Document 9wRLvRkwJ1J0QjyeZzqZLE13

i t i i ; : INTEIliXAL ( OIUU SI'OXOi:\CE UNION CARBIDE CORPORATION CHEMICALS AND PLASTICS P. 0. BOX 3370, BROWNSVILLE, TEXAS 78520 To (Name) Company Location Copy to Operating Department Heads (4) /Ms. Rita Murphy K. G. Townsend/M. Gutierrez J. L. Garcia E. O. Davis A. G. Stephens A. L. Barefoot C. M. Partridge R. C. Glock C. A. Keil W. W. McManus Shift Superintendents (2) S. J. Footer Date June 23, 1975 Originating Dept. Answering letter date Subject Proposed Toxic Hazardous Substances Legislation OSHA - NIOSH, EPA Affecting Brownsville This document summarizes various government lists of chemicals that have been identified as hazardous substances or are scheduled for examination or regulations. Several have appeared as proposed regula tory materials in recent issues of the Federal Register. A list of the top 50 chemicals by usage is included in the belief that some of these will be targeted for investigation. Listed are those compounds which are used or produced at Brownsville. Although there has been some delay in proposal and formal enactment of regulations by the responsible agencies this should not be construed to indicate that regulations are npt forthcoming. Please give this document wide circulation and careful review. I will keep you informed of the proposed legislation as it appears. \ Very truly yours, LTW/gr Attachments L. T. Windel BRB 0568 CHEMICALS LISTED AS HAZARDOUS AIR POLLUTANTS WHICH AFFECT BROWNSVILLE 1. Asbestos 2. Mercury CHEMICALS LISTED AS TOXIC WATER POLLUTANTS WHICH AFFECT BROWNSVILLE 1. None CHEMICALS FOR WHICH STANDARDS HAVE BEEN PROMULGATED BY OSHA AND WHICH AFFECT BROWNSVILLE 1. Asbestos CHEMICALS FOR WHICH CRITERIA DOCUMENTS HAVE BEEN PUBLISHED BY NIOSH AND WHICH AFFECT BROWNSVILLE 1. Ammonia 2. Carbon Monoxide 3. Sulfuric Acid 4. Toluene BRB 0569 EPA* LIST OF CHEMICALS CONSIDERED HAZARDOUS WHEN SPILLED INTO WATER (BROWNSVILLE MATERIALS) PRODUCT FOUND IN (P)RODUCTION, (M)AINTENANCE Acetaldehyde P Acetic Acid P Acetic Anhydride P Ammonia P Butyl Acetate P Butyric Acid P Chlorine P Copper Acetate P, M (Heat exchanger cleaning) Formic Acid P Ferrous Sulfate (Tech Services - Note) Mercury M Nickel Acetate M Phosphoric Acid P Propionic Acid P Sodium Phosphate, All forms P Sulfuric Acid\ Toluene P P ^This advance notice of proposed rulemaking is issued under authority of Section 311 and- 501 of the Federal Water Pollution Control Act as amended (33 U. S. C, 1251 et. seq. ) BRB 0570 400 CHEMICALS FOR WHICH OSHA HAS ANNOUNCED INTENT TO PROMULGATE STANDARDS ( CHEMICALS FOUND AT BROWNSVILLE) PRODUCT DATE EXPECTED PRODUCTION, MAINTENANCE & LAB Acetone MEK Hydrogen Sulfide Aug, 74 Proposal Published Aug, 74 P. L P, L P, M Butyl Acetate(s) Ethyl Formate Methyl Acetate Propyl Acetate Butanol Isopropyl Acetate Jan. 75 Jan. 75 Jan. 75 Jan. 75 Feb. 75 Feb. 75 P, L P. L P, L P. L P. L P, L Isopropanol Feb. 75 L Methanol Ketene Feb. 75 April 75 P, L P Liquified Petroleum Gas April 75 Refrigerants 12, 21, 114 May 75 Ethanolamine\ Acetic Acid June 75 Aug. 