Document 9La89L4J8L4VQ1EyRN5Ner2DR
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TTEECCHHNNIICCAALL RREEPPOORRTT SSUUMMMMAARRYY
TO:TO: TECHNICAL TECHNICAL COMMUNICATIONS COMMUNICATIONS CENTER CENTER --- 201.20 201-2CN
Olmportant - If report is printed on both sides of paper, send two copies to TCC,)
------__ Division
Foy _Enneviirfoenmental Laboratory (EE & pC) __ Environmental Laboratory amental Laboratory(BR8PO) Proiact wFar te oof Pluorochenicals Fate of Fluorochemicals f e fluotochendoals Report Title
(EE & PC)
- Final Comprehensive Report: FC 95 Final To R. 4. Prokop R. A. my A Br Author(s).
Comprehensive Prokop
Report"
FC 95
o AN Verter A, N. Welter e Notebook Reference
mes .
SSEECCUURRITTYYD
3 -- [] Open ConlinJcoenteioowi e Sornons (Company Confidential)
[] Closed (SpecialAuthorization}
|I REUEonEbA 3M CHEMICAL REGISTRY
318/70
rm Dept. Number
0535 0535
rProject N um bar
--
9970612643 9970612643
ld Report Number
--
011011
-- I= mployee Number(s) 00362 09362
PEC NO. of Pages Including Coversheet
TF neirce Roegared 1122
New Chemicals Reported
i-"1 Yes
[] No
KEYWORDS: (Select terms from 3M
Thessann.Soi ae Thesaurus. Suggest other . sepia wins) applicable terms.)
Final Report: CURRENT OBJECTIVE: Final Report:
EtEhnneccoopmmeppraaissossdeess 1a9a7ll7ll
the period 1977
ww--oor11rkk99779pp9.e.errffoorrmmeedd
dduurriinn, gg
EEEE&&PPC -- DDiivv..
Fluorochceaml Fluorochemical
((((A aAaqnnquaauallatyytititcici)cc) aall)
CDO egrada A(Degradation)
~Soil) TTooxxiicciittyy
-- REPORT ABSTRACt': (200-250 words) This abstract information is distributed by the Technical Communications Center to
alert 3M'ers to Compar~y R&D. It is Company confidential material.
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aM coNFIDENTIAL 3M CONFIDENTIAL
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Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988..0000001
Exhibit 1198
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3sMMAAo0o011T7E6s8s800
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The
'
"
" 1 ~ij
on fluorochemicals has been discussea prevlous Y
Tehe esubjeocxttafcltuaonrtoychwemhiiccahlhoafs athipsoternetpiosrlt fiosrCwid95esp(raenad The subject fluorochemical of this report is FC 95 (an ion tn tho environment us (his material is used anionic surfactant) which has a potential for widespread a aking, and evening industrics, both domestically distribution in the environment as this material is used OT ernariona1ly TC 95 chemically 1s the potassium by the chrome plating, and etching industries, both domestically
and internationally. FC 95 chemically is the potassium
eee pertinaroostane sulfonic acid. salt of perfluorooctane sulfonic acid. Cg Pq 50K C8 FI7 SO3K vc 05 FC 95
Sht5s 4ma"teri5a5l8 ainsdantheoffc-hwehmiitcealposwidreurc,turheavisnhgown& maobolveec.ular This material is an off-white powder, having a molecular
weight of 538 and the chemical structure shown above.
T ThisEreporet lcoensoltiondaettesy,alloialveisloarbplteioninsftourdmiaetsi,ondeingratdhaetion, This report consolidates all available information in the Oe lubiiity and partition coefricients and defines areas of aquatic toxicity, soil sorption studies, degradation, The hrovabie environmental Tisk of IC 95. water solubility and partition coefficients and defines
setnods the probable environmental risk of FC 95. M VW hE eTaaeatvTteteehere orbdosessNoeoeonnplloueurbttxbthhipseilee..liritticsayymnuu,d,ebb.njjtebbesaciciholtoot dduemoloefgdefgrtrahatbtedodeecadcathohctiilnonooioninncgcsayualsaallnntdderhTeedappvssooeoorftiorisltbrl(sel~eg~ snoprre-d~gcej~iifio f.). oiinncneTTdhsdshteeteutsu~idadeeniiielesss.
specific experimental methodologys have been defined in
these reports and should be consulted for specific details.
