Document 9JbvQ0dj2V3D2aXe1ok1Rd1w6

AR226-2664 54 > RES EA RC H Precise Research. K Proven Results. AR226-2664 Analytical Report , V . . Air Sampling Fluorochemical Report DuPont Washington Works - Air Sampling Program Round 9 Exygen Research Report No. L0Q01508 Testing Laboratory Exygen Research .3058 Research Drive State College, P 16801 Requester Michel D Aucoin URS Corporation Barley Mill Plaza Building 27 Room 1260 Lancaster Pike and Rt 141 Wilmington, D E , 19805 ALL. D A T A CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Pas:.e 1 of , 3058 Research Drive State College, PA 16801, USA VT: 800.281.3219 F: 814.272.1019 Summary :v ' :: Seven solid media samples were received by Centre Analytical Laboratories, Inc. (dba Exygen Research) (Exygen) from DuPont Corporation. The media represent samples of air collected on OVS tubes. Please see Table 1 for a completed listing of samples received and field air volumes collected. C^ The samples were analyzed for Perfluorooctanoic Acid (C8 Acid) using liquid chromatography / mass spectrometry (LCMS). ^ v: The OVS tubes were separated into three fractions for specific fhiorochemical analysis. Fraction A consisted of the filter, backing material and plastic ring. Fraction B contained the first bed of XAD resin and the PUF backing. Fraction C contained the second bed of XAD resin and PUF backing. Fractions A and B were extracted with 1 mL of methanol. Fraction C was not analyzed but saved for possible future analysis. Perfluorodecanoic Acid (CIO Acid) was added as a surrogate spike to each fraction prior to extraction. 'x Instrument operating conditions can be found at the beginning of each analytical run. Raw ^ instrument data is given in Appendix A. Chain-of-custody information can be found in Appendix B. , : . ' I I ALL DA TA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page 2 of 7 * IResults Summary ' `3s Request # WWK-A-AMS1-E9 A WWK-A-AMS1-E9 B WWK-A-AMS1-E9 C WWK-A-AMS1-E9 (Total) WWK-A-AMS2-E9 A WWK-A-AMS2-E9 B WWK-A-AMS2-E9 C WWK-A-AMS2-E9 (Total) Air Volume Sampled (L) 1439 1439 1439 , ;. . 1442 1442 1442 C8 Acid (mq/m3) < 0.00007 < 0.00007 NA <0.00014 0.00011 < 0.00007 NA 0.00011 . WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B WWK-A-EMS3-E9 C WWK-A-EMS3-E9 (Total) WWK-A-AMS4-E9 A WWK-A-AMS4-E9B WWK-A-AMS4-E9 C WWK-A-AMS4-E9 (Total) . WWK-A-AMS5-E9 A l WWK-A-AMS5-E9 B WWK-A-AMS5-E9 C WWK-A AMS5-E9 (Total) 1392 1392 1392 1417 1417 1417 1453 1453 1453 0.00011 < 0.00007 NA 0.00011 < 0.00007 < 0.00007 NA <0.00014 < 0.00007 < 0.00007 NA <0.00014 WWK-A-AMS6-E9 A WWK-A-AMS6-E9 B WWK-A-AMS6-E9 C WWK-A AMS6-E9 (Total) 1429 1429 1429 < 0.00007 < 0.00007 NA <0.00014 NA - Not Analyzed. B fraction was below the quantitation limit, therefore the backup fraction does not require analysis. 1. "<" is defined as not detected at or above the reported level. 