Document DD5414b152222KYkbM47aoB6d

AKZD Material Safety Data Sheet Chemical Division TITANIUM TETRACHLORIDE POISON G S320 This Material Safety Data Sheet (MSDS) meets the requirements of the federal OSHA Hazard Communication Standard (29 CFR 1910.1200) and the Canadian Controlled Product Regulation, WHMIS classified as: D-1A, D-2A, D-2B, E, F. New Issue 10/88 Supersedes Issue Dated 5/86 MSDS No. 985111/TIT5I4 PIN: UN 1838 II. PHYSICAL/CHEMICAL PROPERTIES The following represent all available, applicable physical hazard data on this product. PHYSICAL STATE/DESCRIPTION: Colorless liquid, irritating odor SPECIFIC GRAVITY: 1.726 at 68F/68F (20C/20C) EMERGENCY TELEPHONE NUMBERS FREEZING POINT: Transportation Emergencies: -22F <-30C) USA-CHEMTREC 1-800-424-9300 CANAPA-CANUTEC: 613-996-6666 All Other Emergencies Call: 312-906-7054 BOILING POINT: 277F (I36.4C) SOLUBILITY: Hydrolyzes in water with evolution of heat. I. PRODUCT IPENTIFICATION/COMPOSrnON VAPOR PRESSURE: Titanium Tetrachloride (approx. 100%), CAS Registry Number 7550-45-0 12.4 mm Hg at 77F (25C) 7.1 mm Hg at 60F (15C) SYNONYM: Titanic Chloride III. CHEMICAL REACTIVITY FORMULA: TiCi4 FORMULA WEIGHT: 189.7 Reacts violently with water producing hydrogen chloride, titanium oxychloride and titanium oxides. This reaction will generate a considerable amount of heat. Fumes strongly when exposed to moist air forming a dense white cloud. It is not sensitive to physical impact In Canada: Akzo Chemicals Ltd., 100 University Avenue, Ste. 908, Toronto, Ontario M5J 1V6 *Also referred to as a Product Safety Information Sheet SAL 00000993A AD irtformadoei concerning this productand/or all suggestions for handlingand use contained herein are offered m good faith and vt believed to be reliable Akzo Chemicals Inc . however, makes no warranty as to the accuracy and'or sufficiency of such information and/or suggestions, as to the product's merchantability or fitness for any particular purpose, or that any suggested use will not infringe any patent Nothing contained herein shall be construed asgra-cjig or extending any license under any patent. Buyer must determine for himself, by preliminary tests or otherwise, the sucability of thr* product for his purposes The information contained herein supersedes all previously rssued bulletins on the s-teO matter covered Akzo Chemicals Inc. 300 S. Riverside Plaza Chicago, Illinois 60606 (312)906-7500 TITANIUM TETRACHLORIDE IV. STABILITY Stable when stored in an inert atmosphere. Use nitrogen containing less than 10 ppm oxygen. V. FIRE HAZARD Not defined as flammable or combustible. However, the product may support combustion and decompose under fire conditions to give off toxic materials such as hydrogen chloride and chlorine gases. It is not sensitive to static discharge. VI. FIREFIGHTING TECHNIQUE Products ofcombustion are irritating to the respiratory tract and may cause breathing difficulty and pulmonary edema. Symptoms may be delayed several hours or longer depending upon the extent of exposure. As in any fire, prevent human exposure to fire, smoke, fumes or products of combustion. Evacuate nonessential personnel from the fire area. Firefighters should wear full-face, self-contained breathing apparatus and impervious protective clothing. If not leaking, keep fire-exposed containers cool with a water spray to prevent rupture due to excessive heat. Do not use high pressure water hose as it may spread product from broken containers increasing contamination or fire hazard. Do not get water inside containers as a vigorous reaction may result, generating high temperatures and pressures. Large Fires: Flood with water. Copious quantities are required to scrub out the liberated hydrogen chloride and wash away the T1CI4 residues. Contaminated buildings, areas