Document BynYZXgMzQkGQDXB562qMvwr4

Page 36-1 R. S. Gajownik Chicago November 28, 1956 CLASS 3600 Rosin maleic type adducts, esterified or not, including fumaric or other acids capable of forming a diene adduct with rosin, and spirit and oil varnishes made therefrom. 3600 - 3629 Rosin maleic type adducts and spirit solutions thereof. 3630 - 3699 Rosin maleic type oil varnishes where the last two figures indicate % oil content in non-volatile portion. Includes adducts formed in situ in presence of oil. The oil varnishes are listed on pages 36-2 and 36-3. Hard resins and their solutions are listed on pages 36-4 and 36-5. Maleic and fumaric oil varnishes in general are superior to oleoresinous varnishes of comparable cost. They are lower in cost and inferior to phthalic alkyds. 0007-PMC-000000258 Page 36-2 November 28, 1956 Type Number Resin Oil Varnishes <3643) (3646) (3648) (3650) (3652) Fum. Int. Hal. Int. Fum. Inc. Fum. Int. Mai. - Int. (3654) (3655) (3666) (3677) 3602 Fum. Int. Mai. Int. Mai. Int. (36A1) (36A12) (36A14) (36A15) (36A16) 36A13 36A13 36A13 36A13 3602 (36C12) ,<36C13) '36C16) (36C19) Mai. Int. Fum. Int. Mai. Int. Mai. Int. (36C25) (36C321 (36C34) (36C38) Mai. Int. Mai. Int. Fum. Ipt. Mai. Int. (36C44) Fum. Int. (36C46) (36C48) (36C54) (36C55) (36C57) Fum. Int. Fum. Int. Gloss Varn. Hal. Int. Mai. Int. (36D31) (36P6) (36M1) (36M4) Fum. Int. Fum. Int. Mai. Int. Mai. Int. (36M8) Mai. Int. (36M9) Mai. Inc. . (36N4) Mai. Int. (36Y11) Mai. Int. 7. Oil Ale. 7. NVM Solvents Vise. GHT 46(662) 48 Soya 48 Soya 49 Soya 47 Castor P.E. Gly. Gly. Gly. Gly. 50 (145) V-X 50 30(145)}70(125) Q--S 50 (145) R-U 50 30(145) 170 (125) L-N 60 38(317)! 62 (323) T-V 54 D.C.O. - 50 (145) 59(662) Soya P.E. 50 (145) 68 Lins. P.E. 60 (145) 77 Lins. P.E. 60 (145) M-I Q-S U-W H-J 35 Lins. 62 Lins. 28 Lins* 62 Lins. 54 D.C.O. - 54 21(329){79(145) T-V 60 (145) R-T 68 50(151)150(145) H 60 (145) R-r 50 (145) H-L 26(6C8) 48 Soya 79 Lins. 45 Soya P.E. Gly. Gly. Gly. 55 55 100 ' 50 (145) 30(145):70(125) None (145) Zo- Za Q-S 29,,-38" S-U 56 Soya 61 (6C18) 41 (662) 90 Lins. Gly. DiPE Gly. P.E. 70 (145) 50 (145) 70 (323) 100 None Z]-Z2 0-Q Zi-Zj 6V9* 59 (28 Lin. (72 (6C22) DiPE 48 Soya Gly. 90 Lins. P.E. - 81 Lins. 79 Lins. Gly. Gly. 50 (145) 50 (1C12)100 None -- 100 None 100 None S-0 u-w 6*"9' 12"-16M 105M-130" 44 (662) 62 Soya 45 Lins. 40 Lins. P.E. 45 (145) P.E. 55 (1F6) - 45 (145) * 40 (145) H-J N-P K-M ArB 55 (38 D.C.O. (62 Soya P.E. 55 (151) 69 (38 Tung (62 Lins. P.E. 60 (145) 65 (66 Lins. (34 D.C.O. Gly. 60 (145) 72 (6Y5) Gly.. 75 98(317) 2(323) K-N M-0 M-0 G-J Max. Color Gard. 14 12 11. 12 12 11 12 12 13 12 a a a a Dark 12 11 12 12 12 14 10 9 9 10 - 10 12 14 a 11-12 9-10 9 12 12 10 0007-PMC-000000259 Cure AV/NVM Remarks Page 36-3 November 28, 1956 F. P. *F T.O.C. Lbs./Gal 0 75*F Number 20" min. 22"-27" 22"-27" 22"-27" 32" std. 20-25 20-25 20-25 20-25 20-30 Chicago only as - Same as (3648)-other than solvent Lacquer Plasticiser 20"-30" *- 20" std. 12-20 15-25 6-10 2-6 - Interior.Brushing Enamels Brushing Enamel 7"-9" -. - - 7 Std. 7 12-16 Driers Added Sanitary - Sanitary (36A12) , Sanitary version of (3654) 105 min. 55 min. 105 min. 55 'mfn. 40 Kin. riM 1Q5 min. j.05 min. 105 min. j.05 min. 105 min. 105 min. 105 min. 105 min. 105 min. 20"-30" 22"-27" 4 25"-30" 15-25 20-25 6-10 8 max. Freight Car Paint Liquid - PC&C Lltho 105 min. 55 min. above 200 105 min. - 9"-13" -. 