Document 9DpqQ9jNwp027YjeNO09Jn2V

DIPHENYL AND CHLORINATED DIPHENYL DERIVATIVES JUNE 1935 DSW 001279 1 DEFENDANT'S DEPOSITION 2 EXHIBIT 1*9-2S 0$ 3 *5 COPY Nfi 2 ADA 000632 WATER PCB-SD0000045799 mmoownm fhie report relates to lit* tosaofeeture f Mphm&rl mi Chloriaeted Dipbeayl Derivatives. It is subaltted to those t tk* 8t Louis Float Is eoaaettiea with wrrlag these operations fm tit# Anniston Pleat to the loot it, Lowls Pleat, ' A description is gives of the sqnipeent sad ipenlloM of the Diphenyl esd Derivatives pleat it lujtiM, both Is text end prints. V* have investigated our present pleat sad opera tions end hsre foisted out iapreveaent* that would he advisable ia e sow pleat. Tbeee laproveatente ere set out la both text eed yriats. Vo attempt hee hoea site to ley eat the eev pleat or detail the e^uipatent, ee neither the sine of the bwlldinga to he oeoupled nor the eepaelty of the waits to be Installed is knows. To seeist those who design this pleat we are sending s tdeplete set ef prlete, both aseewbly sad detsil, showing the equipment es it is installed et present. It is hoped that amah of the equipment at Aanleton tea he weed iw the new pleat. Severel ambers of the tealstoa organisation have written the various eeetloaa of this report. Between these seetiews there has been sons repetition. It is felt, howerer, that this is desirable for et St. Louie different groups shy bo prlnolpellf interested ia Isdlvldsal eeetloae. Hade pert ef this report ere lets sheets, best belanoes, produet speelfieetlowe, ate., designed to help these who will Mhotruet end operate these waits. this report is prepared la qwsdrwplisate, m copy being seat to Mr, DsBois, two eoples te Hr. Livingston, sad ese espy being kept la the Anniston files. DSim iff iM . 1, 1, Buford DSW 001280 ADA 000633 WATER PCB-SD0000045800 ims or CONTESTS BJOTIOB mm 1. Botee ob Diphenyl soft Diphenyl DariTetlYta Plant Itoutwent Pro mb t and Proposed Diphenyl Plant Equipment Chlorinating Plant BC1 Abaorptlon Aroclor Pletillation Aroclor 1160 Assembly of Plants (Proposed) ' PAOa 1 t 7 S 34 . 40 44 1. Hotea on Diphenyl and Diphenyl Derlratlree Plant Operation aa at Anniston Diphenyl Unit Chlorinating Plant HOI Absorption Dietillation of Crude Aroolor Yaettujs Dlatlllatlon Shipping Oontalnara Diphenyl end Aroelor Operating Toroa Schedule of Packings, Oaekata and Supplies 46 47 79 eg 06 101 107 118 117 1. Heat Balance on Present Diphenyl Coprertsr Unit 119 4. Kafftfeotaring Costs f Diphenyl and Dffilxam 0. Laboratory Method, Spacification and mimml Analytical Methods Standard Spaelfteatlo&a Equipment . . S. Schedule Of PrmlM 7. Listing of Manufacturing Equipment with Rotes 184 169 161 III 149 161 866 861 OSW 001281 ADA 000634 WATER PCB-SD0000045801 I JL OSW 001282 ADA 000635 WATER_PCB-SD0000045802 HOWS OH MPHOTYL AID BIFHEHIX dbuyamtes plahts SQumowf, how PRESEHT ARD PROPOSED BTt ROOBRS MoODLLOTOH {RK3KAR0H D2PAHWS3TT) 1, H. BOTORD (maimsjmrm mparwkot) The Erasings Referred to li Thia Beotion era: PIPKEHYL WIT 0-5831 -- Diphenyl Plant - Diegrsanjetle How Sheet of Present Pleat. se--8403 -- Proposed Conrerter Unit and Separating Equipment CHLORIKATXSO WIT 0-083* -- Dlegremetic Layout of Ohlorlnstlng Equipment 0-0835 -- Layout of Chlorinetore 8--8404 -- Suggested Layout of Chlorinetore for Proposed Pleat HOI ABsmmfffl Ho Drawl age ARCOLOR HO, AIM 80--8407 -- Proposed Layout of "lEdO" Plant AR0CLQ8 PIBTlLLAflOH 0-5838 -- Layout of Bsdger Still 8o-t405 -- Proposed Distillation Equipment for Liquid Aroslars Bo-8400 -- Proposed Distillation Equipment for Solid Aroclore ASSEMBLY or PLART3 {PROPOSED} So--140* -- Proposed Oeaerel Layout of Pleat 0SW 001283 ADA 000636 WATER PCB-SD0000045803 pirrom, mw hovumst A unit for producing 41phenyl at St. Louie having e oapeoity of 1,000,000 lha. par year aojr follow one of tiro arrangements. The flrat errangeraent would he the removal end installation at st. Louie of the prawnt three laed pot unite without substantial Iteration. Suoh an arrangement fired with natural gee at 30/ per ' 1,000 M< ft. would aean eg increase of eoet of production due to fuel lone of 0.189/ per lb. or $1,890.00 par yesr over that of Anniston operations. However, bp the elimination of the hensol etlll, wbloh le -later dleoueaed, the reduction in steam ooste would off-aet the edvanoe In gee oate and the total oosta Of hasting eould he brought In line with the heating eoets st Anniston. .- The second possibility and the one which mssi the tcoet dealrhle, end aspeolelly so If large production requiring a number of unite een he foreaen, la tba lnatallotlon of e two lead pot unit ocabined with II heat axehnngera end continuous freotlonetlng oolumns, Sinoe this arrange-> I nent would beta lower heating eoets than for the 8 pot unit with natural gas et SO/ per 1,000 eu. ft., the oo*t for fuel would be reduoed by 0,89/ per lb. of diphenyl or $8,900.00 per year on 1,000,000 lbs. These fuel eoets would be by the seme amount lees thon Anniston ooste. There would probably be additional seringa in maintenance and labor wbloh cannot be predieted at the praeent time. This arrangement le a considerable departure from the praeent Anniston praetioa and Its design end construction should be preceded by development work. The following notaa;dlaouas the possible aomblnations thet may be used for the production of diphenyl end the salient features of the present unit as Compered with the suggested unit. The outline for this dissuasion lsi t OSH 001284 ADA 000637 WATER PCB-SD0000045804 3 I* Diphenyl OpnTerter 1 ! General Dieeusslon ' It Reeotor Teesele St fuels nd firing Kquipnent ' 4, Settings 5t /utooetio Control Kquipoent . i. Piping end Telre ' * Opereilon It Temper*ture end Rate of Operation Ptlld Dleoueelon of Suggested Tw Pot Unit It Peperetlon of Products * UiMtSolm It Equipment for Separating Densol--Diphenyl-- High Boiler Mixture I. Storage f Bensol--Diphenyl-High Boiler St Beooantandetlone OanaMnte on items ee listed ahoTe are as followst OSM 001285 ADA 000630 WATER PCB-SD0000045805 4 mphehtl ooHVSRYro -- puot t>mim ITM 1.1.1. - QEHHHAL DI3C08SI0H ' Mphenyl li produced kjr tbcr heating of benzol vapor to a temperature around 500*0 in alosad raaaala from vhioh the air it xoludLd, condensing these produota and separating diphenyl from the honr.ene and other converted produeta. The moat desirable diphenyl unit ie one In vhioh the meximm utilisation of heat is eomhlnsd vith aiaplialtjr of operation end lou ooet of construction. The most satisfactory type of reaotor vessel hee been found by eotuel manufacturing erperienoe in Anniston to be e steel pot oonteinlng molten lead through vhioh the benzene vapor Is passed. Although at first sight the lend betb appears to be *a Inefficient heat exohunger, jToef.J'tuil JuLa..*h.0,n ,tbe.t. It Is e xo*e dingl y_. t fi Aicni The lead bath has the particular advantage for an operation of this sort that any earben formed tends to float on tho load surfaos or be oerrled out to a conveniently located trap rather than to plug the apparatus. All subsequent discussion will he confined to load pot reaetore. The lecd re notor pot or pots may be heated in various veye end sy be combined with various heet exoh-ngs sppnratue, The more important combinations are Bbotrn In Sobedule 1, DSW 001286 ADA 000639 1 WATER PCB-SD0000045806 0^9000 vav WATER PCB-SD0000045807 ABPM&MMTS or B P a m . COST H D SEAT EECHAfGfflS Is order to determine which arrangement la moat aoonoraioal to lnetsll end operate the variable coats for the varloua etnw- blnatlona ar oomparefi.1 '. Labor and maintenance oowta will alao enter Into the final obtalaahle oowta but these eannot be predicted et this time. The bases need for these computations are aa fellowai ! 1, Steam -- 3S^ per 1000 ibe. at 100 Ibe. preaaurw end utilising only the latent heat. Kquiralent to 40^ per million Q. T, U. (This ia lews then the ooat of steam generated for the Anniston Diphenyl Operations by a small gee fired boiler.) I. Natural gee et 80.Off per million B. T. 0. (Anniston seat). 5. Water ooat gSjf per 1.000 eu, ft. (Average Annlaton water coat. Ineluding city and re claimed water.) Beat requirements are taken from the heat balanoa resently mate, notes and racorda available at Anniston. Where such information was not available, calculations have been mode. J&tX&kMa&tsste. The inatnlletlon eoata era only on e eallaetton af laolrted pleoaa of oquljmant and are without accessories. No designs have been made nd the oosta are only preliminary as foilowes DSW 001266 ADA 000641 WATER PCB-SD0000045808 r It Om S got converter -- g fired {Owed in Arrengeneat 1 A l) ' 14,000.00 tt One & pot ooaverter -- |*i fired (U*i In Arrangement* 8 A I) 10,800.00 8. One 1 pot converter gee fired (Coed la Arrangement 4) f,000.00 4. One 1 pot ooaverter -- llestrlo heated (reeiatanoe) 8,000.00 (Ud In Arrsng*ent.' 4} ,, ', . B Bentol Tnporiser la Hus Use 8task (Used in Arrangement* 1, t, 8, 4, AC) no. oo 4t Beet ezohenger la Coarerted Tepor llae (Used la Arrangement , 3, A S) no, oo f. Heat exohonger lu Converted Vepor line (Used la Arrangements 4 A $) 1,100.00 6, Steen Bested Berutol Vaporiser (Used la Arrangement 4} 400.00 9. Continuous fractionating Oolwsn (Bead la irrangutaat 1, S, 1, A 4) 1,000.00 101 Staam Basted Baa col Still (Uasd la Arrangements 1, S, 8, 4, A @) 3,000.00 11. fuel Heated Diphenyl Still (Heed la Arraagaswnt* 1, 1, 3, 4 1 4) S,400.00 18. Continuous Separation Bqulpmaat (Deed la Arrangement i aad price Include* ooat of Mtsinry develoteasat work) 8,000.00 su 00128' j ADA 000642 WATER PCB-SD0000045809 a All ealoelatiosi ore based tm Anniutoa operations* saly * unit producing 8*000 lb#. of teehaiosl dlphamyl a day. This correspond# to a total conversion per past of li oooverted product** 76jt of converted products being diphenyl end t1& being high boiler. The production of oooverted produote require* theoretically f8,t$ of the benseae actually used, The daily rquireai* of bmzm* are 4*180 lbi. per lay, ' ' fhi* is the present Atrmgmmt at Asaietom end ae shown m mr Drawing #C~ft851. The installation ooneiete of 8 gas fired lead pete* with beuseoe entering through a vaporiser located in the atook for exit of combustion gases* end after conversion* then entering e fraotianating oolwn which partially oonoentratee the oonTerted produote. The mixture which dlaohargee from the bottom of thin column runs 60Jf-76)C converted produote* the balance being beasene. The partial operating costs are as follow!- fuel for Oonrerter (Metered) * Diphenyl 8tlU (Metered) 8teen for Benvoi Still ' (Reflux ratio aeearned as l/Z to 1 and f&% efficiency end El*l0# bensol distilled per day) Water for Sftphlegsmtor and condensers m continuous ooltumo* beasol still end diphenyl still Depreciation an Items l*5,9*lXWkll* totalling | 88*160,00 If* on 1,000,000 lbs. ZsOktJAs&Jtttl 0*51# 0*05 0,16 0,80 0.88 Total for Arrangement Mo, 1 O.fS# Main The above operations could be reduoed by 0*15# by running the continuous column with minor alteration# at a higher temperature so ae to deliver a diphenyl and high boiler mixture and thereby eliminate the beast still. temmmkMM&S . this arrangement would be identical to Arrangement lo, 1 excepting feat a heat escefaasger would be used to rsoover heat from fee vapor* leaving fee converter wit, fiMaem* would first pass through fee vaporiser heated bjr the exit floe gaeee end then to .the * heat exchanger and fens throng fee lead pot mite, the converted vapors after leaving the heat exohanger would paes to fee column for coaoemtratlmc the oouverted product# prior to going to the bousene still. 001290 ADA 000643 WATER PCB-SD0000045810 On the assumption that the heat axohang* would recover SOj of the bent la the converted vapors, which would pepreeeat 10 of the total heat requires eat*# the heat efficiency of the operations would be Increased from 4SjS to $0, fh partial operating coats are as fellows- fuel for Converter Dipbeayl Still (Metered) Btean (Sene ae in Arrangement lo. 1) later 6ane as in Arrangement to, V excepting that lose would) be need on ooluetn ) Depreciation on I tarns 1,6,6,9,10 6 11, . totalling f2B,900,00 10* oa 1,000,000 lbs, iLJksuM^ml 0,*4 0.05 0,10 0*17 Total for Arrangement Mo, S 0,76(1 Motet The above operations oould be reduced by 0,154 by running the continuous oolaaa, after Baking minor alteration, at a higher temperature so as to deliver a diphenyl and high boiler nixtare end thereby eliminate the beitsena still. This arrangement would be the sane a Arrangement Vo, 2 exception that one lead pot would be eliminated. This would necessitate patting the seme bent into two pots that would be put into the three pots of Arrangement Mo, t, The partial operating costa are a foilowl ~ l&EjhMskml fuel - For Converter Diphenyl Still Btmm - Same aw la Arrangement lo, 1 Water * Same as In Arrangement Vo* 1 Depwmeiatlon <m Items g,6,l,f,iP t 11, totalling 1 11,400,00 C 10* on 1,000,000# ' Total for Arr&ngmmt to, 5 O.M* 0.06 0,10 0.17 0,71 ' DSW 001291 lot# I The above operation could be reduced by 0,16# by running the CMti*UOT6 eolwn after Baking imor alterative at a higher temperature o m t deliver a diphiujl mA hi^ boiler aiit^re i&d thereby eliminate the bemswe still* ,' ADA 000644 1 WATER PCB-SD0000045811 /o This arranges*t la th@ saae m imn{WHt Bo. 8 except two of the lead pots would be elinlnated. Tb partial op*rating ooata are a follow!- . fuel - tor Converter * Diphenyl BtUl 8tam - San as Arrangement Xo 1 !at*r Depreciation on Itea* 8,8,7,8,10 A 11, totalling | 16,260.00 10* oa 1,000,000 lbe. total for Arrangement So. 4 0*14# 0*08 0*10 0.16 0.16 0,67# this arrangement consist of a two lead pot convsrter unit, fh incoming baasene is vaporised and superheated In an exchanger located la the stack for exit combustion gases, this superheated beosene vapor attains additional superheat in an exchanger on the exit converted vapors frees the converter unit. These partially eooled converted vapor then enter a syete* of oolunns which continuously discharge the ef^arattd btsiMi, diphenyl and high boiler, this system is us shown m Drawing Ifio-feME. The partial operating oosts are as follow! F*1 - For Converter 8tea* Water Depreciation on Items 8,6,6 & 12, totalling | 16,000.00 f 10* m 1,000,000# Total fur Arrangement So. 8 0*190 0,16 JLJJL 0.680 OSW 001292 ADA 000645 WATER PCB-SD0000045812 // Thi* arrangement consists of a Ingle pot electrically heated. Heat exchangers are provided to hove the exit converted vapors eoadease a*d lajwi their heat to the looing bmm<a vapor* Ooloane wonld be provided for separating the beazeae-diphanylhigh boiler* The above cycle la identical to tile Dow operations excepting that instead of the lead pot, Do mm carbon tabeg acting as resistors and heated by electricity* X the Dow process, benzene vapors are delivered directly fro the top of the beatane eoltwa to the heat exchanger. Dae to the head Of the lead 1 oar process, it would probably be inadvisable to operate this oolttm under 16 lbg, pressure to gave the energy of vaporising the beneol. The partial operating ooets are ag followi- Electricity DO M. X/Ut Fuel for Diphenyl6011 Steam Water tpqpMOiation m I teas 4,7,1,10 4 11, totalling | 15,000,00 @ 10* on 1,000,000# Totel for Arrangedeat 6 0.56# 0.05 0.21 0.18 _&M_ 0,t# lotei If the heating wee done by induction, the Installation cost would be increased by $ 10,000.00- $15,000.00 and the operating cost up to 0.15# per pound diphenyl. Fro the above, it Is evidsat that Arrangesent So. 5 is the cheaper to operate. ' Thin, however, ie followed very closely by both Arrangements los, C I IS with the continuous ooltna operating so ae to eliminate the ben sol still. - REACTOR VESSELS The pots used in this process hare long life and low a&ictetvanon cost. Freraaably these pots could be made larger end for greater capacities, bat the life of such pots and the maintenance costs as oompared with the preseat pots cannot be predicted. DSM 001293 ADA 000646 WATER PCB-SD0000045813 A? i Our iotpwieaee with pot 1b limited to welded pote of low cautioa BtfI and also Crucible Stool Goapany'i Ratistal No* 7, ohromlum I&-86J? and nickel 0-^* These pote hare been B&d b/ two fabricators, but those made by the Slaw Knox Company hare been most satisfactory. . The pot used on preheater Mo* 3. (the loweet temperature pot) ie hammer welded low carbon steel. These pots have lasted well and the last lot purchased was in 1B0, hence the hammer welding* Pote eleetrioally welded would be equally aa good* The depth of the lead in the pot la about 50% The inlet pipe for bantane vapor with distributor is made of 18% chromium, 8% nickel steel* The distributor pipe la secured to the steel cover which is then welded to the pot* The pot need on preheater No, (the intermediate temperature pot) la electrically welded Crucible Steel Company's Beaistal No* 7* The depth of the lead In the pot la about 4i". The inlet pipe for bmtsene vapor along with distributor la Bade of ISfC chrome - 8% nickel steel* This distributor pipe is secured to the oaat steel cover which ie then bolted to a oast steel flange(Va* Stone Type) on the pot. The gasket Used is & S/16" diameter annealed ooppar hoop. The converter pot (the highest teaperature pot) is electrically welded Crucible Steel Company* e Kexlstal No* 7, The depth of the lead in the pot ie about 42" The inlet pipe, sane as above, ie secured to the cast steel oover which is bolted to the flange on the pot. The gasket need is braided asbestos. Da# to the extreme temperatures, the bolted covers an the converter pot have been troublesome when insulated* The bolts would stretch and the joint would leak* Bare covers are now being operated and the bolts tightened as leaks develop. Alloy bolts have been tried bat when the pot was cooled, they contracted and then had to b* selted off. It ie bet seldom necessary to enter the preheater potsj It Is recommended that whether one or two are used, that the heads be welded to the shell and then Insulated* This presumed that welders are available who can sake high pressure welds In carbon steel. The converter pot should have either a bolted cover or a welded oover provided welders are available Ao can make pressure bald* la high ohromiom - high aiekel steels* telding is aot baey after prolonged exposure to these high teaperature vapors, ,It ie believed that the preferred construction would be alloy bolts with thick washers made of a material whose coefficient of expansion is higher than the bolts and Ateh would cause the bolts to loosen ea ooollag, Such would them be imeulaied, which would be so applied __ 001*9^ ADA 000647 WATER PCB-SD0000045814 /3 that it could readily be restored for aooess to the bolts or elss restoring tbs cover of th pot. It has bom suggested that the agitators or ooutaotore be used in the lend of these pote to reduce the bubble else and thereby increase the oontct between the baasea vapor 'and the molten lead. The organisetloa at Anniston have had no experience with snob devices| but It is their belief that maintenance oasts night be sufficient to offset the gain in capacity or recovery attained through its use. It is euspeoted that the shaft of such a_contactor would either distort or else out lleelf in the submerged bearing in the nolten lead if such bearings were use. We understand that the St. Louis Research Department has experimented with such a contactor in a heated lead reactor vessel. Their experience should abundantly have precedence over our beliefs. ftnCLB t FIRING BCWIPV.KT Regarding fuel in the East St, Louie Plant, we have data as followsi- Price per Billion Ilectrloity assuned at \/Z4 / K.W.B, City Ooe - 750 BTB/ou.ft. & a Blniaua prigs of 66*/* Fuel Oil - assuned at 50Be wad 7,66# per gal. & priced @ B*/gal, . Goal - assuned at 10,600 BIO par lb. end priced at |1,4S per net ton f 1.466 0.754 0.S&8 0,066 The above data and prices, excepting those indicated * assuned, were supplied by Mr. 0, DuBols in hie letter to B*BBuford and dated May 7, 1656, (The average price for 1,000 BTO natural gas at Anniston is $0,205/* ou ft. or E4.R05 per million B.T.B.) In this matter Of heat, the guiding principle should be the cheapest fuel that can be cleanly handled and whose burning equip*ant com be so controlled as to maintain fairly dose temperatures l the preheater or preheater m& very dose temperatures within the ooaverUr pot. it is hollered that fuel oil would most nearly meet the o>or* specification. 001295 ADA 000648 WATER PCB-SD0000045815 At Anniston w# hart fired with both fu#l oil and natural gas. At present, oar firing is with natural gas, firad tangentially around th# pot and through I high pressur# burners on both second prah#at#r and converter, There are R high pressure burners an the firFt preheater* The settings opposite the lead bath are radiant end hare accomplished a eery nearly perfect heat application* Whatever type of real need, it would be desirable to attain a einilar radiant setting* From our past experience with oil firing we have found this to be difficult, end with a production less than we hove attained with natural gas* Firing with oil will somewhat increase the maintenance on th pot#* It is believed that next to gar(whloh is eliminated only on account of itF high cost), fuel oil would sake for the cheapest oost* Great o&re must be exerted in the design and application of push fuel oil firing equipment in order to attain the desired production with a minimum of maintenance costs on the pots* , |TB*j 1*1*4 " MM Th# settings for these pots should be of steel plat# and shapes and supported on suitable foundations* The steel setting should be lined with a combination of refractories and Insulating brick or lined with insulating refractories* In th past we hav# Used a first quality firebrick which was backed by natural sll-o-oel. The tewperntures of these shells average #6C, which represent but will heat losses. Such linings should be satisfactory unless such temperatures would make for personal discomfort. The .Insulation over the top of the pots_ should be steel plate'work lined with sil-o-oel and designed for quick removal and replacement* XTM 1*1.6. - 9^9*1 Automatic temperature recording and control equipment Is vary neoessiuy. We have found Wilson-Kaeulea equipment very satisfactory* Similar equipment by other manafaotairera would be equally ee satisfactory. The temperature of the lead in each pot and also the vsporp fro* each pot ar# recorded by awans of pyode and a six point Wllsan-Vowulen fapalog, Th# control is through th pyoda in the lead bath which ere also connected to Wileon-^aeulsa. potentiometer controls which actuate American Radiator Company1 s aotor operated valves on th# high pressure natural gas lines to the icond preheater and converter. There Is mo temperatore oootrol . _y 001296 . ADA 000649 WATER PCB-SD0000045816 T /s derlc* oo tlx first preheater for mdh is largely heatsd by the combustion gases leaving the settings of the seoond preheater end converter* On the first preheater are two high pressor* banters which are manually operated and are used as oanditioas nay warrant to boost the temperature of combustion gases fro the settings of the other two pots* The firing on tbs second preheater sad converter ie by gas directly piped and for lat*u* requirements and without regulation* Additional gag to maintain, oonstant temperatures in the lead is passed to the same burners by the Vllsen-Maeuleo oontrol operating the American Radiator two point valves# that is open or closed. a Controls to hold constant temperatures in the two hottest potf would be required whatever was the type of fuel used* The flow of benteno to the unit ie maintained at a fairly constant rate by means of a Eohutte & Koertiag Rotameter and manuil operation of a throttle valve on the liquid bensene feed line. The euooess of such an arrangement depends on a pump with unvarying delivery* As we have found such an arrangement 00 satisfactory, it is recommended that such an installation and practice be eontlnued in the new plant* imixLAr All piping for carrying the heated vapors between the inlet to the first preheater and the discharge from the lead trap, whether submerged in lead or elsewhere ie 18^ chromium and nickel. Connections are either welded or else by welded flanges with tongue and groove Joints with gaskets of steel and asbestos and made by the Ooetse Ossket & Packing Company. The inlet vapor piping to the converter and the piping between the converter and the lead trap should permit of readily dismounting for aooese to the Interior of the pot or else cleaning the hard and dense carbon adhering to the piping between converter m& trap. Op until now we have never used valves on the pipe lines for handling the heated bmeeae or haasene-diphenyl mixtures* tlsewbere gate valves are used in pipe llnae oonveying the oold eolations* 001297 ADA 000650 WATER PCB-SD0000045817 I 4? PlimNYL OOHTKHra - OPERATION ITKY l.I.i. - TJWPKRATORJC AND RATS OF OPIOUTION fe here opereted our unit over e considerable range #f temperatures. In general, the lower the tempera tyre, or down to about VBO*C, there la but little conversion. At temperatures of 8WB, the oonveralon la about 80/, of which TO/ la diphenyl end 30/ la high boiler. These teats oeuaed ua to operate with the vapors erouad 840*0 with a oonverslon of 18/ of whloh 78/ Is diphenyl and 88/ Is high hollar, and whtob we calculated would make our diphenyl requirements at the ebeapeat cost. ' As the high boiler is with only a limited market, Its minimum production would be desirable. This can be at-' telnefi by lower temperatures and a lover conversion per peae. The benefits of such a reduotlonln high boilers produoed must be offset by the extra processing costs. Is to the rate of operation of our present equipment, we know It bs a daily capeoltjr of 3,000 lbs. per day with a oonveraloa of 18/ per pt.ee. The above production could be maintained with a fester feed of bennol, lower tempernturee end n lower rets of conversion per pass, but at whet economy la Mt kvowa, OSW 001298 ADA 000651 WATER PCB-SD0000045818 t7 , diphkktl oommrm DETAILED DI80US3I0K Of gPOO'^STO TWO POT DHItB iSLJU&i. fuel firing, oil, or. Ooal, la indloated by Its lowar post, as shows in the oompsrieon gives In this report. For the maximum utilisation of beet, heat exhanger le de manded to reoover the beat In the flue gas, In thle ease experience has shown that vaporisation end slight super besting f banned* Is a eotiefed.tory method of recovering the heat la the flue gases* On the present diphenyl converter unit the flue gases are Ilaohbrged et In the proposed unit the flue gnees nre to be disoharged at I00*C, Oontlnuoue freotlonetion of the reaction products Offers possibilities of lower cost equipment, leea off-grade products, heat eoonomy, lower losaes of materiel, and lower labor costs. Utilisation of tbe heat in the reaction pro ducts for the operation of the oontlnuoue fractionating oolusme le one method of obtaining maximum heet eooaemy* the suggested diphenyl unit is shown e e dlcgraBsiatlO flow sheet In Drawing Jf So-8+05, JliSUHSiX All hast is supplied to two lead pots fired Inde pendently end controlled automatically by the lead temperaturea. From the information supplied on St, Louie fuel eoets, fuel ell le reeomended as the cheapest, exeept eosl which offers sonpllestlons of handling end control* The flue geees leaving each pot ere combined and passed through an Insulated taek sontalulng e vaporising end ouperhestlng coll for bengat. The flue gases are discharged to waste at 800*C ' DSW 001299 / ADA 000652 WATER PCB-SD0000045819 45 The heat balance, shown also otj Drawing Re, 6o-405, i# fended m th* flow f DU lfee, of beaeene per hour which giro* a calculated production of 8,540 lbs, of dipSeoyl per day. It Id side based upon Batumi gad aa available at Oil firing should *aJca bo appreciable differmso*. ' - The total heat supplied Id TUiUl (pooel Centigrade Oalta) per hour aa compared with 1.181,040 FO,0* per boor for the present unit or t%, It should ba noted that in the prefect unit additional heat ie supplied for the fractionation of product la the fora of steam in the banana still and gas in the diphenyl Itill* I Om^MsSMsM liquid baasene at storage temperator# ie puaped through (he vaporiser and superheater ooil located in the eta oh Acre it ie converted into vapor and superheated to 8H0C The feetteeee vapor peeeee through the heat exchanger where ltd temperature la raised to iW0, Tfm the heat exchanger It passes to the first lead pot containing lead at 700 where the temperature id raised to S58C, The bensene vapor at M0 th< enters the Converter pot containing lead at 04l0 |ja the oowverter pet the reeotlon to diphenyl and high boiler ootsars aad the reaction gases are discharged at fg0 The g&see ere considered to resob an actual temperature of MX0 at the surface of the lead feet due to unavoidable heat losses are delivered through the lead trap and eyeloa carbon trap to the heat exchanger at f@gCfe lb* reaction gapes leaving the heat exchanger at 818*C pass to the reboiler of the diphenyl oolumm, supply heat for the fractionation aad distillation of diphenyl, leave at 8Rr enter the reboiler of the stripping column, leave at w**0 and Biter the heat exchanger of the reboiler of the baneene colon** the gases leave at 860*0 and go to th# condenser where the bensene d converted product mixture is condensed aad fro# which the hydrogen ie separated* The liquid at 04*0 flows into the bemsna# column la which the bensene is distilled off end returned to the bensene feed tank* from the bottom of the ooltsMI a mixture of diphenyl, high boiler, and the impurities present in en&ll mrn&t end ocatalilng a trace of bensene ie discharged as liquid at the boiling point of *W*c and flows into the stripping coIvm* la the stripping elw* the tmee of hm%m together with the iapurity which bolls eonewher btbtreea bensene sad diphenyl is distilled ff together with a astill m&mi of diphenyl, The liquid flran the reboiler at flews into the diphenyl oolmm. 001300 ADA 000653 WATER PCB-SD0000045820 /3 I the diphwyl ecltm mpur&tae the dlghmyl tram th high boiler) th# diphenyl distilling trom the top is purified material reedy for eel or production of other products and th high holler discharging froa the retailor at Its boiling point B60C* It should he noted that the flow of the hot reaction gases . is strictly ooateiMSttrreot to the liquid products being fractionated. 3eat Bolaaoo (Refer to Drawing Mo. So~40S) A* has already hem pointed out the g&e consumption te 81$ of the present requirements* The ataoM losses of the proposed wait ere reduced to 11.7$ as compared to XTeTjC for the present wait* This peroectage reduction is obtained by lowering the exit temperature frost 66 to 8009CS The actual earing in heat is greater than this due to the smaller amount of flue gases) the stack Iocs for the proposed unit being 16,770 P.C,tf*/hr, as compared with 06,600 FC0./hr. for the present unit* The vaporiser and superheater ooll is the stack is piturned to absorb 1TX,KU) ?.C*9* par hour. Instead of 167,0 F.G.?t/fer, as at present and raising the bwiiDi vapor to 16, This is accomplished V the installation of additional heat transfer surface and the higher temperature of the flue gases leaving the lecd pots* The loss by redietleo and convection from the stack and flues is reduced from 140,460 p.0,U./hr. to 40,000 P.Q.ft./hr, by insulation. the heat exchanger operating on the hot reaction gases end heating the bemsene vapor from 1Q te 48fC recovers 158,760 F,0,tf,/hr,, vhloh is sure than the heat usefully absorbed in the preheater Vo. 1 lead pot of the present malt, absorbing 107,4C0 ?CV*Ar, The high teaperature differenoe existing In this heat exchanger requires only a feu square I feet of he&t transfer surface. Tbs small sis# makes possible the reduction of heat losses te a very low figure. The heat input to the first load pot of the proposed unit is considerably less than that of the second pot of the present unit. The second pot of the proposed unit receiver approximately the ease iMamft as the present third &r oonferter pot. Site total useful heat received by the banienc vapors in the two lead pots is slightly less in the new unit than In the present one. This result is obtained by insulating the lead pots against heat loss to a Mtch greater extent than is dome at present and feeding vapors at higher superheat. Several email changes in construction are necessary to make this possible. - DSW 001301 ADA 000654 WATER PCB-SD0000045821 m 20 The m^nJLmm temperature ht the retailers of the fractionating ooluans t* 28SC in the benssna column, The calculated amount f retail host Including leases for the three fractionating ooluans was 177*000 ?