2. Sample results have not been corrected for blank results or control spike recoveries. 3. Please note the following descriptions of the OVS sample tube fractions: Fraction A B C Fraction Description Frit Extract 1st set beads extract 2nd set beads extract (not analyzed) o . \\ e> . \ \ < d . s4 ' <0.1*-' ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page 3 of 7 OC Data lcs .' . Please note: One control sample was spiked with each perfluorooctanoic acid to give a final concentration of 500 ppb. Air was pulled through the tube at a rate of 1-liter per minute for one hour (60 liters of air). The fractions were separated and analyzed. The acceptable range for control recovery is 75-125%. Request # Control 1 C8 Acid (amount spiked - ppb) 500 C8 Acid (amount recovered - ppb) 495 C8 Acid (percent recovery 99 Blanks Request # WWK-A-AMSFBLK-E9 A ' WWK-A-AMSFBLK-E9 B Voi. Of Air (L) 0 .0 C8 Acid (uq/fraction) <0.10 <0.10 ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page 4 of 7 k' Surrogates . : ; ' '. .: ' . . . . . A surrogate spike (CIO Acid) was added to all OVS tubes to give a final concentration o f 500 ppb in the extract. Surrogate spike recoveries are given in the following table. There are no set criteria for surrogate spike recoveries. Advisory ranges are 75-125%.. / , ; Sample # WWK-A-AMSFBLK-E9 A WWK-A-AMSFBLK-E9 B WWK-A-AMS1-E9A ; WWK-A-AMS1-E9 B - WWK-A-AMS2-E9 A WWK-A-AMS2-E9 B WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B WWK-A-AMS4-E9 A WWK-A-AMS4-E9 B WWK-A-AMS5-E9 A WWK-A-AMS5-E9 B , WWK-A-AMS6-E9 A ' WWK-A-AMS6-E9 B Control Spike A Control Spike B Amount Spiked (PPb) 500 500 : 500 500 , 500 . 500 500 500 500 . 500 500 . 500 500 500 500 500 Amount Recovered Percent Recovery . (PPb) 488 (%) , 98 300 60* 504 : . 101 ; 362 72* 481 . 96 322 ; , 64* : 512 ' , 102 332 66* 538 108 . 352 70* 500 100 335 : 67* .511 . 102 347 69* 490 A 98 297 59* ^ Surrogate recovery outside of advisory range. ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page 5 of 7 Calculations Request# WWK-A-AMSFBLK-E9 A WWK-A-AMSFBLK-E9 B WWK-A-AMS1-E9 A, WWK-A-AMS1-E9 B WWK-A-AMS2-E9 A WWK-A-AMS2-E9 B WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B WWK-A-AMS4-E9 A WWK-A-AMS4-E9 B WWK-A-AMS5-E9 A WWK-A-AMS5-E9 B WWK-A-AMS6-E9 A WWK-A-AMS6-E9 B Control Spike A Control Spike B Vol. Of Air (L) 0 0 1439 1439 1442 1442 1392 1392 1417 1417 1453 1453 1429 1429 0 0 C8 Acid (raw-ppb) <10 <10 <10 <10 158 <10 150 < 10 < 10 <10 69 <10 <10 <10 495 <10 C8 Acid (ug/fraction) <0.10 <0.10 <0.10 <0.10 0.16 <0.10 0.15 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 <0.10 0.50 <0.10 C8 Acid (mg/m3) < 6.00007 <0.00007 0.00011 <0.00007 0.00011 < 0.00007 < 0.00007 <0.00007 <0.00007. <0.00007 <0.00007 < 0.00007 ALL DATA CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Page 6 of 7 Example Calculation . , . . \. ' For sample WWK-A-AMS2-E9 A C8 Acid. " ; :-.V.: : p - v A. : ;V . . , \ = [158ng/miofCS Acicixfl m i i X F u g / iO0Ong)x(l m g / lOOOug)] [(1442 ,L) x (1 m3 / 1000L )] / . '. / -''V'' . \ . . 