A) Aquatic Testing A) Aquatic Testing eIheotsestisnhgiekprotthoactoldsesuetriilviezdedbyfUoSrEPtAhis(s19t7u5d)y(%y)e.re The testing protocols utilized for this study.were
modeled after that described by USEPA (1975)~.
B) Acclimation Procedure Acclimation Procedure
The bblluueeggiillll
rot ees eda in this study were obtained from private trout (Samo
ssuunnffiisshh ((LLeeppoommiiss gairdneri), and
fmmaaatc~hrreooa~cdhhiimrriuun~sn))oaw,,s
rainbow r(aPiinmbeopwhalee
trout (Sa~mo g~irdn~ri), and fathead minnows (Pimephale8
Caneates. "Stock fish were held in Tiberglass holding promela8) used in this study were obtained from private
She Fijiod with carbon Filtered well water maintained hatcheries. Stock fish were held in fiberglass holding
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FC95 Lot 5$3.Carbon-filtered well water of known composition
o
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c. Tetra-Min - a commercial fish food of known
SaicetiAvoailPablee ebys3 OoraInrspeFcatimoneavrndwCopyaingGa2C0oanfaisd0en8tial formation Made Available by 3M for Inspection and Copying as Confidential Information:
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988..00000022
composition
composition
swaoTese1 3MA00176881
-a3 -
0 ) hauatic Tovertebrages - 48 hour Static Log,
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.
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.
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.
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.
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(Duluth) Probit computer program on the 3M TRAC System.
C) A DhDttooaaoquppurhhFPasCnnCt.i4iaca0955,mm,FIaaniggrvlGnnosoeaatttr,,te55ib8822nr3300satSaaooaetrrrtgssgaavvnn-awaiirersy4syrm8mieinsnsgghcooppueuccernorortnneS cttcedeetesnsanttatt,t,inrrcdaaww tteLiipeoroClrnenea5s0sceeedxxffopporoorissnee44dd88carbon
.
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wtehlel well
aww dinadatistetterair,or, sn
w ww ioitftehhrethccechhoeemDumianicptceahadlnliaaaandddmddaeegddpnlaaaa.cnneddd
solubilized in carbon
solubilized
p Tersiot r cotoncethnetraatdidointisonweroef
the
42,
56, 75, Daphnia
m10a0gnaan. d
135
mg/l.
TuILCsC,e?5s,f0t ycvvaotalhlnuueceeessUnStwEwriPaiAttthiho(n99D5s5u%%lwutccehoor)ennffi4Piddr2eeo, nbnicc5tee6, clli7oim m5mpi,itutsstI0e0ww reeraprneerdocgcr1aa3allc5mcuum lolanagtte/eldd.
.
uthselngSM thTeracUSESPyAste(mD.uluth) Probit computer program on
TtTahhfheeteer3ttMeessttTthartappcrrood.tetSoosycccsorotelilmbeuu. dttiillbiiyzzeeUddSEPffoAorr (tt1hh0i7iss8)(g91i~)yd.dyy
was
was
modeled
modeled
after that described by USEPA (1975)~J.
.
Results
Results
dTaabtlaeob1taliinsetds
wuastienrg
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FpCa-r9t5i.tionTuicsoefmfaitceireinatl
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.
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.
200. FbCe p~5rojtoectthedis tporoppoossseedssrealabtiioocnosnhciepntrthatisionchefm acitcoarl
be projected to possess a bioconcentration factor
wofoualdpproximately
of approximately
200.
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Information
Information:
swmAcoress
3MA00176882
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
1119988..00000033
Ysc tic, a |
= bb/
(vereNo. Pre ' Lal
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Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
1119988..00000044
3MMADAO0011T766888833
.
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TABLE 1 - Physicochemical Characterization of FC-95
TABLE ] - Physicochemical Characterization of FC-95
. .
. o 0
.
.
.
