Document BR6pr403YDY97g1ZKXoM3oL0X

fit NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5005 PASSIVATION + Emergency Telephone Number 6S736Medical (708) 920-1510 (24 hours) SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5005 PASSIVATION + DESCRIPTION: An aqueous solution of antimony pentoxide NFPA 704M/HMIS RATING: 2/2 HEALXH 0/0 FLAMMABILITY 0/0 REACTIVITY 0=lnsignificant l=light 2=Moderate 3=High 4=Extresne 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Ocmnunication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INCKEDIENT(S) CAS # APERDX.% Antimony pentoxide 1314-60-9 20-40 SECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes irritation to skin and eyes. Do not get in eyes, on skin, or on clothing. Wear goggles or face shield when handling. Do not take internally. Enpty containers nay contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Immediately flush with water for at least 15 minutes. Fbr a large splash, flood body under a shcwer. Call a physician at once. Do not induce vaulting. Give water. Call a physician. NOTE TO FHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control symptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, do not induce vaniting or give water. NOTE TO EHYSICIAN: Probable mucosal damage may contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory depression and convulsions nay be needed. PAGE 1 OF 7 sal 000009631 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 AREA 7CQ-^05-100C &jyj5 NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5005 PASSIVATION + Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 5 HEALTH EFFECTS INFORMATION PRIMARY ROUTE(S) OF EXPOSURE: Eye, Skin EYE CONTACT; SKIN CONTACT: Can cause moderate to severe irritation. Can cause moderate to severe irritation. SYMPTCMS OF EXPOSURE: A review of available data does not identify any synptans fran exposure. AGGRAVATION OF EXISTING CCNDITICNS: A review of available data does not identify any worsening of existing conditions* SECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: No toxicity studies have been conducted on this product. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES 00IR: dear green SOXUBHITY IN WATER: SPECIFIC GRAVITY: pH (NEAT) * VISCOSITY: POUR POINT: FLASH POINT: FOW: Liquid Ocnpletely 1.3 60 Degrees F 6.4 5 cps/4 cts/39 SUS 60 Degrees F 23 Degrees F Ncne (FMGC) ODOR: None ASTM E--70 ASTM D-445 ASTM D-97 ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: None (FMCC) ASTM D-93 EXTINGUISHING MEDIA: This product would not be expected to turn unless all the water is boiled away. The remaining organics may be ignitable. Use water to cool containers exposed to fire. UNUSUAL FIRE AND EXPLOSION HAZARD: May evolve NOx under fire conditions. SECTION 9 REACTIVITY INFORMATION INOCMPATIBILTIY: None known THEFMAL [BCCMPC61TTCN IRODUCIS: In the event of combustion CO, 002, PAGE 2 OF 7 SAL. 009632 KHMOI NALCO CHEMICAL COMPANY- ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 190 a 7Q0.-O5-- OOO MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALOO 5005 PASSIVATION + Emergency Telephone Number Medical (708) 9201510(24 hour*) _________________________ HS7HS SECTION 9 REACTIVITY INFORMATION ( CONTINUED ) NQx may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed. If significant mists or aerosols are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for requirements arid selection). For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is reocranended. VENTILATION: General ventilation is reccmnended. IRCJiECTIVE EQUHMENT: Use inyenneable gloves and chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.) when attaching feeding equipment, doing maintenance or handling product. If clothing is contaminated, remove clothing and thoroughly wash the affected area. launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CAIL THE FOLLOWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPUL CONTROL AND RECOVERY: Small liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CERCLA in Section 14. