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$-6 4 Js*-? o'/fe/tL- _ ; MATERIAL SAFETY DATA SHEETS For Coatings, Resins and Related Materials PLAINTIFF'S EXHIBIT SECTION I '9evy// AeCct MANUFACTURER: ADDRESS: EMERGENCY AND INFORMATION TELEPHONE: EMERGENCY TELEPHONE: Rust-Oleum Corporation 11 Hawthorn Parkway Vernon Hills, IL 60061 (312) 367-7700 (8:00 a.m. - 5:00 p.m. CDT) (312) 864-8200 (After Business Hours and on Weekends) PRODUCT CLASS: Aerosol MFG. CODE NO.: 2233, 2242, 2255 and 2264 TRADE NAME: HARD HAT Fluorescent Topcoats DATE OF PREPARATION: August 19, 1987 (MJS) SECTION II -- HAZARDOUS INGREDIENTS INGNECHENT/CAS No. Wt, H ACGIH-TLV OSHA-PEL LEL mm H0029C Hexane/110-54-3 Toluena/l08-B8-3 Mineral Spints/aOS2-41-3 PfopeUant/68476-86-8 (Propane, Butane, Isobutano) 30%' 10%' 15%* 30% * 50ppm tOOppm tOOppm 800ppm sooppm 200ppm 500ppm NE 1.2% 1.2% 1.0% 1.8% 137.0 22.0 2.0 85peia 'Nearest SH NE- Not Established NA- Net Applicable SECTION III -- PHYSICAL DATA Bolling Range: Below 0"F Vapor Density: heavier lighter than air Evaporation Rate (Ethersi): taster slower H Volatile (by vol.): NA WtJGal.: NA -------- pH: NA SECTION IV -- FIRE AND EXPLOSION HAZARD DATA Flammability ClassiRcetion: Extremely Flammable Flashpoint: Below 0F (TCC) DOT Clasalllcatlon: Consumer Commodity ORM-D Extinguishing Media: NFPA Class B Extinguishors (carbon dioxide, dry chemical or foam) ^felat Fire-Fighting Procedures: Full protective equipment including self-contained Phing apparatus should be used. Water spray may be ineffective. Water may be used to"cool closed containers lo prevent pressure buildup and possible autoignition or explosion. If water is used, fog nozzles are preferred. Unusual Fire and Explosion Hazards: Keep containers tightly dosed. Isolate from heat, electrical equipment, sparks and open flame. Closed containers may explode when exposed to extreme heal. DO NOT apply to hot surfaces. PRODUCT CLASS: Aerosol MFG. CODE NO.: 2326 and 2391 TRADE NAME: HARD HAT Striping Paints DATE OF PREPARATION: August 19, 1987 (MJS) PRODUCT CLASS: Aerosol MFG. CODE NO.: 2324, 2333, 2344, 2345, 2354, 2355, 2358, 2363, 2364 and 2392 TRADE NAME: HARD HAT Marking Paints DATE OF PREPARATION: August 19, 1987 (MJS) SECTION II -- HAZARDOUS INGREDIENTS INQREOCNT/CAS No. Wt. % ACGIH-TLV OSHA-PEL LEL mm HgQ20< Tokiene/106-88-3 0- tfi% Hexane/110-54-3 5-10% XytoU1330-20-7 6-20% Ethylene Gtycol/107-21-1 0-4% VM&P Naphthe/04742-69-8 1 " 3% Methyl Alcohol/67-56-1 * * 0-4% P/opane/74-96-8 15 - 16% lsobuUne/75-28-5 10-12% Tttanium DtoxMe/t34W-7-7 0-8% (As Nuisance Oust) tOOppm SOppm lOOppm SOppm aooppm 200ppm NE NE NE 200ppm SOOppm lOOppm NE NE 200ppm lOOOppm NE (15.0mgfm 1.2% 1.2% 1.0% 3.2% 0.9% 6.0% 2.3% 1.9% NA 22.0 137.0 0.5 0.12 2.0 96.0 40psia 40p*la NA 'Nearea* 6% This ehamlcal In 2363 and 2332 only. NE - Not Established NA - Mot AppttcaM SECTION III -- PHYSICAL DATA Bolling Range: Below 0F Vapor Density: heavier lighter than ai Evaporation Rata (Ether-1): taster slower H Volatile (by vol.): NA Wt./Gal.: N/ pH: Nr SECTION IV -- FIRE AND EXPLOSION HAZARD DATA Flammability Classification: Extremely Flammable Flashpoint: Below 0F (TCC DOT Classification: Consumer Commodity ORM-D Extinguishing Media: NFPA Class B Extinguishers (carbon dioxide, dry chemical or foam , Special Flra-Flghtlng Procedural: Full protective equipment including self-containe. ] breathing apparatus should be used. Water spray may be ineffective. Water may be use. to cool closed containers to prevent pressure buildup and possible autoignition or explosion If water is used, fog nozzles are preferred. Unusual Fire and Explosion Hazards: Keep containers lightly closed. Isolate from heat electrical equipment, sparks and open flame. Closed containers may explode whei exposed to extreme hast. DO NOT apply to hot surfaces. PRODUCT CLASS: Aerosol MFG. CODE NO.: 2348 TRADE NAME: HARD HAT Striping Paints DATE OF PREPARATION: August 19, 1987 (MJS) SECTION II -- HAZARDOUS INGREDIENTS (NGREOIENT/CAS No. Wt. H ACGIH-TLV OSHA-PEL LEL mmHg20C toluene/106-88-3 XytoUl330~20"7 Hexana/ilO-54-3** VM&P NapIUha/6474?