*C*M*/hr, la order to keep the temperature differences high in the retail ore the minimum temperature of the reaction gaaee leaving the beaseae column retailer mu selected as 860*0, This alee serves the purpose of giving a reserve heat supply of 40.000 per hour in the reaction gages stave t80C, whloh' is still a high enough temperature for heat transfer* The heat exchanger was designed to ebr.orh the heat in the reaction gases from 7tf*C to 618C leaving the proper aaount for fractionation parpoMs* The heat in the reaction products fro R600 to the . condensing teaperature and the latent heat of the condensing products are wasted since it is believed that the separation of the hydrogen will make the fractionation easier* If the presence of hydrogen does not affect fractionation too adversely, there is an additional supply f heat available* Equina eat In no case has the equipment for the proposed unit been detailed* The following construction notes are recorded to supplement fUswlif #405* The first or preheater pot will be stade of Cruolble Iteel Company** Reaistal Mo, 7# or equivalent, with the cover welded on, replacing the preswat bolted construction* This enables the bead of the pot to be lagged* The second or ptmkerter pot will be made of Crucible gte&l Company* e Reels tel Mo* T, or equal, cast steel cover bolted on and all insulated end Mhloh hae been prsvlouely described* She heat exobanger would be constructed of steel or poeeibly *iokel-hro@e steel and will be arranged so that the hot gases pass through the inside of the tubes and the odder bense>ne vapors pace over the outside f them* the heat exchangers a the bottom f the fractionating column will be of the sane type, hot gases inside of the tubes and the boiling liquids outside. *. ... All column will be of the packed type, the taasen column using X/t* Raeohlg Rings end the others Vi, DSW 001302 1 ADA 000655 WATER PCB-SD0000045822 2i The Tnporiier and superheater will be Had of colled pip la m insulated stack, 1 solid core la the stack will fee need to obtain high flue gas velocity, fh casing should be of the Split type as previously described, ~- -. Tb setting end firing equipment for the pots would h designed to neat the fuel selected, gee, oil, or 04II. feislhle It is anticipated that there will be sat difficulty la the initial starting of a diphenyl unit such as is proposed, particularly 4a regard to the balance of the heating surface of the fractionating ooluens and the position of the feed to the oolttans. After the equipment le In adjustment it should give no more trouble than the present equipment. There nay be a tendency for carbon to oollect inside the tubes of the heat exchanger la spite of the qyolooe traps. fhiB carbon will probably be hard and should not decrease the heat transfer such. Arrangements would be Bade to sake it easy to clean out these tubes, EdL> jf-Ptein The heat balance is based upon the assumption that the specific heat ef the beaseae vapors end reaction gases are essentially the sane and is given by the equation p = g6 * 0,000076 t(C) The prellalnary *qulj*e*t design Is based upon the foregoing specific heat and upon the usual heat transfer coefficients applying to sinllar problems. The validity of these relationships has bean partially verified by data furnished by the bow Chemical Company on their diphenyl unit in connection with the patent suit. The fraottoaatlon calculations have been made using Recruit* u Law in the oase ef the bensene eoluan, and experimental data for the diphenyl oolttna* These data are not as ooaplete as could be desired. It is reeonmended that development work be don to verify the specific beat, beat transfer, end fractionation relationships before the final design and installation of the equips sot should*lhe suggested type of continuous separation be adopted instead of the batch operations in use at present. This development work seed not be DSW expensive or lengthy. 00L3Q3 ADA 000656 WATER PCB-SD0000045823 22 Sarisutf The ooabiaatioa of two load pg%te m beat exchanger* md continuous freotionating equipment using the hat In the gae**, as hap bee* described* gives the lowest calculated operating oust* This represents a eevlag of 0*84 coats per lb, over our present praotlo*, fhe oo*binati<m of two lead, pots* a beet exchanger and replaoMHHit of the present b*a*efte still by an improved continuoup oolusn gives a calculated operating ooat 0*06 oeate per lb* more than the design using continuous fractionation equipment* la these calculation* no reduction in labor cost* have been apswssed because of the difficulty and uncertainty of arriving at a reliable figure* There seeae to bo little hope of reducing labor oopte with the present type of equipment whereaB the continuous type of equipment definitely offere euoh a poeolbility. 0* a production of 1*000,000 ib$, of diphenyl a year the suggested equipaent* shown on Drawing 8o~t40Se would save | 5*400*00 per year. ^* m/iw B/it/86 DSW 001304 ADA 000657 WATER PCB-SD0000045824 -?jr PpagmtS MMlMlhin Of HATDRAXi 8A3 AT ST. LODI5 This 1 written after the receipt of Mr, Livingston'* letter of June t4( relative to natural gas b<J direoted to Mr. Hewn, >d also after writing our reooasnsndstione, at which tin* ws did wot know that natural gas might be available. It ia Interesting to learn that you now hare esellsat prospects of buying atratght natural gas (1,000 JW) at at St, Louie for SO^T per 1,000 ou. ft. Tar the firing of the diphenyl converter unit, natural gaa affords a nearly perfect application of beet. v Keturol gaa coating 50^ per 1,000,000 BTU with Its high efflolenoy end ease of handling end burking would probably h* well In lino with fuel oil at 2,6/ per 1,000,000 BTO with its lower efficiency, greeter expense Of handling, storing end burning end the accompanying greater cost of Maintenance on the lead pots. . is to the Monthly gee requirements, we refer to our May, 1*35, production of 80,000 lbs, of diphenyl. Using the average gas tost per pound of diphenyl produosd for 193B up to June 1st and an overage price of gas st 80.ty par 1,000 su. ft., the Monthly gea requirements art 140,000 ou. ft. About 90jf f this gas le used on the oon&estor unit end the balance for distillation purposes, , If the suggested two pot unit with beet exohnngsrs, aad contiguous aeperstion devloea, ere Installed, Monthly production of is,000 lbs. of diphenyl would require @3,000 eu. ft. of gee. The matter of natural gee pressure is of much Importance, All of our burning equipment on the diphenyl con verter unit, stills, etc,, are cf the high pressure type which require natural gaa under e aervloe pressure of BC lbs, per sq. lack. DSW 001305 ADA 000658 WATER PCB-SD0000045825 24 bkpjwatiqx or products - pum bestow l.u.ITEM - EQUIPMENT m StfPARmKO BEKZOIr-DIPHEKtL- HIGH BOILER MIXTURES The vepare leering the converter unit enter freo~ tlenetlnf oolumn, which remorei some f the diphenyl end deliver* mixture of 00-*7B^ oonverted produoto end bennene to etorage teak* prior to distilling for the further renoral of the honfceue* There 1* still for distillation ef diphenyl end also a still for refining the high boiler. Excepting the ona fractionating oolwmn, ell operations are batch, There ceeme to he no good reason why eueh dletilletlon eottid not he made contlnuou*. With large production, tba desirability of continuous operation would he more apparent than on operations ae limited us at present. Itaa 8.1.1. - STORAGE OF BEK^X^mtmir-HiaH BOILER Be have no epeolcl adrloee relative to the storage of benxol, tiphenjrl and high boiler. At present we store the heoeol and high holler in overhead cylindrical tanks and with entire satisfaction. The liquid dlphenol from our still is eeught la rsetsngulsr pans, where it solidifies and ie then dumped out, broken end peeked into containers, either for ehljnent or for further processing. 1 better arrangement for handling the dt phenyl would be to flake on e ehlll wheel or in a etorege tank, lnewlated end with eteea soils. OSW 001306 ADA 000659 WATER PCB-SD0000045826 To beat comprehend the no* of boat in the converter Unit, a boat belenes wee recently made and a copy of which ie Bade a part of this report, Thie beat balance will not be dieeueeed here, except go point out means of obtaining greater heat ' eeonoay In the neir plant. It would stem that fuel oil would most nearly seat the conditions bb eat out in Item 1,1,9, The oombuatlon gtis leaving the pot settings should be wore fully utilized In Vaporising the bennene t nd superheating the TOpor, This onn be attained by inaulrting the setting of thu bent exchr.ngsr and also building the axobeneer of such an area that tho. utmost In euperbeat oan be imparted to the Incoming benzene vapors. The insulated cbm on this raoalver should be of the eplit typo, eueb a re uee on tbe diphenyl still, in order that it oan he opened up quietly at times of shut down, benzol failure or otherwise, end thereby prevent dtniags to ihe heat axchtnger, 3uob a split use males the ooils of the exchanger readily aooBseibls for lnnpection or repairs, ' The tope of the pots with ell connecting piping should be thoroughly Insulated, There is n lnrge emount of heat in the vapor leaving .tho Converter unit, A suitable exahonger will sot* part of this heat by further luoreneing tho superheat in the incoming benzol vapor end thereby reduce the fuel requirements, Buoh as exchanger is reoommended, from tbe partial costa as shown in Item 1.1.1,, the selection of the equipment narrows down to either Arrangements ho. 8 end No, 3 with the bennol still eliminated or els* Arrangesent No. I, Of Arrangement No. 8, It sen be said that it is the old three pot converter unit, sddended by tbo heat exohnnger and with the oolumn ehenged so as to eliminate the benzol still. The system would be continuous except for the separation of the diphenyl and high boiler which would be done in batch equipment. In this design there is little of th? experimental end would wake for e good operating plant. OSW 001307 ADA 000660 WATER PCB-SD0000045827 2^ Arrsngement Kfl, 5 Is the bom 00 Ko I hut with one of the lead pots eliminated. The economise between the two errengemente ere alight. It would sasw that a decision between the two would have to be deferred until the fuel end firing equipment hrd been worked out, If the present three pot setting oan be oonvsrtsd to the now fuel with but little obenga, Arrangement t Should be need. On tho other hand. If new seitinge ere required for proper firing, then Arrangement 3 should be followed. Arrangement So, 6 le designed for the ultimate In hsnt soonoay end for tho oontlnueue eeperetion of the benwenwdlpbsnyl-high boiler. The heet efficiency of the unit would be 60/' re oompared with 49,? ettalned at Anniston *t present, A further use of the heet In tho report would be to etteln the desired continuous separation In columns. We bars never attempted mb eepi'fiitlon but ornnot see a single reason why It would not work, Before such an installation is mads, It la rsoommendsd thot suitable development work be done prior to the final designs. Should a production greater then thet of tho present Whit be desired, riud In combination with continuous separation, sueh might be attained by two or more sets, weeh of two lend bath pots, nnd connected to e single set of oolumns. High boiler, its disposition or purification has not been previously dlsousssd. It is believed thet whatever of the refined product le desired, thet it Oan beet be made On the btob still thet we are using at present. CRMoO/JW /iV/85 OSH 001308 ADA 000661 WATER PCB-SD0000045828 It* following relates. to the pr88t pleat tad its operation. QfcPftOjLty - 1148 U4| 1164 ueo uee lief il 8666 4066 6060 Capacity per Ohlerlnator oer loath 06,096 lbs, . 604,000 Iff,#09 m, 600 m, so 166,000 186,000 146,600 . 148,600 m,660 There are three ehlorlnators as Shorn on Drawing #0~f#8 Ieoh of these is reserved for certain eonpownde, namely Io. 1 for 116# and U6#| Io, i for 4066, 6060 and 6668 attd Io* 8 for 1146, lit#, 1164, 1160 and 1168, The io, 1 ehlorinator an be Operated eoatisttouely, Chlorinators Be, 8 and 8 cannot both be operated at the $me time as ehlorinator*, The present pro otto ie to chlorinate in one while the other eervee as a catch teal;* . The saistbly capacity of the pleat would be the apaelty of obloripetor Io. 1 asking Arcelor* #1181 and UW either singly or in ooabinatlo plus the capacity of Chlorinetors I 8 or Ie, 8 Operating singly to produce those Aroelors, siloted to the individual ohiorinator, either singly or la eoabiaaliea. flhlorlaetpr* The following desorlptlon eaa be aost easily followed V referring to Drawing #C-6St, DiagraoMtio layout of Chlorinating Bqnlpmmtt The chlorinating equipment la e at the preeeat tin# ooasltt* essentially of thros I ft* in diaaetor If ft* steel ahelle t vertically. Each shall obtains a O&tfilyst atsi f Irm turning# aoloeed la a 6f* diaaeter by I ft. long steal aleeve* & oil of l8 nrooght steel pipe in provided U tho annular ipaoe between thfe' ; ~ oeialyst sleeve end dhlorlsator shell * Shis coil is connected'to ' Wo either rtw r water m r#qwlre4 - . , osw 001309 . ADA 000662 WATER PCB-SD0000045829 Chlorine le fed late tie bottom of the ohlorlnator directly beneath the oaialyst mas, The rising gee oauses circulation of the charge 6 A oeatrlfngai pttap la provided for each ohlorlnator for additional oLevalatio ifcioh withdraw material fr<m the bottom sad delivers It to the top, Each ohlorlnator is reserved for a certain olaea of product*, Me for 1168 end 1168. another for 4866, 5060, and 8666, end the third for IH*, 1148,1164,1160 and U*2, Shis is a very neoeasaxy preocmtlon else the catalyst mass le almost impossible to oles end idxiag one Aroclor with smother Is detrimental to quality-. This is particularly true of mixing eve slight amounts of the crystalline Arodors #1166 end 1169 with the others. She ohlorinator for 316 aad 1160 la provided with an emergency internal chlorine supply pipe einoe continuity of operation on this notarial is almost easentlal, foto Imk.aad JrflM _ The ohlorinator for 316 and 1168 is need dependency of the other two and is provided with its own trap and Belting tank. Only Me Of the other two chlorinatore is in opera ilea at a time, the other being used as a trap, (foe melting pot serves the ether two ohlorinstore, IMuM A blowing tank equipped with a steam coil end air distributor is provided for all chlorinated products except 1168 Mid 1168, The air blowing removes the HOI, The Belting point of Aroolore #2168 end 3168 te too high to permit air blowing in a steam heated task, Chlorine Is received in liquid for, at the present time, and Ls converted to vapor as needed la a steel tank heated by hot water. The necessary piping Is provided for HOI fas from the chlorination which is passed through a trap and then to the HC1 absorption ejstwu OSH 001310 ADA 000663 WATER PCB-SD0000045830 29 MMLMma At the present time all products ara dram off lato steal draw for storage prior to further prooeasiag or shipment* This method of handling 1 Tory unsatisfactory because at the large mount of ftps* released* - JAW- '* la general all Waites on the chlorine or BOX Uses are lubricated Meroo-Bordstre plug oockE with screwed connections and walrett oo the liquid lines are all Iron clip type gate volres* 11 equipocnt la the Phlorinator step is eteel or Iron* flfrpulatltyi The bottom half of tho chlorin&tore la lagged with 2* of 65 sagsesia, the blowing tank and melting tank for materials going into JLroolors #1169 and HOP are insulated In the ease my* She pipe lines from the two melting tasks and the lines to the blowing tank are etnas jacketed* pTBWlMS The following drawings of the present chlorinating equipment accompany this roporti layout f Chlorinetore Siagransatlo layout at Chlorinating Equipment 0G~$$55 #0~63 the following relates to the suggested now plant and its operation* jMoriautttrfl fhe present chlorinetors work eery satisfactorily It it suggested that the present three chlorine tors be need la the new plant* melees the requirements are very large* and It was decided that a fW larger wait were preferred to a larger nriaber of units ef the present sis. D5W 001311 ADA 000664 WATER PCB-SD0000045831 3o MLrtagJtokajaOtfiaa ' It would be Tory desirable to provide aob chlorlaator with its individual trap* 0uob would enable aoh ohlorinator to operate continuously on its allotted onpownde* The production of Aroolors #116 and 116 would remain the ease as at present but the production of the other Aroolore would be twice as great as It is at the present tine* The HC1 trm each trap would then pass to a ooataoa trap before passing to the BC1 absorbing systM* These tr&pe are of u* improved design and are arranged to drain by gravity to a catch tank or to the diphenyl aeasurlng tank* - - . the-HOI trm each trap then pastes to a cosaoa trap before passing to the HC1 absorbing syst** These traps are of an laproved design aad arranged to drain by gravity to a ootch tank" or to the diphenyl seaewlag tanks* Two dlpheayl araring tanka ere provided and the present welting tank for 1169 aad 1169 is reooantoded as a oatoh tank. This Involves the laatall*ticm of m additional prop* Tbs present tank is satisfactory for uaa. It a new teak were to be installed a txucped botton would beasocaaaodsd* JMsdaiJfciute It is asauaed that gaseous ohlorias would be available at St, Louie and the vaporiser Is oaitted* ) aSLMem&al The use of a trap for eaob chlorinetor simplifies the piping to the KOI absorber* The HC1 gas obtained contains a snail amount of organic natter which should be removed for the product!oa of the highest quality R01, osu t2$a&LMmM 001312 Products are expected to be stored in tanks or bins in the piece of dnu as at present. This Involves the installation of an additional ptmp for the blowiig burtu ' ADA 000665 WATER PCB-SD0000045832 Mm - liPoo-^lordstrea lubricated pltsf oooke will be used on all repor line# tad all iron gate walfes on liquid Unas as before. Insulation All bank* and traps abould be lagged tilth g* of 16# magnesia. The bottom half of the oWLorlastore Bhcnild b lagged ae before with of 15# magnesia, the pipe llsea to and from the diphenyl salting tanks; the oatoh tank; and the pipe lines from the ohlorinators to the blowing tank.*111 be steam Jacketed* ' praiinis fuggested layout of Ohlorln&tors for it, louie Bo~2404. DSU 001313 ADA 000666 WATER PCB-SD0000045833 tmtAMkMamsm touaiJaatemi The Ml absorbing equipment is eaaentially the usual fused eilloa absorb* in which the BOl gee la dissolved la water and the heat'dissipated. Tb* installation la designed principally as a Means ef, disposing of the HC1 which la formed in the chlorination although, of course, tha hydrochloric add la sold wbwever possible. Tha HOI gas leaving tha final trap of the chlorination equipment la carried by a t* iron pipe ltna to a horlaoutal 16* O.D. x 4fe" a teal draw which serves to aattla out gone of tha organic natter and solid Inpurltlea, Tha g&a then passes through a 6" ataal pipe to the botto of a vertical steal cooler and filter 84* 0*P. x 87* high which Is filled with coke* A riser of fit# lengths of 6* bell and spigot terra-oott* pipe, approximately 10 ft. high carries the gas to the fused silica absorber*. The connection between the terra-ootta pipe and absorbers is made by two lengths of 7" O.D. bell and spigot, sllioa pip forming a trap with drain ahiob leads to the pyrax cooler* Tha HC1 gas passes in series through 15 sllioa absorbers arranged one on top of each other. At tb# top absorber .water is added which flows oouater-currentiy to the gas and is finally discharged as fcydroohlorlo acid tram the silica pipe connecting tha absorbers with the terra-cotta riser. The hydrochloric acid flowB through a cooler consisting of i - 1* Pyrex tubes water Jacketed for 4 ft* each arranged in series and is discharged into a snail brick lined catch tank or box. The cooled acid than flows by rubber lined pip and Tairas to a rubber lined steel tank of 80,000 gallon capacity. The gases learing the top of the sllioa absorbers is oarried by 6* terra-ootta pip# to the base of a drowning tower 18 ft* high, oouptruoted of terra-ootta ball and spigot sections 4* O.D, The drowning tower is filled with ooke and is supplied with water which overflows at the bottom to a drainage ditch. A Durirtm fan is located at the top of the drowning tower to pull the gases through the HOI absorbing systna. DSW 001314 It seems to be praotlbklly Impossible to keep this equipment tight with the result that hydrochloric acid of various strengths is spillad over tha various pleoes of oqulpneiit* To protect the steal supporting structure and the steel equipment, it is covered by a heavy eat of tar. Shi sews to work vary well. ADA 000667 WATER PCB-SD0000045834 The hydxoohlorio acid made 1b yellow la color and ooataine a email amount of organic Batter, Semples of this aeld have already beoa sent to lonnanto Laboratorlea la 8t. Louie for examination. It le understood that It la planned to combine the HC1 from the chlorination of diphenyl with HOI derived fro operations already operating in St, Louie. Accordingly no plans have been mads of BQl absorbing equipment for the St, Louie location, - It sill probably be accessary to Install seat type of filtering apparatus to remove the organic impurities U the HC1 before absorption, A fine coke packing win probably serve this purpose. i CM/lw V86/86 OSH 001315 AOA 000668 WATER PCB-SD0000045835 54 M0TK3 OH AROOLOB DISTILLATIOH BQ.DTPMSMT m\ aboplorb bo. ib4e, ie48. igS4. imp. 3.888, 1808, 4465, P46B Tbs following notea relate to the present plant, Tbo equipment for tho dlstlllettoo of nil distilled Aroolor* except 1888 and 1B6Q aonslsts of a vacuum, plpe-stlll type, apparatus wltbout a fraotloneting column. Pot detailed description tbe .following divisions sill bs uasdt Refer to Drawing fo~683B, 1. Malting Tank . Kettle 5, Qulmby Pump 4, neater B, Fesa Trap 6, Condenser 7, Receiver B. Blending Tanks ,0, Filter Press ' , io Add Scrubber* 11, Vacuum Pumpe 18, not Aroolor Circulating nystsa 13, Wllsout-Meuelen Tepalog 14, Mieoellaneoue . 1, Melting Teak The melting or charging tank la of steel 8* diameter by 3* deep with a l'l* oone bottom and holds 176 gallons. The tank le heated by a simple ring gas burner on the cone bottom. It la filled from drums lifted into position by a obaln hoist, and la dlsohargad through e I l/s" gate valve and pipe Into a funnel con~ twining a 40 mesh strainer. The tank Is legged with tn of Xegle-Ploher 0ament Ho. 86 end le fitted with e tight steal oover eonneoted with an exhaust fan to prevent eeospe of fumes Into tbo work room, lj Kttle The kettle Is a oyllndrlool steel tank SB11 la dlometsr by 3' high, set vartloelly, with rounded top and bottom, with a distillation charge oepeolty of approximately 175 gsllons. The head of this tank has connections for the obarglng pipe, vapor, drain from foam trap and superheated liquid from the banter, ... - *' ' The charging pipe Is 1 l/l" steel pipe Jacketed to allow circulation of hot Aroolor 1148, Close to the kettle is a 1 l/t" Mtroo-JJordstreta lubricated plug oock. osw 001316 ADA 000669 WATER PCB-SD0000045836 Sf The vapor pip i@ 4* sad is oonnetd by a Haag connection to th aonel aetal pipe leading to the foaa trap, .' fh drain trm th foa* trap 1 a me laoh pip* leading throng th* head to within on inch of the bottom of the kettle* The line carrying superheated liquid Trm the h'taW boil i I* teel pipe jacketed for hot Aroclor, There is a Tent pipe eloped by a Meroo-Sordeiro valve oq the tide of the kettle seed for charging, JU_JbibUta Shie ie a Qoiaby Vo, 6 jacketed eorew pwtp with & oepaoity Of 6 gallotts / slant# drive at 1W RFJB, by V~belt drire fm & S H,P, Motor, the pomp ie red by a 1/t* jacketed pipe 11a from the bottom of the kettle. A et**l fate rely* is located in ' this line close to th kettle, Th jxap discharges through a l/t* jacketed steel pipe which is reduced to l6 jnst before it enters the beating ooil, -4 fester this eoeeists ef helical soil of 1* steel pip 8* disaster (to pipe center) oateining six turns, eaoh tar approximately 1 from the other. The ceil is plaoed la a cylindrical jacket and is heated by a Surface Gembustlo, two ring, low pressor, aaliiple jet gas burner of 00 on, A. per hour capacity, The ooil is joined to the pipes leading to and from the kettle by gromad joist wnLcmi, At a short dlstaao# above the union, a l/i* pipe nipple ie welded to the pip coil. The nipple la aloead by a sleere connector and plug* This is seed to sweef oat the heating ooil by removing the plsg end allowing air t carry cut the liquid as it rushes i&to the evacuated quipssat, J steal sate valve ie inserted is the line directly before it enters the tm. I* - Jfena ftm Thie is a device made of 14 gauge nonel metal. It is located on th top of the kettle and If interposed Hi the vapor line between the kettle and oendenser, Externally It is cylindrical in shape XI in diceter Mi 19 high. The Sjfeaer oor if also of monel netad ft in diameter and 4e high having a welded cover and a scalloped lower edge spot-welded to the bee of the outer shell. At the center of the bottW f the foa trap there is a l8 pip leading to within p of the bottom of the kettle. The vapor line connecting the fon trap to the kettle vapor flange ie f 14 gang# nooel notal 4* 0,V, d eaters th foes tre^ tangentially fear laches fro the button* . QSW 00131? M ADA 000670 WATER PCB-SD0000045837 Tb rotary motion thus imparted to th vapor lead to separate the dark colored entrained liquid which flowe mtdmv th lamer oor, through the one lnoh pipe back to the kettlm, Ihm vapor paaae* from th fom trap through 4* 0,8, flanged monel pipe which ie connected to the oondeneor by two Wfln.aaf4 eH All flaagne of the foam trap assembly are welded to th pipw, g^jEaadtanmi '. this le a It ft, length of 8 S/t* monml pipe soclosed by e Jacket of 4* steel pipe* 1 reducing flange connects with the flanged ells et the inlet. It inclines at approximately 46 to discharge Into the eight cylinder located m top of the receiver. The eight cylinder ie of Fyrax glass 7 l/f* 08* x 7* 2,8, a f* long get la two grooved eteel flanges with Preach type Qoetie lead-asbestos gcakete, h--M&akm. This ie a steel tank 80s in dianchor by 88* dop, lie rslls, bottom and cover are Hoed with monel metal, A on inch galvanised pipe line lead from the bottom of this vessel to the blending tanks, X deme of eight inch steel pipe 4 %/t ft, high is welded into the top of the receiver. This dome is lined throughout with monel metal. The top ef the dome has a 8* nipple welded la which connects through a cross to the vaoum pump linet mercury gauge and compressed air supply. The dona ie for the purpose of coollag the-vapor leaving the rooelver end reducing the stoppage of the vacuum lime by sublimate, '- I. Billing tanka. Two galvanised Iren tanks 60s diameter by 45* deep art need for blending. The product is transferred fit the receiver to the blending tanks by compressed air. The blending tanks are equipped with * Lightning* agitators for mixing, 2.. fUtir firm This ie a 18 inch brass plate and frame flpmrry press. Filter doth backed up by tfhatmam lo 1 filter paper is used to treat all liquid Axoclor* The pres is heated by four eleotric strip-heatere# two on each side, iroclor is forced through the preac bf m Obardorfer So, 7 braes hwrring-bona, gear pump, DSW 001316 ADA 000671 r WATER PCB-SD0000045838 Caring distiHatieft a meH morni of hydrochloric acid is formed by decoapoeltiaa., which east be scrubbed out to prevent damage to the v&cmm pomp. two Scrubber* ata^X ?E* high by |4 diameter filled with coke soaked with tOf oaastto code, solution art plaoed between the aystm and the va<nni pmp These are arranged go that they say be used alternately* to permit olmmAng without interruption to AlatlUaUoa. ' Ionsally the system la exhausted by a Wheeler three stage TubeJet Taow Funp. 4 Berime motor drift reciprocating ramus* pump 1b also installed for a'errioe whenever our Mall boiler its abut down* Aroolor 114l is used to beat rariou* points of the system. This is heated by gas in a tank t4* diameter by E4* deep and circulated by a l/4* American Sarah Centrifugal Pomp* Hot Aroclor is supplied as needed to the following pointsi ' (a) focketed lines from kettle to Quisby jraap and fro ooll to kettle 3 jacketed charging kettle Quisby poap jacket Qoisby jwsp packing gland jacket This hot oil circulating equipment with its open heater Is of a typ feioh should not be installed in e new plant* This is a six point recording pyrometer* Two points etch are used at the inlet and outlet to the o@ll# erne in the foam-trap end one in the reoeirer* Baby Fyoda* (thermocouples) are used with this lnetnwsnt* Qostse io,, E gaskets node of oopper and asbestos are need ea all of the flanged Joists of this apparatus. OSH 001319 ADA 000672 WATER PCB-SD0000045839 the discharge part of the Quimby poop is connected to a I To# which la tom oonneets to thw4*ekbm4 i' pip# leading to the haatlag coll and also to a 8* ire plug-cook which eerroa to drain off still hottow* or residues The preamt practice is to ecOWMlete approxiaately g&0 lbs* of still bottoms and fchaa to gaint&ia this m&mX by periodically drawing off the ealeulaied eocrasalaiitm ter this walm, It ia strongly reoossneaded that a draw-off he located la the aide of the kettle snob that 500 lbs. of ?till bottoms will be amtoaatloally maintained ia the ketil, -- . It would be possible to wot* the prascnt vacuum distilling equipment to 6t touts and operate It; as at present; producing both "liquid* and "solid Aroclers with a capacity of approximately S,000 lbs, per day, . If; however; there is the prospect Of an increased dmand for distilled droolers; then it is suggested that the present still he installed at Bt, |oois, equipped as ahoww in Brewing Bo, 8o~2406 for the production of * solid* AroclorS; and a new still be ia8 tailed with a win lap** capacity of 10,000 lbs, a day of the "liquid* Aroolors; as shown ia Drawing Bo, Bo-1405, ft ie very deairable to keep the 8solid* and liquid* droolers separate throughout their manufacture, A small entrant of contamination f the *liquid* Aroolors by "solid* Aroolors will seriously impair the quality. This is particularly true when the contaminating eaterial is crystalline. When the sane still is used for both solid and liquid materials it met. he cleaned rwry carefully ihm ehaaglag mnx frm me product to the other, This cleaning operation is time ooneumiug end wvem with the greatest of ware eooaSiemal ooatasinatioa will ocstr, Aalid_AoalMLJg.Mll (Drawing Bo. The only changes suggested to permit the use of the present still for solid* Aroclore along arei the Installation of a Farke-Oremer heater, or equal, with pump, etc,; for the hot Aroclor U4| to be olroulated in the pump jacket, pipe jackto, melting tank, and condenser jacket. This replaces the crude outfit in use at the present; iaprovtment of the melting tank by the use of hot Aroclor heating ooils in the plaoe of gas and a mechanical mixart better design of gorubber for removal of HOI from the gases going to the vaeuwm pumpt addition of a 10,000 lbs, blending tank for solid" Aroolors alone, DSW 001320 / ADA 000673 WATER PCB-SD0000045840 The denign of this still is ehona la Drawing #8o-406, this drawing show th general layout and principle features lo dotail of tide still hare been prepared* The essential ohaagee proposed for this still a@ oewpared to tha present layout arat ' li Tha tuia of BO,000 lb* atorago tank foodlng the measuring tank and etUl# replacing tha present mas&tisfaotory handling of materials In dmo t. The mse of a ftaan heated neohanioally stirred measuring tank replacing the present fae heated unstirred tank ft* The oee of an internal foam trap in the atill kettle* 4 1 Byron-^ackeoa Peap replacing the Screw Typ Qoiaby fmp* A more compact and better designed condenser. 6* A better designed reoeieer permitting dlecharge by a pmp rather than ooapreeeed air* T A better designed and more omvenieatly located Scrubber for HOI. IX Two 10,000 gallon blending tenka need solely for _ 'liquid* Aroolore* . i Improved ventilating eyaiigw B/H/n OSW 001321 ADA 000674 WATER PCB-SD0000045841 40 Arcelor o XEW Is the product die tillid from chlorinated diphenyl with a chlorine content of A brief history of these operation would. probably be 1* order# The first distillations were Bade la email steel pet* fired by gas* A satisfactory product was nade, but there was *uoh decomposition with low yield* To Improve the yield, w next sonstreeted a wit consisting of & oast Iron pot with thick sides and bottom. the inside of this pot wee completely machined so that the heavy plow type agitator would sweep within l/6* of the entire interior surface* Firing was done with gas* This arrangement increased the yield but carbon building up and adhering to the shell would very often stop theagitator, Shis still was soon abandoned in favor of the proeeat type of distillation equipment which gave higher' recoveries with greater ease of operation. The present still oonsiets of e steel pot with a launder on the Inside of the bell* There is a drain from this launder to the flaker (foHeerly to the quenching tank)* She pot has a removable oover with a vent* The firing is by gas* The suggested plane for a new plant as shown on our Drawing #Bc-*40? proposes a tank, lagged and heated by circulated hot oil or one of the iroclore, for receiving the batch fro* the chlorinetors* Material fro* this tank would be fed to a flaker* fro* which an elevator would elevate to an overhead bia* The above drawing shows a bin of GO,000 lbs* capacity but this an be varied according to operating schedule. . the flaked aaterial would flow to the still pot* which rests mi a platform eoale and fro* which the eocaot weight for a oh&rge it determined. In a similar way, lime is added either fro* a bag or el&ilar device. An alternate way of charging the stills would be to ran in nolten crude fro* the heated storage tank* tlinoe the ohlorlnators require 40 hours to produce 7*600 - 9,000 lbs, of crude and th stills have about the seme capacity some of the crude would be stored hot for about 40 hours* Orode 1161 and 1169 held slightly above the waiting point deoonpoae to some ewtmt* Ihether this amount of decomposition would be appreciable or not is not know* ' OSW 001322 ADA 000675 WATER PCB-SD0000045842 4/ i Conversion f th liquid rod chlorinated material into either finished product r flaked olid fern as rapidly as possible stems tbs most advaetagooue procedure. After a ohlorinator batch is dumped into the storage task the flaker would be started* As rapidly as stills became available moltea material weald be run into them until ell liquid crude was exhausted* Stills would then be charged with flaked material. The stills filled with e batch ere elevated and conveyed to 6 steal setting limed preferably with insulating refractories. These insulating refractories are especially adapted to such batch operations beoeuse f their low capacity for heat* Firing may be by. any fuel, use that which la cheapest sad most convenient* The material dietille out and la flaked on a chill wMML fro which it passes to an elevator and overhead packing bin* Zm these operations, off grade product ecmes off fit both the start and at the tod of a batch run. It is necessary to divert this off grade material from the chill wheel* For this purpose we use a snail vessel with spout. This device deflects the off grade product and prevents it reaching the chill wheel* At the end of the run, the pot with coke, lime, etc., ie lifted fro the setting end removed to an area where it can be opamed end cleaned* All eoatraction must be tight so that a nlataa of dost contacts the operators* The room housing this equipment should be well ventilated both because the stills ere hot and as an extra safeguard against dust* Operators in contact with such dut say develop e severe form of derma title* ~ These operations ns above described are far fro ideal* The bfttoh requires doge matching to prevent off-grads products mixing with the good product at the first end last ef each distillation* this splitting ie entirely dependent m the operator, his cart and visual observations. Another factor complicating operations is the sudden decomposition thst #oours at the end of the distillation. The gas evolved osatAaf large eaomts ef acid forming vapors and also so# ef the 4odSbxr l#f as as extremely finely divided dust i&ieh is dltoolorod ssd decidedly mold, Eftrti made to collect this dust end rework it have not bees successful* Our operations at present ere to discharge these decomposition product* through an exhauster end into the atmosphere. Suoh a procedure 1 a more populous eosammity might cre&t a auleamoe* ' OSW 001323 ADA 000676 WATER PCB-SD0000045843 A better method la desired for cleaning th# ooke and Ham ri<t# wt of to# pot#* At th pros sat time th* dQ8, tightly, adhering maea la chipped out with hare or dislodged by pounding m the pot* the still pots seal# and distort as a result of the residue and are battered h/ the cleaning operation. Vetting the resides has been tried hot did not facilitate their removal. facm* dia tilla ilea has hew easidered hut certain complies ties# prmBmt tfaeueelvoe, The cleaning of such a mmm still would be a serious problem, for if distillation were carried only to the point where the residue would rat nt* the recovery would be low* The material sublimes readily and my air leakage would quickly cause a stoppage by the sdbliaed material* Then too the hold point is very close to the boiling point under reduced pressures* . Data os vacua distillation as done by the laboratory are as follows t- Hold Point of Batch #181 Charge 166 0 field 648 6 Ttesidm* IE 0 Total Distillation Tine - 841*0 s 0 4$> " IS mime. or 89 Cy'mia# MjIW&UmJmmm. 