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Ccnservaticri and Recovery Act (RCRA) 40 CFR 261, since it does not have the characteristics of Subpart C, (i.e. D001 through D017) nor is it PAGE 3 OF 7 SAL 000009633 BB NALCO CHEMICAL COMPANY OKIE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1190 V?P-nn5- 1 COO (t S 7 35 NALCO MATERIAL SAFETY DATA SHEET PRODUCT NMjOO 5005 PASSIVATION + Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) listed under Subpart D. As a non-hazardous liquid waste, it should be solidified before disposal to a sanitary landfill. SECTION 12 ENVIRONMENTAL INFORMATION BIOLOGICAL OXYGEN DEMAND (5-day BOD): Less than 600 ppa CHEMICAL OXYGEN DEMAND: 100,000 ppm If released into the environment, see CEROA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT FROFER SHIPPING NAME/HAZARD CODE - FRODUCT IS NOT REGULATED DURING TRANSPORTATION SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL REGUIATIQNS: OSHA HAZARD CCtMJNICATION RULE, 29 CFR 1910.1200: Based cn our hazard evaluation, the following ingredient in this product is hazardous and the reason is shewn belcw. Antimony ocEpounds - Irritant Antimony ccnpounds (as Sb) = TWA 0.5 mq/m3 ACGnVTLV CERCLA/SUPERFUND, 40 CFR 117, 302: Notification of spills of this product is not required. SARA/SUFERFUND AMENEMENI5 AND READIHORIZATION ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain ingredients listed in Appendix A and B as an Extrenely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): PAGE 4 OF 7 sAt 0009534 NALCO CHEMICAL COMPANY ONE NALCO CENTER * NAPERVILLE, ILLINOIS 60563-1198 ABFA 7CB-3Q5-1 OOO MATERIAL SAFETY DATA SHEET NALCO PRODUCT NAICD 5005 PASSIVATION + Emergency Telephone Number GS735Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION Our hazard evaluation has found this product to be hazardous. Ihe product should be reported under the following EPA hazard categories: XX limediate (acute) health hazard -- Delayed (chronic) health hazard -- Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning oannission, state emergency response ocnmission and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. After October 17, 1989, W3DS(s), or a list of product names for all hazardous substances between zero (0) and 10,000 pounds, not previously reported, nust be submitted. < CONTINUED ) SECTION 313 - LIST OF TOXIC CHEMICAIS (40 CFR 372) : This product contains the following ingredient (s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals. Antimony pentoxide 1314-60-9 20-40 TOXIC SUBSTANCES CONTROL ACT (TSCA) ; The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710) . RESOURCE CENSERVMTCN AND RECOVERY ACT (FCRA), 40 CFR 261 SUBPART C & D: If this product beccnes a waste, it does not meet the criteria of a hazardous waste. FEDERAL WATER P0IU7TICN CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311: This product contains the following ingredient (s) covered by the Clean Water Act: Antimony compounds - Section 307 pars? 5 OF 7 SAL 000009635 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 198 700-305-1 OCD GS7 35 NALCO MATERIAL SAFETY DATA SHEET I PRODUCT _________________NALOO 5005 PASSIVATION + Emergency Telephone Number Medical (708) 920-1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECITCN 112: This product does not contain ingredients covered by the dean Air Act. STATE REGULATIONS: CAUEOFNIA IMPOSITION 65: None of the chemicals on the current Proposition 65 list are kncwn to be present in this product. MICHIGAN CRITICAL MATERIALS: This product contains the following substance (s) identified cn the Michigan Critical Materials Register: Antimony compounds STATE RIGHT TO KNOW LAWS: The following states identify the ingredient (s) shown below as hazardous: Massachusetts - Triethanolamine Regulated in those states using the TLV for antimony caqpouixis as a criteria for listing. SECTION 15 ADDITIONAL INFORMATION None SECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the reccmnended safety precautions and should have access to this informaticn. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further informaticn. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT CN CARCINOGENS, U.S. Department of Health and Hunan Services, Public Health Service, FB 33-135855, 1983. PAGE 6 OF 7 SAL 00009636 NALCO CHEMICAL. COMPANY ONE NALCO CENTEH NAPERVILLE. ILLINOIS 60563-1198 .