LE TO ALLERGIC REACTION UPON I CONTACT WITH SKIN/ EYES/ OR RESPIRATORY TRACT. (SECTION VII. SPILL OR LEAK PROCEDURES I | STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: I COLLECT: RETURN TO CONTAINER 1 * A S T E DISPOSAL METHOD: | DISPOSE OF IN ACCORDANCE WITH LOCAL/ STATE AND FEDERAL REGULATIONS. SECTION VIII. SPECIAL PROTECTION INFORMATION RESPIRATORY PROTECTION RECOMMEND NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF VENTILATION IS INADEQUATE VENTILATION: LOCAL EXHAUST - YES MECHANICAL (GENERAL) - YES PROTECTIVE GLOVES: RECOMMEND IMPERVIOUS EYE PROTECTION RECOMMENDED I 00 0fSB969 CONFIDENT TAl f--* [ MSDS: 88003-10-2 DATE 10/17/88 PAGE 2 SECTION IX. SPECIAL PRECAUTIONS AUTI0NS TO BE TAKEN IN HANDLING AND STORING O^ RE BELOW 120 F AWAY FROM DIRECT SOURCES OF HEAT AND SUNLIGHT. | OTHER PRECAUTIONS: WASH THOROUGHLY AFTER HANDLING i A CLASS OF MATERIALS CALLED NITROSAMINES ARE ANIMAL CARCINOGENS AND SHOULD BE [ TREATED AS POSSIBLE HUMAN CARCINOGENS. BECAUSE MANY RUBBER MATERIALS CONTAIN AMINE- BASED INGREDIENTS/ TRACE RESIDUAL AMOUNTS (WELL BELOW O.U> OF NITROSAMINE ARE I LIKELY TO EXIST IN MOST RUBBER COMPOUNDS AS A RESULT OF BEING FORMED IN EARLIER PROCESSING STEPS; CERTAIN PROCESSING STEPS CAN FORM HIGHER AMOUNTS OF NITROSAMINES, ! AVOID MIXING OR EXPOSING THIS PRODUCT WITH: NITRATES/ NITRITES/ NITROGEN OXIDES | OR OTHER NITROSAMINES AS POTENTIALLY HAZARDOUS LEVELS OF NITROSAMINES MAY BE FORMEI j SALT BATH CURING WITH NITRATE/NITRITE SALTS CAN BE EXPECTED TO PRODUCE HAZARDOUS . ! AMOUNTS OF VOLATILE NITROSAMINES. EMISSIONS FROM SUCH PROCESSES MUST BE EXHAUSTED. ! EMPLOYEES MUST AVOID INHALING FUMES FROM HOT RUBBER PROCESSING. SIGNATURE TITLE CHEMIST AS CONDITIONS OR METHODS OF USE ARE BEYOND OUR CONTROL/ WE DC NOT ASSUME ANY RESPONSIBILITY AND EXPRESSLY DISCLAIM ANY LIABILITY FOR ANY USE OF THIS MATERIAL. INFORMATION CONTAINED HEREIN IS EELIEVED TO BE TRUE AND ACCURATE BUT ALL STATEMENT: CR SUGGESTIONS ARE MADE WITHOUT WARRANTY EXPRESSED OR IMPLIED, REGARDING ACCURACY OF THE INFORMATION, THE HAZARDS CONNECTED WITH THE USE OF THE MATERIAL OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF. COMPLIANCE WITH FEDERAL, STATE, AND L LA*$ AND REGULATIONS REMAINS THE RESPONSIBILITY OF THE USER. O LAST REVISED (06/30/87: i I i c I_______ l._. DO 085970 CONFIDENTTAl Hw SECTION I. MATERIAL SAFETY MANUFACTURER BURTON RUBBER PROCESSING/ INC. o14330 KINSMAN ROAD ICH AL NAME ANt) SYNONYMS BURTON/ OHIO Lcor l DATA SHEET 44021 DATE Mm/ll 214-834-4644 CHEMICAL