Document BymvX16aJG25d6zM9JxvjKd4

Good-rite' CHIMICALS MATERIAL SAFETY DATA SHUT GOOD-RITE# 3190X29 AHTIOXIDAHT ISSUED: Hovenber, 1985 DOC: 85180 SECTIOH I Manufacturer* a Hama Telephone number The BFGoodrich Company (216) 447-6000 Polymer Chemicals Dept. Transportation Emergency Telephone CHggggC: (800)424-9300 Address 6100 Oak Tree Blvd. * Cleveland, Ohio 44131 Chemical Family Aromatic amines Trademark Good-rite# 3190X29 Antioxidant WaTM*/Synonyms Alkylated diphenylamines. AgeRite# Stalite# CAS Registry Ho. 68921-45-9 Fonmila -- SECTIOH II - HAZARDOUS IHCHEDIEMTS Residual diphenylamine CAS Humber 122-39-4 Amount in Product* < 2.01 ACGIH TLV-TWA 10 ag/m? OSHA PEL HR *Typical amount - not a specification. Hotea: TLV-TWA: Threshold Limit Value - Time Weighted Average for concentration of the chemical substance in the ambient workplace air for a normal 8-hour workday, 40-hour workweek, to which nearly all workers may be repeatedly exposed without adverse effect. American Conference of Governmental Industrial Hygienists, 1985/1986 Edition. OSHA PEL: OSHA Permissible Exposure Limit, 8-hour TWA. 29CFR1910.100 < means "less than'* RE means "none established** *0 BFG12011 Th* BFOoodrioh Campowy, ChtiWool Ofoup/6100 Oak Tree B<vd- Clavsiand. Ohio 44131 BFGoodrich Chemical Group The edemtabon contomed Keren m btlioind io 0# reliable, but no eoiee>ntqiioni. guaror* fees or noffanesj of any land ore mode ot e M occurocy. udBbRty lor pomcutor oopbconon* or toe reeum to be odkaned therefrom. The ntotmowcn e bosed on hatowatory wort wen wnaH- scafe equewnem and does not neceesonty wajioqre end product pertomronce. Becouss of the vanotione m methcde. conbmom and rmapmewt used conwr*ercio<K m proceemnq theae miarenais. no womantiea or quomresss are mode os ro ire suitabiliKi of the product* for theqp pbcaeons disclosed Rd icoie teeing and end product pertermanee are Ere lasponabiMy of iheueer.BFGoodwchshqMnofbebqbfetorqndthecueiomef nesumesairtatonaiiafedirvofonv use or nondhng or any mowridt beyond SFGoodneht direct control THE SELLER MAKES NO WA&MNVEL EXPRESS OR MPUED. MCLUOMG BUT NOT UMTTEO TO. 7V IMPLIED WARflANTCS OP MERCHANTAMJTY AND RTNESS FOR A PARTICULAR PURPOSE. Nothing contoured hereet e io be cenmdered ac pertvusmon, recomrnendQiion. nor as on rv ducemew id practice any patented inwaneon edhouf petmmmon of the potent omw. SECTION III - PHYSICAL DATA (Typical data, not specifications) Boilinn Point Hot Determined (HD) Melt Point Hot Applicable (HA) Specific Gravity (H2O-I) 0.97-1.01 Solubility in Mater Negligible % Volatile bv Weight Vapor Density (Air 1) 0.25% Max. HD Appearance and Odor Reddish brown liquid. Slight amine odor. SECTI0M IV - FIRE AMD EXPLOSION HAZARD DATA Flash Point 410F (210C) COC. Ignition Temperature HD Flammable Limits in Air (% bp volume) Lower: HA Upper: HA Extinguishing Media Water. ABC dry chemical. Protein type air foams. Carbon dioxide may be ineffective on larger fires due to a lack of cooling capacity which may result in reignition. Special Firefighting Procedure Wear positive pressure self-contained breathing apparatus (SCBA). Personnel not having suitable respiratory protection must leave the area to prevent significant exposure to toxic combustion gases from any source. In enclosed or poorly ventilated areas, wear SCBA during cleanup immediately after a fire as well as during the attack phase of firefighting operations. Unusual Fire and Explosion Hasarda None known. SECTIOH V - HEALTH HAZARD DATA Threshold Limit Value None established Effects of Overexposure Diphenylamines may be irritating to mucous membranes. which can irritate the eyes and respiratory passages. occur from inhalation or skin contact. Heating may generate vapors Systemic poisoning may Emergency and First Aid Procedure IM CASK OF EYE CONTACT: Flush eyes with plenty of water for at least five (5) minutes while holding eyelids open. See a physician. T case of SKIN CONTACT: Wash the affected area with plenty of soap and water. If irritation develops, see a physician. IN CASE OF INGESTION: Induce vomiting by sticking finger down throat or by giving Syrup of Ipecac. See a physician. 