Document Bmm7QrOZKMqJ2KEQXE8njk8m

>1 'l I rf i U f 12506 V-: I/ RULES AND REGULATIONS '.'Ll'* v. cl4- Bee. *10.70 SdHNHlS-byMMuMiWl Applicability; OucrlpUon of too rayon subcslegory. Bee. 414.104 (Reserved) 410.106 Btandarde of performance for new aources. tion and associated processing to manu facture polyvinyl chloride. 1416.11 Specialised dcJutWtMt*. 414.71 410.72 Specialised definitions. Effluent limitation* guideline* reprcrentkng M degree of efflu ent reduction attainable by the application of tbe heat practicable control technology currently 410.72 410.74 410.70 410.70 available. Effluent limitation* guidelines representing the degree of afflu ent reduction attainable by tlie application of tbe best available technology economically achiev able. | Reserved) Standard* of performance for new sources. Pretreatment standard* for new aources. . H--AcrytonitrUe-Outadlene Styrene lAtt) Myrene-AcryhmltrHe (SAN> fissln CopolySubcalegery 410.00 410.01 410.02 Applicability; description of the acrylonitrile - butadiene - styrene |AS8) end atyrene-acrylonltrlle (SAM) reeln copolymer eubcate- gory. gpeulatlsed definitions. Effluent limitation* guldeltnea 410.106 Pretreatment standards for mw aources. Oubpart K Nylcn 6 tubcaUgsry 418.110 410.111 410.112 410.113 410.114 410.115 416.116 Applicability; description of the ny lon 0 subcategory. Specialized definitions. Effluent limitations guidelines rep resenting the degree of effluent reduction attainable by the ap plication of the beet practicable control technology currently available. Effluent limitations guidelines rep resenting the degree of effluent reduction attainable by tbe *p- ' plication of the best available technology economically schteve- able. (Reserved] Standards of performance for new sources. Pretreatment standards for new sources. . Subpart L--ClluleM Acetate Owbcalageiy 410.120 Applicability; description of the cellulose acetate subcategory. 410.121 Specialised definitions. For the purpose of this subpart: (a) Except aa provided betow. the gen eral deAnlttona, abbreviations and meth ods of analysis set forth hi 40 CFR 401 shall apply to thia outpost. | 416.12 Effluent lisuitatiom Ruhlclinrs repreneutlmg III* degree of rUlucui reduciran attainable by llie applica tion of Ibe best foruclicoble control technology currently available. In establishing the limitations set forth In this section, SPA took into account all information it woo able to collect, de velop and sollett with respect to factors (such as age and else of plant, raw ma terials, manufocturing processes, prod ucts produced, treatment technology available, energy reiftilrements and costs) which can affect the Industry subcntcgorization and effluent levels established It is, however, possible that data which would affect these limitations have not been available and, as a result, these lim itations should bo adjusted for cortaln 410.23 representing the degree of efflu ent reduction attainable by the application of the best practi cable control technology currently available. Effluent limitations guidelines representing the degree of effluent 410.122 410.123 Effluent limitation* guidelines rep resenting the degree of effluent reduction sttslnsble by the tpplication of the best practicable control technology currently available. Effluent limitations guidelines rep plants in this Industry. An Individual dis charger or oMhear interested person may submit evidence to the Regional Admin istrator (or to the State, if the State ha. the authority to issue NPDES permitM that factors relating to the equipment 410.24 410.23 416.80 reduction attainable by the ap plication of the best available technology economically avail able. (Reserved) Standards of performance for new source*. Pretreatment standards for new 410.124 410.129 resenting the degree of effluent reduction attainable by the ap plication of the best available technology economically achieve able. | Reserved) Standards of performance for new sources. or facilities involved, the process applied or other snch factors related to such dis charger are fundamentally different frem the factors considered in the tablishmeitt of the guidelines. On tin basis of such evidence or other available aources. Subpart I--Polyester Subcategary 410.90 410.01 416.82 410.03 410.04 410.86 416.96 Applicability; description of the polyester subcategory. Specialized definitions. Effluent limitations guidelines rep resenting the degree of effluent reduction attainable by tbe ap plication of the best practicable control technology currently available. Effluent limitations guidelines rep resenting the degree of effluent reduction attainable by tbe ap plication of the best available technology economically achieve- able. | Reserved] Standard* of performance for MW source*. Pretreatment standard* for sew sources. tubpart J--Nylon 00 Subcatcgery 416.100 Applicability; description of the nylon 00 aubeategory. 610.101 Specialized definitions. 416.120 Pretreatment standards for new sources. Oubpart M--Acrylics Subcatsgery 410.130 Applicability; description of the acrylics subcategory. 410.131 Specialized definitions. 410.132 Effluent limitations guidelines rep resenting the degree of effluent reduction attainable by the ap plication of the best practicable control technology currently available. 410.133 Effluent limitations guidelines rep resenting the degree of effluent reduction attainable by the ap plication of the best available technology economically achieveable. 010.194 (Reserved) 410.129 Btandarde of performance for new sources. 