Document BabzY9yM6DVoJmEqvNdRYMaX
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SAFETY DATA SHEETARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF FOAM CONCENTRATE
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Material Name: ARCTIC U.S. TYPE 6 (6%) MILSPEC AFFF FOAM CONCENTRATE, ARCTIC 6% MILSPEC AFFF FOAM CONCENTRATE
Synonyms: ARCTIC U.S. TYPE 6 (6%) MILSPEC; ARCTIC U.S. TYPE 6 MILSPEC AFFF; ARCTIC U.S. TYPE 6 MILSPEC; ARCTIC TYPE 6 (6%) MILSPEC, ARCTIC 6% MILSPEC AFFF; ARCTIC 6% MILSPEC; 6% MILSPEC AFFF
Product Description: Mixture.
Product Use: Fire Suppression Agent, Liquid Concentrate.
Restrictions on Use: None known.
Details of the supplier of the safety data sheet: The Solberg Company 1520 Brookfield Avenue Green Bay, Wisconsin 54313 USA Phone:+1 920 593 9445 Emergency Phone: +1 920 593 9445 E-mail: sds@solbergfoam.com
SECTION 2 - HAZARDS IDENTIFICATION
Classification in accordance with paragraph (d) of 29 CFR 1910.1200: Serious Eye Damage/Eye Irritation - Category 2A
GHS Label Elements:
Symbol(s)
Signal Word Warning
Hazard Statement(s) Causes serious eye irritation.
Precautionary Statement(s) Prevention Wear eye protection/face protection. Wash thoroughly after handling.
Page 1 of 9
S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015 US00005607
SAFETY DATA SHEETARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF FOAM CONCENTRATE
Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Storage None needed according to classification criteria.
Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.
SECTION 3 - COMPOSITION / INFORMATION ON INGREDIENTS
CAS Not available 112-34-5 142-31-4
Component Name i Non-hazardous ingredients i Diethylene glycol butyl ether i Sodium octyl sulfate
Percent 60-90 10-20 1-5
SECTION 4 - FIRST AID MEASURES
Description of Necessary Measures: No special measures are necessary.
Inhalation: If adverse effects occur, remove to uncontaminated area. Call a POISON CENTER or doctor if you feel unwell.
Skin: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention.
Eyes: Flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. If eye irritation persists: Get medical advice/attention.
Ingestion: If swallowed, get medical attention. Do NOT induce vomiting.
Most Important Symptoms/Effects: Acute Causes serious eye irritation. Delayed No information on significant adverse effects.
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S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015 US00005608
SAFETY DATA SHEETARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF FOAM CONCENTRATE
SECTION 5 - FIRE FIGHTING MEASURES
Extinguishing Media:
Suitable Extinguishing Media Not applicable as this is a fire suppression agent.
Unsuitable Extinguishing Media None known.
Special Hazards Arising from the Chemical Negligible fire hazard.
Hazardous Combustion Products Under certain extreme conditions there may be release of toxic and/or corrosive gases: oxides of nitrogen, oxides of carbon, oxides of sulfur, hydrogen fluoride.
Fire Fighting Measures Move container from fire area if it can be done without risk. Cool containers with water. Dike for later disposal. Avoid inhalation of material or combustion by-products.
Special Protective Equipment and Precautions for Firefighters Wear protective clothing and equipment suitable for the surrounding fire.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures: Wear personal protective clothing and equipment, see Section 8.
Methods and Materials for Containment and Cleaning Up: Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Stop leak if safe to do so. Collect spilled material in appropriate container for disposal.
Environmental Precautions: Prevent entry into waterways, sewers, basements, or confined areas. Dispose of waste in accordance with environmental legislation.
SECTION 7 - HANDLING AND STORAGE
Precautions for Safe Handling: Wear protective eye/face protection. Wash thoroughly after handling.
Conditions for Safe Storage, Including any Incompatibilities: None needed according to classification criteria. Further information on storage conditions: Keep only in original packaging or containers approved by the manufacturer. Do not mix with other extinguishing agent unless otherwise approved by the manufacturer.
Incompatible Materials: Electrically energized equipment, strong oxidizing agents, water-reactive materials.
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S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015
US00005609
SAFETY DATA SHEETARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF FOAM CONCENTRATE
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION Component Exposure Limits:
Diethvlene glycol butyl ether 112-34-5
: ACGIH:
[10 ppmTWA inhalable fraction and vapor [
: Europe: i
i 10 ppmTWA; 67.5 mg/m3 TWA I 15 ppmSTEL; 101.2 mg/m3 STEL
i i
EU - Occupational Exposure (98/24/EC) - Binding Biological Limit Values and Health Surveillance Measures There are no biological limit values for any of this product's components.
