Document 9NBrgqnyR6EXDLmevqgYQny3
Precise Research. Proven Results.
Enclosure 5
Analytical Report
Fluorochemical Characterization of Water and Sediment Samples
Decatur Bakers Creek #2 -July 2003 (E03-0561) Exygen Research Laboratory Report No. L34910 Revision 1
Testing Labora tory Exygen Research
3058 Research Drive State College, PA 16801
Requester Jess Eldridge 3M Environmental Technology and Safety Services 935 Bush Avenue Building 0002-03-E-09 PO Box 33331 ST. Paul, MN 55133-3331
000010
State College, PA 16801, USA
7 introduction
Results are reported for the analysis of surface Exygen Research (Exygen) from Pace Analytical. project is L34910.
water and sediment samples received by The Exygen study number assigned to the
Specific fluorochemical characterization by liquid chromatography / tandem mass spectrometry (LC/M!YMS) was requested for all samples. A total of 26 samples were received for analysis.
The samples were prepared and analyzed by LC/MS/MS for the following list of fluorochemicak:
l Table 1: Target Analysis
Comwund Name Perfluorohexanesulfonate Perfluorooctanesulfonate . Perfluorooctanoic Acid _ Perfluorocctanesulfonvlamide
Acronvrn C6 Sulfonate fPFHS) C8 Sulfonate (PFOS) C8 Acid (PFOA) FOSA
The analytical methods used were originally developed for groundwater samples and were validated by Exygen. The validation protocol and results are on file with Exygen. Only the C8 Sulfonate, FOSA, and C8 Acid were included in the original method validation. It should be noted that the quality control elements included in this analysis demonstrate the applicability of the method to the additional analytes.
2 Sample Receipt
The samples were submitted in plastic containers. All samples were cooled to 4'C from time of collection to receipt at Exygen Research. Samples were stored at 4% from receipt at Exygen Research until analysis. Samples were collected on 7/21/03 and 7/23/03. Chain-ofcustody information is presented in Attachment C.
3 Holding Times
Field and laboratory spikes of these fluorochemicals have shown stability for periods greater than 90 days. Samples were analyzed within 30 days of receipt.
PAGEZoF5
uw011
4 Methods -Analytical and Preparatory
4.1 LC/MS/MS
4.1.1 Sample Preparation for LC/MS/MS Analysis
Water samples were initially treated with 200 UL of 250 mg/L sodium thiosulfate solution to remove residual chlorine. Solid phase extraction (SPE) was used to prepare the samples for LC/MS/MS analysis. A forty-milliliter portion of sample was used for analysis. The samples were transferred to a Cl8 SPE cartridge. The cartridge was eluted with 5 mL of 100% methanol. This treatment resulted in an eight-fold concentration of the diluted samples prior to analysis.
Sediment samples were first extracted into methanol (5 grams of sediment to 5 mL of methanol). The methanol extract was diluted to forty-milliliters and treated in the same manner as the water samples, using SPE.
4.1.2 Sample Analysis by LC/MS/MS
In HPLC, an aliquot of extract is injected and passed through a liquid-phase chromatographic column. Based on the affinity of the analyte for the stationary phase in the column relative to the liquid mobile phase, the analyte is retained for a characteristic amount of time. Following HPLC separation, ES/MS provides a rapid and accurate means for analyzing a wide range of organic compounds, including fluorochemicals. Electrospray is generally operated at relatively mild temperatures; molecules are ionized, fragmented, and detected. fans characteristic of known fluorochemicals are observed and quantitated against standards.
A Hewlett-Packard HP1 100 HPLC system coupled to a Micromass Ultima MS/MS was used to analyze the sample extracts. Analysis was performed using selected reaction monitoring (SRM). Samples extractions and analyses were performed between 7/31/03 and 8/13/03. Exact dates for extraction and analysis of each sample batch are given in the raw data. Raw analytical data is provided in Attachments D and E.
5 Analysis
5.1 Calibration
A 7-point calibration curve was analyzed at the beginning and end of the analytical sequence for the compounds of interest. The calibration points were prepared at 0, 25, 50, 100, 250, 500, and 1000 ngR (ppt) for LC/MS/MS analysis. The instrument response versus the concentration was plotted for each point. Using linear regression with l/x weighting, the slope, y-intercept and correlation coefficient (r) and coefficient of determination (?) were determined. A calibration curve is acceptable if r 20.985 (rc?~0.970).
Calibration standards are prepared using the same SPE procedure used for samples.
Calibration check standards were analyzed periodically (every three to five sample injections) throughout the analysis sequence. Compliance is obtained if the standard analyte concentrations are within +/-20% of the actual value.
All calibration criteria were met for this analysis.
PAGE3UF5
000012
5.2 Blanks
Extraction blanks were prepared and analyzed with every extraction batch of samples. The extraction blanks should not have any target analytes present at or above the concentration of the low-level calibration standard. For these samples, the extraction blanks were compliant.
instrument blanks in the form of clean methanol solvent were also analyzed after every highlevel calibration standard, and after known high-level samples. Again, the blanks should not have any target analytes present at or above the low-level calibration standard. For the samples presented here the instrument blanks are compliant.
5.3 Surrogates
Surrogate spikes are not a component of the LCNNMS analytical methods.
5.4 Matrix Spikes
Field matrix spikes were prepared at low and high levels for each sample for all compounds of interest. Single laboratory matrix spikes were also performed for each sample. Laboratory control spikes (see section 5.6) consisting of laboratory water spiked at the time of extraction were performed with each analytical set. Matrix spike recoveries are given in Attachment B. For sediment samples, recovery is calculated from the amount present in the sample extract. Please see Section 5.7 for additional discussion of matrix spike recoveries.
5.5 Duplicates
Field and laboratory duplicates were performed for each sample. The duplicate results are included with the sample results in Attachment A.
5.6 Laboratory Control Samples
For LCIMSNS analyses, Milliq water was spiked with all compounds with each extraction set. All recoveries for all compounds were between 70-130% in each LCS. Results are given along with the raw data in Attachment D.
5.7 Statement of Accuracy
Based on results of field spikes, laboratory spikes, field blank spikes, and laboratory control spikes, the analytical accuracy for all compounds is + 30%. Exceptions for the water samples are as follows: BC2 SW-04 high spike (PFOA - 57%, PFOS - 62%, FOSA - 58%). BC2 SW05 high spike (PFOA - 66%, FOSA - 40%), BC2 SW-66 high spike (FOSA - 60%) Outfall to River SW-25 (FOSA - 58%). Also, several low spike samples showed unacceptable recoveries in cases where the spiking concentration was comparable or below the inherent sample concentration. However, all laboratory control spikes, laboratory matrix spikes, and all other field spikes showed recoveries between 70% and 130% for all compounds.
The accuracy for the sediment samples is based upon laboratory spike recoveries, all of which were between 70% and 130% for all compounds.
6 Data Summary
Please see Attachment A for a detailed listing of the analytical results. Results are reported in parts per billion (ppb) (@ml) for the water samples. Sediment samples are also reported in units of parts per billion (ppb) (rig/g). Sediment results are reported on both an as-received and dry-weight basis.
PAGE4ffS
000013
7 Da t&le Retention
Samples are disposed of one month after the report is issued unless otherwise specified. All electronic data is archived on retrievable media and hard copy reports are stored in data folders maintained by Exygen.
8 Attachments
8.1 Attachment A: Results 0.2 Attachment B: Matrix Spike Recoveries
a.3 Attachment C: Chain of Custody
8.4 Attachment D: Raw Analytical Data (Surface Water Samples) 8.5 Attachment E: Raw Analytical Data (Sediment Samples)
9 Signatuies
Paul Connolly, Team Leader - L&MS
Date
Date
Other Lab Members Contributing to Data Karen Rlsha
PAGE5oF5
oc)oo14
SECTION A
000015
pQfgM!iH Precise Research.
Proven Results.
Summary of PFOA, PFHS, PFOS and FOSA in Water Samples
Sample ID
Em SW-04 BC2 SW-04' i3C2, SW-04 Dup BC2 SW-05 BC2 SW-05' BC2 SW-05 Dup BC2-SW-06 BC2-SW-06' BC2-SW-06 Dup Outfall to River SW-25 Outfall to River SW-25' Outfall to River SW-25 Dup Equipment Blank-Pump Equipment Blank-Dredge ... Field Controlflravel Blank
Analyte C8 Acid PFOA
Perfluorooctanolc Acid
4.21 4.21 2.54 0.591 0.616 1.56 12.1 12.3 11.6 15.8 16.0 14.4 ND ND ND
Found
(ng/mL) C6 Sulfonate PFHS
Perfluorohexanesulfonate
0.896 0.882 0.571 0.155 0.152 0.377 6.06 6.30 5.87 7.66 7.10 6.77
ND ND ND
Sample ID
BC2 SW-04 BC2 SW-04' BC2 SW-04 Dup BC2 SW-05 BC2 SW-05* BC2 SW-05 Dup BC2-SW-06 BC2-SW-06" BC2-SW-06 Dup Outfall to River SW-25 Outfall to River SW-25' Outfall to River SW-25 Dup Equipment Blank-Pump Equipment Blank-Dredge Field Control/Travel Blank
Analyte ,$8 Sulfonate PFOS
Perfluorooctanasulfonate
11.5 : 11.5
8.25 -1.67 1.54 4.33 26.1. 26.7 25.1 31.2 31.5 30.8 ND ND ND
Found (ng/mL) FOSA
Perfluorooctsnesulfonylamide
1.39 1.37 0.790 0.146 0.150 0.389 2.43 2.30 2.57 3.26 3.18 3.28
ND ND ND
ND=Not Detected=Response NQ=Not Quantifiable=Response *Laboratory Duplicate
between 0 and 0.025 nglmL between 0.025 ng/mL and LOQ (0.05 ng/mL)
000016
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Oooolr
gyg@L Precise Research.
,, Proven Results.
Summary
sul1m`*$
of PFOA, PFHS, PFOS and FOSA In sb/ll Samples
Sample ID
BC2 SED-04
BC2 SED-04
BCti-SED-05 BC2kED05* BC2-SED-06 BC2-SED-06' Outfall to River SED-25
Outfall lo River S@-25'
Outfall to River SED-25 Dup
Analyte Found (rig/g, as received) Ead44 5
C8 Acid PFOA
C6 Sulfonate PFHS
Perfluorooctanolc Acfd
Perfluorohexanesulfonate
3.02
0.566
2.14
0.413
5.14
1.45
4.41
1.75
14.2
2.46
13.6
2.61
10.7
3.19
7.59
2.26
17.7
4.98
Sample ID
BC2 SED-04 BC2 SED-04' BC2 SED-05 BC2 SED-05' BC2-SED-06 BC2-SED-06' Outfall to River SED-25 Outfall to River SED-25' Outfall to River SED-25 Dup
Analyte Found C8 Sulfonate PFOS
Petfluorooctanesulfonate
14.6 11.9
`..
22.8
25.0
880
. . 992 `,. 107
72.1
140
(rig/g, as received) FOSA
Perfluorooctanesulfonylamlde
7.15 7.84 7.86 12.1 71.4 83.2 28.0 23.5 35.7
N&Not Detected=Response NQ=Not Quantifiabledesponse 'Laboratory Duplicate
between 0 and 0.2 rig/g between 0.2 rig/g and LOO (0.4 y/g)
00003B
State College, PA 16801, USA F: 814.231 .1580 exygen.com
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Upon request. Exygen WI/I provide xrd ship apptopri.tte satnple wtttriwt~ to clients. l'hese containers wtll Include the appropriate preservative tf particular analyses requtre one. It IS the tesponsibtltty ot the citent to hnnd:c these preserved contatners safely. ancl using Lull approprialt safety precauttons Clients requesting overnight delivery ot sample containers will be InvoIced for freight. Euygen reserves the rtght to charge `1 fee for sample contattlers
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-.
"---_ --
--..
000019
Proven Results.
Summary of PFOA, PFHS, PFOS and FOSA in@ Samples
Sample ID
BC2 SED-04 BC2 SED-04' BC2-SED-05 BC2 SED-05' BCP-SED-06 BC2-SEDGG' Outfall to River SED-25 Outfall to River &D-25' Outfall to River SED-25 Dup
Analyte Found C8 Acid PFOA
Perfluorooctanolc Acid
4.31
3.06 7.39 6.34 23.6 22.5 16.9 12.0 26.2
(nglg, dry weight) C6 Sulfonate PFHS
Petfluorohexanesulfonate
0.809
0.591 2.09
2.51 4.08 4.33 5.05 3.57 7.39
Sample ID
BC2 SED-04 BC2 SED-OC BC2 SED-05 BC2 SED-05' BCP-SED-06 BC2-SED-06 Outfall to River SED-25 Outfall to River SED-25' Outfall to River SED-25 Dup
Anaiyte Found C8 Sulfonate PFOS
Perfluorooctanasulfonate
20.9 17.0
32.8 36.0
1460 1640 169
.,114 208
(rig/g, dry weight) FOSA
Perfluorooctanesulfonylamlde
10.2 11.2 11.3 17.4 118 138
44.3 37.2 52.9
ND=Not Detected=Response N&Not Quantifiable=Response `Laboratory Duplicate
between 0 and 0.2 rig/g
behveen 0.2 rig/g and LOQ (0.4 q/g)
000020
State College, PA 16801, USA F: 814.231.1580 eqgen.com
STANDARD TERMS AND CONDITIONS
Services provided by Exygen Research are limited to the terms and conditions stated herein, unless otherwise agreed to in a formal contract.
_-_._.
-I__
_
.
.
._-.
..L
-
SECTION B
000022
!!qgtxL Precise Research.
Proven Reds.
Recovery
Summary
lor PFOA, PFHS, PFOS and FOSA In Water
Slmpl* DalErlplian
Amount Spiked
CBAcldPFOA
AmtFound
AlllCUllI
InSempla
Recovsnd
Rocowr
BCZ SW-04 Lab sprrs
5
4.21
9.14
79
5
0.696
BC2 SW-04 LOW spike Bc2 SW-04 HlQh Splk. Pa02 SW-05 Lab Sp4lia 002 SW-05 Low spIti*
0.1
4.21
10
4.21
5
0.591
0.1
0.591
2.76
-1450'
0.1
0.896
9.92
57
10
o.as6
4.96
87
5
0.165
2.17
1579'
0.1
0.155
EC2SW-05H1~Spikn
10
0.591
7.21
66
10
0.155
SCZSWQGLabSpika.
5
12.1
17.6
114
5
6.06
BC2SW-CSLwS~ke
0.1
12.1
13.9
1600
0.1
6.06
BC2SW.OSHiph
Spike
10
121
24.2
121
10
6.06
OuUslltoRlverSW-25LebSpl~ OulfPlltoRivWSW-25LaS@k~
5
15.8
22.1
126
6
7.66
0.1
15.8
15.0
.a00
0.1
7.66
Duusl(loRwr
SW-25"i9kS@ks
10
15.8
26.2
lo4
10
7.66
fleldCalbdlTravelBlankLwSpks
0.1
NO
0.114
114
0.1
NO
Field Cmlrob'l'ravsl
Blank Hi,,h Spike
10
ND
11.9
11s
10
ND
6.52
92
0.647
-249
9.73
aa
5.00
97
0.607
452
9.58
94
11.6
115
7.11
1050
17.4
113
12.2
91
6.64
-1020'
la.1
104
0.119
119
10.8
108
ca SUIfMe1C PFOS
haunt
AmI Found
Amount
5plbd
InSampt@
Rscowmd
Recovr~
Ut~Punl Spiked
AmtFaund lnt%mpto
FOSA Atnoun
Resowred
Recover
Bc2sw41LabspJlP
5
11.5
q C2SW-OILowS~ke
0.1
11.5
BC2Sw.o4HIghSol!u
10
11.5
BC2SW05LabSplk~
5
1.67
EC2SW05LowSpke BC2SW.O5Hi@tSpik~
0.1
1.67
10
1.67
BC2SW06LabSplke
25
26.1
6C2SW-C6LwSp~ka
0.1
26.1
6C2Sw-C6MphSpika
10
26.1
oUfta"loFfiww
SW.25 LnbSplks
50
31.2
ouaant0RivwSW.25LowSpikE
0.1
31.2
OuUdl IO Rlvar SW-25 Hiph Splks
10
31.2
FMd Canlr~rav~
Blank La* SPtks
0.1
ND
Nkl ConfrWTrw.1 B(mk High Spike
10
NO
17.1
112
5
1.39
6.69
-4610
0.1
1.39
17.7
62
10
1.39
5.94 '
65
5
0.146
5.37
3703'
0.1
0.146
12.8
111
10
0.146
49.8
95
6
2.43
32.1
6mO'
0.1
2.43
43.9
178
10
2.43
80.9
9?3
5
3.26
29.4
.iaoo-
0.1
3.26
41.2
100
10
3.26
0.109
109
0.1
ND
11.4
114
10
ND
5.58
a4
0.672
-718.
7.18
sa
4.66
94
0.496
35.2
4.14
40
7.18
95
2.55
120'
a.44
60
7.97
94
2.66
-600'
9.02
58
0.0895
SC
11.9
119
3058 Research Drive Cokge, PA 16801, USA
F: 814272.1019 exygen.com
pQq$x!"CH ,Precise Research.
`, Proven Results.
Recovery Summary for PFOA, PFHS, PFOS and FOSA in Soil
CB Acid PFOA
CB Sulfonate PFHS
BC2 SED-04 Lab Spike
40
3.02
41.5
96
40
0.566
42.2
104
EC2 SED-05 Lab Spike
40
5.13
43.7
96
40
1.46
44.2
107
EC2 SED-06 Lab Spike
40
14.2
49.4
88
40
2.46
44.5
105
Outfall to River SED25 Lab Spike
40
10.7
47.1
91
40
3.19
44.5
103
CB Sulfonate PFOS
FOSA
I
EC2 SED-04 Lab Spike
BC2 SED-05 Lab Spike
40
14.6
40
2T.8
BC2 SW-06 Lab Spike
800
880
Outfall to River SW-25 Lab Spike
40
107
51.8
93 I 40
7.15
61.0
95
40
7.86
1720
105
800
71.4
153
114
40
28.0
Results reported on an as-received basis
46.5
98
48.1
101
650
72
59.0
77
000024
State College, PA 16801, USA T: 800.2813219 F: 814.272.1019 exygen.com
SJ-CTION C
000025
Required
""mz;"'
Clint Infonllatim:
fcks s.
Section E I ddq,
CHAIN-OF-CUSTODY / Analytical Request
The Chain-of-Custody IS 6 LEGAL DOCUMENT: All relevant
fields must k completed
Document
eccurirtely.
B
Page:
/ of 52,
Ctiint lnlormation
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quotelcontract): `TAT:
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To Be Completed by PaoeAnatytttd and Uient Section C
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Pmjmzl Manager:
Iiiil
r-----.IA-~Z-I-. Q-9-.' I -I I
,Ir;l;C.;N; V
,u
I
I
Sample IDS MUST BE UNIQUE
AIT
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I
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WLE
CONDITION
SAMPLE NOTES
_
- l- - l- -
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-
bi-t-'..,
`. :+:. -
T
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712112003 lof3
3M ENVIROl'lMENT~
LAJ3QRATORY
`J
Pretimhry/Unautl~o~
Report
Project: E03-0561
Requester: Schnobrich. Dana M (223-lN-08) Department: 5307 11 Project Number: 0022674449 Date Received: 6/26/2003 Project Description: Decatur Bakers Creek Comments:
#2 Surface
Water
and Sediment
proiect Results/Activity Pace Field Samphng Event
Completion Date:
project Lead: Jess S. Eldridge
Phone Number 65 l-778-5233
Email Address: jseldridge@mmm.com
Yna Kc IJbe --
dJ tit>
@I\ w ~u-1~ ~7
fag pr,+ p&y* e-- -f--Q psoisf
- .-
mdistjw>
3M Sample Numiw
* SampledDate
E03-0561-49786
l/22/2003
EXYGEN EXYGEN EXYGEN EXYGEN
E03-0561-49787
hpalvtical Method PFOS by ESMS PFHS FOSA PFOA
7/22'2003
EXY `ZEN
%f
EXYGEN
EXYGEN
PFOS by ESMS PFHS FOSA
EXYGEN
PFOA
E03-0561-49788
7/u/2003
i$dl EXYGEN EXYGEN EXYGEN
EXYGEN
E03-0561-49789
PFOS by ESMS PFHS FOSA PFOA
7l22/2003
EXY GEN EXYGEN EXYGEN EXYGEN
E03-0561~49790
~oalvtlcd Method PFOS by ESMS PFHS FOSA PFOA
7i2z2003
LAB EXYGEN EXYGEN EXYGEN EXYGEN
E03-0561-49791
~nrlvtical Method PFOS by ESMS PFHS FOSA PFOA
7l22L2003
L&i
w
EXYGEN
j4nrlvtlclll w PFOS by ESMS
EXY GEN
PFHS
EXYGEN
FOSA
sample De3criptlon
BC2 SW-04
ComDoaents PFOS PFHS FOSA PFOA
BC2 SW-04 DUP
PFOS PFHS FOSA PFOA
BC2
SE&O4
Qmoonenb PFOS PFHS FOSA PFOA
BC2
SW-05
PFOS PFHS FOSA PFOA
BC2 SW-OS DUP
ComDonenta PFOS PFHS FOSA PFOA
BC2 SED-05
ComDonenta PFOS PFHS FOSA
B!d
9uelifie~
RL
Oullilicr
BL
Oullincc
u00028
3M IDMRONMENTAL
LABORATORY
Preliminary/LJnauthoriwdReport
Project: E03-0561 (ant.) 3M SampleNumber
303-056349791 (cont.)
sampled Date 71'22/2003
Sample Description BCZ SED-05
AkAB EXY GEN
&&yticr1 w PFOA
E03-0561-49792
PPOA BC2 SW-06
La&
EXY GEN EXY GEN EXYGEN EXYGEN
E03-0561-49793
Aaalvtical Method PFOS by ESMS PFHS FOSA PFOA
7izz2003
Comlloaeats PFOS PFHS FOSA PFOA
BC2 SW-06 DUP
EXYGEN EXYGEN EXYGEN EXYGEN E03-0561-49794
,hrlvticrl Method PFOS by ESMS PFHS FOSA PPOA
7im2003
PFOS PFHS FOSA PFOA
BC2
SED-06
EXY GEN
~nalvtical Method PFOS by ESMS
EXYGEN
EXYGEN
-
EXYGEN
PFHS FOSA PFOA
E03-0561-49795
7Lzzr.m3
PFOS PFHS FOSA PFOA
Outfall
to River SW-25
EXYGEN EXY GEN EXYGEN EXYGEN E03-0561-49796
l4AE EXYGEN EXYGEN EXYGEN EXYGEN E03-0561-49797
hpdlvtical lk@&fj PFOS by ESMS PFHS FOSA PFOA
7moo3
&@tical Me&&d PFOS by ESMS BFHS FOSA PFOA
7i2mw3
ComPonents PFOS PFHS FOSA PFOA
Outfall
to River SW-25 DUP
PFOS PFHS FOSA PFOA
Outfall
To River SED-25
EXYGEN EXY GEN EXYGEN EXY GEN E03-0561-49813
PFOS by ESMS PFHS FOSA PFOA
7LnROQ3
$hmoom
.-
PFOS
PFHS
FOSA
PFOA
Outfall to River SED-25 DUP
EXYGEN
EXYGEN
w
EXYGEN
EXYGEN
&slvtlcal MetboQ PFOS by ESMS PFHS FOSA PFOA
Crm PFOS PFHS FOSA PFOA
BuvLt
2 of3
4i!d
Qualifier:
I&!
OIllliricr
EL
Qualifier
Iad
Qualifier
4%
ad
Oualllicr
k!i
Qunllfler
000029
3M ENWROlVMENTAL PrenmblaryNnautbor
LABORATORY Report
Projea: EO3-0561 (cont.) 3M Sample Number
E03-0561-59479
Sampled Date
sample Descriptioo Field ControYrravel Blank
EXYGEN EXYGEN EXY GEN EXY GEN E03-0561-59480
PFOS by ESMS PFHS FOSA PFOA
C,msoocnrr PFOS PFHS FOSA PFOA
Equipment
Blank - Pump
EXY GEN EXYGEN EXY GEN EXYGEN
E03-0561-59481
PFOS by ESMS PFHS FOSA PFOA
Q&&J&g& PFOS PFHS FOSA PFOA
Equipment
Blank - Dredge
LAB EXY GEN
EXYGEN EXYGEN EXYGEN
cal M&t@ PFOS by ESMS PFHS FOSA PFOA
-oonenQ
PFOS PFHS FOSA PFOA
000030
W' Laboratory Sample Log-in Sheet (Environmental)
Comcrlete upon ample receipt:
Client andror Project Name
Method ot Delivery
0 Walk-in Tracking r:
a Pick-up YY/nv~
JM
Gm*nk
0 UPS zrfi
L/'
j'
d FedEx. `. r:,
Cl AlrBome
.
0 Other (explain)
Chain of CUStOdy
Temperature Preservation
Custody Seals: intact / 0 broken [explain)
~~~~~ter'>72%F
Cooler ID: Coder ID: 5 Cool& ID:
Coolertemp:
1. 7 *C
Cooler temp: -*c Cooler temp: -"C
Cooler temp: -
OC
Chain of Custody &resent
cl absent
Record: I
sBmpw~i~~e,t
0 with ice pack U none
Completed hy
Complete durfn
LIMS Log-in #
Physical Condition
Chain of cusbdy
Analysis Request
Preservation
/ / l
Signature:
Samples intacf? Samples received agree with COC record7 AAlysis request clear7 Sample containers appropriate? Chemical preservation appropriate? Samples received within holding time? Sample volume/mass adequate?
Explanation
Completed by
Signature:
Complete tollou 9 resolution of any nonconformances:
Slient Zoritacted
Cl Yes client:
lesolution
Date flme):
I /
L/ 2f c 7 /c d
0 No (explaii)
-06
.O No (explain)
0 No (explain)
a Yes
0 Yes Cl Yes 0 Yes
Cl No (explain) 0 No (explain) Cl No (explain) 0 No (explain)
/ /
I Date (Time):
Completed by
Signature:
Date:
Lab Sx Log-in Sheet -Ex
:
.
"
" .:. `.
: .:
..
1,:
`. .:
: _" :.
:. . .
.:_`.
. : ,,' .' 1:
`. .I:
:
`.
: . .
" : ., `. : -: ,' : `., ...
. : : .: : .
`.
LOGIN Account:
CHAIN OF CUSTODY REPORT (ln01) Jul 28 2003, 07:54 am
Login Number: L34910 2046 3M ENVIRONMENTAL LABORATORY
L34910-1'
,..
BC2 Sy-.04
SAMPLES KEPT IN D0000539.
:.: ', .; .-21*JUL:O3 25-J-U&-03
L34910.-2
.:
BC2
L~i4:910-3
" BC2
L34910-4 L3-49.10 -5 SOIL
BC2 EC2 SEE+04, s PERC SOLID
:.:
`: :~.:.:23-~~:~3:
25+JIjL-.~3~
H;.ld~:$l-AUG-03
do000539
,:
:;
L.349lo-6
BC2 SyT- 05
: ,: : ,.,.`..`.' $&tJyL-:Oi3
1 25+&ijy.o3:;,;
.' :.,
Lg4910 -7
BC2 SW:-.05 LOW S?K:.~::(,~:,,:~.,PP.B);!2l;:JUL:O:3. ,25,-JUL-O3
L34910-8
BC2 SW-05 HIGH SPK (10 'P?:~.~:.:,;21-J~~.-0~3: 25+IUL-O3. .. .,
L34910-9 '4
BCZ SW-85.DUP .. : 21-~~L:-.0.3 ,25.;+.:JqLf8~:.,:: ;.
., '.
L34910-10
BC2 SEDtOS
.2l-JUL:f-j3 25-~U~+.83,;
"
SOIL
S PERC SOLID
Hold:til-AUG-03
do000539
L3.4910-11 SOIL
BC2 SED.-06. S PERC SOLID
'.
23-JUL,.-03.: ~s-JuL-.o~:..
Holdhl-AUG-03
do000539
L3.4910.-12
BC2 SIT",0 6 ., '1 ,:: :, .&y;,+J~.~Q:3:: `25.4JTJ&.fQ3 .:.:..\: ; "5
.; :,,
&3-4910-n
BC2 SW.-.06 LOW SPK;:fO ;.'i:.;.I?,Pa:f.,~2'3::;iSUL.~03:.2~-1;7U~.-03
L34910-14
BC2 SW::O,6 HIGH: SP'K'. (10 ::PPB:):.j23 -JUL:-Q:3-. .25-:J'UL-.o3;
L34910-15
B.C2 SW-..06 DUP
,'-. :23---JU&yO3 ,25'JuL-03,
L34910-16
OUTFALL,,T.Q:..RIVER :SW~2.5...2,3~,~L-03 .2,5-.JUI,.+3,
.,::
L34910-l-7
/'
OUTFALL :TO RIVER. SW-.25 23:.;:JUL-03 2.5~JULto'3
COMPLETE ID READS OUTFALL TO RIVER SW-25 LOW SPK (0.1 PPB).
L34910-18
OUTFALL'TO. RIVER SW-25 23.2.:JUL-03
.'.
COMPLETE ID READS OUTFALL Td RIVER SW-25 HIGH SPK (10
L34910-19
OUTFALL TQ RIVER-:.SWk25 D~.P;23tJULyQ.3 25.+UL-O3
: :
Page 1
LOGIN Account:
CHAIN OF CUSTODY REPORT (h01) Jul 28 2003, 07:54 am
Login Number: L34910 2046 3M ENVIRONMENTAL LABORATORY
L34910-20 SOIL
OUTFALL TO RIVER S.ED'2'5' 23-JUL.+03 25.2JUL-03 :
S PERC SOLID
Hold:Ol-AUG-03
d0000539
:L34910-21 SOIL
OUTFALLTO S PERC SOLID
RIVER SED-25 :D:uF 23,-JUL-03
Hold:Ol-AUG-03
do000539
2.5.-WL-03
L349fO-22
F'IELD CONTROL/TRAVEL BLANK, 23-JUL-03: 25i",JUL;-O3 '.. ,:.::'
L34910-23
FIELD ,CCNTROL/TRAVEL.. BLANK LOW- 23 -JUL.-'03 .2.5.-;3UL-03
COMPLETE ID'READS FIELD CONTROL/TRAVEL BLANK LOW SPIKE (Oil PPB).
L34910-24
FIELD CONTROL/TRAVEL.BL,ANR 23-:JUL-03 25.-JUL,-03 ,.
COMPLETE ID READS FIELD CONTROL/TRAVEL BLANK HIGH SPIKE (10 PPB).
L34910-25
EQUIPMENT BLANK-PUMP :Zl-JUL-03. .2S-JUL:-03:.,:
L34910-26
EQUIPMENT BLANK-.DREDGE 23';'JUL-;03 25.-J&-03.
Page
2 Signature:
Date:
_I fr, ;. ,.J&
:1).:.. :
'.
,,: ',
000034
SECTION D
000035
IhI3058 Research Drive n State College, PA 16801
RESEARCH
Phone: 814-272-1039 Fax: 814-231-1580
Date: 08/26/03 Exygen Study # L34910
NOTE TO FILE
NOTE:
Throughout the raw data generated for study L34910 the 498 > 78 monitored transition (perfluorooctanesulfonylamide) was assigned the acronym PFOSA instead of FOSA. Any reference to PFOSA in the raw data is equivalent to FOSA.
Initials: $ Od2blfl3
000036
SpmwxSnuly
No:
Exygcn Siuiy No: .balyl.e:
Ions Manitolul:
Site:
NA I34910 PFOA 413 -> 369 Daanu B&r', Creek
RAW DATA REPORT
Limit of Quaotiutim: lnjatiw Volume: M&X: Sampls Vdumc: Pinal Volume:
JO PPC 1Jrr. W-1 40.0 mL 5.0 mL
Set No: AdYSli Luinrmcnc Extlaction AdYzcd
Type: oak cm
073103A IbmRiti LGUSMS 07fxm O&m-02/03
Unit Y 6
xco72503-0 xCO72503-1
XCO72JO3-2 xco72Jo3-3
xCu72sa3-4
xco72Jo3-5 XcO72503-6 McduMl Wash
0106020 Cwual 01 Cd020 Spk A
010602OSpkB W4910.1 Spk C
L34910-6 Spk D
U4910-12 L34910-16Spk
xco72Jo3-I
Spk E F
u49 IO. 1
w4910.1 Rsp
I349104 U4910-2 L34910-3
xCTl72503-2
U4910-6 L34910-6 Rep
w49m9 w4910.7 L34910-8 xCo72Jo3-3 L3491Mt
L34910.12 Rep U491O.H
U49m.13
U4910-14
xCO72so3-4 U4910-16
W4910-16Rcp L34910-I9
U4910-17 U4910.18 xcomo3-s
U4910.25 L34910.26 U491422 w49 IO-23 U4910-24
XCO71003.6
. .-., -_I
BC2 SW04 BCZ SW-05 BC2 SW-06 outfall tcl River SW-25
Bc2 SW-04 BC2 SWM BCZ SW-04 Dup BC2 SW-04 Low Spk BC2 SW+i Hi,& Spk
BCZ SW-OS BQ SW-OS BC2 SW-Q5 Dup BC2 SW-OS Low Spk BQ SW-05 Hip,! Spk
BCZ SW-06 BQ SW-M Bc.2 SW-06 Dup BC2SW~LowSpk BQ SW-06 High Spk
chaau lo uher SW-2s
outfall la River SW-25
outfall u) Rivet SW-U Dup
Outfdl LO River SW-U Low Spk
Outiall 10 RivaSW-2J
High Spk
equipmult Blmk-pump
Equipmm Bhnk-Dmlgc
Pi&i GxmoUthvcl
Blank
Field Control/hvcl
Bhk Low Spk
Picld CwrmKl'mel
Blank High Spk
c-s
on 103A-1001
cs
073103A-lm
cs
073103A-1003
cs
073103A.I@34
c-5
073103A-LWS
cs
073103A.1006
cs
073lO3A.1007
low
C
073103A.1008
C
073103A-lW9
LCS
073103A.1010
LCS
073103A-101
I
LP
073103A.1012
LP
073IO3A-1013
LF
Otiti3A.1014
LP
073103A-1015
cs
073103A-1016
2s
s
073103A-1017
S
073103A.1018
S
073103A-1019
PF
073103A-1020
FF
073103A-1021
cs
073103A-1022
SO
S
073103A.IO23
5
073103A.lU24
S
073103A.1025
IT
073103A.lM6
IT
073103A-1027
cs
073103A-1028
100
S
073103A.1029
S
073103A-1030
S
073103A.1031
ff
073103A. 1032
PP
073103A-1033
cs
073103A.1034
2.50
s
Of3103A.103s
S
073103A.1036
S
073103A-1037
m
073lO3A.1038
ff
073103A.1039
cs
073103A-I040
Jw
S
073103A-1041
S
073103A.1042
s
073103A.1043
PF
073103A.1044
PF
073103A.1045
cs
073103A-1046
1ooa
Analytc RaovcIy
Found (Ppo (%) -
i (peak
arca - intempt) [mlyte found
I slop x Dp (p&It).arwlyls
alxwunt
hmd added
in cwaol (ppt)
(ppt)] 1 ml
CS I C&bmdw
rmdud
c = conml rampls
s - Slmplc
CX.CbcckSmdd
ND = Nor detecti
NQ -Not qwmifmble
P Rerpantc I Rupocua
lJ' D Lb fmilicd FF I Fild fatiticd LCS m Wontory
"mph rampk
Cmi~ol Spike
bcrwecn 0 and 2S pp, betwcta 25 pp' and LOQ
(JO ppl)
`Sample
l Sampk
wu cwrsetcd usinS the data foucd in w(O73103AR. quirw furbcr dilution. See data w073103AR
J50 8614 16102 29438 66169 142891 264459 267 659 14411 132909 239247 145872 418651 515606 693 1 849301 826648 575640 605630 29529 13780 173871 181075 3JJlY'J 521363 21J% 317J8 2411389 2425189 2J27002 2849870 71294 75537 3012978 3276529 275829) 3102823 77205 156964 652 940 808 34004 35258 322068
NO
47.6
JO
95
452
500
w
8140
SW0
79L
4ha
JWO
a7
*
m
.
Jow
I
.
.
*
100
99247
1ww
J7"
SYl 616
l
*
100
7210
lcml
66
.
*
.
.
100
24200
loow
121"
l
*
.
I
IO0
26200
weal
104A
ND
ND
ND
I14
loo
114
11900
mooa
119
slnndprd Imrcopt Slope
cocf. Of DeL
: Lbmr (Ilx - 44J.OJ7 i 293.343 3 0.986042
weighmd)
SprewJshcec prepared by:
000037
SjmvxStudy
No:
Bxyrcn Study Na:
kldytc:
IOIU Monitored:
Site:
NA I34910 PFHS 399 -> x0 Dccaiur B.&&s Creek
R4 W DATA REPORT
Llmll of Qupntitatlon lnjcction Value: Mti sampk Volum: Fl Vdum:
JopP( 15 rr. Ww 40.0 mL 5.0 ml.
&NIX AdYlC hlkumml Bxinctiw Adyrcd
Type: fhk w:
0731rnA lcanmfurhn LUMS/MSUail#d 07x3 1x13 OaAlIrn
ID
CC&
NO.
(PPI)
Facta
Area
x0372503-0
Gs
0731rnA.UYJI
0
a
xc072503-I
cs
073 103A. 1002
25
1401
XCO72503-2
cs
073103A-Iw3
SO
2842
xco72503-3
cs
073103.4-1004
100
5604
xCO72503-4
cs
073103A.lws
250
13137
XCO72503-5 xCm2so3-6
cs
0731mA-1006
500
26976
cs
073103A-1w7
lca
51345
Methanol wash
C
073103A-1w8
0
Olca7.a conlral OlOW2OSpk A
C
u73lrnA-1009
LCS
07310x-1010
1
0
I
2759
OlWO20 Spk B
LCS
073103&101
I
1
26598
W4910-I SpkC
BCZ SW.O4
LF
073103A.1012
10
30859
I349104 Spk D
BCZ SW-05
LP
0731mA-1013
10
27946
U4910-12SpkE
BC2 SW06
LP
U73103A.1014
LO
55454
l.3491~16 Spk F
cutfall 10 River SW-23
LF
073103A-1015
10
60284
xwwo3-I
cs
0731rnA-1016
25
1444
U491Q1
Bc2 SW.04
s
0731rnA-1017
1
50162
w4910.1 Rep
BC2 SW.04
S
073103A-1018
1
49342
L349104
EC2 SW-M Dup
S
073103A-1019
I
31968
L349102
BC2 SW-04 Low Spk
FF
073103A-IOU)
I
36223
u4910-3
BC2 SW-04 Hi@Spk
w
073103A-1021
100
5426
xcx72.503-2
cs
0731mA-lU22
So
2420
W4910-6
Be2 swos
S
073lMA-ICC3
I
a666
U4910.6 Rep
BC2 SW-05
S
073103A-1024
I
150s
w4910-9
BCZ SW-05 Dup
S
073103A- 1025
I
21096
L349m7
BCZ SW-OS Law Spk
FP
073103A-1026
1
33965
L34910-8
BCZ SW.05 Hiph Spk
FF
073103A.1027
LCQ
5342
xCo72503-3
cs
073103A.1028
100
5959
L3491&12
BC2 SW&i
S
0731rnA.1019
I
2.59042
U4910.12 Rep
BCl SW-W
s
073103kIWO
1
237649
w4910.15
Bcmwwoup
S
073lrnA-1031
I
245687
l.34910.13
BC2 SW-06 Low Spk
FF
073103A.1032
I
275858
L34910-14
BCZ SW-06 Hi@t Spk
FF
073103A-1033
100
YIN
xCO72503-4
CS
0731rnA-1034
250
14198
W4910.16 f.34910.16 Rep
w4910.19 w4910-17
talddl IO ltivcr SW-25
S
oulfall to River SW-25
s
o.ldalIlORiverSW-2I5hp
S
outfzll11R0ivarSW.2L3owSpk IT
073 103A- LO35 073tm.4-Im6 0731rnA.1037 073imA4-1038
1
283517
1
302530
I
276429
I
7J8698
l.34910.18
&fail lo River SW.25 High Spk
FF
073103A.1039
100
10133
xco72503-5 w4910.25
Eqtipmcat Blank.i'ump
CS
0731mA-IWO
s
0731mA.1041
SW
29038
1
0
U4910.26
Wiwm~
Blank-hdgc
S
073IMA-1042
1
0
W491Q22
Field Caatrdfhvcl
Blank
S
073lrnA.1043
1
0
U4910.23
Field C~nvOlfTnvcl
Blank Law Spk
FF
073103A.3044
I
664a
L34910.24
Field C~nUol/hve.l
Blank Hi@ Spk
FF
OnlrnA-lo45
loo
6002
XCO71003.6
cs
073103A.1046
Iwo
60941
Amlyre Found (ppt) RccaYay (%I =
- (peak
area - intercept) (amlytc found
I rlapc x OF (Ppt)-allalyw. found 10 EODWI
UmlJnl .adcd (pp)
(tJFt)I 1. 100
CS = Calibnwm
xacniwd
c = CMtrOl sample
s - SYnple
CK-CiwkSund&d
LF ILabhtlficdurrpk FF - Weld fmifkd sampk La = Iiabamtciy CMud spike
fpPl)
-
No
49.7
99
475
95
5520
54m
92
sm
5cKJo
97
.
sow
.
scol
896
a82
571
647
100
-249+
9730
Iwoo
88
155
IS2
377
607
100
452
9580
tm
94
. .
.
l
100
17400
low0
113*
l
.
.
l
100
18100
lotm
104~
f-40
ND No
119
loo
119
10800
loo00
108
B
: Linw (I/r
tnlaccqi - -23.56k4l
Slope 3 55.9970
Cd. of De!. - 0.98w93
weighted)
Vhqlc
l Sampk
Maqk
was corralal using dm data found in set 073103AR.
mquim futhcr dilution. See dua St 073 103A.R.
residue signiricnntly
cxceedr the spiking kvel; tbxcfcix.
an YEUIILS rccovcry cannot bc czdculud,
000038
Spmvw Stiy No: Baypen SMy No: Andytc: lnnr MrJnilmd: Site:
NA w4910 PFOS 499->vv Dccanu Bakm'r Crick
RAW DATA REPORT
Limil of Qantilatiw:
Injection Mti:
Volwnc
Sample volume: Fmal Volunr:
soppc IJ NWater 40.0 mL 5.0 mL
SOI No: AlUIYSC lluullmull Bauactiw my?.cd
Type: Dam an:
073103A KMnRisha ms/Ms O7AIrn3 o8mLo2m3
Unil Y 6
@YW
m
XCa77503-O
XC0725OE I xco72.nl3.2
xcO72.ul3-3 xco7?.m3-4
xco72so3-J XCUf2503-6
MedIano wash
01~20Conual
0106020 spk A
0106O20 W491O-1
Spk B Spk C
W4910-6 Spk D
l34910-12 Spk E
L34910-16 Spk F
xco72303-I
L3491aI
w4910-1 Rep
w491w
134910.2
L3491O.3
XCO72503-2
L34910.6
u4910-6 Rep
u491O.9
L3491O.7
L34910.8
xCO72.m3-3
u4910-12
w4910.12 Rep L349m1s
u4910-13
w491O-14
xCO72503-4
L3#10-16
uA9LO16
Rep
L3491019
w491O-17 l349lO-18
XCO725is5 U4910.23
L3491&26 w4910-22
W49lOa
134910.24
XCO71Do3-6
spaoaor
m
-
BC2 SW-O4
BC2 SWJJ5
BC2 SW06
ouddl to River swa
_
l
BC2 SW.04 BC2 SW-O4 EC2 SW44 lxp BC2 SWU4 Law Spk BCZ SW-O4 Hi& Spk
EC2 SW45
BC2 SW-05 BC2 SWOS tip BC2 SWOS Low Spk BC2 SW-O5 H~@I Spk
BC2 SW-O6 Bc2 SW55 BC2 SW06 Dup BC2 SW-06 Low Spk BC2 SW06 Hi#t Spk
oulfdl In RIvlwsw.2s cuddl Lo RIVW SW-25
Gutfau to Rivcrsw-25 OAfall IO River SW-2S
IhIp IAW Spk
Chffdl to RIverSW-ZS
Hi@ Spk
Equipnm Blank-Pump
Eqtipmnl
Bhuk-lhdy
Fidd ControUhvel
Blank
Field CoUraUhvel
Blank Low Spk
Field Conudthvd
Blauk High Spk
sam$de
CCdC CS cs cs cs cs cs cs C C l.cs L&s iF ,tF LP LF CS S S S m FF cs S S S FF FlJ cs S S S IT IT cs S s s FF FF cs S S S IT FF cs
Rue
No.
O73103A-1001
073103.4-1002
O73103A.LOO3
O731MA-IMY 073lmA.n3.5
073103A-1006 073103A-I@37
O73lMA-IOOS
073103A-1009
O73103A-1010
073103A-101
I
073103A.1012
O73lMA.1013 073103A.1014
O73103A-lOIS
O73103A.1016
O73103A-1017
O73103A-1018
073103A.1019
O73103A.1020
073103A.1021 O73103A-1022
073103A-1023 013103A-1024
0731O3A-1025 073103A.1026
O73103A.1027 O73103A-IO28
073103A-1029
073lrnA-1030
O73103A.1031
073103A.1032
O73103A-IO33
O731O3A.1034 073103A.103s 073103A.1036
073103A. 1037
073103A.1038
073103A.1039
073103A-1040
073103A-1041
073103A-1012 073103A-lO43
O73103A.IO44
073103A-IO44
073 103A-1046
Std.
COIIC. (Ppl)
0 23 Jo
100 2.50
SW l(Mo
Dludon Factor
1 1' 1 10 IO 10 10 as 1 1 I 1 100 so 1 I I I IW loo 1 I 1 I loo 250 I I I 1 100 SW 1 t 1 I loo IWO
Peak AM
0 971
I%3 M40 7.518 17228 32298
:o:
-0
1673 ISIS?? SO011 202% 96754 120697 954 280183 274170 21172S 191631 6016 1656 44922 46036 112926 149088 4333 3500 558236 571211 56OllS 667186 14981 8S2I 691166 707270 6S6533 68w9 14072 19341 316
0 0 3691 38S3 3se.l
Andyte.
Fnund (PPO
Amwnt
Added @PO
-
:
-3..
-. .-.
-
. I
- ;.. ND
so.4
445 1
SV40 * *
. .
l .
17700
. . . . 12800
. . I . 43900
. . * . 41200
ND ND ND 109 11400
Rcwvcly
(%)
-...- . .
101 09 115"
62"
IllA
17e.u
IW
+mpIc
**SampIe
l Sunpla
VP) mmcred ws curccted
acquirer flUhI
usinK rhc data found in set 073 103AR. U&IS lhe dam found in YI 08O6O3k dilution. See data sat 073 103AR.
000039
Sponsor Study No: Exygcn Study No: `4tidyCC: Ions Monitored: Site:
NA L34910
FOSA
498 -> 78 Decatur Bakct's Creek
RAW DATA REPORT
Limit of Quntiution: Injection Vohtmc: Matrix: SatlQle Valunlc: Final Volume:
50 PPt ISllL W?.tcr
40.0 mL 5.0 mL
Set No: Analyst: Insuument Type: Extraction Da&: Analyzed on:
073 103A Karen Riiha LUMSiMS Unit # 6 07/3 1103 08/01-02/03
EXYl3.= ID
xco72503-0 xco72sa3-1 XCO72503-2 xco72503-3 XC0725034 XCO72503-5 XCO72SO3-6 Metbrnol Wash 0 106020 Control 0106020 SpkA 0106020SpkB L34910-I SpkC L34910-6 SpkD L34910-12 Spk E L34910-16 Spk F XCO72503.1
L349 10-I L34910-1 Rep
L349 IO-4 L349 1o-2 L349 I o-3 XCO72503-2 w4910-6 L349 IO-6 Rep L349 1o-9 L.34910.7 W4910-8 X0372503-3 L349 IO- 12 L34910.12 Rep L34910-15 L34910.I3 L34910-I4 xcor2503-4 L34910-16 L34910-16 Rep L34910-19 L34910-17 L34910-18 XCO72503-5 u4910-25 L34910.26 L34910-22 L349 lo-23 L34910-24 xc071003-5
Sponsor ID
BC2 SW-04 EC2 SW-05 BCZ SW-06 Outfall to River SW-25
BCZ SW-04 BC2 SW-04 BQ SW-04 Dup BQ SW-04 Low Spk BQ SW-04 High Spk
BC2 SW-05 BC2 SW-OS BC2 SW-05 Dup BC2 SW-05 Low Spk BC2 SW-05 High Spk
Bc2 SW-06 EC2 SW-06 BC2 SW-C-5Dup BC2 SW.06 Low Spk BC2 SW-06 High Spk
Dutfall to River SW-25 Outfall to River SW-25 Cutfkll to Rive?SW-25 Dup Outfall to River SW-25 Low Spk Outfall to River SW-25 High Spk
Equipment Blank-Pump Equipment Blmk-Dmdge Field CantrolTnvcl Blmk Field Conuo~ravel Blank Low Spk Field ControI~Trrvcl Blank High Spk
smpk Code cs
cs
cs cs cs
cs cs C
C
LCS LCS LF LF LF LF cs
S S S FF FP cs S S S PF FF CS S S S FF FF cs S S S FF FF cs S S S FF FF cs
Run NO 073103A.1001 073103A-1002 073103A-1003 073103A.1004 073103A-ICG5
073103A-1006 073103A-1007 073103A-1008 073103A-1009 073103A-1010 073103A-1011 073103A-I012 073103A-1013 073103A-1014 073103A-lOIS 073103A-1016 073103A-1017 073103A-1018 073103A-1019 073103A-1020 073103A-1021 073103A-1022 073 lO3A-1023 073103A.1024 073 l03A.I025 073103A.1026 073103A-1027 073103A-1028 073103A-1029 073103A.1030 073103A-1031 073103A-1032 073103A-1033 073103A.1034 073103A-1035 073103A-1016 073103A-1037 073103A.1038 073103A-1039 073103A.1040 073103A.1041 073103A.1042 073103A.lC43 073103A.1044 073103A.IO45 073103A.1046
An&`@ Found (ppt) - (peak uca - intercept) I slope x DF
Recovery (%) -
~vralyte found (ppt).aoalyte found in cm~uol @pt)] x 100
rmouat added @pt)
Std. COW. (ppt)
0 25 50 100 250 500 ICC0
DihtiOll Factor
1 1 1 10 IO 10 10 25 I 1 I I 100 50 I I 1 1 IO0 IO0 I 1 1 1 100 250 1 1 1 1 100 500 1 I I I lo0 loo0
Peak Arca
0 3440 6725 13321 3 1340 65687 127765
0 0 6872 62898 74954 65330 96.556 107094 3545 148109 143575 106161 90364 9716 6634
19717 20175 52363 6703 I 5639 13989 269067 2634 11 276134 284082 11410 33866 358032 358tt72 369645 311246 12191 72430
0 814 0 I2140 16047 139302
Anriylc Found (ppt)
Attwunt Added (ppt)
RCCOVCIY w
ND 50.6 468 5580 4860 7180 7970
*
l
790 672 7180
146 I50 389 498 4140
.
l L *
8440
l I . .
9020
ND ND ND 89.8 II900
50
IO1
St30
94
5OwJ
84A
5ooo
94
5ooa
95"
sow
94^
loo IOOCQ
-71x"+ 58^
IO0
3.51
IOOCQ
40
100
10000
60"
100
loo00
5aA
loo
90
Iwo0
119
&!a&&&&
: Linear (I/x weighted)
1nurccpt = 78.1882
Slope = 134.313
Coet Of Dct = 0.995963
CS = Calibration stand&
LF = Lab fortified sample
C = Conrrol ramplc
FF - Field fortified sample
S = Sample
LCS = I.&omtory cowJo spike
CK = Cheek Stllrdard
ND - Not detected - Rcsponx between 0 and 25 ppt
NQ - Not quDntiflablc - Rcspawc bchveen 25 ppt sod LOQ (50 ppt)
Spreadsheet prcpucd by:
^Sampk was conected using tbc data found in ICI 073103AR *Sample requires tuther dilution. Seedata set 073103AR. +Sampk residue rigniticurtly cxccc& the spiking level; therefore, ao KCW~~Crecowy cannot be calculned.
000040
Protocol Number:
n nEARCH
3058 Research Drive
State College, PA 16801
Phone: 814-272-1039
Fax: 814-231-1580
SAMPLETRANSFERSHEET
NA
Exygen Study Number:
L34910
Exygen Sample #
1 Sponsor Sample #
I
BC2 SED-06 BC2 SW-06 BC2 SW-06 Low Spk
Karen Risha 7/3 l/O3 0800
Requested By (Printed Nan&Date/Time)
Samples removed from: Samples removed from:
&#$-%7
-
Box#
--W
Box+!
-
Shelf# -
Shelf#
-
Samples transferred to the custody of
Samples received from custodian; Samples moved to
f%F 3%
L4
7-Y&3
a9ca7
Sample Custodian Initials/Date/Time
Laboratory
It,3 ocloo
Personnel InitiaWDattlTime
Comments:
r/d73 Sample Custodian
0% 3g
Inkials/Date/Time
December 19,2002/6
000041
E.
n BI EAI<CH
3058 Research Drive
State College, PA 16801
Internal Chain of Custody/Fortification
Bxygen Study Number:
L34910
Sponsor Study/protocol No:
NA
The samples listed below were removed from refrigerator No
Tie fltl
I
I
Sheet
Matrix:
EXYGEN ID NUMBER
VOLUME (mL)
na
0106020 Control
40.0
na
0106020 Splc A
40.0
na
0106020 Spk B
40.0
BC2 SW-04
L34910-1 Spk C
40.0
BC2 SW-OS
L34910-6 Spk D
40.0
BC2 SW-06
L34910-12 Spk E
40.0
OutfaIl to River SW-25
L34910-16 Spk F
40.0
BC2 SW-04
L34910-1
40.0
BC2 SW-C4
L34910-1 Rep
40.0
BC2 SW-04 Dup
L349 1o-4
40.0
SC2 SW-04 Low Spk
L34910-2
40.0
BC2 SW-04 High Spk
L34910-3
40.0
BC2 SW-OS
L34910-6
40.0
BC2 SW-05
L34910-6 Rep
40.0
BC2 SW-05 Dup
L34910-9
40.0
BC2 SW-05 Low Spk
L34910-7
40.0
BC2 SW-05 High Spk
L349 10-g
40.0
BC2 SW-06
L34910-12
40.0
BC2 SW-06
L34910-12 Rep
40.0
BC2 SW-06 Dup
L34910-15
40.0
BC2 SW-06 Low Spk
L34910-13
40.0
BC2 SW-06 High Spk
L34910-14
40.0
Phone: 8 14-272-1039
Fax: 814-231-1580
m
Initials &Z
FORTIFICATION
(ng)
2.0 20.0 200.0 200.0 200.0 200.0
L34910-12 Spk E L349 lo-16 Spk F
F&50203-2 (loo0 ng/rnL) FO60203-2 (1ooQ ng/mL)
All samples were mtaaured:
Time lOW
Date ?&/0?i
After measuring samples were returned to refrigerat r No. 32
Time l/m
Date J-?/3/ 0.3
c0nUIIeIIt.S:
Analysis
200 pL of 250 mg/mL sodium thiosulfale was ad&d to all wnpla
Summary:
Data Set:
Data Set: Data Set:
b731 ah
Set extraction/analysis data verified by:
`Initials /!.!. Initials m before spiking. InitialslDatc:
u -
July 26,2001/6
000042
nR( 3058 Research Drive
EARCH
State College, PA 16801
Phone: 814-272-1039 l3x: 814-231-1580
EXYGEN
STUDY
SAMPLE
NUMBER: m MATIUX: &gg
EXTRACTION
AND ANALYSIS TRACKING SHEET
METHOD: " ANALYTES: PFHS, PFOS. @OA and PFOSq
PROTOCOL NUMBER: u
Client ID I
Exygen ID
STEP
1
STEP 2
Dilutions (muml.)
STEP Dilutions STEP
3
(mualL)
4
I F
Reagents/ Materials Mclhaml
Cl8 SPE
Lot % 43lKpJyB
W5PGi3?J
L3491@16 Spk L34910-I
BC2 SW-05 Dup
L34910-9
BC2 SW-OS Low Spk
L34910-7
BC2 SW-05 High Spk
L34910-8
BC2 SW-06
L34910-12
I
BC2 SW-06
L34910-12 Rep
BC2SW-06Dup
L34910-15
I
BC2 SW-06 Low Spk
L34910-13
BC2 SW-06 High Spk
L34910-14
*lnitialr/Dorr
I
STEP 1: SPE columo clean-up (omitting 40% wash)
I
1 I
STEP 2: Final vohme IO 5 mL collected in I5 mL polypropolene tubes
STEP 3: LC/?&lMS analysis
STEP 4: LC/MS/MS reanatysis.
I 0 . I/
I
I
I I
I
1
I ,l; I w
O*`/I, 0 O-`/r.0
O151.0
1
I
I
\1/ 1
1
;w_ AmmoniumAccl.ate
e,
I
c;4
NA
i!lsw=m
lq3ua.q
tswd
&bin&
ra*F?w
twJm.LWcL~eAhF=Ico.
tp&b3
*Initials and dale under each stp indicates the personnel that performed this step.
$I Mebd of Analysis for the Dmmination of P~~~wo~ctaoc sulfonatc (PFOS). Perfluorooctanc sulfonylamide (PFOSA), and Pcfluorooctanoate
(PoAA)
in Water
coh4hENTs: u
Final extracts stored in refrigerator&
Initials: E
Date: o?l??,/&
July 19,2001/4
n m EARCH
3058 Research Drive State College. PA 16801
Phone: 814-272-1039 Fax: 814-231-1580
-
Internal Chain of Custody/Fortification Sheet
Exygcn Study Number:
L34910
Matrix: m
Sponsor Study/Protocol No:
k.iA
The samples listed below were removed from refrigerator No.
Outfall to River SW-25 Low Spk Outfall to River SW-25 High Spk
Field ControVTraveI Blank Field ControbTravel Blank Low Spk Field ControVI'ravel Blank High Spk
Equipment Blank-Pump Equipment Blank-Dredge
I
I
L34910-17 L34910-18 L349 1o-22 I349IO-23 L34910-24 L34910-25 L34910-26
40.0
40.0
40.0
40.0
40.0
I
40.0
I
40.0
I
!
!
I
Spiking Solution Used
1 Volume Used for Spiking I
InitiaYDate
I
I
I
I
All samples were measured:
Time 1020
Date
After measuring samples were returned to refrigerator No. ~32
Time /Ia
Date Q@t,$!)3
Initials f= Initials f'lEE
C0mnWIt.S:
200 pL of 250 mghL sodium ti~iorutfatcwasadded to all rvnpta bcfar~spiking. InilirldDate:
Analysis Summary:
DataSet: 6731%4
'
Data Set: b73lb3S
Set extraction/analysis data verified by:
_-
_.,-.
l-"._l.l----
.-.__.
.".-_.-
,-_-
-
--
.._~.
-
c E
nM EARCH
3058 Research Drive State College. PA 16801
Phone: 814-272-1039 Fax: 814-231-1580
EXYGEN
STUDY
SAMPLE
NUMBER: m MATRIX: &&I
EXTRACTION
AND ANALYSIS TRACKING SHEET
METHOD: ff ANALYTES: J'FHS. PFOS. PFOA and PFOS4
PROTOCOL NUMBER: Nl
Equipment Blank-Dredge
*Initials and date under each step indicates the personnel that performed t&s step. $$ Method of Analysis for the Determination of Pwfhwwctane sulfonate (PFOS), Perfluorooctane sulfonylarnidc (PFOSA), and Peffluorowtaooate
(POAA) in Water
Final extracts stored io refiigcrator~
Initials: E
Date:
July 19. 200114
-. Masslynx
- .- Sample List
Sample List: C:WIASSLYNX\Fluoroch Printed: Fri Aug 01 O&36:23 2003
___
- -_-.
-I-
-~-__---.----___
103A Decatur BCSPL
-@o%?m fiUDY NO.
Page 1 Page Position: (I. 1)
Vial File Name
41 073103A.1001 42 073103A-1002 43 073103A-1003 44 073103A-1004 45 073103A-1095
46 073103&1006 47 073103A-1007
92 073203A-1008 51 073103A-1009 52 073103A-iOl0 53 073103A-1011 54 073103A-1012 55 073103A-1013 56 073103A-1014 57 073103A-1015 42 073103A-1016 58 073103A-1017 59 073103A-1018 60 073103A-1019 61 073103h1020 62 073103A-1021 43 073103A-1022 63 073103A-1023 64 073103A-i024 65 073103A-1025 66 073103A-1026 67 073103A-1027 44 073103A-1026 68 073103A-1029 69 `073103A-1030 70 073103A-1031 71 073103A-1032
073103A-1033 073103A-1034
73 073103A-1035 74 073103A-1036 75 0731 03A-1037 76 073103A-1038 77 073103A-1039 46 073103A-1040 78 073103A-1041
io" 073103A-1042 073103A-1043 81 073103A-1044
LIMS ID Client ID Sample Description
---
---
--
-
--
-
---
-
--
---
--
--
--
---
--
---
-
--
--
---
--
-
--
---
--
_-
--
__-
--
---
--
---
--
-_-
--
--_
-
--
--
-7
-
--
-
-__
-
--
--
--_
-
--
-
-_-
--
I-
-
--
--
---
--
---
-
-__
-
-
-
---
-
---
--
---
--
--
-
-__
-
-__
--
--_
-
---
-
--
--
---
-
--
---
-_
XCO72503-0,O nglL Standard
XCO72503-`i I
ngR Standard
XCO72503-2,50 ngR Standard
XCO72503-3. 100 r@L Standard
XCO72503-4,250 rig/L Standard
XCO72503-5, 509 rig/L Standard
XCO72503-6.1000 nglL Standard
Methanol Wash
0106020 Control
0106020 Spk A, 50 rig/L
0106020 Spk B, 500 rig/L
L34910-1 Spk C. 5000 rig/L, DF=lO
L34910-6 Spk D, 5000 mJL, DF=lO
L34910-12 Spk E, 5000 rig/L, DF=lO
L34910-16 Spk F, 5000 rig/L, DF=lO
XCO72503-1, 25 nglL Standard
L34910-1
L34910-1 Rep
L34910-4
L3491 O-2
L34910-3. DF-100
XCO725O?b2. 50 nglL Standard
L34910-6
L34910-6 Rep
L34910-9
L34910-7
L34910-8, DF=lOO
XCO72503-3. 100 ng& Standard
L34910-12
L34910-12 Rep
L34910-15
L34910-13
L34910-14, DF=lOO
XCO72503-4,250 rig/L Standard
L34910-16
L34910-16 Rep
L34910-19
L34910-17
L34910-18, DF=lOO
XCO72503-5,500 rig/L Standard
L34910-25
L349 lo-26
L34910-22
L349 lo-23
Matrix
-----_ ---_--
-------
---
--
_-
---
---
--
-_-
--
___ --
--
___
-
--
--_
-
--
--
-_-
--
___
-__
-__-
r__--
Samplefype
Standard Standard Standard Standard Standard Standard Standard Blank Blank
::
EE QC QC Standard Analyte Analyte Analyte
:: Standard Analyte Analyte Analyte
:cc Standard Analyte Analyte Analyte
:: Standard Analyte Analyte Anatyte
:: Standard Analyte Analyte Analyte QC
Cone (rig/L)
85 50
100 250
500
1000 ----
100
ZEO 5000 5000 5000 25 ---_ --
100 10000 50 _-----
100 10000 100 ___ -_--100 10000 250 -----
100 loo00 500 ---100
Cone B Cone C Test ID DF
--
___
0
___
---
0
--
--_
_-
-__
x
-_-
---
0
e-
___
-
___
8
--
--
--
-__
x
---
--_
00 : -
---
--
--e
0
IO
-
--
0
10
---
0
IO
--
10
--
--_
8
1
-
--
0
1
_-
---
0
-
---
0
1
_-
--
0
1
-
--
0
100
-_
-
0
1
-
--
0
1
---
-
1
--
-
:
1
_-
-
0
1
-
-_
0
100
--
-_
1
---
--
i
-
--
1
-_-
--_
:
1
-
_-
0
--
--
0
100
--
0
1
-
--
0
1
-
--_
1
--_
0"
1
--
--
0
-_
0
100
-
___
0
1
1
---
0
-
___
0
-
--_
0
-
---
0
Masslynx - Sample List
Sample List: C:\MASSLYNX\Fluoroc Printed: Fri Aug 01 O&36:23 2003
MS Method
1 C6 CB SULF 2 C6 CB SULF 3 C.6 CB SULF 4 C6 CB SULF 5 C6 CB SULF 6 C6 Cf3 SULF 7 C6 CB SULF 8 C6 CB SULF 9 C6 CB SULF 10 C6 CB SULF
C6 CB SULF :: C6 CB SULF 13 C6 CB SULF 14 C6 CB SULF
C6 CB SULF :t C6 CB SULF
C6 CB SULF :i C6 C8 SULF 19 C6 CB SULF
C8 CEi SULF t: C6 CB SULF
2'5 C6 CB SULF C6 C8 SULF 24 C6 CB SULF 25 C6 CB SULF
C6 C8 SULF :; C6 C8 SULF 28 C6 C8 SULF
C6 CB SULF C6 C8 SULF 31 C6 CB SULF 32 C6 CB SULF C6 CB SULF C6 Ci3 SULF
C6 CB SULF C6 C8 SULF C6 C8 SULF C6 C8 SULF C6 CB SULF C6 CB SULF C6 C8 SULF C6 CB SULF C6 C8 SULF C6 CB SULF
C8 ACID C8 ACID CB ACID C8 ACID CB ACID
C8 ACID C8 ACID
CB ACID C8 ACID CB ACID C8 ACID C8 ACID CB ACID CB ACID CB ACID CB ACID C8 ACID CB ACID CB ACiD CB AClD CB ACID
CB ACID CB ACID C8 ACID CB ACID CB ACID CB ACID CB ACID CE ACID C8 ACID C8 ACID CB ACID
C8 ACID CB ACID
C8 ACID C8 ACID CB ACID CB ACID CB ACID CB ACID CB AC10 CB ACID C8 ACID CB ACID
PFOSA PFOSA PFOSA PFOSA PFOSA
PFOSA PFOSA
PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA
PFOSA PFOSA PFOSA
PFOSA PFOSA
PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA
PFOSA PFOSA
PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA PFOSA
HPLC Method
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water
pfbs water
ppfbms swwaatteerr
pfbs water pfbs water
pms water
pfbs water
pms water
pmswater ppmmsswwaatteerr ppfbms swwaatteerr ppfbms swwaatteerr ppfbms swwaatteerr ppfbms swwaatteerr ppfbms swwaatteerr pmswater pmswater
pfbs water
pmswater
pfbs water
pfbs water pfbs water
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pf4s water pfbs water
ppfbms swwaatteerr
MS Tune File
Fluorochems Fluarochems Fluorochems
Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems
Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems
Fluorochems Fluorochems Fluorochems f luorochems Fluorochems Fluomchems Fluorochems Fluorochams Fluorochems Fluorochems
Fluorochems Fluorochems
Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems
Inj.Volume
15 15
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2
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-&Y@Ql STUDY NO. @-.-fib
-
-
Page 2 Page Position: (2, 1)
Masslynx - Sample List
Sample List: C:\MASSLYNX\Fluoroc hinted: Fri Aug 01 O&36:23 2003
mlcals.PRO\SampleD8\073~03A
Decatur EJCSPL
.-en STUDY NO. .&b!%!?.
Page 3 Page Position: (1, 2)
Vial File Name
45 82 073103A-1045 46 47 073103A-1046
LIMS ID Client ID Sample Description
--
--
--
-
134910-24,OF=loa XCO72503-6. 1000 ngli Standard
Matrix
---
Sample Type
QC Standard
Cone (ngll)
10000 1000
Cone I3 Cone C Test ID DF
--
--
0
100
-
--
0
1
000049
LC/MS/MS SYSTEM AND OPERATING CONDITIONS
Sponsor Protocol No: NA
Qygen Studv No: L349 10
Instrument:
Micromass Quattro Ultima (LCMSIMS Unit #6)
Computer:
COMPAQ Professional Workstation AP200
Software:
Microsoft Windows NT: Version 4 Build 1381: Service Pack 5 Micromass Limited: MassLynx 3.4 Build 004
HPLC Equipment:
Hewlett Packard (HP) Series 1100
HP Bin Pump
HP Vacuum Degasser
HP Autosampler
HP Column Oven
._
HPLC c01urnn:
Genesis C-8,5 cm x 2.1 mm i.d. x 4 p (Exygen ID: 74A) (JONESCHROMATOGRAPHY: Part No. FK5962E)
Mobile Phase (A) : Mobile Phase (B) :
2 mM Ammonium Acetate in Type I Water Methanol
Analyst:
Karen Risha Exygen Research 3058 Research Drive, State College, PA 16801 Phone: (814) 272-1039 FAX: (814) 231-1580
NOTE:
The next 3 pages are computer generated printouts from the masslynx software program. The pages contain the instrument settings used for the analysis of this data set.
All Handwritten Peak ID's by.* lcif%plb3
000050
`brrl Scanning
Method Report
Method:
Last Modified:
C:/MAS~LYNX\FLUOROCK~?X~CALS.PRO\ACQUDB\C~ Thu Jul 31 16:23:50 2003
Page 1
CS SULF C8 ACID PFOSA
Printed:
Fri Aug 01 08:36:30
2003
u
Solvent Delay ( mins ) :
0.00
Analog Function
Channel : 1
4 : Unused MlW of 4 Mass Pairs
( ES?- )
Inter Channel Delay ( Sets ) : 0.03
Span ( Daltons ) :
0.00
Start Time ( Mins ) :
0.00
End Time ( Mins ) :
12.00
Repeats :
1
Channel Parent Daughter
Dwell
(Sets)
1
399.00
80.00
0.20
2
413.00
369.00
0.20
3
498.00
78.00
0.20
4
499.00
99.00
0.20
Co11 Energy
35 10 30 40
(eV 1 Cone
50 10 50 30
(v 1
Ix--_ __II._^__^___-
00005~
__."-.
.__..__-,-,__"--.,-_..-...--.-..-. -
Method Report
Method File: Last Modified:
14 Printed:
c:\masalynx\fluorochemicale.pro\acqudb\pfbe Friday, August 01, 2003 08:27:00
Friday, August 01, 2003 08:36:39
HP1100 LC Pump Initial
Conditions
Solvents
A%
90.0
B%
10.0
C%
0.0
D%
0.0
Flow (ml/min) Stop Time (mins)
Min Pressure (bar) Max Pressure (bar) Oven Temperature Left(C) Oven Temperature Right(aC)
0.300
20.0
0 400
35.0 35.0
HP1100 LC Pump Gradient
Timetable
The gradient Timetable contains 8 entries which are :
Time
A%
B%
C%
D%
0.00
90.0
10.0
0.0
0.0
2.00
90.0
10.0
0.0
0.0
5.00
10.0
90.0
0.0
0.0
9.00
10.0
90.0
0.0
0.0
9.50
0.0
100.0
0.0
0.0
14.00
0.0
100.0
0.0
0.0
14.50
90.0
10.0
0.0
0.0
20.00
90.0
10.0
0.0
0.0
$4 HP1100 LC Pump External
Event Timetable
The Timetable contains 6 entries which are :
Time Initial
0.00 0.05 0.10
11.90 12.00
Column Switch Off Off Off Off Off Off
Contact1 Off On Off Off Off Off
Contact2
Off Off Off On
Off Off
'Contact3 Off Off Off Off On 'Off
Flow
0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
Contact4
Off Off Off Off Off Off
HP1100 Autosampler Initial
Conditions
Draw Speed Eject Speed (pl/min)
Draw Position (mm)
Stop Time (mins)
Injection
Volume(pl)
Vial Number
200.0
200
0.50
20.00
*
15.0
69
water
Page 1
Pressure 400
400 400
400 400 400 400 400
000052
~4 Tuning Method Report
Method:
C:\MASSL~\!?LUOROC~MICALS.PRO\ACQUDB\FLUOROCHEMS
Printed:
Fri Aug 01 08:37:00 2003
u '
Page 1
Dau 395.00
SOURCE ( ESP- )
Capillary
Cone
Hexapole 1
Aperture 1
Hexapole 2
Source
Block
Desolvation
Temp.
Temp.
Pressures
Analyser Gas Cell
Vacuum
Set R&k
3.00 -2.93
20
-21
0.0
0.0
0.0
100
100
300 299
Rdbk
OFF 3.4e-3
Analyser
LM Res 1 HM Res 1 IEnergy 1 Entrance Collision
Exit
LM Res 2 HM Res 2 IEnergy 2 Multiplier
Gas Flows
Cone Gas Desolvation
Set
14.0 14.0 1.0 -2 15 2
14 .o 14.0
2.0 650
Rdbk
131.4 754.2
Rdbk
12 14
16
-648
000053
---
--
------em
--
Quantify
Calibration
%& Study No. :L34910,
Report
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Calibration:
Last modified:
Printed:
--
---
P:\Data\L~~S6\MaPqlynx\Fluoroch~cals.PRO\~~eDB\O73103A Sun Aug 03 07:12:46 2003
Sun Aug 03 07:19:26
2003
----
--
:ompound 1 name: C8 Acid (PFOA) Coefficient of Determination: 0.986042 >alibration curve: 293.343 l x + 445.057 Response type: External Std, Area :urve type: Linear, Origin: Exclude, Weighting:
3.22e5
l/x, Axis trans: None
--Page 1
Decatur BC
X
X
Response
0.0 Rxygen Research,
200.0
I r I ,, I 1 I ,, .
