Document By6R4pawkXBaBroMzBwrXwBMm
~~p eo
CCP33eh00eo47nn83ne.tRFtoe(rs6se1eeea4a)rrcc2hhAA51DDn8inri0vav5eeal2 lygtSStiatiatcctesaaCloClloleggLL,eF,aaaPPbAAb(oT13616or938)00ra112a3t1-to1o2r5r5--wi_iwoeverwa(s.nsc5v1e,c8.n)etrn2eeII9laln1nbi1cc.bc5e.o.8om0m
hone: (814) 231-8032
Fax: (814) 231-1253 or (814) 231-1580
AAnnaallyyttiiccaall RReeppoorrtt
FFlluuoorroocchheemmiiccaall CChhaarraacctteerriizzaattiioonn ooff W Waatteerr SSaammpplleess Centre Analytical Laboratory Report No. 023-014LL CCoottttaaggee GGrroovvee PPoottaabbllee WWaatteerr EEvvaalluuaattiioonn ((EE01-081122))
Centre Analytical Laboratory Report No. 023-014LL
TTeessttiinngg LLaabboorraattoorryy
CCeennttrree50AAn4na8alylAyttaiiccsaaellarLLacabhboorDraiattvooreryy,, IInncc..
SStt3aa0ttee48CCooRlllleeesggeee,a,rcPPhAAD11r66iv88e0011
33MM EEnnvviirroonnmmeennttaall LLaabboorraattoorryy CCoonnttaacctt
KeKnenttRR.. LLiinnddssttrroomm BBllddgg.. 22--33EE--0099 PP..OO.. BBooxx 3333333311
St.Paul, MN 55133-3331 St. Paul, MN 55133-3331 Phone! (651) 778.5362 Phone: (651) 778-5352
Requester
--
Requester
JJaaPmm.BB0leel.ddssgg.B.KK.o.22x-L3L3uE3uEn3n:-d3d00b3b99e1errgg
St.
St.
Pau, MN 55133-3331 P.O. Box 33331
Paul, MN 55133-3331
ATTOI:IN -CLIENT PFIIVILE6E-CONFIDEI J]'IAL
PAPAGGEE1I00FFS5
11778855..00000011
Ex1h7i8b5it 33MMAA00D0E8S533334499
ATTORNEY-CLIENT PRIVILEGE-CONFIDENTIAL
11 IInnttrroodduuccttiioonn
ARRenesasuuylltttssalraroeLabrroearppaootrrottreeiddesf,foorritcthh.ee(aaCnneanaltlyyrss)iissooofmf aatsseeerr3iiee1ss EoofnfvppiooratoabnblmleeenwtwaaaleteLrrabssoaarmmcppilaleeyss. rreTechceeeivseeaddmpbblyyeCCseewnnettrrreee
c0Acoo2nlla3leel9cyctt1tieec4ddal
from Cottage Laboratories,
from Cottage
Grove, Mimesota. Inc. (Centre) from
Grove, Minnesota.
The Conire stu number assigned 10 the project the 3M Environmental Laboratory. The samples were The Centre study number assigned to the project is
023-014.
S(SpLpeCecMcifSiicMfflSulu)oorrowocechsheomrmieicqcaualelsccthheaadrraafcoctrteelrrilizzsaaattiimoopnniobbsyy. iliAquitiodtacclhhorrfoo2mm0aattsooaggmrrpaalppehhsyyw//ettraaonndrdeoemcmoimmvaoadsssfsorsspapeleycstcriotsm.reotrmy
(LC/MS/MS) was requested for all samples. A total of 20 samples were received for analysis.
Tha samples wire prepareandanalyzebdy LOMSMSfortho folowing ist of fuarochemials
The samples were prepared and analyzed by LC/MS/MS for the following list of fluorochemicals:
+
Table 1: Target Anayss
Table 1 : Target Analysis
[ ComuC oundo Namem ----p ----oundTa hAocorom nnymm e|
Perfluorooctane Sulfonate Perfluorohexane Sulfonate
re Perfluorobutane Sulfonate
Perfluorooctanoate
TY PPPEFFMHOSSS
PPEFBBSS
PFOA
Perfluorohexanoate
PHAA
22 SSaammppllee RReecceeiipptt
TwThehereessaamcmpollpeelcestsewwdeer6ree01ss/uu0b1b,mmiittSteeaddmpiinln eiinsnddivwvieiddruueaall rppelacaessittvicedccooonnnttaai6ni7en/r0ss1.aannddChwwaeiernreeanlncoout sppirroeedssyeerrvveiednd.f.ormSSaaatmmipopnlleess
presentedin AtachmentC. were collected 6/01/01. Samples
presented in Attachment C.
were
received
on
6/7/01.
Chain-of-custody
information
is
33 HHoollddiinngg TTiimmeess
TsTahhmeepaalnnsa.alylytStiitccaaabllilmmteeyttahhooordd uuhsiseseddtiwwmaaesspevvraaillioidddaahtteaedds aanggotaaiibnnessat naa vmmaaaxxdiimm.uumm Hhhooowildeginvneggrit,immeesoohff o11u44 ddbaaeyynssotiinnewdwaatttheetrr
fsf1ieai0lm0od0pfnfloeorgsit.iificScfoaatattibopoiennlirsstyioiianndftsewwlaroattntheegirsrerataimnnhddaenooptte1hhr4eeiorrddmmahaa.attsiriccneeosst
have been
have
shown acccpiable validated. However,
shown acceptable
recoveries at 100 it should be noted
recoveries at 100
andthat
and
1000 ng/L for periods longer than 14 days.