`-q-i 70R-30`j-1 OOO MATERIAL SAFETY DATA SHEET NALCO SECTION 17 BIBLIOGRAPHY PRODUCT NALCD 5005 PASSIVATION + Emergency Telephone Number Medical (708) 920-1510 (24 hour*) GS 7 35 ( CONTINUED ) CASARETT AND DOULL'S TOXICOIOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admir, M. O., eds., Maanillian Publishing Ccnpany, Inc N. Y., 2nd editicn, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hughes, J. P., eds., J, P. Lipincott Ccnpany, N.Y., 1981. DANGEROUS IROH-KITES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Feinhold Ccnpany, N.Y., 6th editicn, 1984. IARC M3N0GRAFHS ON THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICAIS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXIOOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd editicn, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, OH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (GSHA). THRESHOLD LIMIT VAIIJES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, CH. PREPARED BY: Ricky A. Stackhouse EtiD., Toxicologist DATE CHANGED: 03/01/89 DATE PRINTED: 07/26/90 PAGE 7 OF 7 SAL 000009637 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1108 A^Efl ?-3C5- i 0CDO NALCQ MATERIAL SAFETY DATA SHEET . PRODUCT Emergency Telephone Number Medical (708) 920-1510 (24 hour*) SAL 000009638 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1130 AREA 70B-30S5-1 ODD Hi NALCQ MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5590 EMJLSION EREAKER Emergency Telephone Number Medical (708) 620-1510 (24 hours) _ ________________ G S 7 36 SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NAIGO 5590 EMLJISION BREAKER DESCRIPTION: A blend of oxyalkylates in a hydrocarbon solvent NFPA 704IVHMIS RATING: 1/1 HEALTH 2/2 FtAMMABTUTY 0/0 REACTIVITY (XLnsignifleant 1=Slight 2=*ioderate 3=High 4=Extrane 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient (s) as hazardous under CSHA's Hazard Ccramnication Rule, 29 CFR 1910.1200. Ocnsult Section 14 for the nature of the hazard (s). INGREDIENT (S) CAS # AFERDX.% Heavy aromatic naphtha Ethylbenzene Naphthalene Xylene 68603-08-7 100-41-4 91-20-3 1330-20-7 40-70 5-10 1-5 1-5 SECTION 3 PRECAUTIONARY LABEL INFORMATION CAUTION: Carbustible. May cause irritation to skin and eyes. Prolonged inhalation of vapor may be harmful. Avoid contact with skin, eyes and clothing. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away frem heat and open flame. Keep container closed when not in use. Enpty containers may contain residual product. Do not reuse container unless properly reconditioned. SECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTION: INHALATION: Immediately flush for at least 15 minutes while holding eyelids open. Call a physician at once. Wash thoroughly with soap and rinse with water. Call a physician. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat symptoms. Call a physician. NOTE TO LHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control syrnptoms and clinical condition. CAUTION: If unconscious, having trouble breathing or in convulsions, PAGE 1 OF 8 SAL 000009639 NALCO CHEMICAL COMPANY ONE NALCO CENTER APEA 703-305-1000 NAPERVILLE. ILLINOIS 60563-1190 MATERIAL SAFETY DATA SHEET ,, NALCO 5590 EMJISION BREAKER PRODUCT Emergency Telephone Number Medical (708) 920-1510 (24 hours) do not induce vaulting or give water. SECTION 5 HEALTH EFFECTS INFORMATION ERIMARY ROUIE(S) OF EXPOSURE: Eye, Skin, Inhalation EYE CONTACT: SKIN CONTACT: INGESTION: INHALATION: Can cause transient to moderate irritation. Can cause transient irritation. Can be harmful. Prolonged inhalation of mist or vapor may be harmful. SYMPTOMS OF EXPOSURE: ACUTE: Inhalation of high concentrations of product can cause nausea, dizziness, vaulting, stupor or unconsciousness. CHRONIC: Prolonged skin contact with product can cause dry skin and defatting, resulting in irritation and dermatitis. AGGRAVATION OF EXISTING OCNDTTICNS: A review of available data does not identify any worsening of existing conditions. SECTION 6 TOXICOLOGY INFORMATION TOXICITY STUDIES: No toxicity studies have been conducted on this product. SECTION 7 PHYSICAL AND CHEMICAL PROPERTIES COLOR: Dark amber SOUJBH2TY IN WATER: SPECIFIC GRAVITY: FLASH POINT: BUR*: Liquid Dispersible 0.98 6 60 Degrees F 132 Degrees F (EMCC) ODOR: Hydrocarbon ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION S FIRE AND EXPLOSION INFORMATION FLASH POINT: 132 Degrees F (FMOC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXPLOSION HAZARD: Containers exposed in a fire should be PAGE 2 OF 8 SAL 000009640 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 19B AREA 708-305- 1 DOQ V* NALCO MATERIAL SAFETY DATA SHEET PRODUCT NAIJ30 5590 EMJLSION BREAKER Emergency Telephone Number Medical (708) 920-1510 (24 hours) g g SECTION 8 FIRS AND EXPLOSION INFORMATION ( CONTINUED ) cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION HKXMPA1TBIUTYS Avoid contact with strung oxidizers (eg. chlorine, peroxides, chronates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL ceaCMPOSmCN PRODUCTS: In the event of canbustion CO, 002 may be forced. