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AIMSUL ANSUL 1NC0RP0RATD MARINETTE, Wi 54143-2542
ANSULITE 6% AFFF (AFC-3) MATERIAL SAFETY DATA SHEET ACCORDING TO 93/112/EEC
l _____ Identification of the Substance/Preparation and of the Company
Trade Name: Manufacturer/Supplier
Address: Prepared by: Phone: Fax: Internet/Home Page: Emergency Phone Number: Date of Issue:
ANSULITE 6% AFFF (AFC-3) ANSUL INCORPORATED One Stanton Street, Marinette, WI 54143-2542 Safety and Health Department 715-735-7411 715-732-3472 http://www.ansul.com CHEMTREC 800-424-9300 or 703-527-3887 February 2002
II. Composition/lnformation on Ingredients
Component
Wt. %
CAS No.
EINECS
Proprietary mixture of hydrocarbon surfactants,
s fluorosurfactants, inorganic salts, and water.
pC>FL-lt>7e Not otherwise specified:
>95
Not applicable
Listed
l c.'ffi'h ^ethylene Glycol Monobutyl Ether(a):
4
112-34-5
203-961-6
L ` >1 ^*Tertiary Butyl Alcohol(a):
0.2 75-65-0
200-889-7
AV9T
/
/j<..-
^ iHexylene Glycol;
(a ) This chemical is
subject
to
reporting
requirements
0.2
of SARA
Title
III
107-41-5
Section 313 and
40
CFR
203-489-0
Section 372.
Class, R, and S Phrases
(See Section XV) (See Section XV) (See Section XV) (See Section XV)
III. Hazards Identification
For Humans
Threshold Limit Values:
Diethylene Glycol Monobutyl Ether:
ACGIH TLV-TWA OSHA PEL (General Industry) 8 hour TWA: Tertiary Butyl Alcohol:
ACGIH TLV-TWA OSHA PEL (General Industry) 8 hour TWA: Hexylene Glycol:
ACGIH TLV-CL
600 ppm. 000 ppm (2950 mg/m3).
100 ppm. 100 ppm (1900 mg/m3).
25 ppm.
Signs and Symptoms: Acute Exposure: Eye Contact: Inhalation: Skin Contact: Ingestion: Chronic Overexposure:
May cause mild to moderate transient irritation. Not an expected route of entry. May cause mild transient irritation and/or dermatitis. Irritating to mucous membranes. Large oral doses could produce narcosis. Kidney, liver, gastrointestinal, and spleen.
Medical Conditions Generally Aggravated by Exposure: Prior diseases of the kidney and liver.
Chemical Listed as Carcinogen or Potential Carcinogen:
National Toxicology Program [x] No
I.A.R.C. Monographs |x) No
For Environment:
(See Section XII).
OSHA (x] No
WHMIS Information:
D2B - Product may irritate skin or mucous membrane.
IV. First-Aid Measures
Inhalation: Eye Contact: Skin Contact: Ingestion:
Remove victim to fresh air. Seek medical attention if discomfort continues. Flush with large amounts of water. If irritation persists, seek medical attention. Wash thoroughly with soap and water. If irritation persists, seek medical attention. If patient is conscious, give large amounts of water and induce vomiting. Seek medical help.
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ANSULITE 6% AFFF (AFC-3) (Continued)
V _____ Fire-Fighting Measures_______________________________
Extinguishing Media: Special Procedures: Unusual Fire and Explosion Hazards:
THIS IS AN EXTINGUISHING AGENT. None. None.
Page 2
VI. Accidental Release Measures
Personal Precautions: Respiratory Protection: Hand Protection: Eye Protection: Skin and Body Protection:
(See Section VIII) (See Section VIII) (See Section VIII) (See Section VIII)
Clean up Precautions: Waste Disposal Methods:
Stop leaks. Contain spill. Remove as much as possible. Place in closed container for proper disposal. Wash spill area with large amounts of water to remove traces as material is very slippery. Prevent material from reaching sewers or waterways to avoid nuisance foaming.
(See Section XIII)
VII. Handling and Storage
Handling: Storage:
Avoid skin and eye contact. Avoid ingestion. Do not mix with other fire fighting agents. See incompatibility information in Section X.
Store in original container. Keep tightly closed.
VIII. Exposure Controls/Personal Protection
Respiratory:
Hand: Eye: Skin and Body: Other:
None expected to be needed. Mechanical ventilation is recommended. Rubber or latex gloves are recommended. Chemical goggles are recommended. Standard fire fighting safety equipment should provide all protection which is necessary.. Eye wash and safety showers are good safety practices.
IX. Physical and Chemical Properties
Appearance: Color: Odor: Specific gravity (H20 =1): Solubility in Water: pH (If in water, % Cone.): Boiling Point: Vapor Pressure (mm Hg): Vapor Density (Air =1): Evaporation Rate
(Butyl acetate =1):
Percent volatile by volume (%): Flash Point: Flammable limits in Air
(% by volume): Autoflammability: Explosive Properties: Oxidizing Properties:
Clear Liquid. Straw yellow. Mild sweet odor. 1 .02. Miscible. Not determined 97 C. Not determined <1.