410.136 Pretreatment standards for mw sources. AtmioarrY: Secs. 301, 904 (b) and (c), 306 (b) and (c) and 307(c) of the Federal Water Pollution Control Act, as amended (33 U.S.C. 1261,1911,1314 (b) and (c). 1816 (b) and (c) information, the Regional Adminislvn tor (or the State) will make a writtei finding that such factors are or are fundamentally different for that faciiii compared to those specified in the Di velopment Document. If such fundamoi tally different factors are found to exi the Regional Attaintstrator or the Stal shall establish for the discharger effluei. limitations in tbe NPDES permit eitlu more or less stringent than the limiia tions establisliod herein, to the exU i dictated by such fundamentally differed factors. Such limitations must be ai proved by the Administrator of the i, vironmenta] Protection Agency. The Ad ministralor may approve or dlsappio, such limitations, specify other limit, tions, or initiate proceedings to revii these regulations. (a) The following limitations estaL 416.103 Effluent limitation* guideline* rep resenting the degree of effluent reduction attainable by the ap plication of the best practicable .and 1917(c)); 36 Btat. 316 ct aeq: Pub. L. 02- 000 Subpait A--Polyvinyl Chloride Subcatogory Ushed the quantity or quality of pollu tants or pollutant properties, controlli by this paragraph which may be di 410.102 control technology currently available. Effluent limitations guidelines rep resenting the degree of effluent reduction attainable by the ap plication or the beat available technology economically achleve- abie. 1416.10 Applicability! dowripllon of . the polyvinyl chloride subralcgury. The provisions of this subport are ap plicable to discharges resulting from the polymerization reaction of vinyl chloride by bulk polymerization, or suspension polymerization, or emulsion polymeriza charged from the manufacture of pol> vinyl chloride by tbe suspension polyn erisation process by a point soun subject to tbe provisions of this subpoi after application of the best practical control technology currently available; FfDHAl MOISUt. VOt. 39, NO. 4 DTH 00008877 # tUlES AND REGULATIONS 12507 SIM BudtaUoia * Rprctentiai tlte dtgno ail educate Avantgo of dally i Maximum fa value, for*) 1 auy Ittaf eMisecuUve day*1, MU Ml onoxd--' reduction oMninoilo Inr Um spplicullun of Uto Inti avuUaUa todunioff cwMulcoHf wUwMii ------------------------------------ (a) Ths foHowing Bmltations estab- iMito unit* (kilograms pc i.ooB kg > lish tha quantity or qiMUty of pollutants i nnotuct) or pollutant properties, oooUroUad by this BOP#_.................. IMM*., .......... i_ -- --Zi----------- T.O OT-- A6 TUB___ _____-- HI....................w t.l .IK) Within Ute range A0 Le 0.0 Kogltah uidta pound. par 1,000 lb af product) ION.................... 0.70 om ........ . 7.u .* TMM_,:....... . I.M .W PM--.-------------- Wlthlu lira range A0 to O.A 'paragraph, which may ho discharged from tha manufacture of polyvinyl chlo ride by tha suspension polymerisation ptroceso by a point sauna subject to the provisions of this sufapart after appiicAtlon of the beat available technology eco nomically achievable: Hndtotlonx Effluent cherectocteUe Effluent Uiaitelleai Annual dally Maximum fax velum lor M auy I day ewraecyro atop Metric unite (kilograms per 1,000 kg ofproduot) DODI................... a 0 am COD............................. .12 .at T*s.................................. OS . 013 pU....... ........... Wltldn the range A0 to 0.0. XngUxh unit* (pounds par 1.0M to __________ o( product) bon#..................... A 00 con....................... . W.............................. .ns pU___ --WlUdu the raugo A0 to t.A AM .a .013 (b) The following limitations estab lished tlie quantity or quality of pollut ants or pollutant properties, controlled by this paragraph, which may be dis charged from the manufacture of poly vinyl chloride by the emulsion polymeri sation process by a point source subject to Ute provisions of this subpart after spctlcatien of the best practicable con trol technology currently available: IlMt toerscteriaHe Sflsail limllxltonx Arorage of dally Maximum far values fur 30 any I duy cammculive days strati not exceed-- McUte Uitlts (kUctgruins IT t,0U0 kg oC product) KOluont characteristic Average of daily Maximum lor values for 30 any 1 day aonsecuUro days shall not exceed-- Metric unite (kHugromJ per I,0u0 kg of product) Doll#. COD.. TSS.... PU...... ........ Oil AM _____ i.MIS L. B10 Within th* Mat* AS to AA DngUali uatto (poondx pm ljtM lb *1 product) BOD#............... All AM COD...................... 1.02 1.M TS8........................ .23 .10 pU......................... Within Ui* nog* AA to 0.A (.b.>. The f,ol,,low,ing .lim..i.ta.t.ions es.tot.blish the quantity or quality of pollutants 1416.14 [Reserved] 8 416.15 Standard* of performance for new (onree*. (a) Tlie following standards of per formance establish tlie quantity or qual ity of pollutants or pollutant properties, controlled by this paragraph, which may be discharged from the manufacture of polyvinyl chloride by the suspension po lymerization process by a new source subject to tiie provisions of this subpart; KOluont limitation! Effluent chxroclerislle Average of dolly Maximum tor values for to any 1 dny .ctroanislencouttived*s*y!x- --------------------- ;------------------------------ fsooKar................................ aASm iTii 1.3 1*1...................... . .30 .............. Within llio range 0.0 to II.O. or pollutant properties, controlled by Metricunit. (kiiopmms per i.ooo tills paragraph, which* may be dis- k*of product) charged from themanufacture of poly- doia#...........................olr vinyl chloride bytheemulsion polymeri- cni>................... t.7o aI . English units (pounds perl ,000 lb uf _________ t product) Shin................... C||h^f_t.._..._.._..._.._..._..._... 0. 1f0^ A13 1^.3 |S.L.....................Within the range 10 to 0.0. (a) The following limitations establish t qusntHy or quality of pollutants or properties, contraded by this which may ba discharged zatlon process by a point source subject to the provisions of this subpart after application of the best available technology economically achievable: -- ....... .................... - ' -- ---- " . ______ Effluent limitation*______ Effluent ehiiruclorixU* Avoroex of daily Mxxlmum for vtluax lor 10 ny 1 day eorueeutive dare hall nut exceed-- Pwfthiu'tiro range t.o to t.A* -------------------------------- English unit. (pound. per 1,000 ib ----------------!__! : BOD#................ 0.37 Alt COD.................. 1.70 .to TIMI jg iw pll................. ......Within the range (.0 to 0.0. (b> The following standards of per formance establish the quantity or qual Um manufseturs of polyvinyl the bulk polymerization i by a point source subject to the jrafciens of this subpart after applicat of Out best practicable control teclify currently avuttabt*: Metric units (kilograms per 1,000 kg of product) BOM.................... 0.20 Ait TCO9D........................................ ..1to1 ..60102 pU......................... WUhln the rang# AA to OA. ity of pollutants or pollutant properties, controlled by this paragraph, which may be discharged from the manufacture of polyvinyl chloride by the emulsion polymerisation process by a new source subject to the provisions of tills subpart: ElBuaut HwluHont Aoarage of dally Maximum lor value! lor 30 any I day consecutive days slmli not execetl-- BOD#................... . AM AM COI>...................... .02 .01 THH........................ .It .00* pll......................... WllMn lire range A0 to 0.A Effluent tbnftelton* --e of dally Maximum tot values fur to any I day consecutive ilayi hall net axcecd- Metric India {kilograms iter IAN Of > product) jItjit*ti,t-.*~.----------------------- s1..i*s o.t..1oo0o A--.......... --- WMhln the ratigo A0 to 0.0. KnglMi imHx (postndx per low Urol product) AII AM A3 __ . .00 .IS ... WMtdo the mage OAtotA Mrtrte units (kltogrorax per 1,000 kg 1 (c) The following limitations estab- ' ------------ af product)------- --_ llsh the quantity or quality of pollutants *&!*............ * or pollutant properties, controlled by this aa.:""I"""!" \n .on paragraph, which may be discharged u.................... wuuntiie range o.oii.a from the manitiMrture ofpolyvinyl chloride by the bulk polymerisation process by a point source subject to the provl- sions of this subpart after application of the best available technology ecoooml- cally achievable: BVrfP, EngHxh umu (p.mu .m i,oo > of product) BOW ^-------------- rr;-------- cou"""";'"" 1.20 .* ................... ____________ "..................... wiihiutira range AOtotA. 5 '> DTH 000088777 NBCtAL MOUTH. VOt. 39, NO. A7--NHOAY, ANN S, W4 11678 RULES AND REGULATIONS do not affect the conclusions of the eco conditions may not reasonably ensure U ' htetun WHk Process Water nomic Impact study. this, adequate precautions (e.g.. Impervi X}--Cost-Benetit Analysis ous liners) should be taken to ensure tong 414.90 Applicability; description of tbo term protection to the environment from processes with process water con TIm detrimental effects of the constit hazardous materials. Where appropriate tact as steam diluent or Absorbent uents of waste waters now discharged by point sources within the Major Organic Product segment of the Organic Chemi cal Manufacturing point source category are discussed In Section VI of the report entitled "Development Document for Effluent Limitations Guidelines for the Major Organic Products Segment of the Organic Chemicals Manufacturing Point Source Category" (December 1974). It is not feasible to quantify in economic terms, particularly on a national basis, the costs resulting from the discharge of the location of solid haaardous materials disposal sites should be permanently re corded hi the appropriate office of the legal Jurisdiction in which the site is lo- F--Publication or Intokmation on Psocesses, Peocebubes, ob Operating Methods Which Result in the Elimi nation oa Reduction or the Discharge or Pollutants In conformance with the requirements of section 304(c), a manual entitled, subestegory. 414.31 Specialised definition*. 414.23 Effluent limitations guidelines repre senting tbo degree or effluent re duction Attainable by the applica tion of the best practicable control technology currently available. 414.33 Effluent limitations guidelines repre senting the degree of effluent re duction Attainable by tbo applica tion of tbo beat available technol ogy economically achievable. 