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY HOTECnCN: Respiratory protection is not normally needed since the volatility and toxicity are lew. If significant vapors or mists are generated, wear a NIOSH approved or equivalent respirator. If it is possible to generate significant levels of vapors or mists, a NIOSH approved or equivalent respirator is reoentoended. For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is reccrtaerded. VENTILATION: General ventilation is reoenmended. Additionally, local exhaust ventilation is reccnnended where vapors or mists nay be released. PROTECTIVE EQUIPMENT: Use impermeable gloves and chemical splash goggles when attaching feeding equipment, doing mintenance or handling product. If clothing is contaminated, remove clothing and thoroughly wash the affected area. launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSPORTATION ACCIDENTS, CALL THE FOLLCWING 24-HOUR TELEPHONE NUMBER (708-920-1510) SPILL CONTROL AND RECOVERY: Snail liquid spills: Contain with absorbent material, such as clay, soil or any commercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CE2RCLA in Section 14. PAGE 3 OF 8 SAL 000009641 NALCO CHEMICAL. COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 7C9-305-100Q * NALCO GS736 ^SBCTIONl^SPIlS^ND MATERIAL SAFETY DATA SHEET PRODUCT NAKI) 5590 EMtJIBICN breaker Emergency Telephone Number Medical (708) 920-1510 (24 hours) large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CE*CXA in Section 14. DISPOSAL: If this product becomes a waste, it meets the criteria of a hazardous waste as defined under the Resources Conservation and Recovery Act (RCRA) 40 CJR 261. Hazardous Waste D001. As a hazardous liquid waste, it most be solidified with stabilizing agents (such as sand, fly ash, or c&nent) so that no free liquid remains before disposal to a licensed industrial waste landfill (Hazardous Waste Treatment, Storage and Disposal facility). A hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CERCTA in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT IRDPER SHIPPING NAME^HAZARD CODE - COMBUSTIBLE LIQUID, N.O.S. COMBUSTIBLE LIQUID NA 1993 CONTAINS - ARCMA1TC HYEKXARBONS SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FEDERAL RBGUIATICNS: OSHA HAZARD CC*MUNICA1TCN RULE, 29 CFR 1910.1200: Based on our hazard evaluation, the following ingredient in this product is hazardous and the reason is shown below. Heavy aromatic naptha - Skin irritant, combustible Ethylbenzene - Eye irritant Naphthalene - Eye irritant Xylene - Eye irritant Ethylbenzene = TWA 100 ppm, STEL 125 ppm AOGIH/TLV 434 mg/m3, 543 irg/m3 ACGIiyTLV Naphthalene = TWA 10 ppm, STEL 15 ppm AOGUyTLV 52 irg/m3, 79 mgt/m3 ACGm/TLV Xylene = TWA 100 ppm, STEL 150 ppm A(XIH/TD/ 434 mg/m3, 651 mg/m3 ACGIH/TLV PAGE 4 OF 8 SAL 000009642 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 7nB-305-1 OO" N NALCO MATERIAL SAFETY DATA SHEET NAICD 5590 EMULSION BREAKER PRODUCT Emergency Telephone Number Medical (708) 920-1510 (24 hours) GS736 Ethylbenzene = TWA 100 ppm, STEL 125 ppm OSHA/FEL 435 mg/m3, 545 mg/m3 OSHA/fEL Naphthalene = TWA 10 ppm, STEL 15 ppm OSHA/FEL 50 mg/m3, 75 mg/m3 OSHA/FEL Xylene = TWA 100 ppm, STEL 150 ppm OSHA/FEL 435 mg/m3f 655 mg/m3 OSHA/FEL (XRCLA/SUFERFUND, 40 CFR 117, 302: This product contains , a Reportable Quantity (RQ) substance and if 3,400 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D. C. (1-800-424-8802) . SARA/SUPER^N0 AMENEMENTS AND REMJTHDRIZAnCN ACT OF 1986 (TITLE III) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain ingredients listed in Appendix A and B as an External y Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Immediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning ccrrmission, state emergency response commission and local fire department is required after October 17, 1987 if ycu have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extrsnely hazardous substance. SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372): This product contains the follcwing ingredient (s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals. Ethylbenzene 100-41-4 5-10 PAGE 5 OF 8 SAL 000009643 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 J AOEA708-305-`G0Q MATERIAL SAFETY DATA SHEET NALCO G S 7 36 PRODUCT NMD 5590 EMJISICN HffiftKER Emergency Telephone Number Medical (708) 920*1510 (24 hours) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) Naphthalene