75 Acetic Anhydride Aug. 75 Formic Acid Aug. 75 Sulfuric Acid Aug. 75 Copper Dusts Sept. 75 Mercury Oct. 75 P. L P, M P. L P, L P, L P, L P. L M M, L BRB 0571 400 CHEMICALS (Continued) PRODUCT DATE EXPECTED Nickel and Salts Oct. 75 Iodine Nov. 75 Carbon Black (Wacker) Dec. 75 Carbon Dioxide Dec. 75 Carbon Disulfide Dec. 75 Silica including Perlite Dec. 75 Hydrogen Peroxide 90% Feb. 76 Oil Mist, Mineral Feb. 76 Methyl Formate Mar. 76 Carbon Tetrachloride Mar. 76 Silica, Crystalline Mar. 76 Chlorine April 76 Phosphoric Acid April 76 Ammonia May 76 Carbon Monoxide May 76 Copper Fume May 76 Toluene Iron Oxide Fume Sodium Hydroxide Stoddard Solvent (Varsol) May 76 June 76 July 76 July 76 PRODUCTION, MAINTENANCE M, L L P P L P, M L P, M P. L L M, P P P, L P, L, M M P, M, L M P, M, L M BRB 0572 CHEMICALS MENTIONED IN SENATE-HOUSE TESTIMONY RELATING TO THE TOXIC SUBSTANCES CONTROL ACT (BROWNSVILLE PRODUCTS) Asbestos Boiler Cleaning Products Chromium Carbonates Chemical Reagents Chlorinated Hydrocarbons Chlorine Detergents Food Additives Mercury Nickel Phosphates Polyvinyl chloride Silica Caustic Soda Freon propellants Sodium Tripolyphosphates CHEMICALS LISTED BY EPA FOR EXAMINATION AS CANDIDATES FOR DESIGNATION AS TOXIC WATER POLLUTANTS (BROWNSVILLE PRODUCTS) Chromium A sbestos Lead Nickel \ BRB 0573 -TOP 50 PRODUCTS BASED ON 1973 PRODUCTION (USED AT BROWNSVILLE) 1. Sulfuric Acid 2. Oxygen 3. Ammonia 5. Sodium Hydroxide 6. Chlorine 8. Sodium Carbonate 11. Phosphoric Acid 15. Urea 17. Toluene 23. Hydrochloric Acid 28. Ethylene Glycol 30. Carbon Dioxide 34. Acetic Acid 40. Acetone 41. Ethanol 45. Aceti<^ Anhydride 49. Acetaldehyde * Regulations will most likely be promulgated on the "top 50" initially by the agencies. BRB 0574 INTERNAL COHItESPONRENCE UNION CARBIDE CORPORATION COATINGS MATERIALS DIVISION P. 0. BOX 3370, BROWNSVILLE, TEXAS 78520 To (Name) Company Location R. C. McDermott J. L. Wyatt Copy to M. Gutierrez D. R. Haley Date November 2, 1982 Originating Dept. Answering letter date Subject List of Teratogens and Carcinogens Found in Brownsville Plant One of the deficiency items listed in our recent Safety and Health Audit was the lack of an up-to-date list of teratogens in the nurse's office. To eliminate this deficiency the attached lists are being distributed to you. One list contains the names of chemicals found in the Browns ville plant that appear in the UCC Internal Exposure Standard List, also included. The first list indicates where the chemical is found in the plant, the amount of material at each location and the reason for being listed, i.e., toxicity, carcinogen or teratogen. The second list is, as aforementioned, the UCC Internal Exposure Standard List which contains various other information about the chemicals found in the Corporation. After review of these lists I recommend that this information be further distributed within the plant to comply with the Divisional requirement of informing employees of identified occupational health risks. KGT :mfw Attachment K. Gran Townsend (2) BRB 0464