0.00011 mg / m3 Other Lab Members Contributing to Data James Miller .ALL DAT CONTAINED IN THIS REPORT WAS GENERATED BY EXYGEN RESEARCH Pa;:e 7 of 7 j 'o Table 1. Login Information / Field Data Sample ID Exygen Lab ID Date Received Description WWKrA-AMSFBLK-E9 A WWK-A-AMSFBLK-E9 B WWK-A-AMSFBLK-E9 C WWK-A-AMS1-E9 A WWK-A-AMS1-E9 B WWK-A-AMS1-E9 C WWK-A-AMS2-E9 A WWK-A-AMS2-E9B WWK-A-AMS2-E9 C WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B WWK-A-AMS3-E9 C WWK-A-AMS4-E9 A WWK-A AMS4-E9 B WWK-A-AMS4-E9 C WWK-A-AMS5-E9 A WWK-A-AMS5-E9 B WWK-A AMS5-E9 C WWK-A-AMS6-E9 A WWK-A-AMS6-E9 B WWK-A AMS6-E9 C Control Spike A Control Spike B Control Spike C L0001508-1 L0001508-2 L0001508-3 L0001508-4 L0001508-5 L0001508-6 L0001508-7 L0001508-8 . L0001508-9 L0001508-10 L0001508-11 L0001508-12 L0001508-13 L0001508-14 L0001508-15 L0001508-16 L0001508-17 L0001508-18 L0001508-19 L0001508-20 L0001508-21 L0001508-22 L001508-23 L0001508-24 12/20/03 12/20/03 12/20/03 : 12/20/03 12/20/03 12/20/03 ' 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/3 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 . 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 Frit extract 1st set beads extract 2nd set beads extract Frit extract 1st set beads extract : 2nd set beads extract Frit extract 1st set beads extract 2nd set beads extract Frit extract ; 1st set beads extract 2nd set beads extract Frit extract 1st set beads extract 2nd set beads extract Frit extract 1st set beads extract 2nd set beads extract . Frit extract 1st set beads extract 2nd set beads extract Frit extract 1st set beads extract 2nd set beads extract Air Volume Sampled (L) 0 0 0 ..1439 1439 1439 .1442 1442 , 1442 1392 1392 1392 1417 1417 1417 1453 : 1453 1453 1429' : 1429 1429, oV 0 0 Table 2. Chain of Custody Sample ID WWK.A-AMSFBLK-E9 A WWK-A-AMSFBLK-E9 B WWK-A-AMSFBLK-E9 C WWK-A-AMS1-E9 A WWK-A-AMS1-E9 B WWK-A-AMS1-E9 C WWK-A-AMS2-E9 A WWK-A-AMS2-E9B WWK-A-AMS2-E9 C WWK-A-AMS3-E9 A WWK-A-AMS3-E9 B WWK-A-AMS3-E9 C WWK-A-AMS4-E9 A WWK-A AMS4-E9 B WWK-A-AMS4-E9 C WWK-A-AMS5-E9 A WWK-A-AMS5-E9 B WWK-A AMS5-E9 C WWK-A-AMS6-E9 A WWK-A-AMS6-E9 B WWK-A AMS6-E9 C Control Spike A Control Spike B Control Spike C Date Collected 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 12/19/03 NA NA NA Date Received at Exygen 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03. 