FAMILY POLYMERIC TRADE,NAMEFORMULA PROPRIETARY-GENERATED BY P0W CHEMICAL SECTION II. HAZARDOUS INGREDIENTS MATERIALS LISTED IN THIS SECTION ARE IN CONCENTRATIONS OF 0.1X OR MORE IF CARCINOGENIC AND IX OR MORE IF TOXIC/ IRRITANT/ ETC. PER 29CFR 1910.1200. DIOCTYL PHTHALATE (DOP);BIS-2-ETHYL ANIMAL CARCINOGEN HEXYL PHTHALATE(DEHP)/CAS 117*81-7 ** SOURCE FOR OTHER- ACGIH'STEL FOR OIL MIST DIALLYL PHTHALATE (DAP) MONOMER/ IPRITANT-EYE/SKIN/RESPIRATORY CAS 131-17-9 ACGIH OSHA OTH TLV PEL ** 5.00 5.0p 10. MG/M3 MG/M3 MG/ NE NE NE * NE- NOT ESTABLISHED 4 SECTION III. PHYSICAL DATA j BOOLING POINT (C F.) N A * | vVcr PRESSURE (MM HG. ) NA 1{ j VAPOR DENSITY (AIR=1) NA SPECIFIC GRAVITY (H20=1 ) 1.49 PERCENT VOLATILE BY VOLUME (X) NA j SOLUBILITY IN WATER NIL EVAPORATION RATE NA i APPEARANCE AND ODOR i* N A - NOT APPLICABLE BLACK POLYMERIC SOLID; CHARACTERISTH - SECTION IV. FIRE AND EXPLOSION HAZARD DATA j FLASH POINT (METHOD USED) NA* FLAMMABLE LIMITS NA J EXTINGUISHING MEDIA - WATER SPRAY/ PROTEIN TYPE AIR FOAM/ ABC DRY CHEMICAL | SPECIAL FIRE FIGHTING PROCEDURES- WEAR SELF-CONTAINED BREATHING J^PIJARATUS. UNUSUAL FIRE AND EXPLOSION HAZARDS" NONE *NA- NOT- APPLICABLE 4 c MSDS: 8S003-10-2 .SECTION V. REACTIVITY DATA DATE 08/17/88, PAGE !. Sr~>ILITY1 HVj^DOUS POLYMERIZATION- ! MATERIALS TO AVOID- stable; avoid decomposition temperatures WILL NOT OCCUR; NO CONDITIONS TO AVOID STRONG OXIDIZING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS | CO/ C02 / HCL {SECTION VI. HEALTH HAZARD DATA f' i THRESHOLD LIMIT VALUE- SEE SECTION II. j j EFFECTS OF OVEREXPOSURE i CONTAINMENT IN POLYMERIC BINDER GREATLY I HAZARDOUS MATERIALS. " ENTRY ROUTE': REDUCES RISK INHALATION/- SKIN/ OF CONTACT WITH EYE Joop/DFHP MAY CAUSE EYE/ SKIN/ MUCOUS MEMBRANE/ UPPER RESPIRATORY TRACT IRRITA- I TION; VERY HIGH LEVELS FED TO RATS/MICE PRODUCED LIVER TUMORS (IARC/NTP); f ANIMAL TESTS ALSO INDICATE THAT TARGET ORGANS ARE THE LIVER/TESTE$/AND FETUS. !DAP MONOMER VAPOR WILL CAUSE IRRITATION OF THE LUNGS/EYE$/NOSE AND THROAT; | LIQUID CONTACT WILL CAUSE CORNEAL BURNS; CONTINUOUS EXPOSURE AT HIGH LEVELS j WILL CAUSE IRRITATION TO LUNGS/ POSSIBLE LUNG CONGESTION/ LIVER DAMAGE. j EMERGENCY AND FIRST AID PROCEDURES j FLUSH EYES/SKIN WITH PLENTY OF WATER - CONSULT PHYSICIAN IF IRRITATION PERSISTS INHALED REMOVE TO FRESH AIR - IF INGESTED/ CONSULT PHYSICIAN J DCAL CONDITIONS GENERALLY AGGRAVATED EY EXPOSURE: INDIVIDUALS WITH CHRONIC RESPIRATORY DISORDERS (I.E./ ASTHMA/ CHRONIC BRONCHITIS/ EMPHYSEMA/ ETC.) MAY BE ADVERSELY AFFECTED BY ANY FUME OR AIRBORNE PARTICULATE I EXPOSURE. SENSITIVE INDIVIDUALS MAY BE SUSCEPTABLE TO ALLERGIC REACTION UPON j CONTACT WITH SKIN/ EYES/ OR RESPIRATORY TRACT. jsECTION VII. SPILL OR LEAK PROCEDURES { STEPS TO BE TAKEN IN CASE MATERIAL IS J! COLLECT: RETURN TO CONTAINER WASTE DISPOSAL METHOD: i DISPOSE OF IN ACCORDANCE WITH LOCAL/ RELEASED OR SPILLED: STATE AND FEDERAL REGULATIONS. .SECTION VIII-. SPECIAL PROTECTION INFORMATION *\ | RESPIRATORY PROTECTION I RECOMMEND NIOSH APPROVED ORGANIC VAPOR RESPIRATOR IF VENT.ILATICN IS INADEQUATE I VENTILATION: LCCAL EXHAUST - YES | MECHANICAL (GENERAL) - YES j PROTECTIVE GLOVES: RECOMMEND IMPERVIOUS EYE PROTECTION - RECOMMENDED I DO 08597? CONFTDFNTTAl. ! MSDS.: ,88003-10-2 DATE 08/17/88 PAGE 3 SECTION IX. SPECIAL PRECAUTIONS PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING \*/-E BELOW 120 F AWAY FROM DIRECT SOURCES OF HEAT AND SUNLIGHT. OTHER PRECAUTIONS: WASH THOROUGHLY AFTER HANDLING ! A CLASS OF MATERIALS CALLED NITROSAMINES ARE ANIMAL CARCINOGENS AND SHOULD BE 1 TREATED AS POSSIBLE HUMAN CARCINOGENS. BECAUSE MANY RUBBER MATERIALS CONTAIN AMINE* j BASED INGREDIENTS/ TRACE RESIDUAL AMOUNTS (WELL BELOW 0.1X) OF NITROSAMINE ARE I LIKELY TO EXIST IN MOST RUBBER COMPOUNDS AS A RESULT OF BEING FORMED IN EARLIER | PROCESSING STEPS; CERTAIN PROCESSING STEPS CAN FORM HIGHER AMOUNTS OF NITROSAMINES. ; AVOID MIXING OR EXPOSING THIS PRODUCT WITH: NITRATES/ NITRITES/ NITROGEN OXIDES ; OR OTHER NITROSAMINES AS POTENTIALLY HAZARDOUS LEVELS OF NITROSAMINES MAY BE FORMED ! SALT BATH CURING WITH NITRATE/NITRITE SALTS CAN BE EXPECTED TO PRODUCE HAZARDOUS | AMOUNTS OF VOLATILE NITROSAMINES. EMISSIONS FROM SUCH PROCESSES MUST BE EXHAUSTED. ^EMPLOYEES MUST AVOID INHALING FUMES FROM HOT RUBBER PROCESSING. SIGNATURE TITLE CHEMIST | AS CONDITIONS OR METHODS OF USE ARE BEYOND OUR CONTROL/ WE DO NOT ASSUME ANY , RESPONSIBILITY AND EXPRESSLY DISCLAIM ANY LIABILITY FOR ANY USE OF THIS MATERIAL. ! INFORMATION CONTAINED HEREIN IS BELIEVED TO BETRUE AND ACCURATE BUT ALL STATEMENT' j OR SUGGESTIONS ARE MADE WITHOUT WARRANTY EXPRESSED OR IMPLIED/ REGARDING ACCURACY | OF THE INFORMATION/ THE HAZARDS CONNECTED WITH THE USE OF THE MATERIAL OR THE 1 RESULTS TO BE OB.TAINED FROM THE USE THEREOF. COMPLIANCE WITH FEDERAL/ STATE/ AND j LCW^L LAWS AND REGULATIONS REMAINS THE RESPONSIBILITY OF THE USER. j (J LAST REVISED <06/30/87; II I 1_____ 4 5973 DO 0 coNFjp______ '3 -j . C T 1.1 * VI. 1 ^~- 11 ii. Ffi A C i F 1> DATA G A TEC.