Xylene 91-20-3 1330-20-7 1-5 1-5 TOXIC SUBSTANCES CONTROL ACT (TSCA) : The chemical ingredients in this product are on the 8(b) Inventory List (40 CFR 710). RESOURCE OCNSERVATTCN AND RECOVERY ACT (RCRA) , 40 CFR 261 SUBPAKT C & D: If this product beccxnes a waste, it does meet the criteria of a hazardous waste as defined under RCRA 40 CFR 261 (consult Section 11). FEDERAL WATER POILUITCN CONTROL ACT, CLEAN WATER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/formerly Sec. 311: This product contains the following ingredients covered by the Clean Water Act: Naphthalene - Section 307, 311 Ethylbenzene - Section 307, 311 Xylene - Section 311 CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product contains the following ingredients covered by the dean Air Act: Ethylbenzene - Section 111 Xylene - Section 111 STATE REGULATIONS: CALIFORNIA FRDPOSITICN 65: Substances )cnown to the State of California to cause cancer may be present as an iirpurity or residue. MICHIGAN CRITICAL MATERIALS: This product contains the following substance(s) identified on the Michigan Critical Materials Register: Naphthalene, Xylene STATE RIGHT TO KNCW IAW5: The following ingredient (s) are disclosed for compliance with State Right To Know Laws: Ethylbenzene Heavy aromatic naphtha Naphthalene 100-41-4 68603-08-7 91-20-3 PAGE 6 OF 8 SAL 000009644 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 70E-305- 1 QGG NALCO MATERIAL SAFETY DATA SHEET PRODUCT NAtCO 5590 MJLSIQN BREAKER Emergency Telephone Number Medical (708) 920-1510(24 hours) Oxyalkylate QxyalXylate Xylene Trade secret Trade secret 1330-20-7 INIEFNATICNAL REGUIAITCNS: This is a WHMIS controlled product under The Bouse of Gannons of Canada Bill 0-70. The product contains the following substance(s), frcta the Ingredient Disclosure List or has been evaluated based on its toxicological properties, to contain the following hazardous ingredient (s): Chemical Name CAS # % ConcentrationRange Heavy aromatic naphtha Ethylbenzene Naphthalene Xylene 68603-08-7 100-41-4 91-20-3 1330-20-7 40-70 5-10 1-5 1-5 SECTION 15 ADDITIONAL INFORMATION F 302666 8ECTION 16 USER'S RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the reccmnended safety precautions and should have access to this information. Pea: any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult your local sales representative for any further information. SECTION 17 BIBLIOGRAPHY ANNUAL REPORT ON CARCINOGENS, U.S. Department of Health and Human Services, Public Health Service, FB 33-135855, 1983. CASAKEIT AND DOUIL'S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Admur, M. 0., eds., MaomiIlian Publishing Ocmpany, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE WORKPLACE, Proctor, N. H., and Hiighes, J. P., eds., J. P. Lipincott Carparry, N.Y., 1981. PAGE 7 OF 8 SAL 000009645 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE, ILLINOIS 60563-1 1SQ AREA 7C?-3Q5- 1 OOO MATERIAL SAFETY DATA SHEET NALCO GS736 SECTION 17 BIBLIOGRAPHY PRODUCT NAICO 5590 HMUISION BREAKER Emergency Telephone Number Medical (706) 920-1510 (24 hour*) ( CONTINUED ) DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, sax, N. Irving, ed. , Van Nostrand Reinhold Ccnpany, N.Y., 6th edition, 1984. IARC EENOGRATHS CN TOE EVALUATION OF TOE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research on Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G, D-, Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS CN CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease Control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, CH, 1984. Title 29 Code of Federal Regulations Fart 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD T.TMTT VAIDES FOR CHEMICAL SUBSTANCES AND PHYSICAL AGENTS IN TOE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, CH. FREPARED BY: Ricky A. Stackhouse EhD., Toxicologist DATE CHANGED: 06/21/90 DATE PRINTED: 07/05/90 PAGE 8 OF 8 SAL 00096*6 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563*1198 =A 700-305-1 OOO N NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5546 LIQUID Emergency Telephone Number Medical (708) 920-1510 {24 hours) G S 7 37 SECTION 1 PRODUCT IDENTIFICATION TRADE NAME: NALCO 5546 LIQUID DESCRIPTION: A blend of oxyalkylated resin adduct esters and oxyalkylated alkylphenol formaldehyde resins in a heavy aromatic naphtha NFPA 704M/HMIS RATING: 2/2 HEALTH 2/2 FLAMMABILITY 0/0 REACTIVITY (^Insignificant l=Slight 2=Moderate 3=High 4=Extreane 0 OTHER SECTION 2 HAZARDOUS