44 MMeetthhooddss -- AAnnaallyyttiiccaall aanndd PPrreeppaarraattoorryy
444.1111 SLLaCCm/pMMlSeSIP/MrMeSSparation for LOMSMS Analysis
4.1.1 Sample Preparation for LC/MS/MS Analysis
WWtaeatmtooervressaarmemsppcllueasslwwceehrrieonieinn.idtiiaSllloyyltedreapalhteeaddsewwieithhxt22o00c00iouunlL.(ooSffPE22)5500wammsgLs/L dSsoodd1ii0uumpmrttehhiopossauuhtrlfaaetteesaSsmoploultieonsn ottoro TLrLeChCme/MMocvSSaer/MMtriSeSdsgiaadennuawaaylalyssscsih.sal.otrAAiendeffo. rwoStyior-hmlidm1ill0apilih0trea%rseppmooeetrttxihiotoarnnancoootlfifossnaaAmm(SpplPlmeeEL)wwawapssaorsatrianuonnssselofdefrrmtrroeeodtphrt1aeonpaaoalrCCe1ws8tehSSsePPcsEEoalmclcaearpcrtltterreiisdddggffeeoo..rr
The cartridge was eluted with 100% methanol. A 5 mL portion of methanol was collected for
pace2065 P~4GE2 OF5
11778855..00000022
AITORNEY-CLIENT PRIVILEGE-CONFIDENTIAL
aannaallyyssiss bbyy LLCC/MMSSM/MSS..
This treatment resuted in an eght10 Gonoentoaften samples
This treatment resulted in an eight-fold concentration of the samples
pproiorrttoo aannaalylsyis..
412 4.1.2 SSaammppllee AAnnaallyyssiiss bbyy LLCC/MMSSM/MS.S
1cIn0olHHuPPmLnLC,C,,aBananseaadliuqoutnottoohffe oeaxxfttfraaictctytiiossfnitnfjoceciatoendd aaannldd fpporaasshsseeeddsatrhtoroounugagrhhyaapalliqsuieid-pnphhatahsseeecccohhrruoommnaatetooaggrtraavppehhiticco rHcthoPeeluLqlmiCqunuis.iddepmBmaroaoabsbteliildoeano,ppnhhEaatshsSoee,,Sahtfhfiepenritoaayvnnioadflaeytstheeeasisarnrareapotldyatiaenaendfddorffaotcohrcreuaarsccatahlhotaaiorrmanaecactatreynerirsspithifscaorsaaeammnoiaonulunytnhztteinoocgffoitaliummemwe.in.cerFFeaoolalnlltoogivnweeiinntogogf oHomrriPgdgLaCantinecsmepccpeoorammarptapuotoirouuennsn,c;dsEs,,mSa/innMlcceSluucidupinsrnosggvialfdlurueoeosrraooacnchrhzaeeepmmdiid,iccaaaflnlas.dg. maEEecolnecctucietrrradoot,sseppramraaneyydafisndssegglaefeonntreeaadrra.nllalyylyooozpnpineesgrraacattheeawdrdia(~acatetererreaialsnaltgtviiveeceloolyyff mknilodwtnemfupoerroacthueremsi;camisolaerceuloebssearrveedionainzdedQ,uafrnatgimateendteadg,aiannstd sdteantedcartedds.. Ions characteristic of
known fluorochemicals are observed and quantitated against standards.
AAanHHaaleywwzoeletttt-PhPeaaccskkaaamrrpddlHHePPe11x11a00c00tsHH.PPLLACCnassyyysssttseemmwccaoosuuppplleeedrdltfooomaaoMdMiiccurrsoohmmgaassssselUUetlctiitmmedaa MMroSSa/McMtSSonwwamasosnuudssoeerddnttgoo (ba(SSenRRtaMwlMy)e.z)e.enSStaah6mme1pp2lsl0eeas1smwwpaeleenrredeeexxe6ttxr1rtara5cac0tcst1t.ee,ddAononanTlhy66os//i1s1H22/Pw00L11aaasCnnddpaen66rd1f/o131r3Mm0/01Se.1dH. SuSSsaaimmnmepgptllneesosesdlewwsceetrerueodsaeanrdnaealaflcyyotrzzioeeanddnbabmlyyyosnMMiistSSo/rMaMinnSSgd ibnestwtuemeennt6p/a1r2/a0m1etaenrds c6a/n1b5/e01o.unTdhie AHtPaLcChmeanntds 0.MS/MS methods used for analysis and
instrument parameters can be found in Attachments D.
55 AAnnaallyyssiiss
55.11
CCAaa7l-lipibobirrmaat ttciiaoolnbnraton Afor7-tphoeinctocmaplioburantdiosn
occfuurrnvveeerewwstaa.ss
aaTnnhaaellyyczzaeelddoraaalttitthohnee
pbbeoeggniisnnnniiwnneggreaannpddreeepnnaddreoofdf
tiahtee 0aanna2al5ly,yitic5c0aa,ll
ss1ee0qq0,uuee2nn5cc0e,e
ef55oa00r00,,thaaepnnocddno.1m100p00Uo00usnnnedgLs/Lno((afp3pipant.)t.errTTeerhhseoet.ssniTnishsotetnruucmmiaeelhinbntrta1rrtieeossnwpporopnnoissinneetgsvv.eewrrseshurueoss tpdhhreoeeppcecao.ornne-ccdeeinnattttreea0it,pioo2tnn5,wwna5ad0ss, cpp1il0oot0itter,edd2t5ffoio0r,r
cecaooaecahcfffiicpcieocnninttt.o((r))U>paasnni0nddgi98cclioo5naaee(ffa*ffibrc2ci0ereen.nlgt9tr7eoo0osff)s.icdoeenlteowrmmitihinnaa1it/ixoonnwe((7)rig~)htwwineegrr,eethddeeettselerommpieinn,eeyd.-.inteAArccceaaplltibbarraanttdiooncnoccrruuerrlvvaeetioiinss
acceptable if r >0.985 (r~ _> 0.970).
CfCoaarllsbibarrmaapttliioeonsn.ssttaannddaarrddss
ffoorr
MSIMS
MS/MS
analysis
analysis
wero
were
pregared
prepared
using
using
the
the
same
same
SPE
SPE
procadure
procedure
used
used
for samples.
CtChaarlloibburrgaahttoioounnt cchthheeocckk assntiaaalnyrdsdaiasrrdcsswewqeeurreeencaaenn.aallyyzCzeeoddmpppleaarrinoodcidecailaliys ((eeovvbeelrrayynttehidreceef ttootffhivieee sssaaammnpdplaleerdirnejecatcnitiaooynntss)s)
tchornocuagnhtoautit onthseareanwailtysis+/-se20q%uoefntche.e aCctoamlpvliaalnec.e is obtained if the standard analyte
concentrations are within +/-20% of the actual value.
Fortho rsuls eporod hee, caivaton cir were mel.
For the results reported here, calibration criteria were met.