1st gram (approx,) 10th e its 176 m Ut r _ e Actual Reading 840C tS8 66 166 864 870 Corrected for Blast Expoeure 46.6*0 E66,T 68.1 867.1 861,8 74.8 PreBBUre 8 mim. 7.5 * 7,6 7,6 7,6 7,8 w Deoomposed at end, coming over dark* Sharp rise from 166 to 70*0 with little coming over. 0r layout, as show on Drawing So-840? makes mo provision far either general ventilation ef the departeat or for the collection end further processing of the product diecharged from the still at the end ef the rm for general rows ventilation we would suggest diee er propeller fane. For the oolleotlon ef th fine duet, decomposition products, etc*, we would recommend hoods, doot-voxfc, collector* etc,, connected to an exhaust fan* . OSH 001324 ADA 000677 WATER PCB-: %, The choice of a collector for this, aerrloe la a difficult oat. Tbt material la acid and th Of particles approach that of fog particle*. tool doth la quickly destroyed, To ua It imi likely that the enooesefnl oaileotor alll be a eorub tower. The material caught la thie tower would them be reworked to Improve the yield. l II t t -j J I ; i ( !1 **% /*a a>/vg DSW 001325 ADA 000878 WATER PCB-SD0000045845 44 wmMjjmmajmmiiMMm mjmmmMmEmumMi n r" - -- - - 4 layout 1b pint of the bov pleat* is show m Drawlag #&o-S40f, This layout show* a building 60 ft* wide by 800 ft, long with loading platforms and walkways oa the side, The boildiiig should be of fire-proof construction with the various unite separated by fire walla, There say be approved door* la thee* fire wall* bat bettor arrangement would) be to have the fire walla without doore but with access to the various room through doortrleading from the tide platforms end walkway. The handling of heavens vapor at high tempersturep end la equipment fired with fas# the dlstllletioe of contorted products by direct fire aad the storage of these products might em to constitute a decided fire and explode* hesard, These dangers ere rrer present but-the equipment ie eo designed and operative are so arranged that there has sever been e& tacplo<dt and only a few small fires in old equipment Which ban' since bea replaced, &vesfrtha past two ye&rs.wsd with equipment as installed, there hea never bee* a fire or explosion. The layout ee shorn tat Drawing #8o-40 is arranged to keep the following in sled, saaely, (l) The beueene feed tanks, which hold considerable benieae, would be in aa isolated building, where if a fire did occur, the d'.Kige would bo at a aiaiema end no dosage would occur to the processing equip*eat. The Bala storage of bonsai would be located t e safe distance from the feed tanks or else under ground sad to protected that damage would not occur if a fire took place in the feed tank house, (} The oonvortor unite are shorn in one end of the building and,in snob a way that extra Waits can be installed in an additional bey of the building end thereby readily admit of future supsafloQ, Capacity of one unit is B,SOO lbs, diphenyl P*r d-7* OSW 001326 ADA 000679 WATER PCB-SD0000045846 (8) Titm Znetnmmt m& Control Room and the iphessjri aisd High Boiler Storage are edjooent to the ooovsrter traits, md the epuce allotted In the center of the building (should be aapl $vm for future and large production, (4) The chlorine tore are ahown in e rather large room JUi ahlch considerable other chlorinating equipment oould be installed at a future tine, Bqulpuent shorn dotted would enable the production to be doubled* Should the equipment ehoim as dotted be iuetalled with telco the eap&oity of the present equipment, than the chlorineting ospaoity would b* three tine that of the present chlorinetore, each with its ova separate trap# (For capacity ate Schedule under chlorine tors) If a production, great? thm that of throe tines three chlorinetors with separate traps etm lie -foreseen, then sore building space should be allotted to the chlorine tors# A Chill wheel is shorn in the chlorine ter roc. This would flake either diphenyl froa the storage tanks or else oertaln of the chlorinated diphenyls from the chlorine tore, for either e&lee requirements or future processing# (6) The distillation equipment for the various krocXom ar shown in two building sections and adjacent to the chlorinetor , The space Allotted would provide for a production of 190,900 lbs, Aroclor #1269, 500,000 Ibe, liquid Aroclors end 60,000 of solid . Aroclor*, other than 1266, per south. If larger productions are Bow foreseen, then greater space (hould be allotted# Future expansion could also be attained by installing equipment In the Karshouee Section, end than building additional Warehouse space <m the end. (6) The H01 absorber* and storage for Muriatic Acid are Shown outside of the building and opposite of tho ohlorinators# Other locations would be equally as good, and it night also be desirable to pipe tho HC1 gas to existing absorption equipment, (7) We have kept In mind, straight line production with "' raw materials entering n end of the building and being processed in a lias and finally arriving la the Warehouse, fitaeroj. W have bow advised that this equipment will probably be installed in an existing building whose dimension ore unknown to ub. Thin study is therefore submitted in tho hope that it night be of essletanoo in laying oat this equipment is your present building# Sffl/Jw V25/56 00132? ADA 000680 WATER PCB-SD0000045847 osw 001328 ADA 000681 WATER PCB-SD0000045848 810YI01 10. I SI0TES OH DIPHEHTL AID DIPHim DmrfATIWES PtMtTB 0PBUTXOM, ta At AVXIBTOV BY J L HOMSTOB f. V. fXXUAMS {OPSUTIM DSPARTMEMT) The Brewlnge Referred to la This Beetles arei mmskMii ,,. 0--iSSl -- Diphenyl Pleat -- Dlegrnoetic now Sheet of Prceeat Pleat OHLORIBATIStl WIT 0--6688 -- PIegm--tic layout of Ghlorlnctlaf Equipment BQi issoaraoH Mo Drewlags ABSomMUMS. 0-4&S9 - Layout of 1169 Pleat ASOOLQR DtSTriOJlTIOI 0-68S8 - Layout of ledger Still OSH 001329 ADA 000682 WATER PCB-SD0000045849 47 iiiwAotw or mmm m fujonom at ium mmoM, mmmi tun JJUX8XOM, MJMMA biphtajl is a polymerisation product f Bfasol resulting firoA th heating of Bansol rapor to teiparatur! around 800^0. It'i formation la aooospanied by the liberation of no Molt of Mydrogm for aoh mol of Mphaayl produced according to th following o* o oo.%reaction! A Hoot c Pipheoyl production to also aooosspaaled fey further polymerisation produets and sow* decomposition yielding ortho, mot sad ptra- dipheaylbeasea, betraphaayl, taro end earboa, fh plaid of Piphyl 4 preat of aversion to higfay polymrs ie a direct fmotioa of tMperfeirw fho manufacture f Diph*ayl as practiced at tbo fwson Chemical riant In Annietoo is shown dingreusatically by drawing go, 0-6681 attached, by actual photographs of th fuipnamt and is deerife*4 as followsl jlaw M&tarlala . Setisol is th <mly raw material required for th production of Biphenyl but it le Signtlal that a par boas! hi wood, this material Is bought under the standard specifications of the Barrett Oeapaay fer Industrial fur Boasol to phi.oh has boos added th following specification for Fooling Faint, the froeeiag point Bust not be below test t b pad in aoordaao with th Bathed f I, # fto*l 0*p,B th fireeaSmg point speclflcatis has bate found to b th Best waluabl tost is determining th gualiiy f Ben!* . -_ i Fast xporieao has show that impurities in bbaBaaaol tend to deoroas tb yield of diphenyl, iaoroM the percentage @f higher pelynera sad low? boillaj @11# 001330 ADA 000683 WATER PCB-SD0000045850 T 46 I tmm isipurltles also Am vp is the resulting diphenyl mi e*u trouble la the dr-odor* subsequently md ism It* .. It i *l*o strongly suspeoted that densetiti* eaong the operator* if caused by iaparitie* la the beusel. Benaol is reoeivwdiii tak ear*. It la unloaded with * #8B6 feetoo pe^p and guaped thresh * If6 line to a ML000 gelloa storage teak looated above ground; 100 tnm the dipheayl building. fhl* tmk la equipped with steaa tells to Jwet freeeing is &ld weather.' Vhm repaired fer nee the kawd it pimped fros this storage teak with * if* flldag pmgs through a ste*-jsoketed; legged; Ijp lias to o of ftw f60 gelloai f#4 teaks* Bensol is popped rom oas of the feed teaks using a festoo 819 asp which gives * line pressure of 85 - 90#. through a l/tm flBZ5 Schutte fearting Sotassster* ffae flow is regulated to 186 gellonq/hcrar through a head operated 2/d8 valve* Tha line Gessure after leaving the control valve is 80# gt^sge. the quid beusol is then led through a waste heat vaporising eoil, located la m ava&limry stack to tha diphsayl .wait, and emerges fro thie o#ll at a temperature of 186 - 1600* and a pressor ef 50# gauge. It is then led to the #1 preheater pot; which is a lead bath pot heated priaeipally by the waste gases fm the #g preheater pot and the oeverter pot; bubbled through the lead and exhausted out the top, The lead te^eratur# is held at 400 45000 and the exit vapor leaves the pot at 850 >'87500 ed a pressure of 18#. The vapor is tbea led to a seoond preheat&mf pot which is slMlar to the first motopi that this ii a fired pot end is operated so as to Maintain a lead te^erature ef ft6 -> ?860 The exit vapor loaves tills pot at a tenperetar of 815 45000 and e presrore ef !#* Ip te end iaeXu&lif this seoead preheating pot there is praotioaUy no ouversie to diphenyl, this is purposely avoided because past experts has shorn that say diphenyl femed prior to the last or convertor pot tended to fora higher polywers end carbon when put through the converter pot. osw 001331 l ADA 000684 WATER PCB-SD0000045851 After ImriMzt the BmmA prdbeater the talari ew put through a third sad final load hath pet sailed th@ oaterUr* %l it a firod pot and th 14 in^aratura i* mluUlmi at 94^0 fhs Kit taper lew# the eoawrter at fgl - TS00 mi a preeaure #. ' the abw motioned load temperature* &r eorreet mi art take with Mil$m*9mXm FyeAs thrmigh teg^wniure well itareed ia th lead hath* Hi tapor tea^eratere# ar also s#aeur#d with WllmmRala Pyoda hat ar# ewly ralsiiw la that th# tesporetor wall* hr Xopat#d ia the disohirge pipe# about It abort the top of the pot sad the bseperabare at *aeure 1 iMthumwi. by radiation* relume of gas flow,, to After leering the converter pot the report pass through a trap Where say load arry=w@r or earboa it dropped out tad these to the fraeiiea&tiag eoltm, it the top of this eoliM a dephlsgsater if operated ia #aeh a aaaaer at to return all of the dipheayl# high boiling Baterlal and pert of the *converted beosel hash to the eeltass LnA S*ieh it is di#ohared at the bottom through a Btess-jaofcotod line to eae of three g&lloa auap tanks* the temperature At the top of the eelusn ia saletained at 70 to WflO fey eoatrel of the eeoliai water tlm threiagh"th* iephlegtaator* ifter ptp&ratioe of the diphenyl, high boiling material tod pert of the beasol, the reMiaihg ewrt4 N&Aol taper &ad hydrogen le peeped through too eoadeaeere where eo.beteatially all of the beaeol la eo@dea**d, Thif le returned to the feed teake and , retitli the Iydros saturated with beasel vapor m%$ eat ef the last ooadeaeer to a eeoler* m through iaio alternate ehaaber* ef a Pittsburg Sfootredryer Voanmjt activated elmlne. ahperber. lore the beasol le absorbed* the hydrogen passed mi through nad wanted to tha atmosphere* DSW 001332 ADA 000685 WATER PCB-SD0000045852 So ##Ain mamtui oowmt DiphtsttyX i Aroelor Building left, &?elept tuildlag right,, PMipphhftennyl k Aroolor Wild inf divided Into three Beetle# tgr fire ytlUt Converter wit end ehlorlaetore la left Motion, Crude Pipbeayl oollectlon and dletillutlea center Motion, preduot etor<e in right Motion* OSW 001333 ADA 000686 WATER PCB-SD0000045853 mm mLo&bm SmtXl houf epatftia* Ko* $3$ Weetoo bmp Srirm Tbgr S EP* Q, t, fa^loilofl proof *otor, faloadiug rata t#W0 galloa? far hour, fUMpd through two Inch lta OSW 001334 ADA 000687 WATER PCB-SD0000045854 ivu l* a #0H* Seetoo ftm* 8wa typ enly a&nr i ***< tor ait t9& |ap* DSW 001335 ADA 000688 WATER PCB-SD0000045855 5S- fcBiftoL mmt %t>em *U feuk |0t PIwUt, tone f>lihta Kttlit OSW 001336 ADA 000689 WATER PCB-SD0000045856 $* bemxol 'motMt ' Mntoi funp abo? twk tuod for h&nfiliaf btoioi to wit food tank. Too upright pifii 6# 8a anti-syjphola BSW 001337 i ADA 000690 WATER PCB-SD0000045857 mum* tm> tm% I - ?S0 0*lli 1 it dalles Pip <mrt*ad ar# fwply plpm fro tHSaol *tor*g*# raturs line* fro ba*ol etjll and wit 1Lqi Onaeetad to tastro- 4ry*x abort>r Mphm/1 unit food pmp In #bon at laft t>t tint f**d tank Ju*t inld |it* OSW 00133a .) ADA 000691 WATER PCB-SD0000045858 mtm mm Sending fro left to right, S#le* - fileo fAulen I feint Tejxjlog record* unit teijMJretftr#* AW# *'Wlleoo Manlea te|>retur eatreler#, enter - Srewo point Fptntioet*r, record* itlll end chloric*tor toaj>*r*tare*. fight enter - Beakol feed pup evltob end fbutt* Soerting feasel flee eter tight - fehliag ?ak^et#i,# regieter* Wool in etereg# tnkf OSW 001339 ADA 000692 WATER PCB-SD0000045859 DxraMXt wif lot*It: *o sUt*ookkss.. Owe 1* foreground used oalp u e by~cas she startriinng or stopping mmilttt OOmne is b*teoks*rocund contains coil type boosol vaporltter* froduets of combustion lets* wait through this stack, ?*por lottos this oil tod eaters center pot hloh Is 01 prehottor* passaso* to left pot whlob Is # prehotier tod then to rignt pot hieb Is the contort**# the apparatus shown in the foreground ts sprleatl tad is Sot part of the dlphonjl salt. DSW 001340 ADA 000693 WATER PCB-SD0000045860 vmmu. mn fop rim ihoiriaf 0 pr#k#atr o*ntr# #$ pr*bo*tr l#ft, *d oonrortor right,, S*troa# rlfht eho i#M tr#p, Beat pip# eat top of thi# tr*p 4i#cbwf#p iato bottom of frAotloaatiag ooitw. ** fteo eo# Id oh Hoop' ho* eoaing fro* tho top* of #aoh pot end Saatfoldo4 to to the horizontal lla# &r r*lui Haeg and u# mood for t&<0Llgi&g pot pr*our# when fhattln* 4oa malt, got# *#14*4 ootor# oa 0 pr#b**t*r end load trap*, * OSW 001341 AOA 000694 WATER PCB-SD0000045861 mam mm FracUeaatini at l#fi fed aoBdea#*** m n&S+r jUtfora* OSW 001342 i ADA 000695 WATER PCB-SD0000045862 40 MFHUtQ VIIT ! t gxrtrefte right ihwf top of fruoticttmting oolttm* Right Oiater ifcoo* dphXeg*tor Condensed groduoi return* to oolw |*fi ot&W end oxtress left eho.w* ben&ol eondoneer*. Condensed product returned to feed tank, Vpptr gig* ooaneotion* ar oooHa* w*t*r 03W 001343 ADA 000696 WATER PCB-SD0000045863 AQTIYATJCP ALUO0U BBIXOL AWOJlM* 0h&aUre ued (teoli** watr idmrpilm# pWw w4 jt^r m^Ut&Uwh 4ttrtag OSH 001344 ADA 000697 WATER PCB-SD0000045864 <zz pm%ol j. The separation of the Bensol, Biphenyl, Sigh Boiler Mixture collected in tbe tump teak# is don# la three steps using three stills, rlsi fhis still consists of a borisontal tank heated by a tubular teas chest using: ste*M at ISO lt5f geg# pressure* this tank If oonneoted to a fractionating oolusa equipped with a coil type dephlegaator and a tubular oondenser. the product collected in the sump tanks is puaped to this still erery eight hours through a lj* Oould centrifugal puap and tbe still boiled down once in etch 4 hours* The bensol which is distilled out Is returned to the diphenyl unit feed tanks and re used. the residue remaining in the still consisting of I - 10% Bensol, Biphenyl and High Boiler is then duaped into the Biphenyl still. jmourndjmu This still consists of a rertloal tank, a fractionating column packed with l$* Bregeat Spirals and a jacketed pipe type oondeneer. The tank is equipped with s submerged type Jtunsey centrifugal pu*p which circulates the diphenyl - high boiler mixture through a gas fired coil heater and back into the tank* Vilson-Maulen Tyod theraooouples located In the tank, at the inlet and outlet of the heating oil end in the column head, oonoectod to a Brown Recording fotentioMeter serve as oontrols for this Still, Tbe oharge, which has the following approximate composition Bensol how boiling hydrooarbons Biphenyl High Boiler, Tars and Oarbon ltf B. t, I76C (approx,), is run by grarity fro the bensol still to the diphenyl still, tow OSW 001345 heat is applied to the ooll until the residual bensol has distilled. This Is returned to the sump tanks. The heat is then increased and collection of the distillate in pans begun. These pans are made of ADA 000698 WATER PCB-SD0000045865 6J (ilwnlitd Iron and par IS* x 4Y* t th first pan contains the low boiling faydrooarboa# and U known u "bead**, this amounts bo approximately SO# par charge* 9bm the potentio-* tutor indicates that th# boiling point f diphenyl bat been reached, the delivery flp* is swung to another pea and boat and dephlegmator regulated in aueh Manor at to Hitill technical diphenyl of 980 or higher freciting point, the nd point of the distillation 1# oarrled t{>0 * *0&0 above the boiling point of diphenyl to insure as complete removal an pottlbla, For this reason some High Holler will be distilled oyer into the last pan. This le known at the taile* and this material, along with the heads, is reaerred for the production of drooler 566, The residue from this distillation is known as orude high holler and Is either pumped to storage, drawn out la drums for storage or dunped into the High Boiler still for subsequent distillation, IichJoUtttJttm fhle le a vacuum still and is of the sane general design as the diphenyl still exoept a reoeiter, trap and yecuun pump hate been added, JChe residue from the diphenyl distillation has the following approximate composition# -. Biphenyl Orthodlphanylhen sene Metadlphenylbensene faradlphenylbensene Tetraphenyl, Tars end Carbon 1*0 6*0 10,0 66,0 5,0 Because of the high boiling range of this material (MOO-6600) it is neoessary to use raewim distillation, the boiling range at 60 m is reduced to - mOfl, the charge is run bgr gravity into the Sigh Boiler Btlll, She temperature at whleb it is dumped is shore its boiling point at the reduced pressure (50 mm} the circulating pump is therefore started and the charge allowed to eool to approximately 175C before the raouum pump is Started, 4. differential of 80C between the inlet and outlet ef the heating noil indicates satisfactory circulation. When the temperature has dropped to IfgOo the vacuum QSW 001346 ADA 000699 WATER PCB-SD0000045866 C4 fW& || started tad the f ih ehaxg drops rapidly to lW&O i hioh tosy>*r&ture ths residual diphenyl distill*. * When this teaperature #f tb polmm head indicates that all the diphenyl is distilled the vacuu* 1* released end the residual diphenyl dram fro* the reoelTsr, Distillation li then continued MStil approximately 10% ef the original barge has distilled, this Is determined by releasing the Y.aouuia periodically ad measuring the contents of the receiver, in experienced operator an judge this sod point quite accurately by observing the floe of distillate through the sight glass. the dLitiilation if then stopped sad the distilled high holler dram froa the reoeiver into pans, the still residues consisting principally of tars sad oarban is dram out sad discarded. Jp&pftoifcr ibe diphenyl wit ha# a eapaeity if 0#000# technical liphwyl per oath. i } i \ *' t DSW 00134? ADA 000700 WATER PCB-SD0000045867 Witt WM From loft to right, 0round floor, honaol reoelrar from adsorber, three crude giphem/1 tump t*nkp, underneath platform dlao*r~ able i* dipbeajrl still tank, rifht, high boiler itiil tank, 0 platform, Bensol still ith fractionating ooluma and oondenser m Seoond platform, Foreground, diphenyl ready for peeking. OSW 001348 ADA 000701 WATER PCB-SD0000045868 7- nm mtm mm ciPf eJ-ostd, hooting coll for high hoilor itili* Sight* omo opoa^ ho&tlng oil for 4i|heyl tille fhM boating W)J1| * hounlod *bov the itill twikp snd *r iopveWd from tho by a fir wall* OSW 001349 ADA 000702 WATER PCB-SD0000045869 6T menu) mphwxj, oouRcnon DSH 001350 ADA 000703 WATER PCB-SD0000045870 mhumjo. mm m no&m round pbov* high boiltr ptlU DSW 001351 AA 000704 WATER PCB-SD0000045871 69 UGH BOILER WILL - lilXl tnk shewing drift to submerged %yp %m$*y pu*p, Uft osoter, frgotioiutin* 0dlua, sight center,, Receiver. Right, Trep, DSW 001352 ADA 000705 WATER_PCB-SD0000045872 fo CHKMJCAJj COMPANY, Diphenyl Operating Record Ending 7'00 A. M.......... #.sr-M.................. 193. .1. ' No. i SHIFT Unit No. ....... . ADA 000706 WATER_PCB-SD0000045873 0SW 0 0 1 3 5 4 WATER_PCB-SD0000045874 ADA 000708 WATER PCB-SD0000045875 ADA 000709 WATER_PCB-SD0000045876 ADA 000710 WATER PCB-SD0000045877 DIPH&m Pww .. Oklhi REPORT . bduotlotoi ` , ' Technloal DJplietiyi 0ru8e High Boiler \i total Distilled High Boiler %A% .;.V::! . Poun'da * 4Hl 44ag. Kydrooblorloi ! ' 9------ . iroolor . $l#t. ,. Br.toh HO Aroclor . , ,, Botch No Aroclor t , Batch No, nentorlosi Bontol } ' '` ' Storage Tank ------- #V^r- jConsuraptlonoi , ' . + .. . Inoheft nr ww-* ' IriohoB,' , Lba. , lbs. Lbs, Lbs, Qas Today ,t f MMii. j&pAoaA 3UI~L jM.'ft. y|jf cu.ft. ou.ft. Previous fley Consumed Diphenyl ' .u _ jnj.ft. ' ouft ' -:jnt ^ '.1 ^'TapihiWay--.-.-.-eu.ft. *1 ,y. . , , , '. Tor ouft .ft. Crude High Boilor Distilled High Roller ' ., |f$g Jbn. For For *. , V 4 Cu * fc 4 ' ( ' ' l '''''i J,,{-;C " OSW 001356 1. ' ",''i >. / it4? ADA 000711 WATER PCB-SD0000045878 AfWBXX mm m tm wsmncw or tm wmu mu 7X Jtnetrumeat? Flow Veter Thermocouple? tootr&lng tfFcmUr Becording Potentiometer Teaperature Control &* Burner? Tank 0uage Bohutte Koertlng 1/**# #18** flleon Vaulen Fyod# ( lion - eonstaniaa) Wilson Weulen f Point fapalog Broun Point Wlleon Kaulen Potentiometer actuating Anarioan JUdiator Co. motor valves* Combustion faglnearlng Co, High ?r??ure (**f) Cehling Tenk-O-Veter jttatUngJfoftjfalt After a careful oheok ha? been paid? of the various control equipment, feed lines, food pump. release line?, water Use? and other equipment the |ti hunter? Are lighted and the lead temperature is the pot? brought up to operating temperature* Thle require? approximately Six hour?. During this period the stack containing the beusol vaporiser 1? ioeed and the product? of combustion disoharfed through a separate Stack* Shi? le done to prevent overheating of the vaporiser eoil, Wheat the system ha? reaobed operating temperature it is swept out thoroughly with carbon dioxide ?o a? to remove any traces of air and avoid explosive mixture# of air and bensol* After this precaution the hansel feed pump 1? started and the flow of hansol started through the wait* The spent burner gases are then turned through the staok containing the bensol vaporiser end the waste heat utilised, the rate of bensol flow is then gradually raised end the whole system brought into equilibrium at a Hew of approximately 110 gallons per hour* gtaanlnf t^a y?lt Vhutting the unit down is ft reversal of starting it* The products of combustion are out off the vaporiser ooil, the bensol flow is stopped and the feed jmsp shut Aosta* The system is than swept out thoroughly for ten minutes with oerboet dioxide to insure complete removal of bomsol, The release lines at the tops of the pots ere then opened t# equalise the pot pressures, oars being taken to opes the converter release, the ft preheater release, and the #1 pro* heater release in the order named to avoid blow bask of lead* The OSH 001359 ADA 000712 WATER PCB-SD0000045879 76 fM 1# then shut off end if the #but Sow 1# to be for my extended tUi, ell water *nd steal# is also shut eff* Qm<Mm M.Sh%J4.p.sSm&aM This piece of oquiphsnt if ft two chamber *otlreted *lu*tn* adsorber used for rswrring; bensol fro* the hydrogen produced la the Kumfeoture of diphenyl ad #l#o for collecting the bensol repore issuing fro the reate of ell feed end collection tanks, the chamber* ere equipped with pipe ooile connected through two my Tlfo to fteaa end water, Purl&g the adsorbing period ooollng water le turned through the eoll# while during the re~aotiratlon period #tea* le turned through the oeile. The operating period# ere fix hour#, during which tine adsorption le teking pleoe In one chamber while r-e.otIrtlon le being aooohpllsbd in the other fthaaber, the temperature of the adsorbing oheW 1# held below Ig&C* the re-aoUratlon ohtnber le hosted M hot *# poeelble with lfi# fteaa for fire hours, then cooled to below WC during the sixth hour* SUi&JSU&ftflliM resent diphenyl unit is operated with ft tin efficiency of 91% The prineippl" factor causing lost operstlng tine 1# carbon formtton, . This le Indicated by changes In operating pressures.and occur# ' Boat frequently in the following orders 1* Gooseneck# fro* oonrerter to trap and fro ti*p to coluMn, met be cleaned bi-*onthly end require# about four hours. Spare gooseneck# are oarried end exchanged* ft, Oonrerter distributor pipe, Bust be cleaned or changed eeal^annuelly, gpare distributor carried on hand, Changing require# about eight hour#* I* ho, t preheater, lust be cleaned about once a year. The carbon forced 1# rery hard end dense and it la necessary to either chip it out or bur* out with oxygen. OSW 001360 AD/A 000713 WATER PCB-SD0000045880 77 Other factors ooeaslonally causing lpet operatiag tine arei Metributor failure flu to pip breakage and Indicated by change in operating pressures or reduoed onTersioo, Thermocouple well failure due to vibration and indicated fey - leakage around the connection at the top of the pot* Feed punp failure dua to tear in the punp to euoh m extent that it falla, to dellrar tha neoeseary pressure* Fot failure indicated by lead running out the firebox door* Whentrer a pot id opened it id essential that the lead be neasured and any neoesdary make up added. The neohanlotl notion of the vaporlaed benaol padding through the molten lead pauses passage of this natal fro* one pot to another end fro* the converter pot to the lead trap. The proper depth of lead in Mo, 1 and So, I preheaters is 48' end in the oonrerter if". The euap tanks and feed tanks are Tented through the teotrodryer. Occasionally these lines booose plugged oauslng baok pressure on the tanks or backing up of the distilled bensol, It is necessary to clean these went lines whenever this ooours. Bensol used for Biphenyl sunufaoture is bought under the follow ing specification?> grade Oomerol&lly Furs Bensol, Color the visible color shall not be darker than a solution of ,0080 fK, ef potaeslu* bichromate in one liter of water. Compari son is to be wade in Messier Tubes - {0 oo sice, BJLstlllatlcm The product shall distill fro start to dry within IvC. within which degrees shall be laeluded the true boiling point of furs Bensene (*O,t0) The method of distillation shall be in aooordanoe with method Jt~4# Four*, 2nd. Eng. Che. 10^1006 {1616). AfilAjMh Th *sh shall not be darker than Mo, 4 Barrett Colorlaetrlo Boale. Test in aooordanoe with directions for Test M, Fours, Xd, Bag, Ohm, DSW 001361 ADA 000714 I WATER PCB-SD0000045881 Aoldltl finished product nfcali oonteln m free *oid 87fi end 80d* ipeelfie aridity *t US0 phell fee Wt#ta jtofetur* lust fee eeeentielly fre of freeing point matt fee not below 4*8^0, tptt io eoooxdwio# irfth method of V. # tool Oorp, DSU 001362 / ADA 000715 WATER PCB-SD0000045882 wmmmu of mmm Aroolor ti * * used to designate th chlorinated produots of diphenyl* The physical properties vary from & light mobile oil to crystalline find non-cry*tsllins solid depending upon the degret of ohlerination sad th oonposition of tb m material* ftraigbt diphenyl chlorinated yields * liquid product of Increasing Visoosity up to ad including: B$ chlorine, Above this th yield is a crystalline solid* itrelght high boiler sod mixture of diphenyl sad high boiler chlorinated yield products of Increasing viscosity up to *o~eryetalline resins* A BUBorieal system *f uomoftolstvire oonsisting of four digits has base dtsloped for identifying the various Arodori* She first digit denotes th raj material used for th ehlorinatio. th figure "one8 indicates loaf? technical diphenyl. the eedoed digit denotes Whether or not th product is distilled* The figure one* indicating vndlstilled. the figure "two* indicating distilled. The last too digits denote th approximate percentage of chlorine contained la the finished product* Thar are several arbitrary deviations from the obove nomenclature as follows i I, Arodors 4Q06 end 44S0* The former is the crude from which the latter is obtained by distillation, the starting raw materiel osteins 40$ distilled high boiler end 00$ technical diphenyl* this is chlorinated to 06$ chlorine. g, droolers 6060 sad 6460, lb former is the crude from which the $.letter is distilled. The starting rev materiel is 100$ distilled high boiler. Tfcia is chlorinated to 10 I* Irocler 1606* this is an undistilled product. The starting rat tutorial consists of 6$ rude high boiler and 76$ technical diphenyl* This is chlorinated to 06$ chlorine, The Aroclers ere not pure compounds but are mixtures of two or aor compounds* lovover* frog their chlorine content they may be assumed to bate the following oempoeltleat DSW 001363 ADA 000716 WATER PCB-SD0000045883 So droolers 1148 and 1148 1140 1848 1164 lino ilmi$4o m% 1848 1103 188 Use 1849 40$ 4416 mo 0400 * QlgSyOlg CjjjHgOlg lH$01g OlgHgCla 6 Oi^sQly OnSgOlf 18al9 JjHfOl 4 OlghgOln OieHgdio the manufacture of dro&ors is divided into two operations, risi Tbs chlorination of tbs n* materials to crude dyoelors. Tbs distillation of ths crude Aroclors to flnlehed products.. This operation Is shown diegrasAtlealiy hr drawing Io O*0f08, fey aotuel photographs end Is dssorlbsd ee followsi be raw materials used in tbs manufacture of tbs droolors ara principally Teohnloal Wphenjl end Chlorine* ions few of tbs Aroolors require orude high boiler or distilled high boiler a* will be shown Inter* ItiAteriKljiJeaAlw filphemyl #r Mgh boiler Is taken fro storage, weighed and duaped into ptess heated melting tanka, LLfttld chlorine is reoelwed in single watt tank ears which are leased fro the manufacturer, So additional storage Is prorlded but ohlerint is used dlreotly fro* the tank ears after being passed through a raporlser. The waporlesr consists of & eylladrlosl tank containing water, heated by pteaa, in which is inmersed two 10* x 4d" cylinders, The liquid cblerine is brought In fro the tank oar through a 1* line and manifolded so as to feed both cylinders* Vaporisation of the liquid takes place and the gaseous chlorine Is discharged fro the cylinders through 1/8* expansion walwes into 1* lines so manifolded that any ehlerlnetor aay be fed fro either vaporiser* frrsssurs |M|ii are used to measure the ohlorlns flow* OSW 001364 ADA 000717 WATER PCB-SD0000045884 &/ MMlMsMm The ohlorinator* are three cylindrical steel tanks, 34 ft* high by $ ft. diameter, The#* bar* flanged oonvex cover* and bottom*. Thay are filled to half their depth with Iron turning* for eatalysis. Tbosa are enolosed ia an iron shell g? in diameter. A one inch ooii for *team and water extend* around the length Of oat&iyat ohanber between the two shell* * the spacing between each torn la approximately two lnohel, - .^ A two inoh line lead* fro* the bottoa of each ohlorinator through e Qould centrifugal pump to the top of the ohlorinator* this is for circulation of the charge during chlorination* In the oovera of the ohlorinator* are inlet line* for charging, hydrochloric acid dlnohait* line*, circulating line* and went line* for a** while charging* The hydroehlorio Add line* from Xo I and So. V chlorine tor* eater a oomaon tin leading to the hydrochloric acid absorption system, So. 1 ohlorinator* whloh is used for 1149 and 1199 dleoharge* its acid through a trap and thenod into the common aeld line beyond So, 9 ohlorinator. the required charge it weighed end duapad into the welting pot, Belted and pumped to the ohlorinator. the chlorine flew ie kept low at first to pretest local everheatlmg and diphenyl sublimation. The eiroulatlng pump la started arter turning an the chlorine. A* the density ef the charge Increases, the oWLoriae flow ie inoreated until the pressure reach#* the maximum shown in the table. The heat of reaction of chlorine and diphenyl 1* so great that cooling water 1* accessary to keep the temperator* within the required Halt*, The maximum temperature shown ia the table ie that neoe**ary to insure complete reaction and to keep the charga molten * During chlorination son material ia oarrled out of the Ohlorinator with the Bel gas by entrainment, foaming or sublimation, for this reason. Bo, I and Bo, 8 ohlorinator* are eater used simultaneously* one being used a* a trap While the other i* in operation, Buaber one ehlorinater being used for crystalline . Aroolor# has it* own trapping system siaot contamination of any of the other Aroolor* with crystal* would render the* unsaleable. A separate trapping system for each Ohlorinator would increase the capacity by one third. The average amount of trapping* 1* # of the finished batch* Whn sufficient has aooumalatwd, it i* used for the OSW 001365 AOA 000718 WATER PCB-SD0000045885 aaufeoture of U8I pr UM, or for toy Of the Ayoolors if bo trapping* fro* th last two are present. |b chlorinating Arcelor containing high belle? particular oar* Bust be taken to minimise fotolug. the aurfact teuilon of thl# Material is apparently higher than that of diphenyl* therefor# a higher ohlorinating ttoperatur* will reduo# fowling tendency. Chlorine mut not be fed too rapidly at low temperature* gaaple* ere takes fro tiae to time to deter!