82"-100" 17-22 5-9 20-30 7 max. Black Drum Enamels - - SKT Vehicle 105 min. 105 min. 80 miti. above 200 27"-37" 10-25 - 105 min. 20"-26" 62"-80" - - 15-20 5-7 - 6-10 6-10 - SET Vehicle C. Weigel supplier-#76 slow drying as Heat Set Vehicle 105 min. - 20-30 - - - 15-20. - - Marine Line 30 max. Enamel Mixing Vehicle 10-14 Driers Added. Wood Sealer. 105 min. 105 min. 105 min. 105 min. 15 max. - 135 - 8-12 - 105 min. 27-30 8-12 - 105 min. 20-30 m 80 min. 7.48 7.40 7.50 7.34 8.16 7.42 7.45 7.61 7.50 7.73 7.60 7.95' 7.60 7.42 7.75 7.50 8.25 7.47 7.91 7.40 8.40 8.12 7.40 7.33 8.18 e 8.19 8.26 7.40 7.35 7.2 7.12 7.6 7.65 7.60 8.45 (3643) (3646) (364S) (3650) (3652) (3654) (3655) '(3666) (3677) (36A1) (36A12) (36A14) (36A15) (36A16) (36C12) (36C13) (36C16) (36C19) (36C25) (36C32) (36C34) (36C38) (36C44) (36C46) (36C48) (36C48) (36C55) (36C57) (36D31) (36F6) (36M1) (36M4) (36M8) (36M9) (36N4) (36Yliy 0007-PMC-000000260 Page 36-4 November 28, 1956 Number Name Hard Resin3 & Their Solutions % Resin_______ NVM Melting Viscosity Solvents Point F _______ GHT_______ 3600 3602 3604 3606 Pentalyn X Mai. Est. Amberol 801 - Ext. Lt. Mai. Est. HG-ll Mai. Est. HG-28 EL Mai. Est. 100 100 100 100 None None None None 295 Std. BR 288-300 BR 264-268 BR 287-291 BR 50% (145)R 44% (317)K-P - - 3608 (3610) : 3612 3614 Pentalyn G HG-28 EL Sol'n. Cellolyn 102 Arochcm 520 Mai. Est. 3606 Mai. Est. Mai. Est. 100 55 100 100 None (323) None None 257-261 287-291 252-270 244-255 BR BR BR BR 4 H-L 40% (317)J-t - 36A9 (36A11) 36A13 (36A23) Amberol 800 Pentalyn X Sol'n. HG-77 HG-28 EL Sol'n. Mai. E3t. 3600 Fum. Est. 3606 100 56 100 50 None 252-259 BR (145) 295 Std. BR None 298-302 BR (145)(329)287-291 BR 36% (317)K-P Z3-Z4 V-JC 36C1 (36C10) 36C11 (36C14) 36C23) (36C29) Arochem 542 Pentalyn G Sol'n. Maleic Resin Fum. Ros. Add. Maleic Ros. Ester Maleic Ros. Ester Mai. Est. 3608 Ros. Add. Fum. Add. Mai. Est. Mai. Est. 100 50 100 50 60 60 None (145) None (4C7) (iC5> (1C8) 206-224 257-261 190-205 280-290 205-215 205-215 BR BR B B B BR D-E -' 42"-50" z4"z6 z3-z4 (36C31) HG-28 EL Sol'n. 36C35 Cellolyn 104 36G37 Amberol 750 36C40 Mai. Ros; Ester (36C41) j Fum. Ros. Add. (36C45) , McWhorters S-2266 3606 Mai. Est. Mai. Est. Mai. Est. Fum. Add. Mai. Est. 60 100 100 100 60 SO (317) Hone None None (4C7) - 287-291 194 BR 311-347 255-26Q 280-290 - BR BR B B - 50% (323XG-I 10'-14' S-U 36C47 36C50 (36C53) 36C60 (36C61) Mai. Ros. Est. Pentalyn K Mai.Ros.Est.Sol'n. P-39 Resin Mai. Ros. Ester 36D1 (36D4) 36D5 (36D33) (36D34) HG-110 HG-15 Sol'n. HG-15 Cellolyn 102 Sol'n. HG-110 Sol'n. Mai. Est. Mai. Est. Mai. Int. Mai. Est. Mai. Est. 100 100 60 100 80 m. 36D5 Mai. Est. 3612 36D1 100 50 100 60 60 None None (1C17) None (1C10) 221-229 '170-180 m 228-252 .* B BR BR - (323) (12D40) (12D40) m. - - 50% (323)A-C ll'-13' - z4"z6 -- A std. G-H R-S 36F1 (36F5) 36F7 36M5 Lewisol 33 Neolyn 2375T Arochen 460 Pentalyn B-56 Mai. Mai. - Est. Est. 100 75 .100 100 None - None None 320 Drop m 130 BR 40% (317)N U Std. - - 36N10 36N14 (36Y1) 36Y9 (36Y10) M-36 Resin S-W 360 Resin HG-28 EL Sol'n. Pentalyn N HG-28 EL Sol'n. Ros. Est. 100 Ros. Est. 100 3606 60 PE Ros.Est 100 3606 . 50 None None (334) None (319) 248-257 248-257 212-229 - BR BR * BR 50% (406)C-F 50% (406) C-E 60% (145)F-J D Std. 0007-PMC-000000261 AV/NVM Color Remarks Page 36-5 November 28, 1956 Minimum F.P. F Lbs jQ&l * T.O.C. @ 75F Number 14 Std. 25-40 25-30 20-25 N Std* Ros* Std* WG-M Ros. Std. 50%(317) 11G 50%(317) 11G 15 Std. 20-25 30-40 25-35 is-30 14 Std. 15 Std. 24-28 11 max. G 11 max. G M max. Ros. Std. 50%(317) 7-10G 50%(317) 9G 10 Max. G 50%(317) 10 Std. 10 max. 25-30 60 Std. 220-235 70 max. 15-20 20 max. - 11 max. G " 11 max. G 10 10 max. 20-25 27-35 105-115 22-28 178 max. - 10 Std. 50%(323) 