and equipment must not be used until they are properly decontaminated. VII. TOXICOLOGY INGESTION: The acute oral LD50 is less than 464 mg/kg in male rats. A single oral dose of 464 mg/kg produced a severe decrease in physical activity and 100 percent mortality. SKIN CONTACT: The acute dermal LD50 is 3160 mg/kg in rabbits. A single dermal application of 1000 mg/kg did not produce symptoms of toxicity in rabbits. Local effects included moderate to severe necrosis and edema. INHALATION: The acute inhalation LC50 is 0.4 mg/I in rats for a four-hour inhalation exposure. The cause of death appeared to be pulmonary edema. Repeated inhalation exposures in rats to 0.04 mg/1 for 6 hours per day/five days per week for four weeks produced decreased weight gain, inflammation of the respiratory tract. pulmonary fibrosis and ft percent mortality. Similar treatment to 0.005 mg/I showed no treatment related effects (Kelly et al., 1981). Small Fires: Use dry chemical or carbon dioxide. T-4624 Page 2 of 6 000009935 SAL 6 S 3 20 TITANIUM TETRACHLORIDE VIII- HUMAN HEALTH INGESTION: The principal routes of exposure are skin contact and inhalation. Contact with the skin or eyes may produce severe irritation or burns. Inhalation of titanium tetrachloride or fumes may produce severe irritation to the upper respiratory tract with coughing, burning of the throat, headache, dizziness and weakness. Lung damage, pulmonary edema and even death may occur after severe exposures. Bronchial irritation with a chronic cough and bronchial pneumonia may result from prolonged or repeated exposures to low concentrations. Titanium tetrachloride is not classified as a carcinogen by IARC, NTP or OSHA. However, in a lifetime inhalation test conducted by DuPont, microscopic lung cancers were found in 5 of 150 rats exposed at 10 mg/m3 T1CI4. This is suggestive evidence for a slight increase in cancer risk with long-term continuous inhalation of vapors from titanium tetrachloride (Lee eta!., 1986). IX. FIRST AID CALL A POISON CENTER OR A PHYSICIAN IMMEDIATELY If a known exposure occurs or if poisoning is suspected, do not wait for symptoms to develop. Immediately start the recommended procedures below and simultaneously contact a Poison Center, a physician or the nearest hospital. Inform the person contacted of the type and extent of exposure, describe the victim's symptoms and follow the advice given. If swallowed, immediately give several glasses of water, but do not induce vomiting.This materia) is corrosive. If vomiting does occur, give fluids again. Have a physician determine if conditionof patient will permit induction of vomiting or evacuation of stomach. Do not give anything by mouth to an unconscious or convulsing person. SKIN CONTACT: Using a dry cloth, immediately wipe away excess material from the skin and remove all contaminated clothing and shoes. Under a safety shower, flush all affected areas thoroughly with large amounts of running water for at least 15 minutes. Do not attempt to neutralize with chemical agents. Get medical attention immediately. Discard contaminated clothing and shoes. EYE CONTACT: Immediately flush the eyes with large quantities of running water for a minimum of 15 minutes. Hold the eyelids apart during the flushing to ensure rinsing of the entire surface of the eye and lids with water. Do not attempt to neutralize with chemical agents. Obtain medical attention as soon as possible. Oils or ointments should not be used at this time. Continue the flushing for an additional 15 minutes if a physician is not immediately available. INHALATION: If inhaled, remove to fresh air. If not breathing, clear victim's airway and start mouth-to-mouth artificial respiration, which may be supplemented by the use of a bag-mask respirator or manually triggered