400.0
600.0
I ,I I 1 )I r I $, I I IT ,ng/l
800.0
1000.0
3058 Research Drive,
State College,
PA 16801
000054
-----
----------
_----------
------mm-
Quantify Calibration
Report
\J Study No.:L34910,
Set No.: 073103A, Eact.Date:07/31/03,
Analyst:K.Risha
Calibration:
Last modified: Printed:
P:\Data\L~SBIS6\~sslynx\Fluoroch~cals.PRO\~~eDB\O73lO3A
Sun Aug 03 07:12:46 2003 Sun Aug 03 07:19:26 2003
Compound 2 name: C6 Sulfonate (PFHS) Coefficient of Determination: 0.989093 lalibration curve: 55.9970 * x + -23.5660 Response type: External Std, Area Curve type: Linear, Origin: Exclude, Weighting:
6.09e4 1
l/x, Axis trans: None
--
Page 2 Decatur BC
. X
E%y!Jen Research, 3058 Research Drive, State College, PA 16601
Quantify Calibration
Report
td Study No.:L34910,
Set No .:073103A,
Ext.Date:O7/31/03,
Analyst:K.Risha
Calibration: Last modified:
Printed:
P:\Data\LCMflrlS6\Masslynx\Fluorochemicals.PRO\~~eDR\O73103A
Sun Aug 03 07:12:46 2003
Sun Aug 03 07:19:26
2003
;ompound 3 name: C8 Sulfonate (PFOS) ioefficient of Determination: 0.992844 ialibration curve: 34.2805 ' x + 56.2500 tesponse type: External Std, Area :urve type: Linear, Origin: Exclude, Weighting:
3.57e4
l/x, Axis Vans: None
Page 3 Decatur BC
Response
0.0 Oxygen Research,
200.0
400.0
600.0
3058 Research Drive, State College, EA 16801
800.0
1000.0
000056
Quantify Calibration
Report
w
Study No .:L34910,
Set No.: 0731031,
Ext.Date:O7/31/03,
Analyst:K.Risha
Calibration: Last modified: Printed:
P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\~~eDB\O73103A
Sun Aug 03 07:12:46 2003 Sun Aug 03 07:19:26 2003
Compound 4 name: PFOSA Coefficient of Determination: 0.995963 :alibration cuwe: 134.313 l x + 78.1882 Response type: External Std, Area :urve type: Linear, Origin: Exclude, Weighting:
1.39e5
l/x, Axis trans: None
Page 4 Decatur BC
X
Response
Exygen Research, 3058 Research Drive, State College, PA 16801
----
-----
___l-----
-----__---_
Quantify Sample Report
Lif Study No. :L34910,
Set No.: 073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Page 1
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\L~SMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LC3HSMS6\Masslynx\Pluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
-------
Sun Aug 03 07:19:29
___-----------
2003 ________-------l_-l____________I____
Name : 073103A-1001 Text:
1: C8 Acid (PFOA)
XCO72503-0,O rig/L Standard
073103A-1001 Sm (Mn, 2x3)
01 -Aug-2003 09:24:14
LC/MS/MS #6
MRM of 4 Channels ES-
413> 369
1.22e4
9.14
Area
550
$4& 2: c6 Sulfonate
(PFHS)
XCO72503-0,O rig/L Standard
073103A-100l'Sm
(Mn, 2x3)
,
3: C8 Sulfonate
(PFO.5)
XCO72503-0,O rig/L Standard
073103A-1001 lOO-
Sm (Mn, 2x3)
Ol-Aug-2003 09:24:1
I,
w
MRM of 4 Channels ES-
01 -Aug-2003 09:24:11 LC/MS/MS #it
il MRM of 4 Channels ES-
(J .,.,,,,.,,,,,,,,,,,,,~,,,,.~,,,,,,,,,,,,,,~,,.~,,,,,,~,~.,,~Tjme
W-
2.00
4.00
6.00
8.00
10.00
Wgen Research, 3056 Research Drive, State College, PA 16601
12.00
000058
Quantify Sample Report
\d Study No.:L34910,
set NO .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Page 2
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LWSMS6\Wllsslynx\Fluorochemicals.PRO\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LCWSMS6\Wasslynx\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
---------------A----_-------
-----p
B---e--
Name : 073103A-3001 Text:
4: PFOSA
XCO72503-0,
0 rig/L Standard
073103A-1001 Sm (Mn, 2x3)
09:24:14 LC/MS/MS #6
RM of 4 Channels ES-
2.00
4.00
6.00
8.00
10.00
12.00
W
Exygen Research, 3058 Research Drive, State College, PA 16801
000059
Quantify Sample Report
Y& Study No.:L34910,
Set No.: 073103A, Ext,Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LO1I~S6\Wlsslynx\Bluoroch~cals.~RO\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluorochsmicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 3
Decatur BC BC 080103
Name: 073103A-3002 Text :
L: C8 Acid (PFOA)
KC072503-I,25 rig/L Standard
073103A-1002 10
Sm (Mn, 2x3)
% j
9.16
8614 I
. .
01 -Aug-2003 09:45:57 LC/MS/MS #6
MRM of 4 Channels ES413> 369 5.36e4 Area
I,
Time
2.00
2: C6 Sulfonate
KC072503-1,25
(PFHS)
rig/L Standard
073103A-1002 Sm (Mn, 2x3)
10
8.99
1401
%-
om.-.
`I ' " a, ", , r " `I x s ' , 7 8 ' I " " ,"`I
2.00
4.00
6.00
8.00
Ol-Aug-2003 09:45:5 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 8.90e3 Area
Y^-------------I 10.00
I
Time 12.00
3: C8 Sulfonate
XCO72503-1,25
(PFOS)
rig/L Standard
073103A-1002 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 09:45:57
LC/MS/MS #6
MRM of 4 Channels ES-
9.26-
499 > 99
971
6.30e3
Area
0 ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,r,,,~,~~~~,~~~~,~~~~,~~~~1Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000060
Quantify Sample Report
WI& Study No.:L34910,
Set No.: 073103A,
Ext,Date:O7/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluoroch~ca~s.PRO\SamgleDB\073l03A
Sun Aug 03 07:08:13
2003
P:\Data\L~sMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Page 4
Decatur BC BC 080103
Printed:
-------------_------
Sun Aug 03 07:19:29 2003
_I_-____-----------
--------------_
Name: Text:
073103A-1002
4: PFOSA
XCO72503-1,25
rig/L Standard
073103A-1002 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 0934535;
LC/MS/MS #E
MRM of 4 Channels ES-
9.88-
498 > 7E
3440
1.94e4
Area
0 "",,`","","","","","","","","'
, , , , , , ,-,Time
2.00
4.00
6.00
8.00
10.00
12.00
when Research, 3058 Research Drive, State College, PA 16801
000061
Quantify Sample Report
qJI Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:X.Risha
SarPple List: Last modified: Method: Last modified: Job code:
P:\Data\LCMSMS6\~eslynx\Fluoroch~cal~.PRO\S~~eDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\FluorochemicalaB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 5
Decatur BC BC 080103
Name: 073103A-1003 Text :
1: C8 Acid (PFOA)
XCO72503-2, 50 rig/L Standard
073103A-1003 loo-
Sm (Mn, 2x3)
%-
01 -Aug-2003 10:07:44
LC/MSNS #6
MRM of 4 Channels ES-
9.15
413> 369
9.76e4
Area
: C6 Sulfonate
:CO72503-2,50
(PFHS)
rig/L Standard
,73103A-1003 Sm (Mn, 2x3)
8.9s ) 284: z
01 -Aug-2003 10:07:44
LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.82e4 Area
2.00
4.00
I S
8.00 -
10.00
Time 1 12.00
I: C8 Sulfonate
(PFOS)
cCO72503-2,50 q/L Standard
01 -Aug-2003 10:07:44
LC/MS/MS #6
373103A-1003 10
%!3
Sm (Mn, 2x3)
MRM of 4 Channels ES9.2E 196:
Area
lir_;;.,
4919T.1im7>ee499
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000062
----I_------______---------
----
--
Quantify
SalrQle Report
'IW Study No .:L34910,
Set No.:O731031,
Ea&.Date:07/31/03,
Analyst:K..Risha
Page 6
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\L~SMS6\Masslynx\Bluoroch~ca~s.P~\S~~eDB\O73lO3A Sun Aug 03 07:08:13 2003
P:\Data\LCMSMS6\Masslynx\FluorochamicalsB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
-----_
-we-___
------we---__
--_^_---
Name: 073103A-1003 Text :
4: PFOSA
XCO72503-2,
50 rig/L Standard
073103A-1003 100-
Sm (Mn, 2x3)
%-
01 -Aug-2003 10:07:44
LC/MS/MS #t
MRM of 4 Channels ES-
9.89-
498 > 7~
$725
3.6aef
AreE
Oxygen Research, 3058 Research Drive, State College, PA 16801
000063
Qlmeify
Sample Report
'W Study No.: L34910, Set No.: 073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Page 7
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\~SMS6\Masslynx\Fluorochemica~s.~RO\S~leDB\O73103A
Sun Aug 03 07:08:13 2003 P:\Data\LCMmS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: ---
Sun Aug 03 07:19:29 ~------
2003 -~---_
-I___-
-----
Name: 0731031-3004 Text :
: C8 Acid (PFOA)
*.' :': b:-.-. .
(CO72503-3,100 rig/L Staijd'ard -
)73103A-1004 10
Sm (Mrt, 2x3)
9.15 29438
01 -Aug-2003 10:29:31)
LC/MS/MS #6
MRM of 4 Channels ES413>369 1.81e5 Area
2: C6 Sulfonate
XCO72503-3,100
(PFHS)
rig/L Standard
073103A-1004 10
Sm (Mn, 2x3)
Time 12.00 _
01 -Aug-2003 10:29:31
LC/MS/MS #6
MRM of 4 Channels ES-
9.01
399 > 80
5604
3.44e4
Area -
3: C8 Sulfonate
XCO72503-3,100
(PFOS)
rig/L Standard
073103A-1004 lOO-
Sm (Mn, 2x3)
%-
9.26 3040T
0%Aug-2003 10:29:31 LC/MS/MS #6
MAM of 4 Channels ES499 > 99 1.92e4 Area
0 I , , 1 , TT-&
, I I 1 1 Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000064
Quantify Sample Report
V Study No.:L34910,
Set No. :073103A,
Rxt.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~~6\Masslynx\Fluoroch~cal~.PRO\S~~eDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCIMSMS6\Masslynx\Fluorocheacicals.PRO\Met~R\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 8
Decatur BC RC 080103
NallW: 073103A-1004 Text :
4: PFOSA
XCO72503-3,100
rig/L Standard,
073103A-1004 100-
Sm (Mn, 2x3)
%-
01 -Aug-2003 10:29:3'
LC/MS/MS #t
MRM of 4 Channels ES-
9.89
498 > 71
7.20er
Are:
0 ~"`["","","","","`,~,,,`,,,`,,,`,,,,,,,
Time
2.00
4.00
6.00
8.00
10.00
12.00 J
RxYgen Research, 3058 Research Drive, State College, PA 16801
Quantify Sample Report
I,& Study No.:L34910,
Set No.: 073103A,
E&.Date:O7/31/03,
Analyst:K.Risha
Page 9
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\Fluoroch~cal~.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:X3 2003 P:\Data\L~fl3S6\nsslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
----
----___-___-----------------__-_l__l_______
Name : 0'?3303A-3005 Text :
1: C8 Acid (PFOA)
YCO72503-4,250 rig/L Standard
)73103A-1005 Sm (Mn, 2x3)
. +
9.15 66169
01 -Aug-2003 lo:51 :16
LCYMSIMS #6
MRM of 4 Channels ES413>369 4.06e5 Area
2.00
4.00
6.00
8.00
10.00
12.00
1: C6 Sulfonate
XCO72503-4,250
(PFHS)
rig/L Standard
073103A-1005 10
Sm (Mn, 2x3)
8.99 13137
Ol-Aug-2003 10:51:1i/ LC/MS/MS #6
MRM of 4 Channels ES399 > 80 8.1 Oe4 Area
pm
Time /
2.00
4.00
6.00
8.00
10.00
12.00 1
3: c8 Sulfonate
XCO72503-4,250
(PFOS)
rig/L Standard
073103A-1005 Sm (Mn, 2x3)
Ol-Aug-2003 10:51:16 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 4.43e4
-;roioo. Tim/e
6.00
8.00
12.00
Exygen Research, 3058 Research Drive,
State College,
PA 16301
Quantify Saw18 Report
&,& Study No.:L34910,
Set No.: 0731031,
Rxt.Dats:07/31/03,
A.nalyst:K.Risha
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LQ1ISMS6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LQISMS6\Maoslyax\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 10
Decatur BC SC 080103
Name: 073103A-1005 Text :
4: PFOSA
XCO72503-4,250
rig/L Standard
073103A-1005 lob
Sm (Mn, 2x3)
%-
Ol-Aug-2003 10:51:16
LC/MS/MS #6
MRM 9.90
313403 .. .-
of 4 Channels ES498 > 78 1.69e5 Area
0 "","",l"`,"","","","l',"","","'
, , , I, ,Time
2.00
4.00
6.00
a.00
10.00
12.00
ExyOen Research, 3058 Research Drive, State Collage, PA 16801
000067
----m-------v
_-------
Quantify SaqG3 Report
94 Study No.:L34910,
Set No .:073103A, Ekt.Date:O7/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\L~~S6\~sslynx\Fluorochamfcale.PRO\SampleDB\O731O3A
Sun Aug 03 07:08:13 2003 P:\Data\L~SMS6\Masslynx\FluorochemicaR\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
-----_
Page 11
Decatur BC EC 080103
Name : 07310331~1006 Text :
1: CB Acid (PFOA)
XCO72503-5,500 rig/L Standard
073103A-1006 100-
Sm (Mn, 2x3)
%-
0%Aug-2003 11:12:56 LCYMWMS #6
MRM of 4 Channels ES413>369 8.51e5 Area
0 ",,I;;","","","","","",",`,""
I , , I 1 ( I / , , , Time
2.00
4.00
6.00
8.00
10.00
12.00
Fr3' 2: C6 Sulfonate
XCO72503-5,500
(PFHS)
rig/L Standard
073103A-1006 100-J
Sm (Mn, 2x3)
%-
01 -Aug-2003 11 :12:58
LC/MS/MS #6
8.99
269767
MRM of 4 Channels ES399 > 80 1.64e5
Area
-
0 "","","",",.,,,.`,"","","","",`,","",",.,
Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
XCO72503-5,500
(PFO.5)
&L Standard
073103A-1006 10
Sm (Mn, 2x3)
%
Ol-Aug-2003 11:12:561
LCYMWMS #6
MRM of 4 Channels ES499 > 99 1.03e5 Area
1
ExYCJea Research, 3058 Research Drive, State College, PA 16801
000068
Quantify Sample Report
w Study No.rL34910,
Set No.: 073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\FluorochbmicalS.PRO\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LCM~S6\bsslynx\FluorocbemiB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 12
Decatur BC BC 080103
Name: 073103A-1006 Text :
: PFOSA
KO72503-5,500 rig/L Standard
01 -Aug-2003 11:12:56
LWMWMS #6
173103A-1006 Sm (Mn, 2x3)
MRM of 4 Channels ES-
IO 7 i
9.90 65685 r
%3O'~~","`~,~~~~,~~~~,`~~~,~~~~,~~~',,~~~,~~~~,~~~
i--
2.00
4.00
6.00
8.00
10.00
498 > ,78 3.53e5 Area
Time 12.00
W
Exygen Research, 3058 Research Drive, State College, PA 16801
060069
Quantify Sanqple Report stuay No.: L34910, Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modifiec:
Method:
Last modified: Job Code:
P:\Data\L~S6\Msslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\~SMS6\Masslynx\Fluorochamicals.PRO\~et~B\D~catur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29
2003
Page 13
Decatur BC BC 080103
Name:
Text:
0731031-1007
1: C8 Acid (PFOA)
)I:CO72503-6, 1000 rig/L Standard
C)73103A-1007 10
Sm (Mn, 2x3)
9.13 264455 I
01 -Aug-2003 11:34:&j
LC/MS/MS #6
MRM of 4 Channels ES413> 369 1.57e6 Area
2: C6 Sulfonate
XCO72503-6,lOOO
(PFHS)
rig/L Standard
073103A-1007 Sm (Mn, 2x3)
A--
Time
12.00
8.97 51345'
01 -Aug-2003 11:34:44 LCNSIMS #6
MRM of 4 Channels ES399 > 80 3.1485 Area
2.00
4.00
6.00
8.00
10100
12100 1
3: C8 Sulfonate
XCO72503-6,1000
(PFOS)
rig/L Standard
073103A-1007 lOO-
Sm (Mn, 2x3)
%-
9.25 _ 32298
01 -Aug-2003 11:34:42 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.87e5 Area
0 "","","","","","","","","",
, , , , , , , , , , , Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research,
3058 Research
Drive, State College,
PA 16801
000070
s---m-
---w--
------
----w---Y-
Quantify S-10 Report
v
Study No.:L34910,
Set No.: 073103& Ext.Date:07/31/03,
Analyst:K.Riaha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SMS6\bsslynx\Fluoroch~cals.P~O\S~leDB\O73lO3A
Sun Aug 03 07:08:13 2003 P:\Data\L~SMS6\Masslyax\Fluorochemicals.PRO\MathDB\Decatur Sun Aug 03 07:13:59 2003
Printed:
Sun Aug 03 07:19:29 2003
----
Pags 14
Decatur EC BC 080103
Name:
Text:
073103A-1007
4: PFOSA
XCO72503-6,lOOO
rig/L Standard
073103A-1007 loo-
Sm (Mn, 2x3)
%-
Ol-Aug-2003 11:34:4:
LC/MS/MS #E
MRM of 4 Channels ES-
9.91 12776Cj7
498 > 7e 6.79e5
Area
Oxygen Research, 3058 Research Drive, State College, PA 16801
000071
---
----
Quantify
Sample Report
I& Study No.:L34910,
Set No .:073103A,
--------Ext.Date:07/31/03,
-------___ Analyst:K.Rfsha
Page 15
Santgle List:
Last modified:
Method: Last modif isd: Job Code:
P:\Data\MIMSraS6\Masal~\Fluoroch~Ca~S.PRO\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LQrl~S6\Massl~\Fluorochemica\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29
2003
--------------____----__----------
----------------_-
Name: 073103A-1008 Text :
1: C8 Acid (PFOA)
Methanol Wash
073103A-1008 IOO-
Sm (Mn, 2x3)
%-
,. .
01 -Aug-2003 11:56:3C
.
LC/MS/MS #6
MRM of 4 Channels ES-
9.13
413 >. 369
3.92e3
Area
1 0 ,~,~,.,,~,.~,~,~.,,,,,,,,,,~~,~~~~,~~~~,~~~~,~.~~,~,~~,~~~~,Time
2.00
4.00
6.00
8.00
10.00
\ 12.00
I& 2: C6 Sulfonate
(PFHS)
Methanol Wash
073103A-1008
lOO0.21
Sm (Mn, 2x3)
%-
01 -Aug-2003 11:56:3C
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
1.03e3
*
0 "","","","","","","","","'*,",~I~~',I..~~l
2.00
4.00
6.00
Time
8.00
10.00
12.00
3: C8 Sulfonate
[Methanol Wash
(PFOS)
073103A-1008 Sm (.Mn, 2x3) ,
. 01 -Aug-2003 11:56:3( LC/MS/MS #E
MRM of 4 Channels ES499 > 9s 932
J 0 ,,,,,,,,,,,~,,,,,,,,,,,,,,,,.,,,,,,,~~~,~,,~,,,~,,~~~,,~,,~~Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000072
Quantify
Sample Report
\d Study No.:L34910,
Set No.: 073103A, Eact.Date:07/31/03,
Analyst:K.Risha
Page 16
Sample List: Last amdified: Method: Last modified: Job Code:
P:\Data\L~~S6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\L~~S6\Massl~\Fluoroch~cals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
-------em
-----__
----
--
---
Name: 073103A-1008 Text :
4: PFOSA
Methanol Wash
073103A-1008 Sm (Mn, 2x3)
-Aug-2003 11:56:3( LC/MS/MS #E
MRM of 4 Channels ES498 > 7E 90:
r t Time 12.00
EKygsn Research, 3058 Ressarch Drive, State College, PA 16801
000073
Quantify Sample Report Study No.: L34910, Set No.:073103A,
Eact.Date:07/31/03,
Analyat:K.Risha
Sample Li6t: Last modified: Method: Last modified: Job Code:
P:\Data\LCW~S6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\~SMS6\Mnsslyrur\FluorochsmicaB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29
2003
Page i7
Decatur BC BC 080103
Nemo: 073103A-1009
Text :
1: C8 Acid (PFOA)
10106020 Control
/073103A-1009 Sm (Mn, 2x3)
%-
. .* _. -. . . -.-
01 -Aug-2003 12:18:Ofj LCNSIMS #6.
MRM of 4 Channels ES413 > 369 1.72e4 Area
9.15 859
0 "",""""`,"","",""I"","",`,,`,,,",,,,,,,,,',
Time
2.00
4.00
6.00
8.00
10.00
12.00
2: c6 Sulfonate 0106020 Control
(PFHS)
073103A-1009 Sm (Mn, 2x3)
01 -Aug-2003 12:18:08 LC/MS/MS #6
MRM of 4 Channels ESloo42 l l .55 3% > 80 765
0 "","","","","","","","`.I"","","","",
Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
0106020 Control
(PFOS)
01 -Aug-2003 12:18:08
I
LClMS/MS #6
MRM of 4 Channels ES-
499 > 99
Exygen Research, 3058 Research Drive, State College, PA 16801
000074
--w---m--
Quantify
Ssmpls Report
&,# Study No.:L34910,
Set No .:073103A,
Ext.Date:O7/31/03,
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\L~SMS6\~sslynx\Bluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\~~S6\Masslynx\FluorochemiB\Decatur
Sun Aug 03 07:11:59
2003
Printed: -----
Sun Aug 03 07:19:29
2003
---
------------
Name: 073103A-1009
Text :
-4: PFOSA
0106020 Control
073103A-1009Sm(Mn,2x3) loo-
: %-
--P--------w
tialyst:K.Risha
--
Page 18
Decatur
SC
BC 080103
m----
Ol-Aug-2003 12:18:0t LC/MS/MS #E
RMof4ChannelsES498> 7E
I I Time 12.00
Exygen Research, 3058 Research
Drive,
State College,
PA 16801
Quantify Saxqle Report Study No.:L34910, Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified:
Method:
Last modified: Job Code:
P:\Data\M1WSMS6\~ssl~\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Rug 03 07:08:13 2003 P:\Data\M41SMS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07x11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 19
Decatur BC BC 080103
Name: 073103A-1010 Text : I1.: CB Acid (PFOA)
0106020 Spk A, 50 rig/L
073103A-1010 Sm (Mn, 2x3)
01 -Aug-2003 12:39:57 LC/MS/MS #6
MRM of 4 Channels ES413>369 8.95e4 Area
2.00
'u 2: C6 Sulfonate (PFHS) 0106020 Spk A, 50 rig/L
073103A-1010 100-
Sm (Mn, 2x3)
%-
Time
6.00
8.00
10.00
12.00
01 -Aug-2003 12:39:57
LC/MS/MS #6
MRM of 4 Channels ES-
8.99
399 > 80
1.73e4
Area
0 ..,.,.~,,,,,,,,,,,,,,,,.,,.,.,,,,,,,...,,
, , , , , I , , , , , , ,Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate (PFOS) 0106020 Spk A, 50 rig/L
073103A-1010 lOO-
Sm (Mn, 2x3)
%-
01 -A~~-2003 12:39:57
LC/MS/MS #6
MRM of 4 Channels ES-
9.27
499 > 99
1673
1.08e4
Area
Or--,
1 rTITime
2.00
4.00
6.00
8.00
10.00
12.00
EKygen Research, 3058 Research Drive, State College, PA 16801
000076
Quantify Sample Report
'114 Study No.:L34910,
Set No.: 073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LCM~S6\bLasslynx\Pluoroch~cals.PRO\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\L(SMSWS6\Masslynx\Fruorochamicalr
Sun Aug 03 07:11:59 2003
Printed: ----
Sun Aug 03 07:19:29 2003 ------Pm..-------es
---e-s-_
Name: 073103A-1010 Text :
4: PFOSA
0106020 Spk A, 50 rig/L
073103A-1010 Sm (Mn, 2x3)
Page 20
Decatur BC BC 080103
--
01 -Aug-2003 12:39:57 LCIMSIMS #6
MRM of 4 Channels ES498 > 78 3.70e4 Area
Time 12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000077
----
----__-____-
-----B--P
m--e--
Quantify Sample Report
rd
Study No .:L34910,
Set No.: 073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
La;tCFdiified: :
P:\Data\LCWSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13 2003 P:\Data\L~SMS6\Massl~\Fluorochemica\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 21 Decatur BC
BC 080103
Printed: ---_----
Sun Aug 03 07:19:29 2003 -----------------a--
_-------__
---
---
Name: 073103A-1013
Text :
1: C8 Acid (PFOA)
0106020 Spk B, 500 rig/L
073103A-1011 lOO-
Sm (Mn, 2x3)
%-
:
9.15
13290g7
01 -Aug-2003 13:01:43 LC/MS/MS #6
MRM of 4 Channels ES413>369 7.82e5 Area
O-o*,
, , I I I , t , , 1 Time
2.00
4.00
6.00
8.00
10.00
12.00
!: C6 Sulfonate
(PFHS)
D106020 Spk B, 500 rig/L
073103A-1011 10
Sm (Mn, 2x3)
8.99 26598
Ol-Aug-2003 13:01:43j LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.54e5 Area
`-"I"`-`T""
Time 1
2.00
4.00
6.00
8.00
10.00
12.00
: C8 Sulfonate
(PFOS)
1106020 Spk B, 500 rig/L
)73103A-1011 10
"i %
Sm (Mn, 2x3)
^ ^-
Y.Z/
151919
Ol-Aug-2003 13:01:4: LCYMWMS #E
MRM of 4 Channels ES499 > 99 8.83e4 Area
i
L--
Time
2.00
4.00
6.00
8.00
10.00
12.00
men Research, 3058 Research Drive, State College, PA 16801
0000%3
Quantify Sam&a ReDort
&f Study No.:L34910,
Set No .:073103A,
Ext.Dater07/31/03,
Analyst:X.Risha
Page 22
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\L~~S6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13 2003
P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29
2003
-----------
----------
Name: 073103A-1011 Text :
4: PFOSA
0106020 Spk B, 500 rig/L
073103A-1011 100-
Sm (Mn, 2x3)
%-
,
01 -Aug-2003 13:01:43
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
3.29e5
Area
ExyOen Research, 3058 Research Drive, State College, PA 16801
Quantify Sanlpls Report Study No.: L34910, Set No.: 073103A,
Ext.Datar07/31/03,
A.ualyrrt:K.Risha
Sampls List:
Last modified: Method:
Last anodifisd: Job Code:
P:\Data\LQIS1IIS6\~ssl~\F~uoroch~cal6.PRO\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LOHSMS6\Masslynx\Fluorochsmicr\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 23
Decatur BC BC 080103
Name: 073103A-1012 Text :
L: CB Acid (PFOA)
L34910-1 Spk C, 5000 rig/L,
DF=lO
073103A-1012 lOO-
Sm (Mn, 2x3)
%-
9.14 2392473
01 -Aug-2003 13:23:31
LC/MS/MS #6
MRM of 4 Channels ES-
413>369
1.38e6
-
Area
0 ~,,,~-,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,~,,,~,.,,,..,,,,,,Time
1
2.00
4.00
6.00
w 2: C6 Sulfonate
(PFHS)
L34910-1 Spk C, 5000 rig/L, DF=lO
073103A-1012 100-
Sm (Mn, 2x3)
%-
8.00
8.98 _ 30859
10.00
12.00 ,
0%Aug-2003 13:23:31
LCfMS/MS #6
MRM of 4 Channels ES399 > 80 1.8485 Area
() ,,,,,,,,.,,,,~,,,,,,,,,,,,~~,,.~,,,~.~~,~~~~~~~,~~~~,~.~~,Time
2.00
4.00
6.00
: Ck3 Sulfonate
(PFOS)
-3491 O-l Spk C, 5000 rig/L, DF=lO
173103A-1012 Sm (Mn, 2x3)
8.00
9.27 5001,
10.00
12.00
01 -Aug-2003 13:23:31 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.91 e5 Area
Time
2.00
4.00
6.00
8.00
10.00
12.00
:\i,
Exygsn Research, 3058 Research Drive, State College, PA 16801
000080
Quantify Sample Report
\rcrf Study NO.:L34910,
Set No.: 073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Sanlple List: Last modified:
Method:
Last snodified: Job Code:
P:\Data\LCbl~S6\Massl~\Fluoxoch~cals.PXO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masalynx\Fluorochsmicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 24
Decatur EC BC 080103
Name: Text:
073103A-1012
: PFOSA
-3491 O-l Spk C, 5000 rig/L, DF=lO
)73103A-1012 10
Sm (.Mn, 2x3),
%
01 -Aug-2003 13:23:31]
' LC/MS/MS #6
MRM of 4 Channels ES-
9.92
7495r I
498 > 78 4.01e5
Area
4
O',`,,,,,,,,`~,.,,,,,,,.,,,,,,`,.,.,,,,,,,,,.,,,,,
L..
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000081
----
-----_
----
Quantify Sampls Report
lJ, study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Laat modified: Job Code:
P:\Data\M41S)blS6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\L~sMS6\Masslynx\Fluorochemicacatur
Sun Aug 03 07:11:59 2003
Page 25
Decatur BC BC 080103
Printed:
--------
Sun Aug 03 07:19:29
Name: 073103A-1013 Text :
2003 ----
I-----
--
L: C8 Acid (PFOA)
L34910-6 Spk D, 5000 rig/L, DF=lO
073103A-1013 10
Sm (Mn, 2x3)
% 1
0%Aug-2003 13:45:17' LCNSIMS #6
MRM of 4 Channels ES413>369 8.79e5 Area
Time
L
2.00
4.00
6.00
8.00
lo:oo
12:oo ]
14 2: Cfi Sulfonate
(PFHS)
L34910-6 Spk D, 5000 rig/L, DF=lO
073103A-1013
I tnf-L
Sm (Mn, 2x3)
01 -Aug-2003 13:45: 1i
LCnbwMS #f
MRM of 4 Channels ES-
8.98
399 > 8C
1.64eE
Aree
3#: C8 Sulfonate rI-34910-6 Spk
(PFOS)
D, 5000 rig/L,
(>73103A-1013 10
Sm (Mn, 2x3)
DF=lO
, , I , , . , , , 10.00
, ,--, Time 12.00
9.25 2029t 3-l
Ol-Aug-2003 13:45:1? LCltWMS #6
MRM of 4 Channels ES499 > 99 1.21 e5 Area
Time
w
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000082
----
P--_------
v-w
---
Quantify
Sample Report
q,,& Study No.:L34910,
Set No.: 073103A,
Ext.Date:07/31/03,
AnalYst:K.Risha
Page 26
Sample List: Last modified:
Method:
Last nmdified: Job Code:
P:\Data\L(41SPIS6\Msslynx\Fluoroch~ca~s.PRO\S~leDB\O73lO3A sun Aug 03 07:08:13 2003 P:\Data\LQll~S6\~eolynx\Pluorochsmica\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29
2003
------____---
--------p-s
I-----
Name: 073103A-1033 Text :
4: PFOSA
L34910-6 Spk D, 5000 rig/L, DF=lO
073103A-1013 100-
Sm (Mn, 2x3)
%-
01 -Aug-2003 13:45: Ii
LC/MS/MS #E
MRM of 4 Channels ES-
9.88
498 > 7E
3.48eE
Area
0 "","`~,""I"","","","","","","'
, , , , , , , , , , Time
L
2.00
4.00
6.00
8.00
10.00
12.00
QJ
Oxygen Research, 3058 Research Drive, State College, PA 16801
000083
Quantify Sample Report
1G Study No.rL34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\lvhssl~\Fluorochsmicals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\L~SMSb\Masslynx\FluorochemicalB\Decatur Sun Aug 03 07:11:59 2003
Page 27
Decatur BC
BC 080103
Printed:
Sun Aug 03 07:19:29
2003
-----
----
-.-----------I----
----v--
Name: 0731031-3014 Text :
* L34C981 OAc-lid2 S(pPkFOEA,)5000 rig/L, DF=l 0
373103A-1014 Sm (Mn, 2x3)
9.14 i-2
416651
0%Aug-2003 14:07:06 LCNWMS #6
MRM of 4 Channels ES413 2.>493e669
Area
L
w 2: C6 Sulfonate (PFHS) L34910-12 Spk E, 5000 rig/L, DF=lO
073103A-1014 lO@
Sm (Mn, 2x3)
%-
0 "~`,""1"","~`,"~`,~~~),~,,`,~~~,,~~'
2.00
4.00
6.00
I: C8 Sulfonate (PFOS) -34910-12 Spk E, 5000 rig/L, DF=lO
373103A-1014 10
Sm (Mn, 2x3)
% 4
10.00
Time 12.00
01 -Aug-2003 14:07:06 LC/MS/MS #6
MRM of 4 Channels ES-
399 > 80 3.30e5 Area -
8.00
9.24 9675r
Time 12.00
01 -Aug-2003 14:07:06 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 5.61e5 Area
Time
Oxygen Research, 3058 Research Drive, State College, PA 16801
000084
Quantify Sqlo Report
*J
Study No.:L34910,
Set No.: 073103A, Ext.Date:O7/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified: Job Cods:
P:\Data\LCMSMSb\MaaslyPx\Fluorochemicals.PRO\S~leDB\O73103A Sun Aug 03 07:08:13 2003
P:\Data\L(3WSMS6\Masslynx\FluorochamiCals.PRO\Met~B\~catur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 28
Decatur BC BC 080103
Name: 073103A-1014 Text:
: PFOSA
-3491 O-12 Spk E, 5000 rig/L, DF=l 0
173103A-1014 Sm (Mn, 2x3)
%1O'~~",~~~~,`~~.,`.~~,`.`~,...~,~"',"~~,~~~'I~~~'
2.00
4.00
6.00
01 -Aug-2003 14:07:06
LC/MS/MS #6
MAM of 4 Channels ES-
9.89 96556
7 78
1
4985.0A2ree5a
Time
8.00
10.00
12.00 ,
Wren Re8earch, 3058 Research Drive, State College, PA 16801
000085
---------------
___-_-_---
--------------me-
Quantify Sample Report N& Study No .:L34910, Set No .:073103A,
m&.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\~SaaS6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\073103A Sun Aug 03 07:08:13 2003 P:\Data\L~SMS6\Masslynx\FluorochamicalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29
2003
Page 29
Decatur BC BC 080103
Neme: 073103A-1015 Text:
.: CEI Acid (PFOA)
L3491 O-1 6 Spk F, 5000 rig/L,
DF=lO
373103A-1015 Sm (Mn, 2x3) ,. lOO-
%-
01 -Aug-2003 14:28:57j LC/MS/MS #6
MRM of 4 Channels ES413>369 2.96e6 Area
L34910-16 Spk F, 5000 rig/L, DF=lO
073103A-1015 100-
Sm (Mn, 2x3)
%-
L34910-16 Spk F, 5000 rig/L, DFdO
073103A-1015 lOO-
Sm (Mn, 2x3)
%-
0 "")""I""I""1~"`I""I~"`l""1""1
2.00
4.00
6.00
0%Aug-2003 14:28:57
LWMSNS #6
MRM of 4 Channels ES-
8.98
399 > 80
3.61 e5
Area
,,,, , , , , , III ,lTime
10.00
12.00
01 -Aug-2003 14:28:5?
LCIMSIMS #6
MRM of 4 Channels ES499 > 99 6.80e5 Area
, 1 I I , j I . I I I Time
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000086
Quantify Sarqple Report
lulr/ Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:X.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Massl~\Fluoroch~cals.PRO\S~leDB\O73~03A Sun Aug 03 07:08:13 2003 P:\Data\LCMSNS6\Masslynx\Fluorochemicars\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Name: 0733.031-I.015 Text :
Page 30
Decatur BC BC 080103
L3491 O-1 6 Spk F, 5000 rig/L, DF=lO
073103A-1015 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 14:28:57
LCNSIMS #6
MRM of 4 Channels ES-
9.90 1070943
498 > 78 5.50e5
Area
0 ~,,,~,,,.,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,~,,,,,~,,,~,,,~,lTime
2.00
4.00
6.00
8.00
10.00
12.00
ExyOen Research, 3050 Research Drive, State College, PA 16801
000087
Quantify
Sample Report
p4 Study No.: L34910, Set No .:073103A, Xxt.Date:O7/31/03,
Analyst:X.Risha
Page 31
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQMSMS6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\LCMSMS6\~sslynx\Fluarochemicalr
Sun Aug 03 07:11:59 2003
Decatur BC EC 080103
Printed: ----_-
Sun Aug 03 07:19:29
---
------
2003 ---------
I----------
Name: 073103A-1016 Text :
1: CB Acid (PFOA)
XCO72503-1,25 rig/L Standard
073103A-1016 Sm (Mn, 2x3)
01 -Aug-2003 14:50:44
LC/MS/MS #6
MRM of 4 Channels ES-
9.13-
413 > 369
6931
4.38e4
Area
0 "","","","`~,"","",""~"","
, , , 7mTime
2.00
4.00
6.00
8.00
10.00
12.00
!: c6 Sulfonate
(PFHS)
KC072503-1,25 rig/L Standard
073103A-1016 `OO7
Sm (Mn, 2x3)
8.98 1444 1
01 -Aug-2003 14:50:44
LC/MS/MS #6 MRM of 4 Channels ES-
399 > 80 8.96e3 Area
%$
4
lr-;;:.,
Time
-
2.00
4.00
6.00
8.00
1o:oo
12100
3: C8 Sulfonate
XCO72503-1,25
(PFOS)
rig/L Standard
073103A-1016 Sm (Mn, 2x3)
01 -Aug-2003 14:50:44/
LC/MS/MS #6
MRM of 4 Channels ES-
9.26
499 > 99
954
5.75e3
Area
m
Time
2.00
4.00
6.00
8.00
10.00
12.00
Xxygen Research, 3058 Research Drive, State College, PA 16801
000088
Quantify
Sample Report
$,# Study No.:L34910,
Set No .:073103A,
Ext,Date:07/33./03.
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\~~S6\~rrasslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:00:13
2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\~catur
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:19:29
2003
Page 32
Decatur BC BC 080103
Name: 073103A-1016 Text :
4: PFOSA
XCO72503-1,25
rig/L Standard
073103k1016 100-
Sm (Mn, 2x3)
%-
.
01 -Aug-2003 14:50:44
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
1.95e4
Area
or,,,,,,,,.,,~,,,,,,,,,,,
2.00
4.00
. , , , I , 1Time
10.00
12.00
Exygsn Research,
3058 Research Drive,
State College,
PA 16801
000089
--
--
--e-w
I_--------
Quantify Sample Report Study No.: L34910, Set No.:O731031,
Ext.Date:07/31/03,
Analyst:K.Risha
Ssmple List:
Last modified: Method: Last modified:
Job Code:
P:\Data\L~SMS6\Massl~\Fluoroch~cals.P~\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\~SMS6\~sslynx\PluorochemlcalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29
2003
----_-------___-------------_______I____________-
Name: Text:
073103A-I.017
1: C8 Acid
L3491 o-1
(PFOA)
073103A-1017Sm(Mn,2x3) lOO-
%-
Page 33
Decatur EC BC 080103
--
01 -Aug-2003 15:12:28 LC/MS/MS #6
MRM of 4 Channels ES413,369 5.12e6 Area
0 ~lll,llll,llll,llll,II.~,IIII,I,II/,,rl,llll
, , , , , , , ,
s7Tjme
2.00
4.00
6.00
8.00
10.00
12.00
2: C6 Sulfonate
L3491 O-l
(PFHS)
073103A-1017Sm(Mn,2x3) 100-
%-
01 -Aug-2003 15: 12:28
LC/MS/MS #6
a.99 5Ol627
MRM of 4 Channels ES399 > 80 3.04e5
Area *
0 ~~~.,~~,~,,~~~,~,,,,.,,,,,,,,,,,,.,,,,,,,,,,~,~,,,,,,,,,,,,Time
2.00
4.00
6.00
3: C8 Sulfonate
L3491 O-l
(PFOS)
073103A-1017 10
Sm (Mn, 2x3)
%-
8.00
9.25
2eo1a3-
10.00
12.00
01 -Aug--2003 15:12:2d LCIMSIMS #6
MRM of 4 Channels ES499 > 99 1.61e6 Area
0 ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,.,,,,~,,.,cc,.,,,,,,,.,,,Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Reeearch, 3058 Research Drive, State CoJ.lege, PA 16801
000090
Quantify
Sanwle
Report
'4
Study No.: L34910, Set No .:073103A, Ext.Data:O7/31/03,
Analyst:K.Risha
Smle List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SblS6\~Haaslynx\Fluoroch~cals.PRO\S~l~DB\O73lO3A Sun Aug 03 07:08:13 2003
P:\Data\LWSMS6\Masslynx\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 34
Decatur EC BC 080103
Name: 073103A-1017 Text : 4: PFOSA
IL3491 O-I
073103A-1017 Sm (Mn, 2x3) 100-
%-
01 -Aug-2003 15:12:28j
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
7.51e5
Area
WSJen Research,
3058 Research Drive, State College, pa 16801
_---_- --.- .
000091
Quantify Sample Report -4 Study No .:L34910, Set No.: 073103A, Ext.Data:O7/31/03,
Analyst:X.Risha
Sample List:
Last modified:
Method: Last modified: Job Code:
P:\Data\LCbl~S6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSblS6\bsasslynx\Fluorochemicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 35
Decatur BC BC 080103
Name: 073103A-1018 Text:
t: C8 Acid (PFOA)
L3491 O-l Rep
073103A-1018 10
Sm (Mn, 2x3)
%
9.13 626646
01 -Aug-2003 15:34:16 LC/MS/MS #6
MRM of 4 Channels ES413> 369 4.94e6 Area
i Time
2.00
4.00
6.00
8.00
lo:oo
12.00 ]
\IJ 2: C6 Sulfonate
L3491 O-1 Rep
(PFHS)
~-.n-.--,.7RlfY?Lblnl6.-.
4-n
IUU-
Sm(Mn,zxa)
%-
9.00 49342
01 -Aug-2003 15:34:18
LC/MS/MS #6
MRM of 4 Channels ES399 > 80 2.99e5 Area
: C8 Sulfonate
-3491 O-1 Rep
(PFOS)
373103A-1018 10
"$ J
Sm (Mn, 2x3)
9.26 27417C I
Ol-Aug-2003 15:34:1 E
LC/MS/MS #6
MRM of 4 Channels ES499 > 99
1.56eE
Area
L
Time
12.00
Oxygen Research, 3058 Research Drive, State College, pA 16801
000092
Quantify Sample Report
w
Study No.:L34910,
Set No.. .073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LBISMS6\Masslynx\Fluoroch~ca~s.PRO\S~~eDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LC1M~S6\MsslyPx\FluorochamicB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29
2003
Page 36
Decatur BC BC 080103
Name : 073103A-1018 Text :
4: PFOSA
L3491 O-l Rep
073103A-1018 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 15:34: 1E
LciMslMs #f
MRM of 4 Channels ES-
9.90
498> 7E
7.30eE
Area
, , , , , , , , 1Time
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000093
Quantify Sample Report
w Study No.rL34910,
Set No.. *073103A, Ext.Date:O7/31/03,
Analyst:K.Risha
Smnple List:
Last modified:
Method: Last modified: Job Code:
P:\Data\LCMSMS6\Maselynx\Fluorochamicals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LWSMS6\Kaaslyrur\Pluorochemicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 37
Decatur BC BC 080103
Name: Text:
073103A-1019
1: CB Acid
1-3491 o-4
(PFOA)
(173103A-1019
10
Sm (Mn, 2x3)
9.14 575640
01 -Aug-2003 15:56:0$ LC/MS/MS #i
MRM of 4 Channels ES413>369 3.34e6 Area
O',,,,,,,,,,,,,,,,,,,,~,,,,,,,,,,~~~,,~,~,~~~~~~~~,~~~,,~~~~rTime
2.00
4.00
6.00
'ccl, 2: C6 Sulfonate
L3491 o-4
(PFHS)
073103A-1019 Sm (Mn, 2x3)
8.00
8.98 3196i
10.00
12.00
01 -Aug-2003 15:56:Od LC/MS/MS #ii
MRM of 4 Channels ES399 > 80
&--
1T.9iAm7r8e5a
-
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
L3491 o-4
(PFOS)
073103A-1019 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 15:56:09
LC/MS/MS #6
MRM of 4 Channels ES-
9.26
499 > 99
1.19e6
Area
0 `~`,,"","","","","",""I"","",
, r . I v , , I , , Time
2.00
4.00
6.00
8.00
10.00
12.00
u
Oxygen Research, 3058 Research Drive, State College, PA 16801
000094
Quantify
Sample Report
\*f
Study No.:L34910,
Set No.: 0731031,
Ext.Date:07/31/03,
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LC3YI~S6\~ssl~\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\LWSMS6\~sslynx\Fluorochamicals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:19:29
2003
Analyst:K.Risha
Page 38
Decatur
BC
BC 080103
Name: 073103A-1019 Text :
4: PFOSA
.
L349l o-4
'
_. ..
073103A-1019 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 l&56:09
LC/MS/MS #6
MRM of 4 Channels ES-
9.91
498>78
5.46e5
Area
0
I#,# 1 II,llll,,jl,,l,l,,,,,,l,l
2.00
4.00
I , , I I > ,,I,,,
6.00
8.00
I 10.00
, , , ,Time 12.00
Eaqygen Research,
3058 R&march
Drive,
State College,
PA 16801
00009s
Quantify Sample Report
w Study No.:L34910,
Set No.: 073103A, lZxt.Date:07/31/03,
Analyst:K.Ri.sha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\M3MSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\~catur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 39
Decatur BC BC 080103
Name: 073103A-1020
Text :
.
: C8 Acid
1-3491 o-2
(PFOA)
(173103A-1020
10
Sm (Mn, 2x3)
9.13 605630
01 -Aug-2003 16:17:55 LC/MS/MS #6
MRM of 4 Channels ES413>369 3.49e6 Area
`-
q,& 2: C6 Sulfonate
IL3491 o-2
(PFHS)
073103A-1020 lO&
Sm (Mn, 2x3)
%-
0 "","","","","","",`~","",
2.00
4.00
6.00
3: C8 Sulfonate
L3491 o-2
(PFOS)
073103A-1020 100-
Sm (.Mn, 2x3).
%-
0 ,~,~,,~,,,,,,,,~,~,,,,,,,.,,,,,,,,,,,,,,~~~,,~,,,,,,,,.,,,,Time
2.00
4.00
6.00
V`
L
Time
12.00
0%Aug.2003 16:17:5Ei]
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
2.18e5
Area
, , I,, , , , , I, a1Tjme
8.00
10.00
12.00
9.27 1916313
0%Aug-2003 16:17:55 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.08e6 Area
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000096
Quantify
Sample Report
Study No.:L34910,
Set No .:073103A,
Ext.Dats:07/31/03,
Analyst:K.Risha
Page 40
Sample List: Last modified: Method:
Last modified:
Job Code:
P:\Data\M3HSMS6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\O73103A
Sun Aug 03 07:08:13
2003
P:\Data\LCM~S6\Masslynx\Fluoroch~cals~PRO\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Decatur BC
BC 080103
Printed:
Sun Aug 03 07:19:29 2003
--1-
-- ---------
--P--------P____
----
Neme:
Text:
0731031-3020
4: PFOSA
1L3491 o-2
073103A-1020 loo-
Sm (Mn, 2x3)
%-
01 -Aug-2003 16:17:55j
LC/MS/MS #6
MRM of 4 Channels ES-
9.92
490 w 78
4.67e5
Area
Exygen Research, 3058 Research Drive, State College, PA 16801
000097
Quantify
Sample Report
w
Study No.:L34910,
Set No.: 073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Page 41
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\LCbl~S6\~sslynx\Fluoroch~ca~s.PRO\S~leDB\O73103A
Sun AUg 03 07:08:13
2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC
BC 080103
Printed: m-m-
Sun Aug 03 07:19:29 2003
----------___
--------a---
Name: 073103A-1021 Text :
-----__
----
* C8 Acid (PFOA) -3491 O-3, DF=lOO
373103A-1021 10
Sm (Mn, 2x3)
01 -Aug-2003 163393423
LClMS/MS #6
MRM of 4 Channels ES-
413>369
3
1.73e5
Area
` 1: C6 Sulfonate (PFHS) L3491 O-3, DF=l 00
073103A-1021 10
Sm (Mn, 2x3)
Ol-Aug-2003 16:39:4
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
5426
3.25e4
Area
1
-
3: C8 Sulfonate (PFOS) L3491 O-3, DF=l 00
073103A-1021 Sm (Mn. 2x3)
01 -Aug-2003 16:39:42
LC/MS/MS #6
MRM of 4 Channels ES-
9.25
499 > 99
6016
3.45e4
Area
L______,
10.00
Time
12.00
Exygen Research, 3058 Research Drive, State Collage, PA 16801
_^ ._-.-.. ~--
l___lll_.
- _-..-....-
000098
-------___
Quantify Sample Report
\*uf Study No.:L34910,
Set No.. *073103A,
--_I_ Ext,Date:07/31/03,
-Analyst:X.Risha
--Page 42
Sarqple List: Last modified:
Method:
Last modified: Job Code:
P:\Data\~S6\Masslynx\Fluorochsmicals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\~et~B\~catur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
-----w--w---
Sun Aug 03 07:19:29
2003
-v----e---
----
------------___
Name: 073103A-1021 Text:
4: PFOSA
-3491 O-3, DF=lOO
01 -Aug-2003 16:39:42
LC/MS/MS #6
)73103A-1021 Sm (Mn, 2x3)
MRM of 4 Channels ES-
%110O-4
9.92
498 > 78
5.15e4
Area
,
o~,~i~,l~~~,~~~`,`~~~,`~~~,~,~~,~~~~,~~~~,,~~~,~~~
2.00
4.00
6.00
a.00
Exygsn Research, 3058 Research Drive, State College, PA 16801
Quantify
Sample Report
q& Study No.:L34910,
Set No.. *073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Page 43
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCM~S6\asslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\L~SMS6\~ssl~\Fluorochemi\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: ---e-m-
Sun Aug 03 07:19:29 2003 ------_-------------
--e------
Name: 013103A-1022 Text :
: c8 Acid (PF~A)
(CO72503-2,50 rig/L Standard
)73103A-1022 10
Sm (Mn, 2x3)
01 -Aug-2003 17:01:2d LC/MS/MS #6
MRM of 4 Channels ES413>369 8.40e4 Area
!: C6 Sulfonate
KC072503-2,50
(PFHS)
rig/L Standard
373103A-1022 Sm (Mn, 2x3)
6.00
8.99 2420
3: C8 Sulfonate
XCO72503-2,50
(PFOS)
rig/L Standard
073103A-1022 `Oo1
Sm (Mn, 2x3)
I ' ' ' I '7
Time
10.00
12.00
01 -Aug-2003 17:01:26 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 9.73e3 Area
z
Time
12.00
Exygen Research, 3058 Research Drive, Stats College, PA 16801
oooioo
--_I_--
--
---
Quantify
Sample Report
&& Study No.:L34910,
Set No.: 0731031,
Ext,Date:07/31/03,
Analyst:X.Risha
Page 44
Sample List: Last modified: Method:
Last modified:
Job Code:
P:\Data\LQMSMS6\Masslynx\Fluorochamicals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\L~SMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:3.9:29 2003
---
---
---------
----
-----I------
Nsme: 073103A-1022
Text :
4: PFOSA XCO72503-2,50
rig/L Standard
073103A-1022 Sm (Mn, 2x3)
01 -Aug-2003 17:01:21
LC/MS/MS #t
MRM of 4 Channels ES 498 > 7t 3.55er Are:
Time 12.00
-en
Research, 3058 Research Drive, State College, PA 16801
00~0?L01
Quantify Smle Report
fullrf Study No.:L349l.O,
Set No.: 073103A, Ext.Dats:07/31/03,
Analyst:K.Risha
Samgle Liat:
Last xmdified: Method: Last modified: Job Code:
P:\Data\LCHSMS6\~ssl~\Fluorochemicals.PRO\S~leDB\O73lO3A
!&XII Aug 03 07:08:13 2003 P:\Data\L(41SMS6\Esslynx\Fluorochamict~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 45
Decatur BC BC 080103
Name: 073103A-I.023 Text :
1: C8 Acid
IL3491 o-6
(PFOA)
073103A-1023 IOO-
Sm (Mn, 2x3)
%-
9.14 _ 173871
0%Aug-2003 17:23:1j
LC/MS/MS #6
MRM of 4 Channels ES-
413>369 1 .Ol e6 Area
0 "","","~`,"","",`~"~"","",`~~'
, I I , , , , 1 , , L , , , Time
2.00
4.00
6.00
8.00
10.00
12.00 ,
q& 2: C6 Sulfonate
L3491 O-6
(PFHS)
073103A-1023 Sm (Mn, 2x3)
0%Aug-2003 17:23:17 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 5.16e4 Area
r13 : C8 .3491
Sulfonate
o-6
(PFOS)
C)73103A-1023 Sm (Mn, 2x3)
100-l
Time 12.00
Ol-Aug-2003 17:23:17 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.66e5 Area
I
2.00
4.00
6.00
8.00
10.00
12.00 1
Emen Research, 3058 Research Drive, State College, PA 16801
000102
Quantify Sample Report
I,, Study No.:L34910,
Set No.: 073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Page 46
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SMS6\Msslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Wlselynx\Pluorochemicals.PRO\~~t~B\D~=atur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed
:
Sun Aug 03 07:19:29
2003
-m-------------w-----------
Name: 073103A-1023 Text :
---------
4: PFOSA
L3491 O-6
073103A-1023 loo-
Sm (Mn, 2x3)
%-
01 -Aug-2003 17:23:17
LC/MS/MS #6
MRM of 4 Channels ES-
9.88
498 > 78
l.Ole5
Area
W
Exygen Research, 3058 Research Drive, State College, PA 16801
000103
Quantify Sample Report
'IJ Study No.:L34910,
Set No .:073103X, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last mmiifiedr Method: Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluorochamicals.PRO\S~l~DB\O73~O3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 47
Decatur BC BC 080103
Name: 073103A-I.024 Text :
: C8 Acid (PFOA)
-3491 O-6 Rep
)73103A-1024 10
Sm (Mn, 2x3)
9.13 181075 i
01 -Aug-2003 17:45:01 LC/MS/MS #6
MRM of 4 Channels ES413>369 1.07e6 Area
2: C6 Sulfonate
IL3491 O-6 Rep
(PFHS)
073103A-1024 Sm (Mn, 2x3)
01 -Aug-2003 17:45:Oj LC/MS/MS #6
MRM of 4 Channels ES399 > 80 5.23e4 Area
Time
2.00
4.00
6.00
8.00
10.00
12.00
L3491 O-6 Rep
073103A-1024 100-
Sm (Mn, 2x3)
%-
01 -Aug-2003 17:45:071
LCIMSNS #6
MRM of 4 Channels ES499 > 99 2.62e5 Area
0 (~~~,"`~,~~~1,`)~`,~`~`1""1""l""l""l
,
, , , I I 1 Time
2.00
4.00
6.00
8.00
10.00
12.00
WSIen Research, 3050 Research Drive, State College, PA 16801
000104
----------_
------
w--w
Quantify Sample Report
ljj& Study No.:L34910,
Set No.: 073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method:
Last modified: Job code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~~eDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\~et~B\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
-----Page 48
Decatur BC BC 080103
Name: Text:
073103A-1024
4: PFOSA
l.3491 O-6 Rep
073103A-1024 lOO-
Sm (Mn, 2x3)
01 -Aug--2003 17:45:Oi LCIMSNS #E
MRM of 4 Channels ES* 498 > 7E! 1 .OleZ
Bxygen Research, 3058 Research Drive, State College, PA 16801
000105
----
-----
-----
M---e-_
Quantify S-10 Report
~II,& Study No.:L34910,
Set No .:073103A,
Ea&.Date:07/31/03,
Rnalyat:K.Riaha
Sample List: Last modified: Method: Last nmdifisd: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals~PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003
P:\Data\U3M~SS\~sslyPx\Fluorochamic\Decatur Sun Aug 03 07:11%59 2003
Printed: -em-
Sun Aug 03 07:19:29 2003 -------------_--
Name: 073103A-1025 Text :
---me-
L: C8 Acid
L34910-9
(PFOA)
073103A-1025 `*OJ
Sm (Mn, 2x3)
9.13 I 35519c )
-----
Page 49 Decatur BC BC 080103
01 -Aug-2003 l&06:53) LC/MS/MS #6
MRM of 4 Channels ES413 >A3re6a9 2.13e6
L 'culrf 2: C6 Sulfonate
IL3491 o-9
(PFHS)
073103A-1025 IOO-
Sm (Mn, 2x3)
%-
8.00 8.99 _
21096
10.00
Time 12.00 ~
Ol-Aug-2003 18:06:53/
LC/MS/MS #6
MRM of 4 Channels ES399 r 80 1.26e5 Area
0 "","",",`,"","","",""I"","'
, , I , , , 1 , I I , Time
2.00
4.00
6.00
8.00
10.00
12.00
3 : C8 Sulfonate
r I -3491 o-9
(PFOS)
()73103A-1025 Sm (Mn, 2x3)
9.24 112921
01 -Aug-2003 18:06:54 LCIMSMIIS #6
MRM of 4 Channels ES499 > 99 6.60e5 Area
Time
wW+n Research, 3058 Research Drive, State College, PA 16801
000106
---
---
Quantify Sample Report
$rf Study No.:L34910,
Set No.: 0731031, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCbl~S6\bZasslynx\Fluoroch~ca~s.PRO\S~leDB\O73103A Sun AUg 03 07:08:13 2003
P:\Data\LCMSMS6\Masslynx\Fluorochenieals.PRO\Met~B\Decatur Sun hug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 50
Decatur BC BC 080103
Name: 073103A-1025 Text :
-. c
4: PFOSA-"
L3491 O-9'
.: -
073103A-1025 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 18:06:53
LC/MS/MS #6
MRM of 4 Channels ES-
9.88
498 > 78
2.66e5
Area
0 "","","","","","",""l"","",
, I r r ( Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygea Research, 3058 Research Drive, State College, PA 16801
000107
v-e-------
-----
__-_-
------------
-------_
Quantify
Sample Report
*d
Study No.: L34910,
Set No.: 0731031,
Ext.Date:07/31/03,
Analyst:K.Rfsha
Sampl.e List:
Last modified: Method: Last modified: Job code:
P:\Data\L~SblS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73~03A
Sun Aug 03 07:08:13 2003
P:\Data\LClblSMS6\Maselynx\Fluoroch~cals.PRO\~et~B\Decatur
Sun Aug 03 07:11x59
2003
Page 51
Decatur BC BC 080103
Printed:
Sun hug 03 07:19:29
2003
----------------____-----------
-Be----
---------
Name: 073103A-1026 Text :
1: C8 Acid
13491 o-7
(PFOA)
073103A-1026 IOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 18:28:44
LC/MS/MS #6
MRM of 4 Channels ES413 > 369 2.97e6 Area
b& 2: C6 Sulfonate
13491 o-7
2.00 (PFHS)
073103A-1026 loo-
Sm (Mn, 2x3)
%-
I I ( I I I, ( I I I ,, Time
6.00
8.00
10.00
12.00
8.98 _ 33965
01 -Aug-2003 18:28:44 LWMSNS #6
MRM of 4 Channels ES399 > 80 2.04e5 Area
0 "","","",`,","","","","","","","",',,,,
Time
2.00
4.00
6.00
8.00
10.00
12.00
#: C8 Sulfonate
-3491 o-7
(PFOS)
373103A-1026 Sm (MI-I, 2x3)
9.26
149081
01 -Aug-2003 18:28:44)
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 8.38e5 Area
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000108
----
-------
---
Quantify Sample Report
$,& Study No.:L34910,
Set No.: 0731031, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Pluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 52
Decatur BC BC 080103
Name: 073103A-1026 Text :
4: PFOSA
IL3491 o-7
073103A-1026 IOO-
Sm (Mn, 2x3)
%-
01 -Au.g-2003 18:28:44/
K/MS/MS #6
MRM of 4 Channels ES-
9.92 67031
498 > 78 3.44e5
Area
0 "",""/"","~`,`~","(`,"","`J,"(`,")
I I I I I 1 Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 1680;
000109
---
---
v------p
Quantify Sample Report
$I& study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:lC.Risha
Salnple List:
Last modified: Method: Last modified:
Job Code:
P:\Data\L~SMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lo3A
Sun Aug 03 07:08:13 2003 P:\Data\L~~S6\blasslynx\FluorochamicalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
--
Sun Aug 03 07:19:29
2003
------------------------------~~~---~~~~
Name: 0731033-1027
Text :
1: C8 Acid (PFOA)
IL3491 O-8, DF=lOO
073103A-1027 Sm (Mn, 2x3) 9.13
Page 53
Decatur BC BC 080103
---
Ol-Aug-2- 003 18:50:3d LC/MS/MS #6
MRM of 4 Channels ES413>369 1.32e5 Area
`md 2I- C6 Sulfonate
(PFHS)
d4910-8, DF=lOO
173103A-1027 10
Sm (Mn, 2x3)
Time 12.00
01 -Aug-2003 18:so:ad
LC/MS/MS #6
MRM of 4 Channels ES-
8.9:
399 > 80
534
3.1 Oe4
Area
m
Time
i
2.00
4.00
6.00
8.00
1o:oo
12100
3: C8 Sulfonate
(PFOS)
L3491 O-8, DF=lOO
073103A-1027 Sm (Mn, 2x3)
01 -Aug-2003 18:50:30 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.67e4 Area
Time 12.00
Rxygen Research, 3058 Research Drive, State College, PA 16601
000110
p-m--
---------------
----ye
Quantify
Sample Report
l,&
Study No.:L34910,
Set No .:073103A,
Ekt.Dats:07/31/03,
Analyet:K.Risha
Page 54
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L(3MSMS6\Masslynx\Fluorochamicals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\L(1MSMS6\Masslynx\Fluor4chsmical\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Decatur
BC
BC 080103
Printed: ------------I_---
Sun Aug.03
07:19:29
2003 -------
-p-s---
Name: 073103A-1027 Text :
: PFOSA
-3491 O-8, DF=lOO
)73103A-1027 10
Sm (Mn, 2x3)
%
Ol-Aug-2003 18:50:8
LC/MS/MS #I
t&M 9.9c 1 563: 3
of 4 Channels ES. 498 > 71 3.03e(
Are;
/
OL;~~~,~~`~,"~~,~~`~,~~`~,~~~`,~~'.,~~~~,~"~,~~~
L
Time
2.00
4.00
6.00
8.00
10.00
12.00
ExyOen Research,
3058 Research
Drive,
State College,
PA 16801
000111
---
----
----m-w-------
---------
Quantify Sample Report
'hd Study No.:L34910,
Set No .:073103A,
Ext,Dats:07/31/03,
Analyst:lC.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\blassl~\Fluoroch~ca~s.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13 3003 P:\Data\LCMSMS6\Ezasslynx\Fluorochemicals.PRO\~et~B\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19$29
2003
s----v-
Page 55
Decatur BC BC 080103
Name:
Text:
073103A-1028
1: C8 Acid (PFOA) XCO72503-3,100 rig/L Standard
073103A-1028 Sm (Mn, 2x3)
01 -Aug-2003 19:12:2C LC/MS/MS #6
MRM of 4 Channels ES413>369 1.85e5 Area
Yd 2: C6 Sulfonate XCO72503-3,100
(PFHS) rig/L Standard
073103A-1028 Sm (Mn, 2x3)
Time 12.00 ~
Ol-Aug-2003 19:12:2C LC/MS/MS #6
MRM of 4 Channels ES399 > 80 3.59e4 Area
rI3': C8 Sulfonate
l(CO72503-3,100
(PFOS) rig/L Standard
173103A-1028 Sm (Mn, 2x3)
10
Time 12.00
01 -Aug-2003 19:12:2d LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.09e4 Area
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State Collega, PA 16801
000112
--
---
-----
Quantify
Sample Report
V& Study No.rL34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:IC.Risha
Page 56
sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\~MS6\~8slynx\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\LQMSMS6\Masslynx\FluorochemicalsB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29
2003
-------
---m---e
--I---P------_1
Name: 073103A-1028 Text :
4: PFOSA
sXC072503-3, 100 rig/L Standard
073103A-1028 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 19:lmd
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
7.45e4
Area
Exrgen Research, 3058 Research Drive, State College, PA 16801
000113
Quantify Sample Report Study No.: L34910, Set No.:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample Lfstr
Last modified: Method: Last modified:
Job Code:
P:\Data\LClrLSMS6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\O73103A
Sun Aug 03 07:08:13 2003 P:\Data\MJM~S6\Masslynx\Fluorochamicals.PRO\MethDB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07~19~29
2003
Page 57
Decatur BC BC 080103
Name: 073103A-1029
Text :
r1: C8 Acid
L34910-12
(PFOA)
073103A-1029 lOO-
Sm (Mn, 2x3)
01 -Aug-2003 19334303 LC/MS/MS #6
MRM of 4 Channels ES413>369 1.47e7 Area
%-
J
0 "","",""(""(`,,`,"","","",""
, , , , , , , , , , , , Time
2.00
4.00
6.00
8.00
10.00
12.00
2: C6 Sulfonate
13491 o-1 2
(PFHS)
073103k1029 lOO-
Sm (Mn, 2x3)
%-
8.99 259042
01 -Aug-2003 19:34:03
K/MS/MS #6
MRM of 4 Channels ES399 > 80 1.50e6 Area
0 "")"",`"`i'"`,"`~,`.","",""l"'
~ , . , , , I . , ~ , , , , Time
2.00
4.00
6.00
8.00
10.00
12.00 .
3: C8 Sulfonate
L3491 o-1 2
(PFOS)
073103A-1029 iOO--
Sm (Mn, 2x3)
%-
9.27 _ 558236
01 -Aug-2003 19:34:03 LCYMSIMS #6
MRM of 4 Channels ES499 > 99 3.19e6 Area
0 ,,.,,,,,~,,,,,,.,,,,,,,,,,~,,,~~~~,~~~~,~,~~,~~~,~~~~,~~.~lTime
2.00
4.00
6.00
8.00
10.00
12.00
Exygea Research, 3058 Research Drive, State College, PA 16801
000114
Quantify Sample Report
\IIJ Study No.:L34910,
Set No .:073103A,
Ea&.Date:07/31/03,
Analyst:R.Risha
Pags 58
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003
P:\Data\LCMSMS6\Mssslynx\Fluorochamicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
---
Sun Aug
------------------______________I_____c_--------
03 07:19:29
2003
Name: 0731031-1029 Text :
4: PFOSA
L3491 o-1 2
073103A-1029 lOO-
Sm (Mn, 2x3)
%-
Ol-Aug-2003 19:34:03
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
1.36e6
Area
0 ~~~~,~~`~,(~(`,J,`~,~~J/,/"~,~(~I,'~(',~'~~,/(~
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State Collage, PA 16801
000115
Quantify
Sample Report
p3
Study No.:L34910,
Set No .:073103A,
Ea&.Date:O7/31/03.
Analyst:X.Risha
Page 59
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCW~S6\Hassl~\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
--~-----------------~----------
Name: 073103A-1030 Text :
-----
--w-m--
1: C8 Acid (PF~A)
L3491 O-12 Rep
073103A-1030 loo-
Sm (Mn, 2x3)
%-
9.11 24251891
01 -Aug-2003 19:55:5C LC/MS/MS #6
MRM of 4 Channels ES413 > 369 1.43e7 Area
() ,,,,,,,.,,,,,,,~,,,,,,,,,,,,,,,,~~,~~~~,~~~~~~~~,~~~~,,,,,lTime
2.00
4.00
6.00
w 2: C6 Sulfonate
(PFHS)
L3491 o-1 2 Rep
073103A-1030 100,
Sm (Mn, 2x3)
%-
8.00 6.98 _
237649
10.00
12.00
Ol-Aug-2003 19:55:5C LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.45e6 Area
i: Cf3 Sulfonate
L34910-12 Rep
(PFOS)
073103A-1030 10
Sm (Mn, 2x3)
% 1 4
9.24 571211
0%Aug-2003 19:55:5C LCIMWMS #6
MRM of 4 Channels ES499 > 99 3.17e6 Area
I Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000116
Quantify Sample Report
bit Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Page 60
Sam;ple List: Last modified: Method: Last modified: Job Code:
P:\Data\LQvI~S6\Wassl~\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\LCLvISMS6\Masalynx\FluorochemicalS.PRO\MethDB\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
-----------------
------
-_-_
--------_--
-----
Name: Text:
073103A-I.030
4: PFOSA
L3491 O-l 2 Rep
073103A-1030
I `7lfXI-7
%-
Sm (Mn, 2x3)
Oi-Aug-2003 19:55:5d
LCIMSNS #6
MRM of 4 Channels ES-
9.90
498 > 78
1.32e6
Area
0 "","","","","","","",`l"~"","'
, , , , , , , , , Time
2.00
4.00
6.00
8.00
10.00
12.00
W
Oxygen Research, 3058 Research Drive, State College, PA I.6801
-.- "_,---- -
-. "..
. ,Ill-.--.------
000117
-------l____l_------____-----------
Quantify Sample Report %a.# Study No .:L34910, Set No.:O73103A,
Ext.Date:07/31/03,
knalyat:X.Risha
Swle List: Last modified: Method: Last modified: Job Code:
P:\Data\W3blSMS6\Wsssl~\F~uorochemicals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMSC\Mssslynx\Pluorochemicals~\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
--
Page 61
Decatur BC BC 080103
Name : 073103A-1031 Text :
: C8 Acid
.34910-15'
(PFOA)
.
)73103A-1031 10
% 1
Sm (Mn, 2x3)
9.13
252700:
01 -Aug-2003 20: 17:38 LC/MS/MS #6
MRM of 4 Channels ES413>369 1.47e7 Area
L
2.00
4.00
6.00
8.00
10.00
12.00
%& 2: C6 Sulfonate
(PFHS)
L3491 o-1 5
I073103A-1031 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 20:17:38( LC/MS/MS #6
MRM of 4 Channels ES-
399 >- 80 1.43e6
Area
0 "","","","","","","`l,""
2.00
4.00
I: C8 Sulfonate
134910-15
(PFOS)
373103A-1031 10
Sm (Mn, 2x3)
, , , ,, , ( , I,, , Time
6.00
8.00
10.00
12.00
9.25
560111 8
Ol-AUQ-2003 20:17:3d
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 3.15e6 Area
L-
Time
%d
2.00
4.00
6.00
8.00
10.00
12.00 J
Oxygen Research, 3058 Research Drive, State College, PA 16801
000118
Quantify Sample Report UJ Study MO.:L34910, Set No.:073103A,
Ext.Date:O7/31/03,
Analyst:X.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCM~S6\~ssl~\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\L(SM~6\Mas~l~\Fluorochemicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
-
Page 62
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
-----e-------------P
-___--------
----m-m-
-------
Name : 073103A-1031 Text :
4: PFOSA
L3491 o-1 5
073103A-1031 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 2O:i 7:3d
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
1.39e6
Area
0 "~~,~~~~/~~~~/~I.I,llll,llll[llll,l,lI,llll,,,,
I r ' I Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000119
Quantify S-10 Report
`4
Study No. : L34910, Set No.:O73103A,
Ea&.Data:07/31/03,
Analyst:X.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCJM~6\~sslynx\Fluoroch~cals.PRO\SampleDB\073103A Sun Aug 03 07:08:13 2003 P:\Data\L(3KSMS6\Masslynx\Fluorochemicalr Sun Aug 03 07:11:59 2003
Printed:
----~-----_----_I-_-------
Sun Aug 03 07:19:29
2003
------
-------____.wl_l
Name: 073103A-3032 Text :
Papa 63
Decatur BC BC 080103
L3491 o-1 3
073103A-1032 10
Sm (Mn, 2x3)
%
9.11 2649670
01 -Aug-2003 20:39:2 LCYMWMS #6
MRM of 4 Channels ES413~369 1.69e7 Arear
-i L
d
Time i
2.00
4.00
6.00
8.00
10.00
12100
qd 2: C6 Sulfonate
L3491 o-1 3
(PFHS)
Ol-Aug-2003 20:39:2
073103A-1032 loo-
Sm (Mn, 2x3)
%-
MRM of 4 Channels ES-
6.98 _ 275858
399 > 80 1.67e6
Area
-
0 ",`,"","","","",,"`,"","","'
, , , , , , , t , , , , , Time
2.00
4.00
6.00
8.00
10.00
12.00
I: C8 Sulfonate
-34910-13
(PFOS)
373103A-1032 Sm (Mn, 2x3)
9.24 66718t 3
Ol-Aug-2003 20:39:25
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 3.69e6 Area
L--
Time
2.00
4.00
6.00
8.00
10.00
12.00
XJWOen Research, 3058 Research Drive, State Collegta, PA 16801
000120
----
--a-------------
---
Quantify Sample Report '1~ Study No .:L34910, Set No.:O73103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\~~S6\~8slynx\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13 2003 P:\Data\LCblSMSb\Masslynx\FluorochemicalR\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29
2003
--
Page 64
Decatur BC SC 080103
Name: 073103A-1032
Text :
4: PFOSA
L3491 o-1 3
073103A-1032 loo-
Sm (Mn, 2x3)
%-
01 -Aug-2003 20:39:25
LCNWMS #6
MRM of 4 Channels ES-
9.90
498>7a
1.4286
Area
, , , , , , , ,, Time
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
Quantify Sample Report
VI& Study No.rL34910,
Set No.: 073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCM~S6\Masslynx\Fluoroch~ca~s.PRO\S~l~DB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicale~\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 65
Decatur BC BC 080103
Name: 0731031-1033 Text :
.: C8 Acid (PFOA)
-3491 O-1 4, DF=lOO
373103A-1033 10
Sm (Mn, 2x3)
9.12 71294
01 -Aug-2003 21:00:54 LC/MS/MS #6
MRM of 4 Channels ES413>369 4.14e5 Area
W 2: c6 Sulfonate
(WI-IS)
/IL3491 O-14, DF=lOO
073103A-1033 Sm (Mn, 2x3)
3: C8 Sulfonate
(PFOS)
L3491 O-l 4, DF=lOO
073103A-1033 100,
Sm (Mn, 2x3)
%-
~":.,,,,,,,,,,~,,,~,,,~,,~,,,~~,,,,,,~~~~,~~~~,~l~,~~~~,~~l'~Time
2.00
4.00
6.00
i.-10.00
Time 12.00
Ol-Aug-2003 21:00:58
LC/MS/MS #6
MRM of 4 Channels ES-
8.96
399 > 80
9718
5.83e4
Area
I 10.00
Time 12.00
01 -Aug-2003 21:00:58
LC/MS/MS #6
MRM of 4 Channels ES-
9.24 _ 14981
499 > 99
8.40e4
.
Area
8.00
10.00
12.00
mea
Research, 3058 Research Drive, State College, PA 16801
000122
-------
Quantify Sample Report
V Study No.:L34910,
Set No .:073103A,
----Ext.Date:07/31/03,
-Analyst:K.Risha
------_ Page 66
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\MZd~S6\Masslynx\Fluorochamicals.PRQ\S~leDS\O73103A
Sun Aug 03 07:08:13
2003
P:\Data\LCMSMS6\bhsslynx\Fluorochamicals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
--we-
Sun Aug
----------
03 07:19:29
2003 -----es-----s-e------
---------__-___-
Name: 073303A-1033 Text :
: PFOSA
-3491 O-l 4, DF=lOO
173103A-1033 10
%4"i
Sm (Mn, 2x3)
01 -Aug-2003 21 :OO:SE
LC/MS/MS #E
MRM of 4 Channels ES-
9.90 1141( 3
498 > 7e 5.88e4
Area
oL;-`~~,"~~,~~~`,`~`~,~`~~,~~~~I'~~'l~~~~I~~'~I~~r
L
Time
2.00
4.00
6.00
8.00
-en
Research, 3058 Research Drive, State College, PA 16801
000123
Quantify Simple Report
V
Study No.:L34910,
Sat No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Page 67
Sqle
List:
Last modified:
Method:
Last modified:
Job Code:
P:\Data\LQMSMS6\Masslynx\Fluoroch~cals.PRO\S~laDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\L~S6\Massl~\Fluoroch~cals.PRO\Met~B\D~catur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29
2003
-----
--a-__--
------
---------_-------------_--
------
Name: 073303A-1034 Text :
1: C8 Acid (PFOA)
.