55.22
BEBxllraaannckktossn eExxttraaccitioonn
bbballanannkkksssshwwoeeurrleednpproreetppaharareevdde
aaannnddy
taaannragaellytyzzaeenddalwwytiitenhs
eepvvreeersryyeneetxxltvroaaccftiaioobnnovbbeaatccthhhe
oocff
ossanammcppelleersst.
oTThhoeef
eixtralcotwioenvebllacnaklsibsrahtoiuonldstnaontdahradv,e aFnory hase targetSaanmaplyetess, phreesGeKnIt cait oornaDbioanvkestwheerceonccoemndtiraatniotn of
the low-level calibration standard. For these samples, the extraction blanks were compliant.
JIInonsvstterruucmamleebnnrttabbtiilaoannrkkssstaiinndtathrhede,ffooarrmnmodofaftccellreeaaknnnommewetnthhahainngoohl-llsseoovlelvvleesnntat mwwpoelrreee.aallssAoogaaainnna,allyhyzzeeeddbaaafnfetkerrsaevsveheroryyukhhiggnhoh:t-
hclheaavavvemeel pcaaasnnliyypbrrattoaatsirrooggnreetttsotadaannnhadealrayedrtedss,1happnrrideensssaeetfnrntteutmreaaklntntoooDrrwanaanbbkhoosia~vv;erehe-lttechhvoeeemlllposowaawml-nleep.vvleeelsl .
calbraton standard. For Again, the blanks should
calibration standard. For
thenot
the
samples presented here the instrument blanks are compliant.
55.33 SSSuuurrrrorrgooagtgeaatstepeisses re not acomponars of taLCMSMS analtcal method. Surrogate spikes are not a component of the LC/MS/MS analytical method.
pacesors PAGE 3 OF 5
11778855..00000033
ATrORNEY-CLIENT PRIVILEGE.CONFIDENTIAL
54
5.4
MMMaaatttririixxspSSipepisikkweeessro propared fo every ik samp at concantatons of S00 nolL for ezch
cocMoonammstperpioexonrnseaepnbnitklteysohofifwgehiinrenetrtertrpeehsrsaettn.p. atrheedSSsaapfmmokpriplneleegvearmPPyoWWufFni#etS5l,d sccMaoonmnattpaalliienneseadpdtikceffoluocnorcoroeocvnchtheroaermtmiisocincaasalrl oofrrGei5esv0iesd0nuuanfsnlgsA/Laaactftohrmlleeeevvaneecllthss
8considerably
B.
higher
than
the
spiking
amount.
Matrix spike recoveries are given in Attachment
FcFiieeollddnsscppihkeeessntwwoeefrrreeaapaaptilrssoiooxioppmrarnetepepslaayrree1dd00ffo0oarr naadlll ww1a0at0toe0rr0 ssgaalmmp.lpeloesrs..eacFFhiiedlfddkssppsiiakkmeepsslewweernree appdrreiepptaa,rreeddelaadtt
cDoinnckenstpriaetiosnwseroef aspupbrmoixtiemd.atelleyk1}0s00pkancdco1v0e0r0e0snagr/eL fgoirveenac1hAtfiealdchsammepnlet. In addition, field
blar~k spikes were submitted. Field spike recoveries are given in Attachment B.
55.55 ADDlulupfpollliidccsaaattmeepssles were analyzed in dupicate. In addon, ik dpicates were lso colected Fe210 s venasng wi tsh amp fests 1 AtiachmenAt All field samples were analyzed in duplicate. In addition, fielci duplicates were also collected.
I~esults are given along with the sample results in Attachment ~,.
55.66 LNLaiablboorwraaattetoorrrwyyasCCosonpnitktrreoodllwiSShaamamllppclloeemsspound of inferest at 25 and 250 ng. Al compounds
seSMhxhiolcloiwqeeepwddtaitrroeeenrfccoowPvvaeHersrAiieeRssspnikbbee1edtt0ww2weo5ieethnnnga77l.00l csaaopnnmkddpeoe11u33nx00d%%iofiiannin0ceete1aarccie6hhs1te3llaaa0dtbb1oo2rr5aaitaoornryyd
conio) samp, Wh the 250 ng/L. All compounds
control sample, which the
exception of PHAA in the 25 ng/L spike extracted on 6/13/01.
57
5.7
STSaammhpaplreleeenRroRoeetllehaaettreesddamCCplooemmremlmaetenendttcssomments associated vith his sample st.
There are no other sample related comments associated with this sample set.
66 DDaattaa SSuummmmaarryy PPlleeaassee sseeee AAttatchamecntAhAffoomrr aeGdeenttaaditleedd slistiingonoffttghhee aannalyaticlal rreessuultss.
77 DDaattaa//SSaammppllee RReetteennttiioonn ScSalamompcilpoelensisacardreeatddaiissippsooassreocddhoiofvfeoodnneoemnmornoatnthtiheavfaatfbeterlrotthhmeedrrieeappooarrtntdsisishisassruudeeddcouplnyleesrsesspOoorlthtesevraiwrsiessessptseopcreeicdfifiieiendd..daAAllall efoleldcetrrosnmicaindtaataineisdbayrcGheivnetde.on retrievable media and hard copy reports are stored in data
folders maintained by Centre.
88 AAttttaacchhmmeennttss
81 AtachAmRoesnutts
8.1
Attachment A: Results
828.2
Aachen:B:Mati SpikeRecoveries (ikian LaboratorySpikes) Attachment B: Matrix Spike Recoveries (Field and Laboratory Spikes)
83 AAttatchmaentcCG::hCCrhaamiinnooeffCCunussttootddyy
8.3
84 AtachmeDnt: LCMSMS Raw Anaical Daa
8.4
Attachment D: LC/MS/MS Raw Analytical Data
11778855..00000044
pacesors PAGE 4 0F5
ATTORNEY-CLIENT PRIVILEGE-CONFIDENT!A
99 SSiiggnnaattuurreess
i oln ohn M.