oxygen supply capable of delivering one liter per second or more. If victim is Page 3 of 6 SAL 000009936 as* - C.S3 20 TITANIUM TETRACHLORIDE breathing, supplemental oxygen may be given from a demand-type or continuous-flow inhaler, preferably with a physician's advice. Get medical attention immediately. X. INDUSTRIAL HYGIENE SKIN CONTACT; Skin contact with liquid or its aerosol must be prevented through the use of impervious clothing, gloves and footwear selected with regard for use condition exposure potential. The recommendations described in this Safety showers, with quick opening section are provided as general valves which stay open, should be guidance for minimiiingexposure when readily available in all areas where handling this product Because use the materia] is handled or stored. conditions will vary depending upon Water should be supplied through customer applications, specific safe insulated and heat-traced lines to handling procedures should be developed prevent freeze ups in cold weather. by a person knowledgeable of the intended use conditions and equipment EVE CONTACT: During the development of safe handling procedures, consideration should be Eye contact with liquid or aerosol must given to the need for cleaning of be prevented through the use of equipment and piping systems to render chemical safety glasses, goggles or a them nonhazardous before maintenance face shield selected with regard for and repair activities are performed. use condition exposure potential. Waste resulting from these procedures should be handled in accordance with Eye wash fountains, or other means of SECTION XIV: DISPOSAL OF MATERIAL/ washing the eyes with a gentle flow of CONTAINER. tap water, should be readily available in all areas where this material is ENGINEERING CONTROLS: handled or stored. Water should be supplied through insulated and In those cases where engineering heat-traced lines to prevent freeze-ups controls are indicated by the use in cold weather. conditions, the following traditional exposure control techniques may be used INHALATION: to effectively minimize employee exposure: local exhaust ventilation, This materia] is normally handled under enclosed system design or process closed process conditions. In an isolation and remote cootrol in emergency situation where adequate combination with appropriate use of ventilation is not available and use personal protective equipment conditions could generate vapor or hydrogen chloride fumes, inhalation INGESTION: must bepreventedthrough the use of NIOSH-approved, acid-gas respirators All food must be kept in a separate with dust, mist and fume filters to area away from the storage/use reduce potential for exposure under the location. Eating, drinking, smoking use conditions. Where exposure and carrying of tobacco products must potential under the use conditions be prevented in areas where there is a necessitates a higher level of potential for exposure to this protection, use a positive-pressure, materiaL Before eating, drinking or air-supplied respirator. smoking, hands and face must be :horoughly washed. Page 4 of 6 sal 00009937 G S321)0 TITANIUM TETRACHLORIDE EXPOSURE LIMITS: No exposure limits have been established for this material. However, contact with moisture liberates hydrogen chloride which is toxic and corrosive. The following exposure limits apply for hydrogen chloride. The federal OSHA Permissible Exposure Limit (PEL) is a ceiling limit of 5 ppm (7 mg/m3) (20 CFR 1910.1000). The American Conference of Governmental Industrial Hygienists (ACGIH) has recommended a Threshold Limit Value (TLV) which is the same as the PEL (ACGIH, 1988). PELS and TLVs refer to airborne concentrations measured in the breathing zone by appropriate sampling techniques. XI. SPILL