XC072503-4,250 rig/L Standard
073103A-1034 10
Sm (Mn, 2x3)
9.13 75537
01 -Aug-2003 21:22:34 LCNSIMS #6
MRM of 4 Channels ES-
413>369 4.32e-5 Area
TT.rl
Time
2.00
4.00
6.00
8.00
10.00
12.00
!: C6 Sulfonate
XC072503-4,250
(PFHS)
rig/L Standard
073103A-1034 loo-
Sm (Mn, 2x3)
%-
01 -Aug-2003 21:22:31
LC/MS/MS #1
MRM of 4 Channels ES399 > 8( 8.49er Are:
i: C8 Sulfonate
l(CO72503-4,250
(PFOS)
rig/L Standard
9.25 8521
Time
Exygan Research, 3058 Research Drive, State Collage, PA 16801
000124
Quantify Sample Report W Study No. :L34910, Set No.: 073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Samgle List:
Last modified: Method: Last nrodified:
Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~ca~s.PRO\SanrpleDB\073103A Sun Aug 03 07:08:13 2003 P:\Data\LWSMS6\Masslynx\Fluorochemicals.PRO\~et~B\Decatur Sun Aug 03 07:11x59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 68
Decatur BC BC 060103
Name: 0731031-1034 Text :
4: PFOSA
KO72503-4,250
rig/L Standard
173103A-1034 lOC-
Sm (Mn, 2x3)
%-
01 -Aug-2003 21:22:34
LC/MS/MS #6
MRM of 4 Channels ES-
9.92 336667
498 > 78 1.7Se5
Area
%Ygen Research, 3058 Research Drive, State College, PA 16601
000125
------_l__l
----
----
-----me
Quantify Sample Report
Study No .:L34910,
Set No.r073103A,
Ext.Date:07/31/03,
Analyst:X.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\F~uotochsmicals.PRO\S~leDB\O73103A
Sun Aug 03 07:08:13 2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatu~
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:19:29
2003
Page 69
Decatur BC BC 080103
Name: 073103A-I.035
Text :
1: C8 Acid
L34910-16
(PFOA)
073103A-1035 lO(F
Sm (MI-I, 2x3)
%-
:
9.11 307297tq
. 01 -Aug-2003 21:44:25 LC/MS/MS #6
MRM of 4 Channels ES413> 369 1.8587 Area
0 ,,,~,~~~~,~~~,,~,~~,~~,,,,~~~,~~,~,~~,~,~~~~~~~~,~,,~,,~~~~Time
2.00
4.00
6.00
2: C6 Sulfonate
L3491 O-16
(PFHS)
073103A-1035 100-
Sm (Mn, 2x3)
%-
0 IIII,IIII,II.~,lll.(.lll,llll,lll,,IIII
2.00
4.00
6.00
3: C8 Sulfonate
IL3491 O-16
(PFOS)
073103A-1035 100-
Sm (Mn, 2x3)
%-
8.00 8.98
10.00
12.00 I
01 -Aug-200321:44:23
LCNS/MS #6
MRM of 4 Channels ES399 > 80 1.74e6 Area
,,,, / ,,,, I, v,Time
8.00
10.00
12.00
9.24 691 16S7
Ol-Aug-2003 21:44:24
LC/MS/MS #6
MRM of 4 Channels ES-
499 > 99 3.86e6 Area
0 ,,,~,,,,;,~,,,,,,,.,,.,,,~,,,,,,~,,,,,,,,,,,~,,,..,,,,,,.,Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000126
Quantify
Sample Report
l&
Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Page 70
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluoroch~ca~s.PRO\S~leDB\O73103A
Sun Aug 03 07:08:13
2003
P:\Data\L~SMS6\Massl~\FluorochsmicaB\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
-------m-e-----
--------------------
------_
Name: Text:
073103A-1035
4: PFOSA
L3491 O-l 6
073103A-1035 lOO-
Sm (Mn, 2x3)
%-
Ol-Aug-2003 21:44:2!
LC/MS/MS #E
MRM of 4 Channels ES-
9.90
498 > 7E
1.82eE
Aree
Exygen Research, 3058 Research Drive, State College, PA 16801
000127
Quantify Sample Report
w
Study No.:L34910,
Set No .:073103A, Ext.Date:07/31/03,
Anal.yst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\L~SblS6\MasslyPx\Fluorochamica~s.PRO\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~Ca~s.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
I_-------------I---------____l_l-
--------------__I_
Name: 0731038-1036
Text :
Page 71 Decatur BC BC 080103
--------
L3491 O-1 6 Rep
073103A-1036 lOO-
Sm (Mn, 2x3)
%-
0%Aug-2003 22:06:04
LC/MS/MS #6
MRM of 4 Channels ES413>369 1.89e7 Area
L3491 O-l 6 Rep
073103A-1036 10
Sm (Mn, 2x3)
% /j
3: CB Sulfonate
L3491 O-1 6 Rep
(PFOS)
073103A-1036 10
9
Sm (Mn, 2x3)
%-
a.98 302530
0%Aug-2003 22:06:04 LCiMSNS #6
MRM of 4 Channels ES399 > 80 1.79e6 Area
9.25 707270`1
01 -Aug-2003 22:06:04 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 3.94e6 Area
Exyoen Research, 3058 Research Drive, State College, PA 16801
000128
Quantify S-10 Report
Lf Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemica~s.P~O\S~leDB\O73lO3A
Sun Aug 03 07:08:13 2003 P:\Data\LCMSblS6\Masslynx\Pluoroch~cais.PRO\Met~B\Decat~r
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 72
Decatur BC BC 080103
Name: 073103A-1036
Text:
4: PFOa$A L3491 O-l 6 Rep
073103A-1036 1OCb
Sm (Mn, 2x3)
%-
01 -Aug-2003 22:06:04
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
1.83e6
Area
0 "","","","","","","","",`I"
2.00
4.00
6.00
8.00
, 1 I I I Time 12.00
Eawgen Research,
3058 Research
Drive,
State College,
PA 16601
000129
Quantify Sample Report
b# Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:X.Risha
Page 73
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LBISMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Kasslynx\FluorochamicaleB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29
2003
----
---I_-------_-_____-_-----------------------
F-m----
Name: Text:
073303A-3037
1: C8 Acid
L34910-19
(PFOA)
m ' .-.. "
073103A-1037 Sm (Mn, 2x3)
100, .-
`.. %-
9.11 _ 2758295
01 -Aug-2003 22:27:50
LCIMSIMS #6
MRM of 4 Channels ES413>369 1.68e7 Area
00,
I I , 1 1 , I I I 1Time
2.00
4.00
6.00
8.00
10.00
12.00
`4 2: C6 Sulfonate L3491 o-1 9
(PFHS)
073103A-1037 lOO-4
Sm (Mn, 2x3)
8.98 276429
01 -Aug-2003 22:27:X LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.67e6 Area
A---
Time
2.00
4.00
6.00
8.00
lo:oo
12100 J
3: C8 Sulfonate
L3491 o-1 9
(PFOS)
073103k1037 loo-
Sm (Mn, 2x3)
%-
01 -Aug-2003 22:27:X
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 3.82e6 Area
, , , , I , , , , . / , Time
10.00
12.00
RW%en Research, 3058 Research Drive, State College, PA 16801
000130
Quantify Sample Report
w
Study No.:L34910,
Set No .:073103A,
Bxt.Date:07/31/03,
Analyst:X.Risha
Page 74
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SMS6\~sslynx\Fluoroch~ca~S.PRO\SampleDB\073103A Sun Aug 03 07:08:13 2003 P:\Data\LQ3SMS6\Masslynx\FluorochamicalaB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
-------------------_~
e-_---s---
--------e_
------m-
Name: 073103A-1037
Text :
4: PFOSA
L3491 o-1 9
073103A-1037 lOO-
Sm (Mn, 2x3)
%-
01 -Aug-2003 22:27:5C
LC/MS/MS #6
MRM of 4 Channels ES-
9.67
498 > 78
1.89e6
Area
0 "",~~`~,~~1~,~~~~,~~~~,~~`~/~~~~,~~~',~"~,~'
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State Collage, PA 16801
."_~
___."
-
--
---
-----------------------
------_I_
Quantify Sarqple Report
'd
Study No.:L34910,
Set No .:073103A,
m&.Dats:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003
P:\Data\LCMSbIS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 75
Decatur BC BC 080103
Printed:
----
Sun Aug 03 07:19:29
2003
----~------__---------____I_____-----
Name: 0731031-1038
Text :
--e-m
--
I: C8 Acid (PFOA)
L3491 o-1 7
I(173103A-1038
10
Sm (Mn, 2x3)
9.12 I1_
310282:
01 *Aug-2003 223493403 LC/MS/MS #6
MRM of 4 Channels ES413>1 Be3769
Area
v
2: C6 Sulfonate
L3491 o-1 7
(PFHS)
073103A-1038 loo-
Sm (Mn, 2x3)
%-
3: C8 Sulfonate
L3491 o-1 7
2.00 (PFOS)
073103A-1038
1 100-l I .-- i
%-
Sm (Mn, 2x3)
10.00
Time 12.00
01 -Aug-2003 mm401
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
1.69e6
Ares
I Ir,.,,,,,.,, 10.00
/ Time 12.00
Ol-Aug-2003 22:49:4d LCIMSIMS #6
MRM of 4 Channels ES499 > 99 3.82e6 Area
ExygOa Research, 3058 Research Drive, State College, PA 16801
000/32
---w-s-
----------
-----------------_----P-e-
-
QLmltify Sample Report
hd
Study No.: L34910, Set No .:#73103A,
Ea&.Date:Q7/31/03,
Analyet:R.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCIMSbiS6\Maaslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LQMSMS6\Masslynx\Fluorochemicals\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 76
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
----e-P
-------------I------c----
------p
Name: 0731031-1038
Text :
v----s--
--
4: PFOSA
L3491 o-1 7
073103A-1038 100-
Sm (Mn, 2x3)
%-
01 -Aug-2003 22:49:4(
LCIMSNS #f
MRM of 4 Channels ES-
9.90
498 > 7E
1.60eE
Ares
Exygen Research, 3058 Research Drive, State College, PA 16801
000133
-----
------
-----__---______
---v---P--
Quantify
Sample Report
&# Study No.:L34910,
Set No .:073103X%,
Ext.Dtite:O7/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMS~S6\Masslynx\BluotocbemicaleDB\O73lO3A
Sun Aug 03 07:08:13 2003
P:\Data\LCHSMS6\Masslynx\Pluoroch~ca~s.PRO\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:19:29
2003
-----------_
Page 77
Decatur BC BC 080103
Name: 073103A-1039 Text:
: C8 Acid (PFOA)
.3491 O-l 8, DF=i 00
)73103A-1039 10
Sm (Mn, 2x3)
9.12 77205
Ol-Aug-2003 23:11:32 LCNSIMS #6
MRM of 4 Channels ES413>369 4.47e5 Area
U 2: c6 Sulfonate
(PFHS)
L3491 O-1 8, DF=lOO
073103A-1039 `OOJ
Sm (Mn, 2x3)
I_
Time
12.00
8.96 10133
01 -Aug-2003 23:11:32 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 6.07e4 Area
2.00
4.00
6.00
8.00
#: C8 Sulfonate
(PFOS)
3491 O-l 8, DF=lOO
)73103A-1039 Sm (Mn, 2x3)
01 -Aug-2003 23:11:32
LC/MS/MS #6
9.26 1407:
MRM of 4 Channels ES499 > 99 8.21 e4
Area
Time
2.00
4.00
6.00
8.00
10.00
12.00
Enqgen Research, 3058 Research Drive, State College, PA. 16801
000134
-----
__-------------
---
Quantify Sample Report bd Study No.: L34910, Set No.:073103A,
Ext.Date:07/31/03,
Analyst:X.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\L~SMS6\2sal~\Fluorochemic\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
---Page 78
Decatur BC BC 080103
Name: 073103A-1039
Text :
4: PFOSA
L34910-18,DF=lOO
073103A-1039 lo9
Sm (Mn, 2x3)
%-
0%Aug-2003 23:11:3: LC/MS/MS#~
MRM of 4 Channels ES-
192.199011
4986.5>1 7eEL
O-;,,,,,,,,,,,,,,,,,,,,~~,,,,,,,,,,,,,,,~,,,~,,,,,
I I I , I I 1 1Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000135
----
------_
______________-------------
!Juantify Sample Report
'kd Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\L~SMS6\Masslynx\FluarachemicaB\Decatur
Sun Aug 03 07:11:59 2003
Printed:
-------
Sun Aug 03 07:19:29
2003
------------------------~~-------------_____
Name: 073103A-1040
Text :
.: C8 Acid (PFOA)
l(CO72503-5,500 rig/L Standard
373103A-1040
10
% 1
Sm (Mn, 2x3)
2.00
4.00
llw( 2: C6 Sulfonate
(PFHS)
XCO72503-5,500 rig/L Standard
9.12 156964 L
I 8.00
073103A-1040 lOO-
Sm (Mn, 2x3)
8.98 29038`-`
%-
---
---
Page 79
Decatur BC BC 080103
Ol-Aug-2003 23:33:24
LC/MS/MS #6
MRM of 4 Channels ES413s 369 9.33e5 Area
10.00
Time 12.00
01 -Aug-2003 23:33:24 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.78e5 Area
0 ~`~`,`~`~,"~~,`~",~`~~,~`~~,"`~,'~~~,~~~~~'..,,,.`~,.~`~l
2.00
4.00
6.00
: C8 Sulfonate
(CO72503-5,500
(PFOS)
rig/L Standard
373103A-1040 10
Sm (Mn, 2x3)
8.00
9.24 1934' I
10.00
Time 12.00
01 -Aug-2003 23:33:24 LCIMWMS #6
MRM of 4 Channels ES499 > 99 1.13e5 Area
w I
2.00
4.00
6.00
8.00
Time 12.00
Oxygen Research, 3058 Research Drive, state College, PA 16801
000136
Quantify Sax@ple Report
14 Study No.:L34910,
Set No .:073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Page 80
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~~S6\Masslynx\Fluoroch~cals.PRO\S~laDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
sun Aug 03 07:19:29 2003
----------w--D---_-
-w-m---
--------__
----__---______
Name: Text:
073103A-3040
4: PFOSA
XCO72503-5,500
rig/L Standard
073103A-1040 IOO-
Sm (Mn, 2x3)
. %-
:. ,. ., f
01 -Aug-2003 23:33:24
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
3.86e5
Area
Oxygen Reiearch, 3058 Research Drive, State Collage, PA 16801
000137
Quantify Sample Report
'ru/ Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method: Last modified: Job Code:
P:\Data\L~~S6\Massl~\Fluoroch~cals.PRO\S~leDB\O73103A
Sun Aug 03 07:08:13 2003 P:\Data\L(3MSMS6\Masslynx\FluorochsmicalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Name: 073103A-1041 Text :
Page 81
Decatur BC BC 080103
L3491 o-25 .
073103A-1041 Sm (Mn, 2x3)
01 -Aug-2003 23:55:0
LC/MS/MS #6
MRM of 4 Channels ES-4
413> 369 1.72e4
Area
9.13
.
652
$4 2: C6 Sulfonate
L3491 o-25
2.00 (PFHS)
073103A-1041 Sm (Mn, 2x3)
I 1
0 ~~~.,~,.~,~..,,...~,~,.~,,,~~,~~~,,~.~~,,,,,,,.,,,,,~,,,,.,,Time
2.00
4.00
6.00
3: C8 Sulfonate
L3491 O-25
(PFOS)
073103A-1041 I lob I -1
Sm (Mn, 2x3)
%-
O'.,.,,,,,,,,.,,,,,..,,~.,,,,,,,,,,,,,,,,,..,~,,,,,,,,.,,,,,,,Time
2.00
4.00
6.00
10.00
12.00
01 -Aug-2003 23:55:08 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 738
I
8.00
10.00
12.00
0%Aug-2003 23:55:08
LC/MS/MS #6
MRM of 4 Channels ES-
9.22
499 > 99
3161
2.21e3
Area
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000138
Quantify Sauqle Report
'4
Study No.: L34910, Set No.: 073303A, Ext.Date:O7/31/03,
Analyst:K.Risha
Sample Ilist:
Last modified: Method: Last modified:
Job Code:
P:\Data\LCHSMS6\Masslynx\Fluorochemicbls.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
P&ted:
Sun Aug 03 07:19:29
2003
Page 82
Decatur BC BC 080103
Name: 0731031-1041 Text :
4: PFOSA
L3491 o-25
073103A-1041 Sm (Mn, 2x3)
I
1-Aug-2003 23:55:08 LC/MS/MS #6
MRM of 4 Channels ES498 > 78 1.12e3
ExyOen Research, 3058 Research Drive, State College, PA 16801
000139
Quantify
Saxnple Report
& Study No.:L34910,
Set No .:073l.O3A.
Ea&.Date:07/31/03,
Analyst:K.Risha
Page 03
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\U3H~S6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslyax\Pluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:19:29 2003
---------_------_----------------~-----------___---
N-2 073103x&-I.042 Text :
1: C8 Acid (PFOA)
L3491 O-26
073103A-1042 10
Sm (Mn, 2x3)
. .
02-Aug-2003 00:16:59
LC/MS/MS #6
MRM of 4 Channels ES-
413>369
1.93e4
Area
2.00
4.00
6.00
8.00
10.00
12.00
%& 2: C6 Sulfonate
L3491 O-26
(PFHS)
02-Aug-2003 00:16:59 LC/MS/MS #6
MRM of 4 Channels ES399 > 80
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
L3491 O-26
(PFOS)
073103A-1042 lOO-
Sm (Mn, 2x3)
02-Aug-2003 00:16:5$
LC/MS/MS #E
MRM of 4 Channels ES-
9.27
499 > 9s
1.55e?
0 ,,,,,,,,,,,,,,,,,~,,,,,,,,,~,,~~,,,,,,,,,,~,,,,,~,,,,,,,,,,,Tjme
`1113'
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000140
Quantify
Sample Report
`ha& Study No .:L34910,
Set No.:O731031,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCNSMS6\Masslyax\Fluoroch~calS.PRO\S~leDB\O73lO3A Sun Aug 03 07x08:13 2003 P:\Data\LC3rISMS6\Essl~\Fluorochemic\Met~B\Decatur Sun hug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
Page 84
Decatur BC BC 080103
Name: Text:
0731031-1042
4: PFOSA
L3491 O-26
073103A-1042 100-
Sm (Mn, 2x3)
%-
02-Aug-2003 00:16:5!
LC/MS/MS #(
MRM of 4 Channels ES-
9.90
498 > 7t
4.77e:
Are:
Exygen Research, 3058 Research Drive, State College, PA 16601
000141
Quantify Swle Rsport
Study No.: L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Ssrnpls List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\bs8l~\Fluoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\LCMSMS6\~sslynx\FluorochemicB\Decatur
Sun hug 03 07:11:59
2003
Printed:
Sun Aug 03 07:19:29
2003
------~------------------I_______-
Name: 073103A-1043 Text :
---__--
1: CB Acid
L3491 o-22
(PFOA)
073103A-1043 Sm (Mn, 2x3)
o1LJ-;
,,,, ~,,,,,,, s>,,7,-,,, ;,,c,,,-,M,
9.15
608
Page 85
Decatur BC BC 080103
----------
02-Aug-2003 00:38:46 LCRvlSJMS #6
MRM of 4 Channels ES413s 369 2.10e4 Area
2.00
2: C6 Sulfonate
(PFHS)
IIL3491 o-22 A-l 043 Sm (Mn, 2x3)
A0.89
0.13
1 AA1
7An-m
4.00
6.00
-- E r4.c
Time
8.00
10.00
12.00
\ 020Aug-2003 00:38:44
G9.53 0.31 0.84
LC/MS/MS #6
MRM of 4 Channels ES-
0 "","","",~"`,"","","","`~,"","","","",
Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
L3491 o-22
(PFOS)
073103A-1043 Sm (Mn, 2x3)
02-Aug-2003 00:38:46 LC/MS/MS #6
MRM of 4 Channels ES-
Exygan Research, 3058 Research Drive, State College, PA 16801
000142
Quantify Sample Report
q& Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\~~S6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCM~S6\Massl~\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed: ----------------_
Sun Aug 03 07:19:29 2003 --_--------------------
Name: 073103A-1043 Text:
4: PFOSA
L3491 o-22
073103A-1043 Sm (Mn, 2x3)
Page 86 Decatur BC BC 080103
I
Aug-2003 00:38:41 LCIMSIMS #l
MRM of 4 Channels ES-
2.00
4.00
6.00
8.00
10.00
12.00
-Glen Research, 3058 Research Drive, State Colleps, PA 3.6801
000143
Quantify Sample Report
&# Study No.:L34910,
Set No .:073103A,
Ext.Date:07/31/03,
Analyst:K.Risha
Sappls List:
Last modified: Method:
Last modified: Job Code:
P:\Data\L~SWS6\~sslynx\8luoroch~cals.PRO\S~leDB\O73lO3A
Sun Aug 03 07:08:13
2003
P:\Data\LCMSMS6\~sslynx\FluorochamicalB\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun hug 03 07:19:29 2003
Page 87
Decatur BC BC 080103
Name: 073103A-1044 Text :
1: C8 Acid (PFOA) L3491 O-23
I073103A-1044
IO
Sm (Mn, 2x3)
02-Aug-2- 003 01:00:38/ LC/MS/MS #6
MRM of 4 Channels ES413>369 2.09e5 Area
L
W 2: C6 Sulfonate 13491 O-23
(PFHS)
073103A-1044 Sm (Mn, 2x3)
Time 12.00
02-Aug-2003 01:00:38 LCBMMS #6
MRM of 4 Channels ES399 > 80 4.02e4 Area
I: C8 Sulfonate -3491 O-23
2.00
(PFOS)
`OOJ 373103A-1044 Sm (Mn, 2x3)
10.00
Time 12.00
396.2941 L--,
02-Aug-2003 01:00:3d LC/MS/MS #6
MRM of 4 Channels ES-
499 > 99
2.2A1reea4
0 ~`~`,~`,,`.,`,,,,,,,,,`,,".,`,,,,,"',,,,'f
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Rosearch Drive, State college,
PA 16801
000144
---_-___--__---------
---w-e---
---
Quantify Sauple Report 14 Study No .:L34910, Set No.:073103A,
Eact.Date:07/31/03,
Analyst:K.Risha
Page 88
Sanple List: Last modified: Method: Last modified: Job Code:
P:\Data\L(SMSMS6\~sslynx\Fluoroch~cals.P~\S~leDB\O73103A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 08OiO3
Printed:
Sun Aug 03 07:19:29 2003
---------------------------
Name: 073103A-I.044 Text :
-----------------------
: PFOSA
-3491 O-23
173103A-1044 Sm (Mn, 2x3)
104
.
%4o'~~~~,`~~`,~`~`r'~~~,~~~`,~~~~,"~'I~"',"~'r"
2.00
4.00
6.00
02-Aug-2003 01:00:31
LC/MS/MS #E
MRM of 4 Channels ES-
9.8s 3 1214
498 > 7E 6.45e4
Aree
Time 8.00
W
Exygen Research, 3058 Research Drive,.Stats
College, PA 16801
000145
-------
-
---_----
------------_
Quantify Sample Report b# Study No. : L34910, Set No .:073103A, Ext.Dats:O7/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified: Job Code:
P:\Data\LCMSMS6\MasalyPx\Fluoroch~cala.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\M3MSMS6\Masslynx\Fluorocbamicals\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29 2003
-Page a9
Decatur BC BC 080103
Name: Text:
073103A-1045
1.: C8 Acid (PFOA)
-3491 O-24, DF=lOO
173103A-1045 10
1 %$
Sm (Mn, 2x3)
02-Aug-2003 01:22:1 C LC/MS/MS #6
MRM of 4 Channels ES413>369 2.06e5 Area
!: C6 Sulfonate
(PFHS)
L3491 O-24, DF=lOO
073103A-1045 10
Sm (Mn, 2x3)
Time 12.00
02-Aug-2003 01:22:1 tj
LC/MS/MS #6
MRM of 4 Channels ES-
8.96
399 > 80
6002
3.39e4
Area
!
w
Time /
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
(PFOS)
L3491 O-24, DF=lOO
02-Aug-2003 01:22: 1C
LC/MS/MS #6
073103A-1045
I "`1lf-ln,
I 1
Sm (.Mn, 2x31,
MRM of 4 Channels ES-
9.25
499 > 99
3853
2.26e4
Area
L
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exyoen Research,
3058 Research Drive, State college,
PA 16801
000146
Quantify
Sample Report
I& Study No.:L34910,
Set No .:073103A, Ext.Date:07/31/03,
Analyst:K.Risha
Page 90
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\~SPIS6\Mssl~\Fluoroch~cals.P~O\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003
P:\Data\LCblSMS6\Masslynx\Fluorochemical\Decatur Sun Aug 03 07:11:59 2003
Decatur BC EC 080103
Printed:
-----__-_
Sun Aug 03 07:19:29 3003
--------
-------
__-----____
-w--m--
----
Name: 0731031-1045 Text :
4: PFOSA
IL3491 O-24, DF=lOO
073103A-1045
1nl-L
Sm (Mn, 2x3)
02-Aug-2003 01:22:1 C/
LCAWMS #6
MRM of 4 Channels ES-
9.89
498 > 78
8.50e4
Area
r , , , r , , 1Time
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000147
Quantify Sample Report
\IJ Study No.:L34910,
Set No.: 0'73103A, Ext.Date:07/31/03,
Analyst:K.Risha
Szizuple List: Last modified: Method: Last modified: Job Code:
P:\Data\L~~6\Masslynx\Fluorochemicals.PRO\S~leDB\O73lO3A Sun Aug 03 07:08:13 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed;
Sun Aug 03 07:19:29 2003
Page 91
Decatur BC BC 080103
Name: 0731031-1046 Text :
1: C8 Acid (PFOA)
XCO72503-6,lOOO rig/L Standard
073103A-1046 10
Sm (Mn, 2x3)
3
9.13 322068
02-Aug-2003 01:43:42] LC/MS/MS #6
MRM of 4 Channels ES413>369 1.93e6 Area
2.00
4.00
6.00
8.00
10.00
12.00
!: C6 Sulfonate
XC072503-6,1000
(PFHS)
rig/L Standard
073103A-1046
loo-
Sm (Mn, 2x3)
%-
02-Aug-2003 01:43:4:
LCWYMS #f
MRM of 4 Channels ES-
8.98
399 > 8C
3.71 e5
Area
0 `,","","","","","","","",
, ~ , , , , , , , , , ,Time
2.00
4.00
6.00
8.00
10.00
12.00
I: C8 Sulfonate
YCO72503-6,1000
(PFOS)
rig/L Standard
373103A-1046 10 9
Sm (Mn, 2x3)
% i
02-Aug-2003 01:43:42/
LC/MS/MS #6
MRM of 4 Channels ES-
9.24
499 > 99
3566!
2.09e5
Area
`~1
Time
2.00
4.00
6.00
8.00
10.00
12.00 J
RXXJen Research, 3058 Research Drive, State College, pA 16801
000148
Quantify Sample Report
&if
Study No .:L34910,
Set No.:073103A,
Bxt.Dats:07/31/03,
Analyst:X.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.~RO\S~leD~\O73103A
Sun Aug 03 07:08:13
2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\M~t~B\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:19:29
2003
Page 92
Decatur BC BC 080103
Name: 0731034-1046 Text :
4: PFOSA
XCO72503-6,lOOO
rig/L Standard
073103A-1046 Sm (Mn, 2x3)
.
100-
%-
02-Aug-2003 01:43:42
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
498>78
7.38e5
Area
Exygen Research, 3058 Research Drive, State College, PA 16801
oool.+!s
Spowx Study No: Fkygecn Study No: Adytr: looa Monitored: site:
NA I34910 PFOA 413 -> 369 Decaau Baker's Geek
RAW DATA REPORT
Limit or Quaacicarion: Iojection Volum: Mati Sample Volum: Fd Volume:
50 ppc
15 IJwaler 40.0 mL 5.0 mL
5s No: AdYSU Insmuncnt Pabaclion Aonlyzad
Typ: Dale: on:
073103AR Karen Risba LClMSlhIS unit d 6 07/31x)3 08/03-04!03
kYP= ID
xCO72503-0 xco72503- I xco72503-2 xc072503-3 XCO72503-4 xCo72503-5 XCO725+33-6 l34910.1 Spk C L34910-12Spk E W4910-16 Spk F xco72503-1
u49mI U4910-I Rep
u49 IO-4 u4910-2 XcO72503-2 w4910-6 W910-6 Rep w4910-9 l349la-7 xco72503-3 w4910.12 L34910-I2 Rep w4910.15 w910.13 xc0m03-4 U4910-16 W49lC-16 Rep w4910-19 w4910-17 xco72503-5 W4910-16 W4910-16 Rep w4910.19 w910-17 xCa71003-6
Spoasor
m
BC2 SW-@4 BCZ SW06 outfali lo River SW-U
BC2 SW.04 BC2 SW-04 BQ SW-04 Dup EC2 SW-04 Low Spk
BC2 SW-05 BCZ SW-05 BC2 SW-05 Dup BC2 SW-05 Low Spk
Bcz SW-06 BC2 SW.06 BC2 SW-06 Dup BC2 SW-06 Low Spk
ChItfall to River SW-zi outfall to River SW-25 oudall to River SW-U Dup Chtfdl to River SW-2S Low Spk
Chidail to River SW-25 Chtfall to River SW-25 oudall to River SW-25 Dop Outfall to River SW-25 Low Spk
sccl
SUItpiS
RUP
cont.
Code
No.
(PPO
wI^
073103AR-101
0
cs
073103AR-102
25
cs
073103AR-103
50
cs
073103AR.104
loo
cs
073103AR.105
250
cs
073103AR-106
500
cs
073103AR-107 low
LF
073103AR-108
LF
073103.&R-109
LF
073103AR.110
cs
073103AR-111
25
S
073103AR-112
S
073103AR-113
S
073103.&R-1 14
FF
073103AR-115
cs
0731MAR-116
50
S
073103AR-117
S
073103AR-1 I8
S
073103AR-119
FF
073103AR-120
cs
073103AR-121
loo
S
073103AR-122
S
073103AR-123
-.
S
073103AR-124
FF
073103AR.I25
cs
073103AR-126 250
S
073103AR-I27
S
073103AR.128
S
073103AR-129
FF
073103AR.130
cs
073103AR-131
SW
S
073103AR-132
S
073103AR-133
* s
073103AR-134
ff
073103AR.135
cs
073103AR-136 loo0
Aaalytc Found (ppt) = (peak arep - intercept) I slope x DF
Recovery (%) =
[adyte found (ppthnalyte found in control (ppc)) x 100
MWt added cm)
cilution
Factor
lcul Km loo
10 10 10 10
10 10 10 10
20 20 20 20
100 100 ml loo
20 20 2n 20
Peti
Area
794
147.21 27994 54680 128556 264862 516215 SO564 92540 114710 14631 216041 216268 131415 142555 29284 40498 39782 81652 112700 55667 30891 I 315651 29773s 354730 127797 82515 83658 75424 78536 271906 380900 391789 364595 362898 477931
Aodyte Foond
(Ppt,
Amounr Ad&d (pwt)
R.XOVU-j
(a)
.*
17800 22100
4210 4210 2540 27W
.* I* 1560 2170
12100 12300 11fxlO 13900
I5800 wxa I4um lSw0
l * . . l . .*
5ooa mm mm
100
100
loo
loo
loo
114 126 -1450+
1579A+ 1800+ -Boo+
i5&U&W8
: Lioepr (11x weigbtod)
Iomccp~ = 220217
Slap = 508.394
Cod. Of Lkt. = 0.99621 I
CS = Calibrationstandard
LF I lab fwtitied saqde
c = control sample
FF = Field foftified sample
s = Sample
LCS = Labaatay Cootml spikm
CK = Check Standard
ND = Not dctixted = Respoue bxwcen 0 and 25 ppc
NQ = NWquantifiable = Responsebetween 25 ppt and LOQ (50 ppt)
Sprwishcet prepared by:
l *Sampk WBIanalyzed with reveal dilution factorsin order to rcommcdatc all compounds. Th appropriate resulu M reported.
%unplc was cormrsd using the data found in sot 073103A. +Sample residue si8rtif~aotIy exceeda du apiking level; thmfw. an accurate recovery cannot ix calculated.
000150
Spoo~v Study No: ibygan Study No: Adyte: Iom Monitored: Site:
NA U4910 PFHS 399.>so Decaha Baker's Creek
RAW DATA REPORT
Limit of Q!lantitation: hjecdon Vohm: Maaix Svnple Volum: Final Volume:
50 PPt l5rr War 40.0 OIL 5.0 mL
Sot No: AMlys1:
InsmmcalTypc:
Enaacfion Dam: Analyzed on:
073103AR Karen Rkha
LcIMslMs
unit w 6
o7i3iiv3
oam3-o4m3
xc0725030 xco72503-I xco72503-2 XCD72503-3 xco72503-4 xco72503-s xco72503-6 W4910-1 Spk C 04910-12 Spk E U4910-16Spk F xc072.503- I
U4910.1 U4910-1 Rep
I349 lo-4 u4910-2 XCO72503-2 u4910-6 U4910-6 Rep L34910-9 w4910-7 xc07.2503-3 w49w12 U4910.12 Rep u4910-I5 w4910-13 xco72503-4 U4910-16 U4910-16Rcp
L34910-19
w910-17 xco72503-s U4910-16 U4910.16 Rep U4910-19 u4910-17 xc071003-6
spolww UJ
BU SW-04 BU SW-06 outfall to River SW-25
BQ SW-04 BQ SW-04 BU SW-04 Dup EC2 SW-04 Low Spk
BU SW-05 BC.? SW-05 BC2 SW-05 Dup BCZ SW.05 Low Spk
BCZ SW-06 BC2 SW-06 BQ SW-06 Dup BG! SW-06 Low Spk
chdnll to River SW-Z OutMl to River SW-25 axfaIl 10 River SW-23 Dup Outfall to River SW-U Low Spk
Gutfnll to River SW-25 cwfau at River SW-23 outfall to River SW-25 tip Cutfail to River SW-25 Low Spk
SOlpie Code cs cs cs cs cs cs CS LF LF LF cs s S S FF cs S s S ff c-s S s S FF cs S S S FF cs S S S FF cs
RUll NO. 073103AR-101 073 103AR-102 073103AR-103 073 103AR.1w 073103AR-105 0?3103AR-106 073103AR-107 073103AR.I08 073103AR.109 073lO3AR-1 IO 073103AR.I I I 073103AR-112 073103AR.113 073103AR-I14 073103AR-115 073103AR-116 073103AR-117 073103AR-11s 073 103AR-I 19 073103AR-120 073103AR-121 073 103AR-122 073103AR-123 073103AR-12.4 073103AK125 073103AR-126 073103AR.127 073103AR-128 073103AR-129 073imAR.130 073103AR-131 073103AR.132 073103AR-133 0731mAR-134 073103Ah135 073103AR.136
A~Iylc Found (ppt) = (peak MP - ialercept) / slope x DF
Recovuy (%) =
[anaiytc found (ppthnllycc found in conaol (ppt)] x 100
ammat added (ppt)
std.
COOC.
@PO
0
25 50 loo 250
Dilulian Facrm
100 100
100
10 IO 10 10
10 10 10 10
20 20 20 20
100 IO0 100 100
20 20 20 7.0
peak Area
0
2074 4718 9231 21488 43819 87115 S566 10314 10701 2324 9381 10152 6122 7036 4266 1526 1565 3729 602.3 9486 26169 27209 25364 30673 21551 6872 6261
6156
6030 45496 33004 30633 29219 2ab60 80818
AOalytC Found (pet)
Amount Ad&d (PPO
Recovery (`k)
I.
11800 127lIO
I. . . .* I.
l * *. *. I.
bob0
6300 5a70 7110
**
l * l . . .
7bb0 7100 6770 6640
SIandard
: Liocar (Ih rcighrcd)
Intenpt = 218.845
Slope = 8S.6521
Cccf. Of Dcr - 0.99b560
CS - Calibcrtionswuiard
LF I Lnb fortified sample
c - commnl sampk
FF = Field fm-tifiid sample
s = Sample
LCS = I;lbaatory Cona Spika
CK = Clwck Staodud
ND = Not detected i: Rwponr between 0 and 25 ppt
NQ = Not quantifiable I Rwponse between 25 ppt and WQ (50 ppt)
Spread&cat prepared by:
000151
Sp~nscrr Study No: ~y&o Study No: Analyte: ions Monitmcd: Site:
NA I24910 PFOS 499 -a 99 Dscafur Raker's Creek
RAW DATA REPORT
Limit of Qusntitation: Injection VoIume: MOUiX Smplo Volume: Fi v01umc:
50 ppc
15 6 w*lcr do.0 mL 10 mL
Sat No: AdySt Instmmcnt Bxtr~don Amfyazd
Type: Date: 08:
073103AR Karen Risk LUMSIMS
07txn3
0&03-04803
Unit Y 6
XC072503-0
xc072503-
I
xc072503.2
xco72503.3
xca7m3-4
xco72503-5
XCO72503d
W4910-1 Spk C
L34910-12
Spk E
L34910-16
Spk F
xco72503-1
w4910-1
u4910-I
I&p
w4910-4
w4910-2
XC072503-2
W4910-6
W4910-6 Rep
L34910-9
u4910-7
XC072503-3
W49lD-12
w4910.12
Rep
w4910-15
w4910-13
xco72503-4
w4910-16
l34910-16
Rep
w4910-19
u4910-17 XCO725M-5
W491&16
W910-16
Rep
L34910-19
Ud910-17
XCO71003d
SpSCU w
EC2 SW-04 BU SW-06 oudal lo River SW-25
BQ SW-&i BU SW-04 BC2 SW-04 Dup EC2 SW-04 Low Spk
BQ SW-OS Bc2 SW-OS BC2 SW-05 Dup EC'2 SW-05 Low Spk
BC2 SW.06 BCZ SW-Q6 BU SW-06 Dttp BC2 SW-06 Law Spk
fhdtdl 10 River SW-25
oudnl to Ftivm SW-z.5
oldl
to Rivu SW-U Dup
OIldell Ia River SW-25 law spt
Oudall to River SW-25 cwfall to River SW-25 Dudal to River SW-25 IxIp Chdal to River SW-25 Low Spt
Sample Code
cs cs cs cs cs cs cs LF
LF LF cs S S S PF cs S S S FP cs S S S FP cs S S S FF cs s S S .FP
cs
SKL
Run
chx.
NO.
(ppt)
073103AR-101
0
073103AR-102
25
073103AR.103
SO
073103AR.104
loo
073103AR-105
250
073103AR-106
500
073103AR.107
Iow
073103AR-108
073103AR-109
073103.&R-I
10
073103AR.Ill
25
073103AR.112
073103AR-113
073103AR-114
073103AR-II5
073103AR-II6
SO
073103AR-117
073 103AR-118
073103AR-119
073103AR-120
073103AR-121
1W
073103AR-122
073103AR.123
073103AR-I24
-.
073103AR-125
073103AR-126
250
073103AR-127
073103AR-128
073103AR-129
073103AR-I30
073103AR-131
500
073103AR-132
073103AR-133
073103AR-134
oniomrb135
073103AR-136
loo0
Adyte Recovery
Fouod @pt) = (@ (57) =
area - intctcept) (malyk found
I slap x DF
(ppt)-mrdy(c
found in conool
pmarnt added (ppt)
(ppt)] 1 100
Dilution F-
1W loo 100
10 10 10 IO
10 10 10 IO
`20 20 20 20
loo ml 1Gu loo
20 20 20 20
PC& Area
0 1481 2986 Sloe 13285 28978 53617 9428 171% 22403 1473 61501 59888 44921 37560 2882 9224 8484 23649 29284 bw4 64499 64047 646s6 77839 13289 17094
17264
16861 16123 28469 81862 84263 822Ql 79698 53157
CS = Calibratioartmdud c I Conud sample s = sample
LF a Lah fortified m&c
IT = Fmld fwtified wmple
LCS - hbwamy
Cmtml spike
CK = (hck Stmdiud
ND = Ncr detected = Rupopre bctwcen 0 and 25 ppt
NQ 9 Not qwtifiablc
I Response between 25 ppt and L0Q (50 ppc)
**Sample ~%Samph
`Sample YSample +!hmplc
was analyzed with several dilution fvtorr in order to lffomtt~bt(I
WPI comeed uiag the data found in set 080603A
rquim lbkr dilutioa See data act OUl603A
requires a higkr spiking level. Sea data set 080603A.
nriduc rignificamly
exceeda the spiking level; thercforc. aa acarak
all cotttpOUad%. lb sppopriacC ~CCOVC~J CU~MI be calculated.
rmdta (LIa nponcd.
MY= Found
(PP0
Amount Added (PPU
Recovery W)
171M)
5wQ
112*
AA
mco
5ooo
* .
82.50
68%
100
-4610%
1670
IJU) 4330
5370
100
37co+
.
l
l
I
loo
31200
3 1soo
308txl
29400
100
-1800+
1.
. .
. .
*.
lD0
S(andard lnterxpt Slope
Cat Of C-a
: tinerr (Ih = 152.345 P 34.2582 ii 0.998217
weighted)
000152
Sponsor Study No: Exygcn Study No: Adytc: Ions MoniWred: Site:
NA L34910 FOSA 490 -=- 78 Decatur Baker's Creek
RAW DATA REPORT
Limit of Quantitxion: Injection Volume: Math: Sample Volume: Final Volume:
so ppl 1s )IL Wstcr 40.0 mL 5.0 mL
Set No: Analyst: lnstzumcnl Extractian Analyzed
Type: Date: on:
073103AR
Karen Rirha
LG?&&!S
Unit # 6
0713 II03
oa/o3-04103
Exygen
ID
xc0725034
XCO72503-I
XCO72503.2
xco72503-3
XCO72503-4
XCO72503-5
xc012s034
L34910-1 SpkC
134910-12
SpkE
L34910-16
SpkF
XCO72503-I
w4910-I
L34910-1 Rep
L34910-4
L34910-2
xco72503-2
L34910-6
L34910-6 Rep
L34910.9
L34910-7
XCO72503-3
L349IO.12
134910-12 Rep
L34910-15
L34910.13
XCO72503-4
L34910.16
L349lO-16Rep
L34910-19 "4910.I7 XCO72503-5
L34910-16
L34910-16
Rep
L34910-19
L349lO-17
xc071003-6
Sponsor ID
BCZ SW-04 BC2 SW-06 outfall to River SW-25
EC2 SW-04 K-2 SW-04 BC2 SW-04 Dup EC2 SW-04 Low Spk
BC2 SW-05 BC2 SW-05 BC2 SW-05 Dup EC2 SW-OS Low Spk
BC2 SW-06 BCZ SW-06 8'22 SW-06 Dup BCZ SW-06 Low Spk
Outfall w River SW-2s Outfall W River SW-25 Outfall w River SW-25 Dup OddI w River SW-25 Low Spk
outfall to River SW-25 Outfsll w River SW-25 Outfall w River SW-25 Dup Outfall w River SW-25 Low Spk
Sample Code cs
cs cs cs cs cs cs
LF LF LF cs S S S FF cs S S S FF cs S S S 5-F cs S S S FF cs S S S FF cs
Atnlyte Rccavcry
Found (ppt) = (peak (%) -
arcs _ inwtcept) / slope x DF fsnalytc found (ppt)-snalyte smotmt
found in control added (ppt)
Run
NO.
073103AlG101
073103,4&102
073103AR-103
073103AR.104
073103AR-105
073 103AR-IO.5
073103AR-107
073103AR-108
073 103AR-109
073103AR.II0
073103AR-Ill
073103AR-I
I2
073103AR-113
073103AR-I
14
073103AR-t1s
073103AR-116
073103AR-II7
073103AR-I
I8
073103.x+-I
19
073103AR.120
073103AR-121
073103AR-122
073103AR-I23
073103AR.124
073103AR.12$
073 103AR-126
073103AR-127
073 103AR-128
073103AR-129 073103AR-t30 073103AR.I31
0731'33AR.132
073103AR-133
073103AR-134
073103AR-135
073103AR-136
@tJ x IO0
Std. COUC. @pt)
0 25 SO IW 250 So0 1000
25
50
100
250
SW
1000
CS = Cslibrstion c = Controlssmpk s = s4mpk
standard
CK = Check Sundsrd ND - Nat detected NQ - Not qustttitisble
LF = Lab fortiftcd FF - Field fortiticd LCS = Lsborzwry
sample sample
Control Spike
- Rcsponsc between 0 and 25 ppt = Response between 25 ppt snd LOQ (50 ppt)
l *Sampk
+bmpk
~1s analyzed with several dilution facwrs in order w rccommodate
residue significantly
excccdr the spiking Icvcl; therefore, u1 sccuntc
all compottttds. The spproptia(e recovery cannot be calculated.
Dilution Facwr
100 100 I00
IO 10 IO IO
10 10 IO 10
20 20 20 20
loo loo loo 100
20 20 20 20
Peak ~rca
0 5175 10303 207 IV 48632 104085 196920 13039 16006 18398 5382 27920 27505 20497 16630 10890 3460 3402 8876 11595 21221 2449s 23261 25908 25736 49195 6718 6206 6506 5831 to2292 32659 31916 32869 26761 190680
Analytc Found (ppt)
Amount Added (PPt)
Recovery (%)
.*
5000
. .
5000
4.
5000
1390
1370 . .
l *
loo
l .
**
l .
. .
I00
2430
2300
2570
2550
1w
120
l .
l *
l *
6.
loo
3260 3180
3280
2660
loo
-6CO+
Staadsrd m lotcmpt Slope
Gxf. Of Der
: Linear (I/x - 61 1.080 = 196.925 - 0.998392
weighted)
Sprcrdshcct
prcprnd by:
results are reported
000153
Masslynx -Sample List
Sample List: C:\MASSLYNX\Fluoroch Printed: Sun Aug 03 08:19:25 2003
Is.PRO\SampleD8\073103AR
i
Decatur BC.SPL
Exygen STUDY NO- w
Page 1 Page Position: (1 I 1)
Vial File Name
LIMS ID Client JD Sample Description
Matrix SampleType
Conc(ng/L)
Cone 6 Cone C Test ID DF
41 073103AR-101
--
---
:
42 073103AR-102
-
-
3
43 073103AR-103
-
-
4
44 073103AR-104
--
45 073103AR-105
-
--
073103AR-106
-
--
XCO72503-0.0 rig/L Standard
;5 XCO72503- I,25 rig/L Standard 50 XCO72503-2,50 rig/L Standard 100 XCO72503-3. 100 rig/L Standard
-_
Standard
---
Standard
---
Standard
---
Standard
-
_-
0
1
-
--
0
-
_-
0
:
-
--
0
XCO72503-4. 250 nglL Standard XCO72503-5, 500 nglL Standard
---
Standard
--
Standard
Ei
_-
--
0
:
-
--
1
7
1; 073103AR-107
-
--
XCO725W6,1000
rig/L Standard
--
Standard
1000
-
--
x
1
8
51 073103AR-108
-
--
L34910-1 Spk C, 5000 q/L. OF=100 ---
5000
-
_--
100
365 j
9
52 073103AR-109
-
-
L34910-12 Spk E. 5000 q/L, DF=lOO --
::
5000
-
--
00
100
/
10
53 073103AR-110
-
--
L34910-16 Spk F. 5000 I-@., DF=lOO ---
QC
5000
-
--
0
100
42 073103AR-111
-
--
XCO72503-1.25 naiL Standard
--
Standard
25
-
--
0
1
54 073103AR-112
-
--
L34910-1, Di=lO"
--
Analyie
-
I_
--
55 073103AR-113
--
-_
L34910-i Rep, OF=10
--
Analyie
___
-
_-
8
::
56 073103AR-114
--
--
L34910-4. DF=lO
--
Analyte
-
_I
0
IO
073103AR-115
---
-
L34910-2: DF=lO
-
QC
Go
-
-
10
073103AR-116
--
-
XCO72503-2, 50 nglL Standard
-
Standard
50
-
_-
8
1
17
073103AR-117
--
-
L34910-6, DF=lO
-
Analyie
--
-
---
0
10
073103AR-118
---
L34910-6 Rep, OF=10
-
Analyte
--
-
---
0
10
::
073103AR-119
-
-
L34910-9, DF=lO
-
Analyie
-
-
0
10
20
073103AR-120
--
-
L34910-7, DF=lO
-
QC
Gd
-__
0
10
21
073103AR-121
-
-
XCO72!%3-3,100 nglL Standard
-
Standard
100
--
-
0
1
22
073103AR-122
-
me
L34910-12. DF=20
-
Analyte
-__
---
--
0
20
073103AR-123
--
-
L34910-12.Rep, OF=20
-
Analyte
-
--
--
0
20
t:
073103AR-124
-
--
L34910-15, DF=20
-
Analyte
-_
--
-_-
25
073103AR-125
--
-
L34910-13,DF=20
-
QC
-
--
0"
si
45 073103AR-126
-
-
XCO72503-4,250 rig/L Standard
-
Standard
El
-
---
1
66 073103AR-127
-
-
L34910-16, DF=lOO
-
Analyte
---
-
---
x
100
28
67 073103AR-128
-
L34910-16 Ret). DF=lOO
-
Analyte
---
_-
---
100
29
68 073103AR-129
-
L34910-19, Di=lOO
-
Analyte
--_
-
--
0"
100
30
69 073103AR-130
-
-
L34910-17. DF=lDO
-
QC
100
-
--
0
loo
31 46 073103AR-131
-
XCO72503%, 5001-&L Standard
-
Standard
500
-
---
0
1
70 073103AR-132
-
--
L34910-16, DF=PO
-
Analyte
--.
-
--
335 71 073103AR-133
-
--
L3491O-16 Rep, OF=20
-
Analyte
---
-
_--
:
;:
34 72 OMl03AR-134
--
--
L34910-19,OF=20
-
Analyte
..--
-
---
0
20
73 073103AR-135
--
--
L34910-17, DF=PO
-
QC
100
-
-_
20
47 073103AR-136
--
---
XCO72503-6, 1000 nglL Standard
--
Standard
1000
-
--
8
1
Masslynx - Sample List
MS Method
HPLC Method
1 C6 03 SULF 03 ACID PFOSA 2 C6 C8 SULF C8 ACID PFOSA 3 C6 C8 SULF C8 ACID PFOSA 4 C6 C8 SULF C8 AC10 PFOSA
C6 C8 SULF C8 ACID PFOSA 65 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 AC10 PFOSA x C6 C8 SULF C8 ACIO PFOSA 9 C6 C8 SULF C8 ACIO PFOSA
C6 C8 SULF C8 ACID PFOSA :: C6 C8 SULF C8 ACID PFOSA 12 C6 C8 SULF C8 ACID PFOSA 13 C6 C8 SULF C8 ACID PFOSA 14 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA :i C6 C8 SULF C8 ACID PFOSA 17 C6 C8 SULF C8 ACID PFOSA la C6 C8 SULF C8 ACID PFOSA 19 C6 C8 SULF C8 ACID PFOSA 20 C6 C8 SULF C8 ACID PFOSA
CS C8 SULF 03 ACID PFOSA C6 C8 SULF C8 ACID PFOSA C6 C8 SULF C8 ACID PFOSA C6 C8 SULF C8 ACID PFOSA C6 CB SULF C8 ACID PFOSA C6 C8 SULF C8 ACID PFOSA 27 C6 Cfl SULF Cl3 ACID PFOSA 28 C6 C8 SULF C8 ACID PFOSA 29 C6 C8 SULF C8 ACID PFOSA C6 C8 SULF C8 ACID PFOSA 3: C6 C8 SULF C8 ACID PFOSA 32 C6 C8 SULF C8 ACID PFOSA C6 Cl3 SULF 03 AC10 PFOSA if C6 C8 SULF C8 ACID PFOSA 35 C6 C8 SULF C8 ACID PFOSA 36 C6 C8 SULF CB ACID PFOSA
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water
pfbs water pfbs wa?er
pfbs waler pfbs water ptbs water pfbs water pfbs water
pfbs water pfbs water pfbs water
$2 z:z pfbs water pfbs water pfbs water pfbs water pfbs water
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water
MS Tune File
Fluomchems Fluorocherns Fluomchems Fluomchems Fluomchems Fluorochems Fluorochems Fluorochems Fluomchems Fluorochems Fluarochems Fluomchems Fluomchems Fluorochems Fiuorochems Fluorochems Fluorochems Fluomchems Fluorochems Fluomchems Fluorochems Ftuorochems Fluorochems Fluorpchems Fluorochems Fluomchems Fluorochems Fluorochems Fluorochems Fluorochems Fluomchems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems
Inj.Votume
::zz :2
15
:: 15 15 15 15 15 15 15 15
:z 15 15 15 15
:: 15
ii 15 15 15 15 15 15
;:
_-(&%I)
Exygen STUDY NO* -----
Page 2 Page Position: (2, 1)
LC/MS/M.S SYSTEM AND OPERATING CONDITIONS
Snonsor Protocol No: NA
Exvgen Studv No: L34910
Instrument:
Micromass Quattro Ultima (LUMS/MS Unit #6)
Computer:
COMPAQ Professional Workstation Al?200
Software:
Microsoft Windows NT: Version 4 Build 138 1: Service Pack 5 Micromass Limited: MassLynx 3.4 Build 004
HPLC Equipment:
Hewlett Packard (HP) Series 1100
HP Bin Pump
HP Vacuum Degasser
HP Autosampler
HP Column Oven
HPLC Column:
Genesis C-8,5 cm x 2.1 mm i.d. x 4 l.r (Exygen ID: 74A) (JONESCHROMATOGR.APHY: Part No. FK5962E)
Mobile Phase (A) : Mobile Phase (B) :
2 mM Ammonium Acetate in Type I Water Methanol
Analyst:
Karen Risha Exygen Research 3058 Research Drive, State College, PA 16801 Phone: (814) 272-1039 FAX: (814) 231-1580
NOTE:
The next 3 pages are computer generated printouts from the masslynx software program. The pages contain the instrument settings used for the analysis of this data set.
All Handwritten Peak ID's by :j!p!o@3
V
_,
.I_^___
.
^-."."--.*""-
000156
____
__-..-
.---
w
Scanning
Method Report
Method:
Last Modified:
C:\MASSLYNX\FXUOROCHEMICALS.PRO\ACQUDB\C6 Thu Jul 31 16:23:50 2003
Page 1
C8 SULF C8 ACID PFOSA
Printed:
Sun Aug 03 08:20:40
2003
Solvent Delay ( mins ) :
0.00
&%3103
u
Analog Function
Channel : 1
4 : Unused MEW of 4 Mass Pairs
( ESP- )
Inter Channel Delay ( Sets ) : Span ( Daltons ) : Start Time ( Mins ) : End Time ( Mins ) : Repeats :
Channel Parent Daughter
1
399.00 80.00
2
413.00 369.00
3
498.00 10.00
4
499.00 99.00
0.03 0.00 0.00 12.00 1 Dwell
0.20 0.20 0.20 0.20
(Sees)
Co11 Energy
35 10 30 40
(eV 1 Cone ( v )
50 LO 50 30
000157
Method Report
Method File:
Last Modified:
'Ird Printed:
C~\&fASSLYNX\FLUOROCHEMICALS.PRO\ACQUDB\pfbs Sunday, August 03, 2003 08:06:07
Sunday, August 03, 2003 08:20:45
HP1100 LC Pump Initial
Conditions
Solvents
A%
90.0
B%
10.0
C%
0.0
D%
0.0
Flow (ml/min) Stop Time (mins)
Min Pressure (bar) Max Pressure (bar) Oven Temperature Left(OC)
Oven Temperature Right(OC)
0.300 20.0
0 400
35.0
35.0
HP1100 LC Pump Gradient
Timetable
The gradient Timetable contains 8 entries which are :
Time
A%
B%
C%
D%
0.00
90.0
10.0
0.0
0.0
2.00
90.0
10.0
0.0
0.0
5.00
10.0
90.0
0.0
0.0
9.00
10.0
90.0
0.0
0.0
9.50
0.0
100.0
0.0
0.0
14.00
0.0
100.0
0.0
0.0
14.50
90.0
10.0
0.0
0.0
20.00
90.0
10.0
0.0
0.0
Flow 0.300 0.300 0.300 0.300
0.300 0.300 0.300 0.300
HP1100 LC Pump External Event Timetable
The TimetabLe contains 6 entries which
Time Initial
0.00 0.05 0.10
11.90 12.00
Column Switch
Off
Off Off Off Off. Off
Contact1 Off On Off Off Off Off
are :
Contact2 Off Off Off On Off Off
Contact3
Off Off Off Off On 'Off
Contact4 Off Off Off Off Off Off
HP1100 Autosampler Initial
Draw Speed
Eject Speed (pl/min) Draw Position (mm)
Stop Time (mins)
Injection
Volume(fll)
Vial Number
Conditions
200.0 200
0.50 20.00 15.0
27
water
Page 1
Pressure 400
400 400 400 400 400 400
400
000158
Id Tuning Method Report
Method:
~:\~SSLYN~\FLUOROCHEMICA.LS.PRO\ACQUDB\FLUOROCHEMS
Printed:
Sun Aug 03 08:20:54 2003
v '.
Page 1
Dau 395.00
SOURCE
( ESP- )
Capillary
Cone
Hexapole 1 Aperture 1
Hexapole 2 Source Block
Desolvation
Temp. Temp.
Pressures
Analyser Gas Cell
Vacuum
Set
Rdbk
3.00 -2.93
20
-15
0.0
0.0
0.0
100 100
300 299
Rdbk
OFF 4.2e-3
Analyser
LM Res 1 HM Res 1 IEnergy 1 Entrance Collision
Exit
LM Res 2 HM Res 2 IEnergy 2 Multiplier
Gas Flows
Cone Gas Desolvation
set
Rdbk
14.0
14.0
1.0
-2
8
15
9
2
11
14.0
14.0
2.0
650 -647
Rdbk
135.1 767.4
000159
---
------~
Quantify Calibration
Report
%& Study No.:L34910,
Set No.: 073103AR,
--Ext.Date:O7/31/03,
-------Analyst:K.Risha
Calibration: Last modified: Printed:
-
P:\Data\LQH~S6\WaselyPx\Fluorochemica Tue Aug 05 07:03:45 2003
Wed Aug 06 11:03:59 2003
--_--_-
>ompound 1 name: C8 Acid (PFOA) :oefficient of Determination: 0.996211 :alibration curve: 508.394 ' x + 2202.17 qesponse type: External Std, Area >urve type: Linear, Origin: Exclude, Weighting:
5.16e5
l/x, Axis trans: None
-------_-
Page 1
Decatur BC
X
Response-
V
0.0 ExypCm Research,
200.0
400.0
600.0
3058 Research Drive, State College, PA 16601
800.0
WL 1000.0
000160
Quantify Calibration
Report
w Study No.:L34910,
Set No.: 073103AR, Ext.Date:O7/31/03,
Analyst:K.Risha
Calibration:
P:\Data\LCM~S6\~sslynx\Bluoroch~cals.~RO\~~eDB\O73lO3~
Last modified:
Tue Aug 05 07:03:45 2003
Printed:
wed Aug 06 11:03:59 2003
------------------l_-_____L_I_____________-----
;ompound 2 name: C6 Sulfonate (PFHS) ;oeffkient of Determination: 0.996560 ;alibration curve: 85.6521 ' x + 218.845 Response type: External Std, Area ;urve type: Linear, Origin: Exclude, Weighting:
8.71e4-
l/x, Axis trans: None
Page 2 Decatur BC ------
X
Response
0.0 Exygan Research,
200.0
400.0
600.0
3058 Research Drive, State College, PA 16801
800.0
1000.0
000161
-------
----------
--_---------____--w--
Quantify
Calibration
Report
l,& Study No. :L34910, Set No. .-073103AR, Ext.Date:07/31/03,
Analyat:K.Risha
Calibration: Last modified: Printed:
----
---------
P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\~~eDB\O73103~ Tue Aug 05 07:03:45 2003 Wed Aug 06 11:03:59 2003
_------
------------I_--------
:ompound 3 name: C8 Sulfonate (PFOS)
::oefficient of Determination: 0.998217
Cialibration ewe: 54.2582 * x + 152.345 Rasponse type: External Std, Area Curve type: Linear, Origin: Exclude, Weighting:
15.44e4-
l/x, Axis trans: None
-------
Page 3
Decatur BC
Response-
Exygen Research, 3058 Research Drive, State Collega, PA 16801
000162
Quantify
Calibration
Report
'%& Study No .:L34910, Set No .:073103AR,
Ext.Date:07/31/03,
&alyst:X.Rioha
Calibration:
P:\Data\LCM~S6\Masslynx\Fluorochemicals.PRO\~~eDB\O73lO3~
Last nmdified:
Tue Aug 05 07 :03:45
2003
Printed:
Wed Aug 06 11:03:59 2003
---------1-----~--~-~--~-~~--~
>ompound 4 name: PFOSA :oeff icient of Determination: 0.998392 2alibration curve: 196.925 ' x + 611.080 qesponse type: External Std, Area htve type: Linear, Origin: Exclude, Weighting:
1.98eE
l/x, Axis trans: None
Page 4 Decatur BC -w--m------
Response
200.0
400.0
600.0
800.0
looo.b
Oxygen Research, 3058 Research Drive, State College, Ph 16801
000163
Quantify SaxQ?le Report
S, Study No.:L34910,
Set No.: 073103Ak Ext.Date:07/31/03,
Analyst:K.Riaha
Sample List:
Last modified:
Method:
Last modified:
Job Code:
P:\Data\LCMSMS6\Wasslynx\Fluorochemicals.PRO\S~leDB\O73lO3~ !I!ue Aug 05 06:59:53 2003 P:\Data\LCM~S6\bss~~\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 1
Decatur SC BC 080103
Name: 073103AR-101
Text :
1: C8 Acid (PFOA) XCO72503-0,O rig/L Standard
073103AFb101 Sm (Mn, 2x3)
, , , , , , , , , , , , , , 1 I II
2.00
4.00
w r2: C6 Sulfonate (PFHS) XCO72503-0,O rig/L Standard
1 I ,nlTime 6.00
03-Aug-2003 19:10:54
*
LC/MS/MS #6
MRM of 4 Channels ES-
413>369
3.99e4 Area
9.13 794
8.00
10.00
12.00
03-Aug-2003 19:10:54 LChWMS #6
MRM of 4 Channels ES399 > 80 797
2.00
4.00
3: C8 Sulfonate (PFOS) XCO72503-0,O rig/L Standard
1073103AA-101 Sm (Mn, 2x3) 1.27
1
6.00
8.00
10.00
12.00
03-Aug-2003 19:10:51
LC/MS/MS #t
MRM of 4 Channels ES499 > 95 1.69eI
6.73
n cl"
11.16
01,,,.,,,,~,,,,,,,~,,,,,~,,,~.~,,~~~,~~~~,~~~~,~~~~,~~~~,~~,~tTime
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College,
PA 16601
000164
Quantify Sample Report
~14 Study No.:L34910,
Set No .:073103AR,
Ext,Date:07/31/03,
Analyst:K.Risha
Page 2
Ssqple List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Masslyax\Fluoroch~calr.PRO\SampleDB\073103~
Tue Aug 05 06:59:53 2003
P:\Data\L~S#IS6\Masslynx\Fluorochermic\Decatur
Sun Aug 03 07:11:59
2003
Decatur Bc BC 080103
Printed:
Wed Aug 06 11:04:02 2003
---_------------___
--1---------------
------m-w-
------
Name: 073103A.R-101 Teat :
4: PFOSA
XCO72503-0,O
rig/L Standard
073103AR-101 Sm (Mn, 2x3)
03 -Aug-2003 19: 1054
IX/MS/MS #6
MRM of 4 Channels ES-
10.02
498 3 78
O',,,`,,,,,,,.`,,l,,`,,,.,,.,,,,,l,,,,',,,,,..,,,,,,,,,,,,,,.,
Time
2.00
4.00
6.00
8.00
10.00
12.00 _
Eacygen Research, 3058 Research Drive, State College, PA 16801
000165
Quantify Sxmple Report
'd
Study No.: L34910, Set No.:O73103AR,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified:
Method : Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\Bluorochsmicals.P~O\S~l~DB\O73lO3~
Tue Auu 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 3
Decatur BC BC 060103
Printed:
-
Wed Aug 06 11:04:02 2003 -L_-------I----------------
--------P-m----_
NamS: 073103AR-102 Text :
: C8 Acid (PFOAI
KO72503-1,25 rig/L Standard
)73103AR-102 10
Sm (Mn, 2x3)
03-Aug-2003 19:32:33
LCRWMS #6
MRM of 4 Channels ES-
9.13
413>369
1422
&We4
Area
2.00
4.00
6.00
8.00
10.00
12.00
'I& 2: C6 Sulfonate
(PFHS)
XCO72503-1,25 rig/L Standard
073103AR-102 lOO-
Sm (Mn, 2x3)
%-
03-Aug-2003 19:32:33 LC/MS/TvlS #6
MRM of 4 Channels ES399 > 80 1.28e4 Area
O~,,,,,,~-,,,,,,~,,,,.,~,,~,,,,,:~~~,~~~
, , , , , ; , , Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
XCO72503-1,25
(PFOS)
rig/L Standard
073103AFb102 lOO-
Sm (Mn, 2x3)
%-
03-Aug-2003 19:32:33 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 8.99e3 Area
RJC'YO*n Research, 3058 Research Drive, State College, PA 1.6601
_. .I
I----~
000166
Quantify Sample Report
ba# study No.:L34910,
Set NO.: 073103AR, Ext.Dats:07/31/03,
Analyst:X.Risha
Page 4
Sample List:
Last modifiad: Method: Last modified:
Job Code:
P:\Data\LCMSMS6\~lasalynx\Pluoroch~cals.PRO\S~laDB\O73lO3~
Tus Aug OS 06:59:53 2003 P:\Data\L~SS\~sslynx\FluorochsmiB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02
2003
--
-------
--_-__--_----
-w--e----
-
--
Name: 073103AR-102 Text :
4: PFOSA
XCO72503-1,25
rig/L Standard
073103AR-102 Sm (Mn, 2x3)
03-Aug-2003 19:32:3I LCIMWMS #E
MRM of 4 Channels ES498 > 723 2.76e4 Area
Time
2.00
4.00
6.00
8.00
10.00
12.00
aul,
Exysren Research, 3058 Research Drive, State College, PA 16801 --.
000167
------
Quantify Sample Report %w' Study No .:L34910, Set No .:073103AR,
Ext.Date:07/31/03,
--A.nalyst:K.Risha
Page 5
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LCMSbiS6\blasslynx\Fluoroch~c~ls.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.P~O\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
--__--------------------_II_-----------------------~_
--s-s--
Name: 073103AR-103 Text :
1: C8 Acid (PFOA)
XCO72503-2,50 rig/L Standard
073103AFb103 1001
Sm (Mn, 2x3)
%-
03-Aug-2003 19:54:17
LCNSIMS #6
MRM of 4 Channels ES-
9.13
413>369
1.66e5
Area
2.00
4.00
6.00
8.00
10.00
12.00 _
: C6 Sulfonate
(CO72503-2,50
(PFHS)
rig/L Standard
)73103AR-103 10
Sm (Mn, 2x3)
% 4
03.Aug-2003 19:54:14
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
47lE
2.93e4
Area
3: C8 Sulfonate
I XCO72503-2,50
(PFOS)
rig/L Standard
073103AR-103 Sm (Mn, 2x3)
Time 12.00
03-Aug-2003 19:54:1 LC/MS/MS #6
MRM of 4 Channels ES-
1.79e4 Area
Time 12.00
Exygen Research, 3058 Research Drive, State Collage, PA 16801
000168
Quantify Sample Report
w
Study No .:L34910,
Set No .:073103AR,
Ext.Date:07/31/03,
Analyst:K.Risha
S-18 List: Last modified: X&hod: Last modified: Job Code:
P:\Data\LCblSMS6\Masslyax\Fluoroch~cala.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorocb~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 6
Decatur BC BC 080103
Name: Text:
073103AR-I.03
4: PFOSA
XCO72503-2,50
rig/L Standard
073103AFb103 lOO-
Sm (Mn, 2x3)
%-
03-Aug-2003 19:54:11
LC/MS/MS #c
MRM of 4 Channels ES-
9.89 _
498 > 7E
10303
5.55e4
Area
0 ,~~~,~~~,I,,,,,,,,,,,,,,,,,~,,~~,,,,~,,,~,~~,,,~~,~,,,,,,,,Time 2.00 4.00 6.00 8.00 10.00 12.00 J
RxYgea Research, 3058 Research Drive, State College, PA 16801
0003.69
Quantify Sample Report
&& Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
A,nalyet:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73103~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochsmicals\Uet~B\Dacatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 7
Decatur BC BC 080103
Name: 073103AR-104 Text :
1: CE? Acid (PFOA)
XCO72503-3,100 rig/L Standard
073103AR-104
1Af-L
Sm (Mn, 2x3)
03-Aug-2003 20:16:01
LC/MS/MS #6
MRM of 4 Channels ES-
9.15
4'13> 369
3.21 e5
Area
: C6 Sulfonate
KiO72503-3,100
(PFHS)
rig/L Standard
173103AFb104 10
Sm (Mn, 2x3)
Time 12.00
03-Aug-2003 20: 16:Olj
LCIMSNS #6
MRM of 4 Channels ES-
6.98
399 > 80
9231
5.35e4
Area
Time 12.00
3: C8 Sulfonate
XCO72503-3,100
(PFOS)
rig/L Standard
073103AFb104
loo7
% 4
Sm (Mn, 2x3)
03-Aug-2003 20:16:0'
LC/MS/MS #f
MRM of 4 Channels ES-
9.25
499 > 9:
5100
2.99er
Are:
Time
`IN
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research,
3058 Research Drive, State College, PA 16801
000170
Quantify Sarqple Report
\r, Study No.:L34910,
Set No.: 073103AR, Ext.Date:O7/31/03,
Analyat:R.Ri.sha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluorach~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003
P:\Data\LCWSblS6\Masslynx\BluorochamfcalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2OQ3
Page 8
Decatur BC BC 080103
Name: 073103AR-104 Text :
r4: PFOSA
XCO72503-3,100 q/L
Standard
073103AB104 lOO-
Sm (Mn, 2x3)
%-
03-Aug-2003 20:16:01
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
498 > 78
1.07e5
Area
0 "~`,"","",""i"","","","",~"`,"'
, r I I 1 Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000171
--
w-e---
--------------
Quantify Saxaple Report
&,+ Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:lC.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQnSMS6\Masslyax\Fluorochemicals.PRO\S~leDB\O73103~ Tue Aug 05 06:59:53 2003 P:\Data\L~SMS6\~asslynx\PluorochamicB\Decatur Sun hug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02
2003
----
Page 9
Decatur BC BC 080103
Name : 073103AR-105 Text :
1: C8 Acid (PFOA)
XCO72503-4,250 rig/L Standard
073103AR-105 la?-
Sm (Mn, 2x3)
%-
9.13 _ 128556
03-Aug-2003 20:37:5C
LC/MS/MS #6
MRM of 4 Channels ES413>369 7.38e5 Area
0 `~~~,~,,,.,,,,"",.,;,,,,.`,,,,l,,",,.',,~~,,I',`~I~~~~l
2.00
4.00
6.00
k# 2: C6 Sulfonate
XCO72503-4,250
(PFHS)
rig/L Standard
073103AR-105 loo-
Sm (Mn, 2x3)
%-
0 "","","","","","","",i"`(
2.00
4.00
6.00
: C8 Sulfonate
(CO72503-4,250
(PFOS)
rig/L Standard
173103AFb105 IO 9
Sm (Mn, 2x3)
8.00
a.98
10.00
Time 12.00
03-Aug-2003 20:37:5C LC/MS/MS #6
MRM of 4 Channels ES-
399 > 80
1.2985 Area
, , , , , , , , , , , , , Time
8.00
10.00
12.00
03-Aug-2003 20:37:5C LC/MS/MS #6
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000172
-----
----------
Quantify Sample Report
L, Study No.:L34910,
Set No.:O73103AR,
--
Ext.Date:07/31/03,
Analyst:K.Risha
------Page lo
Sampla List:
Last modified: Method:
Last modified: Job Code:
P:\Data\~~S6\Masslynx\Fluoroch~cals.P~O\S~leDB\O73lO3~ Tue Aug OS 06:59:53 2003 P:\Data\L~S6\Massl~\Fluoroch~cals.PXO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
--_-----
_I--
---Pm--
----
-----
Name: 073103AR-105 Text :
: PFOSA X072503-4,250
rig/L Standard
173103AR-105 10
%1"I
Sm (MI-I, 2x3)
03-Aug-2003 20:37:X(
K/MS/MS #6
MRM of 4 Channels ES-
9.90 4863: !
498 > 78 2.52e5
Area
I 10.00
Time 12.00
V
Oxygen Research, 3058 Research Drive, State College,
PA 16801
000173
Quantify Sample Report chd Study No.: L34910, Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:R.Risha
Sample List: Laet modified:
Method:
Last modified: Job Code:
P:\Data\LQbSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73lO3~
Tue Aug 05 06:59:53
2003
P:\Data\LC=MSMS6\Nassl~\Fluorochamicals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 11
Decatur BC BC 080103
NWM: 073103AR-106 Text :
: C8 Acid (PFOA)
(CO72503-5,500 rig/L Standard
)73103AR-106 10
7
%-I
Sm (Mn, 2x3)
9.13 264862
03-Aug-2003 20:59:3$ LC/MS/MS #6
MRM of 4 Channels ES413> 369 lSie6 Area
o',,,,,~,,,".,,"`.,`..`,"",."`,"","
I
, , , , , , , , , , ,Time
i
2.00
4.00
6.00
8.00
10.00
12.00 _
qd 2: C6 Sulfonate
XCO72503-5,500
(PFHS)
rig/L Standard
073103AFb106 10
Sm (Mn, 2x3)
%
8.98 43819-J
03-Aug-2003 20:59:3$ LC/MS/MS #6
MRM of 4 Channels ES399 > 80 2.5465 Area
I---
3: C8 Sulfonate
XCO72503-5,500
b"`L""i 2.00
`I ub,ml 4.00
(PFOS)
rig/L Standard
073103AR-106 IOO-
Sm (Mn, 2x3)
`II' trllllll,Txr 6.00
4' 8.00
9.27
%-
rflls' 10.00
m\rma `1 Time 12.00 _
03-Aug-2003 20:59:3<
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.65e5 Area
Oxygen Research, 3058 Research Drive, State College, PA 16801
000174
---__l-------
----
_-___------
-----mm-
Quantify Sample Report
&,J study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: - Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.P~\S~leDB\O73lO3~ Tue hug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
-----
Page 12
Decatur EC BC 080103
Name: 073103hR-106 Text :
4: PFOSA
XCO72503-5,500 073103AR-106 Sm
.rig/L
IMn.
,Standard
2x3)
%-
03-Aug-2003 20:59:39
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 104085
498 > 78 5.47e5
I
Area
0 ~~`~,"","l~,`~"/"",~)","","","~`l"'
2.00
4.00
6.00
8.00
ti
Time /
12100
Oxygen Research, 3058 Research Drive, State College, PA 16801
000175
--
----
---
-------
Quantify
Sampls Report
&,& Study No.:L34910,
Set No.. *073103AR,
Eixt.Date:07/31/03,
Analyst:K.Risha
Samgle List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LCM~S6\~sslynx\Fluorochemicals.PRO\S~leDB\O73lO3~ Tus Aug 05 06:59:53 2003 P:\Data\L~S6\Maeslynx\Fluorcchermic\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02
2003
----
Page 13
Decatur BC BC 080103
Name:
Text:
073103AR-107
1: C8 Acid (PFOA)
XCO72503-6,1000 t-q/L Standard
073103AR-107 loo-
Sm (Mn, 2x3)
%-
9.15
516215
03-Aug-2003 21:21:27 LC/MS/MS #6
MRM of 4 Channels ES413>369 2.96e6 Area
0 ~`~~,`~`~/`~~~/~~`~,`r"l""l""l'("1""
I I I I I , I I . I 1Time
2.00
4.00
6.00
8.00
10.00
12.00
1: C6 Sulfonate
KCO72503-6,1000
(PFHS)
rig/L Standard
073103AR-107 10
Sm (Mn, 2x3)
%$
03-Aug-2003 21:21:27
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
871t5
399 > 80 5.03e5
Area
3: C8 Sulfonate
XCO72503-6,1000
(PFOS)
rig/L Standard
1-0.73-1.0--3.AFb10.7. .-
I 910 1 %-
Sm(Mn,2x3)
I
Time
12.00 .