# progress of the chlorination and Bear the m& txtreme oare mat be take to prevent overrunning the end point. MoweVer* an experienced operator ean finlab to specifications with great aoouraoy, then ohlorlnatLo la complete Arodori llifi. US4. IU0* 1102* 4005 and 506 are puaped to the blowing tank, This tens: la equipped with ateas oolla and perforated pipe for oompreated el*. teaidual hydroohlorio eold la blown out here, the blowing period varies fro four to twelve houra# depending a the Aroder. Those that are to be whipped u erode &r# given the axl*u period while thoae to be dlatilled ere given the stinlmua. then apeolfled by the eue toner that any of the liquid crude Aroclore be whipped a such* they are given epeolal trostaent with puller'a Perth and hydrated line and then filtered. After blowing, the naterial la drawn directly into whipping containers Px Into 50 gallon drum for atorage preparatory to distillation. AroelorS XM0 and 3100 swlt too high to b# blown ao are drawn dlreotly fro the ehlorinator into cpea top drum. These crudes met be disobugod fro the ehlorinator aa rapidly as possible 1a order to prevent Pressing* This method ef diecharging ie disagreeable aa well as haaardous to. the operators and could be greatly improved fcy the installation ef flaking equipment. the following table end chart shows the operating factors involved in the production of eaoh Aroolor* DSH 001366 ADA 000719 WATER PCB-SD0000045886 03ZOOO vav OSW 0 0 1 3 6 7 i i Miiiittr SSffidtUftlf p Il! B It | 9 I III t*tti i t M I) 9 M ~t - *9 *>8 as 8 a 8 8 0 a K 5 5 g g gS S g 8| 8S 5 &8SS8SSE .(a ,N8 -9 J m 8 8 1 * 8 ^ ` * 8 nf III!11 1 llesss-eg .iii i iii, If I ijnstsl rf f f ,, ~3 2 3 S S a a * ^^ e 6 e- $ e 111 i l! 8 111 ISSN WATER PCB-SD0000045887 J W &Q~frtO J fO IUOOO VQV WATER_PCB-SD0000045888 Bf OKWRIKt tTORAOK - Two nd o*rt art at liquid ehlorlna dltobwrging ItaUont* Oontor owr it *t hydrochloric told Xo&dicf fttiioti. OSW 001369 ADA 000722 WATER PCB-SD0000045889 f chlorine tAitthim .* Bot water tank containing two yi^ortslag Oylin<WN Liquid ohlorla# f*d i through dirt trap at left* Omoovu Wterla# dLaoharged thru t&Jyap at top* Upper preeeur gu*g* ueed for controllng chierlaa flow* . OSH 001370 ADA 000723 WATER PCB-SD0000045890 OHLORJHATOKS the thro* chlerlnator* end their circulating puaps ere Shoes, The vertical lines entering the ohlorIn a tor peer the bottom are chlorine lino, The bolted plates permit distributor raplaoa*ent* I the background can be seen the bottom* of the tiro diphenyl netting tonka end the pumps Heed for obarglng the chlorlnators. OSW 001371 ADA 000724 WATER PCB-SD0000045891 as ommmm lift * saittnf task, OmUr * Chlorinutor*, litres* rlfbt - Chlorine eporlfter* OSW 001372 ADA 000725 WATER PCB-SD0000045892 \ &9 ' ran*** omnutow s H&y AtdtrlVoiUr irouW OSM 00I3?3 ADA 000726 WATER.PCB-SD0000045893 frmamm cmmAton fhe Aroeler# iucb u ll& and 1160 era dieohax^ed into open top drutu* Thlt to t ror/ . diee^raetbla* &g wall as dangeroua* operation* Flaker* eoula be vied* *I.l^uld* Aroclor* ere W4( DSW 001374 ADA 000727 WATER PCB-SD0000045894 I 9/ craoraninoN moow ,.:)or No. irted by _Bxm __ Botch No, --iiM____ S Chlorinetor No. A._ ^jkahm__________ ___ TJmp JLIiHJ____ I)ato,,4-OfeM____________________ U1 Hours __ Weight of Botch _ _________ 1 " , * V9 epor 'Bock ' -PPooTIrrvrtTj; ' Vap. ' Bock ' --gwl PoInC~ lap { Temp. ] Pro so,] Bot"cijr""]J''""55it33.. ""] Time ] Temp. ] Proas. } Batch {"SIT. E 1 "1' _JT .'JtU 4UO " A1. *'___ t%t && u tQ ' --W ~x-j ---- j. jumJx :J ~S -44 .X-.4. . I___ !. "1------------ 1-----------i~ 5 M i ! -44 -JO . . 1 "T ` :-j. ** v- -ji-----------{-moo.-; -JO "r~ 1*00. ' -.JO. --80 "fX.-jf Z:E5^2 -JO. 4 _j. Olroyl^-----i-4**T 4 -147J 430140i ~4* T~ ..JJ. -T. .1401 4 11 41 - r------ . woTi 4*10. r1 woX -JO -JO -JO -JO .45 . --n. `f ' 'i J ~T J f-4 mi -JO ' 4 - JO.. .11 ~r .... -4Jjf X-JUlM 4( 400 _f~4M4 -44*X@440- -4*00- jf juoa aa -- T-- Jg| OSW 001375 i I ,< i ADA 000728 WATER PCB-SD0000045895 9/ Mmm 8ioe ooe mol or fejrflpoohlorle add 1* produced for mr/ wd of chlorine u*#d# prorialoa auat fee mad* for tbs eolleetloa of thi by product. fbo eold (U pMJM from the ehlorlnator downward through A trap, thenoo out of the building through a two Inob pipe to a stoond trap et the absorption tyste. from this trap it pa#e through a pooling tower to fitraoail absorber. Those are thirteen in nuwber pieced one above the other, fetor antor the uppermost absorber end flow oounterourreot to the gas, tuffloient water feeing added to produot idYfest add, fhe condensed add pmn through a aerie of one inch Pyre* oooling tube, thanoe to a 80,000 gallon rubber lined tteel storage tank, iny wnabsorbed gas pass** from the absorber to a drowning tower, the weak add absorbed hers beiig run Ter iia*tone to the sewer, ipproxi*tely 88f of the aoid produced i recorerad and absorbed when storage oapecity is available, Bowerer, this 1 Halted to th storage tank mentioned efeov* and two 8,000 gallon tank oar, o tauoh of the add fade Is wasted, fhould Pale* warrant Suoh, the re cover could be substantially increased fey pumping the weak add frow the drowning ijovsr to the absorbers, flaarstlng PifllgulfcUa On the whole the chlorination process give practically wo trouble. 1 few itl of maintenance are listed below In the order *f the frequency of their ooourrano, 1, Distributer! Tha perforated plate of these wuat be replaced gold-annually a It corrode through in ft six to sight month period, 8, The Keroo-iordatrow Valves on the chlorine line* wuat be replaced onoe Or twioe a year flue to leaky *te*a, g, The Crane valves en the raporlaer are equipped with regrindable seats vhloh must fee raground seai-annually, OSH 001376 ADA 000729 WATER PCB-SD0000045896 9J .[t fypftocra^Rio mu m? ' ibo# Vltrcocii abcorbcri. ook* packed drowning lover, 0,000 gallon rubber lined acid itoraga tank, ua1i tank at left 1$ tor 60Be sold carboy nhlpBetf Soto also gravity rubberlined line for tank car loading. DSW 001377 ADA 000730 WATER PCB-SD0000045897 1* rfr . 94 ADA 000731 WATER PCB-SD0000045898 piiiUlatlftn of the -Prude JLrocIors 111 f the droolers exoept Aroolor ltW6 are 'distilled to finished. products, Tk> different type stills are used, Ti*l 1, Atmospheric, on-fractionating, wad for production of Aroolor IE40 I, faouus, Olroulatiag, Coil Seated type, used for production of all other Areciore, iroolw XWiB ^LiUU&U The distillation of this produot has resolved itself into a very simple operation after having paused through a rather complicated development period during which awarel type of dletllletlon were tried, Aroolor 1889 1# the moat highly chlorinated diphenyl having the approximate formula OygHOl*, It melts at approximately JtgE^O and has a distillation range, it atmospheric pressure, of 400$ 4A0&Q Attefipts to vacuum distill this produot failed due to the great tendency of the material to sublime, fh# fact that its boiling point under 1 - A me pressure very closely approaches Its melting point renders the design ef a satisfactory vacuum still extremely difficult, distillation at atmospheric pressure iwing a olosed retort equipped with fin agitator and discharging the vapor through a peeled oolvsea mare unaatiafaotory beoauae of lorn yields and the difficulty of removing the still bottoms. Attests mere made to sublime the produot by passing a current ef air over the surface of the boiling liquid and collecting the sublimed produot in a duet oolleotcr, This method gave fairly satisfactory results but mas discarded due to expanse of installs^ tloa and oost of operation, Another problem tfhioh presented itself in the production of this material was its physical oondltlen after distillation, Collection in pass with the resulting aloe ooollng gave large hard crystals ehJoh the customer found impossible to grind to the desired fineness of one half micros, OSW 001379 ADA 000732 WATER PCB-SD0000045899 M il* sublimation and also distilling into a waier quenching tank with subsequent dr/lng of the quenehed product gate a product of satisfactory physioal characteristics. The letter was discarded however In favor of the fluking wheel which is used et present* The distillation as is now carried oo it show fey parte of driving /O-80M, by * actual photograph and la described as follows! Equipment * The equipment used in this operation oon lists of four Steel pots Id* in disaster X 48 deep, which are used alternately in tvo suitable fire brick, steel jacketed setting#* inside tbs pots is wolded e steel ring or gutter approximately 18* from the bottom* This ring serves as a collector for the distilled product vhloh is oondensed on the sides of the tapper part of the pot* the distillate Is disohargad through a short pipe set in the side of the pot at the ring level* Tbs pots are also provided with suitable covers held in plaoe fey 0 clastps. Beating 4s acocwplished by gas fired through a four ring, lew pressure, Bultj-jet burner wanufaoturod by The gurfaoe Combustion Company. The distillate is oollected in a pan which feeds a 14* diameter x U* water cooled fleking wheel rotating at H EPS* The flaker '' is enclosed by a hood Which is connected to .a Raykond duet oolleotor equipped with stainless steel dyolonae, ' Temperature is measured by fyod tberaooouplee connected to a lilson-ifaulen Indiostlng Fyroaeter* A liroooo axheust fan Is used to clear the still room of fumes liberated at the end of a distillation, 0$W 001380 ADA 000733 WATER PCB-SD0000045900 9/ &stUas tivt hundred pound! of Aroolor 1109 end twenty fire pounds of hydrated Its ere weighed out end charged Into the distillation pot, A gasket of ashes toe rope 1# pieced around the flange and the ootojf put on trJtb 0 damps, This cover is a flat ato el plate with a air in oh pipe W* high welded la its can ter# the pot la dob lifted into the setting with a ohalo-bolal fold the hood onneoicd to the exhaust fan swung Into position over the pipe in the oorer# the do!3very pipe la lengthened to reach the flaker reservoir hy a aleore and nipple# i thermocouple la placed in the material through the cover and heat is applied# While heating the materiel to distillation temperature the flan* 1* allowed to oorer the bottom of the pot. then distillation etarts, the flam* is reduced ao that it lacks two inohes of touching the bottoa, If this la not done the oharga will boil ever into the collecting ring and give black material on the flaker* the aides of the pot above tbe collecting ring act. a a eondeaeer for the distillate* then the temperature of the material reaohee -400^ distillation li imminent. The first of the distillate la generally black so this is collected in a spall pan inserted through a door la th hood* This is withdrawn when the stro&a clears up. The material oaught here is re-distilled with a subsequent batch, The flaker and dust oolleotor are both started the moment distillation start# The average time for heating to distillation point is one hour and distillation also consume# one hour* the distilling range of this groclor is 400" 4WrH5# Toward the end of distillation the color of the distillate again darkens due to decomposition. The operator must watoh for this and Separate the dark material from the shippahle product, Thia material is also re-dlatiUed, Completion of distillation is marked by What Is known si tbe bios*# This is s rather violent buliition of dark oolored eublimate which is strongly add# Its probable oavae is sudden decomposition of very high boiling chlorinated residue which release# considerable hydro chloric add i a short space of time causing sublimation, Then this ooours the fire is immediately cut and the exhaust fan Started, Tbe blow lasts about five minutes# Then it ceases the pot is lifted from the setting, placed in a water filled pan on s cart, rolled into the yard end allowed to oool. OSW 001361 ADA 000734 WATER PCB-SD0000045901 se Tb rViU residue# m * mixture f arboa, partially de composed ijroeioi'i hydroohlorlo acid tad aloiuii ehloride, this mixture ellngs rather tenaciously to the bottoa of the pot, It* renewal to accomplished only by inverting the pot sad hammering Wigorously with sledges, This It sesowhat damaging to the pot hoito*#, to improved type f pot which way eliminate thit pounding It now being built, gaoh twenty four hour production f flaked Apoolor tad the dust caught In the collector It mixed a# thoroughly ip possible la order to ohUin a uniform oolor and pooled either in POO lb* lined burlap begs or 400 lb, tl*ol barrel*, as the customer detiret* The greatest portion, however, ie shipped In bage, flApaolfa She above detorlbed i860 etilla have a boablhed capaotty of 6,000# por 4 hour day or 160,000# per month* i* the Atier now in u* tat not designed for this aervloe and hit too lew capacity* la spit# of groat car# the pen tor flow* occasionally* Thit suet he collected and re-distilled* t Valess the delivery pipe froe the stills is kept hot during the heating period it etops up wlten distillation starts, this necessitate* cleaning it with s red* 6* If for any reason a barge is brought be boiling end then allowed to oool without distilling, it will decompose when reheated and the recovery will be low* '1 ' DSW 001362 ADA 000735 WATER PCB-SD0000045902 99 AnoowtR mamutio* k#ft bov# oyolon lu#t eolltetor#, Owotor. _di#UUtioo pot i* t** firod JUnt, r tl*klnz roil showing diwcbRin# of product. " IujI behind tha roll 0& be # osoond *tlU, Tbcec too or# operated ftltfertifttaXp. k&rg# pipo# obot# ftllif load to w oxhauei fw>. DSM 001383 ADA 000736 WATER PCB-SD0000045903 /oo __ PRODUCT toil RC.Qg(.rL,fe;<0S!L0n_.l2G9 SI 111 NO.___ I__________ DA1CH NO POUNDS 1160 CHANGrt) HI V HAT Fit I Al ^feaSSO -AL-Z& Jc* JL, pf<[ HUN OR orf-CCK OR,_________ ,,____ ._____ POUNDS SI IU BOTTOMS ______ _________________ pounds pwrun on orr-ooLoR_ f______ :_____ firt 0N_jr4*---------------fcf,; 0151., STAtlTOV^JlH____ _ *r!'M* * 0151. enwo ____ HM_____ JJ| OATL ______' oplrat on______ XjuDtfir SHIFT NO. Jt--FROM_4f|0 __ A. I'. P.M. TO AWI- 1)00 --V,th pounds wn UAireiAi AritR cENrniFUGiNS^jtftijB^ "pounds 4 BMA&KS.I 4H___________ OSW 001384 ADA 000737 WATER PCB-SD0000045904 /Of Jukuya -Ci-rtmtilM ill ef the distilled Arodora exoept 18$9 are produced is a TaoUUM ptLll, Phis operation is shown bp drawing 0-$$$$, by * photograph end la described m follow#i Shipment * the qulpMont used for this operation onslste of beating tank, wsed for Melting or werwing the still charge, which diecharge! into the Mein still kettle, This still baa a capacity of approxlwately 1H gallons. The oharge of Aroolor is circulated from the bottom through a Bo, B Quiaby pump to a ga# fired heating noil end back into the top of the kettle, the vapor is discharged through aonel Metal foa* trap to a Monel Metal single tube oondenser. the oondensed produot discharge# through a eight glass into a Monel Metal lined receiver, ' the- entire aysten is evacuated to 1 | bb through 60JS oaustle soda scrubbers by a Wheeler Three Stage Tubejet Yaouuw Pukp, A Devin# Meohanlotu Taouum Tuwp 1* provided as stand-by equipment. Whan needed to prevent freeslng of the charge undergoing distillation Aroolor 114$ heated by gas is circulated through the following Jaoketed parte of the still set up, line fro* still tank to %ulsby puny* tine from boating oil to still tank Charging line $ttij*by pwp utby puMp packing gland The distilled Aroelor is transferred Srtm tbs receiver to either of two 17$ gallon galvanised blending tank# where several batches aro Mixed with fuller*I earth before passing through a IP* plate and fraae Iparry filter prass to finished storage, Temperatures are Measured by fyods connected to a six point Wilson ttaulen Tapalog, Two points each are Measured at the inlet and outlet of the hastily coil, one in the loan trap and one In the reoelrar, DSW 001385 fer^the^pake of brevity, Aroolors 114?, 114$, 1W4, i860 and 1?61 and their orude boaologuos will be referred to hereafter as "liquid Arodors", while Aroolors 1688, 44$ S and $4$0 and their orude boaologues will be referred to as "solid Aroclore", The former are ADA 000738 WATER PCB-SD0000045905 not all strictly liquids, but they tr @aily aelted and, therefor*! @ay bo eo classified* The liquid crude Aroolors ere delivered to the Bodger dtlll in bunged draft* end the solids 1a open-head ArwqU* For charging, the bunged drafts are draw tip by <fbAi-boist to * platforw and the bung plaoed over the lip of the charging tank# Bung and vent are raftered end the An* heated with a gee fie**. Boating 1* not ueoessary for Hit and 1148 in war* weather, but all But bo boated in winter* the aolld Aroolors are broken out of the dru$ into a box and ihorelled into the charging pot, A tesperatur of 100 - 180 it Muffieient for ohargisg the liquid* but the solid* swat be heated to 180 - li&Q to become efficiently liquid to prorent freesleg while charging* this operation la vary erode and afford* considerable roon for iaproTeaent* A hot-oil aystea for heating the charging tank would be Buch pore efficient and cleaner than the open (>i n*e nos used* One percent of hydrated liae is added to the crude Aroolors i the charging tank, this neutralises any residual told arid prevents rubliwation of ferric chloride whioh would diaoolor the distillet* When the still 1> cold before chaining, til Jaoket* are warned with hot Aredor fron the circulating Cysten, If a solid Aa*oelor Is to he distilled, t snail charge of 11if or 1148 is first circulated in the still at atmospheric pressure to beat the aysten thoroughly, This is pumped out just before the charge to be distilled Is ready* In dropping a charge a 40 Mesh soresn Is placed over the funnel of the charging line to take out Most of the line and any foreign Better that may be in the crude. It 1* extreaely important that no foreign natter get past this screen since the clearano* between the screw and the barrel of the tyilnby puftp la extrenely snail and it is therefore easily stalled, fust before charging, the fluiftby PUMP 1* Started and a lev flans applied to the oolls, When the charge is circulating, as indicated by a low tesperatur* differential (lo - 80O) between the inlet and outlet of the ooll, oirouletiot) of hot Aroclor to all jackets but those around the tjuinby punp packing glands If stopped and the Jackets drained* the gas la now turned on full and the sylten evacuated, instillation fro* a oold ayatoei start# in three to five hours after charging depending o the Aroolor being distilled, the l*g between batches te 80 to 46 Minutes* DSW 001388 ADA 000739 WATER PCB-SD0000045906 /0$ line# th* crude obarged pr batob if IjOOO lb# and tb# recovery 91%t only K) lb#, of Ull residue. will b left from each batch* Thl# ii not sufficient to maintain cimUileW* which require * t lnit 100 lb#, Therefora, the first thr# or four batch#! or# not run to eos^letlon #o that otroulation may be maintained While reeldue 1# accumulating, fine# the eapaolty of the reoelrer 1# only l.fOO lb#. tb#ee first batch*! want be eplii# the raotlvar emptied and distillation resumed without reoharglng, fubsequent batch#! are blended with the early onoi no that the eos^oeition of the whole will be uniform. During dietlllation the teajper&ture of the fee* trap eoi*~ oidea very elosely with that of the inlet to the ooil until near tho end when the tourer#ture of both the Inlet end outlet increase rathor rapidly while the foam trap tesperatur# renal*# nearly constant, fh#t> spread of ftr * 40 between the fo*w trap and inlet is attained dietlllation 1* complete. The ebov* It true of the liquid AroclorSj and drooler# t69 and $490, Aroolor 449$ oon#i#t# of mixture of diphenyl and dietilled high boiler chlorinated to 9$? and hae two distinct boiling ranges. The chlorinated diphenyl distill* first nd will oolnoid* with the inlet as above, ifter this hae distilled, the inlet and outlet temperature# will increase and draw away from that of the foe* trap and the stream of distillate will fall off, is the temperature of the liquid increase# that of the vapor in the foaa trap will inerea#* until it again approaches that of the inlet, Another spread indioat*# the end of the distillation. Ifbes distillation is oosplet the valff* on the vacuum line is dosed and the system wanted at a point beyond the receiver, A measured crude oharg* of 17* in the charging tank is now dropped and circulated until the receiver is emptied to the ' blending teak* by means of oowpressod air applied through a wait# in the vacuus U# over the recilvar, Distillation is now roruwed,' From tin* to tia# exoess still residue feist be withdraw# fro* the kettle, Thl# is don# by partially opening a plug valve on the discharge side of th# %uiwhy st the oomnletlo* of a rum. By using oar* in this operation circulation will b# maintained throvwh the ooils while draining, lowevar^ if the wait# is opened too Wide the material in the coils will oarboniea which necessitates drawing ell residues and renewing the ooil, DSW 001967 ADA 000740 WATER PCB-SD0000045907 /Q4 the the Still l* to b take out of operation the pump ia fhut down for l few minute#, a t1m at toe Inlet to tb eoli# oloaed ad f#at plug la the ooilf opened #0 that any material remaining is to eoila *111 b yuU*d through by vacuum, Th* stiU reldaf r* bo* pumped out and a #m*U barge f liquid! Arodor dropped and elrouleted for an hour* She latter 1* don# ao that tb pump will rue freely whan nxt used* Otherwise th high Halting still residues will frock In tb pump and oaua it to itlek, for distillation f th liquid Arodori the ooadeneer u>t b eoled with water to wff*ot oesplott ondensetien* later la uad lateral ttUy bore as needed, This weed if indicated by *flaphJAg* in the Sight (1*11^ which la a spraying and broken stream fro* the discharge lip, than folid Ayoolor# dr# being diatiUad tb eoadeeaer la legged end steam la used in tb jacket* However, rren thee will flash during tb early Stages of distillation and eoma oooling ia neceaaary* SMs la aooowplisbed by mixing water with a teen, Aa wentinned above, all droolera but 1R66 are blown to blending tanka to Inwore uniformity* Tb liquid Arpolor# are treated with .02$ of dried fuller* a earth, heated to 10$~lei<>C sad filtered through tb Sperry press into thirty r fifty gallon galvanised drum* which are used a whipping oontaiaore* ifodors 4465 and 5460 are blended bat wot treated with fuller* s earth since they *lt too high to b filtered I 'ith0, preea. These are drawfc out through diaper aloth into galv?i*Sd iron containers, ioe tb# wag blending tanks are used for both liquid and molid they wuat be serefdly deeped of fuller*# earth before tiling for 4465 end 5460 and the before using again for the liquid must be eleaned again, loro dor IMS if draws directly trap tb reoeiver into galvaniaed iron paas, After thie goiidifio# it la broken out and yacked in alack barrel#* After dietlllation of the latter Irooler to receiver actor must bo removed and thi# tend thoroughly leaned aino a ao&U amount of tola Irodor always remain# end oon ternin*-* tion of toe other Arcelor# with thie would reader then unsaleable. A feparate reoeiver would be of great value hero* ftWAU&S JELUlflUlUat 1* line fltidga Settles to the bottow of tbe barging tank end fonetincf plug toe outlet* Shi# delay# charging and if th# amount f a till residue! in to ftlll ia low they may freak, A, fretting of the still residual may roiult fron several eauaeai OSU 001336 ADA 000741 WATER PCB-SD0000045908 /or 0, Blow Obliging M noted ebore. b, Foreign astter Such a? iron sharings la the Quluby jwep which will stall the sorews, o, Gradual wear In the barrel of the Quieby puiy> will oh reduce? the oapaoity thereof and thereby oeyee? oarboniaatlon la the oollf* d Fower Interruption near or at the end of the run when there la nothing In the atill but high ael ting residua?, Shan distilling the solid irooler* grower interruption? at any tlae during the run 1? serious, e pairing atill residue? so rapidly that the flow through the coll? 1? low enough to cause carbon!aatlon. When a free?* occur? due to foreign Mtter In the puap It la generally necessary to re-oonditlon the pueqi, asking new screw? and ro-grinding the barrel. This Job ooats approximately $100.00, Ip addition, all lines to and from the pup wust be taken down and cleaned out. Any still residue left in the kettle generally staya nolten long enough to allow this to be drawn off as a liquid. Host Interruptions of this kind hare been traced to pup failure, and the use of a satisfactory type of oeotrlfugal puap here would elialnate a greet deal of trouble fro*, thl? souroe. If a power Interruption oocurs it is sofcetine* poeaible for the operator to prerent a freese by drawing all the waterlei fros the still through the Talre at the pu*tf> discharge, However, the residues harden wary rapidly and the operator mist work fast, I, If the solid Aroclors, particularly l88, are allowed to bW the receiver too hot they tend to subliwe sad solidify at the first oonitfiotlop in the raouun line, thus oaualng low vaout*. It is difficult to entirely prerent this since it 1? necessary to keep the distillate swlton, However, m*ob delqy Sxm this Source will be protested if the operator cleans out the fittings at the head of the done after each batch. d Due to gradual abrasion it is neoeisary to racondition the Quieby puap onoa or twice annually depending on the continuity of operation. The following table show? the factors involved In the distilla tien of the rarious Aroclors, OSH 001389 Ada 000742 WATER PCB-SD0000045909 efrzooo vav OSW 001390 S* P f yr III i i m m f( as9a>85a I I I I Iw gHSS 1 ? i P\r r ? r t" itiisiiI 8 8 8 8 8 8 S I Ii . I I II 8 83 8 8 8 8 8 B u i!,, w 5 \W5 3 3 8 8 tSHI ' s? ^ssssH (ft fv? ; f !! I0* * 11 5- assssss* ##ii ** aanun SlfllHlS! 30/ WATER PCB-SD0000045910 /07 m&M&m fscruu distilled Aroelore ar packed in the following types of oontelnorei liquid Arooloret L 19 gauge Galvanised Iron Prams * 50 gallon capacity, ECi" dls, by il-$/4* high, with t* bung and 5/4* font In head. 18 gauge Galvanised Pruwe * 50 gallon eapecity, eai length and diameter M shore without bungs but with If* 1E-bolt cover In head. I. 10 gauge Galvanised Iron Prune - 50 gallon capacity, 1&-1/4* 41. by Jfc-S/4* Mgb with 1` lf-bolt over In head, no bungs. Aroolor# 4485 and 54801 1. H gauge Galvanised Gteel Cans - 59 gallon oepaolty, 16-1/4* 0. P, by 55* high with 9 Inch friction toy. Aroolor 1W8I 1, gleok Barrels with liners. This Aroelor is shipped both lump and pulverised, one cuetower requiring the latter* The willing is done lo a string hwajqor will* This operation Is very difficult in war* weather inoe the Aroolor tends to soften and stick due to friction In the will, In addition to the above, samples and lass drum orders are re packed in 1,4 and 6 oa, screw top bottlesf one pint, ono quart and one half gallon frlotloo top csns| three and five gallon frloiion top wood-sheathed oene and fit# gallon cquer* wood-boxed soraw-top cans* An attached tsble gives the Wight capacity of each of these containers for the different Aroolors, OSW 001391 ADA 000744 WATER PCB-SD0000045911 roe wshbih. akd oowr tamim mmm miomm I 0*1,6 0*1, 6 0*1, 10 0*1, 60 Oil, *8 0*. (ft 0a,60 0*1, 1/10*1, Bound Sound louar# Qalvdt Oalyd, 0*1yd, Black Bteel Blaek fcrodual .JktL, , JBflSu* .ilrM. .. . Jfonw.. ..Qat) .. Dm ....PxM . . Barrel Bert Hit 6 # $ S>40 60-60 880 800*876 Ua 6 + 6 10*40 60-60 860 600*800 llf>4 8 * e 80-40 Ueo 6 - 8 80*40 60*80 80*60 676 600-800 400 600^800 m 6 * 6 80*40 60*80 Uee 6 m 80 4QO 600-800 too-850 lm 6 m 80 400 00 Wl 6 10 80 800 6480 6 ms 6 80 80 80 80 600 m U4S 6 6 80-40 80-60 600 1148 6 - 6 10*40 80-80 800 1164 6 . 80*40 80*60 600 1160 6 - | 80-40 60-60 600 Her 6-1 tlphwjl 80-40 u 60*60 600 OSW 0Q1392 m ADA 000745 '* WATER PCB-SD0000045912 So? BADGER ftlU V*o4 for dietilling All Aroolere exoe.pt 1M94 Ufi btlo* - Quinby circulating gnsftp* Abort * Bt* fircfl coil heftier* left center - iti.ll ten* Showing lower pert of foe tr*p Bight om>ter abort - Condenser# Belov tecuu* trepa end eorubber** M*ht ~ produet reoeirer* OSW 001393 ADA 000746 i WATER PCB-SD0000045913 OSH 001394 /to WATER PCB-SD0000045914 pf'-TunOjji 07 BADO^. UIILT. iM0l > ..MW .. to, - ** ^JW....... Jsehs Charged ____ ,,.J|.11------ .----------..... found* Diet'd. t feunde EU1] Bottom** ----------- -------... W*1fM(itlpp Dtertefl ___ .... I...............'......... Orator DTlIft Jto. .g.. A). tOC> HI To ............. Mi nm P1; I ; _____ _.".Charged, ! iotoh f Drum i B.No. _Aro____ Deed. J * irum | Checked L.jut.4-- *..u~iy*...lPR K'ettle'' *r Fioo[lvor Mi---------- ...A--. J__ Jjov_I ,, Ho. ij __ j/ejL/i,h_t _Ii;o,^_ j '"~T* >j jw&yi.i.. tI t Mi-------- ----- j-tut .4...4....-4]........... iwjol...........-- !-U- U\I........... 9i-*. ..........I ....iwoa ---------- \. I-- ' --- 1 4............................ --- M .*.... ........... ~ Mi-j.. I m, 4- 1! M. juWK -U- Nj ........4-* m Mi i ------- . L .--A. MOO ...fci IMXI. -- --------------- t.. ......... h jaw8..(|9W>J.pli4 ii......... 4-- I i.... v,.- - - - - - - ................. 1-- OSW 001395 ADA 000746 WATER PCB-SD0000045915 ust vipbehu m moon opmtm torn iszismtl The ettaohed organisation chart show* the sen necessary for operating the plant whan la fell operation * Bndtr the Code it 1* necessary to h*re si least four sen for as oh Job, these sen work as follows! Shift 8 Ken - 8 Ken - 8 Ban - 4 San - 4 Man - 8 Kan 8 Men - 8 Shift 8 " Kan $ Ban 8 Ban ~ 8 Man - 8 Kan - 4 Ban 4 Sen - 8 This lineup holds for two wooks, then tbo shifts change forward, Ban fl taking the place of sen fit who hep boon on floating shift, while sen ft takes the afternoon shift, Ben fZ and ft take tha sddnight and day shifts respectively, this gives each van an average of 4 hours per week over an eight-week period, but the Intermittent character of these operations perwits bringing the average down to <0 hours in the course of a year, for continuous operation it would be necessary to have sore experienced operators to keep the average down to forty hours, All day shift sen are kapt to forty hours per week when possible, but never above forty eight, Jhitlag Jtott toftr-itac This Ban Is in charge of hie shift on diphenyl and crude aroelor produotlon, 01* duties are as followsI 1, Bee that sufficient bensol for operation is kept in feed tanks, 8, Begulate feed to converter unit, 8, Take hourly staples of dlphenyl-bensol solution fro ooluam and detersins diphenyl content, by distillation, thus checking conversion, 4, Pu*p diphenyl-bensol solution to bensol still and distil ' the benaol, 8, Operate diphenyl still. f, Operate high-boiler still, T, Bee that converter wait temperatures are correct. 8, Record all data on dlphanyl operation s shown on the attached operating data sheet, 9, perfom any paintenano# that ba Is capable of ahd which does not havo to be referred to the plant Maintenance Gref, This includes changing distributors when necessary, ' OSW 001396 ADA 000749 WATER PCB-SD0000045916 t/s One operator only li necessary when the twit la running emoothly tot on* man should never be left alone on this Job. For this reason U> unit and the chlorinators are always operated simultaneously when possiblei |!hlgrlfl&k> MmMx It Fump raw diphenyl to ohlorlnator* I. lagulete oblorine flo*. 1, dee that ohlorlnator temperature 1* correct, 4, Bah# density* hold point or softening point determinations to aaoertaln progress of ' ohlorlnatlon. B, f\mp ohlorlnatora when batch la finished, I, Operate hydrochloric acid plant, T, Fill aold tan* ears, 8, Assist wilt operator whenever needed, 8, Assist with| or psrfor* small staintananoe jobs, fflsktr.Jl.UU.fiaflr.tl<at f foe that sufficient orud# Arooler is always on hand to keep still operating. (this 1* the duty of the day shift nan), , Charge Belting tank which Supplies crude to still, |( transfer finished batobe# fro* receiver to blending tank#, 4, Fill shipping contalnere with finished Arodor* and store filled containers, 8, Keep pres!see around still and accessories clean. Balmarn X. Charge melting pot with diphenyl for ohlorlnatlon, I, Break out diphenyl from pans after distillation, I. Feck diphenyl for shipment, -- 4, Faok end store crude Aroelora, B, Bundle crude Aroolor drum# for distillation, @ Belp fill carboys with hydroehloric acid, T, Keep premises clean, DSW 001397 ADA 000750 WATER PCB-SD0000045917 M4 9*i that stilt charge* are broken wp, weighed orreotly end charged to the * tills, fhe day operator he* two helper* no tl>*t charges for ell three (hi ft* way he broken out on the day shift. Operate still* and flaker, Kclto AtJOM&taxM . In Bay* 16?$. the operator* In distilled Aj-oclor*, both Badger end l59 oegan to derelop a severe type of derwatitls. At that tie* ventilation faollltio* In both operation* were soft inadequate end the wen were exposed to duet and ftme fro* the hot Aroolor*. Bowsver, several of the won had been subjeot to the sane exposure for three year* previous to this and had suffered o ill effects. At about the *&* period the electrical properties of the distilled droolers began to fall below specifications, therefore it was uauned that SOW* iwpurity, hitherto not present, was onus lag the trouble. Investigation revealed that the beniol then in use Contained appreciable quantities of pareffln, whloh when pyrollsed with bensol produced styrene as an impurity in the diphenyl, then the diphenyl wm dklerlnated, Ifcyrent dlchloride was also forded, This oowpound i* exceedingly instable, giving up hydrochloric sold very readLly. the theory developed fron these findings, and slsoit certainly borne out by olrcuastanoes* was that the styrene dichloride entered the fores of the Skin with Arecler vapor and finely divided dust where t decomposed, the acid fortted soted as an irritant, infection set in end the skis disease resulted. ' fcin specialist* sere consulted, but cure of the disease was found to be slow end difficult. She oowpany beoaw# involved in an expensive litigation sinoe suit wa entered by the majority of the Wen affected. A* S result Of this trouble the follow!