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 12/20/03 Date Extracted by Exygen 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 ; 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA 1/5/04 1/5/04 NA Date Analyzed by Exygen 1/5-1/6/04 1/5-1/6/04 NA 1/5-1/6/04 1/5 - 1/6/04 NA 1/5-1/6/04 1/5-1/6/04 NA 1/5-1/6/04 1/5 -1/6/04 NA 1/5-1/6/04 1/5 -1/6/04 NA 1/5 ^ 1/6/04 1/5 -1/6/04 NA 1/5-1/6/04 1/5 -1/6/04 NA 1/5 - 1/6/04 1/5 - 1/6/04 ' NA Project Storage: Company Name, DuPont de Nemours & Co, Inc. Submitted By; , Michael D. Aucoin . Login Type: Started: . Immediate Receipt of Samples T: . Date Start: . Due Date: 12/22/2003 01/05/2004 '; v ' Received Date: .12/20/2003 '. ; , Received By: ROBB, SHAWN Spread Sample: .- - - -' ' Label: : .. ; : Project Title/Type: Analysis of PFOA in OVS Tubes / ROUTINE Exygen SD/PI: MILLER, JAMES - :. Login Notes: ^ Conform Notes: ; , Conform Sample: . . Conform Request: ' True True Package Carton Packages 7 Containers Mail Date 1Condition ' Shipper/ ID PK0002109 K- 12/20/2003 11:30:09AM . FEDEX Package & Contents Uncompromised 8363912984670200 -LStainer # 24018 C0024019 C0024020 C0024021 C0024022 C0024023 C0024024 C0024025 C0024026 C0024027 C0024028 C0024029 C0024030 C0024031 C0024032 C0024033 C0024034 C0024035 C0024036 C0024037 C0024038 C0024039 C0024040 C0024041 Gross Weight 2.0 g . 2.0 g 2.0 g 2.0 g . 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g "2.0 g 2.0 g 2.0 g . 2.0 g 2.0 g " 2.0 g ,2.0 g ` 2.0 g 2.0 g , 2.0 g 2.0 g 2.0 g 2.0 g 2.0 g . 2.0 g E Container Type Other Other ' Other Other : Other Other Other Other Other Other Other Other ,, Other Other Other Other Other Other Other Other Other Other Other Other Preservative NONE NONE " NONE NONE NONE NONE. NONE NONE NONE NONE NONE NONE NONE NONE: NONE NONE NONE NONE NONE NONE NONE NONE NONE NONE . Temp. Control/Temp. None Mfg, Lot Iscellaneous ' 'tern Key None 1/6/2004 Login.rpt ICOC " Description Q56 Report Version: Dec 22 2003 10:44AM Page 1 of 4 Instance: " Direction / Handled By RECEIVED ROBB, SHAWN Mfg. ID R0078484 R0078484 I* Sample ID L0001508-0001 '001508-0002 01508-0003 L0001508-0004 L0001508-0005 LOD01508-0006 L0001508-0007 1.0001508-0008 LOO01508-0009 LOO01508-0010 L001508-0011 L0001508-0012 L0001508-0013 L0001508-0014 L0001508-0015 L0001508-0016 L0001508-0017 L0001508-0018 L0001508-0019 L001508-0020 L0001508-0021 L0001508-0022 L0001508-0023 LOO01508-0024 Samples Matrix GAS Fraction OVS Tubes Sample WWK-A-AMSFBLK-E9 A '. GAS OVS Tubes WWK-A-AMSFBLK-E9 B . GAS OVS Tubes WWK-A-AMSFBLK-E9C GAS OVS Tubes WWK-A-AMS1-E9 A GAS OVS Tubes WWK-A-AMS1-E9 B GAS OVS Tubes WWK-A-AMS1-E9 C GAS OVS Tubes WWK-A-AMS2-E9 A GAS OVS Tubes WWK-A-AMS2-E9 B . ^ GAS OVS Tubes V7WK-A-AMS2-E9 C /` .. GAS OVS Tubes WWK-A-AMS3-E9 A GAS . OVS Tubes WWK-A-AMS3-E9 B .. GAS OVS Tubes WWK-A-AMS3-E9 C GAS OVS Tubes - WWK-A-AMS4-E9 A GAS , OVS Tubes WWK-A-AMS4-E9 B Ga s OVS Tubes WWK-A-AMS4-E9 C GAS OVS Tubes WWK-A-AMS5-E9 A GAS OVS Tubes WWK-A-AMS5-E9 B GAS , OVS Tubes WWK-A-AMS5-E9 C . GAS OVS Tubes . WWK-A-AMS6-E9 A GAS OVS Tubes WWK-A-AMS6-E9 B : GAS OVS Tubes VWVK-A-AMS6-E9 C GAS OVS Tubes CONTROLA ; GAS OVS Tubes CONTROL B GAS OVS Tubes CONTROL C . . ' Date Sampled Date Received 12/19/2003 12/20/2003 ^ 12/19/2003 12/20/2003 12/19/2003 12/20/2003 . 