Document 99oNO2n89JJ72vz1d8gDaX6DR
Louisiana Division Consolidated Audit
Hazardous Materials Transportation
Review
March 1991 Dow Confidential
DO A 077579 OONFTDFNTT Al
HAZARDOUS MATERIALS TRANSPORTATION
PLANT: Cell Service_____________________________ BUILDING: 5601_________________________________ REVIEW DATE & TIME: 3/25/92 - 8:30-10:00 A..M.
HAZARD MATERIALS TRANSPORTATION TEAM:
SUPERINTENDENT: Roddev Peebles______________ LOSS PREVENTION: Dean Smith__________________ SAFETY ENGINEER:__________________________________ TECHNOLOGY CENTER: Chlor-Alkall______________ DEPARTMENT PERSONNEL:________________________
SECTION MANAGER:___________________________ MAJOR MANAGER: Tom Austin_________________
(To be completed by the Superintendent)
3/13/9 2
DOW CONFIDENTIAL
no A 0??F80 GONFTOFNTT At
Louisiana-!!)! vision March 1991
Dow U.S.A
The Dow Chprmc.il Comiisw
I'O Uo> lr.(l
Plaouernine Lomsifin.'i
0 1 Ml
To: Plant Superintendent/Department Head
SUBJECT: HAZARDOUS MATERIALS TRANSPORTATION REVIEW (HMTR)
The HMTR audit will be part of the Louisiana Division Consolidated Audit Process. The audit will be the responsibility of the Superintendent/Department Head.
The purpose of this audit is to provide an in-depth review of our Louisiana Division hazardous materials transportation practices of materials which, if released, could possibly cause injury to the public. The audit will be reviewing the chemicals shipped or received, including the plant's waste materials with a Hazardous Materials Transportation Index (HMTI) of 2, 3, or 4. (Does not include pipeline transportation).
You should begin your preparations by reviewing the attached program guidelines and developing or updating the HMT Indexes for your plants' various chemicals and potential loss of containment from worst case transportation scenario. You will need to complete and send a copy of the review package to the Audit Facilitator ten (10) calendar days prior to the audit.
A HMTR Audit Team is required for a HMTI of 2, 3, or 4. A U.S. Area Loss Prevention Representative will be required for a HMTI of 3, or 4. A HMTI of 1 requires a review by the Superintendent and his Manager only.
NOTE:
Prompt response to the HMTI calculations is necessary.
A 30 day pre-audit notification to the U.S. Area will be necessary
for some materials. Contact Dean Smith at extension 8879 for U.S.
Area Loss Prevention Representatives as audit team members
(required for HMTI's of 3 or 4). Dean should also be contacted for a
Functional Audit Team if the HMTI of materials is 2, 3, or 4.
DO A 0005B1 GONFTDFNTTAl
March 1991 Page Two
The list of contacts below can be used as additional resources.
Ind. Hygiene Purchasing Loss Prev. HMTl CEI F&EI Safety
Gary Meier Randy Normand Buck Bailey Dean Smith Jim Gibson Maurice Oubre Don Jones
1809 8481 1539 8879 8163 8953 6097
Attached are the "Guidelines for a Hazardous Materials Transportation Review ", including the Audit Instructions which give the details about what is needed to prepare for the audit and how the audit will be conducted. If there are any questions concerning the audit, please contact me at extension 8879.