0.46. ca. 94. None to boiling.
Not applicable. Not applicable. None. None.
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ANSULITE 6% AFFF (AFC-3) (Continued)
Page 3
X. Stability and Reactjyity
Stability:
1
Conditions to Avoid:
Hazardous Reactions:
Conditions to Avoid: Materials to Avoid:
.1
Hazardous Decomposition Products:
Stable |x]
Unstable
None known.
Will not occur [x]
May occur
None known.
Any material reactive with water, electrically energized equipment, or strong oxidizers.
Not known, however, oxides of nitrogen and sulfur may be produced during fire conditions.
XI. Toxicological Information
Product: The toxicity of the product mixture has not been determined.
Components:
Diethylene glycol monobutyl ether:
Irritation Data:
Eye (rabbit)
20 mg/24 hrs Moderate
Toxicity Data:
Oral (rat) LD50
5660 mg/kg.
Dermal (rabbit) LD50 2700 mg/kg.
Target organs:
Kidney, lungs, gastrointestinal, spleen.
Tertiary butyl alcohol:
Irritation Data:
Skin (rabbit)
500 ul/24 hrs Mild.
feye (rabbit)
100 ul/24 hrs Severe.
Toxicity Data:
6 ral (rat) LD50
2743 mg/kg
Inhalation (rat) LC50 >10,000 ppm/4 hrs
Target organs:
Liver, skin.
Hexylene glycol:
Irritation Data:
Skin (rabbit)
465 mg/24 hrs Moderate.
Eye (rabbit)
93 mg Severe.
Toxicity Data:
Oral (rat) LD50
3700 mg/kg
Inhalation (rat) LC50 >310 mg/m3/1 hr.
Target organs:
Sense organs, lungs, kidney.
XII. Ecological Information
Mobility:
Absorption/Desorption:
Degradability:
Biotic and Abiotic Degradation:
Aerobic and Anaerobic Degradation:
Persistence:
Accumulation:
Bioaccumulation Potential:
Biomagnification:
Short and Long Term Effects on:
Ecotoxicity:
Aquatic Organisms:
Soil Organisms:
Plants and Terrestrial animals:
Other Adverse Effects:
Ozone Depletion Potential:
'
Photochemical Ozone Creation Potential:
Global Warming Potential:
,
Effects on Waste Water Treatment Plants:
Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined.
Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined. Not determined.
XIII. Disposal Considerations Dispose of in Compliance with local, state, and national regulations.
XIV. Transport Information____________________
Hazard Class or Division:
Not hazardous.
For additional transport information, contact Ansul Incorporated.
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ANSULITE 6% AFFF (AFC-3) (Continued)
Page 4
:i XV. Regulatory Information
Product:
EU Classification:
Xi.
Irritant.
R Phrases:
36 !
Irritating to eyes.
S Phrases:
26 "
In case of contact with eyes, rinse immediately with plenty of water and seek medical
attention.
36 ;
Wear suitable protective clothing.
Components:
J
Diethylene Glycol Monobutyl Ether:
EU Classification: Xi. ..
Irritant.
R Phrases: 36 Irritating to eyes.
S Phrases:
26 :
In case of contact with eyes, rinse immediately with plenty of water and seek medical
attention.
36 . Wear suitable protective clothing.
Tertiary Butyl Alcohol:
EU Classification: F, Xn.
Highly Flammable, Harmful.
R Phrases: 11 Highly flammable.
20 Harmful by inhalation.
S Phrases: 9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
Hexylene Glycol:
EU Classification: Xi. ,
Irritant.
R Phrases:
36/38
Irritating to eyes and skin.
S Phrases:
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
attention.
36 Wear suitable protective clothing.
Limit Values for Exposure:
Diethylene Glycol Monobutyl Ether:
ACGIH TLV-TWA
600 ppm.
OSHA PEL (General Industry) 8 hour TWA: 1000 ppm (2950 mg/m3).
Tertiary Butyl Alcohol:
ACGIH TLV-TWA
100 ppm.
OSHA PEL (General Industry) 8 hour TWA: 100 ppm (1900 mg/m3).
Hexylene Glycol:
ACGIH TLV-CL
25 ppm.
EINECS Status:
All components are included in EINECS inventories.
Restrictions on Marketing and Use: None
Refer to any other national measures that may be relevant.
XVI. Other Information , None known.
XVII. Disclaimer
::
' IT " ------------------------ --------------------------------- --------------
THE ABOVE INFORMATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORT TO BE ALL INCLUSIVE AND
SHALL BE USED ONLY AS A GUIDE. ANSUL SHALL NOT BE HELD LIABLE FOR ANY DAMAGE RESULTING FROM
HANDLING OR FROM CONTACT WITH THE ABOVE PRODUCT.
MSDS available at http://www.ansul.com
ANSUL is a trademark of Ansul Incorporated orde affiliates. ANSUL INCORPORATED, ONE STANTON STREET: MARINETTE, W l 5 4 1 4 3 -2 5 4 2 715-735-7411
Form No. F-S746-1
20Q2Ansullncorporated
Lltho in U.S.A.
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