03-Aug-2003 21:21:27
LCJMWMS #6
MRM of 4 Channels ES499 > 99 3.12e5 Area
Exygen Research, 3058 Rwearch Drive, State College, PA 16801
000176
-----___
--p----m--------
Quantify Sample Report
w
Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Wasslynx\Fluorochemica~s.PRO\S~leDB\O73103~ Tue Aug 05 06:59:53 2003 P:\Data\Lc3MflrlS6\Masslynx\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02
2003
Name: 073103AR-107 Text :
Page 14
Decatur BC BC 080103
XCO72503-6,1000 rig/L Standard
073103AR-107 100-
Sm (Mn, 2x3)
%-
03-Aug-2003 21:21:27
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
1 .Ol e6
Area
0 `lll,/`l'(l'll,llll,lll',"ll,"l',"",IJ'I,II
, I I . 1 1 Time
2.00
4.00
6.00
8.00
10.00
12.00
EXYgen Research, 3058 Research Drive, State College, PA 16601
000177
Quantify Sample Report
w
Study No.: L34910, Set No.:O73103AR,
Ea&.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modifies:
Method:
Last modified: Job Code:
P:\Data\LQI~S6\Pssl~\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue hug 05 06:59:53 2003 P:\Data\LCMSMS6\~sslynx\FluorochemicalB\Decatur Sun hug 03 07:11:59 2003
Printed:
Wed hug 06 31:04:02 2003
Page 15
Decatur BC BC 080103
Name: 073103AR-108 Text :
1: C8 Acid (PFOA)
L34910-1 Spk C, 5000 rig/L, DF=lOO
073103AB108 Sm (Mn, 2x3)
03-Aug-2003 21:43:18
LC/MS/MS #6 MRM of 4 Channels ES-
413>369 2.96e5 Area
k# 2: C6 Sulfonate
(PFHS)
L3491 O-l Spk C, 5000 rig/L, DF=lOO
073103AFb108 Sm (Mn, 2x3)
Time 12.00
03-Aug-2003 21:43:18 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 3.37e4 Area
: C8 Sulfonate
(PFOS)
-34910-l Spk C, 5000 q/L,
DF=lOO
)73103AR-108 10
Sm (Mn, 2x3)
% :
Time 12.00 I
03-Aug-2003 21:43:1d LCNWMS #6
MRM of 4 Channels ES499 > 99 5.51e4 Area
I 10.00
Time 12.00
ExVgen Research, 3058 Research Drive, State College, PA 16801
000178
Quantify Sample Report 'ln14 Study No.: L34910, Set No.: 073103AR,
Ra&.Date:O7/31/03,
Analyst:R.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\~SMS6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3~
Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 16
Decatur BC BC 080103
Printed: ---
Wed Aug 06 11:04:02 2003 ---------
___-----
_--------
Name: 073103AR-108 Text :
4: PFOSA
L3491 O-l Spk C, 5000 rig/L, DF=lOO "
073103AFb108 10
Sm (Mn, 2x3)
03-Aug-2003 21:43:18
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 13039
498 > 78 6.85e4
Area
-en
Research, 3058 Research Drive, State College, PA 16801
000179
----
--- ------
------
Quantify
Sample Report
4d
Study No.:L34910,
Set No.: 073103AR, F.xt.Date:07/31/03,
Analyst:R.Risha
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\LeMSMS6\Masslynx\Fluorochamicals.PRO\S~leDB\O73lO3~
Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Pluorocb~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
-
Page 17
Decatur BC BC 080103
Name:
Text:
073103AR-109
: C8 Acid (PFOA)
-3491 O-l 2 Spk E, 5000 rig/L, DF=lOO
173103AFb109 Sm (Mn, 2x3)
%110 "$-1
2.00
4.00
6.00
1: C6 Sulfonate
(PFHS)
L3491 O-1 2 Spk E, 5000 rig/L, DF=l 00
073103AFb109 10
Sm (Mn, 2x3)
9.13 92540
03-Aug-2003 22:04:56 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 5.53e5 Area
i--
8.00
10.00
Time 12.00
03-Aug-2-003 22:04:56/ LC/MS/MS #6
MRM of 4 Channels ES-
8.98 10314
399 > 80 6.00e4
Area
2.00
4.00
6.00
3: C8 Sulfonate
(PFOS)
L3491 O-1 2 Spk E, 5000 rig/L, DF=lOO
073103AR-109 100-
Sm (Mn, 2x3)
%-
".
8.00
10.00
Time 1 12.00
03-Aug-2003 22:04:5( LC/MS/MS #6
MRM of 4 Channels ES499 > 9s 1.03e5 Area
muen Research, 3058 Research Drive, State College, PA 16801
000180
----
_-__--
_--_-B------B
-__-____
---
Quantify Sample Report
&,# Study No.:L34910,
Set No.: 073103AR, Rxt.Date:07/31/03,
Analyst:K.Risha
Page ia
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\bssl~\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCHSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 060103
Printed:
Wed Aug 06 11:04:02 2003
.-______-__-__________________--___I_____-------------~--
Name:
Text:
073103AR-109
4: PFOSA
L3491 O-l 2 Spk E, 5000 rig/L, DF=lOO
03-Aug-2003 22:04:56
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
49a> 78
8.15e4
Area
WrJen Research, 3058 Research Drive, State College, PA 16801
-_--
000181 -.-_-_-,_..
l__---_l____------__
-------
------
Quantify Sample Report
-4 Study No.:L34910,
Set No.: 073103AR, Ext,Date:07/31/03,
-----_1_--
Analyst:X.Risha
-
Page 19
Sample List: Last modified: Method: Last modified: Job code:
P:\Data\L~~S6\~ssl~\Fluarochemicals.PRO\S~leDB\O73lO3~ Tus Aug 05 06:59:53 2003 P:\Data\L~SMS6\Masslynx\Fluorochemical$.PRO\~t~B\Decatur Sun Aug 03 07:11:59 2003
Printed: __-----___
Wed Aug 06 11:04:02 2003
--------
----_____-___-___--
Name: 073103AR-110 Text:
---__---
Decatur BC BC 080103
--_---
1
1.3491 O-l 6 Spk F, 5000 rig/L, DF=lOO
C)73103AR-110 10
Sm (Mn, 2x3)
%
9.13 11471r
03-Aug-2003 22:26:4 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 6.50e5 Area
i
I
2.00
4.00
6.00
8.00
2 : C6 Sulfonate
(PFHS)
1-3491 O-l 6 Spk F, 5000 rig/L, DF=lOO
( 173103AR-110 10
Sm (Mn, 2x3)
%
8.96 10701
03-Aug-2003 22:26:4d LC/MS/MS #6
MRM of 4 Channels ES399 > 80 6.13e4 Area
/:
2.00
4.00
8.00
,,
, I
II,
10.00
I,
,lTime
12.00
3 : C8 Sulfonate
(PFOS)
1-3491 O-l 6 Spk F, 5000 rig/L, DF=lOO
( 173103AR-110 10
Sm (Mn, 2x3)
9.25 22405
03-Aug-2003 22:26:4C LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.26e5 Area
w
Exysen Research, 3058 Research Drive, State College, PA 16801
000182
Quantify san@e Report
114 Study No.:L34910,
Set No.. *073103AR,
Ext.Date:07/31/03,
A.nalyst:K.Rieha
Sample List:
Last modified: Method: Last modified:
ifob Code:
P:\Data\LCMSMS6\Masslynx\Fluorochsmicals.PRO\S~leDB\O73103~ Tue Aug 05 06:59:53 2003 P:\Data\L~SMS6\Masslynx\Fluorochemicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Auq 06 11:04:02 2003
Page 20
Decatur BC EC 080103
Nsme: 073103AR-110 Text:
4: PFOSA
L3491 O-l 6 Spk F, 5000 rig/L, DF=lOO
1073103AR-110
I--,-f--ih -.-
I"T
Sm(Mn,2x3)
%-
03-Aug-2003 22:26:4C
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 18398-
498 > 78 9.42e4
Area
Exygen Research, 3058 Research Drive, State College, PA 16801
000183
Quantify Sample Report
Q& Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\L(1MSMS6\Masslynx\FluorocbamicalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 21
Decatur BC BC 080103
Name: 073103AR-111 Text :
1: 03 Acid (PFOA)
XCO72503-I,25 rig/L Standard
073103AR-111 10
Sm (Mn, 2x3)
9.13 14631
03-Aug-2003 22:48:24 LC/MS/MS #6
MRM of 4 Channels ES413> 369 8.76e4 Area
2: C6 Sulfonate
XCO72503-1,25
(PFHS)
rig/L Standard
073103AFb111 100-
Sm (Mn, 2x3)
%-
03-Aug-2003 22:48:23
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
2324
1.44e4
Area
o-,,~-r;,,,`,,,,,,:.,,,`,.,,,,.,,-,;-?,,,.,,,.
, , , , , , , , ,-, , I, Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
XCO72503-I,25
(PFOS)
rig/L Standard
,073103AR-111 lOO-
Sm (Mn, 2x3)
%-
03-Aug-2003 22:48:23 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 9.17e3 Area
Oxygen Research, 3050 Research Drive5 State College, pA 16601
000184
Quantify San@0 Report
q& Study No.:L34910,
Set No.: 0?3103AR, Ext.Date:07/31/03,
AnalystxX.Risha
Page 22
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L(3MSMS6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue hug 05 06:59:53 2003 P:\Data\LCMSMS6\blass~~\FluorochemicalB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
----------------------------------------
------
-------0-----
Name: 073103AR-111 Text :
4: PFOSA
XCO72503-1,25 rig/L Standard
073103AFb111 Sm (Mn, 2x3)
03-Aug-2003 22:48:2: LC/MS/MS #E
MRM of 4 Channels ES498 > 78 2.92e4 Area
Time 12.00
Exygen Research,
3058 Research
Drive, State College,
PA 16801
800185
-
-----a--
----
Quantify
Sample Report
Id
Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LQ3SMS6\~6slynx\Bluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003
P:\Data\LCMSnS6\MasslyPx\FluorochamicalsB\Decatur Sun Aug 03 07:11:59 2003
Page 23
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
--------
-----------------___I___--__
--
Name : 073103AR-112 Text :
1: C8 Acid (PFOA)
IL3491 O-l, DF=lO
073103AFb112 10
Sm (Mn, 2x3)
% 1
9.13 216041
03-Aug.2003 23:lO:Od LCIMSNS #6
MRM df 4 Channels ES413 > 369 1.26e6 Area
II& 2: C6 Sulfonate
(PFHS)
L3491 O-1, DF=l 0
073103AR-112 loo-
Sm (Mn, 2x3)
I_
Time
12.00
03-Aug-2003 23:10:02 LCYMWMS #6
MRM of 4 Channels ES-
6.98 9381
%-
`m
Time
2.00
4.00
6.00
8.00
10.00
: C8 Sulfonate
(PFOS)
83491O-l, DF=l 0
73103AFb112 `OOl
Sm (Mn, 2x3)
03-Aug--2003 23:10:02j LC/MS/MS #6
MRM of 4 Channels ES-
9.24
499 > 99
61501
3.57e5
Area
m
Time
2.00
4.00
6.00
8.00
10.00
12.00
Eawgen Research, 3058 Research Drive, State College, PA 16801
000186
Quantify Sample Report
14 Study No.:L34910,
Set No.: 073103AR, Ext.Dats:O7/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\L~SMS6\MasslyPx\Fluoroch~cal~.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2903 P:\Data\L~SMS6\Ma6slynx\Fluorochamicals.?RO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 24
Decatur BC BC 080103
Name: 073103AR-112 Text :
4: PFOSA
L3491 O-l, DF=l 0
073103AFb112 lOO-
Sm (Mn, 2x3)
%-
. . .. 03-Ayg-2FII3 23:10:02 LC/MS/M'S #6
MRM of 4 Channels ES-
9.89 _ 27920
498 > 78 1.43e5
Area
Oxygen Research, 3056 Research Drive, State Collage, PA 16801
OQOl87
Quantify Sample Report
Study No.: L34910,
Set No .:073103AR,
Ext.Date:07/31/03,
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQIISMS6\Masslyax\Fluoroch~cals.PRO\S~leDB\073103AR
Tue Aug 05 06:59:53
2003
P:\Data\LCMSMSC\Masslynx\Fluoroch~cals.PRO\lsthDB\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Wed Aug 06 11:04:02
2003'
------------------------------_________I_
Name: Text:
073103AR-113
1: CB Acid (PFOA)
L34910-1 Rep, DF=10
073103AFL113 lOO-
Sm (Mn, 2x3)
%-
4
0 ,,,,~,,,,,,,~,,,~,,,,,,I,,,,,~,,,,,,,,,
2.00
4.00
6.00
2: C6 Sulfonate
(PFHS)
L3491 O-1 Rep, DF=lO
073103AR-113 lOO-
Sm (Mn, 2x3)
%-
0 "I
87 " ' , s 8 `T I"",' 2.00
3: C8 Sulfonate
(PFOS)
L3491 O-l Rep, DF=lO
r 8 8 ,I 8 r - / 4 I, f
4.00
6.00
073103AR-113 lOO-
Sm (Mn, 2x3)
%-
AnalystrK.Risha
Page 25
Decatur
BC
BC 080103
----P--P-
03-Aug-2003 23:31:52
LC/MS/MS #6
MRM of 4 Channels ES413 > 369 1.26e6 Area `.
8.00 8.98
I t , 10.00
I , I I 1Time 12.00
03-Aug-2003 23:31:52
LCNWMS #6
MRM of 4 Channels ES399 > 80 5.8Oe4 Area
Time
8.00
10.00
12.00
9.25 59888
03-Aug-2003 23:31:52 LClMStMS #6
MRM of 4 Channels ES499 > 99 3.52e5 Area
wgea
Research,
3058 Research
Drive,
State College,
PA 16801
000188
Quantify Sample Report
'4
Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:R,Risha
Sample List:
Last modified: Method:
Last modified: ifoh Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\O73103~
Tue Auq 05 06:59:53
2003
P:\Data\L(SMSMS6\Masslynx\Fluorochamicals.PRO\MethllB\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 26
Decatur BC BC 080103
NW: 073103AR-113 Text :
4: PFOSA
-34910-l Rep, DF=lO
173103AFb113
10
"i %-
Sm (Mn, 2x3)
03-Aug.2003 23:31:5: LC/MS/MS #r
MRM of 4 Channels ES-
ExygeP Research, 3058 Research Drive, State College, PA 16801
000189
Quantify San&Jle Report
TJ Study No.:L34910,
Set No .:073103AR,
Ext.Date:07/31/03,
Analyst:R.Risha
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~
Tue Aug 05 06:59:53 2003
P:\Data\LCMSMS6\Masslynx\FluotochemicalsB\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 27
Decatur BC BC 080103
Name: 073103AR-114
Text :
1: C8 Acid (PFOA)
L3491 O-4, DF=lO
073103AFb114 100-
Sm (Mn, 2x3)
%-
03-Aug-2003 23:53:41
LC/MS/MS #6
MRM of 4 Channels ES-
9.13
413>369
7.7405
Area
o'v ,,,~,,,,,,,,,,.,,,,,,,,,,,,,.,
2.00
4.00
2: C6 Sulfonate
(PFHS)
L3491 O-4, DF=lO
073103AR-114 loo-
Sm (Mn, 2x3)
%-
# I,III,,IJII
6.00
8.00
a , , , , , , , , , , , Time
10.00
12.00 )
8.98 _ 6122
03-Aug-2003 23:53:41
LCIMSNS #6
MRM of 4 Channels ES399 > 80 3.73e4 Area
0
,,, . , , ,, , ,qTime
2.00
4.00
6.00
8.00
10.00
12.00 ,
* C8 Sulfonate
(PFOS)
-3491 O-4, DF=lO
)73103AR-114
%110
Sm (Mn, 2x3)
03-Aug-2003 23:53:41 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.59e5 Area
Time
ExyOen Research, 3058 Research Drive, State College, PA 16801
00019d
Quantify Sample Report
v
Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCM~S6\bssl~\Fluoroch~ca~s.PRO\S~leDB\O73103~ Tue Aug 05 06:59:53 2003 P:\Data\~SWS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 28
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
---------_-_-__-___
-m-v----
---------------e
__.-_
Name: 073103AR-114 Text :
4: PFOSA
L3491 O-4; DF=l 0
073103AFb114 lOO-
Sm (Mn, 2x3)
`7.
'
%-
03-Aug-2003 23:53:41
LCIMSIMS #6
MRM of 4 Channels ES-
9.90
498 > 78
1.05e5
Area
0 "","","","","","",""I',","","
I I x I I Time
2.00
4.00
6.00
8.00
10.00
12.00
Ewgen Research, 3058 Reseaxch Drive, State College, PA 16801
000191
Quantify S-10 Report
w
Study No.: L34910, Set No.:O73103AR,
Ext.Dats:07/31/03,
Analyst:K.Risha
Page 29
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LQrlSMS6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3~
Tue Aug 05 06:59:53
2003
P:\Data\LWSMS6\Masslynx\Fluotochamicals.~O\~et~E\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
s-m----
Wed Aug 06 11:04:02 2003
-----
-------
---
------__
Name: Text:
073103AR-115
1: C8 Acid (PFOA)
L3491 O-2, DF=lO
I(173103AR-I
10 7
15 Sm (Mn, 2x3)
%
9.15 142555 i
04-Aug-2003 00:15:3Cj LCYMWMS #6
MRM of 4 Channels ES413 > 369 8.29es Area
i
2.00
!: C6 Sulfonate
(PFHS)
L3491 O-2, DF=l 0
I
a.00
10.00
Time 12.00
04-Aug-2003 oo:l6:3d
073103AFb115 Sm (Mn, 2x3) 8.98 7036
L 6.00
3: C8 Sulfonate
(PFOS)
L3491 O-2, DF=lO
073103AR-115 ff-ln,
I
i _.
Sm (.Mn, 2x3) .
0 ~~`,~`~~,"~~,~`~~,~~~~,~"`,~`~~,~"~I~~~~,
2.00
4.00
6.00
a.00
9.27 37566
04-Aug-2003 oo:l sad
LC/MS/MS #6
MRM of 4 Channels ES-
499 > 99 2.19e5 Area
bm
a.00
10.00
Time /
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
._..,_X_*-,II
_._-
._,---
000192 ___-.. ..-
------_---
--s-----w-
------
---s----w
-
Quantify San@e Report
td Study No.:L34910,
Set No .:073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Page 30
Sanpls List: Last modified:
Method: Last modified: Job Code:
P:\Data\LCblSMS6\Masslynx\Fluorochsmicals.PRO\S~leDB\O73lO3~ Tue hug 05 06:59:53 2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.P~O\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC EC 080103
Printed: --____--_---------
Wed hug 06 11:04:02 2003 -----_--A-
Name : 073103AR-115 Text :
----v---------
4: PFOSA
L3491 O-2, DF=lO
073103AFb115 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 00:15:30
LCfMS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
8.43e4
Area
0 "","",1"`,"`1,"`1,"`1,"`1,"","",'11
, , ( , , , , ,Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
..l^^.~---_l_---
.~"_^._"._
_"l-ll---ll
..-
.-
000193
---I__
_____I___--___________________I----------------
Quantify Sample Report
IJ Study No.:L34910,
Set No.. -073103AR, Ext.Dats:07/31/03,
Analyst:K.Risha
Page 31
Sample List: Last modifieh:
Method: Last modified:
Job Code:
P:\Data\LCMSMS6\~sslynx\Fluorochemical~.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\L~SMS6\Masslynx\Fluorochemica\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
_--------______I__--~
-------------c-------------
-------
Name : 073103AR-116 Text:
: C8 Acid (PFOA)
(CO72503-2,50 rig/L Standard
)73103AR-116 10
Sm (Mn, 2x3)
04-Aug-2003 00:37:14
LC/MS/MS #6
9.13 292%
MRM of 4 Channels ES413>369 1.78e5
Area
4
2.00
4.00
6.00
a.00
KC072503-2,50rig/L Standard
073103AK116 Sm (Mn, 2x3)
04-Aug-2003 00:37:1 q
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
4266
2.73e4
Area
I: C8 Sulfonate
KC072503-2,50
(PFOS)
rig/L Standard
073103AFb116 10
Sm (Mn, 2x3)
4
04-Aug-2003 00:37: 19
LC/MS/MS #6
MRM of 4 Channels ES-
9.25
499 > 99
2882
1.77e4
Area
L-;
Time
12.00
Oxygen Research, 3058 Research Driira, State College, PA 16801
000194
Quantify Sample Report
W Study No.:L34910,
Set No.. -073103AR, Ext.Date:O7/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\LQt~S6\Lrlassl~\Fluoroch~cal~.PRO\S~leDB\O73lO3~
Tue Aug 05 06:59:53 2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\~et~B\Decatur
Sun Aug 03 07:11:59
2003
Page 32
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02
2003
-_____-I_---------------
__-----------
-----
Name : 073103AR-I.16 Text :
4: PFOSA
XCO72503-2,50
rig/L Standard
073103AR-116 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 00:37:19
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
5.94e4
Area
0 "`~,"`~,~~`~/)~~`,`~(~,~~~~,~`~J,~"',~(~l,
2.00
4.00
6.00
8.00
, I I I 1 1 Time 12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
800195
----__-----_
-__------I_----I_____
--w-p
Quantify
Szmqls Report
sf
Study No.:L34910,
Sat No .:073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Pluoroch~cals.PRO\S~leDB\O73lO3~
Tue Aug 05 06:59:53 2003
P:\Data\LCMSMS6\~ss~~\FluorochemicalB\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Wed Aug 06 11:04:02 2003
-VW---_
Page 33
Decatur
BIJ
BC 080103
Name:
Text:
073103AR-117
1: C8 Acid (PFOA)
L3491 O-6, DF=lO
~073103AR-117 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 00:59:01
LC/MS/MS #6
MRM of 4 Channels ES-
9.13
419 >369
2.33e5
Area
2: C6 Sulfonate
(PFHS)
L3491 O-6, DF=lO
073103AFb117 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 00:59:01
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
9.39e3
Area -
: C8 Sulfonate
(PFOSI
-3491 O-6, DF=l 0
173103AR117 Sm (Mn, 2x3)
04-Aug-2003 00:59:011
LC/MS/MS #6
MRM of 4 Channels ES-
9.25
499 > 99
9224
5.40e4
Area
Time 12.00
Rawgem Research, 3058 Research Drive, Stats Collage, PA 16801
000196
Quantify
Sample Report
1~ Study No.:L34910,
Set No.: 073103AR, Ext.Date:O7/31/03,
?malyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\L~.SbiS6\Uasslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSbiS6\Maaslynx\FluorochemicB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed hug 06 11:04:02 2003
Page 34 '
Decatur BC
EC 080103
Name: 073103AR-117 Text:
4: PFOSA
L3491 O-6, DF=lO
073103AFb117 100-l
Sm (Mn, 2x3)
%-
04-Aug-2003 00:59:01
LCPMSNS #6
MRM of 4 Channels ES-
9.09
498 > 78
1.84e4
Area
r I I I , r I e I I Time
10.00
12.00
mgen Rasektch, 3058 Research Drive, State College, PA 16801
000197
Quantify Sample Report
$& Study No.rL34910,
Set No .:073103AR,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\~ssl~\Fluorochemicals.PRO\S~l~DB\O73103~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\~sslynx\Pluorochemicalr Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Name: 073103AR-118 Text :
Page 35
Decatur BC BC 080103
.34910-6 Rep, DF=lO
)73103AR-118 10
Sm (Mn, 2x3)
04-Aug-2003 01:20:44 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 2.33e5 Area
w 2: C6 Sulfonate
(PFHS)
L34910-6 Rep, DF=iO
073103AR-118 lOO-
Sm (Mn, 2x3)
%-
, , , , I , , , , , , ,-l Time
10.00
12.00
04-Aug-2003 01:20:44
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
9.36e3
Area
-
O~,,,r,.~,i,,,,,,,~,~,,,r,,,,,~,~~I~,~
, t .m,
Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
(PFOS)
L34910-6 Rep, DF=lO
073103AFb118 10
"i %-
Sm (Mn, 2x3)
04-Aug-2003 01:20:44
LC/MS/MS #6
MRM of 4 Channels ES-
9.27
499 > 99
5.02e4
Area
0 ~~~~~~~~,~~~~,`~~~,`~"I"~
Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, pA 16801
000198
------
-_------
-1--_1
---------~--I_--
Quantify Sarqple Report
'4
Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Ri.sha
Page 36
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCbI~S6\Masslynx\Fluoroch~calS.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 B:\Data\LCNSMS6\Masslynx\Fluoroch~ca~S.PRO\Met~B\Decatur Sun Aug 03 07:X1:59 2003
Decatur BC BC 080103
Printed: -----
Wed Aug 06 11:04:02 2003
--a---
---_-----_---------------------_-__
Name: 073103zm118
Text :
: PFOSA
-34910-6 Rep, DF=lO
)73103AR-118 10
Sm (Mn, 2x3)
04-Aug-2003 01:20:4r
LC/MS/MS #t
MRM of 4 Channels ES-
9.89
498 > 72
3402
1.76eL
AreE
O',,`~,,`,,,,,,,,,r.,,`,,,,,,,`,,,.,,,,,,,,.,,,,,,'
I..
Time
2.00
4.00
6.00
8.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
.,_-^--
-~
000199
_.---.- -
Quantify Sample Report
u
Study No.:L34910,
Set No .:073103AR, Ext.Dats:07/31/03,
Analyst:K.Risha
Page 37
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQrlSMS6\~ssl~\Fluoroch~cals.PRO\S~leDB\O73lO3~
!I'ue hug 05 06:59:53 2003 P:\Data\L~SMS6\Maselynx\Fluorochemica\~et~B\Decatur
Sun Aug 03 07:11:59
2003
Decatur BC EC 060103
Printed: -----__
Wed Aug 06 11:04:02 2003 ------_-------I_-----------------------------_-
---_-_-
Name: 073103AR-119 Text :
1: CB Acid (PFOA)
IL3491 O-9, DF=l 0
073103AR-119 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 01:42:3tj
LC/MS/MS #6
MRM of 4 Channels ES-
9.13
413 > 369
4.77e5
Area
0 I,1 ,(-?Y I ,,1111,/111/1/~1(1~11,1111,1111,111
2.00
4.00
6.00
`4 !: C6 Sulfonate
(PFHS)
-3491 O-9, DF=l 0
173103AFb119 Sm (Mn, 2x3)
> 8.00
8.98
3725
, , I , , , , Time
10.00
12.00
04-Aug-2003 01:42:36]
LC/MS/MS #6
MRM of 4 Channels ES399 > 80 2.31 e4 Area
3: ca Sulfonate
(PFos)
L3491 O-9, DF=l 0
073103AR-119 Sm (Mn, 2x3)
, I.,,j .,,I ,
10.00
I 1 Time
12.00
9.25
23649
04-Aug-2003 01:42:36 LCNSIMS #6
MRM of 4 Channels ES499 > 99 1.3505 Area
wgen Research, 3056 Research Drive, State College, PA 16801
QOO200
Quantify Sample Report bd Study No.: L34910, Set No.:O73103AR,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~~S6\Maselynx\Bluoroch~cals.PRO\S~~eDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\L~SMS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
------_-_------___---
m--------v-
--------m_
Name: 073103AR-119 Text :
Page 38
Decatur BC EC 080103
L3491 O-9, DF=lO
073103AR-119 Sm (Mn, 2x3)
04-Aug-2003 01:42:36 LCIMSNS #6
MRM of 4 Channels ES490 > 78 4.44e4 Area
Time 12.00
E%ygen Research, 3058 Research Drive, State College, PA 16801
000201
-----
----------------
----a------
p-v--
Quantify Sampl.e Report `Id Study No. : L34910, Set No .:073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last nmdified: Job Code:
P:\Data\L~SMS6\~sslynx\Fluorochamicals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCM~S6\blasslynx\Pluoroch~cals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Page 39
Decatur BC BC 060103
Printed:
Wed Aug 06 11:04:02 2003
-I----------__-------------__________II________----
--m--P-_
Name: 073103AR-120 Text :
1 : C8 Acid (PFOA)
1-34910-7, DF=lO
r
t )73103AR-120 Sm (Mn, 2x3)
9.13 1127010
04-Aug-2003 02:04:23
LC/MS/MS #6
MRM of 4 Channels ES413 > 369 6.62e5 Area
2.00
: C6 Sulfonate
(PFHS)
-3491 O-7, DF=lO
173103AR-120
10
Sm (Mn, 2x3)
A--
Time
12.00
6.97 6025
04-Aug-2003 02:04:23
LC/MS/MS #6
MRM of 4 Channels ES-
399>80 3.66e4
Area
3: C8 Sulfonate
(PFOS)
L3491 O-7, DF=lO
073103AFb120 lOO-
Sm (Mn, 2x3)
%-
0 ,,,,-;-,,,,,,,,,,~,,,,~2,,.,0,,0,~,,,,,,,~,,,,,,~,~~~4,.~0~0,~,~~,~,Time 6.00 >
9.25 _ 29284
04-Aug-2003 02:04:22 LC/MS/MS #E
MRM of 4 Channels ES499 > 9E 1.69eE Aree
8.00
10.00
12.00
wgen Research, 3058 Research Drive, State College, PA I.6601
. .--- .-.-
ll^ll_l_----
--...
- -.
----
-
--__-----------
Quantify
Sample
Study No .:L34910,
Report Sat
No .:073103AR,
Ext.Data:07/31/03,
Samgle List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Wasslynx\Fluotochrmicals.PRO\S~i~DR\O73lO3~
Tue Aug 05 06:59:53
2003
P:\Data\LCM93S6\Masslynx\Fluorochsmicals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Printed: e--v--
Wed Aug 06 11:04:02
2003
---
m---w-------
Name: 073103A?i-120 Text :
--e-------
4: PFOSA
L34910-7,DF=lO
073103AFb120 Sm (Mn, 2x3)
-__--
Analyat:K.Risha
----
Page 40
Decatur
BC
BC 080103
I--------___
04-Aug-2003 02:04:23/
LC/MS/MS#6
MRM of 4 Channels ES-
9.89
11595
490 > 78 5.91 e4
I
Area
w
Time
6.00
10.00
12.00
Exygen R-earth,
3058 Research
Drive,
State college,
PA 16801
000203
Quantify Sample Report
qrf Study No.:L34910,
Set No.: 073103AR, E&.Dater07/31/03,
Analyst:K.Risha
Salnple List: Last modified:
Method: Last modif ied:
Job Code:
P:\Data\L~SMS6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003
P:\Data\LCMSMSb\Masslynx\Fluorochemical~.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
I___------____-_---m--w------w-------------
Name : 073103AR-121 Text :
.: C8 Acid (PFOA)
<CO72503-3,100 rig/L Standard
373103AR-121 10 O-4
Sm(Mn,2x3)
9.15 5566:
Page 41
Decatur BC BC 080103
-A----
04-Aug-2003 02:26:03( LC/MS/MS #6
MRM of 4 Channels ES413>369 3.27e5 Area
---~--r-rrpq
Time I
2.00
4.00
6.00
8.00
10.00
12.00
I: c6 Sulfonate
KO72503-3,100
(PFHS)
rig/L Standard
173103AR-121 Sm(Mn,2x3)
04-Aug-2003 02:26:03
LCIMSIMS #6
MRM of 4 Channels ES-
8.9E
399 > 80
948t
5.49e4
Area
, e I I I , I - I I 1 Time
10.00
12.00
3: C8 Sulfonate
(PFOSI
XCO72503-3,100 rig/L Standard
04-Aug-2003 02:26:03 LC/MS/MS #6
073103AR-121 10
% $
Sm (Mn, 2x3)
MRM of 4 Channels ES-
9.27
499 > 99
6004
3.49e4
Area
I
Time
2.00
4.00
6.00
8.00
10.00
12.00 I
Exyoen Research, 3058 Research Drive, State College, PA 16801
__ .--..1-
000204
-
----.
------------s--m-
------m-w
Quantify SamQle Report
%& Study No.:L34910,
Set No.: 073103hR.
Eact.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified:
Job code:
P:\Data\LCMSMS6\Maaslynx\Fluorochemicals.PRO\S~leDB\O73lO3~ Tue hug 05 06:59:53 2003 P:\Data\L~SMS6\Masslynx\Fluoroch~cals.PRO\Met~R\~catur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
--m-p-
Page 42
Decatur BC BC 080103
Nanm: 073103AR-121 Text :
4: PFOSA
(CO72503-3,100
rig/L Standard
373103AR-121 Sm (Mn, 2x3)
04-Aug-2003 02:26:03
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 21221
490 > 78 1.12e5
Area
O',",,"`,,.`..,,,,,,,,,,,`..`,.,.,,,,',,,,'.,.,,
i--
Time
2.00
4.00
6.00
8.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000205
Quantify
Sample Report
q.# Study No.:L34910,
Set No.. *073103AR,
Ext.Date:07/31/03,
Analyst:K.Risha
sanQ1s List:
Last modified: Method:
Last modified:
Job Code:
P:\Data\L~SMS6\Masslynx\Fluorochemicals.P~\S~leDB\O73103~
Tue Aug 05 06:59:53
2003
P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\Met~B\~catur
Sun Aug 03 07:11:59
2003
Printed:
Wed Aug 06 11x04:02
2003
Name: 073103AR-122
Text :
I: C8 Acid (PFOA)
L3491 O-l 2, DF=20
073103AB122 10
Sm (Mn, 2x3)
9.13 308911
%-
Page 43
Decatur BC
BC 080103
04-Aug-2003 02:47:47 LCIMWMS #6
MRM of 4 Channels ES413 > 369 1.81e6 Area
Q
,,,~~,,,,,,,,,,,,,,,,,~,,,~,,,,~
2.00
4.00
!: C6 Sulfonate
(PFHSI
L3491 O-l 2, DF=20
073103AFb122 Sm (Mn, 2x3)
IIIII\/III
I 1 I I I I I v 1 I I I I ,lTime
6.00
8.00
10.00
12.00 1
04-Aug-2003 02:47:47
LC/MS/MS #6
8.98 26169 I7
MRM of 4 Channels ES399 > 80 1.54e5
Area s
L3491 O-l 2, DF=20
073103AR-122 10
Sm (Mn, 2x3)
9.25 64499
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 3.81 e5 Area
o',,~,,,,,,,`,`,,`,,`,`,,,r,"`,`,,',,",,"',l'
- --
I
2.00
4.00
6.00
8.00
Time 12.00
Exygen Research,
3058 Research
Drive,
State College,
PA 16801
0002OE
Quantify
Simple Report
s& Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SXS6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 44
Decatur BC BC 080103
Name: 073103AR-122 Text :
4: PFOSA
L3491 O-l 2, DF=20
073103AR-122 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 0234734;
LC/MS/MS #c
MRM of 4 Channels ES-
9.88
490 > 7E
1.25ef
Area
0 "","","","","","","","","",
I , , , , , , , 1Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
kd 3 iL3.n
---------_--_-P
------------------m--w---
---
-------_
Quantify Swle Report
&d Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\~ssl~\Fluorochamicals.PRO\S~leDB\O73lO3~ Tue Aug OS 06:59:53 2003 P:\Data\LCMSMS6\~sslynx\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 45
Decatur BC BC 080103
Name: 073103AR-123 Text :
1: C8 Acid (PFOA)
13491 O-l 2 Rep, DF=20
073103AFb123 IOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 03:09:25 LCNWMS #6
MRM of 4 Channels ES413>369 I .84e6 Area
0 ~~~~~~~~,~~~`I~~~~I~~~~,"",`~","",
, , v I , I , I , Time
2.00
4.00
6.00
8.00
10.00
12.00 _
: C6 Sulfonate
(PFHS)
.3491 O-l 2 Rep, DF=20
173103AFb123 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 03:09:25
LC/MS/MS #6
k;1RM of 4 Channels ES-
8.98
399 > 80
1.56e5
Area
3: C8 Sulfonate
(PFOS)
13491 O-l 2 Rep, DF=20
073103AR-123 10
Sm (Mn, 2x3)
1 I , . , , I r 1 Time
6.00
8.00
10.00
12.00
9.25 64047
04-Aug-2003 03:09:24
LCYMWMS #6
MRM of 4 Channels ES499 > 99 3.75eS Area
I/
1
Time
2.00
4.00
6.00
8.00
10.00
12.00 I
-0a
Research, 3058 Research Drive, State College, pA 36801.
000288
Quantify Sample Report
w StuUy No.:L34910,
Set No.. *073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified:
Method: Last modified: Job Code:
P:\Data\LWSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemieals.PXO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Name: 073103AR-123 Text :
Page 46
Decatur BC BC 080103
L3491 O-l 2 Rep, DF=20
073103AFk123 10
Sm (Mn, 2x3)
%-
04-Aug-2003 03:09:25
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
23261
498>78
1.19e5
Area
i
Time
Wgen Research, 3058 Research Drive, State College, PA 16801
000209
---
-----
-----
----
-----
Quantify
SanTQle Report
\crl Study No.rL34910,
Set No.. -073103A.R, Ext.Date:O7/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
---Page 47
Decatur BC BC 080103
Name: 073103AR-124 Text :
: C8 Acid (PFOA) -3491 O-l 5, DF=20
)73103AR-124 10
Sm (Mn, 2x3)
04-Aug-2003 03:31:09 LC/MS/MS #6
MRM of 4 Channels ES413>369 1.70e6 Area
O',,,~_r,,,,,,,,,,,,,,,,,,,,~~,,,~,,,,,,,,,,~,,
I I , I I Q I , I I I I 1 Time
2.00
4.00
6.00
8.00
10.00
12.00
!: C6 Sulfonate (PFHS) L3491 O-l 5, DF=20
073103AR-124 10
Sm (Mn, 2x3)
% i
8.98
25364
04-Aug-2003 03:31 :Od LCYMSIMS #6
MRM of 4 Channels ES-
399 > 80 1.46e5 Area
2.00
4.00
6.00
8.00
' 10.00
12.00 I
3: C8 Sulfonate (PFOS) L34910-15, DF=20
073103AFb124 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 03:31:05 LC/MS/MS #e
MRM of 4 Channels ES499 > 96 3.74e5 Area
ExyOen Research, 3058 Research Drive, State Collage,
PA 16801
000210
----w------e--
--------_I
----e-e----
-----v
Quantify Sample Report
w study No.:L34910,
Set No.. -073103AR, Ext.Date:07/31/03,
Analyst:K.Riarha
Page 48
Sample List: Last modified: Method: Last modified: ?ob Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
__-----
----------------e---B--
-----
---
------
Name: 073103AR-124 Text :
4: PFOSA
L3491 O-l 5, DF=20
04-Aug-2003 03:31:0
073103AFb124 Sm (Mn, 2x3)
9.90
25908
498 > 78 1.30e5 Area
2.00
4.00
6.00
8.00
10.00
12.00
W
Oxygen Research, 3058 Research Drive, State College, PA 16801
000211
Quantify Swle Report
\IJ Study No.:L34910,
Set No .:073103AR,
Ext.Date:07/31/03,
Analyst:K.Rieha
Page 49
Santple List: Last modified:
Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochamieals.PRO\S~leDB\O73103~ Tue Aug 05 06:59:53 2003
P:\Data\LCMSMS6\Masslynx\Bluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: --------h----P
Wed Aug 06 11:04:02 2003
-----_
-------------------
Name: 073103AR-125 Text :
L: C8 Acid (PFOA)
L3491 O-l 3, DF=20
073103AFk125
lo9
% 4
Sm (Mn, 2x3)
9.13 3547x )
04-Aug-2003 03:52:55 LC/MS/MS #6
MRM of 4 Channels ES413>369 2.09e6 Area
!: C6 Sulfonate
(PFHS)
L3491 O-l 3, DF=20
IL--
Time
12.00
04-Aug-2003 03:52:55/
073103AFb125 10
Sm (Mn, 2x3)
8.98 30673
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
(PFOS)
IL3491 O-l 3, DF=20
(373103AFb125 10
Sm (Mn, 2x3)
04-Aug-2003 03:52:55
LCIMSIMS #6
9.25 7783:
MRM of 4 Channels ES499 > 99 4.48e5
Area
r I , I , I , I . r I , Time
10.00
12.00
Exygea Research, 3058 Research Drive, State College, PA 16801
000212
-------__
----
mm--
~-----__
--
Quantify Sample Report Study No .:L34910, Set No.: 073103AK
Ext.Date:07/31/03,
Analyst:K.Risha
Page 50
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCblSMS6\~ssl~\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
wed Aug 06 11:04:02 2003
----------------__-----------------------------------_
-----
Name: 073103A.R-125 Text :
4: PFOSA
i-3491 O-l 3, DF=20
073103AR-125 I 1001
I --- i
%-
Sm (Mn, 2x3)
04-Aug-2003 03:52:55;'
LCIMWMS #6
MRM of 4 Channels ES-
9.90 25736
498 ~78 1.29e5
Area
0 Jr~`,~,~`/,`~`,~I~~,`11',1~~//"II,~'~',~'I,,~~I
2.00
4.00
6.00
a.00
RJWgen Research, 3058 Research Drive, Stats College, PA 16801
000213
---------------------------------------~---
-----
Quantify Sample Report
,4 Study No.:L34910,
Set No.. *073103AR, Ext.Dats:07/31/03,
Analyst:K.Risha
Page 51
Sample List:
Last modified: Method: LJz;tCzFfiad:
:
P:\Data\LCMSMS6\Hasslynx\Fluorochamicals.P~O\S~lsDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\FluorochemicalaB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: -____-----------------
Wed Aug 06 11:04:02
2003 -______-___-----_-------------------
Name: 073103AR-126 Text :
1: C8 Acid (PFOAI
XCO72503-4,250 rig/L Standard
073103AFb126 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 04:14:42
LC/MS/MS #6
MRM of 4 Channels ES-
9.13
413 > 369
7.35e5
Area
Q ,,,,,~,.,.,,,,,,,,,,,,,,,.,,,,,,,,,,,,,,,,,
,
, . , , , , Time
2.00
4.00
6.00
8.00
10.00
12.00
: C6 Sulfonate
KO72503-4,250
(PFHS)
rig/L Standard
04-Aug-2003 04:14:44
173103AFb126 10
Sm (Mn, 2x3)
8.96 21551
3: C8 Sulfonate
XCO72503-4,250
(PFOS)
rig/L Standard
073103AR-126
loo7 i
% i
Sm (Mn, 2x3)
2.00
4.00
9.27 1328s
Time 12.00 _
04-Aug-2003 04:14:42 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 7.65e4 Area
Time
8.00
10.00
12.00 ,
-en
Research, 3058 Research Drive, State College, PA 16601
00021.4
Quantify Sample Report
w
Study No.rL34910,
Set No.: 073103AR,
Ext.Dats:07/31/03,
Analyst:K.Risha
Page 52
Sqle
List:
Last nmdifiad:
Method:
Last modified:
Job Code:
P:\Data\~SMS6\~sslynx\Fluoroch~ca~S.PRO\SampleDB\073103A
Tue Aug OS 06:59:53
2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicalsc&tur
Sun Aug 03 07:11:59
2003
Decatur
BC
BC 080103
Printed: ----__-----
wed Aug 06 11:04:02
v-s----
Name: 073103AR-126
Text :
2003 ---__--__-----------___l____________l___-
: PFOSA
(CO72503-4,250
rig/L Standard
)73103AR-126
10 7
%14
Sm (MI-I, 2x3)
04-Aug-2003 04:-l 4:4ii
LCJMSIMS #6
MRM of 4 Channels ES-
9.92
498>7a
4919f
2.56e5
Area
Time
Exygen Resaarch,
3058 Research Drive, State College, PA 16801
000215
--A----------s-------s----
Quantify Sample Report
w
Study No.:L34910,
Set No. :073103AR, Ext.Date:07/31/03,
----
Analyst:K.Risha
---
Page 53
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003
P:\Data\LQ3~S6\Masslynx\Fluorochsmicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: -----B----P
Wed Aug 06 11:04:02 ---m----_-p
2003 ------------_-
vm--------
Naxm: 073103AR-127 Text :
1 . C8 Acid (PFOA)
a491 O-1 6, DF=lOO
173103AFb127 100-
Sm (Mn, 2x3)
%
9.13 82515
04-Aug-2003 04:36:3C LC/MS/MS #6
MRM of 4 Channels ES-
413>369 4.73e5 Area
O-,,,~,,,,,,,.,,,.,,.,.,,,,,,,,,,..,,.,,,,~.,,~,,..,,,.:..,Time
2.00
4.00
6.00
8.00
10.00
12.00
c !: C6 Sulfonate
(PFHS)
073103AFb127 Sm (Mn, 2x3)
MRM of 4 Channels ES-
-
3: C8 Sulfonate
(PFOS)
L3491 O-l 6, DF=l 00
073103AFb127 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 04:36:30 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 9.90e4 Area
Bxygen Research. 3050 Research Drive, State College, PA 16601
000216
QuaId.fy Sample Report
W
Stucly No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Page 54
SaroQle List: Last modified: Method: Last modified: Job Code:
P:\Data\L~:SMS6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\L~SMS6\Masslynx\Bluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: -------------
Wed Aug 06 11:04:02 2003 ------------------e-e--
----------------
Name: 073103AR-127 Text :
4: PFOSA
IL3491 O-1 6, DF=lOO
073103AR-127 Sm (Mn, 2x3)
04-Aug-2-003 04:36:3( LWvlS/MS #t
MRM of 4 Channels ES498 5 7E 3.52& Ares
Time 12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000217
Quantify
Sample Report
t,& Study No.:L34910,
Set No.: 073103AR, Ext.Dats:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug OS 06:59:53 2003 P:\Data\LCMSMS6\~ssl~\FluorochemicalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 55
Decatur BC BC 080103
Name: 073103AR-120 Text :
: C8 Acid (PFOA)
-3491 O-l 6 Rep, DF=lOO
)73103AR-128 10
Sm (Mn, 2x3)
"j
04-Aug-2003 04:58:16
LC/MS/MS #6
9.13 836%
MRM of 4 Channels ES413>369 4.68e5
Area
Time
2.00
4.00
6.00
8.00
10.00
12100
b# 2: C6 Sulfonate
(PFHS)
L3491 O-16 Rep, DF=l 00
073103AR-128 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 04:58:1 d
LC/MS/MS #6
MRM of 4 Channels ES-
8.96-
6261
399 > 80 3.59e4
Area
0 ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,~,~_,~,,,,,~~,ITime
2.00
4.00
6.00
3: Ca Sulfonate
(PFOS)
L3491 O-16 Rep, DF=lOO
073103AR-128 10
4
Sm (Mn, 2x3)
8.00 /
9.27
17264
10.00
12.00 .
04-Aug--2003 04:58:1 d LC/MS/MS #6
MRM of 4 Channels ES499 > 99 9.56e4 Area
W L
wgen Research, 3058 Research Drive, State College, PA 16801
-,-
.-III"_"x.-,
I-
ll.".l,",",
--
_.
.--.-"
-.-.
^--
-
000228
Quantify Sample Report
cy Study No.:L34910,
Set No.: 073103AR, &.Date:07/31/03,
Analyst:K.Risha
Page 56
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCM~S6\Masslynx\Fluoroch~c~ls.PRO\S~l~DB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\L~SMS6\Massl~\Fluorochemical\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
-----------
Wed Aug 06 11:04:02 2003
-w-m--
-----
---
-----
---w---w--___
Name: 073103AR-128 Text :
4: PFOSA
L3491 O-l 6 Rep, DF=lOO
073103AFb128 Sm (Mn, 2x3)
04-Aug-2003 04:58:1 t LC/MS/MS #c
MRM of 4 Channels ES498 > 7.5 3.19e4 Area
Time
2.00
4.00
6.00
8.00
10.00
12.00
%d
Exygen Research, 3058 Research Drive, State College, PA 16801
- -" ..-..-
-.- -._
000219
Quantify
Sample Report
td Study No.:L34910,
Set No.: 073103AX, Xxt.Date:07/31/03,
Aualyst:K.Risha
Page 57
San&e List: Last modified: Method: Last xmdified: Job Code:
P:\Data\LQISblS6\Maaslynx\Fluorochemicals.PXO\S~leDB\O73lO3~
Tue Aug 05 06:59:53 2003 P:\Data\LCM[SMS6\Masslynx\Fluorochemical\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: --es-
Wed Aug 06 11:04:02 2003 -------------_-----------------------~-----------
----s---e-
Name: 073103AX-129 Text:
: C8 Acid (PFOA)
-3491 O-l 9; DF=l 00
173103AFb129 Sm (Mn, 2x3) 10
% 1
Ol"..,".`,`.`.,`~`~,~ 2.00
9.13 75424
~`J,~`~`,`((
4.00
6.00
1,s I'#,# 1,s 8.00
04-Aug-2003 05:20:01 LChlS/MS #6
MRM of 4 Channels ES413>369 4.39e5 Area
, I ,, 10.00
, I Time 12.00
W 2: C6 Sulfonate
(PFHS)
IL3491 O-l 9, DF=lOO
I073103AR-129 10
Sm (Mn, 2x3)
04-Aug-2003 05:20:01
LCIMSIMS #6
MRM of 4 Channels ES-
8.96
399 > 80
6156
3.49e4
Area
3: C8 Sulfonate
(PFOS)
L3491 O-l 9, DF=lOO
073103AR-129 lOtI-
Sm (Mn, 2x3)
%-
Time
12.00
04-Aug-2003 05:20:01 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 9.96e4 Area
0 ,,,/,,,,,/~1,,,,,/,,/III,1111(~111,111I,~I
I . , 1 I I , Q I I 1 1 Time
W-
2.00
4.00
6.00
8.00
10.00
12.00
NWgen Research, 3058 Research Drive, State College, PA 16801
000220
Quantify
Sample
Report
Study No.: L34910, Set No.: 073103AR, Ext.Date:07/31/03,
+4
Analyst:K.Rieha
S7mple List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluorochsmicals.P~\S~leDB\O73lO3~ Twe Aug 05 06:59:53 2003 P:\Data\LCMSMSb\Masslynx\Fluorocheuaicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Page 58
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
-----
--------------v-------
--m----d--
------
-----
Name: 073103x+129 Text:
4: PFOSA
L3491 O-l 9, DF=l 00
073103AR-129 Sm (Mn, 2x3)
04-Aug-2003 05:20:0' LC/MS/MS #E
MRM of 4 Channels ES498 > 7E 3.33eL Are:
Time 12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000221
Quantify Sazqple Report
'4
Study No. : L34910, Set No.:073103AR,
Ext.Dats:07/31/03,
Analyst:X.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\bfasslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003
P:\Data\L~SMS6\Masslynx\Bluorochamical\Met~B\D~catur
.Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 59
Decatur BC
BC 080103
Name: 073103AR-130
Text :
1: C8 Acid (PFOA) 1-3491 O-l 7, DF=lOO
173103AFb130 100
Sm (Mn, 2x3)
9.13 78536 i
04-Aug-2003 OS:41 :44 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 4.61 e5 Area
). C6 Sulfonate (PFHS) i3491 O-l 7, DF=l 00
373103AB130 `O@l
Sm (Mn, 2x3)
I
8.98 6030`
Time 12.00
04-Aug-2003 05:41:4 LCNWMS #
MRM of 4 Channels ES399 > 80 3.55e4 Area
:
3: C8 Sulfonate (PFOS) L3491 O-l 7, DF=lOO
073103AR-130 Sm (Mn, 2x3)
9.25 16123
04-Aug-2003 05:41:49 IX/MS/MS #6
MRM of 4 Channels ES499 > 99 9.43e4 Area
b
Time
Exygen Research, 3058 Research Drive, State College, PA 16801
000222
Quantify Sample Report `d' Study No.: L34910, Sat No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Riaha
Sample List:
Last modified: Method: Laat modified: Job Code:
P:\Data\LWSMS6\biaaslynx\Fluoroch~ca~s.PRO\S~leDB\O73lO3~ Tue hug 05 06:59:53 2003 P:\Data\LC1MSMS6\~sslynx\FluorochemicalB\Decatur
Sun hug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 60
Decatur BC EC 080103
Name: 073103AR-130 Text :
4: PFOSA L3491 O-17, DF=lOO
073103AR-130 Sm (Mn, 2x3)
04-Aug-2003 05:41:49 LC/MS/MS #6
MRM of 4 Channels ES490 B 78 3.01 e4 Area
Time 12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
0002'23
-----_-e-------------m
--------
m------
Quantify
s-10
Report
'J
Study No .:L34910, Set No .:073103AR,
Ext.Date:07/31/03,
Analyst:K.Risha
SamQle List: Last modified: blethod: Last modified: Job Code:
P:\Data\LCM~S6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73~03~ Tue Aug 05 06:59:53 2003 P:\Data\LQ3SMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 61
Decatur EC BC 080103
Printed: ---------------------
Wed Aug
Name: 073103AR-131 Text :
06 11:04:02 2003 -----__~--__----~------~-~~~
P---Y-
1: C8 Acid (PFOA)
XCO72503-5,500 rig/L Standard
073103AFb131 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 06:03:36
LC/MS/MS #6
MRM of 4 Channels ES-
9.15
413>369
1.53e6
Area
*J 2: C6 Sulfonate
(PFHS)
XCO72503-5,500 rig/L Standard
073103AFb131 10
Sm (Mn, 2x3)
%
8.96 45496-
04-Aug-2003 06:03:36 LCh/lSh/lS #6
MRM of 4 Channels ES399 > 80 2.61 e5 Area
I--
~~I~~~' 1~>~~1 I? raI, rx!I' *X,1 `rma I>ss k~~`.~~..l!~~~l
Time
-
2.00
4.00
6.00
8.00
10.00
12.00 _
3: C8 Sulfonate
XCO72503-5,500
(PFOS)
ng./L Standard
073103AFb131 10
Sm (Mn, 2x3)
9.27 28469
04-Aug-2003 06:03:36 LCYMSIMS #6
MRM of 4 Channels ES499 > 99 1.62e5 Area
j , I I I , 1 I I q 1Time
10.00
12.00 _
Exygen Research, 3058 Research Drive, State College, PA 16801
000224
-v-----_-
B-e-
--
Quantify Sample Report
Study No.:L34910,
Set No.: 073103hR,
Ext,Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Maaalynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\MSMSMS6\Masslynx\FluorochsmfcalPB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 62
Decatur BC BC 080103
Name: 073103A.R-131 Text :
4: PFOSA
XCO72503-5,500
rig/L Standard
073103AR-131 IOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 06:03:36
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
1 0229z7
5.22e5
Area
o-,,,,,,,,.,,.,,,,,,.,~,,,,.,.,,,,,.,,,,,,,,,~,.,.
I , , I , , , 1 Time
2.00
4.00
6.00
8.00
10.00
12.00
W!Jen Research,
3058 Research Drive, State College, PA 16801
000225
Quatify
Sample Report
w Study No.:L34910,
set NO.. .073103AR, Ext.Date:07/31/03,
Analyat:K.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCblSMS6\Wassl~\Fluorochgmicals.PRO\S~leDB\O73lO3~ !tUe Aug 05 06:59:53 2003 P:\Data\LCMSMS6\~asslynx\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 63
Decatur 8C BC 080103
Name: 073103AR-132 Text:
1: C8 Acid (PFOA)
L3491 O-l 6, DF =20
073103AW132 lOO-
Sm (Mn, 2x3)
%-
9.13 _ 380900
04-Aug-2003 06:25:24 LCNWMS #6
MRM of 4 Channels ES413 > 369 2.20e6 Area
0 ,,,~~~~~,,,,,,,~,,,,,,,,r,~,,,,,,,,,.,,,,
III
2.00
4.00
6.00
8.00
10.00
12.00
: C6 Sulfonate
(PFHS)
8.96 33004 I
04-Aug-2003 06:25:24 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.86e5 Area
L
2.00
3: C8 Sulfonate
(PFOS)
L3491 O-1 6, DF=20
073103AR-132 lOO-
Sm (Mn, 2x3)
%-
I 8.00
10.00
Time
-
12.00 _
9.26 _ 81862
04-Aug-2003 06:25:24 LCNSIMS #6
MRM of 4 Channels ES499 a 99 4.68eS Area
0 ~~J~,~",,`~)`,`~~~1'~"I""I""I""l""I
,
I , I I , I l Time
w
2.00
4.00
6.00
8.00
10.00
12.00 ,
qgen Research, 3058 Research Drive, State College, PA 16801
000226
-----
-------
--
-------_
Quantify Saraple Report
u
Study No.:L34910,
Set No.: 073103&R, Ext.Date:07/31/03,
Analyst:X.Risha
Page 64
S~19 List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCPISbiS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ me hug 05 06:59:53 2003 P:\Data\L~SMS6\blasslynx\Pluorocheunicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
wed Aug 06 11:04:02 2003
-----------
--I_---------------
----------e-----F-_
--
Name: 073103AFl-132 Text :
4: PFOSA
IL3491 O-l 6, DF=20
073103AFb132 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 06:25:24
LC/MS/MS #f
MRM of 4 Channels ES-
9.89
498 > 7t
1.64e!
Are2
Oxygen Research, 3058 Research Drive, State College, PA 16801
Quantify Sample Report
u
Study No.:L34910,
Set No.: 073103AR, Ext.Dats:07/31/03,
knalyat:K.Risha
Sample Liat: Last modified: Method: Last modified: Job Code:
P:\Data\L~flulS6\Massl~\Fluoroch~cals.PRO\S~leDB\O73lO3~
Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:03 2003
Page 65
Decatur
BC
BC 080103
Name: 0?3103AR-133 Text:
: C8 Acid (PFOA)
-3491 O-16 Rep, DF=20
)73103AR-133 Sm (MIT. 2x31
9.12
391789
04-Aug-2003 06:47:22/ LC/MS/MS #6
MRM of 4 Channels ES413>369 2.26e6 Area
\a& 2: C6 Sulfonate
(PFHS)
L3491 O-l 6 Rep, DF=20
073103AW133 Sm (Mn, 2x3)
%-
2.00
3: C8 Sulfonate
(PFOS)
L3491 O-l 6 Rep, DF=20
0?3103AR-133 Sm (Mn. 2x3)
, , , , , I , , , I , , Time
6.00
8.00
10.00
12.00
04-Aug-2003 06:47:22
LC/MS/MS #6
MRM of 4 Channels ES-
8.97
399 > 80
1.81e5
Area
I I , I I I , I 1 I I 1 Time
10.00
12.00
9.25 84263
I
04-Aug-2003 06:47:22 LWMSNS #6
MRM of 4 Channels ES499 > 99 4.80e5 Area
2.00
4.00
6.00
8.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
a-
---------p-
-----
---
Quantify Sample Report
14 Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Page 66
Saqple List:
Last modified: Method:
Last modified: Job Code:
P:\Data\~SMS6\Masslynx\Fluoroch~cals.PRO\S~~eDa\O73103~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur EC BC 060103
Printed: -----------------c--
wed Aug 06 11:04:02 2003 -------------_------
--------m----e_-
Name: 073103AR-133 Text :
I4: PFOSA
L3491 O-16 Rep, DF=20
073103AFb133 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 06:47:22
LC/MS/MS #6
MRM of 4 Channels ES-
9.91 _
31916
496 > 78 t .61e5
Area
0 /Il~,llll/llrl,llll/~ll,,,~/~,lll,,lll,,llll/lll
, , , , , , , 1 Time
2.00
4.00
6.00
a.00
10.00
12.00
W
Oxygen Research, 3056 Research Drive, State College, PA 16801
000229
------c-----_I----II____
--
----
-----
Quantify Sample Report
w Study No.:L34910,
Set No.: 073103JUI, Ext.Date:07/31/03,
AnalystrK.Rieha
Page 67
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PR0\SampleDB\073103A Tue Aug 05 06:59:53 2003 P:\Data\M3MSMS6\Hasslynx\Fluorochamicals\Decetur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Wed Aug 06 11:04:02 2003
-------_--------------__l________________l
Name: 073103xm-134 Text :
-------w-e-
I: CfI Acid (PFOA)
L3491 O-1 9, DF=20
073103AR-134 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 07:09:05 LCIMSIMS #6
MRM of 4 Channels ES413 > 369 2.02e6 Area
0 ,,,,~,,~,,~,,,,,,,,,,,,,,,,,I,~,,,,,,~,
, , , , , , , , , , Time
2.00
4.00
6.00
8.00
10.00
12.00
: C6 Sulfonate
(PFHS)
-3491 O-1 9, DF=20
)73103AR-134 10
Sm (Mn, 2x3)
8.96 2921 E3
04-Aug-2003 07:09:05 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.65e5 Area
2.00
3: C8 Sulfonate
(PFOS)
L3491 O-l 9, DF=20
073103AFb134 loo-
Sm (Mn, 2x3)
%-
I 8.00
10.00
Time
-
12.00
04-Aug-2003 07:09:05 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 4.64e5 Area
0 ,`,,"`,,`,",""i',","","`l,"","",
I I , I r I , r I I I 1 Time
w _
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
..---
--.
--- .- -
000230
Quantify Sample Report
cw Study No.:L34910,
Set No.: 073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\L~SMS6\Hasslynx\Fluorochamical\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 68
Decatur BC BC 080103
Name: 073103AR-134 Text :
4: PFOSA
L3491 O-1 9, DF=ZO
073103AR-134 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 07:09:0
LChrWMS #$
MRM of 4 Channels ES-
9.90 _ 32869
498 > 78 1.88e5
Area
0 ""I"","","","","","","",,"`,"'
I I I 8 I I Time
2.00
4.00
8.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
^.I
-t.i,.l.".-lll
----.
000231
Quantify Samgle Report
Study No.: L34910, Set No .:073103A.R,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L(1MSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003
P:\Data\LCMSMS6\Masslynx\FluorochemicalsB\Decatur Sun Aug 03 07:11:59 2003
Printed:
wed Aug 06 11:04:02 2003
Page 69
Decatur BC BC 080103
Name: 073103AR-135 Text:
.: C8 Acid (PFOA) -3491 O-1 7, DF=20
173103AR-135 Sm (Mn, 2x3)
I.
9.11 I3_ 362892
04-Aug-2003 07:30:42 LC/MS/MS #6
MRM of 4 Channels ES413 2.>083e669
Area
1
2.00
Vd .?: C6 Sulfonate (PFHS)
L3491 O-l 7, DF=20
073103AR135 lOO-
Sm (Mn, 2x3)
8.00 8.96
10.00
Time 12.00 _
04-Augi2003 07:30:4
%-
0 /lll,lll~,/I~/,III.,llll,llll,l,ll,II,l,lll
, , , , , , , , , , , , ,Time
2.00
4.00
6.00
8.00
10.00
12.00 -
3: C8 Sulfonate (PFOS) L3491 O-17, DF=20
073103AFG135 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 07:30:42
LC/MS/MS #6
MRM of 4 Channels ES-
9.25
499 > 99
4.44e5
Area
0 "",",`,"","`1,"","",1"`,~"`,"
, , , , , , , , , ,,Time
2.00
4.00
6.00
8.00
10.00
12.00
VW
Exygen Research, 3058 Research Drive, State College, PA 16801
000232
Quantify
Sample Report
tws~ Study No.:L34910,
Set No.: 073103AR,
Ext.Date:07/31/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LM~S6\Maaalynx\Fluorochemiea~s.PRO\S~leDB\O73103~ Tue Aug 05 06:59:53 2003 P:\Data\LCHSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\~catur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Pag's 70
Decatur BC BC 060103
Name : 073103AR-135 Text :
4: PFOSA
L3491 O-1 7, DF=20
073103AR-135 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 07330342
LCYMSIMS #6
MRM of 4 Channels ES-
9.91
498 > 78
1.33e5
Area
0 "","","",""i"","","","","","
, I I 1 ITime
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
000233
---
------e-v-----
--e--m
------
-mm----
Quantify Sample Report
I& Study No.:L34910,
Set No.. -073103AR, Ext.Date:07/31/03,
Analyst:K.Risha
Page 71
Sany7le List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\O73103~
Tue Aug 05 06:59:53 2003 P:\Data\L~SMS6\Massl~\FluorochamicaB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: --------------__m__
Wed Aug 06 11:04:02 2003 ---------_--------I_-__-_
---- --w-e--
Name : 073103AR-136 Text :
: C8 Acid (PFOA)
(CO72503-6,lOOO rig/L Standard
173103AFb136 10
Sm (Mn, 2x3)
%
9.12 477931
04-Aug-2003 07:52:21 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 2.78e6 Area
i
!: C6 Sulfonate
(PFHS)
KC072503-6,lOOO rig/L Standard
073103AR-136 10
Sm (Mn, 2x3)
L
a.96 80818
Time 12.00
04-Aug-2003 07:52:21 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 4.81e5 Area
I 0
"",,`,`,,.,..",`,.,,,,`.,.,,.,,,,,..,,'.i
2.00
'
4.00
6.00
hm
8.00
10.00
Time 1 12.00 ]
3: C8 Sulfonate
(PFOS)
XCO72503-6,lOOO rig/L Standard
04-Aug-2003 07:52:21 LC/MS/MS #6
073103AR-136 Sm (Mn, 2x3)
MRM of 4 Channels ES-
100-J
499 > 99
3.02e5
Area
%-
0 ~"`,`~`~,~"`,~~"/`~~`i~~~`l~`~~I~~~~I~~"I
, , , , I , , , I mlTime
2.00
4.00
6.00
8.00
10.00
12.00
W'
Oxygen Research, 3058 Research Drive, State College, PA 16801
000234
Quantify Sample Report
q,d Study No.:L34910,
Set No.: 073103bR, Ext.Date:07/31/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluoroch~cals.PRO\S~leDB\O73lO3~ Tue Aug 05 06:59:53 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicalscatur Sun Aug 03 07:11:59 2003
Printed:
Wed Aug 06 11:04:02 2003
Page 72
Decatur BC BC 080103
Name : 073103AR-136 Text :
4: PFOSA
XCO72503-6,lOOO
rig/L Standard
073103AR-136 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 07:52:21
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 _ 190680
498 > 78 9.76e5
Area
0 ~~~~,~~~/,"~~,I,~~,~~I~,,~~),`~~1,,/(~,'~~I,~~~
Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
00023s
SQOnlor Study No: Exygcn Sludy No: AnalytC lous Monitotd: Sk
NA l34910 PFOS 499~>99 Decaw Baker's Cnek
RAW DATA REPORT
Limit of Quai-ltiladoo: bjecdoa Volum: MUSiX Sample Volume: Fd Vohm:
JO PP' 15rr. Water 40.0 mL 5.0 mL
Set No: Analyst: lnst~ment Exfracdoa Analyrad
Typ: Dar&: w:
080603A Karen Risba LCJMS/?.iS Unit U 6 07r31/03 & 08/06K'3 08fwO3
fiYt?CO m
xc0725030
xco72503-I XCO72SO3-2
xco77503-3
xco72503-4
XCO72503-s
XCO72503-6
0106020 control
OlC6020 Spk A
01064213 Spk B
W4910-12
Spk E
W910-16
Spk F
L34910-16
SQk F
xco72Jo3-1
XCO72503-2
xco72103-3
u4910-I
W4910.1 Rep
w4910-12
W4910-12Rcp
l34910-15
w4910.13 xCO72503-4 XCO72JO3-J
XCO71003-6
SQonsor m
BC2 SW-06 cutfall to River SW-U CkItNl lo River SW-l.5
BQ SW-04 BQ SW-04 BCZ SW-06 BCZ SW-W BC2 SW-06 Dup BQ SW-06 Low Spk
Sample cc&
cs c-9 cs cs cs cs cs C La LC.S LF LF LF cs cs cs S S S S S FF cs cs cs
Analytc Rmvery
Found (ppb (%I =
= (peak
ama - intercept) / alopc x DF
InnalYU
found (pp0-iloalyu
found in cootml
anmum added (pit)
RUlI NO. 080603A-1001 080603A-3002 080603A-1003 080603A-1004 080603A-1005 080603A-1006 080603A-lW7 080603A-lW8 080603A-IM)9 080603A-1010 080W3A.1011 080603A.1012 080603A.1013 080603A.1014 080603A-1015 080603A-1016 080603A-1017 080603A-1018 OEO&l3A-1019 080603A.1020 080603A.1021 080603A-1022 080603A.1023 080603A-1024 OE4l603A-1025
(QQt)] x ml
Std.
cont.
Dilution
(QQl)
Factm
0
25
50
100
250 loo
ILXSI
I
1
1
100
2w
1W 2s
SO
loo
100
100
IW
1W
IW loo
2SO 500
IMJO
Peak AKn
0 1238 2170 6155 105Jl 22336 43039
0 2436 21693 22031 18543 35655 1229 2338 4928 5143 523s 11612 11877 11205 14257 10803 23323 4427 I
Analytc Fouad (QPt)
AilXHlnt Added (PQt)
Recovery (5)
ND
51.3
SO
103
490
SW
98
49800
mw
9s
l
5oow
80900
mwo
99
lI5W
IlSca
26100
26700
25100
32100
100
Sllndard h&`CCQ~ SOQC
Cal. Of Dct.
: Linear (I/x = 184.312 = 43.8624 = 0.998804
weighted)
CS = Calibration
frpndard
C = Cma0i umplc
s = Sample
CK = Clvck Standard
ND = No( dctexcd NQ = Nor quamifinble
I Rcsponv betw~n 0 md 2S ppr = Reapawe between 25 ppr nod LOQ (SO ppt)
l !hmple
+Samplc
WY analyzed with sevwal dilution factors. The lppopriatc
ruiduc signifcmtly
cxcccda the spiking level; tbcrefore,
result is reported. an accurate recovery
cancat be calculated
SprePdtbctt
pnpmd
by:
000236
n I" EAKCH
3058 Research Drive State College, PA 16801
Internal Chain of Custody/Fortification
Exygen Study Number: Sponsor StudyProtocol No: The samples listed below were removed from refrigerator No, Tie 1030
Sheet
Matrixr
Phone: 814-272-1039 Fax: 814-231-1580
Water
t
All samples were measured: Time !Z`kJ
Date bB)cd!b3
After measuring samples were returned to refrigerator No. .a
Time \XS
Date ~%!&!a3
Initials
COKImenkX
200 pL of 250 mghL sodium thiosulfak was added to all aamplo bcfcm spiking. lni~i~ls/Da~:
Analysis Summary:
Data Set: m
Data Set:
-
Data Set:
-
Set extraction/analysis data verified by:
n-E.4 R C H
3058 Research Drive State College, PA 16801
Phone: 814-272-1039 Fax: 814-231-1580
EXYGEN
STUDY
SAMPLE EXTIUCTION
NUh%BER: L3491 Q MATRIX: J&&g
AND ANALYSIS TRACKING SHEET
METHOD: I' ANALYTES: PFHS. PFOS. PFOA and PFOSA
PROTOCOL NUMBER: NA
STEP Dilutions
STEP
3
WJW
4
\
/
e
i
ReagentsI Materials hfnbaaol Ct8 SPE Type I Wnta
Lot #
IIizmE
uJ31 I2l31
NA
I
I - I InitiaMDatr
I
I
1
-I-I-I
I - I
I
I
I
I
I
t,
I-
kziiim- HPt
Mcdlanol Ammonium Acetate
v3(asc1
TypeIwater
NA
InitialsDate
STEP 1: SPE column cltzm-up (omitting 40% wash) STEP 2: Final volume to 5 mL collected in 15 mL polypropolene tubes
OhF: Km 2&a. ca)403
%
STEP 3: LCYAWMS analysis
STEP 4: Lcxwhfs reaualysia.
00 *Initials and date under each step indicates the personnel that perfotmed this step.
$$ Method of Anafysis for the ~~~ina~on of Perfluorooctane sulfanate (PFOS), Pctfluomoctane sulfonylamide (PFOSA). and Perfluorocctanoate (POAA) in Water
COhMENTS:
Final extracts stored in refrigerator 32 Initials: j&Date:
@!-j&v! 03
July 19.2001/4
Masslynx - Sample List
Sample List: Printed: Wed Aug 06 13:15:20 2003
Exygen STUDY NO. C3ct"llO
__--
-.-
Vial File Name
LlMS ID Client ID Sample Description
Matrix Sample Type Cone (ng&@%!f?!?nc
1
41 080603A-1001 --
--
XCO72503-0,O nglL Standard
Standard
0
-.
2
42 080603A-1002 ---
-.
XCO72503- 1,25 rig/L Standard
-.
Standard
25
-.
3
43 080603A-1003
---
-.
XCO?2503-2.50 nglL Standard
. . .
Standard
50
-.
4
44 080603A-1004 --
-..
XCO72503-3. 100 rig/L Standard
---
Standard
100
-
5
45 080603A-1005
---
-.
XCO72503-4. 250 rig/L Standard
---
Standard
250
-
6
46 080603A-1006 ---
--
XCO72503-5.500 t-q/L Standard
--
Standard
500
--
7
47 080603A-1007 ---
XCO72503-6. 1000 rig/L Standard
--
Standard
1000
-.
8
51 080603A-3008 --
01 06020 Control
-.
Blank
--
-.
9
52 080603A-1009 --
0106020 Spk A, 50 rig/L
.. .
QC
100
-.
10 53 080603A-1010 ---
-.
0106020 Spk B, 500 iq/L
-.
500
-.
11 54 080603A-1011 --
-
L34910-12 Spk E. 25000 rig/L. DF=IOO --
::
25000
-.
55 080603A-1012 -
-.
L34910-16 Spk F, 50000 rig/L. DF=200 --
50000
-.
:i
56 080603A-1013 --
L34910-16 Spk F, 50000 rig/L. DF=lOO ---
::
50000
-.
42 080603A-1014 --
-
XCO72503-1.25 rig/L Standard
. . .
Standard
25
--.
:`:
43 080603A-1015 -
-
XCO72503-2.50 rig/L Standard
-.
Standard
50
-
16 44 080603A-1016 --
-
XCO72503-3. 100 rig/L Standard
--
Standard
100
-.
$7 57 080603A-1017 --
--
L34910-1. DF=lOO
-.
Analyte
-.
-.
58 080603A-1018 --
-.
L34910-1 Rep, DF=lOO
-
Analyte
-.
--.
:t
59 080603A-1019 --
-
L34910-12, DF=lOO
-.
Analyte
-
--.
20 60 080603A-1020 --
L34910-12 Rep, DF=lOO
-.
Analyte
-.
-.
21 61 080603A-1021 --
-
L34910-15, DF=lOO
. ..
Analyte
-.
-.
22 62 080603A-1022 --
-.
L3491@13, DF=lOO
-
QC
100
-.
23 45 080603A-1023 --
-.
XCO72503-4,250 rig/L Standard
-
Standard
250
-.
24 46 080603A-1024 --
XCO72503:5.500 rig/L Standard
--
Standard
500
-.
25 47 080603A-1025 --
.-
XCO72503-6, 1000 rig/L Standard
--
Standard
1000
. . .
Page 1 Page Position: (1, 1)
C Test ID DF
-
0
-
-
x
-
0
.-
0
.
. .
-
t:
. . .
0
-
0
. . .
0
.-
0
.-
-
x
. ..
0
-
.I
:
-.