414.34 |Rescrved| 414.33 Standards of performance for new these poSutante to our Nation's water "Development Document for Effluent 41494 Pretreatment standards for new ways. Nevertheless, as indicated in Sec Limitations Guidelines and New Source sources. tion VI. the pollutants discharged have Performance Standards for the Major substantial and damaging impacts on the Organic Chemicals Products Segment of C-..Aqua Systems quality of water and therefore on its ca the Organic Chemicals Manufacturing 414.30 Applicability; description of tbo pacity to support healthy populations of Point source Category," lias been pub aqueous liquid phase reaction sys wildlife, flab and other aquatic wildlife lished and is available for purchase from tems subcategory. and on Its suitability for industrial, rec reational and drinking water supply uses. The total cost of implementing the effluent llmitaUom guidelines Includes the direct capital and operating costs of the pollution control technology em ployed to achieve compliance and the in direct economie and environmental costs the Government Printing Office, Wash ington, D.C. 30401 for a nominal fee. O--Pinal Rvlsmahino In consideration of the foregoing, 40 CFR Chapter I. Subchapter N is hereby amended by adding a new Part 414, Or ganic chemicals Manufacturing Point 414.31 Specialized definitions. 414.33 Effluent limitations guidelines repre senting the degree of affluent re duction attainable by the applica tion f tbs bast practicable control technology currently available. 414.33 Effluent limitations guideline* repre senting tbs degree of affluent re duction attainable by tbs applica IdcnUfled in section VIII and in the Source Category, to read as set forth tion of the best available technol supplementary report entitled "Econom ic Analysis of Proposed Effluent Guide lines Organic Chemicals Industry," (Au gust 1973). Implementing the effluent limitations guidelines will substantially reduce the environmental harm which would otherwise be attributable to the continued discharge of polluted waste waters from existing and newly con structed plants In the organic chemicals manufacturing Industry. The Agency be lieves that the benefits of thus reducing the pollutants discharged Justify the as sociated eeuts which, though substantial in bbadlutg tanas, represent a relatively man peroantoge of the total capital in vestment in the Industry. below. An order of the Federal District Court for the District of Columbia en tered in NRDC v. Train (Civ. No. 160973) on November 20,1973, required that the Administrator sign final effluent limi tations guidelines for this industry cate gory by March 33, 1974. That order was subsequently modified on March 14,1974, and the date for signing extended until April 15, 1974. Thereafter, on March 15, 1974, the District Court ordered that the effective date for effluent limitations guidelines established by its November M order remain applicable and not be af fected by the extension in the publica tion date. The effective date for effluent limitations guidelines for this industry 41434 414.33 414.34 ogy economically achievable. [Reserved) Standards of performance for now sources. - Pretreatment standards for now sources. AuTHoemr: Sees. 301, 304(b) and (e), 306 (b) and (e), 307(0. 316(b), Federal Water Pollution Control Act, as amended; gg us.C. 1361, itll, 1314(b) and <o), 1816(b) and (c). 1317(e), 1396(c); 96 Stet. 616 et aeq.; Pub. L. 3-500. Subpart A--Nonequoous Processes > Subcfitegmy 1414.10 Applicability i description of dm nonaqiMoue processes subcate- E--Sous Waste Contsol Solid waste control^ must be consid ered. The waterborne wastes from the plastics and synthetics industry may contain a considerable volume of metals in various forms as a part of the sus established by the Court's November 2d order is May 13, 1974. Accordingly, good cause is found for the final regulation promulgated as set forth below to be ef fective on May 13,1974. The provisions of this subpsrt are ap plicable to discharges of process waste water resulting from the manufacture of the following products: Productt . Proceat doteriptkma BTX aromatics____ Hydrotreatment of py pended abllde pollutant. Best practicable Dated: April 17,1974. rolysis gasoline. control technology and best available control Mhitotagr. * they are known today, require disposal of the pollutants removed from waste waters In this indus try in Che form of solid wastes and liquid concentrates. In some cases these are nobhaaardous substances requiring only minimal custodial care. However, some constituents may be hazardous and may require special consideration. In order to ensure tong term protection of the en vironment from these hazardous or harmful ConstituenU, special considera tion of dlspool sites must be made. All landfill sites where such hazardous wastes are disposed should be selected so as to prevent horizontal and vertical mi gration of these contaminants to ground John Quarles, Acting Administrator. Subpart A Waoaqueaua Precasts* tuSretaqaiy Sec. 414.10 Applicability; description of the non- aqueous processes subcategory. 414.11 Specialtasd definlUont. 414.13 Effluent limitations guidelines repre senting the degree of effluent re duction attainable by tbo applica tion of the bast practicable control technology currently available. 414.13 Batten* limitations guideline* repre senting tbs degree of effluent re duction attainable by the applica tion at tbo beat available technol ogy economically achievable. 414.14 | Reserved| 414.18 standards of performance for new sources. 414.16 Pretreatment standards for new BTX aromatics.... Solvent estractlon from reformate. CyelebassiM--------- - Hydrogenation of ben zene. Vinyl chloride-------- Addition of hydrochloric acid to acetylene. 1414,11 Speciafised definitions. For the purpose of this subpart: (a) Except as provided below, the gen eral definitions, abbreviations and methods of analysis set forth in Part 401 of this Chapter shall apply to this .subpart. 