-/17/Ec p; GE L;>:T ^Lv:- SEE SECTION II. E^RY ROUTE: I \ H A L A TI 0 N / SKIN/ eye EFFECTS CF Cl E F? / PC-SUP : c T* r:' ifglv E`-k h*;.-poo us -PTt^iALS. c- *- r - t ^ y feoucee ~tc-: :r contact .,ith l'v CAUSE EYE/ SvIN/ '-'JCCUS Y E ;-i t ? A! E / UCPE P E 5 P I R A T C F. Y TRACT IRPITt: u.; very wig a levels tec to pats /v ice produced liver tohops capc/ntp); A'.T\A!_ TESTS A L SC INDICATE THAT TARGET C R G A N S APE THE LIVEP/TtSTES/AND FETUS. cA-a acy fs-st ai:> `'f,,; ecu fee F E . S f EYES/SKIN /.ITi f l t N T V OF *ATEP - CONSULT PHYSICIAN IF it-CITATION PERSISTS IF IV-iLEO FEYC'vL TC F ? E S - -1- - IF INGESTED/ CONSULT PHYSICIAN1 r .E I _ I 1 I S R ' - \ - * / . _ * i G r - * - 0 - --:= ut -70-:-'" -. y - > !_*",, ) ` 1 " - v , : \ V - c ; :. T '* - * ^ i . . ' _-L1 1 1 f - - - * ^ ' -r' - / . :U/ r> i. * r;:J ~ i ! > X p , r u; - ; s (:.{./ a sT-/,*, c- = ,, ic ta: ,c r, :t i S/ ' V r* \ > H J ; '1 ^ / I r: 7 J ^ " T I C * T ; . C I ^ "I - _ r T T ^ L l L K * ; ' C T 1 Z', t ~ 0 \ - l ". -V* *a > -L - - l : <v " i ^ C ~ L r r 7 ; - ; T j - T ^ f ;. t * : , ' /S :: " "L ,; ; 7 : /* . *- - - - * - - K - L -` ' l. - f '. r. ! - 1 7 r .. * - t. r : 0 Li l T - 0 \ S - _ . , -V ' t i. J ' . F -' ' - 1 + ? V - '. ` ' >- . : - - - '.l', . : - ' - 1 S - I * ' S < l ~ i 7 . . . -. ' - : - ~ c1: s: : ?. :. . : - *s - -f.. t; rt ; I ? i IS I O L V1 : T i e .s e . rn 08597^ CONFTorNTTAl. Printed 06-08-1987 C-7000 MSOS ID: D*007375 ! '-"general information MATERIAL SAFETY DATA SHEET SARTOMER COMPANY A DIVISION OF PONY INDUSTRIES 80LMAR AND NIELDS STREETS WEST CHESTER, PENNSYLVANIA 19382 EMERGENCY NUMBERS 800/424-9300 CHEMTREC 215/692-8401 SARTOMER 215/430-2200 INFO ONLY TRADE NAME C-7000 GENERIC NAME DOT PROPER SHIPPING NAME NOT REGULATED DOT HAZARD CLASS NOT REGULATED 2 - SUMMARY OF HAZARDS UN/NA NUMBER N/AP CAUTION PHYSICAL HAZARDS: POTENTIAL DUST EXPLOSION HAZARD ACUTE HEALTH EFFECTS: (SHORT-TERM) SLIGHT INHALATION HAZARD SLIGHT EYE IRRITANT SLIGHT SKIN IRRITANT/ALLERGIC SENSITIZER SLIGHT INGESTION HAZARD NO DATA ON SKIN ABSORPTION FOUND CHRONIC HEALTH EFFECTS: (LONG-TERM) NO APPROPRIATE HUMAN OR ANIHAL HEALTH EFFECTS DATA ARE KNOWN TO EXIST. M Page l 3 - COMPONENTS COMPONENT NAME ZINC DIMETHACRYLATE CAS NUMBER X COMPOSITION BY (WT.) 13189-00-9 GT 99 4 - PHYSICAL AND CHEMICAL DATA BOILING POINT PH N/AP AP 5.3 TO 5.5 FREEZING POINT DRY POINT N/AP N/AP SPECIFIC GRAVITY (H20=1 AT 39.2F) AP 1.50 AT 25C VOLATILE CHARACTERISTICS NEGLIGIBLE VISCOSITY