11G 12 max. G 5-7 33-37 18 Std. 20 Max. 12-18 20 Max. 50% (323) 10G G Ros Std* 11 max. VG-N Ros. Std. 10 -- - 10 Std. ** * - 11 Std. m 10 36 Std. 5 Std. 135 Std. M Ros. Std. - m - 110-120 110-120 8 20-25 6-8 <a 50%NVM(406) 6-8 <a 50%NVM(406) M Rosin Std. 10 Std/ Varnish Resin Varnish Resin Lacquer Resin - Lacquer Resin - Varnish Resin - Furn. Lacq. Sealer & Lacq. Used in Water Dispersions Moisture Set Inks Heat Set Ink Vehicle Lacquer Resin Furn. Lacq. Sealer & Lacq. Match for 3606 Moisture Set Inks Hammer Vehicle Heat Set Ink Vehicle Printing Ink Heat Set Vehicle Brushing Lacquer Brushing Lacquer - Lacquer Lacquer * - Alcohol Soluble Resin Label Varnish * - 295 295 270 285 260 80 270 250 250 105 300 105 200 105 230 260 230 35 200 - 285 230 - 335 285 80 m 32 32 - - 130 20 9.18 9.42 9.26 9.35 9.03 8.35 9.33 9.43 9.4 7.86 9.26 7.32 9.35 7.70 9.55 8.0 8.0 8.25 9.46 - 9.35 9.68 7.75 9.03 8.13 9.14 8.0 at 8.11 8.27 8.42 9.0 9.66 9.37 9.50 9.50 8.35 8.10 3600 3602 3604 3606 3608 (3610) 3612 3614 36A9 (36A11) 36A13 (36A23) 36C1 (36C10) 36C11 (36C14) (36C23) (36C29) (36C31) 36C35 36C37 36C40 (36C41) (36C45) 36C47 36C50 (36C53) 36C60 (36C61) 36D1 ;(36D4) 36D5 (36D33) (36D34) 36F1 (36F5) 36F7 36M5 36N10 36N14 (36Y1) 36Y9 (36Y10) 0007-PMC-000000262 Page 36"6 November 28, 1956 Remarks M&lglc anhydride and fumaric acid may be used more or. less interchangeably in rosin oil varnishes. In general, rosin fumaric varnishes have a faster drying time, harder films and lighter color. Also, fumaric acid is cheaper than maleic anhydride. There fore, it is requested that all new rosin varnishes which may be made with fumaric acid or maleic anhydride, be formulated to utilize fumaric acid. Varnishes made in situ are generally more 'economical than varnishes made by cooking already manufactured hard resins with oils. Therefore, varnish formulators are urged to try to make in situ varnishes whenever possible. Conditions' are now such that the manufacture of maleic hard resins in the Chicago Varnish-Resin Department are economical. Resins equivalent to some of the more popular and useful competitive resins are now being developed. (3643) is a low cost vehicle for industrial application where cost is especially Important. It has fair flexibility and good gloss retention but is rather dark in color. (36C45) should be replaced with (3648). (36C46) should be replaced with (3650) where possible. (3648) a fumaric version of (3645), has been found to dry faster to a harder film that (3045). It is especially adapted for use in low cost finishes. Initial gloss and gloss retention on baking are good. Color retention is fair. This varnish may be used to advantage in shelf goods, drum enamels, and low cost industrial finishes requiring air dry or low temperature baking schedules. (3654) is used primarily in roller coating finishes for tin decorating enamels. It dries rapidly, leaving a hard and tough film with good gloss and adhesion. It tends to be a bit brittle and is usually used with longer oil varnishes. The dried film must withstand various deformation proc esses involved in making metal products. It is suggested that an in situ varnish be used. (3666) is primarily used in interior brushing enamels. It has good flow and rapid air drying speed. (3677) has good scuff resistance and is especially adapted for porch and deck enamels. (36N4) has good flow and is well suited for brushing application. It is suggested for use in industrial primers and enamels, but is not recommended for shelf goods due to its tendency toward instability. 0007-PMC-000000263