12/19/2003 12/20/2003 12/19/2003 12/20/2003 .. 12/19/2003 12/20/2003 ; 12/19/2003 , 12/20/2003 12/19/2003 12/20/2003 ' . : 12/19/2003 12/20/2003 12/19/2003 12/20/2003 12/19/2003 12/20/2003 12/19/2003 12/20/2003 12/19/2003 12/20/2003 12/19/2003 12/20/2003 12/19/2003 12/20/2003 12/19/2003 12/20/2003 12/19/2003 12/20/2003 : 12/19/2003 12/20/2003 12/19/2003 12/20/2003 12/19/2003 12/20/2003 . 12/19/2003 12/20/2003 12/20/2003 12/20/2003 12/2/2003 Date Due 01/05/2004. 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 / 01/05/2004 01/05/2004 . 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 01/05/2004 I 1 I : \ - ^ , 1/6/2004 I Login.rpt : ' . - U0 5 7 Report Version: Dec 22 2003 10:44AM Page 2 of 4 Instance: R0078484 R0078484 ogin ' 0001508-0001 Container 124018/O ther/N O N E .- // '. Bottles , .- ; ... , M ethod' . L0001508-0002 Container 00024019/Other/NONE . :V .7 ' : . ^ : r ;. Method 7 . L001508-0003 Container C0024020/O ther/N O N E -'/ V - : V . ' ... \ . ^ ; Method : >. : L0001508-0004 Container C0024021/O th e r/N O N E 7 .7I. ; Method ; L0001508-0005 . Container C0024022 / Other / NONE ': . .. 7 : Method . L0001508-0006 ' Container C0024023 / Other / NONE l 01508-0007 Container C0024024/O th e r/N O N E /: "/ V ,: . . Method Method L0001508-0008 Container C0024025 / Other / NONE - . . Method L0001508-0009 Container C0024026 / Other / NONE : Method L0001508-0010 Container C0024027/Other/ NONE Method L0001508-0011 Container C0024028/Other/NONE Method L0001508-0012 5 Container "0024029 / Other / NONE . . Method u libB 1/6/2004 Login.rpt Report Version: Dec 22 2003 10:44AM Page 3 of 4 Instance: R0078484 R0078484 L0001508-0013 Container ' C0024030/Other/NONE .: . . . Method : . .. - -------------. . .> '"001508-0014 Container C0024031 / Other/NONE ,-. '. : vV-':/ Method ' . . ------~ ~ ~ . . / ' -- . . L0001508-0015 Container .. ; C0024032 / Other / NONE ^^ ': Met hod \ .'. ; , . / TV ~~': .: : .; L0001508-0016 ' . . :. . / ' Container C0024033/Other/NONES . ' ./ ... . . : : ' . :. ; . b / . v\ : . . ' '. -. ' : Method . .- . .: . L0001508-0017 Container . ' C0024034/Other/NONE . / ^ : : / :/.V : . ; .' Method ' . . .. .. : / . . L0001508-0018 Container . C0024035 / Other / NONE . Method ~~ ' . 1L00Q1508-0019 Container 0024036/Other/N ON E ; .: /. Method : ' - L0001508-0020 i Container C0024037/Other/NONE .. ' ' Method .. .' ii L.Q0.01508-0021 '' . _ Container ; 00024038/Other/NONE . -. . . '. ' . . . . ..... Method -- ~. . ' L0001508-0022 Container , C0024039/Other/NONE . Method . ., ! L0001508-0023 '. Container C0024040 / Other / NONE Method L0001508-0024 Container C0024041 /O th er/N O N E . . Method . 