21234049 5186b/27 2 BFG12012 SECTIOM VI - REACTIVITY DATA Stability Stabla Hazardous Polymerization Will not occur Hazardous Decomposition Products CO, C02 oxidas of nitrogen and snail amounts of aromatic and aliphatic hydrocarbons. Incompatibility (materials to avoid) Avoid contact with strong oxidizing agents such as hydrogen peroxide, permanganates and perchlorates. Depending on the amount and specific materials involved, contact can result in intense heat, boiling, flame development, explosion or toxic gas generation. SECTtOH VII - SPILL OH LEAK PROCEDURE Steps to be taken in case material is released or spilled Contain spill. Becover as much as possible for reuse. Absorb remainder with an inert material. Place into closed container and store in a safe location to awai disposal. Wash the spill area with soap and water. Do not flush chemical into public sewer or water system. Waste Disposal Method Dispose of waste in accordance tilth federal, state and local regulations. For waste disposal purposes, this product is not defined or designated as hazardous b current provisions of the Federal Resource Conservation and Recovery Act (RCRA). 40CFR261. Liquid or dry material may be disposed of by incineration. Most states prohibit disposal of liquids in landfills. Small quantities of liquid may be mixed with a drying or bulking agent so that the resultant mixture may be disposed of in a landfill. SECTIOM VIII - SPECIAL PI If IHFOBMATIOM Ventilation Effective exhaust ventilation should always be provided to draw fumes and vapors away from workers to prevent routine inhalation. Ventilation should be adequate to maintain the ambient workplace atmosphere below the limits listed in Section II. Respiratory Protection Wear a respirator approved by HIOSH/MSHA whenever exposure to mist, fumes or vapors exceed the limits listed in Section IX. Use in accordance with manufacturer's use limitations and OSHA standard 1910.134 (29CFS). Protective Equipment -Wear monogoggles -Wear protective gloves. JO 55 5186b/27 O 3 BFG12013 SKCTIOH n - SPECIAL PRECAUTIQHS -Use under well-ventilated conditions. -For personal hygiene protection, we recommend that employees wash thoroughly after handling product. Always wash-up before eating, smoking or using toilet facilities. -Avoid prolonged or repeated skin and eye contact. -Avoid breathing vapors or mist. -Keep container closed when not in use and upright to prevent leakage. -Loosen bung.before heating drum. -Store at a temperature above 72F (22C) or more to prevent crystallisation. S8CTI0M X - TRAHSPOBTATIOM For domestic transportation purposes, this product is not defined or designated as a hazardous material by the U.S. Department of Transportation under Title 49 of the Code of Federal Regulations, 1983 Edition. e DOT Proper Shipping Hama: Hot applicable DOT Hazard Class: Hot applicable DOT Label: Hot applicable e UH/HA Hazard Ho.: Hot applicable SECTIOH XI - HAZARD CODES wmafLw Health: Flammability: Reactivity: Special: 2 1 0 -- HMI3 <**) Health: Flasaability: Reactivity: Personal Protection: 1 1 0 Splash goggles, glov Hazard Code Key: 0 Insignificant: 1 - Slight; 2 Moderate; 3 m High; 4 - Extreme. (*) national Fire Protection Association. HFPA rating identifies the severity of hazards of material during a fire emergency (i.e., "on fire-). <**) Hazardous Materials Identification System, national Paint and Coatings Association. HMXS rating applies to product Mas packaged- (i.e., ambient temperature). USER'S gBSPOMSIBILITT This bulletin cannot cover all possible situations which the user may experience during processing. Each aspect of your operation should be examined to determin if, or where, additional precautions may be necessary. All health and safety information contained in this bulletin should be provided to your employees or customers. It is your responsibility to use this information to develop appropriate work practice guidelines and employee instructional programs for you operation. 5186b/27 21294OSi 4- BFG12014 DISCLAIMER OF LIABILITY As the conditions or methods of uss ars bsyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of this material. Information contained herein is believed to be true and accurate but all statements or suggestions are made without warranty, express or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results to be obtained from the use thereof. Compliance with all applicable federal, state and local laws and regulations remains the responsibility of the user. 5186b/27 -5 - w & BFG12015