Manager
PE Kevin J Lloyd, Vice President
arertstancus Ging Due Other Lab Members Contributing to Data
Karen Smith
oh
Date
pTmae2 Date
PAGE 5 OF 5
11778855..00005
PLATN20)
CAN
CCeennttrree AAnnaallygttiiccaall
5678 resareh Drive,SteColLLlegaae bPbAo0o0r01raat81to42o9r78ri0i3e2e_ssFA,X,FHZII3nTn-cc12.5.7
3048 Research Drive, State College PA 16801 814-231-8032 FAX 814-231-1253
Analytical Results Cottage Grove Potable Water Evaluation
Wo-- 3M Sampte Identification
T= PFOS (ng,q-)
Wo PFOA (ng/L)
PW#2 PW#2 (laborator~ duplicate) PW#2 (field duplicate) PW#3 PW#3 (taDoratory duplicate) PS#3 (field duplicate) PW#4 PW#4 (laDoratory duplicate) PW#4 (field duplicate) PW#5 PW#5 (laboratory duplicate) PW#5 (field duplicate) Field Blank Control #1 Field Blank Control #2 Low Level Field Spike Control Mid Level Field Spike Centrol
NQ NQ 27.7 N D ND ND 51.1 52.9 54.4 10100 9000 12700 ND NQ 832 8340
491 473 577 600 561 554 1170 1110 1180 42500 45700 56400 I~D F~D 621 7160
oo PFHS (ng/L)
NQ NQ NQ NQ 26.9 NQ 49.7 49.0 45.0 2510 2990 3410 ND HD 887 7750
ots PHAA (ng/L)
14~. 131 134. 165 181 170 261 276 209 9160 9470 10800 I~D I~D 812 6670
Hoss PFBS (ng/L)
NQ NQ NQ NQ NQ NQ 33.2 32.4 29.6 7470 101 O0 104(~0 ND ND 777 6700
Limit ef Detection (LOD) for the procedure is appoximately 2.5 ng/L for PFOS, PHAA and PFHS and 7.5 ng/L for PFOA and PFBS Limit cf Quantitation (LOQ) for the procedure is 25 ngJL for all compounds ND - Compound not detected NQ - Compound defected at a level between the LOD and LOQ. Result is not quar~tifiable. ND < LOD < NQ < LOQ
@
||
AATI"TI'OORRNNEEYY--CCLLIIEENNTT PPRRIIVVIILLEEGGEE--CCOONNFRIDDEENNTTIIAALL
eeeeeseemmenmemmemee Please refer to the reverse side for our standard terms and conditions.
11778855..00000066
-- 3MA00853354
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS LLaabboorraattoorryy MMaattrriixx SSppiikkee RReeccoovveerryy
Sampl0e: Spiked Amount (nolL): Sample ID:
I
PW#2
I
Spiked Amount (ng/L): [
500
I
PPprFrOoosSx [[PPPprFFraHOssSA ePrHaAs A
PFBS
ConCconrraion| osu Sample
Concentration
Matrix Spike Result
Rosur Matrix Spike Result
citora
Criteria
g(hntg) /L)
E 0 w= E E-- x -- PASS 24.1 2) ara as PASS 491 tee pe a PASS 18.2 Tad a1 siz PASS 144 278 Soa PH PASS 7.78
((nngg/L))
486 979 460 615 504
{(%%RReceocvoeverryy))
92.4 97.6 88.4 94.2 99.2
((PaPssa//FsFaiaslil))
PASS PASS PASS PASS PASS
LLoowweerrRReeccoovveerryy LimeLimit: [I 75]
70
I
UUppppeerrRReeccoovveerryyLLimimitit: I
130
I
Note: Sample routs los than 25 ng. ar reported a NO inth resus seston as thy are Note: Sample results less than 25 ng/L are reported as NQ in the results section as they are below ha lof quarto. Resuls ar Gv i i abo for rocovry calculations ony below the limit of quantitation. Results are given in this table for recovery calculations only.
ATTORNEY-CLIENT PRIVILEGE-CONFIDENTIAL
11778855..00000077
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS LLaabboorraattoorryy MMaattrriixx SSppiikkee RReeccoovveerryy
Sample 1: Spiked Amount (ngiL): Sample ID:
I
PW#3
I
Spiked Amount (ng/L): I
500
I
l[pFPrFFoOOaSS PFOA rHvass PFHS [PpHreAsA PFBS
SE Sample Concentration | Result Concentration
A(nngg/iL))
-- v 1 Ei Tr 0 a0 1000 600 107 a1 19.7 165 os 165 140 500 14.0
Matrix Spike Result
((nngg/L))
510 1000 491 609 504
ET Matrix Spike Rosut Result
((%% RReeccoovveerryy))
TG 102.0 80080.0 04394.3 ees88.8 S8098.0
Grtoria Criteria
((PaPssa//FsFaiaslil))
PPPAAASSSSSS PPPPaAAASSsSSSsS PPaASsSs
PASS
Upper Recovery Limit LLoowweerr RReeccoovveerryy LLiimmiitt: I 70 I
Upper Recovery Limit: I
130
I
below the mit of quantitation. Resultsare given i tis table or recoverycalculations only. NNootete:: SSaammppllee rreessuullttss lleessss tthhaann 2255 nngg//LL aarree rreeppoorrtteedd aass NNQQ iinn thhee rreessuullttss sseeccttiioonn aass tthheeyy aarree
below the limit of quantitation. Results are given in this table for recovery calculations only.
ATTORNEY-CLIENT PRIVILEGE-CONRgENTIAL
11778855..00000088
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS LLaabboorraattoorryy MMaattrriixx SSppiikkee RReeccoovveerryy
SSaammppl~eo ~0D::
I PW#4
SSppiikkeedd AAmmoouunntt (gL): (ng/L): I 500
[[FpPrFOOoSnS llppPPrrFFraHOinSsA pPrHoAsA
PFBS
ConTcSeaanmmtrppaleetion|| WMaatRnriexsGSoopnivkee |
Concentration
Result
((nngg/L))
EE BH I =-- 51.1 To 1750 1170 wr 26 49.7 261 a4 261 2 = 33.2
((rniggl/Lt))
622 1790 626 884 633
Wan Soe Matrix Spike Result Result
((%% RReeccoovveerryy))
7 114,2 1240124,0 1153115.3 1246 124.6 1200 120.0
Crtera Criteria
((PaPssa//FsFaiaslil))
TPPAAASSSSSS PPPPAaAASsSSSSSs PPaAsSSs
PASS
LLoowweerr RReeccoovveerryy mt: Limit: [1 75]
70
I
Upper Recovery Lim: Upper Recovery Limit: I
130
I
NbNoeotlteeo::wSShaaemmpIplnleeieroesfsuqulultsasnllteeasstssottnhh.aannR22e55sunnlggs/LLaaarreegrreeeppnoorrttneeddyaasss aNNGbQ.eiinfnoitheererrceeossvueulrtssy ssceeaclctctiiuooinnataaissonttshheoeyyn.aarree
below the limit of quantitation. Results are given in this table for recovery calculations only.