1/6/2004 Login.rpt . . u0b9 Report Version: Dec 22 2003 10:44AM Page 4 of 4 Instance: R0078484 R0078484 CHAIN OF CUSTODY/ANALYSIS REQUEST FO RM Exygen Research Sample Receiving * 3 1 1 7 Research Drive State College, PA 16801, USA T: 814.231.8032 F: 814.231.1580 exygenresearch.com P a g e _____ o f ______ PROJECT INFO RM ATIO N____________ i M ANLYSES REQUESTED C lien t (n am e & address): rs , P roject M a n a g e r (N a m e & E-m ail A ddress): lA u fill/l . Phone: ( 3 o Z ) F a x :_______.............. ...,______ Sam pler: VI ) ....... ........ : _____ _ Project N am e: /V \C V f qc\ R O . # : _ _ _ _ _ _ ____ L _ s J ____ ___________ __ Q u o tatio n # : Please fill o u t this fo rm c o m p le te ly to ensure correct analysis and p ro p er h an d lin g o f yo u r sam ples. Composite Number of Containers . " A i ' M , A O A lY S IS ExyLIMS# Client Sample Identification V 3 \o Y ^ - A yV \S V & t 'V Colle<:tion Collection Date Time j a i i p 3 6 T -I5 D (jl4 ) o 6l4 m .fO O * . '-s 7 ______________ _______ !----- :------- LAB, USE O N LY W f1 U>5( X oU2A\ X 0^60 J i Specify Matrix Comments , pc \ S s s l ..... V, _ J h ..... V _L_ m e \ #r _ A _ J ^ s : ........ Q ~1 \ O t T PROJECT REQUIREMENTS Results D eadline: Laboratory Report Options: I I Sample results only I I Add case narrative I I Add quality control summary Add calibration summary H I Add raw data CD Other jr REV. 3 02 Sampler(s): LK, REK DuPont W ashington Works Air Sampling Program FedEx A irb ill #: Event Number Pump # 669842 669908 6699Q1 669890 669796 669865 Hours 0 1. 2 3 .4 T S ta tio n '#!; AMS-1 AM S-2 AMS-3 AMS-4 AMS-5 AMS-6 Minutes .0 60 120 180 240 Exygen ID WWK-A-AMS1-E9 WWK-A-AMS2-E9 WWK-A-AMS3-E9 WWK-A-AMS4-E9 WWK-A-AMS5-E9 WWK-A-AMS6-9 Hours 5 6 7 8 9 n a s iIS M B if o n (pro) Start Time S iiS m f f l S m 1.004 18-Dec 0619 19-Dec 0641 1.008 18-Dec 0624 19-Dec 0644 . 1.005 18-Dec 0625 19-Dec 0644 1.005 18-Dec 0632 19-Dec 0651 1.006, 18-Dec 0608 19-Dec 0629 1,007 18-Dec 0648 . 19-Dec 0700 Minutes Hours Minutes Hours Minutes 300 10 600 15 900 360 ; 11 660 16 960 420, . 12 720 17 1020 . 480 13 780 18 1080 540 14 840 19 1140 Field Blank: yes WWK-K-AMSFBLK-E9 yes or no W eather: 11/29 = Temperature about 27 degrees, and snowing. 11/30 = Temperature about 28 degrees, and light snow. 0.9642 0.9671 0,9030 0.9377 0.9837 0.9618 Hours 20 21 22 23 24 Event 5 Total M inutes s?rSiai#\7oTii rri~U- 1460 1460 1459 1458 1461 1451 Minutes 1200 1260 1320- 1380 1440 H. C SAFER operational: yes yes or no C om m ents: Total minutes column is the reading from the monitor counter. ^ ~ " :" ~----- --- ~ 12/19/2003 Page 1 of 2 airdatae'/enl9 %' $ i rv.citL;i u . Proven Resets. Sample "ConditionUpon Receipt" F om * Protocol = E x v s e n Scud'- # *' '' . D a te & T im e R eceived . A /fh / 0 & 0 C //9 Scr^ f /// ' ) C o n d itio n o f Sanrales " T em n o rary Storase L ocation Qcc-C.2 Jc,} , In itials S O a te ' _ / ^ Z2- /ic. /c? //7<^. ' . W a v b i i l # ' / / `V i 9 / 2 - 7 Cornments: /2 > ,, / F - j~ v F / v X ^-6 ^ ft- / Z-c/ ' \ } 1 cc::: c. U0 6 2 Fed&C . USAAirbill Express 1 From Date I f; v; ;?