Document B50LQGOvq9QaLjRmyQYXjxO4o

j. in i c K N A L MATERIAL SAFE T r DATA 2hE j. ''SUE DATE : OCTOBER 29, 1 936DATE UPDATED: MARCH 2, 1988 CHEMICAL NAME: 2-3-EP0XY-1-PROPANOL i4 i MANUFACTURER NAME/ADDRESS- DIXIE CHEMICAL COMPANY ~ 35 W* DALLAS AT SHEPHERD O___RflX 134 VO HOUSTON TX 077219 MANUFACTURER PHONE NO: 71.3-474--3271 FMERG___ NjQl 300-424-9300 CHEMTREC CAS OR TRADE NO, 00556-52-5 CHEMICAL FAMILY: EPOXIDE FORMULA: C3H6Q2 EPA REPORTABLE G>TY: DQI ^HIPPTNG, NAMF-- _fiX jgp, N...QS DOT HAZARD CLASS: OXI SUBSIDIARY RISK: NOT 1, TSTFD________ UN I.D. NUMBER: ----- 1 479------------------- ALIAS: GLYCIDOL ***##********#********#***#*##***##**1^^#.#***#***####*#**#**#*##*####*######*#### ** *******************S**E*C*T*IO*N***1 *P**H*Y*S*IC*A*L**D**A*T*A*/H*A*Z*A*R*D*O*U*S***IN*G*R*E*D********************** BOILING POINT 0760MM HG 161 DEG * C VAPOR DENSITY (AIR=1) 2*15 SOLUBILITY (WEIGHTS IN WATER) COMPLETE FREEZING/MELTING POINT -54 DEGR* C* # EOR PRFSSURF: MMHG 8 25 DEGREES C VOLUME & VOLATILE 100% PH OF SOLUTIONS: NOT LISTED EVAPORATION. RATE.. N/A SPECIFIC GRAVITY (H20=1) ' 114 P 9T DP . r.______________ APPEARANCE AND ODOR: CLEAR AND ODORLESS LIQUID BULK DENSITY NDT I TSTPD____ HEAT OF SOLUTION NOT L TSTFD_________ INGREDIENT: GLYCIDOL MFIHYi__ til YCFRTNF % INGREDIENT: 95-99 DIGLYCIDYL ETHER _L=--------- CHLnRO-.GLXCERINE. 1*5 0-2 049659 SL ********#***#****#*#**#**##****# **#**#********# **#*#****#*#**# #***##**#***#* **** * SECTION 2 & 3 FIRE/EXPLOSION HAZARD DATA *#**#*****##**#*#********#****#**#****##**************##*#**#*.#**#********.* a.*#* FLASH POINT DEC F (METHOD USED) iQ2 DEGREES C TOC FLAMMABLE LIMITS IN AIRC% BY VOLUME) LEL. UEL: UNKNOWN UNKNOWN EXTINGUISHING MEDIA: WATER OR CHEMICAL FOAM SPECIAL FTBF FTGHTTNG PBfirFni IRF?: IF POSSIBLE IMMEDIATELY ISOLATE FROM FLAME* UNUSUAL FIRE AND EXPLOSION INFORMATION: AVOID CONTACT WITH ACIDS, METAL HALIDES. FIREFIGHTERS SHOULD WEAR SELF-CPMTAINFD BRFATHTNC APPARATUS. BASIS OR a#****##**#**#*####***##**#*#********##*#*###****##*#*##****#*#*#**#**#**#*##** * SECTION 4.1 HEALTH HAZARD DATA ft****************************************************************************** PERMISSIBLE EXPOSURE LIMITS: ACGIH TLV: GLYCIDOL - 25 PPM OSHA-PEL: GLYCIDOL - 50 PPM MFRS REC: NOT LISTED CARCINOGFNir.TTY STATUS fSHUPCF^ NATIONAL CANCER INSTITUTE BIOASSAY, RESULTS NOT YET PUBLISH ED (NCI-C55549) TQXICIIY DATA; FFFFr.TS nF nVERFXPOSURF, -EUL ACUTE OVEREXPOSURE: INHALATION - MARKED RESPIRATORY IRRITATION* INGESTION - MODERATE EFFECT. CDL LD50 IN RATS: 0*85 C/KG. ^IN-CONTACT,,,- GDI :____RFARTt Y ARSnRBFT) THROUGH SKTN. _________ __________________ CHEMICAL BURN. - DGE: IN MICE, NERVOUS EXCITATION FOLLOWED BY DEPRESSION EYE CONTACT - SEVERE IRRITATION BUT REVERSIBLE CHRONIC nVFRFXPnsilRF :_______________________ __ ____________________________________________________________ INHALATION - GDL; RESPIRATORY IRRITATION PROVIDES ADEQUATE WARNING DGE: SEVERE IRRITATION TO LUNGS INGESTION - GDL: NOT ESTABLISHED, CARCINOGENICITY TESTING IS IN PRQGRFSS (3) DGE; SEVERE INGESTION HAZARD SKIN CONTACT - GDL: NOT ESTABLISHED DGE: SEVERE HAZARD BY ABSORPTION. LONG-TERM REPEATED -----------------------------------------------------APPLICATION CAUSES SKIN CANCER IN RATS (1)______________ SL 04966 EYE CONTACT - NOT ESTABLISHED *************************#*************#*#**#*********#**********************-**- .**.***** ****** *****.*.*.*'S. EV.C*.T*.I*O.*N*.*.*4!.**.2*.**E.*.M*.E*.)R,.G*.*E.*N.*C.*Y,.*/.F*.I*R.*S.*T.*.*A!. ID PROCEDURE JNHALATION: iOT LISTED* EYE CONTACT: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER FOR AT LEAST 15 MINUTES. CONSULT PHYSICIAN, IF NECESSARY. SKIN ..CONTACT REMOVE CONTAMINATED CLOTHING, WASH AFFECTED AREA WITH SOAP AND WATER FOR AT LEAST 15 MINUTES. CONSULT A PHYSICIAN, IF NECESSARY. TREATMENT OF BLISTERS BY PHYSICIAN - DRAW OFF FLUID AVOIDING OTHER PARTS OF SK.IN, CQVFR-WTTB. 17 SILVER..SULFADIAZINE AND-STERIL--DRESS-XNG.