ATTORNEY-CLIENT PRIVILEGE-CONFIDENTIAL
11778855..00000099
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS LLaabboorraattoorryy MMaattrriixx SSppiikkee RReeccoovveerryy
`SSaammppllee IIDD::
I
PW#5
I
SSppiikkeedd AAmmoouunntt ((nnggl/LL)):: I 500 I
[FOS ppPPrrFFioOOsnSA PPpeFHisHaAsSAs
PFBS
ConcSSeaanmmtprplaleetion|| WMaautRriwexSsSptphikee | WMaaRiterinsxuSSltppikee
Grieria
ol) Concentration
(og) Result
4 RReecsouvletry) | (PaCsrsiterFiaail
(ng/L)
(ng/L)
(% Recovery)
(Pass / Fail)
r T5700 To r 0 PASS
4412220555110000000
4413660165580000000
88182290004.0.000
PFFFAAAASIILLLS
2987151451670000
S539274238830000
2111954442.00.00
FFFFAAAAIIIILLLL
7470
9780
462.0
FAIL
Upper Recovery Limit Lover Recovery Limit:
Lower Recovery Limit: [
70
I
Upper Recovery Limit: [
130
I
NbNoeotleteo::w SStaahemmpmplleie rroeefssuGuultassntlleieasstssiotthnha.annR22e55sunnlgtgs/.Lraaerreegrireevppeoonrrttieneddhaasss (NNaQQbeiinfottrhhereerfceoesvuselrtssy ssceaeclctctiiuoolnnataaissonttshheoenyyyaa.rree
below the limit of quantitation. Results are given in this table for recovery calculations only.
`Sample concentration exceeds the spiking levebyl greater than 10X
Sample concentration exceeds the spiking level by greater than 10X
ATTORNEY-CLIENT PRIVILEGE-CONROENTIAL
11778855..00001100
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS FFiieelldd MMaattrriixx SSppiikkee RReeccoovveerryy
SSaammppllee I1DD:: I SSppiikkeedd AAmmoouunntt ((nngg/LL):: I
PW#2 1000
PrPFroOoaSs pPPprrFFuiHOssSAa pres PHAA
PFBS
ConScSeaanmtmrpaeletion|| MMaatRrmeixsuSSlptieke | WFSesust Matrix Spike
Crista
og) Concentration
(og) Result
CoRRoecsouvltery | (paCsrsiteFraiai)
(rig/L)
=
rrr 750 75T 5 PASS (ng/L)
(% Recovery)
(Pass / Fail)
24.1
a2st491
11573309770400
76.6
5os87.9
PPPPAAaaSssSSssS
71118744.4482
7894400114s
78.6
7c0o7r79.7
PPPFAAAASSLSLSSS
7.78
705
69.7
FAIL
LLoowweerrRReceocvoevreyryLiLmimitit: I 70 I
UpperRecoveryLimit Upper Recovery Limit: I
130
I
bNNoeotleteo::wSShaaemmpmplliee rorefessucuultassnilleteasstssiotthnha.annR22e55sunnlgLstLaraaerreegrireevppeoonrrttieneddtiaassstNNabQQleiinotrhheererrceeosvsueulrtssy ssCeelccctuiooanntaaossnstthhe0yy.aarree
below the limit of quantitation. Results are given in this table for recovery calculations only.
ATTORNEY-CLIENT PRIVILEGE-CONFIDENTIAL
11778855..00001111
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS FFiieelldd MMaattrriixx SSppiikkee RReeccoovveerryy
SSaammppllee 0:ID:
I
PW#2
I
SSppiikkeedd AAmmoouunntt ((nngg//LL): I 10000 I
PpPrrFooOsnS oPPPrrFFieHnsSAs rosPHAA
PFBS
ConcSSeaanmmtrepal]etion | VMaartRrixeSsSotpikee |
Concentration
Result
n(rigg/L))
EE eal24.1 aon491 18218.2 14s144 2787.78
((nngg/L))
-- TE10200 e6608860 e3208320 7507530 06710
WReskm Matrix Spike Result
((%% RReeccoovveerryy))
TE 101.8 wr83.7 a083.0 7973.9 io67.0
Gatora
Criteria
((PaPssa//FsFaiaslil))
RPPAASSSSSS PPPPaaAASSssSSss FAL PASS
FAIL
LLoowweerrRReeccoovveerryy LLiimmitit.: I[70]
70
]
Upper Rocorary Limit Upper Recovery Limit: I
130
I
Nota: Sampl resus es than 25 ngaLr reported a5 NQ in th resus scion as hey re Note: Sample results less than 25 ng/L are reported as NQ in the results section as they are below 0 i of quaitation. Results ae ive in 1s ale for recovery calculations ny. below the limit of quantitation. Results are given in this table for recovery calculations only.
,qTTORNEY-CLIEILrF PRIVILEGE-CONFIDENTIAL
11778855..00001122
AAttttaacchhmmeenntt BB:" LLCC//MMSS//MMSS FFiieelldd MMaattrriixx SSppiikkee RReeccoovveerryy
SSoammppilee 0ID:
[
PW#3
I
SSppiikkeedd AAmmoouunntt ((nnggi/LL)):: I 1000 ]
pPPrFRoQOnSS pPPprFFriHOinSsA
PHAA PFBS
aE CE ] [en| Sample
Concentration | Reso Resut crieria Concentration ing) (9) CoRocovory) | (pass Fai (ng/L)
r T Tom r TES PASS 0 a0 1450 50 PASS 6OO 107 ss7 a7 Pass 19.7 6s 1020 a5 PASS 165
Matrix Spike Result (ng/L)
1080 1450 957 1020
Matrix Spike Result
(% Recovery)
108.0 85.0 93.7 85.5
Criteria (Pass / Fail)
PASS PASS PASS PASS
14.0
838
82.4
PASS
LLoowweerr RReeccoovveerryy LLiimmiti:t: [I 75]
70
]
Upper Recovery Lit Upper Recovery Limit: I
130
I
NbNoeotlteeo::wSShaaemmlppleemrroeefssQuuultsasnllteeissassottnhh.aannR22e55snunlggs/LLaaareregirreevppeoonrrttneeddYaasssaNNiQQeiifno thheererrceoesvsueulrtssy ssceaelccctiuoolnnataaissonttshhoeenyyyaa.rree
below the limit of quantitation. Results are given in this table for recovery calculations only.