0
-
0
.-
0
.-
0
.-
0
.-
0
.-
0
.-
0
.-
0
1 1 1
: 1 1 1 1
:oo 200 100 1
: 100 100 100 100 100 100 1 1 1
Masslynx - Sample List
Sample List: C:\MASSLYNX\Fluoroche Printed: Wed Aug 06 13:15:20 2003
.PRO\SampleOB\080603A
Decatur BC.SPL
MS Method
HPLC Method MS Tune File Inj.Volume
1 C6 C8 SULF C8 ACID PFOSA 2 C6 C8 SULF C8 ACID PFOSA 3 C6 C8 SULF C8 ACID PFOSA 4 C6 C8 SULF C8 ACID PFOSA 5 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
; C6 CB SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
ii C6 C8 SULF C8 ACID PFOSA 10 C6 C8 SULF C8 ACID PFOSA
11 C6 C8 SULF C8 ACID PFOSA 12 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
:: C6 C8 SULF C8 ACID PFOSA
15 C6 C8 SULF C8 ACID PFOSA 16 C6 C8 SULF CB ACID PFOSA
17 C6 C8 SULF C8 ACID PFOSA
ia C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C-8 ACID PFOSA
;i C6 C8 SULF C8 ACID PFOSA
21 C6 C8 SULF CB ACID PFOSA 22 C6 C8 SULF C8 ACID PFOSA 23 C6 C8 SULF C8 ACID PFOSA 24 C6 C8 SULF C8 ACID PFOSA
25 C6 C8 SULF C8 ACID PFOSA
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water
Fluorochems 15
Fluorochems
Fluorochems :z Fluorochems 15
Fluorochems 15
Fluorochems Fluomchems iz
Fluorochems Fluorochems :2
Fluorochems 15
Fluorochems 15
Fluorochems 15 Fluorochems Fluorochems 1;
Fluorochems 15 Fluorochems 15
Fluorochems 15 F lwrochems 15 Fluorochems Fluorochems :z
Fluorochems 15
Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15
~xYtiX)n STUDY NO. m'+? 10
Page 2 Page Position: (2. I)
, .
LC/MS/MS SYSTEM AND OPERATING CONDITIONS
Sponsor Protocol No: NA
Exxen Studs No: L34910
Instrument:
Micromass Quattro Ultima (LUMSIMS Unit #6)
Computer:
COMPAQ Professional Workstation Al'200
Software:
Microsoft Windows NT: Version 4 Build 1381: Service Pack 5 Micromass Limited: MassLynx 3.4 Build 004
HPLC Equipment:
Hewlett Packard (HP) Series 1100
HPBinPump
HP Vacuum Degasser
HP Autosampler
HP Column Oven
.
HPLC Column:
Genesis C-8.5 cm x 2.1 mm id. x 4 p (Exygen ID: 74A) (JONESCHROMATOGRAFWY: Part No. FK5962E)
Mobile Phase (A) : Mobile Phase (B) :
2 mM Ammonium Acetate in Type I Water Methanol
Analyst:
Karen Risha Exygen Research 3058 Research Drive, State College, PA 16801 Phone: (814) 272-1039 FAX: (814) 231-1580
NOTE: The next 3 pages are computer generated printouts from the masslynx software program. The pages contain the instrument settings used for the analysis of this data set.
All Handwritten Peak ID's by:
I(&3 v '*
000241
.,& Scanning Method Report
Method: Last Modified:
C:\MASSLYNX\FLvOROCHEMICALS.PRO\ACQUDB\C6 Thu Jul 31 16:23:50 2003
Printed:
Wed Aug 06 13:15:53 2003
Page 1 C8 SULF C8 ACID PFOSA
Solvent Delay ( mins ) :
0.00
Analog Channel Function : 1
4 : Unused MRM of 4 Mass Pairs
( ESP- )
Inter Channel Delay ( Sets ) : Span ( Daltons ) : Start Time ( Mins ) : End Time ( Mins ) : Repeats :
Channel Parent Daughter
0.03 0.00 0.00 12.00 1 Dwell
(Sets)
Co11 Energy
1
399.00 80.00
0.20
35
2
413.00 369.00
0.20
10
3
498.00 78.00
0.20
30
4
499.00 99.00
0.20
40
(eV) Cone ( V )
50 10 .50 . 30
000242
Method Report
Method File: Last Modified:
qur) Printed:
C:\MASSLYNX\FLUOROCHEXICALS.PRO\ACQUDB\pfbs
Wednesday,
August 06, 2003 13:15:26
Wednesday,
August 06, 2003 13:16:00
HP1100 LC Pump Initial
Conditions
Solvents
A%
90.0
B%
10.0
C%
0.0
D%
0.0
Flow (ml/min) Stop Time (mins)
Min pressure (bar) Max Pressure (bar) Oven Temperature Left lC) Oven Temperature Right(OC)
0.300 20.0
0 400
35.0 35.0
HP1100 LC Pump Gradient
Timetable
The gradient Timetable contains 8 entries which are :
Time
A%
0.00
90.0
2.00
90.0
5.00
10.0
9.00
10.0
9.50
0.0
14.00
0.0
14.50
90.0
20.00
90.0
8% 10.0 10.0 90.0 90.0 100.0 100.0 10.0 10.0
C%
D%
Flow
0.0
0.0
0.300
0.0
0.0
0.300
0.0
0.0
0.300
0.0
0.0
0.300
0.0
0.0
0.300
0.0
0.0
0.300
0.0
0.0
0.300
0.0
0.0
0.300
water
Page 1
b@i,lIG
Pressure 400 400 400 400 400
400 400
400
HP1100 LC Pump External
Event Timetable
The Timetable contains 6 entries which
Time Initial
0.00
0.05
0.10 11.90 12.00
Column Switch Off Off Off Off Off Off
Contact1
Off
On
Off Off Off Off
are :
Contact2 Off Off Off On Off
Off
'Contact3 Off Off Off Off On 'Off
Contact4 Off Off Off Off Off Off
HP1100 Autosampler
Initial
Draw Speed
Eject Speed (pl/min)
Draw Position
(mm)
Stop Time (mins)
Injection
Volume(pl)
Vial Number
Conditions
200.0
200 0.50
20.00
15.0
82
000243
hd Tuning Method Report
Method:
C:\MASSLYNX\FLUOROCHEMICALS.PRO\ACQUDB\FLUOROCHEMS
Printed:
Wed Aug 06 13:19:13 2003
Page 1
Dau 395.00
SOURCE ( ESP- )
Capillary Cone
Hexapole 1 Aperture 1 Hexapole 2 Source Block
Desolvation
Temp. Temp.
Pressures
Analyser Gas Cell
Vacuum
Set Rdbk
3.00 -2.93
20
-43
0.0
0.0
0.0
100 99
300 299
Rdbk
OFF 4 .Oe-3
Analyser
LM Res 1 HM Res 1 IEnergy 1 Entrance Collision
Exit
LM Res 2 HM Res 2 IEnergy 2 Multiplier
Gas Flows
Cone Gas Desolvation
Set Rdbk
14.0
14.0
1.0
-2
24
15
29
2
27
14.0
14.0
2.0
650 -646
R&k
132.1 770.3
000244
Quantify
Calibration
Report
\rrf
Study No. :L34910, Set No.: 080603A,
Ext.Date:07/31
br 06/06/03, Analyst:K.Risha
Page 1
Calibration: Last modified: Printed:
---------
P:\Data\LCMSMS6\MassLynx\Fluorochamicals.PRO\~~eDB\O60603A
Thu Aug 07 12:27:57 2003
Thu Aug 07 12:49:55 2003
Y-w----
--_-----___
Decatur BC --------_
Compound 1 name: C8 Sulfonate (PFOS) 2oefficient of Determination: 0.998804 >alibration curve: 43.8624 l x + 184.312 qesponse type: External Std, Area kwve type: Linear, Origin: Exclude, Weighting:
4.43e4
l/x, Axis trans: None
Response
0.0 ExMen Research,
200.0
400.0
600.0
3058 Research Drive, State College, PA 16601
800.0
1000.0
000245
Quantify Sample Report
w Study No.:L34910,
Set No .:080603A, Ext.Date:07/31
bc 08/06/03, Analyst:K.Risha
Page 1
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SllrS6\1sslynx\Fluoroch~cals.PRO\S~leDB\O8O6O3A Thu Aug 07 08:12:08 2003
P:\Data\LCMSMS6\Masolynx\Fluorochemica~s.PliO\MethDB\PFOS Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed: -__-------------
Thu Aug 07 12:49:56 -----
2003 -----------------1----
e--w---------
Name : 0806031-1001
Text:
1: C8 Sulfonate
(PFOS)
XCO72503-0,O rig/L Standard
06-Aug-2003 14:57:47 K/MS/MS #6
MRM of 4 Channels ES499 > 99 1.71e3
0 "","","",""l"","",""l"","","","",""
Time
2.00
4.00
6.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000246
Quantify Sample Report
bJ Study No.:L34910,
Set No.: 080603A, Ext.Date:07/31
k 08/06/03,
Sample List: Last modified: Method:
Last modified:
Job Code:
P:\Data\LCMSMS6\bIasslyruc\Fluoroch~cals.PRO\S~leDB\~aO6O3A Thu Aug 07 08:12:08 2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MetbDB\PFOS Thu Aug 07 08:11:08 2003
Printed:
Thu Aug 07 12:49:56 2003
Analyst:K.Risha
Page 2
Decatur Bc
o111y 080603
Name: 080603A-1002 Text :
1: (?8 Sulfonate
XCO72503-1,25
(PFOS)
rig/L Standard
080603A-1002 lOO-
Sm (Mn, 2x3)
%-
9.35 ._
06-Aug-2003 15:19:26 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 5.57e3 Area
P;K;ygen Research, 3058 Research Drive. State College, PA 16801
000247
---
---L-_--__---__--____I
-----
------P--P_-
Quantify Sample Report
uk) Study No.:L34910,
Set No.: 080603A,
Ext.Date:07/31
& 08/06/03, Analyst:K.Risha
Page 3
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LQiSMS6\Masslynx\Bluoroch~cals.PRO\S~leDB\O80603A Thu Aug 07 08:12:#8 2003 P:\Data\LCMSMS6\Masslynx\F~uorochamicals.PRO\MethDB\PFOS
Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed:
Thu Aug 07 X2:49:56 2003
--------
--------------------_______I_____I______------
I_-----
Name : 080603A-1003 Text :
.: CB Sulfonate
tCO72503-2,50
(PFOS)
rig/L Standard
06-Aug-2003 15:4l :O-/
LC/MS/MS #6
9.32 , 257( I
MRM of 4 Channels ES499 > 99 1.18e4
Area
I; Time
c
Oxygen Research, 3058 Research Drive, State College, PA 16801
000248
Quantify Sax&e Report
w
Study No.: L34910, Set No.:080603A,
Ext.Date:07/31
& 08/06/03, Analyst:K.Risha
Page 4
Sample List: Last modified: Method: Last modified: Job Cods:
P:\Data\~CMSMS6\MasslyPx\FluOroch~cals.PRO\S~leDB\O8O6O3A Thu Aug 07 08:12:08 2003 P:\Data\LCMSMS6\~ssl~\Fluorach~cals.PRO\~et~B\P~OS Thu hug 07 08:11:08 2003
Decatur BC only 080603
Printed:
Thu Aug 07 12:49:56
2003
---------------------------------------------------~
--------_
Name : 080603A-1004
Text :
L: C8 Sulfonate
KC072503-3,100
(PFOS)
q/L Standard
080603A-1004 loo-
Sm (Mn, 2x3)
%-
06-Aug-2003 16:02:51 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.99e4 Area
0 ,,,,~,,,.,.,,,,,.,..,,,,,.,,....,.,.,,.,.
, , r , I , , , , Time
2.00
4.00
6.00
8.00
10.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
0002a9
------se-
------------------
-----------
Quantify
Szuqple Report
w Study No.:L34910,
Set No.: 080603A.
Ext.Date:07/31
& 08/06/03,
--
m-------_
Analyst:K.Rieha
Page 5
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQ3SlrlS6\Masslynx\Pluaroch~cals.PRO\S~leDB\O80603A Thu Aug 07 08:12:08 2003 P:\Data\LCbISMS6\Masslyw\Fluorochemicals.PRO\~et~B\PFOS Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed:
Thu Aug 07 12:49:56 2003 ------------------------__I_________________--_-_____-
Name: 080603A-1005 Text :
L: C8 Sulfonate
KC072503-4,250
(PFOS)
rig/L Standard
080603A-1005 10
%$-I
Sm (Mn, 2x3)
06-Aug-2003 16:24:39 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 4.71 e4 Area
Time
Oxygen Research, 3058 Research Drive, State College, PA 16801
"l_ll--_l--(l.-c--
---_^
._"
._^_I
-
000250
---I_-------
-------
---I_-
-------
Quantify Sample Report
\& stuay k.:L34910,
set No.: 000603A,
Ext.Date:07/31
6 08/06/03, Analyst:X.Risha
Page 6
Saraple List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\bla8sl~\Fluoroch~cals.PRO\S~leDB\O6O6O3A Thu Aug 07 08:12:08 2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\PFOS Thu Aug 07 08:11:08 2003
Decatur EC only 080603
Printed: ------mm-
Thu Aug 07 12:49:56 2003 ----------------____
Name: 0806031-1006 Text :
--------
--we------_-------___
L: C8 Sulfonate
KC072503-5,500
(PFOS)
rig/l Standard
080603A-1006 `Oq
%-4
Sm (Mn, 2x3)
9.31
22336
06-Aug-2003 16:46:17 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 9.64e4 Area
L
Time
Exygen Research, 3058 Research Drive, State College, PA 16801
..-. .~---.----_.-.~~
-w-(_l_ll-.
-_..-
._._~..__
-----
000251
Quantify Sample Report
ll(rc, Study No.:L34910,
Set No.: 080603A,
Ext.Date:07/31
L 08/06/03, Analyst:K.Risha
Page 7
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~S6\Masslynx\Fluoroch~cals.PRO\S~leDB\O80603A
Thu Aug 07 08:12:08 2003 P:\Data\L~SMS6\Masal~\Fluoroch~calB\PFOS Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed: ----------------------
Thu Aug 07 12:49:56
2003 ------------~-----_-___-____
Name:
Text:
080603A-I.007
1: C8 Sulfonate (PFOS) XCO72503-6,1000 rig/L Standard
080603A-1007 100-
Sm (Mn. 2x31
.
I
%-
06-Aug-2003 17:08:OC
LC/MS/MS #6
MRM of 4 Channels ES-
9.33
499 > 99
1.8385
Area
I 1 r I , I I I Time 10.00
W
Bxygen Research, 3058 Research Drive, State College, PA 16801
000252
Quazfitify Sample Report
\r/ Study No.:L34910,
set NO.: 0806031,
Ext.Date:07/31
br 08/06/03, Analyst:K.Risha
Page 8
Sample List:
Last modified: Method: Last modified:
Job Code:
P:\Data\LCblSMS6\Masslynx\Fluorochsmicals.PRO\S~l~DB\O8O6O3A
Thu Aug 07 08:12:08 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\PFOS Thu Aug 07 08:11:08 2003
Decatur.BC only 080603
Printed:
Thu Aug 07 12:49:56 2003
----_--_____
-------_---_____
~-------------l____
-----_
Name: 080603A-1008 Text :
1: C8 Sulfonate
0106020 Control
(PFOS)
080603A-1008 Sm (Mn, 2x3)
06-Aug-2003 17:29:43 LWMSIMS #6
MRM of 4 Channels ES499 > 99 2.05e3
Time
ExyOen Research, 3058 Research Drive, State collsga, PA 16801
000253
---
-------__----------------------_
Quantify
Sample Report
`,M
Study No.:L34910,
Set No.: 080603A,
Ext.Date:O7/31
P 08/06/03,
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Maselynx\Fluorochemicals.PRO~S~leDB\O8O6O3A
Thu Aug 07 08:12:08
2003
P:\Data\LCMSMS6\Masel~\Fluoroch~cals.FRO\Met~B\PFOS
Thu Aug 07 08:11:08
2003
Printed:
Thu Aug 07 12:49:56
2003
Name: 0806031-1009 Text :
1: C8 Sulfonate
(PFOS)
0106020 Spk A, 50 rig/L
080603A-1009 loo-
Sm (Mn, 2x3)
%-
0 . . ..~......,,.,,,,...,....,.~.~,,~~~,..
2.00
4.00
6.00
8.00
Analyst:K.Risha only
e-P--_
Page 9
Decatur
BC
080603
06-Aug-2003 17:51:2t LC/MS/MS #E
MRM of 4 Channels ES499 > 9s 1.06e4 Area
10.00 , y, , 7 Time
WSJen Research,
3058 Research
Drive,
State College,
PA 16801
000254
m---e--
_c--_-__------I__
-------_
Quantify Sample Report
qd Study No.:L34910,
Set No.: 0806031,
Ext.Date:O7/31
& 08/06/03,
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQISMS6\~sslynx\Fluorochrsmical~.PRO\S~leDB\O8O6O3A Thu Aug 07 08:12:08 2003 P:\Data\LC!MSUS6\Masslynx\Fluorochemicals.PRO\MethDB\PFOS
Thu Aug 07 08:11:08 2003
Printed:
Thu Aug 07 12:49:56 2003
Analyst:K.Risha only
Page 10
Decatur BC 080603
Name: 080603A-1010
Text :
1: C8 Sulfonate
(PFOS)
i;0106020 Spk B, 500 rig/l.
080603A-1010 10
Sm (Mn, 2x3)
9.31 21693
06-Aug-2003 18: 13:04
IX/MS/MS #6
MRM of 4 Channels ES499 > 99 9.58e4 Area
L
Time
t
-en
Research, 3058 Research Drive, State College, PA 16801
000255
----
e--------------------------
Quantify Sample Report
yw' Study No.:L34910,
Set No.. *080603A, Eact.Date:07/31
& 08/06/03,
Samgls List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8O6O3A Thu Aug 07 08:12:08 2003 P:\Data\LCMS&S6\Masslynx\Fluorochemicals.PRO\MethDB\PFOS Thu Aug 07 08:11:08 2003
Printed:
Thu Aug 07 12:49:56 2003
~---------------_---__---l____I________
Name: 080603A-I.011 Text :
.: C8 Sulfonate
(PFOS)
-34910-12 Spk E, 25000 rig/L, DF=lOO
380603A-101
100 3
I Sm (Mn, 2x3)
%
Analyst:K.Risha only
--
Page 11
Decatur BC 080603
----_--
w---m--
06-Aug-2003 18:34:45 LC/MS/MS #6
MRM of 4 Channels ES-
499 a 99 9.36e4 Area
men
Research, 3058 Research Drive,
State College, PA 16801
0002564
-----
__---------
-----
w--v---
--------
Quantify
Sample Report
'CJ Study No.: L34910, Set No .:080603A,
Ext.Data:07/31
& 08/06/03, Analyst:X.Risha
Page 12
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\lHasslynx\Pluoroehsmicals.PRO\S~leDB\O8O6O3A Thu Aug 07 08:32:08 2003 P:\Data\LCMSMS6\Masslynx\PluorochamicalsB\PFOS
Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed: ---------------------------
Thu Aug 07 12:49:56
2003 ------___------------
---_---_-_
Name: 080603A-1012 Text :
,: C8 Sulfonate (PFOS) -3491 O-15 Spk F, 50000 rig/L, DF=200
180603A-1012 10
%1-I
Sm (Mn, 2x3)
2.00
4.00
9.32 1054: 3
06-Aug-2003 18:56:25 IX/MS/MS #6
MRM of 4 Channels ES499 > 99 7.99e4 Area
L
Time
8.00
10.00
EWgen Research, 3058 Research Drive, State College, PA 16801
000257
Quantify
Sample Report
'd'
study No.:L34910,
Set No.: 080603A,
Ea&.Date:07/31
br 08/06/03, Analyst:K.Rlsha
Page 13
Saauple List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O8O6O3A Thu Aug 07 08:12:08 2003 P:\Data\LC%SMS6\XasslyPx\Fluorochemicals.PFtO\MethDB\PEOS Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed: _L__------
Thu Aug 07 12:49:56 2003 ---------------------------
Name: 080603A-1013
Text :
----------mm
,: C8 Sulfonate
(PFOS)
-34910-16 Spk F, 50000 rig/L, DF=lOO
180603A-1013 100-
Sm (Mn, 2x3)
%-
9.29 3565! A3 -
06-Aug-2003 19:18:10 K/MS/MS #6
MRM of 4 Channels ES499 > 99 1.54e5 Area
0 ,I,,,,',,,,,,,,,,,',.,,,,,,,',"","",""~
2.00
4.00
6.00
8.00
10.00
Time J
Exyg0n Research, 3058 Research Drive, State College, PA 16801
000258
Quantify
Sarnpls Report
ld
Study No.: L34910, Set No.:O80603A,
Ext.Date:07/31
tr 08/06/03, Analyst:X.Risha
Page 14
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\MasslyPx\Fluoroch~cals.PRO\S~leDB\O~O603A Thu Aug 07 08:12:08 2003
P:\Data\LCMSNS6\BZasslymc\Fluorochedcals.PRO\UethDB\PFOS Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed:
Thu Aug 07 12:49:56 2003
Name: 080603A-1014 Text :
1: CB Sulfonate
XCO72503-1,25
(PFOS)
rig/L Standard
080603A-1014 Sm (Mn, 2x3)
1Ol-h
192.32691
06-Aug-2003 19:39:5 LCNSIMS #6
MRM of 4 Channels ES-
4995.58>e9396 Area
2.00
4.00
6.00
8.00
Eacygan Research, 3058 Research Drive, State College, PA 16801
.-. _I_-._1..-.,-- -*
",,"__.l,_l,_ .l-- .._.--..---..
000259
Quantify
Sample Report
Study No.: L34910,
Set
No .:080603A,
Ext.Date:07/31
Sample List: Last modified: Method:
Last modified: Job Code:
P:\Data\LCM~S6\~ssl~\Fluoroch~cals.PRO\S~~eDB\O80603A
Thu Aug 07 08:12:08
2003
P:\Data\LCMSMS6\Masslynx\Pluorochemica\PFOS
Thu Aug 07 08:11:08
2003
Printed:
Thu Aug 07 12:49:56
2003
I 08/06/03,
Analyst:K.Risha only
Page 15
Decatur
RC
080603
Name: 080603A-3015 Text :
1: CB Sulfonate
XCO72$03-2,50
(PFOS)
rig/L Standard
080603A-1015 100-
Sm (Mn, 2x3)
%-
06-Aug-2003 20:01:4C
LC/MS/MS #6
MRM of 4 Channels ES-
9.36
499 > 99
1.08e4
Area
6.00
8.00
Oxygen Research,
3058 Research
Drive,
State College,
PA 16801
000260
Quantify Sample Report Study No.: L34910, Set No .:080603A,
Ext.Date:07/31
& 08/06/03,
Sm4ple List:
Last modified: Method :
Last modified: Job Code:
P:\Data\LCM~S6\Masslynx\Fluoroch~cal~.PRO\S~leDB\O8O6O3A Thu Aug 07 08:12:08 2003 P:\Data\LCMSMS6\Masslynx\FluorochemicaleB\PFOS Thu Aug 07 08:11:08 2003
Printed:
Thu Aug 07 12:49:56 2003
Analyst:K.Risha only
Page 16
Decatur BC 080603
Name: 080603A-1016
Text :
.: C8 Sulfonate <CO72503-3,100
(PFOS) rig/L Standard
380603A-1016 Sm (Mn, 2x3)
06-Aug-2003 20:23:22
LCIMSIMS #6
MRM of 4 Channels ES-
9.35
499 > 99
4928
2.20e4
Area
I
Time
wgen Research, 3058 Research Drive, State College, pA 16801 ---
000261
Quantify Sample Report
w Study No.:L34910,
Set No.. *080603A, Ext.Date:07/31
& 08/06/03r Analyst:K.Risha
Page 17
Sam~la List: Last modified: Method: Last modified: Job Code:
P:\Data\LCM~S6\Kasslynx\Fluorochamica~s.~RO\S~~eDB\O~O603A
Thu Aug 07 08:12:08
2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\~etbDB\PFOS
Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed: __--I_-------____
Thu Aug 07 12:49:56 2003 -------------a---------------
Name: 0806031-1017 Text :
1: C8 Sulfonate
(PFOS)
L3491 O-l, DF=l 00
080603A-1017 loo-
Sm (Mn, 2x3)
%-
06-Aug-2003 20:45:0; LCIMSIMS #6
MRM of 4 Channels ES499 > 99 2.21 e4 Area
;I
Time
10.00
Exygsn Research, 3058 Research Drive, State College, PA 16801
000262
----
Quantify Sample Report
w
Study No.:L34910,
Set No.. *080603A,
Ext.Date:07/31
& 08/06/03, Analyst:K.Risha
Page 18
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\M3MSMS6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\O80603A Thu Aug 07 08:12:08 2003
P:\Data\LCMSMS6\Masslynx\Fluorochemical.s.PRO\M&ADB\PFOS Tbu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed:
Thu Aug 07 12:49:56 2003
Name: 080603A-1018 Text :
.: C8 Sulfonate
(PFOS)
L3491 O-l Rep, DF=l 00
380603A-1018 10
Sm (Mn, 2x3)
9.35, L 5235
06-Aug-2003 21:06:44 LCNS/MS #6
MRM of 4 Channels ES4992.41> e949
Area-
Time
2.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000263
Quantify Sample Report I,& Study No.zL3493.0, Set No.: 080603A,
Ekt.Date:07/31
bs 08/06/03, Analyst:X.X.isha
Page 19
Sarqple List: Last modified: Method:
Last modified: Job Code:
P:\Data\L(23SMS6\Masslynx\Fluoroch~cal8.PRO\S~leDB\OSO6O3A Thu Aug 07 08:12:08 2003 P:\Data\LCb%MS6\Masslynx\Fluorochemicals.PRO\MethDB\PFOS
Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed: -------------
Thu Aug 07 12:49:56 --------___I
Name: 0806031-1019 Text:
2003 -----~
v--m---
------
---_
1: C8 Sulfonate
(PFOS)
L3491 O-12, DF=lOO ..
D80603A-1019 10
Sm (Mn, 2x3)
9.31 11612
06-Aug-2003 21:28:28
LCIMSIMS #6
MRM of 4 Channels ES499 > 99 5.04e4 Area
Time
Oxygen Research, 3058 Research Drive, State College, PA 16801
000264
---------
-----
---
---P-F
----
Quantify Sample Report `d Study No.: L34910, Set No .:000603A,
Ext.Date:07/31
6L 08/06/03, Analyst:K.Risha
Page 20
Sarqle List: Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\MasslyPx\Fluorochemicala.PRO\S~leDB\O~O6O3A Thu Aug 07 08:12:08 2003 P:\Data\LCMSMS6\Maaslynx\Fluorochemica~s.PRO\MethDB\PFOS
Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed: ----~--------~_-_-__
Thu Aug 07 12:49:56 2003 ~---------__-----------___
Name: 000603A-1020 Text :
------------_
L: C8 Sulfonate
(PFOS)
L3491 O-1 2 Rep, DF=l 00
080603A-1020 10
i , %-
Sm (Mn, 2x3)
9.32 1187?
06-Aug-2003 21:50:16 E/MS/MS #6
MRM of 4 Channels ES499 > 99 5.29e4 Area
Exygen Research, 3058 Research Drive, State College, PA 16801
000265
Quantify Sample Report
,4 Study No.:L34910,
Set No.. *080603A,
Ext.Date:07/31
6r 06/06/03, Analyst:R.Risha
Page 21
Saqple List: Last modified: Method: Last modified: Job Code:
P:\Data\LQISMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O8O6O3A Thu Aug 07 08:12:08 2003 P:\Data\LCMSUS6\Uasslynx\Fluorochernica~s.PRO\MetbDB\PFOS Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed: --e--w--
Thu Aug 07 12:49:56 2003 -__-_-----____----________I_
---
-------e--e------_
Name:
Text:
080603A-1021
: C8 Sulfonate
(PFOS)
-3491 O-l 5, DF=lOO
180603A-1021 Sm (Mn, 2x3)
1
06-Aug-2003 22:12:03 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 4.84e4 Area
2.00
4.00
6.00
8.00
10.00
Time 1
Exygen Research, 3056 Research Drive, State College, PA 16801
000266
--
---I-
Quantify Sample Report
,,& Study No.:L34910,
Set No.: 080603A, Ext.Date:O7/31
-& 08/06/03,
-Analyst:K.Risha
--Page 22
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L(IMSMS6\blasslynx\Fluoroch~ca~s.PRO\S~leDB\O80603A Thu Aug 07 08:12:08 2003 P:\Data\LQbSMS6\Masslynx\Fluorochemicals.PRO\~et~B\PFOS
Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Brinted:
Thu Aug 07 12:49:56 2003
--------l--------_______________II_
---v-------e--
m---s-
Neme: 080603A-1022 Text:
1: C8 Sulfonate (PFOS) L34910-13, DF=lOO
080603A-1022 10
Sm (Mn, 2x3)
9.36
14257
06-Aug-2003 22:33:4t LC/MS/MS #E
MRM of 4 Channels ES499 > 9s 6.13e4 Area
Time
2.00
4.00
6.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000267
-----__
-------------
P--e-----
-----
Quantify Sample Report
'lu, StUaY No.:L34910,
Set NO.: 0806031,
F+xt.Date:07/31
h 00/06/03, Analyst:K.Riaha
Page a3
SaxDQla List: Last modified: Method:
Last modified: Job Code:
P:\Data\M3MSMS6\Masslynx\Fluorochamieals.PRO\S~l~DB\O6O6O3A
Thu Aug 07 08:12:08 2003 P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\MethDB\PFOS
Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed:
Thu Aug 07 12:49:56
2003
----__-----------1-___________I________
----_--I_P----_
Name: 080603A-1023
Text :
,: C8 Sulfonate
<CO72503-4,250
(PFOS)
q/L Standard
180603A-1023
10 7
% 1
Sm (Mn, 2x3)
9.34 10803
06-Aug-2003 22:55:23 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 4.85e4 Area
0 ,`,,~,`,,,,I,`,,~,,,,,,`,,,,,,,,,',',,,",,'
Time
2.00
4.00
6.00
8.00
10.00
Exypen Research, 3058 Research Drive, State College, PA 16601
000X8
Quantify Sample Report
w
Study No.:L34910,
Set No.. *0806033,
Ext.Date:07/31
& 08/06/03, Analyst:K.Risha
Page 24
Sample List:
Last modified: Method:
Last modified: Job Coda:
P:\Data\LCmaSWS6\r#assl~\Fluoroch~ca~s.PRO\S~leDB\O6O6O3A
Thu Aug 07 08:12:08 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MetbDB\PFoS Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed:
Thu Aug 07 12:49:56 2003
Name: 000603A-1024 Text :
1: Cl3 Sulfonate
XCO72503-5,500
(PFOS)
rig/L Standard'
080603A-1024 100-
Sm (Mn, 2x3)
%-
06-Aug-2003 23:17:07
K/MS/MS #6
MRM of 4 Channels ES499 > 991 9.98e4 Area
BJWgen Research, 3058 Research Drive, State College, PA 16801
000269
------
--
--
--s----e
Quantify Sample Report `14 Study NO. : L34910, Set No.:O80603A,
Ext.Date:O7/31
& 08/06/03, Analyst:K.Risha
Page 25
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals~~RO\S~leDB\O8O6O3A Thu Aug 07 08:12:08 2003 P:\Data\LCM~S6\MsslyPx\FluorochemiB\PFOS Thu Aug 07 08:11:08 2003
Decatur BC only 080603
Printed:
-_-_---------------------_____I__-----------___I------
Tbu Aug 07 12:49:56 2003
Name: 080603A-1025 Text :
1: ca Sulfonate
(PFOSI
XCO72503-6,lOOO
r
rig/L Standard
)80603A-1025 100-
Sm (Mn, 2x3)
%-
06-Aug-2003 23:38:5: LC/MS/MS #f
MRM of 4 Channels ES499 > 9s 1.91e5 Area
Exygen Research, 3058 Research Drive, State College, PA 16801
000270
SECTION E
_.--- -
Sponsor Sody No: Exygcn Study No: Anslytc: Ions Mooit& Site:
HA l.34910 PFOA 413 .>369 Lkcanrr Baker's Cnek
RAW DATA REPORT
Liil of Quaodutiw:
bljdoa v01umaz M&X Sample Wei& Fii Volume:
50 PPt lSd. Soil 5.0 g J.OmL
Set No: AdySC Inseum~n~ Extraction Aulyzcd
Type: Daw: on:
080103.4 K&ml Rirhs LCMSMS 86 om1m3 o&urn3
xCO72503-0 XCOR503.I xCm2So3.2 xCO72503-3 XCO72.503~ xCu72503-5 XCO72M3-6
SpXlSO~
m
Sample
COdC cs cs cs cs cs c-s cs
RWr
NO.
080103A-2001 080103A-2002 080103A-2CO3 OB0103A-2lXM 080103A-2005 080103A-UXM 080103A-2007
Std. COnC. (ppt)
0 25 50
loo 250 500 IWO
Dhtion Facux
Peak hrcp 333 9882 17917 34827 78794 171634 315768
.-JYW Pound (PPO
Amount Added @PC)
RCCOVCIy (5)
Adytc Found (p9b)
Mcfhanol Wash l&agent Blmk
C
080103A-2008
C
080103A.2009
525
1
518
ND
Reagent Spk A
LCS
080103A-2010
I
18939
55.3
111
Reagent Spk B
LCS
080103A.201
I
1
163063
536
107
xCO72503-I
cs
080103A-2012
2.5
9820
L34910-5 Spk C
km SED-M
LF
OSOIMA-2013
IO
157971
SIW
96
L34910-10 Spk D
EC? SED-05
LF
080103A-2014
10
166134
J4bo
96
L34910-11 Spk E
BC2 SE&M
LF
080103A.24US
10
187666
6180
W
L3491&20
Spk F
Outf-oIl to P.ivw S.eD-2s
LP
080103A-2016
LO
179090
ss90
91"
*J
xamso3-2
CT
080103A-2017
SO
18190
L34910.5
BC7 SEMU
S
080103A-2018
1
llS4JI
377
3JY2
L34910.5 Rep
BC2 SED-04
S
080103A-2019
1
82762
268
2.14
w910.IO
EC-2 sBD4s
S
080103A-20'20
1
19505s
642
5.14
I3491010
Rep
BC2 SED-OS
S
080103A-2021
1
1677826
551
4.4 I
xco72503-3 xCO72503-4
cs
080103A-2022
Im
33920
cs
080103A4.723 250
79282
w49 lo-1 1
BClSED-06
S
080103A-2U24
1
473416
L34910-11 Rep
BC2 SED-06
S
080103A.2OZ
1
463017
W49Wm
outhll to River SD-25
s
080103A-2026
1
404m
L34910-20 Rw w4910-21
OutN) lo Riva sm25 hrtfidl to Riircc SJiD4S Dup
S
080103A-2027
S
080103A-mm
I
301201
I
532619
xCfJ72503-5 x0372503-6
cs
080103A-2029
500
cs
080103A-2D30
Iwo
14ocm 273386
Andyfe Recovay
Fcund (ppt) (%) =
- (peak M _ irmccpt) I JIG+ L DF
[adym fowd (pplMnalya
foul
amount ridded
&l colltml (per)
(ppc)l x 100
Standard hlaccpt Slope
cat. Of Del.
: Liacar (l/x - 2344.75 = 300.076 - 0.988097
weighted)
Adyo Andytc
Fmmd @pb) - (mdyrc found @PC) I volum cxerkd
(0.04 L)] I wmpk weight (5 r)
Feud (pph) dry weight * malytr found @pa) x (100% I tolll solids (%j)
CS I Calibmimsm&ni C = Cootrol mmpk s I sample
LF s Lab fadfkd luaplc
FF - Fwd fortified sample
LCS = l&omcey
CMml spike
Toid SOlidS (5)
MY& Found (ppb) Dry Weight
69.96 69.96 69.54 69.54
60.41 60.41 63.27 63.27 61.43
*Sample requires dilution. See data %I 080103AR.
"Sample was corrected using the data found in se 080103AR. %I#
000272
Spaua Study No: NA
Baygcn Stxdy No:
L34910
Adyle:
PFEIS
Ionr Monimredz
399 -> 80
Site:
Dccaw Eakdr Gcck
RAW DATA REPORT
Limit of Qwldlalion:
Injcclioo Volume:
Matlil:
Samplr Weight: Fiinl v01umc:
JO PPl I5d.
Soil
5.0 g
5.0 ld.
Ss( No: A&SE inr-1 Exmcdoo Analyyml
TpJ: Da: ml:
080103A ib.mRisha LCMSMS L6 o&mu3 oumm3
`t*(
ww
spoaror
Svnpk
Run
ID
ID
Code
No.
xcu72.503-0 Xcw2JO3.I
cs
080103A-2001
c-5
080103A.2002
xcm2s03.2
c-s
080103A-2m3
xcm?503.3 xcm2Jo3.4
cs
OSOlMA-2W
cs
080103A.2tW5
xcO72503.s XCW2503.6
cs
080103A.2OC'S
cs
080103A-2007
Mclhawl Wnrh
C
080103A-2008
Reagent Blank
C
080103A-2009
ha&co1 Spk A
LCS
080103A-2010
Rcagsel Spk B
LCS
080103A.2011
X(372.503.I
cs
080103A.2012
L34910-5 Spk C
BC2 SED.04
LP
080103A-2013
t.34910.10 Spk D
0C2 SD-OS
Lp
0@3103A-2014
W4910.11 SpkE
BQ SED-06
LF
080103A-201S
L34910.20 Spk F
outfall lo River SD-25
LF
080103A-2016
XCO72N3-2
cs
080103A.2017
w4910-5
BQ SED-0.l
s
080103A.2018
L349w5
Rep
w4910.10
80 SED04 BCZ SEDJJS
S
080103A.2019
S
080103A.2fYU
l-34910.10 Rep
EC2 sRD.05
S
080103A-2021
xcQmo3-3
cs
080103A.2022
xal72503-4
c-s
080103A.2023
L34910.l
W4910-11
Rep
L34910-20
L34910-20 Rep
BC2 SE&O6 BC2 SBD-06 Oulfsll m Ri"rr SD-U outfall In RiversED-2s
S
080103A-2024
s
080103A-2025
S
060103A-2026
S
080103A-2027
W4910-21
outfill to Riva SED-2.3 Dup
s
080103A-2028
xcowo3-5 XClX?303.6
cs
080103A-2029
cs
080103A-2030
Anrlyts Rmvoly
Faud @pt) = (peak uu
(%) -
ldyte
. intmcpc) found
I slop x OF
(ppox,alyte
found in cmmol
amoonl added (ppd
(pm)] x 100
Std.
coot.
Diluliocl
(~0
Facta
0
25
SO
100
2so
3x3 loo0
I I 1 2s 10 10 10 10 50 I 1 I 1 100 254 1 I 1 1 I so0 Ica
Peak Area
0 1572 3699 6481
Imo
31281 58308
0 0 3457 3lOw 176s 30746 32192 12334 32343 3449 4534 3439 10896 129% 6560 14801 111133 Iml3 23354 16649 36172 28497 54198
-Yw Found
(PPO
Amouol Added (pm)
uewvcq (5)
&Ye FOLM (wb)
ND
52.0
104
533
107
5280
104
5530
107
5560
105
5560
103
70.8
0.5l
51.7
0.41
Ill2
1.45
218
1.75
308
2.46
321
2.61
399
3.19
282
2.26
623
4.98
D hwyll Slope
cocf. Of DCL
: Linear (l/x -476.906 - 57.3138 - 0.995587
wcighoxl)
Told SOti& (5)
69.96 69.96 69.54 69.54 60.41 60.41 63.27 63.27 67.43
rrntlYlc htiylc
l%uod (ppb) = [amlytc found fppt) I wlum exmctcd (O.o( L)j I rlmplo vcight (5 g) Found (ppb) dry weight I malytc fwnd (ppb) I (100% I total solids (%))
CS = Calihrathrfadud c = CcmVOl rdmp,o s - Sample
LF I Lb fortified lT * Field tonilied LCS L Laboratory
sampk sampk
Cmtrol Spike
CK=ChskSuodud
M) - Notdetmmi=Rcspwob*wmOaod25pppc
NQ - Not quuifipblc
- Rcrponrr
buwceo
25 ppt sod LOQ (SO ppt)
Andy& bud (ppb)
Weight
0.809 0.591 2.09 2.51 4.08 4.33 5.0s 357 7.39
. _---
--.
000273
Spama Shuiy No: Exypra SMy No: Adya: loal Mwitorcd: Site:
NA L2-4910 PFOS 499 -2.99 tkcatur Baker's Creek
RAW DATA REPORT
Limit of Qllmliuliw: lnpcdaa Vdumc: Matrix Sampls weight Fiat Volume:
SOPPf 15d. soil 5.0 g 5.0 mL
sst NQ: AdYSC ltuhumsnc !2.xlr4ctioo Analy7.ui
Type: Dus: w:
OSOIMA Kyea Birha LChGMS #6 o&QLDY 08mu3
Std.
Amlytc
Amount
Amlyle
Total
hYS=
Smpk
Rut2
COIIC. Dilutia
Peak
FOUIUI
Added
Recovery
Found
Solids
ID xcu72503-p Xcu72503- I XCU7UO3-2
. , - . -5-M. . .`. I..
cc&
Na.
(ppt)
Fmor
Am
(PPQ
(PPO
(%)
hvb)
(%)
c.s
080103A-ux)l
0
0
cs
080103A-2002
25
:
1018
-
cs
080103A-MO3
50'
ton
XCfJ72503-3
cs
080103A.hM
loo
3701
xco72503-4
ci
080103A-2005
2.54
9370
xcO72.503-5
a
080103A.2006
mJ
19171
XCO72503-6
cs
080103A-2007
Iwo
37079
hlelhlnol WYh
C
080103A-2008
0
Reap1 BIank
C
000103A-2009
1
0
ND
Resgcnc Spk A
LCS
080103A-2010
I
2011
51.4
50
103
lbxgcnl Spk B
LCS
080103A-2011
1
17583
4%
500
99
xc.m2503-1
a
080103A-2012
21
430
W4910-5 Spk C
BC2 SE@04
LF
080103A.2Bl3
10
22078
6470
sow
93"
U4910.10
Spk D
BC2 SED-05
Lp
080103A-1014
10
26935
7620
moo
9r
U4910-II
SpkE
BC2 SED06
LF
080103A.2015
IO
336383
.
sow
`*rs
I.3491020 X072503-2
Spk F
outfall m River SED-25
LP
D80103A.2016
cs
080103A-U)l7
10
72248
JO
2'233
.
5Dw
L349m5
BC-2 SEDM
S
080103A-2018
1
60613
.
69.%
l.34910.5 Rep
ac2 SED-04
s
080103A.U)19
I
51074
.
69.96
L34910-IO
X2 SE&OS
s
080103A-2020
I
93844
.
6954
w491010
Rep
Bc2 sED-05
s
080103A.2021
I
106350
.
69.54
xcum3-3
cs
080103A.2022
mJ
3634
xco72503-4
cs
080103A-2023
250
8WS
l.34910.I I
BQ SE&O6
s
080103A-2024
I
2354673
.
60.41
L34910-11 Rep
BQ SED-M
s
080103A-2025
I
1794353
.
60.41
w4910-20
Outfall to Rive? SEDU
S
080103A-2026
I
418516
I
63.27
w4910.20 Rap
OutfalI ra River SED-23
S
080103A-2027
I
287933
.
63.27
w4910-21
Outfall IO River SED-25 Dup
S
080103A-2028
I
409821
l
67.43
xal72xl3.s
cs
080103A~ZJl2Y
ml
17108
XCO72503-6
cs
080103A.2030
Iwo
32192
Amlyu Rumuy
Feud (ppt) m (psak vu - Qtmxpt) I slope I DP
(%) P
[andya found (pp+mtyte
found in canml
mouat dkd (ppt)
(ppt)] x iW
Jilaw&m InUerccp1 stqx
Cd Off&
: Lincy (l/x - 208.s43 I 35.0593 I 0.990916
weighted)
A&w Aosly(c
Found (ppb) i [amlyte fmmd (ppt] x ~oluma mknckd (0.04 L)I I sampk weight (5 g) Pod (ppb) dry weight - analytc found (ppb) x (I 00% I total solids (+)I
CS - tXibnum C I Cmtml s -sample
rurdud m~~plc
LF = Lab fortified FP - Field fmirlcd LCS -L&oratory
sample sample
Cmtrol Spike
CK I Check Sacdad
ND I Noc&wcwd=RUpopl~bmv~~.Oa~d2Sppt
NQ I Not quurtitiablc
- Reaporuc bctwaa
2S ppt and LDQ (50 wt)
mlylc Fwad (ppb) Dxy Weight
`Sample %mplc
requires dilution. See data ICI 080103AR. was corrcctcd using the data found in re( 080103AR.
%a#
000274
Sponsor Study No: Exygco Study No: Adytc: Ions Mooitored: Site:
NA L34910 FOSA 498 -> 78 Decatur Bakea's Creek
RAW DATA REPORT
Limit of Qwtitation:
hjdon
Volume:
Manix:
Sample Weighr
Final Volume:
50 PP' IS pL
Soil 5.0 g 5.0 mL
Set No: AtlllYSi: InauumntTypc: Extraction Da@: Analyzed on:
OBOlO3A Karen Rishs LCMSMS #6 08iO 1103 08102103
Std.
ExY8a w
Sample Code
RUn
COW
NO.
(ppt)
xco72503a
CS
080103A-2001
0
XCO72503-I
cs
OIOIO3A-2002
25
XCO72503-2 xco72503.3
cs
080103A-2003
50
cs
080103A-2004
loo
xco72503-4
cs
080103A-2005
250
xco72503-5 XCO72503-5
cs
080103A-2006
500
cs
080103A-2W7
loo0
Metbanol Wash
C
080103A-2008
Reagent Blank
lla
C
080103A-2009
Reagent Spk A
"a
LCS
080103A-2010
Reagent Spk B
ns
LCS
080103A.201
I
XCO72503-I
CS
080103A.2012
25
L34910.5 Spk C
BC2 SED.04
LF
080103A-2013
L34910-10
Spk D
BC2 SED-05
LF
080103A-2014
L34910-I I Spk E
BCZ SED-06
LF
080103A-2015
L349lO-20
Spk F
Outfall ID River SED-25
LF
080103A-2016
Vd
XCO72503.2
L34910.5
BC2 SED-04
cs
080103A.2017
50
S
080103A-2016
L34910-5 Rep
BC2 SED-04
S
080103A.2019
L34910-LO
6'22 SED-05
S
080103A.2020
L34910-IO
Rep
BC2 SED-05
S
080103A-2021
xco72503-3
cs
080103A.2022
loo
xcci72503-4
cs
080103A-2023
250
L34910-I I
BC2 SED-C.5
S
080103A-2024
L34910-I I Rep
BCZ SED-06
S
080103A-2025
L34910.20
Outfall to River SED-25
s
080103A-2026
L349lO-20
Rep
Outfall to River SED-25
s
080103A-2027
w4910-21
Ouffall to River SED-2S Dup
S
080103A-2028
XCO72503.5
CS
080103A-2029
500
XCO72503-6
CS
080103A.2030
loo0
Attslytc Found (pit) Rccovexy (%) =
= @crk
LTCP - imerccpt) [amlyte found
/ slope x DF
(pptkmalytc
found
.mount added
in control @pt)
(pp~)J x IM)
Analyte Antdytc
Found @pb) = [analytc Found (ppt) x volume extracted (0.04 L)] I sample weight (5 g) Found (ppb) dzy weight = analy?c found (ppb) r ( ICOYI / total rolids (%))
CS - Calibr&nstandard c = Conholsample s - Sample
LF -Lab fortified sample FF - Field fonilied wttplc LCS = Laboratory Control Spike
Dilution FZiElQI
1 I I IO IO IO IO I 1 I I
I 1 I I I
PC& Area
0 3995 7728 IS082 36693 72894 137821
0 0 6150 65424 3817 79517 82212 155090 IO0640 7957 121882 133583 133763 191201 14698 34282 1215533 92977 I 412369 346884 357273 6723 I 1291 I8
Analytc FOund (ppt)
Amount Added (ppt)
RCCOVCTy (%)
Adyte Found (ppb)
ND
43.6
50
477
500
5810
5000
6010
5000
l
5cw
73 70
so00
894
961 982
.
87 9s
98 IO1
77"
7.15 7.84 7.86
&&rd
CWP
lntacept
slaps
Ccuf. Of Da.
: Linear (I/x - 849.062 - 135.358 = 0.996863
weighted)
TOtnl Solids (%
69.96 69.96 69.54 69.54 60.41 60.4 I 63.27 63.27 67.43
CK - Check Standard
ND - Not detected = Reoponrc between 0 and 25 ppt
NQ = Not quantifiable
- Response bctwcm 25 ppt md LOQ
(50 ppt)
Analyie Found @pb) Dry Weight
10.2 Il.2 Il.3
-
`Sample *Sample
requires dilution.
See data set 080103AR.
was corrected using the data found in set 080103AR.
Spreadsheet prepared by:
000275
Work Group-`VG46121 Analysis: Solid% Title: Send
Date Prepared: 29-
ID L34905-21 L34905-22 L34905-23 L34905-24 L34905-25 L34905-26 L34905-27 L34905-28 L3490523 L34905-30 L34910-5 L34910-10 L3491P11 L34910-20 L34910-21 L34921-1
Result 100 100 100 100 100 100 IO0 100 100 100
69.96 69.54 60.41 63.27 67.43 81.19
Product PERC SOLID PERCSOUD, PERCSOLID PERC SOLID PERC SOLID PERCSOLID PERC SOLID PERC SOLID PERCSOLID PERC SOLID PERC SOLID PERC SOUD PERCSOLID PERCSOLID PERC SOLID PERC SOLID
Matrix SOUD SOLID SOUD SOLID SOLID SOLID SOLID SOLID SOUD SOLID SOLlD Soil0 SOLlD SOLID SOLID SOLID,
DF MDLxDF I 0.01 I 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01
CRDLxDF 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0
Flags The Collect
Time Run
Client ID
OB-J&O3 0O:OO 24Jul-03 15%
200874 X33238-32-21
08-Jut-03 0O:OO 29-Jul-03 1534
200875 X33238-32-22
08-J&03 0O:OO 29-J&03 15:34
200876 X33238-32-23
OB-J&O3 0O:OO 29-Jul-03 1534
200077 X33236-32-24
OB-Jul-03 0O:OO 24Jul-03 15:34
200878 X33236-32-25
oaJul-03 0o:oo 29-J&03 15:34
200879 X3323632-26
08-J&03 0O:OO 29-Jul.03 15~34
200860 X33236-32-27
OB-Jul-03 0O:OO 29-Jul-03 15:34
200881 X33236-32-28
O&Jui-03 0O:OO 29-J&03 15%
200882 X33238-32-29
OB-Jul-03 0O:OO 29-J&03 15~34
200883 X33238-32-30
23-Jul-03 14% 24Jul-03 15%
DC2 SED-04
21-Jul-03 14:15 29-Jul-03 15:34
BC2 SED-05
23-J&03 15:25 29-J&03 15%
BC2 SED-06
23-J&03 16:15 29-Jut-03 15:34 OUTFALL TO RIVER SE525
23-J&03 16:15 24Jut-b3 15% OUTFALL TO RIVER SED-25 DUP
23-JuLD3 14:00 24Jul-03 15:34
BASR7-23
Print Date: 30-Jul-03
Page 1 of 1
Analyst: AJ <
Work Analysis:
Group: Solids
* 46121 t Title: Data
Date Prepared: 29-t
r03
Analyst Initiate Date and Time Data Aquired (ctri+t)
AJH
29-Ju1-03 1534
AJH
29-JulO3 16.06
AJH
30.J&f33 0834
CAL ID
WG46121.1 WG46121-2 L34905-21 L3490522 L3490523 L34905.24
I L3490525
L-%905-26 L34905-27 L349ClS-28 L34905.23
I L3.490530
L34910-5 L34910-10 L34910-1 I
CUENT ID
MATRIX
PAN ID
MB
PERC SOL10 1 SOLID
1
UP: L34910-
PERC SCUD ) SOLID
2
74 X33238-3
PERC SOLID ) SOW
3
75 xwm-ah PERC SOLID I souo
4
76 X33238-3
PERC Sa.lO 1 sow
5
1 77 X33238-3b
PERC SOLID ) SCUD 1 6
176 X33238-3b
PERC SCUD 1 SOLID 1 7
PERC SOilD ] SOLID
8
PERC SOLID 1 SLXIO
9
81 X33238-3
PERC SOLID ) SOLID
10
82 X33238-3
PERC SOLID ) SOLM
11
1 83 X33236-3b
PERC SOLID I SOLID i 12
I
r
I
6C2 SED.04
PERC SOLID ) SOCID
13
6C2 SE&OS
PERC SOLID ) SOLID
14
EC2 SEDD6
PERC SOLID ] SOLID 1 15
PAN WEIGHT
I.2578 1 2521
1 1 1 1 1 1
1 1
1.2512 1.2517 1 .i578 1 2574 12638 1.2556
(g) sAMPLE+PAN'gJ
I
I
1.2578
1
43.5159
2
2
2
2
2
2
I
2
I
39.8338
28 6584
I
34.2073
23.9616
1
20 0233
4.2022
DRIED SAMPLE
1
*PAN(g)
IGNITED SAMPLE
/
+PAN(g)
X Solids of X TVS
/
or%Ash
(
1.2578
31.9212
2
2 2
2
2
2
2
I
2
I
0
72.56
100
lco
loo
1W
100 loo
loo
I
100
I
I
28 246
I
20.3121
21.1653
I
.
15.6246
13.9150
I
36481
I
69.96
69.54
I
60.4 1
63.27
67.43
81.19
I
I
I
1
Print Date: 06-Aug43
Page 1 of 1
E
Exygen Study Number:
nn4 EAKCH
3058 Research Drive State Cdlege, PA 16801
Internal Chain of Custody/Fortification
L34910
Sheet
Matrix:
Phone: 814-272-1039 Fax: 814-231-1580
m
w were removed from refrig
Outfall to River SED-25 Dup
L34910-21
5.0
AI1 samples were weighed on balance No. W
Time C%?e
InitiaIs &
After weighing samples were re
Time I.=
InitiaIs &5
bxUnen~:
200 S of 250 mglmL sodium tiosulfatc was added to all sunpler kfmc
Analysis Summary:
Data Set: Data Set: Data Set:
fio~03~ -
rpikiag. Inilials/t)atc:
Initials/Date: Initials/Date: Initials/Date:
Set extraction/analysis data verified by:
Date:
g/hb July 26, 20011t)00278
1
d nma (. EAKC ti
3058 Research Drive
Phone: 814-272-1039
State College, PA 1680 1 Fax: 814-231-1580
SAMPLE EXTRACTION AND ANALYSIS TRACKING SHEET
EXYGEN STUDY NUMBER: MATRIX:
L34910 &!
METHOD: ANALYTES:
ExM-023-014's PFHS. PFOS. PFOA and PFOSA
PROTOCOL NUMBER: m
STEP 1: Add 5mL of methanol and shake by hand for -I minute
STEP 2: Bring up to 40 mL with hypercarb filtered type I water
STEP 3: Centrifuge for 10 minutes at -3OOO rpm
STEP 4: Filter through glass acrodisc
STEP 5: SPE colmnn clean up (omitting 40% wash)
STEP 6: Final volume to 5 mL collected in 15 mL polypropolene tubes
STEP I: LtXWMS analysis
0
STEP 8: LCfMS/MS reanalysis.
8 *Initials and date under each step indicates the personnel that performed this step.
$$ Method of Analysis for the Determination of Perfluor~tancsulfonate
(PFOS) and Pentadeeafluorooctanoic
Acid (PFOA) in Soil
COMMENTS:
Final extracts stored in refrigerator 9 Initials: @ Date:
3
July 19,200114
Masslynx - Sample List
Sample List: Printed: Fri AMJ 01 15:28:30 2003
Exygen STUDY NO. !--3!45(0
Page 1 Page Position: (1, 1)
Vial File Name
LIMS ID Client ID Sample Description
Matrix Sample Type Conc(ng/L)
1 41 080103A-2001 --
-
2
42 080103A-2002
--_
-
3
43 080103A-2003
---
-
4
44 080103A-2004
---
-
080103h2005
_--
-
f
1: 060103A-2006 --
-
080103A-2007 -_
-
ii
080103A-2008 --
-
9
080 I 03A-2009 --
-_
080103A-2010
-_-
-
::
080103A-2011
I-
-
42 080103A-ml2
___
-
::
4 080103A-2013
--
-
080103A-2014
I_
-
::
2 080103A-2015
--
-
16
7 080103A-ml6
-_
-
17
43 080103A-2017
-_
-
18
080103A-2018
-
19
i 080103A-2019 ___
-
20 10 080103A-2020 --
-
21 11 080103A-2021 ___
-
22 44 080103A-2022 ___
-
23 45 080103A-2023 -_
-
24
12 080103A-2024
sm..
-
25
13 080103A-2025
__-
-
14 080103A-2026
--
-
z;
15 080103A-2027 --
-
28
16 080103A-2028
--
-
29 46 080103A-2029 --
-
30 47 080103A-2030 --
-
XCO72503-0.0 nglL Standard
--
Standard
0
XCO72503-I,25 rig/L Standard
_-
Standard
25
xCO72503-2, 50 nglL Standard
--
Standard
50
xCo72503-3, 100 rig/L Standard
-
Standard
loo
XCO72503-4,250 nglL Standard
-
Standard
250
XCO72503-5,500 rig/L Standard
Standard
500
XCO72503-6, 1000 t-g/L Standard
--
Standard
1000
Methanol Wash
-
Blank
--
Reaccent Blank
--
Blank
-
Reagent Spk A. 50 nglL
.-
100
Reagent Spk 6,500 ngR
-
::
500
XCO72503-1,25 rig/L Standard
--
Standard
25
L34910-5 Spk C. 5000 rig/L, DF=lO
-
QC
5000
L34910-10 Spk D,5000 rig/L, DF=lO --
5000
L34970-11 Spk E, 5000 w/L, DF=lO -
::
5000
L34910-20 Spk F, 5000 rig/L. DF=lO --
QC
5000
XCO72503-2. 50 ~111 Standard
-
Standard
50
L34910-5
-
--
Analyte
-
L3491.0-5 Rep
--
Analyte
-
L34910-10
-
Analyte
-
L34910-10 Rep
-
Analyte
XCO72503-3, 100 rig/L Standard
--
Standard
lo0
XCO72503-4,250 nglL Standard
-
Standard
250
L34910-11.
--
Analyte
--
L34910-11 Rep
-
Anaiyte
--
L3491 O-20
-
Analyte
-*
L34910-20 Rep
-
Analyte
--
L34910-21
-
Analyte
-_
XCO72503-5,500 rig/L Standard
-
Standard
500
XCO72503-6,lOOO ngll Standard
--
Standard
1000
ConcB
-_ ----_ -_ --_ -_ ---_-_ --.---
_----__ ---_
ConcC
___ -I -_--
_^_ -_--_--_-----I ----
Test ID DF
0
1
0
1
0
1
1
x
1
0
1
0
0
:
0
1
x
:
0
1
10
:
IO
0
0
ii
0
1
0
1
0
1
0
1
0
1
1
8
1
0
1
0
1
0
0
:
1
ii
1
0
1
t
Masslynx - Sample List Sample List: Printed: Fri Aug 01 15:28:30 2003
MS Method
HPLC Method MS Tune File Inj.Volume
I C6 C8 SULF C8 ACID PFOSA 2 C6 C8 SULF CB ACID PFOSA 3 C6 C8 SULF C8 ACID PFOSA 4 C6 C6 SULF C6 ACID PFOSA 5 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA ; C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID F'FOSA : C6 C8 SULF C6 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA :`: C6 C8 SULF C8 ACID PFOSA 12 C6 C8 SULF C8 ACID PFOSA 13 C6 C6 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
:`: C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C6 ACID PFOSA
:t C6 C8 SULF C8 ACID PFOSA
18 C6 C8 SULF C8 ACID PFOSA
19 C6 C8 SULF C8 ACID PFOSA 26 C6 C8 SULF C8 ACID PFOSA
21 C6 C8 SULF C8 ACID PFOSA 22 C6 C8 SULF C8 ACID PFOSA
23 C6 C8 SULF C8 ACID PFOSA
24 C6 C8 SULF C8 ACID PFOSA C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF CB ACID PFOSA
pfbs water pfbs water pfbs water pfbs water pfbs water
pfbs water pfbs water
pfbs water pfhs water
pfhs water pfbs water
pfhs water pfbs water
ppfbms swwaatteerr pmswater ppfbms swwaatteerr ppfbms swwaatteerr pmswater ppmrnsswwaatteerr ppfbms swwaatteerr pmswater pmswater pmswater
pfbs water pfbs water
Fluorochems 15 Fluorochems 15 Fluorochems Fluorochems :z Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems Fluorochems :: Fluomchems Fluorochems :55 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems f5 Fluorochems 15 Fluorochems 15 Fluorochems Fluerochems ;z Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15 Fluorochems 15
Oxygen STUDY NO. " L3q'0
A t
Page 2 Page Position: (2, 1)
LC/MS/MS SYSTEM AND OPERATING CONDITIONS
Soonsor Protocol No: NA
Exveren S tudv No: L34910
Instrument:
Micromass Quattro Ultima @C/MS/MS Unit #6)
Computer:
COMPAQ Professional Workstation AP200
Software:
Microsoft Windows NT: Version 4 Build 1381: Service Pack 5 Micromass Limited: MassLynx 3.4 Build 004
HPLC Equipment:
Hewlett Packard (HP) Series 1100
HP Bin Pump
HP Vacuum Degasser
HP Autosampler
HP Column Oven
HPLC cohlmn:
Genesis C-8,5 cm x 2.1 mm i.d. x 4 p (Exygen ID: 74A) (JONESCHROMATOGRAPHY: Part No. FK5962E)
Mobile Phase (A) : Mobile Phase (B) :
2 mM Ammonium Acetate in Type I Water Methanol
Analyst:
Karen Risha Exygen Research 3058 Research Drive, State College, PA 16801 Phone: (814) 272-1039 FAX: (814) 231-1580
NOTE: The next 3 pages are computer generated printouts from the masslynx software program. The pages contain the instrument settings used for the analysis of this data set.
All Handwritten Peak ID's by: ' i
000282
w
Scanning
Method Report
Method: Last Modified:
C:\M?GSLYNX\FLUOROCHEMICALS.PRO\ACQUDB\C6
Thu Jul 31 16:23:50 2003
Printed:
Fri Aug 01 15:29:10
2003
C8 SULF CS ACID PFOSA
Solvent
Delay ( mins ) :
0.00
Analog Channel
Function : 1
4 : Unused
MRM of 4 Mass Pairs
( ESP- )
Inter Channel Delay ( Sets ) : 0.03
Span ( Daltons ) :
0.00
Start Time ( Mins ) :
0.00
End Time ( Mins ) :
12.00
Repeats :
1
Channel Parent Daughter
Dwell (Sets) Co11 Energy (eV) Cone ( V )
1
399.00
80.00
0.20
35
50
2
413.00 369.00
0.20
10
10
3
498.00 78.00
0.20
30
50
4
499.00 99.00
0.20
40
30
000283
Method Report
Method File: Laat Modified:
v Printed:
c:\maeslynx\fluotochsmicals.pro\acqudb\pfbs
Friday, August
01, 2003 15:20:36
Friday, August 01, 2003 15:29:16
HP1100 LC Pump Initial
Conditions
Solvents
A%
90.0
B%
10.0
C%
0.0
D%
0.0
Flow (ml/min) Stop Time (mins) Min Pressure (bar) Max Pressure (bar)
Oven Temperature Left(OC) Oven Temperature Right(OC)
0.300 20.0
0 400
35.0
35.0
HP1100 LC Pump Gradient Timetable
The gradient Timetable contains S entries which are :
Time
A%
B%
C%
D%
0.00
90.0
10.0
0.0
0.0
2.00
90.0
10.0
0.0
0.0
5.00
10.0
90.0
0.0
0.0
9.00
10.0
90.0
0.0
0.0
9.50
0.0
100.0
0.0
0.0
14.00
0.0
100.0
0.0
0.0
14.50
90.0
10.0
0.0
0.0
20.00
90.0
10.0
0.0
0.0
b@
HP1100 LC Pump External
Event Timetable
The Timetable contains 6 entries which are :
Time Initial
0.00 0.05 0.10
11.90 12.00
Column Switch
Off Off Off Off
Off Off
Contact1
Off On Off Off Off Off
Contact2 Off Off Off On Off Off
'Contact3 Off Off Off Off On Off
w
Flow 0.300 0.300 0.300 0.300 0.300 0.300 0.300 0.300
Contact4 Off Off Off Off Off Off
HP1100 Autosampler Initial
Draw Speed
Eject Speed (pl/min)
Draw Position (mm)
Stop Time (mins)
Injection
Volume(p1)
Vial Number
Conditions
200.0 200
0.50 20.00 15.0 69
Page 1 water
Pressure 400 400 400 400 400 400 400 400
000284
1111
Tuning Method: Printed:
Method
Report C:\kWi.SLYNX\FZUOROCHEMICALS.PRO\ACQUDB\EWOROCHEMS Fri Aug 01 15:29:30 2003
Page 1
Dau 395.00
SOURCE ( ESP- )
Capillary
Cone Hexapole 1
Aperture 1 Hexapole 2 Source Block
Desolvation
Temp. Temp.
Pressures
Analyser Gas Cell
Vacuum
Set Rdbk
3.00 -2.93
20
-33
0.0
0.0
0.0
100 100
300 299
Rdbk
OFF 3.3e-3
Analyser
LM Res 1 HM Res 1 IEnergy 1 Entrance Collision Exit LM Res 2 HM Res 2 IEnergy 2 Multiplier
Gas Flows
Cone Gas Desolvation
V
Set Rdbk
14.0
14.0
1.0
-2
36
15
19
2
40
14.0
14.0
2.0
650 -648
Rdbk
131.8 751.3
00028s
-----
---------
Quantify Calibration
Report
\Icl, Study No.:L34910,
Set No.: 080103A,
Ext.Date:08/01/03,
Analyst:X.Riaha
Calibration:
Last modified: Printed:
----___
P:\Data\LCWSMS6\blasslynx\Fluorochemicals.PRO\~~eDB\O8OlO3A
Sun Aug 03 07:26:03 2003
Sun Aug 03 07:32:22
2003
------_----
Compound 1 name: C8 Acid (PFOA) >oefficient of Determination: 0.988097 >alibration curve: 300.076 * x + 2344.75 qesponse type: External Std, Area 2urve type: Linear, Origin: Exclude, Weighting:
l/x, Axis trans: None
3.16e5-
-----
Page 1
Decatur BC
Response-
Oxygen Research, 3058 Research Drive, State College, PA 16801
---___I_--
-------MI
---
Quantify Calibration
Report
w
Study No.:L34910,
Set No.. -080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Calibration: Last modified: Printed:
----
P:\Data\L~SWS6\Masslynx\Fluorochsmicals.P~\~~~DB\O80103A
Sun Aug 03 07:26:03
2003
Sun Aug 03 07:32:22
2003
--
-_____---------_II------~~~~~~~~~
:ompound 2 name: C6 Sulfonate (PFHS) Coefficient of Determination: 0.995587 :alibration curve: 57.3138 l x + 476.906 Response type: External Std, Area :urve type: Linear, Origin: Exclude, Weighting:
5.83@4-
l/x, Axis trans: None
--
Page 2
Decatur BC
X
Response-
Exygen Research,
3058 Research Drive, Stats College, PA 16801
0002~7
Quantify Calibration
Report
$,J Study No.:L34910,
Set No.: 080103A,
Ext.Date:08/01/03,
Analyst:R.Risha
Calibration: Last modified:
Printed:
P:\Data\L~SndS6\bssl~\F~uoroch~cals.PRO\~~eDB\O80103A
Sun Aug 03 07:26:03
2003
SUA Aug 03 07:32:22
2003
:ompound 3 name: C8 Sulfonate (PFOS) >oefficient of Determination: 0.990916 Calibration curve: 35.0593 l x + 208.543 lesponse type: External Std, Area Curve type: Linear, Origin: Exclude, Weighting:
3.71 e4
l/x, Axis trans: None
Page 3 Decatur BC
X
Response
Exygen Research, 3058 Research Drive, State College, PA 16801
000288
-__-_.___ --.-.-.-- ..-.
-... ...-.- ..---- -----------
Quantify
Calibration
Report
"4 Study No.: L34910, Set No.: 080103A, Ext.Data:08/01/03,
Calibration:
Last modified: Printed:
-
-----
P:\Data\LCM~S6\Massl~\FluorochemicaeDB\O8OlO3A
Sun Aug 03 07:26:03
2003
Sun Aug 03 07:32:22
2003
---____--__-----___--------
Analyst:R.Risha
------e--y-------
Compound 4 name: PFOSA Coefficient of Determination: 0.996863 :alibration curve: 135.358 l x + 849.062 Response type: External Std, Area >urve type: Linear, Origin: Exclude, Weighting:
1.38e5
l/x, Axis trans.: None
Page 4 Decatur BC
Response
0(I-.0
Exygen Research, 3058 Research Drive,
State College, .
PA 16801
000289
-----
-v------w----w---
-------_------__I_
Quantify
Sample Report
Study No .:L34910, Set No.:080103A,
E&.Date:08/01/03,
Analyst:K,Risha
Sample List: Last modified: Method : Last modified: Job Code:
P:\Data\L~~6\~sslynx\Fluoroch~cals.PRO\S~1eDB\080103A Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicale\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 1 Decatur BC BC 080103
Name : 080103A-2001 Text:
1: C8 Acid (PFOA)
XCO72503-0,O rig/L Standard
080103A-2001 Sm (Mn, 2x3)
2: C6 Sulfonate
XCO72503-0,O
@I I I .m,
2.00
4.00
(PFHS)
rig/L Standard
I I 6.00
02-Aug-2003 02:27:16
LC/MS/MS #6
MRM of 4 Channels ES413>369 2.00e4 Area
9.14
333
10.00
12.00
02-Aug-2003 02:27:16 LC/MS/MS #6
MRM of 4 Channels ES399 > 80
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
(PFOS)
XCO72503-0,O rig/L Standard
02-Aug-2003 02:27:16 LC/MS/MS #6
MRM of 4 Channels ES499 > 99
11.36 11.75 962
0 ~..~,~~~~,.,,,,,,~,,~~,,,~,,~,,~,,,,~,,,~~~~,~~,~,~~,~,~,~~~Time
2.00
4.00
6.00
8.00
10.00
12.00 _
Oxygen Research, 3056 Research Drive, State College, PA 16801
000290
----
---------------------~
Quantify Sample Report
,,d Study No.:L34910,
Set No.: 080103A, Ext.Date:08/01/03,
Analyst:K.Risha
Si?uaple List:
Last modified: Method:
Last modified: Job Code:
P:\Data\LCM~S6\blasslynx\Fluoroch~cala.P~O\S~leDB\O6OlO3A Sun AUg 03 07:25:44 2003 P:\Data\LCMSWS6\Masslynx\Fluoroch~cals.~RO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25 2003
------
Page 2
Decatur
BC
BC 080103
Name: 000103A-2001 Text :
4: PFOSA
XCO72503-0, 0 rig/L Standard
080103A-2001 100-l
Sm (Mn, 2x3)
I
32-Aug-2003 02:27:1 t
V LCNS/MS #IE MRM of 4 Channels ES-
9.79
498 > 7fc
EXygen Research, 3058 Research Drive, Stats College, PA 16801
000291
------
I__-----
---------
Quantify
Sample Report
" 4 Study No.:L34910,
Set No.:080103A,
Rxt.Date:08/01/03,
Analyst:K.Risha
Sample List:
Last madified: Method:
Last modified: Job Code:
P:\Data\LCMSblS6\WasslyPx\Fluorochemicals.PRO\S~leDB\O8OlO3A Sun Auq 03 07:25:44 2003 P:\Data\LCbISMS6\~ssl~\Fluorochsmica\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
---
Page 3
Decatur BC BC 080103
Name: 080103A-2002 Text :
1: C8 Acid (PFOA)
lXCO72503-I,25 rig/L Standard
080103A-2002 10%
Sm (Mn, 2x3)
%-
9.13
98827
02-Aug-2003 02:49:04
LClMS/MS #6
MRM of 4 Channels ES413>369 5.84e4 Area
`d 2: C6 Sulfonate
(PFHS)
XCO72503-1,25 rig/L Standard
080103A-2002 10
Sm (Mn, 2x3)
% 4
3: C8 Sulfonate
XCO72503-1,25
(PFOS)
q/L Standard
080103A-2002 100-
Sm (Mn, 2x3)
%-
02-Aug-2003 02:49:05/
LCIMSNS #6
MRM of 4 Channels ES-
8.98
399 > 80
1579
9.29e3
Area -
L^
Time
12.00
02-Aug-2003 02:49:05
LC/MS/MS #6
MRM of 4 Channels ES-
9.26
499 > 99
6.29e3
Area
A
0 ,,l,71~~,.".,,,,.,,.,.,..~`,"`.,"","",
1 , 3 TyT-cy
Time
2.00
4.00
6.00
8.00
10.00
12.00 ,
Exygen Research, 3058 Research Drive,
State College,
PA 16801
.-BIII""(
--
~,---
.^ --
000292
----
-----
-----
------------_
Quantify Sample Report
\& Study No.:L34910,
Set No.: 080103A, Ext.Date:O8/01/03,
Analyst:K.Risha
Page 4
Ssmgls List:
Last xmdified: Method:
Last modified: Job Code:
P:\Data\LCWSMS6\Masslynx\Fluorochemicals.PRO\S~leDR\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\L(3WSMS6\blasslynx\FluorochemicaR\Decatur Sun Au% 03 07:11:59 2003
Decatur BC BC 080103
Printed:
--------------em
Sun Aug
Name: 000303A-2002 Text :
03 07:32:25
2003 -------
c-----------------_________
: PFOSA
(CO72503-1,25
rig/L Standard
180103A-2002 10
Sm (Mn, 2x3)
%3.
02-Aug-2003 02:49:05
LC/MS/MS #6
MRM of 4 Channels ES-
9.9C) 399!