INGREDIENTS Our hazard evaluation has identified the following chemical ingredient(s) as hazardous under OSHA's Hazard Occrounication Rule, 29 CFR 1910.1200. Consult Section 14 for the nature of the hazard(s). INGREDIENT (S) CAS # APPROX. % Heavy aroratic naphtha Naphthalene 64742-94-5 91-20-3 40+ 1-10 8ECTION 3 PRECAUTIONARY LABEL INFORMATION WARNING: Causes irritation to skin and eyes, combustible. Prolonged inhalation of vapor may be harmful. Do not get in eyes, on skin, or on clothing. Wear goggles or face shield when handling. Avoid prolonged or repeated breathing of vapor. Use with adequate ventilation. Do not take internally. Keep away from heat and open flame. Keep container closed when not in use. Etopty containers may contain residual product. Do not reuse container unless properly reconditioned. 8ECTION 4 FIRST AID INFORMATION EYES: SKIN: INGESTICN: INHALATION: Flush with water for 15 minutes. Cadi a physician. Inroadiately flush with water for at least 15 minutes. For a large splash, flood body under a shower. Call a physician at cnce. Do not induce vomiting. Give water. Call a physician. Remove to fresh air. Treat syuptcros. Call a physician at cnce. NOTE TO FHYSICIAN: No specific antidote is known. Based on the individual reactions of the patient, the physician's judgment should be used to control syuptcms and clinical condition. PAGE 1 OF 8 sAL 000009647 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 6O5S3-1190 inr^ ?C5-!:'5-`2DO MATERIAL SAFETY DATA SHEET NALCO G S 7 37 PRODUCT NALCO 5546 LIQUID Emergency Telephone Number Medical (706) 920-1510 (24 hours) 8ECTION 4 FIRST AID INFORMATION ( CONTINUED ) CMJITCN: If unconscious, having trouble breathing or in convulsions, do not induce vomiting or give water. SECTION 5 HEALTH EFFECTS INFORMATION HLEMARY ROUIE(S) OF EXPOSURE: Eye, Skin, Inhalation EVE OCNTACT: SKIN OCNTACT INCTSTICN: INHALATION: can cause moderate irritation. Can cause severe irritation. Can be harmful. Prolonged inhalation of mist or vapor may be harmful. SYMPTOMS OF EXPOSURE: ACUTE: Inhalation of high concentrations of heavy aromatic naphtha can cause nausea, dizziness, vomiting, stupor or unconsciousness. CHRONIC: prolonged skin contact of heavy aromatic naphtha can cause dry skin and defatting resulting in irritation and dermatitis. AGGRAVATION OF EXISTING OCNDTTICNS: A review of available data does not identify any worsening of existing conditions not previously mentioned, or identified in Section 6 or 14. 8ECTION 6 TOXICOLOGY INFORMATION ACUTE TOXICITY STUDIES: No toxicity studies have been conducted on this product. 8BCTION 7 PHYSICAL AND CHEMICAL PROPERTIES OOICR: Dark amber DENSITY: SOLUBILITY IN WATER: SPECIFIC GRAVITY: FLASH POINT: POEM: Liquid 7.92 lbs/gal. Insoluble 0.95 60 Degrees F 150 Degrees F (H4DC) ODOR: Alcoholic ASTM D-93 NOTE: These physical properties are typical values for this product. SECTION 8 FIRE AND EXPLOSION INFORMATION FLASH POINT: 150 Degrees F (FMOC) ASTM D-93 EXTINGUISHING MEDIA: Based on the NFPA guide, use dry chemical, alcohol foam, carbon dioxide or other extinguishing agent suitable for Class B fires. Use PACT: 2 OF 8 SAL 000009648 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 198 iPEi 70Q-3C5- 1 CCC MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALCO 5546 LIQUID Emergency Telephone Number Medical (708) 920*1510 (24 hours) _________________ (L12L3I- SECTION a FIRE AND EXPLOSION INFORMATION ( CONTINUED ) water to cool containers exposed to fire. For large fires, use water spray or fog, thoroughly drenching the burning material. UNUSUAL FIRE AND EXFIJDSICN HAZARD: Containers exposed in a fire should be cooled with water to prevent vapor pressure buildup leading to a rupture. SECTION 9 REACTIVITY INFORMATION INrrwpftTTRTT.tty; Avoid contact with strong oxidizers (eg* chlorine, peroxides, chrcroates, nitric acid, perchlorates, concentrated oxygen, permanganates) which can generate heat, fires, explosions and the release of toxic fumes. THERMAL DBOCMFOSITICN IRDDUCIS: In the event of combustion CD, CD2 may be formed. Do not breathe smoke or fumes. Wear suitable protective equipment. SECTION 10 PERSONAL PROTECTION EQUIPMENT RESPIRATORY PROTECTION: Respiratory protection is not normally needed since the volatility and toxicity are low. If significant vapors, mists or aerosols are generated, wear a NIOSH approved or equivalent respirator, (ANSI Z 88.2, 1980 for requirements and selection). For large spills, entry into large