8 414.12 EIHwcnl limitations guidelines represruting the degree of effluent reduction otlainalde by llie applica tion of tiie beat practicable control technology currently available. In establishing the limitations set forth or surface waters. In cases where geologic sources. hi this section, EPA took into account FEDfSAl MOIITM, VOL 34, NO. It--THU6S0AV, AMU 35, 1974 DTH 000088778 RULES AND REGULATIONS 14679 all Information it wm able to collect, de velop and aallcit with respect to factors (such as ace and sixe of plant, raw ma terials, manufacturing processes, prod ucts produced, treatment technology available, energy requirements and costa) which can affect the Industry subcatager- teatton and effluent levels established. It Is, however, possible that data which would affect these limitations have not been available and, as a result, these lim itations should be adjusted for certain plants in this industry. An individual discharger or other interested person may submit evidence to the Regional Ad ministrator (or to the State, if the State has the authority to issue NPDKS per mits) that factors relating to the equip ment or facilities Involved, the prooess applied, or other such factors related to such discharger are fundamentally dif ferent from the factors considered In the establishment of the guidelines. On the basis of such evidence or other avail able information, the Regional Adminis trator (or the State) will make a writ ten finding that such factors are or art not fundamentally different for that fa cility compared to those specified in the Development Document. If such funda mentally different factors are found to exist, the Regional Administrator or the State shall establish for tho dis charger effluent limitations in the HPDE3 permit either more or leas stringent than / the limitations established herein, to the extent dictated by such fundamentally different factors. Such limitations must be approved by the Administrator of the > Environmental Protection Agency. The A\ Administrator may approve or disap prove such limitations, shcclfy other i limitations, or initiate proceedings to re vise these regulations. The following lim itations establish tho quantity or qual t ity of poilutaats or pollutant properties, controlled by this section, which may be discharged by a point source subject to > the provisions of this subpart after ap r.n, if1 , plication of the best practicable technology currently available: control Effluent limitalioua Effluent character*etle - Avrragaatdafly Maximum tor vatnm tar *1 any 1 day emwtcuUm Sara aluH not aacaas-- Matria iinlla (kitngrema par 1.000 kg ol preduct) ntu ____ ,~mj a..M00i? it,0i0 ...................... ... Within tlM mm tvitoM* English unite (pounds par 1,000 lb of proiliRl) KMAlD.I.......................... M a mo ,t*r o o* at *_:-------- .. Within tha range 1.0 to U 1414.11 Effluent ItsuhaiioM pruMrlfaaes repreaenling tin degree of effluent reduction attainable by tlie eppffcaItom of the heal svaffabte IccbnoUgy iruueniidaH/ achievable. I The fallowing IhultaUona establish [ibo quantity or quality of poUutanta or ;PoihiUnt properties controlled by this section, which may be discharged by a point source subject to the provisions of this subpait after application of tho best available technology economically achievable: Muttt fffcmelfflrtfflttffl Sttufflnt UmllntAoo* Avfflraciofdftlly Maximum (or valu** tor any 1 day oehoanl*ln^cutntivCIWdMaln Molita uaita (kilogram* par 1,000 kg ot produot) cnooinu.._._.._.._._.._.._._.._..___ am.on sou .mu ths......................... ,m .on |>U.........................Wllhla lbs nap 0.0 ta 9.0. Kasim Mils (pound par 1,000 lb of pradaet) cod.................. am a ms now................. .ms .oou TSS....................... . 023 .01* pH........... .............Wllhla UmiuoiM la 0.0. S 414.14 [Reserved] E 414.15 Standards of performance for new sources. The following standards of perform ance establish the quantity or quality of pollutants or pollutant properties, controlled by this section, which may bo discharged by a new source subject to the provisions of this subpart: Effluent charaeUatatis Effluent Umttattooa Avaragaofdallr Maiimam hr values tor 18 any 1 day eonsecuUva dayi hall not asoaad Matrlc units (kilogram* P*r l, kl at product) hod#................ a o*r a 017 TUB........................ .UM ,0IS pit......................... Within Uis raafs 0.0 to (.a Englleb salts (pounds per 1,000 lb af product) stops................ am o.oi7 TBS----- :....------ . OM . OiS pit......................... WUMa tbs range S O to to. E 414.16 Pretreatment standards for new sources. The pretreatment standards under section 307(c) of the Act for a source within the nonnqueous processes subcategory, which Is a user of a publicly owned treatment works (and which would be a new source subject to section 304 of the Act, if it were to discharge pollutants to the navigable waters), shall be the standard set forth In Part 123 of tide Chapter except that, for the purpose of this section, 1 133.133 iff this Chapter shall be amended to read as follows: In addition to tho prohibitions aet forth in 40 071 138.1*1, tbs prvtreatmoat standard tor laoompstlbls pollutants introduced Into a publicly owned treatment works shall ba tha standard of porforatanoo for now sources apaoUlad la 40 CEB 414.1*; ProvWad. That, If too publicly owned treatment works which receives tha pollutants la oommltted, la Its NPDKS permit, to remove a specified per centage of aay Incompatible pollutant, tha pretreatment standard applicable to users of such treatment works shall, except ta the case of standards providing for no discharge, of pollutants, be oenrespoodtugly reduced la atrlngaacy far that pollutant. Water 8 414.20 Applicability j description of thus processes with process water con-' tact as steam diluent or absorbent ' subealegory. The provisions of this subpart are ap plicable to discharge* of process waste-* water resulting from the manufacture of the following products: Bt products at process descriptions , Acetorn -------------- - Butadiene ----------Ethyl bensene------ Ethylene and pro pylene --.... Ethylene dlchlortde ------------------ Ethylene oxide____ Dehydrogenation at Iso- propanol Coproduct of ethylene Alkylation of benaena with ethylene. Pyrolysis of naphtha or 1 liquid, petroleum gas. Direct chlorination. of ethylene. Catalytic oxidation1 of1 ethylene. 