HANDLING Make sure all personnel involved in the spill cleanup follow good industrial hygiene practices (refer to SECTION X: INDUSTRIAL HYGIENE). Any person entering either a significant spill area or an area of unknown concentration of a vapor or hydrogen chloride fumes should use a positive-pressure, self-contained breathing apparatus or a positive- pressure, air-supplied respirator with escape pack. Small spills can be handled routinely. Use adequate ventilation and/or wear a NIOSH-approved, acid-gas respirator with dust, mist and fume filter to prevent inhalation exposure. Wear protective clothing to prevent skin and eye contact Use the following procedures: Soak up pooled liquid with a suitable absorbent such as clay, sawdust or kitty litter. Sweep up absorbed materia] and place in a chemical waste container for disposal (refer to SECTION XIV: DISPOSAL OF MATERIAL/ CONTAINER). Generously cover contaminated area with a slurry of common household, powdered laundry detergent and water. Using a stiff brush, work the slurry into cracks and crevices. Allow to stand for 2-3 minutes then flush with water. Repeat if necessary. Large spills should be according to a predetermined plan. handled XII. CQRROSiYrrv TO MATERIALS of CONSTRUCTION Under totally anhydrous conditions, mild carbon steel ' may be used. Moisture will cause hydrolysis to titanium oxychloride and hydrogen chloride which will corrode most metals including carbon steel. XIII. STORAGE REQUIREMENTS Containers should be stored in a cool, dry, well ventilated area away from flammable materials and sources of heat or flame. Store away from foodstuffs or animal feed. Exercise due caution to prevent damage to or leakage from the container. Containers should only be opened in a dry, oxygen free inert atmosphere. Carbon steel is the preferred material of construction for storage containers but only if completely anhydrous conditions are maintained. It is strongly recommended that the system be purged to dryness with dry air or inert gas to 35*F (dew point) prior to the introduction of titanium tetrachloride. Page 5 of 6 SAL 000009938 6 S3 20 TITANIUM TETRACHLORIDE XIV. DISPOSAL OF MATERIAL/CONTAINER REFERENCES CITED: Material that cannot be used or chemically reprocessed and empty containers must be disposed of according to any applicable regulations. NOTE: State and local regulations may be more stringent than federal. XV. PREPARATION INFORMATION Prepared by: Product Stewardship, Akzo Chemicals Inc., Chicago, Illinois, (312)906-7500. American Conference of Governmental Industrial Hygienists (ACGIH), Threshold _ Limit Values And___Biological Exposure Indices With Intended__ Cfan&gl For 1988-89. ACGIH: Cincinnati, OH, 1988. Kelly, D. P., Lee, K. P. B. A., "Inhalation Toxicity Tetrachloride Atmospheric Products,'. Toxicologist. 1981. and Burgess, of Titanium Hydrolysis 1: 76-77, Lee, K. P., Kelly, D. P., Schneider, P. W. and Trocimowic, H. J., "Inhalation Toxicity Study on Rats Exposed to Titanium Tetrachloride Atmospheric Hydrolysis Products for Two Years,* Toxicology, and Applied _ Pharmacology. 83, 30-45, 1986. Page 6 of 6 SAL 000009939 DATS t 11/2T/90 IHOEAI 1 10O3Z9O2VO ACCTi 199297 *0 CAT HO I *1*24 PHOSPHORIC ACID, LIQUID** PHOSPHORIC ACID, LIOUIO** PHOSPHORIC ACID. LIQUID** MATERIAL SAFETY DATA SHEET PAOFi 1 PO HOP I 3199M203-B All 737 FISHER SCICNTIFIC CHEMICAL DIVISION 1 REAOEHT LANE FAIR LAWN NJ 07410 |20*I 79S-7IOO EMERGENCY NUMBERi <201 790-7100 LHEMTREC AS9ISTANCCt <9O0> 424*9300 THIS INFORMATION IS BELIEVED TO BE ACCURATE AND REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANV OTHER WARRANTY, EXPRESS OR IMPLIED, WITH RESPECT TO SUCH INFORMATION, ANO WE ASSUME NO LIABILITY RESULTINO FROM ITS USE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. SUBSTANCE