tanks, vessels or enclosed small spaces with inadequate ventilation, a pressure-demand, self-contained breathing apparatus is recommended. VEOTHATICN: General ventilation is recxnmended. Additionally, local exhaust ventilation is recommended where vapors, mists or aerosols may be released. PROTECTIVE EQUUMENT: Wear gloves, boots, apron and a face shield with chemical splash goggles (ANSI Z 87.1 requirements and selection of gloves, goggles, shoes, etc.). A full slicker suit is reocmtended if gross exposure is possible. The availability of an eye wash fountain and safety shcwer is recommended. If clothing is ocntaminated, ranove clothing and thoroughly wash the affected area. launder contaminated clothing before reuse. SECTION 11 SPILL AND DISPOSAL INFORMATION IN CASE OF TRANSKNTATICN ACCIDENTS, CAIL THE FOLLCWING 24-HOUR TEIETHCNE NUMBER (708-920-1510) PAGE 3 OF 8 SAL 00009649 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 7C0-3C5-' OCO fSt NALCO GS737 MATERIAL SAFETY DATA SHEET PRODUCT I NAL30 5546 LIQUID Emergency Telephone Number Medical (708) 920*1510(24 hours) SECTION 11 SPILL AND DISPOSAL INFORMATION ( CONTINUED ) SPILL CCNIROL AND RECOTEFY: Snail liquid spills: Contain with absorbent material, such as clay, soil or any cctnnercially available absorbent. Shovel reclaimed liquid and absorbent into recovery or salvage drums for disposal. Refer to CERCLA in Section 14. Large liquid spills: Dike to prevent further movement and reclaim into recovery or salvage drums or tank truck for disposal. Refer to CSPCLA in Section 14. For large indoor spills, evacuate employees and ventilate area. Those responsible for control and recovery should wear the protective equipment specified in Section 10. DISPOSAL: If this product becomes a waste, it does not meet the criteria of a hazardous waste as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261, since it does not haeve the characteristics of Subpart C, (i.e. D001 through D017) nor is it listed under Subpart D. As a nen-hazardous liquid waste, it should be solidified with stabilizing agents (such as sand, fly ash, or cement) so that no free liquid remains before disposal, to an industrial waste landfill. A near-hazardous liquid waste can also be incinerated in accordance with local, state, and federal regulations. SECTION 12 ENVIRONMENTAL INFORMATION If released into the environment, see CXRC1A in Section 14. SECTION 13 TRANSPORTATION INFORMATION DOT PROPER SHIPPING NAME/HAZARD OOCE - OCMBUST1KLE LIQUID, N.O.S. CCMBUSTTBT.E LIQUID NA 1993 0CNEAIN5 - AROMATIC HYOSXARBONS, NAHGHAIflffi SECTION 14 REGULATORY INFORMATION The following regulations apply to this product. FECERAL REGUIATICNS: OSHA HAZARD CCMIOTCMTCN HJIE, 29 CFR 1910.1200: Based cn our hazard evaluation, the following ingredients in this PAGE 4 OF 8 SAL 000009650 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B Af=>EA 7QB-3Q5- "i OCQ MATERIAL SAFETY DATA SHEET NALCO PRODUCT NALDO 5546 LIQUID Emergency Telephone Number G S 737Medical (706) 920-1510 (24 hour*) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) product are hazardous and the reasons are shewn belcw. Heavy aromatic naphtha - Combustible, skin irritant Naphthalene = Irritant Naphthalene = twa 10 ppm, STEL 15 ppm AcrmVTLV 52 mq/m3 79 wq/io3 bCGIH/TUJ Naphthalene = TWA 10 ppm, STEL 15 ppm QSHA/FEL 50 wq/m3 75 mq/in3 QSHA/PEL Heavy arenatic naphtha 100 ppm TU7 Manufacturer's reexemendation CERCLA/5UPERHJND, 40 CFR 117, 302: This product contains naphthalene, a Reportable Quantity (RQ) substance and if 1,400 pounds of product are released, it requires notification to the NATIONAL RESPONSE CENTER, WASHINGTON, D. C. (1-800-424-8802). SARA/SOTtRFUND AMENEMENES AND REMJTHSOZATICN ACT OF 1986 (TITLE IH) - SECTIONS 302, 311, 312 AND 313: SECTION 302 - EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355) : This product does not contain ingredients listed in Appendix A and B as an Extremely Hazardous Substance. SECTIONS 311 and 312 - MATERIAL SAFETY DATA SHEET REQUIREMENTS (40 CFR 370): Our hazard evaluation has found this product to be hazardous. The product should be reported under the following EPA hazard categories: XX Imoediate (acute) health hazard -- Delayed (chronic) health hazard XX Fire hazard -- Sudden release of pressure hazard -- Reactive hazard Under Section 311, submittal of MSDS's or a list of product names to the local emergency planning commission, state emergency response occmission and local fire department is required