'i Formaldehyde ... Oxidation at methanol. \ Methanol ........ Steam reforming of' natural gas. / Methyl amines....: Addition of ammonia ( to methane. Vinyl acetate_____ Synthesis of ethylene and acetic acid. Vinyl chloride____ Cracking of. ethylene dichloride. Bt products Bt procesi descriptions Acetaldehyde____ Acetylene ._______ Butadiene ....... Butadiene _______ Dehydrogenation of ethanol. Partial oxidation of i methane. Dehydrogenation of n- . butane. Oxidative-dehydrogen ation of n-butane. , Styrene _________ Dehydrogenation ethyl benaena. of (41421 Specialised definitions. For the purpose of this subpart: (a) Except as provided below, the general definition#, abbreviations and methods iff analysis set forth in Part 401 of this Chapter shall apply to this sub part. | 414.22 Effluent limitations guidelines ' representing the degree of effluent reduction attainable by the applica tion of tlie best practicable control technology currently available. In establishing ths limitations set' forth In this section, EPA took into ac count all information it was able to col lect, develop and solicit with respect to factors (such os age end site ot plant, raw materials, manufacturing processes, products produced, treatment technology available, energy requirements and, costa) which can affect the industry subcategoriz&tion and effluent levels es tablished. It is, however, possible that data which would affect these limitations have not been available and, as a result, these limitations should be adjusted for certain plants In this Industry. An In dividual discharger or other Interested DTH 000088779 PfDMAl HOttTfl, VOi. 9V, NO. 91--THMSOAr, AlWt 29, 1*74 11GS0 RULES AND REGULATIONS person may submit evidence to the Re gional Administrator (or to the State, if the State has tlie authority to issue NPDES permits) that factors relating to the equipment or facilities Involved, the process applied, or other such factors related to such discharger are funda mentally different from the factors con sidered in the establishment of the guidelines. On the bails of such evidence or other available information, the Re gional Administrator (or the State) will make a written finding that such factors are or are not fundamentally different for that facility compared to Ufese speci fied in the Development Document. If such fundamentally different factors ere found to exist, the Regional Administra tor or the State shall establish for the discharger effluent limitations in tlie NPDKS permit either more or Hess strin gent than the limitations established herein, to the extent dictated by such fundamentally different factors. Such limitations must be approved by the Administrator of the liuvironinantal Protection Agency. The Administrator may approve or disapprove such limita tions, specify other fimltattons, or Initiate proceedings to revise them regulations. (a) The following HmttaUons estab lish the quantity or quality of pollutants or pollutant properties, oontrotted by this paragraph, which may be discharged from the manufacture of acetone, buta diene (co-product of ethylene), ethyl beneeene, ethylene and propylene, ethyl ene dichloride, ethylene asdds, forntalde- hyde, methanol, methyl amines, vinyl acetate, or vinyl chloride (cracking of ethylene dfahloride) by a point source subject to the provisions of this subpart after application of the best practicable control technology currently avaliable: subject to the provisions of this subpart after application of the best practicable control technology currently available; K(Burnt ebanwterialie K HIuuit limitation* Average o(dally Maximum lor values Cm *0 any I day eorn'cculive day* shall aotexvaad-- Metric unit* kg (okfllIo'ryoradmucat)per 1.0U0 TBBOMW....................................... 01.4333 a.0442 pH........ ...............Within the ranga 3A to 9.0. EagNsli units (psunds par 1,000 lb of product) bom.................. an o. TSS........................ 1.43 .04 pll..........................Wilhiu tlie range 0.0 to 3.0. B 414.23 Effluent lituilaliou* guidelines renrcMMliag lie degree of effluent reduction attainable by ibe applies* tiuii of llie beat available leclinoiogy economically achievable. (a) The following limitations estab lish the quantity or quality of pollutants or pollutant properties, controlled by this paragraph, which may be discharged from the manufacture of acetone, buta diene (co-product of ethylene), ethyl benzene, ethylene and propylene, ethyl ene dichloride, ethylene oxide, formalde hyde, methanol, methyl amines, vinyl acetate, or vinyl chloride (cracking of ethylene dichloride) by a* point source subject to the provisions of this subpart after application of the best available technology economically achievable: .KShient ehtaacUriMte ESlusut UntHsUons Average ofdolly Maximum far vutuua far M *y 1 dsy cMiseeutiv* days aboil ootsscsed-- SfluMt NoilfittMl AmntaSsU* Mmtaramfa. myifcr Mstri* unitejkUejmns par 1AM COD...:..