Dean Smith HMTR Functional Team Leader Building 3302D Ext. 8879
I> CD
DO A 0??f> OONFTDFNTT
CHEMICALS USED IN THE
CELL SERVICE BLOCK
H. MATLAUDIT. DO w.3/9/92: LLM
DOW CONFIDENTIAL
DO A 077583 OONFTDFNTTAl
10
ACETONE (MAY BE USED IN CA#2 AND CHLORINE BLOCKS)
ACETYLENE
AIR
ARI SANITIZER DEODORIZER (USED FOR CLEANING OF RESPIRATORS)
ASBESTOS USED IN CATHODE DRAWING AND PULP
CELL PUTTY
CHLORINE (IN CHLORINE AND CA#2 BLOCK - TURNAROUND)
COBALT NAPHENATE 6% (HARDING AGENT FOR DERAKANE)
COPPER
DERAKANE
DIESEL FUEL
(DMA) DIMETHYLANILINE (ACCELERATOR)
DB-1430 ANTI-FOAM
FREON - R22
GAS UNLEADED
HEAT
HYDROGEN (IN CHLORINE AND CA#2 BLOCKS - TURNAROUNDS)
HCL HYDROCHLORIC ACID (IN CHLORINE AND CA#2 BLOCKS - TURNAROUNDS)
KYNAR (R) 32 (BONDING AGENT)
LIGHT BULBS
LOCQUIC (PRIMER N AERSOL)
MEROPA 220 OIL
MEROPA 320 OIL
MEROPA 460 OIL
MEROPA 680 OIL
MOBILARAMA 247 OIL (METAL PRESERVATIVE)
MOBIL RARUS 427
MOBIL SHC 824
MOLUB-ALLOY CHAIN OIL 22
ROYAL PURPLE THERMYL-GLYDE (SYNTHETIC LUBRICANT IN CR-501 GEAR BOX)
MEKP (METHYL ETHYL KETONE PEROXIDE, ACTIVATES DERAKANE)
METHANES
MINI FIBERS (POLYETHYLENE)
NICKLE OXIDE (TREATMENT FOR BACKBOARD GASKET SEALER TO HELP PREVENT
CREVICE CORROSION ON TITANIUM BACKBOARDS)
NICKLE POWDERS (NOVAMET R CONDUCTIVE NICKLE)
NITROGEN
OXYGEN
PLURONIC F-108
DO A 070504 CONFTDFNTTAl
01/27/92:DW
POLYMER 1165L FLOC PST PIPE SEALANT #567 90 (1 LITER STAINLESS STEEL PST, BACKBOARD
GASKET SEALER) RANDO OIL HD68 REGAL OIL R & O 32 REGAL OIL R & O 68 REGAL OILR&O 150 REGALOILR&O 220 ROOF FLEX (USED TO FILL HOLES IN THE CONCRETE) AND (USED ON TURNAROUNDS
AT CHLORINE AND CA#2) STANNIC OXYCHLORIDE (USED IN FIT TESTING) STYRENE MONOMER (VAPORS FROM DERAKANE) SULFURIC ACID (IN CHLORINE AND CA#2 BLOCKS - TURNAROUNDS) TEFLON FIBERS (FLOUROCARBON FIBER) 7C TRANSMISSION FLUID TRITON DF-12 (WETTING AGENT) TRITION X-114 (WETTING AGENT) URSA SUPER PLUS SAE 10W URSA OIL EXTRA DUTY 30WT WELDING RODS WELD SEALANT/GRADE AA #89
01/27/92:DW
DO A 0??585 CONFTDFNTTAl
CAUSTIC SODA 50% (EXPERIMENTAL) CELL EFFLUENT TEFLON FLOUROCARBON (TEFLON FIBER) MISTRON VAPOR TALC SAFFIL - ALUMINA FIBER
H.MATLAUDIT.DOC:3/9/92:LLM
DO A 0??586 OONFTDFNT TA1
DOW CO.,. jENTiAL
11
CHEMICAL OF CONCERN: ASBESTOS
H.MATLAUDIT.DOC:3/2/92:LLM
PRODUCED FOR THE ASBESTOS DATABASE
DATE: 2 ~/2 ~ 9 7MASTER No 43 'PS 3"
DOW CONFIDENTIAL
DO A 0??587 CONFTDFNTTAl
12
February 24, 1992
Dean Smith HMTI Functional Team Leader Building 3302D
HAZARDOUS MATERIAL TRANSPORTATION INDEX ASSIGNED TO ASBESTOS IS "I"
Because asbestos is relatively inert, the FEI calculation cannot be made. The computer program is not designed for materials like asbestos (M. Oubre). Also there are no available dermal LD50 numbers to calculate skin effects (B. Heinze). Please see next two pages.