^ precautionary measures sere taken. ' 1. All offooted Won were removed from the operation and new wan substituted as rapidly as they oould he trained. ti Adequate ventilation facilities w#r# installed. osw 00L398 ADA 000751 WATER PCB-SD0000045918 ff * $, I complete ehang# of elean elothing ni nd Ptill 1# furalohed to each wan dally. 4, Total*, *oaj># aloohol sad oold eraa* are alao furoiahod, laeh tMX 1* required to rub hi* faoe, nook and am* with oold tree* before going to work and to take * thorough bath and rub hlwielf with aloohol aft*r work. I, The wen are examined regularly by the ?l&t ghyelelan, I, go wan who ahow* a tendenoy to della* title 1* employed In the Ityurlaemt. ft Rigid apeoifloetlon* were a*t up for bentol *o thet there oould bo no reooourrenoa of etyrena, la a rapult of there precaution* there bae been wo reoocurraoc# of der*tltia among the operator*. OSW 001399 ADA 000752 WATER PCB-SD0000045919 sszooo vav WATER PCB-SD0000045920 /// WOKING* A8KXf$ Mt> OTHKR KOOWDlUEi BSKD W WWHNtt AND ARO0WR MASUFAOWKK' fiaakt 1* Dephlegmeting Column Bead and Bottom t, Bephlegtor and Oondenesr llangaa | Bon*ol Still Flanges j, Biphenyl ftill Flanges {. leotrodryer Cooler and Condenser Flanges t Blfh Boiler Still Flanges 1, Hangs* on Oblorlaators and Traps 6, Badger Still Flanges Maadigii&Ul^ Jfrl 1< Bensol roape fc, Ooil Qlands on ieotrodryer fkikk li Beads and Bottoms of Depblegmator and Condenser t* Oolufco Bead on Bensol Still 6,' Column Bead on Biphenyl Still i, Ooter and Plate on teotrodryer ft Oolunn Bead on High Boiler Still it Ohlorinator Beads and Distributor Flanges ? Iron Flanges at hells on Bel Cooler (Ooette Bo I Copper Asbestos Caskets are reooainended as ' replacements at all these points exoept 7 and 8.) li lo. Prabeater Coror Casket 1 Converter Ooter Casket OSW 001401 ADA 000754 WATER PCB-SD0000045921 jfrlMei JjQM l7MeHla|roi and Hosing tank Cover* ti Water 01 end on lot Cooler $ OylUnder Bo&ds on Oblorlne fej>ori*r (t Cover Qaekots os UdB Distillation Pots A. Cover on Badger Still Oharglng Pot It 01m* Gauges on Peed and Bun tanks i'. O-Behds on Cooler tube* - Hoi fleni Jta* It Bead* on Bongo! Bill! Btea* Obesl* lottrlmi .lass 1< Reoeiver Cotor op High Boiler Still Ring Reeking It Centrifugal Pu*pi Handling Crude Arc*o!of and Biphenyl ti Agerloan Mareh Centrifugal Puay> or* Badger Still fiot Aroolor circulating suites, % J( sMJj&ft&tag-AtAaiii It Bight Jar on Badger Still Afti&wJhiUi it Titreo*ll Absorber* and Coke loser* Jlol Plant JhftetJSubbar It bust Oolleotor Pl*nge* and Cone above Oolleoting Barrel I, J>if Oover on High Boiler Itill ! Cover on Badger Still Receiver It (JulabyRwnp Packing (badger Still) It Crane Regriodabl* Seat felve* on Chlorine Paporleer it All Olobe and Cate Waive Stoa* other than thoea with regrindabla seat* OSW 001402 It Toaere at lei Plant *t Acid trap* m Badger Still ADA 000755 WATER PCB-SD0000045922 ';"4S' / DSU 001403 i ADA 000756 WATER PCB-SD0000045923  Hm BAWNOE CW.fKESBW tlVUMti , OOHVEKTER Wit DSW 001404 ADA 000757 WATER PCB-SD0000045924 ADA 000758 WATER PCB-SD0000045925 mummM .stoMgXmkJMlI fZi A tent cm the 6 pot lead hath Diphenyl Unit bob aede on May E2, 1656, Tltf purpose of this teat wee to ueoertkla pertinent feole regarding the heat hnlanoe on the basis of presont operations, The fnote to be brought out by this tect were desired la supplying date for the derlgn of t> more affioient t)nit, the test lasted 6 hours from 9l46 A,M to 5l46 P,K(May ?, 1986) and the following deter*lnslions were aade, 1, Gsr- Consuaption 2. Tempornlure of the Beneol at various polnlp Tomporature of the lead In the pole Temperature of the side wall of the Unit at various points Temperature of Ccmbuetlon Oases B, Amounts of Bensol fed and returned end produotlon ( Procpurer in the various pots, }' the attoohed Print glvee a clear pioture of the heat balance showing tlie heat distribution and the temperatures of the gases at isportnnt point?.! The efficiency of tlie Unit as operated at Anniston Is 46,80?, based on e conruaptiott of ,P ou, ft, of ge per lb, of jjrocoeeed Beneol, le other words 45.5? of Hie total beat cod tent of the gas ie found in the garer- leaving tlie converter, The figures used for the thermal properties of Boa sol are based on tlie formula given in Perry's Handbook on the bottom,of p go 649, Ko data war evallabla to oheok the foneulst It Gar Consumption Converter pot ~ 6 burners on and off Preheater Mo. -8 Preheater Mo, 1-9 * continuous Total 674,9 on,ft,/hr, 659.8 E178.0 00L406 bos heating value of gas - . Total heat in gas 626.9 S cal,/ou,ft, 1,161,640 lb.osl,/hr. l ADA 000759 WATER PCB-SD0000045926 fZZ [t. laMTitime. Moe cured Beneol ledvine Vaporiser Preheotor fil tl Converter Lend Proheater /I H Converter By means of fapnlog After checking the Instruments and on the berl* of Uie requirements of U> hoot balance* the following teuperotureB were chosen for the beoeol t vsrloup points, ; Benr.ol Fend Benr-oJ leaving Vaporiser * entering Preheater * leaving lend Preheater 0X * * Prehen ter /l * entering Preheater / * lenving lend Preheater # * leaving Prehen ter #2 * entering Converter * leaving lend Converter * lenving Converter Reaction osBurned to take place 25C 156 154 { drop in pipe) 41? 570 664 (6 drop in conn* pipe) no 650* . 622 (6 drop in ooan, pipe) 651 760 750C The rending of the Tapelog et this point sne 626C* but wae found to be In error. leopernture of combustion gnree before and after the vaporir.ert Before f>60C % D0,, 6.5 0*> 9.62* (BOjf Exc. Air) After 660 Amounts of benteOe fed returned processed 961iP/hr 697 64 Products Measured 226 1JC Blphoayl t H.B, 9j Be one Hydrogen (onlculeted) Benton* carried by Bydroge(0e3o,) Told Products measured lr calc* tJaocoottatod for 206 0 6 6 66 2#//hr, OSH 001407 there was e wall look on top of the oonverter which might explain the difference. ADA 000760 WATER PCB-SD0000045927 /J 4. froii the height of the lead in the B pots the proseur# oao be calculated. fue height of the lend woe not Measured but taken fro* operating data. Top of Converter Brepaure of Converter C9* of lead Oftloulated 1 lb. Ewjofi i ib. At top of Preheater fift freeoure of Preheater 02 45*of load 1C. 8 16,5 At top of Proheater 01 Brearuro of Preheater fl 47* of lead Proppure of feed line 54.7 AM. 55.4 57.0 49.0 Tne teapori.ture of the Bensol leaving the Vaporiser wap 156 Oorreppondlng to 68.b eboolwte or 45,1 gouge. There is probably a eMail error in the temper*, ture rending aad perhaps also in the height of the lead as reported. rvy> C/18/5& OSH 001408 ADA 000761 WATER PCB-SD0000045928 ntWJKf LWii'.M ..**" f ;d^;V ;V ; iv. DSW 00IA09 ADA 000762 WATER PCB-SD0000045929 ! 1:'K'P '*' .1,1 _ . t t om mm* m m ms *am am fcmft oasts os DM***, m Wfanna, Bota fOs tux m AVRwoi oasts jro* ttmm mwi * . }i 1 V OSW 001410 i f / / i Vi:. ADA 000763 WATER_PCB-SD0000045930 SHAKfC UE0COMTAKV n:op*,, snuxn 6 1300 G't30: 6-1400 c 1430 $ 1400 (3 OfP.R-im TECIfii'iCA. H10H OOILER DISTILLED H - A^oa oRr, C'.VOL AROCLOft <- To (it 1401 Anocun x* ms 1403 Anoa on tr ((4? HQ's Anocio;;;? | HO 1406 AWCs-OT i! I |5fi 1407 AROO. OR ;/ | |M 1408 -ARoCLOR 1160 1400 AR04L0R f U62 1411 AROCc OR jjf lies 1412 ATOCtOR it 1160 |4|3 ARoccon ,-fl lies 1414 AroctOR J 2505 14 If ARO&OR jp SI65 1420 AROCton 4066 1423 AROOLOR f 50&1 riniuro A^CiCLfft To'.'A1. 1491 AROCLOR jX |6|0 1432 AROCUSR <1 1040 1433 AROrLOR ff [242 1436 AR<'Ci OR *7 (240 143C AROO.OR 1230 1431 ARO& OR ^ (254 1430 AROCIOR 4 1260 1439 1440 1442 144? ARvOiOR # 1262 AROCcfiR 1264 Aftoo .OR i? 1260 AR0C1.0R f J2C9 1450 AROCton ,7 4405 1453 moc or.J 54 CO 14S AROCLon i? M42 AROClCA COil^OUNO f23r OSW 001411 ADA 000764 WATER PCB-SD0000045931 y ?Ik A Dt ' DSW 001412 ADA 000765 WATER PCB-SD0000045932 arms:'t.w,0' total 8 V? r- > ?;'( to . ' vk2? 'W uy cor. tour**'&,>21.26~ SYMBOL . IMS MONTH Amount 1 Per lb. *CH O'11300 .01 , , ,!. v. fG/- 1 UWIX'l 10S& K SH1/Mt.'"i. ?l/t<1yO1/ - (*v. hi coar.fi (HO 1 ) Jj3) |>WI0'. MONTH OF " 'buooei r /** * ,Ba5 ' V B|*i8n3. A4 Pel lb r 18 .216 ,000 !.240 *.*l*u w li` UH1 fWrlit UM lHlftA Pt*Wl - illtlfet , Iff** Untf Cfr*l ip film C(olli INI* ft" I** 1$ EtrcUodc*orf>011 1T Stocking IH b- *r*r fn.cM f Hvtintt nfi U*M ^ fcjirdilieh . . 4,. W'HfttvMtUlCN ^ liMjbiluWn* Cfiit PwM) 8*1 E40 .0)5 .491 . .573 .499 .012 .009 I 16 .301 ,047 .233 ,030 .4 0)9 fe.7PT' .404 .300 2t4? __ 3*351 J7.9W TlO^fi? PACKIKt. ANU SHIPNNC COST I liwli j'l li*w ltj( C** jh uw ; p fe*;i CtrtAfU U*r 64 04*1*7*. 14* I*)-of p U*\for. EIo 5h.*W,.?f h<Tp. -fl, . /_ .. . SJ l>*fi 8liln, f.l'i J ) OA'/'-'O Ntlnt llt>inr Equip & BltJpf Jj. tfI UJff>rVI\| _ _ ... . ______....__ v ItUI Pitting Coil !** V ^ . JO hi,n" y.i'* _l` Okpr HntCor* Q Uk*t tirloidi , like' ICI J1 I WtlpMnp ' l*l|t Shipping C(kC| tllKlibvni InvtnlM) 0^rn1n| lncnlofj _ tnotlrttetf M _ Ifirfvorlwt* . , , w ,l*UMo Aoooimt For . timing Invent**} ^ DlifMfd at . . %_ **,Prf* *) v A<i D.T7,, , 07/. wf S'" / v 8ii ' Cl- fl* t i< *t. 0/-/ 3oe ?!- f'.t* .& THIS MONTH Pound* ^ Amount Pertfc. >. p.o 9 S'/?: no .1 . 31 -?'/ r tr(AB 10 DATE Pound* j, s 0 4 . yw P*r lb. M d 0 .tir /- V ' 3. j.j /3 VC ~%m! ' >j v*v . 5" L~f.' ; ; gy ,<?3^ 7 *3 O b. K'J '<3? V'3 -kd V5T#1 rS7'kTy . ::. 3.9,9 ?-. 1p ..H#IH. .77 3*5.1 t*?. 0 I. 5 ,*a --^;yr7" F.ck.tf V (1 r$Vj yi7.7^ . .jc,1 W%-/.rn eo 9>. `i to 0 i. ^ 'S ( ? . ./m .?37(, 1 ni ci '. 7jfi / mi JXj rl ccH rf! 4 C 4- OSW 001413 ADA 000766 WATER PCB-SD0000045933 ,.IM5 . '. * EQUIP.* kv'Ml, H iUt urimu PRODUCT DtSYtUEO IH B01UR If vr*& r* *>*# 1 ' ' Dimm Ii\I UKi1m03 . NrU <,0035 oflVO *e7|| *o? _o090 ; lo230 02?. ,,S3H 0i3 .III* <rt |lMf kbjl tl'U'M ,W^ t It* tti} %ti< tmi}' n CrlV fctA.\ 1*4 Cm ;iW* b'lwit in-% m .*F' fltfvUtf .^v avm #;r iY ' <*( " M. (\<.l I'iK-ei. Y* / ADA 000767 WATER PCB-SD0000045934 L et-oas f 20. A>> FQU1P.? tz.w.os I ,tvt *CvtaL * 32,6.02,13 11"'"*' 1 L., f nflrflOR_ - jimuho H'wt 6s'vr ! 1, "10ir I ' ni !. wvct-o0 I JR -,f AIOCI.OR ITI o i' " Wl , 1 V, IMSTUirl' 111 0 j\j 0m.oAl^E pi J /;RlQl.0n , V.I.1,I> fr Intra Pi art PRODUCT CRUSE WOK OR TOTAL , symbol $0-1 6' 1400 MONTH OF I tf \(fn\rti\<'* ruM t.HtffftW ?r* CH*trci yillMO *(^ iMft ___ VtiwIhUhIaj'c.hU pUCKiHp AND * J't l<v,' ................ I(|i Cm> frb un l>|i C*Morv ........... )l. 1PM p LM C'l f H SWp | t 30 t*AT 1.8 JKt p(vt'ntlltlrrlup C^mI|i ----- -->--Bldgs,/. - . tlUINrVUg C**\ buip 4*1 |l!`) l*feWr||1f*nV A*J tn n ii* '<i itut ici [IT IftflrMftj t , WBc*M<nS.nhni,plprtirnpgol<Cu/>t tfih\*Q ImcMoF) . Vwhnti In _ iUfUitMvtt*ffict<onti1.f...t... _. Instnfot) _ ^ biJfl'Kfl M t,? fs J'T -r. - ., />$<!/<} if i-r/'i-ei -/ o? ' L /</ . -vt / V"// t /</:-. 1 ? ( si/*s' t> 4 '/</> r _>p~5 .i 7. ' ; / wr.r;;'srcrs . *7.3. 73 ri LD -iW/X _.. OSH 001415 ADA 000768 'i'l n WATER PCB-SD0000045935 Lter.pt ^s'* itET. TOTAL * fr6#l L,.,MtOpfl PI 0UMtWL . *U 'Rltf j-O flirKtuyi 531 CMLORiwf EQUIP.* OM1H Amount || product CRUDE W0C<0R/ ",!> . ,, SYMBOL SW6-M0I Pet Lh. umwwu Amount (| Pet U 7MONTH OF//."-i _ *UBCf1 Amount fe M>. ut 163 5 . |1 A ' rerlo. UK* VfilrrUI yii| lohof - tfotriUt |tft| |M Suppllfl V*.rff Cloll* $iii* tfftt *>!> tit llP'lflol) to FmifC((i. 1? StocVInQ |m(f (M.wrilon (> >''M Vwm<< *<* I***1* fojiftUNb/'.......... !<*< lCrnertto UijliNvvtttlon ^ . ", Sh*ti(lpilr'6 Cotf ftutt i Mckihc aho sturriNG con UmU UU'X *f*< Cim ,. . . Itgi Ci'fflbl Uf*i M , CyiVoyt Hi tt<of tm> Cm F m Slag , litoi lit* Stertog B|l| 5lnT*pf fgtilp 6 0fdgi Imtft RtpirUng # UUlftiUnf Coil tvimjf i} 0 >ujf tf } lain link C*tt . lUr C*rlt<1 likor l Cl Melting 4 Weighing . IfUl $llpf#lng Coil ^a IMfti|ilv Ifn(Mot)' Offiilh| Inventor^ ^4 twUfdfn .Frij'Wtfd .^T 3 ' f ic & .........._ , , . . -Jj HUU BrwmM fof ClMlfijlMrflrtM) _ , ...................... ,, fciifimf of 7 <0/< "y$ '`hr t/vif i ii . ii THIS MOUTH round! IT Amount ./ f ei Lb. -I....... year 10 oak found* || Amount |f r<t lb tfufk' ' ,5^ II \ - 1 3 ftt>h goo -f. 3 m Pocbt4 yt, .>SLJf / ;** .*. y\ ><w ji 'Y'Mr ? 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UlHI4cc<iun( For A , kufwd or tnfi ^7 /A\ttr, ^5 . / y^ IffIS MONTH Pound* ?; l </ jT /^ > 0 0 .It'Vi 0 <r: <.> % Y.r 1 /Ji^7 ?7 1-7(3 ISO c-o 3,11^ kr n Srs iPh '',7 ?r> 7/ P rs 7<2l . tvi 7 0>7 p r v' . <5(9 36,470 .075 .5?5 J575 15, 172 f j?;llCl6 5.075 B.A 16 f7.57B Il7 991 ' .002 .001 .200 .150 . I06 <2?l ,H2 .050 // v'J <// VC . 1 v VL.5?* V9i 9 si < f 5.9. .Ci3 | ,035 . 100 c0?0 .001 .037 . 117 .020 .001 ,7 ' cvii *'tn ~nr<AA; n:,/%p J! -<- c- i< '4?A h\\i . ... yy-zMi/fl'trf _. >v4i-/ /4.vi t[. 74, |... ,.001050 C05 .OC* .603 .ooo ;0?l . I5 i -25P ' .0(32 fp"*60 ' 6Of' .102 . 156 .013 .096 .571 .976 f 967' Per lb. S1, VfAR TO D*U Pounds p. ll> ' S. So S 'L 01 7 4 bn\ A on ft Jv 0O 'J% 6' s7 LC^ .//o Bulk' zmi-'M r.?\?4SyA 7:rss A\ o c- (c ............ ,o ,(A j 17P .tile T. I o'O' PseVrd ^ P/I API, /* * S') a n mm7 V;TfiO' - -35 c/ - '1/V7 .. M i ok o ?- o .<COO 7 "'VA z______ * t k1. ~VO i V, 7 4 U Y 0 Vf?t. . b<4 DSW 001417 .1H? 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Mitaf f 91p Rjtfyi .J M". jlpl.fr llrrlnj . , Clorkfi* ^f.uA>&J. $ Jjf_.^Tu*fl*ttPfatrwlln.gryCrajll vt (.)<_ ///. t/ifjje- V.' <1' L*baf_ Ink Crj II Utaf t*r tnaA* .41 lto< ICl 41 IwHofetnj A WeljMftg 1l|l iM^pIng Coil Inv^Mbry Inventory liAMltntd ln_ _ Pftfwtf,, UUIIa Afoeanl For i~ - ^fflrclnj Iniftnlnrj <1 /llVj' fy,uz ... . / ...... -- tilin'c- t / / $ - / / \jtQg~ TM MOHT Anptint PRODUCT 03.OE *.35Cl PR # l ME) /f<f EYMBOL SC,H .. AmpM II P.rU.' | MONTH OF_/V ', los *' .. t/GFf AlAAVAt ftfit to pu_ """ I .fjt ' .V p j -'03s| - .. -- | .*V9 zvr>z fjjo?,*?&7?l :?t :Bi7,Jv>2 17..*,33 ??2 .?.>? .1.7 t ,1.7 {",77B 1 ".'ri;.- 113 li , I i ' 11'*' f ,o?i ( J ! , rj. .zo: .4 17 ui a?. F.591 IB 727 :::~4"{--I--- YEAR 10 OAU *. ` Pawnrf* }j AnrDiinl || "ftt Lli /> - - -7 S5 1 ci. i.. . .i t? 7'* j ______to ?y\mi T*'7c3H ;Tnd :/>r 'n uitl osW 001^18 \1t f'i m ............... --. --- ;"; 1 ADA 00077t WATER PCB-SD0000045938 vrtCt. BLDGS. f 'rftfl, 101AL * u t,< M w iyt' mpi?! - fis: EQUIP, > tt$ A0K1K Amount j! PRODUCT 0*li0k' (WOU.C-rt t i iso ', SYMBOL 50H 6- H06 month of '//, *y Perth. YWR )0 Plf Amowril Pet U>, Guocn Amount fttU (tefa l [t93*' Pel IP 06,560 .530 l.'M |> (MrltCNYL j3i ciuobinp tifixlllm "ill*' IfM.llhPl tfM.lrt'M " IMtcUt tfj*l 4Mt FuppNr* %,te* ciftrti * ?**( *f\rt ft* ' 9f' . bU*4'M) 10 FIMrf Cloth U ClrHft.dclOffuftOH U $\otVtng ^it(l Cf>mtt*ton fl tfi.(itPUM 11 t*ttltfc<*t JJ Ir.ltifinf* "< ji W'WtCfiftrmlph uuic^mipp^ 4.6(7 -(>17 -.007 ,oie ,00? ,,002 0(2 .Ml ,QT>0 .009 ,006 ,031 .371 ,071, .02*1 . ISfe ,62*1 5,441 I tWMMAK0tMrfiNCCO$l . , |i* A**nU 1 !M ***** , fl fcj Cmt tit Ukf .- . - ,11 fifi Carton* *, Cfrtoft"" 11, UHt *< tpt.ot , 'll 1>*tCirj Icf tl*j # # fl_. m p,ur v: i i in | i*Mi tlMlnp ft Uptijt tqulp t Btdfci pi U|j In fttpirklnj j UUI NtUnj ; ^ </r ! v f/a 1it Ukftr link Cm i! 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K dntuiinl n 1 Pel Lb /3 .4 ,1 O in /VUS 4>1 Z3l W V,j6V' >> ,OIQ 1/3 0>'i '/4>, .c? 1 /tV / 77' -oqf ,,*' * ,<7 m 77 6' Bulk ` 6 .ov 7.r Jo? /o .yofy J.y . d^'LV *3 itiS'iS 7<JJ H jj.S.yy ^ Si.tyo>i b.7 it- L.yof . . 4*0 <y,9o v- % L^ot 3 $79 ty*/ "s.o/ ; ?.L l*ol(erf CoO (I < Vtf?<Sl>Vv CTO C' Jr (J<r / fe" c. <J S' o 6 'H \) / 7/ Y.Wv . so-yJ&lt-oy'f OSH 001420 7if f.ir i./1 tuiP ADA 000773 WATER PCB-SD0000045940 ^ ,c* f1il0DTGA.SL ' %* fc**1 o fll'l''1! ii>' nv* - > - : ii T*i. . _ jji ........... EQUIP, f PRODUCT ______ SYMBOL ;*, ,*' ` ', ,fHI&0KUt ^ AnmiiM i 1 ` *" YfAMlODAIf. ' ' ll. .. Aivoi.c*1 Pe lb "I # i */ MONTH OI'_ flUtlGtl. AnU,M ': *5' {&+ fc. IP/* . .J . 9f * Pn li. Pm lb " i S' ' . c_ ii :t , . .- : ..1 A * 'A hull1** M.If'UU `ill nr'.l**- ' * fciumt , . (frit |M Support \ .if f inih Hi* io. rmf/cipth } *l`M . \f> 17 fcfeclrcrfrf *r frlO`l1 ilppklng _ ,j . 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P + i* 4 Bulk ' --s-- I- !l - 'I. ' Pbdiil -ir. p./ it Uir<f OSW 001421 Con of S*rV Adf lOil'lMl Hunlh f r ADA 000774 X WATER PCB-SD0000045941 LfJOIAK.?, EQUIP rnopyt-i ............ . evMROL SCf( 6-* MOP fACKIHC AH HIPf<N0 COSt t |i_ Piirth t .. ............................. r1*N* -ttAi ' ft i*v*> ..................... u faff .Ceilwi* Plr . . Jt jlnktt'l fw HJ / . 4 HV'i4IV\US ..ni' ti.| .. ItJfilt-KtllCr JL tftwlp. P PWb* J*ii i erLCVlziP T*lif Nck>n| CmI ^ w Wik|_y*y % !"*M* . i\ l*Vtr link Cert .. , /. tta>UkM CT <l**ulr tel t <1 Itlielilftf A - uuiihifpifti ct , tytrity tfWoMof^p .. JHflltirwJlR.......... . t . , _ _j(0 -./tffotff__ 1J11 * ' ' wufmt*uh<ff_ a . . 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' ' Solti ' j -.-77 Jo 1 kr#5f rj bjfXk YEtMODMt Poliftdl II . Amoortl fi u., /> 7Jl c7K 1/ (c Wi '/ Futkctf tint osw 001^^ ... tytUUlt.|. IP 11 lit! HoMli. ADA 000777 WATER PCB-SD0000045944 I ifttst. BIOCS.# EQUIP. i, w" jsj r j,/'*C,r&1' - Vrf,r._ vl . f?p c>t /.Roci/m- psrr-jitiJ(f/j?f33,X7I;'*tACox^'lKsoAroca'riivoiN.mrEEp('MI |o9DfCpou'n`i/FNl?yitSMr s/tf.dt ARocioR MQ-M.I.f-107 J, rj-y fifpHfNVt................ miI, >31 t^LCRINC /!, ar6ci or / i ;,r^ - ^ > IIjQHtrtifc#.*/'(VSLilcffjlp.oUr J.LUJ ^Jt4l__t [ft |jrnHl*fl ... . f|Tl*wr . fiT*... . * *W,UkM l| ** SMffUf I'fj ClotwlhppHr* . h* J*ti WtftrK' !('lj)i..->M'L " . . jj piffH CpnerJftft jV fturnlt'Mfll ,, ' mnl_ . 26 O J fcf C T .V tL^ARE [|i UjwfiftW in< _ -_______ J ~hUtHfiUMrtliHUtptGhHwrirvnflyfbUOoofP*t1_B_ulk_ . mckihp #\hb fhh,nnoj&o>i ji, iu( ............... .. . . ff| LKp ................................... j)_M|( Cam I!***loM . . . 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Il3f634|l3,7e3 jirf.j^ *-i- *.* - v.4 . _ ^. _____ Tfarroom h * -* r rcKfl Iflil Col 7} y *Wm*m itufpniorf f it. OptftlftpIwjinUry _ r--Nflrcgi__ ___ I| Uuitc ktfioitti) Fr I, t *) /rii 11 1 2 15-- -- ,.ZZ/JL4.l .| -y. jy_ .fci-;yi;. r-r-- Urn k%$ 1 |.TT4f/F^ J*'-1? Uif< ' V--,-: W4.U jl. D$W 001434 j^-d vf.'jc^!;.v: v.v:v j~.' I " " i - ADA 000787 % VI VX ~l.A j. . % lisr71\2t/. WATER PCB-SD0000045954 WATER PCB-SD0000045955 fctst.puoos. # .1ST TOTAL * jiib) ........" ~r * I Cw*jtr*rHr iQs.Pt - . ............. - 5T Cfwpf.Anoci jf HW_. ut7 .REPUTfL^P -MOtLOft i. p MOB.OR UHC M4 t,iue ... ; M07 AWaVR r M&J7 AAMCoWawR Lin1e254 ... -. Lj40 J.JRC JWDWJE -- lyAiin lMrrl>l , { b/fnlfl ,, . iliw . - ' .- <*'**' h t Ip,k - - f.( fh*B . .. !i 1 'h . [K.Iii. .. Arneonl I Met Ctrutritan . 26 1)1 MTCT SELF ARE. II lirii(tin< 1>m_ . ' * . ' h' PqHMHU>i>_______ ^ M^frM Ceavertfo* . |t*1 CoBeujoi> ^___ h*0jrHiMjfiftuflnr t>tl Pull r^L.CT -.. SYMBOL OWHUP ARv~... r fCH 6-143? ... MONTH OF..../.,.....1..<....1..0..3.5 '"T-_ vcm&fin 1 / ,,,4- PACKltfp Aft& *HIPfISO CQli t*MHf_______ _____ ________ #*gi* ten* .......... .. t- i-ffl . . . ----------- [M Hs* ****____Cfiojr* ..... ..... . ______ ,t lUJ l*H> *T*J*6JI...*.o."ip...*..*.!.#..............- . Uf.,aML'lU*!ai n:-y|7. tl* H. I! tfVti-t>_n_k_O__>H.. ........ _ jU ltWi7'-i iMdi, * " i|0 ut.HWelU'itiil"WthKlng* ph.:. - <44 v^Mtcsri1 . "^T#k itjVTSL FlriiWShHmt*4_6__*n__l._f__f_ ..................._ I___loilnj) tnW'JfJJ.___..__.____._,______ Sekiil[ppppVpMo*t?ilFlMVI I ^ t t. f ,,.......T. AVm* *... &2Ln'r.-::.-- Viti .Ftt-rJ --...........-- . izrr?jF/t7i?T. .Yfbj/.fw r LA,I14\ lzJ:p7. W/M .J.izyjPI Zj^rMw^-n Si. . /i K. v / ,, mu- I ,,,$sr 9y W< IrsvIpTH?] 001436 's'o wA to + -' ADA 000789 ~TTJ- \r--9JftiYAhJi\ WATER PCB-SD0000045956 b~ ' >rn. it0, TOTAl I tn I ... * . . t cciutr. pROPUCT DIS1ILUP AlvQCtOK f I ZOO /X# , . svmpol SCH.6i<33 .. .woimior - / ,0?f - lit|t oirl*f . fcmil / 'h 4, , Hrriftfflt (" U, ftW*rt , H fc,t^ \ fMLVSBff i. . J- . . mv V At ( Ar' "Cl OH / I I s.< or. 1.1 m ? \.* lum: 1 ..(W. i its; y.w.&i '-,;c Aft.'C* OR It 1160 /V'lOCl UKC fit, iwi I hi :> I U'V , g t (!* t. , e, v Hw>' . <!/* J*A'. aV^HiUV t y*m ( I fw** j'. f** ; w i Ut *y ** i io ii>wcu.<i fj. orTwrlOit \ 7 ItK-Vlng t 0 u*l `i " } Iiac*'tuM I, ItKtfHM *.f U*M 1. IrjM.if'inh _ , C(nvtfu<efk 1 ItUfCAMmto* w 4 m ' Crt BwH ...... M ' ! f*0KIKC AKMHtrriKC COST* j) IfMlll j*H Ct*l 7H Iff* C** . ... , It* WVm ,J fc; C^flpiv_ I lh UK- , , $4 Owtip)*_ lk* . M 1c* St| . f.t lvw 1. ;< . ! i > \b ft'ftl J\ tiMlf* fi 8M$* % iwir(Una Ct.it _ oi ` 4~ t . 4t 1v<;.V.t+iv *1 tjf+r c l*>4 4 *1 UV<m' tu , 4! * mi.tr* l WflgMr* . . . ... . <w. , l*t iMK,ip| Ctflt Ktfrr<p. kunUr^. , . lUMtHltf m _ , f ` , rn-tfucr#, ^ t*l>MriwAi"itrr> -# ,, . C* .................... 'j f, L Vil J>i4^ fO.t <MS 551. *001 yA-or/2. fac^rrf t \ ulir. f r./.o.lO o'>/1*1. r ."' . f f. . t . *v; - . /- lr,/, / / ///* ADA 000790 \*1,.' !'' WATER PCB-SD0000045957 If ILDOS. EQUIP.* PRODUCT DISTILLED AR0C10R 1262 total. ,, I H* h*Hj g*. . .. _ SYMBOL JW 6-MSS MONTH OF-V s 1*3 5 ... I__s_t __US'.W-:XJ-J.VO*. M, mU.mZ.ZiTX?fIT??s ZmiJWWO^Oat'uf_i._i_L~_i/_JQL~ _ a perU. |^ Aibm**. H . . -- ....-------- -- .... 01.. ... .............................. ixxxxix::.' \ :x3xSx -------------W,&X> 1S../ITI mop cnyi)i xx/:x. ~|J7w2" .?ui AK0CLC* tlHE ` Totoot. ,... .. . t(03 motion fitf-tl ". .' ' 544 /U!5U.0fl O'ME ' .tliJSUW--------------------.k UVM . Vl1'"*1 , ' f*w* XJXX . ' V ... " / ? ** * \ '/ ;/ i-" .X*S` cw __tP2i ' 1 ...... eTsirr h.33: --/7 ........- - >- . iW j500 . UJ'O ------------- 1. . . .rno . .560 .567 #**77: , . . .400 ,477 *' \ . *$\< Sut*,`r* . ,** fIfH* 10 rmnciMh . .321 '..;v .:j:x.:c " <K? .27e **1v^**vfr.4$rf , I7 ' LUX^X. /LX..................j. zL , 185 |-------------r- . -J.03.0 .036 ..:::7-'jv. rr..!6o .' .'H6 ________ //' - -i, JxJ f_________ J__ l__ .076 ..060 .'(WlUfMWh .... /_Ji_V- , ... .: % y-,t,v-vXi , . . r Xe z,?. , ii rufi* # ,,._______ {. .>_________ |_________ <x .-.pxj -IX XL 200. .gv #*nf lairf^ ku'CmtUl**___ C**1 XXX iX .\XX txxxxl: v :XXffXXXr.'IX V.'ci?:; ''!? x|_ J--------------8------- Xv .1. x. c .... s . ~. j.. 1Z______________ I... L -tmJUQTsL .1,7,V<>!X}{. ........... . ; ) XV03 j 3,BD2 i4.,u35f1f. -Y_ty ... flCWM AW IHIPPWO COM, > tiefcli ^ , ., _ . I OhV ^ ... epM . _ 'l ItW* ........................ _ >|i * M,, C*rUpy> H Ujrw.... < `it " ,,,,.., X-. IHIS 1 --j. {.. X*.- !X..... ---....-.Xl.. t.*'-..'_f.E_X_!_,0.'?.M. 1 t'..V.u.. . ." XX-X XX ...X X/i-'XV j, *. V** riu/A-- !i,, Hitjl ljarijf E^ulp. A fildgt. _ fifklRj C#H_J twi^t 'l j* * r.X.71 <* f4 UM >Cf ... _____ 0 ** *"* .t, Ty. . VI . ,,, 4. 1+lfltMftflni Ceil %,, ,^ MuilAUn UvtnlPfy ` . invfftiiff 7 . tfiMfmerf *n_ ^ I----- J^*IU AMPl ftf___ ___ *..... 17XX .*'.,*;vv,///<'T y Virl OSW t L.._i--X-r--Lj--- 'Cj' -jf*t ________ _________ _~ . fy no ',l Et:--';'X'xdS.L.x 1.3.. ' 1 .O___ X___ -f/y-JJ:. -V- y_'li -- 0- ' 001438 X - - X1 7 X j. .'_ LXX X |-pr.|--r7.T|_rz>t: /'{ t,i - ii -........... ADA 000791 'XX '*11 WATER PCB-SD0000045958 ,,rST. BLOGS. * .tcr.rOTAl > Lh^' ur-*! ptf^- - - EQUUIlPr<. 9I PnROwDUwCTj {vX<StfTi iItUL.Etu0 nAnRvOwCbLvOnft f/ 12c6m4 ^/ jjTtjJpt ........................^ SYMBOL_ 5CW 6-HJ9... , month or. ieaS '. tHISNOHIH ' 1 jfM.: TEWIOBAU'^'.r.f `1L1"VuMSEI ' . / 3$ .. ! . BI>P1 .|| Bulk. I ^ I Ptl,Lfc. | M0PI<! I TtfUi. tt Plltk, -J..~ f _____ }~~wi' 7. Le'ue,w*<'.UV. Vr /> f|M|,ll-or fi* ; [B i'i #* idi>piic t* Iff* | Ffff || w<* Ih ; ). * .. 10 Win Cloth tli Ilfctrodf* Or f 1> ttorklnp Oil j * tiririf'PMfrktvA 11- fowl Pltftf I Uxri f l1 _ _ __ i tfllffl Cthtcrllon _ i k**'1 C"fl/*!?.,, -- , e^VMot CmI Sulk- J rAC-KlNO AMO SHffPIHC 00*1 ,, t( *Uli , ... Hi 1>W ... . - . , #1 Kt|l CM .. , . Hi WVw . . -_ II li|# CmIam ^ (80. Cpihojfi^ . m lotor Ho l*hor _ H 1*l*r( Fet.Sbf . . _ III l*kw /* , f H tlUtVIpilni ;H fli'ol. Itonftr Iqplp. A . riHMUIjPWtVv(ovg cilmsi______ _ . . tiZZ-ty'- 141 lifer link Cm fc * 0| lU CtfWftlU ___ {<1 Uhw let \ . . 7- .. ill WoJ|Hlig* - - Wt tMhHnf Colt _ FlMiwm buitMofy Ofiftlhp tantorjr ' # to . . Pu4M<__ _ ____ HUH* Aettimt fftl_ Ctoilnj tnwMpvy . _ ___ ,_CU^*if4 *1 t Wf|*4 ^ I . I 1 . .H . }Mi ' * found*""' * t " j .* . Amminl I " '* Botk' i*4 ' ----------1- 4-- l-l Pcf It, D 17-' 1* V YfASlOOAIt.* fouoOA AmonM K Pf. tv. t " \>o\ ~7 . 'r o ./DC' PprWrB o'yf JOV ^3j. ~:Z~MnHrnt - 'rrt V*M OSH 001439 \- i ADA 000792 WATER PCB-SD0000045959 LV.i.o't*. t wj7, ^ ' . eouip-t yjj ***_, , . Hf? CfeX* AHOCtoft # 1168 _. ARoaon Uws . ti)t AROM-Ofl # 1166 . i2 Afiooien / IWO *54f JUKUHl UWI l- U"\ g.R^teVM tUUtfef -. . * HaImUI |*\,yfhlltr ,ti<r tM5 fii" flH f I*' ||V'|IH| ' , 10 filler Cloll. 16 C!edr(itlrfur)tm 17 H.Cklnf , ' fermion t-HUlfU.I 1 VnlffWiI bt.rr.er ,>0 1.*n. .Js/7/M!?--____ - ' WwrltMvrrilrr, Wt)t.Mt;<U_.......... 'frViyrtr'lNl M0KIK6 ANR tHlH'INC COM. [f'.ti'iili Vi UHr .. , . ..._.. [n 'll' R' Ik. uvn a Itjl t,rtwii Hr .1 IrrlCrtl '. . t<~ C,rte('r_ _ 0<i ltr.l ___ ,, dr PRr.4# 'A,,*/<> %L1 ' -*-.v 4 4,1K>| SMe, .. it, MW tWiril' fopip * *W|* . . j .LI*U"il ___________ yi/ . , |If* . , r UVw lfOcfc*r^ 1} U** iU<U _4|*UM ICl ,. V MrAfe| 4 (a , , l*l>t iMpi-Ini Coil - I IfhiUivw Initfttof) . a , j. * ! IwBlftlltjl ( "*-_ *. 4/ ,__tltflWd ............... ....... ^ UUtU AewMtil F#,m ,,,, |.,, tnvtntpT) _ t<w_ 'i Ihfptr'/ >Pi* ll.r< 411,V4 t. Or.lr ,/ 2 A'/. . PRODUCT SYMBOL oismuo AROOtOft # 1206 tf~M SCH 6-M42 MON7HOF/p^O 103.5 ,,. evocn . / jjt) 4 ' Amount I ri t, 20,000 1,03? | l,0?0 .013 r .01? i,m y e-iso .006 5 ..000 7.1X55' 8,40? .340 P .312 B07f ,616 .149 . ,12? .owl; 563 s 1 .403'r ,300 ,475 : ,030 ' ,010 ,i3C>S ,07^1 .733 ,094 ,030 128 ,043 2,524 P 2, >*>0 .200). .848 .Oof ,174 .,020 n,35X ,003 \ 1,842 Mil.. . WATER PCB-SD0000045960 `rSr. pLDGS. < if EQUIP. ,.tsf. TOTAL. *. IS/.y^d'.v... PRODUCT DISTILLED AftUCLOS / 1209 ___ , Vh?P>OU_ _SCK 6-H43 MONTH or;/ - J * ............... ..... ' ' . 6 '" un",u " ` p Amount i Ptt lb. ` vr`6ii_J.<ilpMI Ei.u._ily.'_. |!_ 1 I ~ Amautrt j! C*p H| . v~ i:-- ...ffM 0u1i ..................................................) ..l-l -_-.. VJ...J ---------*I--..'..cs.--...2...........I!...I.I .....' .jrH..' :.v3 wqp_j.v,(wW I..ft..1. . , '* ' m3 ciwpe.Anm.0Mf M6P_ |i 544 wioaonaims............. ; i/llll ''.iJKO.L'L, 7V.. :.' ................. 1. f'r jj-Tx.piajWbppi :. i,TtooiIcat3..3 WO CKt KTDHATE .......... ...............?-------- -I!---......................... ...................................... .. , ";4pi ewcE.ARptLCij 0 I * l f .. . " ! . . ,, .,'joOtuc . 40> ArrOCLOft 0 <U9 1413 AROCIPR 0 noy. . -- : >y ; . ti. _. . -/jyt*r-y\; * s.eoc- ,010 U.7/5 544 AHOClpH jllME . ^(LlUS-iK-eBAIE---- L- iit-.--"_____- i'-T ' "oso 030 t-jlfifc* MlfWk gTTV - V,:. . p.eSio e.6is |3` . . /!i.( ../// _ . .420 .4IP .600 , { # C'L' / .......* * / < y !> - .&i .210 .267 . 277 m.Uhv ,. . ftUtcrlit 4*1 1 \ r,(C`flN to r.Ht Cloth.. ! . 1............ - 7 , .. / o?6' i ..045 .040 'ww . f>rr Il,W > 17 Btoftlnfl I 1* . V. : ">f.i ]l;>:>-.//./ -'.7-/.:/.A/.. .it/ofi._______ --.;./..wv..Api. ..!.................. / j, " ( , |, y.* _....... y. ... . ~ .OiW (.0U2a4 ;;.'o.oporr>. fr ,.nlio ,050 ..024 rf OOC: , 110 tllHlVj " * * * ~ ~ rR * .* .* . i1 H4 f.-./jJ'l.' ____ / rt I -' , _i_j_______ ;y ' ',:7 i f`: "______ t_^..y.. .*0'02255... ..026 "irrcr" -r,7?r (f-tuM'iaAt . , , ... ... '26'D Inect Welfare ' H.wsnff il '........... .. ' .<?} 7 c:m\.:::: ,Il!.7 s ji .210 .073 .243 ,C</4 C<r- I'PihMIw .' ] />-u..i*>a2c>!L___J^~c____!--_____ ;___________ j______ ,625 ,<c:i ' ,i CPAVfltipft* ` ' Coil U"lh f J . I nX. .. " : SsM>3 .c>oi ___ :______ : ' hy.it ^/T7 .'J i,I /c'-.J-<>-V1{J >-.;I<v* . ;7i;H .... . > * 'I fii?1.2w,5>033 "."1.4.4c6v7 ir.rv^xt: r. ',_____ i fmm. AHD SlIlPPIKC ctir,, hr ** . ' found! -u1H15 W.D..KTH A`i-m.our.nt .. * -- } fet It. j1 .. YCAR10HAU ' < ' f mmdf * 1.' Amount Mllfll I___ _ .. - -,r. j..,. ; . ;v . ; " \K(|t> C*nc , i ________ ____ .111.. 1.1. r.izisi.j...-vn r'. .11 i U \v* t - J.Id ^Corbopi 11 "jj-y " ' /y __- I'li*/ .//, _ !/ - hi tlfcOf__ _ _ *f*_!"**'I.. n. uki i.. .fi,. ..jh__ 'i^u: j. .......... i^UfcOf Storing ^ > . fl**' Clirtgf 1 Bldg! Uu Ib ftenAfVlny -J-------- -------- ...I JI Util BMApthf Cm^ % . t u ,. . ...l77Tr~>, ,,; r~fl * ifp7 Hu\lnH tn*fntory ................ .......... n."T. - .... ' . . . ,, Pjr'Kf* . . ,. Aptnini Invfnloty taniteirtf ' ' *'J! LI.. . - {,................. 81 ____ ,. <iii- .... if,S >.* M..S..U.L j; .'y,. ' ......77- |~-cr-/" vl^':- ,(r:,/4'.'Vj-<r;: ^ 7 :, xj:-.-1 ^ ___ -------------rs__rr.r-.yy'J r / .Utirto AcwuMfor^ _______ _____ ___jj. . ___Ctoilwi hvfnlerv ____ -------- ---------- 3----- Lry/ ./>X.----- __________________________. ... fopAird #1 _ , ..... . "in** J ? yj/_____.'. 1__1_ -* v. -/. ?. !{; i . u' v.o'/' '/'/ f. .. . * " . r \y v / '> / / / iI _*_ a. , vi/:- ,v. .... /_ jj. ~X7?Y '/ /' tilt / n/ / . <?/" { vyV. OSH 001441 r:; iy.-vri.z.^ 0.1 i: ^ .......A ~i : /, . . f. - f if + J .. . ", t ` . .**.*.- *: ......... i -\yr> ^ --1..................I \ i`................................< ADA 000794 1 11'> f 4 i WATER PCB-SD0000045961 jyyT. PUDOS. t hi #*l KQUtp.g ' PROOUCT DI$TIUED AROCLOH f 4465 r_ ' -i_: `.spr.v.jsfisy-mAb--orl^-SCsH 6-I45.0 fjr-.month of - -- ................ - H20 .CWOB AROCLWl / 4065 ^ ,7' tiwet'Anihoh. $4$0 ".. i" Hit .Ammw u_.. ,, /hOCV #.4C>$3... . ,1* . 544 jV*OC|.?> lVS.................. jM_Uk (lf~ ** WrtrflM ;" B.inipi 'ffi ' )i>>* [(I Tt" lU.fU' lm *. . 10S 5 fKN0M)B MlfflM COST ll_ Hrrtli "........ .111 llkif ............................ _ _ .11 K(|l- t*M __ , . ft|" tikH ' . . ............ II tigl Cirtoni __#l_ _Cirtjr lit UI>M . " f*I <* M.fcwr "__ II link *i|________ _____ i T*fcr,}g W_ UW Wtlt. _ It. ttM.llettjt Equt>. 7uKih Ji_ly I* ii y {jIFt p_.U'vlirf*-.ieMk Jtfl . __ It UUi-CirUMi' .ll 'lik*'-let! It WHfhlkJ ` Ul'.tg.<.>!&/- j *ltW SMffrinji Cl Mlftlmuft Uvfntetf. IrtMftrtttf (*__ |------ trtfoai 1UH* AppoviM l. -e!s5l*JV*1SL,1!I_1I tHigml t . J'wn rj Hh-.u* . `; 1|~ . Wiei'^.y ".' "`Mil Krf77T5i7::jOT3 Hi ' i.cjGta fC 1/o.ii't/. _____ |___ Lyjat___ . b'y, Co 7 ..(Lfg lo 7c 7 _____ 1___ LLCL3A.. .... I . A-ft*. zs7 $ 00 --Ai-ftf S?jUi-j yfp -- : x ok hr)"] OSW 001442 'J-:.i j. ADA 000785 KCl/P7i7 WATER PCB-SD0000045962 ,.EfT 81 t.val , ft'Uf i `*i* , * fir. i $ EQUIP. $ _ 1HIS W0K1II , Arfiftfrtt Ff (fc PRODUCT SVMHOt Dl$TiLlD AR^CLUft ft hA*2 SCH * ^52 MC'VTH OF /jne 5 YUMODUl -t>|U0Gtt4..................*i kt>'u\l FrU, AmnjM Pr`ii ftiM* ^ 4a?* i:*vor AncctcR * Jl<: 2C ,, ArteC Oft / 5vM2 I 4 1 CMOS, ' >. cV *A 42J if ' .. m e *c:* SA 2 n Utbt. * aHii'F^r *:o4i , w *' - _ ... . , ^ k^v r*** , _ _ .. . uv* _____ _____ _ _ _____ t h; Nr.>n_ >4 .ilHl_ . . . , *4 .U--___ .. ... t|*CM;#<T fti$ _ __ . .. _ __ __, 4 U't-f _ . _____ ______ U v^ij, *j T * Jiyy. Mm P* k.rif tn1 4 . . , .... ## . . ,, ft " ^ * ........... * U * 1** Cars _ __ _ ' ____ ` tfci ....................................... uu* ttr ` "' ji.. .^ .* i. t.fc.At l ___ ____ i< V t.*- -ft n pImnhrffC^orjfl J __ _* m1'U*L'Pl llA.n <*l \* ' "** > ...................... 1t*r v.0fc*N PoMl ` Anu'WM f<* it. tunm utu .1.. *. OSH 001443 // > ADA 000796 WATER PCB-SD0000045963 WATER PCB-SD0000045964 WATER PCB-SD0000045965 DSW 001446 ADA 000799 WATER PCB-SD0000045966 '*9 mmMJ. ttsouiovi mktsods, symncmoa imp twtruon . U iariLrUsoX Jtottata A, Plant Method# for Controlling Production of Crude Aroolors l> Bpootfio Gravity t, Acidity 6, Softening Point of Solid Aroolors 4. Bold Point for Aroolor* #U86 end SiSS B. Methods of Analysis for Aroolors as Heed by Control laboratory ' 1* Sotos , Acidity of Distilled Aroolors S Speolflo Qrsvitgf Of liquid Aroolors 4, Tendenoy of Aroolor #665 to Cause Blocking in Aroolor - Stearins Pitch Mixture t( Bold points for Aroolors #1181 end Hot 6, Sold Munber of Crude Aroelore 7, Crystallisation lest on Moo-Crystalline Aroelore . < Distillation Bang# of liquid Aroolor* I. total Chlorine in Aroolors 10, , Pres Chlorides in liquid Aroolors U* Pour point of Aroolors It, loss m Beating of Aroelore IS, Color of Aroolor #6460 14, Coefficient of expansion of Aroolors 15, Deleneinatton of Pressing Points 16* Detemlnotion of Bmeol Insoluble In Solid Aroolors 17, Vaporisation loss et 660 16, Diphenyl in Crude Diphenyl or Diphenyl Still Battens It* Dieleotrlo Constant of Aroolors 0, Itadr Peotor of Aroelore 1, Resistivity of Aroolors 1, Aroolor #1*54; Q,B, Compound Io 1476 Chlorinated Diphenyl, Crude, Aroolor 1116 I, Chlorinated Diphenyl; Crude; Aroolor #U4f 4, Chlorinated Diphenyl, Crude, Aroolor #1141 6, Chlorinated Diphenyl; Crude; Aroolor #1160 t* Ohlorinated Diphenyl; Crude; Aroolor #1164 ? Chlorinated Diphenyl; Crude; Aroolor #1180 6, Chlorinated Diphenyl; Canid#; Aroolor Hill I, Chlorinated Diphenyl* Crude, Aroolor #1166 neLi 001447 ADA 000800 WATER PCB-SD0000045967 /c& U> UmteLteaHAsgitMi. jcoatinded) ...... Id, Chlorinated Biphenyl, Grade, Aroolor #1186 U, Chlorinated Biphenyl' BB Viz, Crude, Aroolor #6668 It* Chiorlneted Diphy|.