PPaarraam meetteerr
Shi Solubility P---- Partition Core Coefficient
TTeests.t
[HE Veith Method neootanol/water n-octanol/water
RReessuullttss
7-10286 ppm
7-10
CSUusFFhhnunGCaadl-d-kkat99ee.5eu5rrewwctthUsahuaiesetsldtuuettffreoerroseeuisutnvnt.eddbbdicicootootoddoTnnerdedgobibginrteertaiiaodoacdcnancooatsstm mtiiipopovoelnnalm neetppttetsseledettoluyspuydedseynydurrtxdg~sgguu)sejt~t:.siit. lta liaitznnMsTnetteeihdduisnsttomoami.22iobbcrioItiroo/ooo2enddbbiaeesiatg-aglarlrcm amasdotrdoeanaanttcsftthehiitiooonnm
diTahtchewuovensslientttlrurw WaoaaC rCapieislsn,initstteeieeoohdnsfettfernrreBcm iM eNaveinetieeottm ctdrrmtrrooaooehnbnbifrtespTetosLslmaomssnnyaw Wytthsst~he~teitie:rcce.mihihmvassalD CDctoaooouewfnrufrdotilinduaC nCglghshdlddoeuettenm hdgshgoeeegeorraealsdibpeptteexoeeopr,reiiFFocoDD COdtse-0eec9c0da5ooatfftuddtuoritsir..dhn,hipisnmnoaaonrnotdgesstiteusttdhstiyen,,
&07" aTlheerocpolvailroncmaetnatbootsremoxtended periods SE time wiirorcd develop, hence this material would be expected to persist
in the environment for extended periods of time unaltered
hbiiL1IIcnfaynovaaeww im TtlhllooyeiyerRcrksokarevi"tiohntenbhrggm aRaiattaaowtw lbiteo`ieostrnctnerhhieaeiratavalddfflebslsedleuog.ugoradolriraoortasodohdmcaceddahthe.etieiegfgoomrm orninaarciddmcaeaeppaltrrlsiooees,oddi,intutuhchiicetoitttfrrohw hacFcaousCshhu.oetld9mbbm5eieieevobcnnenebayillFFsslyyuuoC Ggg-L-go9gone5rep.es.sritbteeiododhoWTfeleoohthgtana-htetse
have never observed the formation of FC-95 by either
Routes] Sherctore, the snvizommcniel Tovers I FC.95 routes; therefore, the environmental levels of FC-95 ant iCibatteen rtoedintrense ne a result of she esogenous anticipated to increase as a result of the exogenous
parreedmaotrion of these
are not production
of this material.
SSooiill ssoorrppttiioonn ssttuud diieess hhaavvee sshhoowwnn tthhaatt apppprrooxxiim maatteellyy 1188..88%%
Change 12 675770) of the Fe 3 Te adsorbs. torre Brith (range 14.6-27.0) of the FC 95 is adsorbed to the Brill
ssaannddyy llooaamm ssooiill uusseedd iinn tthheessee ssttuuddiieess ((TTaabbllee 22))((33))..
Complete dsmorotion of the se 55 which med bees adsorbed Complete desorption of the FC 95 which had been adsorbed
ttoo ssooiill wwaass aaccccoommpplliisshheedd wwiitthhiinn tthhrreeee ((33)) ddeessoorrppttiioonn ttrriiaallss ((TTaabbllee 22)).. MMoboibliliittyy ooff FFCC 99554(3~ss ccaallccu ullaatteedd u uttiilliizziinngg
GChRe" schon devised by Hamaker (Tunes adsorption sesttictents the scheme devised by Hamaker'-'whereby adsorption coefficients
C Convercea to a constants Rog Which SeEichie. he organie are converted to a constant, Koc, which reflects the organic
Sonuent of the S011. umkr O's chown that the. rersete content of the soil. Hamaker
has shown that the relative
Boni oz soup of estssidos eoutd ve aptormmees in mobility of a group of pesticides could be determined in
This inion" aba that a velative. auking mocsne tron highly this fashion and that a relative ranking, moving from highly
2001655 Samobi1e materials would pati. ta sprite co mobile to immobile materials would rg~ult. In applying
Bobi lo when compared 16 ChloRimbah, Ko 12:8." These data more mobile than Paraqual$ K . 20,000 and slightly less this test, FC 95 had a K
value of 4~--5~ing considerably
more mobile than Paraqua~ K
20,000 and slightly less
mobile when compared to Chloroacmben, K
12.8. These data
Thicate that Thoce. foroet which bindPe 35 to sors are indicate that those forces which bindCFc 95 to soil are
"1o0u"it:hehSe0n1c3e ahned Seoomppoinoctaerildyoeeohrop.rifoenctofthmattotrhiiss)mscsoorrinissa weak, hence the complete desorption of material adsorbed
to the soil and secondarily the fact that this material
iiss hhiigghhllyy mmoboibliele..((33))..