AATTTTOORRNNEEYY--CCLLIIEENNTT PPRRIIVVIILLEEGGEE--CCOONNFRIODEENNTTIIAALL
11778855..00001133
or
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS FFiieelldd MMaattrriixx SSppiikkee RReeccoovveerryy
Sample 0: Spiked Amount (ng1L): Sample ID:
I
PW#3
I
Spiked Amount (ng/L): I
10000
I
Pros I GonTcreongvip)aetion|| WaRoTergsEo)nne| W--CiaR--Ro7ecsoSvuoetrvy) |--(paGsTieAroSFnSaai) PFOS ron a0 8100 0 PASS PFOA pris 107 7is0 7a PASS PFHS rian 165 7090 wa FAL PHAA res 140 asso os FAL PFBS
Sample Concentration
(rig/L)
0 600 19.7 165 14.0
Matrix Spike Result (rig/L)
9180 8100 7150 7090 6560
Matrix Spike Result
(% Recovery)
91.8 75.0 71.3 69.3 65.5
Criteria (Pass / Fail)
PASS PASS PASS FAIL FAIL
Lower Recovery int Lower Recovery Limit: I
70
I
Upper Racovary Li Upper Recovery Limit: I
130
I
bNNoeotlteeo::wSStaaemmpnplileettroeefsscuuulltassntllteeasstssiotthnha.annR22e5s5unnlggls/LLa1aarreegrrieevppeoonrritteneddYaas3s aNNGbQ.eiinnfohtfheecoerevssueutrltssy ssCeeacclttciiouonnaiaaossntsthheoenyyyaa.rree
below the limit of quantitation. Results are given in this table for recovery calculations only.
ATI'ORNEY-CLIENT PRIVILEI E-CONFIBENTIAL
11778855..00001144
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS FFiieelldd MMaattrriixx SSppiikkee RReeccoovveerryy
`SaSmapmlpe l1ID0e::
Spiked Amount (ng/L:
Spiked Amount (ng/L):
PpPFrrOooSsn rPPPrFFniHOnsSAs pPrHeAsA
PFBS
Sor We Se | VA Se Sample Concentration | Resch Resut Concentration
Matrix Spike Result
Matrix Spike Result
Crier Criteria
((nngg/L))
--=1 r 57 weT Ze 51.1 170 2180 110 FAL 1170 ier 100 1050 Pass 49.7 21 1150 eo Pass 261 2 os a pass 33.2
n(ngg/L))
947 2480 1100 1150 884
((%% RReeccoovveerryy))
89.6 131.0 105.0 88.9 85.1
((PaPssa//FsFaaislil))
PASS FAIL PASS PASS PASS
Lower Recovery Umit: [70]
Lower Recovery Limit:
UpperRecoveryLi:
Upper Recovery Limit:
NbNeooleteo::wSShaaemmplplliee rroeefssquulultatssnteleasstssiottnhh.aannR22e55sugnlgLs/.LaaargreeivrreeeppnoorritteneddLaasss tNNaQOeiifnno tthheererrceeossvueulrtssy ssceeaclctctiiuoolnnataaissonttshhoeenyyyaa.rree
below the limit of quantitation. Results are given in this table for recovery calculations only.
ATTORNEY-CLIENT PRIVILEGE-CONRI]ENTIAL
11778855..00001155
AAttttaacchhmmeenntt BB:" LLCC//MMSS//MMSS FFiieelldd MMaattrriixx SSppiikkee RReeccoovveerryy
Sampl0e: Sample ID:
I
PW#4
I
Spiked Amount (191): Spiked Amount (ng/L): I
10000
I
Pros ConSco=ogp|)mion| en"7 PnoeStsR|| oeonRTeeS ocsnmoy | eGm7oirar PFOS rox To 152% 1203 Pass PFOA Pris 5 102% Toes PAs PFHS Pra oar 0 ws Pass PHAA res 2 S520 se Pass PFBS
Sample Concentration
(rig/L)
1
51.1 1170 49.7 261 33.2
Matrix Spike
Result (rig/L)
1
10700 13200 10900 590 8520
Matrix Spike Result
(% Recovery)
1
106.5 120.3 108.5 93.3 84.9
Criteria
1 (Pass / Fail)
PASS PASS PASS PASS PASS
LoLwoweerrRReeccoovveerryyLLiimmiitt: [ 70 I UUppppeerrRReceocvoeveryryLiLmimitit: I 130 I
Not: Sala est ss than 25 ra reprea5 NO nh resus econ ss hy aro Note: Sample results less than 25 ng/L are reported as NQ in the results section as they are Seow og of cation. hesurs ro Gn ne ao rover Socios ony. below the limit of quantitation. Results are given in this table for recovery calculations only.
ATTORNEY-CLIENT PRIVILEGE-CONRDENTIAL
11778855..00001166
AAttttaacchhmmeenntt BB:" LLCC//MMSS//MMSS FFiieelldd MMaattrriixx SSppiikkee RReeccoovveerryy
-- Sample ID:
I
PW#5
I
Spiked Amount (ng Spiked Amount (ng/L): I
1000
1
Pros -- ConETc(uooonrm)aionT|rr C fiRTomol sm)t 4 RRToewsao uovter FAT PFOS pron i250 7100 4600 FAL PFOA ors 2510 py prove FAL PFHS his ais 1210 2020 FAL PHAA ros 7 10900 3430 FAL PFBS
Sample Concentration
(ng/L)
10100 42500 2510 916o 7470
Matrix Spike Result (ng/L)
11900 47100 4390 12100 10900
Matrix Spike Result
(% Recovery)
180.0 460.0 188.0 294.0 343.0
Criteria (Pass/Fail)
FAIL FAIL FAIL FAIL FAIL
LoLwoweerrRRececoovveerryyLLimimitit: I 70 I
Usper Recovery Li Upper Recovery Limit: I
130
I
Noto: Samp fouls os than 25 ng. ar report as NO nth resus secon asthyare Note: Sample results less than 25 ng/L are reported as NQ in the results section as they are Selo a iit of Guantaton. Feouls a in i ns ale of covey CACUONS oly. below the limit of quantitation. Results are given in this table for recovery caiculations only.