498 > 78 2.1 le4
Area
01
2.00
4.00
6.00
8.00
10.00
12.00
l%YOen Research, 3058 Research Drive, State College, PA 16801
P-m------
-1_-------
Quantify Sample Report
w Study No.:L34910,
Set No.: 080103A, Ext.Date:08/01/03,
Aaalyst:X.Risha
Sample List:
Last modified: Method: Last modified: Job Coda:
P:\Data\L~SMS6\Mssslyox\Fluoroch~cals.PRO\S~~eDR\O8OlO3A
Sun Aug 03 07:25:44 2003 P:\Data\LCEISMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
SUA Aug 03 07:32:25
2003
Page 5
Decatur BC BC 080103
Name : 080103A-2003 Text:
1: C8 Acid (PFOA)
XCO72503-2,50 rig/L Standard
080103A-2003 lO&
Sm (Mn, 2x3)
%-
02-Aug-2003 03:10:44
LC/MS/MS #6
MRM of 4 Channels ES-
9.13
413>369
l.lle5
Area
2.00
4.00
w 2: C6 Sulfonate
(PFHS)
XCO72503-2,50 q/L Standard
080103A-2003 Sm (Mn, 2x3)
, , . 1, , , , , , ,
8.00
10.00
. , r , ,-y Time 12.00
02-Aug-2003 03:10:44
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
2.28e4
Area -
;: C8 Sulfonate
KO72503-2,50
(PFOS)
rig/L Standard
)80103A-2003 10
Sm (Mn, 2x3)
%j
Time 12.00
7
02-Aug-2003 03:10:44
LC/MS/MS #6
MRM of 4 Channels ES-
9.24
499 > 99
207:
1.28e4
Area
Time
2.00
4.00
6.00
8.00
lo:oo
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000234
--
---
-------
-----------
w------m--
Quantify Sample Report
\& Study No.:L34910,
set NO.: 080103A, Ext.Date:08/01/03,
AMllyst:K.Risha
Page 6
SamQls List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSblS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O6~lO3A Sun Aug 03 07:25:44 2003
P:\Data\L~SMS6\Masslynx\Fluorochamica\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 060103
Printed:
Sun Aug 03 07:32:25
2003
I--------------I-------------I_-----------------------__~_
NW: 000f03A-2003 Text :
4: PFOSA
X072503-2,50 rig/L Standard
02-Aug-2003 03:10:44
LC/MS/MS #6
)80103A-2003 Sm (Mn, 2x3) 10
7 i
%IO'~~~~,~~~~,~~~`,~".,.~`~,~~",~"','~,~,,~~~,',~
MRM 9.90 , 772E5
of 4 Channels ES498 > 78 4.01 e4 Area
A-
Time
2.00
4.00
6.00
8.00
Exygen Research, 3058 Research Drive, State College, PA 16,801
-------
p-w---
-----
-----v----m__
Quantify
s-10
Report
bf
Study No.: Ll34910, set No .:080103A,
Eact.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\~sslyPx\Fluoroch~cals.PRO\S~~eDB\O8OlO3A
Sun Aug 03 07:25:44
2003
P:\Data\~SMS6\Masslynx\Fluorochemicals.PRO\MethDB\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Rage 7
Decatur BC BC 080103
Name: 0801031-2004
Text :
1: C8 Acid (PFOA)
XCO72503-3,100 rig/L Standard
080103A-2004 10
Sm (Mn, 2x3)
9.13 34827
02-Aug-2003 03:32:2d LCYMWMS #6
MRM of 4 Channels ES413>369 2.10e5 Area
Time
L 2.00 4.00 6.00 8.00 1o:oo 12:oo
\d 2: c6 Sulfonate
(PFHS)
XC072503-3,100 rig/L Standard
080103A-2004
10 7
Sm (Mn, 2x3)
02-Aug-2003 03:32:2j
LCJMWMS #6
MRM of 4 Channels ES-
8.98
399 > 80
6481
3.94e4
Area
e
Time
L 2.00 4.00 6.00 8.00 10.00 12.00
: C8 Sulfonate
(PFOS)
KO72503-3, IO0 rig/L Standard
180103A-2004
10 ?I
Sm (Mn, 2x3)
%
02-Aug-2003 03:32:27
LCIMSMS #6
MRM of 4 Channels ES-
9.24
499 > 99
3701
2.21 e4
Area
i
%___--
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000296
Quantify
Sallqlle Report
,cf Study No.:L34910,
Set No.. -000103A, Ext.Date:oa/ow03,
A.ualyst:K.Risba
Page 8
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQHSMS6\Masslynx\Fluoroch~cals.PRO\S~laDB\O8OlO3A
Sun Aug 03 07:25:44
2003
B:\Data\L~SMS6\Maaslyax\Fluorochamicals.PRO\MethDB\Decatur
Sun Aug 03 07x11:59
2003
Decatur BC BC 080103
Printed:
------
Sun Aug 03 07:32:25 2003
--------___l_
--------------_I__
--
-
Name: 080103A-2004 Text :
4: PFOSA XCO72503-3,100
rig/L Standard
080103A-2004 loo-
Sm (Mn, 2x3)
%-
02-Aug-2003 03:32:2$
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498>78
7.93e4
Area
0 `~~~,~"`,J~(~,1~~~,`~",~"(,"",~J'I,"","'
, I I 1 t 1Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygtrn Research, 3058 Research Drive, State College, pA 16801
000297
Quantify Sarr~le Report
w
Study No.:L34910,
Set No.. *080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 9
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L(2dSMS6\Masslynx\Pluoroch~cals.PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\Mas8lynx\Fluorochamica~s.PRO\MethDB\Dscatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
------------_---------------_
Sun Aug 03 07:32:25
2003
-----_--------------
---------I____
Nzuae: 080103A-2005 Text :
1: C8 Acid (PFOA)
KC072503-4,250 rig/L Standard
080103A-2005 10
Sm (Mn, 2x3)
9.13 78794
02-Aug-2003 03:54:13/ LC/MS/MS #6
MRM of 4 Channels ES413>369 4.78e5 Area
w 2: C6 Sulfonate
XCO72503-4,250
(PFHS)
rig/L Standard
080103A-2005 100-
Sm (Mn, 2x3)
%-
3: C8 Sulfonate
[XCO72503-4,250
(PFOS)
rig/L Standard
080103A-2005 Sm (Mn, 2x3)
8.98 15770
02-Aug-2003 03:54:13 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 9.57e4 Area
8 I I , . I I , I r I 1Time
10.00
12.00
02-Aug-2003 03:54:1 I LCNSNS #c
MRM of 4 Channels ES-
499 > 99 5.56e4
Area
Time 12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000298
Quantify
Sample Report
+4 Study No.:L34910,
set NO .:080103A,
Ext.Dats:00/01/03,
&aalyet:K.Risha
Salqple List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\MasslyPx\Fluorochemicals.PRO\S~leDB\O8DlO3A Sun Aug 03 07:25:44 2003 P:\Data\L(IMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 10
Decatur BC BC 080103
Name: Text:
000103A-2005
4L: PFOSA
(CO72503-4,250
rig/L Standard
180103A-2005 10
"f
%$
Sm IMn. 2x31
O'~~",~,",`~~`,`~~~,~~`~,~"`,,~~~,~"~,~~",~"
2.00
4.00
6.00
8.00
02-Aug-2003 03:54:1 Z
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
49% > 78
3669: I
1.95e5
Area
I
Time
12.00
RWgen Research, 3058 Research Drive, Stata Collage, PA 16801
000299
__1----
--
---
--------me-
Quantify Simple Report
N4 Study No.:L34910,
Set No .:080103A,
Fkt.Date:08/01/03,
Analyst:X.Risha
SasllDle List: Last modified: Method: Last modified: Job Code:
P:\Data\LCW~S6\blassl~\Fluoroch~ca~s.PRO\S~leDB\O80103A Sun Aug 03 07:25:44 2003 P:\Data\L(lbiSMS6\Masslynx\FluorochemicaB\Decatur Sun Aug 03 07:11:59 2003
Page 11
Decatur BC BC 080103
Printed:
Sun Aug 03 07:32:25
2003
-----------------------------------------------------
---w----w--
Name: 080103A-2006
Text :
:-C8 Acid (PFOA)
EO72503-5,500 rig/L Standard
)80103A-2006 -loo-
Sm (Mn, 2x3)
%-
9.12 171634
02-Aug-2003 04:15:54j LCIMSIMS #6
MRM of 4 Channels ES413> 369 l,Ole6 Area
2: C6 Sulfonate
XCO72503-5,500
2.00
4.00
(PFHS)
rig/L Standard
080103A-2006 10
Sm (Mn, 2x3)
6.00
8.00
8.98
31281
02-Aug--2003 04:15:54/ LCNSNS #6
MRM of 4 Channels ES399 > 80 1.90e5 Area
I,
I,,
/
10.00
(1, I r 7 Time 12.00 ,
3: C8 Sulfonate
(PFOS)
XCO72503-5,500 rig/L Standard
02-Aug-2003 04:15:54
LC/MS/MS #6
080103A-2006 Sm (Mn, 2x3)
MRM of 4 Channels ES-
lo@4-1
i
9.24 19171
499 > 99 l.lle5 Area
%1 A-?-
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16803
000300
Quantify Sample Report
tiu' study No.:L34910,
Set No.: 080103A,
Ext.Date:08/01/03,
Analyet:K.Risha
Sample List: Lant modified: Method: Last nmdif ied: Job Code:
P:\Data\~SMS6\Massl~\Fluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 1003
P:\Data\LCMSMS6\Mssslynx\Fluoroch~cals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:32:25
2003
Pags 12
Decatur BC BC 080103
Name: 080103A-2006 Text :
4: PFOSA
XCO72503-5,500
rig/L Standard
080103A-2006 1001
Sm (Mn, 2x3)
%-
02-Aug-2003 04:15:54
LC/MS/MS #6
MRM of 4 Channels ES-
9.92
498 > 78
3.82e5
Area
, , , , , , Time
10.00
12.00
Exygen Research, 3058 Research Drive, State Collage, PA 16801
000306
Quantify Sample Report
vd Study No.:L34910,
Set No.: 000103A, Ext.Date:08/01/03,
Analyst:K.Risha
Page 13
Sample List: Last modified: Method:
Last modified: Job Code:
P:\Data\L~SMS6\MasslWr\Fluorochermlcals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LQHSMS6\MasslyPx\FluorochsmicaleB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: -e-p-
Sun Aug 03 07:32:25
2003
~----------------------------
NallBB: 080103A-2007 Text:
e----m-
1: CB Acid (PFOA)
XCO72503-6,lOOO rig/L Standard
080103A-2007 lO&
Sm (Mn, 2x3)
%-
9.13 315768T
02-Aug-2003 04:37:34 LC/MS/MS #6
MRM of 4 Channels ES413>369 1.84e6 Area
0 ,~~,,,~,,,,~~~,,,,,,,~,~,~~,,,,,,,,~,,,,,,,,~,~,,,,,,,,,,,,Time
2.00
4.00
6.00
vii, 2: C6 Sulfonate
(PFHS)
XCO72503-6, 1000 rig/L Standard
080103A-2007 lOO-
I
Sm (Mn, 2x3)
8.00 6.98
10.00
12.00
02-Aug-2003 04:37:34 LC/MS/MS #6
MRM of 4 Channels ES-
399 > 80 3.49e5 Area
2.00
4.00
6.00
3: C8 Sulfonate
XCO72503-6,1000
(PFOS)
rig/L Standard
080103A-2007 loo-
Sm (Mn, 2x3)
%-
%cIJ -
~,~,,,,,,~,,~~,,,,,,,,,,,,~.~~,~,~,,~~~~,~~~~,1(1:~~,..~~,~~~~1Time
2.00
4.00
6.00
8.00 9.25 37079
10.00
12.00
02-Aug-2003 04:37:34
LClMS/MS #6
MRM of 4 Channels ES-
499 > 99 2.12e5 Area
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000302
Quantify S-10 Report
Study No .:L34910,
Set No.:080103A,
Kxt.Date:08/01/03,
Analyst:K.Risha
Page 14
Sample List: Last modified: Method:
Last modified:
Job Code:
P:\Data\LCblSMS6\blasslyPx\Fluoroch~cals.~RO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44 2003
P:\Data\L(1MSMS6\Maselyax\Fluorochamicalr
Sun Aug 03 07:11:59
2003
Decatur
BC
BC 080103
Printed:
--------_I--------_______I
Sun Aug 03 07:32:25
2003 --__------------
------------____
Name: 080103A-2007 Text :
4: PFOSA
XCO72503-6,1000
I
/ 080103A-2007 Sm
I1nfh
rig/L Standard
(Mn, 2x3)
02-Aug-2003 04:37:34/
LC/MS/MS #6
MRM of 4 Channels ES-
9.92 _ 137821
498 > 78 7.22e5
Area
, , , , , , , Time
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801 .._"_I.,-_,.-
000303
Quantify Sample Report Study No .:L34910, Set No.:080103A,
Ext.Date:08/01/03,
Analyst:X.Rieha
Sam@0 List: Last modified: Method:
Last modified: Job Code:
P:\Data\LWSMS6\Masslynx\Fluorochemical~.~RO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003
P:\Data\LCMSMS6\Maeelynx\FluorochemicglsB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:2S
2003
Page 15
Decatur BC BC 080103
Name : 080103A-2008 Text:
1: C8 Acid (PFOA)
Methanol Wash
I0801 0314-2008 Sm (Mn, 2x3)
II 10%(1i7J-W
01,,,,,,,,,,~,~~,,~~~I~,,,,,,~~,,~~,,~~~~,~~~~,~~~~1~~,~,~~~~1Time
2.00
4.00
6.00
2: c6 Sulfonate
Methanol Wash
(PFHS)
080103A-2008 Sm (Mn, 2x3)
9.15 525
I
8.00
I
v
02-Aug-2003 04:59:21
LCNSIMS #6
MRM of 4 Channels ES-
413> 369
5.39e3
A
Area
""\
10.00
12.00
02-Aug-2003 04:59:21 LC/MS/MS #6
MRM of 4 Channels ES399 > 80
O~,...,,...,....,,,..,..,.,.,..,~...,,...,....,....,~...,...,~Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
Methanol Wash
(PFOS)
080103A-2008 Sm (Mn, 2x3)
MRM of 4 Channels ES-
Exygsn Research, 3058 Research Drive, State College, PA 16801
000304
Quantify Sample Report Study No .:L34910, Sot No.:080103A,
Ext.Dats:08/01/03,
AnalystrK.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\M4sslynx\Fluoroch~cals.PRO\S~l~DB\O8OlO3A Sun hug 03 07:25:44 2003 P:\Data\LCMSMS6\blasslynx\FluorochamicalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
----
Sun hug
------l----__-__------------~----
03 Oi'r32:25
2003
Name: 080103A-2008 Text :
.: PFOSA
klethanol Wash
180103A-2008 100-I
Sm (Mn, 2x3)
Page 16
Decatur BC BC 080103
----------a___
I
-Aug-2003 04:59:2
LC/MS/MS #
MRM of 4 Channels ES,
9.?3
498> 7t
Oxygen Research, 3058 Research Drive, Stats College, PA 16801
000305
Quantify Sample Report
Study No.:L34910,
Set Nb .:080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
saIllQ1e List:
Last modified: Method: Last modified: Job Code:
P:\Data\LCMISMS6\bfasslyPx\Bluoroch~cals.PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25 2003
Page 17
Decatur BC BC 080103
Name: 080103A-2009 Text :
1: C8 Acid (PFOA)
Reagent Blank
080103A-2009 Sm (Mn, 2x3)
100-J
b
%-
OW,
.i-. , , , , Y., , ,,,, f: I, ,>Time
2.00
4.00
6.00
2: C6 Sulfonate
Reagent Blank
(PFHS)
02-Aug-2003 05:20:57 LC/MS/MS #6
MRM of 4 Channels ES413s369 1.71e4 Area
9.10 518
8.00
10.00
12.00
02-Aug-2003 05:20:57
I
LC/MS/MS #6
MRM of4 Channels ES-
%-
0 ,,,,,~,~,,,,,~,~~.,,~,~~r,~,~,,.~~,~.,~,.~~.r~~~~,~~~~,~~~~ITime
2.00
4.00
6.00
8.00
3: C8 Sulfonate
Reagent Blank
(PFOS)
080103A-2009 Sm(Mn,2x3)
10.00
12.00 _
02-Aug-2003 O&20:57 LC/MS/MS #6
MRM of 4 Channels ES-
0 ,~,,,,,,,,,,~~,,,,,,,,,,r~~,~,~~~~,~~~~,,~,~,~~~.,,~~.r,~.,ITime
2.00
4.00
6.00
8.00
Exygen Research, 3058 Research Drive, State College, PA 16801
10.00
12.00
000306
Quantify Sample Report
,d Study No.:L34910,
Set No.:080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~~S6\Masslynx\Fluorocb~ca~s.PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44
2003
P:\Data\LBrlSMS6\Masslynx\FluorochemiealB\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:32:25
2003
Page 18
Decatur BC BC 080103
Name: 080103A-2009 Text:
4: PFOSA
Reagent Blank
080103A-2009 Sm (Mn, 2x3)
C2-Aug-2003 05.:20:57
LX/MS/MS #6
MRM of 4 Channels ES-
9.93
498 > 78
747
11.84
i
O'~~~~,~`~~,~~~~,~~~~,~~~~,~~~~,,~,,,~,,,,,,,,,,.,,,,,,,,,,,,,
2.00
4.00
6.00
8.00
10.00
Time 12.00
ExVoen Research, 3058 Research Drive, Stat- College, PA 16801
---------_
--I_--
----e-1111-------__--
Quantify Saarplrr Report
w
Study No.:L34910,
Set No.: 080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\~S6\bsslynx\Fluoroch~cals.PRO\S~leDB\O8O~O3A
Sun Aug 03 07:25:44
2003
P:\Data\LCMSMS6\Masslynx\Fluorochamicala\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 19
Decatur BC BC 080103
Name: 080103A-2010 Text:
1: C8 Acid (PFOA)
Reagent Spk A, 50 rig/L
080103A-2010 Sm (Mn, 2x3)
02-Aug-2003 05:42:42 LC/MS/MS #6
MRM of 4 Channels ES413>369 1.12e5 Area
1: C6 Sulfonate
(PFHS)
qeagent Spk A, 50 rig/L
180103A-2010 10
Sm (Mn, 2x3)
Time 12.00
02-Aug.2003 05:42:42
LC/MS/MS #6
MRM of 4 Channels ES-
8.96
399 > 80
345i
I.9834
Area
L
2.00
4.00
6.00
3: C8 Sulfonate
(PFOS)
Reagent Spk A, 50 rig/L
080103A-2010 10
Sm (Mn, 2x3)
02-Aug-2003 05:42:44 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.21 e4 Area
2.00
4.00
Time
6.00
8.00
1o:oo
12100 J
Oxygen Research, 3058 Research Drive, State College, PA 16801
000308
Quantify Sample Report
w Study No.:L34910,
Set No,: 080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSbIS6\~sslyPx\Fluoroch~cals.PRO\S~leDB\O80103A
Sun Aug 03 07:25:44 2003
P:\Data\LCMSMS6\Masslynx\Fluorochamicals\Decatur
Sun Aug 03 07:ll:SS
2003
Printed:
Sun Aug 03 07:32:25 2003
Page 20
Decatur BC BC 080103
Name: 080103A-2010 Text :
: PFOSA
leagent Spk A, 50 rig/L
180103A-2010 Sm (Mn, 2x3)
-I % i
,
02-Aug-2003 05:42:44
LCYMSIMS #6
MRM of 4 Channels ES-
9.90
498 > 78
675C
3.52e4
Area
O'..,,,,,l',,,.`,`,~`,,l,`,.`,,,,',,,"',,',,.,',~
Time
2.00
4.00
6.00
8.00
10.00
12.00
-gOA Research, 3058 Research Drive, State College, PA 16801
000309
-----
---
v-e----
-----_
Quantify Sample Report
q&J Study No.: L34910, Set No.:080103A,
Ext.Data:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: irob Code:
P:\Data\LQaSMS6\ManslyPx\FluorochemicalP\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\~SMS6\MasslyPx\Fluorochemicals.PRO\Met~B\Decatur
Sun Aup 03 07:11:59 2003
Page 21
Decatur BC BC 080103
Printed: -----------------------
Sun Aug 03 07:32:25
2003 --M---w----
--w------_
Name : 080103A-2011 Text:
L: C8 Acid (PFOA) Reagent Spk B, 500 ng./L
080103A-2011 Sm (Mn, 2x3)
9.15 163063
02-Aug-2003 06:04:24
LCiMS/MS #6
MRM of 4 Channels ES413 > 369 9.90e5 Area
m
Time I
2.00
4.00
6.00
8.00
10.00
12.00
!: C6 Sulfonate (PFHS) Reagent Spk B, 500 rig/L
02-Aug-2003 06:04:23/
080103A-2011 10
Sm (Mn, 2x3)
6.99 31000
%-
I: C8 Sulfonate (PFOS) qeagent Spk B, 500 rig/L
380103A-2011
`OO-4
%I-,I
Sm (Mn, 2x3) 2.00
9.25 1758: I3L-
02-Aug-2003 06:04:23
LC/MS/MS #6
MRM of 4 Channels ES> 99
4991.05e5 Area
Time
8.00
10.00
12.00 ,
Oxygen Research, 3058 Research Drive, State College, PA 16801
_II_ .._.
ll--_------- -
QOO31Q
----
-----
Quantify Sanr~le Report
u
Study No.:L34910,
Set No .:080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Sampls List: Last modified: Method: Last modified: Job code:
P:\Data\LCM~S6\Masslynx\Pluoroch~cals.PRO\S~l~D~\O8OlO3A
Sun Aug 03 07:25:44
2003
P:\Data\LCbl~S6\Masslynx\Fluorochsmicals.PRO\Met~B\D~catur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 22 Decatur BC BC 080103
Name: 080103A-2011 Text :
4: PFOSA
Reagent Spk 8,500 rig/l
080103A-2011 100-j
Sm (Mn, 2x3)
%-
0%Aug-2003 06:04:23
LCNSNS #6
MRM of 4 Channels ES-
9.89
498> 78
3.52e5
Area
0 "","","","","","","","","",
, I , 1 , , , ,Time
2.00
4.00
6.00
8.00
10.00
12.00 _
Exyrren Research, 3058 Research Drive, State College, PA 16801
.""-.
..-
.._.
"-.~--_--
."-
000311
Quantify
Sam&i
Report
44 Study No.:L34910,
Set No.. -080103A, Ext.Date:08/01/03,
Analyst:K.Risha
Page 23
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LCW~S6\~sslynx\FluorochamicaB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
------_----
Sun Aug 03 07:32:25
2003
---
------------
-------
------
Name: 080103A-2012 Text :
1: C8 Acid (PFOA)
KC072503-1,25 rig/L Standard
080103A-2012 Sm (Mn, 2x3)
.
02-Aug-2003 06:26:1 C
LC/MS/MS #6
MRM of 4 Channels ES-
I
9.14
413>369
982C I
5.69e4
Area
\,& 2: C6 Sulfonate
(PFHS)
XCO72503-1,25 rig/L Standard
080103A-2012 lOO-
Sm (Mn, 2x3)
%-
I v 10.00
Time 12.00
02-Aug-2003 06:26:1 C
LC/MS/MS #6
MRM of 4 Channels ES-
8.99
399 > 80
1.13e4
Area
0 ,,,#.r*
I , I . I . , I I I I I Time
2.00
4.00
6.00
8.00
10.00
12.00 _
3: C8 Sulfonate
XCO72503-1,25
(PFOSI
rig/L Standard
080103A-2012 100-
Sm (Mn, 2x3)
%-
02-Aug-2003 06:26:1 t
Lcnns/Ms #6
MRM of 4 Channels ES-
9.25
499 > 9s
5.93e3
Area
rllwf
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College,
PA 16801
Quantify
Sample Report
\\r~ Study No.:L34910,
Set No.: 080103A,
Ext.Date:08/01/03,
Analyst:X.Xisha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\Fluorochemicals.PXO\s~leDB\O~OlO3A
Sun Aug 03 07:25:44 2003
P:\Data\LQ3SWS6\~sslynx\Fluorochsmicals.PRO\MethDB\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:32:25
2003
Page 24
Decatur BC BC 080103
Name: 0801031-2012 Text :
4: PFOSA
XCO72503-1,25
rig/L Standard
080103A-2012 100-
Sm (Mn, 2x3)
%-
02-Aug-2003 06:26:1 t)
LClMShlS #6
MRM of 4 Channels ES-
9.88
498 > 78
2.01e4
Area
0 "","","'1,"","'~,"","","","",",
I , , , , , , , Time
2.00
4.00
6.00
8.00
10.00
12.00
me=
Research,
3058 Research
Drive, State College,
PA 16801
Quantify
Sample Report
9b*1/ Study No.:L34910,
Set NO.: 080103A,
EXt.Date:08/01/03,
Analyst:R.Risha
Sanlpls List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochsmicals.PRO\S~leDB\OSOlO3A Sun Aug 03 07:25:44 2003 P:\Data\L(SM~S6\~sal~\Fluorochemi\D~catur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 25
Decatur BC BC 080103
Name: 0801031-2013 Text :
: C8 Acid (PFOA) -34910-5 Spk C, 5000 rig/L, DF=lO
380103A-2013 10
Sm (Mn, 2x3)
9.13 157971
02-Aug-2003 06:47:56j LC/MS/MS #6
MRM of 4 Channels ES-
413>369 9.32e5 Area
!: C6 Sulfonate (PFHS) L34910-5 Spk C, 5000 rig/L, DF=lO
080103A-2013 10 ]#
Sm (Mn, 2x3)
%
,,,,,,,,,,,,,,,,
I ,,,,,,,,,,,,,,,,,,,,,,,,,,
2.00
4.00
6.00
3: C8 Sulfonate (PFOS) L34910-5 Spk C, 5000 rig/L, DF=lO
080103A-2013 100-
Sm (Mn. 2x3)
%-
0 ,,"~,,,,,,,,,,,,,~,,`,`,."`,"","","",
2.00
4.00
6.00
8.98 30746
02-Aug-2003 06:47:5 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.76e5 " Area
8.00
499 > 99 1.36e5 Area
1 c , I I I I , I I 1 Time
8.00
10.00
12.00
RW!Wn Research, 3058 Research Drive, State Collage, PA 16801
000324
Quantify Sample Report
,d Study No.:L34910,
Set No.. *OBO103A, Ext.Date:08/01/03,
Analyst:R.Risha
Sample List: Last modified2 Method: Last modified: Job Coda:
P:\Data\LCab~S6\blas8l~\Fluotochamicals.PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44 2003 P:\Data\L~SMS6\Masslynx\FluorochamicalB\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:32:25
2003
Page 26
Decatur BC BC 080103
Name: 080103A-2013 Text :
r: PFOSA
-3491 O-5 Spk C, 5000 rig/L, DF=lO
180103A-2013 10
Sm (Mn, 2x3)
%
I
i
O'~~~,,`~~~,`~",~`,~,`~~~,~~~~,~~~~,~~,',~~~~,`~~
2.00
4.00
6.00
8.00
02-Aug-2003 06:47:56
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 79517 ,
498 > 78 4.18eS
Area
L10.00
lime 12.00 1
ExyOen Research, 3058 Research Drive, State College, PA 16601
0003l5
Quantify SamQls Report
A,& Study No.:L34910,
Set No.: 080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\bsslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\Masslyax\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 27
Decatur SC BC 080103
Name: Text:
080103A-2014
1: C8 Acid (PFOA)
IL3491 O-1 0 Spk D, 5000 rig/L, DF=lO
080103A-2014 Sm (Mn, 2x3)
%-
02-Aug-2003 07:09:35/ LCNSIMS #6
MRM of 4 Channels ES413> 369 9.88e5 Area
2.00
4.00
6.00
: C6 Sulfonate
(PFHS)
-34910-10 Spk D, 5000 rig/L, DF=lO
380103A-2014 loo-
Sm (Mn, 2x3)
8.00
8.98 3219: 2
10.00
12.00 _
02-Aug-2003 07:09:3!j LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.89e5 Area
L
2.00
4.00
6.00
3: C8 Sulfonate
(PFOS)
134910-10 Spk D, 5000 rig/L, DF=lO
080103A-2014 lOO-
Sm (Mn, 2x3)
%-
0 ,~,,,,,,,,,,,,,~,,~,,,,,,,,,,,,,,,,~,,,,,,,,,~,,,,,,,,,,,.lTime
!
2.00
4.00
6.00
A-8.00
10.00
Time 12.00
9.25 _ 26935
02-Aug-2003 07:09:35 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.62e5 Area
8.00
10.00
12.00
%Wen Research, 3058 Research Drive, State College, PA 16801
00032.6
Quantify
Sample Report
\J Study No.:L34910,
Set No.: 080103A, E&.Date:08/01/03,
Analyst:K.Risha
Page 28
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\Fluoroch~cal~.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003
P:\Data\LBISMS6\Masslynx\Fluorochemicalscatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Rug 03 07:32:25
2003
-----
----------I_----
-------------_-
-----
Name: 0801031-203.4 Text :
4: PFOSA
-3491 O-l 0 Spk D, 5000 rig/L, DF=lO
180103A-2014 Sm [Mn. 2x3)
I
.
r
02-Aug-2003 07:09:36
LCNSIMS #6
MRM of 4 Channels ES-
9.09 8221; !
498 > 78 4.27e5
Area
O'.,.,,,,~,,,,`.,.,..,,.,,,,,.,,,,,,,,',,,',,,,l.~
L-
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
Quantify Sax&s Report
t& Study No.:L34910,
Set NO.: 080103A,
mct.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQHSMS6\~sslyax\Pluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\Masslynx\FluorochamicalsB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 29
Decatur BC BC 080103
Name: 080103A-2015 Text :
* C8 Acid (PFOA)
-34910-l 1 Spk E, 5000 rig/L, DF=lO
380103A-2015 10
Sm (Mn, 2x3)
0x2 1
2.00
4.00
6.00
\14 2: C6 Sulfonate
(PFHS)
L34910-11 Spk E, 5000 rig/L, RF=10
080103A-2015 lOO-
Sm(Mn,2x3)
%-
9.13 18766t 5
02-Aug-2003 07:31 :17 LC/MS/MS #6
MRM of 4 Channels ES413> 369 l.lle6 Area
L-_-
8.00
10.00
Time 12:oo
02-Aug-2003 07:31: 17
LC/MS/MS #6
MRM of 4 Channels ES-
8.96
399> 80
1 .SOe5
Area
2.00
4.00
6.00
: C8 Sulfonate
(PFOS)
-34910-l 1 Spk E, 5000 rig/L, DF=lO
)80103A-2015 10
Sm (Mn, 2x3)
8.00
9.27 33638:
10.00
12.00 J
02-Aug-2003 07:31 :17
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.9566 Area
mgen Research, 3056 Research Drive, State Collage, PA 16601 "--^...-.1- -..- -.-
--------_
-------
-------------__--
Quantify
Sample Report
,,& Study No.:L34910,
Set No.. -080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 30
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SMS6\~ss~ynx\Fluoroch~cals~PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44
2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\~et~B\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:32:25
2003
----------------__I-----------___________I_
-------------___-_
Name: 080103A-2015 Text :
I: PFOSA
-34910-I 1 Spk E, 5000 g/L,
DF=lO
380103A-2015 10
7
% -i
Sm (Mn, 2x3)
02-Aug-2003 07:31 :l'
LC/MS/MS #I
MRM of 4 Channels ES-
9.88
15509t 3
498 > 71 7.93e!
Are:
O',,,`,~.",.,~`,,.",,,`,,`,~`,.".,,,,',,',,,,,,
L.
Time
t
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
ooam9
Quantify
Sanlple Report
w Study No.:L34910,
Set No. :080103A,
Ext.Date:08/01/03,
Analyst:X.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\~S6\Masslynx\Fluorochamicals.PRO\S~leDB\O6OlO3A
Sun Aug 03 07:25:44 2003
P:\Data\LQHSMS6\Masslyax\Fluorochemicalsr
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 31
Decatur flC BC 080103
Name: 000103A-2016
Text :
1: CB Acid (PFOA) L34910-20 Spk F, 5000 rig/L, DFdO
080103A-2016 loo-
Sm (Mn, 2x3)
%-
9.13 1790901
02-Aug-2003 075254 LCIMSNS #6
MRM of 4 Channels ES413> 369 1.02e6 Area
0 ,,,.;7-..,,~...,~,..,,~~,,...~,.~~.,..~.,~..~~~.~,..~.,.~.~,Time
2.00
4.00
6.00
: C6 Sulfonate (PFHS) -3491 O-20 Spk F, 5000 rig/L, DF=lO
180103A-2016 `O(+
Sm (Mn, 2x3)
8.00
8.96 3234:
10.00
12.00
02-Aug-2003 07:52:54 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.91e5 Area
O',,`,,,,~,,,,,,,`,,`,,.~`,,,",`,',,",,,,,'~ L 2.00 4.00 6.00
3: C8 Sulfonate (PFOS) L34910-20 Spk F, 5000 rig/L, DF=Y 0
080103A-2016 100-
Sm (Mn, 2x3)
%-
8.00 9.25
,,I, , 10.00
b - 1 Time 12.00
02-Aug-2003 07:52:54 LCIMSIMS #6
MRM of 4 Channels ES499 > 99 4.1385 Area
, I , I , . . I j 1 Time
10.00
12.00
Oxygen Research, 3056 Research Drive, State College, PA 16801
000320
Quantify Sample Report
,14 Study No.:L34910,
Set No.. l 080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
SamQle List: Last modified: Method: Last modified: Job Code:
P:\Data\M3HSMS6\nbasslynx\Fluoroch~cals.PRO\S~~aDB\O8OlO3A
Sun Rug 03 07:25:44
2003
P:\Da~a\LCMSIS6\Masslyrur\FluorochamicalS.PRO\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Printed:
-------A--
Sun Aug 03 07:32:25
2003
----------__-------~----
Name: Text:
0801031-2016
Page 32
Decatur EC EC 080103
---
tL34910-20 Spk F, 5000 rig/L, DF=IO
080103A-2016 lOO-
Sm (Mn, 2x3)
%-
02-Aug-2003 075254
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 z 78
5.19e5
Area
, , , , , I , , , Time
10.00
12.00
Oxygen Research, 3058 Research Drive, State Collage, PA 16801
w-w----
--------
-----
---
Quantify Sample Report
-,+, Study No.:L34910,
Set No.: 080103A,
Ext.Dats:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Coda:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~~eDB\O8OlO3A
Sun Aug 03 07:25:44
2003
P:\Data\LCMSMS6\Masslynx\Fluorochesnicals.PRO\Mat~B\D~catur
Sun Aug 03 07:11:59 2003
Printed:
e---e------
Sun Aug 03 07:32:25
2003 ------------------------~-_-
Nams: 0801031-2017 Text :
1 : C8 Acid (PFOA)
(CO72503-2,50 rig/L Standard
180103A-2017 10 9
Sm (Mn, 2x3)
9.13 181901
---m-m-
page 33 Decatur BC BC 080103
02-Aug-2003 08:14:41 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 1 .lOe5 Area
2.00
4.00
6.00
8.00
`IlId 9I: C6 Sulfonate
i : KO72503-2,50
(PFHS)
rig/L Standard
180103A-2017 10
Sm (Mn, 2x3)
02-Aug-2003 08:14:41/
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
3449
2.06e4
Area
2.00
4.00
6.00
i: C8 Sulfonate
KC072503-2,50
(PFOS)
rig/L Standard
080103A-2017
`Oo7
% 1
Sm (Mn, 2x3)
02-Aug-2003 08:14:41
LCIMSNS #6
MRM of 4 Channels ES-
9.24
499 z 99
2233
1.34e4
Area
I_;;, - 10.00
Time 12.00
-en
Research, 3058 Research Drive,
Stata College,
PA 16801
088322
--
QUantify Sample Study No .:L34910,
-------------_
Report Set No.:080103A,
Ext,Dats:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\blasslynx\Fluor4ch~cals.PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44 2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\~t~B\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Sun Aug 03 07:32:25
2003
w--m--
-------
------
-w--I__----p_
Name: 080103A-2017 Text :
4: PFOSA
(XCO72503-2,50 rig/L Standard
080103A-2017 Sm (Mni 2x3)
Page 34
Decatur BC BC 080103
02-Aug-2003 08: 14:41[ LC/MS/MS #6
MRM of 4 Channels ES498 > 78 4.1 Oe4 Area
Time 12.00
Oxygen Research, 3058 Research Drive, State College, PA 36801 ."_ -----
000323
-----
-I_-------
Quantify Sample Report
\&
Study No.:L34910,
Set No.: 080103A,
Ext.Data:08/01/03,
Analyst:X.Risha
Page 35
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Msssl~\Fluoroch~cals.PRO\S~leDB\O~DlO3A
Sun Aug 03 07:25:44 2003
P:\Data\L~~S6\~sslyIw\Fluoroch~cals.PRO\Met~B\Decatur
Sun Aug 03 07:ll:SS
2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:32:25
2003
-------___
--------------------------------~----
------
Name: 080103X-2018
Text :
1: C8 Acid
L3491 o-5
(PFOA)
180103A-2018 10
Sm (Mn, 2x3)
9.15 115451
02-Aug-2003 08:36:27 LC/MS/MS #6
MRM of 4 Channels ES413>369 6.67e5 Area
i
2.00
4.00
6.00
8.00
!: C6 Sulfonate
L3491 o-5
(PFHS)
02-Aug-2003 08:36:2
080103A-2018 Sm (Mn, 2x3)
10
8.98
4534
2.00
4.00
6.00
8.00
10.00
12.00 I
3I: C8 Sulfonate
-3491 o-5
(PFOS)
)80103A-2018 Sm (Mn, 2x3)
9.27 1.. 60613
02-Aug-2003 08:36:2? LC/MS/MS #6
MRM of 4 Channels ES499358A>ere59a9
Time
2.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
'cc
000321
-w---_II
-----A
--1_-
-v---1_--
----
Quantify Sample Report
\Ir, Study No.:L34910,
Set No.: 080103A,
Ext.Date:08/01/03,
Analyst:X.Riaha
Page 36
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~~S6\bssl~\Fluoroch~cals.P~\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\MasslyPx\Fluorochemicals\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
--WV--
Sun Aug 03 07:32:25
2003
--------------------------------
Name: Text:
0801031-2018
--_-_--
----
: PFQSA
-3491 o-5
380103A-2018 Sm (Mn, 2x3)
9.90
12188:
02-Aug-2003 08:36:2;
LC/MS/MS #f
MRM of 4 Channels ES-
496> 7E
2
6.28e5
Area
I
Time
12.00
Exyoen Research, 3058 Research Drive, State College, PA 16801
Quantify
sml.9
Rsport
\ulJI Study No.:L34910,
Set No .:080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Wethod: Last modified:
Job Code:
P:\Data\LCM~S6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LCblSMS6\Masslynx\FluorochemicalB\Decatur Sun Aug 03 07:11:59 2003
Printed:
-m--v-
Sun Aug 03 07:32:25
--------------
2003 -m---e---
-------m
Name: 080103A-2019
Text :
1: C8 Acid (PFOA) rI-3491 O-5 Rep
I
(180103A-2019 Sm (Mn, 2x3)
lOO-4
`2
,
%1 I
I-
%& 2: C6 Sulfonate
L3491 O-5 Rep
(PFHS)
080103A-2019 Sm (Mn, 2x3)
Page 37
Decatur BC BC 080103
02-Aug-2003 08:58:12 LC/MS/MS #6
MRM of 4 Channels ES-
413>369 4.81e5 Area
Time 12.00 _
02-Aug-2003 08:58:12 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 2.09e4 Area
3 : C8 Sulfonate
-3491 O-5 Rep
(PFOS)
380103A-2019 Sm (Mn, 2x3)
9.25 51074
Time 12.00 ~
02-Aug-2003 08:58:12 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 3.06e5 Area
, , , , , , , , , , , `Time
10.00
12.00
-gOa Research, 3058 Research Drive, State College, PA 16801
WO3Xi
.
"_
_-_.---
-.-.
._
--.--
_
._-,,__
"--_
.
quantify
saxuple Report
,&
study
NO.:L34910,
Sat No.: 060103A, Ext.Date:06/01/03,
Analyst:K.Risha
page 38
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Massl~\Fluoroc~cals.PRO\S~leDB\OSOlO3A
Sun Aug 03 07:25:44
2003
P:\Data\LCM~S6\Masslynx\Fluoroch~cals.PRO\MethDB\Decatur
Sun Aug 03 07:11:59
2003
Decatur BC BC 080103
Printed:
v----e-
Sun Aug
_I_-----__----------------------------_--
03 07:32:25
2003
Name: 0801031-2019 Text :
4: PFOSA
L3491 o-5 Rep
I(180103A-2019 Sm (Mn, 2x3)
9.88 13358:
02-Aug-2003 08:58:1:
LCYMWMS #1
MRM of 4 Channels ES-
498 > 7t
3
6.93e!
Are:
2.00
4.00
I
Time
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
008327
---
----_-
--------
---------
Quantify Sample Report
w Study No.:L34910,
Set No.. -080103A, Ext.Date:08/01/03,
Analyst:K.Risha
Page 39
Sample List: Laat modified: Method:
Last modified: Job Code:
P:\Data\L~SMS6\Wasslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3A
sun Aug 03 07:25:44
2003
P:\Data\LCWSblS6\Wasslynx\BluorochemfcslB\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:32:25 2003
--m-e---------
---------------------------------_-
---
Name: 080103A-2020 Text :
.: C8 Acid (PFOA)
-3491 o-1 0
380103A-2020
lo?
Sm (Mn, 2x3)
02-Aug-2003 09: 19:59 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 1.13e6 Area
2.00
4.00
6.00
8.00
10.00
12.00
)* C6 Sulfonate
i3491 o-1 0
(PFHS)
02-Aug-2003 09:19:5
080103A-2020 10
Sm (Mn, 2x3)
8.97 10896
Area
v
Time /
2.00
4.00
6.00
8.00
10.00
12.00 I
3: C8 Sulfonate
L3491 o-1 0
(PFOS)
,080103A-2020 IOO-
Sm (Mn, 2x3)
%-
02-Aug-2003 09:19:5I LCiMSlMS #E
MRM of 4 Channels ES499 > 99 5.38e5 Area
, I I I l , I ( I ,lTime
10.00
12.00
Eyygen Research, 3058 Research Drive, State College, PA 16801
Quantify
Sample Report
w Study No.:L34910,
Set No.. l 080103A, E%t.Date:08/01/03,
Aualyst:K.Rieha
Santpls List: Last modified: Method: Last modified: Job Code:
P:\Data\LC41~S6\bsslylur\Fluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LCM~S6\Massl~\Fluoroch~cals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25 2003
Page 40
Decatur BC BC 080103
Name: 080103A-2020 Text :
4: PFOSA
L3491 (J-1 0
080103A-2020 100-
Sm (Mn, 2x3)
%-
02-Aug-2003 09:19:59
LWMWMS #6
MRM of 4 Channels ES-
9.91 _ 133763
498 > 78 6.89e5
Area
1 t I , r I , , 1 Time
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000329
------
Quantify Sample Report
,4 Study No.rL34910,
Set No.. *000103A, Ext.Date:08/01/03,
--Analy8t:K.Risha
-Page 41
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LQb~S6\Maasl~\Fluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\L~SMS6\Ma~al~\FluorochamicaB\Decatux Sun Aug 03 07:11:59 2003
Decatur SC BC 080103
Printed: ----
Sun Aug 03 07:32:25 2003 ----------_---------A--
Name: 080103A-2021 Text :
----__l--------_--_
--me-------
: C8 Acid (PFOA)
-3491 O-l 0 Rep
)80103A-2021 10
Sm (Mn, 2x3)
9.13 16782 6
02-Aug-2003 09:41:4j
LC/MS/MS #6
MRM of 4 Channels ES413>369 9.66eS Area
: C6 Sulfonate
-3491 O-l 0 Rep
(PFHS)
)80103A-2021 lo&
Sm (Mn, 2x3)
I
8.98 1299s
Time 12.00
02-Aug-2003 09:41:47 LWMWMS #6
MRM of 4 Channels ES399 > 80 7.94e4 Area
2.00
4.00
6.00
8.00
3: C8 Sulfonate
IL3491 O-l 0 Rep
(PFOS)
02-Aug-2003 09:41:47/
080103A-2021 `Oo-2
Sm (Mn, 2x3)
2.00
4.00
6.00
8.00
10.00
E%ygen Research, 3058 Research Drive, State College, PA 16801
12.00
---------___-__1--___I-----------
Quantify Sanlple Report
,4 Study No.:L34910,
Set No.: 080103A, Ext.Date:08/01/03,
?tnalyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\bssl~\Fluoroch~ca~s.PRO\S~leDB\O60103A Sun Aug 03 07:25:44 2003 P:\Data\L~SMS6\Mrrssl~\~luorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
--
Page 42
Decatur BC BC 080103
Name : 000103A-2023 Text :
4: PFOSA
L3491 O-l 0 Rep
080103A-2021 loo-
Sm (Mn, 2x3)
%-
02-Aug-2003 09:41:47
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 191201
498> 78 9.92e5
Area
0 ~,,,,,,~,,~,,,,,,,,,,~~~,~,,,,,~,,,~~~~,~~~~,.~~~~~~~,~~~,;Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000331
Pm-------
--
m-v--
Quantify Sample Report
`NY Study No .:L34910,
Set No.:080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L(=blSMS6\Massl~\Fluoroch~ca~s.PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44 2003
P:\Data\LCMSMS6\Masslynx\Fluorochamicsls.PRO\Met~B~Dacatur
Sun Aug 03 07:11:59
2003
Page 43
Decatur RC BC 080103
Printed:
Sun Aug 03 07:32:25
2003
-me--
-----------
----------cI_-------------
---
Name:
Text:
080103A-2022
: CB Acid (PFOA)
(CO72503-3, 100 rig/L Standard
)80103A-2022 lo9
Sm (Mn, 2x3)
%
02-Aug-2003 10:03:27j
LC/MS/MS #6
MRM of 4 Channels ES-
9.15
413> 369
2.02e5
Area
i
2.00
4.00
10.00
Time 12.00
!: C6 Sulfonate
KO72503-3,100
(PFHSI
rig/L Standard
380103A-2022 10
Sm (Mn, 2x3)
02-Aug-2003 10:03:27j
LChK/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
656C
3.80e4
Area
2.00
4.00
6.00
8.00
3: C8 Sulfonate
XCO72503-3,100
(~~0s)
rig/L Standard
080103A-2022 10
Sm (Mn, 2x3)
02-Aug-2003 10:03:2?
LC/MS/MS #6
MRM of 4 Channels ES-
9.25
499 > 99
3634
2.23e4
Area
2.00
4.00
6.00
L-;,
Time
12.00
RJWWn Rssawch, 3058 Research Drive, Stats Collage, PA 16801
QOO332
-------------PI-
----
Quantify
Sample Report
q,d Study No. :L34910, Set No.: 080103A,
Ext.Date:08/01/03,
kralyst:K.Risha
Sample List: Last modified: Method:
Last modified:
Job Code:
P:\Data\LCMSWS6\Masalynx\Fluoroch~cals~PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44
2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
-Page 44
Decatur BC BC 080103
Name: 0801031-2022
Text :
4: PFOSA
IXCO72503-3,
100 rig/L Standard
080103A-2022 lOO-
Sm (Mn, 2x3)
%-
02-Aug-2003 10:03:27j
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 _ 14698
498 > 78 7.86e4
Area
0 "","l',"","","","","","","","'
Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
-------e---P-
---
----
----
Quantify Sample Report
w
Study No. :L34910, Set No .:080103A,
Bxt.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\Lc=MSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\OSOlO3A sun hug 03 07:25:44 2003
P:\Data\LcZIISMS6\Massl~\Fluoroch~cals.PRO\MethDB\Decatur sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 45
Decatur BC BC 080103
Name: Text:
080103A-2023
1: C8 Acid (PFOA)
XCO72503-4,250 rig/L Standard
080103A-2023 Sm (Mn, 2x3)
lOO-
9.13
%-
1 0 "8 r,=
* ,,r f 8 ,(I 2.00
r I I,8 8 n ,,I 4.00
r 8 I,`) 6.00
8 ,,I'#
tJ 2: C6 Sulfonate
(PFHS)
XCO72503-4,250 rig/L Standard
080103A-2023 100-
Sm (Mn, 2x3)
(,)`I
r
8.98
%-
02-Aug-2003 10:25:1 C LC/MS/MS #6
MRM of 4 Channels ES-
413>369 4.72e5 Area
, , , I , , I a I , Time
10.00
12.00
02-Aug-2003 10:25:1 C
LC/MS/MS #6
MRM of 4 Channels ES399 > 80 9.02e4 Area *
o- ~"`,`."`,"")`.","","","","",
, I I I 1 , , I 1 . 1 Time
2.00
4.00
6.00
8.00
10.00
12.00 I
1: C8 Sulfonate
#CO72503-4,250
(PFOS)
rig/l Standard
080103A-2023 Sm (Mn, 2x3)
02-Aug-2003 10:25:1 C
LC/MS/MS #6
MRM of 4 Channels ES-
9.25
499 > 99
8965
5.15e4
Area
Time
2.00
4.00
6.00
8.00
10.00
12.00
wgen Research, 3058 Research Drive, State College, PA 16801
Quantify
Sample Report
w Study No.:L34910,
Set No.: 080103A, Ekt.Date:08/01/03,
Analyst:K.Risha
Page 46
SamOle List: Last modified: Method: Last modified: Job Code:
P:\Data\LOMS~S6\~ssl~\Fluorochemicals.PxO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LWSMS6\Masslynx\FluoroChsmicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:32:25 2003
----
---------------------------
---
--es---_
--
Name : 080103A-2023 Text:
4: PFOSA
IXCO72503-4,250
rig/L Standard
080103A-2023 Sm (Mn, 2x3)
02-Aug-2003 10:25:1( LCIMSNS #f
MRM of 4 Channels ES-
2.00
4.00
6.00
8.00
10.00
12.00
ExyrJen Research, 3058 Research Drive, State College, PA 16801
Q00335
--
---------
---------------------
Quantify Sruqple Report
\d Study No.:L34910,
Set No.: 080103A, Ext.Date:08/01/03,
Analyst:K.Risha
Sample List:
Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\bs8l~\Fluoroch~cals.PRO\S~leDB\OSOlO3A
Sun Aug 03 07:25:44
2003
P:\Data\LCbIS~B\Masslynx\Fluorochemicals.PRO\MethDB\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Naalm : 0801031-3024 Text:
Page 47
Decatur BC BC 080103
)80103A-2024 10
Sm (Mn, 2x3)
9.12 47341r 5
02-Aug-2003 t 0:47:04 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 2.88e6 Area
i--
Time
L
2.00
4.00
6.00
8.00
10.00
12100
U& 2: C6 Sulfonate L3491 o-1 1
(PFHS)
080103A-2024 100-
Sm (Mn, 2x3)
%-
02-Aug-2003 10:47:05
LC/MS/MS #6
MRM of 4 Channels ES-
8.96
399 > 80
1.03e5
Area
0 "","","",`11',"","","",`l","'
, , I 1 , , , , 1 Time
1
2.00
4.00
6.00
8.00
10.00
12.00
: C8 Sulfonate -3491 o-1 1
(PFOS)
)80103A-2024 Sm (Mn, 2x3)
9.25 3-235467:
02-Aug-2003 10:47:04 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.27e7 Area
O1,,,,,,,,,,,,,,,,~~,,~,~,~,,,,,~,,.,,,,,,,,,,,St,.,..,.,.,,,,Time
2.00
4.00
6.00
8800
10.00
12.00
Exygsn Research, 3058 Research Drive, State College, PA 16801
,-1
-.--. --
-------_-_
--u---w-
----
Quantify Sample Report
14 Study No.:L34910,
Set No.: 080103A,
Ext.Date:06/01/03,
Analyet:IC.Xisha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O8OlO3A
Sun Aug 03 07:25:44
2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cala.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Name: 08010311-2024 Text :
Page 46
Decatur BC BC 060103
L3491 o-1 1
080103A-2024 100-
Sm (Mn, 2x3)
%-
02-Aug-2003 10:47:05!
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 1215533
498 > 78 6.18e6
Area
0 ~,~~,l~/(,~rll,~ll.,~I'I,I.II,)I)/,IIIr,llll,lll
Time
2.00
4.00
6.00
a.00
10.00
12.00
ExVgen Research, 3058 Research Drive, State collage,
PA 16601
000337
Quantify
Sample Report
,,, Study No. zL349l.0, Set No.:080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 49
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCblSMS6\Masslynx\Pluoroch~cals.PRO\S~l~DB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\~et~B\Decatur Sun Auu 03 07:11:59 2003
Decatur BC BC 080103
Printed:
--e---w------
Sun Aug 03 07:32:25
-__-----
2003
-------
--w---_-----P
Name: 0801031-2025 Text :
1,: CB Acid (PFOA)
-3491 O-1 1 Rep
180103A-2025 1007
Sm(Mn,2x3)
%-
9.12 463017
02-Aug-2003 11:08:44) LC/MS/MS #6
MRM of 4 Channels ES413>369 2.77e6 Area
q& 2: C6 Sulfonate
(PFHS)
L3491 O-1 1 Rep
080103A-2025
I 10 01
Sm (Mn, 2x3)
I 8.96
Time 12.00
02-Aug-2003 11:08:44 LC/MS/MS #6
MRM of 4 Channels ES399>80 1.09e5 Area
3: CB Sulfonate
L3491 O-1 1 Rep
(PFOS)
080103A-2025 Sm t.Mn.2~3) ,
02-Aug-2003 11:08:4~
LC/MS/MS #t
MRM of 4 Channels ES-
9.26
499 > 95
1 .OOei
Are:
, I I I I , I I 1Time
2.00
4.00
6.00
8.00
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
--------
------v--m
----~-----------
---me--
Quantify Sample Report
,,ul Study No.:L34910,
Set No.: 080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 50
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCblSMS6\~ssl~\Fluoroch~cals.PRO\S~le~\OBOlO3A
Sun Aug 03 07:25:44
2003
P:\Data\L~fl3S6\Masslynx\Fluorochemicat~B\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC EC 080103
Printed:
Sun Aug 03 07:32:25
2003
-------
----------------------~
w----w--
-----------P--_
Name: 0801031-2025 Text :
4: PFOSA
(L3491 O-l 1 Rep
080103A-2025 lOc-
Sm (Mn, 2x3)
%-
02-Aug-2003 11:08:4d
LC/MS/MS #6
MRM of 4 Channels ES-
9.87 929771--
4982.78
4.73e6
Area
0 `~,~,~`~~,~~`~,.~~,,~,,,,,,,,,,,,,,,,,,,,,,,,,,,c....,.,,,,
2.00
4.00
6.00
a.00
1 oloo
Time 12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
"I.
-l-.,. ".
_,1.,,,1-111"----1 .-- ---
------
---------
------
__----~----_
Quantify Sample Report Study No.: L34910, Set No .:080103A,
Ea&.Date:08/01/03,
Analyst:K.Risha
SaIlple List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\SamgleDB\O80103A Sun Aug 03 07:25:44 2003 P:\Data\LQ3SMS6\Masslynx\Fluorochsmicals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 51
Decatur BC BC 080103
Name: 0801031-2026
Text :
1: C8 Acid (PFOA) L3491 O-20
080103A-2026 lOO-
Sm (Mn, 2x3)
%-
9.12 4042097
02-Aug-2003 11:30:2d LC/MS/MS #6
MRM of 4 Channels ES413>369 2.37e6 Area
0 ,,,,,,~,,,,,,,,,,,,,,,,,,,,,,,,,,.,,,,,,,,,,~~,~,,,,,,,,,,rTjme
2.00
4.00
6.00
2: C6 Sulfonate L3491 O-20
(PFHS)
080103A-2026 loo-
Sm (Mn, 2x3)
%-
8.00 8.96
10.00
12.00
02-Aug-2003 11:30:26 IX/MS/MS #6
MRM of 4 Channels ES399 > 80
1.41 e5
Area
0 `.`I~~`~,~`/(/,~~./`~,,,~~~./"~`,",~,
, , I , . I 1Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate L3491 O-20
(PFOS)
080103A-2026 10
Sm (Mn, 2x3)
9.25 418516
02-Aug-2003 11:30:26 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.35e6
I
2.00
4.00
6.00
8.00
Exygen Research, 3058 Research Drive, State College, PA 16801
10.00
12.00
000340
--
---------w-
----m-P
----w--m-
Quantify Sample Report
Study No.:L34910,
Set No .:080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 52
Samgla List:
Laot modified: Method: Last modified: Job Code:
P:\Data\LCM~S6\bIasslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\~sslynx\Fluorochgmica\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:32:25
2003
---------------------
------
-----
------
-----
Name: 06010311-2026
Text :
: PFOSA
.3491 O-20
)80103A-2026 Sm (Mn, 2x3)
02-Aug-2003 11:30:26
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 i341236:
4928.1A>Ore7ea86
Time
Oxygen Research, 3050 Research Drive, State College,
PA 16801
000341
--
-e---p
-----
------
e-v--
------
Quantify Sample Report
vd Study No.:L34910,
Set No .:080103A,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 53
Sample List:
Last modified: Method: Last modified: Job Code:
P:\Data\LQH~6\Maselynx\Fluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\L~SMS6\Massl~\Fluoroch~cals.PRO\~at~B\Dacatur Sun Aug 03 07:11:59 2003
Decatur Be BC 080103
Printed: -------
Sun Aug 03 07:32:25 2003 ---__------------------~
-_----^------------_--_-____
Name: 080103A-2027 Text :
,: C8 Acid (PFOA)
-3491 O-20 Rep
380103A-2027
10
% 1
Sm (Mn, 2x3)
L
\clr) 2: C6 Sulfonate
L3491 O-20 Rep
2.00 (PFHS)
080103A-2027 lOO-
Sm (Mn, 2x3)
%-
9.13 30120' 1.
02-Aug-2003 1152: 11 LCIMSIMS #6
MRM of 4 Channels ES-
413>13.7669e6 Area
8.00 8.97
10.00
Time 12.00
02-Aug-2003 11:52:11 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 9.68e4 Area
0 "","","","","","","","","","",""I"",
Time
2.00
4.00
6.00
8.00
10.00
12.00
3: C8 Sulfonate
113491 O-20 Rep
(PFOS)
080103A-2027 1001
Sm (Mn, 2x3)
%-
02-Aug-2003 11:52:11/ LCMNMS #6
MRM of 4 Channels ES499 > 99 1.68e6 Area
0 "","","","","","","",""I""
, I , , , I , 1 , I Time
2.00
4.00
6.00
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
QUO34~2
----
----------------L---I_--
---------
Quantify Sample Report
\& Study No.:L34910,
Set No.: 080103A, Ext.Date:08/01/03,
Analyst:R.Risha
Page 54
Sanrple List: Last modified: Method:
Last modified: Job Code:
P:\Data\L~SMS6\MasslyPx\Fluoroch~ca~s.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003
P:\Data\L~SMS6\Massl~\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Sun Aug 03 07:32:25
2003
-----111-----e-
------_--------------
---
Name: 080103A-2027 Text :
: PFOSA
-3491 O-20 Rep
)80103A-2027 100-
Sm (Mn, 2x3)
%-
0%Aug-2003 71:52:111
LCYMWMS #6
MRM of 4 Channels ES-
9.08
346884
498> 78 1.78e6
Area
0 ,~,,,,,,,,,,,,,,~,,,,,,,,,,,,,,,,,,,,,,,,,,,,,1.~
Time
2.00
4.00
6.00
8.00
10.00
12.00
wgen Research, 3058 Research Drive, State College, PA 1680%
WQ34-3
---w----m-
------------
P-B--
-----
Quantify Sample Report
\d Study No.:L34910,
Set No.: 000103A,
Ext.Date:08/01/03,
A.nalyst:K.Rislha
Page 55
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SblS6\Mas~~\Fluoroch~cala.PXO\S~l~DX\O8OlO3A Sun Aug 03 07:35:44 2003 P:\Data\L~SbIS6\Masslynx\FluorochemiB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: ---__--
Sun Aug 03 07:32:25 --------------e-w-
2003 -------------------
Name: 080103A-2028 Text :
.: C8 Acid
-3491 o-21
(PFOA)
180103A-2028 10
Sm (Mn, 2x3)
%
9.13
53261: 3
02-Aug-2003 12:13:52/ LCIMSNS #6
MRM of 4 Channels ES413>369 3.15e6 Area
:
!: C6 Sulfonate
L3491 o-21
(PFHS)
080103A-2028 Sm (Mn, 2x3)
L.
8.00
10.00
Time 12.00
8.98 36172`
02-Aug-2003 12:13:523 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 2.1 le5 Area
2.00
4.00
6.00
8.00
3: C8 Sulfonate
L3491 O-21
(PFOS)
080103A-2028 Sm (Mn, 2x3)
9.25 40962
02-Aug-2003 12:13:5: LC/MS/MS #(
MRM of 4 Channels ES-
499 > 9! 2.39et Are;
, I I c I , I s t I 7 Time
10.00
12.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
-------------B-P-
----
--------_
Quantify
Sample Report
qrrr, Study No.:L34910,
Set No.: 080103A,
Ea&.Date:08/0l./03,
Analyst:K.Risha
Sample List: Last modified: Wethod: Last modified: Job Code:
P:\Data\~SMS6\Mass~~\Fluoroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\LQ3SMS6\Maeslynx\FluorochamicalsB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 56
Decatur BC BC 080103
Name: 080103A-2028.
Text :
4: PFOSA
L3491 o-21
080103A-2028 lOO-
Sm (Mn, 2x3)
%-
02-Aug-2003 12:13:52
LCYMWMS #6
MRM of 4 Channel8 ES-
9.87
498 > 78
1.82e6
Oxygen Research, 3058 Research Drive, State College, PA 16801
Quantify Saqle Report
w
Study No.:L34910,
Set No.: 080103A,
Eact.Date:08/01/03,
Ana1yst:K.Rish.a
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\LCMSMS6\Massl~\Fluoroch~ca~s.PRO\S~leDB\~80103A Sun Aug 03 07:25:44 2003 P:\Data\LCMSMS6\Masslynx\FluorochamicalsB\Decatur Sun Aug 03 07:1X:59 2003
Printed:
Sun Aug 03 07:32:25
2003
Page 57
Decatur BC BC 080103
Name: 080103A-2029 Text :
1: c8 Acid (PFOA)
l>(CO72503-5,500 rig/L Standard
080103A-2029 1 oo-
Sm (Mn, 2x3)
%-
9.13 _ 140009
02-Aug-2003 12:35:3! LC/MS/MS #(
MRM of 4 Channels I%413 > 36! 8.49el Are:
0 ,,,~,`;;,~,,,,,,,,,,,~~,,i,,~,,~~~~,,,~~,~~~~~~,~i~~~~,,~,,,Time
2.00
4.00
6.00
\wlr' 2: C6 Sulfanate
IXCO72503-5,500
(PFHS)
rig/L Standard
080103A-2029 lOO-
Sm (Mn, 2x3)
%,
8.00 8.98
10.00
12.00 J
02-Aug-2003 12:35:34 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.72e5 Area
: C8 Sulfonate
:CO72503-5,500
(PFOS)
rig/L Standard
80103A-2029 Sm (Mn, 2x3)
9.24 17108
02-Aug-2003 12:35:39 LC/MS/MS #6
MRM of 4 Channels ES499 z 99 1.02e5 Area
VI&--
A--
2.00
4.00
6.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
Time 12.00 ]
000346
-w-p---
----------------------------------~--__I_---
Quantify Sample Report ,& Study No. : L34910, Set No.:080103A,
Eact.Date:08/01/03,
Analyst:K.Risha
Page 58
Salnple List: Lallt modified: Method: Last modified: Job Code:
P:\Data\LCWSMS6\~sslyPx\Fluorochamicals.PRO\S~leDB\O80103A Sun Aug 03 07:25:44 2003
P:\Data\L~SMS6\Masslylur\FluorachamicB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: m-v---
Sun Auq -------
Name: 080103A-2029 Text :
03 07:32:25 2003 --_----------------
--
--e--M-_
i: PFOSA
(CO72503-5,500
rig/L Standard
38010319-2029 10
"i i %
i
Sm (Mn, 2x3)
o"~~`,~`~~,~,~~,~`~`,~~",~~~`,`~~'r'~'~,'~'~,~~r
2.00
4.00
6.00
02-Aug-2003 12:35:39(
LC/MS/MS #6
MRM of 4 Channels ES-
9.88 6723' I
498 > 78 3.54e5
Area
L
Time
8.00
10.00
12.00
Exygen Research, 3058 Research Drive, State College, PA 16801
---m-v-
---------
-------
----
---
Quantify Sample Report
,w Study No.:L34910,
Set No.: oa0103A, Ext.Dats:08/01/03,
Analyst:K.Risha
Page 59
Sample List: Last modified:
Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~ca~s.PRO\s~leDB\OaOlO3A Sun Aug 03 07:25:44 2003
P:\Data\LQ3SMS6\Masslynx\FluarochemicalaB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
------__-I_-_
Sun Aug
03 07:32:25 -------
2003 ---------__--------
-----l-----_l__
Name: 080103A-2030
Text :
1: CB Acid (PFOA)
XCO72503-6,1000 rig/L Standard
I080103A-2030 10
Sm (Mn, 2x3)
9.12 273386
02-Aug-2-003 12:57:2d LCMWMS #6
MRM of 4 Channels ES-
413>369 1.66e6 Area
llu7 2: C6 Sulfonate
XCO72503-6,lOOO
(PFHS)
rig/L Standard
080103A-2030 lOO-
Sm (Mn, 2x3)
%-
L
Time
12.00
8.98 _ 54198
02-Aug-2003 12:57:26 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 3.29e5 Area
: C8 Sulfonate
(CO72503-6,1000
(PFOS)
rig/L Standard
380103A-2030 10
Sm (Mn, 2x3)
% y/
2.00
4.00
6.00
02-Aug-2003 12:57:26 LCIMSIMS #6
MRM of 4 Channels ES499 > 99 1.91e5 Area
Exygen Research, 3058 Research Drive, State College, PA 16801
..*- .-. ._-.-._--.""",,I-,__..,~
_--- .".__
Quantify Saalple Report
,J
Study Na.:L34910,
Set No.: 080103A, Ext.Date:08/01/03,
?umlyst:K.Risha
Page 60
Sample
List:
Last modified:
Method:
Last modified:
Job Code:
~:\Data\L~SMS6\Mssslynx\Fluaroch~cals.PRO\S~leDB\O8OlO3A Sun Aug 03 07:25:44 2003 P:\Data\L~SMS6\MasoLynx\Fluorochsmicalp.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 3003
Decatur EC BC 080103
Printed: ----------
Sun Aug 03 07:32:25 ---__------
NBlM: 080103A-2030 Text:
2003 ------------~-----------------_----
4: PFOSA
IXCO72503-6,lOOO
rig/L Standard
080103A-2030 100-
Sm (Mn, 2x3)
%-
02-Aug-2003 12:57:26j
LX/MS/MS #6
MRM of 4 Channels ES-
9.89
498 > 78
6.85e5
Area
0 "","","","","","",",`,"","`,,".`,",,,"",
Time
L
2.00
4.00
6.00
8.00
10.00
12.00
Eqgen Research, 3058 Research Drive, State College, PA 16801
-.-_--I.-.
_
ooow9
spwsoc study No:
Exypcn Study No: .bdytC: lms MoniIMcd: She:
NA
L34910 PFOA 413 -r369 Dccvur B&u's Creek
RAW DATA REPORT
Lid of QuaIuition:
l+ction
Volume:
Ma&
Sample weigh
Fii v01urnc:
50 PPI IS& soil 5.Og 5.0 mL
S.StNo:
A&SC
Lnrbummt Exuacdon Adyzsd
Type: Date: w:
080103AR Karen Rirha LCMSMS #6 08mlrn3 081'34M3
l%YpCU m
xCJ372503-a xc.o72503-1
spoolor
m
Run
NO.
cs
080103AR-301
cs
080103AR-302
Std.
*a
Am0uol
bYW
TOW
COIIC. Dilution
Puk
Pwnd
Added
Rccmciy
Found
SOtid.
(pp1)
Factor
hma
(PEN)
(PPO
6)
(ppb)
(%)
0
672
25
13717
XUY72503.2 xCO7u03.3
cs
080103AR-303
50
29040
cs
080103AR-304
1W
51582
xco72503-4 XCU72.503.5
cs
080103AR-305
2.50
cs
080103AR.3%
so0
113798 242355
XCO72503.6 L34910.I 1 Spk E L34910.I 1 Spk E L34910-20 Spk P
BCZSED-06 EC-2 SED-06 Outfall to River SED-Ls
cs
080103AR-307
LP
080103AR-308
LF
080103AR.309
LP
080103AR-310
469994
369 1
l .
5ooo
29373
L.
5ooo
28261
.*
moo
L34910.5
BC2 SED-04
S
080103AR.311
18223
l *
69.96
L34910-5 Rep
EC2 SED-04
s
080103AR.312
14512
.*
69.%
u4910.10
BC2 SED-05
s
080103AR.313
32594
l *
69.54
U491QIO
Rep
BC2 SED-05
S
080103ASb314
31062
.*
6954
xCO72503-1
cs
080103Alb315
12807
bv
XCO72.503-2
cs
080103AR.316
25414
L34910-I I
BC2 SED-06
s
080103AR.317
9410
*.
60.41
L34910-11 Rep
BC2 SED-06
S
080103AR.318
9587
. .
60.41
L34910-1 I
EC2 SD-06
S
080103AR.319
80473
1780
14.24
60.41
u4910-11
Rep
w4910-20
L34910.20 Rep
BC2 SED-06 OulfaB lo River SED-2.5 Odd1 to River SED-25
s
080103AR.320
s
080103AR-321
S
080103AR.322
76840
1700
7081
.*
5379
.*
13.M)
60.41
63.27
63.27
x(x72503-3
cs
080103AR-323
41160
xCu72503-4
cs
080103AR-324
96206
W491C-20
Outfall IO Rivu S@D-2.i
S
080103AR-325
61092
134a
IO.72
63.27
W49lDzo
RqJ
W491021
L34910-21
Outfall co Rivn SED-25 Outfill to Rhr SEWI5 Dup outfall IO River SED-25 Dup
S
080103AR.326
s
080103AR-327
S
080103AIG328
44037
949
10169
l
99240
2210
739
63.27
67.43
17.68
67.43
xm72503-5
cs
080103AIG329
215048
xa7uo3-6
cs
080103AR-330
4c6254
Standvd IIWCC~~ Slop
Cd. Of Da.
: Linw (l/x P 2443.00 - 438.457 = 0.990236
weighti)
hnplylc Fcucd @pb) 1 halyW found (pp0 x volume extracted (0.04 L)] I sample weight (5 g) hdyte Fwad (ppb) dry weight = maly(c found (ppb) I (lGU% I total solids (R))
CS - Calibration
nandndud
c - cmlml s = sample
wmple
LF = Lab fortified PF = Fwld fort&d LCS * Laborntay
sample sample
Gxuol Splkc
CK = Check Stiard ND I NIX detected NQ = Nor quantifiable
* Rerpmsc betwan 0 and 2.5 pp'
* Raponse bctwcc2.n5 ppl UMI LCQ
(50 pal)
A=JYE Found @pb) Dry WciglM
23.6 225
16.9
w
12.0
26.2
**Sample
was analyzed with scvaai dilution facmn in onier to accommcda~c
all compounds.
The appmprialc
rwulu we rcponcd.
000350
SpmwxStudyNo:
Exy@a Study No: Al&B: l0n.l Monitored: Site:
NA
L34910 PFOS 499.>PP Dccahu Bakefs CIcck
RAW DATA REPORT
' Limit of Quautition:
Injjstioo Volume: MlUk Sample Wcighc Fmxl Votumc:
so PPl IS& Soil -5.0 g 5.0 mL
kt No: AdYSC hbuaKn1 extlacdon Adyzcd
Type: Dam: w:
080103hR lcareo Rilha LCMSMS 16 08sJlrn3 08&4/03
EXYpeD D
xCO72503-0
xCO72503-I
xc07u03.2
xco72503-3
xCu72503-4
xco72503-s
XCO72503-6
U4910-11
SpkE
(34910.1lSpkE
I34910-20
Spk F
u4910.5
u4910-5 Rep
L34910-10
U4910.10
Rep
XC072503- I
XCO72.503-2
w4910-II
WPIO-11
Rep
w4910-II
L34910-II
Rep
L349lc-20
L34910-20 Rep
X0372503-3
xCO72503-4
W910.20
w4910-20 Rep
U491@21 L349Lc-21
xCO72503-s
Xu)72503-6
Spoo= ID
BC2 SED-06 BC2 SEDW `&fall LO River SED-25 BC2 SED-04
acz sm.04 ac2 sm.OS
EC2 SED-05
BCZSED-06 aa SED-06 BCZ SED-06 BC2 SED-06 Outfall to River SED-2S ouu-dl to River sell-25
Sample
c.z&
cs
cs cs cs cs cs cs LF LF LF s s S S cs cs S S s s S s c.s cs S S s s l-3 cs
RU NO. 080103AR-301 080103AR-302 080103AR-303 080103AR.304 080103AR.305 080103AR-306 080103AR-307 080103AR.308 080103AR.309 080103AR-310 080103AR~311 080103AR.312 080103AR-313 080103AR-314 080103AR.315 080103AR.316 080103AR-317 080103AR-318 080103AR.319 080103AR-320 OS0103AR.37.L 080103AR-322 080103AR.323 080103AR.324 080103AIb325 080103Ah326 080103AR.327 080103AR-328 080103AR.329 080103AR-330
Std.
Adp
AUUUUI
Adylc
Twd
cont.
Dilution
Rak
FOUOd
Added
Rccovuy
Found
Soli&
(ppt)
Fxtw
Area
CPPO
@PO
(W
(pph)
(70)
0
0
2s
1442
50
3003
Nil
5613
250
11976
SW
2.5896
AadyrC
&Jnd (Ppb) Dry Weight
loo0
51730
low
5387
100
51842
so00
**
SW0
ml
9506
19lM
5ooo
II4
10
9121
1830
14.64
69.96
20.9
10
7449
1490
11.92
69.96
17.0
10
14012
2850
22.80
69.54
32.8
10
15401
31M
2s.w
69.54
36.0
7.5
1301
50
2860
100
66379
100
48118
M
10
526238
l *
10
390663
l .
60.4 I 60.41 60.41 60.41
104
6714
13400
107.20
63.27
I69
loo
4609
9010
loo
4445
72.08
63.27
114
2.w
11649
10
63108
. .
IO
45122
.*
63.27
r
63.27
100
8701
17500
10
Bow3
. .
140.00
67.43
208
67.43
500
24473
IcaJ
44784
Analy~ Recavuy
Found (pp') = (pwk arw . intercept) I slope x DF
(57) i
Iadyte found (ppthnalytc
fowd in CWiTOl (ppl)]
amount added (ppt)
x 100
S&i&&&w Intcrccp~ Slope
Cosf. Of Del.
: Limu (I/x I 254.789 = 48.3413 - 0.991571
weighted)
AsrlyrC tiytc
Found (ppb) = [analytc found (ppt) x volume extracted (0.04 L)] I sample weight (5 p) Found (ppb) dry weight I analyo found @pb) x (100% /total sc4idr (+))
CS = CJibradacl
standard
c 3 cantrcI1 ramplc
s -.samplc
LF = Lab fwtificd Pp = Field fonihcd LCS = Laboratory
runplc ramp10
Control Spike
CK = Uicck St+ndud
ND I Notdstatrd
= Rcrpcw ktwsen 0 aad 25 ppt
NQ I Nor quantifiable
- Response between 25 pp, lad LOQ (SO pp')
Sponsor Shldy No: Exygcn Study No: Adytc: loos Monitored: Site:
NA L34910 FOSA ea.>78 Decatur Bakda Creek
RAWDATAREPORT
Limit ofQwtitatioo: lnjtdioo Volume: Mst-ix:
Sample Weight: Final volume:
50 PPt 15 pL Soil s.0 g S.OlllL
Set No: Analyst: lnsbummt Type: Extrsction Date: Atlslymlo11:
080103AR Karen Riha LCMSMS #6 08/01/03 08/04/03
Exym
SpOOSW
Sample
Run
m
m
CC&
No.
xco72503-0
cs
080103.4R.301
xco72503-I
cs
080103AR-302
XCO72SO3-2
cs
080103AR-303
XCO72503-3
cs
08OlO3AR-304
XC0725034
cs
080103.4R-305
XCO72503-5
CS
080103AR-306
XC0725036
cs
080103AR-307
W4910-11
Spk E
BC2 SED-06
LF
080103AR-308
L34910-11
SpkE
BC2 SED-06
LF
080103AR-309
L34910-20 Spk F
Outfall to River SED-25
LF
080103AR-310
w4910.5
BC2 SED-04
S
080103AR-31
I
L34910-5 Rep
EC2 SED-04
S
080103AR-312
w4910-10
EC2 &ED-OS
S
080103AR-313
L34910.lORep
BC2 SED-05
S
080103AR-314
XCO72503-I
cs
080103AR-315
XCO72503.2
CS
OBOlO3AR-316
Qid
Ll4910-II
L349lO-I I Rep
0C2 SEDM BC2 SED-06
S
080103AR-317
S
080103M-318
L34910-II
SC2 SED-C.5
s
080103AR-319
L34910-II
Rep
BC2 SED-W
S
080103AR.320
L34910-20
Outid ta River SED25
S
080103AR-321
L349lQZO Rep
Outfall (0 River SED-25
S
080103AR-322
XCO72503-3
cs
08OlO3AR-323
XC0725034
CS
080103AR-324
L34910-20
Outfall to River SED-25
S
080103AR-325
L34910-20
Rep
Outfall to River SED-25
S
080103AR.326
w4910.21
Outfall to River SED-25 Dup
S
080103AR-327
L349IO-21
Outtkll 10 Rivn SED-25 Dup
S
080103AR.328
xca72503-5
cs
OgOlO3AR-329
XCO72503-6
cs
080103AR-330
Analytc Found (ppt) - (peak area _ inracept) I slope x DF
Recovery (%) -
,lardyte found @pl)-analytc
found io contml (ppt)l x IO0
~moont added @PI)
Std. COUC. (PPO
0 25 50 100 250 500 1000
25 50
IO0 250
500 I000
Analyte Analyte
Found (ppb) = [malytc found (ppt) x volume extracted (0.04 L)] I sample weigbt (5 6) Found (ppb) dry wcigbt = lnnlyte found (ppb) x (lCO?`a I total soli& (%))
CS = Calibrntion
sundud
c = cootroi sample
s - Sample
LF - Lab fortified sample FF - Field fortified sample LCS - Laboratory Control spike
Aoalylc
AnKJlmr
Adyfe
TOM
DilUtiOll
Peak
Found
Added
RCCOVCIY
Found
Solids
Factor
Area
(ppt)
(ppt)
x
(ppb)
(0%
0
5040
I0269
19684
45565
93155
179184
2308
5000
21870
5000
13524
.*
5000
16680
.I
69.96
I8189
.*
69.96
19503
l .