IDENTIFICATION SUBSTANCEt PHOIPHORIC ACIO, LIQU10** CAS-NUHBER 7694-39-2 TRADE NAMES/SVNONYMS t WHITE PHOSPHORIC ACtD| ORTHOPHOSPHORTIC ACIOl META-PHOS-META-PHOSPHORIC ACIOl ORTHO-PHOSPHORIC ACIDl SONAC) EVITSl WC-REINIOER) STCC 4930Z4S) UN IBOSl A-ZSOl A-242) A-36S| A-365-P) H304P| ACCI9BB1 CHEMICAL FAMILY! INORGANIC ACIO MOLECULAR FORMULAI H3-P-04 MOLECULAR WEIGHTi 9*.00 CERCLA RATTNOS (SCALE 0-3)1 HEALTH*! FIRE0 REACTIVITY*! NFPA RATINGS (SCALE 0-4>l HEALTH2 FIRE*0 REACT1VITY0 PERSISTENCE-O COMPONENTS AND CONTAMINANTS COMPONENTt PHOSPHORIC ACID PERCENTi SS.O COMPONENT! WATER PERCENT) 1S.0 EXPOSURE LIMITS! PHOSPHORIC ACIDl 1 M0/M3 OSHA TWA| 3 MCI/MS OSHA STEL 1 MQ/MS AC01H TWA| 3 MO/M3 ACOIM STEL BOOO POUNDS CERCLA SECTION 103 REPORTABLE QUANTITY SUBJECT TO SARA SECTION 313 ANNUAL TOXIC CHEMICAL RELEASE REPORTINO PHYSICAL DATA DESCRIPTION! ODORLESS, COLORLESS SYRUPY LIOUIO. BOILING POINTi 31S P (IBS C) MELTING POtHTi 70 P <21 C> SPECIFIC GRAVITY! 1.6SS VAPOR PRESSURE I 2.2 MMNO 21 C EVAPORATION RATE I NOT AVAILABLE PHt 1.9 B O.IN SOLN. SOLUBILITY IN WATER! COMPLETE SOLVENT SOLUBILITY! SOLUBLE IN ALCOHOL VISCOSITY! 29 CP 20 C PIPE ANO EXPLOSION OATA FIRE AND EXPLOSION HAZAROl NEOLtOIBlF FIRR HAZARD WHEN IXPOSFO 10 MPAf OR r I AMT. FIREF t OHT|NO MEDIAl ORY CHEMICAL, CARBON OIOXIOE, WATER SPRAY OR REOUIAR FO (1990 EMEROENCY RESPONSE OUIOEBOOK. DOT P S900.S). FOR LAHOER FIRES. USE WATER SPRAY, FQO OR REOUIAR FOAM (19B0 EMEROENCY RESPONSE OUIOEBOOK, DOT P 5900.S). FIREF I GMTINOi MOVE CONTAINER FROM FIRE AREA IF YOU CAN DO IT WITHOUT RISK. APPLY COOLJMO $4t. 0009 9*0 9 OATS- J7/90 INDEX) 11*03280280 ACCTr 16S2S7-OI CAT MOl A2424 PAOEl 2 PO NBRt 3ISBKI203-E AEL 737 WATER TO SIDES OF CWTA f NCflS THAT ARE EXPOSED TO FLAMES UNTIL WELL AFTER PIPE IS OUT. STAY AWAY FROM ENOS OF TANKS I1SS0 EMERGENCY RESPONSE OUIOEBOOK. OOT P SSOO.B, OU1DE PACE SOI. USE POINT SUITABLE PON TYPE QF FIRE. USE WATER IN FLOODING QUANTITIES AS FOO. COOL CONTAINERS WITH FLOODING AMOUNTS OF WATER. APPLY FROM AS FAR A DISTANCE AS POSSIBLE. AVOIO BREATHING CORROSIVE VAPORS. KEEP UPWIND. TRANSPORTATION DATA OEPARTMENT OF TRANSPORTATION HAZARO CLASSIFICATION AS CFR 172.1011 CORROSIVE MATERIAL DEPARTMENT OF TRANSPORTATION LABELINO REQUIREMENTS AS CF* 172.101 AND SUSPART Ei CORROSIVE DEPARTMENT OP TRANSPORTATION PACKAOINO REQUIREMENTSl 4S CFR 173.24 J EXCEPTIONS AS CFR ITS.244 TOXICITY FMOSPHORtC ACIDt IRRITATION DATAi S9S MO/24 HOURS SKIN-RABBIT SEVERE I IIS MQ EYE-RABBIT TOXICITY DATAi 2740 MO/KO SKIN-RABBIT LOJOf 1530 MO/KO ORAL-RAT LDSOi 220 MO/KO UNREPORTED-MAN LOLO. CARCINOOEN STATUSl none. LOCAL EFFECTSl CORROSIVE- INHALATION, SKIN. EYE, INGESTION. ACUTE TOXICITY LEVELi MODERATELY TOXIC BY iNOESTIONi SLIGHTLY TOXIC BY ABSORPTION. TARGET EFFECTSl NO OATA AVAILABLE. AT INCREASED RISK FROM EXPOSUREi PERSONS WITH PRE-eXISTINO RESPIRATORY SKIN OISEASC. SEVERE. OCRMAL OR HEALTH EFFECTS AND FIRST AID INHALATION! PHOSPHORIC ACIOl CORROSIVE. SEE INFORMATION ON ACIOIC CORROSIVE COMPOUNDS. ACIDIC CORROSIVESt ACUTE EXPOSUHE- MAY CAUSE RESPIRATORY TRACT IRRITATION WITH COUOMINO. CHOKIMO, AND POSSIBLY BURKS OF THE MUCOUS MEMBRANES. OTHER INITIAL SYMPTOMS MAY 1NCLUOE 0I22INESS, HEADACHE, NAUSEA AND WEAKNESS, IN SOME CASES PULMONARY EDEMA MAY OEVELOP, EITHER IMMEDIATELY IN SEVERE CASES, OR MORE LIKELY AFTER A LATENT PERIOO OF S-7Z HOURS. THE SYMPTOMS MAY INCLUOC TIGHTNESS IN THE CHEST, DYSPNEA, FROTHY SPUTUM, AND CYANOSIS, PHYSICAL FINDINGS MAY INCLUDE HYPOTENSION, WEAK, RAPIO PULSE ANO MOIST HALES. RECOVERY MAY BE PROLONGED ANO RELAPSES ARE POSSIBLE. IN SEVERE EXPOSURES. DEATH DUE TO ANOXIA MAY OCCUR WITHIN A FEW HOURS AFTER ONSET OF PULMONARY EDEMA SYMPTOMS OR F0LL0W1M0 A RELAPSECHRONIC EXPOSURE- DEPENOINO ON THE CONCENTRATION ANO DURATION OF EXPOSURE, REPEATEO OR PROLONGED