UNITS, TEMP. SOLUBILITY IN WATER N/AP SLIGHT VAPOR PRESSURE STABILITY N/AP STABLE VAPOR SP GR (AIR*1 AT 60 - 90F) HAZARDOUS POLYMERIZATION N/AP MAY OCCUR APPEARANCE AND OOOR WHITE POWDER WITH SLIGHTLY ACIDIC ODOR DO 085977 C onftdfntiai Printed 06-08-1987 C-7000 HSDS 10: D-007375 MATERIAL SAFETY DATA SHEET ' , | - PHYSICAL AND~CHEMICAL DATA*(continued) CONDITIONS AND MATERIALS TO AVOID HEAT, DIRECT SUNLIGHT, OXIDIZING CONDITIONS STRONG OXIDIZING AND REDUCING AGENTS HAZARDOUS DECOMPOSITION PRODUCTS CARBON MONOXIDE, CARBON DIOXIDE, ZINC OXIDE, AND ZINC PEROXIDE MAY BE RELEASED IN A FIRE INVOLVING THIS PRODUCT. 5 - OCCUPATIONAL EXPOSURE LIMITS SUBSTANCE SOURCE DATE TYPE VALUE TIME 6 - FIRE AND EXPLOSION FLASH POINT METHOD: AUTOIGNITION TEMP. METHOD* N/AP N/AP FLAMMABLE LIMITS (X VOLUME IN AIR) LOWER: N/AP UPPER: N/AP FIRE AND EXPLOSION HAZARDS WHEN MIXED WITH AIR AND EXPOSED TO IGNITION SOURCE, SUFFICIENT FLAMMABLE DUST MAY EXIST TO BURN IN OPEN OR EXPLODE IF CONFINED. USE GOOD HOUSE* KEEPING PRACTICES TO AVOID RENDERING DUST AIRBORNE. FLAMMABLE VAPORS HAY ALSO BE PRESENT FROM OVER HEAT ING/MCLTING/DECOMPOSITION. VAPORS MAY CAUSE FIRE/EXPLOSION IF SOURCE OF IGNITIG,.' IS PRESENT. EXTINGUISHING MEDIA DRY CHEMICAL C02 WATER SPRAY FOAM WATER FOG SPECIAL FIREFIGHTING PROCEDURES DO NOT ENTER FIRE AREA WITHOUT PROPER PROTECTION. SEE SECTION ON DECOMPO SITION PROOUCTS POSSIBLE. FIGHT FIRE FROM SAFE DISTANCE/PROTECTED LOCATION. APPLY AQUEOUS EXTINGUISHING MEDIA CAREFULLY TO PREVENT FROTHING/STEAM EX PLOSION. USE WATER SPRAY/FOG FOR COOLING. AVOID CONTACT WITH MOLTEN PRODUCT TO PREVENT SERIOUS BURNS. AVOID RAISING POWDERED MATERIALS INTO AIRBORNE DUST, CREATING AN EXPLOSION HAZARD. NOTIFY AUTHORITIES IF LIQUID ENTERS SEWER/PUBLIC WATERS. 7 - HEALTH HAZARDS ROUTES OF EXPOSURE INHALATION -- PRIMARY ROUTE PROLONGED OVEREXPOSURE MAY CAUSE COUGHING, SHORTNESS OF BREATH, DIZZINESS AND INTOXICATION. EYE CONTACT -- PRIMARY ROUTE MAY CAUSE MINOR EYE IRRITATION. SKIN ABSORPTION NO APPROPRIATE HUMAN OR ANIMAL HEALTH EFFECTS DATA ARE KNOWN TO EXIST. SKIN IRRITATION PRIMARY ROUTE THIS MATERIAL HAS BEEN SHOWN TO BE A SLIGHT SKIN IRRITANT AND AN ALLERGIC SENSITIZER INGESTION THIS MATERIAL MAY BE A SLIGHT HEALTH HAZARD IF INGESTED IN LARGE QUANTITIES. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE THIS MATERIAL OR ITS EMISSIONS MAY INDUCE AN ALLERGIC OR SENSITIZATION REACTION AND THEREBY AGGRAVATE SYSTEMIC DISEASE. m Page 2 Do DO NF 085978 rFNr tA/. Print d 06-08-1987 C-7000 MSDS ID: D-00737S MATERIAL SAFETY DATA SHEET 1 PROTECTIVE EQUIPMENT / CONTROL MEASURES RESPIRATORY PROTECTION NIOSH/MSHA APPROVED DUST OR HIST RESPIRATOR SHOULD BE USED IF AIRBORNE PARTICULATE IS GENERATED WHEN HANDLING THIS MATERIAL. EYE PROTECTION EYE PROTECTION SUCH AS CHEMICAL SPLASH GOGGLES AND/OR FACE SHIELD MUST BE WORN WHEN POSSIBILITY EXISTS FOR EYE CONTACT DUE TO SPLASHING OR SPRAYING LIQUID, AIRBORNE PARTICLES, OR VAPOR. CONTACT LENSES SHOULD NOT BE WORN. SKIN PROTECTION DEPENDING ON THE CONDITIONS OF USE, PROTECTIVE GLOVES, APRON, BOOTS, HEAD AND FACE PROTECTION SHOULD BE WORN. THIS EQUIPMENT SHOULD BE CLEANED THOROUGHLY AFTER EACH USE. ENGINEERING CONTROLS PROVIDE LOCAL EXHAUST OR GENERAL ROOM VENTILATION TO MINIMIZE EXPOSURE TO DUST. IF MECHANICAL VENTILATION IS USED, ELECTRICAL SYSTEMS SHOULD CONFORM TO NATIONAL ELECTRIC CODE. OTHER HYGENIC PRACTICES EMERGENCY EYE WASH FOUNTAINS AND SAFETY SHOWERS SHOULD BE AVAILABLE IN THE IMMEDIATE VICINITY OF ANY POTENTIAL EXPOSURE. OTHER WORK PRACTICES USE GOOD PERSONAL HYGIENE PRACTICES. WASH HANDS BFr"P EATING, DRINKING, SMOKING, OR USING TOILET FACILITIES. PROMPTLY REMOVE SOILED CLOTHING/WASH THOROUGHLY BEFORE REUSE. SHOWER AFTER WORK USING PLENTY OF SOAP AND WATER. 9 - EMERGENCY AND FIRST AID INHALATION IF OVERCOME BY EXPOSURE, REMOVE VICTIM TO FRESH AIR IMMEDIATELY. GIVE OXYGEN OR ARTIFICIAL RESPIRATION AS NEEDED. OBTAIN EMERGENCY MEDICAL ATTENTION. PROMPT ACTION IS ESSENTIAL. EYE CONTACT IN CASE OF EYE CONTACT, IMMEDIATELY RINSE LJTH CLEAN UATEr. TOR 20-30 MINUTES. RETRACT EYELIDS OFTEN. OBTAIN EMERGENCY MEDICAL ATTENTION IF PAIN, BLINKING, TEARS OR REDNESS PERSIST. SKIN CONTACT REMOVE CONTAMINATED CLOTHING AS NEEDED. WASH SKIN THOROUGHLY WITH MILD SOAP/WATER. FLUSH WITH LUKEWARM WATER FOR 15 MINUTES. IF STICKY, USE WATER LESS CLEANER FIRST. INGESTION IF LARGE QUANTITY SWALLOWED, GIVE LUKEWARM WATER (PINT) IF VICTIM COMPLETELY CONSCIOUS/ALERT. DO NOT INDUCE VOMITING/RISK OF DAMAGE TO LUNGS EXCEEDS POISONING RISK. OBTAIN EMERGENCY MEDICAL ATTENTION. EMERGENCY MEDICAL TREATMENT PROCEDURES TREAT SYMPTOMATICALLY. NOT APPLICABLE 10 - SPILL AND DISPOSAL PRECAUTIONS IF MATERIAL IS SPILLED OR RELEASED RELEASE MAY CREATE A DUST EXPLOSION HAZARD. MAY CONTAMINATE WATER SUPPLIES. EXTINGUISH ALL IGNITION SOURCES. ON LAND, SWEEP/SHOVEL INTO SUITABLE DISPOSAL CONTAINERS OR VACUUM USING EQUIPMENT WHICH AVOIDS IGNITION RISK. AVOID MAKING DUST. ON WATER, CONTAIN/MINIMIZE DISPERSION/ COLLECT. REPORT PER REGULATORY REQUIREMENTS. WASTE DISPOSAL METHODS CONTAMINATED PRODUCT/SOIL/WATER MAY BE RCRA/OSHA HAZARDOUS WASTE (SEE AO CFR 261 AND 29 CFR 1910). COMPLY WITH FEDERAL/STATE/LOCAL REGULATIONS FOR SOLID WASTE DISPOSAL. LANDFILL SOLIDS AT PERMITTED SITES. USE REGISTERED TRANSPORTERS. 