-.... BOM. TM....r____ PH................ l.M Ml Xngttab ulnbitoef (pounds product) pn 1AM con........... TBHOADI............................... pn............... . .13 1414.24 l Reserved] S 414JK Standard* of performance for new sources. (a) The following standards of per formance establish the quantity or quodtty of pollutants or pollutant properties, controlled by this paragraph, which may be discharged from the manufacture of acetone, butadiene (co-product of ethylene), ethyl benzene, ethylene and propylene, ethylene dichloride, ethylene oxide, formaldehyde, mathanol, methyl amines, vinyl acetate, or vinyl chloride (cracking of ethylene dichlorkle) by a new source subject to the provisions of this subpart: RAueiii ebaracioriffllto KAuanl Until alien* Average of dally Maximum lor values far M any 1 day , eomeeutlee days shall noteaceed-- . Metric unite (kilograms par 1AM kg of product) BOM.................. 0.11 aim TSS...................... .10 .334 PU...................... . Within th* rang* 3.01* 3.0. English unite (pounds par 1AM Ibof prodoet) BOM.................. Tim____ _____ an ,it ao pH...................... . Wilhlti Uw rang* 0J Is 3.0. -i '1 . jf -i * :i "i I i i F.flhmut ebvaeterislte KSimil Umlletiw* A<rrr:M( <>f <lnlly Minimum far- valin* Sir 10 any 1 day . nmiUn day* aha|l I mi fsited-- BOM. IT::: BOM. Metric unit* (kilograms per l.ouo kg at product) 0.13 0.053 SO .Ml Within the range S.0 to f.tl. English oniti (gaund* par 1,000 lh of product) a is s ow .20 .UN Within the range AS to U (b) The following limitations establish the quantity or quality of pollutants or pollutant properties, controlled by this paragraph, which may be discharged from tlw manufacture of acetaldehyde (dehydrogenation of ethanol), acetylene (partial oxidation of methane), buta diene (dehydrogenation of n-butane), butadiene (oxidative-dehydrogenation of n-butane), or styrene by a point source Metric units (kilogram* par 1,000 kg of product) rnoonw.............................. aao .011 ft* '.025 ins........................ , ooo .010 P......................... WUbiu Um nuft ftO to 0.0. English unite (psund* per 1,000 lb of product) con................. a au BOM.................... .044 .025 TSS........................ .0* .0* an......................... WUWft tho W0 M to 1.0. (b) The following limitations estab lish the quantity or quality of pollutants or pollutant properties, controlled by this paragraph, which may be discharged from the manufacture of acetaldehyde (dehydrogenation of ethanol), acetylene (partial oxidation iff methane) butadiene (dehydrogenation of n-butane), buta diene (oxidative-dehydrogenation of n-butane) or styrene by a point source subject to the provisions of this subpart after application of the best available technology economically achievable: (b) The following limitations estab lish the quantity or quality of pollutants or pollutant properties, controlled by tills paragraph, which may be discharged 7 from the manufacture of acetaldehyde (dehydrogenation of ethanol), acetylene (partial oxidation of methane), buta diene (dehydrogenation of n-butane). butadiene (oxidative-dehydrogenation of ;. > n-butane) or styrene by a new source . subject to the provisions of this subpart. r*' " `' Eminnt limitations XSliIMt ehanclorlsll* Msslinum lor ArVosrhsingst otefrdMstir sny) dsy mnmrutln das* sfasB net taeead-- 1 MstMe unite (kilogram* pst i.mkd product) BOD*........ :........45 aw 0.34 pu*?:::::::::::::::: wtuiin'"* rang*.te , English unitoef p(prondauncdts) par IAW b ' r. BOW...;..:;;-.n3 tbs........ . pll............. ...:i..i IN .n Within Um nag* 3.0 le I.aNs IA { KBMAL RtOltIM, VOL 3*, NO. SI--IMUSIDAY, APRIL IS, IVYS DTH 000088780 I 1 \ .V T> r, t 4* Lv / Pi j-ft: ^' { 414.26 Pretrealmeut standards for new sources. The pretreatment standards under section 307(c) of the Act for a source within the processes with process water contact as stream diluent or absorbent subcategory, which Is a user of a publicly owned treatment works (and which would be a new source subject to section 306 of the Act, if It were to discharge pollutants to the navigable waters), shall be the standard set forth in Part 128 of this Chapter except that, for the purpose of this section. 1 120.133 of this Chap ter shall be amended to read as follows: In addition to tho prohibitions set forth In 40 cm 138.131, the pretreatment stand ard for incompatible pollutants Introduced Into e publicly owned trostment works shall ba the standard of performance for new sources speoUed In 40 era 414.2ft; Prodded, That, If the publicly owned treatment works which reoelves the pollutants Is committed. In Its NPDBQ permit, to remove s specified percentage of any Incompatible pollutant, the pretreatment standard applicable to users of such treatment works shell, except In the ease of standards providing for no dtacharge of pollutants, be oorteapondingly re duced in strtageaey far that pollutant. Eubpsit G-Aqueaus liquid Phase ftaaettosi Systems Suhcafegory 414.30 Applicability i description of Ilie aqneons liquid phase reaction systems submtegnry. 17m provisions of this subpart art ap plicable to discharges ot process waste water resulting from the manufacture of the following products: . Ot product* at process descriptions Acetic add------------- Oxidation of acetaldc- .1 hyde. Acrylic acid....--. Synthesis with carbon monoxide and acety 4; Opal Ur..................... lene. Distillation of ooal tar. MferkMurNi. Hydrogenation of eth ylene oxide. OaUlytlc oxidation of p-xylene. TtrvphttuUie Mid Purification of crude (polrimfirato). terephtliallc acid. Jr Ct product* Cl process descriptions Acetaldehyde..