Document 9Jo4boz1aM3m5Jv9mG75pnpoR

MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: oman eS A A SR FC-1094 FLUORAD(TM) Brand Fluorochemical Su--actant ID NUMBER/U.P.C.: 98-0211-6603-2 00-51135-10422-4 98-0211-660d-0 00-51135-10423-1 98-021--6685-7 00-51135-1042&-8 98-0211-8859-8 08-Sl135-10972-4 ISSUED: FEBRUARY 6, 1997 SUPERSEDES: AUGUST 22, 1896 DOCUMENT: 05-6285-0 I. INGREDIENT C.A.S. NO. PERCENT NA''ER ................................ 7732-18-5 AMMONIUM PERFLUROALKYL CARBOKYLATE .. 3825-26-- 1~.0 - AMMONIUM PERFLUOROALKYL CARBOKYLATE .. 6139-43-4 0.1 - AMMONIUM PERFLUOROALKYL CARBOXYLATE .. 21610-47-4 0.1 - AMMONINM PERFLNOROALKYL CARBOXYLATE .. 68258-11-0 0.1 - NOTE: The i~lgr~dienSs o Lh s piocucL aie i~cluded on 7SCA. 2. PHYSICAL DATA faa Doi BOILING POINT: ............... ca. i00 C VAPOR PRESSURE: .............. ca. 18 mmHg ~ Calc. @ 20 C VAPOR DENSITY: .............. ca. 0.62 Air 1 Calc. @ 20 C EVAPORATION RATE: ............ < 1.0 Butyl Acetate Frans SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. ca. 1.1 Wate- 1 PERCENT VOLATILE: ........... 80 % pH: ......................... ca. 5 V viIsSoCoOsSaItTtY:: evens .................. nT (2.0% Aqueous) N/A MELTING POINT ................ N/A APPEAR~iqCE AND ODOR: Light colcred liquid; slight 1 cdor. 3. FIRE ~ EXPLOSION HAZARD DATA 8@.@ 21.0 1.0 1.0 1.0 FLASH POINT: ................. Setaflash None FLAMMABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam Abreviations: N/D No_ Determined N/A Not Applicable 22777722AA..00000011 Exhibit 2772A State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055441199446600 sesreinraces) mean Porochemicnt suctactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 6, 1997 PAGE: 2 ot 6 33. IEFIREaANDBST EXPLOSIONBHAAZNARDD NA DATA eons (continued) Tealeioe Posesuee 2% Bevtote Spas Sosshins. shpesstes: Binrer SPECIA!~ FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, race mask, and protective coverinq for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo~ products of comus_ion. T08tcoat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS TO AVOID: Not Applicable HAZARDOUS POLYMERIZATION: Will Not Occur HAZCCaAarRrbbDooOr.nUSM MDoonEnoCoxOxiMidPdeOeSIaaTnndIdONCCaarPrbbRooOnDnUCDDTiiSoo:xxiiddee,, OOxxiiddeess ooff Fluoride, ~nmonia. N Kiittrrooggeenn,, Hdpyddzrooggeenn 5. ENVIRONMENTAL INFORMATION Phreical anheaLoh assests EespATatocy protections vemeiiacion, amd SPILL RESPONSE: Refer to other sections of this MSDS for physical and heal h hazards, respiratory information protection, regarding ventilaton, and personal protective equipment. In the U.S.A., call (612) 733-11@ or 1612) 733-6100 for 24-hour spill assistance. Ccntain sill. Cover with absorbent ma_eral. Ccllect spilled material. For spills to grollnd: Collect contaminated soil. Pllmp contaminated water from puddles or stagnant storm sewers. ?lace collected waste in approved containers, and seal. For spil s to ground or surface water: Notify appropriate authorities. Contact 3M to evaluate further needs. RECOMMENDED DISPOSAL: ncinerate in an industrial or commercia facility in the Fass contaminated water thecuh anion exchange cosine If a coll@~ustible material. Combustion products will include Pass ccntaminated water thrcllgh anion exchange resin. If contact 3M for assistance. p-esence cf necessary IIF. necessary, ENVIRONMENT/~L DATA: Tee Tee phen solder Craxical Qcygen Daman (C005 NEL (0.00070 Data fcr product solds: Chemical Oxygen Demanc (COD): Nil (0.00070 g/g); 20-Day Biochemcal Oxygen Demand (BOD2@): Nil; 96-Hr. LC50, Shins Sukeian (LaponisTabrochiEae)s 569 mastsSoe, Lise, Fiend Bluegill Sunfish (Lepomis macrochirus): 569 mg/L; 96-Hr. LC50, Fathead Minnow(Pimephales piomelas): 766 ln~!L; 48-Hi ECS0, Daphnia magna: 6~2 fib Star pi pp Ra mgiL; 14 Day EC50 (cell dry weight), G~een Algae (Selenastrum capriccrnutum) 73 mg/L. Soil Adsorption Coefficient (Koc): -7, ~ndicates very nigh mobility. (St/]dy used a sandy loam soill. Volatile REGULATORY Volatile Organic Compoundst INFORMATION: Organic Compounds: N N//A A.. Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722AA..00000022 I3MM_MMNNO0S5441189446611 LT -------- MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 6, 1997 PAGE: 3 ot 6 a 5. ENVIRONMENTAL INFORMATION (continued) -- SE ER VOC Less H20 & Exempt Solvents: N/A. Since regulations before disposal. vary, consult applicab e U.S. EPA Hazardous Waste EPA Hazardous). I regulations or Number None BE authorities (Not U.S. ~he components of ths procuct are in compliance with the chemical registration requi-ements of: TSCA, EINECS, CDSL, AICS, MITI. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSURE : No No I~EACTIVITY : No ACUTE : CHRONIC : Yes Yes SUGGESTED FIRST AID EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. ET SR RE IEI AE SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a ~nysic an. Wash ccntaminated clothing before reuse and dispose of son_amnatec shoes. I ST INHALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin conLac_. Weai ap/iopiiaLe gloves when handling Lhs TIA Sr wn pry material. A pair o- gloves made from the follo~ing material(sl are recoK~rlended: utyl rubber. Use one o~ more of the following personal protection tems as necessary to prevent skin con act: head Ei ae aL covering, coveralls. Protective garments iother than glovesi should mot vite oF teTotloniog maces aber ' be mace of eiLhe~ o- Lhe following ma_eials: polyethylene/polyvinylidene chloride (Saranex) Coverall made of Tyvek(r). Hear- r/lbbe'- boots when cleaning up spills. Use with appropriate local exhaust ventiation. Provide sufficient VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf-cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is rot adeq/late, use appropriate respiratory Asbreviations: N/D - No Determired N/A - Not Applicable 22777722AA..00000033 33MM_MMNON0055441199446622 M08: 7-054 FLA) Brand Pluosochesioal Sureactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 6, 1997 PAGE: 4 ot 6 Co7. mPsREcCkAUmToIOwNAwRyY TIRNFAORTMAITIOONN ((eceonnttintueedd) protection. RESPIRATORY PROTECTION: Avoid breathing ot vapors, mists or sp-av. Avoid breathing ot airborne material. Select cne of the fo lowing NIOSH a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA regulations: full-face high-efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENT2~L INGESTION: Do not eat, drink or smoke when using areas thoroughly with soap and water. before eating. ths procuct. Wash exposed Wash hands after nandlng and RECOMHENDED STORAGE: Store at temperatu-es above 32 degrees F (O degrees C). container closed when not in use. Keep FIRE AND EXPLOSION AVOIDANCE: Not applicable. OTHER PRECAUTIONARY INFOP!4ATION: HMIS KAZARD RATINGS: HEALTH: 2 FL~@MAB LITY: @ REACTIVITY: 0 PERSONAL ?ROTECTION: X (See p-ecautions, section 7.) INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* WATER ................................ AHMONIUM PERFLUOROALKYL CARBOKYLATE .. AHMONIUM PERFLUOROALKYL CARBOKYLATE .. A~IMONINM PERFLNOROALKYL CARBOKYLATE .. AHHONIUH PERFLSOROALKYL CAR~OXYLA'I'E .. NONE 0.01 0.1 0.1 0.1 NONE mg/m3 mg/m3 mg/m3 mg/m3 NONE NONE TWA ACGIH Y TWA 3M Y TWA 3M Y TWA 3H Y * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to pee Ststhuse 1 heoacsc sett 7 EL the pctential contrbution to the ove~a 1 exposure by the cutaneous route incll~ding ml~co~s membrane and eye, either by airborne or, more particl~larly, by direct Somacs with the subatencer vehiLles Cun alvas shin Seception: by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOUIqCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Indl~strial Hygine Assoc. Workplace Environmental Exposl~re 3H: 3H Helisal ~epartment Guideline - NONE: None EsLablished Level Gl~ideline Commsow 8. HEALTH HAZARD DATA EYE CONTACT: No toxicity ~ata fo~ the solution. Robceriations WD = Now Determined MWA = tot Applicable Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722AA..00000044 33MM_MMNN0055441189446633 MMSSDDSS:: PFGC--1I009844 FFLLUUOORRKADD((TTWM)) BBrraanndd FFlluuoorroocchheemmiiccaall SSuurrffaascttaanntt FEBRUARY 6, 1997 PAGE: bot 6 J 8. HEALTH HAZARD DATA (continued) Single exposure may cause: Moderate Eye Treitations signs/symptons can include cedness, Hcderate Eye Irritation: swelling, pain, tearing, and mazy vision. swelling, pain, tearing, signs!symptoms can and hazy v sion. include redness, SKIN CONTACT: signe/symptons can include redness, sel ing, and itching. Mild Skin Irritation (after prolonged or repeated contast): signs/symptoms can include redness, swel ing, and itching. May be absorbed th-ouqh the skin and persist in the body fo- an extenced time. Mo toxicity fata for the solution. No toxicity data for the solution. INH/J~ATION: by Inkalation to moderate llness requiring medical by inkalation to moderate cusntities of attention may cuantities of this material result from a single this material. exposure Hay be absorbed by inhalaticn and persist in tke body tor an extenced time. No toxicity data for the solution. Kepeated inhalation exposure produced Liver changes and elevated Repeated inhalation exposure produced bleed Crpmneriuecide dowels in nue, } blood crganofluoride levels in rats. liver changes and elevated Single overexposure, above recoK~nended guidelines, may sause: Zrsitation (sper sespleatory): signs/symptoes can include Irritation (llpper respiratory): signs/symptoms can inclllde screness of <he nose and throat, coughing ang sneezing. screness of _he nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended guidelines, may cause: Liver uetects: signa/eymptons can include yellow skin(jaundice) Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. IF SWALLOWED: ngestion is not a lkely rcllte of exposl~re to this prod~c . Sines say cesiic on a single saaliouing of 8 mderste quinticy of llness may resul_ -rom a single swallow ng of a moderate quantity cf this material. Ho toxicity data for the solution. No toxicity data for the sollltion. CANCER: WARIING: Contatas a chemical vhich can cause cancer. (3825-26-1) WARNIhG: Contains a chemical which can cause cancer. (3820 26 1) 1983 and 1993 studies concucted Join:ly by M and ubent) 11983 and 1993 studies concucted join_ly by 3H and DuPont). mami: MUTAGENICITY: eoriun pulustoalhsl corbonylale was mol utagwiic in initio Ammo~liull pei1uo~oalkyl c~rboxyla~e was mutagenicity assays. Did not cause cell transformation in a mammalian mutagenicity assays. Did not cause cell noL muL~genic in invikio transformation in a mammalian cell transformation assay. Bobrariationss WD - Nor Detarnired WA - Not Applicarle Asbreviations: N/D - No Determimed N/A - Not Applicable 22777722AA..00000055 I3MM_MMNNO055441199446644 Ho C1084FORA (D0 Bean Poroshesicat Surfactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 6, 1997 PAGE: 6 ot 6 Cw me Te 8. HEALTH HAZARD DATA eed (continued) RammoouEVcELrOMIAIvTAeL ToiTNS: REPRODUCTIVE/DEVELOPMENTAL TOXINS: Ammonium perfluoroalkyl carboxylate was not teratogenic in -abbits by Cea MEdhisteatiaoidn vis nok teEeRegenis to favsbYShige8 oral administration and was not teratogenic to rats by gavage and inhalation ex~osu-es. OTHER HE~_LTH HAZARD INFORMATION: Health hazart information is baset on data for ammonium per~lucroalkyl carboxylate solids. SECTION C~ANGE DATES HEALTH HAZD. DATA SECTION CHANGED SINCE AUGUST 22, 1996ISSUE Robeeriationss WD - Nox betesnired WA - tot Applicatie Abreviations: N/D No_ Determined N/A Hot Applicable 'he in ormaticn in this Material Safety ~ata Sheet (HS~S) is believed to be correct as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED ~O, ANY IMPLIED WARRANTY OF MERCIIANTABILI~Y OR FITNESS FOR A ~ARTICULAR PURPOSE OR COURSE O? PERFORMANCE OR USAGE OF TRADE. Nser is responsible for determining whether he 3M prodllct is fit for a particu ar purpose and suitable for user's method of use or ap~licat on. Given Lhe vaieLy o acLois LhaL can ~fec~ Lhe use and application of a 3M pioducL, some o- which are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit EN Patiouiarporporeand Seitabke Sor srestsmethed ofwtof spPhLCHIon: for a particl~lar pl~rpose and suitable for ~se~'s method of l~se or application. 20 provides infomation 1 shone orm ux 4swivicn to bts customs, Our 3M p~ovdes inoimaLion in elecLionic oiln as a seivic~ Lo iLs cusLomeis. Due to the remote possibility that electronic transfer may have resul_ed in errors, omissions or alterations in this information, 3M makes no representations as to its completeress or accuracy. Tn addition, in-ormation obtained f~om a database may not be as current as the information in _he MSDS available directly frcm 3M. 22777722AA..00000066 33MIM_MMNNO0S5441199446655 MATERIAL SAFETY DATA SHEET Sopyright, 1997, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FC-1OO7 FLUORAD(TM) Brand Fluorochemical Su--actant ID NUMBER/U.P.C.: ZF-0002-0603-5 - ISSUED: FEBRUARY 6, 1997 SUPERSEDES: AUGUST 22, 1996 DOCUMENT: 06 5425 1 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 773?-18-5 75.0 AivlHONiUH PERFLUROOCI'ANOATE .......... 3825-26- 24.0 AMMONIUM PERFLUROHEXANOATE .......... 2161o-47-4 0.1 1.0 AMMONIUM PERFLUROHEPTANOATE ......... 6130-43-4 0 A -- AMMONIUM PERFLUROPENTANOATE ......... 68259-11-0 0 2. PHYSICA~ DATA BOILING POINT: ............... 100 C VAPOR VAPOR . PRESSURe: DENSITY: .............. .............. CRA 18 K~nHg calc @ C.62 Air calc @ 20C 1 20C EVAPORATION RATE: ............ < 1.0 811tyl Acetate I SOLUBILITY IN WATER: ........ complete ne SP. GRAVITY: ................. 1.13 Water i PERCENT VOLATILE: ........... 75 % by wt pH: ......................... 4.0-7.0 VISCOSITY: .................. < 10 CPS MELTING POINT ................ N/A APPEAR~NCE AND ODOR: Clear, colorless to pa e liquid, slight ammonia odor 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: ................. > i00 C Se_a- ash FLAMMABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam SPECIAL FIRE FIGHTING PROCEDLrRES: Wea~ full protective clothing, incllding helmet, self-contained, positive pressure or pressure demand b-eathing a~paratus, bunker and p~nLs, bands a-ound aims, waisL and egs, f~ce mask, and coat Abreviations: N/D No_ Determined N/A Not Applicable 22777722BB..00000011 Exhibit 2772B State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055442211999955 ass 7 EY fg meses sian MSDS: FC-I007 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 6, 1997 PAGE: 2 ot b 3. FIRE AND EXPLOSION HAZARD DATA (continued) protective covering for expcsed areas o- the head. UNUSU/~L FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo- products of com~us_ion. 4. REACTIVITY DATA STABILITY: Stable INN NCoOoxMt PA AATppIppBllIiiLccIaaTbcYliee- PMAATTEIRRIIIA~LLSS 0TO AA0VO1I0D:: HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides ot Nitrogen, Hyd-ogen Fluoride, ~nmonia. 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: ai Sraa in ae Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled ma_er al. Clean up residue with water. Place in an approved metal container. Seal the container. RECOMMENDED DISPOSAL: ncinerate in an industrial or commercia facility in the p~esence cf a coll@~ustible material. Combustion products will include HF. ENVIRONHENTAL DATA: Chemical Oxygen Demand (COD): 0.000175 g/g; Theoretical IDxygen Demanc (''hOD): 9.08 g/g; 5-~ay Biochemical Oxygen Demand (BUD5): Nil; 20-Day Biochem cal Oxygen Demand (BUD20): Nil; 96-Mr LC50, ee EL on Fathead minnov~ (Pimephales promelas): >1000 mg/L; 96 [Ir LC50, Bluegill sunfish (Lepomis macrochirus): 996 mg/L; d8-Hr EC50 TE a in, Inobility), Water flea (Daphnia magna): >100@ mg/L; 14-Day EC50 icell dry wei@ht), Green Algae (Selenastrum capricornutum): 130 mg/L; ISTE, CAR Sr 14-Day EC50 (sell count) Green Algae (Selenastrum capricornutum): 75 mg/L REGULATORY Volatile VOC Less INFORMATION: Organic Compounds: H20 & Exemp~ SolvenSs: N/A. Since regulations before disposal. EPA Hazardous). vary, consult applicab e N.S. EPA Hazardolls Waste regulations or Nllmber None authorities (Not N.S. ~he components of ths procuct are in compliance with the chemical registration requirements of: TSCA, EINECS, CDSL, AICS, MITI. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSURE : No No P.EACTIVITY : No ACUTE : CHRONIC : Yes Yes Asbreviations: N/D - No Determimed N/A - Not Applicable 22777722BB..00000022 33MM_MMNN0055442211999966 ES -- MSDS: FC-I007 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 6, 1997 PAGE: 3 ot b mmm -- SUGGESTED FIRST AID THaT ee fe oro en EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a Dnysican. Wash ccntaminated clothing betore reuse and dispose ot son_amnatec shoes. IN~LALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWA!~LOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION ome EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac . Wear appropriate gloves when handling ths material. A pair o gloves made from the following material(sl are recoK~rlended: ~utyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace of either o- the following ma erals: polyethylene/polyvinvlidene chloride (Saranex) Coverall made of Tyvekir). Hear rubbe~ boots when cleaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: EE a Se ST Avoid bieaLhing o vapois, misLs oi sp~ay. Avoid bieaLhing of airborne material. Select cne of the fo lowing NIOSII a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA reglllations: full-face high-efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTA~ INGESTION: Do not eat, drinn or smoke when using a~eas thoroughly with soap and water. before eating. ths procuct. Wash exposed Wash h~ds afte~ handling ~d RECOMHENDED STORAGE: Store at temperatures above 32 degrees F (0 degrees C). Keep Abreviations: N/D No_ Determined N/A Not Applicable 22777722BB..00000033 33MM_MMNN0055442211999977 Ho 1007FODR0BeAan Poroshesicat Sustacant MSDS: FC-I007 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 6, 1997 PAGE: 4 ot b Cr7. ePRmEaCAeUaTImOoNwARRYTIoNmFORRTMAITIoOnN nei (continued) container closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Not applicable. OTHER PRECAUTIONARY INFOP!4ATION: HMIS KAZARD RATINGS: HEALTH: 2 FL~dMAB LITY: O REACTIVITY: 0 PERSONAL PROTECTION: X (See p-ecautions, section 7.1 INGREDIENTS EXPOSURE LIMITS V2~LUE UNIT TYPE AUTH SKIN* WATER ................................ AHMONIUM PERFLUOROOC~ANOATE .......... A~MONIUM PERFLUOROHEXANOATE .......... ~IMONIUM PERFLUOROHEPTANOATE ......... A~IMONIUM PERFLUOROPENTANOATE ......... NONE 0.01 0.1 0.1 0.1 NONE mg/m3 mg/m3 mg/m3 mg/m3 NONE NONE TWA ACGIH Y TWA 3M Y TWA 3M Y TWA 3M Y me Sonts beter 16the ovecaL] pdote by Lot curamects. route * SKIN NOTATION: ~isted subsSances indicated wi~h "Y" unde~ SKIN ieei 5o the pctential contrbution to the ove~a 1 exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ wth the substance. Vehicles can alter skn abscrption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Industrial Hygine Assoc. Workplace Environmental Exposure 3M: 3M Metical Department Gl~ideline - NONE: None Established Level Guideline 8. HEALTH HAZARD DATA re Tabarias a shy soe ay ea amaasne EYE CONTACT: No toxicity data for can be irritating to the the solution. Ammonum perfluoroalkanoates eye and may cal~se eye injl~ry from airborne exposure. SKIN CONTACT: May be absorbed th-ough the skin and persist in the body fo~ an extenced time. No LoxiciLy daLa foi Lhe soluLion. Some ammoniuil pei1uo~oalkanooLes are slightly toxic when abscrbed through the skin. IN~LALATION: May be absorbed by inhalaticn and persist in the body for an extenced Lime. No toxicity data for the solution. Some anmonium perfluoroalkanoates can be considered moderately toxic by inhalation on a single Robeeriationss WD = ox Detesnired WA = Wot Applicatle Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722BB..00000044 33MM_MMNN0055442211999988 MSDS: FG-1007 FLUORAD(TM) Brand Pluorochemical Surfactant MSDS: FC-I007 FLOORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 6, 1997 PAGE: b at b 8. Comm HEALTH mem HAZARD oN DATA Gesmes (continued) Singha Saretposuce, Soove secommanted Juideliras, my siser exposure; a median lethal ccncentration for a 4-hour ex~osu-e in the albino rat is 980 mi ligrams per cubic meter. Single overexposure, above recoK~nended guidelines, may sause: Teettation (upper respiratory): sians/ewmptoes can Include Irritation (upper respiratory): siqnsisymptoms can include screness of _he nose and throat, coughing and sneezing. IF SWALLOWED: ngestion is not a i keiy rcute at exposure to this praduc_. Ho tortcity data for the solution. A mixture of ammoniun No toxicity data for the solution. A mixture of ammonium perfitcroahanoates wae heserately toxic. in albine rate fron a single perflucroal]<anoates was mocerately toxic in albino rats from a single SEi3 ipasurer acute oral E060 (<b) 18 S40 ma. Far ar of bot oral exposure; acute oral LD50 (rat) is 540 mg. per kg. of body weight. CAI{CER: WARING: Contatne a chemical which can cause cancer, (3823-261) WARNING: Contains a chemical which can cause cancer. (382o-26-1 1953 and 1993 studies conducted Joins by WM and Dupont) 11983 and 1993 studies concucted jain_ly by 3H and DuPant). Naixture of asmeniun pecfivorsoctanoate, sracrive MUTAGENICITY: A mixture of ammonium perfluorooctanoate, ammonium perflucroheptanoa_e, ammonium perfluoropentanoate and ammonium perflucrohexanoate was not mutagenic in nvitro Ftagenicity assays: ihe mixture did not cause cell transformation in mutagenicity assays. The mixture did not cause cell transfo-mation Cn mien analy a maK~rlalian cell _-ansformation assay. REIBVE /O ORVRO LOBITTAL TONS: REPRODUCTIVE/DEVELOPMENT~_L TOXINS: A mixtllre of ammonium perflllorooctanoate, ammonillm pertiicioheptancazes SRenAUrperlsoropantanonte and ammonium perflucroheptanoa_e, ammonium perfluoropentanoate and ammonium BEA Tas ne Seetiopec raetss . perflucrohexanoate was not teratogenic in rabbits by oral administration and was not teratogenic to rats sy garage Thiele! inhalation exposures. and SECTION CHANGE DATES HEALTH HAZD. DATA SECTION CHANGED SINCE AUGUST 22, 1996ISSUE Rbreviationsy WO + Wor Brtemived WAT Wet melon ABbreviations: N/D - No Determined N/A - Not Applicable Te Trormatien Tn This Faveriol Gefery Dues Greet TO] eRe ob The in-ormaticn in this Material Safety Data Sheet (HSDS) is believed to be correct as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLNDING, BK~ NOT LIMITED ~O, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS Goer 15 Cospunsibie Gor duteiniuiry wihee hw 9% product 1 Gib Gor 4 Use~ is PACLLCULAY pigose and suitable fof Leerts method of Loe of application. Given particu FOR A PARTICULAR PURPOSE OR lesponsible o~ deteimi~ing ar purpose and suitable for COURSE O~ PERFORMANCE OR USAGE OF TRADE. whethe~ _he 3M pioduct is fit oi a user's method of use or ap~licaton. Given the varety of factors that can affect the use and application of a 3M product, some o- which are uniq]e]y within the user's knowledge and control, ~t is essential that the user eva uate the 3M product to determine whether it is fit oL a paiLic~lai puipose and suiLable oi ~se-'s meLhod of use oL applic~Lion. Satsaions or alterations in this informations maker no fepresentations as to 3M provdes information in electronic form as a service to its customers. Due to the remote ~ossibility that electronic transfer m~y have resll ed in errors, omissions or alterations in this information, 3M makes no representations as to A rte I EI Ee TR its completeness oi ascuracy. In addition, in-oimation obtained ~om a database may not be as current as the information in _he MSDS available directly frcm 3M. 22777722BB..00000055 33MM_MMNN0055442211999999 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FC-1O-3 FLUORAD ID NUMBER/U.P.C.: WEE (TM) Fluorochemical Surfac_ant ZF-0002-0501-1 - ZF-0002-0597-7 - ISSUED: FEBRUARY 7, 1997 SUPERSEDES: AUGUST 20, 1396 DOCUMENT: 07-1075-6 ZF-0002-0573-0 I. INGREDIENT C.A.S. NO. PERCENT NA''ER ................................ AMMONIUM PERFLUOROOC?ANOATE .......... AMMONIUM PERFLUROHEKANOATE .......... AMMONIUM PERFLUROHEPTANOATE ......... AMMONINM PERFLNOROPENTANOATE ......... 7732-18-5 3825-26-2161o-47-4 6130-43-d 68253-11-0 0.1 0 0 2. PHYSICAL DATA 70.0 29.0 1.0 BOILING POINT: ............... i00 C EY VAPOR PRESSURE: .............. VAPOR DENSITY: .............. 18 ii~nHg calc @ 0.62 Air 20C 1 calc @ 20C EVAPORATION RATE: ............ < 1.0 Butyl Acetate 1 SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. =PERCENT VOLATILE: ........... Uh 1.16 Water i calc @ 20C 70 % by wt pH: ......................... 4.0-7.0 VISCOSITY: .................. < i0 CPS MELTING POINT ................ N/A APPEAP-ANCE AND ODOR: Clear, colorless to pa e liquid, slight ammonia odor 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: ................. 6etaflasn None (Setaflash CC) FLAMIW3%BLE LIMITS - LEL: ..... N/A FLA}4}4ABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self contained, Abreviations: N/D No_ Determined N/A Not Applicable 22777722CC..00000011 Exhibit 2772C State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055442233223322 FLMSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant FEBRUARY 7, 1997 PAGE: 2 ot 6 3. FIRE AND EXPLOSION HAZARD DATA (continued) positive pressure or pressure demand b-eathing avparatus, bunker and pants, bands a-ound arms, waist and egs, face mask, and protective covering for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo- products of comus_ion. coat 4. REACTIVITY DATA we STABILITY: Stable INCOMPATIBILITY - MATERI~_LS TO AVOID: Not Applicable HAZARDOUS POLYMERIZATION: Will Not Occur HAZ"CAaRrbDoOrU.SMDonEoCxOiMdPeOSIaTnIdONCarPbRoODnUCDTiSo:xide, Hydrogen Fluoride, Carbon Monoxide and Carbon Dioxide, Hydrogen Fluoride, ~oxic vapors, gases or particulates may be procucts of decompcsition. AAmmmmoonniiaa tnerma 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled ma_eral. Clean lip residlle with water. Place in an approved metal container. Seal the container. RECOHHENDED DISPOSA!~: ncinerate in an industrial or commercia facility in the p~esence cf a coll@~llstible material. Comhllstion prodl~cts will incll~de HF. ENVIRONMENT~L DATA: TIBIEI yrs cots on, os ~otal Organic Carbon (TOC): 64 g/kg; Chemical Oxygen Demand ICOD): 0.2 g/kg; 5-Day Biochemical Oxygen Demand (BUDS): Nil; 20-Day Sram e Se a ee Biochemical Oxygen Demand (BOB20): Nil; Theoretical Oxygen Demand Ee pear Toei i'l'hO~): 96 g/kg; 96-Hr LCSC, Fathead minnow (?imephales promelas): >1000 mg/L; 96-H~ LC50, Bluegill sunfish (Lepcmis macrochirus): 970 mgiL; 48 Hr EC50 (Mobility), Water flea (Daphnia magna): >1000 mg/L; ~4-Day EC50 (cell dry weigkt), Green algae ISelenastrl~m capricornl~tllm): 120 m@!L; ~4-Day EC50 (cell collnt), Green algae (Selenastrum capricornutum): ~0 mg/L REGULATORY Volatile VOC Less INFORMATION: Organic Compounds: N/A. H20 & Exempt Solvents: N/A. Since iegulaLio~s before disposal. EPA Hazardous). vaiy, consulL applicab e U.S. EPA IIazardous Waste iegLlaLions o Number None auLhoiiLi~s (Not U.S. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSURE : No No P.EACTIVITY : No ACUTE : CHRONIC : Yes Yes Asbreviations: N/D - No Determimed N/A - Not Applicable 22777722CC..00000022 33MM_MMNN0055442233223333 re ms msn MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant FEBRUARY 7, 1997 PAGE: 3 ot 6 mmm -- SUGGESTED FIRST AID THaT ee fe oro en EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a Dnysican. Wash ccntaminated clothing betore reuse and dispose ot son_amnatec shoes. IN~LALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWA!~LOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION ome EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac . Wear appropriate gloves when handling ths EETor TbSnSE AR material. A pair o gloves made from the following material(sl are recoK~rlended: ~utyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace of either o- the following ma erals: polyethylene/polyvinvlidene chloride (Saranex) Coverall made of Tyvekir). Hear rubbe~ boots when cleaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: EE a Se ST Avoid bieaLhing o vapois, misLs oi sp~ay. Avoid bieaLhing of airborne material. Select cne of the fo lowing NIOSII a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA reglllations: full-face high-efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTA~ INGESTION: Do not eat, drinn or smoke when using a~eas thoroughly with soap and water. before eating. ths procuct. Wash exposed Wash h~ds afte~ handling ~d RECOMHENDED STORAGE: Do not store containers on their sides. Store at room temperature. Abreviations: N/D No_ Determined N/A Not Applicable 22777722CC..00000033 33MM_MMNN0055442233223344 FEMSDS: FC-I013 FLOORAD (TM) FEBRUARY 7, 1997 PAGE: 4 ---- Fluorochemical Surfactant ot 6 7. PRECAUTIONARY INFOR/~ATION (continued) Keep ccntainer closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Not applicable. EXPOSURE LIMITS EE INGREDIENTS WATER ................................ AHMONIUM PERFLUOROOC~ANOATE .......... VALUE NONE 0.01 AHMONIUM PERFLUOROHEXANOATE .......... 0.1 AHMONIUM PERFLUOROHEPTANOATE ......... 0.1 AHMONIUH PERFLUOROPENTANOATE ......... O.1 UNIT NONE mg/m3 mg/m3 mg/m3 mg/m3 TYPE AUTH SKIN* NONE NONE TWA ACGIH Y TWA 3M Y TWA 3M Y TWA 3M Y teean Sentsoithoe SVuetati1sxiPoboestnby toe siamOLE sovte * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contrbution to the ove~a 1 exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ wth the substance. Vehicles can alter skn abscrption. SOUIqCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists Ge 3M: 3M Medical Department Guideline - NONE: None Established 8. HEALTH HAZARD DATA EYE CONTACT: Moderate Eye Irri_aton: signs/symptoms can include redness, swelling, STII Ot STL pain, tearing, and hazy vision. No toxicity data for can be irritating to the the solution. Ammon um perfluoroalkanoates eye and may cause eye injury from airborne exposure. SS Tein dzcication after prolonged or epested contact) SKIN CONTACT: Hild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swel ing, and itching. May be absorbed th~ol~gh the skin and persist in the body fo~ an extenced time. No toxicity data for the solution. Some ammonium perfluoroalkanoates are slightly toxic when abscrbed through the skin. INHALATION: May be absoibed by inhalaLicn and pe~sis~ in Lh~ body o~ an exLenc~d time. No toxicity .data for the solution. Some anmonilm perfl/loroalkanoates Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722CC..00000044 33MM_MMNN0055442233223355 soos:routesraces (hy Pisorocheiont sucesctant MSDS: FC-I013 FLOORAD (TM) Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE: bot 6 CemmemwewnoN 8. HEALTH HAZARD DATA eeemmes (continued) SiTnigmlse TCaveazieexposucmei, hSioorteenaspecoormmcaanttesdmgeutiadelines, myoSaouser i can be consitered moderately toxic by inhalation on a single exposure; a median lethal ccncentration for a 4-hour exDosu-e in tkc albino rat is 9@0 mi ligrsms per cubic meter. Single overexposure, above recoK~nended guidelines, may sause: Irritation (upper respiratory): signs/symptoms can include tonaes ox capentes ovesesgoruce, stove seconded idetines, m3 screness of _he nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended @uideiines, may LaiverCeBnesfuarcnteecrs sofignuap/peeyrmpsrhoanssenncan include yellow ekin(jaundice) caus@: Liver Effects: and tenderness signs/symptoms can of upper abdomen. include yellow skin(jaundice) IF SW~LOWED: ngestion is not a lkely rcute of exposure to this produc_. No toxicity data for the solution. A mixture of ammonium per~lucroalkanoates was mocerately toxic in albino rats ~rom a single oral exposure; acute oral LD50 (rat) is 540 mg. per kg. of body weight. i063 ara Tonsstoates coneucted 35b1y nanCdDuLtonyt) CANCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1 11983 and 1993 studies concucted join_ly by 3H and DuPont). SerehicrshaoohmtaumppoctELassinopeeniaasosvteean;d axniun H~TAGENICITY: A mixtllre of ammonillm perflllorooctanoate, ammonillm perflucroheptanoa_e, ammonium perfluoropentanoate and ammonium perflucrohexanoate was not mutagenic in mutagenicity assays. The mixture did not T all EoinE atomationassay, Co" SoH ranatommtion tn a maK~rlalian cell _-ansformation assay. nvitro cause cell transformation RermoouCTIvE/DRvELOMITAL ToNNS: REPRODUCTIVE/DEVELOPMENTAL TOXINS: A mixture of ammonium perfluorooctanoate, ammonium El aisiatestion os vasmot Chestaron1tsa toe oy quvage se perflucroheptanoa_e, ammonium perfluoropentanoate perflucrohexanoate was not teratogenic in rabbits by oral administration and was not teratogenic to and ammonium rats By gavage and inhalation exposures. SECTION C~AIqGE DATES HEA~TH HAZD. DATA SECTION CHANGED SINCE AUCUST 20, 1996ISSUE Asbreviations: N/D - No Determired N/A - Not Applicable 22777722CC..00000055 33MM_MMNN0055442233223366 soos:routesraces (hy Pisorocheiont sucesctant MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant FEBRUARY 7, 1997 PAGE: 6 ot 6 SECTION C~AIqGE DATES Robceriations: WD = Now beternired WA = ot Applicable Abreviations: N/~ - No_ Determined N/A - Not Applicable The in-ormaticn in this Material Safety Data Sheet (HSDS) is believed to be correct as of the date isslled. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, S~'I NOT LIMITED "0, ANY IMPLIE~ WARRANTY OF MERCHANTASiLi"Y OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE 07 PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether _he 3M product is fit for a particu ar purpose and suitable for user's method of use or apDlicaton. Given the varety of factors that can affect the use and application of a 3M prodllct, pudgrphelagdnrrgbeelhipfotrig ned vad some o whick are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit ON PAECiouiarpurposeand SuLtabRe TOF seectsmethodofute ofapplicetions for a particular purpose and suitable for user's method of use or application. provides information in electronic form se 3 service to ita customess. Gun 3M provdes information in electronic form as a service to its customers. Dl~e to the remote ~ossibility that electronic transfer may have resul_ed in errors, ai Tonmor teraions"in this Seosmatiosonress ne sebvecoensnstetao omissions oi alLeiaLions in Lhis inoimaLion, 3M makes no iepiesen~a~ions as Lo its completeness or accuracy. In addition, in-ormation obtained f~om a database A more SiSuceesentht tnfrastioTn% the HADS. svaiiselestrectly Fees She may not be as current as the information in _he MSDS available directly frcm 3M. 22777722CC..00000066 33MM_MMNN0055442233223377 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FX-1OO3 FLUORAD(TM) Brand Fluorochemical Su--actant ID NUMBER/U.P.C.: ZF-0092-0122-6 - ISSUED: FEBRUARY 7, 1997 SUPERSEDES: AUGUST 22, 1996 DOCUMENT: 10 4270 4 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 773?-18-5 AivlMONiUM PERFLUROOCI'ANOATE .......... 3825-26- 43.0 - INERT PERFLUORO COMPOUNDS ............ Unknown < TRIDECAFLUOROHEPTANOIC ACID, ,~@MON UM SALT ...................... 6139-43-d 0.5 - AMMONINM NONAFLNOROPENTANOA~E ........ 68259-11-0 O.~ - 50.0 45.0 3.0 1.0 1.0 NOTE: lneiL Pei1uoio Compounds or use in the U.S. ~re noL on TSCA. NoL oi colnlns~cial sale 2. PHYSICAL DATA BOILING POINT: ............... ca. i00 C fae. azo VAPOR PRESSUP~E: .............. ~8 mmNg Calc. @ 20 C VAPOR DENSITY: .............. C.62 Air 1 Calc. @ 20 C EVAPORATION RATE: ............ < 1.0 Butyl Acetate 1 SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. ca. 1.3 Wate- 1 I PERCENT VOLATILE: ........... pH: ......................... hs(Bulk) 50 % 8.0-9.5 VIBCORITE: verre 0 VISCOSITY: .................. (0.5% N/D Aqueous) MELTING POINT ................ N/D APPEARANCE AND ODOR: Clear, colorless to pa e yellcw liquid, slight ammonia odor. S. FIRE AI4D EXPLOSION HAZARD DATA FLASH POINT: ................. Non-Vlammable FLAMMABLE LIMITS - LEL: ..... FLAMMABLE LIMITS - UEL: ..... Setaflasn N/A N/A Abreviations: N/D No_ Determined N/A Not Applicable 22777722DD..00000011 Exhibit 2772D State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055443344558888 M08: Fi-1003 FLA) Brand Pluosochesioal Sureactant MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE: 2 ot b EE 3. FIRE AND EXPLOSION HAZARD DATA (continued) AUTOIGNITION TEMPERATURE: ... N/D EXTINGUISEING MEDIA: Water, Carbon dioxide, Dry chemical, ?oam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothinq, includinq helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, face mask, and protective covering for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo- products of camus_ion. coat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERI~_LS TO AVOID: Not applicable. Eareor Monoeiae. ana Careon Dioxide, Ocides of Nitrogen, Arszegen HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hyd-ogen Fluoride, ~nmonia. 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe precautions from other sections. Cover with absorbent material. Collec_ spilled material. Place in an approved metal container. RECO~HENDED DISPOS~I~: Discharge spent solutions and small quantities (less than 5 gal. (19 LI) to a wastewate~ treatment system. Reduce cischarge ra_e f foaming occurs. Incnerate in a permitted hazardous waste ncinerator in the presence of a cambllstble material. Combllstion products will include HF. ENVIRO~MENT~ DATA: Data are for product solics: Chemical Oxygen Demand (SOD): N1 mgiKg); 20-Day Biochemical Oxygen Demand (BAD2@): Nil; 98-H~. LC5@, naloimeafna6s3t2eumnaysapeLlosoonmymitSohn)e.7(5onmk/sidseyS0eeLvignn.irByESG0o,vaMniAcrgoetes System, Bluegill Sunfish (Lepomis macrochirus): 569 mg/L; 96-Hr. LC50, FaLhe~d Hinno~(Pimephales piomelas): 766 mgiL; 48-Hi ES50, Daphani~ magna: 632 mg/L; 14 Day EC5O (cell dry weight), Green Algae ISelenastrum capricornutum) 73 mg/L; 30-Min. ECS0, Microtox System, Photobacteril~m phosphorellm: >1,000 mg!L; OECD EC50: >I,0S0 mg/L. vosteen 1SuneEe wo. REGU~TORY Volatile VOC Less INFO~TION: Organic Compounds: N/D. H20 & Exempt Solvents: N/D. ~his product is in compliance with the chemical registration iequir~llenLs o EINECS. Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722DD..00000022 33MM_MMNN0055443344558899 Ho 1000FORA (D0 Bean Poroshesiat Sustacant MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE: 3 ot b mie Toman 5. ENVIRONMENTAL INFORMATION enemies (continued) EPCRA HAZARD CLASS: FIRE ~AZARD: PRESSURE: No No Cemmmerae 6. SUGGESTED FIRST AID RIBACTIVITY: No ACUTE: CERONIC: Yes Yes EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Flush skin with la-ge amounts of water, medical attention. f irritation persists, get Clonesspptece sonnei3 prysiean. IN}IALATION: t signs/s~nptoms occur, remove person to tresh air. It signs/symptoms continue, call a physician. TENIores 1concious, do venting mmasiatly as dicted IF SWA!~LOWED: f swallowed: If conscious, induce vomitng immediately as directec by mecical personnel. 7. PRECAUTIONARY INFOP/4ATION EYE PROTECTION: Avoid eye contact. ~he following Should be combination, as appropriate, to prevent eye goggles. worn alone or in contact: Wear vented etisL Pe32 Doves vase fron the.Followingmateriais} are SKIN PROTECTION: Avoid skin contac_. material. A pair o- Wear appropriate gloves made from gloves when handling ths the following material(sl are recoK~rlended: ~utyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: apron, head covering, coveralls. Pro_ective garments (othe~ than gloves) should be made of either of the following materials: polyethylene/polyvinvlidene chloride (Saranex). VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Use in a wel ventilated area. Provide sufficient ventilation to maintain enissicns below recomnendec exposllre limts. If exhal~st ventlation s not adequate, use appropriate respiratory prctection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or sp~ay. Avoid breathing of airborne material. Select one of the fo lowing NTOSH a~proved respirators based on airborne concentrat on of contaminants and in accoicance wiLh OSHA iegulaLioils: full-face high-efficiency filler respirator, full face supplied air respirator. PREVENTION OF ACCIDENT~.L INGESTION: Do not eat, drin or smoke when using th s procuct. Wash exposed Ambreviations: N/D - No_ Determined N/A - Not Applicable 22777722DD..00000033 33MM_MMNN0055443344559900 soos: ree100sraces tu)mean Porochemicnt suctactant MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE: 4 at b Cr7. ePRmEaCAeUaTImOoNwARRYTIoNmFORRTMAITIoOnN nei (continued) areas thoroughly with before eating. soap and water. Wash hands after nandlng and RECOMMENDED STORAGE: Store at temperatu-es above 32 deqrees F (O deqrees C). container closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Not applicable. Keep OTHER PRECAUTIONARY INFORI~TION: HMIS KAZARD RATINGS: HEALTH: 2 FL~dMAB LITY: O REACTIVITY: 0 PERSONAL PROTECTION: X (See p-ecautions, section 7.1 INGREDIENTS EXPOSURE LIMITS V2~LUE UNIT TYPE AUTH SKIN* WATER ................................ AHMONIUM PERFLUOROOC~ANOATE .......... NERT PERFLUORO COMPOUNDS ............ ~RIDECAFLUOROHEPTANO C ACID, A~MONIUM SALT ...................... AHMONIUM NONAFLUOROPENTANOA'IE ........ NONE 0.01 NONE NONE mg/m3 NONE 0.1 @.1 mg/m3 mg/m3 NONE NONE TWA ACGIH Y NONE NONE TWA 3M Y TWA 3M Y * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contrbution to the ove~a 1 exposure by the cutaneous route incll~ding ml~co~s membrane and eye, either by airborne or, more particl~larly, by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOUIqCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American 3H: 3M Melisal Indl~strial Oepartment Hygine Assoc. Guideline Workplace Environmental Exposl~re - NONE: None Established Level Gl~ideline 8. HEALTH HAZARD DATA EYE CONTACT: Severe Eye Irrita ion: signs/symptoms can incl~de redness, swelling, pain, tearing, cloudy appearance of the cornea, impaired vision anc possible peilnanen_ly impaired vision. WS Shin Teeitation fatter protons or repeited contact) SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swel ing, and itching. May be absorbed through the skin and persist in the body fo~ an extenced time. IN~L~LATION: llness iequiiing medical aLLenLionlnay lesulL iom a single exposuie Aobcortationss WD = No. Detwcaird WA = Nol Applicable A~b~evia~io~ls: N/D - No De~eimi~ ed N/A - No~ Applicable 22777722DD..00000044 33MM_MMNN0055443344559911 M08: Fi-1003 FLA) Brand Pluosochesioal Sureactant MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE: b at b Cw me Te 8. HEALTH HAZARD DATA eed (continued) ay be ahsceted by nhaiaticn and peat in the body for an extences by inhalation to moderate cuantities of this material. May be absorbed by inhalaticn and persist in the body for an extenced time. Single overexposure, above recoKm-lended guidelines, may cause: Irritation (upper respiratory): signs/symptoms can include Prolonged or xepested overexposuces above recomended uideines, may screness at _he nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended ~uidelines, may Liver Ettocts: signs/eywptons can include yeLiow sKin()aundice) cause: Liver Et~ects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. ertion ie not a Likely seute of siposure to this produc: IF SW~_LLOWED: ngestion is not a lkely rcute of exposure to this produc_. llness may resul_ -ram a single swallow ng of a moderate quantity cf this material. CANCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1) 1985 ana 1993 studies concucted Joincly By SH and Buber) 11983 and 1993 studies concucted jain_ly by 3H and DuPant). SamcoucriveoRvELomaTN Tors: REPRODUCTIVE/DEVELOPMENT~_L TOXINS: Not teratogenic in rabbits by oral adminstraticn. Not teratogenic to rats by gavage or inhalation exposures. A Feier Tori oie Surmary Sheet Le available. OTHER HEALTH HAZARD INFORIV~TION: A Procuct Toxicity Sunmary Sheet is avai able. SECTION CHANGE DATES HEALTH HAZD. DATA SECTION CHANGED SINCE AUGUST 22, 1996ISSUE Reber WD er DeteRRied WA Wr RppITeRTe A~breviations: N/D - No Determined N/A - Not Applicable Te Tnferatie Tn THES Fterial Tefety Tots Sheet (D0) Te Beller tobe The in-ormaticn in this Material Safety Data Sheet (HSDS) is believed to be correct as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLNDING, BK~ NOT LIMITED ~O, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE O7 PERFORMANCE OR USAGE OF TRADE. ive is tespuimiote for uleaninivg WCE I SH produ 13 LIC for 4 Use~ is lesponsible o~ deteimi~ing whethe~ _he 3M pioduct is fit foi a BARC: puisose and suitible fof users method of se oF application. Given particu ar purpose and suitable for user's method of use or ap~licaton. Given the varety of factors that can affect the use and application of a 3M product, some o- which are uniq]e]y within the user's knowledge and control, ~t is essential that the user eva uate the 3M product to determine whether it is fit oL a paiLic~lai puipose and suiLable oi ~se-'s meLhod of use oL applic~Lion. 3M provdes information in electronic form as a service to its customers. Due to the remote ~ossibility that electronic transfer m~y have resll ed in errors, aay nox be ae Suceenat5 he Sndoemation5 he WEDS available sifecely fees Sh. omissions or alterations in this information, 3M makes no representations as to its completeness oi accuracy. In addition, in-oimation obtained ~om a database may not be as current as the information in _he MSDS available directly frcm 3M. 22777722DD..00000055 33MM_MMNN0055443344559922 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: women TI, FX-1OO5 FLUORAD(TM) Brand Fluorochemical ID NUMBER/U.P.C.: ZF-0002-05d4-1 - ZF-0002-0689-4 - ZF-OOO2-Oi8/-@ - FELL Su--actant ZF-0002-066@-8 - - ZF-0002-$726-4 - - 98-0211-b68/-6 @@-bl13b-10218-3 ISSUED: FEBRUARY 7, SUPERSEDES: OCTOBER DOCUMENT: 1@-4251-2 19@7 8, 1996 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 7732-18-5 AMMONIUM PERFLUOROOC?ANOATE .......... 