> . fedEx Tracking Number- Sender's Name ! \- J K V V ' , 1 ,i I > W ,y -V \ \ h A . l l- Phone Company- _ .< U 4 V L \ i (~ ' Address V'T City ~V . ' A. ' ->0 <,/ ' -V; N >\a i r Kt j OeptyRoorSuire/Room - vr State v ! ZIP t o ^ i 4a Express Package Service S. J .. Packages up io m lb s . 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Other f ^ "Special Handling ^/"S A hU R D A Y Delivery r Includo.FedEx address in Section 3. r-- i HOLD Weekday I-- i HOLD Saturday l I . ^ AvailableonlyforFedExPriority ; V Oyafnight andFedEx3Dey -ft selectZIP codas U at FedEx Location Not availablelor FedExRrstQverroght I__ ! at FedEx Location Availableonlyfor FedEx Ptiority Overnight sndFedEx2Dayia Poes this shipment contain dangerous goods? selectlocations - ------ -- One box most be checked. -------------- K 0 ' D yes QYes Shipper's Declaration .not required Dry Ice dry tee, 9, UN 1845- Dangerous Goods(including DryIce) cannot beshippedinFedExpackaging. Cargo Aircraft Only 7 Payment B ill to: 1 [Obtain Recip. Euler FedEx Acct. No. or Credit Card No. below. -- -------- -- I Acct. No. ^MAcScelNnode.lrn! [^R e cipien t | [Third Parry . P i Credit Card I jCash/Check Total Packages V Total Weight l Total Declared Value* i .00 tQur liability is limited to S300unless you declare ^tfigher value. See back lor details. 8 Release Sijjnatui Sign to a u fto rii devfyfvilhaut obtainingsignature. if ByWgiTing y id authorize us to cfetiverthis shipment wiihoul obtaining a signature - antfagree to indemnify and hold us harmless from any resulting claims. Questions? Visit our Web site at fedex.com or calU.800.Go.FedEx'; 800.463.3339. . . flov.Date.10/01` Parr* i576120I9I4-2OO1 FedEx*PRINTEDIN.SA WCSL02 . < Total Charges 4M b \o CD CD Washington Works No Charge Skipper Ship To: Exygen Research 3058 Research Drive : State College, PA 16801 Attn: Shawn Robb or John Flaherty 814-272-1039 D ate: 10/27/2003 NCS # : 38-200304715 R o u tin g : FED EX ( SEE ABOVE ACCT) F. C vB .: COLLECT : D ate Shipped: B/ L: Phone Number: Q uantity 1 Product Code / Description Box containing glass sample tubes for analysis W eight - 10 Units lbs. F re ig h t Class: TUBES, GLASS, NOI. O rig in a to r: Crane, Alison A Cost Code: 7035-507483-862200 Purchase Order # : Value for Customs: D im en sio n s: Ship From : Stores Status: P h o n e:4448 H aza rd o u s S hip m en t? No O Yes M SD S S h eets R equired? No O Yes M a te ria l Class: Corrosive Flammable Toxic Other Shipping # : U64 Special In s tru c tio n s : This N-C-S will cover 6 shipments beginning 10/30/03. > > > Will deliver package to Stores with completed FEDEX Bill. CRG Account Number 2230-5551-6 Weekend samples will be delivered directly to FEDEX. < < < < C o m m en ts: V "'-"v ' . - u (j 65