Results of the acute static aquatic tests are tabulated Results of the acute static aquatic tests are tabulated (Table'a3. "Based on aquitic Comers criteria sotabianed (Table 3). Based on aquatic toxicity criteria established oy NESS Fo 3 outa be considered s1iphily oxic. gy the by NIOSH FC 95 would be considered slightly toxic ;~ the Vartehrates and Snvertebrate wiitized in this tect (8)! vertebrates and invertebrate utilized in this test~ ) TIS hated that The Invertebyate daca correrate well It is noted that the invertebrate data correlate well
Ld
eacedAvBieamby3a Ororensppcatlomnaarr.d Copying535s0C45o5r5e8n formation Made Available by 3M for Inspection and copying as Confidential Information:
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988..00000055
-- 3MA00176884
.
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.
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.
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.
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.
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.
hatchability was not affected at based on these studies, although
hatchability was not affected at
this dose level. it is to be noted
this dose level.
that
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9
m ACngug/ns/1uilm lattiatalnianvkkre.ossuubggsgegeresvstatiitninoggn tthwhaaatts
the toxic made of a
the toxic
action of few fish
action of
FCin FC
95the 95
151.0
is
cumulative.
BaBaas3see0dd-daooynn tethhxeeposrrueersseuulltttsso oo1f.f9tthmhege/lhhi1i~g1fooppCaattFhhCool9loo5ggidicicdaall neoetxxaamcmioninnatatrtiiioobnun,t, e
.
to abnormal histopathology (Table 5). a 30-day exposure to 1.9 mg/l "" C FC
to abnormal histopathology (Table 5).
95
did
not
contribute
TABLE 2
TABLE 2
-
-
Soil
Soil
Sorption
Sorption
TTeesstt
oonn
FFCC
9955
.
Parameter
Parameter
Test
Solution
Results
Test
Solution
Results
SSooiill SSoorrppttiioonn
AdAsdosroprpttiioonn
Vater
18.8%
Water
18.8%
DDeessoorrppttiioonn
Vater
Water
1I0a000d~%soroobffedaam moouunntt
.
KKoo
45adsorbed 45
OC
.
.
MSMuaabcdjeeecAAtvvtaaoiPillarabbollleeecbbiyyv33eMOMrffdooerrIInnIssnppePeccattiiioomnneaarnn.dd3CCMo.oppyNyoii.nnggC2aa.ss0CC4o-on5nf3ifid0de9enntitiaall IInnffoorrmmaattiioonn:
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988.00000066
aA T6885 3MA00176885
*
.
.
.
.
_6-
6 -
TTAABBLLEE 33
FFCC 9955::
9966
HHoouurr
AAccuuttee
SSttaattiicc
Testing
Testing
TTeesstt OOrrggaanniissmm
6m9g6h/h1 LLeCgS,0
mg/l
Fathead Minnow
Fathead Minnow
335177..66
51
BBlluueeggiillll SSuunnffiisshh
0688
RRaaiinnbbooww TTrroouutt
I1ni
BB.. IInnvveerrtteebbrraattee 4488 HHoouurr SSttaattiicc TTeesstt
DDaapphhnniiaa ~Maaggnnaa
559O0.2
49.2
mllgoo/ww1eerr mg/1 212688..44 46 6622 88..66
434282...887
38.7
LLiim miittss
UU mpgp/pp1eerr
mg/l
555600..22
56
774 1122..55
555666.6
56.6
.
.
M`MSauacbdjeeecAAtvva0aiillPaarbbollteeecbbtyyiv33eMMOrffodorrerIInnIssnppPeeccattliioomnneaavrnn.dd3CCMo,oppyNyoii.nnggC2aa.ss0CC4o-on6nf3ifid0de9enntitiaall IInnffoorrmmaattiioonn::
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988..00000077
33MMAA0000117766888866
.
.
0
o . .
.
7 -
.
TABLE 4
Percentage Hatch, Percentage Survival, Mean Total Length and Average Wet Weight of Fathead Minnow
V Frayryi(nPgimC epohnaZcee~ntrpartoiomneslaoSf)l~CurFinCg95E. ~usure to
Concentration mg/l
11..99
Hatch %
5 95
1.0
96.5
0.45
96.5
0.28
95.5
0.12
97.5
Control
98
Solvent Control 89
Survival %
4422c
86 90 94 95 93 100
90 Days Post Hatch Total Length Wet Weight
mm
2200..55
20 20.5 21 20 20 21
mg
7722
62.5 66 64 63 61.5 64.5
bWawoorrkk pperrffoorrmmeedd bbyy EEGG&&GG BBiioonnoommiiccss LLaabboorraattoorryy,, IInncc..
bsummary table submitted to Environmental Laboratory, 3M, St. Paul, as part of final report.