69.54
26862
I510
12.08
69.54
4380
a99 I
21988
60.41
16805
60.41
200293
l *
60.41
IS0384
. .
60.41
6516
.*
63.27
5371
**
63.27
17628
40103
61447
3m
28.00
63.27
51717
2940
9119
.*
23.52
63.27
67.43
78207
4460
86063
167421
35.68
61.43
Standard w lntucepr Slops
Chef. Of Dct.
: Lincu (l/x = 610.451 = 174.067 - 0.996985
weighted)
CK = Check Staodard
ND = Not dcrectcd - Rsrpoow behvca 0 md 25 ppt
NQ - Not quantifiable
= Respmsc bctwcco 25 ppt and LOQ
(50 ppt)
Analyie F-xnd W-4 Dry Weight
17.4
44.3 37.2 52.9
**Sample -Sample
was analmd
with several diltttioo factors
requircr reextmuion.
Ssc data set 0806038.
in order to accommodotc
all compounds.
The appropriate
results arc rcportcd.
000352
Masslynx - Sample List
Sampie List: Printed: Mon Aug 04 07:47:05 2003 ---
&ygen STUDY NOa a
-.
Page 1 Page Position: (I, 1)
Vial File Name
LIMS ID Client ID Sample Description
Matrix Sample Type Cone (rig/L) Cone B Cone C Test ID DF
2 1
41 080103AR-301
---
---
XCO72503-0. 0 rig/L Standard
---
Standard
" 0
2
42 080103AR-302
-
--
XCO72503- 1. 25 m-r/L Standard
--
Standard
3
43 080103AR-303
--
-
XCO72503-2; 50 n$L Standard
_--
Standard
z
4
44 0801 03AR-304 --
--
XCO72503-3. 100 nglL Standard
--
Standard
100
45 080103AR-305
-
-
XCO72503-4,250 ngiL Standard
--
Standard
250
6" 46 080103AR-306
-
-
XCO72503-5.500 nglL Standard
--
Standard
500
7
080103AR-307
-
-
XCO72503-6, 1000 ngR Standard
--
Standard
loo0
8
080103AR-308
--
-
L34910-11 Spk E, 5ooO nglL, OF=1000 --
CC
5ooct
0801 03AR-309 -
-
L34910-11 Spk E, 5000 rig/L, OF=100 --
QC
5000
l"o
080103AR-310
--
--
L34910-20 Spk F, 5000 n&L, DF=lOO -
QC
5000
11
080103AR-311
-
-
L34910-5, DF=lO
-
Analyte
--
12
080103AR-312
-
-
L34910-5 Rep, DF=lO
-
Analyte
--
080103AR-313
-
--
L34910-lO.DF=lO
-
Analyte
-_
::
080163AR-314
--
-
L34910-10 Rep, DF=lO
-
Analyte
-_
15 42 080103AR-315
-
--
XCO72503-1,25 rig/L Standard
-
Standard
25
18
43 080103AR-316
-
--
XCO72503-2, 50 @IL Standard
-
Standard
50
17
080103AR-317
-
--
L34910-ll.DF=l60
-
Analyte
--
18
080103AR-318
-
-
L34910-ll.Rep, DF=lOO
-
Analyie
--
080103AR-319
--
-
L34910-11, DF=lO
-
Analyte
m-w
2
080103AR-320
-
-
L34910-11 Reo. DF=lO
-
Analyte
---
12 080103AR-321
--
-
L34910-20, Di~lOO
--
Analyte
--
z
13 080103AR-322
--
-
L34910-29 Rep, DF=lOO
_--
Analyte
---
080103AR-323
-
-
XCO72503-3. 100 rig/L Standard
--
Standard
100
;i
080103AR-324
-
-
XCO72503-4. 256 rig/L Standard
--
Standard
250
25
14 080103AR-325
-
-
L34910-20. DF=lO
--_
Analyte
-I
26
15 0801 OJAR-326 -
-
L34910-20 Rep, OF=10
_-
Analyte
--
27
16 080103AR-327
-
--
L34910-21. DF=lOO
--
Analyte
--
28
17 080103AR-328
-
-
L34910-21; DF=lO-
___
Analyte
29
080103AR-329
-
--
XCO72503-5. 500 rig/L Standard
--
Standard
500
30
"4; 080103AR-330
-
-
XCO72503-6. 1000 rig/L Standard
-
Standard
1000
---
0
1
___
--
0
1
--
_-
0
1
_-
-
0
1
--
--_
0
1
-_
--_
0
___
-_-
0
:
-
---
0
1000
--
---
0
100
-.v
---
0
100
-
---
0
10
-
---
--
_-
x
::
--
___
0
10
--
___
1
--
--
8
1
--
___
0
100
-
---
0
100
-
--
0
IO
-
---
0
10
--
0
100
--
-
0
100
-
-
0
1
-
-
0
1
0
10
-
-
0
10
-
0
--
-
0
:F?
--
..-
0
-
0
:
Masslynx - Sample List
Sample List: C:V\nASSLYNX\Fluorochemicals.PRO\SampleDt3~g66103AR
03 Printed: Man Aug 64 07:47:05 2003
---
Decatur BCSPL -
MS Method
1 C6 C6 SULF C8 ACID PFOSA
2 C6 C8 SULF C8 ACID PFOSA
3 C6 C8 SULF C8 ACID PFOSA
4 C6 C8 SULF C8 ACID PFOSA
5 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
7" C6 C6 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
4" C6 CB SULF C8 ACID PFOSA
IO C6 C8 SULF C9 ACID PFOSA
11 C6 C8 SULF C8 ACID PFOSA
12 C6 CB SULF C6 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
:: C6 C6 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
:i
C6 C8 SULF C8 ACID PFOSA
17 C6 C6 SULF C8 ACID PFOSA
18 C6 C6 SULF C8 ACID PFOSA
19 C6 C8 SULF C8 ACID PFOSA
20 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA
2
C6 C8 SULF C8 ACID PFOSA
23 C6 C8 SULF C8 ACID PFOSA
24 C6 C8 SULF C8 ACID PFOSA
25 C6 C8 SULF C8 ACID PFOSA
26 C6 C8 SULF C8 ACID PFOSA
27 C6 CB SULF C8 ACID PFOSA
28 C6 C8 SULF C8 ACID PFOSA
29 C6 C8 SULF C8 ACID PFOSA
30 C6 C8 SULF C8 ACID PFOSA
HPLC Method
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water
MS Tune File
Fluorochems Fluorochems Fluarochems
Fluorochems Ftuorochems Fluorochems Fluorochems Fluorochems Fluorochems Ftuarochems
Flucrochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Fluorochems Ffuorochems Fluomchems Fluorochems
Inj.Volume
15 15 15 15 15 15 15
i: 15
iz 15 15 15 15 15 15 15 15 15
:55 15
:: 15
:"5 15
&ygen STUDY NC?. c3qqJ0
Page 2 Page Position: (2. 1)
LC!/MS/MS SYSTEM AND OPERATING CONDITIONS
Soonsor Protocol No: NA
Exvgen Studv No: L349 IO
Instrument:
Micromass Quattro Ultima (IX/MS/MS Unit #6)
Computer: Software:
COMPAQ Professional Workstation AP200
Microsoft Windows NT: Version 4 Build 138 1: Service Pack 5 Micromass Limited: MassLynx 3.4 Build 004
HPLC Equipment:
Hewlett Packard (HP) Series 1100
HP Bin Pump
HP Vacuum Degasser
HP Autosampler
HP Column Oven
HPLC Column:
Mobile Phase (A) : Mobile Phase (B) :
Genesis C-8,5 cm x 2.1 mm i.d. x 4 p (Oxygen ID: 74A) (JONESCHROMATOGRAPHY: Part No. FK5962E)
2 mM Ammonium Acetate in Type I Water Methanol
Analyst:
Karen Risha Exygen Research 3058 Research Drive, State College, PA 16801 Phone: (8 14) 272-1039 FAX: (8 14) 23 L-1580
NOTE:
The next 3 pages are computer generated printouts from the masslynx software program. The pages contain the instrument settings used for the analysis of this data set.
All Handwritten Peak ID's by. * lip0!6/*3
"-_....-
--._---.....---
080355
Scanning
Method Report
fd
Method: Last Modified:
C:\MASSLYNX\FLUOROCHEMICALS.PRO\ACQUDB\C6
Thu Ju$ 31 16:23:50 2003
Printed:
Mon Aug 04 07:47:13
2003
Page 1 C8 SULF C8 ACID PFOSA
Solvent Delay ( mins ) :
0.00
ATlalog Function
Channel : 1
4 : Unused
MFN of 4 Mass Pairs
( ESP- )
Inter Channel Delay ( Sets ) : 0.03
Span ( Daltons ) :
0.00
Start Time ( Mins ) :
0.00
End Time ( Mins ) :
12.00
Repeats :
1
Channel Parent Daughter
Dwell (Sets) Co11 Energy (eV) Cone ( V )
1
399.00 80.00
0.20
35
50
2
413.00 369.00
0.20
10
10
3
498.00 78.00
0.20
30
50
4
499.00 99.00
0.20
40
33
Method Report
Method File: Last Modified:
C:\MASSLYNX\FLUOROCHEHICALS.PRO\ACQUDB\pfbs
Monday, August 04, 2003 07x38:50
,J Printed:
Monday, August 04, 2003 07:47:18
u
HP1100 LC Pump Initial
Conditions
Solvents
A%
90.0
B%
10.0
C%
0.0
D%
0.0
Flow (ml/min)
Stop Time (mins)
Min Pressure (bar)
Max Pressure (bar)
Oven Temperature Oven Temperature
Left(OC) Right (OC)
0.300 20.0
0 400
35.0 35.0
HP1100 LC Pump Qradient
Timetable
The gradient Timetable contains 8 entries which are :
Time
A%
B%
C%
D%
Flow
0.00
90.0
10.0
0.0
0.0
0.300
2.00
90.0
10.0
0.0
0.0
0.300
5.00
10.0
90.0
0.0
0.0
0.300
9.00
10.0
90.0
0.0
0.0
0.300
9.50
0.0
100.0
0.0
0.0
0.300
14.00
0.0
100.0
0.0
0.0
0.300
14.50
90.0
10.0
0.0
0.0
0.300
20.00
90.0
10.0
0.0
0.0
0.300
HP1100 LC Pump External
Event Timetable
The Timetable contains 6 entries which
Time
Initial 0.00 0.05 0.10
11.90 12.00
Column Switch Off Off Off
Off Off Off
Contact1 Off On
Off Off Off Off
are :
Contact2 Off Off Off On Off Off
'Contact3 Off Off Off Off
On Off
Contact4 Off
Off Off Off
Off Off
HP1100 Autosampler Initial
Draw Speed Eject Speed (pl/min)
Draw Position
(mm)
Stop Time (mins)
Injection
Volume(pl)
Vial Number
Conditions
200.0 200
0.50
20.00 15.0 27
water
Page 1
Pressure 400 400
400 400 400
400 400 400
000357
Tuning Method:
Printed:
Method
Report
C:\MASSLYNX\FLUOROCHEMICAtS.PRO\ACQUDB\FLUOROCHF,MS Mon Aug 04 07:47:28 2003
Page 1
SOURCE ( ESP- )
Capillary Cone Hexapole 1 Aperture 1 Hexapole 2
Source Block
Desolvation
Temp.
Temp.
Pressures
Analyser Gas Cell
Vacuum
Set
Rdbk
3.00 -2.93
20
-16
0.0
0.0
0.0
100 100
300 299
Rdbk
OFF 3.6e-3
Analyser
LM Res 1 HM Res 1 IEnergy 1 Entrance Collision Exit LM Res 2 HM Res 2 IEnergy 2 Multiplier
Gas Flows
Cone Gas
Desolvation
Set Rdbk
14.0
14.0
1.0
-2
11
15
21
2
14
14.0
14.0
2.0
650 -647
Rdbk
134.7 765.9
000358
---
------
Quantify Calibration
Report
Study No.: L34910, Set No.: 080103AR,
----
Ext.Date:08/01/03,
aalyst:K.Risha
Calibration: Last modified: Printed:
-------w----v
P:\Data\L~SMS6\Masslynx\Fluoroch~ca~8.P~O\~~eDB\O8OlO3~ Tue Aug 05 07:30:00 2003 'l'ue Aug 05 07:31:58 2003
--m-e-----
>ompound 1 name: C8 Acid (PFOA) Coefficient of Determination: 0.990236 Calibration curve: 438.457 * x + 2443.00 qesponse type: External Std, Area Curve type: Linear, Origin: Exclude, Weighting:
4.70e5
l/x, Axis trans: None
---_-----_
Page 1 Decatur BC
X
Response
~~,~~,,.~,,~~~.,~.~
0.0
200.0
q, " ' ' , " , " ' ' , " " 1 " "1"'
400.0
600.0
800.0
8 IngIL 1000.0
WgOn Research, 3058 Research Drive, State College, PA 16801
000359
----
-------__l---___I
-------------
Quantify Calibration
Report
`U Study No .:L34910, Set No.:O80103AR,
Ext.Date:08/01/03,
Calibration:
Last modified:
Printed:
-----
-------~_
P:\Data\L~SMS6\Masal~\Fluorochexrcic Tue Aug 05 07:30:00 2003 Tue Aug 05 07:31:58 2003
-----------
Axzalyst:K.Risha
Compound 2 name: C6 Sulfonate (PFHS) :oefficient of Determination: 0.990051 :alibration curve: 77.0647 l x + 374.700 Response type: External Std, Area >urve type: Linear, Origin: Exclude, Weighting:
8.1584. 1
l/x, Axis trans: None
-----------__
Page 2
Decatur BC
-------___
X
Response
0.0 Exygen Research,
200.0
400.0
600.0
3058 Research Drive, State College, PA 16801
800.0
rig/L 1000.0
---
-------
-------
---------------
Quantify Calibration
Report
w Study No.:L34910,
Set No.. ~080103AR, Ea&.Date:08/01/03,
Analyst:K.Rioha
Calibratioq: Last modified: Printed:
P:\Data\LQISMS6\Masslynx\Fluoroch~cals.PRO\~~eDB\O8OlO3~ Tue Aug 05 07:30:00 2003
'he Aug 05 07:31:58 2003
>ompound 3 name: C8 Sulfonate (PFOS) ;oefficient of Determination: 0.991571 >alibration curve: 48.3413 l x + 254.789 Response type: External Std, Area >urve type: Linear, Origin: Exclude, Weighting:
5.1704
l/x, Axis trans: None
------_- Page 3 Decatur BC
Response
O~,,,,,,,,,,,,,,,,,,,,~,~~r~~,~,~~~~,~~,~,~~'~,~~,~ln/L
0.0
200.0
400.0
600.0
Wgen Research, 3058 Research Drive, State College, PA 16801
800.0
1000. ?
0003Gl.
Quantify
Calibration
Report
p4
Study No.:L34910,
Set No. :080103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
Calibration: Last modified: Printed: ------------------------
P:\Data\LChiSMS6\bsslynx\Fluoroch~cala.PRO\~~eDB\O8OlO3~
'l'ue Aug 05 07:30:00
2003
'Pus Aug 05 07:31:58
2003
-------m----------
>ompound 4 name: PFOSA ;oefficient of Determination: 0.996985 ;alibration curve: 174.067 * x + 610.451 qesponse type: External Std, Area >urve type: Linear, Origin: Exclude, Weighting:
1.79eE
l/x, Axis trans: None
Page 4
Decatur
BC
Response
200.0
400.0
600.0
-en
Research,
3058 Research
Drive,
State College,
PA 16801
800.0
1000.0
---_
PI---
---m--m
----_
------
Quantify Sample Report
Study No.:L34910,
Set No.: 080103AR,
Ea&.Date:08/01/03,
Analyst:K.Risha
Page 1
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LBISMS6\Wasslynx\Fluorochemicals.PRO\S~leDB\O8OlO3~
Tue Aug 05 07:24:43 2003 P:\Data\LCbISMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC
BC 080103 da
Printed:
Tue Aug 05 07:32:01 2003
Name : 080103AR-301 Text :
1: C8 Acid (PFOA)
XCO72503-0,O rig/L
Standard
080103AR-301 Sm (Mn, 2x3)
r2: c6 Sulfonate
XCO72503-0,O
I I I II I I I~~#, I-I,I,
2.00
4.00
(PFHS)
rig/L Standard
080103AFb301 Sm (Mn, 2x3)
aII ,, 6.00
, , , , , , , ,c., 8.00
04-Aug-2003 08:35:x LC/MS/MS #6
MRM of 4 Channels ES413>369 4.35e4 Area
9.13 672
,:,-Time 10.00
04-Aug-2003 08:35:5C LCIMSIMS #6
MRM of 4 Channels ES399 > 80 834
2.00
4.00
6.00
8.00
10.00
3: C8 Sulfonate
(PFOS)
XCO72503-0,O rig/L Standard
04-Aug-2003 08:35:5C LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.96e3
Oxygen Research, 3058 Research Drive, State College, PA 16801
QQQ3G3
Quantify Sample Report -lrl Study No.: L34910, Set No .:080103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
Sanlple List: Last modified: Method: Last modified: Job Coda:
P:\Data\L~SMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Tue Aug OS 07:24:43
2003
P:\Data\L~SMS6\bsslynx\FluorochemicB\Decatur
Sun Aug 03 07:11:59 2003
Page 2
Decatur BC BC 080103
Printed:
l'ue Aug 05 07:32:01 2003
------------------_____________________--~
Name: 080103AR-301 Text :
----___---___
4: PFOSA
XCO72503-0,O
rig/L Standard
080103AFb301 Sm (Mn, 2x3)
OC-Aug-2003 08:35:5C
\I
LC/MS/MS #6
MRM of 4 Channels ES-
Exygen Research, 3058 Research Drive, State College, PA 16801
0003G4
------
----em--------------
----------m-__
Quantify Sample Report Study No.: L34910, Set No.: 080103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 3
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24x43 2003
P:\Data\LcMSMS6\Masslyax\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01 2003
-----------------__-----~-----
------__--
__-------
Name : 080103AR-302 Text:
: C8 Acid (PFOA)
3CO72503-1,25 rig/L Standard
380103AR-302 Sm (MI-I. 2x31
04-Aug-2003 08:57:29 LC/MS/MS #6
MRM of 4 Channels ES413> 369 8.44e4 Area
!: C6 Sulfonate
KC072503-1,25
(PFHS)
rig/L Standard
080103AR-302 10
Sm (Mn, 2x3)
Time
04"Aug-2003 08:57:29/
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
2217
1.42e4
Area
2.00
4.00
6.00
3: C8 Sulfonate
XCO72503-1,25
(PFOS)
rig/L Standard
080103AR-302 10
Sm (.Mn. . 2x3) ,
%7 -
O~,,,,,,,,,,~,,,,,,,,,,,,,,,
2.00
4.00
6.00
8.00
9.24 1442
10.00
I
04-Aug-2003 08:57:2$ LC/MS/MS #6
MRM of 4 Channels ES499 > 9s 9.02e? Area
8.00
10.00
Rxygen Research, 3058 Research Drive, State College, PA 16801
---
--
___-...
000X5
Quantify Sanrple Report Study No.: L34910, Set No.:O80103AR,
Ext.Dats:06/01/03,
Analyst:K.Risha
Szunple List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SblS6\Mssl~\Fluoroch~cals.PRO\S~leDB\O6OlO3~ !Cue Aug 05 07:24:43 2003 P:\Data\L~SP3S6\MsslyPx\FluaEochemic\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Tue Aug 05 07:32:01 2003
Page 4
Decatur BC BC 080103
Name: 080103AR-302 Text:
4: PFOSA
XCO72503-1,25
rig/L Standard
080103AR-302 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 08:57:2d
LCIMSIMS #6
MRM of 4 Channels ES-
9.92 5040--
498 > 78 2.63e4
Area
Exygen Research, 3058 Research Drive, State College, PA 16601
---_------
w-e----
--------------I_---
-
Quantify Sampla Report
"4 Study No.: L34910, Set No.:O80103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Masslyax\Pluorochemicals.PRO\S~leDB\O8OlO3~
Tue Aug 05 07:14:43
2003
P:\Data\L(3MSMS6\~ssl~\Fluoroch~cals.PRO\Met~B\Decatur
Sun Aug 03 07:ll:SS 2003
Page 5
Decatur BC BC 080103
Printed:
----------__--------~~
Tue hug OS 07:32:01 2003 -a---------------e------s----
Name: 080103AR-303 Text :
----------_-_
1: C8 Acid (PFOA)
XCO72503-2,50 rig/L Standard
080103AR303 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 09:19:12
LC/MS/MS #6
MRM of 4 Channels ES-
9.13
413>369
1.67e5
Area
2.00
4.00
`4 2: C6 Sulfonate
(PFHS)
XCO72503-2,50 rig/L Standard
080103AFk303 Sm (Mn, 2x3)
, , , , , , , , , , , , a , , , , , ,-Time
8.00
10.00
04-Aug-2003 09:i 9:12
LC/MS/MS #6
MRM of 4 Channels ES399 > 80 2.81 e4 Area
3: C8 Sulfonate
XCO72503-2,50
2.00
4.00
(PFOS)
rig/L Standard
080103AR-303 100-
Sm (Mn, 2x3)
%-
8.00 9.27
Time
10.00
04-Aug-2003 09: 19: 12 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.63e4 Area
8 + , I I I I , r r t I Time 10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
---
~---___-
---_---I----------
----------
Quantify Sample Report
,& Study No.:L34910,
Set No.: 080103AR, Ekt.Date:08/01/03,
Analyst:K.Risha
Sanrple List: Last modified: Method: Last modified: Job Code:
P:\Data\~:SMS6\Masslynx\Fluorocb~cals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07~24~43 2003 P:\Data\LCMSMS6\Maselynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Tue Aug 05 07:32:01 2003
---__
----_
Page 6
Decatur BC BC 000103
Name : 080103AR-303 Text :
4: PFOSA
XCO72503-2,50
rig/L Standard
080103AFb303 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 09:19:12
LCIMSNS #6
MRM of 4 Channels ES-
9.90
498 > 78
5.34e4
Area
II ,I 10.00
I Time
EWgen Research, 3058 Research Drive, State College, PA 16801
----
-m--o-
---4-----
-------I_-------------
Quantify Sample Report
\& Study No.:L349XO,
Set No .:080103AR,
Ext.Date:08/01/03,
Analyst:IZ.Risha
Page 7
Sam$Jle List: Last modified:
Wethod: Last modified:
Job Code:
P:\Data\LCMSMS6\Massl~\~luoroc~~cala.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: -------------v-m-
'has Au% 05 07:32:01
Name: 080103JiR-304 Text :
2003 --___------
--------e-v--
: C8 Acid (PFOA)
<CO72503-3, 100 rig/L Standard
380103AR-304 10
Sm (Mn, 2x3)
04-Aug-2003 09:41 :o
LC/MS/MS #
MRM of 4 Channels ES-
9.13
413>369
5158;
3.00e5
Area
:
v
Time
2.00
4.00
6.00
8.00
10.00
2: C6 Sulfonate
XCO72503-3,100
(PFHS)
rig/L Standard
080103AFb304 10
Sm (Mn, 2x3)
04-Aug-2003 owl :od
LC/MS/MS #6
MRM of 4 Channels ES-
8.96
399 > 80
8536
5.07e4
Area
2.00
4.00
6.00
8.00
10.00
3 : C8 Sulfonate
1 tCO72503-3,100
(PFOS)
rig/L Standard
(380103AR-304
10 01
% 1
Sm (Mn, 2x3)
04-Aug-2003 09:41:00
LCNWMS #6
MRM of 4 Channels ES-
9.2:
499 > 99
561:
3.18e4
Area
--
1
Time
w
2.00
4.00
6.0~
8.00
10.00
I
WZTen R-earth,
3058 Research Drive, State College, PA 16801
000x9
Qwlntify Sample Report
ud Study No.:L34910,
Set No.: 080103X& Ext.Date:08/01/03,
Analyst:K.Risha
Page 8
Salnple List: Last modified: Method:
Last modified:
Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\LCMSMS6\~sslynx\Fluorochemical\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: -----_--_
Tue Aug 05 07:32:01 2003 __-_--__----___----------------~----------------------
Name : 080103AR-304 Text:
,: PFOSA
KO72503-3,100
rig/L Standard
180103AR-304 10
Sm (Mn, 2x3)
%
04-Aug-2003 09:41 :OC
LC/MS/MS #6
MRM of 4 Channels ES-
9.92 19684 L
498 > 78 1.03e5
Area
/ ,
O",`,,,~,,,`,,,,~,ll,,`,,,.,,,,".,,,.,,,,',~,~,,
1.
Time
2.00
4.00
6.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000370
Quantify Sample Report
r
Study No. :L34910, Set No.: 080103AR, Ext.Dats:08/01/03,
I
Analyst:K.Risha
Page 9
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LCMSMS6\~ssl~\Fluoroch~cals.PRO\S~leD~~O8OlO3~
Tue Aug 05 07:24:43
2003
P:\Data\LCMSMS6\Masslyax\Fluoxoch~cals.PRO\Met~~\Decatur
Sun Aug 03 07:11:59
2003
Decatur BC BC 080103
Printed:
Tue hug 05 07:32:01
2003
~~~-~~----~---1----__~~-_-__-1_------------------~--~-----1----1
Name : 080103AR-305 Text:
1: C8 Acid (PFOA)
XCO72503-4,250 rig/L Standard
080103AFb305 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 10:02:40
LC/MS/MS #6
MRM of 4 Channels ES413>369 6.66e5 Area
@ ,,,,~,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,
I , , 1 G r I , r , I Time
2.00
4.00
6.00
8.00
10.00
J
v 2: C6 Sulfortate
(PFHS)
XCO72503-4,250 rig/L Standard
080103AR-305 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 10:02:4C
LCYMWMS #6
MRM of 4 Channels ES-
6.98
399 > 80
1.20e5
Area
r
A
0 /111,111,,1,,1,1111(1111,11/1/111~/1111,
r I, rI I,I I
Time
2.00
4.00
6.00
8.00
10.00
: C8 Sulfonate
(CO72503-4,250
(PFOS)
rig/L Standard
)80103AR-305 IO
j
Sm (Mn, 2x3)
9.25 1197( 3
04-Aug-2003 10:02:4C
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 6.98e4 Area
I
Time
Exygen Research, 3058 Research Drive, State College, PI 16801
000371
--
------
--
-----___
-
Quantify Sample Report
w
Study No.:L34910,
Set No.: 080103AR, Ext.Date:08/01/03,
Analyst:K.Ri.aha
Page 10
SaluQle List: Last modified: Method: Last modified: Job Code:
P:\Data\LWSMS6\ailsssl~\Fluoroch~cals.PRO\S~leDB\O8OlO3~ me Aug 05 07~24~43 2003 P:\Data\LQrlSMS6\Masslynx\Pluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11x59 2003
Decatur EC BC 080103
Printed:
'Pus Aug 05 07:32:01 2003
----__-----------------------~-~-------~
-----A-
__----
Name: 080103AR-305 Text :
: PFOSA
KO72503-4,250
rig/L Standard
180103AFL305 Sm (Mn, 2x3)
04-Aug-2003 10:02:4C
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 45565 i
498 > 78 2.39e5
Area
i-
Time
2.00
4.00
6.00
8.00
EXy!GWn Research, 3058 Research Drive, State College, PA 16801
e-------_-
------_-__-
-Y-e----
-----------_
Quantify
Sample Report
'lid Study No.: L34910, Set tio.:O80103AR,
Ext.Date:08/01/03,
Aualyst:K.Risha
Page 11
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluaroch~cals.PRO\S~leDB\O8OlO3~
!tWe Aug 05 07:X:43
2003
P:\Data\LCMmS6\Wasslynx\Fluoroch~cals.RRO\~ethDB\~catur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Tus Aug 05 07:32:01 2003
------------I_------------____I__-
--------I_-
----__--_
Name: 080103AR-306 Text:
.: C8 Acid (PFOA)
l(CO72503-5,500 rig/L Standard
180103AR-306 IO 01
Sm (Mn, 2x3)
9.14 24235!
04-Aug-2003 10:24:22j
LC/MS/MS #6
MRM of 4 Channels ES413 z 369 1.40e6 Area
by 2: C6 Sulfonate
[XCO72503-5,500
(PFHS)
rig/L Standard
080103AR-306 -IO&
Sm (Mn, 2x3)
%-
0 llll,llll,lll,,ll,l,lllr,ll~l,~,,I,II,,/III
2.00
4.00
3: C8 Sulfonate
XCO72503-5,500
(PFOS)
rig/L Standard
080103AR-306 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 10:24:2d
LC/MS/MS #6
MRM of 4 Channels ES-
8.97
399 > 80
2.48e5
Area
, , , I , , , , , , , , Time
6.00
8.00
10.00
9.27 25896
04-Aug-2003 10324324 LC/MSlMS #6
MRM of 4 Channels ES499 > 99 1.52e5 Area
Eacygen Research, 3058 Research Drive, State College, PA 16801
Quantify Sample Report
1~ Study No.:L34910,
Set No.: 080103AR, Ext.Date:08/01/03,
Analyst:X.Risha
Sample List:
Last modified: Method:
Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\L(3MSMS6\Masslynx\FluorochsmicalB\Decatur
Sun Aug 03 07:11:59 2003
Printed:
Tue Aug 05 07:32:01 2003
Page 12
Decatur BC BC 080103
Name: 080103AR-306 Text :
I4: PFOSA
XCO72503-5,500
rig/L Standard
080103AFk306 1 oo-
Sm (Mn, 2x3)
%-
04-Aug-2003 10:24:2;
LC/MSlMS #f
MRM of 4 Channels ES-
9.90
498 > 78
4.79e5
Area
@ ,,,,,,,~,,,,~,,~,~~~~~~~,,~~~~~~~~~~~~,i~~~~~
, , , , , , Time
2.00
4.00
6.00
8.00
10.00
Oxygen Research, 3058 Research
Drive, State College, PA 16801
---0----e--s-
-_----
-m--e
Quantify Saxple Report
hd Study No.: L34910, Set No .:080103AR,
Ekt.Date:08/01/03,
Analyst:K.Risha
Sample List:
Last modified: Method: Last modified: iToh Code:
P:\Data\L~SMS6\~sslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Tus Aug 05 07:24:43 2003
P:\Data\LCMSMS6\Masslynx\Fluorochamieals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Printed: -----__------------------
Tue Aug 05 07:32:01
2003 -------l_l-------------~----
Name: 080103AR-307 Text:
.: C8 Acid (PFOA)
YCO72503-6,1000 rig/L Standard
380103AFb307 10
% $ i
Sm (Mn, 2x3) :
9.13 L4 46999,
2.00
4.00
8.00
: C6 SUlfOnate
(CO72503-6,lOOO
(PFHS)
rig/L Standard
180103AR-307 10
Sm (Mn,`2x3)
8.96 8151(
A----
Page 13
Decatur BC BC 080103
04-Aug-2003 10:46:08 LC/MS/MS #6
MRM of 4 Channels ES41322.693e669 Area
Time 10.00
04-Aug-2003 10:46:08] LCIMSNS #6
MRM of 4 Channels ES399 > 80 4.74e5 Area
6.00
I3: C8 Sulfonate
lXCO72503-6,lOOO
(PFOS)
rig/L Standard
080103AR-307 10 3
Sm (Mn, 2x3)
1 %
Oi,,,,,,,,,~,,~,,,,~,,,,,,,~,,,,,,,,,~,,,,,,,,,~,~,~~~~,~~~~
2.00
4.00
6.00
I p ' " I",
r Time
8.00
10.00
9.25 51 730T
04-Aug-2003 10:46:08
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.90e5 Area
Time
8.00
10.00
Oxygen Research, 3058 Research Drive, Stats College, PA 16801
000375
--v---e--
-------
-------------------_
--
Quantify Szunple Report
Id
Study No .:L34910,
Set No.:O80103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\LCMSMS6\Masslyax\Fluoroch~cals.PRO\S~leDB\O8OlO3~ Tua Aug 05 07:24:43 2003 P:\Data\LCMSMS6\Massl~\FluorochsmicalB\Decatur Sk Aug 03 07:11:59 2003
Page 14
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01
2003
-----------------------------------------------------~-------
Name: Text:
080103Ub307
,: PFOSA
3CO72503-6,1000
rig/L Standard
180103AFb307 10
03
%
Sm (Mn, 2x3)
04-Aug-2003 10:46:04
LC/MS/MS #6
MRM of 4 Channels ES-
9.91
1791& i
498 > 78 9.27e5
Area
i
O'~.~~,~..`,~".,`...,`.`.,~~~~,`~","'~,'~.~,."
I
Time
2.00
4.00
6.00
8.00
Bxygen Research, 3058 Research Drive, State College, PA 16801
000376
Quantify Sample Report
w Study No.rL34910,
Set No.: 080103AR, Ext.Date:08/01/03,
Analyst:K.Risha
Page 15
S-10 List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Pluoroch~cals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\LCMSWS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01
2003
------------------------B-------m--
--------
Name:
Text:
080103AR-308
1: C8 Acid (PFOA)
L34910-11 Spk E, 5000 rig/L, DF=lOOO
080103AFb308 lOO-
Sm (Mn,. 2x3)
I
r
%-
04-Aug-2003 11:07:51
LCIMSNS #6
MRM of 4 Channels ES-
9.13
413 > 369
2.44e4
Area
\wl 2: C6 Sulfonate
(PFHS)
L3491 O-1 1 Spk E, 5000 rig/L, DF=lOOO
080103AFb308 lo&
7 %-
Sm (Mn, 2x3)
I 3
Time
10.00
04-Aug-2003 11:07:51
LC/MS/MS #6
MRM of 4 Channels ES-
8.96
399 z 80
3SOe3
Area
0 l.l,lll.,II,I,I.I.,I.I.,
2.00
3: C8 Sulfonate
(PFOS)
L3491 O-l 1 Spk E, 5000 rig/L,
4.00
DF=lOOO
080103AR-308 Sm (Mn, 2x3)
I ,, I ,, r II,,,
6.00
c I ,,
8.00
I I ,, I I. ,'. I ,I Is IG Time
10.00
04-Aug-2003 11:07:51
LClMSiMS #6
MRM of 4 Channels ES499 > 99 3.29e4 Area
Time
Eacygen Research, 3058 Research Drive, State COllegO,.PA 16801
000377
---------_I
--------_I_-
-------w---e-
------
Qwultify Sample Report
$4
Study No.: L34910, Set No.:O80103AR,
Ext.Date:08/01/03,
A.nalyst:K.Riaha
SanTpls List: Last modified: Method: Last modified: Job Code:
P:\Data\LCM~S6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\L~SMS6\Maaalynx\Fluorachamica\Met~B\D~catur
Sun Aug 03 07:11:59 2003
Page 16
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01 2003
--------A--A--a---------m-----e----
-------I---____
Name: 080103AR-308 Text :
4: PFOSA
-34910-l 1 Spk E, 5000 rig/L, DF=lOOO
180103AR-308 10
"i
Sm (.Mn, 2x3).
04-Aug-2003 11:07:511
LC/MS/MS #6
MRM 9.90
230E;
of 4 Channels ES-
498 > 78
. .
1.26e4
Area
Oj
I;;;-
Time
2.00
4.00
6.00
8.00
Exygen Research, 3058 Research Drive, State College, PA 16801
000378
we-
-----
----m--m---
-----
----
Quantify Sanrple Report
w Study No.:L34910,
Set No.: 080103AR, Ra&.Date:O8/01/03,
Analyst:X.Risha
Page 17
Sample List:
Last modified: Method: Last modified: Jab Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leD~\O8OlO3~
Tue Aug 05 07:24:43
2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 000103
Printed: ----w-w---_
Tue Aug 05 07:32:01 2003 ---_----------___I___
--we--
Name: 080103AR-309 Text:
: C8 Acid (PFOA)
-34910-11 SpkE,5000ng./L,DF=100
160103AFb309 10
Sm (Mn, 2x3)
MRM of 4 Channels ES-
9.13
413 > 369
2937
1.82&i
Area
T
2.00
4.00
6.00
8.00
: C6 Sulfonate
(PFHS)
.34910-11 SpkE,5000ng/L,DF=lOO
Time 1
~60103AR-309 10
Sm (Mn, 2x3)
MRM of 4 Channels ES399Bao 2.6ae4 Area
3: C8 Sulfonate
(PFOS)
L34910-11 SpkE,SOOOng/L,DF=lOO
060103AR-309 10
Sm (Mn, 2x3)
6.00
9.25
51842
6.00
a.00
Area Time
Rxygen Research, 3058 Research Drive, State College, PA 16801
v-m--
--------
w------e---
-----
--------e---P-__
Quantify Sample Report
,,= Study No.:L34910,
Set No.: 080103AR, Ext.Date:08/01/03,
Analyst:X.Risha
Page 18
Sample List: Last modified: Method:
Last moUified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochsmicals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\Lc3MSMS6\Masslynx\Fluorochemicals.PRO\~ethDB\Decatur Sun Aug 03 07:11:59 2003
Decatur BC EC 080103
Printed:
Tue Aug 05 07:32:01 2003
--
------------------__________I_________-_
Name:
Text:
080103AR-309
: PFOSA
.34910-l 1 Spk E, 5000 rig/L, DF=lOO
MO1 03AR-309 10
Sm (Mn, 2x3)
%
04-Aug-2003 11:29:3f
LC/MS/MS #E
MRM of 4 Channels ES-
9.87 2187C 1
498 > 78 1.12e5
Area
1
L
Time
Exygen Research, 3058 Research Drive, State College, PA 16801
000380
----------__-------_--
-------e-w----
-----
Quantify Sample Report +, Sway NO .:L34910, Set No .:080103AR, Ext.Date:08/01/03,
Aualyst:K.Risha
Page 19
Stunple List: Last maifiea: Method: Last modified:
Job code:
P:\Data\L~SMS6\blasslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Tus Aug 05 07:24x43 2003 P:\Data\LeMSMS6\~sslynx\Fluorochamicals.PRO\MetMB\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed: e----d-
Tue Aug 05 07:32:01 2003
----------------
-----------
Name : 080103AR-310 Text:
-----------__--_-
: C8 Acid (PFOA) -34910-20SpkF,5000nglL,DF=l00
180103AR-310 10
Sm (Mn, 2x3)
04-Aug-2003 11:51:14)
LC/MS/MS#6
9.13 2826
MRM of 4 Channels ES413>369 1.66e5
Area
2.00
4.00
6.00
8.00
: C6 Sulfonate (PFHS) ,34910-20SpkF,5000ng/L,DF=lOO
380103AB310 10
Sm (Mn, 2x3)
LC/MS/MS#6
MRM of 4 Channels ES-
8.96
399 > 80
433t
2.50e4
Area
I(
: C8 Sulfonate (PFOS)
.34910-20SpkF,5000
ng/L,DF=lOO
)80103AR-310 10
Sm (Mn, 2x3)
04-Aug-200311:51:1
MRM of 4 Channels ES499 > 99 5.36e4 Area
Time
Rxygsn Research, 3058 Research Drive, State College, PA 16801
0003Rl.
Quantify Sample Report
,J Study No.:L34910,
Set No.: 080103AR, Ext.Date:08/01/03,
Analyst:K.Risha
Page 20
Sample List: Last modified: Method:
g;tCrdFfied: :
P:\Data\LCMSMS6\MasslyPx\Fluorochemicals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\LCMSMS6\Masslynx\fluorochamicalsB\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01 2003
-----_
-----_----_----~--~~~-
_-------
we---
-----
Name : 080103AR-310 Text :
: PFOSA
-3491 O-20 Spk F, 5000 rig/L, DFd 00
180103AFb310 Sm (Mn, 2x3)
10
"$ -1
%
i
i
O'~~~~,~~~~,`~~~,~~~`,~"`,"~`,~~'~,"'~,~'~~,~',
2.00
4.00
6.00
8.00
04-Aug-2003 1151 :14j
LC/MS/MS #6
MRM of 4 Channels ES-
9.90 13521
498 > 78 6.94e4
Area
-
r
,
Exygen Research, 3058 Research Drive, State College, PA 16801
00038Z
,,,-,,
X,".,.l.-
.._
--_-,
_."I
l-,.l-ll.-
,.._
._-,
.~l---ll
-.
-__-----------------ll-_---------
Quantify Sample Report
'14 Study No.:L34910,
Set No.:080103AR,
Ext.Date:08/01/03,
Analyst:X.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluoroch~cals~PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\LQIISMS6\MasslyPx\FluorochemicalB\Decatur Sun Aug 03 07:11:!59 2003
---
Page 21
Decatur BC BC 080103
Printed: -----__
Tue Aug -----
Name: 080103AR-311 Text :
05 07:32:01 2003 ----------------w-m-
---------___
: C8 Acid (PFOA)
-3491 O-5, DF=lO
>80103AR-311 10
Sm (Mn, 2x3)
, %-j
i 4
2.00
04-Aug-2003 12:12:52 LC/MS/MS #6
MRM of 4 Channels ES413 > 369 1.06e5 Area
Time 10.00
!: C6 Sulfonate
(PFHS)
L34910-5, DF=lO
04-Aug-2003 12:12:5
380103AR-311 Sm (Mn, 2x3) 10 85.8916
I-~`~,~~,,.,,,~,,,,,,,,,,,~,,,,~,,,,,,,,,,,,~,~~,,,,,,~,..,..,,
Time
2.00
4.00
6.00
8.00
10.00
RWgen Research, 3058 Research Drive, State College, PA 16801
-P-M---
-----------
-----------s---m-
Quantify
Sample Report
',d Study No.:L34910,
Set No .:080103AR, Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method:
Last nodified: Job Code:
P:\Data\LCMGMS6\Massly\Fluoroch~cals.PRO\SampleDB\O80103AR Tue Aug 05 07:24:43 2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Tus Aug 05 07:32:01
2003
---
Page 22
Decatur BC BC 080103
Name: 080103AR-311 Text :
: PFOSA
.3491 O-5, DF=lO
180103AFb311
10
Sm (Mn, 2x3)
% 1
04-Aug-2003 12~1252
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
1668C )
498 > 78 .8.67e4
Area
O',,.,,"~,,`,,,,,,,`,"",,,,,,,`,,,,"',,',',,,,.
IL-
Time
2.00
4.00
6.00
8.00
10.00
Ewgen Research, 30.58 Research Drive, Stata college,
PA 18801
000384
Quantify Sample Report
Study No.: L34910,
Set No .:080103AR,
$4
Ext.Date:08/01/03,
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Ma~~l~\Fluoroch~cals.~~\S~leDB\O8OlO3~
Tue Aug 05 07:24:43
2003
P:\Data\LQISMS6\Masslynx\PluorochsmiEalsB\Decatur
Sun Aug 03 07:11:59
2003
Printed: ----
Tue Aug 05 07:32:01
----_
--------
2003 -w--e-------
Name: 080103AR-312
Text :
1: C8 Acid (PFOA)
IL3491 O-5 Rep, DF=lO
080103AR-312 Sm (Mn, 2x3)
2.00
2: C6 Sulfonate
(PFHS)
`u' L3491 O-5 Rep, DF=lO
080103AFb312 Sm (Mn, 2x3)
Analyst:X.Risha
Page 23
Decatur
BC
BC 080103
---
-----
04-Aug-2003 12:34:34
LC/MS/MS #6
MRM of 4 Channels ES-
413r369
.
8.59e4
Area
Time
3: C8 Sulfonate
(PFOS)
L3491 O-5 Rep, DFd 0
080103AFk312 Sm (Mn, 2x3)
1 Time
04-Aug-2003 12:34:3d
MRM of 4 Channels ES9.24 7449
wgen
Research,
3058 Research
Drive,
State College,
PA 16801
60038s
------
__-----
-----
---1----------__
Quantify Sample Report
Study No.:L34910,
Set No .:080103AR,
Ext.Dats:08/01/03,
Analyst:K.Risha
Page 24
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Wasslynx\Fluorochamicals.PRO\S~leDB\O~OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\LCMSMS6\Masslynx\FluorochemicalsB\Decatur
Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01 2003
------~--------~------------
--P---P--__
Name: 080103AR-312 Text :
4: PFOSA
IL3491 O-5 Rep, DF=lO
080103AFb312 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 12:34:35(
LC/MS/MS #6
MRM of 4 Channels ES-
9.87
498>78
9.40e4
Area
Exygen Research, 3058 Research Drive, State College, PA 16801
0003f3G
--v---s----
-------
--e--w---
Quantify Sample Report
Study No.:L34910, w
Set No.: 080103AR, Ext.Date:08/01/03,
Analyst:K.Riaha
SangZle Liat:
P:\Data\L~S2HS6\bssl~\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:.
Tue Aug 05 07:24:43 2003
Method:
Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Tue Aug 05 07:32:01 2003
---------_
Page 25
Decatur BC BC 080103
Name: 080103AR-313 Text :
1: C8 Acid (PFOA)
L3491 O-1 0, DF=lO
080103AR-313 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 12:56:21 LC/MS/MS #6
MRM of 4 Channels ES413> 369 1.86e5 Area
0---
I
r I , I , , , , I , Time
2.00
4.00
6.00
8.00
10.00
~ 2: C-.6 -S--u-l-fanate----- ,fP__F-H--S, 1
1.3491 O-l 0, DF=lO
C)80103AR-313 lOO:
Sm (Mn, 2x3)
%-
040Aug-2003 12:56:2'
LC/MS/MS #E
MRM of 4 Channels ES-
8.96 1564-
399 > 8C 9.26eZ
Are5
!-
3: C8 Sulfonate
(PFOS)
L3491 O-l 0, DF=lO
080103AR-313 loo-
Sm (Mn, 2x3)
%-
9.25 _ 14012
04-Aug-2003 12:56:21 LCIMSNS #6
MRM of 4 Channels ES499 > 99 8.15e4 Area
Exygen Research, 3058 Research Drive, State College, PA 16801
000387
Quantify Sample Report Study No.: L34910, Set No.:O80103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
Sawple List: Last modified: Method: Last modified: Job Code:
P:\Data\LCWSMS6\Masslynx\Fluorochemicals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\L~SMS6\Masslynx\FluorochemicaB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Tue Aug 05 07:32:01 2003
Page 26
Decatur BC BC 080103
Name : 080103AR-313 Text :
4: PFOSA
L3491 O-1 0, DF=lO
080103AR-313 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 12:56:21
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
I .Ol e5
Area
Fxygen Research, 3058 Research Drive, Stats College, PA 16801
000388
-------------
--__--_-------
------7----
Quantify Sample Report Study No.: L34910, Set NO .:080103AR,
Rxt.Date:08/01/03,
Aualyst:K.Risha
Sample List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SMS6\Mssl~\Fluoroch~cals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\LCM~S6\Masslynx\Fluorochsmicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Printed:
Tue hug OS 07:32:01 2003
Page 27
Decatur BC BC 080103
Name: 080103AR-314 Text :
: C8 Acid (PFOA)
-3491 O-l 0 Rep, DF=lO
)80103AR-314 10
Sm (Mn, 2x3)
9.13 ,3106:
04-Aug-2003 13:18:lC
LC/MShlS #6
MRM of 4 Channels ES413 > 369 1.85e5 Area
4
hLb=
Time
L
2.00
4.00
6.00
8.00
10.00
2: C6 Sulfonate
(PFHS)
`& L3491 O-l 0 Rep, DF=lO
080103AFb314 100-I
Sm (Mn, 2x3)
%-
04-Aug-2003 13:18:lC
LC/MS/MS #6
MRM of 4 Channels ES-
8.96
399 > 80
1811
l.lOe4
Area
0 ,,,,1,,~,,.,,.,,,,,,,,.,,~,,,,,,,,,,,,,,,,,
, - 7. , I I Time
2.00
4.00
6.00
8.00
10.00
: C8 Sulfonate
(PFOS)
-3491 O-l 0 Rep, DF=lO
)80103AR-314 10
Sm (Mn, 2x3)
04-Aug-2003 13: 18: 1C LC/MS/MS #6
MRM of 4 Channels ES499 > 99 9.18e4 Area
Rxygen Research, 3058 Research Drive, State College, PA 16801
QQ0389
-v-s---
----------------I_____________
--v-v
Quantify Sample Report Study No.: L34910, Set No.:O80103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 28
Sample List: Last modified:
Method: Last modified:
sob Code:
P:\Data\L~SMS6\Ma~sl~\Fluorochamica~s.PRO\S~leDB\O8OlO3~
Tue hug 05 07:24:43 2003
P:\Data\L~SMS6\Masslynx\Fluorochamicals.P~\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Decatur BC BC 080103
Printed: --------
Tue Aug 05 07:32:01 2003 ------------------____I______
Name: 080103.m-314 Text:
:: PFOSA
-3491 O-l 0 Rep, DF=l 0
380103AR-314
10 "$
%d
Sm (Mn. 2x3)
I
,
-I
04-Aug-2003 13:18:1(
LWMSIMS #E
MRM of 4 Channels ES-
9.67
498>7E
2686:
1.41e5
Area
Time
, Exygen Research, 3058 Research Drive, State College, PA 16801
000390
-----------
---------
----s-Y----
Quantify
sample Report
Study No.: L34910,
Set No.:O80103AR,
u
Ext.Date:08/01/03,
Sample List:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:
Tus Aug 05 07:24:43
2003
Method:
P:\Data\LCMSMS6\Masslyzuc\FluorochamicalB\Dacatur
Last modified:
Sun Aug 03 07:11:59
2003
Job Code:
Printed: ----
-__-__
Tue Aug 05 07:32:01
2003
-----__--
---------------__----------------------------
Name: Text:
080103AR-315
: C8 Acid (PFOA)
(CO72503-1,25 rig/L Standard
J80103AR-315 1001
%
Sm (Mn, 2x3)
----__---__
Analyst:R.Risha
Page 29
Decatur
BC
BC 080103
04-Aug-2003 13:39:58 LCIMSNS #6
MRM of 4 Channels ES413> 369 8.23e4 Area
0
!: c6 Sulfonate
KC072503-1,25
(PFHS)
rig/L Standard
380103AR-315 10
Sm (Mn, 2x3)
Time
04-Aug-2003 13:39:5d
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
2099
1.27e4
Area
f
0 ,..r,.-.,....,,..,,,..,,...,,,,..,....,,.,!
2.00
4.00
6.00
3: C8 Sulfonate
: KCO72503-1,25
(PFOS)
rig/L Standard
380103AR-315 10
9
Sm (Mn, 2x3)
8.00
T-
9.24 1301
10.00
1
04-Aug-2003 13:39:58 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 8.29e3 Area
un 1 ,~~~,(~~`,~~~~,~~`~,`1~~,~~`~,~`1',"'~,'~~~/
I Time
2.00
4.00
6.00
8.00
10.00
Wgen
Research,
3058 Research
Drive,
State College,
PA 16801
000391
--w---m-------
------------------
---
Quantify Saqle Report Study No. : L34910, Set No.:O80103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
Page 30
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicalst~B\Decatur Sun Aug 03 07:11:59 2003
Decatur BC BC 080103
Printed:
-------__------
Tue Aug 05 07:32:01
2003
--------------l__-
Name: 080103AR-315 Text:
4: PFOSA
/XCO72503-1,25
rig/L Standard
080103AFb315 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 13:39:5d
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
498>78
2.30e4
Area
Oxygen Research, 3058 Research Drive, State College, PA 16801
Quantify S-10 Report
Study No.:L34910,
Set No .:080103AR, Ext.Date:08/01/03,
Analyst:K.Risha
Cd
Sample List:
P:\Data\L~S6\~ssl~\Fluoroch~cals.PRQ\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LQlmS6\Masslynx\Fluorocbemicals.PRO\~et~B\Decatur
Last modified:
Sun Aug 03 07:11:59 2003
Job code:
Page 31
Decatur BC BC 080103
Printed:
---4------e--
Tue
Aug 05
------____----
07:32:01
2003
---c-----------___---------
Name: 080103AR-316 Text :
1: C8 Acid (PFOA)
XCO72503-2,50 ngJL Standard
080103AR-316 lOc--
Sm (Mn, 2x3)
%-
9.12
254147
04-Aug-2003
1 14:01:43
LC/MSJMS #6
MRM of 4 Channels ES-
413>369
1.50e5
Area
: C6 Sulfonate
(CO72503-2,SO
(PFHS)
ngJL Standard
180103AFL316
10 "3
Sm (Mn, 2x3)
8.9Z j 421' 1
04-Aug-2003 14:01:44 LCIMSIMS #6
MRM of 4 Channels ES399 > 80 2.50e4 Area
2.00
4.00
6.00
: C8 Sulfonate
(PFOS)
(CO72503-2, 50 ngJL Standard
)80103AR-316 10
Sm (Mn, 2x3)
J
i
Ok..,...,,....,..`,,..`.,"..,.`.',...,,
2.00
4.00
6.00
% V
8.00
10.00
Time 1 I
7
04-Aug-2003 14:01:43
LCJMSJMS #6
9.2! i 286( I
MRM of 4 Channels ES499 > 99 1.66e4
Area
I___
Time
8.00
10.00
kygen Research, 3058 Research Drive, State College, PA 16801
0003!?3
--
--------------
---------me
-
Quantify Sample Report
Study No.rL34910,
set NO .:080103AR, Eact.Date:08/01/03,
Analyst:K.Risha
Ud
Sample List:
P:\Data\LCM~S6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\Decatur
Last modified:
Sun Aug 03 07:11:59 2003
Job Code:
Page 32
Decatur BC EC 080103
Printed:
-m-e--
Tue Aug 05 07:32:01 2003 -------------------_-~-_-------------_-_____
Name: 080103AR-316 Text :
: PFOSA
(CO72503-2,50
rig/L Standard
180103AR-316 10
Sm (Mn. 2x3)
.
.
I
% 3
04-Aug-2003 14:01:4I
LCIMSIMS #f
MRM of 4 Channels ES-
9.90 I 8991
498 > 7E 4.83e4
Arez
o'~"~,`~`~,~`~~,~~~`,~;`~,`~",~~'~,'~",~'~~,~~~
Time
2.00
4.00
6.00
8.00
Rwgen Research, 3058 Research Drive, State College, PA 16801
000394
Quantify Sample Report
Study No.: L34910, Set No.: 080103AR, Ext.Date:08/01/03,
Analyst:K.Risha
tic,
Sample List:
P:\Data\LCMSMS6\Masalynx\Fluoroc~~cals.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LCMSMS6\EIaaslynx\Fluorochemicalr
Last modified:
Sun Aug 03 07:11:59 2003
irob Code:
Printed: ---
Tue Aug 05 07:32:01 2003 ------me-------
~---~---------------_
Name: 080103AR-317 Text :
: C8 Acid (PFOA)
.3491 O-1 1, DF=lOO
)80103AR-317 Sm (Mn, 2x3)
9.11
10
941(
-I
Page 33 Decatur SC BC 080103
04-Aug-2003 14:23:2? LC/MS/MS #6
MRM of 4 Channels ES-
413 > 369 5.65e4 Area
Time
2.00
4.00
6.00
8.00
1o:oo
2: C6 Sulfonate
(PFHS)
`& L3491 O-1 1, DF=l 00
080103AFb317 Sm (Mn. 2x3)
04-Aug-2003 14:23:2? LC/MS/MS #6
MAM of 4 Channels ES399 > 80
Oi.,.,,....,..,.,,...,.,,,,....,...~,....,....,..~.,~~.~,.~~.
Time
2.00
4.00
6.00
8.00
10.00
3: C8 Sulfonate
(PFOS)
L3491 O-1 1, DF=lOO
080103AR-317 Sm (Mn, 2x3)
04-Aug-2003 14:23:2?
LC/MSlMS #6
MRM of 4 Channels ES-
9.24
499 > 99
3.85e5
Area
Exysen Research, 3058 Research Drive, State College, PA 16801
-------------__-----_----
----e--------w-----
--------
Quantify
Sample Report
study No.:L34910*
Set No.:080103AR,
Ea&.Date:08/01/03,
Analyst:K.Risha
\r,
Sample List:
P:\Data\LX=MSHS6\Masslyax\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur
Laet modified:
Sun Aug 03 07:11:59 2003
Job Code:
Printed:
Tus Aug 05 07:32:01 2003
Page 34
Decatur BC BC 080103
Name: 080103AR-317 Text:
4: PFOSA
L3491 O-1 1, DF=lOO
080103AR-317 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 14:23:27
LC/MS/MS #6
MRM of 4 Channels ES-
9.89 219887
498 > 70 1.09e.5
Area
0 "","",11","","","","`1,"","'
I,1II
I I 1 , , , I , Time
2.00
4.00
6.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
----------
--------
-------___
------a---
Quantify
Sample Report
Study No .:L34910, Set No .:080103AR, Xxt.Date:08/01/03, ',d
Analyst:X.Risha
S~lei List:
P:\Data\Lc3MSMS6\Masslyrur\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\~et~B\Decatur
Last modified:
Sun Aug 03 07:11:59 2003
Job Code:
Page 35
Decatur BC BC 080103
Printed: ---_-
'he Aug -~--------_-
Name: 080103AR-318 Text :
05 07:32:01 2003 -----
-------_-m___
-I------____
1: CS Acid (PFOA)
IL3491 O-l 1 Rep, DF=lOO
080103AFb318 100-
Sm (Mn, 2x3)
%-
04-Aug-2-003 14:45:lj LCNSIMS #6
MRM of 4 Channels ES413>369 5.66e4 Area
O';`,,,r,,,,,,,,,,,,,,,,,,,,~
2.00
4.00
2: C6 Sulfonate
(PFHS)
w L3491 O-l 1 Rep, DF=lOO
080103AR-318 Sm (Mn, 2x3)
,II,Iq
I,,!
6.00
,I I 8.00
8.95 207
, , ,";`: 10.00
, , , , , , ,h Time
04-Aug-2003 14:45:17 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.56e3 Area
2.00
4.00
6.00
8.00
10.00
3: C8 Sulfonate
(PFOS)
L3491 O-l 1 Rep, DF=lOO
080103AFb318 10
i
Sm (Mn, 2x3)
9.25 48518
04-Aug-2003 14:45:17 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.82e5 Area
L Emen Research, 3058 Research Drive, State College, PA 16801
Time 000397
--_ .-.
. .._-._. -.----
--.. -
--s--p
---s---P-----
---_-
---
Quantify
Sample Report
Study No.: L34910, Set No.:O80103AR, 'J
Ext.Date:O8/01/03,
Analyst:K.Risha
Saznple List:
P:\Data\LCMSMS6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug OS 07:24:43 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluorochamicalsr
Last modified:
Sun Aug 03 07:11:59 2003
Job Code:
Page 36
Decatur BC BC 080103
Printed: ----------------b-----s
Tue Aug
Name: 080103AR-318 Text :
05 07:32:01 2003 ----------
---_^----
-m-m----
: PFOSA -3491 O-l 1 Rep, DF=lOO
380103AR-318 Sm (Mn, 2x3)
10
"i J
%10~.`.~,"~.,`~`.,."`,`...,~`~.,~~'.,~"','.'.,.~~
2.00
4.00
6.00
8.00
04-Aug-2003 14:45:17
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
498 > 78
16405
0.63e4
Area
1.
Time
Ekygen Research, 3058 Research Drive, State College, PA 16801
000398
Quantify
Sample Report
Study No.: L34910, Set No .:080103AR,
Ext.Date:08/01/03,
Analyst:X.Risha
Page 37
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cal~.PRO\S~leDB\O8OlO3~
Tus Aug 05 07:24:43 2003 P:\Data\LCM~S6\Masslynx\Fluorochemica\Decatur Sun Aug 03 07:11:59 2003
Decatur BC EC 080103
Printed: --------s-e---
Tus Aug 05 07:32:01 2003 ___---------------------
m-w-- ---------
Name: 080103AR-319 Text :
1: C8 Acid (PFOA)
iL3491 O-l 1, DF=lO
`080103AR-319 IOO-
Sm (Mn, 2x3)
%-
9.11 _
80473
04-Aug-2003 l&07:04 LC/MS/MS #6
MRM of 4 Channels ES413>369 4.67e5 Area
!: C6 Sulfonate
(PFHS)
L3491 O-l 1, DF=l 0
080103AR-319 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 15:07:04
LC/MS/MS #6
MRM of 4 Channels ES-
a.95
399 > 80
1.36e4
Area
0 /, , I, I ,-. I,, .1), 2.00
3: C8 Sulfonate
(PFOS)
L3491 O-1 1, DF=lO
. r I I,. 1 I., 4.00
1 I, I, F<", 6.00
/ I I I, 8.00
080103AR-319 100-
Sm (Mn, 2x3)
9.25 _
526238
%-
10.00 ,-, , , , , Time
04-Aug-2003 15:07:04 LCIMSIMS #6
MRM of 4 Channels ES499 > 99
3.05e6
Area
, , I , I I , I I I I Time
2.00
4.00
6.00
8.00
10.00
&Id
Exygen Research, 3058 Research Drive, State College, PA 16801
000399
Quantify Sample Report ',d Study No .:L34910, Set No .:080103AlZ,
Ext.Date:08/01/03,
A.nalyst:K.Risha
Sample List: Last modified: Method: Last nmdifiad: Job Code:
P:\Data\L~SMS6\~sslynx\Fluoroch~cals.PRO\S~~eDB\O8OlO3~ Tua Aug 05 07:24:43 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 38
Decatur EC BC 080103
Printed: --e-e------------
Tua Aug 05 07:32:01 2003 -----
-----__--------___
Name: 080103Xfi-319 Text:
4: PFOSA
IL3491 O-l 1, DF=lO
080103AR-319 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 15:07:04/
LC/MS/MS #6
MRM of 4 Channels ES-
9.87
498 > 78
1 O.OOe5
Area
2 , , , , , , , Time 10.00
Exygen Research, 3058 Research Drive, State Collega,
PA 16801
II-
______
__-___l----.---
000400
Quantify Sample Report
Study No.:L34910,
Set No .:080103AX,
Ext.Date:08/01/03,
Analyst:X.Risha
\r,
Sample List:
P:\Data\LCM~S6\Mas~lynx\Fluoroch~cals.P~\S~leDB\O8OlO3~
Last xuodified:
Tue hug 05 07:24:43 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluorochemical9\Decatur
Last modified:
SW hug 03 07:11:59 2003
Job Code:
Printed:
Tue hug OS 07:32:01 2003
Page 39
Decatur BC BC 080103
Name: 080103AR-320 Text:
1: CB Acid (PFOA)
L3491 O-l 1 Rep, DF=lO
080103AR-320 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 15:28:46j
LC/MS/MS #6
MRM of 4 Channels ES413>369 4.58e5 Area
0 "1',"","",""["","","","",""
, , , , , , I , , , , Time
2.00
4.00
6.00
8.00
10.00
2: C6 Sulfonate
(PFHS)
13491 O-1 1 Rep, DF=lO
080103AFb320 100-
Sm (Mn, 2x3)
%-
8.96 _ 2458
04-Aug-2003
1
15:28:46
LC/MS/MS #6
MRM of 4 Channels ES-
399 > 80
1.49e4
Area
I: CB Sulfonate
(PFOS)
L3491 O-1 1 Rep, DFdO
04-Aug-2003 15:28:46
LC/MS/MS #6
080103AR-320 Sm (Mn, 2x3)
MRM of 4 Channels ES-
10
% 1
9.25 390663
L
499 a- 99 2.30e6 Area
Time
2.00
4.00
6.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
OoQ4Qa
--w--w--___
----w---s--
-------e-----
--c----I__I
Quantify Sample Report
Study No. : L34910, Set No.:O80103AR, 44
Eatt.Date:08/01/03,
Analyst:K.Risha
Sample List:
P:\Data\LCMSMS6\Maaslynx\Fluorochamicals.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LCHSMS6\Masslynx\Bluoroch~cals.PRO\Met~B\Decatur
Last modified:
Sun Aug 03 07:11:59 2003
Job Code:
Page 40
Decatur BC BC 080103
Printed: -m---_-v
Tue Aug 05 07:32:01 2003 -_-_----__-----__--_______l___l-_
Name: 080103AR-320 Text:
-7--e--w--__
: PFOSA
-34910-l 1 Rep, DF=lO
)80103AR-320 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 15:28:46
LC/MS/MS #6
MRM of 4 Channels ES-
9.87 i503ad c
498 r 78 7.59e5
Area
0- ~~~~,~~~~,~1~,,"~,(ll~~,'~~~,~~~~,~'~',~~'~,'~C
i-
Time
L
2.00
4.00
6.00
8.00
10.00
E-en
Research,
3058 Research Drive,
State College,
PA 16801
Quantify Sample Report Study No. : L34910, Set No .:080103AR,
Ext.Date:oa/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCM~S6\MasSl~\FluOrocbemicalS.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003
P:\Data\LCMSMSS\Masslynx\Fluorochamical8.PRO\Met~R\Decatur Sun Aug 03 07:11:59 2003
Printed:
Tue Aug 05 07:32:01
2003
Page 41
Decatur BC BC 080103
Name: oaoio3sb321
Text :
1: C8 Acid (PFOA) L3491 O-20, DF=l 00
080103AR-321
loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 15:50:25
LC/MS/MS #6
MRM of 4 Channels ES-
9.12
413 > 369
4.43e4
Area
2.00
2: C6 Sulfonate (PFHS) L3491 O-20, DF=lOO
080103AR-321 10
Sm (Mn, 2x3)
I , I , , , . , , , , , ,\ Time 10.00
04-Aug-2003 1550324
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
334
2.23e3
Area
3: C8 Sulfonate (PFOS) L3491 O-20, DF=lOO
080103AR-321 Sm (Mn, 2x3)
04-Aug-2003 15:50:25
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 3.96e4 Area
Time
Oxygen Research, 3058 Research Drive, State College, PA 16801
QQQM?3
Quantify Sample Report
Study No.:L34910,
`id
Set No .:080103AR, Ext.Date:00/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Dats\LCblSMS6\Masslynx\Fluoroch~cal8.PRO\S~leDB\O8OlO3~ !Pue Aug 05 07:24:43 2003 P:\Data\LCMSMS6\Masslynx\FluarachamicarsB\Decatur Sun Aug 03 07:11:59 2003
Printed:
Tue Aug 05 07:32:01
2003
Page 42
Decatur BC BC 080103
Name: 080103AR-321
Text :
4: PFOSA
L3491 O-20, DF=lOO
080103AR-321 Sm (Mn, 2x3)
04-Aug-2003 15:50:2t LC/MS/MS #E
MRM of 4 Channels ES498 > 78 3.40e4 Area
Time
Exygen Research, 3058 Research Drive, Stats College, PA 16801
000404
Quantify Sample Report
Study No. : L34910, Set No.:O80103AR, ',d
Ext.Date:O8/01/03,
Analyst:R.Risha
Sanrple List:
P:\Data\LCMSMS6\Ma5slynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LCMSMS6\MaSslynx\Fluoroch~cals.PRO\Met~B\Decatur
Last modified: Job Code:
Sun Aug 03 07:11:59 2003
Page 43
Decatur BC BC 080103
Printed: ----------me-----___
Tue Aug 05 07:32:01 2003 -_--__-_------
----_-------___~
Name: 080103AR-322 Text :
1: C8 Acid (PFOA)
IL3491 O-20 Rep, DF=i 00
080103AR-322 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 16:12:Oij LC/MS/MS #6
MRM of 4 Channels ES413>369 3.44e4 Area
O~,,,,,~,,,,,,,,.,~-;-rn-,,,,,,,
, , , ,m
Time
2.00
4.00
6.00
8.00
10.00
,,& 2: C6 Sulfonate
(PFHS)
L3491 O-20 Rep, DF=lOO
080103AR-322 Sm (Mn, 2x3)
04-Aug-2003 16:12:07
LCIMSNS #6
MRM of 4 Channels ES-
8.93
399 > 80
2307
1.76e3
Area
2.00
4.00
6.00
8.00
3: C8 Sulfonate
(PFOS)
IL3491 O-20 Rep, DF=lOO
080103AR322 Sm (Mn, 2x3)
/ %P
2.00
4.00
6.00
8.00
ExyOen Research, 3058 Research Drive, State College, PA 18801
10.00
04-Aug-2003 16: 12:0-/1 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.76e4 Area
10.00
Time
080405
-v--m
--w-v--
_------
-----------1___
Quantify Sample Report
Study No .:L34910, Set No.:O80103~R,
Ext.Date:08/01/03,
'4
Analyst:K.Rlsha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Piassl~\Fluoroch~cals.RRO\S~leDE\O8OlO3~ Tue Aug 05 07:24:43 2003 P:\Data\L~SMS6\Maeslynx\FluorochemicalB\D~catur Sun Aug 03 07:11:59 2003
Page 44
Decatur BC BC 080103
Printed:
Tus Aug 05 07:32:03 2003
--------~---------__-_-------,----------~-,
Name: 080103AR-322 Text :
-P--1-----
1: PFOSA
-3491 O-20 Rep, DF=lOO
380103AR-322 10
7
%-j
Sm (Mn, 2x3)
.
I
04-Aug-2003 16: 12:07
LC/MS/MS #6
MRM of 4 Channels ES-
9.9c ) 537'
498 > 78 2.09e4
Area
Time
6.00
8.00
men
Research, 3058 Research Drive, State College, PA 16801
--I-------------___---__l_______l_____---~
Quantify Sample Report Study No .:L34910, Set No.:O80103AR,
Ext.Date:08/01/03,
Analyst:K.Riaha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Maselynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~ Tue Aug OS 07:24:43 2003 P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Print sd :
Tue Aug 05 07:32:01 2003
Name: 080103AR-323 Text:
1: C8 Acid (PFOA)
----
Page 45
Decatur BC BC 080103
080103AFb323 Sm (Mn, 2x3)
MRM of 4 Channels ES-
2: C6 Sulfonate
XCO72503-3,100
(PFHS)
rig/L Standard
080103AR-323 Sm (Mn, 2x3)
3: C8 Sulfonate
XCO72503-3,100
2.00
4.00
(PFOS)
rig/L Standard
080103AR-323 Sm (Mn, 2x3)
04-Aug-2003 16:33:5C
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
4.74e4
Area
10.00
04-Aug-2003 16:m:sd
LC/MS/i'vlS #6
MRM of 4 Channels ES499 > 99
Area
Bxygen Research, 3958 Research Drive, State College, PA 16801
----
----------__I-
-----I_-------
Quantify Sample Report
Study No .:L34910, Set No .:080103AR, Ext.Date:O8/01/03,
Analyst:K.Risha
'W
Sample List:
~:\Data\L~SMS6\~sslynx\Fluoroch~cals.PRO\S~leDB\O6OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LCMSMS6\Masslynx\FluorochemicalsR\D~catur
Last modified:
Sun Aug 03 07:11:59 2003
Job Code:
Printed:
Tua Aug 05 07:32:01 2003
Page 46
Decatur BC BC 080103
Name: 080103AR-323 Text :
: PFOSA (CO72503-3,100
rig/L Standard
180103AR-323 10
Sm (Mn, 2x3)
% 1
i
04-Aug.2003 16:33:X
LCYMSIMS #6
MRM of 4 Channels ES-
9.89
498 > 78
17621
9.3104
Area
Oxygen Research, 3058 Research Drive, State College, PA 16801
----I_-----~----I---I-
s-m------
Quantify S-10 Report
Study No.: L34910, Set No .:080103AR, Xxt.Date:08/01/03,
Analyst:X.Risha
'4
Smgls List:
P:\Data\LCMSblS6\Masslyrur\$luoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:X:43
2003
Method:
P:\Data\L~SMS6\Pssl~\FluorochamicR\Decatur
Last modified:
Sun Aug 03 07:11:59 2003
Job Code:
Page 47
Decatur BC BC 080103
Printed: -------m-P
Tam Aug 05 07:32:01 -L_4---
Name: 080103AR-324 Text:
2003 ----M--P_-
--
-----
1: C8 Acid (PFOA)
XCO72503-4,250 rig/L Standard
080103AFb324 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 16:55:35
LC/MS/MS #6
MRM of 4 Channels ES413>369 5.78e5 Area
0 ,,,,,~.,,,,,,,,,",,,.,,..,`,`,,`,,,",,,,,
2.00
4.00
6.00
8.00
1: C6 Sulfonate
KO72503-4,250
(PFHS)
rig/L Standard
180103Ak324 10
Sm (Mn, 2x3)
6.96 17041
04-Aug-2003 16:55:35] LC/MS/MS #6
MRM of 4 Channels ES399 > 80 1.05e5 Area
2.00
4.00
6.00
8.00
10.00
I: C8 Sulfonate
KC072503-4,250
(PFOS)
rig/L Standard
080103AFG324 Sm (Mn, 2x3)
9.24 1164Z 3
04-Aug-2003 16:55:35
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 6.79e4 Area
IL--
2.00
4.00
6.00
8.00
10.00
Fxygen Research, 3058 Research Drive, State College, PA 16801
Time
oaa4e9
--------II____-__---_--------~-----
--
Quantify Sample Report
Study No .:L34910, Set No.:080103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
%d
Semple List:
P:\Data\L~SMS6\Mssslynx\Pluoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:
me Aug 05 07:24:43
2003
Method:
P:\Data\LCMSMS6\~sslynx\Fluorochemicalt~B\Decatur
Last modified:
Sun Aug 03 07:11:59 2003
Job Code:
Page 48
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01 2003
--_--__--_____------------------------------------
-----e--m
Name: 080103AR-324 Text :
4:: PFOSA
r1l(CO72503-4,250
rig/L Standard
380103AR-324 10
Sm (Mn, 2x3)
% 3
1
O'~~,~,~~~.,~~`~,~~",~~`~,~`~`,~~'.,'~~~I~"~I~~~
2.00
4.00
6.00
04-Aug-2003 16:55:3d
LC/MS/MS #6
MRM of 4 Channels ES-
9.89 4010: 3
498 > 78 2.14e5
Area
L
Time
8.00
Exygea Research, 3058 Research Drive, State College, PA 16801
QQQ410
Quantify
Sample Report
Study No.: L34910, Set N0.:060103AR,
Ext.Date:08/01/03,
Analyst:K.Risha
yud
Sample List:
P:\Data\L~SMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\LCMSMS6\Mssslynx\Fluorochemicals\Decatur
Last modified:
Sun Aug 03 07:11:59
2003
Job Code:
Page 49
Decatur BC BC 080103
Printed:
---_
`he --------_-------
Aug 05 07:32:01
2003 ---------------------
---_--___
---B---e_
Name: 080103AR-325
Text :
1: C8 Acid (PFOA)
13491 O-20, DF=lO
080103AR-325 10
Sm (Mn, 2x3)
0", i
9.11 61092
I
04-Aug-2003 17:17:2C
LCYMWMS #6
MRM of 4 Channels ES413>369 3.65e5 Area
,00- "","","","","","","",""I
A
i
2.00
4.00
6.00
8.0
w 2: C6 Sulfonate
(PFHS)
13491 O-20, DF=lO
080103AR-325 100-
Sm (Mn, 2x3)
04-Aug-2003 17: 17:2 LC/MS/MS #6
o-~~`~,~`.`,~"`,`...,~~~~,".`,~~'~,'..','.~',~'~`,~`~~,`."