Samplo conceriaan coos he sping lvygreeater than 10X Sample concentration exceeds the spiking level by greater than 10X
A'I'rORNEY.CLIENT PR!VILEGE-CONFll]EI TIAL
11778855..00001177
AAttttaacchhmmeenntt BB:: LLCC//MMSS//MMSS FFiieelldd MMaattrriixx SSppiikkee RReeccoovveerryy
SSaammppllee IIDD::
[
PW#5
SSppiikkeedd AAmmoouunntt ((nngt/)L:): I 1[100000000
[pFPrFFooOnSs PPPrrFFaiHOssSA pPeHaAsA
PFBS
GonSSceaanmtmpaelteion|| MWaatvFriewxsSSuoptnikee | WMaaRrtreinxsuSStopinkee
Ciera
ng Concentration
(og) Result
C4 RReecsouvletry) | (paCsrsite(rFiaai)
(ng/L)
(ng/L)
(% Recovery)
(Pass / Fail)
-- 1 T5700 77% 750 Tr PASS
4412202551510000000
62612125171100000000
111119926665..0900
PPFFAAAASSILLSS
B729514E167000
22121015313100000000
111122285112..4394
PPPFAAAASSISLSSS
7470
20700
132.3
FAIL
Lower Recovery Lit:
Lower Recovery Limit: [
70
I
Upper Recovary Lint Upper Recovery Limit: I
130
]
NbNoeotlateo::w SStaahemmlppilmleei rroeefssuuqlulttassntllieetssasstittohnha.annR22e55sunnlgtgis/LLaaaorreeGrireevppeoonrrttieneddhaasss fNNabQQleiinfottrhhereerrceeosvsueulrtssy ssceeacclttciiouonaniaaosnttshhoeenyylyaa.rree
below the limit of quantitation. Results are given in this table for recovery calculations only.
ATrORNEY-CUENT PRIVILEGE-CONRDENTIAL
7178855..00001188
Ek EEREEEEEERERERR]
tI EERE! o 0 o o 0 o
0
o 0 o
0 0
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EERE EERE E
E
o
n
=
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E
8 ThEFEEEEEEEEEEEEEEERE
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EERE =
D
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EEE EEE ?
4
ELI p Eemplplalslalc ttf
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oe slo fele le lef flee fel lff eo|e2
11778855..00001199
me
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11778855..00002200
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HT
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1785.0021
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| EBI E Hl HeE h e h 2 1k 3 i Ie El HH sSghe ihel h 1Jsi i: h0 i 330] I{Hy l hie le)aft| 3faHgE HoNH3 [Leib BgRE & letae:
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- 1785.0022
wan 6/4/2001 Pos Evontz Project: E01-0812
ATTORNEY-CLIENT PRIVILEGE-CONRDENTIAL
IEAVIROWNENTALLABORATORY 3M ENVIRONMENTAL LABORATORY CONTRACT LABORATORY WORK ORD BY SAMPLE CONTRACT LABORATORY WORK ORDER BY SAMPLE
Conan CENTRE Contract Lab(s): CENTRE
pete? Page 1 of 2
Requester: Gc, Mk A Project Dae Ds 1801 Requester: Gaetz, Mark A Depa 455105 Por Leat os Luntberg Department: 452100 fasion Pon Naber61.78.5631 Project Number: Do Reseed 6401 Eo Abe. Bnd com Date Received: 6/4/01 ProtDes am Bobet Evbion Project Description: CG Potable Water Evaluation
Project Due Date: 6/18/01 Project Lead: James K. Lundberg Phone Number: 651-778-5631 Email Address: jklundberg@mmm.com
Comments: Seif ooking fr: CHCHCS bone Acisd CHSC Sulphide Comments: Specifically looking for: C4/C6/C8 Carboxylic Acids and C4/C6/C8 Sulphonic Acids.
supoue: /To) Ship Date: ~/d~O,]
ISump Number Semple Date__ sie pecrpon Avis pee 3M Sample Number Brisa STH FE Soe E01-0812-25297 Anicos| ual Mhod Cempmens Analysis Code LOS ons Fonts Sem wn LCMS_SCAN O Em FS E01-0812-25298
Analysis Code
IRSEN fons Fev Som aor LCMS_SCAN ERT FR Te TRS E01-0812-25299
Analysis Code
[BES owes ovasem sor LCMS_SCAN ETI OTT FWA ed Fe E01-0812-25300
Analysis Code
BREN lov Lows sem san LCMS SCAN EFT S T E01-0812-25301 Rios in eos Compones Analysis Code ISSN ewsn Loui Sem won LCMS_SCAN BTR IT FS E01-0812-25302 Aen mtn vetea pa Analysis Code
LLCCM MSS__SSCCAANN
ETI OTF Tew Tee Sp E01-0812-25303 Aeiitos" in tod Compan Analysis Code
LLCCMMSS__SSCCAANN
BOT FRR E01-0812-25304 tie" pm wets Compass Analysis Code LOSS iovissam Louis sam wien LCMS_SCAN I -- E01-0812-25305 Neots ic Metad Comments Analysis Code LARSON Lowen frre wen LCMS_SCAN EST PS Dy E01-0812-25306 Aint ea wetaa amps Analysis Code LERSN lose Lossom acon LCMS_SCAN DC E01-0812-25307
Analysis Code
LOISoN oan Lois sem ann LCMS_SCAN EPR WR FS O E01-0812-25308 Amita ihcMend Compares Analysis Code ORSON Lowen Cos sen sant LCMS_SCAN ET E01-0812-25309
Sampled Date 6/1/01
Sample Description PW#2 Sample
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#2 Sample Dup
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#2 Low Level Field Spike
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#2 Mid Level Field Spike
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#3 Sample
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#3 Sample Dup
LCMS Scan Analytical Method
LCMS Scan
Components
LLCCM MSS SSccaann
6/1/01
PW#3 Low Level Field Spike
LEMS Scan Analytical Method
LCMS Scan
LCoCmMpSonSecnatns
LCMS Scan
6/1/01
PW#3 Mid Level Field Spike
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#4 Sample
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#4 Sample Dup
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#4 Low Level Field Spike
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/'01
PW#-4 Mid Level Field Spike
Analytical Method
Components
LCMS Scan
LCMS Scan
6/1/01
PW#5 Sample
Analysis Due Date 6/14/01 6/14/01 6/14/01 6/14/01 6/14/01
66/1144/0011 66//1144/0011
6/14/01 6/14/01 6/14/01 6/14/01 6/14/01
11778855..00002233
awn 6/4/2001
AATTTTORNEY3-MCELNIVEINROTNMEPNRTIAVLILLAEBGOREA-TCOROYNFIDENTIAL
CONTRA3CMT
CONTRACT
LABORATORY WORK ORDER BY SAMPLE. ENVIRONMENTAL LABORATORY
LABORATORY WORK ORDER BY SAMPLE
Project: E0L-0812
Project: E01-0812
Contract Labs): CENTRE.