3825-26-- 26.0 - LOWER PERFLUOROALKYL CARBOXVLATE SAlT ............................... 2161s-47-4 1.@ - LOWER PERFLUOROALKYL CARBOX~LA'I'E SAlT ............................... 6130-43-4 1.O - LOWER PERFLUOROALI~L CARBOXVLATE SAlT ............................... 6825@-11-0 0.1 - 2. PHYSICAL DATA 70.0 29.0 2.0 2.0 1.0 BOILING POINT: ............... ~00 C VAPOR PRESSURE: .............. 18 K~nHg Calc. @ 20 C VAPOR DENSITY: .............. 0.62 Air 1 Calc. @ 20 C EVAPORATION P~tTE: ............ N/A SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. ca. 1.2 Wate~ 1 TIE I PERCENT VOLATILE: ........... pH: ......................... (Bulk) 70 % 9.0-6.0 (2% Aqueous) VISCOSITY: .................. N/D MELTING POINT ................ N/A APPEARANCE AND ODOR: Light yellow liquid. 3. FIRE ~ EXPLOSION HAZARD DATA massson i et FLASH POINT: ................. None (Setaflash CC) FLAI41iABLE LIMITS - LEL: ..... N/A FLAI414ABLE LIMITS - UEL: ..... N/A Abreviations: N/D No_ Determined N/A Not Applicable 22777722EE..00000011 Exhibit 2772E State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055443355550066 M08: Fi-1008 FLA) Brand Pluosochesioal Sureactant MSDS: FX-1005 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 7, 1997 PAGE: 2 ot b EE 3. FIRE AND EXPLOSION HAZARD DATA (continued) AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISEING MEDIA: Water, Carbon dioxide, Dry chemical, ?oam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothinq, includinq helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, face mask, and protective covering for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo- products of comus_ion. coat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERI~_LS TO AVOID: Not applicable. Eareor Monoeiae. ana Careon Dioxide, Ocides of Nitrogen, Arszegen HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hyd-ogen Fluoride, ~nmonia. 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled ma_eral. Clean up residue with water. Place in an approved metal container. Seal the container. RECOHHENDED DISPOS~I~: ncinerate in an industrial or commercia facility in the p~esence cf a coll@~ustible material. Combustion products will include HF. ENVIRONMENTAL DATA: Not determined. REGULATORY Volatile VOC Less INFORMATION: Organic Compollnds: N/D. H20 & Sxempt Solvents: N/~. Eon linear. US)" uEnMaracWaasste haboeomre (Hot br Since regulations before disposal. vary, consult applicab e U.S. EPA Hazardous Waste regulations or Number None authorities (Not U.S. EPA Hazardo~ls). ~he com~onenLs of Lhs piocucL aie in compliance wiLh Lhe chemical registration requirements of: TSCA, EINECS, CDSL, AICS, MITI. EPCRA HAZARD CLASS: FIRE HAZARD: PRESSURE: No No I~EACTIVITY: No ACUTE: CHRONIC: Y~s Yes 22777722EE..00000022 33MM_MMNN0055443355550077 FS MSDS: FX-1005 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 7, 1997 PAGE: 3 ot b er -- pr SUGGESTED FIRST AID TLDity me wo. ve nro ee 0 si EYE CONTACT: nmediately flush eyes with large amounts of water. Get immedate medical attention. SKIN CONTACT: Flush skin with la-ge amounts of water, medical attention. f irritation persists, get IN~L~LATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac_. Wear appropriate gloves when handling ths material. A pair o- gloves made from the following material(sl are recoK~rlended: ~ltyl rllbber. Nse one o- more of the following personal protection tems as necessary to prevent skin con_act: apron, head covering, coveralls. Pro_ective garments (othe~ than HETiethrayngiiioeus tnhiaacises(Sparaomanir? i gloves) should be made of either of the following materials: polyethylene/polyvinylidene chloride (Saranex). VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf- cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or sp~ay. Avoid breathing of airborne material. Select cne of the fo lowing NIOSH approved respirators based on airborne concentraton of contaminants and in accorcance with OSHA regulations: full-face high-efficiency filter lespiraLoi, full-face supplied sit ~espiia~oi. PREVENTION OF ACCIDENT~_L INGESTION: Do not eat, trin or smoke when l~sing areas thoroughly with soap and water. befoie eaLing. ths procllct. Wash exposed Wash hands after nandl ng and RECOMHENDED STORAGE: Sto<e at temperatures above 32 degrees Y (0 deg<ees C). container closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Keep ccntainer tight y closed. Keep Abreviations: N/D No_ Determined N/A Not Applicable 22777722EE..00000033 33MM_MMNN0055443355550088 Ho 1008FARR (D0 Bean Poroshesiat Sustacant MSDS: FX-1005 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 7, 1997 PAGE: 4 ot b km TATOn 7. PRECAUTIONARY INFORMATION Gees (continued) OTHER PRECAUTIONARY INFORIV~tTION: HMIS KAZARD RATINGS: HEALTH: 2 FL~MAB LITY: @ REACTIVITY: 0 PERSONAL PROTECTION: X (See p-ecautions, section /.I INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* WATER ................................ Ne EST AHMONIUM PERFLUOROOC~ANOATE .......... LOWER PERFLUOROALKYL CARBOXYLATE en SALT ............................... LOWER PERFLUOROALKYL CARBOXYLATE SALT ............................... LOWER PERFLUOROALKYL CARBOXYLATE SALT ............................... NONE UE0.01 0.10.1 0.1 0.1 NONE Sh mg/m3 ned mg/m3 mg/m3 mg/m3 NONE NONE RR TWA ACGIH Y TR WY TWA 3M Y TWA 3M Y TWA 3M Y oe Feeerria Sorte bation 16 heovecac] posers by tae cutaneots route * SKIN NOTATION: ~isted substances indicated with "Y" under SKiN refer to the pctential contr bution to the ove-a 1 exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ wth the substance. Vehicles can alter skn abscrption. Tu Ameren Cfararee of Govecnnental Industrial Mpgieniate SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Industrial Hygine Assoc. Workplace Environmental Exposure 3M: 3M Medical Department Guideline - NONE: None Established Level Guideline 8. HEA~TH HAZARD DATA erroLrisaclon slara/mpotocnie nclide rodney sueline, EYE CONTACT: Severe Eye Irrita_ion: signs/symptoms can include redness, swelling, pain, tearing, cloudy appearance of the cornea, impaired vision anc possible permanen ly impaired vision. SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): Hay be dbsockes thous the skin and paceiat i the body fo: an signs/symptoms can include redness, swel ing, and itching. May be absorbed through the skin and persist in the body fo~ an exLe~lc~d Lime. INHALATION: llness reql~iring medical TREAT SL BLL ee by inhalation to moderate attention may cuantities of result from a single this material. exposl~re Seritavion (sane esplatory)s igasreymptons can include soreness rritation (upper ~espiratory): signs/symptoms can include soreness of the nose and throat, coughing and sneezing. Aebreviationss WD - ve: betecaires WA = ot eplicatie Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722EE..00000044 33MM_MMNN0055443355550099 M08: Fi-1008 FLA) Brand Pluosochesioal Sureactant MSDS: FX-1005 FLOORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE: bot b Cemmemwewn oN 8. HEALTH HAZARD DATA eeemmes (continued) May be absorbed by inhalaticn and persist in the body for an extenced Erotorges ox sepeates ovesesgosure, ove fecommendsd Juldelines, may time. Prolonged or repeated overexposure, above recommended @uideiines, may Liver Eefoctes sign/eymptons can include yellow exin(jsundice) cause: Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenterness of upper abdomen. IF SW;~LLOWED: eetion ie not a Likely seute of siposure to this product. ngestion is not a lkely route of exposure to this praduc_. "liners may sonal from a single sualloving of 3 sderate quintity of llness may resul_ -ram a single swallowng of a moderate quantity cf this material. 1985 ana 1993 svubtas contucted $oinily by 4 ond Buber) WARNING: Contain a chemical which can cause cancer. (3823-261) CAI~CER: WARNING: Contains a chemical which can cause cancer. (3820-26-1) 11983 and 1993 studies concucted jain_ly by 3H and DuPant). SECTION C~AIqGE DATES HE2~LTH HAZD. DATA SECTION CHA~GED SINCE OCTOBER 8, 1996ISSUE Robceriationss WD = Now Determined WA = ot Applicable Abreviations: N/~ - No_ Determined N/A - Not Applicable correct as of the The in-ormaticn in correct as of the datethis date issued. Material isslled. 3M MAKES Safety 3H MAKES NOData NO WARRANTIES, EXPRESSED OR Sheet (HSDS) is believed WARRANTIES, EXPRESSED OR INPLIED, to be IMPLIED, INCLUDING, B~'I NOT LIMITED "O, ANY IMPLIE~ WARRANTY OF MERCHANTABiLi"Y OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE O7 PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether _he 3M product is fit for a PartLouiag purpose. ana Sultabie fof upeErs method OF ies of applications Given particu ar purpose and suitable for user's method of use or apDlicaton. Given Eh varioey of factors that can 1EEect the. use and sPPLiCMtion of a M prasvers the varety of factors that can sffect the use and application of a 3M prodllct, oma 5% ulcr ace miasely iShin the user's Rnoviedos and Sontiols Ct br some o- whick are uniquely within the user's knowledge and control, t is SSiuntial that Un Gas waists WeSE prosuct (0 duLsdetie snLheE 14 is Gi essential LhaL Lhe use eva uaLe Lhe 3M pioduc~ Lo deL~imine ~heLhei iL is iL Lory paceiclias purpose sad suitable for eects nachos of wee of spel Lcirion. for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resul_ed in errors, its' Somplaterass of ascucacy. In addition, information cbrained fzom a database omissions ol ~lLeiaLions in Lhis inoimaLion, 3M makes no iepiesenLaLions ~s Lo its completeness or accuracy. In addition, in-ormation obtained f~om a database may not be as current as the information in _he MSDS available directly frcm 3M. 22777722EE..00000055 33MM_MMNN0055443365551100 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FX-1OO6 FLUORAD (TM) Brand Fluorcchemical Surfactant ID NUMBER/U.P.C.: ZF-0002-0827-0 - ISSUED: FEBRUARY 7, 1997 SUPERSEDES: AUGUST 22, 1996 DOCUMENT: 07 3196 8 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 773?-18-5 ndvlHONiUM PERFLUROOCI'ANOATE .......... 3825-26- PERF~UORO COMPOUNDS ++ ............... Unknown AMMONIUM PERFLUROHEKANOATE .......... 2161o-47-4 0.1 - AMMONIUM PERFLUROHEPTANOATE ......... 6130-43-d 0.1 - AMMONINM PERFLNOROPENTANOATE ......... 68259-11-0 O - 70.0 28.0 1.0 1.0 1.0 0.- NOTE: + NOT ON TSCA. NOT FOR COKMERCIAL USE OR SALE IN THE U.S. 2. PHYSICAL DATA BOILING POINT: ............... VAPOR PRESSUP~E: .............. i00 C (Typica I ois 20 18 mmHq calc @ 2OC VAPOR DENSITY: .............. C.62 Air 1 calc @ 20C EVAPORATION RATE: ............ < 1.0 Butyl Acetate 1 SOLUBILITY IN WATER: ........ complete pm aL SP. GRAVITY: ................. 1.2 Water - PERCENT VOLATILE: ........... 70 % by wt pH: ......................... 6.0 8.0 VISCOSITY: .................. N/D MELTING POINT ................ N/A APPEARANCE AND ODOR: Clear, colorless to pa e liquid, sli@ht ammonia odor 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: ................. > 100 C Se_a- FLAH14-ABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... AUTOIGNITION TEMPERATURE: ... EXTINGUISHING MEDIA: N/A N/A Wa~ei, Caibon dioxide, Diy chemical, ~oam ash Abreviations: N/D No_ Determined N/A Not Applicable 22777722FF..00000011 Exhibit 2772F State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055442233779933 0: pone reso (ans Paemhemien Surtctant MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical S~rfactant FEBRUARY 7, 1997 PAGE: 2 ot 6 avewe mss wDBR Geese 3. FIRE AND EXPLOSION HAZARD DATA (continued) SPECIA!~ FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, race mask, and protective coverinq for expcsed areas o- the head. UNUSUA~ FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo~ products of comus_ion. coat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS TO AVOID: None known. verte a Thon Sime, Oude of Kitsogens pioaen HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hydrogen Fluoride, ~nmonia. 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled ma eral. Clean up residue with water. Place in an approved metal container. Seal the container. RECOMMENDED DISPOSAL: ncinerate in an indllstrial or commercia facility in the p~esence cf a coll@,ustible material. Combustion products will include HF. ENVIRONMENT/~L DATA: o3y= rls3/2 S0-0ay AosheBACAL cxpsen Denard (800EH] = MELE Chemical IThOD) Oxygen Demand (COD) 0.0002 0.11 g!g; 20-Day Biochemical g/g; Theoretical Oxygen Oxygen Demand (BOD?0) Demand Nil; Fathead minnow (pimephales promelas) 96-hr LC50 >1000 mg!L; Water flea (Daphnia magnal 48-hr EC50 >1000 mgiL; Bluegill sunfish ILepomis macrosnirus) 96 hr LC50 967 mg/L; Green algae (Selenastrum capriccrnutum) 14-day EC50 (cell dry weight) 12d mg/L. REGULATORY VolaLile VOC Less INFORMATION: Oiganic Compounds: N/A. II20 & Exempt Solvents: N/A. Since regl~lations before disposal. EPA H~zaidous). vary, conslllt applicab e U.S. EPA Hazardous Waste regl~lations or Number None al~thorities (Not U.S. ~he ingredients of this product are in conpliance with EINECS. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSURE : No No P.EACTIVITY : No ACUTE : CHRONIC : Yes Yes Asbreviations: N/D - No Determimed N/A - Not Applicable 22777722FF..00000022 33MM_MMNN00S5442233779944 rn ms os rns st MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical S~rfactant FEBRUARY 7, 1997 PAGE: 3 ot 6 mmm -- SUGGESTED FIRST AID THaT ee fe oro en EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a Dnysican. Wash ccntaminated clothing betore reuse and dispose ot son_amnatec shoes. IN~LALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWA!~LOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION ome EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac . Wear appropriate gloves when handling ths EETor TbSnSE AR material. A pair o gloves made from the following material(sl are recoK~rlended: ~utyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace of either o- the following ma erals: polyethylene/polyvinvlidene chloride (Saranex) Coverall made of Tyvekir). Hear rubbe~ boots when cleaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: EE a Se ST Avoid bieaLhing o vapois, misLs oi sp~ay. Avoid bieaLhing of airborne material. Select cne of the fo lowing NIOSII a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA reglllations: full-face high-efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTA~ INGESTION: Do not eat, drinn or smoke when using a~eas thoroughly with soap and water. before eating. ths procuct. Wash exposed Wash h~ds afte~ handling ~d RECOMHENDED STORAGE: Store at temperatures above 32 degrees F (0 degrees C). Keep Abreviations: N/D No_ Determined N/A Not Applicable 22777722FF..00000033 33MM_MMNN0055442233779955 Ho 1008FREAD (0) Bend Pnsrochemiest furtctant MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical S~rfactant FEBRUARY 7, 1997 PAGE: 4 ot 6 Cr7. ePRmEaCAeUaTImOoNwARRYTIoNmFORRTMAITIoOnN nei (continued) container closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Not applicable. OTHER PRECAUTIONARY INFOP!4ATION: HMIS KAZARD RATINGS: HEALTH: 2 FL~dMAB LITY: 1 REACTIVITY: 0 PERSONAL PROTECTION: X (See p-ecautions, section 7.1 INGREDIENTS EXPOSURE LIMITS V2~LUE UNIT TYPE AUTH SKIN* WATER ................................ AHMONIUM PERFLUOROOC~ANOATE .......... PERFLUORO COMPOUNDS + ............... AHMONIUM PERFLUOROHEXANOATE .......... AHMONIUM PERFLUOROHEPTANOATE ......... AHMONIUH PERFLUOROPENTANOATE ......... NONE 0.01 NONE 0.1 0.1 O.1 NONE mg/m3 NONE mg/m3 mg/m3 mg/m3 NONE NONE TWA ACGIH Y NONE NONE TWA 3M Y TWA 3M Y TWA 3M Y * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to eemonet better vo tha oPecai] exposureby Loe. svtammots.sate the pctential contrbution to the ove-a 1 exposure by the cutaneous route IneiEsing mocose memhiune ms ope, SLeheE by e1ebotny ote mare Pertioulacly. including mucous membrane and eye, either by airborne or, more particularly, 7 Sheers Convact with The Subetances VenLLles con ALeet SER SbscEptions by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOUIqCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Indl~strial Hygine Assoc. Workplace Environmental Exposl~re 3H: 3M Melisal Oepartment Guideline - NONE: None Established Level Gl~ideline Cemmmewwe 8. HEALTH HAZARD DATA EYE CONTACT: Moderate Eye Irri aton: signs/symptoms pain, tearing, and hazy vision. can inclllde redness, swelling, Canta Trrfeatingvo the tyeans may ouaseope srry No toxicity data for can be irritating to the the solution. Ammonum perfluoroalkanoates eye and may cause eye injury from airborne exposl~re. SKIN CONTACT: May be absorbed through the skin and persist in the body fo~ an extenced time. No toxicity data for the solution. Some ale sligbLly Loxic when ab~cibed Lhough ammonium perfluoroalkanostes Lhe skin. IN~LALATION: May be absorbed by inhalation and persist in the body for an extenced Robeeriationss WD = ox Detesnired WA = Wot Applicatle Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722FF..00000044 33MIM_MMNNO055442233779966 13, ps. ose eis sn MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical Surfactant FEBRUARY 7, 1997 PAGE: bot 6 BE 8. HEALTH HAZARD DATA ca(continued) -- time. No toxicity data for the solution. Some anmonium perfluoroalkanoates can be considered moderately toxic by inhalation on a single exposure; a median lethal ccncentration for a 4-hour exmosu-e in the albino rat is 930 mi ligrams per cubic meter. Single overexposure, above recoK~nended guidelines, may sause: Irritation (upper respiratory): signs/symptoms can include screness of _he nose and throat, couqhing and sneezinq. IF SW~-~LOWED: ngestion is not a lkely rcute of exposure to this produc_. En Bp ee No toxicity data for the solution. A mixture of ammonium perflucroalkanoates was mocerately toxic in albino rats from a single oral exposure; acute oral LD50 (rat) is 540 mg. per kg. of body weight. LT A EL CANCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1 11983 and 1993 studies concucted join_ly by 3M and DuPont). A alature of asmonlus perflucrooctanoate, ammorius MUTAGENICITY: A mixture of ammonium perfluorooctanoate, ammonium perflucroheptanoa_e, ammonium perfluoropentanoate and ammonium perflucrohexanoate was not mutagenic in nvitro S------ mlltagenicity assays. The mixtllre did not a maK~rlalian cell _~ansformation assay. REPRODUCTIVE/DEVELOPMENT~.L TOXINS: cause }cell transfo-mation A mixture of ammonium perfluorooctanoate, ammonium perfll<croheptanoa e, ammonillm perfl~oropentanoate and ammonil~m perflucrohexanoate was not teratogenic in rabbits by oral administration and was not teratogenic to rats my gavage and inhalation exmosu~es. SECTION CHA~GE DATES HEALTH HAZD. DATA SECTION CHANGED SINCE AUGUST 22, 1996ISSUE Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722FF..00000055 33MM_MMNN0055442233779977 soos: reei00sraces (oy meant Plsrochemicnt suctactant MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical S~rfactant FEBRUARY 7, 1997 PAGE: 6 ot 6 SECTION C~AI~GE DATES Robceriations: WD = Now beternired WA = ot Applicable Abreviations: N/~ - No_ Determined N/A - Not Applicable The in-ormaticn in this Material Safety Data Sheet (HSDS) is believed to be correct as of the date isslled. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, S~'I NOT LIMITED "0, ANY IMPLIE~ WARRANTY OF MERCHANTASiLi"Y OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE 07 PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether _he 3M product is fit for a particu ar purpose and suitable for user's method of use or apDlicaton. Given the varety of factors that can affect the use and application of a 3M prodllct, pudgrphelagdnrrgbeelhipfotrig ned vad some o whick are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit ON PAECiouiarpurposeand SuLtabRe TOF seectsmethodofute ofapplicetions for a particular purpose and suitable for user's method of use or application. provides information in electronic form se 3 service to ita customess. Gun 3M provdes information in electronic form as a service to its customers. Dl~e to the remote ~ossibility that electronic transfer may have resul_ed in errors, ai Tonmor teraions"in this Seosmatiosonress ne sebvecoensnstetao omissions oi alLeiaLions in Lhis inoimaLion, 3M makes no iepiesen~a~ions as Lo its completeness or accuracy. In addition, in-ormation obtained f~om a database A more SiSuceesentht tnfrastioTn% the HADS. svaiiselestrectly Fees She may not be as current as the information in _he MSDS available directly frcm 3M. 22777722FF..00000066 33MM_MMNN0055442233779988 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M products is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FX-1OO2 FLUORAD(TM) Brand Fluorochemical Salt ID NUMBER/U.P.C.: ZF-0092-0098-8 - ISSUED: FEBRUARY 7, 1997 SUPERSEDES: AUGUST 22, 1996 DOCUMENT: 10 4089 8 ZF-0002-0119-1 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 773?-18-5 ndvlHONiUH PERFLUROALKYL CARSOXYLA'I'E .. 3825-26- 2@.0 - AMMONIUM PERFLUROALKYL CARBOKYLATE .. 6139-43-4 1.0 - AMMONIUM PERFLUOROALKYL CARBOKYLATE .. 2161o-47-4 1.0 - AMMONIUM PERFLUROALKYL CARBOXYLATE .. 68259-11-0 1.0 - RR 2. PHYSICAL DATA 75.0 25.@ 3.0 3.0 3.0 BOILING POINT: ............... ca. 100 C i Cain VAPOR PRESSUILE: .............. VAPOR DENSITY: .............. ca. 18 mmHg Calc. @ 20 C ca. 0.62 Air 1 Calc. @ 20 C EVAPORATION RATE: ............ < ].0 81]ty] Acetate ] SOLUBILITY IN WATER: ........ complete FERS I Ey SP. GRAVITY: ................. 1.1 Water - PERCENT VOLATILE: ........... ca. 75 % pH: ......................... 8.0-9.5 VISCOSITY: .................. N/D MELTING POINT ................ N/A APPEAR~NCE AND ODOR: Clear, colorless to pa e yellcw liquid, slight ~mmonium odor 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: ................. None (Setaflash CC) FLAMMABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam SPECIAL FIRE FIGHTING PROCEDLrRES: Wear full protective clothing, incllding helmet, self-contained, positive pressure or pressure demand b~eathing apparatus, bunker and pants, bands a~ound aims, waist and egs, face mask, and coat Abreviations: N/D No_ Determined N/A Not Applicable 22777722GG..00000011 Exhibit 2772G State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055443333554455 LE MSDS: FX-1002 FLUORAD(TM) Brand Fluorochemical Salt FEBRUARY 7, 1997 PAGE: 2 at b 3. FIRE AND EXPLOSION HAZARD DATA (continued) protective covering for expcsed areas o- the head. UNUSU/~L FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo- products of campus_ion. 