C "SSiiggnnififiiccaannttllyy rreedduucceedd aatt PP == 00..0055
TABLE 5
Histopathological Examination of Fathead Minnow 14
(Pime~h~les promela~) exposed 30 day to 1.9 mg!1 C
FC 95 '
Test Material
Number of Observations
Histopathological Findings
Control
I0
9/10 fatty liver change
M14eCrYeC 0955
891///1I1000 b ttiiasscssutueeeriaaauluttog olliyylslsiissdisease
1100
8//1100 ffaattttyy lliivveerr cchhaannggee
2/10 normal
Wawoorrkk ppeerrffoorrmmeedd bbyy EEGG&&GG B Biioonnoommiiccss L Laabboorraattoorryy,, IInncc..
St. Paul, as part of final Summary table submitted to
bsSutm. mPaaryul,tabaslepsaurbt moifttefdinatol
report. EEnnvviirroonnmmeennttaall
report.
L Laabboorraattoorryy,,
33MM,
'
.
MMaacdee AAvvaaiillaabbllee bbyy 33MM ffoorr IInnssppeeccttiioonn aanndd CCooppyyiinngg aass CCoonnfifiddeenntitiaall IInnffoorrmmaattiioonn::
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988..00000088
33MA00176887
.
Co
.
.
.
_88 -
BcBooontththrogglrr,oouupp6s/s10oo,ff ooarnrgdgaanndiiosssmmesds eeoxrxhghiaibnbiiittseemdds f8fa/a1tt0tty.y lliBivvveeirdrenccchheaanngogefess,,tissue
Scuotnotlryosli, s9/i1n0,theandcondtorsoeld gorrgoaunpisimss i8nd/1i0c.ativEevidofencaedeolfaytissue
of the organism. ainuthoilsytsoisloginicathleprceopnatrroatliognrouopf
in histological preparation of
itsissinuedsicafotilvleowionf ga ddeaetlahy
tissues following death
of the organism.
DDiissccuussssiioonn
The primary purpose of this roport is to provide a single
C35 and to provide an analysis of potential environmental source for The primary
source for
aalplllurpeeonnvsveiirrooonnfm meteh nntitsaall
data report data
generated relating to is to provide a single
generated relating to
FrCisk9.5 and to provide an analysis of potential environmental
risk.
wTThhheie cheennvvciairnroonnbmmeeendntet pimmacaytyedbbee asccoonfnsosilidldoeewrrese:dd
to
to
be
be
a
a
closed
closed
system
system
which can be depicted as follows:
Ay Soil
. N\ wt Water
mIIatt,j, ttehhseetrareebfflooirsreeh,, anffoollellqoouwwislsibtthrhiaauttm,cchherememimicacaialnlsswieetnnhttieenrriinnagg sttihhnigisslessyyessnttveiemrmonment,
omr'ay iempsatactbliosnhalaln pehqausielisbroifumt,heredm epaiinctewdithcinyclae.single environment,
or impact on all phases of the depicted cycle.
9
oIInfn
FtthhCee05ssppeiecnciiftfiihcce
ccfaaossleelowaatit nghhaannmddannwweeer:ccaann
represent
represent
the
the
impact
impact
Yo Photodegradation Air Volatility ? of FC 95 in the following manner"
No Photodegradation ~
Air
.~, . Volatility ?
Soil__.
Soil.
No,_ No BBiiooddeeggrraaddaattiioonn
orgy NE, com .
VolRaRatatitele?i?ty
N~X q~
a 19% Comple%~!7
desor~t~o~rw 19%
Adsorbed Adsorbed
Toxic to Fry 19 m/l ------= yager" ----------> Sediment Toxic to Fry 1.9 mg/l
/// Water
~ Sediment
286 pon
yd
JPPrroojjeecctteedd ttoo m miinniim maallllyy bbiiooccoonncceennttrraattee,, llooww lliippoopphhiilliicciittyy
.
.
.