____ Oxidation of ethylene with oxygen. Caprolactam--------- Oxidation of cyclohex ane. Ooal tar--........ Pitch forming. * Carbonylatlon and con densation. acetone. Cumene oxidation and cleavage. " Ot product* 03 proceaa detoripticm* - AwUldahydv.. A___ DUwUijrl tDrvphtbalate. Oxidation of vthylvna with air. Nitration and hydro* Conation of beruseno. Condensation of phenol and acetone. aerification of terephthallc acid. 04 product* AarytfttM....____ ' P-Cmol- |`i MUi|li is I'- ftj.. Tr*pbth*Jlc xcM. TtUMthjrl toad__ 04 proceaa deacriptkma Bsterlfloatton of acrylic aeht. Sulfonatkm of toluene. Acetone cyanohydrin process. Nitric add process. Addition of ethyl chlo ride to lead amalgam. RULES AND REGULATIONS 8 414.31 Specialised definitions. For the purpose of this subpart: (a) Except as provided below, the gen eral definitions, abbreviations and meth ods of analysis set forth In part 401 of this Chapter shall apply to this subpart. 8 414.32 Effluent limitations guidelines representing llie degree of effluent reduction nllainahie l>y the applieslion of the best practicable control technology currently available. In establishing the limitations set forth In this section, EPA took into account all Information It was able to collect, develop and solicit with respect to factors (such as age and stoe> of plant, raw materials, manufacturing processes, products produced, treatment technology available, enewmiU'em^t. and croU) which can affect the industry subcategItortoto. ahtokwmevaenrd, peoffsluseibnlet ltehvaetl edsattaablwishheicdh. umitatbBf!l^muUl<haBiLlfuat^> for cermdiuftrv An ininterested SVrr!nJ?i!b2H evidence to the Re- gional Administrator Cor to the State. if the State has the authority to issue NPDE8 permits) that factors relating to the equipment or facilities involved. the process applied, or other such factors related to such discharger are fundamentally different from the factors considered in tlje establishment of the guidelines: On the basis of such evidence or other available Information, the Regional Administrator (or the State) will make a written finding that such factors are or are not fundamentally different for that facility compared to those specified to the Development Document. If such fundamentally different factors are found to exist, the Regional Administrator or the1 State shall establish for the discharger effluent limitations In the NPDES permit either more or less stringent than the limitstlons established herein, to the extent dictated by such fundamentally different factors. Such limitations must be approved by the Administrator of the Environmental Protection Agency. The Administrator may approve or dtoapprove such limitations, specify other limitations, or Initiate proceedings to revise these regulations. (a) The following limitations establish tphoe,,lluq'tuaann.t tpitryopoerrqt.i,eusa,litcyoon.tfroplolellduta.bnytst.h.o.isr paragraph, which may be discharge^ from the manufacture of acetic acid, acrylic acid, coal tar . (distillation). ethylene glyool, terephthalic acid (oxidatlon of p-xylene), or polymer grade terephthalic acid (purification of terephthalic acid) by a point source subject to the provisions of this subpart after application of the best practicable control technology currently available: 14881 Besot Hmllsllerai any 1 day Avitriifeoldally slues tor ID eoneMUllve days MMde unitso(fkiptoreetnfuyente) per l.ooft kg --------------------------------------- ...................... B*j l|j pH .........................within (jw rsnys4Ate to. ............................................ " (pamatoper MX* Bonl ---------------------- ----" tss...42 is ***................... withiatheianmaatoSA -...... ........................................................ <b) ^ foliowlng limitations estab- ^ h the Quantity or Quality of pollutants ^^2* properUes controlled by thUP<^nMir^0`^- SSbTJZ chxrgsd from the manufacture of aoetaldJ*JhgVlJj, (ocaxuidroat^ioUn mof ct^ihJrtianu^ <wnTith^ aceton* `cumene process) by a point *ource *ub)ect to the provisions of this, aubPart aftr application ot the best. trohndogy curront- y -------------------------------------------------------- , Emwot limitation* EButnt --------------------i"im.i.i"huij' cberacteriiille Mulmum (or valuo* kill "r ` d*r ------------------------------------------------- ----- m..h,, ..n. ---------- --_____ o< product) bow........ ....... ass ass witwnuL ranc*totot'a* .ii^ ^u (pmnd, p i.mo u, at product) BOO# ....... iTS JIT . wltUn& _______________________________ _________ <c> The following limitations estab- 11411U** quantity or quality of pollutants 01 pollutant properties, controlled by this Paragraph, which may be discharged from Uie manufacture of acetaldehyde (oxidation of ethylene with air), aniline, btophenol A, or dimethyl torephthalate a Point source subject to the pro- vision* of this subpart after application of the best practicable control technology currently available: -----------------------------------------;--------------- kbm*di solutions r.miwnt dwraewnatto Ann** ommi. Miannimy u1mdiffar medoTniiiwumaa*iiltuTortoi1lwa0yda- --------------------------------- ----------------- Metric mute (kiiocmm* por i,om n of product) jfgp*............... L}` # pH..'"""";""" wittuaciMmw**.too. Kocteb DB|M p*. 1()H " _______ is ot product) Bop*............... 1.11 asi^ puT"""""""" wiuuo'ul*mmo to u> .&** r _ ' no si--rt. i -14 FEDERAl RESliTES, VOt. 13, NO. SI--THUBSOAY, Aftlt 21, m4 DTli 0088781