ACGIH - Threshold Limit Values - Biological Exposure Indices (BEI) There are no biological limit values for any of this product's components.
Engineering Controls Ensure compliance with applicable exposure limits. If necessary, use appropriate local exhaust ventilation to keep exposures below the regulated limits.
Individual Protection Measures, such as Personal Protective Equipment Eye/face protection Wear splash resistant safety goggles.
Skin Protection Wear suitable protective clothing such as coveralls or long sleeve shirt and pants.
Respiratory Protection No respirator is required under normal conditions of use.
Glove Recommendations Wear suitable gloves: nitrile, latex, rubber gloves.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Appearance Odor Odor Threshold Melting Point Freezing point Boiling Point Range
i Clear light yellow liquid i Physical State
f Mild
( Color
i Not available
pH
i Not available
( Boiling Point
i Not available
i Evaporation Rate
t Not available
( Flammability (solid, gas)
f Liquid i Light yellow
7-8 i Not available i Not available t Not available
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S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015
US00005610
SAFETY DATA SHEETARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF FOAM CONCENTRATE
j Autoignition
Not available
|Lower Explosive Limit Not available
|Upper Explosive Limit Not available
|Vapor Density (air=l) Not available
|Water Solubility
Complete
j Viscosity
2 -1 0 cSt
|Density
Not available
Flash Point
Does not flash
Decomposition
Not available
Vapor Pressure
Not available
Specific Gravity (water=l)
1.009- 1.049 |
Partition coefficient: n-octanol/water Not available
Solubility (Other)
Not available
Molecular Weight
Not available
Other Information: No information is available.
SECTION 10 - STABILITY AND REACTIVITY
Reactivity: No hazardous reaction when handled and stored according to provisions.
Chemical Stability: Stable under normal conditions of use.
Conditions to Avoid: None known.
Incompatible Materials: Electrically energized equipment, strong oxidizing agents, water-reactive materials.
Hazardous decomposition products: None known.
Thermal decomposition products: Under certain extreme conditions there may be release of toxic and/or corrosive gases: oxides of carbon, oxides of sulfur, oxides of nitrogen, hydrogen fluoride.
SECTION 11 - TOXICOLOGICAL INFORMATION
Acute and Chronic Toxicity:
Component Analysis - LD50/LC50 The components of this material have been reviewed in various sources and the following selected endpoints are published:
Diethvlene glycol butyl ether (112-34-5) Oral LD50 Rat 5660 mg/kg Dermal LD50 Rabbit 2700 mg/kg Sodium octyl sulfate (142-31-4) Oral LD50 Rat 3200 mg/kg Water (7732-18-5) Oral LD50 Rat >90 mL/kg
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S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015
US00005611
SAFETY DATA SHEETf? ri: ARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF
FOAM CONCENTRATE
Immediate Effects Causes serious eye irritation.
Delayed Effects No information on significant adverse effects.
Irritation/Corrosivity Data Causes serious eye irritation. Causes mild skin irritation.
Respiratory Sensitization No information available for the product.
Dermal Sensitization No information available for the product.
Component Carcinogenicity None of this product's components are listed by ACGIH, IARC, NTP, DFG or OSHA
Germ Cell Mutagenicity No information available for the product.
Tumorigenic Data No information available for the product.
Reproductive Toxicity No information available for the product.
Specific Target Organ Toxicity - Single Exposure No information available for the product.
Specific Target Organ Toxicity - Repeated Exposure No information available for the product.
Aspiration hazard No information available for the product.
Medical Conditions Aggravated by Exposure No information available for the product.
SECTION 12 - ECOLOGICAL INFORMATION Component Analysis - Aquatic Toxicity
Diethvlene glycol butyl ether 112-34-5
Fish: LC50 96 h Lepomis macrochirus 1300 mg/L [static]
Algae:
EC50 96 h Desmodesmus subspicatus >100 mg/L IUCLID
Invertebrate:
EC50 48 h Daphnia magna >100 mg/L IUCLID
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S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015
US00005612
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'
Persistence and Degradability No information available for the product.
Bioaccumulative Potential No information available for the product.
Mobility No information available for the product.
Other Toxicity No additional information is available.
SAFETY DATA SHEETARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF FOAM CONCENTRATE
SECTION 13 - DISPOSAL CONSIDERATIONS
Disposal Methods: Dispose of contents/container in accordance with local/regional/national/international regulations.