ApApTsrhsreiim msscactarhhariereilmlrm yyaetsatibtbircyyciaaalmmllleleyyaanenscsrreoepsoopfyrfreseststtheeehneenmtteew waddanadtteeaarrabbwwtooamvvayoeeyssspFFhCCaaennrdd99e55.sseeeeccnnoFtotnCeendrrdsas9ar5rittihlhldyeyeoesvveeinniaavnvoiirtroonnm meenntt datahdedesssooorrtrbebpsrfrppoeeenrrsm mtaroafinnaeenlFnCttlelyyc05osttoyofsrteoeeinimtthh0eea1rnr1dssdoaoiitim ldl ooaasncnpdcdh/u/eororrer.insseeddFtCiihm mee9en5lntat..dbooreasC Ctooomnmrpoyplt leettee m md 2o7eodd%seecoll~trV ~w~oh.C0"nichoTIttf aFsfiCsssunuu9c5nnksknnforoiowwmmnnpoww srho theaietnlthchoederridinooror c1mncioguothrtt ttignhhfiissthtemm haeatlaetferbirioniadarlailntogvvrooyllaattiilliizzeess,, ttafhhoaarftatecgFFotCCiw ng99h55icihdtdooeaaessspspuennmoaotretss uunncim hddaeeptrroggroowtaanptpcheheorowttaoionyllsyyslsiiagisrshe.~"lt~h5e tehnB Bevaaisserefiddonndmooeinnnngttthahlee Sink for foregoing FCit 95apapnedarsaquthataitcwoartegrawniasymss aarerethteheenivntireornmm edeinattael
sink for FC 95 and aquatic organisms are the intermediate
MSMuaabcdjeeecAAtvvataoiillPaarbbolleteebbcyyiv33eMMOrffodorerIInnIssnppePecactitiiomoennraavnn. dd3CCMo,oppyNyoii.nnggC2aa.ss0CC4o.on6nf3ifid0de9enntitiaall
Information
Information:
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988..00000099
aA 688s 3MA00176888
. ,'
receptors. It is in the aquatic area that a ~ deleterious action o FC 95 may be found.
152 Se Fecoriad al FC BT LONL TILER oF athens mi As noted above, reduced survival rates of fathead minnow
fry were recorded at FC 95 concentrations of 1.9 Ppm. The no effect level of FC 95 may be assumed to be approximately 0.19 ppm. These data may serve in a predictive fashion, hence the above noted levels of FC 95 may impact on a human food sOUrce by significantly reducing the survival rates of these organisms.
It is to be emphasized that the environmental concentration of FC 95 more accurately describes the degree of risk associated with this chemical.
We have made severalassumptions which are basic to the simplistic model used in our calculations: . l1)) TT inoottaialtls pperonddtuiurccetttiiyoon.n iiss aatt CChheemmoloilittee aanndg iitt iissdidsiscchhaarrggeedd
2) No FC 95 is removed by the treatment facility.
3) All effluent is discharged to the Mississippi River.
4) FC 95 is discharged uniformly.
5) River flow and all other parameters are constant, hence not subject to seasonal and/or climatic conditions.
The formulae Used in these Projections include:
omc op I) MG/min = (RRi_i__v_everr Floww~CCFP~M)(~Coonnvveerrssiioonn,.~agal],/f1633)~. Time, min
2) MG/min X 1440 = MG/Day
, ~=x ~nnum
33)) LLbbss//dayy == ((m mgg//1l XX w wet,.
Mississippi River flow at low flow record is I0,000
Ibs. H20 per gal)(~G/Day)
lbs. By0 Per gal)(MG/Day)
Hastings, MN, based on a I0 CFS.
.
TThhee
ttoottaall
5S--yyeeaarr
pprroodduuccttiioon
.
figures
we
~ear
~icker,
zigures
Commercial
an est~-~i
~,__. ~
~u~m~cas
f~gures were
Division
ifPr~ov[ifd~eud
~byy UD,.
RRr.,
n
the
Mi SSl_. ss. lxpmp. a]~e.R~~v-eenrvirbo~n.m.e.n.t.a.l.. co
n UEl. llzin g t hese
During the period 1973 1978~u~fh~une~ mo-l.l~~reentwraastlcoanlcuolfatFeCd 95
to h~ e ~~ ng/,,l at Has -
, .... ~u ~or FC 95
-"
the period ~av~ .~^~ngs, MN, Whil~ ~ ~
was calculated
wa .... - ~?'u-lw~ is Droieef~ ~w m~ Projected f~
is determ~i-ned ",t=h-~at xas t t~thee ePnrevsiern.o ..t..-..a~ ~n,d-a.lpsr"oi'n~ jek'c_tleodt~IFlneCcvee95ltsheiot f
Production, FC 95 Will not present an unreasonable environmental
o
risk.