The "calculated" HMTI would be less than 1. However, asbestos is carcinogenic and with your recommendation an HMTI of 1 will be assigned.
John Lewis Cell Service
H.MATLAUDIT.DOC:3/2/92:LLM
DO A OF?588 CONF TDFNTTAl
PRODUCED FOR THE ASBESTOS DATABASE
DATE:
(2- <f ~_____ ______________
Dow cotMiSgfiftiHa.
.i 3
OCT-30-'91 13:19
ID:DOW CELL SERUICE
LA TEL HO:504-389-6070
To:
H > 4- '-(/ ^HetiT
8245 POT -L
Zi'oze
Fa* #o>
HAZARDOUS MATERIALS TRANSPORTATION
^ l&\/} $
REVIEW QUESTIONNAIRE
?/)>( 6f2>
III. HEALTH AND ENVIRONMENTAL EFFECTS
7. ^ ^ _ n F-o/z4$et>7o$ ?
1. What 1$ acute toxicity of the materials?
7c r,
- Inhalation (LC50 In ppm)
/w&n*/%,.
Dermal (LD50 In mq/ko)
nM___________________
- Oral (LD50 In mg/kg)
l. Are potential health effects reversible?
Yes [] No ft
3. Can people readily escape contaminated areas?
Yes No[] 4. What Is effect on aquatic life? ____
a/* '/UZ,
5. Does material biodegrade?
Yes [J No
6. Would a spill cause long-term groundwater toxicity problems? Yes () No JH'
7. Does material exhibit any warning properties?
Yes [] No N
6. Is material corrosive to skin?
Yes [] No pi
9. Has recommended protective equipment been tested?
Yes JA No []
10. Please Submit -
A Material Safety Data Sheet (MSDS)
-- A Transportation Equipment Data-Emergency Response Sheet
(TEDER)
DO A 022589
CONFTDFNT TAl
w** *
PRODUCED FOR THE ASBESTOS DATABA'
DATE: SzA'Z
n
Q-4
MASTER No.
qct-28-'91 MON 16:38 ID:LAD-TECH CENTER 6650 TEL NO:FAX 504 389 6160 OCT-28-'91 1H5? ID:DOW CELL SERVICE LA TEL NO;504-389-6070
8340 P01 8243 P01
to
Mflvuce
'o/zfp.
SAMPLE OUTPUT FROM LOTUS 1-E-3 PROGRAM
HAZARDOUS MATERIAL8 TRANSPORTATION REVIEW ' CEL PAEI, AND SKIN RANK CALCULATIONS (REVISED 1/14/90)
TANK CAR ' STYRENE
C/w You
P/zqvioe, Fok
As&esros, %>$
tfi/At&GZS ?
INPUT DATA
HUIIItMIIIIMlilMimilMlMMI
eEPO_CON.CENTRATIQN^>
_
IIIIIHIIntMilM
"MATERIAL FACTOR(FAEl GUIDE) .|
A NFPA HEALTH RATING (Nh) * 1 NFPA FLAMMABILITY RATING (Nl)
BTU'fiJ>gBMl.B8
"MOLECULAR WEIGHT h 1 VAPOR PRESSURE MM HO $2S DEG C
rt THERMAL INSTABILITY 06G C
PHYSICAL'STATE PENALTY
VI8COU5 LIQUID............. ,70
LIQUID.................... .