EXPOSURE MAY CAUSE EROSION OF THE TEETH, INFLAMMATORY AND ULCERATIVE CHANGES IN THE MOUTH, ANO POSSIBLY JAW NECROSIS. BRONCHIAL IRRITATION WITH COUOH AMD FREQUENT ATTACKS OF BRONCHIAL PNEUMONIA MAY OCCUR. OASTROINVEST INAL DISTURBANCES ARE ALSO POSSIBLE. FIRST AID- REMOVE FROM EXPOSURE AREA TO FRESH AIR IMMEDIATELY. IF BREATHING HAS STOPPEO, Give ARTIFICIAL RESPIRATION, MAINTAIN AIRWAY ANO BLOOD PRESSURE AND ADMINISTER OXYDEN IF AVAILABLE- KEEP AFFECTEO PERSON WARM ANO AT REST. TREAT SYMPTOMATICALLY ANO SUPPORTIVfLY. ADMINISTRATION OF OXYGEN SHOULD BE PERFORMED BY QUALIFIED PERSONNEL. GET MEDICAL ATTENTION IMMEDIATELY. SKIN CONTACT! PHOSPHORIC ACIDI seeCORROSIVE, INFORMATION ON ACIDIC CORROSIVE COMPOUNDS. ACUTE EXPOSURE- OIRECT CONTACT MAT tAUSfc StVL.-t PA.r., . -u HO j , BROWNISH OR YELLOWISH STAINS. BURNS MAT BE DEEP WITH SHARP COOES * NEAL SLOWLY WITH SCAR TISSUE FORMATION. _ CHROMIC EXPOSURE- EFFECTS DEPEND ON THE CONCENTRATION ANO DURATION EXPOSURE. REPEATEO OR PROLONOIO CONTACT MAT RESULT IN DERMATITIS vN EFFECTS SIMILAR TO ACUTE EXPOSURE. FIRST AIO- REMOVE CONTAMINATED CLOTHINO AMD SHOES IMMEDIATELY. WASH AFFECTED AREA WITH SOAP OR MILD DETEROENT AND LARGE AMOUNTS OF WATER UNTIL NO EVIDENCE OF CHEMICAL REMAINS (AT LEAST IS-ZO MINUTES). IN CASE OF CHEMICAL BURNS, COVER AREA WITH STERILE. DRV DRESSING. BANOAOE SECURELY. BUT MOT TOO TIGHTLY. GET MEOICAL ATTENTION ItWEOIATELV. EVE CONTACT! SAL 000009941 OATH 11/27/VO INDEX! 1I6032S0260 ACCT s 16B2I7-OI CAT NOt A2424 PAQEi 3 PO NBR) 3160X1203-* PEL TJ7 PHOSPHORIC ACIOi CORROSIVE. DIRECT CONTACT WITH A 0.I6M SOLUTION BUFFEREO TO PH 2.S CAUSED A MOOEAATE, BRIEF STINOINO SENSATION, BUT NO INJURY WHEN APPLIED AS A SINGLE DROP IN HUMAN EYES. WHEN AOJUSTEO TO PH 3.A, A DROP OF THE SOLUTION CAUSED NO DISCOMFORT. IRRIGATION OF RABBIT EVES FOR S MINUTES WITH PH 3.S SOLUTION CAUSED SLIQHT TRANSIENT EPITHELIAL EDEMA AND CONJUNCTIVAL HYPEREMIA, RUT THE EYE WAS NORMAL WITHIN 24 HOURS. WHEN INJECTEO INTO THE CORNEAL STROMA OR APPLIEO TO THE CORNEA AFTER REMOVAL OF THE EPITHELIUM, IT CAUSEO (DETECTABLE INJURY BELOW PH S.S. EVE BURNS MAY RESULT FROM SPLASHES OF CONCENTRATED SOLUTIONS. SEE INFORMATION ON ACIOIC CORROSIVE COMPOUNDS. ACIDIC CORROSIVESl ACUTE EXPOSURE- OIRECT CONTACT MAY CAUSE PAIN, LACRIMATIOH, PHOTOPHOBIA AND ANO BURNS. IN MILO BURNS, THE EPITHELIUM REGENERATES RAPIDLY AND THE EYE RECOVERS COMPLETELY. IN SEVERE CASES, THE EXTENT OF INJURY MAY NOT BE FULLY APPARENT FOR SEVERAL WEEKS. ULTIMATELY, THE WHOLE CORNEA MAY BECOME DEEPLY VASCULARIZED AND OPAQUF. RESULTING IH BLINDNESS. IN THE WORST CASES, THE EVE MAY BE TOTALLY OESTRO.ED, CHRONIC EXPOSURE- EFFECTS DEPEND ON THE CONCENTRATION ANO OURATION OF EXPOSURE. REPEATED OR PROLONOEO CONTACT MAY CAU5E CONJUNCTIVITIS OR EFFECTS AS IN ACUTE EXPOSURE. FIRST AID- WASH EYES IMMEDIATELY WITH LARGE AMOUNTS OF WAtER, OCCASIONALLY LIFTINO UPPER AND LOWER LIDS, UNTIL NO EVIDENCE OF CHEMICAL REMAINS (AT LEAST 16-20 MINUTES). CONTINUE IRRIGATING WITH NORMAL SALINE UNTIL THE PH HAS RETURNED TO NORMAL (30-60 MINUTES). COVER WITH STERILE BANOAOES. OET MEDICAL ATTENTION IMMEDIATELY. INQESTtONi PHOSPHORIC ACIDl CORROSIVE. SEE INFORMATION ON ACIOIC CORROSIVE COMPOUNDS. ACIDIC CORROSIVESl ACUTE EXPOSURE- MAY CAUSE CIRCUMORAL BURNS WITH DISCOLORATION ANO CORROSION OF THE MUCOUS MEMBRANES OF THE MOUTH. THROAT AND EB0PHA0U3. THERE MAY BE IMMEDIATE PAIN ANO DIFFICULTY OR INABILITY TO SWALLOW OR SPEAK. EPIQLOTTAL EOCMA MAY RESULT IN RESPIRATORY DISTRESS AND POSSIBLY ASPHYXIA. MARKED THIRST, NAU5EA, VOMITING AND DIARRHEA MAY OCCUR. DEPENDING ON THE AREA ANO DEGREE OF CORROSION, THE VOMITUS MAY CONTAIN FRESH OR OARK BLOOO ANO LARGE SNRCOS OF MUCOSA. SHOCK MAY OCCUR WITH MARKED HYPOTENSION, WEAK ANO RAPIO PULSE, SHALLOW RESPIRATION. AND CLAMMY SHIN. CIRCULATORY