| B,B |U( Crude, Aroolor #4066 18* Qhlorlneted Blgb Bailer, Crude; Aroolor #6060 1.4* Chlorinated Biphenyl, BietlUed, Aroolor 0%tit IB, Chlorinated Biphenyl; UtlUiit Aroolor #1X46 16, Chlorinated Biphenyl; BietlUed, Aroolor #1X46 17, Chlorinated Biphenyl; BietlUed, Aroolor #1X61 16, Chlorinated Biphenyl, BietlUed, Aroolor #1660 16, Chlorinated Diphenyl, BletiUed, Aroolor #16E #1X66tO, Chlorinetod Biphenyl, BietlUed, Aroolor #1X64 tl. Chlorinated Biphenyl, Bletilled, Aroolor t, Chlorinated Biphenyl, BietlUed, Aroolor #1X66 (Veter Queoohed) g&. Chlorinated Biphenyl, BietlUed, Aroolor #1616 ~"*4, Chlorinated Biphenyl, Bietilied, Aroolor #1646 (Ooaatook A Veeeott) til Ohlorlaeted Biphenyl' B,X, Mig,' Aroolor #4466 X6, Chlorinated High Boiler, Aroolor #6460, BietlUed ' 67, Aroolor Moisture Proofing Coapound fax #801 UU laboratory feet tqoipnent, Shoving the Pieces Available for transfer to Bt, bouts i *w 001446 WATER PCB-SD0000045968 '6/ aioftoi ft I. mmnm iBTaops A* Fr4oU mi * OMltr+Uln* BM^sss&iks&sm. lignotm pmmm wises. turn g iw-............. _ osw 001449 ADA 000802 WATER PCB-SD0000045969 - PLANT METHODS FOR CONTROLLING THE PHODUOTION-OF 0RUD8_________ AROOLOR3______________________ epEQirio orarm The temperatures et which the gravities of liquid Aroolora ara taken very with the vleooeity of the liquid* A motel cylinder of sultahlo sine Is provided for oetohlng the senple from the ehlorlnetor, The eample, after being oeught, le oooled under the tap to within about 10*0 of the temperature et whloh the gravity t to be taken* The hydrometer le then immersed In the liquid to e depth Just sufficient to oovsr the bulb end Is held in this position with the left herd while the liquid is stirrsd vigorously with the thernomater in the right band* This stirring la oontinuel until the temperature of the liquid is one degree shove the desired gravity temperature* At this point the thermometer le qulokly removed and the hydrometer allowed to sink gently es far as it will into the eenter of the cylinder of liquid* The hydrometer le reed end this reeding recorded es the gravity of the Aroolor, .... The gravities of AroolorsJllO, 1148, 1148, 1160, end 1154. ere taken at B*C, The grevltlee of Aroolore 1160 end 1168 ere taken et 00*0. The following teblo shows the limits within which eaoh Aroolor should be finished. mo - 1,118 - 1.117 1148 - 1.845 - 1.880 1150 - 1,483-1.488 1184 - 1.803- 1.507 . mo - 1.863 - 1*667 lies - No hydrometer (Must be finished by Weetphel) mm Be sure the enmpls la stirred well but carefully in order to avoid breakage. The hydrometer should be rend quickly ee poaaible, since tbe tanpereturc drops would give e wrong reeding. , DSW 001450 era ADA 000803 WATER PCB-SD0000045970 msm. Approximately 85 eo of the liquid nroolor (or BO greme f e Mild iroolor) le poured into a 60 eo beaker, To this 100 eo of elooholtiBtel slxtur (furniahed by the laboratory) 1* added. The mixture 1 litre ted With H/10 eeuatlo eolution (also obtained from tbe laboratory), tofore the titration la atarted a little water la added from the tap. VkB tba end point la ranched the water layer will be colored pink. Tbe Hoeing operation ie oonplete when leee than B oo of the eeuatlo olutioa art required to reaoh the end point. ere OSM 001451 ADA 000804 WATER PCB-SD0000045971 wnmw POINT orj^miROMs Ball end Ring Method Preparation of the Sample Tha semple aboil ba melted and all trod thoroughly, evoiding OYsrheatlng or inoorporating air bubbles In tha wees and than poured into tha ring bo aa to leave a alight treeas on ooollng* Rinos the Aroolore brink considerably on ooollng, tha ring should be veil filled, nearly to overflowing, A little of tbe snoeae abould be drawn over the top of the ring at severel points ao e to prevent the ooolad Aroolor from drop ping out of the ring. In the seme wey, the aeoond ring la filled with e tanderd Aroolor of known softening point. The atendord Arocior should have a softening within et least 10 to 16* of the Aroolor being tested, The rings while being 'filled should raat on a oleen een lid or on e brass piste vbieb hns been amalgamated to prevent the aroolor from adhering to it. The Aroolor in the rings should be fully eooled and hardened before prooedlng with the test, . "Add wetar (not ebote roots temperature) to the beaker until the wurfeoe of the water la ew above the plate holding the ring*'whan the ' ring support la suspended In the beaker. Piece the rings oontdining the Aroolor to be tested and the standard Aroolor on tbo ring support, Fleoe a ball on the center of the upper surface of the Aroolor in each ring, Buepend tbe thermometer ao that the bottom of the bulb la level with tbe bottom of the rings and Just midway between the two rings. Pleas beaker end epperetue on e 6 inch roubd hot piste end heat. The temperature recorded by the thermometer st the inetent the Aroolor iouohee the bottom piste la reported as the softening point, Tbe heating la oontlnuod until both Aroolora beta dropped to tbe bottom plate, Ssisx 1, The standard Aroolor le run along with the sample under test la order to oompensete for variations in rate of beating, dilution of glyoerln, and thermometer variations, t, Bensol la need for oleanlng the rings and bells. 00 9. Vster can be used Usteod of glyoerln for softening points ap to 00*0, 4, for softening points above 100*0, well boiled glyoerln should be used, The usual glyoerln Is not aatlafuotory aa at 186 to 150*0, It boils with loss of water while the temperature remains practically constant. It Is well to hove a supply of high-boiling glyoerln on hand to be used Cnly for oftoning points above 100*0, 9, Air bubbles on the rings end balls during the test should be voided as far as possible. ADA 000605 WATER PCB-SD0000045972 rtf Psy>rlpH&*s* Arp*2*\u* The receptacle for the Aroclor le s 4-x/s x 1" (lug tub whiob til |git sealed t on* end, This tube 1* Jacketed by * pleoe of asbestos |gpg]> trapped twite around the tube end is inserted la a square sight MM bottle whieh is Insulated on the bottom by i lsjsr of 1 inob ssbsstfi fibre Tfae tub* is bold In pleoe by * large eork, All of this insulitios Is used In an effort to keep the Arooior from ooollng too rapidly Ml It is best to get additional insulation by wreppiag the eight ounoe battle in towel after the sample is added, ffrooodure Kelt about 100 ge. of the sample la e beaker on the hot piste ni pour it into the tube until it is filled within 1-l/e"- of the top, fb netertel will probably crystallise due to the oold tube end will bare t be heeted over gas burner to melt it Sgein, When it If melted insert 1 suitable thermometer (500-300*0) which is fitted with a oork to hold it it pleoe. The bulb of the thermometer should be fitted in the eentef if the sample, ears being taken that it is not too eloee to the side of the tube* If the determination Is made on 1189 or 1889 the tube should be bested until the thermometer reeds ebout 800*0 and It if placed In the sibtltos Jaokft end then put in the bottle, Beading# on the thermometer ere taken et 80 eeoond intervale. At first the temperature will drop . rspidly (about d between readings) but around 850* the drop will decrease end usually s point will he reaohed where the drop will stop, end will either stay constant for two or more readings or will start to go beek up, Iht correct hold point Is the point at which the temperature remains con stant or in oas# the temperature starts to go bank up the highest point is this rise Is token, for example! 548/ 845, 840 , 880, 889 , 848. 839, 897, 848*0 would be the oorreot hold point. In the ease of 1180 or 1880 the procedure is the same exoept tbit the tube is heated to only 800*0 instead of 500*0 after the thermo miter is inserted, eri OSW 001453 ADA 000806 WATER PCB-SD0000045973 MWIM I i MamMm, mmom * theft* of Anatytlo fet Amlet* u Dili \j Oontrftl tetofttoi? mtM eHnaeo. mut&m UBfsofim mnrxgtPf mm m iw _ osw 0014S4 ADA 000807 WATER PCB-SD0000045974 Asr WTKS QH AROQLOR TKBTXm A number of A.S.f.M. Methods ere used ia beating Aroolors, uofc titi Fire Point Plash Point Tleoositr-Seybolt Softening Point S-fB IKS "S6 Tbe A.B.T.V, directions ere erectly followed for such teste. i i Color. Lotlboad, for oolor of liquid Aroolora, tbe Lorlboad flitoneter with 1" ooll le used, Standard olle of the Kstlonel Petrol ' fji Atacoiation {K.P.A, standards) ere reported to be no longer swell*-" ' it]#. The following oontersion table 1b need! K.P.A, Oolor numbers ` 1/4 */* s/ l l-l/B. e Lorlbond Analysis Yellow 510 - .6 Bed 100 1.1 l.f e.4 .16 6.0 .50 (d.o 1,80 Pielcotric Strength} AS3M D 11?, Ko equipment hen been iUllefi et Anniston for making this teat. _____ feau. on Bsetlna* 6 houre *t 100*0. Thia teat le elnller to l*S.T>v, Teat &-fl eroept tbat owen le wmlntelneO et 100*0 end tloe of ttetlng it ertendad to 6 hours. Tbla teat la uee| on 0,1, materiel hr* eo apeolfied, A 40 gm. sample la used In tbe place of 50 gas. art OSU 001455 ADA 000808 WATER PCB-SD0000045975 /4A DIRECTIONS FOR TEST NO.___ SUBJECT i Agiftity of pistlllad Aroolore METHOD:______ WaOH Titration______________ _______ (60 4,1) frtmot the Aroelor earn weighed Into a S50 as beekar enS 100 eo of 0,F. bantatte added. Wtr solution bee bees effected the sample i titrated with 01 8 aloohollo BeOH solution, using 1 o (about 10 drop*) at if pheaolpbtbeletn solution >t a Indicator. .. The and point la ranched wbes the solution la visibly pink throughout. Rapid stirring should be used While tbs NsOH solution is being added. The results are reported is mg> of NaOH per gras of sesple. It la unusual for a dlatllled Aroolor of the 1800 series to require more then .6 oe titration, which is squlvelast to .004 add Bo. The eloohollo HaOH aolutlon la prapored hjr tasking up 8 so of J^B equeoue oeustlo solution to 860 oc volume with eloohol (Formula A) are DSW 001456 ADA 000809 WATER PCB-SD0000045976 /&9 ' ' DIRECTIONS FOR TEST NO.__ lfr-IO-SE SUBJECT I Specific Brevity of Liquid fepoStora METHOD; Stlmti Specific gravity 1* determined by means of the Westpbal balance. The temperatures at whioh the specific gravities of liquid Axoolor# are taken very with the vieooslty of tbe liquid. Tbe specifications for each Aroolor should State tbe temperature for both the drooler and the water to which comparison of grevity is made, In plant practise, speciflo gravities of droolers containing up to B4jl chlorine arc node et 65/ft5*C while specific gravities of droclors containing ehlorin# ere made et to/P0*0, Speclfle gravities of any of the droolors may be unde at m/e6*C hy uae of tbe 1)S(T.U< method for road tore, eaphalt oemcnta, soft tars pltobes, sariel designation D70-57, 19B7 (Aeaerlbad in Bureau of Standards' Miscellaneous Publication No. 110, Standards and Specifications for Ncnactallle Minerals end their produets, page IBS.) BppagstM. Weatphal Balance: Similar to Elmer and Amend Catalog No. 16950. Plwnmet need mot have thermometer seals to 0*0 but should not he sub ject to injury bf use et thle temperature. Cylinder: Pyres glee* hydrometer Jar 1.5" x Thermometert Use thermometer whioh has bean checked for eooureoy of soele in the range used. Procedure Pleoe the Westpbal in sueb position that the plummet is 7 -- 9 inches above tbe work bench. By means of tbe leveling sores, adjust the Westph&l balance to show sero reading with a clean dry plummet in air. Suspend the plummet during adjustment in a empty cylinder to protect the epperetua from air currents. Beet the drooler to be tested to a temperature about 15* higher then the temperature et which determination is to be made, for example, if specific gravity is wanted at 65*0, the drodor Should be bested to about 80*0. Than pour the bested Aronlor into e elean Pyres cylinder whioh bee been warmed by writing at edge of hot plate. The cylinder should be filled with the droolor to within about 1 inch of the top. * OSH 001657 ADA 000810 I WATER PCB-SD0000045977 /7# fm .* DIRECTIONS FOR TEST NO. 14-10-88 SUBJECT _____________________________________________ __________________ METHOD J___________ Allow the Aroolor la the cylinder to air (tool until the tempera ture is about t degrees above that desired* then plaoe the cylinder la * hot water bath w&leb it it > temperature about 5 degrees above the daalred tamperatur#, i liter beaker containing sufflatent water to be equal to or above the level of the Aroolor In the oylindar is a setlefactory water bath. In ease the Speclflo Gravity In to be taken at 80/60*, n glycerin both should be substituted for the water bath to avoid tbo water vapor with Its condensation on tbe Westphal balano* 1 which la present If water la uaad at high temperatures auob as 85*0. Without disturbing tba adjustment of the Westphal which Is set . to read sero with plummet In air, plaoe the cylinder containing the Aroolor In sueh position that the plummet is Immersed in Aroolor and add weights to the beam of the Westphal until the beam Is again level. The plummet should bow be oomplctely immersed as well as about l/E" of the suspension wire ond the plwaraet should not touoh the eyllndar at any point. Stir the Aroolor with a thermometer at frequent intervals until the desired temperature Just is reached. It this point the weights are quickly adjusted until equilibria is obtained and the reading.noted. Saving obtained tbe reading for Aroolor et the desired tempera ture, the specific gravity la obtained by dividing this figure hy the reeding when the plusmet is Immersed In yure water St tba same tempera ture. Tbe reeding for weter la obtained in tbo some manner ea for Iro~ elor. Since tbe reading for water is constant, provided there ere no errors tn weights or Westphal, this figure need not be determined with each Aroolor test. Tbe figure for wetor wbloh is used eg e constant should, howeyer, be obeoked ones a month or whenever greatest eoouraoy is needed. The readings for water et 06*0 and 80*0 are respectively ! .881# end .8678. OaloUla tlon of Result Eswapie 1. Assume readings as followsi Westphal reading with plummet In lv Westphal reeding with plismset in Aroolor at 65*0 Westphal reeding with plummet In water at 65*0 Then sp. gr, St 65/68*0 e l,80fe8 1.8888 ,6888 Zero 1.6085 ,6883 Example g. Assume readings e follows) Westphal reeding with plummet In air Westphal reeding with plumoet in Aroolor at 80*0 Westphal reading with plummet la water et 60*0 Then ip. gr, at 80/80*0 * 1,6485 * 1,6668 6678 OSW Zero 1.6435 .8678 001458 ADA 000811 WATER PCB-SD0000045978 /?/ fat DIRECTIONS FOR TEST NO.__ lfrMHW SUBJECT :___________________________________________ ' * METHODi __________________ ^________________________l isiis, 1. Tfa# weights need with the Weetpbnl balene should be checked periodically k; weighing each on an analytical belenee. . g. The edjuetment of the liquid to the exeat temperature desired te moot important. Do not allow to eool rcpldly.and stir frequently enough to Maintain a uniform temperature from top *0. bottom. la the cylinder. ' . 1 re DSW 001459 ADA 000812 WATER PCB-SD0000045979 I m , DIRECTIONS FOR TEST NO. Tendency of Aroolor 8555 to o*uh Blooming la SUBJECT IX*Art1 Pi.tali JUlTt'ira---------... -------- --_ METHOD o_______ ..A yAit>>iitia--.--.-- feigb oat 10 grams of Aroolor 8565 end 15 greats of stearin# pitch. Molt the Aroolor lo o Beaker end odd the steering pitch in two or three portions, stirring ell the time end gradually raising the temperature.over e period of fire to 10 minutes to 1S0*C to 800*0. Btlrring Is.continued et this temperature until e uniform mixture hee been obtained. Thin may require 10 ndnutee or more. The pitch ie added to the melted aroolor so as to avoid exoesalve oxidation of the piteh, When the mixture Is uniform end reasonably free from foam it is et once poured into a small salve tin (the tin 8" in diameter is e convenient else). The salve tin le covered end the mixture allowed to oool. ! .. When oooled to room temperature the tin ie opened end the surface 1 of the Arodlor-stonrine pitch mixture is "seeded" with crystals. The seeding operation consists simply in rubbing the finger lightly over a sample of Robertson roofing which hes bloomed badly or over e previous test sample of an Aroolor-steerlne pitch mixture that is covered with bloom eo as to pick up a trace of the bloom on the finger-tip and then finger printing the new Aroclor-stearine pitch mixture with the same finger. Oere must be taken not to pick up too wuoh of the white bloom end transfer It to the new test mixture as the "seed" may then ba ml#7 taken for bloom. The salve tin eontaiping the seeded eemple le covered and Is then plaotd in e warm speoe at about 40*0. At the end of three days the sample is Inspected end if very dlstlnot bloom bee not developed the surface le rubbed over with the finger tip eo to spread the seed crystals that ere already present over the entire surfeos. The sample Is then rs-sesded in two spots as before by finger printing with a finger that bee been lightly rubbed over a surface ooversd with the bloom. The sample is inspected twioe weekly for the appearance of bloom. The bloom appears first as a slight dulling of the surface, then ee s whitish powder on the surface end finally under the micro- soopc sc white transparent needle-like crystals. In the case of an Aroolor with e strong tendency to bloom the white costing develops within two weeks. In the eases Where bloom does not appear by the end of two weeks the tests should he continued to at least four weeks before e negative re mult Is reported, five weeks is safer. ' ,,rt QSW 001460 r ADA 000813 WATER PCB-SD0000045980 ` *73 j 8* DIRECTIONS FOR TEST NO.; ! SUBJECT? Tendency of Aroolor #568 to.Pause Blooming ete, : METHOD I ______________________________________________________ I I !. Kotos i The preparation of s homogeneous mixture of Aroolor end otearlne j fiteh free from excessive foe* when the Mixture ie ready to pour into j tbs solre tin apparently require* some experlenoe* I The otearlne plteb la *o*ft pitch" obtained fro* Ur. p, V, I Jenkins of Mellon Institute, Pittsburgh, Penneylrenls, for use In the | test for blooming* . ere < | i 1 DSW 0014-61 ADA 000814 WATER PCB-SD0000045981 /*< ' DIRECTIONS FOR TEST NO. SUBJECT; Bali Feints for Aroolors I4.ee & Ugp METHOD,!____________ :__________________ ____________ , Description of Apparatus The raoaptoola for the Arcolor 1* * 4 l/t x 1** glass tub* which ki bean sealed it one nt. this tube le Jacketed by pleoe of ssbestoa paper wrapped trie* around the tube end le inserted tu s square eight~ox, bottle whloh Is Insulated os the bottom bp leper of X* asbestos fibre. The tube is held In pleoe by * large oork. All of this Insulation is used in an effort to keep the Aroolor fro cooling too rapidly end it is best to get additional insulation by wrapping the eight-ox. bottle in towel after the sample is added. procedure Molt shout 100 gat. of the sample In beaker on the hot plate and pour it into the tube until it is filled within X l/S" of the top. The swterieX will probably crystellite due to the sold tube end will here to be heated error s gee burner to salt It again, when It le melted Insert s suitable thermometer (800-S60<0) which is fitted with a eorfc to hold it in place. The bulb of the thermometer should be' fitted in the eonter of the sample, ears being taken that It is sot too elose to the side of tube. If the determination le made on 1180 or 1S60 the tube should be heated until the thermometer reads about 300*C and it la pleosd In the asbestos Jeeket and then put in the bottle. Readings on the thermometer are token nt go nee. Intervals. At first the temperature will drop rapidly (about d* between readings) but around 880* this drop will de area so and usually a point will be reached where the drop will stop, end will either stay oonatant for two or mors readings or will start to go book up. The eorreet hold point le the point at whleh the temperature remains oonatant or la aese the temperature starts to go hook up the highest point la this rise ia token. For example! 846, 848, 840, 886, 8se, 830, j>48. 830, 337. *4**0 would he the correct hold point. In the cese of 1X68 or 1X88 the procedure is the earn exeept that the tube is heated to only 800*0 instead of 800*0 after the thermometer le inserted. Xm all readings a atom correction la made (unless partial immer sion thermometer la used) by use of the following formula} OSW Stem correction iil (T-t) 001462 X Factor for expansion of mercury In glass ,000138 X length, expressed in degrees, of the mercury eolws emergent from the bath. T Observed thermometer reading. I e Mean temperature of the emergent stem which is found by plaolsg s second thermometer st the middle of the exposed thread of mer- . eury. J1 ADA 0008IS WATER PCB-SD0000045982 I (JI WATER PCB-SD0000045983 /Y6 DIRECTIONS FOR TEST NO. 1*^14-08 SUBJECT! Aejd fflumtyve of Oru&e MrooXmre_____ METHOD: 1,08 *ltrtlon ___________ Frooedure Dissolve BO frame of Arcelor la 80 eo 0P. hansel. oontaiaed in 6 850 eo beaker, AM SO eo of 95JZ ethyl eloohol end titrate with 6,1': ReOH solution using 10 drops of lj( pbsnolphthalel* solution ee indicator. Before starting the titration, a little distilled water la added; this causes sharper and quicker eeperetion of the aqueous layer from the oon-equaous layers Oeloulate the eoldlty lh allllgreras of Rat re quired per gram of eeaple. On account of the strong ReOH solution used for titration, the blank titration of the reagenta may ha emitted, Ugo RaOR per gras sample titration in eo * 80 vt. of staple example: If the titration of 60 grama of sample ia 1,8 eo, the aold number la found aa follows: 1.8 z SO divided by 50 ,48 Mgm ReOB per gram of Aroolor. ora OSH 00X464 ADA 000817 WATER PCB-SD0000045984 (77 ' . DIRECTIONS FOR TEST NO. SUBJECT; Orytailtwetioa Taat oa Won Crystalline Aroolore METHOD; Solution la T M A g grade naphtha_______________ The tost ii beaed on the relative insolubility of eryetalltne droolers In naphtha. . Weigh 90 gratae of powdered Aroolor (preferably finely powdered) Into a wide south 6 ounoe bottle. Add 40 create of naphtha end stopper tightly. Shake until solution la ooapleta hut do not warm to heeten . solution. Set aside for 9 deye. If so crystallisation tehee piece within this period the materiel Is eoneldered satisfactory. Raecents WJftg, . -Tarsieh makers end Paintere grade. Initial boiling point 1P&-1S7 and ond point 9BD-995*f. Obtainable from-Worfoyfl Oil Company, Blralnghajo, at 19/ par gallon. or* OSH 001465 ADA 000818 WATER PCB-SD0000045985 tra DIRECTIONS EOR TEST NO.___14-31-g8 SUBJECT! W*tU*etln Range *f Liquid Aroolore METHOD; , A.B.T.M, PBQ-80 With UoliflteUoti The apparatus, consisting of flask, condenser tube, shield, end thermometer, la eisotly the seme os described under LS.T.H, test PBO30 "Distillation of Bituminous Materials suitable for Road Treatment*'. The method is changed to the extent that thermwnater readings ere taken ebon specified percentages (usually 10, 60, 90$ of Aroolor here been distilled Instead of following the A.s.T.U, procedure of weighing the distillate between specified thermometer readings. In testing Aroolors 1864, 1848, 1848, -eto., 100 ee of nanple are taken for test end the distillate is received in t 100 oo graduated oyllndar. In . tasting Aroolor 1860, 100 gas. of sample Is weighed Into the distilling flask end distillate received In n tsred flask or beaker resting on pan of s torsion balance with 100 gra socle. ' . Procedure Transfer 100 oo of sample (weigh 100 grama in tha ease of Aroolor I860) into the distilling flask. Assemble epparatus as deeerlbed under A.S.T.H, 080-50. Insert thermometer (A.8.T.U. high distil ling 0-400*0) through cork in the nook of the flask so that the top of tho bulb Is level with the lowest point of Juncture of tha fcubuloture and ns ok of the flask. Apply heat to the fleak supported on two sheets of 80 mash wire geuxe so that the first drop oones over in from f to 15 minutes. Conduct distillation st rata of 50 to TO drops par minute. Oolleot distillate In 100 oo graduated cylinder (or tarsd flask In case of Aroolor I860). When 10J> has been collected as distillate, note end record the thermometer reeding. Repeat when 50 and hoe been collected. Itor record purposea the temperoture whan first drop fells end when eooh aueeeasiva lO^S has been ooliected (up to 90J*) should usually be recorded even where spoclfleatlons require only the 10, 60, asd 60 readings. No corrections for emergent stem or pressure ere applied to the thermometer rood!age. ere DSW 001466 ADA 000819 WATER PCB-SD0000045986 DIRECTIONS FOR TEST NO. SUBJECT i fatal (Marine 1 Aroelfb METHOD i imim 1 Atf&e titration _____ _ Anti* Naicnwo. i, g i.o.. W ti9ih___________________ _____________ Chlorine in Aroolora may h i*tndHt t; fuela* of the m;lt with oodles psroxi# is a iurg^ss-Farr fusle* ewp* estreating the fusion with water, HUU7I11 the wUr ertreet with mitrle'aeld, ttd'yrilpl> ieting the chlorine by addition of exaeee of adlver nitrate* After filtration, tba uitii of silver at trot* la determined by titretlen against poteeelua thiocyanate, using farrlo mm&lwm sulfate at indicator, . Apparatus The, fusion cup used is the Burgoew-Parr Sulfur Bonk No. g for flnne ig~ titles* A lead gasket lo ueod. For ignition, tka M la suspended through o l-s/ld* round hole is a l/** transits flats. Thle allova the fusion eup to extend through the fiats for about s/6B Ignition ia ffsotsd hr strongly heating the bottam of the fuels* amp with the full flame of e Maher bursar for two mlam tea, phages. for Fusion The fusion mixture la me&e up of about li grams (mm Mtsl mtstmg) of U peroxide ait 0*0 U 0*9 grama of finely powdered sene eager, the amount of ease sugar depending upon tha height ef aarboa oontelned la the sample* Tha reagents ahould ha free from shlorlae, or a blank run a&d aerreetad sooerdi&fiy* h feale mixture &e veil mixed by piecing tbs lngradlaata la a well hottla with rubber stopper end shaking vlgoroualr* gtjfrin MQOlXftSt She non crystalline type ere weighed in the fora of well pelieteT Thaos ere prepared hr haetlsg the Aroaler auUl soeh e eeaaiatamor lo reached as will permit drafflng It from a glees stirring rod onto a tinned aurfnee (a earn top), oaeh drop forming a pallet, 8hen aool these pellets eon he removed from the surface by Inserting a apetule mn&or them* 4 grmm ate used* The pellets are brushed into tha bottom of the refit tup end the fusion mixture pleeed am top of then. After (tightening the lid, the eherge is reedr for fueiom. The eryetalllhe type lo weighed In tfe powdered fern, .4 grem being used. They to charged ia the mm meaner as the non-erystelllu* type, DSU 001467 LIQUID AROOLORgt 0 to *90 tress are weighed hy dropping from e attiring rod MU a pleas of thin bemlspberUelly shaped glass, uhloh hoe been Just previously taral, and vWob rameUa on tha helenea* rt la neeeasery to hoot the jmmn> vlmms Aroelars to "Areppiug" aonaleteney. The plea# of glaaa then easily alii off the halanoa pa into the * * mfm ADA 000820 WATER PCB-SD0000045987 i (Qo I n(i *o. i DIRECTIONS FOR TEST NO.__ 14-18-84 SUBJECT j,_ METHOD l_____ The following quantities of sample, sugar, ml AgNO, sure used for the respective chlorine contents: . 01 Content l` 4#~ 6* mi - cc* aftjJ - nl Weight of Semple .16 -- ,60 areas .80-.SO .88 - .80 * .40 -.41 .40- .41 * Amount Sugar AgRO, 0,0 SO ee .16 g.[l/t sooop) 60 eo .SO g.(l sooop) 60 ee 80 g. " T6 ee .SO g. * 100 ee Procedure Pleoe the fusion sup, which oontelne the preparea sample end fusion Btxture. in the transits ignition plete end apply the full flerne of the Maker turner to the Mottos of the fusion ottp for Minutes, (<JADTI0* Do not stend too seer the fusion during ignition) Then remove the fleae end oool under the tap. When tool remove sorew eep. Thoroughly rinse the eup cover with water, eolleotlng the rlnainge in e elena 400 ee benker. ' Then place the fusion eup on its side In the Meeker end cover with a .watch glass, 60 -- T8 ec will he is the honker from rinsing the eep, end this i suffiolont to deoompoee the charge. Remove the eup end rinse well. Then decomposition is complete rlnee off'coveredess end edd pure RNOg, with stirring, until acid is present in excess to the extent of shout 10 eo. (About 60 co of sold ere required,) Add erectly 60, ?6 or 100 o of standard sliver sitrste solution from e pipette (depending upon ohlorlne present) end stir to offset coeguletion of the silver nltreto precipitate, filter with euotion through an neheetos pad on s 1.6" perforetod porcelain plete end weoh banker end filter 4 times with small portions of cold water. Allow the filter to drain completely between washings. Transfer tbs filtrate beck into the 400 oo booker end rlnee the flask twice, adding the rinsings to the beaker. Add 6 SC of ferric iron indicator to the solution end titrate with standard X0H3 solution until 6 distinct pink tint is Just obtained. Calculation of Chlorine Oontent DSW 001468 Subtract the volume of IONS required from the volume of KCKS required to titrate the amount of standard AgKOs solution used. This will give ADA 000821 WATER PCB-SD0000045988 f6f - f*ge I DIRECTIONS FOR TEST NO. 14-15-04____________ SUBJECT l________________________________________________________________ METHOD:' the volume Of KOHS equivalent to the chlorine In the enmjie, Multiply the volume mt> obtained by tba Ohlorlne value Of each to of KONfi end divide by the weight or sample takes. for emmole t If 80 oo of silver nitrate solution le equivalent to 61,4 oo Of EONS solution and tho value of 1 oo of KOKS solution It ,005770 tram dj then If It It found that 0.3 gram of ample shown e gOHS titration of 10.4 oo the percent or chlorine let (61.4 - 10.4) a .005770 x 100 64.09jS 01 .5 It oete the fusion mixture or other reagents contain ehlorlno, the amount must bo determined end deducted from tho chlorine found. Solutions Required Standard AffiO Solutlont About 0.10 Mj dleaolte 19,6 grant of Oliver nitrate In each liter of water. Protect the solution from light. Fifty eo of this solution will preolpltete by theory 0.176 gram of chlorine. Standard KCK3 solution: About 0.06 Kf dissolve 8 grema of SOUS In 1 liter of water. 1 ee about .003 gram chlorine. fcrrlo Iron Indioa tor; TJac a saturated solution of ferric ammonium alum. Pure Hltrlo Acid. TO?: Stock cold suffices provided It le eolorleee. It can he boiled is a beaker until eolorleee If neoeaeary. Standardisation of Solutlona Weigh 0,8 and 0.15 gram portions of pure dry NaOl into aepnrata 800 eo beakers. Add 650 oo of distilled water-to each and 10 eo of pure 60,C ttrie cold. When eolution is oomplete, add 50 00 of standard AgJJO* solution from pipette. Stir well and filter through an asbestos mat on perforated porcelain plate, using motion. Wash filter and trans fer the filtrate back to tho beaker in the same manner ee when working with a sample* tltrots tho flitretee with standard MRS solution, using ferris Iron indicator. OSH 001469 The value of 80 ee of AgN0 solution in torus of KOKS solution is found by subtracting the oo of K0R3 solution In titrating the O.S gram of DeOI from teles the number of oo of KONS eolution used in titrating the 0.18 great of RatU. ADA 000822 WATER PCB-SD0000045989 Pegs He. 4. DIRECTIONS FOR TEST NO. 14-13-34 SUBJECT I METHOD f This value Is checked by titrating 60 90 of AgNOg solution added to 400 00 of water end 10 eo of pure 60^ HHO, with EONS solution. This titration should agr#e very olosely (el 0.1 eo) with the velue found from the titration* of NsCl. The titration must he made slowly to avoid drainage error. Binoe pure NsCl eontelne 01 hy theory, the velue of the KONi in terms or ehlorlno my ho found hy dividing the weight of ohlorlne in the NeOl teken hy the eo of ICONS equivalent to the silver nitrate required. " -. | XlffiEliU Two 0,6 gran portion* of NaOl show TONS titrations of 13.11 and 16.13 so. Two 0.16 gran portions of Nad show EONS titrations of 37.28 snd 67.64 00. The K0NS equivalent to 50 00 of AgNOg la than (57.60 37.64) -- 13.16 or 61.4 oe. By titration of 60 eo of AgN0 Against IONS solution, it la found that 61.36 eo era required. This agrees within ,04 eo of the value obtained fro the NeOl titretlena. ' The ohlorlne value of the EONS le then. *6066 * *3 divided hy 61.4 -- 15.18 or .003770 grama 01 per eo of EONS, The ohlorlne value may also be eelouleted from the titration of 0.15 gram of Nad. 0.6066 x .16 dilrldad by 61.4 -- 37.86 gives .003770 grass Cl Ter #0 Of EONS. Ms 1, The fusion materials have explosive propartlea If wrongly handled} consequently eere must he taken to use safe proportions, to secure e good mixture free of large lumps, and to properly seat tho eorer of the fusion oup. The fusion mixture must he kept sway from water or molet air, either of which may Ignite the charge, The fusion mixture should not he ground to rsduoo lumps. ` 2; The method os described is not applicable to volatile organ!e com pounds unions precautions sra teken to avoid lose of sample during weighing* OSW 001470 ADA 000823 WATER PCB-SD0000045990 /SJF Peg Ko. # DIRECTIONS FOR TEST MO, llrltbSt SUBJECT:_________________________________ _ METHOD I___________________ .____________________ $, On aooount of the high chlorine content of May of the Aroolora end the small amount of sample taken, great aeouracy is required In weighing, transfer, end nixing of the sample. The pipette end burette for measur ing the standard solutions must he very olenn to svold drainage errors. `# | 4. Fusions which show hlaok carbon depositee on the oover ana side of I the fusion cup may or nay not give the fall ehlorlne content. If e :eerbon deposit Is found, e seoond fusion should he smde using e smaller sample or reducing the amount of sugar is the charge or both, 0, Mixing the fusion oherge by shaking after the screw eap has been drawn down may leed to Incomplete fusions. The mixing of the sample with the fusion mixture should be done In such e way that the sample Is fully covered with tho mixture* d. The temperature et which the standard solutions ere standardised should be noted. In ease room temperatures very from this temperature, appropriate volume oorreotlone should he made. V, The fusion mixture materials should he essentially free of chlorine. The chlorine content mey he determined by making a blank fusion, that is, without addition of sample, and titrating in the usual way. five co of AgHOe may be added instead of SO eo. The EONS titration is then oompersd with titrations of t ee portions of ig'NOs solution in like volumes of solution end nitric cold. ere OSW 001471 WATER PCB-SD0000045991 t&4 DIRECTIONS FOR TEST NO, SUBJECT; Free Chlorides in Liquid Aroolors_______ METHOD; Opalesoeneo tf Water Extraot with AgS08 Procedure Weigh TO gram* {_ 1 gram) of sample Into b TOO eo erienmeyer flask. Add 100 00 of boiling hot water, stopper and thoroughly shake for 8 to 3 minutes, Oool, In water both* Deoant the water layer through e filter paper Into 160 00 beaker. Add 1 eo of HNO* and 3 eo of 0,1 8 AgNO* solution. At the erne tltao add like emounta of reagents to each of three ISO oo beakers containing (1) 100 ee of water, (3) 100 oc of water 0,6 ee of standard ,0888 8 NeOl solution and (8) 100 ee of water 1 ee of standard KeOl 1 solution. Mix oontenta of eaoh beaker by stirring, Four minute a after mixing, compare the turbidity of the sample against the turbidities of tbe known solutions, 4 sample showing turbidity less than produoed by the 0.5 eo HeOl solution {equivalent to .OOljC) should bs reported as ,000. Samples showing turbidities equal to or greater than the 0.6 00 Ha'Cl solution should be estimated ts closely as possible from standard 8aCl solutions at 0.6 ee Intervals, 0,5 ee NeCl solution 1.0 eo Bed solution 1.6 ee Nad solution -. ,00155 01 OOE^, 01, .003/5 Cl etc. ' Solutions Required i Standard BeCl solution, .Ogee 8, 1 ee ,001 gra 01. Dissolvo 1,640 grans purs Ary NsOl is suffielent water to measure 1 liter. Silver Nitrate solution, 0,1 f (l.Tjt). Dissolve If grama of dry silver nitrate In sufficient water to measure 1 liter, 1 ee ,01? gm. AgMC, 1 eo Is equivalent to ,0035 ga. Cl or to 5,5 ee of the standard ,088* 8 Nad solution. 