-89-B Methyl AIcohoi/87-56-1 Propene/74-98-6 lsobutana/75-28-5 Titanium Dw*ida/13483-7-7 7- 19% 4- 15% 13% 0- 3% 2-4% 12% 8% 9-15% lOOppm tooppm SOppm 300ppm 200ppm NE NE NE 200ppm tOOppm 500 NE 200ppm tOOOppm NE tS.Omp/m 1.2% 1.0% t.2W 0.9% 6.0% 2.3% 1.9% NA 22.0 9.5 137.0 2.0 98.0 40pste 40p*U NA 5H **Thl chnmlcxl In 2SSt only. NE - Not Eaubilthsd NA - Not Applicable SECTION III -- PHYSICAL DATA Bolling Range: Below 0F Vapor Density: heavier lighter than air Evaporation Rate (Ether-1): faster'slower H Volatile (by vol.): NA WtJGal.: NA pH: NA SECTION IV -- FIRE AND EXPLOSION HAZARD DATA Raimmimobility Classification: Extremely Flammable Classification: Consumer Commodity ORM-D Flaihpolnt: Below 0F (TCC) gulshlng Media: NFPA Class B Extinguishers (carbon dioxide, dry chemical or loam) Special Flre-FIghtlng Procedures: Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. Water may be used 10 cool closed containers lo proven! pressure buildup and possible autoignilion or explosion. 11 water is used, fog nozzles are preferred. Unusual Fire and Explosion Hazards: Keep containers tightly dosed. Isolate from heal,' electrical equipment, sparks and open flame. Closed containers may explode when exposed lo extreme heal. DO NOT apply to hot surfaces. SECTION II - HAZARDOUS INGREDIENTS INGAEOENT/CAS No. Wt. % ACGIH-TLV OSHA-PEL LEL mm H8&20 XytoV1330-20*7 Toiuene/106-88-3 Methyl Alcohol/67-58-1 VM&P N^htba/84742-80-8 Propane/74-96-6 taobuiane/75-28-5 Lead Cnromaiar77S8-97-6 Lead (In Dry Flim)/7439-S2-1 'Numt fi% 2Mt* 10%' 4% 2% 12% 8% 5%* 5%* lOOppm lOOppm 200ppm 300ppm NE NE O.OSmg/m 0.15mo/m NE- Not Established lOOppm 200ppm 20Cppm NE lOOOppm NE O.Q5mgfm 0.05 mgfm 1.0% 1.2% 6.0% 09% 2.3% 1.9% NA NA 9.5 220 96.0 2.0 40pSia 40paia NA NA NA - Not Applicable SECTION III -- PHYSICAL DATA Bolling Range: Below 0F Vapor Density: heavier lighter than ai Evaporation Rata (Ether-1): (aster slower % Volatile (bv vol.): NA Wt./Gi).: Ni . i pH: N> 1 i SECTION IV -- FIRE AND EXPLOSION HAZARD DATA l ' Flammability Classification: Extremely Rammable DOT Classification: Consumer Commodity ORM-D Flashpoint: Below 0*F (TCC I Extinguishing Madia: NFPA Class B Extinguishers (carbon dioxide, dry chemical or foam Special Flra-Flghtlng Procedures: Full protective equipment including seif-container > breathing apparatus should be used. Water spray may be ineffective. Water may be user > , < to cool closed containers to prevent pressure buildup and possible autoignition or explosion . 1 If watef is used, fog nozzles are preferred. 1. Unusual Fire and Explosion Hazards: Keep containers tightly closed. Isolate from heat \- , electrical equipment, sparks and open flame. Closed containers may explode whoi > 1 exposed to extreme heel. DO NOT apply to hot surfaces. ` , BIRD 022704 '. & /^c 37/^i Ev<2-ir-r pjeAr//// ^ MATERIAL SAFETY DATA SHEET For Coatings, Resins and Related Materials SECTION 1 MANUFACTURER: Rus-Oeum Corporation ADDRESS It Hawthorn Parkway -- Vtonon Hdla H 60061 EMERGENCY TEL.: (3121BG4-8200 (Jli busutoss hours and on waakands) INFORMATION TEL.: (312) 367-7700 {B-&.00 pm COT) PRODUCT CLASS: Aikyd Reun-Hrgk Gloss and Ral Enamals ufo cone no. 412. 