.
eSiean rr SeCsena Made Available by 3M for Inspection and Copying as Confidential Information:
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
1198.0010
33MMAA0000117766888899
*
-- 1i00 --
. . .
o
. . . . .
CCoonncclluussiioonnss
UUnnddeerr tthhee teesstt ccoonnddiittiioonnss eemmppllooyyeedd iinn cchhaarraacctteerriizziinngg tthhee , y
pphhyyssiiccoocchheemmiiccaall aanndd has been determined
eennvviirroonnmmeennttaall pprrooppeerrttiieess ooff FFCC 9955
ONSESPERV that this material:. , ~,~ ~ ^,~%.~')
iSt ioofdrde ANT
322I1)))))
hhiiisassass wwraeaaatnnsteiersnnr t--aoossncoocttlltuuaabnnbtlooolelel,,/mjwiwac22atr88te66oerbrip papppp lamarm r= tdtiiett/giirooaTMnn\ datcciooosentfffiicciiee<~nntt
ooff~~n1100T_NP' s
i
Oy
4435))))
5)
miiIiIsissnnnnrhhaaeoiiwggcschhooisllnnftyyttrayrrnmaamcoocwttbabtseiietodldleerm ossdttiiiunuuncddcryyeBBo,,drrbiiillstsallouul rrvvdsasiiaaevvnnsgaaddtrllyyaatdirllrasaooatittaatoemmeincaoossfflooliillytthheesigffnaaittfhheieacaddant Ah @Se
mFGFeniCCxxonttroen99nn55ow..ttwaswwfhhrNNaeeyoobnnnwoooarttttsmhhhhaeeeelrrreeedpphxxuaiappcrsrooeastasdmuomuerperteaetteoterhrccsosooalnnocwwcsgeeeetyrnrnaetettrroiaabsaatttsddiiievvoocreennavrrlessledewwylalayssyatsiaa11gf.f.tn99ffhieeifmccmsigtgt/c/eedlalddonste
66)) wwonTloooeeruvvueell`llddwa..papshhraaovvaxeebinmoaaarnntmeaelelysstthii7mimasantttgeoe/ddp1ateuehnnnodvvleiiorrrgooyncmmoeeonnnbdttisaatellirovneccsdoo,nnaccteewnnhttetrrrheiaasittniioodnnoaslel
oFufCCnifa95o55prpnwwrlaeoyrrxeeimiammntaatennoluuyfftaahcce7ttuuMnrrgiee/sddlsisuaasttnidpeCCprhhieemmcooRollinvidieittrtee.ioaannnsdd, wwowouhulelrddeibbnee
daillscharged
discharged
77)) mumbblaaniieyyioovflleoolonnrgsoogtmtiilccoyaafbblleeFiCnaddateemomgg95eerr.taattddaahaabebttooiill~ooiiinntts,,eesishhaassseeinnpccaapeeirreennssRooiuuvlliiettnnrcc.ororffeeaasscceehheemmiiiinnccaaeellnnvviiooTrrrrooSnnmmpeennmttaaell n.. t
8)
8)
FFplCCreevse995le5,sn, t
uuofnnadndeFeCrurnr9tth5eh.eaesotteneassbttleccooennnddviiittiriooonnnmssenddteeasslccrriirbibesedkd.
will
will
not
not
ifm"iWy
present an unreasonable environmental risk.
SuDpe vo
Bibliography
AP"
Bibliography
1.
MMeenndd`aeenldl',, SuAA.p.,,porTTtee"cc,hhnniiJccaaanlluarRRyeeppoo1rr7tt,.. 19""7AA9nn.aallyyttiiccaall
Methodology
Methodology
~%~
and Support", January 17, 1979.
2.
RReeiinoneferr,,FlEuE.o.AA r.o.,c, arTTebecochnhnsniic-caal1l 11RR,eeppoJorurtlt:y:
19BB,iiood1de9e7gg8rr.aaddaattiioonn
Studies
Studies
of Fluorocarbons -III, July 19, 1978.
3.
3.
W Weellsashnh,d,
SFS.C.K K.1.,,43T TeoencchhnSnioiicclaa,ll
RR Feeepbpororurtat.r. y
AA 2d7d,ssoor1rp9pt7t8iio.onn
of
of
FC
FC
95
95
and FC 143 on Soil, February 27, 1978.
4.
4.