--------------------------------INGESTION: Nni. 1 TSTFD NOTES TO PHYSICIAN (INCLUDING ANTIDOTES) NOT LISTED. ft************************************************************************* ***** *************************S*E*C*T*I*O*N**541*R*E*A*C*T*I*V*I*T*Y**D*A*T*A*********************** *******4 'ABILITY : ^STABLE IF PH (6 OR) 8 CONDITIONS TO AVOID: NOT L. TSTFD_________________ HAZARDOUS POLYMERIZATION: MAY OCCUR___________________________ ;__________________________________________ CONDITIONS TO AVOID: STORE AT 30 DEGREES F OR BELOW TO PREVENT POLYMERIZATION INCOMPATIBILITY (MATERIALS TO AVOID): AVOID CONTACT WITH STRONG ACIDS OR ALKALIS AND METAL HALIDESSUCH AS /f- .. '-v-V:' AM:; __ SL 049661 STANNIC AND FERRIC CHLORIDES HAZARDOUS DECOMPOSITION PRODUCTS: GLYGEEINE AND/OR ROLY CLYCIBOL FRQDUGTS. * SECTION 6 SPILL OR LEAK PROCEDURES ******* ************************************* it********************************* STEPS TO RF TAKEN TF MATFKTAI TS .VPTIIFD HR1 RFI FASF_D_:.................................................... ............................ CONTAIN AND RECOVER. HANDLE HASTE CONSISTENT WITH STATE REGULATIONS. SMALL QUANTITIES MAY BE CONVERTED TO CLYCERINE WITH LESS THAN 0.1% GLYCIDOL BY DILUTING INTO A TEN FOLD EXCESS OF WATER, ADJUSTING THE PH TO 4 OR LESS UTTH Sltt FHPTH APT!). AND At 1 nWTNfc TO -TTANP FftR TURFF DAYS_____&..XQUFR PH, -MORF____ WATER, AND HEAT WILL ACCELERATE THE PROCESS. WASTE DISPOSAL METHOD: DISPOSE OF BY INCINERATION. ******************************************************************************* ************************S*E#C*T*IO*N***7^1**S**P*E*C*I*AL *P*R*O*X*E*C*TO*N************** RESPIRATORY PROTECTION: NIOSH APPROVED RESPIRATORY PROTECTION OR ORGANIC VAPORS IF FIRE - WEAR SFI F-nONTAINFD KRFATHTNG APPARATUS FOR RFSCUF. ************************************************************************** ***** * SECTION 7.2 SPECIAL PROTECTON DATA **********tt****************;||li*L************IMMt*IMMMM***tttt*.lE**tttt VENTILATION(TYPE): LOCAL EXHAUST - USE LOCAL VENTILATION TO GFNFRA1. FXHAIIST - DO NlflT RFt Y ON KFNFRA1 REMOVE VAPORS AT THE SOURCE. FXHAUST_____________________________________ ' +; Mz , u,; -o. kVE PROTECTIONIHEMICAL GOGGLES -CLOVES^ IMPERVIOUS GLOVES flTHFR PROTECTTVF EHIITPMFNT,:_____________________________ _______ !___________ WEAR PROTECTIVE CLOTHING AS REQUIRED TO PREVENT SKIN CONTACT. " 1 :||M--r--------7"rr~-------------------- ' 1 Y-r" ^, - : ,v.-'I'' - . , ` "VA ;-:V ` . r. - , ,r , :!%S' "I , y* ' 1 1 ' -) as H.****************************************##***##*******#************************ ** ************************S**E*C*T*IO*N***8**1****S*P*E*C*IA**L**P*R*E*C*A*U*T*IO*N**S*********************** SPECIAL PRECAUTIONS AND COMMENTS: ^"TORE AT TO DECREES F OR BELOW TO PREVENT POLYNERIZATION CQNTRQLS AIR-BORNE AaPORS USUALLY NEAR OR LESS THAN DETECTABLE LEVELS OF t PPM. WRlPin TNHAJ ATTHN, SKTNAND EYE CONTACT, AND INGESTION.--------------------------------------------- ******************************************************************************** **************************S*E*C**TI*O*N**8***2**R*E*F*E*R*E*N*C*E**S*************************** *.*****..,* REFERENCES: NOT LISTED ******************************************************************************** **************************S**E*C*T*IO*N***8*.4***M*IS*C***IN*F*O**R*M*A*T*IO**N**************************** MISC INFORMATION: DOT HAZARD CLASS: OXIDIZER DSOHTIPPSIHNIGPPIrN.QGNTN.AATMNEF:n:___OnXnIDrIZnEnR NO* phi v5p&IM/_C_O__C__L_A__S__S___5_._11 PC, 5046 ___ tmmw y: V<> ' L` f!` ' $<v-' 049663