634. 721. 745. 662. A6G 866. 906. 925 931 935.964,9(5.977.2764 and 2766 TRADE NAME: Indusinat Enemeis-USDA Approead topcoats SECTION tl HAZARDOUS INGREDIENTS mORCDIENT/CAS. No. Mnorai Stm 16062-41 3 *Nsarast ** Wt. to 30- Boding fUga: 307-369* (153-196*0 Evaporation Rat* (Ethar 1): lular a) EXPOSURE LIMITS ACC1H-TLV OSHA-PEL LEL mm Hg420C tOOpprn SOOppm l-Oto 20 ME--Mot asUbJiahad NA-nof appUcatts SECTKM U - PHYSICAL DATA Vapor Oonaily: heavier bgttar than au 4a Volatile (by wot i:ll-to Wl/GbI.: 70-110 tbs. pH: HA $;;i 8>v; ft&.'Sf'S SECTION IV -- FME AMP EXPLOSION HAZARD DATA FlammabtUty CUaalUcatbxc OSHA Cum b Combustibte bqtao Flashpoint: 1Q4*F (TCC) DOT Ctassilfcstlon: Consumer Commootly ORM-D EsUnouistUng Madia: NfPA Class 8 winnowsheri (Carbon dKW/de. dry chemical or town) Special Fir* Fighting Procedures: FUi piotecliva equipment inducting sell-containad breathing apparatus mould be used. Wal*r spiay may bs inenecitv*. Water may 0* used to cool dosed container* to prevant pressure build-up and possrbto auiagmitoA or a` plosion. It wtr s used.' tog nozzles are ptatoti*). y*UMMt*fin afdEaptosioA Hazards: >totp coreainws tightly dosed. Isolate Iroqt neat. etowinqstequpiTi^ni. spaihs endopan |i'',IUa>e, Closed dgrweinaie may atpleoe when imposed (oexirtirna hast. pO NOT apply to hoi sttflacsat ` `k '<** *'; *'' ?i,;. ' ' .' .I1' CTIM V-HEALTH HAZAfiOOilM . 1 b It$*d*crtQvfttipoeure: -v j `\ iM> lAcut* (Inhalation)? enseihevc, uplMiofi M (he respiteiofytiea*oacute nervous'system <j*pr***o eparectaniaaPr'MadjehA " duzmeas. sioggering. contusion. unconsciousness or coma '** Acuta (ilun or Eya Contact): Primary Union! winch delatt the skin and can toad to damvtiM tout rapaaiad overeapoturas. Ingestier*: g*a*eirtisi*4f wroattoo, nsweea. vonuunp and dtarihee. Chronic: Reports have anown rapaaiad and protongta occupational ovaraappsura to advent* wilh parmanam beam and nervous i**"a-m-o-. V.', /Atv,'i6. .. N, -i-: Emaroancy and First AM ProcMhiraa:> * *. *'. ?*. t / `... ^ v Inbefaiton; Remove from aaposuta. restore breathing and noMy a pnystetan. Cya Coetoci: Flush epfiidiii|ir mth torgg^mcimto^wsit'.tor pl}e**MS ratDvt^\Nmtry.aMyt*cin. *7 SUn Contact: Wa*n iflectad was wA soap and waiar. remove cotoanuhatodtlaUunB and wasn'bafori ftoto#.* > Infaaiian: 00 NOT mowea omibng. Aaap parson warm, gum **C gat maaciJ auamton. Aipuaton ol us* mstarial into lha lung* can mum chaaueai pnaumonsia wn>cti can d* taut. SUOOlty:Onstabie Stabte SECT(ON VI *t REACTIVITY QATA *1 V * - *'* '". '-"T tncoa^atlbto: Wen Strong Ondamg Aganta Hssardou* Oatoeipeartion Products: 8y opan llama -- Carbon Monomto and Carbon Otostoa tlaxardous Folyiaanzstion: Will Not Occur ( "j V '``f/V-7 j * ,* SECTION VU -- SPHJL OR LEAK PROCEDURES Rafaaaa cr SpU! PmradurM: Ramoua ail sotecas of rgrwbcn, v*mua< area and tomoto with mart absorbani and nun-sparking tools. S cantsMar*. Motorspttf ano orpas*c vspois dunring fOTsyra^doairog. tn,pQnbngi%vaaw HK>$H PPtotofl 9>4>P!id^Mjaspda|orw Hoods (TC19C). Eya Piotactioa: U--sa wiarv4mtoa o4^f3lpWfo^P'aqim Rj'asholi^^asr- T'i - 0(ParPratoctltoAuipiaiurUs'wTlprviOitogiovaandiorc>cDBngiopr*tomTiratoAfiao'ifclncotKact.s> VsnUtouan: Ptovuto ganarsl dUoiroa gr- top^.eahau^^anplanorv in .vptun>p aog-paltorp to-Kasp TLV.f^-^aurdMs iagtadronts batom accapubUt tends. 'aSr;`f'v ^/--r. storaQa Gf KFPA Cl II CombuMibte hguids Contamars snoukl ba grouodad whan pouring. OtTaf Ptacaudont: DO NOT um mtornuiy. Empty conuinar* may ba hazardous. S <? i-if S BIRD 022705