1.00
' COMPRESSED GAB..............1.30
LIQUIFIED FLAM OA8 -- 1,90
^ LBS OF PROOUCT PER CONTAINER
*' SHIPPING PRESSURE(PSI OF MATERIA
) RELIEF VALVE SETTING (LBS)
,, DERMAL 1050 FOR 8KIN EXP08URG vV
17.00
150,000 5
78 . 2,001
.V
TtJAAfKSj
x/oAtrj Cewis
fly, 0/7o p*#dfic
SUMMARY #tIIII
CEI 64.00
FAEl 142.22
SKIN RAN
0
T C4iCKP
CoWOMM*
Zftfuj'j-y aW O ^ 4
TVrr*rr TVttfS'* jWO G-'Vf*>'wA f~* A Sc^4r^.AL
c.\vc-4
IIMIIM ' M
| Mil MtlktM *!
CALCULATED FACTORS........
, YW O
CHEMICAL EXPOSURE INDEX RANKING
ACUTE HEALTH HAZARD FACTOR
ACUTE HEALTH FACTOR 8CALE
LBS VAPOR RELEASED IN 15 MIN, VAPOR QUANTITY SCALE *
DISTANCE 8CALB#
MOLECULAR WEIGHT SCALE # SHIPPING PRESSURE FACTOR THERMAL INSTABILITY FAOTOR PROCESS PENALTIES FACTOR PROCESS PENALTIES 60ALE * CHEMICAL EXPOSURE INDEX
CHEMICAL EXPOSURE SCALE If
21714.2S 1,00
8B3.6S 2.00 4.00 4.00 0.00 2.00 2.00 2.00
64.00
1.00
PRODUCED FOR THE ASBESTOS DATABASE
t*UP(TT,>l*l'llftPffil<*1
* '/ ymnnimiiit >>>m>>4
wmw .4.3/txr
-
FIRE A EXLQSION INDEX RATING
MATERIAL FACTOR GP BASE FACTOR HANDLING & TRANSFER FACTOR ACCESS FACTOR SPILL CONTROL FAQTOR FI -GENERAL PROCESS FACTOR
24.00 1.00 0.65 0.3S 0 50 2.70
SP BASE FACTOR
1.00
TOXIC MATERIALS FACTOR PROCESS OPERATION, PURGE FACT
0.40 0,30
QUANTITY IN 8TORAGE FACTOR IGNITION SOURCE FACTOR (FIRED HT
0.40 0.00
OPERATING PRESSURE FACTOR
0.09
F2-8PECIAL PROCESS HAZARDS FACT
2.19
............ .
MMItMIIKtMtMKIMIMIM.iMM
II I M
F3-UNIT HAZARD FACTOR (-F1-F2) FAEI-FIRf A EXPL08ION INDEX
5 93 142.22
FIRE A EXPLOSION RANKING
4
r>
33 ZO Tt
3-t T>
Tj 3
Z--t \\>>
--t Cn
X-> ^o0
HAZARDOUS MATERIAL COVERED IN AUDIT: ASBESTOS
NATURE OF HAZARD:
Extended exposure to certain airborne friable asbestos particles can cause asbestosis, lung cancer and mesothelioma.
Asbestos is not considered hazardous by DOT and is not regulated. It is non-flammable, non-explosive, non-reactive and does not affect the skin.
Public perception places asbestos in the "Hazardous" category.
H.MATLAUDIT.DOC:3/2/92:LLM
PRODUCED FOR THE ASBESTOS DATABASE
DATE: 3'/%.
____________________
MASTER No. jLUtfS qtu.
DOW CONFIDENTIAL
DO A 070591 OONFTDFNTTAl
14
TRANSPORATION INCIDENTS WITHIN LAST TWO YEARS: NONE
H.MATLAUDIT.DOC:3/9/92:LLM
n0 A 0??59? CONFTOFNTTAl
DOW CONFIDENTIAL
16
ITEMS REQUIRING ACTION FROM PREVIOUS HMTR AUDIT:
NONE: THIS IS THE FIRST AUDIT
H.MATLAUDIT.DOC:3/9/92:LLM
oo
OONF
DOW CONFIDENTIAL
17