SECTION 14 - TRANSPORT INFORMATION
US DOT Information: UN/NA #: Not regulated as dangerous goods
IATA Information: UN#: Not regulated as dangerous goods
IMDG Information: UN#: Not regulated as dangerous goods
TDG Information: UN#: Not regulated as dangerous goods
SECTION 15 - REGULATORY INFORMATION
U.S. Federal Regulations:
Diethvlene elvcol butvl ether
SARA 313:
112-34-5
1 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substituted phenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, Chemical Category N230) (related to Glycol ethers)
Page 7 of 9
S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015 US00005613
SAFETY DATA SHEETARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF FOAM CONCENTRATE
U.S. State Regulations: The following components appear on one or more of the following state hazardous substances lists:
Component
CAS CA MA MN NJ PA
i Diethylene glycol butyl ether 112-34-5 No No No Yes Yes
|Water
7732-18-5 No No No No Yes
Not listed under California Proposition 65.
Canadian WHMIS Ingredient Disclosure List (IDL) Components of this material have been checked against the Canadian WHMIS Ingredients Disclosure List. The List is composed of chemicals which must be identified on MSDSs if they are included in products which meet WHMIS criteria specified in the Controlled Products Regulations and are present above the threshold limits listed on the IDL.
Diethvlene glycol butyl ether 112-34-5
! I1% f
Component Analysis - Inventory:
Diethylene glycol butyl ether (112-34-5)
US CA EU AU PH J P - ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX TW
Yes DSL EIN Yes Yes Yes
Yes Yes
No Yes Yes Yes Yes
Sodium octyl sulfate (142-31-4) US CA EU AU PH JP-ENCS JP - ISHL KR- KECI/KECL KR - TCCA CN NZ MX TW
Yes DSL EIN Yes Yes Yes
No Yes
No Yes Yes No Yes
Water (7732-18-5) US CA EU AU PH JP-ENCS JP - ISHL KR - KECI/KECL KR - TCCA CN NZ MX TW
Yes DSL EIN Yes Yes No
No Yes
No Yes Yes Yes Yes
SECTION 16- OTHER INFORMATION
HMIS Rating Health: 2 Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
NFPA Ratings Health: 2 Fire: 0 Reactivity: 0 Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
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S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015
US00005614
SAFETY DATA SHEETARCTICTM U.S. TYPE 6 (6%) MIL SPEC AFFF FOAM CONCENTRATE
Summary of Changes NewSDS: 08-December-2015
Key / Legend: ACGIH - American Conference of Governmental Industrial Hygienists; ADR - European Road Transport; AU - Australia; BOD Biochemical Oxygen Demand; C - Celsius; CA - Canada; CAS - Chemical Abstracts Service; CERCLA - Comprehensive Environmental Response, Compensation, and Liability Act; CLP - Classification, Labelling, and Packaging; CN - China; CPR Controlled Products Regulations; DFG - Deutsche Forschungsgemeinschaft; DOT - Department of Transportation; DSD Dangerous Substance Directive; DSL - Domestic Substances List; EEC - European Economic Community; EINECS - European Inventory of Existing Commercial Chemical Substances; EPA - Environmental Protection Agency; EU - European Union; F Fahrenheit; IARC - International Agency for Research on Cancer; IATA - International Air Transport Association; ICAO International Civil Aviation Organization; IDL - Ingredient Disclosure List; IDLH - Immediately Dangerous to Life and Health; IMDG - International Maritime Dangerous Goods; JP - Japan; Kow - Octanol/water partition coefficient; KR - Korea; LEL - Lower Explosive Limit; LLV - Level Limit Value; LOLI - List Of ListsTM - ChemADVISOR's Regulatory Database; MAK - Maximum Concentration Value in the Workplace; MEL - Maximum Exposure Limits; NFPA - National Fire Protection Agency; NIOSH National Institute for Occupational Safety and Health; NJTSR - New Jersey Trade Secret Registry; NTP - National Toxicology Program; NZ - New Zealand; OSHA - Occupational Safety and Health Administration; PH - Philippines; RCRA - Resource Conservation and Recovery Act; REACH- Registration, Evaluation, Authorisation, and restriction of Chemicals; RID - European Rail Transport; SARA - Superfund Amendments and Reauthorization Act; STEL - Short-term Exposure Limit; TDG - Transportation of Dangerous Goods; TSCA - Toxic Substances Control Act; TWA - Time Weighted Average; UEL - Upper Explosive Limit; US United States.
Other Information:
Disclaimer: Safety data sheet is for concentrate as received NOT for end-use solution.
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S-016 Issue date: 2015-12-08 Revision 1.0
Formulation No: 2262015 US00005615