COLLAPSE MAY DEVELOP ANO IF UNCORRECTED. LEAO TO RENAL FAILURE. IN SEVERE CASES, GASTRIC ANO, TO A LESSER OEOREE. ESOPHAGEAL PERFORATION MAY OCCUR WITH PERITONITIS ACCOMPANIED BY FEVER ANO ABOOMINAL RIGIDITY. ESOPHAGEAL, GASTRIC OR PYLORIC STRICTURE MAY OCCUR WITHIN A FEW WEEKS, OR MAY BE DELAYED FOR MONTHS OR EVEN YEARS. DEATH MAY RESULT WITHIN A SHORT TIME FROM ASPHYXIA, CIRCULATORY COLLAPSE OR ASPIRATION OF EVEN MINUTE AMOUNTS. IF DEATH 18 DELAYED, IT MAY BE OUE TO PERITONITIS, SEVERE NEPHRITIS OR PNEUMONIA, COMA ANO CONVULSIONS SOMETIMES OCCUR TERMINALLY. CHRONIC EXPOSURE- OEPENOINO ON THE CONCENTRATION, REPEATEO INOESTION MAY RESULT IN INFLAMMATORY AND ULCERATIVE CHANGES IN THE MUCOUS MEMBRANES OF THE MOUTH ANO OTHER EFFECTS AS IN ACUTE INOESTION. FIRST AIO- DO NOT USE 0A8TRIC LAVAOE OR EMESIS. OIIUTE THE ACID IMMEDIATELY BY DRINKING LAROE QUANTITIES OF WATER OR MILK. IF VOMITINO PERSISTS. AOMINISTER FLUIOS REPEATEOLY. INOE3TEO ACIO MUST BE DILUTED APPROXIMATELY too FOLO TO RENDER TT HARMLESS TO TISSUES. MAINTAIN AIRWAY ANO TREAT SHOCK (OREISBACH, HAHOBOOK OF P0IS0N1N0, I2TH ED.). OET MEDICAL ATTENTION IMMEDIATELY. IF VOMITINQ OCCURS, KEEP HEAO BELOW HIPS TO HELP PREVENT A|P f MAT l OH REACTIVITY REACTIVITYl REACTS MILDLY WITH WATER AND EVOLVES HEAT. INCOMPATIBICITIESi PHOSPHORIC ACID! BASES! VIOLENT REACTION. GFERRARNOITUES I MAETTTAALCSKEAONDBYALLHOOYTSCI OVNECREYNTCROATRERDOSAIVCEI&, . ESPECIALLY WHEN H1EATtEUDl. METALS) REACTS WITH LIBERATION OF EXPLOSIVE NVOROOEM OAS. -- RTTHUMETHRRrr~FDR1i PETOMR0LE"WntTPWE.---------------- . .. .. .. . . PLASTICS. RUBBER, COATINGS! MAY BE ATTACKEO. PORCELAIN! ATTACKEO BT MOT CONCENTRATED ACID. SODIUM TETRAHVOROBORATCl GENERATES HEAT ANO NAY BE EXPLOSIVE ON RAPIO MIXING. DECOMPOSITION) THERMAL DECOMPOSITION MAY RELEASE TOXIC OXIDES OF PHOSPHORUS. POLYMERIZATION! HAZARDOUS POLYMERIZATION HAS NOT BEEN REPORTED TO OCCUR UNDER NORMAL TEMPERATURES AND PRESSURES. STORAGE ANO OISPOSAL G S? 64 DATEl -T/fO INOEXl 1i*03250260 ACCTl 14I2ST-01 CAT NO( A2424 PAOE > 4 PO NBAl 310BK12O3-B REl 737 OBSERVE Ail FEOERAl, STATE ANO LOCAL REGULATIONS WHEN STOR1NO OR DISPOSING OF THIS SUBSTANCE. FOR ASSISTANCE. CONTACT THE DISTRICT DIRECTOR OF THE ENVIRONMENTAL PROTECTION AGENCY. STORAGE* PROTECT AOAINST PHYSICAL DAMAOE. STORE IN COOL, DRV. WELL VENTILATED LOCATION, AWAY PROM ANT AREA WHERE THE FIRE HAZARD MAv BE ACUTE INFPA 41, HAZARDOUS CHEMICALS OATA. 1 ST S) . STORE AWAY FROM INCOMPATIBLE SUBSTANCES. DISPOSAL** OISPOSAL MUST BE IN ACCORDANCE WITH STANDARDS APPLICABLE TO QCNERAT0R9 OP HAZARDOUS WASTE, 40 CFR 202. EPA HAZARDOUS WASTE HUMMER 0002. lOO POUND CERCLA SECTION 103 REPORTABLE OUANTtTV. CONDITIONS TO AVOIO MAV LURN BUT DOBS NOT IONITE RIAOtlV. FLAMMABLE, POISONOUS OASES MAY ACCUMULATE IN TANKS ANO HOPPER CARS. MAV IONITE COMBUSTIBLES (WOOD. PAPER. OIL. ETC.I. SPILL AND LEAN PROCEDURES SOIL SPILLi DIO A HOLOING AREA SUCH AS A PIT. POND OR LAOOQN TO CONTAIN SPILL AND DIKE SURFACE FLOW USINO BARRIER OF SOU, SANDBAOS. FOAMED POLYURETHANE OR POAMEO CONCRETE. ABSORB LIOUID MASS WITH FLY ASH OR CEMENT POWOffl. NEUTRALIZE SPILL WITH SIAKEO LIME, SODIUM BICARBONATE OR CRUSHEO LIMESTONE. AIR SPILL! KNOCK DOWN VAPORS WITH WATCH SPRAY. KEEP UPWIND. WATER USED TO KNOCK DOWN VAPORS MAV BECOME CORROSIVE OR TORIC ANO SHOULO BE CONTAINED PROPERLY FOR LATER DISPOSAL. WATER SPILLi NEUTRALIZE WITH AGRICULTURAL LIME, SLAKED LIME, CRUSHEO LIMESTONE, OR SODIUM BICARBONATE. USE MECHANICAL OREDQES OR LIFTS TO ERTRACT IMMOBILIZED HASSES OF POLLUTION ANO PRECIPITATES. OCCUPATIONAL SPtLLi 00 NOT TOUCH SPILLED MATERIAL. STOP LEAK IF YOU CAN 00 IT WITHOUT RISK. FOR SMALL SPILLS. TAKE UP WITH SAND OR OTHER ABSORBENT MATERIAL ANO PLACE INTO CONTAINERS FOR LATER OISPOSAL. FOR SMALL DRY SPILLS. WITH CLEAN SHOVEL PLACE