after October 17, 1987 if you have: -- 10,000 pounds or more of a hazardous substance, or -- 500 pounds or the threshold planning quantity, whichever is less, of an extremely hazardous substance. PAGE 5 OF 8 SAL 000009651 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 198 ARFA 7CQ-^C5- ' ?CO MATERIAL SAFETY DATA SHEET NALCO eS7 37 PRODUCT NALOO 5546 LIQUID emergency Telephone Number Medlcel (708) 820-1510 (24 hour*) SECTION 14 REGULATORY INFORMATION ( CONTINUED ) SECTION 313 - LIST OF TOXIC CHEMICALS (40 CFR 372) 5 Hiis product contains the following ingredient (s), (with CAS # and % range) which appear(s) on the List of Toxic Chemicals. Naphthalene 91-20-3 1-10 TOXIC SUBSTANCES CONTROL ACT (TSCA) r Hie chemical ingredients in this product are cn the 8(b) Inventory list (40 CFR 710) . RESOURCE CONSERVATION AND RECOVERY ACT (FCRA) , 40 CFR 261 SUHPAKT C & D: If this product becomes a waste, it does not meet the criteria of a hazardous waste. FEDERAL WATER POILOTICN OCNIROL ACT, CLEAN WA1ER ACT, 40 CFR 401.15/ formerly Sec. 307, 40 CFR 116/fonnerly Sec. 311: This product contains the following ingredient covered by the deem Water Act: Naphthalene - Section 307, 311 CLEAN AIR ACT, 40 CFR 60, SECTION 111, 40 CFR 61, SECTION 112: This product does not contain ingredients covered by the dean Air Act. STATE KEEUIATICNS: CALIFORNIA IROFOSITICN 65: None of the chemicals cn the current Proposition 65 list are knewn to be present in this product. MICHIGAN CRITICAL MAHRLAIS: This product does not contain ingredients listed on the Michigan Critical Materials Register. STATE RIGHT TO KNOW LAWS: Regulated in those states using the TLV for naphthalene as a criteria for listing. SECTION 15 ADDITIONAL INFORMATION None PAGE 6 OF 8 SAL 000009652 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1198 AREA 7CS-3Q5- 1 OOO NALCO MATERIAL SAFETY DATA SHEET PRODUCT NALCO 5546 LIQUID Emergency Telephone Number Medical <708) 920-1510 (24 hours) SECTION 16 U8BR'8 RESPONSIBILITY This product material safety data sheet provides health and safety information. The product is to be used in applications consistent with our product literature. Individuals handling this product should be informed of the recommended safety precautions and should have access to this information. For any other uses, exposures should be evaluated so that appropriate handling practices and training programs can be established to ensure safe workplace operations. Please consult ycur local sales representative for any further information. 8ECTI0N 17 BIBLIOGRAPHY ANNUAL REPORT CN CARCINOGENS, U.S. Department of Health and Hunan Services, Public Health Service, PB 33-135855, 1983. CASAREIT AND DOUIX/S TOXICOLOGY, THE BASIC SCIENCE OF POISONS, Doull, J., Klaassen, C. D., and Adraur, M. 0., eds., Maomi Ilian Publishing Corpany, Inc., N. Y., 2nd edition, 1980. CHEMICAL HAZARDS OF THE HCRKPLACE, Proctor, N. H., and Hughes, J. P., eds., J. P. Lipinocrtt Ccnpany, N.Y., 1981. DANGEROUS PROPERTIES OF INDUSTRIAL MATERIALS, Sax, N. Irving, ed., Van Nostrand Reinhold Company, N.Y., 6th edition, 1984. IARC MONOGRAPHS OJ THE EVALUATION OF THE CARCINOGENIC RISK OF CHEMICALS TO MAN, Geneva: World Health Organization, International Agency for Research cn Cancer, 1972-1977. PATTY'S INDUSTRIAL HYGIENE AND TOXICOLOGY, Clayton, G. D., Clayton, F. E., eds., John Wiley and Sons, N. Y., 3rd edition, Vol. 2 A-C, 1981. REGISTRY OF TOXIC EFFECTS ON CHEMICAL SUBSTANCES, U.S. Department of Health and Human Services, Public Health Service, Center for Disease control, National Institute for Occupational Safety and Health, 1983 supplement of 1981-1982 edition, Vol. 1-3, CH, 1984. Title 29 Code of Federal Regulations Part 1910, Subpart Z, Toxic and Hazardous Substances, Occupational Safety and Health Administration (OSHA). THRESHOLD LIMIT VALUES FCR CHEMICAL SUBSTANCES AND EHYSICAL AGENTS IN THE WORKROOM ENVIRONMENT WITH INTENDED CHANGES, American Conference of Governmental Industrial Hygienists, OH. PAGE 7 OF 8 SAL 000009653 NALCO CHEMICAL COMPANY GNE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 1 SB AT NALCO GS7 37 SECTION 17 BIBLIOGRAPHY MATERIAL SAFETY DATA SHEET PRODUCT NALOO 5546 LIQUID Emergency Telephone Number Medical (708) 920-1510 (24 hour*) ( CONTINUED ) PREPARED BY: Ricky A. Stackhouse RiD., Ttoaoologist EAIE CHANGED: 11/28/89 DATE PRINTED: 08/20/90 r PAGE 8 OF 8 SAL 000009654 NALCO CHEMICAL COMPANY ONE NALCO CENTER NAPERVILLE. ILLINOIS 60563-1 19B AREA 700-305- 1 OOO