UUSS//EEKPPaAAcro--inMMevetethrhotodedsbsrafftooerrsA AcacunudtteeATT mopoxhxiiibcciiiattynys,TTeesEstct ow wlioitgthhicaFFliisshhR,e, search
M Searicerosin6v6e0r/t3e-b7r5a-t0e0s9,and107A5m . phibians, Ecological Research
Series 660/3-75-009, 1975.
5. Unpublished data
5. Unpublished data
6.
6.
CChhiioonuud,, CCRaoardryygerTT..,,IL. VViKirorghginiellrtHH:.. FFrPreeaeerddt,i, tiD DoaanvviiddCoeW.f. fiSScccihhemmneetddddiainnngdg,,
BEaBnniidvooiaarRccocconuudmmm geaeunlrtlaaatLtli.ioonnK ScoooihfefnnecSSreete:lleaecnctdP teeaddTretcOO ithrringgooaanlnnoiigccCyoCCeh1hfe1efm(imi5c)ciic:aealnls4ts,7, 5a-n4d78,
1077. Environmental Science ~nd Technology 11(5): 475-478,
1977.
7."7,
WHaammaCakhkeeerm~,i, caJJl..W sW,..,, C Cohlelmecictailosn,
Hu""mIIan nntteerrHpperareletttahattiiaoonnnd oHfumDaon w HSeeailcthntiafnid
c
otofhfeSSoEoinilvlirL Loeenaamccehhniitnn,gg thPeapeErnsv,iroVnolm.en1t,,
E EAxxppeerriim meennttss"" ADow
C ChoelmlieccatlionUSAo,f MDiowdlaSncdi,enMtiicfhicigaPnap4e8r6s4,0.Vol. I, Dow
Chemical USA, Midland, Michigan 48640.
MSMuaabcdjeeecAAtvvtaaoiiPllarabbolll~eecbbiyyv33eMOMrffdooerrrIInnIssnppPeecactiiioomnneaarnn.dd3CCMo.oppyNyoii.nnggC2aa.ss0CC4o-on5nf3ifid0de9enntitiaall IInnffoorrmmaattiioonn:
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988..00001111
MADO176890
3MA00176890
on
=
ii -
o .
8. R ReeggiEisdstitrrtyiyonoo,ff TCThoorxxiiisccteE Enffsffeeencc,ttHss.Eoo.ff CaCnhhdeemmiEic.caJa.ll SSFuaubibsrstctahaninlccdee,ss,, Ed''7s7.66
E ppan-.dxdxivvtaaiWonnendldf, aC CriCie,,h;rUUi.sN.SStae.t.nisD oDeneenapp,laH arrt.tIEm mne.sentntaitntduooftfeEHH.eJfea.oalrltFthhOa,c,icrucEEpdhdauiutlccdiaao,ttniioaoEnlnds.
aSSnaadffeetW tyy elaafnnaddre;HHeeaNallattthhi,o, nWW aal sahsIhininnsggttitotounn,t,eDD.f.CoC.r.,,
June, 1976. Occupational June, 1976.
9.
WWeellttFeeCrr,,51A4A..2NN3..0,, LoTTteecchh5nn66ii,ccaallFeRbReerppuooarrrtty:: 16,AAqquu1aa0tt79ii.cc
Toxicity
Toxicity
Studies:
Studies:
FC 214-30 Lot 566, February 16, 1979.
10. Welter, A.N., Technical Report: Aquatic Toxicity Studies:
WeltFeCr,232A.NL.o,t T61e0c,hniJcaanluarRyepo1r7t,: 197A5q.uatic Toxicity Studies:
FC 232 Lot 610, January 17, 1979.
1I1I.. TTooddddU~,sinJJ..gW W.S.,i, muTTleeaccthhenndiiccaSalulnlRRieegpphootr,rtt:: JanFFCuCar99y55//P9P,hhoot1to9o7ll9yy.ssiiss SSttuuddyy Using Simulated Sunlight, January 9, 1979.
3
.
.
. MSMuaabcdjeeecAAtvvao-aiPil~raabo-bltleeecbbiyyv33eMOMrffdooerrrIInnIssnppePeccattlii0omnneaavrnn.dd3CcMo~,ppyNyoii~.nggC-a2a-~s0Cc4oo-nn6ff3iidd0ee9nnttiiaall IInnffoorrmmaatitio0nn:i
Subject to Protective Order In Palmer v. 3M, No. C2-04-6309
11119988..00001122
. 33MMAA0000117766889911