MATERIAL INTO CLEAN, DRV CONTAINER ANO COVER. MOVE CONTAINERS FROM SPILL AREA. FOR LAROER SPILLS, DIKE FAR AHEAD OF SPILL FOR LATER OISPOSAL. KEEP UNNECESSARY PEOPLE AWAY. ISOLATE HAZARD AREA AND DENY ENTRY. REPORTABLE QUANTITY (ROM 9000 POUNDS THE SUPERPUNO AMENDMENTS ANO REAUTHORIZATION ACT (SARA) SECTION 304 REOUIRES THAT A RELEASE EQUAL TO OR OAEATEft THAN THE REPORTABLE QUANTITY FOR THIS SUBSTANCE BE IMMEDIATELY REPORTED TO THE LOCAL EMERGENCY PLANNING COMMITTEE ANO THE STATE EMERGENCY RESPONSE COMMISSION <40 CFR 399.401. |F THE RELEASE OF THIS SUSSTANCe IS REPORTABLE UNDER CERCLA SECTION 103, THE NATIONAL RESPONSE CENTER MUST BE NOTIFIED 1M4C0IATSLV AT (SOO) 424-SS02 OR 1202) 42S-2S7S IN THE METROPOLITAN WASHINGTON, D.C. AREA <40 CFR 302.01. PROTECTIVE EQUIPMENT VENTILATlONl FROVIDC^LOCAL^KXNAUST^tNTtLAUON AND/OR GENERAL OILUTION VENTILATION TO MEET RESPIRATOR! _ THE FOLLOWING RESPIRATORS ANO MAXIMUM USE CONCENTRATIONS ARE RECOMMENDATIONS BT THE U.S. DEPARTMENT OF HEALTH AND HUMAN SERVICES, NIOSM POCKET * TO CHEMICAL MAZAROSl NIOSH CRITERIA DOCUMENTS OR BY THE U.S. OEPARTMt F LABOR, 2S CFR ISIO SUBPART Z. __ ^ THE SPECIFIC RESPIRATOR SELECTED MUST BE BASEO ON CONTAMINATION LEVELS FOUWO IN THE WORK PLACE, MUST NOT EXCCEO THE WORK INO LIMITS OF THE RESPIRATOR AMO BE JOINTLY APPROVEO BY THE NATIONAL INSTITUTE FOR OCCUPATIONAL SAFETY ANO HEALTH ANO THE MINE SAFETY ANO HEALTH ADMINISTRATION (HIOSM-MSMA) . PHOSPHORIC ACXOl ______ it M0/M3- ANY SUPPLIED-AIR RESPIRATOR OPERATEO IN A CONTINUOUS PLOW MOOC. SO M0/M3- ANY SUPPLIED-AIR RESPIRATOR WITH A FULL FACEPIECE. S41 0009943 . ... OATEt IHOEXl tI/27/tO I11O32SO2B0 Aceri iss2st-oi CAT NOl A242* PAOE i 9 PO NMl 218BNIJ03-S HU. ?3t ANY SELF-CONTAINED BREATHINO APPARATUS WITH A FULL FACEPIECE. AMY AIR-PURIFYING PULL FACEPIECE RESPIRATOR WITH A HION-EFF1CIENCY PARTICULATE FILTER. 2000 MO/MS- ANY SUPPLlEO-AIR RESPIRATOR WITH FULL FACEPIECE AND OPERATED IN A PRESSURE-OEMANO OR OTHER POSITIVE PRESSURE MOOE. ESCAPE- ANY AIR-PURIFYIHG FULL FACEPIECE RESPIRATOR [GAS MASH) WITH A CHIN-STYLE OR FRONT- OR BACK-MOUNTED CANISTER WITH A HIOH-EFFICIENCY PARTICULATE FILTER. ANY ESCAPE-TYPE SELF-CONTAINED BREATHINO APPARATUS, FOR FIREFIOHTJNO AND OTHER IMMEDIATELY DANGEROUS TO LIFE OR HEALTH CONDITIONS I SELF-CONTAINED BREATHINO APPARATUS WITH FULL FACEPIECE OPERATEO IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. SUPPLIED-AIR RESPIRATOR WITH FU'.L FACEPIECE ANO OPERATED IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MOOE IN COMBINATION WITH AN AUXILIARY SELF-CONTAINEO BREATHINO APPARATUS OPERATEO IN PRESSURE-DEMAND OR OTHER POSITIVE PRESSURE MODE. CLOTMfNOt EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE (IMPERVIOUS) CLOTHINO AND E0U1PMENT TO PREVENT ANV POSSIBILITY OF SHIN CONTACT WITH THIS SUBSTANCE. OLOVESl EMPLOYEE MUST WEAR APPROPRIATE PROTECTIVE OLOVES TO PREVENT CONTACT WITH THIS SUBSTANCE. EYE PROTECTIONi EMPLOYEE MUST WEAR SPLASH-PROOF OR CHJST-RESISTANT SAFETY OOOOLES ANO A FACESH1ELD TO PREVENT CONTACT WITH THIS SUBSTANCE. FMEROfNCY WASH FACILITIES! WHERE THERE IS ANY POSSIBILITY THAT AN EMPLOYEE'S EYES AND/OR SKIN MAY BE EXPOSED TO THIS SUBSTANCE. THE EMPLOYER SHOULD PROVIOE AN EYE WASH FOUNTAIN AND QUICK DRENCH SHOWER WITHIN THE IMMEDIATE WORK AREA FOR EMERGENCY USE. AUTHORIZED - FISHER SCIENTIFIC, INC. CREATION DATE! 11/30/S4 REVISION DATEl t0/t0/90 -ADDITIONAL INFORMATION THIS INFORMATION IS BELIEVED TO BE ACCURATE ANO REPRESENTS THE BEST INFORMATION CURRENTLY AVAILABLE TO US. HOWEVER, WE MAKE NO WARRANTY OF MERCHANTABILITY OR ANY OTHER WARRANTY, EXPRESS OR IMPLIEO, WITH RESPECT TO SUCH INFORMATION, ANO WE ASSUME HO LIABILITY RESULTING FROM ITS USE USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION FOR THEIR PARTICULAR PURPOSES. SAL 000099 G S? 64 I J