0$W 001472 Notch Determination of free ehlorldes Is usually confined to Aroolor 1TO4. The method ebovo is eleborsted from ASTV liatbod Dll7-31, Testing Kleetrleal Insulating Oils, paragraph 15, Mineral Aside {chlorides and sulfates), ers ADA 000825 WATER PCB-SD0000045992 f8sr DIRECTIONS FOR 'TEST NO. lfr-gS-88 __________ SUBJECT j ?W Point of Aroclors_________ __ _____________________ METHOD}_____ A8TM D97-30 -- Clout and Paw Point ASTM Definition "The pour point of petroleum oil is the lowest temperature et which the oil will pour flow whan It is chilled without disturbance under definite prescribed conditions,** She method of test halo* follows ISSN direction* exactly except that observations ere made et intervale of **C lnsteed of #*l and results ere reported on Centigrade eoele, Apparctua i sketch of the oseemhled epparatua Is attached. For details of epperetue see ABTM DC7-50. Procedure . Pour the Arooldr into the oleen dry test jar to e height of 8 to 8 l/_4**. Insert oork carrying the test thermometer and adjust so that the thermometer is in tbs eenter of the test Jar and the beginning of the eeplllery is l/eB below the surfeoe of the Arealor.' Verm without stir-.. ring to e temperature of 4d*0 in a bath at 40*0, Cool to 80*0 in an air or water bath. ..Adjust temperature of the cooling hath so that it is 0 to 16*C below the expected pour point of the Aroelor and maintain in tble range throughout the tent* Piece disk () in bottom of jeekst end insert teat jar (with the ring gasket, f, 1 inch above tbs bottom) Into the jaoket. Disk, gasket end Inside of jaoket must he oleen end dry. Beginning et a temperature 10*0 before the expected pour point, at each test thermometer reading whloh is on even number, oerefully remove test Jer end tilt just enough to esoertain whether there is e movement of the'Aroelor In the test Jer. The complete operation of removal end replacement should not require more then 8 seconds. If the sample has not ceased to flow when its temperature has reeohed 8*0, place the test Jer direotly in e cooling bath of eultable temperature. Ae soon as the sample in the test Jar does not flow when the jer is tilted, hold the test Jer in e horlsCntal position for exeotly 6 seoonds ee measured by e stop watch. If oil shows movement, replace test Jer in oooling medium end repeat test et the next temperature 8*C lower. Continue testing in this manner until a point Is reached et which the sample shows m movement when the test Jar is held horiwmteiiy for xeotly g pcoonde. Bote the thermometer reading et this solid point. The pour point is recorded as the temperature 8*0 above the solid point. OSH 001473 ADA 000826 WATER PCB-SD0000045993 Mo. f DIRECTIONS FOR TEST NO. SUBJECTS_________________________ METHOD s,______________ ;____________ ' Koto The oooling medlume usually employed are ahown below: Materiel Aroolor ,1840 Approx. Pour Point 88*0 Cooling Medium lee end Veter lower limit for Medium 10*0 Aroolor 1804 10*0 loe, Veter and Salt (HaOl) Aroolor 1840 Aroolor 1848 -*c ~*o*c Crushed lee and salt Qeeollns end solid 00* -18*0 --55*0 Crushed lot end eeleiua ehlorlde eryatel* any be need for temperaturea down to --*8*0. ore OSH 001^74 ADA 000027 WATER PCB-SD0000045994 k- ''?:'#/. $?#:# *,<M.i-*S\:'$i?;:$.%i$4'MW jv. * *<r ;-$v ; ; S ;'.' '**&, r,S % K'irt v '- ).*', 'Vi '('('f *i.' i i- OSH 001S fc ; .. k-: if-.i* Vi ,'/!"*' X .".' > ',-i . <. ..i. , a ADA 000828 WATER PCB-SD0000045995 /as DIRECTIONS* FOR TEST NO- SUBJECT s ^mm &n feting of Arodlors___________ METHOD; g Hours et 163*6, ASUf feet M-SO SiratNOfi &Q6B ob heating of oil and asphaltic compounds ism designation Dfl-SO.____________________ ___ _________________ Apparatus Beating Ovan: Frees Eleotrlo Ovsn with resolving (6 to 6 rpm) aluminum shelf, Elmer and Amend fy>. 16408 or equivalent. TherBoastan "Asm Lobb on Beet, 165 io lf0*0M. The thermometer li located Ib front of end IotoI with the revolving shelf in euoh e manner that It ey he read through the double glass window of the oven floor. posting Dishes: S os, 0111 style, flat bottom, soaaless ointment box, deep pattern, as made by American Oen Oo, Prooeflure - Weigh on s rough belenoa about 60 grams (+. 1 gm) of the sell mixed sample Into an eoouretely taxed heating dish, let stand until dish end oontenta are at room temperature, than weigh accurately. EUoe dish la one of the reessses of the resolving shelf of the oven whieh bee been brought to 15C, then elose oven end start rotation of shelf. Maintain an oven temperature of 1S*0 (586*F) for 6 hours after , the sample has been lntroduoed and the oven has egeln raeohed that temp- aratura, Than ramose sample from wren,- eeol end reweigh. From lose In weight, aaloulete the loss due to volatilisation, ~ . , Boring the 6 hour beating period the temperature should not vary more thafl 1*0, All tests showing a greeter variation in temperature should be repeated. ' Under ordinary elroumatnnee* a number of samplee haring about the game degree of volatility mey be tested at the same time. Samples varying greetly In volatility should be tested separately. Where extreme aeeureoy is required not more then one material should he tested at one time and duplicate samples of it should be pieced simultaneously in the oven. This test is exaotly thet described under A87M Dfr-80 which should be consulted for further details of apparatus. the test Is designed to cover lose in weight exclusive of water. If water i preeeit, It should flret be resowed by suitable methods of dehydration before proceeding with the heat test. OSW 001076 I ore ' WATER PCB-SD0000045996 DIRECTIONS FOR TEST NO. 14-41-84 SUBJECT* Color of Arooler 8460 method i Doribond Color of 1:1 Solution In Toluol Weigh (on a trip balance or oquiTalant) tfO grama of.tbs Aroolor Into a tared SCO oo beaker* AAA about SB oo olaar toluol, warm anA stir until the Aroolor la dissolved* Place beaker with eontente on belanee anA add toluol until the total content of tbe beaker la 100 grama (BO grama Aroolor end BO greus* toluol) Fill * ona-Inob Lorlbond Call with thia solution and obtain DoTlbond eolor readinga in tbs usual way. ora DSW 001477 ADA 000830 WATER PCB-SD0000045997 /9o DIRECTIONS FOR TEST NO. X4'-CT"'gS SUBJECT: effloi*nt of Expansion of Aroolors METHOD( Calculation team Bp, Or. Date _______ TOWIOIgT OF EXPANSION IB AROOOR8 Average coefficient of expansion between two glxen temperatures is calculated from speoifie crnitiu as determined by experiment ot these temperatures, Example for Aroelor 1854 Aversg* Coefficient of expansion over range from 88C to 06*0, Bp, Or, St s/es 1.6316 {Determined}- .. Bp. Or. et 66/65 1*6066 x (Calculated from shore) Bp. Or* at 66/66 1*5460 * f (Determined) fomtlei L y- x x (66 - 88) .000665 6/e/*0 Tbs fomuls is dorire 6 from l/x - l/y which gives the Vylis phonne in volume per Bait volume from 66*0 to 66*0, divided by the mother of degrees la the temperature rouge* It is not strictly eoeurete heoeuse the eoefflelent probably ehongss xltb the ehonge In temperature hut may be oonsldsred an approximate average eoefflelent for the given reage. OSH 001478 ere ADA 000831 WATER PCB-SD0000045998 DIRECTIONS FOR TEST NO. SUBJECT l Potsrmlnatlon of greening Points. ________ METHOD? The astbode below are those recommended by Baaeeroh Dept, greasing Point of Diphenyl (revised method) - Arriatr to 100 #m, of Diphenyl are plseed Is * 100 oo Griffin beaker. end heated until the entire Mane In malted. The liquid i stirred with an Anschutz (40*-105*0) thermometer. A reading U taken when the first crystals appear. If supercooling takes plane the tenperature will riee imediateljr after the first oryetele appear and beoorae constant within one minute. This ie the initial freezing point of the eaaple of Diphenyl and is no recorded. * greening Point of Arooiora For lowfraazing materials aueh aa iroolor 1&19, the reoantmended method ie an follows: Seventy euhlo centimeters of iroolor 1219 are pleoed la a 100 oo OrIffin-type beaker. Thle beaker la pleoed In turn in e 160 oe beaker. The 100 eo beaker la supported by its flared rim on the rim of the larger beaker and benge loosely in the larger beaker. The nested beakers ere non pleoed in an tee sludge. Initial greeting Point. The iroolor ie stirred vitb an Aneohutz thermometer (eeale 10 to 66*0). The temperature ie read every minute and seeds of both g-ohlorodlpbenyl end 4rohlorodlphenyl are added every minute until oryetele begin to form in the liquid. The tenperature at which oryetele are first seen to appear ie noted. Oontlnue the stirring and temperature readings at one minute intervale until a thin slurry ie obtained. In ease supercooling tokos plnos (ae it often does), s temperature rise will oeour after oryetele have appeared. In thle event, continue,the stirring and temperature readings until two or three oonsaoutive readings again show deereasing temperatures. _ The highest temperature attained after oryetele begin to appear is taken as the "initial fretting point". In oaee of no superoooling with resultent^Lso in temperature, the temperature at which oryetele firat appear Is taken aa the "initial freezing point". Bolldlfloetion Point. The 100 eo beaker is then removed from the larger beaker and placed dlreetly in the lee sludge. Temperature readings are continued until the Aroelor becomes too thick to stir or until the bulb of the thermometer is exposed. The last reliable tempera ture Is reoor&eft oo the solidification point. OSH 001479 . f ADA 000832 WATER PCB-SD0000045999 I MSL2zJL directions for test no, SUBJECT? Determination of Preening Polntn (aoafd.) METHODS Drustw Foist. The freeslng feist of the Aroolor U arbitrarily takes a* the average of tb* "initial freezing point" and the "solldlfleetion point". She "initial freezing point" and the "solidification point" should he reported along with the "freezing point". Cheek. As a oheok on the initial (Teasing point the beaker may he removed from the lee sludge, warmed in the hand, while the Aroolor le stirred with the thermometer, until the temperature la E* to 4*0. helow ' the initial freeslng point. .The beaker le then wrapped in, e towel end | held In the bend, Stirring la OOStinuad until the crystal's In the Aro- elor Just melt. The temperature at this point is reoorded as the final 'malting point. If carefully determined, the final melting point serves aa a oheok on the Initial freezing point end should not differ by more than a few tenths of e degree at moat from the initial freeslng point. . If the malting point oheok is made, the average of the final malting point end initial freezing point Is taken as the eheoked initial freezing point; 1. If earefully tarried out and if the Aroolor is frequently seodsd with both 6-ohlorodiphcnyl and 4-ohlorodlphenyl, the determination of ini tial freezing point should not require cbaoklng by the malting point method. However, the Aroolor is Very readily super--cooled so that unless great oare la token, it my he oooled several degrees below ita Initial freezing point before oryetslllsation starts. The result is that when crystallization does.set In the temperature rises but the maximum tempera ture Is mot attained end observed initial freeslng point is therefore low. I, It ia for this reeeon that the 100 oo beaker la jacketed with a larger beaker during the determination of the initial freezing point. The jacket serves to slow up the rate of oooling and insures a more accu rate determination than the method where the 100 cc beaker Is placed directly in the ioa^sludga for the determination of Initial freezing pol&tt OSH 001460 , g. On account of the abort exposed mercury ooluan of the Anschutz thermometers, corrections of observed temperatures for emergent stem are not ordinarily required. Under usual conditions of test, this correction is below 0.1*0. If conditions of test ere such that the stem correction la large, the appropriate correction should be made and recorded as a corrected temperature. Beale corrections, if any, should always be applied. 4, In the determination, tbs stirring should be oontinuoua and the temperature readings made at one minute intervale throughout the test. The change fresa the water jacket to the ice bath should bo made qulekly without Interruption of the one minute readings end the point of change to the iea bath should be indicated on the time temperature curve. ADA 000833 WATER PCB-SD0000046000 <* - ADA 000834 WATER PCB-SD0000046001 I t*4 DIRECTIONS FOR TEST NO.._____________________ SUBJECT; METHOD s Determination of Beanol Ineoluble In Solid Aroolora * Pgooe&hrs Crush about 50 grams of reala. Weigh out X gtm into a tare<3 12$ eo flask, *2d 25 do of benzol and agitBte the flask with e olrouler motion for a few minutes. Then add KB eo more of benzol, washing down the aide of the fleak. Allow to stead for 1 hour. Prepare e } Oooeh eruelbla with aa aebaatoa pad la the usual meaner and dry to oonatant weight. Arrange the crucible for filtration ty auetloa. ' niter tbo solution through the eruoible, using slight vuotioa. XJeo about 50 OO Of benzol totreaefer the iaaoluble roe toriel left adhering to tbo aides of the flask and to wash any adhering film of resin from the aides of the eruolhle. Dry the eruelhle end flask in sn oven at 105-110*0, OOOl and weigh* Add to the weight of the insoluble materiel in tho crucible any insoluble matter remnialng in the flask. Raport lnsoluhla matter ee percentage of original weight of raaln token. 1, The method described shore is the one need by the H, n. Robertson Company. r OSH 001482 ADA 000835 WATER PCB-SD0000046002 DIRECTIONS FOR TEST NO.__ SUBJECT? Vaporisation Lost St 68*0 METHOD?_________________________________ The test halos is that given to us by the H. H. -Robertson Company. They ceil for tho 100 hour lose at 150*F (60*0). procedure i, Halt slightly more then SO gram* of Aroalor in a suitable container, / being oereful mot to rsleo tho temperature higher then neoeeeery to make |tbo reels fluid. Four Into a tared shallow glass oontalner (100 allll-[ oeter Fatrl dish), aool to room temperature sod weigh. Heat for 100 houre (4 days. 4 houra) at 06*0. Is a drying oten provided with a venting outlet for awoepe of volatile matter. Remove from the oven, oool to room tenpereture and revelgh. Report lose In weight a peraantage of original weight. mss. . I 1. On eoeount of the mall vaporisation lose at 66*0, the weights must be taken very OBrefully. It la very Important In obtaining these eloeo veldts that the dish end contests he at atmospheric temperature when the weights are token. 1 g. Robertson's first description of this test called for the determination of loss efter @0. 100. end 100 houre of drying, from this dote] they drew up eurvea showing loss against time. Their latest pro cedure calls only for the loss on 100 hours drying. ore 05U 001463 ADA 000836 WATER PCB-SD0000046003 i '9C | . DIPHlENYL IN CRUDE DIPHKNSX, OB ' ' piphknVl BTiLh nomm . * * %* * ! . , ' Procedura - .. * .* V. ' . *. Transfer 100 to *00 grams of the sample' io a *50 co beaker, ` vlgb bodker.and contents on e rough bnlanoe to nearest gm#.- form beoker until contents ore '.liquid then pour *100 to 150 gretps into e *50 ec distilling, flask'wiib 10 Inch *1 stilling column attached. flewelg.h beaker end eontente, thereby obtaining by dlfferenoa the Weight of sample used, ' " . flfioe 800*0 or 400C thermometer In the top of the 10 Inch dls- | 'tilling ohiuhin In such -e way thet the top of the bulb is even with the bottom 1 pt the aide tteok outlet.' Distill off %pe diphenyl end collect in e weighed recelTl^gflek until, the thermometer r.eefis *75*0. / Weigh the receiving ' flask again end eaioulete results. ' ; ' ' ' ' f, diphenyl wt, dlphsnyjl it 100 ; . . wt. Of e.emple ' * ' Pour .the .residue In the flesi( while still' liquid into e cftseerole or pen kept for this purpose. tUnse wi,th benzol and allow to dry. . . ,fjp.P?r*Sa^ ' . `' -. . .' '' ` . ; .'The distilling flask is e *50 fco ' flask to which t 10 inch oolunrn with aide, outlet peer top is attached. The ooiwn_be indentations to Increase surface ere. "Afbestos peper nhould be wy.eppefl' opoubd the eoiumn, - ' ' v , ' ,& Maker bur.ftor is used in heating '/ the flask, Bipoe 0 high boiling point . must, be reached, the transits board or i 1, wire, gauge on which the flask rests sbpuid bate e bole nearly as large a* .'..the diameter of the flask. ' The fltoie way jelso,be applied directly to the flask ., without the use of any transits board or wire gauge, xt neeesosry, asbestos . paper should be pleoed at the top of th# flask. . . . ', 'I l06 oc distilling flcek makes a convenient raoalvsr for the distillate. bmsm. era osw 001464 ADA 000837 WATER PCB-SD0000046004 DIKLIWTRIC OOW9TANT OF ABOOLORS Oondener Definitions Axtjr sleotrloel onduetor upon which an elactrloel charge on bs stored la e sleotrloel condenser. Paj* 0,1 tonga. _(gJT^j>0|r_fiJ_ la eleotrieal condenser ana be charged with a osrteln quantity of-.at.eilo eleotrlelty, depending upon lte shape end else. This property te known as- lte eepadltenoe, end tbe fared la tfae absolute unit used, for oonvenienoe the fared la subdivided Into the atere-ferad--symbol tf (Oroek letter ), and the sieromierofared--symbol am?, A fared la de fined ee the oapeoltano* of a oondenser auoh that one ooulomb of eleotrloal energy will produce a potential dlff, of 1 volt between lte terminal a, A * lord-fared la ,000001 farad and a mloromloro-fared la ,000000000001 fared. The mleronioro-fersd la the only unit employed in Aroolor work. Meleotrio Oonstent The dlelaetrio oonatant of any Material la defined ee the ratio of the depooity of a condenser made up with e dleleatrlo of the materiel In question to the oapeolty of the same, having air as the dleleotrlo. Apparatus Beating Oven A freet-thermo-oleobrlo oven, foroed sir, serial Ho. ttl-tl, is used for heating and maintaining the Aroolor at 100*0, the testing temperature, Boles.ere drilled through the aide of the oven to aooooodnte the terminal leads, standard Oonfleoeer. Oa . This'condenser Is a Oeneral Radio Precision Oondenser, Type Xftg-L, Serial Bo, 11B9, It ba$ a fine worn gear vernier whtoh permits the sotting of this oondenser to be reed to e fraction of a mloroaloro-farsd The aoala of the standard oondenser la divided into 1000 parte by tho vernier employed, end oxooptlng the first three hundred divisions and osw lest one hundred dlvistona, the eepeolty ohanges viry uniformly with ehenga of setting, Zn other words it Is almost straight line oondenser betsssn settings of from $00 to 400 divisions. Below setting of BOO and above -MOO the line is not straight due to edge effect encountered in engaging or disengaging the plates, The oondenser .should therefore be used between BOO and 400 seal divisions (100-1450 mf). - 001485 . ada 000838 WATER PCB-SD0000046005 /Pa The oondeneer ii supplied with Its calibration obnrt showing nieromloro-fered equivalence of sods Uriel on* et each loo divisions, from thle ohert, the accompanying chart ia made, showing the onpooitenoe equivalent for eeoh possible eoele totting (Fig. 8-), Tot OondsnseE, Og Tbit oondeneer it a multlplepleta variable air eondeeser. Two euoh eoadeneere tra mode part of the epporetus, One baa-a capacity of 50 maf, (Qtntrtl Radio 834-Xt 1solantIts dialaotrlo) and tbe other a sopeolty of 100 min and toobtet its obtloua range of uatfulntat. Tbe condenser it Mounted (locally) in a reotengulcr metel ease, open at the top, and should fit oe snugly at potalbla, The rotor-shaft oonet through tba front plate of tho box and a stuffing box, peeked with itbaatoa twine. Tbe purpose of tbit box ia to oontaln tbe liquid temple tround tbe platee of tho eondeneer wbiob should, at the time of testing, be completely submerged in tbe liquid (Aroolor) Balancing OondeMer^jOa) Thle tan be any type of sir oondeneer with an effeotiTe eapaolty of 1800 jaof. 1 Oenerel Radio Type E46-I la ueed. A three plate midget tir oondeneer it ueed in parallel with thle oondeneer for vernier effeot. Oeneolty Bridge A Oenerel Radio Type 16 ie ueed, Thle ia tbe mein part of the apparatus and furnishes the arms wbiob make possible tbe balsnoing of tbe system. A rerietanoe box is provided in oonneotion with the bridge and ten be ueed in either arm. ` A. 0. Souros. 0# .. The souroe of A.O. is o Oonerol Radio pure sine wate audio osollletor, type 118*8, end Is fed by a 6 volt storage battery. MUXin., The aapllfler eonelets of two stages of audio-frequency ampli fication, USi&g two 0,1* *01-1 tubes, two audio transformers, end A, B, end 0 batteries, It is used for eoeentuatlne the null point or balenoe point. Bwltofats, M DSW 00i486 1. For sonneeting 6 volt storage battery to audio osollletor, I. for oonneetlng I volt storage battery end *Bn battery to filament snd plate of amplifier tubes. S, For placing reeletenee box in either A or B era of oepeolty bridge. , ADA 000839 WATER PCB-SD0000046006 opsooo vav i i iB * T0 "SO . ' * /2 T /F -- " oer y ; J * WATER PCB-SD0000046007 twooo vav WATER PCB-SD0000046008 ZOf JlUgEiM ' Ths two rtr*g taHtfUl used iri Tot6 automobile batteries. fh "flM bettery is *ny convenient 4S volt block, jttunr Pherger An A,O,~D,0 rectifier, teeUaghousa, style 574795, is used tor keeping the two storage batteries charged, SsskM ths sooompenytng wiring diagrams will make the hook-up eleer. Procedure tor Measurement Test Oon&aneer ' , ^ The difference la capacity between the plates opened end elosed must be Seteroinefl with *e high degree of eooureoy es possible. In this test sir Is used es the dieleotrlo medium between the pistes of the eondenser. This constant will not ohnage appreciably during Che life of the condenser, hut it Is sdrlsable to check It from time to time. The test oondsnser is pleoed In the oven (et 100*0) end allowed to ooma to temperature, Thle takes about BO minutes. The terminal a ere eonneeted to the leads from the apparatus by naans of the alrnpa provided. The plates of the' eondenser ere then turned to the elosed (maximum enpaolty) position, The rotor-sbeft will enoounter e stop peg, Oere nmet bo token BOt to turn the oondenser pletea too herd against this stop, es It might be bent, thus giving e false reading. Hut, the standard oondenser le set St szeotly 400, The two switches carrying the power supply from the batteries ere now closed, end the tuning fork os the oscillator Is prleked gently with finger sell to start It vibrating, A thle le done, e loud note will be heard In the heed-phonea, Next, tho balancing oondenser, Oe, ie turned until a minimum noise level is produced, Thle nolee level Lb further reduced by moving the reel stance oontrole end midget condenser simultaneously until the weakest signal is evident, The system ie now eld to be belenoed, both with reepeot to the onpaotty, end resistance In each era of the bridge. The reeding on the standard condoneer (400) le recorded, Kent, the test oondenser (a turned to Its minimum (open) position, until the rotor-shaft la pressed against the stop, Now, without touohtng tbs balancing condenser or midget eondenser, tho standard eondenser is turned toward a higher setting until another minimum nolea level le reached. Tbs fine balance le obtained thle time by varying tho etnnderd condenser end resistance decodes simultaneously, When s balance te reached the rend ing le recorded from thn standard oondenser a* before. Only these two feedings (400 end the lest) ere aeoessery for computing the oepeolty of the different* la position of the pistes Of the testing oondenser, The _ , .. OSW 001489 ! AOA 000642 -i WATER PCB-SD0000046009 ZOSL ' Change In re*l*tanoe necessary la Immaterial* Tha second reading *111 | founfi to Vo about 180 divisions higher for the 880 anf condenser and bout @0 division* higher for the 100 nf condenser* Tha sntlre above procedure la repeated, ualng the eoond read ing for tha next Initial setting, ato. until the range from 400 toSSOO socle divisions Is oovered, ' Each pair of readings is then translated into wmS aatown under "OaleulatlontVsnd'tha smaller subtracted from the larger to obtain tha spooltanoe difference for minimu* and maximum aettlnre of teat oondeaear using efraa.the dITlaotrienadlum. The dlfferenoea thus found era eversgad to give the oorreot oonatent for the range covertd, ,1^stlBdL8mAM The Aroolor Is poured into the condenser until it just oovered the plates* The oondenaer it then placed In the oven and allowod to re-- nslp there t*o hours before making the teat, so that it *111 eon* to 100*0, the testing tarepareture* Exactly the acne proeadure is used ee in deter mining the condenser eonatent, except that only two determinations ere taken as checks because tbs initial belenoc will be separated from the find balance by veil over half the useful scale on the standard eondenear. if the first initial reeding Is 400, the next initial reeding should be somewhere near 600, or perhaps 400, depending, or course, on the nature of the substance under examination. Also, the original setting can be tho high one provided the test condenser is at lie mlninure (open) setting. Even numbers given above are for example purposes end do not have to be used, bnt are more conven ient for calculations* gsloulatlttLS then condenaera era connected in parellel, the following, formula Obtelnet <1 (totsl gapeoity) (qi q + **) "* T *"ob ' --In this method the total capacity conalata of Oa Ox Os, Since Oe stays constant, and Oa can be found,- Ox can also be found by subtracting the initial Oe freo the Final Os* ` With the initial and final scale reading at hand it Is only seoaaeary te consult tha chart to obtain the equivalent mmfj tho smaller la subtracted from the larger to obtain the difference In wnf I- This differenoe, when taken with the liquid In tho COndonesr la divided by the constant for testing condenser (dlff* with air In the condenser) to obtain the ratio referred to In the definition of D.O., ie, the dielectric eonatent of tha material lm question* - DSW OOltSO ** M t ADA 000843 WATER PCB-SD0000046010 2 03 MsssAt final rending Inittel Dtffs/SBft* Constant for testing condenser S&0 Therefore, &,C, 1076 * 4,81 too Ssl' *194 400 mt .ftes* sbgti 1194 *18 1076 2512. la About TOO 00 Of naopJt are neoe**ry for s teat, fc, A hydrometer 1 provided for tooting, tbe storage batteries from time to time# Tbe lotteries should be disconnected from the rest of tbe set when charging' Jsllure to do this *111 ooveo a fuse to bio* out* 4 Tor D'Cf inennur einent the sample my bo heated to 100*0 on s hot plate end then poured Into the condenser without any lo.es in eoouraoyv ' A cover is provided for tbe apparatus end should be kept is piece whenever the apparatus is not In use 6' If there is any "crecklng" sound in tho receivers the tubes should be tented by a reliable Radio shop* All ooonsotlona and contests should bo kept es free as possible from dirt and grease ere OSW 001491 ADA 000844 WATER PCB-SD0000046011 Sfr800Q vav i +4 7e ` 66q * Oof WTWiW kb riwai,,<WTOiW5' <wram tto* 'im wi dNXOTfy *tvof? to sokstvaEcfrt WATER PCB-SD0000046012 9t"8000 VQV WATER PCB-SD0000046013 ZP8000 vav WATER PCB-SD0000046014 8WOOO VQV S6M00 HSO 4 * . ` . t * s ., V. \ i , . , ;> v /v'.` < * * . . :1 s s s te a s i WATER_PCB-SD0000046015 mmjmm mismm When condenser* ere need on A,0 circuits there le e energy leu Id the dieleotrlo, Thle Idee erleee through the repeated oyele of linage* of eieotrto flu* through which the dioloctrle le takes by applied eilemting voltage. Thle lose, inoreeesa with the frequency! henoe, the frequency he to be reported with the result* It nlao Terlee with the teaporoture of tho condenser, end he&ei this else must tos reported ea perl of the result* Ths "Power Feotor" is the ratio of ell energy losses is n di-- iliolrie to the "sppnrent power" Is the dleleotrlo* It is usually txprese ed Is percentage. In the teat to he deeorlbed the standard temperature used is 100*0, a6 th-.< standard frequency is 1000 eyalee per second* Bonoe, it ' le not necessary to inolude these habitual constants in reporting results* smjfe&\*r. antomipot.iw Inasmuch as the seme equipment is used for measuring power factor i dielectric oonetant, the method will he outlined, unking refcrenoe to. that iretbed* ipparatks . The epperetue !e the seme ss tbst used Is dleleatrie oonetant soeeureraent sxospt for the testing cell* A drswing of the cell la ettsohsd (figure i). It consists of i Cylinders Of the dimensions shown and t# oattlnsd Is an BOO oo Griffin Beaker* In the eesemhtr the beaker contain ing the oeli la plaosd lo the oten in the same piece es the dieleotrlo constant condenser, and le cc&neotsd to the sane leads. Due to the fact that the test 1* sffooted appreciably by small amounts of stray ourrenta, the 000 oo beaker is insulated from the iron floor by means of a glees *1" stilt, upon Which it stands, end the inner electrode is suspended from e ring stand by mobs of s gloss stirring rod, pesssd through s cork, end "hooked" St the bottom* The wire loop passing through the vert!eel red of the inner electrode Is hung on this glass hook. ' 0$U 001496 To measure the Power Taster of an Aroolor, the test cell is filled about two thirds full of the liquid, and the leads connected, ee in dielectric constant measurement. The standard condenser Is set on about 1600 scale reading and the system brought to belanos ss directed in the dtteotrLc oohstent prooodurs, The Ce reeding end si so the resistance reeding ere noted* The one of the leads le disconnected outside the oven, ere being taken to move the two ends as little ee possible from their to&nected position, end the system again brought to balance by manipulating yy' the owteenndWarCd' j*fk&>kdeli&t#f*t>l'''WAbdl t^'eljrjjinc* decodes* The nyw mreadings end Wre M'*? :A? '' '"iV- $!&X-. - ADA 000849 WATER PCB-SD0000046016 Zop Oslottlatlons ft* equation for 1*1 as obtained by our Instruments lot r#n . R, * Bealstands reeling corresponding to 0at* Bj Reel stance reading eorreeponding to Oei* 0s8 Largest reading (la maf) oa std* oond*nsar* 0* * Bnalleet reading (la aaaf) on atd oondcnetr* f * STeiueney la oyoles per second, -Ejtewpla 0** 1900 *ole reading 995*0 Jtnf ' ''' 0s8 w 1981 soela reeding 1194*9 aaf Pa * 180 ohm* (reading on decades) It* * 105 olna (reading on decades) X , * 1000 C.p.s. ` ii . 11C21x1aM (elide rule) (1) The inner electrode should he suspended ee nearly ea possible in the center of the outer electrode (I) Zt R, -- B8 le negetltc, the means that the power factor Is o low that It la within the lower limit of mseauremeht (<&,) of the apparatus, In this ease it le reported ae 0, (9) The same general notes under dleleotrie constant also apply to power factor* trs DSM 001497 v -.vxn.vx <* t. it*J5^n*T.v>r *<}, 'U' ADA 000850 WATER PCB-SD0000046017 4 it, v *'W)rrrf?:-v- ,'iul;W.''`./J!^'M J'ACl'On CBM,- ' *Vd He. 4 Vv: 'y fj t'*---'*:. i ...> .. - j, ' HI} 1 ; ,, 1 v . \* `r-y /; ------------------ *---- r:l/<. *r ** 4 V'--" .. \. -.v iV, -t- : & T* .. ** \ i i /;' . rt* * i i* i 4 T * -"*- i < *: *1V !>* A 4M .t y < ** * r . * *> - V i* Sr **! ,,\ i *' 14 I A i U>:-:r <' `i * ,4 J'j- ;-v \hy. /.M K ;-------- >1 * " ' *' . ' < t '. . . -i ;i * ' '' '';' "> : .v'-i'i ;! ,; . ."'i :' A . ........................ ADA 000851 WATER PCB-SD0000046018 WATER PCB-SD0000046019 * mmofii wwm tmptonon pkpahtmekt ' 2/2 METHOD FOR jg DKTgRMIKATIOH Of &^Srfo7l Brox8Trrin or wcftiMB Binss), mm 11. im DSM 001500 ADA 000853 WATER PCB-SD0000046020 Z13 ' mmmn oT Akooims . ' fleglftlaaie. (symbol R). Obstruction to eleotrlo flow. The ratio of voltage i*)7to current (I) in o conductor or oloeed oiroult. (it t/i. Ohm's Lav)* The practical unit of raalatanoe la the oha. ' .glaoirloelJtoolBj.lyitl^B. The current which flows between two conductors Insulated front aaoh other by e dielectric la aede up of two oo- ponenta (1) that whloh flows through the dieleotrio Itself end (B) that Which flows through a surface film of moisture or other sent conducting materiel (oil, duet, or foreign matter) These components ere designated respectively ss "relume rsnietivity'1 end as "surface resistivity** . y&luroe Resistivity. Bywbol p (Oreek letter "rho".) Also called specific reel stance. Defined es the resistance between two opposite faoee of a unit oube of the substance, p > RA/h where A is orose-eeotionel area and h Is<length or the ourront psth through the substance. The prectior1 unit of realettvity is the ohn-oentlmetar (ohra-cm.). The resistivity of Aroolors is reported in multiples of 10 ohm~oa, A volume reslativity of 73 % 10 ohm-oa ts equivalent to saying that the reslstenos offered by the substance between two opposed parallel feces of 1 sq* da. each, pleocfl 1 o apart is 73 x 10 otaraa. Following the pmotiee of the General Kleotrlo Company, resistivity is measured with the substance under test (Arcelor) at 100*0. "Resistivity" ss applied to Aroolors elwtye refers to volume resistivity. Surfeos resistivity (aymbol B, Oreek latter "Siena") ie defined ss the reslstenos between two opposite edges of a square surface film. The practical unit Is the ohm-oa (between opposite edges of a film 1 am. square) 8 Rb/l where R is rseistnnos of s rsotangle of film of length l end breadth b Measurements of surfoce reststlvity *re applied to solid 4i- eleotrlos rather then to liquid. For most materials the surface resistivity is much lower than the volume resistivity* Atmospheric humidity conditions st time of measuring may frequently greatly alter tho eurfeoe resistivity. ers OSU 001501 'r t ' ' ADA 000854 WATER PCB-SD0000046021 Z/4 MAsMijS^ DlismoTiBoa Outline of Method Paing Mfgote Meter the megohm Bttir Is essentially calibrated bridge with a v soman tub* volt meter as the null Indicator, A blueprint le attached showing the elroult diagram end the brief Inetruatlon* fuyniehed by tbe neqpfeoturer . for the operation of the megohm meter, Resistivity le obteined by matching the voltage eoroee tbe P reeletor (see blueprint) with that eoroee tbe A reiietor. The reeletenoe is megobae le reed dlreotly frost the dlel eoutrol ling the'log arithraetloelly tapered rheoetet B, Thie reeding in megohms divided by O.m give* the speolflo reeletenoe In ohae x lOtyou, On. The . measurements ere Bede with the dleleotrlo under test et 100*0*, the apparatus is eultable in the range 10,000 ohae-10,000 megofan/ou. cm* About one pint of sample le required* sm}ns. Batteries; Two 45 volt Redlo .B Betterlee, eeriee oonneoted ere used. Two 1*5 volt dry eelle, eeriee oonneoted* The betterlee should be tested from tine to time by Beane of e pooket wolfooter for redlo batteries end those betterlee showing week eelle (more then e few volte below rating) should be replaoed, Betterlee ere used for e oouroe of voltage to obtain the desired steadiness elnoe otherwise the normal leakage ourrent through the dleleotrlo would be meeked by the larger currents flowing Into end out of the test eleotrodee with eeob pulsation or Irregularity of the voltage* ` Test Terminals or KXsetrodeet Brass nlokel-pleted oyllnders made ooordlng to drawing Bo. M-IW59003, mean area 191 *q. am*, spaced SB4 ok. apart* Copies of this drawing are etteohed. These terminal should be repleted as required to maintain an even eurfaoe finish. The eleotrode oonetant (Aree/Length) for these terminals is T6. See "Calibrations of XleotrodeBn for derivation of this oonetant* These test terminals msy eleo be puroheMd from tbe Central Kleotrlo Ooopeny* The aleotrodee are pleoefi on B" diameter pyrax glees piete resting on the hotton of e 000 Ml pyrex beeker to eomplet* the eleotrode assembly* Tbe oyllnders are fully immersed in tbs liquid dleleotrlo under test, ' DSW psetlnx Oveni A free tbormo-oleotrlo oven, forood sir, 00 to 160*0, else 10" x 18", serial Bo* 081-01 is used for heating the Aroolor end test eleotrodes to 100*0 at whtoh temperature the resistivity le measured* 001502 Two holes ere out through the book of the oven through which the flexible wires to the eleotrodee are introduced. Olaes tubing le used at the hole* Where the lneuleted wires oome through. Inside tbs oven, tbs wire* ere covered with porcelain beads. The ends of the wires ere joined to screw flip to which the wires from the teat eleotrodee nay be Joined when ready for measurements* . ADA 000855 1I WATER PCB-SD0000046022 ^roaedure for Rsslstlvlty Mfoaurenant fteparoVloB _of tlectrodMi Before uie, the aleotrodes, |ltii plete, end banker must be Very carefully cleaned eafl dried. Ole an first with nsell brush and betsene to rmove grime, Weeb with hot dletllled water, dry end weeh In eerbon tetrsohlorlde end dry at 100*0 for at least one hour, for cleaning after uee in Aroolor, waah with bsnncnc to remote oil Aroolor. Then waah thoroughly with olean oerbon-tetreQhlorids end dry at 100*0 for at leant 16 minutes, Po not touch with the fingera any surfacee of the electrode*, glass plot*, or baeker (whlob era to cone in oontaot with the liquid to be tested} after the last washing. Filling of Electrodes! Bait the sample to be tested to 100*0 6*0, on hot plate* Pour the eubatenoa to be tested (Aroolor) into the dried electrode assembly until the liquid entirely oovers the cylindrical eurfeoee of the electrode with l/0 to l/*w exoeee, Core must be used to ueko aura that tho lip of the aostainer, from whlob the liquid is poured, ie eleen. Tilt the beaker in suob manner tbet all elr bubbles in the Aroolor will rise to the aurfaoe, Place the beaker (containing tho electrodes and Aroolor) In the forced dreft oven which ie maintained st 100*0 ^ 5, Mobbutaments are made after about 16 minutes besting, ~ paedlng The attached page gives the method for making the readings with the General Radio Type 644->A Megohm Meter, ggm ' 1, The electrode*. are oentered ea closely as eon be judged with .the ays,_More exact centering ie not neooaasry since the average space between surfaces remain# oonstent. After centering, cere must be taken tbet the electrode position is not further disturbed by jerrlng or by vibration ' from oven motor* -1 I t, Resistivities of Aroolor# are usually msesured st the temperature of 100*0 specified by the General Elsotrlo Oompeny for testing Aroolor 1864, The usual effect of tempereture on reeletltity ia that If the dleleotrlo contains moisture, the application of bent will reduoe the moisture content end simultaneously lnorease the reslstlrlty. In the oeee of e thoroughly Ary dielectric, however, looroeet of temperature usueily ba the reverse effect. Prolonged beating of e dielectric, if in exoeas of soft or conser- vstlva working temperature, Is injurious end tends to beaten tbs breakdown of the materiel by decomposition or ebemlonl cbnnge, The Oensrol Electric Company specified tbet Aroolor 1164 after beating st 100*0 for 96 hours shell show no loss in resistivity, 6, The resistivity of Aroolors Is lowered by the presence of poler impurities such as ferric chloride or hydrooblorio sold. These pole* Im purities effect the resistivity to s greeter extent in the more liquid Aroclors then |n the viscous Aroolor* (Reference] R, B. Class). DSM 001603 ADA 000856 'R I. WATER PCB-SD0000046023 4c The resistivity of e flleleetri with extern* ting current* It usually lat* that with continuous curronte, sad dscreeses progreetlveiy ** o rule with lnOfoAte in frequency, owing to dielectric energy losses, 0, For the meeeuroroent of resistivity by the above method about 1 pint (470 1) of sample it required. 4, Duplicate Beseuromenta on one temple should ebook within about 80^. or* DSW 001504 ADA 000857 WATER PCB-SD0000046024 ztr KsgiBamTrer yaiuoes ph^rotoiob Bafaranoat BtenAnt'd Bn<rtwk for IlMttUtl S^lMtrii Oouraayj Kleotrios! Oondanaara, j)l alto trio BOLIBS SUalaUvltr ta oba-aa. Faraffis ruaofl Quarts (ordinary tamp,) Uio, Vadroa or Bonsai Uio( Oaaafle Qlaae (ordinary tamparetura) Bubber Bekallta Onglasafl Poroalaln (orfllnery tampereture) Itartla 1 to 10000 X 1018 oi to 10000 x io18 ,10 to 150 x 10** Of44 to te X lO18 10 to 10000 X 1018 100 x 10000 x 10*E 0,8 to 3 x 1018 100 to 1000 a l16 0,1 to 10 a 10 LIQUIDS Trenaformar Oil 1 transformer Oil B tritta Aatra^l (keroaane) Osetor Oil ' tthyl Jllaobol Ltnaaad Oil Oliva oil taler, Diatlllad *mlor 1864 (100*0, tOO ft) i are 490 x 10* 8100 s 10 470000 x 10 80000 x 10 8,3 X 10 80 a 10 1000 X 10 0SW 001505 ?0 x 10 100 to 800 x 10 ADA 000858 WATER PCB-SD0000046025 -V *4 "' t TYPE. 5.44*A MEGOHM MCTtR '' 1(i 6 Aft*ffc **9M-lUio*.An I I HI A 4 . 10ft A RMft1*IMCft*1M9AA ft-9 IOll R-tOtCKn *IAfflItMt IMH609*A4*A SLU% too MA WAswwjmf im tus Ammcs or c&mtum Am imAxsoos foramss 1. Xartell bettarlae or pew**t-ettppl,jr Mtt a*4 tuba* as daecrlbtd is aeeofflpenjring Inatruatloa book, page i i. Throw OR-OTF evitoh to OS end wait about two almitaa for tub# to t p before beginning aeaeuratM&te, . I. Coonoot sakaoen reeletor to % tinduit baking the *blgb-potnr- Is wlro obott > feasible. Two'or throe tnebee la eatlafastory. 4. Pt eoutrol knob (8HSC-OPSR>W-<aJAR) to CHIdt, % 6. Turn ttRO ADJtS? kaob until gslvanowatsr road* taro. " If the t of odjuaMoNt Is igeufflatest, iln fr-c or.*-* voltage flokuy probably jraaoat Is the reeletor. If the aero grift# steadily is the a dlreetlea, the prsaansa #C eapasitanae la the onkaevn reeletor la looted, la either ease, refer tt the ycrosadur* glvea la the.lnatrde~ s hoot, pegs 4. . ' - , ' . . @ Turn eootrol knob to WAfg and adjuart. OT.TJPLI nrlteh end OW dial for mto reeding of galreiwoat*. ... f, Reed resletanoe Is aegote* fro* HMOOe dial ad .tbo KOLTIPLIlft tab-* ' .. ; ' "... ,. 8. Tor more seoureU leteraloatio&a rtcbeek tfc* calvBOM*tor aero la 4 ut & above. ' * i> osw 001506 ADA 000859 i i -< WATER PCB-SD0000046026 I J . ZiS -wt f - iy t. tb MS00HK3 All' e&4 ***fl 4b* rfttalt ti li t. '' .14. It \H XULT1PLIXR la In tha 100 or .1000 yaaltios, rndUfOj t**m bf 1.00 if m Agguraoy groU* tbt 10^ It 4*alr*4, * ' FOR TOTHCT ISFORWTIOA SSI TH8 IBSfTOTOTIOT SOOt , .t -v ' 'C Vi V, OSM 001507 sill w* ADA 000860 WATER PCB-SD0000046027 1-99000 vav WATER PCB-SD0000046028 gawioi II. 8tAKHABP SPIOIFJOAMOIS 8iAii mmwki oamurc HSPgQflQI DKPAMttM OSU 001509 ADA 000862 WATER PCB-SD0000046029 p 2ZZ\ STANDARD SPECIFICATION THE SWANN CORPORATION froducl:. -Code No--i4om*ii54-i Cr*dci JLlAl..gMP&yaa ________________Date Authorked_i/l/l5 Supersedes Specification I)ated___'1L_______ . Tolerable Limits Typical Value ft Swann Chenleal Company shall teat eaeh 35O0~pound batoh of >.476 tide for shipment to Pittsfield and shall forward thair teat data together with a two-quart advanee temple for our Laboratory analysis lad release. ' fbt following art the ebeaieel, physical and eleotrioal specifications ifelob must ba mat by the Owann Chemioal Company* Born Point (A..S if*lli luwvr <; * wiy* P'M) , Ipecifio Gravity at oS0(Btftrrtd to ntr at 15wy(A8W ~g&730ff) Pour pint Usfsi P-$ff) fligher than 5500c. 46-49 seconds Baybolt Univereal. Oolor (MPA) (XB8 Method **3955618) Aoldity (XBS Method H-5955bl|1 Chlorides and Sulphates (ABTV 0117*31) Krtporation at 10000. for 6 hour* (IBS Method H-5955b2P) Lose than 1. Less than 0.01 mg. HtOH/gm of aample Kone loea than 0.4f( Dietillation Bang# (ASSM D-20) 10* point - 350*35500 50% Point * 355*36800 90j Point * 368*37500 Stability There shell be no liberation of ohlorlne or ohloridaa when the material 1b heated at 100*0 in glaaw vessels in eontaot with air for periode of at least one month. fixed Chlorine Content 53 + 0*5it osk ooisio heeietivity at 100*0 under 500 volt D,0,(lleotro flee-Drawing M*l$59wj) Ore ater than 100 x 10? ohme/om? Aging Oharaoteriatloa at 100*0 for 9o hours In air Mo lesa in resistivity over original value. hleleotrlo Oonatant at 100*>o 4*15 - 4*35 (Method h~59557*) , hielaotrle Strength (iSTM D~117*3l) Sot lees than 3O.O kilovolts. Approved by_.___________________ Approved by________________________ ____ __ Chief Cheraiel Sale* Manager /Approved by Work* Manager Authorized by Chemical Director ADA 000863 WATER PCB-SD0000046030 jr Standard Specification or The swann Corporation Product :_Woria_BLtid_Piph@niL.te4Code No^J4 6115-1113_______ Grade_Date Authorized^*. lf/fl/jf 0 OontfOl Xfifit Supersedes Specification Dated________________ _ B - Biitory .Tset Tolerable Limits TypicalValue 0 6p. Or. at $5/6500 waatphal B Dbleria 0 Aoifl Vtmbtr, Mgs HaOH/gs l.ljzfi * 1.1576 - - ~ Approved by. Approved by DSW 001511 _Approved by----------------------------------------------------------------------------- Chief Chemist Sales Msnagrer Works Manager Authorized by------ Chemical Director ADA 000864 WATER PCB-SD0000046031 ZZ4 ' ' STANDARD SPECIFICATION Of The Swann Corporation productJPlpfetayl ,..Uni4i.Code No_14Q11Q=I242 Gradet. . 0 m Control TO0t Jj , History |?#at ________________ :Dale Authorized g Supersedes Specification Dated___________________ Tolerable Limits Typical Value 0 6p. Or. at 65/65*0, Waatpbal 1*573 - 1.57$ fi { Chlorine . - 0 Aold Humber, Ilgm HaOH/gm - C Oontamlnatlom Diphenyl Mona Crystalline IrooXor Hone 42 i 0.5 Approved by__ Approved by. Chief Chemist Works Manager OSW 001512 Approved by Sales Uaniccr Authorized by______ Chemical Director ADA 000865 WATER PCB-SD0000046032 zzr Standard specification OP the Swann Corporation product . Chlorinated Diphenyl, Crude .Code 140110-1148 Grade: Aroelor 1146___________________ .Date Authorized 6 * Control Tost Supersedes Specifiedtion Dated. H Bistorj Test Tolerable Limits . ^E/ Typical Value 0 $p. Or. at 65/65*0, Westphal 1*458 - 1,440 B i, Chlorine - 0 lold Humber, Mgm HaOH/ga - 0 Contamination| Biphenyl Crystalline Aroelor Negative Negative 46. e - 46.5 OSH 001513 Approved by . Chief Chemist ` Approved by Approved by!__ Works Manager Authorized by -- ' ...-- -% Sales Manager Chemical Director ADA 000866 WATER PCB-SD0000046033 ' ' STANDARD SPECIFICATION OF The Swann Corporation Mud Ohlorlttfttdd Aroolor, Orudfcode 140110*1150 Cnd' 0 v> Oontrol Tilt B Hiitory ft it ________________________ Date Authomed-lfM# 1 Supersedes Specification Dated----------------------------- Tolerable Limits Typical Value 0 ep. Or, at 65/6500, Veatphal - B f Oblorlna - 0 loidNunber, Mg MaOH/g 4" I 0 Oontenlnatlon: Diphtayl Kigali* Crystal lino Aroolor KgatIt 1*450 - I.455 - %toved by Chief Chemlit Approved by______________________ Approved by. Authorized by____ DSU 001514 Sales Manager f!hFmtrjl Tlirector ADA 000867 WATER PCB-SD0000046034 r ZZ7 _ " . STANDARD SoPrECIFICA. TION The'Swann corporation - ^ct. Chlorinated Diphenyl. OwftgCode Nn 140110-1151 - jJOolOr_lI^4-Dale At1iorired-T*at. ! w Control Tvat 0 m^tox? S*st Supersedes Specification Dated Tolerable Limits Typical Value t Bp. Or. tt 65/6500f Wegtpha.1 1*554 - 1*559 I i Ohlorlne { &si& Suaher Mgm, KeOH/gn Contnminetiom Diphenyl negative 1 Oryatalllne Aroolor Neg&tivi I - 54*5 to 55.8 DSW 001515 (Approved by________________ _________ _______ Approved by-----------------------------------------.-- ! Chief Chemist Sales Manager lApIvovcd by_ ______________ Authorized by. Work. Manager Chemical Director ADA 000868 WATER PCB-SD0000046035 I zzs Product Standard Specification OF The swann Corporation . JSnsM_______ _____ Code No_ l0!W^ll0 Grade-.JdPOOlor~ll60--------------------------------------------------- Date Authorised---Tent. JLg/g|/jf 0 * Oo&trol TtRt Supersedes Specification Dated1__________________ H * Blotoj? S'#Tolerable Limits Typical Value 0 6p Or. at $0/90*0t Weatphal 1.613 - l*6l8 H it Chlorine . ~ 0 AelA Number, Hgm NaOH/feo * -0 Contamination* Diphenyl _. Negative Crystalline Aroolor Negative ' 59*9 to 60*3 alt tO 1.25 Approved by. Approved by _____________ Chief Chemist Approved by. Work* Manager Authorized by OSU 001516 Sites Manager Chemical Director ADA 000869 WATER PCB-SD0000046036 119 Standard Specification OP ' THE SWANN CORPORATION Product :_ahlCClBi-tJg. ___________ Code No Id0ll0-ll6g___ _ Grade:____ AjOolor ll6j__________________ Date Atho,iadl,5li?Ze'!5? 0 " Ootttrol T#t B - History Tost Supersedes Specification Dated Tolerable Limit# Typical Value 0 Bp, Or* at 90/90^0, Wwtphal 1.657 - 1*642 B ft Ohlorlno ** 0 Aold Ruaber, Mgn HaOH/gm - 0 Contamination? Diphenyl Hegativ Crystalline iroolor Negative 61.7 - 62.1 *26 Approved by.-----Approved by-- Chief Chemist Woifcs Manager Approved by. OSH 00151? ADA 000870 Sales Manager Authorized by________________ __ . .. ... __ Chemical Director WATER PCB-SD0000046037 Standard Specification OF The Swann Corporation Product 1 ahlPrla&IM..PlpM&lL>QglieCode Grade Aroolor 1166 G Control T*at B - Bistory T*at _____________ Date Authorized- 7/5/54 -it/ss/n.Supersedes Specificatioii Dated- Tolerable Limits Tvnical Value *0 Bold Itoint, 00 B Ohlorina, % 0 Contamination? Biphenyl H5 " l6$ - Heg&tm ^Changed from prOTioua specification. 15T 67.36 osu 001518 Approved by. 1# B# Dirhif Chief Chemist B* It, Col* Approved by_ Work# Unngtr Approved by Robert S Weatherly Safes Manager Paul Logo Authorized by,, Chemlcsl Director ADA 000871 WATER PCB-SD0000046038 STANDARD SPECIFICATION op i The Swann corporation ! j^ri- ChlorinatedDiphenyl. QlMCode No- U<n.lQ~ll% pjf;_____ATO<>Xor_lji9Date Authorized_____ Z/j/Si___ { Control T@St l \\ History I**t Supersedes Specification Dated----- W/&3/5JL__ , Tolerable Limits Typical Value Vi Hold Point, *0 8 Ohlorin* 0 Oontai&inatioat Dijvbsnyl 825 " 250 Htgatiy* W 66,8 x0hagd from prsTious speoifiostion OSW 001519 JL B, Osrbsr Approved by Chief Chetnitt Approved by B* B. 0olt , Works Manager Robert S, Weatherly Approved by. Sales Manager Authorized by Paul Logue Chemical Director ADA 000B72 WATER PCB-SD0000046039 I K3*. STANDARD SPECIFICATION OF The Swann Corporation M,lft; Qhlorlnataa DipheajliHB Mix pyaa r^, Nn. 1*0110-2565 tode:.--ArOfllPr_15f>5------------------------------------------------ Date Atithorlzed_Itt t-ll/jj/} $ Q Oolltrol Ttlt Supersedes Specification Dated H - History Tact . TolereWe Limits Typical Value 0 Softening Point,*0, Barratt B Softening Point,c, D36-26 B jt Ohior in 0 Acid Humber, Ma N&OH/ga 0 Blowing Test, 3 I loan at 163*0, I>6-*7 B Bp. Or. at 25/2500, J)f0-27 B i Iron 78 + 30 .- Nagpitlv & & 794 70.0 64.9 0.3 - 1,0 - *3 1*733 11 Aroolor 1565 is the pro duet of chlorinating crude High Boiler and Diphenyl (*5*75) ojji 01, ApprovcdJjy Approved by Chief Chemist Work, Manager Approved by Authorized by OSH 001520 Sales Manager Chemical Director ADA 000873 WATER PCB-SD0000046040 Z*3 STANDARD SPECIFICATION OP the Swann Corporation ProductU2lOri0j|t_d Mj&miXi_B.Ml3L0glflg_codc No.____ 140ll0-10fc Grade:---- 4rfilr_4-06j? 0 ~ Control test B ~ History test - -- Date Authorised----7/3/34------ Supersedes Specification Dated---*1/13/31- Tolerable Limits Typical Value C Soft Point, Barrett, G Std. at 78 + m SH jC Chlorine 64 - 64.6 *Ao id. Number, Ugm NaOH/gm C Contamination; Diphenyl negative Crystalline Aroelor * 77*0 64.5 *42 Aroolor 4065 is the product from chlorination of a mixture of diphenyl and distilled high boiler (60:40) to a Barratt softening point of 7800 + 2. ^Changed from previous specification. QSW 001521 Approved by___ A. JQi.JSStlSlE____________ Chief Chemist Approved by___Bobtrt B Weatherly Sabs Manager Approved by___fiiJBi__fldj Works Uanigtr Authorised by___ *jJ(0tfi. Chemical Director ADA 000874 WATER PCB-SD0000046041 234 STANDARD SPECIFICATION OF The swann Corporation product: 3e _______ Grade:___ ArC5lcr.-506.0.Date AuthorisedJ#nta,__U/.l3/3 * 0 * OO&trol T^Bt B * History fiat Supersedes Specification Dated____ _ Tolerable Limits Typical Value 0 Softening Point, Barritt, 0 116 * Tint H % Chlorine - 0 Aoid Nurnbir, Mgm NaOH/gm - 0 Oontenlnatloni Diphenyl Negative Crystalline Aroolor Negative llf 59*9 - 60.8 g.i Aroolor 5060 la distilled High Boiler chlorinated to 6O5C 01. Approved by-------Approved by. OSW 001522 Chief Chemiat Worka Manager Approved by. Authorised by-- Stic* Manager Chemical Director ADA 000875 WATER PCB-SD0000046042 f US S' Standard Specification or THE SWANN CORPORATION product igfrlgfififttga piphgnyjlj.Uisiillel____Code No__14Qni=lJU2 Grade:-- -^4^----------- ,------ ---------------------------------Date Authorised 7/?/?4______ 0 indieatis OOntrol tests Supersedes Specification Dated-. 12/25/52___ whlob ars to be nede on erery lot, ' Tolerable Limits Typical Value 0 Bp* Gr at 65/65?0* Westphal Bp. Or, at *5/2590., T0"t7 0 Lovibond color, 1*. follow #510 Pour Point, 00., 7"tfft / Visooalty at 90,900, p88~g6 *C *54-$ Distillation Range, D20 1st drop, 90 m 1 g0T I.568 + .005 0.1 0.5 50 * 55 510 515 555 - 545 I.565 - 1.572 1.574 1.595 0.1 - 0.5 ,, 17.8 to io.6 -54.0 to-54.6 82 to 87 Ooeff. of Xsrpenslon Plash Point, 0., 92-24 Fire Point, 0., D9E-24 i loss on Beating at 165 0., I>6*27 Refractive index, t00, Inline 0 laid Ruaber, Mm* RaOB/ga .01 Max. Resistivity at 10090. SOOtdo, Obm^ou Rieleotrle Constant %t 1000, 1000 ops. Power Faetor at 1000, 1000 eps. 176 - 180 m r5:P I.6169 - 1.6285 100 to 500 x 109 4o'$ 4$ ^Changed from frevlous spoolfloatlon OSW 0Q1523 Approved by_<--At He _________ Chief Chemist Apj>rovcd by R R. Pole Works Manager Approved by__ jlobort S Weatherly Sales Manager Authorized by__ P&Ul IOU6 Chemical Director ADA 000876 WATER PCB-SD0000046043 St3C Standard Sopr ecification The Swann Corporation product --flhlMiantMJ?4jJhsml,JDiiMlllfl____ Code No HOlllsl i|0_ Grade:-------------------------------------------------Date Athori2ed__l/3/34_ 0 " Ooittrol Jilt Supersedes Specification Dated. 18/85/38 B - History fast Tolerable Limits Typical Value 0 flp*0r# at 65/65POj Waatpfaail B Sp.Or* at 85/B5O0, 7D~*7 1.455 . .005 1.459 0 Oolor, iPTibond, 1", Tallow ^510 H Pour Point, 90, D97^2B *6*6 ' H Tisoorlty at 56,6 *0 Viaoosity at 54.4*0 Viaooaity at 57*70 75 - 60 ' 65.9 tid.o B Haifa point, 0 B fire Point,0 H f> loss at 163*0, d6-*7 195 0 An id Ntmber, Mgsa HaOH/pa B i> Praa Ofaiorida# 0 - .01 003 B Distillation Banga* D20-B8T let drop.O0 10* 3 1 Changed fro* prayious spaoifioation. D$W 001524 Approved by_AJBa_fittfet]P Chief Chendat -Aj>j*rovc<t by__ Be _B.._OPla , Works Manager Approved by_____ Rofaart S fth>rly Safes Manager *5 Authorized by_____ PSttl JJXO&0 Chemical Director ADA 000877 WATER PCB-SD0000046044 STANDARD SPECIFICATION . or The Swann Corporation 140111-1249 Product:-- chlorinated. .Bip^syaJ..J>titm4__code no.___ Uam-igsi______ Aroelor 1*49 Grade:------ AlOfllW -lEpl------------ ---------------------------------------Date Authorized ' Supersedes Specification Dated. , Tolerable Limits Typical Value Aroolort 1249 and ll^l are not likely to be made diraotly in the futurd but only by blending 1248 and 1250 or 1250 and I254 respectively* fb teste to be made on these Aroolors^ however pro* dueed, are the same as for Aroolor 1246. 8peeifioation limits cannot be laid down until history is obtained* DSW 001525 Approved by-----Approved by_: Chief Chemist .. Works Manager Approved by___ Authorized by... Sates Manager Chemical Director ADA 000878 WATER PCB-SD0000046045  Standard specification . THE SWANN CORPORATION toducl.'- Qhlorlaatdd piphanyl Distilled 140111-lgqQ ixoolor 1850 ( Oontrol feat I * History tilt -Date Authorized-------________il/lj/jJ! Supersedes Specification DatedTolerable Limits Typical Value {Sp.Or. at 65/65*0, Weatphal I Bp.Or. at I5/S5*0. 70-|7 . .. g Bolor, lovibond, 1% Tallow f510 I Visoosity at >8,9*0 m [ B Hash Toint, OO, I>92-< IB lire Point, *0, I>92-*4 B Lost at I6500, 6"i7 1B Pour Point, OO, Bg7"*& 0 laid Humber, U&a BaOH/pi B ft Fra* Chlorides S Distillation Banfe, D20-88T :lat drop, 0 IH >0% ,01 Max, 1,448 58,3 BW* 97 Beo. 318 See, 198 - 198 Kona at 340 ,004 * * 538 >78 Approved by- Approved by- OSH 001526 Clvief Chemist Worlts Manager Approved byAuthorized by. Sales Manager Cfaemicat Director ADA 000679 WATER PCB-SD0000046046 Z33 STANDARD SPECIFICATION OF . . THE SWANN CORPORATION Product Grade i--. Aroelar lt6l . ' 0 w OonXXOl ftgt H - History Tt JEtiSiUlftA_____ Code NoJJOMlrlfSl_____ ----------------------------------Date Authorized___ T/.f/SM______ . Supersedes Specification Dated__ W.&IH_____ Tolerable Limits Typical Value B Bp. Or. t *5/*50, P70-I7 0 Bp* Or. at 90/9000, Weetphal x0 XoviWnd oolor, 1, yellow 510 0 H F A Oolor H Pour Point, ^c, P97"* x0 Yiaooalty at 98.900* D88-f6 B pie ti Hat ion Bang*,P20-28T let drop - St 1,63* #005 #5 - 1,00 88-98 1,648 " la6^8 1,653 - 1,638 0,4 1,4 34*9 - 58,0 91,3 - 105,0 B Ooeff, of Xxpanaion a lose at l63>C, p6~27 B Befraotlve Index, tOC, D-line *0 Aoid Humber, gm HaOH/ga 0 *- 0,01 ft Ohlorlne B ft Fee ohlorldta *0benge4 from previous apeolfieatlon* ,48 * ,56 1,6501 - 1,6517 OO48 61,4 - 61,5 OSH 001527 . A, B. Gerber Approved by_`________________ Chief Chemist B. B. Oole Approved by Works Manager Approved by_ Bobert B, Weatherly " Sales Manager Paul tofeue Authorized by_______________________________ Chemical Director ADA 000880 WATER PCB-SD0000046047 STANDARD SPECIFICATION op The SWANN CORPORATION product -Code No-- 140111-1264 endcU MSPSMtIMM mr control Tot S - History ftt. -Date AuthorizedSupersedes Specification Dated- Tolerable Limits T&H t8 lg/2l/^g g Typical Value B ep.Or. at t5/B5C, D70-27 0 oolor Lofiboni, 1", Tellow 510 0 Softening Point, Barrett, B Softoning Point, Dj6-26~*0 B i Los at l6j0, D6-t7 0 Aold Kuuber,' Mgm Ba0H/g jLroolor 1264 1 in experimental stag where re quireme nte eannot be speoified. If further produeed the above tests are desired* Approved by.. Approved by Chief Chemist Work, Manager Approved by. Authorized by OSU 001526 Sate, Manager J Chemical Director ADA 000881 WATER PCB-SD0000046048 Z4f STANDARD SPECIFICATION op THE SWANN CORPORATION Product _BliMUt4______ Code No___ 140111rli6S______ Grade 0 Control TOBt H <- Biatozy Teat _______________ _________ Date Authorized ....1/9/jt_____ Supersedes Specification Dated.__________________ Tolerable Limits Typical Value 8 Bp. or. at 5/*5*C, Pyeonometer B f loas it l6j0, I>6-17 0 Add Humber, Mgm NaOH/gm x0 Hold Point ` C Oolor f l" oubo not greater than .... ,, 05 Hex. l$5 - l6oe Standard 1*804 - i*8U .15 - .14 140 - 155 ^Changed from previous sped fie at ion* OSH 001529 Approved iy A]>provcd by 1> BOerber Chief Chemist Be Be COlt Works Manager Approved by______Bobert Be Weatborly Sates Manager Authorized by Paul Logue Chemical Director ADA 000882 WATER PCB-SD0000046049 - Standard Specification OP The Swann Corporation . Ohlorlnatod Diphenyl, Distilled m. UOlU-lg^Q Grade - c " Control T@t | Hlatory Test . ____________ Date Authorized___2Z9/_34_____ Supersedes Specification Dated__!2/2j/^l!_____ Tolerable Limits Typical Value H epOr at i5/t50, Fyonooetar ' B loss at 163*0, P6-27 .*0 Sola Point, *0 ' 0 j Moisture at 105*0 , 0 Color **5 - *55 0 ~ 1*0 Moisture Test* Dry 10 grams In moisture dish at 105*0 for 3 I hours or longer* *Changed from previous spee 1 float!os 05M 001530 Approved -------------------- Chief Chemist Approved by___ R*. --S*l*---------------------Works Manager Approved t.y R<*> trt 3 wthd y Sates Manager Authorized by.--g.tUlJfijgU Chemical Director ADA 000883 WATER PCB-SD0000046050 24S - STANDARD SPECIFICATION op THE SWANN CORPORATION ' product Pighgayl Pip till* dcode Wn, I40111-l8iq___________ i GradeL._AlO.OlOr_X6l9-------------------- ---------------------------------Date Authorized._IfJl.ti,. ll/lj/jl Supersedes Specification Dated Tolerable Limits Typical Value . Bp, Or, at t Weetphal Color1 lovibond, 1*, Tellotr #510 freezing Toint, 0 flash Tolnt, 0 J>9a~24 ?lw Toint, 0, sediment Aoid dumber, mgm JSeOH/gm 1,15 14,0 158 177 lone *005 ill of the above items should be detenained on every batoh until history Is obtained* 1 . Aroolor 1019 i a eutaotio mixture of para t5% and ortho 75% ohloro diphenyl* Approved by_____ Approved by OSW 001531 --------------------Chief Chemist Approved by________ _____ Sales Manager Works Manager Authorized by Chemical Director ADA 000884 WATER PCB-SD0000046051 "BWW" J?## Standard specification . OF The Swann Corporation Product. Ohlorlnated Diphenyl, Distilled m*. n, 140111-1048 Grade 0-KJontrOl @St .fifflMAftfllE-k.MSQ&it______Date Authorized_J'Mliu _12> j/jf Supersedes Specification Dated---------------------------- Tolerable Limits Typical Value 0 Distillation Hangs$ D20-28T but oorreoted for emergent 'tea of thermome ter* 1st drop* 0 m * 0 laid number, aa HaOB/gm 0 Color Lovibond, 1* ysllow foV) 0 Sp* ,Gr. at 65/65*0, Wastpbal 1*455 JLroolor 1648 is a Middle out from the dietillation of Aroolor II48; it is a fractional portion of JLroolor 124ft, Approved by-------- Approved by I D$W 001532 _____________ Chief Chemist Approved by---------------------- ------ ------------------ ' Seles Manager Works Manager Authorized by. Chemical Director ADA 000885 WATER PCB-SD0000046052 STANDARD SPECIFICATION op , ' the Swann Corporation Product KB MixCode No____ 14011W465 cdcu_. -Arcelor4465 6 * Control feet I - Bietory Till -Date Authorized--T lit. 12/JQ/JZ Supersedes Specitication Dated- Tolerable Limits Typical Value E 0p. On It l5/ll!o Bton g * $$/$50, Yeetphal 0 tovibond Dolor, 1"* Yellow #510 o softening Point, Barrett, o B Softening Point> O0, DjS-Po 8 Ooeff. of Sxpanefcm B * Lose at 163*0, P6*7 B ftefraotive index . 0 loll Huaber, Mga NaOH/gm. 0 Crystallisation Teat ([Dae below) 4*3 - 6.4 71 - 76 0 - .055 Hone 1.718 - 1.716 1.695 - 1.70* 4*3 - 3.3 7t5 - J6 60 - $2,7 'W9 Q06 - .03 Aroeler 4465 is the proOust obtained from distillation Of AXOOlor 4065 whlob le a Mixture of 4 distilled High Boiler ndb0$ Diphenyl ehlorlnoted to 64.8 to 64.o chlorine with Barrett softening point of 70 to 600 (Comparison standard valuta at 7) Aroolor 4465 le designated as *0oal Tar Basin, Clear? In oomspondenoe and on shipments to H. H. febertaon oo. Crystallisation Tests Transfer |04O grams of sample to s 150 to beaker, heat to 1000, add a Minute traoa of powdered Aroolor 1*60 aa teed eryatala and Maintain at. lOD-lOJoc fbr *4 hours* At and of thla tin* It whould be noted whether the seed crystal* have grown or have disappeared. Approved by-----Approved by----- DSW 001533 Chief Chemist Approved by. ------ ---------------- Works Manager Authorized by Sales Manager Chemfeal Director ADA 000886 WATER PCB-SD0000046053 *4t Standard Specification or The Swann Corporation ProductCode Nn imil-MSo Grade 0 m OOtttWl ff#% M - Bistory AM _____________ ^DaieAuthorlZcd_.*^.4*/_?3/5* Supersedes Specification Dated____________________ Tolerable Limits , Typical Value 0 lovibond Color, 1% YtllOff #$19 8 6?# or. M t5/*5o, &-70-I7 0 60ft* Point - BsrrtU# 0 B son* Point 056-16,0 8 Oosff of Expansion B loss M I6500, D6-I7 0 A0id Husibir, 80S NaOH/es H Rsfr&Stiv X4 0 Crystallisation lit0 .. iroolor 546O li ths prodnot from th# distillation of aroolor 5060 whlehis distill* High Bollsr Ohlorlnntsd to 60jC 01. OryatallUatlon Tstti Until furthtr oonalderation is sivsn to this tsst. transfer 50-40 grams to a bsaksr. nslt down, than Maintain at 100-X050 for one week, 80 to if thors is any tsndsnoy toward srystaliUation, Kxmlns daily. Apjirovcd by_.. Ajtproved by------ Chief Chemist Works Manager OSU 001534 Approved by_ Sties Manager Authorized by___ Chemical Director ADA 000887 WATER PCB-SD0000046054 STANDARD SPECIFICATION OF The Swann Corporation Frodud Aroolor Mutttr0p,rpoliag. Compound ^ 14011^103. *4T i Crsdc _J301.. . - I -- - Dale Authorized m/4/94-- Supersedes Specification Dated_____ . Tolerable Limits Typical Value Softening Point U.e.T.M.) 58*0*0 Furol Yi*oolty at, 9*90<? 45 aeoonde fax JOl Is a mixture of Aroolor 44^5 ~ and Paraffin (5400) OSH 001535 I Approved-by--------------------- , 10/33/M Chief Chemist I' ; Approved by__B--fit_COl* Approved by_______ fobart S Weatherly Sales Manager Authorized by_____ Paul lABUft m *> ADA 0008B8 WATER PCB-SD0000046055 mmm i iix. tt0M?oir! nsi iwwaori bum camion mmm mmmmt mmeuitut osw 001536 ADA 000889 WATER PCB-SD0000046056 Z+9 HSQg88AHT ABOOLOR EQUIPMENT . mt Speeifio OrOTity i041.tr . Free Ohlorjdee Color Resletlrity i Diet. Range Tieooeltjr , -------- ---------------________ - . --------------------------------------------------------------------------------- ,------------------- Available to bo toot to Hot Available _________ __________ ---------------------------------------------------------------- ,------------ Weatphal.balenoa Hubbard bottloo Oravlty Jars Spool a], hydrometer* Hose Hone Lotlbond eolorlnater Hegoba meter Cello Flee&e Condensers Shield Thermometer Ylaooalneter Iffux rooopteoloo Thermometers Weieotric .Oonetant Ofoo, Beriol Ho* 681-01 Audio f stag# amplifier Audio osoUlator Reeleteno# box Std, sir eondansar Balancing oondenser Vernier ooadeneer Oondeneer oell storage betterleo Oran tberaomete*1 Power Feotor 8am# as 0. 0 Power feotor oell iging Toil Same a reelatlvlty Loss On Hosting . . qsm 001537 Oreo with rotating ebelf Thermometer Pour Point Ohiorlno Hone oxoept tbansoeaeter S Parr bombs and tightening rook ADA 000890 WATER PCB-SD0000046057 TMT . soft, n, i Hold Pt. Hemo. Index Fleph Pt. . Bentene High Boiler r IJ-0 PAQI KO, t Available to be lent to St, LOMi SefTeqtooeter Hoi Areliable A8T,M, esombly Barrett eeeeinbljr M.O.A. tbervoneter Cleveland open oup eeeeably end thermometer Berrett diet* equipment. Freering pt. thormoneter leeh test etandards Yigreaux oolunrn OSH 001538 ADA 000891 WATER PCB-SD0000046058 DSW 001539 ADA 000892 WATER PCB-SD0000046059 ,57. gOHKDUW Of WUWMQ8 OSM 0015*0 ( ' ' ADA 000B93 WATER PCB-SD0000046060 t mum. flm% kyimt - 9m USB Mapass*tie How mt p.wa&.JwMa ' layout ItlootUaf ftw&g# IWrt Qnmad foundation for Btertfa fk & foaot fmm Iromi food task XU. WYURta WEf layout as *f fuse 1950 Bamonerelded &wetie fet fraction#ttaf OolfMi & fref ftridk Butting Hour & Humor O&ptf&f* Jteteil of illoil HuteU Of ft*ok fteinlute SWI fip&ag OtaMtttral Itool gtwwtural Iteul .. Fow&datiuau floor Orating 9 lasdruiliag Saeidf fitting* fur fraotimatlag Oolwi <ka fifing for Haraere u. MmmmM Ifig !* ioasol tiill - AmbXy 8 8 Fr*otiiUaf Ootem 9 fek# * b c gtmoteral gtuui fuf^part Mphtoyl 9till - Aatmtlr ~ s * * Alteration to pt9mt ftill 8 - Sw@y bmp 4 iufport * * luster * u - tml Bapg&ri * literati#* ^5$ C*-$@Sl @-6*01 0-9699 o~9eei 0*5590 6-5690 0*55#f 0-6B95 ogft#4 0*5596 ItSM 0~f$97 (Mf#g 0*51^ B~66 0-5681 0-568E 0-6998 0*695? 0-695? 0-6146 C-W74' 0-9870 0*9871 6*9571 6-9878 0-5455 OSW 001541 ADA 000894 WATER PCB-SD0000046061 2SS 11# SeUar Still Aaeeafcly * --* * Fmp ft Support - '* * * -Kiln Jacking Box * * Fwp Brlea Hoed Bousing 6. 8 - Motor m * * . Still Body * 1 8 - Mleoellaneou* Oeatlag* * * Funp Shaft* 7oa Trap ' and gteav Coil * * * - Still Support * * - Ooluan A Reoalrer * 8 8 - Wpiftg * * * - leater * 8 - Txteanlon to Beater , Support 8 * * - Jteoeirer A Sight Glees * * * * General Buyout 0-64W -84a c-sm 6-0418 6-8414 o-eUI 6-0487 6-0481 6-0408 0-8490 0-0491 0-0498 0-0058 0-6658 Beotrodryer - Oeaeral Iffijout 0-6460 fa Uymt - Jhsne 1056 Melting Jot Steel Supporting Structure TentJlaitag Hood ea e.a OhlorlnatPr A Fitting* Biagramatio Layout 0-0066 0-6598 0-6609 O-080S 0-0899 0-6400 0-0866 0-6068 B01 Absorbers * Layout 6o 1188 e' " Beo. 1889 a - SG.OGO Oulloti Aoi4 tmk e e. - fttt. a. - Aeid Ooollng Oolla a' - Teak for 80Ba Aoid e a - Steal Stair* ft Tower* a a a a a - Tank Oar Loading Station 0-0815 0-6606 0-0866 0-6887 0-6891 0-0417 0-0487 0-6481 0-6468 OSW 001542 ADA 000895 WATER PCB-SD0000046062 9xrm mMAmuamm Vacua* Still (Badger) - General payout 0 * - Blending Tank 0 8 - Tubejet Support 0 8 * - Monel Ton Trap 126 Still - Qenerel Layout a t _ Setting a B ,, ?ot . 8 - Raymond Bust Colledtori ft Exhaust 7an & Ductwork 8 8 ,, Hood for Flaker 0-6051 0-6078 0-6499 0-665 0-6880 c-em B-6123 0-6124 0-6478 0-6788 W/J * 6/27/55 DSW 001S43 ADA 000896 WATER PCB-SD0000046063 05 W 001544 ADA 000897 WATER_PCB-SD0000046064 Mtm m f u of twt wmrmt m om AT AHItfeTOi, ROtttfQ WAT ffllOH IS AYA&A&t FOR TRANSFER 10 raw n, umot A&osQ sits AFFROZIMATK WK0HTS, 00OTS,WC# Rfl W T, WRRITT WCHMIEftlJIQ tERmKBHT r# it followsi- imm Ootmrter fait SAMritUc Bqutpawt ChiorLasting Iqulpaeat tnr&tie AoM Fit WetllUtloa VqalfMdt OSH 001545 ADA 000898 WATER PCB-SD0000046065 668000 VQV i II ft * ' ftft ft -p>r * ^ i Iff F IH j ! *1! n*J iiii i I; {f' iI !faiphs?i1nh ?| I* ! *t r I! ! ! i ? i 1F U { au m i *6 b 'li * u V I* f MM li i ?M ? B Of I | (| ii H st I t 111 I SS Hill |$ * ! n il Mil! ! C* I * I il!! I!|! l' If h|r I \* rfi 111 5V1I*Ii 5*lHiil ff*ili I1 1 i iI { let t i ill ff*ll' s OSH 0 0 1 5 4 6 WATER PCB-SD0000046066 006000 vay DSW 00X 547 : nil I I I ill J i iJ ------! |Si !iI : i : ! i!tllf ! *ill s I it I J i S l 1s t r v- WATER PCB-SD0000046067 1.06000 VQV # HMH ii * i*i i; Nil i* t S *1 S1' &t |** l i l l l i{ m g I'* ft6 II HI I krr i ; i` |gv` fi ? V" f+ ?. i,,. rp iiiiii? iH^ ii.' v ' | 1 M i S M Ml I { ill Ml ill 05y 001548 I{ 8*2? WATER PCB-SD0000046068 OSM 0 0 1 5 4 9 I L ADA 000902 WATER PCB-SD0000046069 06000 vav WATER PCB-SD0000046070 OSSTOO MSO w)60oo vav WATER PCB-SD0000046072