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PLAINTIFF'S EXHIBIT
f Hill and Griffith Company Material Safety Data Sheet
May be used to comply with OSHA's Hazard Communication Standard, 29 CFR 1910.1200. Standard mint be consulted for specific requirements.
N.A. = NOT APPLICABLE
N.E. = NOT ESTABLISHED
1. PRODUCT IDENTIFICATION
PRODUCT NAME (s): Red ChiefDry Core Paste
Manufacturer Address:
Telephone:
The Hill & Griffith Co. 1262 State Avenue Cincinnati, Ohio 45204 (513) 921-1075
Fax:
(513) 921-9180
EMERGENCY TELEPHONE: (800) 424-9300
Call Chemtrec
II. HAZARDOUS MATERIAL IDENTIFICATION SYSTEM *
CATEGORY Flammability Health Reactivity Personal Protection
RATING
1
2
0 B
These ratings are based on NFPA regulations
LEGEND 1=Sligbt Hazard 2=Modexate Hazard 0=MImmal Hazard B=Glasses and Gloves
III. HAZARDOUS INGREDIENTS
HAZARDOUS INGREDIENTS Iron Oxide Inert Nuisance Dusts As respirable dust
-
CAS.NO. 1317-60-8 Mixture
ACGIH THRESHOLD LIMIT VALUE' 5 mg/m3 10 mg/m3
%
5-10 50-60
OSHA PERMISSIBLE
RANGE
EXPOSURE LIMIT
NE
15 mg/m3
@ This material contains Silicon Dioxide in some form. IARC Monographs on the evaluation ofthe Carcinogenic Risk of r't'pmimlc to Humans (Volume 42, 1987) concludes that there is sufficient evidence for the carcinogenicity of crystalline silica to experimental animals, and that there is limited evidence ofthe carcinogenicity of crystalline silica to humans. Classified by the
IARC as 2A.
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Product Name: Red ChiefDry Core Paste
IV. PHYSICAL/CHEMICAL PROPERTIES
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Appearance and Odor. Red powder, sweet odor.
Water Solubility: Miscible.
Melting Point(F): NA
Boiling Range(F): NA
Specific Gravity(water=l): NE
Vapor Pressure(mmHg): NA
Vapor Density(Air=l): NA TPQ: NA
Percent Volatile By Weight: NA
Evaporation Rate(Butyl Acetate=l): NA RQ: NA
V. FIRE AND EXPLOSION INFORMATION
Flash Point(C.O.C.)(F): NA
Auto-Ignition Temperature(0F): NE
Flammable Limits: LEL: NE
DEL: NE
Extinguishing Media: Alcohol foam, COz, or chemical.
Unusual Fixe or Explosion Hazards: Material may bum in the presence offlames or high heat sources.
Speclwianl FAiirret-Fighting Procedures: Use full facepiece with self-contained breathing apparatus when fighting fires near tmhiiss
VI. CHEMICAL REACTIVITY INFORMATION
Conditions Contributing to Instability: None. Incompatible Materials: Strong acids or oxidizers. Conditions to Avoid: None. Hazardous Decomposition Products: Various oxides of carbon and hydrogen. PRINTED IN U.S.A
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t Product Name: Red ChiefDry Core Paste
VII. HEALTH HAZARDS A. Summary/Risks
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Signs and Symptoms of Overexposure: Eyes- irritation with redness and swelling; Sldn- may irritate; Inhalation- may cause coughing and sneezing.
Medical Conditions Generally Aggravated by Exposure: May aggravate pre-existing medical conditions. Primary Route(s) ofEntry: Inhalation, skin contact, and ingestion. Target Organs: Eyes, lungs, and skin. Acute Health Effect: Overexposure could lead to skin irritations and lung or mucous memhranft irritation.
I
Chronic Health Effect: Overexposure could lead to severe damage to skin, eyes, lungs, or mucous msmi^nf.s Carcinogenicity: Seepage 1. Notes to Physician: None.
VII. HEALTH HAZARDS B. First Aid/Emergency Procedures
Inhalation: If overcome, immediately remove from exposure and seek medical attention. Skin Contact/Absorption: Wash skin thoroughly with soap and water. Ifirritation develops, seek medical attention. Eye Contact Hush with clear flowing water for at least 15 minutes. Ifirritation persists, seek medical attention. Ingestion: Ifingested, DO NOT induce vomiting; call a physician immediately.
VIII. SPILL, LEAK AND WASTE DISPOSAL PROCEDURES
Procedures for clean-up ofspills/leaks: Stop spill as soon as possible. Scoop up or clean up using best m^anc possible. Water may be used to clean area. Notify proper authorities if the need exists.
Waste Disposal: Waste generated during application, demolition, breakage or spillage may be hazardous wastes as defined by RCRA (40 CFR part 261). Place waste and spillage in closed containers. Dispose ofin approved landfill in accordance with federal, state and local regulations.
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I Product Name: Red ChiefDry Core Paste
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IX. PROTECTION AND CONTROL INFORMATION
Hygienic Practices: Minimize breathing vapors, mists, fumes or dusts. Avoid prolonged or repeated contact with .ctrfn Remc contaminated clothes, launder before reuse. Remove contaminated shoes; clean before reuse.
Ventilation Requirements: Provide ventilation sufficient to prevent exceeding recommended exposure limits. Respiratory Protection: Use NIOSH approved organic cartridge Type 7 respirator for vapors and/or a fine particulate filter for
dusts, ifnecessary. Eye Protection: Use safety glasses, splash goggles, or face shield when eye contact may occur. Protective Gloves: Use chemical-resistant gloves, ifneeded, to avoid prolonged or repeated skin contact. Other Clothing and Equipment: As required to prevent contact Engineering Controls/Work Practices: Keep containers and storage containers closed when not in use. Special Considerations for Repair/Maintenance of Contaminated Equipment: Provide adequate respiratory, eye'and stem
protection.
X. PRECAUTIONS FOR SAFE HANDLING AND USE
Storage Segregation: Always segregate materials by major hazard class. Special Handling/Storage: Do not transfer contents to unlabeled containers). Other Comply with all federal, state and local regulations.
XI. DOT SHIPPING REQUIREMENTS
Shipping Name(s): Any Packaging
Compound, Adhesive
Date Prepared:
07-28-97
Prepared by: Lon R. Yeager
Supersedes: 10-14-93
Print Date- 07 28 97
Title: Corporate Government Regulatory Manager
As ofthe date ofpreparation ofthis document, the forgoing information is believed to be accurate and is provided in good faith to comply with applicable federal and state law(s). However, no warranty or representation with respect to such information intended or given.
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