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERII~LS TO AVOID: Not applicable. HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides at Nitrogen, Hyd-ogen Fluoride, ~nmonia. 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: F TPeLohl andebLh PAsa brats SempiFRCecy prevenltion.eSemeiaiariokn, and Refer to other sections of this MSDS for information regarding physical and heal_h hazards, respiratory protection, ventilat on, and personal protective equipment. In the U.S.A., call (612) 733--110 or 1612) 733-6100 for 24-hour spill assistance. Ccver with absorbent material. Collec_ spilled material. Place in a U.S. DOT-approved container. RECOHHENDED DISPOSA!~: Discharge spent solutions and small quantities (less than 5 gal.<19 El) to a wastewate~ treatment system. Reduce cischarge ra_e f foaming occllrs. Incnerate in a permitted hazardolls waste ncinerator in the presence of a cambust ble material. Combustion products will include HF. ENVIRONMENTAL DATA: EN Chemical Oxygen Demand (COD): Nil; ?0-Day Biochemical Oxygen Demanc IBO~2@): Nil; 9@-H~. LC5@, Bluegill Sun sh (Lepomis macrochirus): 2280 mg/L; 96-Hr. LC50, Fathead Hinnow(Pnephales promelas): 3060 Ri hl Sl et ER mgiL. 48 IIr. EC50, Daphnia magna: 2530 mg/L; 14 Day EC50, G~een Algae Seomintrimcanpic112oPgVm(caal:tCouontm).Hso abvaces effets ISelenastrum capricornutum): 292 mg!L (cell dry wt.); ld-Day EC50, Selenastrl~m caricornl~tum: 172 mg/L (cel collnt). No adverse effects upon hatchability o Pimephales pramelas eggs at 100 mg/L. REGULATORY Volatile VOC Less INFORMATION: Organic Compounds: N/A. H20 & Exempt Solvents: N/A. ~he com/onenLs of Lhs piocucL aie in compliance wiLh Lhe chemical registration requi-ements of: TSCA, EINECS, CDSL, AICS, MITI. EPCRA HAZARD CLASS: FIRE HAZARD: PRESSURE: No No R!BACTIVITY: No ACUTE: CHRONIC: Yes Yes 22777722GG..00000022 33MM_MMNN0055443333554466 FE ------ MSDS: FX-1002 FLUORAD(TM) Brand Fluorochemical Salt FEBRUARY 7, 1997 PAGE: 3 at b mmm -- SUGGESTED FIRST AID THaT ee fe oro en EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Flush skin with la-ge amounts of water, medical attention. f irritation persists, get IN~L~LATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac_. Wear appropriate gloves when handling ths material. A pair o- gloves made from the following material(sl are recoK~rlended: ~ltyl rllbber. Nse one o- more of the following EEE RTI personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace of either o- the following ma_erals: polyethylene/polyvinylidene chloride (Saranex) Coverall made of Tyvek(r). ~ear rubbe~ boots when cleaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf-cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or sp~av. Avoid breathing of airborne material. Select cne of the fo lowing NIOSH a~proved iespiraLois based on aiiborne concenL~aLon of conLami[lanLs and in accorcance with OSIIA regulations: full face high efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTAL INGESTION: Do haL eaL, JiinA oi smoke ~hen using areas thoroughly with soap and water. before eating. Lhs piocucL. Wash exposed Wash hands after nandlng and RECOMMENDED STORAGE: SLoie aL iooln Lelnpeia~uie. Keep cunLainei closed when haL in use. A~b~evia~io~ls: N/D - No De~eimi~ ed N/A - No~ Applicable 22777722GG..00000033 33MM_MMNN0055443333554477 ses: ree1002paces tu)mean Porochesicnt suit MSDS: FX-1002 FLUORAD(TM) Brand Fluorochemical Salt FEBRUARY 7, 1997 PAGE: 4 ot b Cr7. ePRmEaCAeUaTImOoNwARRYTIoNmFORRTMAITIoOnN nei (continued) rigs : FIRE AND EXPLOSION AVOIDANCE: Not applicable. OTHER PRECAUTIONARY INFORI~ATION: HMIS HAZARD RATINGS: HEALTH: 2 FL,~IMAB LITY: O REACTIVITY: 0 PERSONAL PROTECTION: X (See p-ecautions, section 7.1 INGREDIENTS EXPOSURE LIMITS VA~UE UNIT TYPE AUTH SKIN* WATER ................................ AHHONIUH PERFLUOROALKYL CARBOKYLATE .. AHMONIUM PERFLUOROALKYL CARBOXYLATE .. AHMONIUM PERFLUOROALKYL CARBOKYLATE .. AHMONIUM PERFLUOROALKYL CARBOKYLATE .. NONE 0.01 0.1 0.1 0.1 NONE mg/m3 mg/m3 mg/m3 mg/m3 NONE NONE TWA ACGIH Y TWA 3M Y TWA 3M Y TWA 3M Y oe tome Soni autIon 20theOVesaL1 mPoRureby Tae cutameoLs routh * SKIN NOTATION: ~isted substances indicated with "Y" under SKiN refer to the pctential contr bution to the ove-a 1 exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ wth the substance. Vehicles can alter skn abscrption. SACaIN: American Confererce of Governmental Industrial Mygieniste SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Industrial Hygine Assoc. Workplace Environmental Exposure 3M: 3M Medical Department Guideline - NONE: None Established Level Guideline 8. HEA~TH HAZARD DATA EYE CONTACT: Mild Eye Irritation: pain, and tearing. signs/symptoms can nclude redness, swel ing, FEET fecteation iaeter prolongs or repestes contact) SKIN CONTACT: Hild Skin Irritation (after ?rolonged or repeated contact): signs/symptoms can include redness, swel ing, and itching. May be absorbed th~ol~gh the skin and persist in the body fo~ an extenced time. CoAively tatsaantitios ofthis mueriats nt IN~ALATION: llness may occur a-ter a single overexposure by inhalation to relatively large ql~antities of this material. liiLaLion (upoe~ ~espiiaLoiy): signs/sympLoms of the nose and throat, coughing and sneezing. can include soieness May be absorbed by inhalation and persist in the body for an extenced Robceristionss WO - Not Determined WA - ot Applicatle Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722GG..00000044 33MM_MMNN0055443333554488 Mos: pi-1002 FLA) Brand Fluosochesionl Salt MSDS: FX-1002 FLUORAD(TM) Brand Fluorochemical Salt FEBRUARY 7, 1997 PAGE: bot b Cemmemwewn oN 8. HEALTH HAZARD DATA eeemmes (continued) Frolorged cx sepested overexposure, hove fecommended Juidelines, may time. Prolonged or repeated overexposure, above recommended guidelines, may LaiverCeBnttfaarcntosr:e sofignusp/peeyrmpsrhoansseenc.an include yellow skin(jaundice) cause: Liver Effects: and tenderness signs/symptoms can of upper abdomen. include yellow skin(jaundice) IF SWALLOWED: rSlienenceamaly "sosats from a single sualloving of 3 mderate quintity of nqestion is not a 1 kely rcute of exposure to this produc_. llness may resul_ -rom a single swallowng of a moderate quantity cf this material. ~he oral LD50 for ammonium perfluoroalky carboxylate is 040 milligrams per kilogram of body weigh_ in the albino rat. CANWCAERRN:ING: Contains a chemical which can cause cancer. (3825-261) WARNING: Contains a chemical which can cause cancer. (382o-26-1) 1903 ana 1993 studies conducted 1oinCly By SH and BUFR) 11983 and 1993 studies concucted join_ly by 3H and DuPont). ResmoouctIve/DRvELOM@ITAL ToNINS: REPRODUCTIVE/DEVELOPMENT~_L TOXINS: Toe Cetrtegont= Lr EALbCts bf oer] adsinisteaticn. Not tecatogents to Not teratogenis in rabbits by oral adminstraticn. Not teratogenic to Fateh Sevag ox tAmaiation exposes. rats by gavage or inhalation exposures. SECTION C~AIqGE DATES HEA~TH HAZD. DATA SECTION CHAI~GED SINCE AUGUST 22, 1996ISSUE Robceviationes WD - Not Daterired WA = lot Applicable Abreviations: N/D No_ Determined N/A Not Applicable 'he in ormaticn in this Material Safety Data Sheet (HS/iS) is believed to be collect as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED ~O, ANY IMPLIED WARRANTY OF MERCIIANTABILI~Y OR FITNESS EOR A ~ARTICULAR PURPOSE OR COURSE Om PERFORMANCE OR USAGE OE TRADE. User is omponsinie for determining dhather he SH product io fit for 3 Nser is responsible for determining whether he 3M prodllct is fit for a PAECLCULAF puigose ana suitable fof userts method of Loe of application. Given particu ar purpose and suitable for user's method of use or apmlicat on. Given DTV UT ERASIS iat can CEG Ue ew and sppiscacion of + 3 pruucts Lhe vai eLy o acLois LhaL can ~fect Lhe use and application of a 3M pioducL, oma 55 Uhleh acesrkasely within the user's Rnoviados and Sonteols + bo some o- which are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit fon a panticllan punpose and suitable fon ]se'-'s method of use or applicstion. to the como poamhiat sniacitiolniietrnanyfr aay have rorsicIend Cesare, 3M provdes inoimaLion in elecLionic oiln as a seivice Lo iLs cusLomeis. Due to the remote possibility that electronic transfer may have resul_ed in errors, omissions or alterations in this information, 3M makes no representations as to may not be 4s current as the Information in che MSDS availble directly fre SW its completeness on accuracy. Tn addition, in-onmation obtained f~om a database may not be as current as the information in _he MSDS available directly frcm 3M. 22777722GG..00000055 33MM_MMNN0055443333554499 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: oman eS A A SR FC-1094 FLUORAD(TM) Brand Fluorochemical Su--actant ID NUMBER/U.P.C.: 98-0211-6603-2 00-51135-10422-4 98-0211-660d-0 00-51135-10423-1 98-021--6685-7 00-51135-1042&-8 98-0211-8859-8 08-Sl135-10972-4 ISSUED: FEBRUARY 19, SUPERSEDES: FEBRUARY DOCUMENT: 05-6285-0 1997 6, 1997 I. INGREDIENT C.A.S. NO. PERCENT NA''ER ................................ 7732-18-5 AMMONIUM PERFLUROALKYL CARBOKYLATE .. 3825-26-- 1~.0 - AMMONIUM PERFLUOROALKYL CARBOKYLATE .. 6130-43-4 0.1 - AMMONIUM PERFLUOROALKYL CARBOXYLATE .. 2161o-47-4 0.1 - AMMONINM PERFLNOROALKYL CARBOXYLATE .. 68259-11-0 0.1 - NOTE: The i~lgr~dienLs o Lh s piocucL aie i~cluded on 7SCA. 2. PHYSICAL DATA faa Doi BOILING POINT: ............... ca. i00 C VAPOR PRESSURE: .............. ca. 18 mmHg ~ Calc. @ 20 C VAPOR DENSITY: .............. ca. 0.62 Air 1 Calc. @ 20 C EVAPORATION RATE: ............ < 1.0 Butyl Acetate Frans SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. ca. 1.1 Wate- 1 PERCENT VOLATILE: ........... 80 % pH: ......................... ca. 5 V viIsSoCoOsSaItTtY:: evens .................. nT (2.0% Aqueous) N/A MELTING POINT ................ N/A APPEAR~iqCE AND ODOR: Light colcred liquid; slight 1 cdor. 3. FIRE ~ EXPLOSION HAZARD DATA 8@.@ 21.0 1.0 1.0 1.0 FLASH POINT: ................. Setaflash None FLAMMABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam Abreviations: N/D No_ Determined N/A Not Applicable 22777722HH..00000011 Exhibit 2772H State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055441199446666 sesroots acest) mean Porochemicnt suctactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: 2 ot 6 33. IEFIREaANDBST EXPLOSIONBHAAZNARDD NA DATA eons (continued) Tealeioe Posesuee 2% Bevtote Spas Sosshins. shpesstes: Binrer SPECIA!~ FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, race mask, and protective coverinq for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo~ products of comus_ion. T08tcoat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS TO AVOID: Not Applicable HAZARDOUS POLYMERIZATION: Will Not Occur HAZCCaAarRrbbDooOr.nUSM MDoonEnoCoxOxiMidPdeOeSIaaTnndIdONCCaarPrbbRooOnDnUCDDTiiSoo:xxiiddee,, OOxxiiddeess ooff Fluoride, ~nmonia. N Kiittrrooggeenn,, Hdpyddzrooggeenn 5. ENVIRONMENTAL INFORMATION Phreical anheaLoh assests EespATatocy protections vemeiiacion, amd SPILL RESPONSE: Refer to other sections of this MSDS for physical and heal h hazards, respiratory information protection, regarding ventilaton, and personal protective equipment. In the U.S.A., call (612) 733-11@ or 1612) 733-6100 for 24-hour spill assistance. Ccntain sill. Cover with absorbent ma_eral. Ccllect spilled material. For spills to grollnd: Collect contaminated soil. Pllmp contaminated water from puddles or stagnant storm sewers. ?lace collected waste in approved containers, and seal. For spil s to ground or surface water: Notify appropriate authorities. Contact 3M to evaluate further needs. RECOMMENDED DISPOSAL: ncinerate in an industrial or commercia facility in the Fass contaminated water thecuh anion exchange cosine If a coll@~ustible material. Combustion products will include Pass ccntaminated water thrcllgh anion exchange resin. If contact 3M for assistance. p-esence cf necessary IIF. necessary, ENVIRONMENT/~L DATA: Tee Tee phen solder Craxical Qcygen Daman (C005 NEL (0.00070 Data fcr product solds: Chemical Oxygen Demanc (COD): Nil (0.00070 g/g); 20-Day Biochemcal Oxygen Demand (BOD2@): Nil; 96-Hr. LC50, Shins Sukeian (LaponisTabrochiEae)s 569 mastsSoe, Lise, Fiend Bluegill Sunfish (Lepomis macrochirus): 569 mg/L; 96-Hr. LC50, Fathead Minnow(Pimephales piomelas): 766 ln~!L; 48-Hi ECS0, Daphnia magna: 6~2 fib Star pi pp Ra mgiL; 14 Day EC50 (cell dry weight), G~een Algae (Selenastrum capriccrnutum) 73 mg/L. Soil Adsorption Coefficient (Koc): -7, ~ndicates very nigh mobility. (St/]dy used a sandy loam soill. Volatile REGULATORY Volatile Organic Compoundst INFORMATION: Organic Compounds: N N//A A.. Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722HH..00000022 33MM_MMNNO055441189446677 rT -------- MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: 3 ot 6 a 5. ENVIRONMENTAL INFORMATION (continued) -- SE ER VOC Less H20 & Exempt Solvents: N/A. Since regulations before disposal. vary, consult applicab e U.S. EPA Hazardous Waste EPA Hazardous). I regulations or Number None BE authorities (Not U.S. ~he components of ths procuct are in compliance with the chemical registration requi-ements of: TSCA, EINECS, CDSL, AICS, MITI. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSOIqE : No No I~EACTIVITY : No ACUTE : CHRONIC : Yes Yes SUGGESTED FIRST AID EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. ET SR RE IEI AE SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a ~nysic an. Wash ccntaminated clothing before reuse and dispose of son_amnatec shoes. I ST INHALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin conLac_. Weai ap/iopiiaLe gloves when handling Lhs TIA Sr wn pry material. A pair o- gloves made from the follo~ing material(sl are recoK~rlended: utyl rubber. Use one o~ more of the following personal protection tems as necessary to prevent skin con act: head Ei ae aL covering, coveralls. Protective garments iother than glovesi should mot vite oF teTotloniog maces aber ' be mace of eiLhe~ o- Lhe following ma_eials: polyethylene/polyvinylidene chloride (Saranex) Coverall made of Tyvek(r). Hear- r/lbbe'- boots when cleaning up spills. Use with appropriate local exhaust ventiation. Provide sufficient VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf-cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is rot adeq/late, use appropriate respiratory Asbreviations: N/D - No Determired N/A - Not Applicable 22777722HH..00000033 33MM_MMNON0055441199446688 Ho C1084FORA Bean Poroshesicat Surfactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: 4 at 6 Cr7. ePRmEaCAeUaTImOoNwARRYTIoNmFORRTMAITIoOnN nei (continued) protection. RESPIRATORY PROTECTION: Avoid breathing at vapors, mists or sp-av. Avoid breathing at airborne material. Select cne of the fo lowing NIOSH a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA regulations: full-face high-efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTAL INGESTION: Frome thority With soap Do not eat, drink or smoke areas thoroughly with soap and water, when using and water. Wash hirds after aandling ths procuct. Wash exposed Wash hands after nandlng aanrdd before eating. RECOMHENDED STORAGE: Store at temperatu-es above 32 degrees F (O degrees C). container closed when not in use. Keep FIRE AI~D EXPLOSION AVOIDANCE: Not applicable. Nonflammable. OTHER PRECAUTIONARY INFOP.MATION: ar rpotivionprosicns mentionedth Sesion 1 of No smoking: Smoking while using this p-oduct can result in contamination of _he tobaccc and/or smoke and lead to the formation of the hazardous decomposition produc_s mentioned in section 4 of this HSDS. HMIS KAZARD RATINGS: HEALTH: 2 FL~MAB LITY: @ REACTIVITY: 0 PERSONAL ?ROTECTION: X (See p~ecautions, section 7.) INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* WATER ................................ AHMONIUM PERFLUOROALKYL CARBOXYLATE .. AHMONIUM PERFLUOROALKYL CARBOKYLATE .. A~IMONINM PERFLNOROALKYL CARBOKYLATE .. AHHONIUH ?ERFLSOROALKYL CAR~OXYLA'I'E .. NONE 0. 01 0.1 0.1 0.1 NONE rag/m3 mg/m3 rag/m3 mg/m3 NONE NONE TWA ACGII[ Y TWA 3M Y TWA 3M Y TWA 3H Y * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contrbution to the ove~a 1 exposure by the cutaneous route incll~ding ml~co~s membrane and eye, either by airborne or, more particl~larly, by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOUIqCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental 3M: 3M Metical Department Gl~ideline - NONE: None Established Industrial Hygienists Robeaviationss WD = ox botasnired WA = tot Applicatie Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722HH..00000044 33MM_MMNN0055441189446699 Ho C1084FORA Bean Poroshesicat Surfactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: bot 6 Comm mews we 8. HEALTH HAZARD DATA NSoioottoexiccxipesyeuicteamafoyrcutshseessolution. EYE CONTACT: No toxicity data for the solution. Single exposure may cause: Hcderate Eye Irritation: swelling, pain, tearing, signs!symptoms can and hazy vsion. include redness, SKIN CONTACT: Mild Skin Irritation (after prolonqed or im/syoran ipncltoseotescmessss svel:ings 3nd seeming. signs/symptoms can include redness, swel repeated ing, and contact): itching. Hay be sbsocbed theoush the akin and persist ir the body fo: an May be absorbed th-ough the skin and persist in the body fo- an extenced time. No toxicity data for the solution. INHALATION: iiness requiring medical by inhalation to moderate attention may cuantities of result trom a single this material. exposure May be absorbed by inhalaticn and persist in the body for an extenced Wo torsetey daca for the solution. time. No toxicity data for the solution. Repeated inhalation exposure produced liver changes and elevated blood crganofllloride levels in rats. Sinate eveserpamuces Sov. sesomenied Guidelivess may Swiss: Single overexposure, above recoK~nended guidelines, may cause: Iesttatson. (upper sespizatory): signs/eyeptoes can include Irritation (upper respiratory): signs/symptoms can include Eeeness ot FR Sore ana Shesats Sheahan ana sneezing. screness of _he nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended @uidelines, may Lives Eftocte: signa/emptons can dnclude yellow skin(jsundice) cause: Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. IF SWALLOWED: liners say sossls fron a single sallovtng of a moderate quantity cf ngestion is not a lkely rcute of exposure to this produc_. llness may resll -rom a single swallowng of a moderate ql~antity cf this material. No toxicity data for the solution. RRTN56I3RGasndCo1n9t9a3inssLubiocnhemciocnadluctuendinJocramnlycaubsye Icansciekr.S(U39E25-2601) CAIqCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1) 11983 ~nd 1993 sLudies concucLed j~in_ly by 3H ~nd DuPing). MUTAGENICITY: Anmonium perfl/loroalkyl c~rboxylate was not mutagen~c in invitro Aobreviationss WD = Nor Doternired WA = lot Applicatie Asbreviations: N/D - No Determired N/A - Not Applicable 22777722HH..00000055 33MIM_MMNNO055441199447700 Ho C1084FORA Bean Poroshesicat Surfactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: 6 ot 6 Cw me Te 8. HEALTH HAZARD DATA eed (continued) mutagenicity assays. Did not cause cell transformation in a manmalian cell transformntion assay. RaopuEVcE OImEvITeAL TorNS: REPRODUCTIVE/DEVELOPMENTAL TOXINS: Anmonium perfluoroalkvl csrboxylate was not teratoqenic in -abbits by Co MEdhiseeation and wis ot. tecakegenie to favsbY ghvagh apd oral administration and was not teratogenic to rats by gavage and inhalation exDosu-es. OTHER HE~-~TH HAZARD INFOI~ATION: Healtk hazard information is based on data for ammonium perflucroalkyl carboxylate solids. SECTION CHANGE DATES PRECAUT. INFO. SECTION CHANGED SINCE FEBRNARY 6, 1997ISSUE Robeeriationss WD - Nox betesnired WA - tot Applicatie Abreviations: N/D No_ Determined N/A Not Applicable l'he in ormaticn in this Material Safety ~ata Sheet (HS~S) is believed to be correct as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED ~O, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR Freese:an Pose, and Suite Sof SevEremevhedchvas of sPAicetion. Given FITNESS Nser is particu FOR A ~ARTICULAR PURPOSE OR responsible for determining ar purpose and suitable for COURSE O~ PERFORMANCE OR USAGE OF TRADE. whether he 3M prodllct is fit for a user's method of use or ap~licat on. Given Lhe vaieLy o acLois LhaL can ~fec~ Lhe use and application o a 3M pioducL, some o- whick are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit EN Patiouiarporporeand Seitabke Sor srestsmethed ofwtof spPhLCHIon: for a particl~lar pl~rpose and suitable for ~se~'s method of l~se or application. provides SuformaLion In vivcLione fom es + SEVECN LW 8 customs. Du 3M p~ovdes inoimaLion in elecLionic oiln as a seivic~ Lo iLs cusLomeis. Due to the remote Rossibility that electronic transfer may have resul_ed in errors, oimuionsor siterarions Ln thi. Informations Sh maker meseprasentatiseo.n1e3 omissions or alterations in this information, 3M makes no representations as to its completeress or ascuracv. Tn addition, in-ormation obtained f~om a database may not be as current as the information in _he MSDS available directly frcm 3M. 22777722HH..00000066 I3MM_MMNNO0S544119447711 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M products is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FX-1OO2 FLUORAD(TM) Brand Fluorochemical Salt ID NUMBER/U.P.C.: ZF-0092-0098-8 - ISSUED: FESRUARY 19, SUPERSEDES: FEBRUARY DOCUMENT: 10 4089 8 1997 7, 1997 ZF-0002-0110-1 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 7737-18-5 ndvlHONiUH PERFLUROALKYL CARSOXYLATE .. 3825-26- 2@.0 - AMMONIUM PERFLUROALKYL CARBOKYLATE .. 6130-43-4 1.0 - AMMONIUM PERFLUOROALKYL CARBOKYLATE .. 21610-47-4 1.0 - AMMONIUM PERFLUOROALKYL CARBOXYLATE .. 68259-11-0 1.0 - RR 2. PHYSICAL DATA 75.0 25.@ 3.0 3.0 3.0 BOILING POINT: ............... ca. 100 C i Cain VAPOR PRESSUILE: .............. VAPOR DENSITY: .............. ca. 18 mmHg Calc. @ 20 C ca. 0.62 Air 1 Calc. @ 20 C EVAPORATION RATE: ............ < ].0 Rl]ty] Acetate ] SOLUBILITY IN WATER: ........ complete FERS I Ey SP. GRAVITY: ................. 1.1 Water - PERCENT VOLATILE: ........... ca. 75 % pH: ......................... 8.0-9.5 VISCOSITY: .................. N/D MELTING POINT ................ N/A APPEAR~NCE AND ODOR: Clear, colorless to pa e yellcw liquid, slight ~mmonium odor 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: ................. None (Setaflash CC) FLAMMABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam SPECIAL FIRE FIGHTING PROCEDLrRES: Wear full protective clothing, incllding helmet, self-contained, positive pressure or pressure demand b~eathing apparatus, bunker and pants, bands a~ound aims, waist and egs, face mask, and coat Abreviations: N/D No_ Determined N/A Not Applicable 2277772211..00000011 Exhibit 2772I State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055443333555500 EE MSDS: FX-1002 FLUORAD(TM) Brand Fluorochemical Salt FEBRUARY 19, 1997 ?AGE: 2 ot b 3. FIRE AND EXPLOSION HAZARD DATA (continued) protective covering for expcsed areas o- the head. UNUSU/~L FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo- products of campus_ion. 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERII~LS TO AVOID: Not applicable. ~AZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Honoxide and Carbon Dioxide, Oxides ot Nitrogen, Hyd-ogen Fluoride, ~nmonia. 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: F TPeLohl andebLh PAsa brats SempiFRCecy prevenltion.eSemeiaiariokn, and Refer to other sections of this MSDS for information regarding physical and heal_h hazards, respiratory protection, ventilat on, and personal protective equipment. In the U.S.A., call (612) 733--110 or 1612) 733-6100 for 24-hour spill assistance. Ccver with absorbent material. Collec_ spilled material. Place in a U.S. DOT-approved container. RECOHHENDED DISPOSA!~: Discharge spent solutions and small quantities (less than 5 gal.<19 El) to a wastewate~ treatment system. Reduce cischarge ra_e f foaming occllrs. Incnerate in a permitted hazardolls waste ncinerator in the presence of a cambust ble material. Combustion products will include HF. ENVIRONMENTAL DATA: EN Chemical Oxygen Demand (COD): Nil; ?0-Day Biochemical Oxygen Demanc IBO~2@): Nil; 9@-H~. LC5@, Bluegill Sun sh (Lepomis macrochirus): 2280 mg/L; 96-Hr. LC50, Fathead Hinnow(Pnephales promelas): 3060 Ri hl Sl et ER mgiL. 48 IIr. EC50, Daphnia magna: 2530 mg/L; 14 Day EC50, G~een Algae Seomintrimcanpic112oPgVm(caal:tCouontm).Hso abvaces effets ISelenastrum capricornutum): 292 mg!L (cell dry wt.); ld-Day EC50, Selenastrl~m caricornl~tum: 172 mg/L (col collnt). No adverse effects upon hatchability o Pimephales pramelas eggs at 100 mg/L. REGULATORY Volatile VOC Less INFORMATION: Organic Compounds: N/A. H20 & Exempt Solvents: N/A. ~he com/onenLs of Lhs piocucL aie in compliance wiLh Lhe chemical registration requi-ements of: TSCA, EINECS, CDSL, AICS, MITI. EPCRA HAZARD CLASS: FIRE HAZARD: PRESSURE: No No R!BACTIVITY: No ACUTE: CHRONIC: Y~s Yes 2277772211..00000022 33MM_MMNN0055443333555511 FE ------ MSDS: FX-1002 FLUORAD(TM) Brand Fluorochemical Salt FEBRUARY 19, 1997 ?AGE: 3 at b mmm -- SUGGESTED FIRST AID THaT ee fe oro en EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Flush skin with la-ge amounts of water, medical attention. f irritation persists, get IN~L~LATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac_. Wear appropriate gloves when handling ths material. A pair o- gloves made from the following material(sl are recoK~rlended: ~ltyl rllbber. Nse one o- more of the following EEE RTI personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace of either o- the following ma_erals: polyethylene/polyvinylidene chloride (Saranex) Coverall made of Tyvek(r). ~ear rubbe~ boots when cleaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf-cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or sp~av. Avoid breathing of airborne material. Select cne of the fo lowing NIOSH a~proved iespira~ois based on aiiborne concenL~aLon of conLami[lanLs and in accorcance with OSIIA regulations: full face high efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTAL INGESTION: Do haL eaL, JiinA oi smoke ~hen using areas thoroughly with soap and water. before eating. Lhs piocucS. Wash exposed Wash hands after nandlng and RECOMMENDED STORAGE: SLoie aL iooln Lelnpeia~uie. Keep cunLainei closed when haL in use. A~b~evia~io~ls: N/D - No De~eimi~ ed N/A - No~ Applicable 2277772211..00000033 33MM_MMNN0055443333555522 Ho 1002yon 0 fran Peroshesint a1 MSDS: FX-1002 FLUORAD(TM) Brand Fluorochemical Salt FEBRUARY 19, 1997 ?AGE: 4 ot b Cr7. ePRmEaCAeUaTImOoNwARRYTIoNmFORRTMAITIoOnN nei (continued) FIRNNEoottANaaDppppllEiiXccPaaLbbOllSeeI..ON ANNVoonOnfIflDlaAamNmmCmiEab:bllee.. Contmmitationof Shetobscts sok sEave.sid 142855the formation OTHER PRECAUTIONARY INFORI~ATION: No smoking: Smoking while using this p-oduct can result in contamination of _he tobaccc and/or smoke and lead to the formation of the hazardous decomposition produc_s mentioned in section 4 of this HSDS. HMIS KAZARD RATINGS: HEALTH: 2 FL,~MAB LITY: O REACTIVITY: 0 PERSONAL PROTECTION: X (See p-ecautions, section 7.1 INGREDIENTS EXPOSURE LIMITS VA~UE IYNIT TYPE AUTH SKIN* WATER ................................ AHHONIUH PERFLUOROALKYL CARBOKYLATE .. AHMONIUM PERFLUOROALKYL CARBOXYLATE .. AHMONIUM PERFLUOROALKYL CARBOKYLATE .. AHMONIUM PERFLUOROALKYL CARBOKYLATE .. NONE 0.01 0.1 0.1 0.1 NONE mg/m3 mg/m3 mg/m3 mg/m3 NONE NONE TWA ACGIH Y TWA 3M Y TWA 3M Y TWA 3M Y Tee Titihutie 1 heovis Senge 7 Sra * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contr bution to the ove-a 1 exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ wth the substance. Vehicles can alter skn abscrption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Industrial Hygine Assoc. Workplace Environmental Exposure 3M: 3M Medical Department Guideline - NONE: None Established Level Guideline 8. HEALTH HAZARD DATA EYE CONTACT: Mild Eye Irritation: pain, and tearing. signs/symptoms can nclude redness, swel ing, SKIN CONTACT: Mild Skin IiiiLaLion (afLer /iolonged oi iamasrun ianthre:msaimeaeesrooonpsnd Senin signs/symptoms can include redness, swel lepe~L~d ing, and conLasL): itching. Ya beshes theo the skin an pacet In. the Edy fox am May be absorbed th~ol~gh the skin and persist in the body fo~ an extenced time. IN~ALATION: llness may occur a-ter a single overexposure by inhalation to relatively large quantities of this material. Robceriations WD = Now Determined MWA = tot Applicable Abreviations: N/D - No_ Determined N/A - Not Applicable 2277772211..00000044 33MM_MMNN0055443333555533 Mos: pi-1002 FLA) Brand Fluosochesionl Salt MSDS: FX-1002 FLUORAD(TM) Brand Fluorochemical Salt FEBRUARY 19, 1997 ?AGE: bot b Cemmwmwewn oN 8. HEALTH HAZARD DATA esmes (continued) Zesttation (weer cespieatory): stzae/aymptons can tnclude soreness rritation (upper -espiratory): signs/symptoms can include soreness Hay be aneorbed by snhaiaticn and persist in the body for an extences of the nose and th-oat, coughing and sneezing. Hay be absorbed by inhaiaticn and persist in the body tor an extenced Frotorged ox capeated avesesgosure, above zecomended Juldelinesy ay time. Prolonged or repeated overexposure, above recommended @uidelines, may cause: Liver Eefactes sians/eymprons can include yellow sxin(iaundice) Liver Effects: enero Se and tenderness siqns/symptoms can of upper abdomen. include yellow skin(jaundice) 1 swmesonso: IF SWALLOWED: ngestion is not a i keiy rcute ot exposure to this produc_. llness may resul_ -rom a single swallowng of a moderate quantity cf this material. ~he oral LDb0 ~or ammonium per~iuoroaiky carboxyiate is o40 milligrams per kilogram of body weigh_ in the albino rat. CANCER: WARNING: Contains a chemical which can cause cancer. (382a-26-1) 1903 ana 1953 eubias contucted JoincLy By Su ond Buber) 11983 and 1993 studies concucted join_ly by 3M and ~uPont). REPRODUCTIVE /ORVELOPAITAL ToKTNS: REPRODUCTIVE/DEVELOPMENTAL TOXINS: Not teratogenic in rabbits by oral adminstraticn. Not teratogenic to rats by gavage or inhalation exposllres. SECTION CHANGE DATES PRECAUT. INFO. SECTION CHANGED SINCE FEBRUARY 7, 1997ISSUE Robcoviationes WD = Now Daternired WA = lot Applicable Abreviations: N/D - No_ Determined N/A - Not Applicable Te TemoratTen To UNIS WCor al Safety Tats Shel (SDS) To Bellet Tobe ?he in-oimaLicn in Lhis MaLeiial SafeLy DaLa SheeL (HSDS) is believed Lo be correct as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BU~ NOT LIMITED ~O, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A ~ARTICNLAR PNRPOSE OR CONRSE O? PERFORMANCE OR NSAGE OF TRADE. User 1s responsible for deterninird Whether che SK product ie Tit for 3 User is responsible for determining whether _he 3M product is fit for a BArLicuaLs pigose anh Sui Labiv Gus ubwirs meLlod OF Law of apsiical on. Give paLicu ai pui~ose and suiLable lot ose2's lneLhod of LSe Oi apolicaLon. Given Ere uations of Facests That can 1kuct the, use and appLicacion of a M presets the varety of factors that can affect the use and application of a 3M product, some et la TriGnly elt hee haley a nny Be some o- which are uniquely within the user's knowledge and control, t is essential that the user eva 1late the 3M product to determine whether it is fit for a particular purpose and suitable for use-'s method of use or application. 3M provdes information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resul_ed in errors, ita' completerass of ascucacy. In addition, information obtained fom a database s~issions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, in-ormation obtained f~om a database may noL be as cuiien~ as Nle informaLion in _he MSDS available di~ecLly frc~l 3M. 2277772211.00000055 33MM_MMNN0055443333555544 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: women TI, FX-1OO5 FLUORAD(TM) Brand Fluorochemical ID NUMBER/U.P.C.: ZF-0002-05d4-1 - ZF-0002-0689-4 - ZF-OOO2-Oi8/-@ - FELL Su--actant ZF-0002-066@-8 - - ZF-0002-$726-4 - - 98-0211-b68/-6 @@-bl13b-10218-3 ISSUED: FEBRUARY 19, SUPERSEDES: FEBRUARY DOCUMENT: 1@-4251-2 19@7 7, 1997 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 7732-18-5 AMMONIUM PERFLUOROOC?ANOATE .......... 3825-26-- 26.0 - LOWER PERFLUOROALKYL CARBOXVLATE SAlT ............................... 2161s-47-4 1.@ - LOWER PERFLUOROALKYL CARBOXVLATE SAlT ............................... 6130-43-4 1.O - LOWER PERFLUOROALI~L CARBOXVLATE SAlT ............................... 6825@-11-0 0.1 - 2. PHYSICAL DATA 70.0 29.0 2.0 2.0 1.0 BOILING POINT: ............... ~00 C VAPOR PRESSURE: .............. 18 K~nHg Calc. @ 20 C VAPOR DENSITY: .............. 0.62 Air 1 Calc. @ 20 C EVAPORATION P~tTE: ............ N/A SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. ca. 1.2 Wate~ 1 TIE I PERCENT VOLATILE: ........... pH: ......................... (Bulk) 70 % 9.0-6.0 (2% Aqueous) VISCOSITY: .................. N/D MELTING POINT ................ N/A APPEARANCE AND ODOR: Light yellow liquid. 3. FIRE ~ EXPLOSION HAZARD DATA massson i et FLASH POINT: ................. None (Setaflash CC) FLAI41iABLE LIMITS - LEL: ..... N/A FLAI414ABLE LIMITS - UEL: ..... N/A Abreviations: N/D No_ Determined N/A Not Applicable 22777722JJ..00000011 Exhibit 2772J State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055443355551111 M08: Fi-1008 FLA) Brand Pluosochesioal Sureactant MSDS: FX-1005 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 19, 1997 ?AGE: Z ot b EE 3. FIRE AND EXPLOSION HAZARD DATA (continued) AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ?Dam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothinq, includinq helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, face mask, and protective covering for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section re- products of comus_ion. coat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERI~_LS TO AVOID: Not applicable. Eareor Monoeiae. ana Careon Dioxide, Ocides of Nitrogen, Arszegen HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hyd-ogen Fluoride, ~nmonia. 5. ENVIRONMENTAL INFORI4ATION SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled ma_eral. Clean up residue with water. Place in an approved metal container. Seal the container. RECOHHENDED DISPOSA!~: ncinerate in an industrial or commercia facility in the p~esence cf a coll@~ustible material. Combustion products will include HF. ENVIRONMENTAL DATA: Not determined. REGULATORY Volatile VOC Less INFORI431TION: Organic Compollnds: N/D. H20 & Sxempt Solvents: N/~. Eon linear. US)" uEnMaracWaasste haboeomre (Hot br Since regulations before disposal. vary, consult applicab e U.S. EPA Hazardous Waste regulations or Number None authorities (Not U.S. EPA Hazardo~ls). ~he com/onenLs of Lhs piocucL aie in compliance wiLh Lhe chemical registration requirements of: TSCA, EINECS, CDSL, AICS, MITI. EPCRA HAZARD CLASS: FIRE HAZARD: PRESSURE: No No I~EACTIVITY: No ACUTE: CHRONIC: Y~s Yes 22777722JJ..00000022 33MM_MMNN0055443365551122 FS MSDS: FX-1005 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 19, 1997 ?AGE: 3 ot b er -- pr SUGGESTED FIRST AID TLDity me wo. ve nro ee 0 si EYE CONTACT: nmediately flush eyes with large amounts of water. Get immedate medical attention. SKIN CONTACT: Flush skin with la-ge amounts of water, medical attention. f irritation persists, get IN~L~LATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac_. Wear appropriate gloves when handling ths material. A pair o- gloves made from the following material(sl are recoK~rlended: ~ltyl rllbber. Nse one o- more of the following personal protection tems as necessary to prevent skin con_act: apron, head covering, coveralls. Pro_ective garments (othe~ than HETiethrayngiiioeus tnhiaacises(Sparaomanir? i gloves) should be made of either of the following materials: polyethylene/polyvinylidene chloride (Saranex). VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf- cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or sp~ay. Avoid breathing of airborne material. Select cne of the fo lowing NIOSH approved respirators based on airborne concentraton of contaminants and in accorcance with OSHA regulations: full-face high-efficiency filter lespiraSoi, full-face supplied sit ~espiia~oi. PREVENTION OF ACCIDENT~_L INGESTION: Do not eat, trin or smoke when l~sing areas thoroughly with soap and water. befoie eaLing. ths procllct. Wash exposed Wash hands after nandl ng and RECOMHENDED STORAGE: Sto<e at temperatures above 32 degrees Y (0 deg<ees C). container closed when not in use. Keep FIRE AlqD EXPLOSION AVOIDANCE: Keep ccntainer tight y closed. Nonflammable. Abreviations: N/D No_ Determined N/A Not Applicable 22777722JJ..00000033 33MM_MMNN0055443355551133 OS -- MSDS: FX-1005 FLOORAD(TM) Brand Fluorochemical S~rfactant FEBRUARY 19, 1997 ?AGE: 4 ot b im sm 7. PRECAUTIONARY INFORMATION -- (continued) I EO Co oe pt, OTHER PRECAUTIONARY INFORI~ATION: No smoking: Smoking while using this p-oduct can result in contamination ot _he tobaccc and/or smoke and lead to the formation of the hazardous decomposition produc_s mentioned in section 4 of this HSDS. HMIS KAZARD RATINGS: HEALTH: 2 FL~dMAB LITY: C REACTIVITY: 0 PERSONAL PROTECTION: X (See p-ecautions, section INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* WATER ................................ NONE NONE NONE NONE AHMONIUM PERFLUOROOC=ANOATE .......... 0.01 mg/m3 TWA ACGIH Y LOWER PERFLUOROALKYL CARBOXYLATE SALT ............................... 0.1 mg/m3 TWA 3M Y LOWER PERFLUOROALKYL CARBOXYLATE SALT ............................... 0.1 mg/m3 TWA 3M Y LOWER PERFLUOROALKYL CARBOXYLATE EI SALT ............................... 0.1 mg/m3 TWA 3M Y * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contr bution to the ove~a 1 exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ wth the substance. Vehicles can alter skn abscrption. SOURCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Industrial Hygine Assoc. Workplace Environmental Exposure 3M: 3M Medical Department Guideline - NONE: None Established Level Guideline 8. HEALTH HAZARD DATA EYE CONTACT: Severe Eye Irrita_ion: signs/symptoms can include redness, swelling, pain, tearing, cloudy appearance of the cornea, impaired vision anc possible permanen ly impaired vision. SKIN CONTACT: Mild Skin Irritation (after prolonged or signs/symptoms can include redness, swel repeated ing, and contact): itching. May be absorbed through the skin and persist in the body fo~ an exterlc~d Lime. INHALATION: llness requiring medical attention may result from a single exposl:re Ambreviations: N/D - No_ Determined N/A - Not Applicable 22777722JJ..00000044 33MM_MMNN0055443355551144 MMSSDDSS:: FF-X1-01008055 FFLLUOOORRKADD((TTWM)) BBrraanndd FFlluuoorroocchheemmiiccaall SSuurrffaascttaanntt FEBRUARY 19, 1997 PAGE: bot b 8. Caw HEALTH mHAaZvARoD oA DATA G(ceonetminmueedd) by inhalation to moderate cuantities of this material. Zeritation (upser espiratory): sigus/symptoss can include soreness rritation (upoer -espiratory): signs!symptoms 51 the nose and thiout, SoLghing and sneezing. at the nose and th-oat, coughing and sneezing. can include soreness May be absorbed by inhalaticn and persist in the body time. Prolonged or repeated overexposure, above recommended Prolonged or repeated overexposure, above recommended cause: Liver Bffacte: signa/eymptons can include yellow Liver Effects: na Sardoress of upper sbdonen. and tenterness signs/symptoms can of upper abdomen. include yellow for an extenced Juidelines, guidelines, maymay skin(jaundice] skin(jaundice) IF SW;~LLOWED: ngestion is not a lkely route of exposure to this praduc_. Ihness say resslc frm a single saliouing of mderate quntity ct llness may resul_ -ram a single swallowng of a moderate quantity cf this material. CAI~CER: 1985 and1993 studies concucted $oincly by WM and Durant). WARNING: Contains a chemical which can cause cancer. (3820-26-1) 11983 and 1993 studies concucted join_ly by 3H and DuPont). SECTION CF~AI~GE DATES PRECAUT. INFO. SECTION CHA~GED SINCE FEBRUARY 7, 1997ISSUE Robreriationst WD = No: Deteraired WA = Not Applicatle Abreviations: N/D - No_ Determined N/A - Not Applicable To Tneormation Tn This FATerTaT Safety Tava Sheet GOS To bile oh The in-ormaticn in this Material Safety Data Sheet (HSDS) is believed to be Correct a6 of the date Lesued. IM HAKLS 10 TAKKAITLES, EAVESO)n INFLLEU, correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSS, OR IMPLIE~, INCLUDING, BUT NOT LIMITED ~O, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE O~ PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether _he 3M product is fit for a PAticUaE PuEpose and SULLabie fof userts method of Lee or pslication. Given particl~ ar pl~rNose and sl~itable for l~ser's method of l~se or aplicaton. Given the variety of factors that can affect the use and application of a 3M product, the var ety of factors that can affect the use and application of a 3M product, ome 07 WhiGh atu Unk ivLs within Ue UsvEs Aiouledgy aid ConLcol, St 5 soKle o- which a2@ uniqJely wiLhin Lhe use2's knowledge and conL~ol, L is esgential that the user evaluate the Hf product to determine whether it ie fit essential that the user eva uate the 3M product to determine v~hether it is fit for a particular purpose and suitable for user's method of use or application. 3M pray des information in electronic form as a service to its customers. Due axtaslons or aiterations'in this Information, 3 makes no representations 2s to Lo Lhe iemoLe ~ossibiliLy LhaL elecLionic Lzansfei moy have iesJl_ed in eriois, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, in-ormation obtained f~om a database may not be as current as the information in he MSDS available directly from 3M. 22777722JJ..00000055 I3MM_MMNN0055443355551155 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FC-1O-3 FLUORAD ID NUMBER/U.P.C.: WEE (TM) Fluorochemical Surfac_ant ZF-0002-0501-1 - ZF-0002-0597-7 - ISSUED: FEBRUARY 19, SUPERSEDES: FEBRUARY DOCUMENT: 07-1075-6 1997 7, 1997 ZF-0002-0573-0 I. INGREDIENT C.A.S. NO. PERCENT NA''ER ................................ AMMONIUM PERFLUOROOC?ANOATE .......... AMMONIUM PERFLUROHEKANOATE .......... AMMONIUM PERFLUROHEPTANOATE ......... AMMONINM PERFLNOROPENTANOATE ......... 7732-18-5 3825-26-2161o-47-4 6130-43-d 68259-11-0 0.1 0 0 2. PHYSICAL DATA 70.0 29.0 1.0 BOILING POINT: ............... i00 C EY VAPOR PRESSURE: .............. VAPOR DENSITY: .............. 18 ii~nHg calc @ 0.62 Air 20C 1 calc @ 20C EVAPORATION RATE: ............ < 1.0 Butyl Acetate 1 SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. =PERCENT VOLATILE: ........... Uh 1.16 Water i calc @ 20C 70 % by wt pH: ......................... 4.0-7.0 VISCOSITY: .................. < i0 CPS MELTING POINT ................ N/A APPEAP-ANCE AND ODOR: Clear, colorless to pa e liquid, slight ammonia odor 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: ................. 6etaflasn None (Setaflash CC) FLAMIW3%BLE LIMITS - LEL: ..... N/A FLA}4}4ABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self contained, Abreviations: N/D No_ Determined N/A Not Applicable 22777722KK..00000011 Exhibit 2772K State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055442233223388 FEMSDS: FC-I013 FLOORAD (TM) FEBRUARY 19, 1997 ?AGE: Z ---- Fl~orochemical Surfactant ot 6 3. FIRE AND EXPLOSION HAZARD DATA (continued) positive pressure or pressure demand b-eathing avparatus, bunker and pants, bands a-ound arms, waist and egs, face mask, and protective covering for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section re- products of comus_ion. coat 4. REACTIVITY DATA RE mm STABILITY: Stable INCOMPATIBILITY - MATERI~_LS TO AVOID: Not Applicable HAZARDOUS POLYMERIZATION: Will Not Occur HAZCaArRbDoOr,USMDonEoCwOiMdPeOSIaTnIdONCarPbRoODnUCDTiSo:xide, Mydeogen Fluoride, Carbon Monoxide and Carbon Dioxide, Hydrogen Fluoride, ~oxic vapors, gases or particulates may be procucts of decompcsition. AAmmmmoonniisa tnerma 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled ma_eral. Clean lip residlle with water. Place in an approved metal container. Seal the container. RECOHHENDED DISPOSA!~: ncinerate in an industrial or commercia facility in the p~esence cf a coll@~llstible material. Comhllstion prodl~cts will incll~de HF. ENVIRONMENT~L DATA: Bischenteas angen perand (EoEITs Wis Theseetieal Suysen Besar ~otal Organic Carbon (TOC): 64 g/kg; Chemical Oxygen Demand ICOD): 0.2 g/kg; 5-Day Biochemical Oxygen Demand (BUDS): Nil; 20-Day Biochemical Oxygen Demand (BOB20): Nil; Theoretical Oxygen Demand Tot ngrie Shs ses Bileshit sunEion (Lebris macoihirasts $10 i'l'hO~): 96 g/kg; 96-Hr LCSC, Fathead minnow (Fimephales promelas): >1000 mg/L; 96-H~ LC50, Bluegill sunfish (Lepcmis macrochirus): 970 mgiL; 48 Hr EC50 (Mobility), Water flea (Daphnia magna): >1000 mg/L; ~4-Day EC50 (cell dry weigkt), Green algae ISelenastrl~m capricornl~tllm): 120 m@!L; ~4-Day EC50 (cell collnt), Green algae (Selenastrum capricornutum): ~0 mg/L REGULATORY Volatile VOC Less INFORMATION: Organic Compounds: N/A. H20 & Exempt Solvents: N/A. Since iegulaLio~s before disposal. EPA Hazardous). vaiy, consulL applicab e U.S. EPA IIazardous Waste iegLlaLions o Number None auLhoiiLi~s (Not U.S. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSURE : No No P.EACTIVITY : No ACUTE : CHRONIC : Yes Yes Asbreviations: N/D - No Determimed N/A - Not Applicable 22777722KK..00000022 33MM_MMNN0055442233223399 re ms msn MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant FEBRUARY 19, 1997 ?AGE: 3 ot 6 mmm -- SUGGESTED FIRST AID THaT ee fe oro en EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a Dnysican. Wash ccntaminated clothing betore reuse and dispose ot son_amnatec shoes. IN~LALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWA!~LOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFOPd4ATION ome EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac . Wear appropriate gloves when handling ths EETor TbSnSE AR material. A pair o gloves made from the following material(sl are recoK~rlended: ~utyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace of either o- the following ma erals: polyethylene/polyvinvlidene chloride (Saranex) Coverall made of Tyvekir). Hear rubbe~ boots when cleaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: EE a Se ST Avoid bieaLhing o vapois, misLs oi sp~ay. Avoid bieaLhing of airborne material. Select cne of the fo lowing NIOSII a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA reglllations: full-face high-efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTA~ INGESTION: Do not eat, drinn or smoke when using a~eas thoroughly with soap and water. before eating. ths procuct. Wash exposed Wash h~ds afte~ handling ~d RECOMHENDED STORAGE: Do not store containers on their sides. Store at room temperature. Abreviations: N/D No_ Determined N/A Not Applicable 22777722KK..00000033 33MM_MMNN0055442233224400 reonon Pcsoctmion stn MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant FEBRUARY 19, 1997 ?AGE: 4 ot 6 T--T------------------------------ 7. PRECAUTIONARY INFORMATION (continued) Keep ccntainer closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Not applicable. Nontlammable. ee set OTHER PRECAUTIONARY INFOP!4ATION: No smoking: Smoking while using this p-oduct can result in contamination of _he tobaccc and/or smoke and lead to the formation ot the hazardous deconposition produc_s mentioned in section 4 ot this HSDS. INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* WATER ................................ ~IMONIUM PERFLUOROOC~ANOATE .......... A~IMONIUM PERFLUOROHEXANOATE .......... AHMONIUH PERFLUOROHEPTANOATE ......... A~IMONIUM PERFLUOROPENTANOATE ......... NONE 0.01 0.1 O.1 0.1 NONE mg/m3 mg/m3 mg/m3 mg/m3 NONE NONE TWA ACGIH Y TWA 3M Y TWA 3M Y TWA 3M Y aemavet betterso she. Soesa.1 supotureby Loe" stramects.sate * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contrbution to the ove-a 1 exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOU!qCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Indl~strial Hygienists - AIkA: American industrial Hygine Assoc. Workplace Environmental Exposure 3M: 3M Melical Department Guideline - NONE: None Established Level Guideline 8. HEALTH HAZARD DATA TREFAL inten an chi co, sins EYE CONTACT: Moderate Eye lrri_at on: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision. piles Arhivona No toxicity data for can be irritating to the the solution. Ammonum perfluoroalkanoates eye and may cal~se eye injl~ry from airborne exposure. ie Primdesitation iaftes prolonged of sepested contact) SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swel ing, and itching. May be absoibed Lh~ough Lhe skin and peisisL in Lhe body o~ an extenced time. No toxicity .data for the solution. Some ammonium perfl/loroalkanostes Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722KK..00000044 33MM_MMNN0055442233224411 soos:rootsraces (oy Pisorocheiont sucesctant MSDS: FC-I013 FLOORAD (TM) Fluorochemical Surfactant FEBRUARY 19, 1997 FAGE: bot 6 Cw me Te 8. HEALTH HAZARD DATA eed (continued) are slightly toxic when abscrbed through the skin. INHALATION: May be absorbed by inhaiaticn and persist in tke body tor an extenced time. No toxicity data for the solution. Some anmonium perfluoroalkanoates can be considered moderately toxic by inhalation on a single Sine cvecexSepvae srecuomcmaentsed esseiires, my swise: exposure; a median lethal ccncentration tor a 4-hour ex~osu-e in tke albino rat is 990 mi liqrams per cubic meter. Single overexposure, above recoK~nended guidelines, may sause: Irritation (upper respiratory): signs/symptoms can include screness ot _he nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended ~uidelines, may Liver Ettacts: signs/eywprons can include yeLiow skin(jaundice) cause: Liver Ettects: signs/symptoms can include yellow skin(jaundice) and tenJerness of upper abdomen. IF SW~-~LOWED: ngestion is not a lkely rcute of exposure to this produc_. Ho texiciey data for the solution. A mixture of amentus No toxicity Jata for the solution. A mixture of ammonium perflucroalkanoates was mocerately toxic in albino rats from a single ealAnporutes aout oral 050 (EW) 16.540 m0 porKp ofRody oral exposure; acute oral LD50 (rat) is 540 ms. per ks. of body weight. T1553 Sha 1953 stusser consuctes 3ounily ByI ana Bubontrs CANCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1 11983 and 1993 studies concucted join_ly by 3H and DuPont). MUTAGENICITY: A mixture of ammonium perfluorooctanoate, ammonium perflucroheptanoa_e, ammonium perfluoropentanoate and ammonium perflucrohexanoate was not mutagenic in nvitro ml~tagenicity assays. The mixtl~re ~id not cause cell transfo-mation Resmooucrve/pRvELOMEITAL ToNINE: a maK~rlalian cell _~ansformation assay. REPRODUCTIVE/DEVELOPMENT~ TOXINS: Be La or rTechie e 1hERIE on os A mixture of ammonium perfluorooctanoate, ammonium perfll~croheptanoa e, ammonillm perfl~oropentanoate and perflucrohexanoate was not teratogenic ~n rabbits ammonil~m by oi~l adminisL~aLion a~ld ~as noL Le~aLogenic Lo iaLs ~y garage ond inhalation exposures. SECTION CHANGE DATES PRECAUT. INFO. SECTION CHANGED SINCE FEBRUARY 7, 1997ISSUE Aobcortationss WD = No. Detwcaird WA = Nol Applicable A~b~eviaLio~ls: N/D - No DeLeimi~ ~d N/A - NoL Applicable 22777722KK..00000055 33MM_MMNN0055442233224422 A ---- MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant FEBRUARY 19, 1997 ?AGE: 6 ot 6 Asbreviations: N/D - No_ Determined N/A - Not Applicable l'he in ormaticn in this Material Safety ~ata Sheet (HS~S) is believed to be correct as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED ~0, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS Nser is p~rticu sit il ee Ln el the var A some o- FOR A FARTICULAR PURPOSE OR COURSE 07 PERFORMANCE OR USAGE OF TRADE. responsible for determining whether he 3M prodllct is fit for a ar purpose and suitable for user's method of use or ap~licat on. Given ety of factors that can affect the use and application of a 3M product, whick are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit for a particl~lar pl~rpose and suitable for ~se~'s method of l~se or application. 3M prov des information in electronic form as a service to its customers. Due Bom ns np ne, 2 to the remote Rossibility that electronic transfer may have resul_ed in errors, Rr mn Ma mA omissions or alterations in this information, 3M makes no representations as to its completeness or ascuracv. In addition, in-ormation obtained f~om a database m~y not be as current as the information in _he MS~S available directly frcm 3M. 22777722KK..00000066 33MM_MMNN0055442233224433 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FX-1OO3 FLUORAD(TM) Brand Fluorochemical Su--actant ID NUMBER/U.P.C.: ZF-0092-0122-6 - ISSUED: FEBRUARY 19, SUPERSEDES: FEBRUARY DOCUMENT: 10 4270 4 1997 7, 1997 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 7737-18-5 AivlMONiUM PERFLUROOCI'ANOATE .......... 3825-26- 43.0 - INERT PERFLUORO COMPOUNDS ............ Unknown < TRIDECAFLUOROHEPTANOIC ACID, ,~dMON UM SALT ...................... 6139-43-d 0.5 - AMMONINM NONAFLNOROPENTANOA~E ........ 68259-11-0 O.~ - 50.0 45.0 3.0 1.0 1.0 NOTE: lneiL Pei1uoio Compounds or use in the U.S. ~re noL on TSCA. NoL oi colnlns~cial sale 2. PHYSICAL DATA BOILING POINT: ............... ca. i00 C fae. azo VAPOR PRESSUP~E: .............. ~8 mmNg Calc. @ 20 C VAPOR DENSITY: .............. C.62 Air 1 Calc. @ 20 C EVAPORATION RATE: ............ < 1.0 Butyl Acetate 1 SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. ca. 1.3 Wate- 1 I PERCENT VOLATILE: ........... pH: ......................... hs(Bulk) 50 % 8.0-9.5 VIBCORITE: verre 0 VISCOSITY: .................. (0.5% N/D Aqueous) MELTING POINT ................ N/D APPEARANCE AND ODOR: Clear, colorless to pa e yellcw liquid, slight ammonia odor. S. FIRE AI4D EXPLOSION HAZARD DATA FLASH POINT: ................. Non-Vlammable FLAMMABLE LIMITS - LEL: ..... FLAMMABLE LIMITS - UEL: ..... Setaflasn N/A N/A Abreviations: N/D No_ Determined N/A Not Applicable 22777722LL..00000011 Exhibit 2772L State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055443344559933 M08: Fi-1003 FLA) Brand Pluosochesioal Sureactant MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: Z at 6 EE 3. FIRE AND EXPLOSION HAZARD DATA (continued) AUTOIGNITION TEMPERATURE: ... N/D EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ?Dam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothinq, includinq helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, face mask, and protective covering for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section re- products of camus_ion. coat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERI~_LS TO AVOID: Not applicable. Eareor Monoeiae. ana Careon Dioxide, Ocides of Nitrogen, Arszegen HAZARDOUS POLYMERIZATION: Will Not Occur HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides of Nitrogen, Hyd-ogen Fluoride, ~nmonia. 5. ENVIRONMENTAL INFORI4ATION SPILL RESPONSE: Observe precautions from other sections. Cover with absorbent material. Collec_ spilled material. Place in an approved metal container. RECOMMENDED DISPOS/~L: Discharge spent solutions and small quantities (less than 5 gal. (19 LI) to a wastewate~ treatment system. Reduce cischarge ra_e f foaming occurs. Incnerate in a permitted hazardous waste ncinerator in the presence of a cambllstble material. Combllstion products will include HF. ENVIRONMENT/~L DATA: Data are for product solics: Chemical Oxygen Demand (SOD): N1 mgiKg); 20-Day Biochemical Oxygen Demand (BAD2@): Nil; 98-H~. LC5@, naloimeafna6s3t2eumnaysapeLlosoonmymitSohn)e.7(5onmk/sidseyS0eeLvignn.irByESG0o,vaMniAcrgoetes System, Bluegill Sunfish (Lepomis macrochirus): 569 mg/L; 96-Hr. LC50, Fa~he~d Hinno~(Pimephales piomelas): 766 mgiL; 48-Hi ES50, Daphani~ magna: 632 mg/L; 14 Day EC5O (cell dry weight), Green Algae ISelenastrum capricornutum) 73 mg/L; 30-Min. ECS0, Microtox System, Photobacteril~m phosphorellm: >1,000 mg!L; OECD EC50: >I,0S0 mg/L. vosteen 1SuneEe wo. REGULATORY Volatile VOC Less INFORMATION: Organic Compounds: N/D. H20 & Exempt Solvents: N/D. ~his product is in compliance with the chemical registration iequir~llen~s of EINECS. Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722L1.00000022 33MM_MMNN0055443344559944 Ho 1000FRAO(0 Bean Poroshesiat Sustacant MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: 3 ot 6 mie Toman 5. ENVIRONMENTAL INFORMATION enemies (continued) EPCRA HAZARD CLASS: FIRE ~AZARD: PRESSURE: No No Cemmmerae 6. SUGGESTED FIRST AID I~EACTIVITY: No ACUTE: CERONIC: Yes Yes EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Flush skin with la-ge amounts of water, medical attention. f irritation persists, get Clonesspptece sonnei3 prysiean. IN}IALATION: t signs/s~nptoms occur, remove person to tresh air. It signs/symptoms continue, call a physician. TENIores 1concious, do venting mmasiatly as dicted IF SWA!~LOWED: f swallowed: If conscious, induce vomitng immediately as directec by mecical personnel. 7. PRECAUTIONARY INFOR/4ATION EYE PROTECTION: Avoid eye contact. ~he following Should be combination, as appropriate, to prevent eye goggles. worn alone or in contact: Wear vented etisL Pe32 Doves vase fron the.Followingmateriais} are SKIN PROTECTION: Avoid skin contac_. material. A pair o- Wear appropriate gloves made from gloves when handling ths the following material(sl are recoK~rlended: ~utyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: apron, head covering, coveralls. Pro_ective garments (othe~ than gloves) should be made of either of the following materials: polyethylene/polyvinvlidene chloride (Saranex). VENTILATION PROTECTION: Use with approoriate local exhaust venti ation. Use in a wel ventilated area. Provide sufficient ventilation to maintain enissicns below recomnendec exposllre limts. If exhal~st ventlation s not adequate, use appropriate respiratory prctection. RESPIRATORY PROTECTION: Avoid breathing of vapors, mists or sp~ay. Avoid breathing of airborne material. Select one of the fo lowing NTOSH a~proved respirators based on airborne concentrat on of contaminants and in accoicance wiLh OSHA iegulaLioils: full-face high-efficiency filler respirator, full face supplied air respirator. PREVENTION OF ACCIDENT~.L INGESTION: Do not eat, drin or smoke when using th s procuct. Wash exposed Ambreviations: N/D - No_ Determined N/A - Not Applicable 22777722LL..00000033 33MM_MMNN0055443344559955 a ------ MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: 4 at 6 EI 7. PRECAUTIONARY INFORMATION (continued) areas thoroughly with before eating. soap and water. Wash hands after nandlng and RECOMMENDED STORAGE: Store at temperatu-es above 32 deqrees F (O deqrees C). container closed when not in use. Keep FIRE AND EXPLOSION AVOIDANCE: Not applicable. Nontiammabie. Tor EisSTE ESE ee, OTHER PRECAUTION/~RY INFORI~ATION: No smoking: Smoking while using this p-oduct can result in contamination of _he tobaccc and/or smoke and lead to the formation at the hazardous deconposition produc_s mentioned in section 4 at this HSDS. HMIS KAZARD RATINGS: HEALTH: 2 FL~dMAB LITY: O REACTIVITY: 0 PERSONAL PROTECTION: X (See p~ecautions, section 7.1 INGREDIENTS EXPOSURE LIMITS VALUE I/NIT Pr WATER ................................ AHMONIUM PERFLUOROOC~ANOATE .......... NERT PERFLUORO COMPOUNDS ............ ~RIDECAFLUOROHEPTANO C ACID, A~MONINM SALT ...................... ~IMONIUM NONAFLUOROPENTANOA'IE ........ Re NONE 0.01 NONE NONE mg/m3 NONE 0.1 @.1 mg/m3 mg/m3 TYPE AUTH SKIN* BE NONE NONE TWA ACGIH Y NONE NONE TWA 3M Y TWA 3H Y * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contrbution to the ove~a 1 exposure by the cutaneous route incll~ding ml~co~s membrane and eye, either by airborne or, more particl~larly, by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOUIqCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Indl~strial Hygine Assoc. Workplace Environmental Exposl~re 3H: 3M Medical Oepartment Guideline - NONE: None Established Level Gl~ideline 8. HEALTH HAZARD DATA EYE CONTACT: De wi ia Severe Eye Irrita ion: signs/symptoms can incl~de redness, swelling, pain, tearing, cloudy appearance of the cornea, impaired vision anc possible peilnanen_ly impaired vision. Sen Trritation [after prolonged or repeated contact] SKIN CONTACT: Mild Skin Trritation (after ?rolonged or repeated contact): Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722LL...00000044 33MM_MMNN0055443344559966 soos: ree100sraces tn) mean Porochemicnt suctactant MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: bot 6 CemmemwewnoN 8. HEALTH HAZARD DATA eeemmes (continued) aina/symptons can snclude cednesss svedings and dishing. signs/symptoms can include redness, swel ing, and itching. May be absorbed th-ough the skin and persist in the body fo- an extenced time. INHALATION: llne~s requiring medical by inkalation to moderate attention may cuantities of result from a single this material. exposure May be absorbed by inhalaticn and persist in tke body for an extenced time. Single cvesexposuce, above zecommanted Guidelines, may Tiuse: Single overexposure, above recoK~nended guidelines, may sause: Sesitation (upper respiratory): signe/symptons can include Irritation (upper respiratory): signs/symptoms can include screness of _he nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended guidelines, may Liver Eefoctes signa/eymptons cn include yellow skin(jsundice) caus@: Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. Tienia not 3 Likely seute of sxposuze to this protic. IF SWALLOWED: ngestion is not a i kely rcute of exposure to this produc_. llness may resul_ -rom a single swallowng of a moderate quantity cf this material. CANCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1) ERS na 1553 Tustos sersucred JoimiLyby 0 sea Bub) 11983 and 1993 studies concucted join_ly by 3H and DuPont). RermoouCTIvE/DRvELOMITAL ToNIS: i} REPRODUCTIVE/DEVELOPMENTAL TOXINS: Not teratogenis in rabbits by oral admin straticn. Not teratogenic to rats by gavage or inhalation exposures. OTHER HEI~LTH HAZARD INFORI4ATION: A ?rocuct ''oxisity Sunmary Sheet is avai able. SECTION CHANGE DATES PRECAUT. INFO. SECTION CHAI~GED SINCE FEBRUARY 7, 1997ISSUE Asbreviations: N/D - No Determired N/A - Not Applicable 22777722LL..00000055 33MM_MMNN0055443344559977 soos: ree100sraces) mean Porochemicnt suctactant MSDS: FX-1003 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: 6 ot 6 SECTION CP~AI~GE DATES Robceriations: WD = Now beternired WA = ot Applicable Abreviations: N/~ - No_ Determined N/A - Not Applicable The in-ormaticn in this Material Safety Data Sheet (HSDS) is believed to be correct as of the date isslled. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, S~'I NOT LIMITED "0, ANY IMPLIE~ WARRANTY OF MERCHANTASiLi"Y OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE 07 PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether _he 3M product is fit for a particu ar purpose and suitable for user's method of use or apDlicaton. Given the varety of factors that can affect the use and application of a 3M prodllct, pudgrphelagdnrrgbeelhipfotrig ned vad some o whick are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit ON PAECiouiarpurposeand SuLtabRe TOF seectsmethodofute ofapplicetions for a particular purpose and suitable for user's method of use or application. provides information in electronic form se 3 service to ita customess. Gun 3M provdes information in electronic form as a service to its customers. Dl~e to the remote ~ossibility that electronic transfer may have resul_ed in errors, ai Tonmor teraions"in this Seosmatiosonress ne sebvecoensnstetao omissions oi alLeiaLions in Lhis inoimaLion, 3M makes no iepiesen~a~ions as Lo its completeness or accuracy. In addition, in-ormation obtained f~om a database A more SiSuceesentht tnfrastioTn% the HADS. svaiiselestrectly Fees She may not be as current as the information in _he MSDS available directly frcm 3M. 22777722LL..00000066 33MM_MMNN0055443344559988 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FX-1OO6 FLUORAD (TM) Brand Fluorcchemical Surfactant ID NUMBER/U.P.C.: ZF-0002-0827-0 - ISSUED: FEBRUARY 19, SUPERSEDES: FEBRUARY DOCUMENT: 07 3196 8 1997 7, 1997 I. INGREDIENT C.A.S. NO. PERCENT MATER ................................ 7737-18-5 ndvlHONiUM PERFLUROOCI'ANOATE .......... 3825-26- PERF~UORO COMPOUNDS ++ ............... Unknown AMMONIUM PERFLUOROHEKANOATE .......... 21610-47-4 0.1 - AMMONIUM PERFLUROHEPTANOATE ......... 6130-43-d 0.1 - AMMONINM PERFLNOROPENTANOATE ......... 68259-11-0 O - 70.0 28.0 1.0 1.0 1.0 0.- NOTE: + NOT ON TSCA. NOT FOR COKMERCIAL USE OR SALE IN THE U.S. 2. PHYSICAL DATA BOILING POINT: ............... VAPOR PRESSUP~E: .............. i00 C (Typica I ois 20 18 mmHq calc @ 2OC VAPOR DENSITY: .............. C.62 Air 1 calc @ 20C EVAPORATION RATE: ............ < 1.0 Butyl Acetate 1 SOLUBILITY IN WATER: ........ complete pm aL SP. GRAVITY: ................. 1.2 Water - PERCENT VOLATILE: ........... 70 % by wt pH: ......................... 6.0 8.0 VISCOSITY: .................. N/D MELTING POINT ................ N/A APPEARANCE AND ODOR: Clear, colorless to pa e liquid, sli@ht ammonia odor 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: ................. > 100 C Se_a- FLAH14-ABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... AUTOIGNITION TEMPERATURE: ... EXTINGUISHING MEDIA: N/A N/A Wa~ei, Caibon dioxide, Diy chemical, ~oam ash Abreviations: N/D No_ Determined N/A Not Applicable 22777722MM..00000011 Exhibit 2772M State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055442233779999 soos: ree1008paces (oy meant Plsrochemicnt suctactant MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical S~rfactant FEBRUARY 19, 1997 ?AGE: Z ot 6 EE 3. FIRE AND EXPLOSION HAZARD DATA (continued) SPECIA!~ FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, race mask, and protective coverinq for expcsed areas o- the head. UNUSUA~ FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo~ products of comus_ion. coat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS TO AVOID: None known. HAZARDOUS POLYMERIZATION: Will Not Occur HAZCCaAarRrbbDooOr.nUSM MDoonEnoCoxOxiMidPdeOeSIaaTnndIdONCCaarPrbbRooOnDnUCDDTiiSoo:xxiiddee,, OOxxiiddeess ooff Fluoride, ~nmonia. N Kiittrrooggeenn,, Hdpyddzrooggeenn 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled ma oral. Clean up residue with water. Place in an approved metal container. Seal the container. RECOMMENDED DISPOSAL: ncinerate in an indllstrial or commercia facility in the p~esence cf a coll@,ustible material. Combustion products will include HF. o3y= rls3/2 S0-0ay AosheBACAL cxpsen Denard (800EH] = MELE ENVIRONMENT/~L DATA: Chemical Oxygen Demand (COD) 0.0002 IThOD) 0.11 g!g; 20-Day Biochemical g/g; Theoretical Oxygen Oxygen Demand (BOD?0) Demand Nil; Fathead minnow (pimephales promelas) 96-hr LC50 >1000 mg!L; Water flea (Daphnia magnal 48-hr EC50 >1000 mgiL; Bluegill sunfish ILepomis macrosnirus) 96 hr LC50 967 mg/L; Green algae (Selenastrum capriccrnutum) 14-day EC50 (cell dry weight) 12d mg/L. REGULATORY VolaLile VOC Less INFORMATION: Oiganic Compounds: N/A. II20 & Exempt Solvents: N/A. Since regl~lations before disposal. EPA H~zaidous). vary, conslllt applicab e U.S. EPA Hazardous Waste regl~lations or Number None al~thorities (Not U.S. ~he ingredients of this product are in conpliance with EINECS. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSURE : No No P.EACTIVITY : No ACUTE : CHRONIC : Yes Yes Asbreviations: N/D - No Determimed N/A - Not Applicable 22777722MM..00000022 33MM_MMNN0055442233880000 ret m os rns st MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical S~rfactant FEBRUARY 19, 1997 ?AGE: 3 ot 6 mmm -- SUGGESTED FIRST AID THaT ee fe oro en EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a Dnysican. Wash ccntaminated clothing betore reuse and dispose ot son_amnatec shoes. IN~LALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWA!~LOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORI~ATION ome EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac . Wear appropriate gloves when handling ths material. A pair o gloves made from the following material(sl are recoK~rlended: ~utyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace of either o- the following ma erals: polyethylene/polyvinvlidene chloride (Saranex) Coverall made of Tyvekir). Hear rubbe~ boots when cleaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: EE a Se ST Avoid bieaLhing o vapois, misLs oi sp~ay. Avoid bieaLhing of airborne material. Select cne of the fo lowing NIOSII a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA reglllations: full-face high-efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTA~ INGESTION: Do not eat, drinn or smoke when using a~eas thoroughly with soap and water. before eating. ths procuct. Wash exposed Wash h~ds afte~ handling ~d RECOMHENDED STORAGE: Store at temperatures above 32 degrees F (0 degrees C). Keep Abreviations: N/D No_ Determined N/A Not Applicable 22777722MM..00000033 33MM_MMNN0055442233880011 ms pte ceo mo ein Pramas tact MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical S~rfactant FEBRUARY 19, 1997 ?AGE: 4 ot 6 T--T------------------------------ 7. PRECAUTIONARY INFORMATION (continued) container closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Not applicable. Nonflammable. OTHER PRECAUTIONARY INFOP!4ATION: No smoking: Smoking while using this p-oduct can result in contamination of _he tobaccc and/or smoke and lead to the formation ot the hazarSous deconposition produc_s mentioned in section 4 ot this HSDS. HMIS KAZARD RATINGS: HEALTH: 2 FL~dMAB LITY: 1 REACTIVITY: 0 PERSONAL PROTECTION: X (See p-ecautions, section 7.1 INGREDIENTS EXPOSURE LIMITS V2~LUE UNIT TYPE AUTH SKIN* WATER ................................ AHMONIUM PERFLUOROOC~ANOATE .......... PERFLUORO COMPOUNDS ............... ~IMONIUM PERFLUOROHEXANOATE .......... A~IMONIUM PERFLUOROHEPTANOATE ......... ~MONIUM PERFLSOROPENTANOATE ......... NONE 0.01 NONE 0.1 0.1 @.1 NONE mg/m3 NONE mg/m3 mg/m3 mg/m3 NONE NONE TWA ACGIH Y NONE NONE TWA 3M Y TWA 3M Y TWA 3M Y * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contrbution to the ove~a 1 exposure by the cutaneous route incll~ding ml~co~s membrane and eye, either by airborne or, more particl~larly, by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOUIqCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American 3H: 3M Melisal Indl~strial ~epartment Hygine Assoc. Guideline Workplace Environmental Exposl~re - NONE: None Established Level Gl~ideline 8. HEALTH HAZARD DATA EYE CONTACT: Moderate Eye Irri aton: signs/symptoms can inclllde redness, swelling, pain, tearing, and hazy vision. piper hereto obeieiepstoy sad No toxicity data for can be irritating to the the solution. Ammonum perfluoroalkanoates eye and may cause eye injury from airborne exposl~re. SKIN CONTACT: May be absorbed through the skin and persist in the body fo~ an extenced time. Abreviations: N/D - No_ Determined N/A - Not Applicable 22777722MM..00000044 33MM_MMNN0055442233880022 Ho 1008FREAD (0) Bend Pusrochemiest furtctant MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical Surfactant FEBRUARY 19, 1997 ?AGE: bot 6 Cw me Te 8. HEALTH HAZARD DATA eed (continued) No toxicity tata for the solution. Some ammonium perfluoroalkanoates are slightly toxic when abscrbed through the skin. IN~TION: May be absorbed by inhalaticn and persist in tke body for an extenced time. No toxicity data for the solution. Some anmonium perfluoroalkanoates can be considered moderately toxic by inhalation on a single exposure; a median lethal ccncentration for a 4-hour ex~osu-e in tke albino rat is 9@0 mi ligrams per cubic meter. Single overexposure, above recoK~nended guidelines, may sause: Irritation (upper respiratory): signs/symptoms can include screness of _he nose and throat, coughing and sneezing. IF SW~LOWED: ngestion is not a lkely rcute of exposure to this produc_. Fertinerontknaas mneaosntatteelsy Soulsinasbraitsrfeeon 3 single No toxicity data for the solution. A mixture of ammonium perflucroalkanoates was mocerately toxic in albino rats from a single oral exRosure; acute oral LD50 (rat) is 540 mg. Rer kg. of body weight. 1955 4nd 1953 Feuer contuckes 3ainily by oH ans Bubont WARNING: Contains a chemical which can cause cancer. (3023-261) CANCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1 11983 and 1993 studies concucted join_ly by 3M and DuPont). MUTAGENICITY: A mixture of ammonium perfluorooctanoate, ammonium perflucroheptanoa_e, ammonium perfluoropentanoate and ammonium perflucrohexanoate was not mutagenic in nvitro ml~tagenicity assays. The mixtl~re did not cause cell transfo-ma~ion RemmonEuVcELrOMIAIvEAeL Tove: a maK~rlalian cell _~ansformation assay. REPRODUCTIVE/DEVELOPMENT~ TOXINS: A mixture of ammonium perfluorooctanoate, ammonium ei Thi ae rot Seratoaentioe rats oy gavage ara perfll~croheptanoa e, ammonillm perfl~oropentanoate perflucrohexanoate was not teratogenic ~n rabbits by oral administration and was not teratogenic to and ammonil~m rats ~y gavage and inhalation exposures. SECTION CHANGE DATES PRECAUT. INFO. SECTION CHANGED SINCE VVSRUARY 7, ~997ISSUE Asbreviations: N/D - No Determimed N/A - Not Applicable 22777722MM..00000055 33MM_MMNN0055442233880033 soos: ree1008paces (oy meant Plsrochemicnt suctactant MSDS: FX-1006 FLUORAD (TM) Brand Fluorochemical S~rfactant FEBRUARY 19, 1997 ?AGE: 6 ot 6 SECTION C~AI~GE DATES Robceriations: WD = Now beternired WA = ot Applicable Abreviations: N/~ - No_ Determined N/A - Not Applicable The in-ormaticn in this Material Safety Data Sheet (HSDS) is believed to be correct as of the date isslled. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, S~'I NOT LIMITED "0, ANY IMPLIE~ WARRANTY OF MERCHANTASiLi"Y OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE 07 PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether _he 3M product is fit for a p~rticu ar purpose and suitable for user's method of use or apDlicaton. Given the varety of factors that can affect the use and application of a 3M prodllct, ome 3% whlch 47a amkiely ithin the user's Koowisdoe andcontrols Ct be oo some o whick are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit ON PAECiouiarpurposeand SuLtabRe TOF seectsmethodofute ofapplicetions for a particular purpose and suitable for user's method of use or application. provides information in electronic form se 3 service to ita customess. Gun 3M provdes information in electronic form as a service to its customers. Dl~e to the remote ~ossibility that electronic transfer may have resul_ed in errors, ai Tonmor teraions"in this Seosmatiosonress ne sebvecoensnstetao omissions oi ~lLeiaLions in Lhis inoimaLion, 3M makes no iepiesen~a~ions ~s Lo its completeness or accuracy. In addition, in-ormation obtained f~om a database A more SiSuceesentht tnfrastioTn% the HADS. svaiiselestrectly Fees She may not be as current as the information in _he MSDS available directly frcm 3M. 22777722MM..00000066 33MM_MMNN0055442233880044 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: oman nS A A SR FC-1094 FLUORAD(TM) Brand Fluorochemical Su--actant ID NUMBER/U.P.C.: 98-0211-6603-2 00-51135-10422-4 98-0211-660d-0 00-51135-10423-1 98-021--6685-7 00-51135-1042&-8 98-0211-8859-8 08-Sl135-10972-4 ISSUED: FEBRUARY 27, SUPERSEDES: FEBRUARY DOCUMENT: 05-6285-0 1997 19, 1997 I. INGREDIENT C.A.S. NO. PERCENT NA''ER ................................ 7732-18-5 AMMONIUM PERFLUROALKYL CARBOKYLATE .. 3825-26-- 1~.0 - AMMONIUM PERFLUOROALKYL CARBOKYLATE .. 6130-43-4 0.1 - AMMONIUM PERFLUOROALKYL CARBOXYLATE .. 2161o-47-4 0.1 - AMMONINM PERFLNOROALKYL CARBOXYLATE .. 68259-11-0 0.1 - NOTE: The i~lgr~dienLs o Lh s piocucL aie i~cluded on 7SCA. 2. PHYSICAL DATA faa Doi BOILING POINT: ............... ca. i00 C VAPOR PRESSURE: .............. ca. 18 mmHg ~ Calc. @ 20 C VAPOR DENSITY: .............. ca. 0.62 Air 1 Calc. @ 20 C EVAPORATION RATE: ............ < 1.0 Butyl Acetate Frans SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. ca. 1.1 Wate- 1 PERCENT VOLATILE: ........... 80 % pH: ......................... ca. 5 V viIsSoCoOsSaItTtY:: evens .................. nT (2.0% Aqueous) N/A MELTING POINT ................ N/A APPEAR~iqCE AND ODOR: Light colcred liquid; slight 1 cdor. 3. FIRE ~ EXPLOSION HAZARD DATA 8@.@ 21.0 1.0 1.0 1.0 FLASH POINT: ................. Setaflash None FLAMMABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam Abreviations: N/D No_ Determined N/A Not Applicable CA Approximately 22777722NN..00000011 Exhibit 2772N State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055441199447722 sesreiseraces) mean Porochemicnt suctactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 27, 1997 ?AGE: 2 ot 6 33. IEFIREaANDBST EXPLOSIONBHAAZNARDD NA DATA eons (continued) Tealeioe Posesuee 2% Bevtote Spas Sosshins. shpesstes: Binrer SPECIA!~ FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand b-eathing apparatus, bunker and pants, bands a-ound arms, waist and egs, race mask, and protective coverinq for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo~ products of comus_ion. T08tcoat 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIALS TO AVOID: Not Applicable HAZARDOUS POLYMERIZATION: Will Not Occur HAZCCaAarRrbbDooOr.nUSM MDoonEnoCoxOxiMidPdeOeSIaaTnndIdONCCaarPrbbRooOnDnUCDDTiiSoo:xxiiddee,, OOxxiiddeess ooff Fluoride, ~nmonia. N Kiittrrooggeenn,, Hdpyddzrooggeenn 5. ENVIRONMENTAL INFORMATION Phreical anheaLoh assests EespATatocy protections vemeiiacion, amd SPILL RESPONSE: Refer to other sections of this MSDS for physical and heal h hazards, respiratory information protection, regarding ventilaton, and personal protective equipment. In the U.S.A., call (612) 733-11@ or 1612) 733-6100 for 24-hour spill assistance. Ccntain sill. Cover with absorbent ma_eral. Ccllect spilled material. For spills to grollnd: Collect contaminated soil. Pllmp contaminated water from puddles or stagnant storm sewers. ?lace collected waste in approved containers, and seal. For spil s to ground or surface water: Notify appropriate authorities. Contact 3M to evaluate further needs. RECOMMENDED DISPOSAL: ncinerate in an industrial or commercia facility in the Fass contaminated water thecuh anion exchange cosine If a coll@~ustible material. Combustion products will include Pass ccntaminated water thrcllgh anion exchange resin. If contact 3M for assistance. p-esence cf necessary IIF. necessary, ENVIRONMENT/~L DATA: Tee Tee phen solder Craxical Qcygen Daman (C005 NEL (0.00070 Data fcr product solds: Chemical Oxygen Demanc (COD): Nil (0.00070 g/g); 20-Day Biochemcal Oxygen Demand (BOD2@): Nil; 96-Hr. LC50, Shins Sukeian (LaponisTabrochiEae)s 569 mastsSoe, Lise, Fiend Bluegill Sunfish (Lepomis macrochirus): 569 mg/L; 96-Hr. LC50, Fathead Minnow(Pimephales piomelas): 766 ln~!L; 48-Hi ECS0, Daphnia magna: 6~2 fib Star pi pp Ra mgiL; 14 Day EC50 (cell dry weight), G~een Algae (Selenastrum capriccrnutum) 73 mg/L. Soil Adsorption Coefficient (Koc): -7, ~ndicates very nigh mobility. (St/]dy used a sandy loam soill. Volatile REGULATORY Volatile Organic Compoundst INFORMATION: Organic Compounds: N N//A A.. Abreviations: N/D - No_ Determined N/A - Not Applicable CA - Approximately 22777722NN..00000022 33MM_MMNN0055441189447733 EU -------- MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 27, 1997 ?AGE: 3 ot 6 a 5. ENVIRONMENTAL INFORMATION (continued) -- SE ER VOC Less H20 & Exempt Solvents: N/A. Since regulations before disposal. vary, consult applicab e U.S. EPA Hazardous Waste EPA Hazardous). I regulations or Number None BE authorities (Not U.S. ~he components of ths procuct are in compliance with the chemical registration requi-ements of: TSCA, EINECS, CDSL, AICS, MITI. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSOIqE : No No I~EACTIVITY : No ACUTE : CHRONIC : Yes Yes SUGGESTED FIRST AID EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. ET SR RE IEI AE SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a ~nysic an. Wash ccntaminated clothing before reuse and dispose of son_amnatec shoes. I ST INHALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWALLOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin conLac_. Weai ap/iopiiaLe gloves when handling Lhs TIA Sr wn pry material. A pair o- gloves made from the follo~ing material(sl are recoK~rlended: utyl rubber. Use one o~ more of the following personal protection tems as necessary to prevent skin con act: head Ei ae aL covering, coveralls. Protective garments iother than glovesi should mot vite oF teTotloniog maces aber ' be mace of eiLhe~ o- Lhe following ma_eials: polyethylene/polyvinylidene chloride (Saranex) Coverall made of Tyvek(r). Hear- r/lbbe'- boots when cleaning up spills. Use with appropriate local exhaust ventiation. Provide sufficient VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf-cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is rot adeq/late, use appropriate respiratory Asbreviations: N/D - No Determired N/A - Not Applicable CA - Approximately 22777722NN..00000033 33MM_MMNON0055441199447744 Ho C1084FORA (D0 Bean Poroshesicat Surfactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 27, 1997 ?AGE: 4 at 6 Cr7. ePRmEaCAeUaTImOoNwARRYTIoNmFORRTMAITIoOnN nei (continued) protection. RESPIRATORY PROTECTION: Avoid breathing at vapors, mists or sp-av. Avoid breathing at airborne material. Select cne of the fo lowing NIOSH a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA regulations: full-face high-efficiency filter respirator, full-face supplied air respirator. r Do noteeat,t3eiaIOnF smoke WShean lUsi!ng tA his prosuE ct. WashR exposed PREVENTION OF ACCIDENT2~L INGESTION: Do not eat, drink or smoke when using areas thoroughly with soap and water. ths procuct. Wash exposed Wash hands after nandlng and before eating. RECOMHENDED STORAGE: Store at temperatu-es above 32 degrees F (O degrees C). container closed when not in use. Keep FIRE AI~D EXPLOSION AVOIDANCE: Not applicable. Nonflammable. OTHER PRECAUTIONARY INFOP!4ATION: ar orpotivionpresses mentionedthseston of No smoking: Smoking while using this p-oduct can result in contamination of _he tobaccc and/or smoke and lead to the formation of the hazardous decomposition produc_s mentioned in section 4 of this HSDS. HMIS KAZARD RATINGS: HEALTH: 2 FL~MAB LITY: @ REACTIVITY: 0 PERSONAL ?ROTECTION: X (See p~ecautions, section 7.) INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* WATER ................................ AHMONIUM PERFLUOROALKYL CARBOXYLATE .. AHMONIUM PERFLUOROALKYL CARBOKYLATE .. A~IMONINM PERFLNOROALKYL CARBOKYLATE .. AHHONIUH ?ERFLSOROALKYL CAR~OXYLA'I'E .. NONE 0. 01 0.1 0.1 0.1 NONE rag/m3 mg/m3 rag/m3 mg/m3 NONE NONE TWA ACGII[ Y TWA 3M Y TWA 3M Y TWA 3H Y me Sonit potion 16 he oveLaC3 aesureby Loe cutamects. route * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contrbution to the ove~a 1 exposure by the cutaneous route incll~ding ml~co~s membrane and eye, either by airborne or, more particl~larly, by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOUIqCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists : a eae Emaremmnta apomen - AIKA: American Indl~strial Hygine Assoc. Workplace Environmental Exposl~re 3M: 3M Medical Department Guideline ater how avtisie - NONE: None EsLablished Level Level Gusdenine Gl~ideline Robeaviationss WD = Nox Dotesnired WA = Mot Applicable Ch = Appreximately Abreviations: N/D - No_ Determined N/A - Not Applicable CA - Approximately 22777722NN..00000044, 33MIM_MMNNO0S5441199447755 Jaz: 7c-1084 ERO) Brand Fiuerochesicat Srfactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 27, 1997 ?AGE: bot 6 Cememmew en 8. HEALTH HAZARD DATA Sinaie explents my causes lo toxicity data for the solution. EYE CONTACT: No toxicity data for the solution. Single exposure may cause: Hcderate Eye Irritation: swelling, pain, tearing, signs!symptoms can and hazy vsion. include redness, SKIN CONTACT: Mild Skin Irritation (after prolonqed or Ciamaraotons Sun Inthude. sosmeses Sok:inee na Leonings signs/symptoms can include redness, swel repeated ing, and contact): itching. ay ba sbscstad hioush the kin 108 pssst i. the body for an May be absorbed th-ough the skin and persist in the body fo- an extenced time. No toxicity data for the solution. INHALATION: iiness requiring medical by inhalation to moderate attention may cuantities of result trom a single this material. exposure May be absorbed by inhalaticn and persist in the body for an extenced to tendetey aca for the solution, time. No toxicity data for the solution. Repeated inhalation exposure produced liver changes and elevated blood crganofllloride Fe camommeniet Guin teses wo esas Single overexposure, levels in rats. above recoK~nended guidelines, may cause: Sesitation (uppes cospleatory): signe/syeptons can include Irritation (upper respiratory): signs/symptoms can include frome cy Reg po Ll et egret screness of _he nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended @uidelines, may Lives Ettestes sigmereymptons oun inchute yeiiow shin(jmndioe) cause: Liver Effects: signs/symptoms can include yellow skin(jaundice) and tenderness of upper abdomen. IF SWALLOWED: "liners may sossis from single sealioeing of a mednrate quantity of ngestion is not a lkely rcute of exposure to this produc_. llness may resll -rom a single swallowng of a moderate ql~antity cf this material. No toxicity data for the solution. B5I6N3Ga:vCo1n9t5a3inSstecnhemciocnacluctuehdichJoc1ann-1ycaubsye 3canscnedr.b(3o825-261) CAIqCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1) 11983 ~nd 1993 sLudies concucLed j~in_ly by 3H ~nd DuPing). MUTAGENICITY: Anmonium perfl/loroalkyl c~rboxylate was not mutagenic in invitro Rebreviattonss Wh = No Deraraired WA ot Applicable = Apprexinaraly Asbreviations: N/D - No Determired N/A - Not Applicable CA - Approximately 22777722NN..00000055 33MM_MMNN00S5441199447766 Ho C1084FORA (D0Bean Poroshesicat Surfactant MSDS: FC-I094 FLUORAD(TM) Brand Fluorochemical Surfactant FEBRUARY 27, 1997 ?AGE: 6 ot 6 Cw me Te 8. HEALTH HAZARD DATA eed (continued) mutagenicity assays. Did not cause cell transformation in a manmalian cell transformntion assay. RaopuEVcE OImEvITeAL TorNS: REPRODUCTIVE/DEVELOPMENTAL TOXINS: Anmonium perfluoroalkvl csrboxylate was not teratoqenic in -abbits by Co MEdhiseeation and wis ot. tecakegenie to favsbY ghvagh apd oral administration and was not teratogenic to rats by gavage and inhalation exDosu-es. OTHER HE~-~TH HAZARD INFOI~ATION: Healtk hazard information is based on data for ammonium perflucroalkyl carboxylate solids. SECTION CHANGE DATES HEADING SECTION CHANGED SINCE FEBRNARY i~, 1997ISSUE Aobeeriationss WD - Now betesnired WA - Not Applicable Ch - Apprexinately Abreviations: N/D No_ Determined N/A Not Applicable CA Approximately l'he in ormaticn in this Material Safety ~ata Sheet (HS~S) is believed to be correct as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED ~O, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A ~ARTICULAR PURPOSE OR COURSE O~ PERFORMANCE OR USAGE OF TRADE. vor 13 TospafmofiiOrnmIiRierg uheRhee EMF pRoSit afistfotr 3 Nser is responsible for determining whether he 3M prodllct is fit for a particu ar purpose and suitable for user's method of use or ap~licat on. Given En eter, Eosiors Shas etn SEioe:che ove ond PAL ionoBk Fposo ers Lhe vaieLy o acLois LhaL can ~fec~ Lhe use and application o a 3M pioducL, some o- whick are uniquely within the user's knowledge and control, t is essential that the user eva uate the 3M product to determine whether it is fit EN Pare iouiar parapndSouistabele FOF aserts method ofuse of apELACIEION, for a particl~lar pl~rpose and suitable for ~se~'s method of l~se or application. 3 proven Sufocmativn tn vlectonic fom ex 4 swevicy Lo Ix Customer, Sue 3M p~ovdes inoimaLion in elecLionic oiln as a seivic~ Lo iLs cusLomeis. Due to the remote possibility that electronic transfer may have resul_ed in errors, oimuionsor siterarions Ln thi. Informations Sh maker meseprasentatiseo.n1e3 omissions or alterations in this information, 3M makes no representations as to its completeress or ascuracv. Tn addition, in-ormation obtained f~om a database may not be as current as the information in _he MSDS available directly frcm 3M. 22777722NN..00000066 33MM_MMNN0055441189447777 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FC-1O-3 FLUORAD ID NUMBER/U.P.C.: WEE (TM) Fluorochemical Surfac_ant ZF-0002-0501-1 - ZF-0002-0597-7 - ISSUED: MARCK 4, 1997 SUPERSEDES: FEBRUARY 19, DOCUMENT: 07-1075-6 1997 ZF-0002-0573-0 I. INGREDIENT C.A.S. NO. PERCENT NA''ER ................................ AMMONIUM PERFLUOROOC?ANOATE .......... AMMONIUM PERFLUROHEKANOATE .......... AMMONIUM PERFLUROHEPTANOATE ......... AMMONINM PERFLNOROPENTANOATE ......... 7732-18-5 3825-26-2161o-47-4 6130-43-d 68259-11-0 0.1 0 0 2. PHYSICAL DATA 70.0 29.0 1.0 BOILING POINT: ............... i00 C EY VAPOR PRESSURE: .............. VAPOR DENSITY: .............. 18 ii~nHg calc @ 0.62 Air 20C 1 calc @ 20C EVAPORATION RATE: ............ < 1.0 Butyl Acetate 1 SOLUBILITY IN WATER: ........ complete SP. GRAVITY: ................. =PERCENT VOLATILE: ........... Uh 1.16 Water i calc @ 20C 70 % by wt pH: ......................... 4.0-7.0 VISCOSITY: .................. < i0 CPS MELTING POINT ................ N/A APPEAP-ANCE AND ODOR: Clear, colorless to pa e liquid, slight ammonia odor 3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT: ................. 6etaflasn None (Setaflash CC) FLAMIW3%BLE LIMITS - LEL: ..... N/A FLA}4}4ABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self contained, Abreviations: N/D No_ Determined N/A Not Applicable CA Approximately 2277772200..00000011 Exhibit 2772O State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0504524322342444. ER MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant MARCH 4, 1997 ~AGE: 2 ot 6 3. FIRE AND EXPLOSION HAZARD DATA (continued) positive pressure or pressure demand b-eathing avparatus, bunker and pants, bands a-ound arms, waist and egs, face mask, and protective covering for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section fo- products of comus_ion. coat 4. REACTIVITY DATA we STABILITY: Stable INCOMPATIBILITY - MATERIA!~S TO AVOID: Not Applicable HAZARDOUS POLYMERIZATION: Will Not Occur HAZ"CAaRrbDoOrU.SMDonEoCxOiMdPeOSIaTnIdONCarPbRoODnUCDTiSo:xide, Hydrogen Fluoride, Carbon Monoxide and Carbon Dioxide, Hydrogen Fluoride, ~oxic vapors, gases or particulates may be procucts of decompcsition. AAmmmmoonniiaa tnerma 5. ENVIRONMENTAL INFORMATION SPILL RESPONSE: Observe precautions from other sections. Ventilate area. Contain spill. Cover with absorbent material. Collect spilled ma_eral. Clean lip residlle with water. Place in an approved metal container. Seal the container. RECOHHENDED DISPOSA!