2.00
4.00
6.00
: C8 Sulfonate
(PFOS)
.3491 O-20, DF=lO
180103AFL325 IO
Sm (Mn, 2x3)
8.00
10.00
9.24 65101 6
04-Aug-2003 17:17:2d
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 3.76e5 Area
i--
Time
Exygen Research, 3058 Research Drive, State College, PA 16801
Quantify
Sample Report
Study No.: L34910, Set No.:080103AR, 'W
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List:
P:\Data\LCblSWS6\MasslyPx\Fluoroch~cal~.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\L~SMSb\~sslyPx\Pluoroch~cals.PRO\Met~B\Decatur
Last modified:
Sun Aug 03 07:11:59 2003
Job Code:
Printed:
Tue Aug 05 07:32:03 2003
Page 50
Decatur BC BC 080103
Name: 080103AR-325 Text:
4: PFOSA
IL3491 O-20, DE1 0
080103AR-325 loo-
Sm (Mn, 2x3)
%-
04-Aug-2003 17:17:26
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
498 > 78
3.12e5
Area
Exygen Research, 3058 Research Drive, State College, PA 16801
------------------------
---------
--------w------
Quantify San~le Report Study No.: L34910, Set No.:O00103A.R, Ext.Date:08/01/03, 'id
Analyst:X.Risha
Sample List:
P:\Data\LCMSblS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O80103~
Last modified: Method: Last modified: Job Code:
Tue Aug 05 07:24:43 2003 P:\Data\LWSMS6\Masslynx\Fluoroch~cals.P~O\Met~B\Decatur
Sun Aug 03 07:11:59 2003
Page 51
Decatur BC BC 080103
Printed:
'Ibs Aug 05 07:32:01 2003
---
--------------------------
Name: 080103AR-326 Text:
-------------
-------------___^_-__
: C8 Acid (PFOA)
.3491 O-20 Rep, DF=lO
)80103AR-326 IOO-
Sm (Mn, 2x3)
%-
9.12 _ 44037
04-Aug-2003 17:39:07 LC/MS/MS #6
MRM of 4 Channels ES413>369 2.64e5 Area
2.00
~: C6 Sulfonate
(PFHS)
-3491 O-20 Rep, DF=lO
180103AR-326 1Och
Sm (Mn, 2x3)
8 I I , ,v
Time
6.00
8.00
10.00
04-Aug-2003 17:39:0 LCfMS/MS #6
%-
0 "~~,~~~`,`~~~,~"~I~"`,`~`~1~~~~1"'~I~'~'I'~~~l"~`~~"~
2.00
4.00
6.00
: C8 Sulfonate
(PFOS)
-3491 O-20 Rep, DF=lO
180103AR326 10th
Sm (Mn, 2x3)
%-
8.00 9.24
10.00
04-Aug-2003 17:39:0+ LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.63e5 Area
Wgen Research, 3058 Research Drive, State College, PA I.6801
Quantify Saalple Report study No.: L34910, Set No.: 080103JUi, Ext.Date:08/01/03,
lur,
Analyst:K.Riaha
saup10 List: Last modified: Method: Last modified:
P:\Data\LWSMS6\Masalynx\Fluorochemicals.PRO\S~leDB\O6OlO3~
!Pue Aug 05 07224~43 2003
P:\Data\L~SMS6\Masslypx\Fluoroch~cals.PRO\Met~B\Decatur
Sun Aug 03 07:11:59
2003
Job Code:
Printed:
Tue Aug 05 07:32:01
2003
Page 52
Decatur BC BC 010103
Name: oao103AR-326 Text :
4: PFOSA
L3491 O-20 Rep, DF=l 0
080103AFb326 lOO-
Sm (Mn, 2x3)
%-
04-Aug-2003 17:39:07
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
498>78
2.62e5
Area
0 "","",`,","","","","","",l"`,
I r I , I t Time
2.00
4.00
6.00
8.00
10.00
INygen Research,
3058 Research
Drive,
State College,
PA 16801
00043.4
Quantify Sample Report
Study No.: L34910, Set No.:O80103AR, ' '4
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List:
P:\Data\LCMSMS6\Masslynx\Fluo~och~ca~s.PRO\S~leDB\O8OlO3~
Last modified:
Tue Aug 05 07:24:43 2003
Method:
P:\Data\L(ZrlSblS6\bssl~\Fluoroch~cals.PRO\Met~B\Decatur
Last modified:
Sun Aug 03 07:11:59 2003
Job code:
Page 53
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01 2003
--------------------------------
Name: 080103AR-327 Text :
1: C8 Acid (PFOA)
I-3491 O-21, DF=lOO
(180103AR-327 10
Sm (Mn, 2x3)
04-Aug-2003 18:00:4j
LC/MS/MS #6
MRM of 4 Channels ES-
9.13
413 > 369
1016s
6.21e4
Area
q,d 2: C6 Sulfonate
(PFHS)
IL3491 O-21, DF=lOO
080103Ak327 100-
Sm (Mn, 2x3)
%-
Time
04-Aug-2003 18:00:47j
LC/MS/MS #6
MRM of 4 Channels ES-
8.98
399 > 80
3.35e3
Area
3: ca Sulfonate
(PFOS)
L3491 O-21, DF=lOO
080103AR-327 Sm (Mn, 2x3)
04-Aug-2003 18:00:4? LCRvWMS #6
MRM of 4 Channels ES499 > 99 4.95e4 Area
Time
Ekygen Research, 3058 Research Drive, State College, PA 16801
00043.5
Quantify Sample Report
Study No .:L34910, %d
Set No.:O80103A?i,
Ext.Date:08/01/03,
Analyst:K.Risha
SausQls List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\~aslynx\Fluorocbemica !#.m Aug OS 07:24:43 2003 P:\Data\LCMSMS6\Massl~\Fluoroch~cals.PRO\~et~B\Decatur Sun Aug 03 07:11:59 2003
Page 54
Decatur BC BC 080103
Printed:
Tue Aug 05 07:32:01
2003
__~----------------------------~
-------------------
Name: 080103AR-327 Text :
4: PFOSA
IL3491 O-21, DF=l 00
080103AR-327 Sm (Mn, 2x3)
04-Aug-2003 i&00:4: LCIMSNS #t
MRM of 4 Channels ES498 > 7E 4.67eL Are2
Time
J
men
Research,
3058 Research Drive, State College, PA 16801
----."---
.__"__-
---
Quantify Sample Report Study No. : L34910, Set No.:O80103AR, '14
&&.Date:08/01/03,
Analyst:K.Rieha
Sample List:
P:\Data\LCbISMS6\Massl~\F~uoroch~cals.PRO\S~~eDB\OSOlO3~
Last modified: Method: Last modified: Job Code:
Tue Aug 05 07:24:43 2003 P:\Data\L~SMS6\Masslynx\Fluorochemicals.PRO\Met~B\Decatur Sun Aug 03 07:11:59 2003
Page 55
Decatur BC BC 080103
Printed: -----m--e------
Tue Aug 05 07:32:01 2003 -------------------l_l-------ll-------------
Name: 080103AR-328 Text :
: C8 Acid (PFOA)
.34910-21,DFdO
)80103AR-328 10
Sm (Mn, 2x3)
9.16 9924( I
04-Aug-2003 18:22:28/ LCNWMS #6
MRM of 4 Channels ES413 > 369 5.73e5 Area
1
L
Time
2.00
4.00
6.00
8.00
10.00
w 2: C6 Sulfonate
(PFHS)
[L34910-21, DF=lO
04-Aug-2003 18:22:2d
080103AB328 Sm (Mn, 2x3)
LC/MS/MS #6
MRM of 4 Channels ES399 > 80 2.84e4 Area
Time 10.00
04-Aug-2003 18:22:28!
lOO-
9.28
%-
Oxygen Research, 3058 Research Drive, State College, PA 16801
000419.7
---_---_
---_-------_
-----
----------------
Quantify
Sample Report
Study No .:L34910, '4
Set No.:O80103A~,
Ext.Date:08/01/03,
Sample List: Last modified: Method: Last modified:
Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorach~cals.PRO\S~leDB\O8OlO3~
Tue Aug 05 07324343
2003
P:\Data\LCMSMS6\Masslynx\Fluoroch~cal8.?RO\~et~B\Decatur
Sun Aug 03 07:11:59
2003
Printed:
Tue Aug OS 07:32:01
2003
Name : 080103AR-328 Text:
4: PFOSA
L3491 O-21, DF=l 0
080103AR-328 100-
Sm (Mn, 2x3)
%-
Analyet:K.Risha
-e---e--_
Page 56
Decatur
BC
BC 080103
04-Aug-2003 18:22:2d
LC/MS/MS #6
9.87
78207
MRM of 4 Channels ES498 > 78 3.95e5
Area
Exyoen Research,
3058 Research
Drive,
State College,
PA 16801
Quantify Sample Report Study No.: L34910, Set No.:080103AR, 'hd
Ext.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07:24:43 2003
P:\Data\LCMSMSS\Masslynx\Fluorochemicals.PRO\~et~R\Decatur Sun Aug 03 07:11:59 2003
Printed:
Tue Aug 05 07:.32:01 2003
Page 57
Decatur BC BC 080103
Name : 080103AR-329 Text :
: CB Acid (PFOA)
(CO72503-5,500 rig/L Standard
)80103AR-329 10
Sm (Mn, 2x3)
3
9.15 21504E
04-Aug-2003 18:44:11] LC/MS/MS #6
MRM of 4 Channels ES413>369 1.26e6 Area
2.00
4.00
,4 2: C6 Sulfonate
XCO72503-5,500
(PFHS)
rig/L Standard
080103AR-329 10 ]
Sm (Mn, 2x3)
%
,,",`,,,,"","`,,"`,,"`,
2.00
4.00
3: C8 Sulfonate
(PFOS)
IXCO72503-5, 500 rig/L Standard
080103AR-329 Sm (Mn, 2x3) 1000- "~`//"`,~`J~,"'
`r ,,`,,"`,,'
%-
2.00
4.00
6.00
8.00
10.00
8.99 _ 37183
04-Aug-2003 18:44:11 LC/MS/MS #6
MRM of 4 Channels ES399 > 80 2.23e5 Area
1,,1 ,,,,,,/,,,,
$ ,,,,,,
I,,,(,,
Time
6.00
8.00
10.00
I ,,,,,,,,,
"19,,.,277,,q
04-Aug-2003 18:44:11 LC/MS/MS #6
MRM of 4 Channels ES-
,,,, y.f
6.00
8.bO
10.00
wgen Research, 3058 Research Drive, State College, PA 16801
Quantify Sample Report
study No.: L34910, Set No.:O80103AR, 'Id
Rxt.Date:08/01/03,
Analyst:K.Risha
Sample List: Last modified:
P:\Data\LCMSMS6\~sslynx\FluorochemicalS.PRO\S~~eDB\O80103~ Tue Aug 05 07~124~43 2003
Method: Last modified:
P:\Data\LCMSMS~6\Masslynx\Fluorochamica~s.PRO\MethD~\Decatur Sun Aug 03 07:11:59 2003
Job Code:
Printed:
Tue Aug 05 07:32:01 2003
Name: 080103AR-329 Text:
Page 58
Decatur BC BC 080103
X072503-5,500 rig/L Standard
180103AFk329 Sm (Mn. 2x31
04-Aug-2003 18:44:11
LCIMSIMS #6
MRM of 4 Channels ES-
498 > 78
I
4.48e5
Area
A-
Time
Exyoen Research, 3058 Research Drive, State College, PA 16801
QQQ420
Quantify Sample Report
Study No .:L34910, h@
set No.:O80103AR,
Ext.Date:08/01/03,
Sample List:
P:\Data\LWSMS6\Masslynx\Fluorochemicale.
Last modified:
TLIS Aug 05 07:.24:43 2003
Method:
P:\Data\LCMSMS6\Masslynx\FluorachemicalsB\D~catur
Last modified:
Sun Aug 03 07:.11:59 2003
Job Code:
Analyst:K.Risha
Page 59
Decatur BC BC 080103
Printed: ----___
!l'ue Aug OS 07:32:01 2003 ------------_---------_-___
Name : 000103AR-330 Text :
--s----p___
----
----
1: C8 Acid (PFOA)
KC072503-6,lOOO rig/L Standard
080103AR-330 10
%100,
Sm (Mn, 2x3) 2.00
9.15 406254
"
" I" "
I" ''," " I
4.00
6.00
8.00
" L
04-Aug-2003 19:05:53 LC/MS/MS #6
MRM of 4 Channels ES413>369 2.39e6 Area
Time 10.00
2: ~6 Sulfonate
(PFHS)
w XCO72503-6,lOOO rig/L Standard
080103AR-330 IOO-
Sm (Mn, 2x3)
,,,`,,,,,,,,,,`,,,,,,
04-Aug-2003 19:05:5:
LC/MS/MS #6
MRM of 4 Channels ES-
8.99
::;`1
`,,,",,,`,'
y%!f
%-
0 ""I"","",""
2.00
4.00
6.00
8.00
10.00
3: C8 Sulfonate
(PFOS)
XCO72503-6,1000 rig/L Standard
180103AW330 10 9
Sm (Mn, 2x3)
04-Aug-2003 19:05:53 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.57e5 Area
2.00
4.00
6.00
8 .""
I".L
I
Exygsn Research, 3058 Research Drive, State College, PA 16801
Time 2
000421
Quantify Saxqpls Report
Study No.:L34910, b+'
Set No .:080103AR,
Ext.Date:08/01/03,
Aaalyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\~sslynx\Fluorochemicals.PRO\S~leDB\O8OlO3~ Tue Aug 05 07::24:43 2003 P:\Data\LCMSMS6\Maeslynx\Fluoroch~cals.~RO\Met~B\Decatur Sun Aug 03 07::L1:59 2003
Printed:
Tue Aug 05 07:32:01 2003
Page 60
Decatur BC BC 080103
Name: 080103JUi-330 Text :
4: PFOSA
XCO72503-6,lOOO
rig/L Standard
080103AR330 100-
Sm (Mn, 2x3)
%-
04-Aug-2003 19:05:53
LC/MS/MS #6
MRM of 4 Channels ES-
9.89
498 > 78
8.67e5
Area
10.00 , , , , . , Time
Exygen Research, 3058 Research Drive, State College, PA 16801
800422
NA I34910 PFOS 499 -> 99 Decatur B&w's Creek
RAW DATA REPORT
Limit of Qumtitati~n: kjcctian Volume: MSTiX Sample Weight FIOJ Volume:
Set No:
AnnlYSC
hruummt-rypc:
Exbvtioa
Date:
AwJyzcd on:
081203A KuCn RidU LCMSMS % OWI M3 08113Ki3
Exygca
m
XC08 1103-O
xco.91103-I
XC081 103.2
Xcu8lO3-3
XC081 103.4
xcm31103.5
Xc081 103-6
MclhlDd WadI
Reagent Blank
Ru&nl Spk A
Rsegenr Spk B
L34910-11 SpkE
L34910-I1 Spk B
XC081 103-L
XC081 103-2
Xc081 103-3
L34910. I1
w4910-11
Rep
u4910-11
w4910-11
REp
XC0611034
Xc081 103.5
xcO81103-6
spam
111 01 ml BC2 SED.06 BQ SED-06
BCZ SED-06 BQ SED-06 BQ SBD-06 BC2 SEII-&
SUnpk
RUII
CC&
No.
es
ORI203A.3001
0
cs
OIil203A.3002
2.7
cs
081203A-3003
SO
cs
081203A-MO4
100
cs
061203&3005
230
cs
09 1203A.3006
SO0
cs
081203A.3a)7
IWO
C
081203A.3008
C
081203A.3W9
LCS
081203A-3010
LCS
081203A.3011
LF
081203A.3012
LF
081203A-3013
cs
061203A.3014
7.5
cs
081203A-3015
50
cs
081203A-3016
100
S
081203A.3017
S
081203A-3018
S
081203A.3019
S
08 1203A.3020
cs
081203A-3021
250
cs
0817D3A.3022
500
cs
081203A-3023
1000
halyle Rcfovay
Pound (ppl) (%) a
- (peak - - iuterccp~) I slope (amlyle found (ppt)-unllylc -c
I DP found
in conuol
Xldlxf (PP0
(PPl)] I loo
.hdytc Farad (ppb) = [.w.lyte hnd (ppt) x volume uuacti
(0.04 L)I I sample wei& (S n)
Analytc Found (ppb) dry weight = malyw found (ppb) x (1Wa I t-1 solid, ("k))
C-3 = Calibntiooruuxhl c = cwtrol lpmplc s -Sample
LF 3 Lab fortifud FF = Picld fatihed LCS I Lnborwry
ramp10 sampk
Coauol Spike
0
909
IS%
3803
9700
19165
39020 0
0
ND
1963
49.2
21166
533
8541
21swI
91234
*
954
2208
4213
4378
1100&l
493s
124aoa
422%
l
48356
I
11039
20668
39291
98 107 105
880.00
60.41
1460
99240
60.41
1640
60.4 I
60.41
CK . Ckck SMprd
ND - Noc&kwedrRupumebcnv~0and~ppr
NQ . Not quantifiable
= Rcrponss
bccwcco U ppt and LOQ (SO ppr)
*Dilution
wzu for PFOSA.
Spawn Study No: Exygcn Study No: An+lC Ions Monitored: Site:
NA L34910 FOSA 498 -,-a Dscatur B&a's Creek
RAW DATA REPORT
Limit of Qwmiutioo: Lnjsction Volume: Mabix: Smlpk Weight: Final Volume:
$0 PPt 1SpL Soil 5.0 g 5.0 mL
Set No: AMlYSC lmtmmat Extrsction Andy24
Type: Date: on:
081203A Klrm Risha LCMSMS #6 OWl2'03 OS/l 3:03
Wsm ID
xcos I 103-o
xcoEIlo3-I
XC081 103-2
xc081 103.3
XC081 103-4
XCOBI 103-S
XCOB 1103-5
Mcthnnol Wash
Reagent Blaok
Reagent Spk A
Rupent Spk B
L349 LO-1 I Spk E
L349 IO-1 I Spk E
w
XCOBI 103-I
XC08 I 103-2
XC08 1103.3
L34910-11
L34910.I I Rep
L34910-II
L34910-II
Rep
XC081 103-I
XC081 103-s
XC081 103-6
Sponsor ID
I). 0~ Il. EC2 SED-06 BC2 SED-06
BC2 SED-06 BC2 SED-06 BC2 SED-06 BC2 SED-06
Sample Code
cs cs CS cs CS CS cs C C LCS LCS LF LF CS CS CS S S S S cs cs cs
Run NO. 081203A33001 OSI203A-3002 081203A.3W3 OS I203A.3004 081203A.3OOS 081203A.3006 OBl203A-3007 081203A-3038 081203A-3009 081203A-3010 081203A-3011 081203A-3012 081203A-3013 0131203A-3014 081203A-3015 081203A-3016 081203A-3017 081203A-3018 081203A.3019 081203A.3020 081203A-3021 081203A-3022 081203A-3023
Anatyte Raovy
Found @pt) -(PC& (X) -
ww . iotacspt) Imalytc found
J slope x DP
(ppt)-wMyl.
found in coatrol
amount added @pt)
(opt)l x IO0
std.
COW. @pt)
0 23 SO loo 250 500 loo0
Dilution Factor
I 1 I IOW 100 25 SO loo 1000 loo0 loo 100 250 so0 IO00
Peak Area
0 3s47 7692 lSS22 39080 7390s 145023
0 0 725s 72614 1141s 122331 4230 8197 16248 I446 1737 13834 l6OlS 41122 78848 149443
AJwe
Found
(ppt)
Amourit
Added (ppt)
Recovery (%)
AaPlytC Found @pb)
ND
4J.S
50
91
481
SW
96
*
IOWQO
812W
IooooO
n
l
.
8930
71.44
IWO0
83.20
2gmdad Cwp totempt Slope
Cocf.OfDct.=
: Line= (I/x - 434.455 = 150.037
0.998129
weighted)
TOtd SOlidS (K)
60.41 60.41 60.41 60.41
hnrlyte An~lyte
Found @pb) = [analyte found (ppt) x volume cxbwtcd (0.04 L)]! prmple weight (3 g) Pound @pb) dry weight - uralyrc found (ppb) x (I 00% I total solids (%))
CS = Wibntion c - Contxol s - Slmpk
rtmdard umple
LF - hb fortified FF - Field foltificd LCS - Laborwtory
wnple sample
Contxol Spike
CK * Cheek Standud ND - Not dctated NQ = Not qwtitiablc
- Response bctwcen 0 md ZS ppt = Rerpoose between 25 ppt md LOQ
(SO ppt)
*Dilution
was for PFOS
Spreadsheet prepared by: $$ , 08/29(03
A&t0 Fwnd (Ppb) Dry Weight
118 138
000&?4
E
nTM EARCH
3058 Research Drive State College, PA 16801
Phone: 8 14-272- 1039 Fax: 814-231-1580
\J
Internal Chain of Custody/Fortification Sheet
Exygen Study Number:
L34,9 10
Matrix: &iJ
ere removed from refrig
All samples were weighed on balance No. 2
Time @m
Date
Initials m
After wei hing samples were returned to re t-i erator No. ,?2
Time lLfzz6
Date &$&
Initials L&E
Comments: ZOOpL of 250 mghL sodium thiosulfate WII added to all samplesbefore spiking. Initials/Date:
Analysis Summary:
Data Set *1203A
Data Set:
-
Data Set:
+
Initials/Date: Initials/Date: Initials/Date:
Set extraction/analysis data verified by.
. -
3058 Research Drive
Phone: 814-272-1039
State College, PA 16801 Fax: 814-231-1580
SAMPLE EXTRACTION ANIl ANALYSIS TRACKING SHEET
EXYGEN STUDY NUMBER: MATRIX:
L34910 m
METHOD: ANALYTES:
ExM-023-014 Is PFHS. PFOS. PFOA and PFOSA
PROTOCOL NUMBER: &
*Client ID
na
na
na
BC2 SED-06
I
BC2 SED06
BC2 SED-06
Exygen KD
STEP STEP STEP STEP STEP STEP Dilutions
STEP Dilutions STEP
1
2
3
4
5
6
WJmL)
7
(mUmL)
8
Reagent Blank
I
I
I
I
I
I
1 Reagent Spk A , f
Reagent Spk B 1 L34910-11 Spk E 1 1
I I
I &.l/;rLl/o
1
:
1 L34910-11
1\ ! I! \ 1 j
! ! I( ,/y(,o-yo , P).fd
II -
L34910-11 Rep
\L
\L
w
*
JI
J, ~~~v\*~@~p
\v
Reagents/
Materials
LOl#
Mabaa cl8 SPE
2-b
w3 ILp7B2
NA
GTlwaslwsa-crodisc
I
I
STEP 4: Fiiter through glass acrodise STEP 5: SPE column clean up (omitting 40% wash) STEP 6: Final volume. fo 5 mL collected in 15 mL polypropolenc tubes STEP 7: LCXVWMS analysis STEP 8: LC/MS/MS reanalysis.
*Initials and date under each step indicates the personnel that performed this step,
$$ Method of Analysis for the Determination of PerfIuorooctauesulfonate (PFOS) and Pentadecafluorcoctanoic Acid (PFOA) in Soil
COMMENTS:
Final extracts stored in refrigerator .32
Initials: aDafez
* July 19,2001/4
n04
i
30.58 Research IXve
c
Phone: 814-272-1039
AESCARCH
State College, PA 16801
Fax: 814-231-1580
Protocol No.: None Method No.: s
PREPARATION OF EXTRACTED CALIBRATION
Exygen Study No.: Am&es:
m PEfls, PFAS. PFOS. PFQd
STANDARDS
Matrix: Sample Vol:
T~DC I Water" 4&1&
Vertical arrows in a column indicate identical vafues.
**This must be a unique number. Use this system: Extracted Calibration Sofn ID
Samples removed fro-r
I lkezer # -a
Time: mm
40 mL of each sample measured using a ,p
rnL graduated cylinder.
After measuring, samples returned t-9
/ freezer #
Time: 6%
Samples fortified:
Initials/Date:
/ Eall/!V
SPE clean-up (omitting 40% Wash):
Initials/Date: ZE
I
Fiial ~olumc adjusted to 5 mL: Extracts placed in refrigetator # XL
Initials/Date: PE I s Initials/Date: &G / I
QG+
#: XCMSfDDl'Y-0,1,2,3. InitiaWDate: InitialsAIate: Initials/Date:
etc.
CEEl /a
05 1
fe
/ '
s
STANDARD
EXPIRATION
Comments:
*This type I water has been filtered through a hypercarb filter
J$ Method of Analysis for the Determination of Petfluorooctaoe mlfooatc (PFOS), Pcrfluorocctane sulfonylamide (PFOSA). and Perfluorooctanoatc (poti)
DATE! h Water
8f25/03
Q
July la,2oolM
Masslynx - Sample list
Sample List: C:\MASSLYNX\Fluoroch Printed: Wed Aug 13 09:36:59 2003
Is,PRO\SampleD8\081203A
Decatur EC.SPL --.
Vial File Name
LIMS ID Client ID Sample Description
Matrix Sample Type Cone @g/L) Cone B ConcC Test ID DF
I
08 1203A-3001 --
-_-
2
: 08 1203A-3002 --
_-
3
3 08 1203A-3003 --
--
4
4 08 1203A-3004 --
..-
5
5 081203A-3005 --
_-
6
6 08 1203A-3006 --
--
08 1203A-3007 --
--
s' 9'2 08 1203A-3008 --
--
9
11 08 1203A-3009 --
-
081203A-3n10
--
--
::
:; 081203A-3011 --
--
12
14 081203A-3012
--
_I
13
I5 081203A-3013
--
-
2 081203A-3014 --
--
2
3 081203A-3015 --
-
16
4 081203A-3016 --
-
17 16 081203A-3017 -
-
da 17 081203A-3018 --
-
19
18 081203A-3019
-
-
20
19 081203A-3020
--
-
21
5 081203A-3021 -
-
22
6 081203A-3022
-
-
23
7 081203A-3023 -
-
XC081 103-O. 0 ng!L Standard
---
XC081 103-I,25 nglL Standard
---
XC081 103-2.50 ngtL Standard
---
XC081 103-3. 100 rig/L Standard
--_
XCO81103-4,250 rig/L Standard
--
XC081 103-5,500 rig/L Standard
-
XC081 103-6, 1000 rig/L Standard
-_
Methanol Wash
-_
Reagent Blank
_--
Reagent Spk A, %I nglL
-_-
Reagent Spk B, 500 nglL
_--
L34920-11 Spk E, 100000 nglL. OF=1000 ---
L34910-11 Spk E. 100000 rig/L, DF=lOO ---
XCO81103-1.25 nglL Standard
--
XC081 103-2,50 ngR Standard
_--
XC081 103-3, 100 rig/L Standard
--
L34910-11,0F=1000
--
L3491 O-l 1 Rep, DF=lOOO
-
L34910-II. DF=lOO
--
L3491 O-1 I Rep, DF=lOO
--
XC081 103-4,250 rig/L Standard
--
XC087 103-5.500 rig/L Standard
_-
XC081 103-6, 1000 nglL Standard
--
Standard Standard Standard Standard Standard Standard Standard Blank Blank SC
::
gt%dard Standard Standard Analy-te Analyte Analyte Analyte
x5 50 100 250 500 1000 _--
50 500 100000 100000
2 100 ---
250 500 1000
--
-
--
--
-_
--
-_
--
-- c-- --
--
--
---
--
--
--
-_-
--
-
--
--
--
-
-_ --_ -
--- --
-
--
- --
- -- -
--
-
-_
-
-
-
0
0
:
0
1
1
8
1
1
00
1
0
1
0
1
n
i
0"
1
0
1000
0
100
I
:
I
1
a0
1000
0
1000
0
100
0
loo
0
I
0
1
0
1
Masslynx - Sample List
Sample List: C:\MASSLYNX\Fluoroch Printed: Wed Aug 13 093659 2003
als.PRO\SampteDB\O81203A bf$!jbs
Decatur BCSPL
MS Method
HPLC Method MS Tune File Inj.Volume
1 C6 C8 SULF C8 ACID PFOSA 2 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA : C6 C8 SULF C8 ACID PFOSA 5 C6 C8 SULF C8 ACID PFOSA 6 C6 C8 SULF C8 ACID PFOSA 7 C6 C8 SULF C8 ACID PFOSA 8 C6 C8 SW-F C8 ACID PFOSA 9 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF 26 ACiD PFOSA
:I: C6 C8 SULF C8 ACID PFOSA 12 C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA :1 C6 C8 SULF C8 AClD PFOSA
C6 C8 SULF C8 ACID PFOSA :i C6 C8 SULF C8 ACID PFOSA
C6 C8 SULF C8 ACID PFOSA :3 C6 C8 SULF CB ACID PFOSA 19 C6 C8 SULF C8 ACID PFOSA 20 C6 C8 SULF CB ACID PFOSA 21 C6 C8 SULF C8 AClD PFOSA 22 C6 C8 SULF C8 ACID PFOSA 23 C6 C8 SULF C8 ACID PFOSA
pfbs water pfbs water
pfbs water pfbs water pfbs water pfbs water pfbs water
PfbS Wi3t8r
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water
pfbs water pfbs water pfbs water pfbs water pfbs water pfbs water
Fluorochems 15
Fluorochems Fluorochems :z
Fluomchems 15 Fluorochems
Fluorochems ;z Fluorochems 15
Fluorochems 15 Fluorochems 15
Fiuorochems i5 Fluorochems 15 Fluorochems 15 Fluorochems
Fiuorochems :; Fluorochems
Fluorochems :z Fluorochems 15
Fluorochems 15
Fluorochems 15 Fluorochems 15 Fluorochems 15
Fluorochems 15 Fluorochems 15
ExVgen STUDY NO; !-SW 10
.' .
I
Page 2 Page Position: (2, 1)
LUMSI'MS SYSTEM AND OPERATING CONDITIONS
SDonsor Protocol No: If?&
Exvg;en Studv No: L34910
Instrument:
Micromass Quattro Ultima (LC/MS/MS Unit #6)
Computer:
COMPAQ Professional Workstation AK?00
Software:
Microsoft Windows NT: Version 4 Build 1381: Service Pack 5 Micromass Limited: MassLynx 3.4 Build 004
HT'LC Equipment:
.Hewlett Packard (HP) Series 1100
HP Bin Pump
HP Vacuum Degasser
HP Autosampler
HP Column Oven
HPLC coh.uM:
Genesis C-8,5 cm x 2.1 mm i.d. x 4 p (Exygen ID: 74A) (JONJZSCHROMATOGRAPHY: Part No. FK5962E)
Mobile Phase (A) : Mobile Phase (B) :
12mM Ammonium Acetate in Type I Water Methanol
Analyst:
IKaren Risha IExygen Research 3058 Research Drive, State College, PA 16801 I?hone: (814) 272-1039 FAX: (814) 231-1580
NOTE: The next 3 pages are computer generated printouts from the lmasslynx software program. The pages contain the instrument settings used fbr the analysis of this data set.
All Handwritten Peak D's by: glp$6~~3
Scanning
Method Report
lul, Method: Last Modified:
C:\MASSLYNX\E-LUOROCHECALS.PRO\ACQUDB\C6
Thu Jul 31 16:23:50
2003
Page 1 C8 SULF C8 ACID PFOSA
Printed: Solvent
Wed Aug 13 09:37:33
2003
Delay ( mins ) :
a.00
N5]1310
v '
halog Function
Channel : 1
4 : Unused MRM of 4 Mass Pairs
( ESP- )
Inter Channel Delay ( Sets ) : 0.03
Span ( Daltons
) :
0.00
Start Time ( Mins ) :
0.00
End Time ( Mins ) :
12.00
Repeats :
1
Channel Parent Daughter
Dwell (Sets) Co11 Energy (eV) Cone ( V )
1
399.00
80.00
0.20
35
50
2
413.00
369.00
0.20
10
10
3
498.00
18.00
0.20
30
50
4
499.00 99.00
0.20
40
30
Method Report
Method Pile: Last Modified:
C:\mSSLYNX\FLUOROCHEMICALS.PRO\ACQUUEi\pfbs Wednesday, August 13, 2003 09:25:46
Printed: 'ad
Wednesday, August 13, 2003 09:37:56
HP1100 LC Pump Initial Conditions
Solvents
A%
90.0
8%
10.0
C%
0.0
D%
0.0
Flow (ml/min) Stop Time (mins) Min Pressure (bar)
Max Pressure (bar) Oven Temperature Left(OC) Oven Temperature Right(OC)
0.300 20.0
0
400 35.0
35.0
HP1100 LC Pump Gradient Timetable
The gradient Timetable contains 8 entries which are :
Time
A%
B!k
C%
0.00
90.0
10 .o
0.0
2.00
90.0
10.0
0.0
5.00
10.0
90.0
0.0
9.00
10.0
90 .o
0.0
9.50
0.0
100.0
0.0
14.00
0.0
1OO"O
0.0
14.50
90.0
10.0
0.0
20.00
90.0
10.0
0.0
D%
Flow
0.0
0.300
0.0
0.300
0.0
0.300
0.0
0.300
0.0
0.300
0.0
0.300
0.0
0.300
0.0
0.300
'*r'HPllOO LC Pump External Event Timetable
The Timetable contains 6 entries which
Time Initial
0.00 0.05 0.10 11.90 12.00
Column Switch Off Off
Off
Off Off Off
Contact1 Off On
Off Off
Off Off
are :
Contact2 Off Off Off On Off Off
Contact3 Off Off Off Off On Off
Contact4
Off Off Off Off
Off Off
HP1100 Autosampler Initial
Draw Speed Eject Speed (pl/min)
Draw Position (mm)
Stop Time (mins)
Injection
Volume(@)
Vial Number
Conditions
290.0 200
0.50
20.00 15.0 47
Page 1 water
Pressure 400 400 400 400 400 400 400 400
_ .I--t..
.~,Y_
-_...
.-
Tuning Method Report
'4 Method:
C:\MASSLYNX\E~UOROCHEMXCALS.PRO\ACQUD~~\E'LUOROCHEMS
Printed:
Wed Aug 13 09:37:50 2003
Page 1
.
\d Dau 395.00
SOURCE ( ESP- )
Capillary
Cone Hexapole 1
Aperture 1 Hexapole 2 Source Block Desolvation
Temp. Temp.
Pressures
Analyser Gas Cell
Vacuum
Set Rdbk
3.00 -2.93
20
-42
0.0
0.0
0.0
100 100
300 299
Rdbk
OFF 3.5e-3
Analyser
LM Res 1 HM Res 1 IEnergy 1 Entrance Collision Exit LM Res 2 HM Res 2 IEnergy 2 Multiplier
Gas Flows
Cone Gas Desolvation
Set
14.0 14.0
1.0 -2
15 2 14.0 14.0 2.0 650
Rdbk
132.1 755.7
Rdbk
26
38
29
-648
_--_"
__II__
--IIxI--"
--a--
-------------___l_------
e-----w__
Quantify Calibration
Report
Study No.:L34910,
Set No .:081203A,
lWt.Date:08/12/03,
Analyst:R.Risha
14
Calibration:
P:\Data\LCM~S6\Wasslynx\Bluorochemicals.PRO\~~eDB\O8l2O3A
Last modified:
Man Aug la 10:47:18 2003
Printed:
MOn AUg 18 10:50:24 2003
m-----m--
------------e---
------------
1C>ompound 1 name: C8 Sulfonate (PFOS)
C;oefficient of Determination: 0.998540 C:alibration curve: 39.6727 * x + 10.4732 FResponse type: External Std, Area C;urve type: Linear, Origin: Exclude, Weighting:
3.97e4-
l/x, Axis trans: None
--A---
Page 1
Decatur BC
Response
1I-S0
( 3
,`I
",""2/,"`0I 0.0
400.0 I'#
~l'~"l'+~n
600.0
I - 3 ~`I-8~~00.0
Oxygen Research,
3058 Research Drive, State College, PA 16801
r I ,'
(`1 rig/L 1000.0
. ..-
--
..-
__.---_1_-.-.-- .
--
__---_-...
_----
--
I_-------c-----I_--__l__l____
----
--------_-__
Quantify
Calibration
Report
Study No.:L34910,
Set No .:081203X,
Fzt.Date:08/12/03,
Analyst:K.Risha
Calibration: Last modified: Printed:
-----------
P:\Data\LCblSMSS\Masslynx\Fluoroch~ca~s.PRO\~~eDB\O81203A
Mon Aug 18 10:47:18 2003
Mon Aug 18 10:50:24 2003
-----we
-____----
-------------___
:ompound 2 name: PFOSA :oefficient of Determination: 0.9981213 ;alibration curve: 150.037 * x + 434.455 lesponse type: External Std, Area h-ve type: Linear, Origin: Exclude, Weighting:
1.50eZ I-
l/x, Axis trans: None
Page 2 Decatur RC
Response
0,'
7 r 0 I' " `I ' r 11 I f 3 I z ' 8 8 11
0.0
200.0
400.0
e 5 I""('
600.0
#`II",
`I,`,
800.0
Exygen Research, 3058 Research Drive, State College, PA 16801
/ I rig/L 1000.0
--
-_----
----------c_----
-----
-----------------____
Quantify Saa~~~le Report Study No.: L34910, set NO .:081203A,
Ext.Dats:08/12/03,
Analyst:K.Risha
Sample List:
Last modified: Method: Last modified: Job Code:
Printed:
P:\Data\M1M~S6\Masslynx\Fluoroch~cals.PRO\S~leDB\O81203A Man Aug 18 10:47:09 2003 P:\Data\LCHSMS6\~sslynx\Fluorochemicals.P~O\Met~B\PFOS Mon Aug 11 09:49:08 2003
Yon Aug 18 10:50:26 2003
Page I
Decatur BC and PFOSA 081103
Name : 081203A-3001
Text:
1: CB Sulfonate (PFOS) XC081 103-0,O rig/L Standard
081203A-3001 Sm (Mn, 2x3)
13-Aug-2003 14:43:39 LCYMSNS #6
d MRM of 4 Channels ES-
2.00
4.00
6.00
8.00
10.00
v 2: PFOSA
XC081 103-0,O rig/L Standard
Aug-2003 14:43:3
081203A-3001 Sm (Mn, 2x3)
h;lRM of 4 Channels ES-
Exygen Research, 3058 Research Driva, State College, PA 16801
A-----
----_-
--------_
-----------_1---_____-_-___
Quantify Sample Report
Study No.:L34910,
Sat No .:081203A,
Sxt.Date:08/12/03,
Analyst:R.Riaha
sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~ca~s.PRO\S~leDB\O8l2O3A Man Aug 18 10:47:09 2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\PFoS Mon Aug 11 09:49:08 2003
Printed:
Hon Aug 18 10:50:26 2003
Page 2
Decatur BC and PFOSA 081103
Name: 081203A-3002 Text :
1: C8 Sulfonate
(PFOS)
XC081 103-1,25 rig/L Standard
081203A-3002 lOO-
Sm (Mn, 2x3)
13-Augc2003 15:05:11 LCIMSIMS #6
MRM of 4 Channels ES-
%-
O~.,,,,,,,`~,,,,,,,,,..,,,,.,`.,.,,,'.,,,',,,',,,,l,,,,,,,
2.00
4.00
6.00
8.00
10.00
v 2: PFOSA XC081 103-1,25 rig/L Standard
081203A-3002 Sm (Mn, 2x3)
13-Aug-2003 15:05:11 LC/MS/MS #6
MRM of 4 Channels ES498 > 78 1.79e4 Area
Time
2.00
4.00
6.00
8.00
10.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
----P
--------------e--w-
-----
Quantify Sax&e Report Study No .:L34910, Set No.:O81203A,
Ext.Dats:08/12/03,
Analyst:K.Riaha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluarochemicals.PRO\S~leDB\O9l2O3~ Mon Aug 18 10:47:09 2003 P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\bIethDB\PFOS Man Aug 11 09:49:08 2003
Printed:
Man Aug 18 10:50:26 2003
-----
Page 3
Decatur BC and PFOSA 081103
Name: OB1203A-3003 Text:
1: C8 Sulfonate
(PFOS)
XC081 103-2,50 rig/L Standard
081203A-3003 lOO-
Sm (Mn, 2x3)
%-
9.35 1 89tj7
13-Aug-2003 15:26:51 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1 .OOe4 Area
1
01--,,,~,~,,,,,,,,,,,,,.,,,~,,,,,,,,,~,,,,~Time
2.00
4.00
6.00
8.00
10.00
2: PFOSA
XC081 103-2,50 rig/L Standard
081203A-3003 10
Sm (Mn, 2x3)
%
13-Aug-2003 15:26:51
LC/MS/MS #E
MRM of 4 Channels ES-
9.9f
498>7E
769:
3.73e4
Area
i Time
Exygen Research, 3058 Research Drive, State College, PA 16801
000439
--------------m----m-
-_----
------
------
Quantify Sample Report
Study No.: L349l.0, Set No. : 081203A, Ext.Date:O8/12/03,
Analyst:K.Risha
Cd
Sample List:
P:\Data\LCMSMS6\~sslynx\Fluorochemical8.PRO\S~leDB\O8l2O3A
Last modified:
Mon Aug 18 10:47:09 2003
Method:
P:\Data\LCIGMS6\Masslynx\Fluorochemicals.PRO\MethDB\PFOS
Last modified:
Man Aug 11 09:49:08 2003
Job Code:
Printed:
Non Aug 18 10:50:26 2003
Page 4
Decatur BC and PFOSA 081103
Name: 081203A-3004 Text :
1: C8 Sulfonate
XC081 103-3,100
(PFOS)
rig/L Standard
081203A-3004 10
% 1
Sm (Mn, 2x3)
0 "","","l',"","","",""l""I""I'
I
2.00
4.00
6.00
r2: PFOSA `url XC081 103-3, 100 rig/L Standard
081203A-3004 10
Sm (Mn, 2x3)
I%%.%
13-Aug-2003 15:48:3
9.33
3803
2.18e4
Area
- --
Time
8.00
10.00
l3-Aug-2003 l5:48:30
LC/MS/MS #6
MRM of 4 Channels ES-
9.95 15522
498 > 78 7.50e4
Area
I
b
Time /
00
Exygen Research, 3058 Research Drive, State College, PA 16801
000440
--_e--
---------------_----~
-p-w--
--__-__--
Quantify Sample Report
Study No.: L34910, Set No .:081203A,
`d
Ext.Date:08/12/03,
Analyst:K.Risha
Sample List:
P:\Data\L~SMS6\b~sl~\Fluoroch~cal~.PRO\S~leDB\Oal2o3A
Last modified:
Moon Aug 18 10:47:09 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cal=.PRO\Met~B\P~OS
Last modified:
Mon Aug 11 09:49:08 2003
Job Code:
Page 5
Decatur BC
and PFOSA 081103
Printed:
MOn Aug 18 10:50:26 2003
--------------------.-----~--------------
Name : 081203A-3005 Text :
I--------_------_w_
1: C8 Sulfonate
XC081 103-4,250
(PFOS)
rig/L Standard
08 1203A-3005 Sm (Mn, 2x3)
13-Aug--2003 16:10:151 LCNShlS'#6
MRM of 4 Channels ES-
9.35
499 > 99
5.54e4
Area
2: PFOSA
`W IXCO81103-4,250
rig/L Standard
081203A-3005 Sm (Mn, 2x3)
%-
13-Aug-2003 16:iO:lfjl
LC/MS/MS #6
MRM of 4 Channels ES-
390.9850--
498 > 78
1.88e5
Area
Oxygen Research, 3058 Research Drive, State College, PA 16801
-----------------------~
Quantify
Saarple Report
Study No .:L34910,
Set No .:081203A,
Ext.Date:O8/12/03,
Nd
Sample List:
P:\Data\L~~S6\Wlsslynx\Fluoroch~ca~s.PRO\S~leDB\O81203A
Last modified:
Man Aug 18 10:47:09
2003
Method:
P:\Data\LCMSMS6\Masalynx\Fluorocharnica~s.PRO\MethDB\PFOS
Last modified:
Man Aug 11 09:49:08
2003
Job Code:
Printed :
Man Aug 18 10:50:26
2003
Name: 0812031-3006 Text :
1: C8 Sulfonate
XC081 103~5,500
(PFOS)
rig/L Standard
081203A-3006 Sm (Mn, 2x3)
v--w------
Analyst:K.Rirha
Page 6
Decatur
RC
and PFOSA 081103
13-Aug-2003 16:32:0
2.00
4.00
6.00
8.00
2: PFOSA
XCO81103-5,500
rig/L Standard
081203A-3006 lOO-
Sm (Mn, 2x3)
%-
130Aug-2003 16:32:0tj
LC/MS/MS #6
MRM of 4 Channels ES-
9.95
498 > 78
3.53e5
Area
0 ~ll`,,~~~,",~,~.`~,,~,~,,,-~,"~~/~"~,~"r,
, I I 1 Time
2.00
4.00
6.00
8.00
10.00
Oxygen Research,
3058 Research
Drive,
State College,
PA 16801
-------------------------
----------_l__
Quantify Sample Report
Study No.:L34910,
Set No .:081203A,
Ext.Date:08/12/03,
Analyst:K.Riaha
Saarple List: Last modified: Method: Last modified: Job Code:
P:\Data\LMSMS6\Massl~\Fluo~ochamicals.PRO\S~laDB\O8l2O3A
Man Aug 18 10:47:09 2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MethDB\PFOS
Man Aug 11 09:49:08 2003
Printed:
Mon Aug 18 10:50:26
2003
__-__-___~~---~-~-~----~--____-_--~~~~~~-~-~~~-----~~
Name: 081203A-3007 Text :
1: C8 Sulfonate (PFOS) XC081 103-6, 1000 rig/L Standard
081203A-3007 100-
Sm (Mn, 2x3)
,1,,1 [,,,,(,
9.33 ~~~,,Lr~,,,3~~~~
%-
-----
Page 7 Decatur BC and PFOSA 081103
----------__
13-Aug-2003 16:53:41 LCIMSIMS #6
MRM of 4 Channels ES-
0 "","","",""
2.00
4.00
6.00
8.00
10.00
2: PFOSA
XC081 103-6,lOOO rig/L Standard
081203A-3007 100-
Sm (Mn, 2x3)
%-
13-Aug-2003 16:53:41
LC/MS/MS #6
MRM of 4 Channels ES-
9.96
498 :, 78
1 45023T
6.91e5
Area
*
I I a , I a - Time
6.00
8.00
10.00
Oxygen Research, 3058 Research Drive, State College, PA 16801
--
-----
___---l-l__--
---
Quantify Sample Report Study No .:L34910, Set No.:081203A,
Ea&.Date:08/12/03,
Analyst:K.Risha
Sam&Jle List: Last modified:
Method:
Last modified: Job Code:
P:\Data\L~SMS6\Wasslynx\Fluoroc~~cals.PRO\S~leDB\O8l2O3A Man Aug 18 10:47:09 2003
P:\Data\LCMSMS6\Masslynx\Fluorochem.icals.PRO\MethDB\PFOS Mon Aug 11 09:49:08 2003
Printed:
-___-_-___--_-
Mon Aug
-__-
18 10:50:26
------__-----I---------
2003
Name: 081203A-3008 Text :
1: C8 Sulfonate
Methanol Wash
(PFOS)
081203A-3008 Sm (Mn, 2x3)
--m---
Page 8 Decatur BC and PFOSA 081103
-------m---e
13-Aug-2003 17:15:22 LC/MS/MS #6
MRM of 4 Channels ES10.47 11.23 4gg>gg
944
2: PFOSA
Methanol Wash
081203A-3008 Sm (Mn, 2x3)
I
v - 1+Aug-2003 17:15:22/ LCiMSiMS #6
MRM of 4 Channels ES-
9;\96
498 > 76
I
2.00
4.00
6.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
0004"-4
Quantify Sample Report
Study No.: L34910,
Set No.: 081203A,
Ext.Date:08/12/03,
Analyst:K.Risha
Sample List: Last modified:
Method: Last modified:
Job Code:
P:\Data\LQISMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8~2O3A Mon Aug 18 10:47:09 2003
P:\Data\LCWSMIS6\Massl~\Fluoroch~cals.PRO\Met~B\PFOS Mon Aug 11 09:49:08 2003
Printed:
Man Aug 18 10:50:26
2003
Page 9
Decatur BC and PFOSA 081103
Name: 081203A-3009 Text :
1: C8 Sulfonate
Reagent Blank
(PFOS)
081203A-3009 Sm (Mn, 2x3)
13-Aug-2003 17:36:58 LC/MS/MS #6
MRM of 4 Channels ES-
c Time
2.00
4.00
6.00
8.00
10.00
2: PFOSA
0 ~~~~,11~1,11~1/~~11,II..,II,I,III.,~III,,III(,,,,,,,,,,,,/,
2.00
4.00
6.00
8.00
10.00
Time
Exygen Research, 3058 Research Drive, State College, PA 16801
om4n5
Quantify SangAe Report
Study No.: L34910,
Set No.: 081203A,
Ext.Date:OI3/12/03,
Salnple List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\blasSl~\Fluorocbemicals.PRO\S~leDB\O8l2O3A
Man Aug la 10:47:09
2003
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\MetbDB\PFOS
Mon Aug 11 09:49:08
2003
Printed:
MOA Aug 18 10:50:26
2003
Nm:
081203A-3010
Text :
Analyst:K.Risha
Page 10
Decatur
BC
and PFOSA 081103
2: PFOSA
Reagent Spk A, 50 rig/L
081203A-3010 10 ,_-
Sm (Mn, 2x3)
%
13-Aug-2003 17:58:42
LC/MS/MS #6
MRM of 4 Channels ES-
9.96
498 > 78
3.57e4
Area
Time
2.00
4.00
6.00
8.00
10.00
Oxygen Research,
3058 Research
Drive,
State College,
PA 16801
--
w-4---__I
v-----e-----_-_
----------
Quantify Sarqple Report Study No.: L34910, Set No .:081203A,
Ext.Date:O8/12/03,
Analyst:K.Risha
Page 11
S~lS List:
Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\SampleDB\O81203A Man Aug 18 10:47:09 2003 P:\Data\LCMSMS6\Masslynx\FluorochemicalB\PFOS Man Aug 11 09:49:08 2003
Decatur BC and PFOSA 081103
Printed:
Won Aug 18 .X0:50:26 2003
-- -----------__------~-------------------
Name: 081203A-3011 Text :
-v---4----_____
1: C8 Sulfonate ;
(PFOS)
081203A-3011 10
Sm (Mn, 2x3)
9.36 21166
13-Aug-2003 18:20:23/ LC/MS/MS #6
MRM of 4 Channels ES499 199 1.12e5 Area
w 2: PFOSA Reagent Spk B, 500 rig/L
081203A-3011 100-
Sm (Mn, 2x3)
%-
I
Time
1%Aug-2003 18:20:23
LC/MS/MS #6
MRM of 4 Channels ES-
9.97
498 > 78
3.5le5
Area
I ' ' Time
Exygen Research, 3058 Research Drive, State College, PA 16801
0004a7
--------
----
----
--
Quantify Sasqqle Report
Study No.: L34910, Set No .:083203A, bJ
Ext.Date:08/12/03,
Analyst:K.Riaha
Samiple List:
~:\Data\~~SMS6\Masslynx\Fluoroch~cals.PRO\S~leDB\O8l2O3A
Last modified:
MOP Aug 18 10:47:09 2003
Method:
P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\MetbDB\PFOS
Last modified:
Mon Aug 11 09:49:08 2003
Job Code:
Printed:
Mon Aug 18 10:50:26 2003
---a-__
Page 12
Decatur BC and PFOSA 081103
Name : 081203A-3012 Text :
1: C8 Sulfonate
(PFOS)
,L34910-11 Spk E, 100000
rig/L,
DF=lOOO
`081203A-3012 Sm (Mn, 2x3)
13-Aug-2003 18:42:04 LC/MS/MS #6
MRM of, 4 Channels ES499 > 99 4.55e4 Area
2.00
4.00
6.00
u ~3~~~~~ 1 Spk E, 100000 rig/L, DF=lOOO
081203A-3012 lOO-
Sm (Mn, 2x3)
%-
Time
8.00
10.00
13-Aug-2003 18:42:04
LC/MS/MS #6
MRM of 4 Channels ES-
9.90
498 > 78
11415
5.23e4
Area
Oxygen Research, 3058 Research Drive, State College, pA 16801
---
-----_l_
--------_----l_---l--------
Quantify Sas@e Report
Study No .:L34910, Sat No.:081203A, '4
Ext.Date:08/12/03,
Analyst:X.Risha
Sample List:
P:\Data\LCEISMS6\Nasslynx\Fluaroch~cals.PRO\S~leDB\O8l2O3A
Last modified:
MOP Aug 18 10:47:09 2003
Method:
P:\Data\LCMSMS6\MasslyPx\Fluoroche.micals.PRO\MeithDB\PFOS
Last modified:
Man Aug 11 09:49:08 2003
Job Code:
Printed:
Man Aug 18 10:50:26 2003
---e-e-
Page 13
Decatur BC and PFOSA 081103
Naxm: 0812031-3013
Text :
L: C8 Sulfonate
(PF0.S)
L34910-11 Spk E, 100000
rig/L,
DF=lOO
081203A-3013 10
Sm (Mn, 2x3)
%
"
2.00
4.00
6.00
13-Aug-2003 19:03:46
LC/MS/MS #6
MRM of 4 Channels ES-
9.36
499 > 99
91234
4.77e5
Area
8.00
: PFQSA
-34910-l 1 Spk E, 100000 rig/L, DF=lOO
381203A-3013
10 7
-1
%
Sm (,Mn. . 2x3)a
i
~`,",,,,,`,`,",`,,`,,,,,,"`,,~`,',,"'I,",I',,
2.00
4.-00
6.00
13-A~2003
19:03:4C
LC/MS/MS #6
MRM of 4 Channels ES-
9.98
12233 I
498 > 78 5.76e5
Area
I
8.00
1 0.00
Time
-
Eaqgen Research, 3058 Reseazch Drive, State College, PA 16801
,_.-,_ ...-_".._-.-l*-l~.l-.,-.-
111--
------_I_
stucly NO .:L34910, Set No.:O81203A, b
Ext.Date:O8/12/03,
Analyst:K.Risha
Sample List:
P:\Data\LCblSMS6\Masslynx\Fluoroch~cals.PRO\S~ieDB\O81203A
Last modified:
MOA Aug 18 10:47:09 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluorochexkala.PRO\MathDB\PFOS
Last modified:
MOA Aug 11 09:49:08 2003
Job Code:
Printed:
MOA Aug 18 10:50:26 2003
------
e--------------_---____c_
----
Name: 0812031-3014 Text :
1: C8 Sulfonate
(PFOS)
XC081 103-l) 25 rig/L Standard
081203A-3014 100-
Sm (Mn, 2x3)
---
Pags 14 Decatur BC and PFOSA 081103
-------
%-
n 0 , I, ,,,
, ,,, , , , t ,, , , , , , , , , , , St ,a I r II
2.00
4.00
6.00
,11311 2: PFOSA
XC081 103-1,25 rig/L Standard
081203A-3014 100-l
Sm (Mn, 2x3)
I I I II t / 8.00
I, I I a I, r I I ,, , . I I Time 10.00
13-Aug-2003 19:25:2 LCIMSIMS #6
%-
-gem Research, 3058 Research Drive, State College, PA 16801
-_I_-_--_-_-----__----~---_-_c_------------
Quantify
Sample Report
Study No.: L34910, Set No.: 081203A,
Ext.Date:09/12/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\L~SMS6\Masslynx\FluoroCh~ca~s.PRO\S~leDB\O91203A Man Aug 18 10:47:09 2003 P:\Data\LCMSMS6\Masslynx\Pluorochemicals.PRO\Met~B\PFOS Mon Aug 11 09:49:08 2003
Printed:
Man Aug la 10:50:26
2003
--
Page 15
Decatur BC and PFOSA 081103
Name: 0812031-301.5 Text :
L: C8 Sulfonate
(PFOS)
XC081 103-2,50 rig/L Standard
081203A-3015 10
Sm (Mn, 2x3)
13-Aug-2003 19:47:12
LC/MS/MS #6
MRM of 4 Channels ES-
9.36
499 > 99
2208
1.24e4
Area
"
2: PFOSA
XC081 103-2,50 rig/L Standard
081203A-3015 Sm (Mn, 2x3)
1__;_ Time
13-Aug-2003 19:47:12 LC/MS/MS #6
MRM of 4 Channels ES498 > 78 3.75e4 Area
Time
Oxygen Research, 3058 Research Drive, State College, PA 16801
Quantify Sample Report
Study No.: L34910, Set No.:081203A,
F.xt.Dats:08/12/03,
Analyst:K.Risha
'Iled
Sample List:
P:\Data\LCMSMS6\Masslyax\Fluorochemicals~eDB\O81203A
Last modified:
Mon Aug 18 10:47:09 2003
Method:
P:\Data\LCbiSMS6\Masslynx\Fluorochemicals.PRO\Met~B\PFOS
Last modified:
Mon Aug 11 09:49:08 2003
Job Code:
Printed:
_---
Mon Aug
--_--I___-____--I----T----------------_--I
18 10:50:26
2003
Name : 081203A-3016 Text :
1: C8 Sulfonate
XC081 103-3,100
(PFOS)
rig/L Standard
081203A-3016 10
Sm (Mn, 2x3)
9.36 421: I1-
Page 16
Decatur BC and PFOSA 081103
---
13-Aug-2003 20:08:511 LIZ/MS/MS #6
MRM of 4 Channels ES499 > 99 2.30e4 Area
'r, 2: PFOSA
XC081 103-3, 100 rig/L Standard
081203A-3016 lOO-
Sm (Mn, 2x3)
%-
Time 10.00
13-Aug-2003 20:08:51
LC/MS/MS #6
MRM of 4 Channels ES-
9.96
498 > 78
7.75e4
Area
I
10.00
I , I r I I Time
Exygen Research, 3058 Research Drive, State College, PA 16801
000452
-----me---
----___-
---_-----
Quantify Saq~le Report
Study No.:L34910,
Set No.: 081203A, Ext.Date:08/12/03,
Analyst:K.Risha
v Sample List:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~~leDB\O8l2O3A
Last modified:
Man Aug 18 10:47:09 2003
Method:
P:\Drlta\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\PFOS
Last modified:
Man Aug 11 09:49:08 2003
Job Code:
Printed:
Mon Aug 18 10:50:26 2003
---
e-e-
Page 17
Decatur RC and PFOSA 081103
Name: 0812031-3017 Text:
1: C8 Sulfonate
(PFOS)
13-Aug-2003 20:30:33
LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.39e4 Area
0-,,,,,,~,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,;~
2.00
4.00
6.00
8.00
2: PFOSA
`d IL3491 O-l 1, DF=l 000
081203A-3017 Sm (Mn. 2x3)
1 13-Aug-2003 20:30:3 K/MS/MS #6
MRM of 4 Channels ES-
Oxygen Research, 3058 Research Drive, State College, PA 16801
000453
-----
-__-----------_----_c___
-----__
Quantify Sample Report ,'I& Study No.: L34910, Set No.: 081203A, Ext.Date:08/12/03,
Analyst:K.Risha
Sample List: Last modified: Method: Last modified: Job Code:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\S~~eDB\O81203A Mon Aug 18 10:47:09 2003 P:\Data\L~SMS6\~asslynx\Fluoroch~cals.PRO\Met~B\PFOS Mon Aug 11 09:49:08 2003
Printed:
Man Aug 18 10:50:26
2003
-----_
Page 18
Decatur BC and PFOSA 081103
mine : 081203A-3018 Text :
1: C8 Sulfonate
(PFOS)
I134910-l 1 Rep, DF=lOOO
381203A-3018 `OO-4
Sm (Mn, 2x3)
13-Aug-2003 20:52:12
LC/MS/MS #6
MRM of 4 Channels ES-
9.35
499 > 99
4935
2.74e4
Area
L
2: PFOSA
IL3491 O-l 1 Rep,
DF=lOOO
081203A-3018 100-
Sm (Mn, 2x3)
%-
L
Time
13-Aug-2003 20:52:12
LC/MS/MS #6
MRM of 4 Channels ES-
-L19:-7.9367
498.70>e378
Area
0 ,.,.,.,..,,`..,,,,,,....,.,.,,.".,,.'..,.,,.,
Time
2.00
4.00
6.00
8.00
10.00
-en
Research, 3058 Research Drive, State College, PA 16801
Quantify Sample Report
Study No.: L34910, Ilru'
Set No .:081203A,
Ext.Date:08/12/03,
Analyst:K.Risha
Sample List: Last modified:
P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\S~leDB\081203A
Won Aug 18 10:47:09
2003
Wethod:
P:\Data\L~SMS6\Masslynx\Fluorochamical\PFOS
Last modified:
Mea Aug 11 09:49:08
2003
Job code:
Printed:
Yon Aug 18 10:50:26 2003
Page 19
Decatur BC and PFOSA 081103
Name: 081203A-3019 Text :
1: '28 Sulfa&
(PFOS)
L34910-11, DF=lOO
?
-
-. ...'k"
"
:' . L
081203A-3019
I inh, I `""i 7
% j
Sm (Mn, 2x3)
. .
13-Aug-2003 21:13:5
9.34
499 > 99
2.24e5
Area
w 2: PFOSA
L3491 O-l 1, DF=l 00
08120314-3019 Sm (Mn, 2x3) 100-
%-
13-Aug-2003 21:13:55
LC/MS/MS #6
MRM of 4 Channels ES-
9.96 138347
498 > 78 6.48e4
Area
Oxygen Research, 3058 Research Drive, State College, FA 16801
880455
Quantify
Sample Report
Study No.: L34910, Set No.: OBl203A, hd
Ext.Date:08/12/03,
Analyst:X.Risha
Sample List:
P:\Data\L~SMS6\MasslynX\Fluoroch~cals.PRO\S~leDB\O8l2O3A
Last modified:
Man Aug 18 10:47:09 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluorochamicals.PRO\WethDB\PFOS
Last modified:
Mon Aug 11 09:49:08 2003
Job Code:
Printed:
Mon Aug 18 10:50:26
2003
_----________-_--_____________________-----
Name: 081203A-3020
Text :
1: C8 Sulfonate
(PFOS)
L3491 O-l 1 Rep, DF=lOO
081203A-3020 Sm (Mn, 2x3) 100- 9.36
%-
Page 20 Decatur BC anc PFOSA 081103
13-Aug-2003 21:35:42 LC/MS/MS #6
MRM of 4 Channels ES499 > 99 2.51e5 Area
0 1111/11~1,1111,1111,1111,1111,1111,11/1]1~
2.00
4.00
6.00
2: PFOSA
w L34910-17 Rep, DFdOO
081203A-3020 10
3 %-
Sm (Mn, 2x3)
8.00
10.00
13-Aug-2003 21:35:42
LC/MS/MS #6
MRM of 4 Channels ES-
9.98
498 > 78
7.31e4
Area
0 "","","",""1"",`,","","","",
, . I I Time
2.00
4.00
6.00
8.00
10.00
Ekygen Research, 3058 Research Drive, State College, PA 16801
000456
Quantify Sample Report
Study No.: L34910, Set No.: 081203A, Ext.Date:08/12/03,
Analyst:K.Risha
'U
Saxnple List:
P:\Data\LCMSMS6\Maaslynx\Fluorochemicals.PRO\S~leD~\O81203A
Last modified:
Mon Aug 18 10:47:09 2003
Method:
P:\Data\LCMSMS6\Masslynx\Fluorochemicals.PRO\Met~B\PFOS
Last modified:
Mon Aug 11 09:49:08 2003
Job Code:
Page 21
Decatur BC and PFOSA 081103
Printed:
Man Aug I.8 10:50:26
2003
-__-_l----_-__----______I_____
-------w-e---
---------_-__-
Name : 081203A-3021
Text :
1: C8 Sulfonate
XC081 103-4,250
(PFOS)
rig/L Standard
081203A-3021 lOO-
Sm (Mn, 2x3)
%-
13-Aug-2003 21:57:23
LCYMSIMS #6
MRM of 4 Channels ES499 > 99 5.85e4 Area
2: PFOSA
`N& XC081 103-4,250
rig/L Standard
081203A-3021 lOO-
Sm (Mn, 2x3)
%-
, 10.00
I , I I Time
13-Aug-2003 21:57:23
LCNWMS #6
MRM of 4 Channels ES-
9.98
411227
498>78 1.97eS
Area
0 ~`~~,~`~~,~"~,~~`~I~~"l~~~`l"~`l~~~'l"~'/~'~
, I I
Time
2.00
4.00
6.00
8.00
10.00
Exygen Research,
3058 Research Drive, State College, PA 16801
Quantify Sample Report
Study No.: L34910, Set No.:Oa1203A, "lr/
mt.Date:oa/12/03,
Analyet:K.Risha
Sanyrle List:
P:\Data\L~SMS6\Wrsslyax\Fluoroch~cals.PRO\S~leDB\D8l2O3A
Last modified:
Non Rug la 10:47:09 2003
Method:
P:\Data\LCMSMS6\Masslynx\FluorochamicalPB\PFOS
Last modified:
Mon Aug 11 09:49:08 2003
Job Code:
Printed:
Man Aug 18 10:50:26 2003
Page 22
Decatur BC and PFOSA 081103
Name: 00120331-3022 Text :
1: C8 Sulfonate
XC081 1034,500
(PFOS)
rig/L Standard
081203k3022 Sm (Mn, 2x3)
13-Aug-2003 22:19:Oq LC/MS/MS #6
MRM of 4 Channels ES499 > 99 1.09e5 Area
,& 2: PFOSA
XC081 103-5, 500 rig/L Standard
081203A-3022 lo&
Sm (Mn, 2x3)
13-Aug-2003 22:19:0 LC/MS/MS #6
MRM of 4 Channels ES-
%-
~~.,.`,,`..,,...,`."
2.00
4.00
6.00
8.00
10.00
Exygen Research, 3058 Research Drive, State College, PA 16801
------
-------------------c_
-----__I---
-----e--
Quantify Sample Report
Study No.: L34910, Set No .:OB1203A, Ext.Date:O8/12/03,
Analyst:K.Risha
pw
Sample List:
P:\Data\LCMSMS6\Masslynx\Fluoroch~cals.PRO\Samp~eDB\OB1203A
Last modified:
Mon Aug 18 10:47:09 2003
Method:
P:\Data\LCMSMS6\Masslynx\FluorochemicalsB\PFOS
Last modified:
Mon Aug 11 09:49:08 2003
Job Code:
Printed:
Mon Aug 18 10:50:26 2003
----
Page 23
Decatur BC and PFOSA 081103
Name: 0832031-3023 Text:
1: C8 Sulfonate
(PFOS)
XC081 103-6, 1000 rig/L Standard
081263A-3023 lOO-
7 %-
Sm (Mn, 2x3)
13-Aug-2003 22:40:47
LC/MS/MS #6
MRM of 4 Channels ES-
9.36
499 > 99
2.13e5
Area
0 Ilrl,llll,~lll,,ll~,l~~l,llll/llll(l,l/,llI
I,
, , , , , , Time
2.00
4.00
6.00
8.00
10.00
2: PFCISA
XC081 103-6,1000
rig/L Standard
081203A-3023 100-
Sm (Mn, 2x3)
13-Aug-2003 22:40:4 LC/MS/MS #6
MRM of 4 Channels ES-
%-
0 !`r',/!r,,"r*,rr*I
2.00
4.00
6.00
8.00
10.00
J
Oxygen Research, 3058 Research Drive, State College, PA 16801
9/19/2003 Project: E03-0561
3MENVIR
ONMINMLLMORATORY FinaIRcpolt
1 of3
Requester: Schnobrich, Dana M (223-lN-08) Department: 530711 Project Number: 0022674449 Date Received: 6/26/2003 Project Description: Decatur Bakers Creek Comments:
#2 Surface
Water
and Sediment
Completion Date: g/2/2003
Project Lead: Jess S. Eldridge Phone Number: 65 l-778-5233 Email Address: jseldridge@nmm.com
Statement of Accuracy: Based on results of field spikes, laboratory spikes, field blank spikes, and laboratory control spikes, the analytical accuracy for all compounds is f 30%. Exceptions for the water samples are as follows: BC2 SW-04 high spike (PFOA 57%, PFOS - 62%, FOSA - 58%), BC2 SW-05 high spike (PFOA - 66%, FOSA - 400/a), BC2 SW-06 high spike (FOSA - 609/)), Outfall to River SW-25 (FOSA - 58%). Also, several low spike samples showed unacceptable recoveries in cases where the spiking concentration was comparable or below the inherent sample concentration. However, all laboratory control spikes, laboratory matrix spikes, and all other field spikes showed recoveries between 70% and 130% for all compounds. The accuracy for the sediment samples is based upon laboratory spike recoveries, all of which were between 70% and 130% for all compounds.
Sediment sample results are reported as received. Results reported as dry weight are available in the Exygen report.
REVISED REPORT: BGJ-Pace-9/19/03
Due to schedule changes, the original sample dates entered were revised to relect the actual collection
dates.
Pace Field Sampling Event - Complete
3M Sample Number E03-0561-49786
sampled Date 7l2 xxO3
Ii&! EXYGEN EXYGEN EXYGEN EXYGEN
E03-0561-49787
PFOS by ESMS PFHS FOSA PFOA
9i21i2003
Sample Description BC2 SW-04
PFOS PFHS FOSA PFOA
BC2 SW-04 DUP
EXYGEN JXYGEN EXYGEN EXYGEN E03-0561-49788
EXYGEN EXYGEN EXYGEN EXYGEN E03-0561-49789
L&E EXYGEN EXYGEN
PFOS by ESMS PFHS FOSA PFOA
7l23L2003
ical Methpd PFOS by ESMS PFHS FOSA PFOA
7Lw2003
PFOS by ESMS PFHS
PFOS PFHS FOSA PFOA
BC2
SED-04
m PFOS PFHS FOSA PFOA
BC2
SW-OS
PFOS PFHS
11.5 ng/mL 0.896 n&L 1.39 nahL 4.21 I&&
8.25 ng/mL 0.571 ng/mL 0.790 n@nL 2.54 ng/mL
14.6 rig/g 0.566 rip/g 7.15 rig/g 3.02 n#g
1.67 ng/mL 0.155 n@nL
EL
Oualifinr
0.05
0.05 0.05
0.05
BL
-
0.05
0.05
0.05
0.05
EL
OUlliripr
0.4
0.4
0.4
0.4
EL
Ourliner
0.05
0.05
Project: E03-0561 (cont.) 3M Sample Number
E03-0561-49789 (cont.)
I&! EXYGEN EXYGEN
E03-0561-49790
FOSA PFOA
SampledDate 7/21/2003
7m2003
EXYGEN EXYGEN EXYGEN EXYGEN
303-0561-49791
LAB
EXYGEN EXYGEN JXYGEN EXYGEN
E03-056149792
PFOS by ESMS PFHS FOSA PFOA
7nv2003
m
PFOS by ESMS PFHS FOSA PFOA
7n3mo3
I& EXYGEN EXYGEN EXYGEN EXYGEN
E03-0561-49793
PFOS by ESMS PFHS FOSA PFOA
7n3noo3
LBB EXYGEN EXYGEN EXYGEN EXYGECN
E03-0561-49794
PFOS by ESMS PFHS FOSA PFOA
7r2312003
EXYGEN EXYGEN EXYGEN EXYGEN
E03-0561-49795
PFOS by ESMS PFHS FOSA PFOA
7i23i2003
La EXYGEN EXYGEN EXYGEN EXYGEN
E03-0561-49796
PFOS by ESMS PFHS FOSA PFOA
7m2003
LAE EXYGEN
FXYGEN
EXYGEN
PFOS by ESMS PFHS FOSA
Sample Description
BC2 SW-05
FOSA PFOA
BC2 SW-05 DUP
PFOS PFHS FOSA PFOA
BC2
SED-05
PFOS PFHS FOSA PFOA
BC2
SW-06
PFOS PFHS FOSA PFOA
BC2 SW-06 DUP
Comnonentr PFOS PFHS FOSA PFOA
BCZ SED-06
PFOS PFHS FOSA PFOA
Outfall
to River SW-25
cPFOS PFHS FQSA PFOA
Outfall
to River SW-25 DUP
PFOS PFHS FOSA
0. I46 ng/mL 0.591 nghL
4.33 nghL 0.377 nghd 0.389 ng/ti I .56 nghnL
22.8 ndg 1.45 rig/g 7.86 rig/g 5.14 ngtg
26.1 nghd 6.06 nghnL 2.43 nghL 12.1 n&nL
25.1 nghd 5.87 nghL 2.57 nghL 11.6n&nL
880 rip/g 2.46 rig/g 71.4 ndg 14.2 nglg
31.2 n&L 7.66nghL 3.26 nghL 15.8 n&L
30.8 n&L 6.77 nghL 3.28nghL
l3L
Oualirtrr
0.05
0.05
EL.
Oualiner
0.05
0.05
0.05
0.05
EL
-
0.4
0.4
0.4
0.4
BL
Oualiner
0.05
0.05
0.05
0.05
BL
Dualinrr
0.05
0.05
0.05
0.05
BL
-
0.4
0.4
0.4
0.4
EiL
Dulllifrcr
0.05
0.05
0.05
0.05
BL
Oullifier
0.05
0.05
0.05
_a---."
.,- .__.~_
.---."
,... _._1.".1_."_
--
-_
9/19/2003
3MENVIR
0NMENTAL,LABOFL4'-K)RY Final Report
Project: E03-0561 (cont.) 3M Sample Number
E03-0561-49796
L&l
EXYGEN
E03-0561-49797
(cont.) PFOA
sampled Date 7i23i2003
7L23/2003
Sample Description Outfall to River SW-25 DUP
PFOA Outfall To River SED-25
UE
EXYGEN
EXYGEN EXYGEN EXYGEN
E03-0561-49813
PFOS by ESMS
PFHS FOSA PFOA
7i23l2003
PFOS
PFHS FOSA PFOA
Outfall
to River SED-25 DUP
LAB EXYGEN
EXYGEN FXYGEN EXYGEN
E03-0561-59479
LBB
EXYGEN EXYGEN EXYGEN EXYGEN
E03-0561-59480
PFOS by ESMS PFHS FOSA PFOA
712V2003
s
PFOS by ESMS PFHS FOSA PFOA
ll2V2QO3
PFOS PFHS FOSA PFOA
Field ControbTravel Blank
PFOS PFHS FOSA PFOA
Equipment
Blank -Pump
LAE EXYGEN
EXYGEN EXYGEN EXYGEN
E03-0561-59481
LAB
EXYGEN EXYGEN EXYGEN EXYGEN
PFOS by ESMS PFHS FOSA PFOA
7/21/2003
PFOS by ESMS PFHS FOSA PFOA
m PFOS PFHS FOSA PFOA
Equipment Blank - Dredge
ComDonentr
PFOS PFHS FOSA PF0,4
14.4 nghL
107 ndg 3.19 nglg 28.0 rig/g 10.7 rig/g
140 rip/g 4.98 nglg 35.7 rig/g 17.7 ndg
ND nghL ND llghL ND nghL ND n&L
ND nghL ND nghnL ND nghL ND ng/mL
ND nghL ND n&L ND nghL ND nghL
3 of3
a OuPlifier
0.05
BL
Oualirier
0.4
0.4
0.4
0.4
BL
Olaliner
0.4
0.4
0.4
0.4
EL
Ovalifier
0.05
0.05
0.05
0.05
BL
!ilulmc
0.05
0.05 0.05
0.05
BL
OuPliner
0.05
0.05
0.05
0.05
Project Lead Review:
Date: 9// 9/os