1M Page 3 DO 085979 CONFTDFNTTAL J Frinted 06-08-1987 C-7000 MSDS ID: D-007375 MATERIAL SAFETY DATA SHEET 1 | - ADDITIONAL PRECAUTIONS HANDLING AND STORAGE PROCEDURES TYPICALLY SHIPPED IN FIBER DRUMS LINED WITH POLYETHYLENE. STORE IN A DRY PROTECTED LOCATION TO PREVENT POTENTIAL DILUTION. STORAGE IN STEEL CONTAIN ERS MAY CAUSE PRODUCT DISCOLORATION DUE TO RUST. DECONTAMINATION PROCEDURES FOLLOW STANDARD PLANT PROCEDURES OR SUPERVISOR'S INSTRUCTIONS FOR DECONTAMINATION OPERATIONS. 12 - LABEL INFORMATION USE STATEMENT FOR INDUSTRIAL USE ONLY KEEP OUT OF REACH OF CHILDREN SIGNAL WORD CAUTION PHYSICAL HAZARDS POTENTIAL DUST EXPLOSION HAZARD HEALTH HAZARDS INHALATION HAZARD EYE IRRITANT SKIN IRRITANT INGESTION HAZARD PRECAUTIONARY MEASURES DO NOT HANDLE NEAR HEAT, SPARKS, OR OPEN FLAME. AVOID ACCUMULATION OF DUST IN ENCLOSED SPACE. KEEP CONTAINER CLOSED WHEN NOT IN USE. AVOID CONTACT WITH EYES. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR. AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. USE WITH ADEQUATE VENTILATION. PREVENT CONTACT WITH FOOD, CHEWING, OR SMOKING MATERIALS. WASH THOROUGHLY AFTER HANDLING. DO NOT TASTE/SWALLOW. 13 - SUPPLEMENT NPCA HM1S RATING HEALTH FLAMMABL1LITY REACTIVITY PERSONAL PROTECTION 1 1 J 4(DUST) PROTECTION QUALIFIERS AND COOES USED IN THIS MSDS EQ > EQUAL AP APPROXIMATELY LT > LESS THAN GT * GREATER THAN TR - TRACE UK > UNKNOWN N/AP * NOT APPLICABLE N/P - NO APPLICABLE INFORMATION FOUND N/DA > NO DATA AVAILABLE 14 - DISCLAIMERS SOME OF THE INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE PROOUCT ITSELF. THE INFORMATION IN THIS MSDS WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESS OR IMPLIED, REGARDING ITS CORRECTNESS. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE AND DISPOSAL OF THE IN Page 4 DO 085980 CONFIDENT! At J Printed 06-08-1987 C-7000 MSDS ID: D-007375 MATERIAL SAFETY DATA SHEET DISCLAIMERS (continued) PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH THE HANDLING, STORAGE, USE OR DISPOSAL OF THE PROOUCT. THIS MSDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PROOUCT, THIS MSDS INFORMATION MAY NOT BE APPLICABLE. THIS MSDS HAS BEEN PREPARED IN ACCORDANCE WITH THE REQUIREMENTS OF THE OSHA HAZARD COMMUNICATION STANDARD (29 CFR 1200). Page 5