Contract Lab(s): CENTP~
suppue: JT0,
Page 2012
Page 2 of 2
33M SSaammppllee NNuummbbeerr EOLORIzIs
_
Sampled OTSampled
DDaattee
__
ISSaammWpplleeSDDpeesscecrriippttiioonn
AAnnsalyysbsiss DDobuee DDaaettee
E(Accon0ona1nth-t0.)a)8s12Co-2t5e309
6/1/01
PW#5 Sample
Ansiyten) Method
--
LMSSCAN Analysis Code
LCMS SCAN
LCMS Scan Analytical Method
LCMS Scan
CLoomupsonseenatns
o1ant
ABEn01aL-i08sE1C2o-2Sd5e310 6A/n1sO/T0y1tica Method PWP#W5 ESaSmepCLlioeCmMDDpouSnnpeSnctasn
6/14/01
LOMSSCAN Analysis Code
LCMS SCAN
Lomssean Analytical Method
LCoOmMponSeenatns
aot
EAEn0ai1y-0so8s1E2C-o2Se5:3T11
AL6/OTC1m/M0a1SiSacanMethea
LCMS Scan
WETCTomeponeendts Re PW#5 Low Level Field Spike
6/14/01
LACnMalSysiSs CCoAdNe LBCLMwS ESCIAsNE
Analytical Method
LOSTMS Scan LCMS Scan
PWR MALCLCLoCmMMpSSonSSFeccneaatnnslis
S101 6/14/01
LAEAnOn0aa1lMyl-ySs0si8iSss1CC2Ca-oA2dd5eNe312 AAL6/nCn1a/M0aly1StticSaaelanMMeetthhoodd PW#5 Mid CLLCoeoMmvmpeSpolonFneSieneenltadtsnsSpike
1401
EAELn0CaI1lM-yC0sSi8Os1SR2CC-oZ2At5eSN31n3 OAL6n/TC1a/Mi0i1TScaSlcanMethod FedField BhEBlankLCCoCComMnptooSrnoelSmncStaamsnmpsle #00T1
6/14/01
Analysis Code
B LOMSSCAN LoL MS Sean RBI LCoMnS SeSane S rant S LCMS SCAN
Analytical Method LCMS Scan
Components LCMS Scan
6/14/01
E01-0812-25314
ALnOaNiSsSCCoAdeN Analysis Code
A6AL/nnC1as/M0liy1SiticcSaaclanMMeetthhoodd
Field
Blank Control Sample
CLoOmMpoSneSnetesn Components
#02
1401
EAELCn0O1MaL-i0OS8sS1SCZ2C-oE2AeS5N3I1s5 AL6n/C1aO/0iM10v1SieaSlcanMethod LTooww LLeevveell FCFLoeiCemllMpddoSSSnppeSiinkcktaeesnCCoomntaroll SSaammplpele
6/14/01
LCMS SCAN Analysis Code
LCMS SCAN
LOMS Sean Analytical Method
LCoMmSponSeenetns
1401
AEn0a1-iE0O8sTO1CS2aI-Z2dI5eS3S1T6G
TOLCMS
6/1/01
Scan
NMdid
LLeevveell
Fld Spe Compal LCMS Scan
Field Spike Control
SSaammppllee
AnabyticalMethod
Components
6/14/01
LOMSSCAN Analysis Code
LCMS SCAN
LCSSean Analytical Method
LCMS Scan
CCoMmSpoSnceantns
1401
LCMS Scan
6/14/01
11778855..00002244
AAT'I'TTOORRNNEEYY--CCLLIIEENNTT PPRRIIVVIILLEEGGEE--CCOONNFFIIDDEENNTTIIAALL
~~ CATCE ~ntA r~AAnnaaligttiiccaallLaLbaobrooarrtaaootroniirieeesss.,, IIInncc..
eo
Prone: 514) 221.802 3048 Research Drive
Phone: (814) 231-8032
State
Fax (814) 231-1283 1 (319) 231.1580 College, PA 16801
www.centrelab.com
Fax: (814) 231-1253 or (814) 231-1580
SSaammppllee ""CCoonnddititiioonn UUppoonn RReecceeiipptt"" FFoorrmm
.
Sponsor Prowcol E0=08112
a
Sponsor Protocol
CCeennwtrree SStudyy # _O23-014
DDatae&&tTTiiemmee RReecceeiivveedd _6/6/01
/10/30o3_0
CondioftSaimpolens __ C= We? La = A
Temporary Storage Location __C=.
Temporary Storage Location
.
Itn[oriailst&&aDDaltastee _Cno_(f0fol
wapbitis _Fed Ex P76 4350 2P6 _
QWORDproces login SumpleCondilononRece pos
Q:\WOKD"~procesa-iogin\SampkCondidononR~c~ipt.doc
11778855..00002255
Sanary 17,2000
January 17, 2001/l
-
ATTORNEY-CLIENT PRIVILEGE-CONFIDENTIAL
JH ENMANm TIER ~PRIORliTY OVERNIGHT ~'ED
1785.0026