~: ncinerate in an industrial or commercia facility in the p~esence cf a coll@~llstible material. Comhllstion prodl~cts will incll~de HF. ENVIRONMENT~L DATA: TIBIEI yrs cots on, os ~otal Organic Carbon (TOC): 64 g/kg; Chemical Oxygen Demand ICOD): 0.2 g/kg; 5-Day Biochemical Oxygen Demand (BUDS): Nil; 20-Day Sram e Se a ee Biochemical Oxygen Demand (BOB20): Nil; Theoretical Oxygen Demand Ee pear Toei i'l'hO~): 96 g/kg; 96-Hr LCSC, Fathead minnow (Fimephales promelas): >1000 mg/L; 96-H~ LC50, Bluegill sunfish (Lepcmis macrochirus): 970 mgiL; 48 Hr EC50 (Mobility), Water flea (Daphnia magna): >1000 mg/L; ~4-Day EC50 (cell dry weigkt), Green algae ISelenastrl~m capricornl~tllm): 120 m@!L; ~4-Day EC50 (cell collnt), Green algae (Selenastrum capricornutum): ~0 mg/L REGULATORY Volatile VOC Less INFORMATION: Organic Compounds: N/A. H20 & Exempt Solvents: N/A. Since iegulaLio~s before disposal. EPA Hazardous). vaiy, consulL applicab e U.S. EPA IIazardous Waste iegLlaLions o Number None auLhoiiLi~s (Not U.S. EPCRA HAZARD CLASS: FIRE HAZARD : PRESSURE : No No P.EACTIVITY : No ACUTE : CHRONIC : Yes Yes Asbreviations: N/D - No Determimed N/A - Not Applicable CA - Approximately 2277772200..00000022 33MM_MMNN0055442233224455 re mm sn MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant MARCH 4, 1997 ~AGE: 3 ot 6 mmm -- SUGGESTED FIRST AID THaT ee fe oro en EYE CONTACT: nmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: nmediately wash skin with soap and la-ge amounts of water. Renove contaminated clothing. If signs/symptoms occur, call a Dnysican. Wash ccntaminated clothing betore reuse and dispose ot son_amnatec shoes. IN~LALATION: f signs/s~nptoms occur, remove person to fresh air. If signs/symptoms continue, call a physician. IF SWA!~LOWED: Do not induce vomiting. Drink two glasses of water. Call a physician. 7. PRECAUTIONARY INFORMATION ome EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac . Wear appropriate gloves when handling ths EETor TbSnSE AR material. A pair o gloves made from the following material(sl are recoK~rlended: ~utyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace of either o- the following ma erals: polyethylene/polyvinvlidene chloride (Saranex) Coverall made of Tyvekir). Hear rubbe~ boots when cleaning up spills. VENTILATION PROTECTION: Use with appropriate local exhaust venti ation. Provide suf cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: EE a Se ST Avoid bieaLhing o vapois, misLs oi sp~ay. Avoid bieaLhing of airborne material. Select cne of the fo lowing NIOSII a~proved respirators based on airborne concentraton of contaminants and in accorcance with OSHA reglllations: full-face high-efficiency filter respirator, full-face supplied air respirator. PREVENTION OF ACCIDENTA~ INGESTION: Do not eat, drinn or smoke when using a~eas thoroughly with soap and water. before eating. ths procuct. Wash exposed Wash h~ds afte~ handling ~d RECOMHENDED STORAGE: Do not store containers on their sides. Store at room temperature. Abreviations: N/D No_ Determined N/A Not Applicable CA Approximately 2277772200..00000033 33MM_MMNN0055442233224466 os,Ptsmm on croton ssn MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant MARCH 4, 1997 ~AGE: 4 ot 6 T--T------------------------------ 7. PRECAUTIONARY INFORMATION (continued) Keep ccntainer closed when not in use. FIRE AND EXPLOSION AVOIDANCE: Not applicable. Nontlammable. ee set OTHER PRECAUTIONARY INFOP!4ATION: No smoking: Smoking while using this p-oduct can result in contamination of _he tobaccc and/or smoke and lead to the formation ot the hazardous deconposition produc_s mentioned in section 4 ot this HSDS. INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* WATER ................................ NONE NONE NONE NONE ~IMONIUM PERFLUOROOC~ANOATE .......... 0.01 mg/m3 TWA ACGIH Y A~IMONIUM PERFLUOROHEXANOATE .......... 0.1 mg/m3 TWA 3M Y AHMONIUH PERFLUOROHEPTANOATE ......... O.1 mg/m3 TWA 3M Y A~IMONIUM PERFLUOROPENTANOATE ......... 0.1 mg/m3 * SKIN NOTATION: ~isted substances indicated with "Y" the pctential contrbution to the ove-a 1 exposure by TWA 3M Y IRR under SKIN refer to the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ w th the substance. Vehicles can alter sk n abscrption. SOU!qCE OF EXPOSURE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Indl~strial Hygienists - AIkA: American industrial Hygine Assoc. Workplace Environmental Exposure 3M: 3M Melical Department Guideline - NONE: None Established Level Guideline 8. HEALTH HAZARD DATA TREFAL inten an chi co, sins EYE CONTACT: Moderate Eye lrri_at on: signs/symptoms can include redness, swelling, pain, tearing, and hazy vision. piles Arhivona No toxicity data for can be irritating to the the solution. Ammonum perfluoroalkanoates eye and may cal~se eye injl~ry from airborne exposure. ie Primdesitation iaftes prolonged of sepested contact) SKIN CONTACT: Mild Skin Irritation (after prolonged or repeated contact): signs/symptoms can include redness, swel ing, and itching. May be absoibed Lh~ough Lhe skin and peisisL in Lhe body o~ an extenced time. No toxicity .data for the solution. Some ammonium perfl/loroalkanostes A~breviations: N/D - No_ Determined N/A - Not Applicable CA - Approximately 2277772200..00000044 33MM_MMNN0055442233224477 sos: re-totspaces (on) Pisorocheiont sucesctant MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant MARCH 4, 1997 ~AGE: bot 6 Cw me Te 8. HEALTH HAZARD DATA eed (continued) are slightly toxic when abscrbed through the skin. INHALATION: May be absorbed by inhalaticn and persist in the body tor an extenced time. No toxicity data for the solution. Some anmonium perfluoroalkanoates can be considered moderately toxic by inhalation on a single Sine cvecexSepvae srecuomcmaentsed esseiires, my swise: exposure; a median lethal ccncentration tor a 4-hour ex~osu-e in tke albino rat is 990 mi liqrams per cubic meter. Single overexposure, above recoK~nended guidelines, may sause: Irritation (upper respiratory): signs/symptoms can include screness ot _he nose and throat, coughing and sneezing. Prolonged or repeated overexposure, above recommended ~uidelines, may Liver Ettacts: signs/eywprons can include yeLiow skin(jaundice) cause: Liver Ettects: signs/symptoms can include yellow skin(jaundice) and tenJerness of upper abdomen. IF SW~-~LOWED: ngestion is not a lkely rcute of exposure to this produc_. Ho texiciey data for the solution. A mixture of amentus No toxicity Jata for the solution. A mixture of ammonium perflucroalkanoates was mocerately toxic in albino rats from a single ealAnporutes aout oral 050 (EW) 16.540 m0 porKp ofRody oral exposure; acute oral LD50 (rat) is 540 mg. per kg. of body weight. T1553 Sha 1953 stusser consuctes 3ounily ByI ana Bubontrs CANCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1 11983 and 1993 studies concucted join_ly by 3H and DuPont). MUTAGENICITY: A mixture of ammonium perfluorooctanoate, ammonium perflucroheptanoa_e, ammonium perfluoropentanoate and ammonium perflucrohexanoate was not mutagenic in nvitro mlltagenicity assays. The mixtllre ~id not cause cell transfo-mation Resmooucrve/pRvELOMEITAL ToNINE: a maK~rlalian cell _~ansformation assay. REPRODUCTIVE/DEVELOPMENT~ TOXINS: Be La or rTechie e 1hERIE on os A mixture of ammonium perfluorooctanoate, ammonium perfll~croheptanoa e, ammonillm perfl~oropentanoate and perflucrohexanoate was not teratogenic ~n rabbits ammonil~m by oi~l adminisL~aLion a~ld ~as noL Le~aLogenic Lo iaLs ~y garage ond inhalation exposures. SECTION CHANGE DATES HEADING SECTION CHANGED SINCE FEBRUARY 1~, 1997ISSUE Aobcortationss WD = No. Dutwrmited WA = Nob Applicable CA = Approximately A~b~eviaLio~ls: N/D - No DeLeimi~ ~d N/A - NoL Applicable CA - Appioxim~Lely 2277772200..00000055 33MM_MMNN0055442233224488 uo, e-i0n2yKeRD (0 ivorochemient Srtactant MSDS: FC-I013 FLOORAD (TM) Fl~orochemical Surfactant MARCH 4, 1997 ~AGE: @ ot 6 Aobeeriationss WD = Nox Deternired WA = Mot Applicatle CA = Approximately Asbreviations: N/D - No_ Determined N/A - Not Applicable CA - Approximately The TroreatIen Tn TS TATerIaT SeEety Doth Sheet TRIS) T3 Belle tobe l'he in ormaticn in this Material Safety ~ata Sheet (HS~S) is believed to be correct as of the date issued. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED ~0, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A ~ARTICULAR PURPOSE OR COURSE 07 PERFORMANCE OR USAGE OF TRADE. Nser is responsible for determining whether he 3M prodllct is fit for a p~rticu ar purpose and suitable for user's method of use or ap~licat on. Given Ehreof nfact,ors tharcan Ledactthe uot ndappHLoCf 3aMRW pLrosoucnts the var ety of factors that can affect the use and application of a 3M product, some o- whick are uniquely within the user's knowledge and control, t is Srintial that tne weessTaLustathe'31 produeh determinewhether Ltie. f1t essential that the user eva uate the 3M product to determine whether it is fit for a particl~lar pl~rpose and suitable for ~se~'s method of l~se or application. a provides tnformation 1n exectzonte fom as a sepvice to tts custosecs. tue 3M prov des information in electronic form as a service to its customers. Due to the remote Rossibility that electronic transfer may have resul_ed in errors, Caierionsor sieurations In this information SW natednoEeprasentatiseo.n1s5 omissions or alterations in this information, 3M makes no representations as to EES Corletertna of accuracy. in asiition, Lntermation spesined fon a database its completeness or ascuracv. In addition, in-ormation obtained f~om a database Ray nox be 56 current a5 She. sndommation 1% She HAUS avaiiaple rectly FEck Sh may not be as current as the information in _he MS~S available directly frcm 3M. 2277772200..00000066 33MIM_MMNN0055442233224499 MATERIAL SAFETY DATA SHEET Sopyright, 19~7, Minneso_a Mining and Manufacturing Company. Aii rights reserved. Copying and/cr downloading o~ tkis information ~or the purpose of properly uti izing 3M proJucts is allowed provided that: 1) _he information is copied in full with no changes unless prior agreement is obtained from 3M, and 2) neither the copy nor the original is resold or otkerwise distributed with _he intention o~ earning a profit thereon. DIVISION: SPECIALTY SHEMICALS DIVISION TRADE NAME: FC-126 FLUORAB Brand Fluorochemical Surfac_ant atiomy onmstisseozitcot Shosiiiosont=s G0meii3se10beses ID NUMBER/U.P.C.: ZF-0092-03ST-6 98-021--1~40-7 - ZF-0002-1102-7 00-51135-0221&-6 98-0211-8624-8 00-51135-10463-9 9~-021--/393-S 00-bl13b-l@!61-4 ISSUED: MARCH 17, 1997 SUPERSEDES: AUGUST 23, 1996 DOCUMENT: 10-3804-i I. INGREDIENT C.A.S. NO. PERCENT AMMONIUM PERFLUOROOC~ANOATE .......... 3825-26-- 80.0 - AMMONIUM PERFLUGROHEKANOATE .......... 21610-47-4 6.0 - AMMONIUM PERFLUROHEPTANOATE ......... 6139-43-d 1.0 - AHMONINM PERFLNOROPENTANOATE ......... 68259-11-0 1.@ - 2. PHYSICAL DATA 90.0 12.0 5.0 5.0 BOILING POINT: ............... VAPOR PRESSURE: .............. VAPOR DENSITY: .............. EVAPORATION PJiTE: ............ SOLUBILITY IN WATER: ........ N/A N/A N/A N/A apprec. SP. GRAVITY: ................. ca. 0.5 Wate~ 1 pePERCENT VOLATILE: ........... pH: ......................... (Bulk) N/A 4 (2% Aq~eo~ls) VISCOSITY: .................. N/A MELTING POINT ................ N/D APPEAP~ANCE ~!qD ODOR: Light colcred powder; slight cdor. 3. FIRE ~ EXPLOSION HAZARD DATA FLASH POINT: ................. Nonflammable FLAMMABLE LIMITS - LEL: ..... N/A FLAMMABLE LIMITS - UEL: ..... N/A AUTOIGNITION TEMPERATURE: ... N/A EXTINGUISHING MEDIA: Water, Carbon dioxide, Dry chemical, ~oam SPECIAL FIRE FIGHTING PROCEDURES: Wear full protective clothing, including helmet, self-contained, posiSive piessune oi piessuie demand b-eaShi~lg a/paia5us, bunkei coa5 Abreviations: N/D No_ Determined N/A Not Applicable CA Approximately 22777722PP..00000011 Exhibit 2772P State of Minnesota v. 3M Co., Court File No. 27-CV-10-28862 33MM_MMNN0055442299440088 MSDS: FC-126 FLOOP~AD Brand Fl~orochemical Surfactant MARCH 17, 1997 ~AGE: 2 at 6 3. FIRE AND EXPLOSION HAZARD DATA (continued) and pants, bands a-ound arms, waist and egs, face mask, and protective covering for expcsed areas o- the head. UNUSUAL FIRE AND EXPLOSION HAZARDS: See Hazardous Decomposition section to- products at campus_ion. 4. REACTIVITY DATA STABILITY: Stable INCOMPATIBILITY - MATERIA!~S TO AVOID: CE Not Applicable HAZARDOUS POLYMERIZATION: Will Not Occllr HAZARDOUS DECOMPOSITION PRODUCTS: Carbon Monoxide and Carbon Dioxide, Oxides Fluoride, ~nmania. of Nitrogen, Hyd-ogen 5. ENVIRONMENTAL INFORMATION SE ETT e SPILL RESPONSE: Observe precautions from other sections. Collect spilled material. Use wet sweeping compound or water to avoid dusting. Clean up residue with water. Place in a closed container. RECOMMENDED DISPOSAL: Large quantities may adversely affect biological wastewater treatment systems. Do not use in products or processes that could resu t in aquatic concentra_ions greater than 1/10 of the lowest ECo0 or LC5O concentration. Incinerate large quan_ites in an industrial or commercial incinerator. Comhllstion prodl~cts will incll~de HF. Do nct dispose of in a sanitary landfill. ,isposal alternative: Dispose cf waste product in a -acility permitted to accept chemical waste. ENVIRONHENTAL DATA: 3M COHPOSED HAZARD ASSESSKENT ENVIRONMENTAL FATE AND EFFECTS: ~his substance did not degrade significantly in a ready biodegradation test. This compol~nd is completely fll~orina ed iperfluorinated), or it contains perfluorinatec portions. Peifl~cioalkyl g~oups iesi~ degiada~ion in mo~ na~uial environments. ~his sllhstance has mnimal toxicity to aql~atic crganisms DL tn dps co 0 Lowest LC50, EC50, or IC5@ < or l~0O mg/L). (100 ngiL < ~his substance has insignificant toxicity to wastewater treatment I TT SH AT ee system organisms (sludge respiration IC50 > 100O mg/L). ~his substance has not been found to bioconcentrate or accumu ate significantly in one oi more living oiganisms. Abreviations: N/D - No_ Determined N/A - Not Applicable CA - Approximately 22777722PP..00000022 33MM_MMNN0055442299440099 MSDS: FC-126 FLOOI~AD Brand Fl~orochemical Surfactant MARCH 17, 1997 ~AQE: ~ t 6 Csmona 5. ENVIRONMENTAL TIwNFoORRMAATTIIONN Gentes (continued) SUPPORTING DATA Biodegradation: Theoretical Oxyqen Demand (ThOD): 0.320 Chemical Oxygen Demand (COD): 0.0008 gig 20-Day Biochemical Oxygen Deman~ (BOD201: 0.0007 g/g Aquatic toxicity: ratreos minox (reepralespromelae sone ios 300 sa Fatkead minnow (Pimephales promelas) 96-hr LCS0: 300 mg/L Water flea (Daphnia magna) 96-hr LC50: 220 mg/L Green +13 (Selunaserim apeisocrusuni sehe 650: 51000 m/L Green algae (Selenastrum capricornu_um) 96-hr EC50: >1800 Hicecton{ta) (Potosacterion rosporesn: Sommin EC: 10 mafk Hicrctox(tm) (Photobacterium phosporeuml 30-min ECb0: 8/0 mgiL mgiL Wastewater treatment (OECD Kethod 202): Activated Sludge Respiration Inhibi_ion 3-hr EC50: >IS00 mg/L Bioconcentration: Fatkead minnow (BCF): 1.8 (Pimephales promelas) 3-2-hr. Bioconcentration Factor REGULATORY Volatile VOC Less INFORMATION: Organic Compounds: N/A. H20 & Exempt Solvents: N/A. Since regulations before disposal. EPA Hazardous). vary, consult applicab e U.S. EPA Hazardous Waste regulations or Number None authorities (Not U.S. ~he components C~SL, AICS and of ths HiTi. procllct are in compliance with ~SCA, E NECS, FIRE ~AZARD: No PRESSURE: No REACTIVITY: No ACUTE: CHRONIC: Yes Yes SUGGESTED FIRST AID EYE CONTACT: mmediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Te voretery flu shin ul lucge amouns of wate Remorse mmediaLely 1ush skn will: laige alnounLs of waLei. eS othr before tonsa. TTStSTer COIL 8 physician. wash contaminated clothing. If irritation persists, call contaminated clothing before reuse. Remove a physician. Wash ionaimpioteSines Sa prpriatan, 4 1 IN~L~LATION: f signs/sympLolns occui, iemove peison Lo fiesh aii. If signs/symptoms continue, call a physician. Aobceriationss WD - Nox Detesnirad WA - lot Applicable CA - Approximately Abreviations: N/D No_ Determined N/A Not Applicable CA Approximately 22777722PP..00000033 33MM_MMNN0055442289441100 MSDS: FC-126 FLOORAD Brand Fl~orochemical Surfactant MARCH 17, 1997 ~AGE: 4 at 6 Coswe 6. SUGGESTED pmFIRST aAImD Getwed (continued) IF DDS5oWAnn!oo~ttLOiWinEndDd:uuccee vvoommiittiinngg.. D Drriinnkk ttwwoo ggllaasssseess ooff wwaatteerr.. CCaallll aa pphhyyssiicciiaann. 7. PRECAUTIONARY INFORPLkTION EYE PROTECTION: Avoid eye contact. Wear vented goggles. SKIN PROTECTION: Avoid skin contac_. Wear appropriate gloves when handling th s material. A pair o- gloves made from the following material(sl are recoK~rlended: sutyl rubber. Use one o- more of the following personal protection tems as necessary to prevent skin con_act: head covering, coveralls. Protective garments iother than glovesi should be mace at either o the tallowing ma_erals: polyethylene/polyvinylidene chloride (Saranex). VENTILATION PROTECTION: Ha LE ee epoptiss TespiEhory Use with appropriate local exhaust venti ation. Provide suf-cient ventilation to maintain emissions below recommended exposure imits. f exhaust ventilation is nct adequate, use appropriate respiratory protection. RESPIRATORY PROTECTION: Avoid breathing of a rborne material. Select one of the following NIOSH approved respirators based on ai-borne concentration ocontaminants and in accordance with OSHA regulations: full--ace highefficiency filter -espirator, full-face supplied air respirator. PREVENTION OF ACCIDENTAL INGESTION: Do not eat, drin or smoke when using th s procuct. Wash exposed areas thoroughly with soap and water. Wash hands after nandlng and before eating. RECOMMENDED STORAGE: Keep ccntainer dry. Keep ccntainer closed when not in use. **PREVENT MOISTURE CONTAHINATION TO KEEP POWDER FREE FLOWING ** FIRE AIqD EXPLOSION AVOIDANCE: No smoking while handling Lhis maLerial. OTHER PRECAUTIONARY INFORIW_ATION: HMIS KAZARD RATINGS: HEALTH: 3 FL~dMAB LITY: C REAC?IVITY 0 PERSONAL PROTECTION: X (See p~ecautions, section 7. INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* Robceristionss WD - Not Determined WA - Not Applicatle Ch - Approximately A~breviations: N/D - No_ Determined N/A - Not Applicable CA - Approximately 22777722PP..00000044 I3MM_MMNN005544229441111 MSDS: FC-126 FLOORAD Brand Fl~orochemical Surfactant MARCH 17, 1997 ~AGE: bot 6 7. PRECAUTIONARY INFORMATION (continued) INGREDIENTS EXPOSURE LIMITS VALUE UNIT TYPE AUTH SKIN* AHMONIUM AHMONIUM AHMONIUM AHMONIUM PERFLUOROOC=ANOATE .......... PERFLUOROHEKANOATE .......... PERFLUOROHEPTANOATE ......... PERFLUOROPENTANOATE ......... O.Ol 0.1 0.1 0.1 mq/m3 mg/m3 mg/m3 mg/m3 TWA ACGIH Y TWA 3M Y TWA 3M Y TWA 3M Y * SKIN NOTATION: ~isted substances indicated with "Y" under SKIN refer to the pctential contrbution to the ove-a 1 exposure by the cutaneous route including mucous membrane and eye, either by airborne or, more particularly, by direct contac_ wth the substance. Vehicles can alter skn abscrption. SOD-RCE OF EXPOSD-RE LIMIT DATA: - ACGIH: ~nerican Conference of Governmental Industrial Hygienists - AIKA: American Industrial Hygine Assoc. Workplace Environmental Exposure 3M: 3M Metical Department Guideline Level Guideline 8. HEA~TH HAZARD DATA EYE CONTACT: TLD:re sreesranie of the Sotmasyimpaired Heton md Severe Eye Irrita_ion: signs/symptoms can include redness, swelling, pain, tearing, cloudy appearance of the cornea, impaired vision anc possible permanen ly impaired vision. Based cn data on a s n~ury consisting o- nilar material airborne corneal opacity. prcduct may cause eye SKIN CONTACT: Hoderate Skin irritation: signs/symptoms swelling, itching, and dryness. can include redness, May be absorbed through the skin and persist in the body fo~ an extenced time. rritation may persist removed from the skin. for several days f procuct is not p~omptly INHALATION: Hay be absorbed by inhalaticn and persist in the body for an extenced Lime. Single overexposure, above recoK~nended guidelines, may cause: a wma Irritation (upper respiratory): signs/symptoms can include soieness of _lie nose and LbioaL, coughi~lg and sneezing. Prolonged or repeated overexposure, caNse : above recommended guidelines, may A~breviations: N/D - No_ Determined N/A - Not Applicable CA - Approximately 22777722PP..00000055 33MM_MMNN0055442299441122 MSDS: FC-126 FLOORAD Brand Fluorochemical Surfactant MARCH 17, 1997 PAQE: @ ot 6 BE 8. HEALTH HAZARD DATA ca(continued) -- Liver Effects: and tenderness signs/symptoms can of upper abdomen. include yellow skin(jaundice) IF SWALLOWED: nqestion is not a lkely rcute of exposure to this produc_. llness may resul_ -rom a single swallowng of a moderate quantity cf this material. CANCER: WARNING: Contains a chemical which can cause cancer. (382o-26-1) TA RL 11983 and 1993 studies concucted join_ly by 3M and DuPont). sT oma,TI osLsin enn REPRODUCTIVE/DEVELOPMENTAL TOXINS: Not teratogenis in rabbits by oral admin straticn. Not teratogenic to rats by gavage or inhalation exposures. OTHER HEALTH HAZARD INFORMATION: A 3M Product ?oxicitv Summary Sheet is available. ---------- SECTION C~ANGE DATES ENVIRON. DATA SECTION CHAI~GED SINCE AUGUST 23, 1996ISSUE ein Abreviations: 4, sn N/~ - No_ Determined 0 ot N/A - Not Applicable CA - Approximately Lh Eh Ra An. ?he in-ormaticn in this Material Safety Data Sheet (HSDS) is believed to be correct as of the date isslled. 3H MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, $5'1 NOT LIMITED "O, ANY IMPLIE~ WARRANTY OF MERCHANTASiLi"Y OR HE il eT re FITNESS FOR A PARTICULAR PURPOSE OR COURSE O7 PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether _he 3M product is fit for a particu ar purpose and suitable for user's method of use or apDlicaton. Given the varety of factors that can sffect the use and application of a 3M prodllct, some o- which are uniquely within the user's knowledge and control, t is essential LhaL Lhe use eva uaLe Lhe 3M pioduc~ Lo deL~imine ~heLhei iL is iL for a particular purpose and suitable for user's method of use or application. eh See Ma tn 3M provides information in electronic form as a service to its customers. Due to the remote ~ossibility that electronic transfer may have resul_ed in errors, omissions ol ~lLeiaLions in Lhis inoimaLion, 3M makes no iepiesen~a~ions ~s Lo its completeness or accuracy. In addition, in-ormation obtained f~om a database may not be as current as the information in _he MSDS available directly frcm 3M. 22777722PP..00000066 33MM_MMNN0055442289441133